TW201200160A - Cosmetic for makeup - Google Patents

Abstract

The object of the present invention is to provide a cosmetic for makeup, more specifically, a cosmetic having good coloring, excellent maintinence, easy to pick up, and without skewness even thought it feels flexible. Provided is a cosmetic for makeup, comprising: (A) a silicone gel containing a cross-linking type polyether modified silicone and a silicone oil, (B) an oil, and (C) a powder. Preferably, the above silicone gel uses a gel containing 20 to 30% by mass of a cross-linking type polyether modified silicone and 70 to 80% by mass of silicone oil.

Description

201200160 VI. Description of the invention: [Technical field to which the invention pertains] The color of polyoxymethylene is well absorbed and held. The present invention relates to a blended polyether makeup cosmetic. In detail, it is a powder makeup cosmetic that is excellent in color development and excellent in makeup. [Prior Art] The eye shadow is applied to the eyelids and the end of the eye to form a shadow, and the body feels to enhance the beauty of the eye. (3) From the appearance to the colorful, in order to show the colorful color, in addition to: in the eye makeup, the other is the matching of the colored pearlescent pigments of the Chin/mica system to the gloss and texture of the cosmetics (Non-patent literatureυ Inch, with various product types (4) Green to record (including oil (4) and solid shape (including powder solid shape, oily stick shape, wrong pen shape 匕 =) only by compression molding in the balance of the capacity (four) Mainstream of powder solid axis. *', generally in eye shadow, must have (1) easy to push and feel tight, (2) coating film will not shine, (3) no color change, (4) _ No # sweat and sebum infiltrated and have good makeup, (5) good safety, etc. In addition, it is also required to impart transfer resistance without transfer and thinning, and it is not sticky and dry. Among the above-mentioned properties required for a makeup such as a two-eye shadow, such as the feeling of use or the ease of taking out the product from the container, the ease of taking out the product from the container, the degree of spread during coating, and the touch The sense of use is closely related to the rheology of the product. So try a variety of In the case of the improvement of the rheology of the makeup and the cosmetic material, for example, it is described in the patent document that the refreshing touch, the soft feeling, and the elasticity which are lacking in the conventional solid shape of the conventional powder 322748 3 201200160 are described. Cosmetics, lanthanide: partially crosslinked organic polyoxane polymerization containing (A) partially crosslinked organic polyoxonium containing long-chain alkyl groups, (B) excluding (A) above σ is a combination of (dimethicone/dimethicone/vinylmethionone crosslinked polymer), (c) polydioxygen, (D) hydrocarbon Oil and/or ester oil, and (E) powder, which is excellent in elasticity and makeup when the product is used. However, it is formulated with a cross-linked organic oxygen having a long-chain base. In the cosmetic of the alkane polymer, there is another disadvantage that the color development is weak. [Prior Art Document] [Patent Document] [Patent Document 1] Japanese Laid-Open Publication No. WO2006/120876 [Non-Patent Document] [Non-Patent Document 1 "The 2nd Edition of New Cosmetics", edited by Kazuo Kazuo, Nanshan Hall, 2001 Page 428 [Summary of the Invention] [Problems to be Solved by the Invention] An object of the present invention is to provide a makeup cosmetic which overcomes all the disadvantages of the conventional makeup cosmetics as described above, in particular, good color development and excellent makeup. In order to solve the above problems, the inventors and other intents have repeatedly reviewed 4 322748 201200160 and found that it is found that the soft and flexible touch does not cause the product to lean on one side. To solve the above problems, the present invention can be completed by blending a crosslinked polyether modified polyoxyl siloxane. That is, the present invention provides a makeup cosmetic characterized by: (A) inclusion The parent-linked polyether modified poly-oxygenated oxygen and polyoxygenated silicone gel, (B) oil, and (c) powder. [Effect of the Invention] The makeup cosmetic of the present invention can be obtained by blending a crosslinked polyether modified polyoxosulfuric acid and a polyoxygenated silicone gel. It is easy, even if it is soft and soft, it does not cause the product to lean against the side (the phenomenon that the product leans against one side of the container), and the color is excellent. Further, in the case of a hard product prepared with a small amount of the above polyoxyl siloxane, an unexpected effect which is particularly noticeable in pearlescence can be obtained. [Embodiment] [Formation for carrying out the invention] Hereinafter, the makeup cosmetic of the present invention will be described in detail. The make-up cosmetic of the present invention contains, as an essential component, a polyoxymethylene gel (ingredient A) comprising a crosslinked polyfluorene-modified polyfluorene oxide and a polyoxygenated oil. The present invention is not limited to the cross-linking type (four) modified poly-coin and the jujube-enriched gel. For example, it is preferable to mix a 2Q to 3Q f ^ poly-stone oxygen gel. In the case of such a condensed temperament, it has been widely used in the emulsification system. It is not limited to the use of 322748 5 201200160 as long as it is used in oily cosmetics. The coffee can be exemplified by the following: (poly = 曱, 矽 烧 / PEG-10 / 15) cross-linked polymer, etc., i n * " ch3 H3C ••SI·

