TW201230959A

TW201230959A - Composition and method for controlling harmful arthropod

Info

Publication number: TW201230959A
Application number: TW100144824A
Authority: TW
Inventors: Ryo Ishikawa; Tsutomu Araki
Original assignee: Sumitomo Chemical Co
Priority date: 2010-12-08
Filing date: 2011-12-06
Publication date: 2012-08-01
Also published as: JP2012136497A; KR20130126942A; CN103237448A; WO2012077813A1

Abstract

This invention relates to a composition for controlling harmful arthropod, the composition containing chromafenozide and at least one compound for controlling riceblast selected from a group consisted of ferimzone, fthalide, kasugamycin hydrochloride, diclocymet and thiophanate methyl.

Description

201230959 六、發明說明：【發明所屬之技術領域】本發明是關於有害節肢動物防治組成物及有害節肢動物之防治方法。【先前技術】一直以來，作為有害節肢動物防治組成物的有效成分已知有許多化合物（例如，參照The Pesticide Manual-15th edition(BCPC 出版）；ISBN 978-1-901396-18-8)。【發明内容】本發明的課題是提供對有害節肢動物具有優異的防治效力的有害節肢動物防治組成物及有害節肢動物的防治方法。本發明是關於含有可芬諾（chromafenozide)與由下述的群（A)所選出的1種以上的稻熱病防治化合物的組成物，顯示相乘效果，對於有害節肢動物具有優異的防治效力者。群（A):由富米綜（ferimzone)、熱必斯（fthalide)、嘉賜黴素鹽駿鹽、雙氯氰菌胺（diclocymet )及甲基多保淨 (thiophanate methyl)所成的群0 亦即，本發明提供以下的[1]至[5]等。 [1] 一種有害節肢動物防治組成物，係含有可芬諾及由群 (A)所選出的1種以上的稻熱病防治化合物，群（A):由富米綜、熱必斯、嘉賜黴素鹽酸鹽、雙氯氰菌胺及曱基多保淨所成的群。201230959 VI. Description of the Invention: [Technical Field to Be Invented] The present invention relates to a harmful arthropod control composition and a method for controlling harmful arthropods. [Prior Art] Conventionally, many compounds have been known as active ingredients of harmful arthropod control compositions (for example, refer to The Pesticide Manual-15th edition (published by BCPC); ISBN 978-1-901396-18-8). Disclosure of the Invention An object of the present invention is to provide a method for controlling harmful arthropod control compositions and harmful arthropods which have excellent control effects against harmful arthropods. The present invention relates to a composition comprising one or more rice fever control compounds selected from the group (A) described below, which exhibits a multiplication effect and has excellent control effects against harmful arthropods. . Group (A): a group consisting of ferimzone, fthalide, gibberellin salt, diclocymet and thiophanate methyl That is, the present invention provides the following [1] to [5] and the like. [1] A harmful arthropod control composition comprising cofinine and more than one rice fever control compound selected by group (A), group (A): by Fu Mi, Thermos, Jiaci A group of oxytetracycline hydrochloride, dicyandiamide and thiopurine.

