201221158 六、發明說明： 【發明所屬之技術領域】 本發明係-種二氧化氣釋放瓶其製造方法，制侧於—種能穩定 且長時間釋放低劑量二氧化氣於—空氣内，對該空氣進行消毒、殺菌、除 臭，亚形成保護，⑽止細菌、病毒、黴_病人侵而不傷害該空氣 中的人畜等生物之二氧化氣釋放劑及其製造方法。 【先前技術】 二氧化氣（Chlorine dioxide)於常溫常壓下，為—黃綠色的氣體。由於 二氧化氣本身具有-未成對的自由活性電子，因此二氧化氣具有強效的氧 化能力’可用來氧化如：細菌、病毒、黴菌等病原體的蛋白質、胜狀、dna 或RNA，以消滅該等病原體。目前，於醫療衛生、食品加王、環境保護、 工業循_水、畜牧養_及汗核理等產業中，二氧化氣已取代習用的 氣氣或臭氧，來進行消毒、殺菌、除臭。 現今’市面上有穩定型二氧化氣溶液與雙觸型_製鮮兩種二氧 化氯釋放劑’可用來產生二氧化氣。以穩定型二氧化氯溶液而言，其係將 二氧化氯吸餘碳_ (Na2C03)、嚷_ (响办.聰2C>)、過氧化氣 (H2〇2)或氫氧化鈉（Na0H)等溶液中，讓二氧化氯轉换成亞氯酸根（叫 _)之型態存在，於使用前，穩定型二氧化氣溶液必須經由活化或酸化，才 能產生二氧化氯。再者，以雙試劑麵體製劑而言，其含有二種試劑，分 別為亞氯義収_，於使时，將鱗觸添加至輕量的水令，2 能得到二氧化氯溶液供使用，藉此得到二氧化氯。 但是，上述該等二氧化氯釋放劑存在著無法穩定產生二氧化氯的缺 201221158 點，也就是說，隨著使用的時間獻，該等二氧化氯釋放劑產生的二氧化 氯會逐誠少，紐提縣時_赫、職及除臭魏：糾，於使用 初期’該等二氧化»放舰生的二氧化紐度㈣容易受遭溫度及 濕度的影響而突獻增，-般而言，於使用初期時，在空氣中測得的二氧 化氯漠度高達數萬_，她於研究報導指出空氣中二氧化氣具備消毒、 殺菌、除臭的有效濃度叫0ppm有數千倍的差異。雖然，目前並無證據顯 不人體處於濃度過高的二氧化氣環境中會5|發如：雜等重大疾病，但是 對於過敏患者而言，吸人過多的二氧化氣易引發呼吸相關器官過敏，導致 身體不適。是以’市面上的二氧化氣職綱實絲需改善之空間。 、^此録穩定且長時間釋放鋪量二氧化氯於一空氣内 、.—’氣釋放^’係本發明人及從事研發二氧化氣釋放劑相關人士積極 研發之方向。 【發明内容】 π本發明人麵於市面上的二氧錄釋放継法穩統產生二氧化氣， 吏^於使用初期時’在空氣中測得的二氧化氯濃度過高且無法帶來長時間 ' 杀又菌除臭功效，乃極力從事於二氧化氣釋放劑之改良與研發， 經過不斷地嘗試與努力，終於開發出本發明。 本I月之目的係提供一種能穩定且長時間釋放低劑量二氧化氯於一空 :内★對該減進订〉肖毒、殺菌、除臭，並形成保護，以防止細菌、病毒、 ?菌等病紐从而不傷害該空氣巾的人料生物之二氧化麟放劑。 為了達到上述之目的，本發明之二氧化氣釋補n凝膠狀結構 且包括： 201221158 混合液’係包括亞氣酸鹽、離子抓取劑以及活化劑；以及 吸水體，係吸附有該混合液。 本發明之另一目的係提供一種能穩定且長時間釋放低劑量二氧化氯於 一空氣内，對該空氣進行消毒、殺菌、除臭，並形成保護，以防止細菌、 病毒、黴菌等病原體入侵而不傷害該空氣中的人畜等生物之二氧化氯釋放 〇 劑的製造方法。 為了達到上述之目的，本發明之二氧化氯釋放劑的製造方法，該二氧 化氣釋放劑係為一凝膠狀結構，該製造方法包括： 提供步驟：提供一混合液，該混合液包括亞氣酸鹽、離子抓取劑以及 活化劑；以及 吸附步驟：使用一吸水體吸附該混合液。 本發明利用該亞氣酸鹽以及該活化劑反應生成二氧化氯，以提供消 毒、殺菌、除臭之功效；此外，於生成該二氧化氣時，會伴隨著離子的產 生，利用該離子抓取劑降低該離子的濃度，以穩定地產生該二氧化氣；再 者，利用該吸水體吸附該混合液，使得該二氧化氣得以被吸附於該吸水體 中，以延緩該二氧化氯釋放至一空氣，使得該空氣中的二氧化氯可長時間 地維持於具備消毒、殺菌、除臭的有效濃度範圍内，不致於大量地釋放至 。亥二氣中，且不易受到周遭溫度、渔度變化，而影響該空氣中二氧化氯的 /辰度，藉此，可以形成保護，防止細菌、病毒、黴菌等病原體入侵至該空 氣内’且不致於傷害該空氣中的人類、家畜等生物體。 【實施方式】 本發明之二氧化氯釋放劑，係為一凝膠狀結構且包括： 201221158 混合液’係包括亞氯酸鹽、離子抓取劑以及活化劑；以及 吸水體’係吸附有該混合液。 其中’該亞氣酸鹽係可為亞氯酸鈉、亞氣酸鉀或亞氯酸鋰。 該離子抓取劑係可為金屬離子螯合劑或離子交換樹酯。較佳地，該離 子抓取劑係為乙二胺四乙酸（丑卿丨enediaminetetraacetic acid ; EDTA) 〇 該活化劑係可為酸類或鹽類。較佳地，該活化劑係為檸檬酸（Citric acid )。 該吸水體係可為高吸水性樹酯、明膠、纖維或泡棉。較佳地，該吸水 體係為高吸水性樹酉旨。 此外’以該混合液之重量計，該亞氣酸鹽之重量百分比係為〇 〇1_5% ; 又’以該混合液之重量計，該離子抓取劑之重量百分比係為〇 〇1_2% ;再， 以該混合液之重量計，該活化劑之重量百分比係為0.01-5%。 請參看第一圖所示’本發明之二氧化氣釋放劑的製造方法，該二氧化 氣釋放劑係為-凝膠狀結構，該製造方法包括： 提供步驟（S1):提供一混合液，該混合液包括亞氣酸鹽、離子抓取劑 以及活化劑；以及 °及附步驟（S2):使用一吸水體吸附該混合液。 其中’該亞氣酸鹽係可為亞氣酸鈉、亞氣酸鉀或亞氣酸鋰。 該離子抓取劑係可為金屬離子螯合劑或離子交換樹酯。較佳地，該離 子抓取劑係為乙二胺四乙酸。 遠/舌化劑係可為酸類或鹽類。較佳地，該活化劑係為擰檬酸。 該吸水體係可為高吸水性樹酯、明膠、纖維或泡棉。較佳地，該吸水 201221158 體係為高吸水性樹酯。 此外’以該混合;夜之重量計，該亞氯酸鹽之重量百分比係為0.01-5% ; 又，以該混合液之重量計，該離子抓取劑之重量百分比係為讀_2%;再， 以該混合液之重量計’該活化劑之重量百分比係為⑽15%。 為了讓審查委員更容純解本發明之内容，特舉以下實施例說明，其 詳細說明茲如下所述： 首先’將1克亞氯酸鈉（純度40%)溶解於150毫升水中，形成一亞 氣酸納溶液。 接著’分別添加350毫克檸檬酸及3.5毫克乙二胺四乙酸至該亞氯酸鈉 浴液中均勻混合’以得到一混合液。 最後’取10克高吸水性樹酯吸附該混合液，以製備完成本實施例之二 氧化氣釋放劑。 於本實施例中，該亞氯酸鈉會與該檸檬酸反應生成二氧化氣以及檸檬 酸納。由於該檸檬酸鈉於該水中會解離成檸檬酸根離子以及鈉離子，加上 該乙二胺四乙酸會與該鈉離子形成一穩定的錯合物，降低了該鈉離子的濃 度，使得該二氧化氣可以穩定地產生；此外，該二氧化氣可吸附於該高吸 水性樹酯之孔洞内，使得該二氧化氯得以緩慢地被釋放於一空氣内。 為了進一步瞭解本實施例之二氧化氯釋放劑釋放二氧化氣至一空氣中 的情況，將本實施例置放於一 1立方公尺之檢測空間底部中央，並利用二 氧化氯濃度檢測器遵照下列方式檢測該檢測空間内二氧化氣的濃度，檢測 方式1，係置放該二氧化氣濃度檢測器距離本實施例2公分處；檢測方式2， 係置放該二氧化氣濃度檢測器距離本實施例30公分處·，檢測方式3，係置 201221158 放該一氧化氟濃度檢測益距離本實施例100公分處；檢測方式4，係置放該 一氧化氣?辰度檢測益於該檢測空間頂部四角落處。 凊參看第二圖所示，檢測方式1於使用5分鐘後二氧化氯的濃度為 9.08ppm，經過兩個月後，其濃度則為〇98ppm ;檢測方式2於使用5分鐘 後二氧化氯的濃度為0.75ppm ’經過兩個月後’其濃度則為〇.38ppm ;檢測 方式3於使用5分鐘後二氧化氣的濃度為〇.52ppm，經過兩個月後，其濃度 則為0.39PPm ;檢測方式4於使用5分鐘後二氧化氯的濃度為〇.48ppm，經 過兩個月後’其濃度則為〇.37ppm。