201134915 六、發明說明： 【發明所屬之技術領域】 本發明係有關一種膠布的製造方法，特別是關於一種高接著與高 耐磨之複合膠布的製造方法。 【先前技術】 聚氣乙烯{PVC，〔Poly(vinyl chloride)〕}是人造聚合物中最重要 且使用最普遍的一種，主要是因為它具有很大的變異性，在製造聚氣 乙烯產品的過程中可配合不同的用途和需要，加入各種可塑劑及添加 φ 劑來改變其物理或化學性質。 聚氣乙烯的最大特徵為添加液狀可塑劑後，玻璃轉換溫度(丁⑴點 就會開始下降’因可塑化而可製得半硬質至軟質具有廣泛彈性率的材 料’這是軟質聚氣乙烯具實用性之原因。且聚氯乙烯加工範圍非常廣， 由不同聚合度搭配各類改質劑使用，可以獲得完全不同物性的產品， 所以為廣泛使用之高分子。 然而，聚氣乙烯的熔融溫度不高，其成型的溫度通常控制在攝氏 150至湖度之間，因此聚氣乙烯的耐溫性差，此外，聚氣乙稀的化 學乡且成成分為碳、氫、氣，當聚氯乙稀產生熱分解後，會產生致癌的 # 氣化氫，進而影響人體健康。 0此’本發鴨在針對上述之_，提出—種高接著與高财磨之 複合膠布的製造方法’以解決習知所產生的問題。 【發明内容】 本發明之衫目的，在雜供-種冑縣與冑耐紅複合膠布的 =方法’其係在製造過財，布浸於硬化獅溶液中 ，以加強 的接著強度Θ時更與聚氣乙烯和聚氨基甲酸醋之複合膠膜相互 «’以有断健體氣含t ’並降低傷害人舰康的機會。 ▲ 達上述目的本發明提供—種高接著與細狀複合膠布的製 ^、、首先於-硬化稀釋溶液中浸洗一底布，其中硬化稀釋溶液之 201134915 組成成分包含1重量份之異氰酸· (ISQeyana_m_ (Hy_硬化齊丨!，及80重量份之甲苯。接著便加熱此底布，以烘乾^ 再來係形成-結合料於底布之一表面，最後將兼具聚氣乙烯(pvc)與聚 氨基y酸δ旨〇^)之_複合顧透過上狀結合_合誠布之表面。 兹為使貴審查委員對本發明之結構特徵及所達成之功效更有進 -步之瞭馳職’謹伽健之實_配合詳細之綱，說明 如後： 【實施方式】 以下請參閱第1 @ ’首先如步驟S10所示，於—硬化稀釋溶液中 浸洗-材質為聚醋(polyester)之底布，以降低底布之黏度，使底布上附 有的溶液«為彳5瞻饼;Jr公尺(g/Gm2)，其巾硬化稀釋溶液之組 成成/7包3 1重量伤(PHR)之異氰酸酯基(|S0Cyanate)系之異氰酸鹽 (Hylene)硬化劑，及80重量份之甲苯。接著如步驟S12所示係以攝 氏180±20度對底布加熱1〇〜20秒，以烘乾之。再來如步驟S14所示， 使用30〜120目之上糊輪裱糊一結合料於底布之一表面，其中結合料 之組成成分包含100重量份之接著劑與5重量份之架橋劑，且接著劑 為發泡聚氨酯(PU)，架橋劑為異氰酸酯基。 結合料裱糊完後，如步驟S16所示，係以攝氏18〇±2〇度對底布 加熱10〜20秒，以烘乾之。最後如步驟Si8所示，在溫度為攝氏18〇 ±20度的環境下，利用壓花輪對兼具聚氣乙烯(pvc)與聚氨基甲酸酯 (TPU)之一複合膠膜施壓，以將此膠膜透過上述之結合料貼合於底布之 表面。元成之複合膠布的結構剖視圖如第2圖所示，底布1〇貼合有複 合膠膜12,其中底布之厚度為〇.彳釐米，複合膠膜的厚度為〇 5釐米。 聚氣乙婦本身是人造聚合物中使用最普遍的一種，此外，聚氨基 甲酸酯之物性介於塑膠材料與橡膠材料之間，因此當聚氯乙烯加入聚 氨基甲酸酯摻混，不但可以有效降低整體氣含量，也由於具有彈性， 將可取代可塑劑之功能。再者，聚酯底布於硬化稀釋溶液浸洗後，基 201134915 於受浸後之底布與接著劑有相容之效果，可加缝合膠膜中聚氯乙歸 與聚氨基甲酸酯相互之接著強度。 將製造好的複合料送至實驗室分析錄，得卿_接著強度 為50牛頓/公分(N/cm)以上，且其勝面耐磨效果為〇 5克/1〇〇〇轉以 下，由此可知，此複合膠布具有優於一般膠布之高接著與高耐磨特性。 以下介紹上述複合膠膜的製造流程，如第3圖所示，首先如步驟 S20所示，將包含聚氯乙烯與聚氨基甲酸醋之複合膠料混合分散置 於混煉裝置中，並以9G〜18G度進行混煉，其中複合膠料之組成成分 φ 包含重量伤之填充劑、重量份之可塑劑、50重量份之塑膠粉、 50重量份之聚氧基甲酸醋粒、2重量份之鋇-鋅(Ba_Zn)系液態安定劑、 1重量伤環氧大豆油。接著如步驟S22所示，將複合膠料從混煉裝置 中引出，並送至薄膜產生裝置，經連續壓延至一固定厚度而形成複合 膠膜，此厚度為0.5釐米。 —綜上所述，本發明將底布浸於硬化稀釋溶液中，以加強布料的接 著強度’同時更利用聚氣乙烯和聚氨基甲酸酯之複合膠膜的化性以 取代具有高氣含量之聚氣乙稀，並同時降低傷害人體健康的機會。 以上所述者，僅為本發明一較佳實施例而已，並非用來限定本發 • 日月實施之範圍’故舉凡依本發明申請專利範圍所述之形狀、構造、特 徵及精神所為之均等變化與修飾，均應包括於本發明之申請專利範圍 内。 【圖式簡單說明】 第1圖為本發明之複合膠布的製造方法流程圖。 第2圖為本發明之複合膠布結構剖視圖。 第3圖為本發明之複合膠膜的製造方法流程圖。 【主要元件符號說明】 12複合膠膜 10底布201134915 VI. Description of the Invention: [Technical Field] The present invention relates to a method for producing a tape, and more particularly to a method for producing a high-adhesion and high-wear composite tape. [Prior Art] Polyethylene (PVC, [Poly (vinyl chloride)]} is the most important and most commonly used one of artificial polymers, mainly because it has great variability in the manufacture of polystyrene products. The process can be combined with different uses and needs, adding various plasticizers and adding φ agents to change their physical or chemical properties. The most characteristic feature of polyethylene is that after adding liquid plasticizer, the glass transition temperature (the point of D(1) will start to decrease.] It can be made semi-hard to soft with a wide elastic modulus due to plasticization. This is soft polyethylene. It has practical reasons, and the processing range of polyvinyl chloride is very wide. It can