TW201229143A - Colored resin composition for color filter and color filter using the composition - Google Patents

Abstract

This invention is related to a colored resin composition for color filter comprising a color material compound represented by following formula (1) (wherein, R1 to R6 each in dependently represents C1-C30 alkyl, aryl, halogen atom or amino; Y represents a sulfur atom, an oxygen atom, an amino, a substituted or non-substituted carbon atom; R1 and R2, R2 and R3, R3 and carbon atom of Y, or R4 and R5 each independently/or may simutaneonsly form aliphatic saturated hydrocarbon ring structure or aromatic ring structure; anion part of X<SP>-</SP> represents a halogno C1-C10 alkylsulfonylimidoanion, a halogeno C1-C10 alkylsulfonyl methide anion, or a halogeno C1-C10 alkylsulfonato anion, the substitution number of halogen atoms in each halogeno C1-C10 alkyl is at least (3), binder resin, solvent, polymerization initiator and curing agent, and a color filter having a cured layer of the composition. The color filter of the invention is more excellent in thermoresistance when compared to prior dye color filter, and a high contrast ratio can be reached in comparison with prior pigment color filter.

Description

201229143 VI. Description of the Invention: [Technical Field] The present invention relates to a coloring resin composition for forming a color filter, a color filter formed therewith, and a color filter formed using the color filter An electronic display device such as a liquid crystal display device, an image sensor (CCD, CMOS), or an organic EL display. [Prior Art] Image sensor (CCD, CMOS) used in liquid crystal display devices such as notebook computers, LCD TVs, and mobile phones, and input devices such as digital cameras and color photocopiers. Colorization requires a color stencil. The methods for producing the color filter used in the liquid crystal display device and the solid-state imaging device include a dyeing method, an electrodeposition method, a printing method, a pigment dispersion method, etc., but in recent years, a pigment dispersion method has been the mainstream. The method of patterning is represented by a photolithography method using a mixture of a photosensitive resin composition and a pigment dispersion to form a color filter. Recently, there has also been a method of ink-jet printing a colored ink without directly applying a mask to a substrate to form a color filter. Color purity, chroma, brightness, and contrast are important to enhance the characteristics required for color filters. By increasing the brightness, it is possible to suppress the amount of backlight and reduce the power consumption, which is a technology that is necessary for the environment. In order to increase the color purity of the color filter and increase the content of the coloring pigment, it is necessary to select a pigment having a better spectral waveform. On the other hand, it is necessary to increase the transmittance because of the increase in brightness, so it is necessary to reduce the pigment concentration or thinner the film 4 323679 201229143 film. In order to carry out the pigment microparticles in combination with these opposite characteristics, there is a limit in resistance and dispersion stability, and improvement in brightness and resistance are currently not achieved. Further, Patent Document 5 discloses a rheological improvement method of C.I. Pigment Red 177, which is a method of disposing a telluride of C.I. Pigment Red 177 in a composition containing C.I. Pigment Red Π7. However, it does not touch the application of color filters. As a method for solving such problems, a review of a color calender using a dye is carried out. When a dye is used, it has a purity and brightness which cannot be achieved by a pigment, and since there is no particle, light scattering can be suppressed to enhance contrast. advantage. However, dyes are more inferior to pigments in terms of durability such as light resistance and heat resistance, and it is generally difficult to satisfy the financial properties and heat resistance required for a display body requiring long-term reliability such as a television. For example, in the following Patent Documents 1 and 2, a color calendering sheet using a triphenyldecane-based compound is reported, but the triphenylnonane-based compound is significantly inferior in light resistance and heat resistance, and is not in a practical grade. Further, in Patent Documents 3 and 4, a color filter using a methine dye compound is reported, but for organic EL, it is limited to use in which resistance such as heat resistance is not required, and no related resistance is described. The data. Although these dyes are excellent in color characteristics, dye compounds which are suitable for use in liquid crystal displays and which require high heat resistance are hardly practical. Therefore, a high-quality color filter which is excellent in color characteristics and excellent in durability is desired as a next-generation color filter. [References] (Patent Document) 323679 5 201229143 Patent Document 1: Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. JP-A-2009-134906 (Patent Document 5) JP-A-63-172772 SUMMARY OF THE INVENTION (Problems to be Solved by the Invention) An object of the present invention is to provide a colored resin composition which can provide a sharp contrast color A highly reliable color filter having excellent properties and excellent heat resistance, and a color filter using the composition. (Means for Solving the Problem) As a result of intensive studies to solve the above problems, the present inventors have found that a colored resin composition containing a specific color material compound is used as a color filter pixel, whereby the above problem can be solved, thereby completing the present invention. . In other words, the present invention relates to the following invention. (1) A colored resin composition for a color filter comprising a color material compound represented by the following formula (1), a binder resin, a solvent, a polymerization initiator, and a hardener;

(wherein, 匕 to R6 each independently represent a hydrogen atom, a Cl to C30 alkyl group, an aryl group, a halogen atom or an amine group, and Y represents a sulfur atom, an oxygen atom, an amine group, 6 323679 201229143 a substituted or unsubstituted carbon atom , 1 and Rz, 匕 and R3, 匕 and γ carbon atoms, or 疋R4 and R5 may independently or simultaneously form an aliphatic saturated hydrocarbon or aromatic ring structure, and the anion moiety represents halogenated C1 to C10 alkylsulfonimide anion, _C1 to cl〇 alkylsulfonyl methide anion (halogeno C1 ~ CIO alkylsulfonyl methide anion),

Or a functionalized C1 to C10 alkylsulfonate anion (halogeno Cl~CIO alkylsulfonato anion), each toothed ci to a CIO alkyl group having a halogen atom substitution of at least 3). (2) The colored resin composition for a color filter according to (1) above, wherein X of the formula (1) is an bis(trifluoromethanesulfonyl)imide anion, and di(difluoromethanesulfonyl) a methide anion or a triflate anion. (3) The colored resin composition according to the above (1) or (2), wherein Y of the formula (1) is a sulfur atom. (4) The colored resin composition according to any one of the above (1) to (3) wherein the rule 1 of the formula (1) and the carbon atoms of R2, R2 and R3, R3 and γ, and R4 and Rs are each independently / Or at the same time form an aromatic ring structure. (5) The colored resin composition for a color filter according to any one of the above items (1) to (4), wherein the color material compound represented by the formula (丨) is the following formula 1-A, 1-B or lc; 323679 7 3 201229143 r12

1-A

1-C (wherein, 1^ is a C1 to C4 alkyl group, R12 is a C to a C4 alkyl group which may be substituted with a hydroxyl group, and R21 is a group represented by the following formula B_1, B-2 or B_3' R31, R32, R33 And R34 each independently represents a Cl to a C4 alkyl group, and X—is the same as the formula (1);

