TW201216858A - Method for protecting living plants from harmful insects via a sheetlike structure - Google Patents

Abstract

The present invention provides a method for protecting living plants from harmful insects by using a sheetlike structure impregnated with an insecticide to cover the surface of the trunk, pseudotrunk, branch, root ball and/or root region of the plant. Additionally provided are living plants whose trunk, pseudotrunk, branch, root ball and/or root region surface is covered with a sheetlike structure impregnated with an insecticide. The invention also relates to a rectangular sheetlike structure impregnated with an insecticide and comprising a fastening means which, following tubular coverage of the surface of trunk, pseudotrunk or branch of a plant, allows a permanent hold thereto. It further relates to a sheetlike structure impregnated with an insecticide, in the form of a perforated sheet which has a continuous interruption between the outer and inner edges. Lastly, it also relates to the use of the sheetlike structure for protecting living plants from harmful insects.

Description

201216858 VI. Description of the Invention: [Technical Field] The present invention provides a method for covering a surface of a plant trunk, a stem, a branch, a root group and/or a root region by using a tablet-shaped clock body impregnated with an insecticide. A method of protecting living plants from pests. Also provided are living plants in which the trunk, the stem, the branches, the roots and/or the root zone are covered with a tablet-like structure impregnated with an insecticide. The present invention is also directed to a rectangular sheet-like structure that is impregnated with an insecticide and includes a fixing member that allows for permanent retention after tubular coating of the trunk of the plant, the stem or the surface of the branch. It is further related to a sheet-like structure impregnated with an insecticide in the form of a perforated sheet having a continuous interruption between the outer edge and the inner edge. Finally, it is also about the use of the sheet structure to protect living plants from pests. The invention includes combinations of preferred features and other preferred features. [Prior Art] Various insects require living plant parts for reproduction and/or development. For example, 'bark beetles and bark bark aphids enter living plants to lay eggs in them. Certain insects, such as plant-destroying butterflies, beetles, and gibberella, are printed on plant parts, and hatching larvae enter the woody parts of the plant to continue their development. Other insects eat leaves, needles or bark. In the case of cork ’, precious cork should be protected from the invasion of cork bark beetle. Various insects spend the winter in the bark of the living tree and move to the canopy in the spring to eat. Moreover, in the root zone itself and around the plant, pests (such as citrus beetles, chafers, leaf bees and weevils) are inhabited to prevent hatching and/or emergence of such pests, as well as eating bark and trunk. So far, pesticides have been sprayed directly on protected plants and plant parts. 158662.doc 201216858 The above disadvantages are drift (not location-accurate application) and therefore contamination of the perimeter. For this reason, many technologies cannot even be used in water protection areas or flowering periods to protect bees (including bumblebees) and, in the application of the prior art, to treat whole trees and shrubs, and to spray large amounts of insecticides. SUMMARY OF THE INVENTION The object of the present invention is to find a method for protecting living plants, such as trees and shrubs, from pests. The object is achieved by a method for covering a surface of a plant trunk, a stem, a branch, a root group and/or a root region by using a sheet-like structure impregnated with an insecticide to protect the living plant from pests. . [Embodiment] A living plant is a biologically active and intact plant. It is different from dead plants that can no longer grow. The roots of living plants are usually in contact with the substrate, for example with the soil: the matrix in the basin. For example, a tree in a dormant state, such as in a long time, is also considered a living plant. As long as it has biological activity and complete right root rhizomes (such as trees with exposed roots (4) living plants and plants are all those with at least one trunk, false stems or branches. In addition, suitable plants for them have skin # (10) And more preferably at least 30 c... (10) (preferably at least 10 乂cm) of the roots of the roots. Other suitable plants are those of which are trees and irrigated; >, 20 i diameter roots Examples are trees and shrubs. ^ 5 0 C m) Preferred plants are trees, such as conifers (Pinus, Larch, Stone Pine, Fir, Cedar, Right Tree, Spruce, Citi Mapan, Hedgehog, Birch, Pear) Trees, cedars, and deciduous trees (such as +, oak (such as cork), 158662.doc 201216858, moon, white, white snail, wild eucalyptus, elm, horn, cherry, chestnut, Lime tree, American walnut, white poplar, sycamore, peach, eucalyptus, hedgehog, eucalyptus, walnut, rubber tree, porch, willow, turkish). The better plants are deciduous trees. Preferably, the deciduous tree is a fruit tree, X hunger--, ·, Hu, 1 丨 丨 j such as frequency fruit tree, 4 tree, eucalyptus, eucalyptus [S0rbus d〇mestica], stone fruit (such as cherry tree, acid) Cherry, plum, black, peach, apricot, nectarine, or small fruit grown in trees (eg blackcurrant, gooseberry, better, pome fruit, and stone fruit) In another embodiment, the oak tree, such as a soft deciduous tree, is the main stem of the plant organ, and the stem and the branch are known to those skilled in the art. The part of the plant that is structurally shaped like the trunk is also considered to be a dry stem. The base may be exposed or surrounded by a substrate. The diameter of the trunk, the stem and the branches is usually at least 0.5 cm, preferably at least 2 cm, and more preferably at least 5 〇 of the root zone of the plant is often understood as the root extension a region near the plant. It is preferably a nearly circular region around the plant on the surface of the soil. In a preferred embodiment of the method of the invention, the sheet structure is used to cover the trunk, the stem and/or the branches of the plant (more specifically Trunk or dummy, especially trunk) another method of the invention In a preferred embodiment, the sheet structure is used on the surface of the plant roots. ^ In another preferred embodiment of the method of the invention, the sheet structure is used for the surface of the roots of the plant. The cover sheet structure covers the trunk and the dummy Dry, branch, root and/or root surface 158662.doc 201216858 Here 5 my "covering sounds> g 接触 contact. shy" ^ 曰 sheet-like structure in area and surface at least partially in the method of the invention Wherein, the sheet structure covers the surface for at least 1 month, more preferably at least 3 months, and is excellent for at least 1 week, preferably 12 months less. The sheet structure can be frosted for ^6 months, and especially to a suitable sheet. Examples of structures include up to 3 years. Materials, non-woven plastic materials, paper, leather, and cotton = as polypropylene, polyethylene, and polystyrene (for example, he is a better material. Or a sheet material, and the sheet material generally has an area of at least coffee V, preferably at least 0.005 m2 and more: up to 0.05 m2. The area is up to ... preferably up to 30 0 m, more preferably up to 3.0 m2. Mesh::=Γ: Γ-based textile materials, more specifically textile fibers can be natural or synthetic fiber mesh. Fibers of interest are of course also included; blends comprising two or more different fibers. Examples of the natural fiber include "or hemp fiber 1 is a synthetic fiber made of a suitable polymer. Examples include polyamine, polyester, polyacrylonitrile or polyfluorene. Preferred is decylamine, polyfluorene hydrocarbon' And poly vinegar, more preferably dense smoke, especially polypropylene or vinylidene, and polyester. Especially preferred is polyester fiber, more specifically polyethylene terephthalate (PET). The fiber can be monofilament m multifilament, and can be structured. In the case of polypropylene and polymethylene, the polymer of interest may be a polypropylene or polyethylene homopolymer. In addition, 'copolymer, except ethylene or propylene, respectively Including a small amount of other comonomers. Suitable comonomers may be other 158662.doc 201216858 hydrocarbons, such as ethylene or propylene, and butene, 2-butene, isobutylene, pentene, 1-hexene, 1 - heptene, octene, styrene or cardiomethylstyrene, diene and/or polyene. The fraction of comonomer in polyethylene or polypropylene is generally not more than 20% by weight, preferably not more than 丨〇% by weight. The nature of the comonomer and the lanthanide are selected by those skilled in the art according to the desired fiber properties. Particularly preferred for fiber manufacture are relatively high molecular weight viscous products characterized by their melt flow index (measured according to ISO 1133). A material preferably has a enthalpy of from 1 to 6 〇g/1 〇min. At least one polypropylene or polyethylene having a smelting flow index (230 C, 2.16 kg), preferably having a melt flow index MFR of 1 to 50 g/l ( min (23 〇 ec, 2 16 polypropylene, more preferably 10 Up to 45 g/l 〇 min, and for example 3 〇 to 4 〇 g / 1 〇 min. Such polypropylene grades are particularly suitable for the manufacture of fibers. Of course, it is also possible to use mixtures of two or more different grades of polypropylene depending on the type of mesh. The textile fiber may have a thickness of 0.05 to 0.6 mm, preferably 〇.1 mm to 0.4 mm, more preferably 0_12 to 0.35 mm, and preferably 〇2 to 〇3 mm. The preferred mesh preferably has a number of sides. a pattern of meshes. These webs preferably consist of only a mesh of mesh type, for example consisting only of a quadrilateral mesh or only a hexagonal mesh, or may also comprise two or more different meshes, such as The combination of an octagonal shape and a quadrilateral mesh. Here, the mesh of the mesh is preferably substantially the same type. Words, although the network does show slight deviations in the shape or size of mesh, but this will vary around the average equivalent Broadly sieve of mesh size range, for example, 0.5 mm to 25 mm, more

