201138702 六、發明說明： 【發明所屬之技術領域】 本發明關於一種由不織布構成的清潔巾 (以卿ngstueh)，特料.：#清潔及家務清潔以及用 在醫藥、化粧、或身體保養範圍，具有一由一種纖維絮構 成的載體層，該纖維絮在所選之面積區域利用一結合劑姓 合而在其餘面積區域不結合，並有至少—種作用物質在該 載體層之内及/或之上，該作用物質具有預設之功能性。 本發明還關於一種製造這種抹布的方法。 【先前技術】 以不織布為基礎的清潔巾廣泛被使用，且大多由水柱 鞏固的不織布材料構成。所有清潔巾都有报軟而舒服的手 感，對於主觀的及使用及感覺宜像具某種物體的材料給使 用者的感覺或在使用時覺得有膨鬆體積感。 人們將擦拭分成乾擦和濕擦’在濕清潔巾的場合，如 -般在身體保養範圍、在家務清潔、以及在汽車保養的場 合，係將不織布構成的載體材料用一作用物質（例如保養 劑、水、或乙醇或其混合物）含浸，俾能除了載體材料本身 的清潔作用外’還提供使用者其他魏，這些附加功能， 舉例而言：為加強清潔主量，主保養的㈣〔例如使皮膚 脂潤（R献fe_g)〕、或漆保養或木材保養作用，此處只列 舉-例子。乾擦的例子為利用栻塵布作清潔，& 了將灰塵 擦入纖維布中，纖維布之用於作清潔的那一面宜最成較開 放式。 201138702 人們大多希望清潔巾不只能作一個功能，而係能作好 幾個功能。因此，舉例而言，在us 2005/0136099A1提到 一種以不織布為基礎的用保養皮膚的洗劑（L〇ti〇n)含浸的化 粧物品，它除了清潔作用外還有其他功能。因此依Us 2005/0136099A1，在一不織布載體的表面上設有點狀疣 突，由微珠粒（剝離顆粒）構成，它們除了利用洗劑作清潔和 保養外，另外在皮膚上有一種剝離效果。這些點狀疣突（它 們依此文獻係在-分別的工作步驟施到_製成的不織布載 體上）由一彈性體材料構成，例如竹子（Bambus)或磨碎的洋 撖欖（Olive)的核、或鹽粒或糖粒或由其他礦物材質構成。 【發明内容】 種不織布構成的清潔巾，它的 ch)性質，例如軟的手感及膨鬆 作用。此外，該清潔巾要能簡 本發明的目的在提供一 特色為有很好的觸覺（haptis 體積感，且有多功能之清潔 單而廉價製造。 的』巾a!:係利：具有”專利範圍第1項的所有特 清潔巾的方’：请專利範圍第6項關於-種製造本發 項：巾的方法。本發明較佳的設計見於申請專利範圍附 工業清.絮及^ * 叫叩褥庾的滑潔巾，特別可拜 ”系及豕務清潔以及用在醫藥 '化粧、 圍，具有一ώ ^ 粧或身體保廣 成的詩 維絮（纖維網）他r，英., 成的載體層，今_祕+ f央.web, 。亥纖維各在所選之面 合而在其餘；级r t 傾^•巧判用—結合劑 -餘面積區域不結合，並有 ^種作用物質在 4 201138702 載體層之内及/或之上，該作用物質具有預設之功能性。 其中，該至少—種作用物質利用該結合劑結合在載體層表 面上及/或在載體層内。 由於該纖維絮（Faserflor)只在所選之面積區域結合，也 只在這些面積區域設有一作用物質，因此纖維在鞏固的 (verfestigt，英.cons〇i1(jated)區域與設有作用物質的區域 之間有最大可能的可運動性。不同於一般清潔巾所用之傳 統之水柱鞏固的扁平且較無體積感的不織布，本發明的清 潔巾的特色為有大的體積感，高的跳躍彈性、高軟度、= 舒適的手感。 又、及 所用的結合劑將纖維絮結合成不織布。利用同時加入 的作用物f，可達成其他功能，因此造成多功能的清潔效 果。 藉著所用結合劑的量對作用物質的量的比例，以及藉 著改變纖維絮的可润濕性的變化，可得到很強力結合而耐 刮損的產物或很軟的產#，其表面可和粗縫的布相當。作 少勿處的比例可在很大的範圍變化’藉著把該作用物質〔大 二：粒子形式，直接或間接由浮紗(跳紗)(F1〇tte，英：fl〇at) 改變。的表面改質可使它們結合到結合劑母質中的作用 所要用於載體層的 . 纖維、、，.口 s浏、以及作用物質的選 擇係看各應用目的而^ ^ 什麼限制，此h 4 處’使用本發明，原則上沒有 合。 此處行家可很容易地找出適合其用途的材料紐 201138702 因此，纖維絮的纖維可由化學纖維或由天然纖維或由 自由變化的混合纖維構成，所用化學纖維宜為聚烯（例如 PP、PE、CoPO)、聚 g旨（例如由 PET、PBT、PTT、c〇pEs 構 成）' 聚酿胺（例如PA6、PA66、CoPA)'聚内酯纖維聚乙烯 醇纖維、聚乙烯乙酸酯纖維、或纖維素再生纖維、如粘絲 (Viskose)或溶纖維素（Lyocell)及/或相關的結合纖維。所用 天然纖維的例子，例如典型之羊毛或棉纖維，然而也可考 慮其他類型，例如扁平紗（Flach)、苧麻（Hanf，英：hemp)、 瓊麻（Sisal)及類似物。各依所要之性質分佈輪廓由線而定由 相關之親水性及嫌水性纖維構成的混合物顯示很適合。 在此，化學纖維可包含可捲縮的、捲縮的（gekrauseh， 英：crimped)及以及相關的震置，也可使用纖維素 (Zellstoff^在程序中受較高度捲縮作用的高度捲縮纖維會 造成彈性產物，載體層可為單一纖維層或由相同或不同之 纖維層由多層建構。 特別適合作清潔巾者為纖度最A 1〇 &德士 (dtex)的纖 維。如纖度更粗，則由於其纖維韌度大，一般不使用。較 之纖維纖度在0.9 dtex〜3.3 dte範圍，然而也可考慮纖度 遠j於1分德士的微纖維，所用之纖維絮的單位面積重量 在12克/平方米與100克/平方米之間變化，且宜在25 克/平方米與60克/平方米之間變化。 =合劑可為一種丙烯酸酯、苯乙烯丙烯酸酯、乙撐乙 烯乙、丁二烤丙稀酸酯、sbr、卿尺_及/或聚胺基甲 酸乙酯類型的結合劑。 6 201138702 纖維對固體結合劑成分的重量比例可在 之間變化，且宜在ι.·2與5:1之間變化。 .1 斤加的軟而粘性的結合劑分散物或對應地選擇的結合 4混合物除了使纖唯絮 ° 性。葬… 還會使灰塵有較佳附著 1 7藉者使用固體作用物質，同樣地可達成不同的效果。 粒、別聚合物構成之所添加的粉末或微顆 子、閃免小片、磨碎的植物原料（竹子、洋橄欖 =礦物性物：當作剝離作用物、微封囊之粒子狀添加 匕Η在使用時崩解）可藉著流出之作用物質補充該剝離 。彿石、環糊精或類似物質可呈作用物質的儲存站 或供應站（Spender)的形式而具有類似功能。膨張作 =微封囊可藉著封囊（Kapsel，英：崩解以及該到 貝的點的體積增大而加強剝離效果。吸濕的粒子可考慮 :及收水分，同樣可將所加之固體活性物質(它們由上： :’为質釋出)的可自由選擇的組合在下文中列舉 =藥草萃取物_uie咖ake，英：herbext_)(例如 ^)、油、不同類型的維他命.芳香物質、抗微生物之物質、 所有種類的_如多元醇）、保養洗劑、洗濯作 =(肥幻或類似物。以上列舉者只是例子，本發明並不 每些例子。結合劑與活性物質之間的每個重量單位的 t例且在1 : 〇和i : 4之間變化。 由、-口劑以及活性物質(它們係以液體為基礎，例如一 水性分散液或呈糊膏形式存在)構成的混合物宜呈點圖案 、方式施到載體層上。如此可確保材料有特別的軟度及彈 201138702 :兆的彈性，點圖案可呈規則或不規則方式分佈。但本發明 絕非限於點圖案，由結合劑與作用物質構成的混合物可呈 :何幾何形狀施覆’例如也可呈線、條帶、網狀或格狀構 蛻、具有長方形、菱形或橢圓幾何形狀或類似物者的形式。 一種製造本發明的清潔巾的較佳方法包含以下措施： (a) 藉著將纖維構成的一種纖維絮在—集層裝置上用習知 方式集層而製造一載體層； (b) 如有必要將載體層作預鞏固’以在纖維絮中造 結合； (c) 將纖維絮中剩餘水分調成因方法而異者； ⑷製造一種由結合劑與至少一活性物質構成的混合物， 並將混合物施到該載體層之所選面積區域； (e)將步驟⑷所得的載體層隨該混合物作溫度處理，以作 乾燥，並將纖維絮的纖維利用該結合劑結合成一不織 布，且如有必要，可將結合劑交聯並將該作用物質利 用結合劑固定在載體層表面上或載體層中，如有必 可將作用物質粒子燒結在一起。 上述方法有-優點：它可簡單而廉價地實施，盘上述 =前技術不同者，將纖維絮結合成Μ布的作業 从作用物質的作業係在單一工 〇 又 質“丁々，“ 作步驟凡成》在此該作用物 如下文還要說明者）可各依所要之應用以簡單 载體層中以及密集在載體層表面。 入 :製造纖維絮’可使用習知技術。廉價的纖維原料可 W作具有中度不織布強度的微弱預結合的纖維絮，其 8 201138702 先決條件為，它們要滿手感的需求。