S 3 323745 201230959 [2] 如[1]所述之有害節肢動物防治組成物，其中，可芬諾與稻熱病防治化合物的重量比是50 : 1至1 : 100。 [3] —種有害節肢動物的防治方法，其包含有效量之可芬諾及由群（A)所選出的1種以上的稻熱病防治化合物施用於植物或植物的栽培地的步驟，群（A):由富米綜、熱必斯、嘉賜黴素鹽酸鹽、雙氯氰菌胺及曱基多保淨所成的群。 [4] 如[3]所述之有害節肢動物的防治方法，其中，可芬諾與稻熱病防治化合物的重量比是50 : 1至1 : 100。 [5] 如[3]或[4]所述之有害節肢動物的防治方法，其中，有害節肢動物是鱗翅目害蟲。【實施方式】本發明的有害節肢動物防治組成物是含有可芬諾及下述群（A)所選出的1種以上的稻熱病防治化合物（以下有時簡稱為本稻熱病防治化合物）。群（A):由富米綜、熱必斯、嘉賜黴素鹽酸鹽、雙氯氰菌胺 -及甲基多保淨所成的群。 - 在本發明所使用的由富米綜、熱必斯、嘉賜黴素鹽酸鹽、雙氯氰菌胺及甲基多保淨都是公知的化合物，例如記載於「The Pesticide Manual-15th edition (BCPC 出版）； ISBN 978-卜901396-18-8」的第 2U、497、904、685、350 及1036頁等。這些化合物可由市售製品獲得，或可以由公知方法製造而得。在本發明的有害節肢動物防治組成物中，可芬諾與本 4 323745 201230959 稻熱病防治化合物的含有比率並無特別的限定，但相對於可芬諾1000重量份，本稻熱病防治化合物通常在2至 1000000重量份，理想是20至100000重量份。本發明的有害節肢動物防治組成物也可以單純將可芬諾與本稻熱病防治化合物混合而成，但通常使用的是將可芬諾、本稻熱病防治化合物與惰性載體混合，必要時添加界面活性劑或其他的製劑用補助劑，使其製劑化成為油劑、乳劑、可流動劑、水和劑、顆粒水和劑、粉劑、粒劑等。前述的製劑化的有害節肢動物防治組成物是可直接或添加其他的惰性成分成為有害節肢動物防治劑而使用。在本發明的有害節肢動物防治組成物中，可芬諾與本稻熱病防治化合物的合計量通常是0. 01至99重量％，理想是0. 1至90重量％的範圍，更理想是在0. 5至70重量％的範圍。製劑化時所用的固體載體而言，可列舉如高嶺黏土、鎮1呂海泡石（attapulgite)黏土、盤脫石、蒙脫石、酸性白土、葉蠟石、滑石、矽藻土、方解石等礦物；玉米穗軸粉、胡桃殼粉等天然有機物，尿素等合成有機物；碳酸鈣、硫酸銨等鹽類；合成含水氧化矽等合成無機物等所成的微粉末或粒狀物等。液體載體而言，例如可列舉二曱苯、烷基苯、曱基萘等芳香族烴類；2-丙醇、乙二醇、丙二醇、乙二醇單乙基醚等醇類；丙酮、環己酮、異佛酮（isophorone) 等酮類；大豆油、綿實油等植物油；石油系脂肪族烴類；酯類；二曱亞砜；乙腈及水等。[3] The harmful arthropod control composition according to [1], wherein the weight ratio of the cofenfen to the rice fever control compound is from 50:1 to 1:100. [3] A method for controlling a harmful arthropod, comprising the step of applying an effective amount of cofinol and one or more rice fever control compounds selected by the group (A) to a cultivation site of a plant or a plant, A): A group consisting of Fumi, Thermos, gibberellin hydrochloride, chloricillin and sulfhydryl. [4] The method for controlling harmful arthropods according to [3], wherein the weight ratio of the cofinine to the rice fever control compound is from 50:1 to 1:100. [5] The method for controlling harmful arthropods according to [3] or [4], wherein the harmful arthropod is a lepidopteran pest. [Embodiment] The harmful arthropod control composition of the present invention is one or more rice fever control compounds (hereinafter referred to as a rice fever control compound) which are selected from the group of the following groups (A). Group (A): a group consisting of Fumi, Thermos, gibberellin hydrochloride, chloramphenicol - and methylpreservation. - a compound known in the art for use in the present invention is a compound known as "The Pesticide Manual-15th", which is a compound known as "Fusei", "Herbis", gibberellin hydrochloride, dicyandiamide and methylpreservation. Edition (BCPC); ISBN 978-b 901396-18-8", 2U, 497, 904, 685, 350, and 1036 pages. These compounds can be obtained from commercially available articles or can be produced by known methods. In the harmful arthropod control composition of the present invention, the content ratio of the Fenno and the 4 323745 201230959 rice fever control compound is not particularly limited, but the rice fever control compound is usually in the form of 1000 parts by weight of the Fenfenol. 2 to 1,000,000 parts by weight, desirably 20 to 100,000 parts by weight. The harmful arthropod control composition of the present invention may also be simply mixed with the fentanol and the rice fever control compound, but generally, the cofenfen, the rice fever control compound and the inert carrier are mixed, and if necessary, an interface is added. The active agent or other preparations are formulated into an oil, an emulsion, a flowable agent, a water and a granule, a granule water and a granule, a powder, a granule, and the like. The aforementioned formulated harmful arthropod control composition can be used as a harmful arthropod control agent by directly or adding other inert ingredients. In the harmful arthropod control composition of the present invention, the total amount of the fentanol and the rice fever control compound is usually from 0.01 to 99% by weight, preferably from 0.1 to 90% by weight, more preferably 0. Range of 5 to 70% by weight. The solid carrier used in the formulation may, for example, be a kaolin clay, an attapulgite clay, a bauxite, a montmorillonite, an acid white clay, a pyrophyllite, a talc, a diatomaceous earth, a calcite, or the like. Minerals; natural organic matter such as corn cob powder, walnut shell powder, synthetic organic compounds such as urea; salts such as calcium carbonate and ammonium sulfate; fine powders or granules formed by synthesizing inorganic minerals such as aqueous cerium oxide. Examples of the liquid carrier include aromatic hydrocarbons such as diphenylbenzene, alkylbenzene, and decylnaphthalene; alcohols such as 2-propanol, ethylene glycol, propylene glycol, and ethylene glycol monoethyl ether; acetone and rings; Ketones such as ketone and isophorone; vegetable oils such as soybean oil and cotton oil; petroleum aliphatic hydrocarbons; esters; disulfoxide, acetonitrile and water.