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S 201216858 Good 1 mm to 20 mm. The preferred mesh size (the length of the side of the square square mesh) is 5 mm, preferably 25 mm, more preferably 1.5 mm as the upper limit, 0.1 mm, preferably 0.25 mm, more preferably 0.5 mm, especially 0.7 as the lower limit. Within the range of mm. The mesh of the mesh is preferably selected from the group consisting of quadrilateral, hexagonal or octagonal mesh. The quadrilateral mesh is a parallelogram with meshes of edges & b and b. The term "parallelogram" of course also includes the terms "rectangle" and "square". The smaller angle between the two sides of the parallelogram is generally between 6 and 9 inches. between. In the case of a boundary line of 90, the parallelogram is a rectangle. In the case of the boundary line of a = b and 9 ,, it is a square. In addition, the parallelogram has a height ha. In the case of a rectangle or a square, the height 匕 is equal to the length of the edge & Square pain is especially good. In the case of a hexagonal mesh, three pairs of sides a, b and C which are respectively parallel to each other are arranged with distances ha, hb and he. In the case of the person's side (four), they are different from each other: the four sides of the line a, b,. The heart is set by distance I & Those skilled in the art understand that octagons cannot be used to make continuous patterns. The mesh comprising the octagonal mesh thus also includes at least one other mesh. These can be quadrilateral meshes. In a specific embodiment of the invention, the parallelogram, hexagonal and quadrilateral heights hAoa to 0.99 _, preferably 〇1 to 〇9, more preferably 0.12 to 0.8 mm and preferably 0.25 to 0.7 mm. For parallelograms, the aspect ratio b/ha is 1:1 to 5:1, preferably ^ to 4:ι and more preferably 2:1 to 4:1. Therefore, in the case of a ratio of ~:1, the mesh can include a square of 0.1 to 0.99 mm side length I58662.doc -9- 201216858. For larger ratios b/ha, the structure is elongated in both directions. By a distance ha of no more than 0.99 mm, it is even possible to effectively prevent relatively small insects from passing through the mesh, and the length can be greater than 0.99 mm' so that the mesh permeability is not excessively hindered. In the case of a hexagon, the ratio ((hb+hc)/2)/ha is 1:1 to 5:1, preferably 1:1 to 4.1 and more preferably 2:1 to 4:1. This is similar to a parallelogram. In the case of 丨:丨, the structure is a regular hexagon having three equilateral sides with an equal distance of not more than G.99 mm. In the case of a larger ratio ((hb+he)/2)/ha, the hexagon is elongated in the - direction. The effect on insects and air passage is for parallelograms. In the case of octagons, the ratio ((hb+hc+hd)/3)/h^1:1 to 5:1, preferably to 4.1 and more preferably from 2.1 to 4:1. This is similar to a parallelogram. In the case of the ratio ^:, the structure is a square shape having four equilateral sides, and there is an equal distance not exceeding ο·99 _ between each other. In the larger ratio ((hb+hc+hqingh, If)\the edge is elongated in _ direction. The effect on insects and air passing is for parallelograms. Except for quadrilateral and hexagonal mesh For example, in this embodiment, it is also possible to use a quadrilateral and an octagonal diaper, and σ, or change the mesh edge of the mesh of the partial mesh to be more tightly woven, or include Other relatively thick textile fibers of the same type may be woven at a certain distance for stability purposes. The terms "height" and "county _ each door of the arsenal" are not considered The open area of each mesh of the fiber or coated fiber. Similarly, the term "mesh size" based on the purpose of the present invention is not classified as the eyelet size, such as the mesh or the mesh of the coated fiber. 158662.doc Open area of 201216858. The textile web material according to this embodiment of the invention is described in WO 2010/012671. The thickness of the fibers used to make the textile material of the invention, more specifically the web of the invention, is Those who are good at the technology choose according to the nature of the network. In general, the thicker the fiber, the stronger the mechanical stability of the mesh; on the other hand, the proportion of the open zone to the fiber coverage zone will continue to decrease with less mesh size. Generally, the fiber thickness should be at least 2 inches. %, preferably at least 4G% and better at least the open area of the town. Available

network. The network of J 较佳 is preferably a single layer network. However, it may also be referred to as a spacer fabric where the two webs are joined together by a single yarn to form a double layer. The term "impregnation" means that the textile structure is treated by any of the at least one insecticide' to achieve a homogeneous distribution of the mixture on or within the sheet structure. Homogenization means that the concentration of the insecticide is substantially the same at each point of the sheet. In the embodiment, the impregnation is formed into a sheet-like structure of monofilament or more by coating a sheet-like structure with at least one insecticide and a binder (^A). Silk or fiber to complete. The function of the adhesive is to fix the killer on the monofilament or enamel, enamel or fiber of the sheet structure or on the pre-formed sheet structure ("at the end of the edge coating;:") The effect of this is that the active ingredient cannot be leached at least very slowly. The polymeric binder can in principle be used to include any desired binder, as long as the binder can specifically immobilize the mixture of Therefore, 158662.doc 201216858 is preferably a binder known from the field of textile impregnation and textile coating. It should be understood that a mixture of two or more different binders may also be used. Examples include (meth)acrylic acid. a homopolymer or a copolymer, a polyurethane, a polyisocyanurate or a hydrazine, such as a polyethylene ruthenium. The binder of interest may be, for example, a binder by polymerizing an ethylenically unsaturated monomer, preferably selected from the group consisting of (meth) acrylate, more preferably (f-) acrylic acid - to c12 vinegar, (meth) acrylate containing cross-linking groups, (meth) acryl, maleic acid or Maleic acid ester, acrylonitrile, stupid ethylene, B At least one monomer of the group of vinyl acetate, vinyl alcohol, ethylene, propylene, allyl alcohol or vinyl chloride. In a preferred embodiment of the invention, it comprises from 5 to 95% by weight of the monomer. a copolymer of an ethylenically unsaturated monomer of at least one (fluorenyl) acrylate (A) having the formula H2C=CHRi_c〇〇R2, wherein the rule 1 is 11 or a methyl group and R is 1 to 12 carbon atoms, An aliphatic, linear or branched hydrocarbon group of preferably 2 to 10 carbon atoms. R1 is preferably Η. Examples of suitable groups R2 include, in particular, anthracenyl, ethyl, n-butyl or 2-ethylhexyl Preferably, the ethyl group, n-butyl group or 2-ethylhexyl group. Further, the copolymer comprises 1 to 2% by weight of (fluorenyl)acrylic acid or a (meth)acrylic acid derivative (Β) having other functional groups. It may be in the form of a specific (meth) acrylate and/or (meth) acrylamide. The functional group serves to bond the binder to the web and may be used for crosslinking. For example, it may be in the form of 〇: 〇-Hydroxyalkyl (meth) acrylate, (meth) acrylate having a % oxygen group, such as shrinkage Glycerin, (meth) acrylamide or a derivative thereof, such as (mercapto)acrylic acid of the formula H2C=CH(CH3)-CO-HN-CH2-OH via methyl decylamine.