由此可知，本實施例於該檢測空間内， 在使用兩個月後，其釋放於空氣的二氧化氯濃度依然維持在具有消毒、殺 菌、除臭功效的濃度範圍内，而且相較於市面上的二氧化氣釋放劑，在使 用初期，其釋放於空氣的二氧化氣濃度僅為數ppm ,不致於傷害該空氣中 的人類、家畜等生物，且不會對人體產生不適之反應。 顯然地，依照上面實施例中的描述，本發明可能有許多的修正與差異。 因此需要在其附加的權利要求項之範圍内加以理解，除了上述詳細的描述 外，本發明還可以廣泛地在其他的實施例中施行。上述僅為本發明之較佳 實施例，並非用以限定本發明之申請專利範圍；凡其它未脫離本發明所揭 示之精神下所完成的等效改變或修飾，均應包含在下述申請專利範圍内。 【圖式簡單說明】 第一圖係本發明之二氧化氣釋放劑的製造方法的流程示意圖。 第一圖係本發明之實施例利用不同檢測方式，於不同時間下偵測二氧 化氯濃度的結果。 201221158 【主要元件符號說明】 (si)提供步驟 (S2)吸附步驟201221158 VI. Description of the Invention: [Technical Field] The present invention relates to a method for producing a chlorine dioxide release bottle, which is capable of stably and prolonging the release of low-dose dioxide gas in the air for a long time. The air is disinfected, sterilized, deodorized, sub-formed, and (10) sterilized by bacteria, viruses, mildews, and the like, and does not harm the human body and the like. [Prior Art] Chlorine dioxide is a yellow-green gas at normal temperature and pressure. Since the oxidizing gas itself has an unpaired freely active electron, the oxidizing gas has a strong oxidizing ability, which can be used to oxidize proteins such as bacteria, viruses, molds, etc., scent, dna or RNA to eliminate the And other pathogens. At present, in the industries of medical and health, food plus king, environmental protection, industrial _ water, animal husbandry _ and sweat nuclear, the dioxide gas has replaced the conventional gas or ozone for disinfection, sterilization and deodorization. Today, there are stable dioxide dioxide solutions and two-touch type two fresh chlorine dioxide release agents, which can be used to generate dioxide gas. In the case of a stabilized chlorine dioxide solution, it is a chlorine dioxide-absorbing carbon _ (Na2C03), 嚷_ (Yingo. Cong 2C), peroxidizing gas (H2〇2) or sodium hydroxide (Na0H). In the solution, the type of chlorine dioxide is converted into chlorite (called _). Before use, the stabilized dioxide gas solution must be activated or acidified to produce chlorine dioxide. Furthermore, in the case of a two-reagent facet preparation, it contains two kinds of reagents, respectively, which are chlorinated, and when added, the scales are added to a light water, and 2 can be used for a chlorine dioxide solution. Thereby, chlorine dioxide is obtained. However, the above-mentioned chlorine dioxide-releasing agents have a lack of 201221158 points which cannot stably produce chlorine dioxide, that is to say, with the time of use, the chlorine dioxide produced by the chlorine dioxide-releasing agents will be less , Newt County when _ He, job and deodorant Wei: Correction, in the initial use of 'the two oxidations» put the ship's dioxide resistance (four) is susceptible to temperature and humidity and suddenly increase, generally At the beginning of the use, the chlorine dioxide measured in the air is as high as tens of thousands of _, she reported in the study that the effective concentration of air dioxide in the disinfection, sterilization, deodorization is thousands of times 0ppm difference. Although there is no evidence that the human body is in an excessively high concentration of dioxide gas, it will cause major