8 323679 201229143 wherein R22 is ci C4 alkyl, R23 is phenyl, and ^ is C1 to C4 alkyl' R25 is a mono- or disubstituted amino group substituted with a C1 to C4 Hyun group which may be substituted by a cyano group. , * indicates the key position). (6) The colored resin composition for a color filter according to the above (5), wherein X- in the formula 1-A, 1-B or 1-C is a bis(trifluoromethane) anthracene An anion, tris(trifluoromethanestone xanthine) methide anion, or trifluorosulfonate anion. The colored resin composition for a color filter according to the above (5) or (6), wherein, in the formula 1-Α, Ru is an ethyl group, Ri2 is 2-ethyl group, and χ- is two (three) a fluorononanesulfonyl)imide anion, a tris(trifluoromethanesulfonyl) anthracene anion, or a trifluoromethylsulfate anion; wherein R21 is a formula B_1, Β-2 or Β-3 The base 'X- represented is a tris(trifluoromethanesulfonyl) sulfhydryl anion, and R22 of the formula Β-1 is a methyl group. The R23 of the formula B-2 is a phenyl group, and R24 is a fluorenyl group, and the formula B- R25 of 3 is 2 fenylethylguanidinoamine; any one of the cores of formula 1-C to R34 is fluorenyl' Γ is a tris(trifluorodecanesulfonyl) fluorenyl anion. The colored resin composition according to any one of the above (1) to (7), which further comprises a metal phthalocyanine pigment. (9) A color filter having the above (1) to (7) The colored resin composition according to any one of (1) to (7) above, wherein the colored resin composition of the coloring resin composition is patterned or the metal phthalocyanine pigment is further contained. Patterned hardened layer. (10) — A display device equipped with the color filter of the above (9). (11) A solid-state imaging element provided with the color filter 9 323679 201229143 described above. (Effect of the invention) In the colored resin composition of the invention, the color material compound represented by the formula (1) is provided, whereby a highly reliable color filter pixel having sharp color characteristics and excellent heat resistance can be provided. Further, the blue used in the present invention is used. In the case of a color material compound, the obtained color filter can achieve a very high contrast ratio. [Embodiment] The colored resin composition for a color light-receiving sheet of the present invention contains a binder resin, a solvent, and a polymerization initiator (for example, photopolymerization). a starter or a thermal polymerization initiator), a hardener, and a specific color material compound. Further, depending on the necessity, a color material compound such as a pigment or a dye, a surfactant, a heat hardener, a polymerization inhibitor, and a UV absorber may be contained. The present invention is described in more detail below, but the present invention is not limited thereto. In the present invention, an additive or the like used in a color filter may be used as the foregoing. (1) A component other than the specific color material compound to be used. The method for producing a halogen resin used in the colored resin composition of the present invention is mainly a photolithography ink-jet method, and the photo-polymerization initiator is excellent in developability. The resin composition of the present invention, the latter is not required to be a polymerization initiator, and a thermosetting resin composition containing a thermally polymerizable (four) material can be used. The present invention can be represented by the above formula (1) using a special coloring material compound. In the formula (1), the ci to (10) alkyl group, for example, may be exemplified by mercaptoethylpropylisopropyl, butyl, bromopropyl (t-butyl), isobutyl, pentyl or ethylidene. L butyl, benzyl, hexyl, 1-methylpentyl, ethyl ethyl butyl, cyclohexyl, propyl, 2 - carboxylic acid 10 323679 201229143 ethyl, carboxyethyl, cyanoethyl, decyl ethyl , ethoxyethyl, butoxyethyl, trifluoromethyl, pentafluoroethyl, 2-heptyl, n-heptyl, octyl, decyl, decyl, undecyl, dodecyl, thirteenyl , fourteen, fifteen, sixteen, seventeen, eighteen, nineteen, arachyl, twenty base (eicosyl), twenty-one base, twenty-two base, twenty-three base, twenty-four base, fifteen base, one sixteen base, twenty-seven base, twenty-eight base, twenty-nine base, three Triacontyl, isoheptyl, isooctyl, isodecyl, isodecyl, isodecyl, isotridecyl, isotetradecyl, isopentadecyl, isohexadecyl, iso-seven Basis, iso-octadecyl, iso-n-decyl, iso- 20-base, 丨s〇arachy 1 , isoeicosyl, iso- 21-unit, iso- 22-base, iso-tertiary , iso-tetrakisyl, iso-tetradecyl, iso-hexadecyl, iso-tevenyl, iso-octadecyl, iso-octadecyl, iso-octadecyl, diterpenyl, b-ethyloctyl, 1 -methylheptyl, cyclohexylethyl, bheptyloctyl, 2-methylcyclohexyl, 3-mercaptocyclohexyl, 4-methylcyclohexyl, 2,6-dimethylcyclohexyl, 2, 4-didecylcyclohexyl, 3,5-dimethylcyclohexyl, 2,5-dimethylcyclohexyl, 2,3-didecylcyclohexyl, 3 3,5-trimethylcyclohexyl, 4 _T-butylcyclohexyl, 2-ethylhexyl,! A diamond base (Bu^(7)), 2-adadori, benzyl, and the like. Ri to R6t of the formula (1), and examples of the aryl group include a phenyl phenyl group, an indolyl group, a porphyrin group (ind〇Unyl), and a quinolyl group (qUin〇lyl). These may have a substituent such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tert-butyl, pentyl or the like (C1 to C5). Fluorine atom, gas atom, desert atom, moth atom, etc.; methoxy, ethoxy, propoxy, butoxy, third 323679 11 201229143 oxy, hexyloxy, etc. (Cl to C6 Alkoxy; hydroxyethyl, hydroxypropyl and the like hydroxy (C1 to C5) alkyl; methoxyethyl, ethoxyethyl, ethoxypropyl, butoxyethyl, etc. (C1 to C5) Alkoxy (C1 to C5) alkyl; 2-hydroxyethoxy and the like hydroxy (C1 to C5) alkoxy; 2-methoxy ethoxy 2-ethoxyethoxy, etc. (C1 to C5) Alkoxy (C1 to C5) alkoxy; a functional group such as a sulfonic acid group, a 2-sulfonic acid ethyl group, a carboxyethyl group or a cyanoethyl group (sulfonic acid group, carboxyl group or cyano group, etc.) is substituted for C1 to C4 alkyl; a mono- or di-C1 to C5 alkylamino group which may be substituted by a cyano group (wherein the ci to C5 alkyl group is independently the same or different) when di-C1 to C5 alkylamino groups are used. Preferable examples thereof include N-C1-C4 alkyl-2-phenyl-3-yl group (for example, compound No. 6 in Table 1 described later), and 2-(Cl-C4 alkyl). (for example, the compound Νο. 4 in Table 1 described later), or the N-C1-C4 alkyl-fluorene-(C1 to C4 alkyl group which may be substituted by a cyano group) is substituted with a phenyl group (for example, the compound No. 5 of Table 1 described later). And so on, these groups are preferably r5. The ring structure of the aliphatic saturated hydrocarbon system or the aromatic system may be independently or simultaneously formed by the carbon atom of the formula (1) and R2, 匕 and R3, R3 and γ, or R4 and R5, respectively. One ring of the rings is composed of 5 to 6 members, and may be a single ring of a benzene ring, or may be a naphthalene ring, a trtrahydr〇quinoline ring or the like, or a ring or a substituent. The ring formed is a condensed ring formed by 2 to 3 rings. Specific examples thereof include a stupid ring, a naphthalene ring, an onion ring, a cyclopentene ring, a cyclohexane ring, a ring ring or a tetrahydro ring. The rings may be substituted with a substituted C1 to C4 alkyl group or a mono or diπ to C4 alkylamino group. Preferred rings include a benzene ring, a Cai ring or a tetrahydroguanidine shower ring. More specifically, the benzene ring formed by R3 (the compound t 4 to 6 of the following Table 1), and the carbon atom of R3A γ are the same. 323679 12 201229143 The naphthalene ring formed by the combination (the compound of the following Table 1) Ν〇·1 to 3, etc.), a benzene ring formed by R4 and Rs, or a tetrahydroquinoline ring bonded by a substituent on the benzene ring (Compound Nos. 1 to 3 and 7 of Table 1 described later). The ring may be substituted by a hydroxyl group-substituted C1 to C4 alkyl group or a mono- or di-C1 to C4 alkylamino group, etc. The ring formed by R4 and R5 or the substituent on the benzene ring is bonded to form a tetrahydroquine. a phenyl ring, more specifically a phenyl group substituted with a di C1 to C4 alkylamino group, or an a-C4 alkyl group substituted with an N-hydroxy group, an amine of Ri R6 of the formula (1) The substituent may be a substituted or unsubstituted amino group. The substituent of the amine group having a substituent may be the same one as described above. Preferred examples of the alkyl group-substituted yarn may be dimethylamine or two. The mono- or di-C1 such as isobutylamino group is a 4-alkylamino group, more preferably a di- to C-alkylamino group. The _-atom of the formula (1) includes a gas atom, a gas atom, and an atom. ,

Or, in the color material compound of the above formula (1), r2 γ is preferably an F·, an oxygen atom, a substituted or unsubstituted amine. The amine group having a substituent may be exemplified by the same oxime as in the above 1 to oxime, or a sulfur atom. The following situation occurs. The carbon atoms of Y combine to form naphthalene. For better cases, 323679 13 201229143 (i) The formation of R2 and R3 can be ci $ r/( p ^

To the case where a C4 alkyl group is substituted with a benzene ring, and Y is a -C(CH3)2- group or a sulfur atom. (I 〇 R2 R3 and the carbon atom of Y are combined to form a naphthalene ring. The case of the above (1) or (ii) is more preferably the following (5)) or (iv). (Out) In the above (1), 'γ is -c(CH〇2-base, m is a hydrogen atom, R5 is NQ-C4, and the base is 2-phenyl, which is called a 3-amino group, and 2_(C1_C4) a porphyrin group, or an N-C1-C4 alkyl-N- (a cyano-substituted π to C4 alkyl group) a substituted phenyl group; or γ is a sulfur atom, and L to 匕 form a single or a second C In the case where a C4 alkylamino group is substituted with a strepyl group (the latter compounds N〇4 to 7 and the like are described later). (iv) In the case of the above (ii), a C1 to C4 alkyl-2 which may be substituted with a hydroxyl group is formed by I. In the case of 2, 4-trimethyltetrahydroquinolinyl (Compound Nos. 1 to 3, etc. in Table 1 described later). Further, in the above (i) to (iv), hydrazine is preferably bis(trifluorodecanesulfonate). An anthracene anion, a tris(trifluoroanthracenyl)sulfonyl anion, or a triflate anion, more preferably a tris(trifluorodecanesulfonyl)methide anion. Specific examples of the preferred coloring material compound of the formula (1) include compounds represented by the following structural formulas.

Type A, 1-B, 1-C 14 323679 201229143 r12

Wherein Rn is CU-C4 alkyl, R12 is hydroxy-substituted Cl to C4, and R21 is represented by the following formula B_1, 2_(C1 to C4 alkyl)_1_α, 0, scary, Β_2 a 4-(mono or disubstituted amino)phenyl group represented by N-C1 to C4 alkyl-2-phenyl-3-yl or hydrazine-3, and R31, R32, R33 and R34 are each independently represented C1 to C4 alkyl, X—is the same as the above formula (1), preferably bis(trifluorodecanesulfonyl)imide anion, tris(trifluorodecanesulfonyl)indenide anion, or The triflate anion is more preferably a tris(trifluorodecanesulfonyl) anthracenide anion. 15 323679 201229143 Type B-l, B-2, B-3

Wherein R22 is n-C4 alkyl (preferably C C3 alkyl, more preferably methyl), R23 is phenyl, and R24 is C1-C4 alkyl (preferably CM-C3 alkyl, more preferably Is a methyl group), R25 is a mono- or di-substituted amine group substituted by a C1 to C4 alkyl group which may be substituted by a cyano group, and * represents a bonding position. Further, of the disubstituted amino groups of R25, two C1 to C4 alkyl groups which may be substituted by a cyano group are independently the same or different. A preferred embodiment of R25 is a disubstituted amine group in which one side is an unsubstituted C1 to C4 alkyl group and the other side is a cyano group substituted with a C1 to C4 alkyl group. Specific examples of the color material compound represented by the formula (1) are shown in Table 1, but the present invention is not limited thereto. 16 323679 201229143 [Table l]