S 5 323745 201230959 界面活性劑而言，例如可列舉烷基硫酸酯鹽，烷基芳基磺酸鹽，二烷基磺基琥珀酸鹽、聚氧乙烯烷基芳基醚磷酸鹽、木質素磺酸鹽，萘磺酸酯甲醛聚縮合物等陰離子界面活性劑及聚氧乙烯烷基芳基醚，聚氧乙烯烷基聚丙烯嵌段共聚物，山梨糖醇脂肪酸酯等非離子界面活性劑，及烧基二曱基録鹽等陽離子界面活性劑等。其他的製劑用補助劑而言’例如可列舉聚乙烯醇、聚乙稀σ比洛酮等水溶性高分子，阿拉伯樹膠、海藻酸及其鹽，缓曱基纖維素（CMC)、三仙膠（xanthan gum)等多糖類，銘鎂矽酸鹽、氧化鋁溶膠（alumina sol)等無機物；防腐劑；著色劑及PAP(酸性磷酸異丙酯）、BHT等安定化劑等。本發明的有害節肢動物防治組成物是可用於保護植物免於對植物進行攝食、吸汁等加害的有害節肢動物（例如有害昆蟲及有害蟎）的加害。本發明的有害節肢動物防治組成物具有防治效力的有害節肢動物，例如可列舉以下的鱗翅目害蟲。二化模蛾（Chilo s叩pressalis)、三化填蛾（Tryporyza incertulus)、稻縱捲葉野螟蛾（Cnaphalocrocis medinalis)、棉捲葉野镇（Notarcha derogata)、印度穀粉填蛾（Plodia interpunctella)、亞洲玉米模（Ostrinia furnacalis)、菜娱（Hellula undalis)、早熟禾草螺 (Pediasia teterrellus)等填蛾類；斜紋夜蛾（Spodoptera litura)、甜菜夜蛾（Spodoptera exigus)、東方黏蟲 (Pseudaletia separata)、甘藍夜蛾（Mamestra brassicae)、 201230959 球菜夜蛾（Agrotis ipsilon)、黑點銀紋夜蛾（Plusia nigrisigna)、稻填蛉（Naranga aenescens)、粉斑夜蛾屬 (Trichoplusia)、棉鈴蟲屬（Heliothis)、葉蛾屬 (Helicoverpa)等夜蛾類；單帶弄蝶（Parnara guttata)等弄蝶類；紋白蝶（Pieris rapae)等白蝶類；小捲葉蛾屬 (Adoxophyes)、梨小食心蟲（Grapholita molesta)、豆捲葉模（Leguminivora glycinivorella)、豆小捲葉蛾 (Matsumuraeses azukivora)、小角紋捲葉蛾（Adoxophyes orana fasciata)、捲葉蛾（Adoxophyes honmai)、茶長捲蛾（Homona magnanima)、亂紋蘋果捲葉蛾（Archips fuscocupreanus)、蘋果蠹蛾（Cydia pomonella)等捲葉蛾類；茶細蛾（Caloptilia theivora)、潛葉蛾（Phyllonorycter ringoniella)等細蛾類；桃小食心蟲（Carposina niponensis)等蛀果蛾類；潛蛾屬（Lyonetia)的潛葉蛾；毒蛾屬（Lymantria)、毛蟲屬（Euproctis)等毒蛾類；小菜蛾 (Plutellaxylostella)等巢蛾類；棉紅鈐蟲（Pectinoph〇ra gossypiel la)、馬鈴薯塊莖蛾（phthorimaea operculel la) 荨麥蛾類，美國白蛾（Hyphantria cunea)等的燈蛾類；衣蛾（Tinea translucens)、小衣蛾（TineolaMsseiiiella) 等蕈蛾（Tineidae)類。前述有害節肢動物中，較佳例可列舉如二化螟蛾（Chi 1〇 suppressalis)、二化模蛾（Tryp〇ryza incertuius)、稻縱捲葉野填蛾（Cnaphalocrocis medinalis)、棉捲葉野填 (Notarcha derogate)、印度榖粉螟蛾（pl〇dia 7 323745 201230959 interpunctella)、亞洲玉米模（〇strinia furnacalis)、菜煩（Hellula undalis)、早熟禾草模（Pediasia teterrellus)專模蛾類；單帶弄蝶（parnara gUttata)等弄蝶類’斜紋仪蛾（Spodoptera 1 i tura)、甜菜夜蛾（Spodoptera exigus)、東方黏蟲（Pseudaletia separata)、甘藍夜蛾 (Mamestrabrassicae)、球菜夜蛾（Agrotis ipsilon)、黑點銀紋仪蛾（Plusia nigrisigna)、稻填蛉（Naranga aenescens)、粉斑夜蛾屬（Trich〇plusia)、棉鈴蟲屬 (Heliothis)、葉蛾屬（HeliC0verpa)等夜蛾類。本發明的有害節肢動物防治組成物也可使用作為防治植物病害之目的，例如可防治水稻的稻熱病（Magnap〇rthe grisea# ° 本發明的有害節肢動物防治組成物是藉由施用於植物或植物的栽培地，用以防治有害節肢動物之目的而使用。此處的植物而言，可列舉如植物的莖葉、植物的花、植物的果實、植物的種子等。 -本發明的有害節肢動物的防治方法是藉由處理本發明的有害節肢動物防治組成物而實施，具體而言，例如可列舉如莖葉撒佈等對植物的莖葉的處理，土壤處理等對植物的栽培地的處理等。在本發明的有害節肢動物的防治方法中，對植物莖葉的處理方法，具體而言，可列舉例如施用在莖葉撒佈等植物的表面的處理方法。將本發明的有害節肢動物防治組成物在植物或植物S 5 323745 201230959 The surfactant may, for example, be an alkyl sulfate salt, an alkyl aryl sulfonate, a dialkyl sulfosuccinate, a polyoxyethylene alkyl aryl ether phosphate, a lignin sulfonate. Anionic surfactant such as acid salt, naphthalene sulfonate formaldehyde polycondensate, and polyoxyethylene alkyl aryl ether, polyoxyethylene alkyl polypropylene block copolymer, sorbitol fatty acid ester and other nonionic surfactants And a cationic surfactant such as a thiol hydrazine salt. Other examples of the preparation auxiliary agent include, for example, a water-soluble polymer such as polyvinyl alcohol or polyvinylpyrrolidone, gum arabic, alginic acid and a salt thereof, slow buffered cellulose (CMC), and Sanxian gum. Polysaccharides such as (xanthan gum), inorganic substances such as magnesium citrate and alumina sol; preservatives; coloring agents, stabilizers such as PAP (acidic isopropyl phosphate) and BHT. The harmful arthropod control composition of the present invention is an injuring agent for harmful arthropods (e.g., harmful insects and harmful cockroaches) which can be used to protect plants from ingesting, sucking, and the like. The harmful arthropod control composition of the present invention has a control effect on harmful arthropods, and examples thereof include the following lepidopteran pests. Chilo s叩pressalis, Tryporyza incertulus, Cnaphalocrocis medinalis, Notarcha derogata, Plodia interpunctella , Asian corn mold (Ostrinia furnacalis), Hellula undalis, Pediasia teterrellus, etc.; Spodoptera litura, Spodoptera exigus, Pseudaletia Separata), Mamestra brassicae, 201230959 Agrotis ipsilon, Plusia nigrisigna, Naranga aenescens, Trichoplusia, cotton boll Noctuidae such as Heliothis and Helicoverpa; butterflies such as Parnara guttata; white butterflies such as Pieris rapae; Adoxophyes and P. (Grapholita molesta), Leguminivora glycinivorella, Matsumuraeses azukivora, Adoxophyes orana fasciata Adoxophyes honmai, Homona magnanima, Archips fuscocupreanus, Cydia pomonella, and other leaf-moth moths; Caloptilia theivora, Phyllonycter ringoniella, etc. Moths, Carposina niponensis, such as the fruit moth; Lyoenet's leaf miner; Lymantria, Euproctis, etc.; Plutella xylostella and other nests Moths; Pectinoph〇ra gossypiel la, phthorimaea operculel la, buckwheat moth, Hyphantria cunea, etc.; Tynea translucens, vest Moth (Tineola Msseiiiella) and other species of Tineidae. Among the above-mentioned harmful arthropods, preferred examples include Chi 1〇suppressalis, Tryp〇ryza incertuius, Cnaphalocrocis medinalis, and cotton leaf field. Filling (Notarcha derogate), Indian cockroach moth (pl〇dia 7 323745 201230959 interpunctella), Asian corn mold (〇 strinia furnacalis), Hellula undalis, Pediasia teterrellus model moth; Butterfly, such as parnara guttata, Spodoptera 1 i tura, Spodoptera exigus, Pseudaletia separata, Mamestrabrassicae, Spodoptera exigua (Agrotis ipsilon), Plusia nigrisigna, Naranga aenescens, Trich〇plusia, Heliothis, HeliC0verpa, etc. Moth. The harmful arthropod control composition of the present invention can also be used for the purpose of controlling plant diseases, for example, rice fever which can control rice (Magnap〇rthe grisea#° The harmful arthropod control composition of the present invention is applied to plants or plants by The cultivation site is used for the purpose of controlling harmful arthropods. Examples of the plant herein include stems and leaves of plants, flowers of plants, fruits of plants, seeds of plants, etc. - harmful arthropods of the present invention The method for controlling the harmful arthropod control composition of the present invention is carried out, and specific examples thereof include treatment of stems and leaves of plants such as stems and leaves, and treatment of plant cultivation sites such as soil treatment. In the method for controlling a harmful arthropod of the present invention, the method for treating the stems and leaves of the plant may, for example, be a method of treating the surface of a plant such as a stem or leaf. The harmful arthropod of the present invention is used. Control composition in plants or plants

