201132582 六、發明說明： 【發明所屬之技術領域】 本發明關於使用特殊水與鋁來產生氫之氫製造方法及 氫製造裝置。 【先前技術】 向來已知使用氫當作燃料氣體。作爲製造氫的製造方 法’已有提供許多的發明。例如，已知將水1 00%熱分解以 得到氫之方法’或將硫酸熱分解，使用碘水來取出氫之I S 法（Iodine-Sulfe)法等。IS法係經過本生反應步驟、碘氫 濃縮分解行程與硫酸濃縮分解行程的3個行程，由水分解 氫與氧而取出者（專利文獻1)。另外，已知使金屬鋅與 磁鐵礦反應，而產生氫當作反應生成物的水之分解方法（ 專利文獻2 )。 已知藉由使鋁或鎂與水接觸，而產生氫的氫之製造方 法（專利文獻3 )。 先前技術文獻 專利文獻 專利文獻1 :特開2005-4 1 764 專利文獻2:特開2001-270701 專利文獻3 :特開2007-290888 【發明內容】 發明所欲解決的問題 -5- 201132582 於將水1 00%熱分解以得到氫之方法中，水由於氫與氧 的強連結，據說理論上若不給予3,000°c〜5000°c的溫度’ 則無法分解成氫與氧。於以3,000°C以上的溫度將水熱分解 而得到氫之方法中，由於得不到能實質上得到3，000°C以上 的高溫之方法，或無法廉價地製作用於保持如此的高溫狀 態空間與外界隔離之設備，或不考慮將水連續地供應至高 溫的空間內之手段等，包含有許多的問題，故由水的熱分 解來生成氫係尙未實現。 於專利文獻1所示的IS法中，由於需要900 °c左右的高 熱，必須使用高溫氣體爐等當作熱源。此高溫氣體爐係製 造成本高，而且經過3個步驟來製造氫，製造氫的成本係 非常高。 於專利文獻2所示的水之分解方法中，使金屬鋅和磁 鐵礦在600°C與水蒸氣反應而製造氫，必須具備用於製作 6〇(TC的水蒸氣之加熱手段。 於專利文獻3所示的水之製造方法中，係使用pH爲4-1 〇的不凍水當作水，即使在〇°C以下也產生氫者。於此專 利文獻3中，藉由鋁與水的反應來產生氫，但由於是在0°C 以下的低溫進行反應，於低溫下不大量產生氫，無法以高 的經濟效率來產生氫。 本發明之目的提供一種藉由使特殊水與鋁接觸而可製 造氫的氫之製造方法，與一種藉由使特殊水與鋁接觸而可 用於高效率地製造氫之氫製造裝置。 201132582 解決問題的手段 本發明的氫之製造方法的特徵係：使水最初通過離子 交換樹脂，然後使先通過電氣石與由流紋岩或花崗岩的至 少1個所成之含有6 5〜7 6 %二氧化矽之岩石的任一方，之後 通過另一方，所生成的水爲特殊水，藉由將前述特殊水與 鋁置入容器內，於前述容器內使其接觸的狀態下，使前述 容器內的溫度成爲3 0°C以上且未達前述特殊水的沸點，而 使前述特殊水與前述鋁反應產生氫。本發明之特徵係將前 述容器內的溫度保持在80°C以上且未達前述特殊水的沸點 之間。本發明之特徵係使前述鋁成爲粉末，使前述容器內 的溫度成爲80°C以上且未達前述特殊水的沸點使其產生氫 ’而使前述特殊水成爲鹼性（鹼性特殊水），將新的鋁粉 末供應至前述容器內之鹼性特殊水中，無加熱手段的加熱 下將前述容器內的溫度保持在80 °C以上且未達前述特殊水 的沸點之間，使其產生氫。本發明之特徵爲於前述容器內 的溫度爲30 °C以上且未達80t時，藉由加熱手段使前述容 器內的溫度繼續上升。本發明之特徵係前述離子交換樹脂 爲強酸性陽離子交換樹脂（RzS03Na)。本發明之特徵係 於生成前述特殊水用的電氣石中，混合鋁、不銹鋼、銀的 至少1種類之金屬。本發明之特徵係前述流紋岩爲由黑曜 石、真珠岩、松脂岩中的至少1個所成的岩石。本發明之 特徵係對前述特殊水100重量而言，前述鋁爲5重量以上。 本發明之特徵係前述鋁的重量爲1〇重量以上。本發明之特 徵係使在前述特殊水中加有氫氧化鈉的氫氧化鈉水溶液於 201132582 前述容器內與鋁接觸。本發明之特徵係不用由前述容器的 外部來加熱之加熱手段，而藉由前述氫氧化鈉水溶液與前 述鋁的反應熱，使前述容器內的溫度成爲30°C以上。本發 明之特徵係藉由氫氧化鈉水溶液與前述鋁的反應熱，而使 前述容器內的溫度成爲8 0°C以上。本發明之特徵係前述氫 氧化鈉水溶液中的氫氧化鈉之濃度爲〇. 1 %以上。本發明之 特徵係前述氫氧化鈉之濃度爲3 %以上。本發明之特徵係於 前述容器的底處具備前述鋁，前述氫氧化鈉水溶液的液面 係在比該鋁的最上位還上位。 爲了達成上述目的，本發明的氫之製造裝置之特徵係 具有： 使水最初通過離子交換樹脂，然後使先通過電氣石與 由流紋岩或花崗岩的至少1個所成之含有65〜76%的二氧化 矽之岩石的任一方，之後通過另一方，而使所生成的特殊 水成爲鹼性者（鹼性特殊水）、 收納鋁用的容器、 於前述容器中投入鋁用的鋁投入手段、 將由前述鋁投入手段投入前述容器內的鋁載置於其上 同時使前述鋁溶化的殘留物經由網目落下在前述容器的下 方者，其係配置在比前述容器的底部還高位的網構件、 與前述容器的內部連絡者，其係將鹼性特殊水導入前 述容器內同時由前述容器內排出該鹼性特殊水用之液體循 環通路、 在前述液體循環通路的途中所具備者，其係對前述容 -8 - 201132582 器內供給前述鹼性特殊水用之液體投入手段' 在前述液體循環通路的途中所具備者，其係由前述容 器內取出前述鹼性特殊水用之液體取出手段' 在前述液體循環通路的途中所具備者，其係捕捉由前 述容器內所取出的前述鹼性特殊水連同所取出的殘留物用 之殘留物捕捉手段、 在前述液體循環通路的途中所具備者，其係對前述液 體投入手段供給前述鹼性特殊水同時收納由液體取出手段 所取出之前述鹼性特殊水用之槽。 本發明之特徵爲前述液體取出手段係由在接近自前述 容器排出前述鹼性特殊水之位置之側所具備的第1泵及第1 閥所構成，前述液體投入手段係由在接近將前述鹼性特殊 水導入前述容器中之側所具備的第2泵及第2閥與槽所構成 ’在前述液體循環通路的途中之前述第1泵的上游側具備 前述殘留物捕捉手段，在前述第1泵的下游側具備前述槽 °本發明之特徵爲前述鹼性特殊水之特殊水係藉由使前述 特殊水與鋁在容器內以溫度成爲3(TC以上而使其產生氫所 &成者。本發明之特徵爲前述鹼性特殊水之特殊水係在前 述特殊水中混合氫氧化鈉而使氫氧化鈉的濃度成爲〇. 1 %以 上者。本發明之特徵係前述氫氧化鈉的濃度爲3 %以上。 發明的效果 本發明的氫之製造方法的申請專利範圍第1項所使用 的材料，係僅使用市售的鋁與特殊水（創生水）之2種材 -9 - 201132582 料’使容器內的溫度成爲3 0 °C以上而使彼等產生氫。於本 發明中’作爲材料，即使沒有以化學劑或鋁以外的金屬當 作主要材料’也可僅使用鋁與特殊水（創生水），以非常 廉價的成本來製造氫。 本發明所使用的特殊水係大量含有氫氧離子（Η302· )或氫氧化離子（〇『）或氫離子（η+)等的氫原子者。 鋁由於是電極兩性元素，推測若特殊水成爲3 〇艺以上的溫 度’則在鋁上出現許多的正電極與負電極.，該正電極與負 電極係產生微弱電流而促進容器內的特殊水之電性分解， 由特殊水產生大量的氫。再者，由於自特殊水產生氫的時 間長，故可產生大量的氫。由此推測本發明是否具有藉由 特殊水中所含有的氫氧離子（Η302·)來延遲在鋁的表面 上結膜之效果。 於本發明中，當使特殊水與鋁在容器內接觸而產生氫 時，由於容器的加熱溫度係3 0°C以上且未達特殊水的沸點 ，故可在大氣壓下完成容器的加熱。由於是大氣壓下的加 熱，故不需要如以往之水的熱分解之3,000°C〜5,000°C般 的特別裝置，可用便宜且簡單的裝置使產生氫。當使用加 熱手段來加熱容器內的鋁與創生水時，可藉由加熱的停止 來停止氫的產生。因此，可快速地進行氫的產生與停止， 可應用於以氫爲燃料所使用的各種裝置。 一旦將裝有特殊水與鋁的容器加熱至8 〇°C以上而使產 生氫後，若使新的鋁接觸（若置入容器內）該特殊水’則 藉由產生氫後的特殊水與新的鋁之接觸’即使沒有以加熱 -10- 201132582 手段來加熱，容器內的溫度也保持在8 (TC以上，而繼續產 生氫。由於即使不用加熱手段也繼續產生氫，可節省加熱 所花費的燃料成本。中性的特殊水係在與鋁反應而產生一 部分的氫後，特殊水成爲鹼性，即使沒有進行加熱手段的 加熱，此容器內的鹼性特殊水也與新添加的鋁反應，將容 器內的溫度保持在以上，氫繼續產生。再者，當鋁爲 粉末時，所產生的氫量係大幅增加。 將鋁置入容器的底處，以創生水（或後述的氫氧化鈉 水溶液）覆蓋鋁的最上位置。即，若將鋁浸漬於創生水或 氫氧化鈉水溶液中，則可藉由創生水中所含有的氫氧離子 (Η3 02·)來延遲氧化被膜在鋁之表面上的產生，可延長 氫的產生時間。 亦可僅代替特殊水，使用在特殊水中混合有氫氧化鈉 的氫氧化鈉水溶液。當使用在特殊水中混合有氫氧化鈉的 氫氧化鈉水溶液時，由於氫氧化鈉水溶液與鋁在容器內接 觸而產生反應熱。該反應熱係可藉由自己升溫而使容器內 的溫度成爲3 (TC以上，即使不用由容器的外部來加熱之加 熱手段，也可在容器內產生氫。藉由鋁與氫氧化鈉水溶液 的反應熱，容器內的溫度係成爲氫更大量產生的80°C以上 ，故亦可適用於欲大量產生氫的情況。以往之由容器的外 部來加熱之加熱手段的溫度係600 °C〜5, 〇〇〇 °C，需要昂貴 的設備，但於本發明中可省略由容器的外部來加熱之加熱 手段，僅使用在特殊水中加有氫氧化鈉的氫氧化鈉水溶液 與鋁，可以低成本製造氫。本發明係藉由反應熱的自己升 -11 - 201132582 溫而產生氫者，由於不用由容器的外部來施加火或電熱的 加熱手段，故此氫產生方法的裝置係可搭載於汽車等。 於本發明的氫之製造方法中，藉由使用在特殊水中混 合有氫氧化鈉的氫氧化鈉水溶液，與僅特殊水的情況相比 ，可增加氫的產生量，同時可大幅減少氧的產生量。當極 度降低氧的產生比率時，可使含有氫與氧的氣體中分離氧 對方法成爲簡單者，可減低氫的製造成本。 於本發明的氫產生裝置中，使用不用加熱手段而僅使 與鋁接觸也產生氫的鹼性特殊水。作爲僅與鋁接觸也產生 氫的水，使用使特殊水與鋁接觸，一旦加熱至8 (TC以上而 產生氫後的水（成爲鹼性），或混合有特殊水與氫氧化鈉 的氫氧化鈉水溶液之任一者。於收納鹼性特殊水與鋁用的 容器內，收納承載鋁用的載置構件，將該載置構件配置在 容器內，以使其成爲容器內之底面的上方。載置構件上的 鋁係藉由與鹼性特殊水反應而溶化成爲極小的粒或或糊狀 的渣，通過網構件的網目落下至下方，作爲殘留物蓄積在 容器內的底部。藉由設置在容器的下部連絡液體循環通路 ，在該液體循環通路之途中由容器內排出殘留物的液體取 出手段，及捕捉由容器內所排出的殘留物用之殘留物捕捉 手段，以及供應鹼性特殊水或氫氧化鈉水溶液至容器內的 液體投入手段，可藉由鹼性特殊水的循環而使該容器內所 蓄積的鋁之殘留物自動地排出到外部，同時隨時對容器內 供給鹼性特殊水。於此裝置中，若使用在不打開容器的蓋 子下隨時可供應鋁已知之鋁投入手段，則可在不打開容器 -12- 201132582 下進行鋁的投入與自容器內排出殘留物，可繼續地產生氫 。由於可繼續地產生氫，故可適用於長時間驅動的汽車等 【實施方式】 實施發明的形態 本發明的氫之製造方法係藉由使特殊水與鋁在指定的 溫度範圍內（3 0°C以上且未達特殊水的沸點未達）接觸而 產生氫。 於說明本發明的氫之製造方法之前，首先，對於本發 明所使用的特殊水（以下稱爲「創生水」），以圖1至圖3 爲基礎來說明。圖1係顯示創生水的製造裝置之一實施例 的構成圖。經由連絡管1 8 a、1 8 b、1 8 c，依順序串聯連接 第一軟水生成器10、第二軟水生成器12、離子生成器14與 岩石收納器1 6。於第一軟水生成器1 0中，例如將具有如自 來水管之壓力的水從自水供給管20經由連絡管22導入內部 。於水供給管2 〇與連絡管2 2之間具備如水龍頭的入口用開 關閥2 4，於連絡管2 2的途中具備止回閥2 6。於岩石收納器 16的出口側安裝吐出管28，於吐出管28的前端或途中具備 出口用開關閥3 0。 當爲自來水時’由水供給管20所送出的水係依順序經 過第一軟水生成器1〇、第二軟水生成器12、離子生成器14 與岩石收納器1 6，藉由打開出口用開關閥3 〇而由吐出管2 8 取出。當爲自來水以外時，雖然未圖示，但可藉由泵將水 -13- 201132582 槽中所積存的水經由水供給管2 0導入至第一軟水生成器1 0 。此時，於泵與第一軟水生成器10之間具備止回閥26。 第一軟水生成器10與第二軟水生成器12係在其內部大 量收納粒狀的離子交換樹脂32，圖2中顯示其截面圖。軟 水生成器10、12的本體3 4係筒狀，於該筒狀的上下端面具 有水的出入口 36a、36b。於筒狀本體34的內部，在與上下 的端面有稍微距離的位置之內壁，各自具備在中央有開孔 的遮擋構件38a、38b。於該一對遮擋構件38a、3 8b之間， 以收進細網40的狀態來收納離子交換樹脂32。於與上下的 出入口 36a、3 6b有稍微距離的位置之內壁，具備中央有開 孔的遮擋構件38者，係將裝有離子交換樹脂32的網40配置 在一對遮擋構件38之間，以便在出入口 36a、36b附近形成 空間42a、42b。又，使水由遮擋構件38a、38b的中央之孔 出入者，係爲了使水必然與離子交換樹脂32接觸。網40裝 有離子交換樹脂32者，係在爲了洗淨粒狀的離子交換樹脂 3 2而取出時，連同網40—起取出粒狀的離子交換樹脂32。 第一軟水生成器10與第二軟水生成器12例如其高度爲 8 0 cm，內徑爲10cm。