158662.doc - \2~ S 201216858 A rare unsaturated monomer (c) of A and B, such as acrylonitrile or styrene. Usually, the other monomer amount is from 〇 to 3% by weight. More preferably, it comprises 70 to 90% by weight of an acrylate of the formula H2C=CH2_c〇〇r2 (wherein R2 includes 4 to 8 carbon atoms and preferably n-butyl group and (4) ethylhexyl group) and 1 G to 20 parts by weight. A binder of % acrylonitrile, wt% (mercapto)acrylic acid or a (meth)acrylic acid derivative having a functional group (specifically, (meth)acrylic acid hydroxymethyl decylamine). The above preferred binder 3 is preferably prepared by a method known to those skilled in the art, preferably by emulsion polymerization. Preferred are acrylate adhesives, in particular copolymers, which are obtainable by emulsion polymerization of components B1 to B4 and optionally B5. As component B1, one or more, preferably i, 2 or 3, preferably a (meth) acrylate of formula (I), H2C=CR1-C00R2(I) wherein each symbol has the following meaning: R1 is Η or ch3, preferably η, and R is Cl_Cl〇-alkyl, preferably decyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, second butyl, third Butyl, n-pentyl, second amyl, neopentyl, 1,2-dimercaptopropyl, isopentyl, n-hexyl, isohexyl, n-heptyl, n-octyl, 2-ethylhexyl, N-decyl or n-decyl, especially methyl, ethyl, n-butyl or 2-ethylhexyl, excellent ethyl, n-butyl or 2-ethylhexyl. Component B 1 is preferably methyl acrylate, ethyl acrylate, n-butyl acrylate, 2-ethylhexyl acrylate and methyl f-methacrylate. Also preferred is C 158662.doc 13· 201216858 Dilute butyl ester itself or a leak thereof with methyl methacrylate or ethyl acrylate. Especially preferred is n-butyl acrylate. The substance used as component B2 is selected from the group consisting of glacial methyl methacrylate, methyl methacrylamide, hydrazine, hydrazine, bishydroxymethyl maleic acid diamine and ν, ν, bishydroxyindole At least one monomer of the group consisting of diammonium fumarate. Preferred are hydrazine-hydroxymethyl acrylamide and hydrazine-hydroxymethyl decyl acrylamide, and hydrazine-methyl decyl amide. The substance used as component Β3 is one or more monomers, preferably selected from one or two monomers consisting of propionic acid, methacrylic acid, vinyl sulfonic acid, maleic acid and fumaric acid. Preferred is acrylic acid and methyl acetoacetate; particularly preferred is acrylic acid. The substance used as component Β4 is one or more monomers, preferably one selected from the group consisting of Β4α and/or Β4Β or two monomers. Groups of Α4Α(π) and/or ((1)), H2C=CR3X (II) ZHC=CHZ (III) where each symbol has the following meaning: R3 is Η or CH3, preferably Η X is z, -CO-NH-CH2-NH-CO-CR3=CH2 or COO-CH2-CO-ch2-coor4, preferably z; Z is CCmH2, CONH-CH2-OR5, COO-Y- OH, coo-glycidyl, CHO, CO-Y-OH, preferably c〇NH2; Y is a Ci-Cs-extension group, preferably a c2_c6-extension group, and R4, R5 are the same or The different is a linear or branched alkyl group; and the (meth) acrylate-modified benzophenone is as described, for example, in Ep_a 〇 346 158662.doc • 14·201216858 734. Preferred monomers from the group B4A are acetamyl acrylate, acetamethylene methacrylate, acrylamide, methacrylamide, dimethylamine maleate, N-methoxy- Methyl acrylamide, N-n-butoxymethyl acrylamide, 3-hydroxypropyl acrylate, 3-hydroxypropyl methacrylate, 4-hydroxybutyl acrylate, 4-hydroxybutyl Mercapto acrylate, 6-hydroxyhexyl acrylate, 6-hydroxyhexyl methacrylate, 2-hydroxy-3-isopropyl propyl acrylate, 3-hydroxy-3-chloropropyl methacrylate, glycidol acrylate Ester and mercapto-acrylic acid glycidol vinegar. Particularly preferred are acrylamide, 3 propyl propyl acrylate, butane diol monoacrylate acetate, glycidyl methacrylate and 4-propenyl oxy-benzophenone . The monomer substances of the group B4B are allyl acrylate, decyl allyl acrylate, allyl methacrylate, decyl allyl methacrylate, diallyl maleate, dimercapto maleate Allyl ester, allyl fumarate, fluorenyl fumarate, propylene carbonate, diallyl phthalate, dimethyl propyl phthalate, diallyl terephthalate , Didecyl allyl terephthalate, p-divinylbenzene, butane-1,4-diol diallyl ether and butyl-i,4-diol di-decyl, allylic bond. The preferred monomers of group B4 are those of group B4A, preferably one or two monomers from the group. Preferred monomers of group B5 are those of group B5A, and the vinyl aromatic monomer of group b5b. Preferably, acrylonitrile or mercapto acrylonitrile is used, preferably acrylonitrile is used as component B5A 〇158662.doc -15- 201216858 Group B5B is preferably ethylene and α-methylstyrene, especially preferably Stupid. In a preferred embodiment, acrylonitrile is used as a monomer for the preparation of the acrylate 5 component of the acrylate adhesive. The acrylate adhesive (Β) is obtained by emulsion polymerization of the following materials (the data represented by weight / 〇 based on the total amount of ruthenium, respectively): bl) 20 to 93% by weight, preferably 50 to 9% by weight , especially 6 〇 to 9 〇 wt% 'specifically 75 to 85% by weight of component B1; b2) 1 to 5 by weight. /. 'preferably 1.5 to 3% by weight of component b2; b3) 0.2 to 5 wt%. , preferably 〇 5 to 4 by weight. /〇, particularly preferably 0.75 to 4% by weight 'specifically 1 to 3% by weight of component B3; b4) 0 to 7% by weight, preferably 〇 to 5% by weight, particularly preferably 4 to 5% by weight,疋s 0 or 0.2 to 4.5% by weight of component B4; and b5) 0 to 40% by weight, preferably 5 to 4% by weight, particularly preferably 5 to 3% by weight, specifically 0 or 5 to 26 Weight ❶ /. Component B5. Suitable methods are known and described by those skilled in the art, for example, in W〇 2005/064072 (page 20, line 20 to page 23, line 15). The weight average molecular weight of the obtained non-crosslinked emulsion polymer is generally between 4 Å and 250 Å (the molecular weight measured by GPC (gel permeation chromatography) is generally a constant chain terminator (for example) The organic sulphur compound is generally adjusted in the form of an aqueous dispersion and is generally used in the form of the insecticide formulation of the present invention. The preferred acrylic vinegar binder may further comprise Commonly used additives known to the skilled person, such as film formers and/or plasticizers, such as adipic acid 158662.doc •16·201216858

The surgeon knows. , diester mixture, from the two acid buffer acid and alcohol are good at this technology in addition to the above binders, other suitable for the polysulfuric acid and polyoxime, melamine / formaldehyde condensation polyoxane, A resin having a fluorinated hydrocarbon group, a trihydrate, a methylol urea derivative, and a curable polyester are preferably a polyoxygenated oil. Preferably, the polyoxyxanic oil and the polyoxyxanthene wax are generally in the form of a linear or cyclic polyorganooxygen oxyhydroxide, preferably a polyalkylene group and/or a polystyrene group, and the alkyl group is, for example, a fluorenyl group. Ethyl, propyl or octyl, preferably fluorenyl. More preferably, it is a corresponding compound in which polydimethylsiloxane, poly(methylphenyloxane), and a certain proportion of mercapto groups thereof are replaced by higher alkyl groups. The molecular weight is preferably between 1000 and 150,000. Optionally, the polyoxyl oil and, in particular, the polyoxyxide wax may include a consistency regulator such as a metal soap such as stearic acid clock, highly dispersed vermiculite, PTFE, boron nitride or urea to obtain a paste or fat. Consistency. For the manufacture of the sheet-like structure of the present invention, in particular, the binder may be in the form of a solvent-soluble formulation, preferably an aqueous formulation. However, the present invention also encompasses the use of solvent-free formulations. In a preferred embodiment, the aqueous formulation used comprises from 5 5 to 99% by weight water, preferably from 85 to 98% by weight water and from 1 to 45% by weight, preferably from 2 to 15 parts by weight. / 〇 solid, the specified amount is expressed based on the total amount of all components in the formulation. The exact concentration also depends on the adsorptivity of the textile substrate. The solid is in the form of at least one binder, a mixture of pesticides, optionally at least one crosslinking agent, and optionally other components. 158662.doc 201216858 It is preferred to use at least a water dispersible crosslinker. In particular, in the case of a preferred propylene-mixing agent, it may preferably be in the form of a crosslinking agent having a free isocyanate. These may preferably be employed in the form of a isocyanuric acid vinegar having a free isocyanate, preferably derived from an aliphatic, cycloaliphatic or aromatic diisocyanate, having a 4 to (2) carbon atom, of isocyanuric acid vinegar. . Examples include diisocyanate dihexyl vinegar, diisocyanate U2_+ dialkyl vinegar, diisocyanate 2,2,- and 2,4, dicyclohexylmethane or diiso(tetra)fluorene-toluene vinegar: Jiajia is based on diisocyanate, Yiyiji vinegar, isocyanuric acid vinegar. Particularly preferred is isocyanuric acid (IV) having other hydrophilic groups such as, in particular, a polyepoxy group. Those skilled in the art are aware of the preparation of such isocyanuric acid vinegar. It is preferably used in the form of a solution in a polar aprotic solvent such as ethylene carbonate or propylene carbonate. Further details of preferred crosslinkers having isocyanato groups are disclosed in WO 2008/052913, page 34, line 6 to page 35, line 3. It is especially preferred to use isocyanurate based on diisocyanate 1 > 6-extended ketone (HMDI) and having other polyethylene oxide groups, which are soluble in propylene carbonate ( Containing 7% by weight of HMm of propylene carbonate). The free isocyanate content is from about 11 to 12% by weight of the solution. The crosslinking agent is preferably used in an amount of from 1 to 1% by weight based on the total amount of solids in the formulation. Isocyanurate-based crosslinkers are particularly suitable for crosslinking the above copolymers. The compound may further comprise general additives and adjuvants, uv stabilizers and colorants. Examples of such additives are mentioned on page 35, line 17 to page 37, line 5 of WO 2008/052913. In addition to purely aesthetics, colorants and pigments can be useful against, for example, birds or mammals, or camouflage insecticide nets to protect against insects. And -18- 158662.doc