323745 8 201230959 的栽培地處理時，其處理量會因處理的植物的種類，防治對象的有害節肢動物種類或發生程度，製劑形態，處理時期，氣象條件等而變化，但以可芬諾與本稻熱病防治化合物的合計量，對於該栽培植物場所每10000m2通常是0.5 至 lOOOOOg，理想是 5 至 lOOOOg。乳劑、水和劑、可流動性劑等通常是以水稀釋而撒佈處理。這時，可芬諾與本稻熱病防治化合物的合計的濃度通常是0. 0001至10重量％，理想是0. 0001至5重量％的範圍。粉劑、粒劑等通常是不稀釋而直接處理。本發明的有害節肢動物的防治方法是可使用於旱田、水田、草皮、果樹園等農耕地或非農耕地用。本發明是，可在栽培以下所列舉的「植物」的農耕地等，用以防治該農耕地的有害節肢動物。農作物：玉米、稻、小麥、大麥、黑麥、燕麥、高梁、棉、大豆、花生、騫麥、甜菜、油菜、向曰蔡、甘嚴、煙草等。蔬菜：茄科蔬菜類（茄子、番茄、青椒、辣椒、馬鈴薯等），葫蘆瓜科蔬菜（胡瓜、南瓜、節瓜（Cucurbi ta pepo, Zucchini)、西瓜、香瓜等）、十字花科蔬菜（油菜、蘿蔔、蕪菁、山葵、大頭菜（Kohlrabi)、白菜、包心菜、芥菜、花椰菜、菜花等），菊科蔬菜（牛旁、茼蒿、朝鮮薊、萵苣等），百合科蔬菜（青葱、洋葱、大蒜、蘆筍等），芹科蔬菜 (紅蘿蔔、歐芹、芹菜、歐洲防風草等），藜科蔬菜（菠菜、蒸菜等），薄荷科蔬菜（紫蘇、薄荷、九層塔等），草莓、甘 9 323745 201230959 藷、山芋、芋等。果樹：仁果類（蘋果、西洋梨、日本梨、木瓜海棠、榲樟（Cydon i a ob 1 onga )等），核果類（桃、李、油桃（nectar丨狀）、梅、櫻桃、杏、歐洲李（prunus domestica)等），柑橘類（溫州柑、橙、擰檬、萊姆、葡萄柚等），堅果類（栗、胡桃、榛果（€〇^1113 116士61'〇01^113¥31\1：11111^6巧^)、杏仁果、開心果、腰果、澳洲胡桃等），液果類（藍莓、小紅基、里，》、、莓、木莓等），葡萄、柿、撖欖、枇杷、香蕉、咖啡、棗椰子、可可椰子、油椰子等。果樹以外的樹木：茶、桑，花木類（夏鵑、茶花、紫陽花、山茶花、白花八角、櫻花、鵝掌楸、紫薇、金木犀 4 ) ’街道樹（日本椁（Fraxinus japonica)、樺樹、花水木、桉樹（Eucalyptus)、銀杏、紫丁香花、楓樹、櫟樹、白揚樹、短毛紫荊花、楓香、法國梧桐（piatanus)、櫸樹、曰本香柏、日本冷杉、日本鐵杉、杜松、松、本州魚鱗雲杉、曰本紅豆杉、楡、曰本七葉樹等），珊瑚樹、羅漢樹、杉、檜、變葉木、日本衛矛、紅芽石楠等。草坪：結縷草類（野結縷草、高麗結縷草等）、百慕達草類（狗牙根等）、小糠草類（bent grass)(小糠草、匍匐翦股賴、纖細剪股草等）、蘭草類（長葉草、大早熟禾等）、羊茅類（高狐草、軟羊茅、匍匐紫羊茅等）、黑麥草類（多花黑麥草、多年生黑麥草等）、鴨茅、貓尾草等。其他：花弁類（玫瑰、康乃馨、菊、洋桔梗、滿天星、非洲菊、萬壽菊、鼠尾草、矮牵牛、馬鞭草、鬱金香、翠 10 323745 201230959 菊、龍膽、百合、香堇、仙客來、蘭、鈴蘭、薰衣草、紫羅蘭、葉牡丹、櫻草、聖誕紅、唐菖蒲、嘉德麗雅蘭、雛菊、蕙蘭、海棠等），生質燃料植物（痲瘋樹、紅花、亞麻芥類、柳枝稷、芒草、草葦、蘆竹、洋麻、樹薯、柳等），觀葉植物等。上述「植物」也可是藉由基因重組技術或交配的育種法而賦予耐性的植物。實施例以下，將以製劑例及試驗例更詳細說明本發明，但本發明並非僅限定於下面的例。在以下的例中，如無特別註明份均表示重量份。製劑例1 將可芬諾5份及富米綜10份，添加於月桂基硫酸鈉4 份、木質磺酸鈣2份、合成含水氧化矽微粉末20份及矽藻土 5 9份的混合物中，充分攪拌而得水和劑。製劑例2 將可芬諾5份及熱必斯10份，添加於月桂基硫酸鈉4 份、木質磺酸鈣2份、合成含水氧化矽微粉末20份及矽藻土 5 9份的混合物中，充分攪拌而得水和劑。製劑例3 將可芬諾5份及嘉賜黴素鹽酸鹽1份，添加於月桂基硫酸鈉4份、木質磺酸鈣2份、合成含水氧化矽微粉末20 份及石夕藻土 68份的混合物中，充分攪拌而得水和劑。製劑例4 11 323745 201230959 將可芬諾5份及雙氯氰菌胺5份，添加於月桂基硫酸鈉4份、木質磺酸鈣2份、合成含水氧化矽微粉末20份及石夕藻土 64份的混合物中，充分攪拌而得水和劑。製劑例5 將可芬諾5份、富米综10份及熱必斯10份，添加於月桂基硫酸鈉4份、木質磺酸鈣2份、合成含水氧化矽微粉末20份及矽藻土 49份的混合物中，充分攪拌而得水和劑。製劑例6 將可芬諾5份、嘉賜黴素鹽酸鹽1份及熱必斯10份，添加於月桂基硫酸鈉4份、木質磺酸鈣2份、合成含水氧化矽微粉末20份及矽藻土 58份的混合物中，充分攪拌而得水和劑。製劑例7 將可芬諾5份及曱基多保淨40份，添加於月桂基硫酸鈉4份、木質磺酸鈣2份、合成含水氧化矽微粉末20 份及矽藻土 29份的混合物中，充分攪拌而得水和劑。製劑例8 藉由將可芬諾0. 5份、熱必斯2份、高嶺黏土 87. 5 份及滑石10份充分粉碎混合而得粉劑。製劑例9 藉由將可芬諾1份、嘉賜黴素鹽酸鹽0. 1份、高嶺黏土 88. 9份及滑石10份充分粉碎混合而得粉劑。製劑例10 12 323745 201230959 藉由將可芬諾0. 5份、雙氯氰菌胺0. 5份、高嶺黏土 • 89份及滑石10份充分粉碎混合而得粉劑。 - 製劑例11 藉由將可芬諾0.5份、富米綜2份、熱必斯2份、高嶺黏土 85. 5份及滑石10份充分粉碎混合而得粉劑。製劑例12 將可芬諾5份、熱必斯5份、含聚氧乙烯烷基醚硫酸銨鹽50份的白碳30份及水55份混合，藉由濕式粉碎法微粉碎而得可流動劑。製劑例13 將可芬諾5份、雙氯氰菌胺5份，含聚氧乙烯烷基醚硫酸鏔鹽50份的白碳30份及水60份混合，藉由濕式粉碎法微粉碎而得可流動劑。製劑例14 將可芬諾5份、嘉賜黴素鹽酸鹽0. 5份、雙氯氰菌胺 5份、含聚氧乙烯烷基醚硫酸銨鹽50份的白碳35份及水 54. 5份混合，藉由濕式粉碎法微粉碎而得可流動劑。製劑例15 將可芬諾10份、嘉賜黴素鹽酸鹽1份，含聚氧乙烯烧基醚硫酸銨鹽50份的白碳35份及水54份混合，藉由濕式粉碎法微粉碎而得可流動劑。製劑例16 將可芬諾10份、曱基多保淨40份，含聚氧乙烯烷基醚硫酸銨鹽50份的白碳25份及水30份混合，藉由濕式粉 13 323745 201230959 碎法微粉碎而得可流動劑。其次，將本發明效果藉由試驗例顯示。試驗例1 將可芬諾原體、熱必斯原體及雙氯氰菌胺原體l〇mg，分別溶解於含有solgen TW-20(第一工業製藥製）的丙酮 (和光純藥製）lml後，以含有展開劑（商品名：dain(註冊商標），住友化學）0.02容量％的水稀釋成為預定的濃度。又，將嘉賜黴素鹽酸鹽一水和物以含有展開劑（商品名： dain(註冊商標），住友化學）0. 02容量％的水稀釋成為預定的濃度。將可芬諾的水稀釋液與熱必斯的水稀釋液、雙氯氰菌胺的水稀釋液或嘉賜黴素鹽酸鹽一水和物的水稀釋液混合，調製成試驗用藥液。在盆中種植甘藍，培養至4葉期。一片一片剪取該甘藍的葉，在前述的試驗用藥液中浸泡處理60秒。風乾後，將該甘藍葉放入於舖有濾紙的杯（直徑120mm，高80mm)，在杯中各放養斜紋夜蛾的4齡幼蟲各10隻。處理4日後觀察供試驗的蟲的生死狀況，藉由下式校正而算出-殺蟲率。並且，試驗重複進行3次。其結果示於第1表。殺蟲率（％) = 100x(Mt-Mc)/(100-Mc)323745 8 201230959 When the cultivation site is treated, the amount of treatment will vary depending on the type of plant to be treated, the type or degree of harmful arthropods to be controlled, the form of preparation, the treatment period, meteorological conditions, etc., but with Fenfen and Ben. The total amount of the rice fever control compound is usually from 0.5 to 100 g, preferably from 5 to 100 g, per 10,000 m 2 of the cultivated plant site. Emulsions, water and agents, flowable agents and the like are usually disposed of by dilution with water. The range of the range of 0.0001 to 5% by weight, preferably 0.0001 to 5% by weight, is usually in the range of from 0.0001 to 10% by weight. Powders, granules, etc. are usually treated directly without dilution. The method for controlling harmful arthropods of the present invention can be used for agricultural fields or non-agricultural fields such as dry fields, paddy fields, turf, and orchards. According to the present invention, it is possible to control harmful arthropods in the agricultural land by cultivating a "plant" farmland as exemplified below. Crops: corn, rice, wheat, barley, rye, oats, sorghum, cotton, soybeans, peanuts, buckwheat, beets, rapeseed, sorghum, sweet, tobacco, etc. Vegetables: Solanaceae vegetables (eggplant, tomato, green