In Table 1, when X is α, it represents tris(trifluorodecanesulfonyl)methide 17 323679 201229143 anion, when it represents bis(trifluoromethanesulfonyl)imide anion, and when r is trifluoro Methanesulfonate anion. The coloring material compound used in the colored resin composition of the present invention can be obtained, for example, by the known synthesis method described in "Theory for the Preparation of Dye Chemistry" (3, pages 7 to 375) by Teijing Fung Co., Ltd., but the anion portion is A commercial product of a gas anion can be purchased and synthesized by salt exchange by adding a corresponding salt or acid. In the present invention, when a color material compound is synthesized by salt exchange, for example, a color material compound in which an anion portion X is a gas anion is dissolved in a solvent, and a salt or an acid of the corresponding compound is added. It is about 5 to 3 equivalents, and then it is stirred at a predetermined temperature (e.g., 0 to 100 ° C) and the precipitated crystals are filtered, whereby it can be easily obtained. Examples of the solvent to be used in the reaction include water or methanol, ethanol, isopropanol, acetone, N,N-didecylguanamine (hereinafter abbreviated as MF), and N-mercapto-2-pyrrolidone (hereinafter abbreviated as NMP). ) a water-soluble polar solvent. These solvents may be used singly or as a mixture of plural solvents as necessary. The salt corresponding to the objective compound may, for example, be a metal salt of bis(trifluoromethanesulfonyl)imide, a metal salt of bis(difluoromethanesulfonyl) ruthenium, or trifluorosulfonate. Alkali metal salts and the like. The total solid content of the colored resin composition of the present invention (refers to the total amount of the solid content obtained by the color material compound, the binder resin, the curing agent, the dispersing agent, etc., in addition to the solvent. The following is also synonymous.) 1 part by mass The content of the color material compound represented by the above formula (1) is usually 〇. The amount is 〇 to 6 parts by mass, preferably 2 to 30 parts by mass, more preferably 3 to 30 parts by mass. Further, depending on the case, it is more preferable that the total solid content of the colored resin composition of the present invention contains the formula (1) 18 323679 201229143 color material compound of 2 to 10% by mass, preferably about 3 to 10% by mass. A colored resin composition. When the content is too large, precipitation and aggregation occur, and the adhesion to the substrate is lowered due to insufficient curing. There is no major problem when the amount is too small, but the color characteristics do not have a tendency to obtain sufficient color purity. The binder resin used in the present invention preferably has the following properties. That is, (i) the function of dispersing or dispersing aid for the dispersion stability of the pigment or water-insoluble dye when dispersed; (ii) soluble in the development processing step when manufacturing the color filter when using photolithography An organic developer to be used; (iii) a polymerization initiator (for example, a photopolymerization initiator or a thermal recombination initiator) and a hardener (for example, polymerization) contained in the colored resin composition of the present invention in order to form a finely detailed pattern The monomer, more specifically, a photopolymerizable monomer or a thermally polymerizable monomer, etc., has excellent hardening properties. The colored resin composition of the present invention obtained by mixing 5 liters of binder resin for 5 weeks must be stabilized, and a polymerization initiator (for example, a photopolymerization initiator or a thermal recombination initiator) and a polymerizable monomer (photopolymerizable monomer) are contained therein. Or (and the thermopolymerizable monomer), the composition of the formula (such as the color material compound, the pigment dispersion liquid, etc.) is excellent in compatibility, and does not cause precipitation or aggregation during storage or use. When the material is used in the inkjet method, since alkali solubility is particularly required, a resin which is compatible with other color material compounds and additives can be selected. 1 A known resin can be used as the binder resin, and it is preferred to have i or more carboxyl groups or hydroxyl groups as described later. An individual polymer of an ethylenically unsaturated monomer (hereinafter referred to as a thiol-containing solid 323679 19 201229143 unsaturated monomer or a hydroxyl group-containing unsaturated monomer) or copolymerizable with the ethylenically unsaturated monomer The copolymer of the other ethylenically unsaturated monomer having an aromatic smoky group and an aliphatic hydrocarbon group (hereinafter referred to as another unsaturated monomer) is usually preferably a copolymer. When an epoxy group is added to a side chain or a terminal of the copolymer, an epoxy (fluorenyl) acrylate resin or the like which is used for the addition of the copolymer (mercapto) acrylate can be used. These monomers or the like may be used singly or in combination of two or more kinds. The above-mentioned carboxyl group-containing unsaturated monomer which can be used in the present invention may, for example, be: (i) for example, acrylic acid, mercapto acrylic acid, crotonic acid (cr〇t) 〇nic acid), 2_chloroacrylic acid, cinnamic acid, and other unsaturated monocarboxylic acids; (ii) maleic acid, sodium butyric acid, anti Unsaturated dicarboxylic acids (anhydrides) such as fumaric acid, itaconic acid, itaconic anhydride, citraconic acid, citraconic anhydride, mesaconic acid; (iii) trivalent or higher unsaturated polyvalent carboxylic acid (anhydride); (iv) 2-(indenyl)propenyloxyethylhexahydrophthalic acid, phthalic acid 2-(methyl Ethyl methoxyethyl ester 2-hydroxypropyl ester, 2-propenyl methoxyethyl 2-transethyl ethyl o-dicarboxylic acid The unsaturated monomers may be used singly or in combination of two or more. Among them, (mercapto)acrylic acid is preferred. The above-mentioned hydroxyl group-containing unsaturated monomer which can be used in the present invention can be, for example, 20 323679 201229143: (fluorenyl) 2-hydroxyethyl acrylate, 2-hydroxypropyl ketone (meth) acrylate, 3-hydroxypropyl (meth) acrylate, 4 butyl butyl (meth) acrylate, 3-hydroxy butyl (meth) acrylate Ester, 5-hydroxypentyl (meth)acrylate, 4-hydroxypentyl (meth)acrylate, 3-hydroxypentyl (meth)acrylate, 6-hydroxyhexyl (meth)acrylate, (methyl) 5-hydroxyhexyl acrylate, 4-hydroxyhexyl (meth)acrylate, 5-hydroxy-3-methylammonium (meth)acrylate, cyclohexane-1,4-dimethanol-mono(decyl)acrylic acid Ester to C8 diol (mono)(fluorenyl) acrylate; C3 to C3 triol (mono or di)(fluorenyl) acrylate such as glycerol monomethacrylate; 2_(2-hydroxyethyloxy) Ethyl (meth) acrylate, polyethylene glycol mono (meth) acrylate, polypropylene glycol mono (meth) acrylate , poly(ethylene glycol-propylene glycol) monomethyl propylene hydrazine a, etc. by the end of the polypyrrolidine (meth) acrylate vinegar (preferably poly C1 to C4 singeol monomethyl (acrylic acid vinegar); etc. containing a trans-group (meth) acrylate. These hydroxy group-containing ethylenically unsaturated monomers may be used singly or in combination of two or more kinds. These divalent unsaturated monomers having a hydroxyl group are usually preferably the above-mentioned hydroxyl group-containing (meth) acrylate, more preferably a (meth) acrylate hydroxy C1 to C6 ester. The hydroxyl group-containing unsaturated monomer (preferably a hydroxyl group-containing (fluorenyl) acrylate) can be used as a monomer for copolymerization with the above carboxyl group-containing unsaturated monomer (preferably (meth)acrylic acid). . Further, examples of the other unsaturated monomer include styrene, styrene-ethylbenzene, o-ethylene-toluene, m-diethylphenyltoluene, p-mentyltoluene, o-chlorostyrene, m-chlorostyrene, and Aromatic vinyl compounds such as chlorostyrene and p-methoxystyrene; methyl (meth) acrylate, (fluorenyl) 323679 21 201229143 ethyl acrylate, n-propyl (meth) acrylate, (mercapto) acrylate Isopropyl ester, n-butyl (meth)acrylate, isobutyl (meth)acrylate, second butyl (meth)acrylate, tert-butyl (meth)acrylate, 2-hydroxy(hydroxy)acrylate Ethyl ester, benzyl (meth) acrylate, paracumylphenoxyethylene glycol (meta) arcylate, (mercapto) acrylate 2-carbo- 3-phenoxypropyl ester, o-phenylphenol glycidyl ether (mercapto) acrylate, o-phenylphenol (fluorenyl) acrylate hydroxyethylate, (mercapto)acrylic acid stupid ethyl ester, etc. Carboxylic ester (preferably C1 to C4 alkyl (decyl) acrylate containing phenyl) ; cyclopentyl (meth)acrylate, cyclohexyl (meth)acrylate, trimethylcyclohexyl (meth)acrylate, norborny 1 (meta)arcylate, (Methyl)-propyl acetoacetate-reduced methyl ester, (methyl) phenyl phenyl decyl methacrylate, (meth) cyano decyl methacrylate, (mercapto) acrylate (isobornyl (meta) Arcylate), (mercapto) acetic acid (bornyl (meta) arcylate), (meth) mentholic menthol (meta) arcylate, (mercapto) acrylic acid vinegar (fenchyl (meta)arcyla1:e), (mercapto) (adamantyl (meta) arcylate), (mercapto) acrylic acid diammonium carbonate, tricyclic [5.  2.  1.  02, 6] 癸-8-yl = (fluorenyl) acrylate (tricyclo [5.  2.  1.  02, 6] dec-8-yl = (meta)arcylate), three rings [5.  2.  1.  02, 6] 癸-8-4-methyl = (fluorenyl) acrylate (trieye 1 〇 [5· 2· 1.  02, 6]dec-4-methyl=(meta)arcylate), (fluorenyl)cyclodecyl acrylate, 2-(meth)acryloxyethyl hexahydrophthalic acid, (mercapto)acrylic acid Compound containing an alicyclic skeleton such as t-butylcyclohexyl ester 22 323679 201229143 (preferably a (fluorenyl) acrylate containing a C5 to CIO aliphatic ring, more preferably a C5 to C10 aliphatic ring of (meth)acrylic acid Ester); polyethylene glycol mono (meth) acrylate vinegar, polypropylene glycol mono (meth) acrylic acid vinegar, poly (ethylene glycol propylene glycol) monomethyl acrylate vinegar, etc. Alcohol mono(methyl)-propyl acetoacetate; methoxy polyethylene glycol monodecyl acrylate, lauryloxy polyethylene glycol mono(meth)acrylic acid polyethyleneglyc〇i mon(meta)arcylate ), octyloxy polyethylene glycol polypropylene glycol mono(meth)acrylic acid g, nonylphenoxy polyethylene glycol monoacrylic acid vinegar, mercapto oxypolypropylene glycol monoacrylate, propylene oxy oxy polyethylene m alcohol mono (methyl) propyl riding g | isobutyl group of polyalkylene glycol mono (meth) oleic acid vinegar (preferably C1 sC1 〇 基 end of the poly C2 to C 4 calcined diol (meth) acrylate vinegar; acrylic acid 2-aminoacetic acid, methyl propyl phthalate 2-amino ethoxylate, 2-propylpropyl propyl acrylate, methyl propyl acrylate 2_ Aminopropyl vinegar, 3-amino (IV) acrylate, 3-aminopropyl methacrylate acrylate, etc. (preferably (f-based) acrylic π to ^ burning vinegar); glycidyl acrylate g Glycidyl arcylate, methacrylic acid glycidyl, (meth)acrylic acid 3,4-epoxybutyl vinegar, (meth)acrylic acid (3'4-epoxycyclohexyl) methyl vinegar, (methyl)acrylic acid 4_ unsaturated succinic acid glycidyl ether or the like (tetra) acid glycidol vinegar (preferably containing an epoxy group (meth) acrylic acid C1 to C6 aliphatic g, preferably It is (meth) propylene ^glycidyl ester); vinyl acetate, vinyl propionate, vinyl butyrate, ethylene vinegar such as acenaphthyl acetate, vinyl ethyl group, vinyl ethyl group, and propyl ketal (4), Ψ基(4) shouting glycidyl fines saturated bond; acrylonitrile 'mercapto acrylonitrile, chloropropionitrile, cyanide 323679 23 201229143 vinylidene compounds such as vinylidene Acrylamide, mercapto acrylamide chloropropenylamine, N-phenylmaleimide, N-cyclohexylmaleimide, N_(methyl) propylene oxime N-(meta) aCryl〇xyphthalimide, N-(2-hydroxyethyl)propenamide, b (2-ylethyl)methylpropionide, Malayan Unsaturated (tetra)amine or unsaturated quinone imine; aliphatic conjugated diene compound such as dibutyl, isopentadiene, and pentylene; polystyrene, polymethyl acrylate, polymethyl methacrylate, The polymer molecular chain end such as polybutyl acrylate, polybutyl methacrylate or polyfluorene has a monopropenyloxy group or a monomercaptopropoxy group=macromonomer. These other unsaturated monomers are used singly or in combination of two or more. Among the above, 'other unsaturated monomers are preferably a phenyl-containing (fluorenyl) propylene oxime C1 to C4 alkyl ester, a C5 to C10 aliphatic ring-containing (meth)acrylic acid, and a terminal ci to cio Alkyl poly C2 to C4 alkanediol (mercapto) phthalic acid vinegar, (meth)acrylic acid amine C1 to C4 alkyl ester, and epoxy group-containing (meth) acrylate (meth) acrylate ester. More preferably to be stupid: instead of (meth)acrylic acid bismuth to C4 vinegar or contain it. 1 〇 二 之 ( ( ( 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又The copolymer side chain is further introduced with an unsaturated double bond: the polymer may also be exemplified by the following compounds: in the cis-butane diacid field and can be polymerized therewith: the present ethylene, ethylene, acrylic, acrylic acid The maleic acid needle portion of the copolymer of acrylamide or the like, which has an epoxy group such as acryl acrylate or glyceryl methacrylate having 323679 24 201229143 alcohol such as propylene glycol. a half-ester compound obtained by the reaction of propionic acid S; and a hydroxyl group of a copolymer having an alcoholic acrylate having an alcoholic group such as acrylic acid, acrylate or hydroxyethyl acrylate, and acrylic acid A compound obtained by the reaction. In addition, a polyurethane resin, a polyimide resin, a polyester resin, a commercially available ACA-200M (manufactured by DAICEL Co., Ltd.), ORGA-3060 (Osaka Organic Chemical Co., Ltd.), ΑΧ3_ΒΝΧ〇2 (made by Nippon Shokubai Co., Ltd. ), UXE-3024, UXE-3000, ZGA-287H, TCR-1338H, ZXR-1722H, ZFR-1401H, and ZCR-1642C are manufactured by Nippon Chemical Co., Ltd.). The binder resin contained in the colored resin composition of the present invention is preferably a (mercapto)acrylic copolymerized resin of a copolymer of (fluorenyl)acrylic acid (preferably methacrylic acid) and a monomer copolymerizable therewith, preferably a copolymer of (fluorenyl)acrylic acid (preferably methacrylic acid) and a (fluorenyl) acrylate compound (including a hydroxyl group-containing (meth) acrylate) (also known as (fluorenyl) fluorenyl acrylate) acrylic acid Ester copolymer). The binder resin is preferably a copolymer having a copolymer acid value of from 1 Torr to 300 (mgKOH/g) or/and a hydroxy group of from 1 Å to 2 Å (mgK 〇 H/g). More preferably, the molecular weight of the copolymer having an acid value of from 50 to 250, more preferably from about 1 to about 2, is sufficient as long as the binder resin task can be completed, and the weight average molecular weight (Mw) (in terms of styrene) is usually 2 〇〇0 to 4〇〇〇〇〇, preferably about 3,000 to 100,000, and more preferably about 5 to 7 inches, and most preferably about 8,000 to 40,000. 