201138702 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a cleaning towel composed of a non-woven fabric (in the case of qing ngstueh), special materials: #清洁和家清洁清洁和用用药,化妆, or body care, Having a carrier layer composed of a fiber floc which is bonded in a selected area region by a binder and not in the remaining area, and has at least one active substance within the carrier layer and/or Above, the active substance has a predetermined functionality. The invention also relates to a method of making such a rag. [Prior Art] Non-woven fabric-based cleaning wipes are widely used, and are mostly composed of a water-reinforced nonwoven material. All wipes have a soft and comfortable feel, and are subjective and use and feel like a material with a certain object to give the user a feeling or feel bulky when in use. People divide the wipe into a dry wipe and a wet wipe. In the case of a wet wipe, such as in the scope of body care, housekeeping, and in the maintenance of the car, the carrier material composed of the non-woven fabric is used as a substance (for example, maintenance). Impregnation of the agent, water, or ethanol or a mixture thereof, in addition to the cleaning action of the carrier material itself, it also provides the user with other functions, such as: for the purpose of strengthening the cleaning amount, the main maintenance (4) [for example Make skin moisturizing (R fe_g)], or paint maintenance or wood maintenance, only examples - here. An example of dry rubbing is cleaning with a dust cloth, & dust is rubbed into the fiber cloth, and the side of the fiber cloth used for cleaning should be the most open type. 201138702 Most people hope that the cleaning towel can not only do one function, but the system can do several functions. Thus, for example, in US 2005/0136099 A1, a non-woven fabric-based cosmetic lotion (L〇ti〇n) is added which has other functions besides cleaning. Therefore, according to US 2005/0136099 A1, a dot-like projection is provided on the surface of a non-woven carrier, which is composed of microbeads (peeling particles) which, in addition to cleaning and maintenance with a lotion, have a peeling effect on the skin. These punctate condyles (which are based on this document in the separate working steps applied to the non-woven carrier) consist of an elastomeric material, such as bamboo (Bambus) or ground olives (Olive). Nuclear, or salt or sugar granules or composed of other mineral materials. SUMMARY OF THE INVENTION A cleaning towel composed of a non-woven fabric has a ch) property such as a soft hand and a bulking effect. In addition, the cleaning towel should be able to provide a feature that is characterized by a good touch (haptis volume, and a multi-functional cleaning sheet that is inexpensive to manufacture. The scope of all the special cleaning wipes of the first item is as follows: Please refer to item 6 of the patent scope for the method of manufacturing the present invention: the towel. The preferred design of the present invention is found in the scope of the patent application.叩褥庾 滑 , , , , , , , , 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 医药 医药 医药 医药 医药 医药 医药 医药 医药 医药 医药The carrier layer, today _ secret + fyang.web, . hai fiber in the selected face and the rest; level rt 倾 ^• skill judgment - bonding agent - the remaining area does not combine, and has a role The substance has a predetermined functionality in and/or on the carrier layer of 4 201138702. The at least one active substance is bound to the surface of the carrier layer and/or in the carrier layer by means of the bonding agent. Since the fiber floe (Faserflor) is only combined in the selected area, it is only