pepper, pepper, potato, etc.), gourd melon vegetables (cucumber, pumpkin, zucchini (Cucurbi ta pepo, Zucchini), watermelon, cantaloupe, etc.), cruciferous vegetables (canola) , radish, turnip, wasabi, kohlrabi, cabbage, cabbage, mustard, broccoli, cauliflower, etc., compositae (cow, sage, artichoke, lettuce, etc.), liliaceae (shallot, onion, garlic, Asparagus, etc.), celery vegetables (carrots, parsley, celery, parsnips, etc.), leeks (spinach, steamed vegetables, etc.), mint vegetables (perilla, mint, nine-story tower, etc.), strawberry, gan 9 323745 201230959 Potato, hawthorn, donkey, etc. Fruit trees: pome fruit (apple, western pear, Japanese pear, papaya sea bream, Cydon ia ob 1 onga, etc.), stone fruit (peach, plum, nectarine, nectar, cherry, apricot, European plum (prunus domestica), etc., citrus (Wenzhou mandarin, orange, lemon, lime, grapefruit, etc.), nuts (chestnut, walnut, hazelnut (€〇^1113 116士61'〇01^113¥ 31\1:11111^6 Qiao ^), almond fruit, pistachio, cashew, Australian walnut, etc., liquid fruit (blueberry, small red, ri,,,, raspberry, raspberry, etc.), grape, persimmon,撖枇杷, 枇杷, banana, coffee, date palm, coconut palm, oil coconut, etc. Trees other than fruit trees: tea, mulberry, flower and wood (summer, camellia, hydrangea, camellia, white flower octagonal, cherry, gooseberry, crape myrtle, golden wood rhinoceros 4) 'Street tree (Fraxinus japonica, birch, flower water wood) , Eucalyptus, Ginkgo, Lilac, Maple, Eucalyptus, Populus, Short-haired Bauhinia, Liquidambar, Piatanus, Eucalyptus, Sakamoto Cedar, Japanese Fir, Japanese Hemlock , Juniper, Pine, Honshu Spruce, Sakamoto yew, Sakae, Sakamoto, etc.), coral tree, arboreal tree, cedar, medlar, variegated wood, Japanese lance, red bud. Lawn: Zoysia (wild knot grass, Korean knotted grass, etc.), Bermuda grass (dog root, etc.), small grass (bent grass) (small grass, scorpion, slender shear Herbaceous grass, etc., bluegrass (long leaf grass, big bluegrass, etc.), fescue (high foxgrass, soft fescue, purple fescue, etc.), ryegrass (multi-flowered ryegrass, perennial ryegrass, etc.) ), Dactylis, Timothy, etc. Other: flower buds (rose, carnation, chrysanthemum, eustoma, gypsophila, gerbera, marigold, sage, petunia, verbena, tulip, green 10 323745 201230959 chrysanthemum, gentian, lily, incense堇, cyclamen, orchid, lily of the valley, lavender, violet, leaf peony, primrose, Christmas red, gladiolus, gardeya, daisy, cypress, sea bream, etc.), raw fuel plants (jatropha, safflower, Flax mustard, switchgrass, miscanthus, grasshopper, arundo, kenaf, cassava, willow, etc., foliage plants, etc. The above "plant" may also be a plant which confers tolerance by genetic recombination technique or mating breeding method. EXAMPLES Hereinafter, the present invention will be described in more detail by way of formulation examples and test examples, but the present invention is not limited to the following examples. In the following examples, parts unless otherwise indicated indicate parts by weight. Formulation Example 1 5 parts of Coffenesol and 10 parts of Fumi Rice Complex were added to a mixture of 4 parts of sodium lauryl sulfate, 2 parts of calcium lignosulfonate, 20 parts of synthetic aqueous cerium oxide micropowder and 59 parts of diatomaceous earth. , fully stirred to get water and agent. Formulation Example 2 5 parts of Coffenesol and 10 parts of Frepirs were added to a mixture of 4 parts of sodium lauryl sulfate, 2 parts of calcium lignosulfonate, 20 parts of synthetic aqueous cerium oxide micropowder and 59 parts of diatomaceous earth. , fully stirred to get water and agent. Formulation Example 3 5 parts of Coffenesol and 1 part of gibberellin hydrochloride were added to 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 20 parts of synthetic aqueous cerium oxide micropowder, and Shiyoshizao soil 68. The mixture is thoroughly stirred to obtain water and a solvent. Formulation Example 4 11 323745 201230959 5 parts of Coventino and 5 parts of chloramphenicol were added to 4 parts of sodium lauryl sulfate, 2 parts of calcium lignosulfonate, 20 parts of synthetic aqueous cerium oxide micropowder and Shiyoshizao In 64 parts of the mixture, the mixture was thoroughly stirred to obtain water and a solvent. Formulation Example 5 5 parts of Coffenes, 10 parts of Fumio and 10 parts of Ferbis were added to 4 parts of sodium lauryl sulfate, 2 parts of calcium lignosulfonate, 20 parts of synthetic aqueous cerium oxide micropowder and