S 201216858 Moreover, black provides the required shadow and reduces the harmful effects of UV light on active ingredients and textile fibers when used outdoors. The use of a wetting agent and a copper-increasing agent allows a sheet-like structure (such as a polyolefin fiber) which is only difficult to wet and thus uneven, to be uniformly coated with a treatment liquid. For this reason, a water-miscible solvent can also be used, ‘however, it is not suitable because it is harmful to the environment. Those skilled in the art are familiar with commonly used adjuvants and their concentrations. The formulation preferably includes an antioxidant, a peroxide scavenger, a uv absorber, and a light stabilizer. It is especially recommended when exposed to the uv light shoulders of the fascinating outdoors or in the greenhouse. The above additives protect the substrate fibers and active ingredients from decomposition by radiation. Suitable UV absorbers are described, for example, in w〇 〇 2/465〇3 or in arm 077101. The Uv absorbent is first used as a component for impregnation in the formulation; and the gossip is incorporated early in the fiber manufacturing process, for example, in the form of polyalkylenes and polyfluorenes, it is also advantageous to use various stability with different protective effects. a mixture of tinctures. Generally, from about 5% to about 5% by weight of the untreated web, from 0.25 to 4% of the stomach and from about 5% to about 3.5% by weight of the stabilizer. The amount of the formulation will be adjusted accordingly by those skilled in the art. In another embodiment, the impregnation is performed by mixing at least one insecticide with the polymer and extruding the polymer and the at least one insecticide to form a monofilament that is processed to form a tablet of the present invention. The structure (variant B) is carried out. In the embodiment in which the additional insecticide of the present invention is incorporated into the sheet-like structure of the fiber-formed structure, the impregnation is carried out by directly at least one of the filaments of the fiber, for example, The dimensional composition of the invention or its presence therein. Preferably, it is constructed as a network. 158662.doc -19· 201216858 Suitable polymeric materials which may be incorporated into the monofilaments of the mixtures of the invention are thermoplastic polymers which are preferably based on ethylenically unsaturated monomers, such as polyolefins, polyvinyl chlorides, polyvinyl alcohols , poly(fluorenyl) acrylate, and polyester and polycarbonate' and, if desired, a mixture of the above polymers with each other or with a thermoplastic elastomer. Particularly preferred are polyethylenes such as low density polyethylene (LDPE), such as linear low density polyethylene (LLDPE), ultra low density polyethylene (ULDPE), medium density polyethylene (MDPE) and high density polyethylene (HDPE). , a polyethylene resin (such as a copolymer of ethylene and an α-olefin having at least 3 carbon atoms), a polypropylene homopolymer, a random copolymer of propylene and an α-olefin having four or more carbon atoms, and embedded a copolymer of a segment, a copolymer of ethylene and an unsaturated carboxylic acid, such as poly(ethylene/mercapto methacrylate), poly(ethylene/vinyl acetate) or poly(ethylene/acrylic acid), and copolymers and copolymers thereof a mixture of things. Examples of thermoplastic elastomers include thermoplastic elastomers based on olefinic and stupid ethylene. Preferred are copolymers with ethylene or propylene as a major component, and block copolymers comprising polystyrene and polyisoprene and/or polybutadiene blocks and hydrogenated derivatives of such copolymers . For the manufacture of monofilaments, insecticides and polymers are soluble and kneaded. The masterbatch may also be prepared by kneading a suitable amount of the pesticide and the polymer, and then diluting the masterbatch to the desired concentration by melt-spinning another amount of the polymer. If a masterbatch process is used, the masterbatch and subsequent dilutions may also use different polymers, such as lLdpe for masterbatch and HDPE for dilution of the masterbatch. In addition to the polymer and the insecticide, the polymer composition comprises, if desired, a powdery carrier material, preferably from talc, kaolin, dry soil, fine powder 158662.doc

S 201216858 si〇2, a group of carbon and dextrin. If present, the powdery carrier material is preferably present in an amount of from 0.01 to 10% by weight. The powdery carrier material may be melt-kneaded with the mixture of the pesticide and the polymer, but it is preferred to first mix the mixture of the pesticide with the powdery substance, and then mix the mixture with the polymer, for example, melt-kneaded. It is especially preferred to use a mixture of a powdered substance and a mixture of insecticides to prepare a masterbatch. In addition to the polymer, the insecticide, and the powdery carrier as desired, the polymer composition includes conventional additives such as pigments, antioxidants, lubricants and the like, as required for the thermoplastic molding composition. For the manufacture of filaments according to such embodiments, the mixture is extruded and the extrudate is processed to produce granules by melt-kneading, preferably at elevated temperatures, for example, by preparing a mixture of a polymer, an insecticide and, if desired, other additives. . The stretching of the particles can be carried out by melt spinning or extrusion to obtain a wire which can be woven, for example, by the Raschel method. Details of the web material of this embodiment of the invention and its method of manufacture are described, for example, in WO 2008/004711. Insecticides covered include all known insecticides. Suitable insecticides are more specifically referred to as the following known active ingredients (see "The Pesticide Manual", 2003 edition, Ε·C. Tanlin): 1) Acetone cholinesterase (AChE) inhibitor uric acid Examples of esters are alanycarb, aldibarb, aldoxycarb, allyxycarb, aminocarb, bendiocarb, and refuge ( Benfuracarb), bufencarb, butacarb, butocarboxim, butoxycarboxim, 158662.doc 21 201216858 carbaryl, carbofuran, Carbosulfan, cloethocarb, dimetilan, ethiofencarb, fenobucarb, fenothiocarb, formetanate ), furathiocarb, isoprocarb, metam-sodium, methyliocarb, methomyl, metolcarb, cockroach ( Oxamyl), pirimicarb, promecarb, propoxur Oxur), thiodicarb, thiofanox, trimethacarb, XMC, xylylcarb, and triazamate. There are institutional acid esters, examples are acephate, thiol ratio, azamethiphos, azinphos (-methyl, -ethyl), ethyl bromide Bromophos-ethyl, bromfenvinfos (-methyl), butathiofos, cadusafos, carbophenothion, chlorethoxyfos , chlorfenvinphos, chlormephos, chlorpyrifos (-methyl/-ethyl), coumaphos, cyanofenphos, cyanamide Cyanophos, chlorfenvinphos, demeton-S-methyl, demeton-S-methylsulphon, dialifos, diazinon, line filling (dichlofenthion), dichlorvos/DDVP, bis-Tex-22-158662.doc