These areas of area are provided with an active substance, so that the fibers have the greatest possible mobility between the consolidated (fefestigt) and the area where the substance is provided. The cleansing towel of the present invention is characterized by a large volume, a high jumping elasticity, a high softness, a comfortable hand feeling, and a bonding agent used for the fiber. The floc is combined into a non-woven fabric. By using the simultaneously added active material f, other functions can be achieved, thereby causing a multifunctional cleaning effect. By the amount of the binder used, the ratio of the amount of the active substance, and the variability of the fiber floc The change in wetness can result in a very strong combination of scratch-resistant products or a very soft product. The surface can be comparable to a coarse-skinned cloth. The ratio of the less-to-be-changed can vary over a wide range. The active substance [sophomore: particle form, directly or indirectly changed by float yarn (F1〇tte, English: fl〇at). The surface modification can make them bind to the bonding agent matrix. The fiber to be used for the carrier layer, the choice of the material, and the choice of the substance to be used depends on the purpose of each application. What is the limit? This is used in this h 4 ', in principle, there is no combination. It is easy to find the material suitable for its use. 201138702 Therefore, the fiber of the fiber floc may be composed of chemical fiber or natural fiber or a mixture of freely varying fibers, and the chemical fiber used is preferably a polyolefin (for example, PP, PE, CoPO), Polyg (for example, composed of PET, PBT, PTT, c〇pEs) 'Polylanamine (eg PA6, PA66, CoPA)' polylactone fiber polyvinyl alcohol fiber, polyvinyl acetate fiber, or cellulose regeneration Fibers, such as Viskose or Lyocell and/or related bonding fibers. Examples of natural fibers used are, for example, typical wool or cotton fibers, however other types are also contemplated, such as flat yarns (Flach), ramie (Hanf, hemp), Sisal, and the like. The distribution profile of each of the desired properties is determined by the line from a mixture of related hydrophilic and anaerobic fibers. Here, the chemical fibers may comprise crimpable, crimped and associated shocks, or cellulose (Zellstoff^ is highly crimped in the program by higher curling). The fibers cause elastic products, and the carrier layer can be a single fiber layer or a multi-layered construction of the same or different fiber layers. Particularly suitable for use as a cleaning towel is the fiber with the finest A 1 〇 & dtex. Thick, because of its high fiber toughness, generally not used. Compared with the fiber fineness in the range of 0.9 dtex~3.3 dte, however, it is also possible to consider the microfiber of the fiber denier farther than 1 minute, the unit weight of the fiber batt used. It varies between 12 g/m2 and 100 g/m2, and preferably varies between 25 g/m2 and 60 g/m2. = Mixture can be an acrylate, styrene acrylate, ethylene vinyl B, butyl butyl acrylate, sbr, qing _ and / or polyurethane type bonding agent. 6 201138702 fiber to solid binder composition weight ratio can vary between, and should be in ι .·2 and 5:1 change. .1 kg The soft and viscous binder dispersion or the correspondingly selected binder 4 mixture, in addition to the fiber, can also be used to bury the dust. It also makes the dust better attached. 