diatomaceous earth. In 49 parts of the mixture, the mixture was thoroughly stirred to obtain water and a solvent. Formulation Example 6 5 parts of coffeine, 1 part of gibberellin hydrochloride and 10 parts of ferrets were added to 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, and 20 parts of synthetic aqueous cerium oxide micropowder. In a mixture of 58 parts of diatomaceous earth, the mixture was thoroughly stirred to obtain water and a solvent. Formulation Example 7 50 parts of Coventino and 40 parts of thiophene were added to a mixture of 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 20 parts of synthetic aqueous cerium oxide micropowder and 29 parts of diatomaceous earth. Medium, fully stirred to obtain water and agent. Formulation Example 8 A powder was obtained by sufficiently pulverizing and mixing 0.5 parts of ketoneno, 2 parts of ferrets, 87. 5 parts of kaolin clay, and 10 parts of talc. Formulation Example 9 A powder was obtained by thoroughly pulverizing and mixing 1 part of Coffenes, 0.1 part of gibberellin hydrochloride, 88.9 parts of kaolin clay, and 10 parts of talc. Formulation Example 10 12 323745 201230959 A powder is obtained by fully pulverizing and mixing 0.5 parts of fentanol, 0.5 parts of chloramphenicol, 89 parts of kaolin clay, and 10 parts of talc. - Formulation Example 11 A powder was obtained by sufficiently pulverizing and mixing 0.5 parts of Coffenes, 2 parts of Fumi, 2 parts of Frens, 85.5% of kaolin clay, and 10 parts of talc. Formulation Example 12 5 parts of Coffenes, 5 parts of Furbis, 30 parts of white carbon containing 50 parts of ammonium polyoxyethylene alkyl ether sulfate, and 55 parts of water were mixed and finely pulverized by wet pulverization. Flow agent. Formulation Example 13 5 parts of capfenolone, 5 parts of chloricillin, 30 parts of white carbon containing 50 parts of polyoxyethylene alkyl ether barium sulfate and 60 parts of water were mixed, and finely pulverized by wet pulverization. Degreasable agent. Formulation Example 14 5 parts of coffeine, 0.5 part of gibberellin hydrochloride, 5 parts of dicyandiamide, 35 parts of white carbon containing 50 parts of polyoxyethylene alkyl ether sulfate, and water 54 5 parts of the mixture were finely pulverized by a wet pulverization method to obtain a flowable agent. Formulation Example 15 10 parts of Coffenesine, 1 part of gibberellin hydrochloride, 35 parts of white carbon containing 50 parts of polyoxyethylene alkyl ether sulfate, and 54 parts of water were mixed by wet pulverization method. It is pulverized to obtain a flowable agent. Formulation Example 16 10 parts of Coffenesol, 40 parts of thiocarbamate, 25 parts of white carbon containing 50 parts of ammonium oxyalkyl alkyl ether sulfate and 30 parts of water were mixed by wet powder 13 323745 201230959 The method is finely pulverized to obtain a flowable agent. Next, the effects of the present invention are shown by test examples. Test Example 1 The procarbazine, the genus and the chloramphenicol were dissolved in acetone (manufactured by Wako Pure Chemical Industries, Ltd.) containing solgen TW-20 (manufactured by Kosei Kogyo Co., Ltd.). After lml, it was diluted to a predetermined concentration with water containing 0.02% by volume of a developing agent (trade name: dain (registered trademark), Sumitomo Chemical Co., Ltd.). Further, the carbachol hydrochloride monohydrate was diluted to a predetermined concentration with water containing a developing agent (trade name: dain (registered trademark), Sumitomo Chemical Co., Ltd.) of 0.02% by volume. The water dilution of the fenfenol is mixed with the water dilution of the carbacetal solution, the aqueous dilution of the chloricillin or the aqueous dilution of the salbutamycin hydrochloride monohydrate, to prepare a test solution. Cabbage is planted in pots and cultured to the 4-leaf stage. The leaves of the cabbage were cut out one by one, and immersed in the aforementioned test solution for 60 seconds. After air drying, the cabbage leaves were placed in a cup covered with filter paper (120 mm in diameter and 80 mm in height), and 10 of the 4th instar larvae of the Spodoptera litura were stocked in the cup. After 4 days of treatment, the life and death of the tested insects were observed, and the insecticidal rate was calculated by the following formula. Also, the test was repeated three times. The results are shown in Table 1. Insecticidal rate (%) = 100x(Mt-Mc)/(100-Mc)