CHS •Si~I CH, 〇

•81-O

Ch3 I —.......SI ' CH<I q CHS (CHJ,

<〇U !〇)n (I) CHa

HjC —-81—~_

I

CHS

<ch2)sm One, one 〇·mmmmm _s l·- "〇_ -C«3 . P -k J CH3 ! •SI——CH3 constitutes the suspicion: :=°, Q is 1 to 250 The integer can be used by the user, and the oxygen oil of the rubber material is as long as the previous cosmetics, such as the kiwi oxygen burning (for example: dimethyl has no special ship,: the key-like group gathers the stone and burns, etc. Appearance, twenty-methyl ring five oxygen / stone burning (for example: octamethyl ring four stone oxime oxygen burning (a H dimethyl ring six money); volatile poly T, L5), etc. - . Methyl decane (for example, manufactured by Shin-Etsu Chemical Co., Ltd.), which is a finely-prepared polyglycolic acid which is commercially available as KSG210 (available from 20 to 3 〇 牛 仏 仏 化学 化学) The clathrate is crosslinked with 7 〇 to 8 〇  methyl methoxy oxane / (PEG-1 〇 / 15)) (a gel containing 15 to 25 dandan 0% by weight of polydimethyl siloxane) ), KSG24 〇 polymer and 75 $ δ Γ % of poly dimethyl ketone / (PEG_1G / 15)) cross-linked to 85 mass% of the ring five stone oxime oxygen gel) and so on. 322748 6 201200160 The blending amount of the polyoxyl siloxane in the make-up cosmetic of the present invention is preferably set to 5 to 40% by mass. The blending amount varies depending on the elasticity (soft or hard) of the desired product. For example, the hardness measured by a physical property measuring instrument having a thickness of 1 〇〇 to 9 ( (2 ι μ Φ, 1.5 mm needle, 2 cm/min, room temperature) In the case of a hard cosmetic, the amount of the polyoxymethylene gel is preferably 5 to 2% by mass. On the other hand, for example, when a soft cosmetic having a hardness of 2 ι to 2 物 (2 π ιηφ, 1.5 _, 2 cin / min, room temperature) is prepared, the amount of the polyoxyl gel is adjusted. It is preferably set to 2 〇 to 4 〇 mass%. The makeup cosmetic of the present invention contains, in addition to the above polyoxyl gel (component A), an oil component (ingredient B) and a powder (ingredient c) as essential components. The oil component (ingredient B) can be selected from the group consisting of polyoxyphthalic acid or vinegar oil having a low viscosity (preferably 50 c or less) used in conventional cosmetics and the like, and is not particularly limited. The polysulfuric acid oil may be the same as or different from the polyoxime oil constituting the above polysulfide gel (A < points). When a specific example is given, for example, a direct polymerization dimethyl ketone with a low degree of polymerization (poly fluorene), a methyl phenyl polyoxo, a fluorenyl 11 oxy group; a methylphenyl group; 7 Oxygen-fired copolymer, and a ring-shaped octadecyl ring of four money, ten decyl ring five money. These may be blended in one or two or more types. Further, the polyoxygenated oil may be a commercially available product, and preferred examples thereof include: silicone KF-96 (6CS), silicone KF-96 (IOCS), silicone KF_96 (; 2 () CS), silicone KF_995, silicone KF -56 and so on. The vinegar oil can be appropriately selected among users of conventional cosmetics and the like, and examples thereof include diisostearyl malate, cetyl ethylhexanoate, and trinium 2-322748 7 201200160 ethylhexanoic acid glycerin s Purpose. Among them, especially when it is made into a hard cosmetic, it is made by blending malic acid diisostearyl s, which gives the eye examination a pearly luster and further enhances the sparkle of pearlescence. In addition, when a soft cosmetic is prepared, one or two or more selected from the group consisting of polysulfuric acid are blended. The blending amount of the oil component U in the (4) cosmetic of the present invention is B! Up to 60% by mass, preferably 2 to 3G mass%, and 2 to 15 masses, if the blending amount is less than i. "The ductility during coating is deteriorated. If it exceeds the mass%, it may easily occur during handling. One side of