diseases such as: miscellaneous diseases, but for allergic patients, excessive intake of dioxide gas may cause respiratory related organ allergy. Causes physical discomfort. It is the space for the improvement of the market for the gas dioxide in the market. ^ This record is stable and long-term release of the amount of chlorine dioxide in an air, -" gas release ^' is the direction of the inventors and those engaged in the development of gas dioxide release agents. SUMMARY OF THE INVENTION π The inventors of the present invention produced a stable generation of dioxide gas in the market by the dioxin release method, and the concentration of chlorine dioxide measured in the air was too high at the initial stage of use and could not bring long The time 'killing and deodorizing effect is the improvement and research and development of the dioxide release agent. After continuous trial and effort, the present invention has finally been developed. The purpose of this month is to provide a stable and long-term release of low-dose chlorine dioxide in one space: within the ★ ★ reduction of the poison, sterilization, deodorization, and protection to prevent bacteria, viruses, bacteria Waiting for the disease, so as not to harm the human body of the air towel. In order to achieve the above object, the present invention provides a dioxate-removing n-gel-like structure and includes: 201221158 a mixed solution comprising a gas sulphate, an ion grabbing agent, and an activator; and a water absorbing body adsorbing the mixture liquid. Another object of the present invention is to provide a stable and long-time release of low-dose chlorine dioxide in an air, disinfecting, sterilizing, deodorizing, and forming protection against pathogens such as bacteria, viruses, molds, and the like. A method for producing a chlorine dioxide-releasing agent for living organisms such as humans and animals in the air. In order to achieve the above object, in the method for producing a chlorine dioxide releasing agent of the present invention, the sulfur dioxide releasing agent is a gel-like structure, and the manufacturing method comprises the steps of: providing a mixed liquid comprising a sub-liquid a gas salt, an ion grabber, and an activator; and an adsorption step: adsorbing the mixture using a water absorbing body. The invention utilizes the gas sulfite and the activator to react to form chlorine dioxide to provide disinfection, sterilization and deodorization effects; in addition, when the gas is generated, the generation of ions is accompanied by the use of the ions The agent reduces the concentration of the ion to stably generate the dioxide gas; further, the water mixture is adsorbed by the water body to allow the gas to be adsorbed in the water body to delay the release of the chlorine dioxide To the air, the chlorine dioxide in the air can be maintained in an effective concentration range for disinfection, sterilization, and deodorization for a long time, and is not released to a large amount. In the second gas, it is not easy to be affected by the temperature and the change of the surrounding temperature, and affects the chlorine dioxide in the air. This can protect the bacteria, viruses, molds