7 The borrower uses a solid action substance, which can achieve different effects. Addition of powder or micro-particles, granules, and ground plant material (bamboo, olive, minerals: as a stripping agent, micro-encapsulated particles) Η Disintegration at the time of use) The exfoliation may be supplemented by the effluent substance. Fossil, cyclodextrin or the like may have a similar function in the form of a storage station or a supply station (Spender). The microcapsule can enhance the peeling effect by means of a capsule (Kapsel, English: disintegration and the increase in the volume of the point to the shell. The hygroscopic particles can be considered: and the water is collected, and the solid active substance can also be added ( The freely selectable combinations of them from: : 'released for quality' are listed below = herb extract _uie ake, English: herbext_) (eg ^), oil, different types of vitamins, aromatic substances, antimicrobial Substance All kinds of _ such as polyol), maintenance lotion, washing = = (fat fantasy or the like. The above enumeration is only an example, the present invention is not every example. Each weight unit between the binding agent and the active substance t example and varies between 1: 〇 and i: 4. The mixture of the -, the oral and the active substances (they are based on a liquid, such as an aqueous dispersion or in the form of a paste) is preferably in a dot pattern. The method is applied to the carrier layer. This ensures that the material has a special softness and elasticity of 201138702: mega-element, and the dot pattern can be distributed in a regular or irregular manner. However, the present invention is by no means limited to the dot pattern, and the bonding agent acts. The mixture of substances may be in the form of a geometrical shape, for example, in the form of a line, a strip, a mesh or a lattice, a rectangle, a diamond or an elliptical geometry or the like. A preferred method of making the cleaning wipe of the present invention comprises the following steps: (a) producing a carrier layer by layering a fiber of a fiber onto a layering device in a conventional manner; (b) It is necessary to pre-consolidate the carrier layer to make a bond in the fiber floc; (c) to adjust the residual moisture in the fiber floc to a different method; (4) to make a mixture of a binder and at least one active substance, and to mix the mixture Applying to the selected area of the carrier layer; (e) subjecting the carrier layer obtained in step (4) to temperature treatment with the mixture for drying, and combining the fibers of the fiber floc into a non-woven fabric using the bonding agent, and if necessary The binder may be cross-linked and the active substance may be immobilized on the surface of the carrier layer or in the carrier layer by means of a binder, if necessary, the particles of the active substance may be sintered together. The above method has the advantage that it can be implemented simply and inexpensively, and the above-mentioned prior art is different, and the operation of combining the fiber batt into a crepe is performed in a single process and the quality is "single," In this case, the substrate can be applied in a simple carrier layer and densely on the surface of the carrier layer, as will be explained below. Into: The fiber batt can be made using conventional techniques. Cheap fiber raw materials can be used as weak pre-bonded fiber batt with moderate non-woven strength, which is a requirement for full hand feel.