the powder 0: component) includes a body pigment, a colorant, a pearlescent agent, and a conventional makeup cosmetic. $ ^ Examples of constitutional pigments can be exemplified by: pulverized minerals such as mica 1 mica, talc, and soil; phthalic anhydride, zinc oxyacid, fluorine-containing phlogopite, synthetic talc, sulfur f-oxygen, hard fat, oxygen Brain, carbon _ and so on. Examples of the m-oxygenating agent (coloring pigment) include, for example, iron oxyhydroxide black, ultramarine blue, titanium oxide, zinc oxide, and bismuth iron-, and representative examples of the pearlizing agent include, for example, a dioxide, iron oxide. Coated Titanium Mica, Carmine Red Coated Titanium Mica (Titanium Cloud Luss Blue Coated Titanium Mica, Oxidation_Lipid^^ Carmine Red/Platformed Titanium Mica, Iron Oxide/Prussian Blue Treatment Qin 4T Prussian Blue Mica, Oxidation Chin black treatment of titanium mica, C _ ^ = chemical treatment of tanned titanium coated mica, yttrium oxide coated oxygenated M powder, dioxic colored oxide coated mica, titanium oxide coated & talc, β mother , titanium oxide coating 322748 8 201200160 cerium oxide, titanium oxide coated alumina, titanium oxide coated glass powder, polyethylene terephthalate / polydecyl methacrylate laminated film powder, bismuth oxychloride The fish powder of the present invention has a powder blending amount of 5 to 80% by mass, preferably 15 to 70% by mass, more preferably 20 to 70% by mass, and less than 5% by mass. There is a tendency to be biased to one side when handling, such as exceeding 80% by mass, dip In the cosmetic of the present invention, in addition to the essential components A to C described in the above, > in the range of the effect of the present invention, it is also possible to appropriately mix the makeup cosmetics. Other components used include, for example, hydrocarbon oils, surfactants, preservatives, antioxidants, humectants, pharmaceuticals, perfumes, etc. The makeup cosmetic of the present invention is not particularly limited, for example, powder components are separately used. The oil component is mixed, and the polyoxymethylene gel is dispersed in an alcohol and formed by wet molding. The makeup cosmetic of the present invention is suitable for oily makeup cosmetics by its characteristics. Among them, it is particularly suitable for making eye shadows. When used as an eye shadow, the cosmetic of the present invention is elastic, can be well taken from a container, and is excellent in color development, and has good makeup. [Examples] The following examples are further described in detail, but the present invention is not limited to the examples. In addition, the amount of blending is not specifically stated, and is intended to be of mass %. The formulation shown in Table 1 was prepared to prepare a soft cosmetic (eye shadow) containing 30% by mass of polyfluorene 9 322748 201200160 oxygen gel. [Table 1] Raw material name classification Example 1 Comparative Example 1 Comparative Example 2 Mica c 11 68 11. 68 11. 68 Kaolin c 5 5 5 Crosslinked polymethyl acrylate c 7 7 7 Iron oxide c 3 3 3 Preservative c 0· 1 0. 1 0. 1 Titanium telluride coated mica c 30 30 30 methyl phenyl polyoxy siloxane c 5. 5 5. 5 5,5 octyloxy glycerol c 0. 2 0.2 0. 2 tocopherol B 0. 02 0. 02 0. 02 polydimethyl oxime Alkane B 7. 5 7. 5 7. 5 Polyoxyl gel n A 30 _ A polyoxyl gel A — 30 A polyoxyl gel 3) A — — 30 Total 100 100 100 Holding makeup ◎ 〇〇 Dip with a finger ◎ 〇 △ color ◎ △ 〇 Δ physical property measured by the hardness (2mm Φ, 1. 5mm needle, 2cm / min, 25 ° C) 90 140 45 physical properties measured by the hardness of the instrument (3mm φ, 1mm, 2cm/miη, 25°C) 112. 