and other pathogens from invading into the air. It does not harm humans, livestock and other organisms in the air. [Embodiment] The chlorine dioxide releasing agent of the present invention is a gel-like structure and comprises: 201221158 a mixed liquid comprising a chlorite, an ion grabbing agent and an activator; and a water absorbing body Mixture. Wherein the sub-acid salt may be sodium chlorite, potassium sulfite or lithium chlorite. The ion grabbing agent can be a metal ion chelating agent or an ion exchange resin. Preferably, the ion scooping agent is ethylenediaminetetraacetic acid (EDTA). The activator may be an acid or a salt. Preferably, the activator is Citric acid. The water absorbing system can be a highly water-absorbing resin, gelatin, fiber or foam. Preferably, the water absorbing system is a highly water-absorbent tree. In addition, the weight percentage of the gas sulfite is 〇〇1_5% by weight of the mixed liquid; and 'the weight percentage of the ion grabbing agent is 〇〇1_2% by weight of the mixed liquid; Further, the weight percentage of the activator is from 0.01 to 5% by weight of the mixed liquid. Referring to the first aspect of the invention, a method for producing a dioxide gas releasing agent according to the present invention, wherein the gas dioxide releasing agent is a gel-like structure, the manufacturing method comprising: providing a step (S1): providing a mixed liquid, The mixed solution includes a sulphuric acid salt, an ion grabbing agent, and an activator; and a step (S2): adsorbing the mixed liquid using a water absorbing body. Wherein the sub-acid salt may be sodium sulfite, potassium sulfite or lithium nitrite. The ion grabbing agent can be a metal ion chelating agent or an ion exchange resin. Preferably, the ion scooping agent is ethylenediaminetetraacetic acid. The far/tongue agent can be an acid or a salt. Preferably, the activator is citric acid. The water absorbing system can be a highly water-absorbing resin, gelatin, fiber or foam. Preferably, the water-absorbing 201221158 system is a highly water-absorbing resin. In addition, the weight percentage of the chlorite is 0.01-5% by weight of the mixture; and the weight percentage of the ion grabbing is 2% by weight of the mixture. Further, the weight percentage of the activator is (10) 15% by weight of the mixture. In order to make the reviewer more purely explain the contents of the present invention, the following examples are described, and the detailed description thereof is as follows: First, '1 gram of sodium chlorite (purity 40%) is dissolved in 150 ml of water to form a A sub-gas sodium solution. Then, '350 mg of citric acid and 3.5 mg of ethylenediaminetetraacetic acid were separately added to the sodium chlorite bath to uniformly mix' to obtain a mixed solution. Finally, 10 g of the superabsorbent resin was adsorbed to adsorb the mixed solution to prepare the dioxin releasing agent of this example. In this embodiment, the sodium chlorite reacts with the citric acid to form a dioxide gas and sodium citrate. Since the sodium citrate dissociates into citrate ions and sodium ions in the water, the ethylenediaminetetraacetic acid forms a stable complex with the sodium