323679 25 201229143 The ratio of the two monomers in the (mercapto)acrylic acid-(fluorenyl) acrylate copolymer is not particularly limited, but if the development is considered, the (meth) propylene is: The molar ratio of the body (preferably (meth) acrylate) is 1: 0. 5 to 1: 10, preferably 1: 1 to 1: 5 or so. Further, the above (indenyl) acrylate compound may be exemplified by the above-mentioned (meth) acrylate having a hydroxyl group and the above (meth) acryl vinegar. The (meth) acrylate is preferably a (meth) acrylate containing a C5 to C10 aliphatic ring or the above phenyl substituted meth to C4 alkyl acrylate, more preferably benzyl (fluorenyl) acrylate. ester. More preferably, the (meth)acrylic-(fluorenyl) acrylate copolymer is a (meth)acrylic acid and a phenyl-substituted (meth)acrylic C1 to C4 alkyl ester (preferably (benzyl) benzyl acrylate. Copolymer, or a copolymer of (mercapto) propylene fluorene and a (fluorenyl) acrylate containing a C5 to C10 aliphatic ring, which is a copolymer composed only of the two, and further, does not cause Within the range of hindrance (for example, 0 to 30 mol%, preferably 〇 to 20 mol%, more preferably 〇 to 10 mol%) may contain other (mercapto) acrylate compounds. Further, the term "(fluorenyl) acrylate" or the like is used in the present invention to mean a diacid, a methacrylate or the like. For example, the meaning of (meth)acrylic acid acrylate or / and methacrylate is used. When the solubility of the coloring material compound represented by the formula (1) with respect to the colored resin composition is low, it can be dispersed using a dispersing agent and a dispersing aid in the same manner as the pigment of any of the components described later. Generally, a dispersing agent or a dispersing aid is used in dispersing the pigment. Therefore, when the resin composition of the present invention contains a pigment, the resin composition of the present invention preferably contains a dispersing agent, or a dispersing agent and a dispersing aid. 323679 26 201229143 The dispersant is a dye-based dispersant having a good absorbing property to a pigment, a resin-based dispersant, a surfactant, and the like. In the present invention, it is preferred to use the pigment in combination with the pigment. For example, a pigment-based dispersant is used. As a technique for dispersing a pigment, a known method of mixing a pigment with a telluride of a pigment of the above-mentioned Patent Document 4 or a metal salt thereof, or a method of mixing a substituted aminomethyl derivative with a pigment is known. The resin-based dispersant may be a non-polar non-ionic one. However, a polymer resin having an acid value or an amine value which imparts good pigment absorbing properties is common, and examples thereof include an acrylic resin and a polyurethane resin. , polycarboxylic acid, polyamide resin, polyester resin, and the like. Specific examples thereof include ED211 (manufactured by Nanmoto Chemical Co., Ltd.), AJISPERrtm PB821 (manufactured by Ajinomoto Fine-Techno Co., Ltd.), and Solsperse RTM71000 (manufactured by Avecia Co., Ltd.). The above-mentioned superscript RTM represents a registered trademark. The dispersant content in the resin composition of the present invention is from about 0 to 30% by mass in the total solid content, preferably from about 〇 to about 20% by mass. The binder resin (copolymer) used in the present invention may be a commercially available product or may be synthesized. A polymerization initiator is used in the production of the binder resin. Here, specific examples of the polymerization initiator used in the synthesis of the copolymer include, for example, α,-azobis(isobutyronitrile), α,α azobis(2-methylbutyronitrile), T-butyl peroxyoctoate, di(t-Butyl)peroxide, benzoyl peroxide, decyl ethyl ketone peroxide (methyl ethyl ketone peroxide) and the like. For the total of 100 parts by mass of all the monomers used in the synthesis of the copolymer, the polymerization initiator content is 〇.  01 to 25 parts by mass. 27 323679 201229143 Further, in the case of synthesizing a copolymer, it is preferred to use an organic solvent described below. The organic solvent is preferably sufficiently solvable for the monofunctional monomer, the polymerization initiator, and the like used. The reaction temperature at the time of synthesizing the copolymer is preferably from 5 Torr to 12 (rc, particularly preferably from 80 to 100 t. Further, the reaction time is preferably from i to 6 Torr, more preferably from 3 to 20 hours. Copolymerization of the binder resin The copolymer having an acid value of usually from about 1 Torr to about 3 Torr (mgK 〇H/g), preferably from about 100 to 300, or/and a copolymer having a valence of from 10 to 200 (mgKOH/g) is more The acidity is lowered when the acid is 4 or the hydroxyl group is less than 1 Torr. The weight average molecular weight (Mw) of the copolymer is preferably from 2,000 to 400,000, more preferably from 3,000 to 100,000, still more preferably from 5,000 to 50,000. In the present invention, the binder resin may be used singly or in combination of two or more kinds. In the present invention, the total amount of the colored resin composition is used. The binder resin content is usually in the range of from 5 to 99 parts by mass, preferably from 5 to 50 parts by mass, more preferably from 1 to 50 parts by mass, still more preferably 2 parts by mass per part by mass of the solid portion. To 50 parts by mass, when the binder resin content is less than 5 parts by mass, the basic developability is lowered, and it may be produced. Region residues and scum film portion other than pigmentation problems. May include light or heat polymerizable monomer used in the present invention, when the radical polymerization hardening agent, when the hardening of the ion include an epoxy resin, may be mentioned other. Melamine hardener and the like. Specific examples of such may include 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, and 2-ethyl 323679 28 201229143 hexyl ester, ethylene glycol II ( Methyl) acrylate, diethylene glycol bis(indenyl) acrylate vinegar, diethylene glycol (meth) acrylate, tetraethylene glycol (mercapto) acrylate, trihydroxy fluorenyl Propane tris(mercapto) acrylate, pentaerythritol bis(indenyl) acrylate, neopentyl alcohol tri(meth) acrylate, pentaerythritol tetrakis(yl) acrylate, dipentaerythritol Hexa(indenyl)acrylate, glycerol (meth)acrylic acid vinegar, bisphenol A type epoxy bis(indenyl) acrylate, bisphenol f type epoxy bis(indenyl) acrylate, bisphenol-type ring Oxygen bis(indenyl) acrylate, ethoxylated succinyl propyl succinyl succinyl acrylate, propane oxidized trisyl propyl propane tri(meth) acrylate, ethoxylated glycerol tris(yl) acrylate , E-rolled triiso(cyano)acrylic acid vinegar, di(tris-propyl mercapto) tetra(meth)acrylate, B Of New pentaerythritol tetra (Yue-yl) acrylate, 9, 9-stage-bis [4- (2-Bing Xixi yl) phenyl] Ti and the like (Yue-yl) acrylate compound. Commercially available products include KAYARADrtm RP-1040, KAYARADrtmDPCA-30 (above, manufactured by Nippon Kayaku Co., Ltd.), UA-33H, UA-53H (above, manufactured by Shin-Nakamura Chemical Co., Ltd.), M-8060C East Asia A (meth) acrylate compound sold under the trade name, such as Synthetic Co., Ltd.). Further, examples of the thiol-based polymerizable monomer include TEMPIC, TMMP, PEMP, and DPMP (the above is manufactured by SAKAI Chemical Industry Co., Ltd.). In addition, the epoxy resin may be exemplified by Nippon Kayaku Co., Ltd., trade name NC-6000, NC-3000, EOCN-1020, XD-1000, EPPN-501H, BREN-S or NC-7300L; DAICEL Chemicals Limited 29 323679 201229143 Company, trade name CELLOXIDE2021P, EHPE3150, CYCLMERrtm M100 or EPOLEAD PB3600, etc.; made by Japan Epoxy Resin Co., Ltd., trade name EPIK0TE^828, EPIKOTEmX8000 or EPIKOTEmYX4000; etc., manufactured by CHISS0 Co., Ltd., trade name SILA ACE 〃 %510, etc.; manufactured by Handan Chemical Industry Co., Ltd., trade name TEPIC and other commodities. Further, examples of the melamine curing agent include methylolated melamine and Mw-30 (manufactured by Sanwa Chemical Co., Ltd.). The polymerizable monomer suitable as the curing agent is preferably a polyfunctional (fluorenyl) acrylic acid S-functional compound, more preferably a 3- to 6-functional (fluorenyl) acrylate compound. The 3- to 6-functional (fluorenyl) acrylic brewing compound may be neopentyl alcohol (tri- or tetra) (meth) acrylate or dipentaerythritol (tri-octadecyl) acrylate. The cough content is 1 to 80 parts by mass, preferably 10 to 60 parts by mass, more preferably 20 to 60 parts by mass, based on the total solid content of the colored resin composition. 5 to 3 parts by mass. The color material compounds of the formula (1) can be used in combination of two or more kinds or alone. Further, it is also possible to apply a mixture of other dyes and a mosquito coloring material compound used in the colored resin composition of the present invention to blue sputum, erythromycin, chlorophyll, and the like according to its chemical structure. For example, the table! The recited compounds N〇1 to 3 show a blue color which is suitable for blue pixels and, in addition, can be displayed by mixing with yellow, and is also suitable for green halogen. In addition, the compound n〇 5 shows a red color and is suitable for red halogen. In addition, the compound n〇7 shows yellow color, which is mixed with blue to show green color, and is suitable for green alizarin 323679 30 201229143. The color material of the formula (1) is selected for the color of the pixel of the appropriate purpose: The colored resin mixture is mixed with a known blue color, a work color, a page color, a green color, a purple color, an orange color, a drum main Ί "= pigments of various colors, and the coloring matter of the formula (1) is different from the target pixel. The blue color is the blue or purple wood or the pigment, the red color is the red or yellow dye or the color =, the green color is the green or yellow dye or the pigment. 1) The color material compound is used together. The pigment which can be used in combination with the colored resin composition of the present invention is preferably one of those having a prior characteristic of a color calendering sheet, and can be suitably selected from dyes, = and inorganic pigments, depending on It may be used singly or in combination of two or more. In the total solid content of the colored resin composition, the content is from 0 to 60 parts by mass, preferably from 〇 to 3 parts by mass, depending on the case. The dragon is 5 to 3G parts by mass or less When the colored resin composition of the present invention is blue strontium, the color material compound of the formula (丨) is preferably a color material compound of (4) money color. For example, the above formula 1 Specifically, it is preferred to use a compound to a compound Ν〇丄 to 3, etc. The dye or pigment which can be used in combination at this time is not particularly limited, but is usually preferably from the viewpoints of hue and durability. An organic pigment such as blue or purple is used. Examples of the organic pigment include anthraquinone, phthalocyanine, triphenylmethane, benzimidazolone, and hydrazine. A ketone (quinacridone), an azo chelate 31 323679 201229143 azochelate, azo, oxime, quotient (Isoindoline), isoindolinone, dermatone ( Pyranthrone), Indanthrone, Anthrapyrimidine, Dibromoquinone ((1301*01110&111;11&amp;111:111*0116), Huang Shitan ( Flavanthrone), perylene, and epoxide (pe) Rinone), quinophthalone, thioindigo, dioxazine, quinophthalone, xanthene, etc.; acid dyes, basic dyes, direct dyes Etc. lake pigment which is insolubilized under a precipitant; dyed lake pigment, and the like. More specific color index (color·index) can be enumerated: pigment blue (pigmentblue) 1, 1: 2, 9, 14, 15, 15: Bu 15:2, 15:3, 15:4, 15: 6, 16 , 17, 19, 25, 27, 28, 29, 33, 35, 36, 56, 56: 1, 60, 6 Bu 61: Bu 62, 63, 66, 67, 68, 7 Bu 72, 73, 74, 75, 76, 78, 79; Pigment )%% (Pigment violet)  : : 1, 2, 2: 2, 3, 3: Bu 3:3, 4, 5, 5 23, 25, 27, 29, 3 Bu 32, 37, 39, etc. Among them, Pigment Violet 23, metal phthalocyanine and phase resistance are excellent. : Pig 14, 15, 16, 19, 42, 42, 44, 49, 50, pigment blue 15: 6 The coloring resin composition of the present invention is preferably a compound of the formula 1-A and the pigment violet 23 And use the better form - can be used together with the second:: the metal indigo pigment 'success reduction. The compound and the boat that displays the i color, the private color of his color, The organic pigment of the heartgate & Jingkou colored resin composition is: can be used for / J limit, for example, red f 323679 32 201229143 can use the combination of pigment red 254, 177 and pigment yellow 150, 139, 138, green pixels are suitable for use with pigment green?, 36, 58 and pigment yellow 150, 139, 138, etc. Among them, pigment red 254 and metallic green pigment pigment greens 36 and 58 are particularly excellent in hue and resistance. One of preferable examples of the colored resin composition of the present invention is a combination of a color material compound of the formula (1) and a metal indigo pigment (preferably a copper indigo pigment). In particular, in the case of the blue resin or the green pigment, in the colored resin composition of the present invention, it is preferred to use a combination of the metal indigo pigments of the respective colors. The inorganic pigment to which the colored resin composition of the present invention can be used is not particularly limited. For example, composite metal oxide pigments, black titanium oxide (titanium suboxide), titanium oxide, barium sulfate, zinc oxide, lead sulfate, chrome yellow lead, red iron oxide (colcothar), ultramarine (ultramarine), Prussian blue (ferric hexacyanoferrate) ), chromium oxide, antimony white, iron black, lead dan, sulphide, cadmium yellow, red, purple, purple, barium sulfate, magnesium carbonate and other metal oxides, metal sulfides, sulfates, Gold ^ hydroxide, metal carbonate, and the like. Further, carbon carbon particles, metal fine particles such as zinc, or the like may be used. The dyes which can be used in combination with the colored resin composition of the present invention are not particularly exemplified by acid dyes, testability (IV), direct dyes, vat dyestuffs, naphth〇1 alcohol dyes, reactions &gt; = dispersion Dyes, etc. It is generally preferred to be soluble in an organic solvent. The dyes in the organic solvent can be suitably used as a dispersion. ’’,. Insoluble 323679 33 201229143 In addition, the organic solvent-insoluble dye can be modified by a known modification method. It is known that, for example, in the case of an acid dye or a basic dye, an organic amine compound (for example, n-propylamine, ethylhexylpropionate, etc.) is reacted to be converted into an amine salt dye, or a sulfonic acid group thereof is used to make the above organic amine. The compound is modified to be a dye having a sulfonamide group or the like. These amine-modified dyes can also be used in the colored resin composition of the present invention. The specific dye color index is solvent blue 2, 3, 4, 5, 6, 23, 35, 36, 37, 38, 43, 48, 58, 59, 67, 70, 78, 98, 102, 104; basic blue 7; acid blue 80, 83, 90; purple dye can be solvent vioelt 8, 9: violet 4, 5, 14 'Experimental purple (5831 (: \ ^ 〇 161:) 10, test red (5351 (: \ / &quot;] _ 161:) Bu 14, alkaline jaundice 33 761 7611 〇% 〇 19, 21, 40, basic orange (^33 "orange" 22, etc. The photopolymerization initiator added by the photochromic resin composition of the present invention used in photolithography is preferably used for the general use of an exposure light source. The ultraviolet rays emitted from the high-pressure mercury lamp have sufficient sensitivity, and examples thereof include a radically polymerizable photo radical initiator, an ion-curable photo-acid generator, or a photobase generator (ph〇). T〇_base generator), etc. Photopolymerization can be combined with a polymerization accelerator called a sensitizer which is hardened with less exposure energy. The photopolymerization initiator which can be used is not particularly limited. Specific examples of the column may be cited. Benzi 1 (benzi 1), Benzoin ether (benz〇in, benzoin butyl ether, puppet propyl hydrazine, ~ benzophenone (benz〇phen〇ne), 3, 3, - 曱Benzo-4-methoxybenzonitrile, benzoic acid (benzQylbenz〇ic 34 323679 201229143 acid), esterified benzamidine acid, 4-benzylindolyl-4'-methyldiphenyl sulfide , benzyl dimethyl ketal, 2-butoxyethyl-4-mercapto acetoacetate, chlorothioxanthone, fluorenyl hydrazine, sodium sulfonate, ethyl sulfonate , isopropyl thioxanthone, dimethyl thioxanthone, diethyl thioxanthone, diisopropyl thioxanthone, dimethyl decyl decyl phthalate, 1-(4-dodecane albino 2-hydroxy-2-mercaptopropan-1-one, hydroxycyclohexyl phenyl ketone, 2-hydroxy-2-mercapto-1-phenylpropan-1-one, ι_(4-isopropyl Phenyl)-2-hydroxy-2-methylpropan-1-one, methyl benzoyl fooiate, 2-mercapto-1-(4-mercaptothiophenyl)-2 -(N-morpholinyl)propan-1-one, 2-benzyl-2-dimethylamino-i-(4-(N-morpholine)phenyl)-butanone-1, 2, 4-bis(trimethylsulfonyl)-6-(4-methoxyphenyl) -1,3,5-3-triazine, 2,4,6-tris(trichloroindenyl)-1,3,5-s-triazine, 2,4-di(tribromoindolyl)- 6-(4'-methoxyphenyl)-1,3,5-s-triazine, 2,4,6-tris(tribromoindolyl)-1,3,5-s-triazine, 2 , 4-di(trichloroindenyl)-6-(1,3-benzodioxol-5-yl)-l,3,5-s-triazine, dibenzophenone, benzamidine Benzoate, 1-(4-indolylthiophenyl)butane-1,2-dione-2-indole-0-benzoate, 1-(4-methylthiophenyl) Butadiene-1,2-dione-2-indole-0-acetate, 1-(4-methylthiophenyl)butan-1-one oxime-indole-acetate, 4, 4' - bis(diethylamino)benzophenone, isoamyl p-dimethylamine benzoate, ethyl p-nonylaminobenzoate, 2,2'-bis(0-chlorophenyl)-4 , 4,5,5'-tetraphenyl-1,2'-biimidazole, diazo-naphthoquinone-based initiator, etc. Further, commercially available products include: KAYACURErtmDMBI, KAYACURErtm BDMK, KAYACURErtm BP -100, KAYACURErtmBMBI, KAYACURErtm DETX-S, KAYACURErtmEPA (all manufactured by Nippon Kayaku Co., Ltd.), 35 323679 201229143 GR0CURErtm 1173, GR 0CURErtm 1116 (all manufactured by Merck Japan Co., Ltd.), IRGACURErtm 907, IRGACURErtm369, IRGACURErtm 379EG' IRGACURErTM OXE-01&gt; IRGACURErTM OXE-02' IRGACURErTM PAG103 (all manufactured by Ciba Specialty Chemicals), TME-Sambo ( Sanwa Chemical Co., Ltd.), biimidazole (made by Heijin Chemical Co., Ltd.), STR-110, and STR-1 (all manufactured by Respe Chemical Co., Ltd.). When a thermosetting resin composition is used in an inkjet method or the like, a thermal polymerization initiator is generally used. However, a photopolymerization initiator may be used in combination if necessary. The thermal polymerization initiator may be an azo compound or an organic peroxide, and examples thereof include 2, 2'-azobisisobutyronitrile, 2, 2, and azobis(2,4-12-diyl). Valeronitrile), 2, 2, azobis(2-f-butyronitrile), di(tertiary butyl peroxide), dibenzyl hydrazine peroxide, cumene peroxy neodecanoate ) Wait. The polymerization initiators used in the present invention may be used singly or in combination of two or more kinds as necessary. When the total solid content of the colored resin composition is 1 part by mass, the polymerization initiator content is 〇 5 to 5 parts by mass, preferably i to 25 parts by mass, more preferably 1 to 10 parts by mass. The organic solvent to be used in the present invention can be sufficiently used, such as a binder resin, a photopolymerizable monomer, a polymerization initiator (photopolymerization initiator or a thermal polymerization initiator), which is a component of the colored resin composition. The solvency is also sufficient for the monofunctional monomer, the polymerization initiator, and the like used in the synthesis of the binder resin. Further, it is also possible to use a dispersion which maintains dispersion stability when a pigment dispersion is prepared. 36 323679 201229143 The organic solvent used in the present invention is (methyicellos °lve), acesulfame sulphate, diced sulphate, etc., sulphide sulphide, sulphonic acid, acesulfame acetate §, dingsai sulphonic acid棘 乙酸 乙酸 @ 旨 旨 旨 ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; And acetic acid methyl acetate, acetic acid ethyl acetate, acetic acid I hospital base (preferably C1 to C4 alkyl) g-type acetic acid g-like solvent; methyl propionate methyl vinegar, methoxypropionic acid Ethoxy ethoxylate A, ethoxylated vinegar, etc. (4) Lai; lactic acid w, lactic acid, lactic acid, vinegar, lactic acid, vinegar, diethylene glycol monomethyl hydrazine, diethylene glycol monoethyl ether, etc. Diethylene glycols; - methyl hydrazine, monoethyl hydrazine, tetrahydro alpha pentane, H, etc.; ketones such as propyl hydrazine, methyl ethyl ketone, mercapto butyl ketone, cyclohexyl ketone (preferably) For C3 to C6 ketone chest media); methanol, ethanol, butanol, isopropanol, (4). Preferred solvents are usually exemplified by _ solvent and acetic acid _ solvent, more preferably ketone solvent and propylene The diol is used alone or in combination of two or more. Further, the organic solvent is usually used in an amount of 40 to 10,000 based on the total solid content (10) parts by mass of the colored resin composition. The parts by mass are preferably from 1 to 1 part by mass, more preferably from 100 to 400 parts by mass, still more preferably from 1 to 3 parts by mass. Preferred composition of the colored resin composition of the present invention. One example of the ratio is as follows. In addition, the content ratio is a mass ratio (%) contained in the total amount of solid content (full solids) of the colored resin composition of the present invention. 323679 37 201229143 Content of solid content The ratio is 3 to 30% for the color material compound represented by the above formula (1), 5 to 50% for the binder resin, and 5 to 50% for the curing agent, and the coloring matter other than the coloring material compound of the formula (1) is 〇, And the polymerization initiator is from i to 25%. Preferably, the color material compound represented by the above formula (1) is from 2 to 10%, the binder resin is from 1 to 50%, and the hardener is from 20 to 50%. 1) The coloring matter other than the coloring material compound is 0 to 60%, and the polymerization initiator is 1 to 丨〇%. In the resin composition, the solvent content is from about 100 to about 1000% by mass based on the total amount of the solid content (about 1 to 10 times by mass). Further, the convenience of the coloring resin composition of the present invention, from the viewpoint of coating, etc. Look at 'the viscosity at 25 ° C is 8 to 20 mP. s or so, preferably 10 to 15 mP. s or so. The colored resin composition of the present invention is a mixture of the above-mentioned binder resin, hardener, photopolymerization initiator, specific color material compound, organic solvent, etc., by a dissolver or a homomixer. And manufacturing. In addition, 'other pigments or dyes may be added as necessary, but when they are pigments or dyes with low solubility, they are dispersed using a suitable dispersant and dispersed by a disperser such as a paint shaker. The body is then added to the colored resin composition for mixing. The colored resin composition of the present invention may be added with various additives such as a filler, a surfactant, a thermal polymerization inhibitor, an adhesion promoter, an antioxidant, an ultraviolet absorber, an anti-agglomerating agent, and the like as necessary. Further, the colored resin composition of the present invention can be precisely filtered by a filter or the like in order to take out foreign matter or the like after the preparation thereof. Next, a method of producing a color filter and a light sheet having the layer of the cured product 38 323679 201229143 from the colored resin composition of the present invention will be described. * First, the colored resin composition of the present invention is applied to a substrate such as a glass substrate or a tantalum substrate, a spin coating method, a (four) cloth method, a slit and spin method, a die coating method, and a bar coating method. The method is such that the film thickness is "coated in a manner of 111, preferably 0. 5 to 5/zm. Depending on the necessity, it is pressed to 'inside at a temperature of 23 to 15 〇t:, 1 to 6 minutes, preferably at a temperature of 1,2 〇C, for 1 to 1 minute, and dried under reduced pressure. Further, a pre-baking treatment is carried out with a hot plate or a dry material to form a film. Then, by irradiating radiation (for example, electron beam, violet, or squall line) through a predetermined mask pattern by a conventional photolithography method, an aqueous solution of the surfactant, an aqueous solution, or a mixed aqueous solution of a surfactant and an alkali agent, etc. Developed by developing solution. Examples of the shirting method include a dipping method, a spray method, a shower method, a paddle method, and an ultrasonic development method. It is also possible to combine any two or more depending on the situation. After the unirradiated portion of the unexposed portion was removed by the immersion, the post-flooding treatment was carried out. The post-baking treatment is carried out, for example, at a temperature of 130 to 30 (TC, 1 to 120 minutes, preferably 150 to 250 ° C, for 1 to 30 minutes, to have a colored cured film of the present invention. In the color filter of the present invention, the thickness of the cured layer of the colored resin composition is not particularly limited, and is usually about 1 〇//m, preferably about i to 5 am. In the above, the surfactant may be a polyoxyethylene alkyl ether, a polyoxyalkylene alkyl ether, etc. Further, the alkali agent may be sodium carbonate, potassium carbonate or sodium hydroxide. Potassium hydroxide, monoethanolamine, tetradecylammonium hydroxide, etc. In the present invention, it is preferred to use an aqueous solution containing both a face and a surfactant containing 323679 39 201229143. The development is usually at 1 〇 to 50 C ' Preferably, it is carried out at a treatment temperature of 2 to 4 Torr, usually at a treatment time of 3 Torr to 6 sec., preferably 30 to 120 sec. The heat filter of the color filter of the present invention obtained as above has heat resistance. It is high, and the color difference UEab) before and after the heat resistance test described later is 3 Å or less, and more preferably The color filter of the cured layer of the colored resin composition of the present invention is used for a solid-state imaging device used in a liquid crystal display device, an organic EL display, a digital camera, or the like. The color filter has a patterned halogen composed of a cured layer of the colored resin composition of the present invention as described above. In the display device of the present invention, the liquid crystal display device is, for example, The backlight, the polarizing film, the display electrode, the liquid crystal, the alignment film, the common electrode, the color filter of the present invention, the polarizing film, and the like are sequentially laminated. The organic EL display is on or under the multilayer organic light-emitting element. Any one of the color filter of the present invention is formed or laminated. Further, the solid imaging element is provided with the color filter layer of the present invention, for example, by providing a transfer electrode and a photodiode. The present invention is produced by laminating microlenses. [Embodiment] Hereinafter, the present invention will be described in more detail by way of examples, but the present invention is not limited thereto. In the examples, the "%" is a meaning of "% by mass" unless otherwise specified. (Synthesis Example 1) 323679 40 201229143 It is described in the Example of JP-A-52-76329 In the method, a compound represented by the following formula (100) is obtained.