5 185 92 1) KSG_2i〇 manufactured by Shin-Etsu Chemical Co., Ltd. (containing 20 to 30% (polydimethylsiloxane/PEG-10/15) )) conjugated polymer with 70 to 803⁄4 polydimethyl oxime Polyfluorene gel) 2) KSG-16C manufactured by Shin-Etsu Chemical Co., Ltd. contains 20 to 30! (polydimethylsiloxane/vinyl polymethyl oxime) cross-linked polymer with 70 to 80 % polydimethyl oxane polyoxyl gel) 3) ksG-41 manufactured by Shin-Etsu Chemical Co., Ltd. (containing 25 to 35 % (vinyl polymethyl decane / lauryl polydimethyl dream) Oxane) cross-linked polymer and poly-gel of mineral oil of 65 to 753⁄4) 10 322748 201200160 The manufacturing method uses the Emid mixer to mix the powder components (category C in the table) twice at 2000 rpm. Each time for 5 seconds, the oil component (category B in the table) was mixed twice at a speed of 2000 rpm using an EMI mixer for 10 seconds, and the mixture was mixed with a polyoxyl gel (in the table). Classification A) Mixing and dispersing with alcohol (dispersing device, at 3000 rpm for 2 minutes), filling in a container, compression molding, and drying at 60 °C. The characteristics of each of the obtained cosmetic materials were evaluated in accordance with the following evaluation methods and evaluation criteria. Also, the hardness was measured. The result of the combination is shown in Table 1 ° (Evaluation method) For the makeup, color development, and finger picking, each product reviewer (10) is required to use each cosmetic to perform a five-stage functional evaluation (points). The average value of the points is determined based on the following evaluation criteria. (Points) 5: Excellent 4: Good 3: Normal 2: Slightly worse 1: Very inferior (evaluation basis) ◎: Evaluation value (average value) 4. 0 or more 5. Below 0 points 〇: Evaluation value (average value 0点11 322748 201200160, the above value is less than 2. 0 points △: evaluation value (average value) 2. 0 or more is not up to 3. 0 points X: evaluation value (average value) 1. 0 or more is not up to 2. 0 points 11 322748 201200160 The cosmetic of the first embodiment having the crosslinked polyether modified polyoxyl siloxane was excellent in the pick-up property from the container, excellent in color development, and excellent in makeup. On the other hand, in Comparative Example 1 and Comparative Example 2 in which a crosslinked type organosiloxane polymer having a long-chain alkyl group or a crosslinked type alkyl modified polyfluorene is used in Patent Document 1, A sufficient color development is obtained to indicate that the adhesion is also poor. Further, the cosmetic of Example 1 is not hard or soft, and has a moderate elasticity and is excellent in use feeling. (Examples 2 to 6) According to the formulation shown in Table 2 below, a hard cosmetic (eye shadow) containing 15% by mass of a polyoxyl gel was prepared. 12 322748 201200160 Raw material name classification Example 2 Example 3 Example 4 Example 5 Example 6 Talc Cl 28. 56 21. 18 22. 48 26. 68 21. 68 Mica Cl 21 21 21 18 8 Crosslinked polyacrylic acid Methyl ester Cl 2 2 2 2 2 Preservative C 2 0. 1 0. 1 0. 1 0. 1 0. 1 Iron oxide C 2 0. 12 1. 5 1.2 I—Titanium oxide coated mica C2 20 31 30 20 5 Titanium oxide coated borosilicate glass C 2 5 - 10 20 Titanium oxide coated alumina C 2 — — — 20 曱 笨 基 基 矽 5. 5. 5. 5. 5. 5. 5. 5. 5. 5. 5.5 Polydimethyloxane B 2. 5 2. 5 2.5 2. 5 2. 5 Octyloxyglycerol B 0. 2 0. 2 0.2 0.2 0. 2 Tocopherol B 0. 02 0. 02 0.02 0. 02 0. 02 Polyoxyl gel n A 15 15 15 15 15 Total 100 100 100 100 100 Hardness measured by physical property tester (2mm φ, 1. 5mm needle, 2cm/min, 2Krange, RT) 135 125 155 100 205 Drops 7.6 8.3 8. 3 8 8. 3 KSG_21◦ manufactured by Shin-Etsu Chemical Co., Ltd. (containing 2() to 3% by weight of poly(fluorene oxide/(pEG_iG/(5)) crosslinked polymer and 70 to 8M polydimethyloxane polyelectrolytic gel) [Table 2] The method is to use the Henschel Lion machine to make the powder 2__; ^ in the table C1) mix for 2 minutes, use the Henschel mixer to 23 rp shr ί = the last component (category in the table) (8) Mix for 1 minute, use ^, _ oil component (in the table (10), the mixture will be transferred to the mixture and the polyoxoquinone (the prize in the table is 322748 13 201200160