Mt :在供試驗的化合物處理群t的死蟲率（％)Mt : dead insect rate (%) of the treated group in the test compound

Me :在供試驗的化合物未處理群中的死蟲率（％) 14 323745 201230959 第1表供試驗的化合物濃度（ppm) 殺蟲率（％) 可芬諾 0. 25 46. 7 可芬諾+熱必斯 0. 25+0. 025 63. 3 可芬諾+熱必斯 0. 254-0. 25 70 可芬諾+熱必斯 0. 25+12. 5 73. 3 可芬諾+雙氣氰菌胺 0. 25+0· 125 83. 3 可芬諾+雙氣氰菌胺 0. 25+0. 25 80 可芬諾+雙氯氰菌胺 0. 25+2. 5 70 可芬諾+嘉賜黴素 0. 25+0. 025 73. 3 可芬諾+嘉賜黴素 0.25+0.25 76. 7 可芬諾+嘉賜黴素 0. 25+2. 5 73. 3 試驗例2 將可芬諾原體及富米綜原體10mg，分別溶解於含有 solgen TW-20(第一工業製藥製）的丙酮（和光純藥製）lml 後，以含有展開劑（商品名：dain(註冊商標），住友化學） 0. 02容量％的水稀釋成為預定的濃度。將可芬諾的水稀釋液與富米綜的水稀釋液混合，調製成試驗用藥液。在盆中種植甘藍，培養至4葉期。一片一片剪取該甘藍的葉，在前述的試驗用藥液中浸泡處理60秒。風乾後，將該甘藍葉放入於舖有滤紙的杯（直徑120mm，高8Omm)，在杯中各放養斜紋夜蛾的4齡幼蟲各10隻。處理4日後觀察供試驗的蟲的生死狀況，藉由下式校正而算出殺蟲率。試驗重複進行3次。其結果示於第2表。殺蟲率（°/〇 = 100x(Mt-Mc)/(100-Mc). 15 323745 201230959Me : Dead insect rate (%) in untreated group of tested compounds 14 323745 201230959 Table 1 Compound concentration for test (ppm) Insecticidal rate (%) Coventino 0. 25 46. 7 Coventino + 热必斯0. 25+0. 025 63. 3 Coventino + Hotbis 0. 254-0. 25 70 Coventino + Hotbis 0. 25+12. 5 73. 3 Coventino + 5+ 可可诺 + 双双 + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +芬诺+嘉嘉霉素 0. 25+0. 025 73. 3 fenfenol + carnamycin 0.25+0.25 76. 7 fenfenol + carnitrol 0. 25+2. 5 73. 3 test Example 2 10 mg of cofino and protoplasts were dissolved in 1 ml of acetone (manufactured by Wako Pure Chemical Industries, Ltd.) containing solgen TW-20 (manufactured by Kokusai Kogyo Co., Ltd.) to contain a developing agent (trade name: Dain (registered trademark), Sumitomo Chemical) 0. 02% by volume of water diluted to a predetermined concentration. The water dilution of the fentanol was mixed with the water dilution of the Fumi-type complex to prepare a test solution. Cabbage is planted in pots and cultured to the 4-leaf stage. The leaves of the cabbage were cut out one by one, and immersed in the aforementioned test solution for 60 seconds. After air drying, the cabbage leaves were placed in a cup with a filter paper (120 mm in diameter and 8 mm in height), and 10 of the 4th instar larvae of the Spodoptera litura were stocked in the cup. After 4 days of treatment, the life and death of the tested insects were observed, and the insecticidal rate was calculated by the following formula. The test was repeated 3 times. The results are shown in the second table. Insecticide rate (°/〇 = 100x(Mt-Mc)/(100-Mc). 15 323745 201230959