而且，例如離子交換樹脂32的收納 高度爲70cm (於上下有空間42a、42b的存在）。此時，離 子交換樹脂32的收納高度必須是在水中能充分進行離子交 換的高度。另一方面，離子交換樹脂32的收納高度若過高 (例如離子交換樹脂32的收納高度約200cm以上），則離 子交換樹脂32成爲水的阻力，通過軟水生成器之內部的流 量減少，故離子交換樹脂3 2的收納高度較佳爲不使流量減 -14- 201132582 少的高度。將收納離子交換樹脂3 2的容器分成2個者，係 爲了將第一軟水生成器10或第二軟水生成器12的高度壓低 到與離子生成器14或岩石收納器16相同程度的高度，而且 爲了避免通過該處的水之壓力損失導致流量減少。又，亦 可將2個軟水生成器1〇、12彙總成1個，而成爲1個軟水生 成器。 離子交換樹脂32係用於去除水中所含有Ca2 +或Mg2 +或 Fe2 +等的金屬離子，以使水成爲軟水，尤其是用於使水的 硬度成爲接近零的程度。作爲離子交換樹脂3 2，例如使用 苯乙烯·二乙烯基苯的球狀共聚物經均勻磺化的強酸性陽 離子交換樹脂（RzS03Na )。此離子交換樹脂32係與水中 所含有Ca2 +或Mg2 +或Fe2 +等的金屬離子發生以下的離子交 換反應。 2RzS03Na + Ca2+ ^ ( RzS03 ) 2Ca + 2Na + 2RzS03Na + Mg2+ — ( RzS03 ) 2Mg + 2Na + 2RzS03Na + Fe2+ -> ( RzS03 ) 2Fe + 2Na + 即，藉由通過離子交換樹脂32，可去除水中所含有的 Ca2 +或Mg2 +或Fe2 +等。藉由使用強酸性陽離子交換樹脂（ RzS03Na )當作離子交換樹脂32，而產生鈉離子（Na+ ) 。作爲離子交換樹脂3 2 ’亦可產生N a+以外者’產生N a+者 例如宜使用強酸性陽離子交換樹脂（RzS03Na )。水若爲 自來水，則該自來水中除了含有Ca2 +或Mg2 +或Fe2 +等的金 屬離子，還含有氯’但藉由使自來水通過離子交換樹脂32 ，此氯係完全沒有發生變化。 -15- 201132582 另一方面，藉由使水（H20 )通過離子交換樹脂32 ’ 發生如以下的變化。 H20 — H + + OH- ...... ( 1 ) H20 + H + — H30+ ...... ( 2 ) 即，如（1) (2)所示，藉由通過離子交換樹脂32’ 由水產生氫氧化離子（〇Η·)與水合氫離子（H30+)。 如此地，當水爲硬水時，藉由通過離子交換樹脂3 2 ’ 由水去除Ca2 +或Mg2 +或Fe2 +等的金屬離子而成爲軟水。又 ，藉由通過離子交換樹脂32，在水中產生Na +與OH·和水合 氫離子（H30+)。然而，自來水中所含有的氯（C1 )係不 離子化而照原樣通過。 其次，圖3中顯示前述離子生成器14的部分截面圖。 離子生成器1 4係複數個筒匣44以同樣配置而上下連續地串 聯連結者。於各筒匣44的內部中收納僅粒狀的電氣石46或 粒狀的電氣石46與板狀的金屬48之混合物的任一者。電氣 石由於具有正電極與負電極，藉由該正電極與負電極，使 在水中具有4〜14微米波長的電磁波，而且切斷水的團簇 ，使產生水合氫離子（H30+)。具有該4〜14微米波長的 電磁波之能量係0.004watt/cm2。此處，所謂的電氣石46， 係可爲電氣石經細碎者，也可爲電氣石與陶瓷和氧化鋁（ 亦有含銀者）的重量比以約1〇:8〇:1〇所市售的稱爲電氣石 九粒的電氣石混合物。此電氣石九粒中所含有陶瓷係具有 分離正電極與負電極之作用。此處，可對於陶瓷而言以重 量比1 0 %以上的比例混合電氣石4 6，在8 0 0。(：以上加熱，可 -16- 201132582 製作經由水的攪拌在指定的期間（例如直徑4mm係約3個 月）消滅的電氣石Μ。電氣石46係藉由加熱而增加強度， 可增長耐磨滅期間。通過離子交換樹脂3 2而使水成爲硬度 接近零的軟水，在軟水中磨合電氣石46彼此。於硬度接近 零的軟水中，可防止鎂離子或鈣離子附著於電氣石46的負 電極，可防止電氣石46的正與負電極之作用的降低。 作爲前述金屬’使用鋁、不銹鋼、銀的至少1種類 之金屬。作爲此金屬48 ’宜爲在水中不生錄或不溶於水的 金屬。於此金屬之中’錯具有殺菌作用或抗菌作用連同 漂白作用，不銹鋼具有殺菌作用或抗菌作用連同洗淨提高 作用，銀具有殺菌作用或抗菌作用。作爲金屬48，不能採 用銅或給，因爲具有毒性。又’金等高價的材料從成本上 來看亦無法採用。前述電氣石46與金屬48的重量比宜爲 1 0 : 1〜1 : 1 0。若超過該範圍’則一方的材料變過多，無法 同時發揮兩方的材料之效果。 同厘44係成爲一開放的同狀，在其底面50設有多數 的孔52。於筒匣44的內部裝入電氣石46與金屬48時，以電 氣石46或金屬48不通過底面50的孔52之方式，設定孔52的 大小。如圖3所示，各筒匣4 4係以設有多數的孔5 2之底面 50爲下側，在底面50上載置電氣石46或金屬48。然後，設 定各筒匣44的內部，以使得由下位往上位流動。即，於各 筒匣44中，已通過底面50的多數孔52之水係設定成由下往 上噴射到電氣石46與金屬48。此處，由於自來水具有高的 水壓，故具有該水壓的水係強勢地衝撞筒匣44內的電氣石 -17- 201132582 46與金屬48，設定孔52的大小及個數，以藉由該水的力量 而將電氣石46與金屬48在筒匣44內攪拌。將水噴射到電氣 石而攪拌電氣石者，係爲了藉由該攪拌而在電氣石與水之 間發生摩擦，由電氣石將正與負電極溶出到水中而切斷水 的團簇，使大量產生水合氫離子（h3o+)。 作爲實際的設置例，重疊4段具有內徑5cm且深度爲 7cm的容納容積之筒匣44，於該筒匣44內充分收納電氣石 46與金屬48，但電氣石46與金屬48之份量爲在筒匣44內藉 由水的力量可自由移動者。可增減筒匣44的段數，也可成 爲加大容納容積的1個筒匣44。如此地，使電氣石46與金 屬48分散於已縮小容納容積的複數之筒匣44，連接彼等複 數的筒匣44，可藉由水的力量而提高電氣石46與金屬48的 攪拌效率。收納於筒匣44內的電氣石46，由於溶於水而在 數個月消滅，故各筒匣44例如可藉由螺合等的手而容易裝 卸，可在各筒匣44內容易地補充電氣石46。再者，金屬48 由於不溶於水而不需要補充，但亦可更換裝有電氣石46與 金屬48的筒匣44全體。筒匣44亦可按照所使用的流量之大 小來改變其容納容積。 爲了增加對通過筒匣44的水所施加的負離子，藉由電 氣石46彼此的磨合而產生正電極與負電極，藉由水接觸該 電氣石46，可達成負離子的增加。又，爲了切斷水的團簇 ’使大量地產生水合氫離子（H30+ )，亦可在筒匣44內僅 收納電氣石46。然而，藉由使金屬48與電氣石46混合，彼 等係接觸會合可更增加電氣石46中所產生的負離子。 -18 - 201132582 電氣石46中由於具有正電極與負電極，故若以水來攪 拌電氣石，則水（H20 )係解離成氫離子（H+ )與氫氧化 離子（〇Η·)。 H20 — H+ + OH- ...... ( 1 ) 再者，藉由氫離子（H+)與水（H20)，產生具有界 面活性作用的水合氫離子（H30+ )。此水合氫離子（H30 + )之產生量係遠多於前述離子交換樹脂32所產生的量之量 〇 Η 2 〇 + Η + ·~> Η 3 Ο + ...... (2) 此水合氫離子（Η3ο+)的一部分係與水（η2ο)結合 —體而成爲氫氧離子（Η302·)與氫離子（Η+)。 Η30+ + Η2〇 — H302- + 2Η+ ...... ( 3) 使已通過離子交換樹脂32的水通過離子生成器14，而 在水的內部產生水合氫離子（H3〇+)與氫氧離子（h3〇2_ )和H +與OPT。再者，已通過離子交換樹脂32的氯（Cl ) 與在離子交換樹脂32所產生的Na+係不反應，而就那樣地 通過離子生成器14。 使已通過離子生成器14的水接著通過岩石收納器16的 內部，該岩石收納器收納火成岩中之含有許多二氧化矽的 岩石（含有約65〜76%二氧化矽的岩石）54。作爲火成岩 (分爲火山岩與深成岩）中之含有許多二氧化矽的岩石54 ’在火山岩中有黑曜石或真珠岩或松脂岩等的流紋岩，在 深成岩中有花崗岩。於岩石收納器1 6的內部，收納黑曜石 ，真珠岩，松脂岩，花崗岩的岩石中至少1種類以上的岩 -19- 201132582 石。黑曜石或真珠岩或松脂岩等的流紋岩、或花崗岩係帶 負電子。再者，黑曜石或真珠岩或松脂岩等的流紋岩或花 崗岩係酸性岩。流紋岩係具有與花崗岩相同的化學組成者 〇 此等火成岩中之含有的65〜76%二氧化矽的岩石（黑 曜石或真珠岩或松脂岩等的流紋岩、或花崗岩等的深成岩 )係在原石的狀態下具有-20〜-240mV氧化還原電位。但 是，岩石54係去除溶於水者。岩石收納器1 6例如是內徑爲 10cm、高度爲80cm的筒，其內部例如是以不減低水的通 過流量之程度的量，容納5mm〜50mm粒左右的大小之火成 岩中的含有許多二氧化矽的岩石54。 於此岩石收納器16的內部，若使已通過離子生成器14 的水通過，則在水中增加〆（負電子）。結果，自來水中 所含有的氯（C1)係藉由負電子而成爲氯離子。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hydrogen production method and a hydrogen production apparatus using hydrogen and aluminum to produce hydrogen. [Prior Art] It has been known to use hydrogen as a fuel gas. Many inventions have been provided as a manufacturing method for producing hydrogen. For example, a method of thermally decomposing 100% of water to obtain hydrogen is known, or an Isine-Sulfe method in which sulfuric acid is thermally decomposed, and iodine water is used to take out hydrogen. The IS method is obtained by decomposing hydrogen and oxygen from water by three steps of the primary reaction step, the iodide hydrogen concentration decomposition step, and the sulfuric acid concentration decomposition step (Patent Document 1). Further, a method of decomposing water in which metal zinc is reacted with magnetite to generate hydrogen as a reaction product is known (Patent Document 2). A method for producing hydrogen which generates hydrogen by contacting aluminum or magnesium with water is known (Patent Document 3). PRIOR ART DOCUMENT Patent Document Patent Document 1: JP-A-2005-4 1 764 Patent Document 2: JP-A-2001-270701 Patent Document 3: JP-A-2007-290888 SUMMARY OF THE INVENTION Problems to be Solved by the Invention-5-201132582 In the method in which 100% of water is thermally decomposed to obtain hydrogen, water is said to be incapable of being decomposed into hydrogen and oxygen by theoretically not giving a temperature of 3,000 ° C to 5000 ° C due to strong hydrogen and oxygen. In the method of thermally decomposing water at a temperature of 3,000 ° C or higher to obtain hydrogen, a method of substantially obtaining a high temperature of 3,000 ° C or higher is not obtained, or it cannot be inexpensively produced for