A) Mixing and dispersing with an alcohol (dispersing device, 3 rpm), filling in a container, compression molding, and drying at 60 °C. , #W The hardness and drop strength of the obtained cosmetic were measured. Falling: The method of defeating the strength is to make each cosmetic material; the object is assembled in the state of the second packing box, and the container is placed downwards from the 3_high two: metal plate, to (4) investigate the number: owe The crack was evaluated, and the impact resistance was evaluated from its flat value. The results of the consolidation are presented in Table 2. = The material of the present invention having 15 qualitatively modified _ modified aerogel has a full hardness and excellent drop strength. Moreover, these more versatile cosmetics can give a conspicuous pearly sensation. (4) In the same manner as in the second embodiment, the Γ 品 品 ( ( ( ( ( Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Rating ^). The determination is made based on the average value of the impurities. Dan, and the results also merged. 322748 14 201200160 [Table 3] Raw material name classification Example 7 Example 8 Example 9 Example 10 Example 11 Mica C 34. 06 36. 68 37. 98 37. 18 29. 18 Talc C 20 10 10 12 5 Antiseptic Agent C 0. 1 〇· 1 0. 1 0· 1 0· 1 Iron oxide C 0. 12 1. 5 1.2 — — Titanium oxide coated mica C 20 31 30 20 5 Titanium oxide coated borosilicate glass C 5 — — 10 20 Titanium Oxide Coated Alumina C — One _ 20 Polydimethyloxane B 2 2 2 2 2 Diisostearyl Malate B 3. 5 3. 5 3. 5 3. 5 3 5 octyloxyglycerol B 0. 2 0. 2 0. 2 0.2 0. 2 Tocopherol B 0. 02 0. 02 0. 02 0. 02 0. 02 Polyoxyl gel n A 15 15 15 15 15 Total 100 100 100 100 100 Pearlescent brightness at the time of coating ◎ ◎ ◎ ◎ Pearl brightness of appearance ◎ ◎ ◎ ◎ ◎ Hardness measured by physical property measuring instrument (2 min φ, 1 needle, 2 cm/min, 25 ° C) .5 mm 130 150 140 125 135 1) KSG-210 manufactured by Shin-Etsu Chemical Co., Ltd. (containing 20 to 30% (polydimethyl decane / ({> £ (5_1 〇 / 15)) cross-linked polymer with 70 to 803⁄4 polydimethyl oxane polyoxyxide gel) The cosmetics (hard type) of the composition shown in the following Table 4 were produced by the same method. The painters (10 persons) were required to use the cosmetics of Examples 12 to 16 described in Table 4, and the degree of the face of the eye was The sensory evaluation (points) of the 卩 般 进行 。 。 。 。 。 。 官能 官能 官能 官能 官能 官能 322 322 322 322 322 322 322 322 322 322 322 322 322 322 322 322 322 322 322 322 322 322 322 322 322 322 322 322 322 322 322 322 322 322 ” refers to the phenomenon that the pearlescent agent does not fall on the cheeks or clothes when it is applied (drops), and has good adhesion properties to the skin. [Table 4] Raw material name classification Example 12 Example 13 Example 14 Example 15 Example 16 Talc C 11 11 11 11 11 Synthetic phlogopite C 10 10 10 10 10 Mica C 25 25 25 25 25 Preservative C 0. 1 0. 1 0· 1 0· 1 0. 1 Polyoxygenated Antimony iron C 0. 18 0. 18 0. 18 0. 18 0. 18 Polyethylene terephthalate / polymethyl methacrylate laminated film powder C 15 15 15 15 15 Titanium oxide coated boron lanthanum Acid glass C 20 20 20 20 20 Polydimethyl siloxane Β 5. 5 — _ _ Methyl phenyl polyoxy siloxane Β — 5. 5 Ethylhexanoate cetyl ester Β — — 5. 5 _ Tri-2-ethylhexanoic acid glycerol Β 11.5 _ Malic acid diisostearyl Β — — _ 5 5 Lost water Yamanashi sesquiisostearate Β 1 1 1 1 1 Octyloxyglycerol 0. 2 0. 2 0· 2 0· 2 0. 2 Tocopherol Β 0. 02 0. 02 0. 02 0. 02 0. 02 Polyoxygenated gel υ A 12 12 12 12 12 Total 100 100 100 100 100 Pearl Δ △ ◎ ◎ ◎ ◎ Brightness of pearlescent light during coating Δ 〇 Δ Δ ◎ 1) Shin-Etsu Chemical Co., Ltd. The manufactured KSG-210C comprises 20 to 30% (polydimethylsiloxane/(PEG_1〇/15)) crosslinked polymer and 70 to 80% polydimethyloxane polyoxyxide gel. 16 322748 201200160 It is apparent from the results shown in Tables 3 and 4 above, particularly in a hard cosmetic formulated with 10 to 20% by mass of a polyoxyl siloxane, by blending an ester oil as an oil. Among them, diisostearyl malate is preferred, and the pearly sensation can be further enhanced (the pearl enamel is attached to the eyelid and the pearly brilliance). [Simple description of the diagram] None. [Main component symbol description] None. 17 322748