be used with various polymerization agents with different polymerization degrees to obtain completely different physical properties. Therefore, it is a widely used polymer. However, the melting of polystyrene The temperature is not high, and the molding temperature is usually controlled between 150 degrees Celsius and the lake degree. Therefore, the temperature resistance of the polyethylene gas is poor. In addition, the chemical composition of the gas mixture is carbon, hydrogen, gas, and polychlorinated. After the thermal decomposition of ethylene, it will produce carcinogenic # gasification hydrogen, which will affect human health. 0 This 'the hair duck in the above-mentioned _, proposed a high-quality and high-grinding composite tape manufacturing method' Solving the problems caused by the conventional knowledge. [Summary of the Invention] The purpose of the shirt of the present invention is that the method of the miscellaneous supply - the seedlings of the 胄 胄 胄 胄 胄 红 红 ' ' ' ' ' ' ' , , , , , , , In order to strengthen the strength of the joint, it is more compatible with the composite film of polyethylene and polyurethane, so as to reduce the chance of injuring the human body. ▲ To achieve the above purpose, the present invention provides - The seeding is followed by the preparation of the fine composite tape, and firstly dipping a base fabric in the hardening diluted solution, wherein the hardening diluted solution of the 201134915 component contains 1 part by weight of isocyanic acid (ISQeyana_m_ (Hy_ hardened丨!, and 80 parts by weight of toluene. Then heat the base fabric to dry it and then form a binder to one surface of the base fabric. Finally, it will combine polystyrene (pvc) with polyamino acid. δ 〇 ) ^) _ compound Gu through the upper form _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Reduce the viscosity of the base fabric, so that the solution attached to the base fabric «for 彳5 Cake; Jr meters (g/Gm2), the composition of the towel hardening dilution solution / 7 packets of 3 1 weight loss (PHR) isocyanate group (|S0Cyanate) isocyanate (Hylene) hardener, and 80 The toluene is added in parts by weight. Then, as shown in step S12, the base fabric is heated at 180 ± 20 degrees Celsius for 1 to 20 seconds to be dried. Further, as shown in step S14, the paste wheel is used in the range of 30 to 120 mesh. The paste is bonded to one surface of the base fabric, wherein the composition of the binder comprises 100 parts by weight of an adhesive and 5 parts by weight of a bridging agent, and the adhesive is a foamed polyurethane (PU), and the bridging agent is an isocyanate group. After the paste is finished, as shown in step S16, the base fabric is heated for 10 to 20 seconds at a temperature of 18 〇 ± 2 Torr to be dried. Finally, as shown in step Si8, at a temperature of 18 〇 ± 20 ° C, an embossing wheel is used to apply a composite film of polyoxyethylene (pvc) and polyurethane (TPU) to The film is adhered to the surface of the base fabric through the above-mentioned binder. The structural cross-sectional view of the composite tape of Yuancheng is as shown in Fig. 2, and the composite film 12 is bonded to the base fabric, wherein the thickness of the base fabric is 〇.