maintaining such a high temperature state. The means for isolating the space from the outside, or the means for continuously supplying water to a space at a high temperature, and many other problems include a problem that the formation of a hydrogen system by thermal decomposition of water is not realized. In the IS method disclosed in Patent Document 1, since high heat of about 900 °C is required, it is necessary to use a high-temperature gas furnace or the like as a heat source. This high-temperature gas furnace system is inherently high, and after three steps to produce hydrogen, the cost of producing hydrogen is very high. In the method for decomposing water according to Patent Document 2, metal zinc and magnetite are reacted with steam at 600 ° C to produce hydrogen, and it is necessary to provide a heating means for producing 6 〇 (water vapor of TC). In the method for producing water shown in Document 3, unfrozen water having a pH of 4-1 〇 is used as water, and hydrogen is generated even below 〇 ° C. In Patent Document 3, aluminum and water are used. The reaction produces hydrogen, but since it is reacted at a low temperature of 0 ° C or lower, hydrogen is not generated in a large amount at a low temperature, and hydrogen cannot be produced with high economic efficiency. The object of the present invention is to provide a special water and aluminum. A method for producing hydrogen which can be hydrogenated by contact, and a hydrogen producing apparatus which can be used for efficiently producing hydrogen by bringing special water into contact with aluminum. 201132582 Means for Solving the Problem The method for producing hydrogen according to the present invention is characterized by: The water is initially passed through an ion exchange resin and then passed through either the tourmaline and at least one of the rock containing 65 to 76% ceria formed by rhyolite or granite, and then passed through the other side. Water for special water By placing the special water and aluminum in a container and bringing them into contact with each other in the container, the temperature in the container is 30° C. or higher and the boiling point of the special water is not reached, so that the special water is made. Reacting with the aforementioned aluminum to generate hydrogen. The present invention is characterized in that the temperature in the container is maintained above 80 ° C and does not reach the boiling point of the special water. The invention is characterized in that the aluminum is powdered into the container. The temperature is 80 ° C or higher and does not reach the boiling point of the special water to generate hydrogen ', and the special water is made alkaline (alkaline special water), and the new aluminum powder is supplied to the alkaline special water in the aforementioned container. The temperature in the container is maintained at 80 ° C or higher and does not reach the boiling point of the special water under heating without heating means to generate hydrogen. The present invention is characterized in that the temperature in the container is 30 ° C. When the temperature is less than 80t, the temperature in the container is further increased by heating means. The present invention is characterized in that the ion exchange resin is a strongly acidic cation exchange resin (RzS03Na). In the tourmaline for producing the special water, at least one type of metal of aluminum, stainless steel, and silver is mixed. The present invention is characterized in that the rhyolite is formed of at least one of obsidian, nacre, and rosin. The present invention is characterized in that the aluminum is 5 or more by weight based on 100 parts by weight of the special water. The present invention is characterized in that the weight of the aluminum is 1 重量 or more. The present invention is characterized in that the special water is added The sodium hydroxide aqueous solution of sodium hydroxide is contacted with aluminum in the aforementioned container in 201132582. The present invention is characterized in that the heating means for heating by the outside of the container is not used, and the heat of reaction of the aqueous sodium hydroxide solution with the aluminum is used. The temperature in the container is 30 ° C or higher. The present invention is characterized in that the temperature in the container is 80 ° C or higher by the heat of reaction between the aqueous sodium hydroxide solution and the aluminum. The present invention is characterized in that the concentration of sodium hydroxide in the aqueous sodium hydroxide solution is 0.1% or more. The present invention is characterized in that the concentration of the above sodium hydroxide is 3% or more. The present invention is characterized in that the aluminum is provided at the bottom of the container, and the liquid surface of the aqueous sodium hydroxide solution is higher than the uppermost position of the aluminum. In order to achieve the above object, the apparatus for producing hydrogen of the present invention is characterized in that: water is initially passed through an ion exchange resin, and then 65 to 76% is formed by first contacting tourmaline with at least one of rhyolite or granite. One of the rocks of the cerium oxide, and then the other water is used to make the special water to be alkaline (alkaline special water), a container for accommodating aluminum, an aluminum input means for introducing aluminum into the container, The aluminum which is put into the container by the aluminum input means is placed thereon, and the residue in which the aluminum is melted is dropped under the container through the mesh, and is disposed at a position higher than the bottom of the container, and The internal contact person of the container is configured to introduce the alkaline special water into the container while discharging the liquid circulation passage for the alkaline special water from the container, and the refrigerant circulation passage is provided in the middle of the liquid circulation passage.