S 201216858 (dicrotophos), dimethoate, dimethylvinphos, dioxabenzofos, disulfoton, EPN, ethion, ethoprophos , etrimfos, famphur, fenamiphos, fenitrothion, fensulfothion, fenthion, ° flupyrazofos, Fonofos, formothion, fosmethilan, fosthiazate, heptenophos, iodofenphos, iprobenfos, Isazofos, isofenphos, isopropyl O-salicylate, isoxathion, malathion, mecarbam ,methacrifos, methamidophos, methidathion, mevinphos, monocrotophos, naled, omethoate, acetaminophen Oxydemetonmethyl, (mercapto/ethyl) para (parathion(-methyl/-ethyl)), phenthoate, phorate, phosalone, phosmet, phosphamidon, phosphocarb ), phoxim, (thiol/ethyl) pirimiphos (-methyl/-ethyl), profenofos, propaphos, propetamphos, Prothiofos, prothoate, baisong 158662.doc -23- 201216858 (pyraclofos), pyridasphenion (pyridaphenthion). Pyridathion, quinalphos, sebufos, sulfotep, sulprofos, tebupirimfos, temephos , terbufos, tetrachlorvinphos, thiometon, triazophos, triclofon, and vamidothion. 2) sodium channel regulator / pressure sensitive sodium channel blocker pyrethroids, examples are anarina (arrinathrin), arylene (d-cis-trans, d-trans) 5β-race Allethrin (d-cis-trans, d-trans)s beta-cyfluthrin, bifenthrin, bioallethrin, fenthrin-S-cyclopentyl-isomer, organism Bioethanomethrin, biopermethrin, bioresmethrin, chlovaporthrin, cis_cypermethrin, cis-benzol Cis-resmethrin, cis-permethrin, clocythrin, cycloprothrin, cyfluthrin, cyhalothrin , cypermethrin (alpha-, beta-, theta-, zeta), cyphenothrin, deltamethrin, alkyne Ementhrin, (1R-isomer), esfenvaierate, etofenprox, fenfluthrin, fen Ning (fenpropathrin), than cyanide gas ° daisy painting aims (fenpyrithrin), of Fen Lee • 24- 158662.doc

S 201216858 (fenvalerate), flubcycyrinate, flucythrinate, flufenprox, flumethrin 'fluvalinate', benzyl snail Fubfenprox), gamma-cyhalothrin, imiprothrin, kadethrin, xeronine, metofluthrin, hundred Permethrin (cis-, trans-), phenothrin (IR-trans isomer), prallethrin, provirthrin, prolu Protrifenbute, pyresmethrin, benzyl-cypermethrin, RU 15525, silafluofen, tau-fluvalinate, sulphate Tefluthrin, terallethrin, tetramethrin (-IR-isomer), tralmethrin, transHuthrin, ZXI 8901 , and pyrethrum (pyrethrum); DDT ° dioxin, an example of indoxacarb 〇 3) acetylcholine receptor agonist / antagonist ' Smoke test class instance is an alkylene off culture (, acetamiprid), clothianidin (clothianidin), ° husband Clothianidin (dinotefuran), benefits of the amine (of imidacloprid), dilute 0 chlorfluazuron amine (nitenpyram), nitric acid gland. Nithiazine, thiacloprid, thiamethoxam, smog, bensultap, and cartap ° 4) acetylcholine receptor modulator 158662.doc -25- 201216858 Spinosynes, an example of spinosad. 5) GABA-regulated chloride channel antagonist organochlorine, such as camphechlor, chlordane, endosulfan, γ-HCH, HCH, heptachlor, and lingdan ( Lindane), and methoxychlor, fiproles 'examples are acetopr〇ie, ethiprole 'fipronii', pyrafluprole , Pyriprole, and vaniliprole. 6) Chloride channel activators mectines, examples are avermectin, emamectin, indomethacin, ivermectin, and silk Worm (milbemcycin). 7) Juvenile hormone analogs, examples are diofenolan, epofenonane, fenoxycarb, hydroprene, kinoprene, rarity cool (methoprene), pyriproxifen, and triprene ° It is preferred to use insecticides which are active against tree worms, more specifically aphids which are propagated in trees and bark. These include, for example, insecticides such as pyrethroids (e.g., 'apha-cypermethrin'). Fipronil 'amidrazone' and chlorfenapyr are also suitable. The best insecticides are α-saiding, chlorhexidine, permethrin, flubens 158662.doc

S •26- 201216858 The best insecticides are nitrile, amidoxime and kefanpa. Especially good a pyrethroid. A particularly preferred insecticide is in the embodiment, wherein the insecticide is a KFPA agent (X-Sai Ning, Ding Ning, and α-赛宁宁) in another specific preferred

Two or three insecticides

Fungicides, herbicides and/or growth regulators.