當使用短纖維的情形，宜將它們利用 ,.B 土夕一梳理窃 (Krempel)梳理（Kardieren)成纖維絮，此處宜用—種隨機集 層（Wirrlegung，英：random laying)〔隨機（不規則）技術 (Random-Technologie)〕，但如果想要能有特別的不織布性 質或希望有多層纖維構造時，也可為縱集 及/或橫集層（Querlegung)的組合或更複雜的梳理設置。同 樣可採用與空氣集層（Airlaid-Vlieslegung)的組八。 由纖維絮構成的載體層在纖維在集層裝置上集層後， 宜在進一步加工過程作預鞏固以改善可使用性，依本發明 一較佳實施例係利用低壓水柱方法作預鞏固。這點宜在高 可達50巴的壓力實施，尤宜使單列或多列設置的水柱喷嘴 的孔直徑70〜120微米，且喷嘴距載體層的距離為〇 2〜〇 8 毫米。 由此顯示出，使用低壓水柱方法，可用特別的方式影 響纖維絮的性質，以使在以後當作清潔巾使用。因此纖維 絮的機械強度提高很多，使得在生產程序中的可操作性大 大改善。另方面，用此方式微弱結合的纖維絮的特點為極 軟的手感與大的膨.鬆體積感，因此它們特別適合用於當作 清潔巾。另一優點為：纖維絮受到水柱鞏固程序而自動地 潤濕。因此在習知技術本來須用水作預潤濕以提高印刷程 序的生產確實性〔例如利用軋染機（F〇ulard)//汲取羅拉 (Sch0pfwalzen)作的程序〕的作業可省卻。藉著在低壓水柱 方法之背向喷嘴的相反側上選用適當的模板（Schabl〇n)，舉 201138702 例而言可產生穿孔及有槽孔的纖維絮構造，它們隨後當作 相關的載體層用。 在預鞏固之後，將纖維絮構成的載體層用以一種混合 物處理，該混合物由結合劑和至少一作用物質構成。此用 印刷的混合物宜呈分散液形式。如此該載體層可直接在一 印刷機中用該分散液（它含有該結合劑與加入的作用物質） 印刷。 所用的分散液宜包含： --丙烯酸酯、苯乙烯丙烯酸酯、伸乙基乙烯乙酸酯、丁 一稀丙烯酸醋、SBR、NBR、及/或聚胺基甲酸乙醋類 型的交聯過或可交聯的結合劑，及 --輔助劑，如 0稠化劑（例如部分交聯的聚丙烯酸酯及其鹽類） 0分散劑 〇交聯劑 °助流劑 0手感改良劑（例如矽力康化合物或脂肪酸酯衍生物） 及/或 〇填充劑 如有必要，還有活性物質。 該作用物質可經由結合劑加入載體層中，也可密集在 其表面，至於那些變更例較佳，係取決於所要的用途。 為了要密集在表面，該添加的物質或作用物質宜呈粒 子形式’換言之，使用由結合劑與粒子構成的組合。由此 10 201138702 分散液，可將大不相同的結合劑與粒子構成的 合印刷上去。 n 為了在表面密集，所添加物質或作用物質宜呈粒子形 式，換言之，使用結合劑與粒子構成的分散液。由此分散 液，可將由大不相同種類的結合劑與粒子構成的幾乎=何 =口印刷上去。出乎意料的，事實顯示，t此載體層用一 分散液（由粒子、結合劑及可能有的其他成分）將冑體層印刷 時：較粗的粒子大部分在多孔隙載體由表面上渡出。如此 形成似雙點式的構造，由作用物f構成的粒子或帶有作用 物質的粒子在載體表面密集且利用一部分的結合劑結合在 載體層表面，因此它們可在載體層表面利用其(自由的)表面 發揮其完全的作用，而另一部分的結合劑則侵入到多孔隙 的載體材料的較深處，在該處固^並結合在載體材料中。 社人粒子的尺寸宜針對所要印刷的面積，例如載體層中一 σ。點之所要尺寸。在點圖案的情形中，粒子直徑在大於〇 «〜500微米間變化。基本上’作用物質的粒子尺寸並非 致者’而係呈-種分佈。換言之’往往有-種粒子尺寸 的分佈的頻譜。上述的界限係為各種主成分分率。粒子尺 寸肩配合所要之施覆量、點尺寸及點分佈而設定。 ；此外粒子的尺寸係針對所要印刷的載體材料的孔隙 = 確保粒子留在載體表面，從液體過濾的經驗值顯示： β田粒子直徑約為載體材料的平均孔隙直徑的約三分之一 告4往仍有90%的粒子在載體材料的表面上被過濾 掉w粒子直徑在一半的平均孔隙直徑的等級時，甚至有 201138702 99%粒子在載體表面被過濾掉。 只丨不上，在一般所用的纖 維絮（FaSerf1〇r)的場合’粒子直徑小於5〇〇微米（且宜_ 微米〜_微米）的粒子證實較佳。但行家可容易利用上述 規則，而不須做另外發明性的事宜，gp可對於具預設之孔 隙率的載體材料找到適合的粒子尺寸。 所用的結合劑宜為（混合之）聚合物分散液，其粒子尺寸 遠小於5G微米，所用結合劑係為用於結合不織布所用的習 用產物，且宜由水性聚合化物分散液構成。 所用結合劑的玻璃轉換溫度點可變化，然而對於軟產 物-般宜自Tg<HTC的「軟」結合劑。軟結合劑—般甚至 較有枯性’由此對於特；t料，舉例而言，吸收灰塵的能 力提南’辅助物質用於調整㈣的枯度。利用適當結合劑， 可將此清潔巾的觸感在很大的範圍中變化。 在印刷程序之後，將材料你、、田 W ^ ^ /皿度處理以作乾燥並使结 合劑交聯’並使加入的作用物質利用結合劑燒結到載體層 表面上或與載體層表面燒結。 然後可將材料捲取起來。 本發明的清潔巾的較佳應用為家務、衛生、㈣及/ 或醫藥範圍的應用。 【實施方式】 以下利用二個實施例說明本發明的實施例，但本發明 的一般性不限制於此。 〔實施例1〕 -種梳理過的纖維絮’單位面積重量35克，平方米， 12 201138702 由100%(聚酯）再生纖維（1.7分德士/34毫米）構成，利用 一喷嘴條帶（DiiSenstreifen)用15巴的水壓作預網化 (vornetzen)/緊密化。並在一第二噴嘴條帶上從另一側施以 35巴的水壓。將過量的水抽掉直到剩餘水分16〇%為止。 利用很弱的低壓〔相較於水纏結㈣如⑽咕⑽㈣輩固〕 作鞏固。將這種纖維絮（它結合成-種很軟而有體積感的不 織布）隨後進入一旋轉網版印刷機（它具有2〇點/平方公分） 並用一種結合劑聚合物分散液以2〇克/平方米的施覆是呈 點狀印刷。印刷過的不織布在一個帶乾燥機中在18〇。〇乾 燥，使結合劑交聯，並使聚合物粒子燒結上去或燒結在一 起。 在此，結合劑-聚合物分散液的組成如下： 自交聯丁基·/丙烯酸基聚合物結合劑分散液：He : 15份 共聚醯胺粉末：80〜170微米；熔解範圍在1〇9〇c左右： 21份 交聯劑a/n/i 2份 增祠劑 3份 水 曰 59份 知到的不織布，最大拉伸力量為從100 N/5cm，橫13.5 N/5CIT1，最大拉力拉伸為縱61%，橫190%。加入之共聚醯 磨的作用且有剝離的作用。此清潔巾具有軟手感， 其度2.656毫米（四層，當〇 5 kpa的負荷加到以平方公分 面積上為時十秒的場合測量），由此得到比重〇 〇 $ 1毫克 /立方公分。而先前技術以100%的聚酯纖維為基礎以及作 狀印刷用二階段方法製造的-般不織布則具比重0.075 13 201138702 毫克/平方公分，因此手咸龢I* Of. ^ 扣于琢較硬，換言之，較不軟且較緊 密’體積感較小，且由於您由私、 w y在度較尚，能儲容的污物較小， 因此’它比本發明的清潔巾差。 〔實施例2〕 一種梳理的纖維絮，單位面積重量50克/平方米，由 100% (聚酯）再生纖維構成（1 7分德士/34毫米），利用一喷 嘴條帶以15巴水Μ預網化/緊密化。並在—個第二喷嘴條 帶上由另一側施35巴水壓。將過剩的水抽離到剩餘水分14〇 %為止。利用低壓（比起水纏結鞏固來很弱）作鞏固。此纖維 絮（它結合成一很軟而有體積感的不織布）隨後進入一旋轉 網版印刷機（具有10點/平方公分），並用一種結合劑_聚合 物膨脹的微球封囊分散液以3()克/平方米的施覆量作點狀 印刷。印刷過的不織布在一個帶乾燥機中在18〇<t乾燥，使 結合劑交聯，使膨脹作用的微球封囊爆裂（zerplatzen)，並 將聚合物粒子燒結上去或燒結在一起。 15份 Η份 7ocsh 2份 3份 59份 在此，結合劑-聚合物分散液的組成如下： 自交聯丁基-/丙烯酸基聚合物結合劑分散液：m 化粧用途HDPE粉末，1〇〇〜3〇〇微米 化粧用途微封囊，10〜20微米(未處理者）When short fibers are used, they should be used. .B Krempel carding (Kardieren) fiber wadding, where random layering (Wirrlegung, English: random laying) [random ( Random-Technologie, but if you want to have special non-woven properties or want a multi-layer fiber construction, it can also be a combination of vertical and/or horizontal layers or more complex combing. Settings. The same can be used with Group 8 of Airlaid-Vlieslegung. The carrier layer composed of the fiber floc is preferably pre-consolidated in a further processing to improve the workability after the fibers are