彳cm, and the thickness of the composite film is 〇5 cm. Polyurethane itself is the most commonly used one of artificial polymers. In addition, the physical properties of polyurethane are between plastic materials and rubber materials. Therefore, when polyvinyl chloride is added to polyurethane, not only is polyvinyl chloride blended with polyurethane. It can effectively reduce the overall gas content, and because of its elasticity, it will replace the function of plasticizer. Furthermore, after the polyester base fabric is dipped in the hardened dilute solution, the base fabric after the impregnation is compatible with the adhesive according to the 201134915, and the polychloroethylene and the polyurethane in the suture film can be added to each other. Then the intensity. The prepared composite material is sent to the laboratory for analysis, and the strength is 50 Newtons/cm (N/cm) or more, and the wear resistance of the surface is 〇5g/1〇〇〇 or less. It can be seen that the composite tape has a higher quality and a higher wear resistance than the general tape. The manufacturing process of the above composite film is described below. As shown in FIG. 3, first, as shown in step S20, the composite compound containing polyvinyl chloride and polyurethane is mixed and dispersed in a mixing device, and 9G is used. Mixing at ~18G, wherein the composition φ of the composite compound comprises a weight-damage filler, a weight of the plasticizer, 50 parts by weight of the plastic powder, 50 parts by weight of the polyoxyformic acid vinegar, and 2 parts by weight.钡-zinc (Ba_Zn) is a liquid stabilizer and 1 weight of epoxidized soybean oil. Next, as shown in step S22, the composite compound is taken out from the kneading apparatus and sent to a film producing apparatus which is continuously calendered to a fixed thickness to form a composite film having a thickness of 0.5 cm. In summary, the present invention immerses the base fabric in a hardening dilution solution to enhance the bonding strength of the fabric. At the same time, it further utilizes the chemical properties of the composite film of polyethylene and polyurethane to replace the high gas content. The gathering of ethylene and ethylene, while reducing the chance of harm to human health. The above is only a preferred embodiment of the present invention, and is not intended to limit the scope of the present invention. The scope, structure, features, and spirit of the present invention are equivalent. Variations and modifications are intended to be included within the scope of the invention. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a flow chart showing a method of manufacturing a composite tape of the present invention. Figure 2 is a cross-sectional view showing the structure of the composite tape of the present invention. Fig. 3 is a flow chart showing a method of manufacturing a composite film of the present invention. [Main component symbol description] 12 composite film 10 base fabric