Claims (1)

201200160 VII. Scope of application for patents: 1. A make-up cosmetic material's characteristics include: (A) a poly-stone-containing oxygen gel containing cross-linked poly-polymer modified poly-growth and poly-wei oil, (B) oil, and (C) Powder. 2. The makeup cosmetic according to the first aspect of the invention, wherein the (4) oxygen gel comprising the cross-linked poly- lysine (4) oxygen gel contains 20 to 3 3% by mass of the following formula (1) ( Polydimethylene oxide/PEG-10 (10) crosslinked polymer and 70 to 80% by mass of polyoxosulfuric acid gel, CHa *CHa CH, 1 CH3 ' 叱c—— s!~«〇. A _ CH, 1 L* ch3 J p L (where η is 3 to 30, number) I CH, CHa p is 1 to ίο, q is 1 to 250. 3. Poly: C. The makeup cosmetic according to item 2, wherein the gas/yield is polydimethyl siloxane. Any of the above-mentioned (A) polyether oxygen gels comprising crosslinked polyether modified polyfluorene oxide and polyoxyxylene oil, 20 to 40 mass, of the cosmetic makeup 322748 1 201200160 And a coloring cosmetic according to any one of claims 1 to 3, wherein the (A) contains a crosslinked polyether. The modified polyoxyl and polyoxygenated polyoxygenated gel is 5 to 20% by mass, and the hardness measured by the physical property meter is 100 to 900. 6. The makeup according to claim 5 of the patent application scope The above-mentioned (B) oil is divided into diisostearyl malate. 7. The makeup cosmetic according to any one of claims 1 to 6, which is an eye shadow. 322748 201200160 4. Designated representative map: There is no schema in this case. (1) The representative representative figure of this case is: (). (2) The symbol of the symbol of the representative figure is simple: 5. If there is a chemical formula in this case, please reveal the best display. Chemical formula of the invention: Chemical formula not represented in this case. 322748