layered on the layering device. According to a preferred embodiment of the invention, the low pressure water column method is used for pre-consolidation. This should preferably be carried out at a pressure of up to 50 bar, and it is preferable to have a single column or a plurality of columns of water column nozzles having a hole diameter of 70 to 120 μm and a distance of the nozzle from the carrier layer of 〇 2 to 〇 8 mm. It has thus been shown that the use of a low pressure water column method can affect the properties of the fiber floc in a special manner so that it can be used as a cleaning wipe later. Therefore, the mechanical strength of the fiber floc is greatly improved, so that the operability in the production process is greatly improved. On the other hand, the fiber batt which is weakly bonded in this manner is characterized by a very soft hand and a large bulky feeling, so that they are particularly suitable for use as a cleaning towel. Another advantage is that the fiber floc is automatically wetted by the water column consolidation process. Therefore, in the prior art, it is necessary to pre-wet with water to improve the production reliability of the printing process (for example, the operation by using a pulverizer (F〇ulard)//"Roller" (Sch0pfwalzen) can be omitted. By using the appropriate template (Schabl〇n) on the opposite side of the nozzle to the opposite side of the low pressure water column method, perforated and slotted fiber floc structures can be produced in the case of 201138702, which are then used as the relevant carrier layer. . After pre-consolidation, the carrier layer of fibrous floes is treated with a mixture consisting of a binder and at least one active substance. The printed mixture is preferably in the form of a dispersion. Thus the carrier layer can be printed directly in a printing press with the dispersion which contains the binder and the added active material. The dispersion used preferably comprises: - acrylate, styrene acrylate, ethyl vinyl acetate, butyl acrylate, SBR, NBR, and / or polyurethane urethane type crosslinked or Crosslinkable binders, and - adjuvants, such as 0 thickeners (such as partially crosslinked polyacrylates and their salts) 0 dispersants 〇 crosslinkers ° flow aids 0 feel modifiers (such as 矽Likang compounds or fatty acid ester derivatives) and/or lanthanum fillers, if necessary, also active substances. The active substance may be added to the carrier layer via a binder or may be densely attached to the surface thereof, as those variations are preferred depending on the intended use. In order to be densely packed on the surface, the added substance or active substance is preferably in the form of a particle. In other words, a combination of a binder and particles is used. Thus, the 10 201138702 dispersion can print a combination of very different binders and particles. n In order to be dense on the surface, the added substance or the acting substance is preferably in the form of particles, in other words, a dispersion composed of a binder and particles. With this dispersion, it is possible to print almost any of the different types of binders and particles. Unexpectedly, the facts show that the carrier layer uses a dispersion (by particles, binders and possibly other components) to print the corpus callosum: the coarser particles are mostly on the surface of the porous carrier. . In such a two-point configuration, the particles consisting of the substrate f or the particles with the active substance are densely packed on the surface of the carrier and bonded to the surface of the carrier layer by a part of the binder, so