(100) The compound lg of the above formula (100) and water 2 g were added to a 100 ml beaker, and stirred at normal temperature for 30 minutes. The ruthenium salt of tris(trifluoromethanesulfonium)methide was dissolved in 3% of DMF, and the DMF solution was dropped into the above solution and stirred for 3 hours.

The precipitate was filtered, washed with water and dried to give a dye (Compound N 〇. D 〇. 8 g. Decomposition temperature 2603⁄4, maximum absorption wavelength: 6 〇lm (cyclohexanone). (Synthesis Example 2) Adding Basic to 300 ml beaker 4 parts of Red 14 vapor (manufactured by Tokyo Chemical Industry Co., Ltd.), 150 parts of water, and stirred at room temperature for 2 minutes. Dissolve 5·7 parts of tris(trifluoromethanesulfonium) methide salt in 5·7 The (10) plant dripped the DMF solution into the solution for 3 hours. The precipitate was filtered, washed with water and dried to obtain a dye (Compound 表ο. 5 in Table 1). Maximum absorption wavelength: 532 m (cyclohexanone). Example 3) Add 1 part of Basic Orange 22 vapor (manufactured by Tokyo Chemical Industry Co., Ltd.), 2G water in 5 〇 0 ml beaker, and stir for 5 G minutes at 5 (rc). Part 2 (difluorodecanethione) 曱The base salt of the base compound was dissolved in I 4 parts of 323679. 41 201229143 DMF' The DMF solution was dropped into the above solution and stirred for 2 hours. The precipitate was filtered, washed with water and dried to give a dye (Compound No. 6 of Table 1). Maximum absorption wavelength: 508 nm (cyclohexanone). (Synthesis Example 4) Adding Basic Yellow 1 to a 500 ml beaker 5 parts of water (100 parts of water, manufactured by Tokyo Chemical Industry Co., Ltd.) and stirred at 50 ° C for 20 minutes. Dissolve 9 parts of tris(trifluoromethanesulfonium sulfonate) methoxide as a dmf in 9 parts. The DMF solution was dropped on the above solution and stirred for 3 hours. The precipitate was dried, washed with water and dried to give a dye (Compound No. 7 of Table 1). Maximum absorption wavelength: 419 nm (cyclohexanone). (Synthesis Example 5) (Combination Synthesis of Resin (Copolymer)) In a 500 ml four-necked flask, 60 g of mercaptoethyl ketone, 10 g of methacrylic acid, 33 g of benzyl methacrylate, and α, α azobis(isobutyronitrile) lg were poured. While stirring, nitrogen gas was introduced into the flask for 30 minutes. Thereafter, the temperature was raised to 8 (TC, and the mixture was stirred at 80 to 85 ° C for 4 hours. After the completion of the reaction, the mixture was cooled to room temperature to obtain a colorless transparent and uniform copolymer solution. These are precipitated in a 1:1 mixed solution of isopropyl alcohol and water, filtered, and the solid fraction is taken out and dried to obtain a copolymer (A). The polystyrene-equivalent weight average molecular weight of the obtained copolymer (A) The acid value was 152. (Example 0) Copolymer (A) 5 as a binder resin .4g, a photopolymerizable monomer, Kayarad RTM DPHA (manufactured by Sakamoto Chemical Co., Ltd.), 6 g, a photopolymerization initiator, Irgacure RTM907 (manufactured by Ciba Specialty Chemicals), 1. 5 g, and Kayacure rtmDETX-S (Japanese medicine) 6克, 〇·6g of Compound No. 1 of Synthesis Example 1, as a solvent, cyclohexanone 20g and propylene glycol monoterpene ether acetate (PGMEA) 8.6g, respectively The colored resin composition of the present invention is obtained. (Example 2) (i) C.I. Pigment bluel5 : 6/AjisupaRTM PB821/