容-8 - 201132582 The liquid supply means for supplying the alkaline special water in the device is provided in the middle of the liquid circulation path. The liquid extraction means for taking out the alkaline special water in the container is provided in the middle of the liquid circulation path, and captures the residual alkali water taken out from the container together with the residue remaining The object capturing means, which is provided in the middle of the liquid circulation path, supplies the alkaline special water to the liquid input means and accommodates the tank for the alkaline special water taken out by the liquid take-out means. The present invention is characterized in that the liquid take-out means is constituted by a first pump and a first valve provided on a side close to a position at which the alkaline specific water is discharged from the container, and the liquid input means is such that the alkali is approached The second pump and the second valve and the groove provided in the side of the container are provided with the residue capturing means on the upstream side of the first pump in the middle of the liquid circulation path, and the first The downstream side of the pump is provided with the above-mentioned groove. The special water system of the present invention is characterized in that the special water and the aluminum are caused to have a temperature of 3 (TC or more in the container to generate hydrogen & The present invention is characterized in that the special water of the alkaline special water is mixed with sodium hydroxide in the special water to make the concentration of sodium hydroxide 〇. 1% or more. The present invention is characterized in that the concentration of the sodium hydroxide is 3% or more. Effect of the Invention The material used in the first aspect of the patent application method of the hydrogen production method of the present invention is only one of commercially available aluminum and special water (created water) - 9 - 201132582 The temperature in the container is set to 30 ° C or higher to cause hydrogen to be generated. In the present invention, as the material, even if no metal other than a chemical agent or aluminum is used as the main material, only aluminum and special water may be used ( Chuangsheng Water), which produces hydrogen at a very low cost. The special water system used in the present invention contains a large number of hydrogen atoms such as hydroxide ions (Η302·) or hydroxide ions (〇『) or hydrogen ions (η+). Since aluminum is an elemental element of the electrode, it is presumed that if the special water becomes a temperature above 3 〇, then many positive and negative electrodes appear on the aluminum. The positive and negative electrodes generate a weak current and promote the inside of the container. The electric decomposition of special water produces a large amount of hydrogen from special water. Furthermore, since hydrogen is generated from special water for a long time, a large amount of hydrogen can be generated. It is therefore presumed whether the present invention has hydrogen contained in a special water. Oxygen ions (Η302·) to delay the effect of conjunctiva on the surface of aluminum. In the present invention, when special water is brought into contact with aluminum in the container to generate hydrogen, since the heating temperature of the container is above 30 ° C and not Da The boiling point of the water is sufficient, so that the heating of the container can be completed under atmospheric pressure. Since it is heated under atmospheric pressure, a special device such as 3,000 ° C to 5,000 ° C which is thermally decomposed by conventional water is not required, and it can be used inexpensively and simply. The device generates hydrogen. When the heating means is used to heat the aluminum and the creation water in the container, the generation of hydrogen can be stopped by the stop of the heating. Therefore, the generation and the stop of hydrogen can be quickly performed, and the hydrogen can be applied to hydrogen. Various devices used for fuel. Once the container containing special water and aluminum is heated to above 8 °C to produce hydrogen, if new aluminum is contacted (if placed in a container), the special water will be borrowed. The contact between the special water after hydrogen generation and the new aluminum 'even if it is not heated by means of heating -10-201132582, the temperature inside the vessel is maintained at 8 (TC or more, and hydrogen continues to be produced. Since the hydrogen is continuously generated even without heating means, the fuel cost for heating can be saved. The neutral special water system reacts with aluminum to generate a part of hydrogen, and the special water becomes alkaline. Even if the heating is not performed, the alkaline special water in the container is reacted with the newly added aluminum to be in the container. The temperature remains above and hydrogen continues to be produced. Further, when aluminum is a powder, the amount of hydrogen generated is greatly increased. The aluminum is placed in the bottom of the container, and the uppermost position of the aluminum is covered with the creation