that they can be utilized on the surface of the carrier layer (free The surface exerts its full function, while another portion of the binder invades into the deeper portion of the porous carrier material where it is bonded and incorporated into the carrier material. The size of the social particles should be specific to the area to be printed, such as a σ in the carrier layer. The desired size of the point. In the case of dot patterns, the particle diameter varies between 〇 «~500 microns. Basically, the particle size of the acting substance is not the same as that of the substance. In other words, 'there is often a spectrum of the distribution of particle sizes. The above boundaries are various principal component fractions. The particle size shoulder is set with the required amount of application, point size and point distribution. In addition, the size of the particles is for the pores of the carrier material to be printed = ensuring that the particles remain on the surface of the carrier, and empirical values from liquid filtration show that the diameter of the beta field is about one third of the average pore diameter of the carrier material. When 90% of the particles are still filtered on the surface of the carrier material, the w particle diameter is on the order of half the average pore diameter, and even 201138702 99% of the particles are filtered off on the surface of the carrier. However, in the case of a fiber floc (FaSerf1〇r) generally used, particles having a particle diameter of less than 5 μm (and preferably _micrometer to _micrometer) have proven to be preferable. However, it is easy for an expert to utilize the above rules without having to make additional inventive matters, and gp can find a suitable particle size for a carrier material having a predetermined porosity. The binder used is preferably a (mixed) polymer dispersion having a particle size much smaller than 5 Gm, and the binder used is a conventional product for bonding nonwoven fabric, and is preferably composed of an aqueous polymer dispersion. The glass transition temperature point of the binder used can vary, however, for soft products, a "soft" binder from Tg <HTC is preferred. Soft binders are generally even more rude. Thus, for special materials, for example, the ability to absorb dust is used to adjust the dryness of (4). The feel of the wipe can be varied over a wide range with a suitable binder. After the printing process, the material, W, and the film are treated to dry and crosslink the binder and the added active material is sintered to the surface of the carrier layer or sintered to the surface of the carrier layer. The material can then be taken up. Preferred applications of the cleaning wipes of the present invention are in the household, sanitary, (four) and/or medical applications. [Embodiment] Hereinafter, embodiments of the present invention will be described using two embodiments, but the generality of the present invention is not limited thereto. [Example 1] - Kind of carded fiber floc 'Unit weight 35 g, square meter, 12 201138702 Composition of 100% (polyester) recycled fiber (1.7 dtex / 34 mm) using a nozzle strip ( DiiSenstreifen) is pre-networked (vornetzen)/tightened with a water pressure of 15 bar. A water pressure of 35 bar was applied from the other side on a second nozzle strip. Excess water was pumped out until the remaining moisture was 16%. Use a very weak low pressure [compared to water entanglement (four) such as (10) 咕 (10) (four) generation solidification] for consolidation. The fiber wadding (which combines into a soft, volumey nonwoven) is then fed into a