SolsperseRTM5000/PGMEA=15. 0/6. 0/1. 0/78. 0 (mass ratio) composition ratio after mixing, add 〇. 3mm beads (bead) 4〇〇g, for 60 minutes with paint vibrating bottle The treatment was carried out, and the zirconium beads were removed by filtration, whereby Pigment Dispersion 1 was obtained. In addition, the above-mentioned C. I. Pigment bluel 5 : 6 is a copper indigo pigment, Ajisupa PB821 (trade name, Ajinomoto Fine-techno Co., Ltd.) and Solsperse RTM 5000 (trade name, manufactured by Lubrizol Co., Ltd., Japan) are dispersed. The agent 'PGMEA is a solvent of propylene glycol monoterpene ether. In addition, the above RTM represents a registered trademark. (ii) In the resin composition obtained in the same manner as in Example 1, 19 g of the pigment dispersion obtained in the above (i) was added to obtain a colored resin composition of the present invention. (Example 3) A colored resin composition of the present invention was obtained in the same manner as in Example 1 except that the compound N〇.1 of Synthesis Example 1 as a color material compound was changed to Compound No. 5 of Synthesis Example 2. (Example 4) (i) C. I. Pigment Red254/AjisupaRTMPB821/PGMEA= 15. 0/10. 0/75. 0 (mass ratio) composition ratio after mixing, adding 〇. 3mm error 323679 43 201229143 beads _ 'The treatment was carried out for 6 G minutes in a paint shaker bottle, and the wrong beads were removed by rubbing, thereby obtaining a pigment dispersion liquid 2. (1) In the test composition obtained in the same manner as in Example 3, 19 g of the pigment dispersion liquid 2 was added to obtain a colored resin composition of the present invention. (Example 5) In addition to Synthesis Example 1 as a color material compound The compound N〇. 1 was changed to the compound No. 6 of Synthesis Example 3, and the colored resin composition of the present invention was obtained in the same manner as in Example 1. (Example 6) A compound of Synthesis Example 2 as a color material compound was used. In the same manner as in Example 4 except that the compound No. 6 of the synthesis example 3 was used, the color resin composition of the present invention was applied. (Example 7) A compound N of Synthesis Example 1 as a color material compound was used. In the same manner as in Example 1, except that the compound No. 7 of the synthesis example 4 was changed, the colored resin composition of the present invention was obtained. (Comparative Example 1) Except that 19 g of the above-mentioned Example 2 (i) was used. In the same manner as in Example j except that the pigment dispersion liquid i was used instead of the compound No. 1 (0.6 g) of Example 1, the colored resin compound containing only the pigment (CI Pigment bluelS: 6) was used for the comparative coloring resin composition. (Comparative Example 2) Except for Compound No. of Synthesis Example 1 In the same manner as in Example 1, except that the coloring material compound of the formula (1) was used, a colored resin grade 323679 201229143 was obtained. (Comparative Example 3), except Compound No. 1 of Synthesis Example 1. Changed to the previous dye Bas ic