The amount may be from 0.1 to 1000 mg/m2, preferably from 70 to 130 mg/m2, more preferably from 9 to ii. . The amount of cytosine is usually from 5 〇 to 15 〇 mg/m 2 , preferably from 川 to 丨 mg mg/m 2 , more preferably from 90 to 11 〇 mg/m 2 . The amount of chlorpyrifos is usually from ls to 45, preferably from 20 to 40 mg/m2, more preferably from 25 to 35 mg/m2. The amount of permethrin is usually from 50 to 750 mg/m2', preferably from 75 to 650 mg/m2, more preferably from 100 to 55 mg/m. The amount of Xeronine is usually 5 to 3 mg/m2, preferably 7.5 to 25 mg/m, more preferably 1 to 2 mg/m2. The Rukofan faction is associated with pyrethroids and can be adjusted by those skilled in the art. The mg/m. The amount of the gram is usually in the form of a mixture of 5 ι to ι 5 ’. The gram is: the pyrethroid ratio is usually 0.06-30:1 ', preferably 〇.l-i〇:i, more preferably. The particle size of the insecticide in the aqueous formulation is usually 50 nm to 20 μm, preferably 50 nm to 8 μm, preferably 5 〇 ηιη to 4 μιη 'more specifically 50 nm to 500, except for the insecticide, the sheet material can be further Includes at least one insect repellent. Suitable insect repellents are, for example, N,N-diethyl-m-toluidine (DEEt), 15S662.doc • 27-201216858 N,N-diethylphenylacetamide (DEPA), 1-(3 -cyclohex-1-yl-carbonyl)-2-mercaptopiperine, (2-hydroxymethyl-cyclohexyl)acetic acid lactone, 2-ethyl-1,3-hexanediol, insecticide (indalon) ), methyl neodecylamine (MNDA), {+/-)-3-allyl-2-indolyl-4-oxocyclopentan-2-(+)-alkenyl (+)-trans Chrysanthemum (esbiothrin), limonene, eugenol, (+) oil eucamal-1-ol, (-)-1 -Extraction of oil - eucamalol, Eucalyptus maculata, Vitex rotundifolia, Cymbopogan martinii, Cymbopogan citratus, Cymopogan nartdus Ethyl butyl acetaminopropionate or icaridin (2-(2-hydroxyethyl)-1-mercaptopropyl ester of 1-piperidinecarboxylate). For example, insect repellents and other insecticides can be applied to the sheet structure in advance, such as by spraying a textile material (using Fendona® from BASF SE, for example, a spray comprising alpha-saidingin). However, it is also possible to apply these components only in situ (for example, Fendona® self-impregnation using BASF SE, for impregnating a net made of textile fibers, including a-saidnin); or using Bayer Crop Science Κ-0 ΤΑΒ®1-2-3, used to impregnate textile fabrics including chlorpyrifos). Sheet-like structures impregnated with insecticides, especially textile webs, are commercially available. Examples are Interceptor® from B ASF SE (DryNet® impregnated with α-赛宁宁), DuraNet® from Clarke Moquito Control Products Inc. (impregnated with α-赛宁宁 polyethylene mesh), from Dawa Plus ® of Tanna Netting Co. Ltd (Netet) of BestNet Europe Ltd., NetProtect® from Bestnet Europe Ltd (Iridian with Polychlorinated Poly--28-158662.doc s 201216858) ) 'Iconet® from Syngenta AG (impregnated with Seronine), Olyset® from Sumitomo Chemical (polyethylene mesh impregnated with permethyst) and Lifenet9 from Bayer Crop Science AG (Immerse the propylene network of the first annihilation). The term "pest" according to the invention includes insects in the true sense, and destructive arachnids, especially as a vector for the spread of disease. Examples of pests are from Diptera, Siphonaptera, Blattaria, Blattodea, Dermaptera, Hemiptera, Hymenoptera ( Hymenoptera), Orthoptera, Isoptera, Thysanura, Phthiaraptera, Araneida, Lepidoptera, Coleoptera, and Acarina and insects from the genus Chilopoda and Diplopoda. Preferred are pests from Diptera, Hemiptera, Hymenoptera, Odonata, Lepidoptera, Coleoptera, and the eye. It is especially a pest from Lepidoptera and Coleoptera. Examples of pests are as follows: Lepidoptera, such as Agrotis ypsilon, (Agrotis segetum), Alabama argillacea, Anticarsia gemmatalis, Argyresthia conjugella, Autographa gamma, Bupalus piniarius, Cacoecia murinana, Cameraria ohridella, Capua reticulana, Cheimatobia brumata, Chorstone 158662.doc -29- 201216858 fumiferana, Choristoneura occidentals, Ciiphis unipuncta, Cydia pomonella, Dendrolimus pini, Cucumber wilderness Diaphania nitidalis, Diatraea grandiosella, Earias insulana, Elasmopalpus lignosellus, Estigmene acrea, Eupoecilia ambiguella, Buli moth Evetria bouliana), Feltia subterranea, Galleria mellonella, Li Grapholitha funebrana, Grapholitha molesta, Heliothis armigera, Heliothis virescens, Heliothis zea, Hellula undalis, Hibernia defoliaria , Hyphantria cunea, Hyponomeuta malinellus, Keiferia lycopersicella, Lambdina fiscellaria, Laphygma exigua, and coffee leaf miner (Leucoptera coffeella) ), Leucoptera scitella, Lithocolletis blancardella, Lobesia botrana, Loxostege sticticalis, Lymantria dispar, mold moth ( Lymantria monacha), Lyonetia clerkella, Malacosoma neustria, Mamestra brassicae, Orgyia pseudotsugata, Ostrinia nubilalis, Panolia Flamma), red worm (Pectinophora gossypiella), night worm (Peridroma saucia), Butterfly (Phalera • 30-158662.doc s 201216858 bucephala), Phthorimaea operculella, Phylcrostis citrella, Pieris brassicae, Platyphyllus Scabra), Plutella xylostella, Pseudoplusia includens, Rhyacionia frustrana, Scrobipalpula absoluta, Sitotroga cerealella, Sparganothis pilleriana, Autumn, worm (Spodoptera frugiperda) 'Spodoptera littoralis, Spodoptera litura, Thaumatopoea pityocampa, Thaumatopoea processionea, Green oak moth (Tortrix viridana) ), Trichoplusia ni, and Zeiraphera canadensis; beetles (Lepidoptera), such as Agrilus sinuatus, Agrilus viridis, narrow Gent ( Agrilus bigutattus), Agrilus planipennis, Agriotes l Ineatus), Agriotes obscurus, Amphimallus solstitialis, Anisandrus dispar, Anoplophora glabripennis, Anoplophora chinensis, Anoplopophora sp. .), cotton boll weevil (Anthonomus grandis), apple flower (Anthonomus pomorum), European insect (Aphthona euphoridae), Athous haemorrhoidalis, Atomaria linearis, vertical pit cutting Blastophagus piniperda, Blitophaga undata, Bruchus rufimanus, Beans 158662.doc -31 - 201216858 (Bruchus pisorum), lentils (Bruchus lends), Pear tusks (Byctiscus betulae) ), Cassada nebulosa, Cerotoma trifurcata, Cetonia aurata, Ceuthorrhynchus assimilis, Ceuthorrhynchus napi, Chaetocnema tibialis, Tobacco Needles Conoderus vespertinus, Crioceris asparagi, Ctenicera ssp. Diabrotica longicornis, Diabrotica semipunctata, Diabrotica 12-punctata Diabrotica speciosa, Diabrotica virgifera, Epilachna varivestis, Tobacco flea (Epitrix hirtipennis), Eutinobothrus brasiliensis, Hylobius abietis, Hypera brunneipennis, Hypera postica, Ips typographus, peas Lem bilineata, Lema melanopus, Leptinotarsa decemlineata, Limonius californicus, Lissorhoptrus oryzophilus, Melanotus communis , pollen mites (Meligethes .aeneus), large chestnut golden tortoise (Melolontha hippocastani), large chestnut golden tortoise (Melolontha melolontha), rice negative worm (Oulema oryzae), big cucurbit (Ortiorrhynchus sulcatus), elliptic worm (Otiorrhynchus ovatus) , horseradish leafhopper (Phaedon cochleariae), pear leaf bud Phyllobius pyri, Phyllotreta chrysocephala, Phyllophaga sp., Beans 158662.doc -32-s 201216858 (Phyllopertha horticola), Phyllotreta nemorum, yellow Phyllotreta striolata, Popillia japonica, Sitona lineatus and Sitophilus granaria; flies, mosquitoes (Diptera), such as Aedes Aegypti), Aedes albopictus, Aedes vexans, Anastrepha ludens, Anopheles maculipennis, Anopheles crucians, Anopheles sinensis Anopheles albimanus), Anopheles gambiae, Anopheles freeborni, Anopheles Ieucosphyrus, Anopheles minimus, Anopheles quadrimaculatus, red head Calliphora vicina, Ceratitis capitata, Chrysomya bezziana, Chrysomya hominivorax, Secondary spiral spot fe: (Chrysomya macellaria), Chrysops discalis, Chrysops silacea, Chrysops atlanticus, Cochliomyia hominivorax, Contarinia sorghicola , Cordylobia anthropophaga, Culicoides furens, Culex pipiens, Culex nigripalpus, Culex quinquefasciatus, Culex tarsalis, veins Culiseta inornata, Culiseta melanura, Dacus cucurbitae, Dacus oleae, Dasineura brassicae, onion seedlings (Delia) Antique), cornfield I58662.doc -33- 201216858 Delia coarctata, Delia platura, Delia radicum, Dermatobia hominis, Fannia canicularis, Geomyza Tripunctata, Gasterophilus intestinalis, Glossina morsitans, Glossina palpalis, red chest 4i (Glossina fus Cipes), Glossina tachinoides, Haematobia irritans, Haplodiplosis equestris, Hippelates spp., Hylemyia platura, Hypoderma lineata, rapids Fine samples (Leptoconops torrens), Liriomyza sativae, Liriomyza trifolii, Lucilia caprina, Lucilia cuprina, Lucilia sericata, muscle rope (Lycoria pectoralis), Mansonia titillanus, Mayetiola destructor, Musca domestica, Muscina stabulans, Oestrus ovis, Opomyza florum, Oscinella frit, Pegomya hysocyami, Phorbia antiqua, Phorbia brassicae, Phorbia coarctata, Phlebotomus argentipes, Colombia Psorophora columbiae, Psila rosae, Psorophora discolor, Prosimulium mixtum, cherry (Rhagoletis cerasi), Rhagoletis pomonella, Sarcophaga haemorrhoidalis, Sarcophaga sp., Simulium vittatum, Stomoxys 158662.doc -34- s 201216858 calcitrans ), Tabanus bovinus, Tabanus atratus, Tabanus lineola and Tabanus similis, Tipula oleracea and Tipula paludosa; Herbivore (Folding): such as Dichromothrips corbetti, Dichromothrips ssp, Frankliniella fusca, Frankliniella occidentalis, Frankliniella tritici, ciScirtothrips citri, Thrips oryzae, Thrips palmi and Thrips tabaci; termites (Isoptera), such as the yellow-necked flower (Calotermes) Flavicollis), Leucotermes flavipes, Heterotermes aureus, Reticulitermes flavipes, South Reticulitermes virginicus, Reticulitermes lucifugus, Termes natalensis, and Coptotermes formosanus; 蟑螂(蜚蠊目), such as Blattella germanica, Blattella Asahinae), Periplaneta americana, Periplaneta japonica, Periplaneta brunnea, Periplaneta fuligginosa, Periplaneta australasiae, and Blata orientalis i beetle (Hemiptera, including Homoptera), such as green crickets (Acrosternum 158662.doc -35- 201216858 hilare), Blissus leucopterus, Cyrtopeltis notatus, Dysdercus cingulatus, and mediators Dysdercus intermedius, Eurygaster integriceps, Euschistus impictiventris, Leptoglossus phyllopus, Lygus lineolaris, Lygus pratensis, rice green pupa (Nezara viridula), 蝽象 (Piesma qua Drata), Solubea insularis, Thyanta perditor, Acyrthosiphon onobrychis, Adelges laricis, Aphidula nasturtii, Aphis fabae, strawberry root Aphis forbesi, Aphis pomi, Aphis gossypii, Aphis grossulariae, Aphis schneideri, Aphis spiraecola, Aphis sambuci ), Acyrthosiphon pisum, Aulacorthum solani, Bemisia argentifolii, Brachycaudus cardui, Brachycaudus helichrysi, Taocai (Brachycaudus persicae), Brachycaudus prunicola, Brevicoryne brassicae, Capitophorus horni, Cerosipha gossypii, Chaetosiphon fragaefolii , Cryptomyzus ribis, Dreyfusia nordmannianae, Dreyfusia piceae, spokes Dysaphis radicola, Dysaulacorthum pseudosolani, Dysaphis plantaginea, Dysaphis pyri, Vicia faba 158662.doc . 35 _ s 201216858 (Empoasca fabae), Hyalopterus pruni, Hyperomyzus lactucae, Macrosiphum avenae, Macrosiphum euphorbiae, Macrosiphon rosae, Megoura viciae , Melanaphis pyrarius, Metopolophium dirhodum, Myzus persicae, Myzus ascalonicus, Myzus cerasi, Peach leaf ( Myzus varians), Nasonovia ribis-nigri, Nilaparvata lugens, Pemphigus bursarius, Perkinsiella saccharicida, Phorodonhumuli ), apple psyllamali, Psylla piri, Rhopalomyzus ascalonicus 'Rhopalosiphum maidis', Heguyi Guancai Rhopalosiphum padi), Rhopalosiphum insertum, Sappaphis mala, Sappaphis mali, Schizaphis graminum, Schizoneura lanuginosa, Mai Chang Guancai Sitobion avenae), Trialeurodes vaporariorum, Toxoptera aurantiiand, Viteus vitifolii, Cimex lectularius, Cimex hemipterus, Reduvius senilis , Triatoma spp. and Arilus critatus. Ants, bees, wasps, plant wasps (Hymenoptera), such as Athalia rosae, Atta cephalotes, Atta capiguara, Atta cephalotes, charcoal grilled Ants (Atta 158662.doc -37- 201216858 laevigata), Atta robusta, Atta sexdens, Atta texana, Crematogaster spp. ), Hoplocampa minuta, Hoplocampa testudinea, Monomorium pharaonis, Solenopsis geminata, Solenopsis invicta, Solenopsis richteri, United States Fire ant (Solenopsis xyloni), red ant (Pogonomyrmex barbatus) 'Pogonomyrmex californicus, Pheidole megacephala, Dasymutilla occidentalis, Bombus spp., Southern bee After (Vespula squamosa), Vespa (Paravespula vulgaris), Paraspula pennsylvanica, Paraspula germanica, North American white-faced bee (Dolichovespula maculata), Vespa crabro, Polistes rubiginosa, Camponotus floridanus and Linepithema humile, moth and striata (Orthoptera), such as Acheta domestica, Gryllotalpa gryllotalpa, Locusta migratoria, Melanoplus bivittatus, Melanoplus femurrubrum, Melanoplus mexicanus, Migration of Melanoplus sanguinipes, Melanoplus spretus, Nomadacris septemfasciata, Schistocerca americana, Schistocerca gregaria, Moroccan Python Maroccanus), greenhouse stove horse 158662.doc -38 -