water (or an aqueous sodium hydroxide solution described later). That is, if aluminum is immersed in the creation water or the aqueous sodium hydroxide solution, the generation of the oxide film on the surface of the aluminum can be delayed by the hydroxide ions (Η3 02·) contained in the creation water, and the hydrogen can be prolonged. The time of production. It is also possible to use only an aqueous sodium hydroxide solution in which sodium hydroxide is mixed in a special water instead of the special water. When an aqueous sodium hydroxide solution in which sodium hydroxide is mixed in a special water is used, heat of reaction occurs due to contact of the aqueous sodium hydroxide solution with aluminum in the container. The heat of reaction can be set to 3 (TC or more) by heating itself, and hydrogen can be generated in the container even without heating means heated by the outside of the container. By aluminum and sodium hydroxide aqueous solution The reaction heat is high, and the temperature in the container is 80 ° C or more which is generated by a larger amount of hydrogen. Therefore, it is also applicable to a case where a large amount of hydrogen is to be generated. The temperature of the heating means conventionally heated from the outside of the container is 600 ° C to 5 ° 〇〇〇 ° C, expensive equipment is required, but in the present invention, the heating means for heating from the outside of the container can be omitted, and only the sodium hydroxide aqueous solution and aluminum with sodium hydroxide added to the special water can be used at low cost. In the present invention, hydrogen is produced by the temperature of the reaction heat rising from -11 to 201132582, and since the heating means for applying heat or electric heat from the outside of the container is not required, the device for generating the hydrogen can be mounted on a car or the like. In the method for producing hydrogen of the present invention, by using an aqueous sodium hydroxide solution in which sodium hydroxide is mixed in a special water, hydrogen generation can be increased as compared with the case of only special water. At the same time, the amount of oxygen generated can be greatly reduced. When the oxygen generation ratio is extremely lowered, the method of separating oxygen in a gas containing hydrogen and oxygen can be simplified, and the manufacturing cost of hydrogen can be reduced. In the case of using a non-heating means, only a special alkaline water which generates hydrogen by contact with aluminum is used. As a water which generates hydrogen only in contact with aluminum, special water is used in contact with aluminum, and when heated to 8 (TC or more, hydrogen is generated. Any one of the following water (basic) or an aqueous solution of sodium hydroxide mixed with special water and sodium hydroxide. The container for carrying aluminum is housed in a container for storing alkaline special water and aluminum. The mounting member is placed in the container so as to be above the bottom surface of the container. The aluminum on the mounting member is melted into extremely small particles or paste-like slag by reacting with the alkaline specific water. The mesh of the mesh member is dropped to the lower side and accumulates as a residue in the bottom of the container. The liquid circulation path is connected at the lower portion of the container, and the residue is discharged from the container on the way of the liquid circulation path. The liquid take-out means, the means for capturing the residue for capturing the residue discharged from the container, and the liquid supply means for supplying the alkaline special water or the aqueous sodium hydroxide solution into the container, which can be circulated by the alkaline special water The residue of aluminum accumulated in the container is automatically discharged to the outside, and alkaline special water is supplied to the container at any time. In this device, aluminum can be supplied at any time without opening the lid of the container. By means of the input means, the aluminum can be injected and the residue can be discharged from the container without opening the container -12-201132582, and hydrogen can be continuously generated. Since hydrogen can be continuously generated, it can be applied to a car that is driven for a long time. BEST MODE FOR CARRYING OUT THE INVENTION The method for producing hydrogen according to the present invention generates hydrogen by bringing special water into contact with aluminum in a predetermined temperature range (at 30 ° C or higher and not reaching the boiling point of special water). Before describing the method for producing hydrogen according to the present invention, first, the special water (hereinafter referred to as "creative water") used in the present invention will be described based on Figs. 1 to 3 . Fig. 1 is a view showing the configuration of an embodiment of a manufacturing apparatus for creating water. The first soft water generator 10, the second soft water generator 12, the ion generator 14, and the rock receiver 16 are connected in series via the connecting tubes 1 8 a, 1 8 b, and 18 c. In the first soft water generator 10, for example, water having a pressure such as a water pipe is introduced into the inside from the water supply pipe 20 via the connection pipe 22. An inlet switching valve 24 such as a faucet is provided between the water supply pipe 2 and the connection pipe 22, and a check valve 26 is provided in the middle of the connection pipe 22. The discharge pipe 28 is attached to the outlet side of the rock receiver 16, and