In the same manner as in Example 1, except for Blue 7, a colored resin composition was used. (Comparative Example 4) The compound No. 1 of Synthesis Example 1 was changed to the conventional dye Basic

A colored resin composition for comparison was obtained in the same manner as in Example 1 except for Red 14. (Comparative Example 5) The compound No. 1 of Synthesis Example 1 was changed to the conventional dye Basic

A colored resin composition for comparison was obtained in the same manner as in Example 1 except for Orange 22. (Production of Color Filter of the Present Invention) The colored resin compositions (Examples 1 to 7) obtained above were applied to respective glass substrates. The obtained coated substrate is pre-baked (8 (rCxl〇〇 second) and then exposed through a patterned mask to harden the exposed portion. Secondly, it is developed in an aqueous alkali solution containing a surfactant, after washing with water at 2 Heating in 〇〇 ° C and post-baking to obtain a color filter having a pixel pattern. The obtained color of the light-passing sheet is resolved with a line angle of 1 ine and space of 5 Am. It is confirmed that there is no residue, peeling of the pixels, etc. (Evaluation test) (i) Evaluation of substrate for evaluation of heat resistance and color filter for comparison (with the evaluation of the cured layer, 45 323679 201229143 price substrate) The colored resin composition of the present invention and the comparative colored resin composition were applied to the other glass substrates, and then subjected to total exposure and post-baking (20 (TC, 5 minutes) treatment). It is a color filter having vivid color characteristics. On the other hand, in addition to the evaluation substrate of Comparative Example i and Comparative Example 3, the evaluation boards of Comparative Examples 2, 4, and 5 were in the material stage. Have a significant visual color, It is not suitable as an evaluation substrate for color filters. (ii) Evaluation method and evaluation results The heat resistance and the comparison were evaluated as described below. Further, the comparative example was prepared for the gas-level substrate as described above in the stage of producing the evaluation substrate. The evaluation method was used as the evaluation substrate user, and the following evaluations were not performed. The evaluation substrates obtained in the above were subjected to 2:10 (C) for 120 minutes, UV-3150, and a knife photometer, manufactured by Shimadzu Corporation. The spectroscopic (four) rate of the optical plate was measured. The chromaticity of the color difference cC before and after the treatment was compared with the two eccentricity values (cd/on2) and vertical of the optical plate: The earth plate 'and * the brightness value of the two polarizing plates in parallel/the glow of the vertical direction...the ratio of the luminance value (Cd/Cm2) (the value of the glow in parallel) is calculated and compared. The evaluation of the heat resistance is _ '° Not in Table 2, the evaluation results are shown in Table 323679 46 3 ° 201229143 Table 2 Evaluation results of heat resistance [Table 2]

In the case of "~", it is indicated that in the stage of producing the substrate for evaluation, the drying stage is faded, and the transmittance of the absorption wavelength is more than 70%, and the effect of the heart color is not achieved, so the evaluation test is not performed. Yg^ 卜目目&gt; The color of the cured layer having the colored resin composition of the present invention has a long region in any region of the wavelength range of about 400 to 620 nm. Next, when the color filter of the present invention contains the compound of the formula (1) as a substance, the absorption of the compound of the formula (1) is the rightmost: when the light transmittance of the color light-receiving sheet is preferably about the right of the weight, the range is obtained. High-density color filter examples, 3, U 7 β, for example, 'Using the resin composition obtained from the real and the resin composition obtained by the upper layer of the ^ ^ ^ ^. Evaluation basis and the transmission of large wavelengths and the transmittance of the wavelength For example, Example ι (absorption maximum wavelength 601 nm): penetration rate of 3 flutter. &quot; 323679 47 201229143 Example 3 (absorption maximum wavelength 532 nm): penetration rate 30% Example 5 (absorption maximum wavelength 508 nm): transmittance 13% Example 7 (absorption maximum wavelength 416 nm): penetration rate 20% On the other hand, for comparison, a substrate for evaluation obtained by separately containing a resin composition of Comparative Examples 2 to 5 as a color material compound, except for Comparative Example 3, after the step of preparing the evaluation substrate was used. In the baking step, the dye was significantly discolored by decomposition of the dye, and the obtained substrate was found to have a transmittance of more than 70% in the maximum absorption wavelength of the dye used, and the color filter effect could not be obtained. Further, the evaluation substrate obtained by using the resin composition of Comparative Example 3 which was not significantly discolored in the post-baking step, as shown in Table 2, showed that the color difference before and after the heat resistance test was as high as 48.7, and it was found that the heat resistance was insufficient. In the heat resistance test, the color difference (AEab) before and after the test was 30 or less, and the others were 1 or less, and it was found that the heat resistance was excellent. . From the above results, the color luminescence obtained by using the resin composition of Examples 1 to 7 containing a specific ionic moiety ,-, particularly a compound of the formula (1) having a tris(trifluoromethane sulphide) sulfhydryl anion anion The sheet was significantly superior in heat resistance to the color filter obtained by using the resin composition of Comparative Examples 2 to 5 which have been dyed in the past. Further, the examples 2, 4, and 6 are mixed pigments of the color material of the present invention, but the insoluble components of (4) are not precipitated and the shape S is also good. This means that the resin composition of the coloring matter compound of the present formula (1) may be used in combination with the pigment as necessary. Therefore, the resin composition of the present invention has broad applicability. 323679 48 201229143 Table 3 Comparison of evaluation results [Table 3] Comparative Example 1 172 〇〇 Example 2 1 〇 8 〇〇 Comparative Example 1 85 〇〇 From the comparative evaluation results of Table 3, 'Comparative Example 1 Both Examples 1 and 2 showed good results compared to the pigments. In particular, the results of Example 1 only dyeing indicate a significant improvement in the contrast that is difficult to achieve with the pigment. Therefore, it was confirmed that the colored resin composition of the present invention has suitability as a next-generation color filter. (Industrial Applicability) The color filter of the cured layer of the colored resin composition of the present invention having the color material compound of the formula (1) described above does not fade at the manufacturing stage and the boat sheet is defective. The color property of the bright color is superior to that of the conventional dye-based color filter, and the color material compound contains the color material of the formula based on the color light-based film containing the pigment-based color material compound. The color county film is not only excellent in heat resistance, but also can achieve high contrast. This is because the resin composition of the present invention is applied to a color light-receiving film, which has high heat resistance and contrast, high quality and high reliability. The two sensations can also be mixed well with the pigments depending on the application. Therefore, the resin composition of the present invention is industrially * [Simple description of the drawing] 323679 49 201229143 None [Description of main component symbols]

Claims (1)

201229143 * VII. Patent application scope: 1. A colored resin composition for a color filter containing a color material compound represented by the following formula (1), a binder resin, a solvent, a polymerization initiator, and a hardener ; (wherein Rr to R6 each independently represent a hydrogen atom, a C1 to C30 alkyl group, an aryl group, a halogen atom or an amine group, and Y represents a sulfur atom, an oxygen atom, an amine group, a substituted or unsubstituted carbon atom, Ri and R2, R2 and R3, R3 and Y carbon atoms, or R4 and R5 may form an aliphatic saturated hydrocarbon system or an aromatic ring structure, respectively, or an anionic moiety χ- denotes a halogenated C1 to C10 alkane. a sulfonimide anion, a halogenated C1 to C10 alkylsulfonyl methide anion, or a functionalized C1 to C10 alkyl sulfonate anion, each having a halogen atom substitution of at least 3 in a halogenated C1 to C10 alkyl group ). 2. The colored resin composition for a color filter according to claim 1, wherein the oxime of the formula (1) is an bis(trifluoromethanesulfonyl)imide anion, a di(trifluoromethyl) group. Calcination thiol) methide anion, or trifluoromethylate anion. 3. The color filter resin composition according to the invention of claim 2 or 2, wherein the oxime of the formula (1) is a sulfur atom. 4. A color filter as claimed in any one of claims 3 to 323679 201229143 Aromatic ring = and _ separate = Please use the colored resin for color grading sheet described in the scope of the patent item: and the material of the formula (1) is the following formula: A, i-B or 1-C: R12 1-C (wherein Ru is a Cl to C4 alkyl group, R12 is a ci to C4 group which may be substituted by a group, and Ru is a group represented by the following formula B_1, B-2 or B-3, heart, R32, R33 and R34 each independently represent a C1 to C4 alkyl group, and χ- is the same as 2 323679 201229143 (1): In the formula, R22 is a C1 to C4 alkyl group, R23 is a phenyl group, R24 is a C1 to C4 alkyl group, and R25 is a mono- or disubstituted amino group substituted by a C1 to C4 alkyl group which may be substituted by a cyano group, and * represents Bonding position). 6. The colored resin composition for a color filter according to claim 5, wherein the oxime in the formula A, 1-B or 1-C is bis(trifluoromethanesulfonyl)imide An anion, a tris(trifluoromethanesulfonyl) anthracene anion, or a trifluorosulfonate anion. The colored resin composition for color filters according to claim 6, wherein Ru in the formula A is ethyl, Rlz is 2-hydroxyethyl, and X is bis(trifluorodecanesulfonate). An imine anion, a tris(trifluoromethanesulfonyl) methide anion, or a trisole R21 is a formula B1, B-2 or B-3} triflate anion; Formula 1_B Lanthanum is a tris(trifluorofluoranesulfonyl anion). It contains a metal anthraquinone pigment. 323679 3 201229143 9. A color filter comprising: a patterned cured layer of the colored resin composition according to any one of claims 1 to 7 or a metal anthocyanin pigment; The patterned cured layer of the colored resin composition according to any one of claims 1 to 7. 10. A display device equipped with a color calender as described in claim 9 of the patent application. A solid-state imaging element comprising the color filter of claim 9 of the patent application. 4 323679 201229143 IV. Designated representative map: (1) The representative representative of the case is: (). (There is no picture in this case) (2) A brief description of the symbol of the representative figure: (none) 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: R. w R» 3 323679