S 201216858 (Tachycines asynamorus), Senegal Oedaleus senegalensis, Zonozerus variegatus, Hieroglyphus daganensis, Kraussaria angulifera, Italy Calliptamus italicus, Cho: rtoicetes termiriifera and Locustana pardalina, arachnids, such as arachnids, and examples of their genus Argaidae ), Ixodidae and Sarcopteridae, such as Amblyomma americanum, Amblyomma variegatum, Ambryomma maculatum, Argas persicus Boophilus annulatus, Boophilus decoloratus, Boophilus microplus, Dermacentor silvarum, Dermacentor andersoni, Dermacentor Variabilis), long glass eye (Hyalomma truncatum), Ixodes ricinus, Ixodes rubicundus, shoulder Ixodes sc?apularis, Ixodes holocyclus, Ixodes pacificus, Ornithodorus moubata, Ornithodorus hermsi, Ornithodorus Turicata), Ornithonyssus bacoti, Otobius megnini, Dermanyssus gallinae, Psoroptes ovis, Rhipicephalus sanguineus, appendix Rhipicephalus appendiculatus, Rhipicephalus evertsi, Sarcoptes scabiei, and the monument (Eriophyidae 158662.doc -39- 201216858 spp.), such as the frequency. Schlechtendali), Phyllocoptrata oleivora and Eriophyes sheldoni; Tarsonemidae spp. such as Phytonemus pallidus and Polyphagotarsonemus latus; fine Tenuipalidae spp. such as Brevipalpus phoenicis; Tetranychidae spp. such as Tetranychus cinnabarinu s), Tetranychus kanzawai, Tetranychus pacificus, Tetranychus telarius and Tetranychus urticae, Panonychus ulmi, citrus Panonychus citri and Oligonychus pratensis: Araneida, such as Latrodectus mactans and Loxosceles reclusa, fleas, such as Juveniles Ctenocephalides felis, Ctenocephalides canis, Xenopsylla cheopis, Pulex irritans, Tunga penetrans, and Nosopsyllus fasciatus, aphids, Domestic fish (Iguana), such as Lepisma saccharina and Thermobia domestica, Coleoptera (Lipper), such as Scutigera coleoptrata, Polypod, Such as the millipede (Narceus spp.), 蠼嫂 (Geoptera), such as Forficula auricularia, worm (Emu), such as Pediculus humanus capitis , iD (Pediculus humanus corporis), Yinyi (Pthirus pubis), cattle 158662.doc -40- s 201216858 Wind (Haematopinus eurysternus), Haematopinus suis, Bovine hurricane (Linognathus vituli), Boomera (Bovicola Bovis), Menopon gallinae, Menacantus stramineus and Solenopotes capillatus, nematodes such as Heterodera glycines, H. avenae, and beet bags H. schachtii, H. trifolii, H. gottingiana, H. cajani, H. zeae, potato Globodera rostochiensis, G. pallida, G. tabacum., Meloidogyne arenaria, Southern root knot nematode (Μ· incognita), Javan root knot nematode (Μ·javanica), Northern root-knot nematode (Μ·hapla), M. chitwoodi, Ditylenchus destructor, stolon line (D. dipsaci), D. angustus, Anguina tritici, A. agrostis, Afrina/Anguina wevelli, and short-stem nematodes Pratylenchus penetrans), P. brachyurus, p. C0ffeae, P. zeae, female short-stem nematode (p. g00deyi), Soxhlet short body Nematodes (P. thornei), p. vulnus, Radopholus similis, Hirschmanniella oryzae, H. mucronata, thorn cyst Nematodes (Η, spinicauda), Crownworm (Hoplolaimus columbus), H. seinhorsti, 荔. indicus, kidney line 158662.doc •41 · 201216858 rot (Rotylenchulus reniformis), Tylenchulus semipenetrans, Helicopterus multicinctus, H. mucronatus, double uterine helix (Η· dihystera), pseudo strong spiral nematode (H. pseudor Obustus), Criconemella C. xenoplax axestis, C. spharocephalum ° In a preferred embodiment, the pests of Lepidoptera are the species of the genus Grecillariidae, especially Thaumetopoeinae, Cossinae, Zeuzerinae, Larentinae, and Ennominae. The best lepidopteran pests are oak pro ces sionary (Thaumetopoea processionea), pine processionary (Thaumetopoea pityocampa), goat moth (Cossus cossus), leopard moth (leopard moth) Zeuzera pyrina)), gypsy moth (Lymantria dispar), horse-chestnut leaf miner (Cameraria ohridella), oak leafroller (Tortrix viridana), winter moth (winter Moth (Operophtera brumata)), and mottled umber (Erannis defoliaria). In a preferred embodiment, the coleoptera pests are of the order Curculionidae, Bupraestoidae, Cerambycidae, Scarabaeidae and Hemiptera, in particular Scolytinae, Molytinae, Rhynchophorinae, Changji Dingya