the outlet switching valve 30 is provided at the front end or the middle of the discharge pipe 28. When it is tap water, the water sent from the water supply pipe 20 passes through the first soft water generator 1 〇, the second soft water generator 12, the ion generator 14 and the rock hopper 1 6 in order, by opening the outlet switch. The valve 3 is removed and taken out by the discharge tube 28. When it is other than tap water, although it is not shown, the water accumulated in the tank of water -13-201132582 can be introduced into the 1st soft water generator 10 by the water supply pipe 20 by the pump. At this time, a check valve 26 is provided between the pump and the first soft water generator 10. The first soft water generator 10 and the second soft water generator 12 house a large amount of granular ion exchange resin 32 therein, and a cross-sectional view thereof is shown in Fig. 2 . The main bodies 34 of the soft water generators 10 and 12 are cylindrical, and water inlets and outlets 36a and 36b are formed on the upper and lower ends of the cylindrical shape. Inside the cylindrical body 34, the inner walls at positions slightly spaced apart from the upper and lower end faces each have shielding members 38a and 38b having openings at the center. The ion exchange resin 32 is housed between the pair of shutter members 38a and 38b in a state in which the fine mesh 40 is received. The inner wall having a position slightly spaced from the upper and lower inlets and outlets 36a and 36b is provided with a shutter member 38 having an opening at the center, and the net 40 containing the ion exchange resin 32 is disposed between the pair of shielding members 38. In order to form spaces 42a, 42b near the entrances and exits 36a, 36b. Further, the water is made to pass through the hole in the center of the shielding members 38a and 38b in order to bring the water into contact with the ion exchange resin 32 inevitably. When the mesh 40 is equipped with the ion exchange resin 32, the particulate ion exchange resin 32 is taken out together with the net 40 when it is taken out for washing the granular ion exchange resin 32. The first soft water generator 10 and the second soft water generator 12 have, for example, a height of 80 cm and an inner diameter of 10 cm. Further, for example, the ion exchange resin 32 has a storage height of 70 cm (there are spaces 42a and 42b in the upper and lower sides). At this time, the storage height of the ion exchange resin 32 must be a height at which ion exchange can be sufficiently performed in water. On the other hand, if the storage height of the ion exchange resin 32 is too high (for example, the storage height of the ion exchange resin 32 is about 200 cm or more), the ion exchange resin 32 becomes a resistance to water, and the flow rate inside the soft water generator is reduced, so that the ion is reduced. The storage height of the exchange resin 3 2 is preferably such a height that the flow rate is not reduced by -14,32,582. The container for accommodating the ion exchange resin 32 is divided into two in order to lower the height of the first soft water generator 10 or the second soft water generator 12 to the same level as the ion generator 14 or the rock container 16, and In order to avoid pressure loss of water passing therethrough, the flow rate is reduced. Further, two soft water generators 1 and 12 may be combined into one, and one soft water generator may be used. The ion exchange resin 32 is used to remove metal ions such as Ca2+ or Mg2+ or Fe2+ in water to make water soft water, and particularly to make the hardness of water close to zero. As the ion exchange resin 32, for example, a strongly acidic cation exchange resin (RzS03Na) which is uniformly sulfonated using a spherical copolymer of styrene-divinylbenzene is used. This ion exchange resin 32 undergoes the following ion exchange reaction with a metal ion such as Ca2+ or Mg2+ or Fe2+ contained in water. 2RzS03Na + Ca2+ ^ ( RzS03 ) 2Ca + 2Na + 2RzS03Na + Mg2+ — ( RzS03 ) 2Mg + 2Na + 2RzS03Na + Fe2+ -> ( RzS03 ) 2Fe + 2Na + That is, by removing the water by the ion exchange resin 32 Ca2+ or Mg2+ or Fe2+. Sodium ions (Na+) are produced by using a strongly acidic cation exchange resin (RzS03Na) as the ion exchange resin 32. As the ion exchange resin 3 2 ', it is also possible to generate a N a+ other than N a+. For example, a strongly acidic cation exchange resin (RzS03Na ) is preferably used. When the water is tap water, the tap water contains chlorine ions such as Ca2+ or Mg2+ or Fe2+, and also contains chlorine. However, the tap water does not change completely by passing the tap water through the ion exchange resin 32. -15- 201132582 On the other hand, the following changes occur by passing water (H20) through the ion exchange resin 32'. H20 — H + + OH— ( 1 ) H20 + H + — H30+ ( 2 ) That is, as shown by (1) (2), by passing the ion exchange resin 32 'Hydration ions (〇Η·) and hydronium ions (H30+) are produced from water. As described above, when the water is hard water, soft water is removed by removing metal ions such as Ca2+ or Mg2+ or Fe2+ from the water by the ion exchange resin 3 2 '. Further, Na + and OH · and hydronium ions (H30 + ) are generated in water by passing through the ion exchange resin 32. However, the chlorine (C1) contained in the tap water is ionized and passes as it is. Next, a partial cross-sectional view of the aforementioned ion generator 14 is shown in FIG. The ion generator 14 has a plurality of cartridges 44 connected in series in the same arrangement and continuously connected in series. Any one of the granular tourmaline 