ions, thereby reducing the concentration of the sodium ions, so that the two The oxidizing gas can be stably produced; in addition, the oxidizing gas can be adsorbed into the pores of the superabsorbent resin, so that the chlorine dioxide can be slowly released into an air. In order to further understand the case where the chlorine dioxide releasing agent of the present embodiment releases the dioxin gas into an air, the present embodiment is placed in the center of the bottom of the detection space of one cubic meter, and is compliant with the chlorine dioxide concentration detector. The concentration of the dioxide gas in the detection space is detected in the following manner. The detection mode 1 is to place the dioxide gas concentration detector at a distance of 2 cm from the embodiment; and the detection mode 2 is to set the distance of the gas dioxide concentration detector. In the present embodiment, 30 centimeters, the detection mode 3, is set to 201221158, the concentration of the fluorine oxide is determined to be 100 centimeters in the present embodiment; and the detection mode 4 is to set the oxygen gas to be detected in the detection. Four corners at the top of the space.凊 Refer to the second figure, the detection method 1 after the use of 5 minutes, the concentration of chlorine dioxide is 9.08ppm, after two months, the concentration is 〇98ppm; detection method 2 after 5 minutes of chlorine dioxide use The concentration is 0.75ppm 'after two months', the concentration is 〇.38ppm; the detection method 3 after 5 minutes of use, the concentration of dioxide is 〇.52ppm, after two months, the concentration is 0.39PPm; In the detection mode 4, the concentration of chlorine dioxide was 〇.48 ppm after 5 minutes of use, and after two months, the concentration was 〇.37 ppm. It can be seen that, in the detection space, the concentration of chlorine dioxide released from the air in the detection space is maintained within the concentration range of disinfection, sterilization and deodorization effects, and compared with the market. In the initial stage of use, the concentration of the dioxide released into the air is only a few ppm, which does not harm humans, livestock and other organisms in the air, and does not cause discomfort to the human body. Obviously, many modifications and differences may be made to the invention in light of the above description. It is therefore to be understood that within the scope of the appended claims, the invention may be The above are only the preferred embodiments of the present invention, and are not intended to limit the scope of the claims of the present invention; any equivalent changes or modifications made without departing from the spirit of the invention should be included in the following claims. Inside. BRIEF DESCRIPTION OF THE DRAWINGS The first drawing is a schematic flow chart of a method for producing a dioxide gas releasing agent of the present invention. The first figure is the result of detecting the concentration of chlorine dioxide at different times using different detection methods in an embodiment of the present invention. 201221158 [Explanation of main component symbols] (si) Provide step (S2) adsorption step