158662.doc -42- S 201216858 Branch (Agrilinae); Buprestinae, Lamininae, Melonthinae and Tinginae. The superior coleopteran pest is the European spruce bark beetle (Ips typographus), the oak bark beetle (Scolytus intricatus), and the large elm bark beetle (Scolytus scolytus). ), Six-spined spruce bark beetle (Pityogenes chalcographus), great spruce bark beetle (Dendroctonus micans), mountain pine beetle (Dendroctonus ponderosae) , large brown pine beetle (Hylobius abietis), green weevil (Phyllobius spec), red palm weevil (Rhynchophorus ferrugineus), beech giant locust ( Beech splendor beetle (Agrilus viridis), jewel beetles (Agrilus spec·), o_ak jewel beetIe (Coraebus undatus), flat-faced longhorns (Saperda spec .)), Asian longhorn beetle (Anoplophora glabripennis), citrus longhorn beetle (Anopolophora chinensis) )), great capricorn beetle (Cerambyx cerdo), pine sawyer (monochamus galloprovincialis), sawyer beetles (mono chamus spec.), big chestnut golden tortoise ( Forest cockchafer (Melolontha hippocastani)), common cockchafer (Melolontha melolontha), sycamore 158662.doc -43- 201216858 sycamore lace bUg (C〇rythucha ciHata). In a particularly preferred embodiment, the method of the present invention is suitable for protecting living cork from pests (such as cork by covering the trunk and/or branch surface of the cork by using a sheet structure impregnated with an insecticide. The dangerous gold of the bark beetle. The present invention is directed to a living plant in which the surface of the trunk, the stem, the branches, the roots and/or the roots is covered with a tablet-like structure impregnated with an insecticide. The present invention is also a rectangular sheet-like structure (specifically, a textile web) which is impregnated with an insecticide and which comprises a fixing member which is allowed to be permanently held after the tubular coating of the trunk of the plant, the dummy stem or the surface of the branch. The fixing member includes, for example, an adhesive material, a belt, a rope or a hook and loop fastener, and preferably a fishing ring fixing member. When the sheet-like structure is tubular, the members are connected to adjacent corners. The rectangular sheet-like structure is substantially rectangular in shape, such as a square, or a trapezoid. Generally, at least two opposing sides are substantially parallel. Each side has i coffee to l〇.〇m, preferably 5 (^ to 5.0〇1, and especially 1〇 (^ to 2 5 claw length. In a preferred embodiment (referred to as "backbone height network") ), the flaky structure beans have a height of 30 cm to 5.0 m, preferably 5 〇 to 3 〇 m, and more preferably ribs to 2 2 m. The height depends on the height of the trunk covered by the sheet structure to be used. The length is generally such that the sheet structure can cover the trunk, the stem or the length of the branches = length. Usually 10 cm to 5.0 m, preferably 3 〇 cmi3 〇 m, and more preferably 50 cm to 1 _ 5 m » in another In the preferred embodiment ("sleeve mesh"), the sheet-like structure has a diameter of 5 cm to 50 cm, preferably 2 cm to 30 cm, and more preferably 4. The height of the crucible to the height of the crucible is generally a sheet-like shape. The structure can cover the length of the trunk, dry stem or branch length I58662.doc • 44 - 201216858. Usually 10 cm〇m, preferably 30 cm to 3.0 m, and more preferably 5〇cm to 1.5 m. The invention further provides a tablet-like structure impregnated with an insecticide (especially a woven fibrous web) in the form of a perforated sheet having a continuous interruption between the outer edge and the inner edge. The continuous interruption can take substantially radial The shape of the aperture. The shape of the apertured sheet may be circular, elliptical, square, rectangular or similar to the shape of the aperture. The shape of the aperture with the apertured piece may be circular, elliptical, square, rectangular or the like. One of the other shapes is similar. The hole may also take the form of at least one slit (for example, in a preferred embodiment, the diameter of the hole of the sheet is usually 〇.1, a cross-shaped slit). The perforated sheet and the hole are basically It is round. It has a hole of cm to 2 m. It is preferably 1〇cm to 1.0m and especially 30cm to 80cm. The diameter of 1.0m to 20m is usually 1〇cm to 30m, especially 2.0. m to 1〇_〇m. The diameter of the hole with the apertured sheet is of course smaller than the diameter of the apertured sheet. In another preferred embodiment, the apertured sheet is substantially rectangular. Each side has a diameter of 50 cm to 30 m.佳1〇瓜至2〇m, and especially 2 〇〇 length. In order to place the perforated sheet against the trunk or the dummy dry, the edge of the hole may be provided with an elastic material containing a hook and loop fastener as needed. It is fixed in the soil of the outer edge region by a common tent pile or the like. The present invention provides the present invention. The use of a sheet-like structure for protecting living plants from pests. The present invention provides a number of advantages: individual plants or specific parts of plants can be protected from insects in a highly targeted and precise manner. 158662.doc -45 - 201216858 Activity hazard. No environmental pollution, as in the case of spraying applications. Therefore, the environment is protected and can be applied at present, even for the purpose of protecting water or protecting specific organisms, the application of pesticides has been restricted to date. . Plants are effectively protected from infiltration into bark or trees by living and/or breeding insects or parts of edible plants. Pests are usually killed when in contact with the net. This method is less laborious and is less expensive in the long run than conventional insecticide spray methods because it lasts for a long time. The sheet-like structure in the form of textile fibers is air permeable and therefore harmless to living plants. EXAMPLES Example 1 - Trunk Covered with High Nets Example 1 was used from a BASF SEi Intercept 〇r8 mesh and impregnated with sub-nanning (polyacetate mesh 75 denier, 155 mesh). The rectangular net length is 18〇^ and the height is 160 cm. » The net is wrapped around the trunk (about 3 cm in diameter) and covers the surface of the trunk 180 cm above the ground. The net was secured to the trunk by standard commercial tape that was wrapped around the trunk and covered at approximately 1 〇 em & 18 cm from the ground. Alternatively, the tape can be replaced with a rope, rubber band or belt (elastic or inelastic) having a hook and loop fastener. For example, you can also use the DuraNet® ^ Dawa Plus ^ NetProtect® . Iconet® . 〇Iyset@ or Lifenet® to replace the Interceptor® network. Example 2 - Trunk Covered with Sleeve Nets Example 2 uses a net as in the example. The rectangular net is 2〇 cm long and ι〇 cm. Wrap the net around the trunk (about 3 cm in diameter) and cover the trunk surface 1 〇 cm wide at 2 〇 em (6 〇 or 160 cm) from the ground. The net is secured to the trunk by standard commercial tape. Alternatively, use a rope with a hook and loop fastener, 158662.doc • 46· 201216858 rubber band or belt (elastic or inelastic) replacement end. tape. In addition, the sleeve network can be bundled. Example 3. Trunk covered with a high net including a hook and loop fastener

Hook and loop fasteners. Make sure it is securely attached to the trunk. In the operation example 3, the side of the net of the example has a width of the hook and loop fastener 2 and the example 4 is covered with a circular net covering the root zone. Only example 4 uses a jntereept〇r8 net in the form of a perforated sheet, which has The outer diameter of 5 · 0 m and the diameter of the hole of 1 〇 cm and a radial cut between the inner and outer edges. The perforated sheet is placed around the roots of the soil (about 15 cm in diameter). The trunk is located in the hole area. In the outer edge region of the perforated sheet, about 10 tent piles were inserted through the net into the soil for a fixed purpose. Interceptor® nets can also be replaced with, for example, DuraNet®, Dawa Plus, NetProtect®, Iconet®, Olyset® or Lifenet®. 158662.doc 47·

Claims (1)

201216858 VII. Scope of application for patents: 1. 2. 3. 4. 5. 6. 7. A sheet-like structure by using a pesticide-impregnated tablet to cover the stems, dried stems, branches, and roots The surface of the group and the 7 or root domain to protect: the main method of pest damage. The method of claim 1, wherein the sheet structure is a textile material. The method of claim 1 or 2, wherein the pests are lepidoptera and lepidoptera such that the plants are trees. And the method of any one of claims 1 to 3, wherein the method is a method tree according to any one of claims 1 to 4. The method of any one of the preceding claims, wherein the insecticide comprises pyrethroid, fi nil, /amidrazone, and/or kefir (chl 〇rfenapyr). A method of any one of items 1 to 6, wherein the sheet structure covers the surface for at least one month. 8. A living plant that has been immersed in a tablet structure on its surface, dried stems, branches, roots and/or roots by insecticide. 9. A rectangular sheet-like structure impregnated with an insecticide and comprising a fixing member that can be permanently held after tubular covering the trunk, false stem or branch surface of the plant. 10. A sheet-like structure as in the case of the kiss item 9. The fixing member includes a hook and loop fastener that connects adjacent corners when the sheet-like structure is in an official shape. 11. A sheet-like structure in which 35 insecticidal I is impregnated, in the form of a perforated sheet having a continuous interruption between the outer edge and the inner edge. 12. The sheet structure of the item 11 of the month, wherein the aperture of the apertured piece is from 0. 1 cm to 2 158662.doc 201216858 m, and the diameter of the apertured piece is from 10 cm to 30 m. 13. Use of a sheet-like structure according to any one of claims 9 to 12 for protecting living plants from pests. 158662.doc S 201216858 IV. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbolic symbol of the representative figure is simple: 5. If there is a chemical formula in this case, please reveal the characteristics that can best display the invention. Chemical formula: (none) 158662.doc