Mt :在供試驗的化合物處理群中的死蟲率（°/〇)Mt : mortality rate in the compound treated group for testing (°/〇)

Me :在供試驗的化合物未處理群卡的死蟲率（％) 第2表供試驗的化合物濃度（ppm) 殺蟲率（％) 可芬諾 0. 25 66. 7 可芬諾+富米综 0. 25+0. 025 96. 7 可芬諾+富米綜 0. 25+0. 5 90 可芬諾+富米綜 0. 25+2. 5 90 試驗例3 將可芬諾原體及曱基多保淨原體l〇mg，分別溶解於含有solgen TW-20(第一工業製藥製）的丙酮（和光純藥製） lml後，以含有展開劑（商品名：dain(註冊商標），住友化學）〇. 02容量％的水稀釋成為預定的濃度。將可芬諾的水稀釋液與曱基多保淨的水稀釋液混合，調製成試驗用藥液。在盆中種植甘藍，培養至4葉期。一片一片剪取該甘藍的葉，在前述的試驗用藥液中浸泡處理60秒。風乾後，將該甘藍葉放入於鋪有濾紙的杯（直徑120mm，高80mm)，在杯中各放養斜紋夜蛾的4齡幼蟲各10隻。處理4曰後觀察供試驗的蟲的生死狀況，藉由下式校正而算出殺蟲率。試驗重複進行3次。其結果示於第3表。殺蟲率（％) = 100x(Mt-Mc)/(100-Mc)Me : Dead insect rate (%) of the untreated group card of the test compound. Table 2 Compound concentration for the test (ppm) Insecticidal rate (%) Coventino 0. 25 66. 7 Coventino + Fumi Comprehensive 0. 25+0. 025 96. 7 Coventino + Fumi Comprehensive 0. 25+0. 5 90 Coffin + Fumi Comprehensive 0. 25+2. 5 90 Test Example 3 Cofinogen And 曱多多保原 , , , , , , , , , , , , sol sol sol sol sol sol sol sol sol sol sol sol sol sol sol sol sol sol sol sol sol sol sol ( ( ( ( ( ( ( ( ( ( ( ( ), Sumitomo Chemical) 〇. 02% by volume of water is diluted to a predetermined concentration. The water dilution of the fentanol was mixed with a hydrazine-based water dilution to prepare a test solution. Cabbage is planted in pots and cultured to the 4-leaf stage. The leaves of the cabbage were cut out one by one, and immersed in the aforementioned test solution for 60 seconds. After air drying, the cabbage leaves were placed in a cup covered with filter paper (120 mm in diameter and 80 mm in height), and 10 of the 4th instar larvae of the Spodoptera litura were stocked in the cup. After 4 weeks of treatment, the life and death of the tested insects were observed, and the insecticidal rate was calculated by the following formula. The test was repeated 3 times. The results are shown in Table 3. Insecticidal rate (%) = 100x(Mt-Mc)/(100-Mc)

Me :在供試驗的化合物未處理群中的死蟲率（％) 16 323745 201230959 第3表供試驗的化合物濃度（ppm) 殺蟲率（％) 可芬諾 0. 25 46. 7 可芬諾+曱基多保淨 0. 25+0. 025 76. 7 可芬諾+甲基多保淨 0.25+0.5 86. 7 可芬諾+甲基多保淨 0. 25+2. 5 76. 7 【圖式簡單說明】無【主要元件符號說明】無 s 17 323745Me : mortality rate in the untreated group of the tested compound (%) 16 323745 201230959 Table 3 Compound concentration for testing (ppm) Insecticidal rate (%) Coventino 0. 25 46. 7 Coventino + 曱基多保净0. 25+0. 025 76. 7 芬芬诺+methyl多保净0.25+0.5 86. 7 芬芬诺+methyl多保净0. 25+2. 5 76. 7 [Simple description of the diagram] No [Main component symbol description] No s 17 323745

Claims

201230959 VII. Scope of application for patents: 1. A harmful arthropod control composition containing more than one rice fever control compound selected by Coventino and by group (A), group (A): by Fumi comprehensive Ferimzone), fthalide, kasugamycin hydrochloride, diclocymet, and thiophanate methyl. 2. A harmful arthropod control composition as described in claim 1 wherein the weight ratio of coventino to rice fever control compound is 50:1 to 1:100. 3. A method for controlling harmful arthropods, comprising the step of applying an effective amount of cofinol and one or more rice fever control compounds selected by the group (A) to a cultivation site of a plant or a plant, group (A) ): A group consisting of Fumi, Thermos, gibberellin hydrochloride, chloricillin and sulfhydryl. 4. The method for controlling harmful arthropods according to claim 3, wherein the weight ratio of the fentanol to the rice fever control compound is 50:1 to 1:100 〇5. The method for controlling harmful arthropods according to Item 4, wherein the harmful arthropod is a lepidopteran pest. 323745 201230959 IV. Designated representative map: (1) The representative representative of the case is: (). (There is no picture in this case) (2) The symbol of the symbol of this representative figure is simple: (none) 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: This case does not represent the chemical formula 2 323745