rotary screen printer (which has 2 〇 / cm ^ 2 ) and a binder polymer dispersion of 2 gram The application of / square meter is printed in dots. The printed non-woven fabric was placed in a belt dryer at 18 inches. The crucible is dried to crosslink the binder and cause the polymer particles to sinter or sinter together. Here, the composition of the binder-polymer dispersion is as follows: Self-crosslinking butyl-/acrylic-based polymer binder dispersion: He: 15 parts of copolymerized guanamine powder: 80 to 170 μm; melting range is 1〇9 〇c or so: 21 parts of cross-linking agent a/n/i 2 parts of sputum agent 3 parts leeches 59 parts of known non-woven fabric, the maximum tensile strength is from 100 N/5cm, horizontal 13.5 N/5CIT1, maximum tension pull Stretched to 61%, 190%. The addition of the copolymerized crucible has the effect of peeling. This cleaning towel has a soft hand feeling of 2.656 mm (four layers, measured when a load of k 5 kpa is added to a time of ten seconds on a square centimeter area), thereby obtaining a specific gravity 〇 1 1 1 /cm ^ 3 . The prior art is based on 100% polyester fiber and the two-stage method of printing is made of a non-woven fabric with a specific gravity of 0.075 13 201138702 mg / cm ^ 2, so the hand salt and I * Of. ^ buckled harder In other words, it is less soft and tighter. 'The volume is smaller, and since you are private, wy is more, the dirt that can be stored is small, so it is worse than the cleaning towel of the present invention. [Example 2] A carded fiber batt having a basis weight of 50 g/m 2 , composed of 100% (polyester) recycled fiber (17 dtex/34 mm), using a nozzle strip with 15 bar of water Μ Pre-networked / compact. And on the second nozzle strip, 35 bar water pressure is applied from the other side. The excess water is pumped to the remaining moisture of 14%. Consolidation with low pressure (weakened by consolidation of water entanglement). The fiber floe, which combines into a soft, volumey nonwoven fabric, then enters a rotary screen printer (having 10 dots per square centimeter) and uses a binder-polymer expanded microsphere encapsulating dispersion to 3 () grams / square meter of the amount of application for dot printing. The printed non-woven fabric is dried at 18 Torr in a belt dryer to crosslink the binder to swell the expanded microspheres and sinter or sinter the polymer particles together. 15 parts of 7ocsh 2 parts 3 parts 59 parts Here, the composition of the binder-polymer dispersion is as follows: Self-crosslinking butyl-/acrylic polymer-based polymer binder dispersion: m Cosmetic use HDPE powder, 1〇〇 ~3〇〇 micron cosmetic use micro-encapsulation, 10~20 microns (untreated)
交聯劑a/n/I 增稠劑 水 所得不織布的最大拉力：從13〇N/5cm，橫21N/5cm， 最大拉力拉伸：縱65%，橫204%。所加HD_PE粉末具有 14 201138702 •Jij磨作用日士 有剝離作用，該剝離作用由於很突出的點（由膨 脹的微封囊造成者）而更大大加強。此清潔巾具有軟手感， 即使在高拉伸情形也可看得出。它具有0.9 mm之有體積感 予度（四層，在〇 5 kPa負荷施到25 cm2面積上為時1 〇秒 的場合）’由此造成比重0.031毫克/立方公分。 【圖式簡單說明】 無 【主要元件符號說明】 無 15Crosslinking agent a/n/I Thickener Water Maximum tensile force of non-woven fabric: from 13〇N/5cm, transverse 21N/5cm, maximum tensile force: 65% vertical and 204% horizontal. The added HD_PE powder has 14 201138702 • The Jij grinding action has a peeling effect which is greatly enhanced by the prominent point (caused by the expanded micro-encapsulation). This wipe has a soft hand and can be seen even in high stretch situations. It has a volumetric sensitivity of 0.9 mm (four layers, when the load of 〇 5 kPa is applied to a 25 cm2 area for 1 sec.), resulting in a specific gravity of 0.031 mg/cm 3 . [Simple description of the diagram] None [Key component symbol description] None 15