46 or the mixture of the granular tourmaline 46 and the plate-shaped metal 48 is accommodated in the inside of each of the cartridges 44. Since the tourmaline has a positive electrode and a negative electrode, the positive electrode and the negative electrode have an electromagnetic wave having a wavelength of 4 to 14 μm in water, and the cluster of water is cut off to generate hydronium ion (H30+). The energy of the electromagnetic wave having the wavelength of 4 to 14 μm is 0.004 watt/cm 2 . Here, the so-called tourmaline 46 can be a finely divided tourmaline, or a weight ratio of tourmaline to ceramics and alumina (also silver-containing) at about 1〇:8〇:1〇 A tourmaline mixture called a tourmaline nine. The ceramic system contained in the tourmaline nine particles has the function of separating the positive electrode and the negative electrode. Here, for the ceramic, the tourmaline may be mixed at a ratio of more than 10% by weight to 80%. (: The above heating, can be -16-201132582 to make a tourmaline that is eliminated by agitation of water during a specified period (for example, a diameter of 4 mm for about 3 months). Tourmaline 46 is increased in strength by heating, and can be worn to increase wear resistance. During the extinguishing period, water is made into soft water having a hardness close to zero by the ion exchange resin 32, and the tourmaline 46 is ground in soft water. In soft water having a hardness close to zero, magnesium ions or calcium ions can be prevented from adhering to the negative of the tourmaline 46. The electrode can prevent the action of the positive and negative electrodes of the tourmaline 46 from being lowered. As the metal, at least one type of metal such as aluminum, stainless steel or silver is used. As the metal 48', it is preferably not recorded or insoluble in water. Metal. In this metal, 'wrong has bactericidal or antibacterial action together with bleaching effect, stainless steel has bactericidal or antibacterial effect together with cleaning effect, silver has bactericidal or antibacterial effect. As metal 48, can not use copper or give Because of its toxicity, the high-priced materials such as gold cannot be used in terms of cost. The weight ratio of the tourmaline 46 to the metal 48 is preferably 10: 1~ 1 : 1 0. If it exceeds this range, the material of one of the materials becomes too large, and the effect of the two materials cannot be exhibited at the same time. The same 44 is an open shape, and a plurality of holes 52 are provided in the bottom surface 50. When the tourmaline 44 is filled with the tourmaline 46 and the metal 48, the size of the hole 52 is set such that the tourmaline 46 or the metal 48 does not pass through the hole 52 of the bottom surface 50. As shown in Fig. 3, each of the cartridges is 4 The bottom surface 50 of the hole 5 2 having a plurality of holes is a lower side, and the tourmaline 46 or the metal 48 is placed on the bottom surface 50. Then, the inside of each of the cylinders 44 is set so as to flow from the lower position to the upper position. In the crucible 44, the water system having passed through the plurality of holes 52 of the bottom surface 50 is set to be sprayed from the bottom to the top to the tourmaline 46 and the metal 48. Here, since the tap water has a high water pressure, the water system having the water pressure is strong. The tourmaline -17-201132582 46 and the metal 48 in the cylinder 44 are set to set the size and number of the holes 52 to stir the tourmaline 46 and the metal 48 in the drum 44 by the force of the water. The water is sprayed onto the tourmaline to stir the tourmaline in order to be between the tourmaline and the water by the agitation. The friction is caused by the tourmaline dissolving the positive electrode and the negative electrode into the water to cut off the cluster of water, so that a large amount of hydronium ion (h3o+) is produced. As an actual example, the overlapping 4 segments have an inner diameter of 5 cm and a depth of 7 cm. The cartridge 44 containing the volume sufficiently accommodates the tourmaline 46 and the metal 48 in the cartridge 44, but the amount of the tourmaline 46 and the metal 48 is freely movable by the force of water in the cartridge 44. The number of the cylinders 44 can also be one cylinder 44 for increasing the storage volume. Thus, the tourmaline 46 and the metal 48 are dispersed in a plurality of cylinders 44 having a reduced capacity, and the plurality of cylinders are connected.匣44, the stirring efficiency of tourmaline 46 and metal 48 can be improved by the force of water. Since the tourmaline 46 accommodated in the cartridge 44 is dissolved in water for several months, each of the cartridges 44 can be easily attached and detached by, for example, a screw or the like, and can be easily replenished in each of the cartridges 44. Tourmaline 46. Further, the metal 48 does not need to be replenished because it is insoluble in water, but the entire cylinder 44 containing the tourmaline 46 and the metal 48 may be replaced. The cartridge 44 can also vary its containment volume depending on the amount of flow used. In order to increase the negative ions applied to the water passing through the cartridge 44, the positive electrode and the negative electrode are generated by the running-in of the electric stones 46, and the contact of the tourmaline 46 by water provides an increase in negative ions. Further, in order to cut off the water clusters to generate a large amount of hydronium ions (H30+), only the tourmaline 46 may be accommodated in the cartridge 44. However, by mixing the metal 48 with the tourmaline 46, their contact contact can increase the negative ions generated in the tourmaline 46. -18 - 201132582 Since the tourmaline 46 has a positive electrode and a negative electrode, if the tourmaline is stirred with water, the water (H20) is dissociated into hydrogen ions (H+) and hydroxide ions (〇Η·). H20 — H+ + OH- (1) Further, by hydrogen ions (H+) and water (H20), hydronium ions (H30+) having an interface activity are produced. The amount of the hydronium ion (H30 + ) produced is much larger than the amount produced by the ion exchange resin 32 〇Η 2 〇 + Η + ·~> Η 3 Ο + ...... (2) A part of this hydronium ion (Η3ο+) is combined with water (η2ο) to form hydroxide ions (Η302·) and hydrogen ions (Η+). Η30+ + Η2〇—H302- + 2Η+ (3) The water having passed through the ion exchange resin 32 is passed through the ion generator 14, and hydronium ions (H3〇+) and hydrogen are generated inside the water. Oxygen ions (h3〇2_) and H + and OPT. Further, chlorine (Cl) which has passed through the ion exchange resin 32 does not react with the Na+ system generated in the ion exchange resin 32, and passes through the ion generator 14 as it is. The water that has passed through the ion generator 14 is then passed through the interior of the rock receiver 16, which houses a plurality of cerium-containing rocks (rocks containing about 65 to 76% cerium oxide) 54 in the igneous rock. As a igneous rock (divided into volcanic rocks and deep diagenes), there are many ceria-containing rocks. 54' In the volcanic rocks, there are obsidian or nacre or rosin rocks, and there are granites in the plutonic rocks. In the interior of the rock storage device, there are at least one type of rock -19-201132582 stone in the rock of obsidian, pearlite, rosin, and granite. A rhyolite of an obsidian or a true pearl or rosin, or a negative electron of a granite belt. Furthermore, rhyolites such as obsidian or nacre or rosin, or acidic rocks of granitic rocks. The rhyolite series has the same chemical composition as the granite. The rock of 65 to 76% of cerium oxide contained in such igneous rocks (the rhyolite of the obsidian or the pearlite or rosin, or the deep diagenes such as granite) It has an oxidation-reduction potential of -20 to -240 mV in the state of rough stone. However, the Rock 54 system removes those dissolved in water. The rock container 16 is, for example, a cylinder having an inner diameter of 10 cm and a height of 80 cm, and the inside thereof is, for example, an amount that does not reduce the flow rate of water, and contains a large amount of dioxide in the igneous rock having a size of about 5 mm to 50 mm. Awkward rock 54. When the water that has passed through the ion generator 14 is passed through the inside of the rock container 16, enthalpy (negative electron) is added to the water. As a result, chlorine (C1) contained in tap water is a chloride ion by a negative electron.
Cl + e· — C1— ...... ( 4 ) 此Cr與前述Na +係作爲離子而成爲安定狀態。所謂安 定的狀態，就是意味不蒸發而長期間保持離子狀態。又， 前述氫氧離子（Η3〇Γ )亦作爲離子而成爲安定狀態。藉 由使水通過岩石54，與已通過離子生成器14的水相比，進 一步產生水合氫離子（Η30+)，而且亦進一步產生氫氧離 子（Η302·)和氫離子（Η+ )。 H20 + Η+ — Η30+ ...... ( 2 ) H30 + + H20 — H302- + 2H+ ...... ( 3) 藉由使水通過岩石54，另外亦發生以下的反應。 -20- 201132582 OH' + H+ _ h20 ……（5 ) 2H+ + 2e' 2H2 ...... ( 6 ) 再者，水若通過岩石收納器1 6，則由於岩石54的負電 子’水的氧化還原電位由+ 340mV變成-20〜-24〇mV。若使 用熱水代替水，則負的氧化還原電位更安定。再者’已通 過岩石54的水係含有大量的溶存氧或活性氫。 如圖1所示，水係最初通過離子交換樹脂’其次通過 電氣石46 (或電氣石46與金屬48的混合者），然後通過岩 石收納器1 6者係特殊水（創生水）。創生水中含有許多的 Na+、Cl·、H+、OH.、H2、水合氫離子（H3〇+ )、氫氧離 子（H3〇2_ )、活性氫及溶存氧。此水的能量爲 0.004watt/cm2，具有4〜14微米波長的電磁波’具有-20 〜-240mV的氧化還原電位。 作爲本發明的氫之製造方法中使用的水，使用水已依 順序通過離子交換樹脂32、電氣石46 (或電氣石46與金屬 4 8的混合者）、岩石5 4的創生水。圖1中，水係依順序通 過離子交換樹脂32、電氣石46 (或電氣石46與金屬48的混 合者）、岩石5 4，但亦可使用水已依順序通過離子交換樹 脂32、岩石54、電氣石46 (或電氣石46與金屬48的混合者 )者。即，‘如圖4所示，亦可使水依順序通過第一軟水生 成器10、第二軟水生成器12、岩石收納器16與離子生成器 14° 於此圖4中，已通過離子交換樹脂32的水係接著通過 岩石54。藉由此岩石54，在水的內部產生e·(負電子）。 • 21 - 201132582 結果，自來水中所含有的氯係藉由負電子而成爲氯離子。 Cl + e' -> CT ...... ( 4 ) 此Cl·與離子交換樹脂32所產生的Na+作爲離子而成爲 安定狀態。再者，已可過離子交換樹脂32的水亦會有不含 Na +的情況。 於已通過離子交換樹脂32的水中，如前述（1) (2) 所示，H +與〇Η·和水合氫離子（H30+ )係存在。已過離子 交換樹脂32的水然後藉由通過岩石54，亦發生以下的反應 OPT + H+ — H20 ( 5 ) H2〇 + H+ — H30+ ( 2 ) 2H+ + 2e· — 2H2 ( 6 ) 於此反應中，水合氫離子（H30+ )係以比離子交換樹 脂3 2所產生的量還更多的量產生。 如以上，於離子交換樹脂32之後，藉由通過岩石54， 在水中變成有以往存在的Na+和OH·與新產生的Cl_和水合 氫離子（H30+ )之存在。又，已通過岩石5 4水氧化還原電 位爲-2 0〜-240mV。若使用熱水代替水，則負的氧化還原 電位更安定。再者，已通過岩石54的水係含有大量的溶存 氧或活性氫。 使已通過此岩石54的水接著通過內藏有電氣石46與金 屬48的離子生成器14之內部。藉此，發生以下的反應。 H20 H + + OH' ...... ( 1 ) Η 2 Ο + Η + —* Η 3 Ο + ...... (2) -22- 201132582 此水合氫離子（H3o+)係大量地產生。又’水合氫離 子（H30+ )的一部分係變成氫氧離子（H3021 。 H3〇+ + H2O ~^ Η 3 0 2 + 2 Η + ...... (3) 結果，於已通過電氣石46與金屬48的水中，水合氫離 子（Η30+)、氫氧離子（Η302_) 、ΟΗ·及Η +係增加。 如圖4所示，水已依順序通過離子交換樹脂3 2、岩石 54、電氣石46 (或電氣石46與金屬48的混合者）者，係含 有Na+、Cl—、ΟΗ·、水合氫離子（Η30+ )、氫氧離子（ Η302· ) 、Η+、溶存氧及活性氫，含有與圖1所作出的創生 水相同的成分。再者，具有具〇.〇〇4watt/cm2的能量之4〜 14微米電磁波與-20〜-24 OmV的氧化還原電位。結果，圖4 所作出的水與圖1所作出的創生水係具有同樣的效果。由 於圖4的裝置所生成的水係與圖1所生成的創生水在水中含 有者的結果爲相同，故圖4的裝置所生成的水亦爲創生水 〇 以下顯示此創生水的水質檢査結果。括弧內顯示與此 創生水比較下的自來水之値。惟，自來水中與創生水相同 的値係爲「相同」。亞硝酸性氮及硝酸性氮：1 .8mg/l (相 同）、氣離子：6.8mg/l ( 9_0mg/l) 、一·般細囷：〇個 /ml (相同）、氰離子：未達O.Olmg/Ι (相同）、水銀：未達 0.0005mg/l (相同）、有機磷：未達0.1m g/Ι未達（相同） 、銅：未達〇.〇lmg/l (相同）、鐵：未達〇.〇5mg/l (未達 0.08mg/l )、錳：未達0.01mg/l (相同）、鋅：未達 0.005mg/l (未達 〇.〇54mg/l)、鉛：未達 0_01mg/l (相同） -23- 201132582 、六價鉻：未達〇.〇2mg/l (相同）、鎘：未達〇.005mg/l ( 相同）'砷：未達〇.〇〇5mg/l (相同）、氟：未達0.l5mg/l (相同）、鈣離子·鎂離子等（硬度）：1.2mg/l ( 49.0mg/l )、酚類：未達〇.〇〇5mg/l (相同）、陰離子海面 活性劑：未達〇.2mg/l (相同）、pH値：6.9 (相同）、臭 氣：無異臭（相同）、味道：無異味（相同）、色度：2 度（相同）、濁度：〇度（1度）。 創生水係具有以下列舉的許多特徵。 (a)含有水合氫離子（H30+)、氫氧離子（h302-) 、氫離子（H+) '氫、羥基（〇『）、硫酸離子（S042·) 、碳酸氫離子（HCOT)、碳酸離子（C032·)、偏矽酸（ H2Si03)與游離二氧化碳（C02)。 (b )具有界面活性作用。 具有界面活性作用（OW型創生水乳化作用）。 (c )具有微弱能量（培育光線）作用。 電氣石係放出微弱能量（4〜14微米波長的電磁波） 。此微弱能量係切斷水的大團簇，由水中將團簇內所抱住 的有毒氣體或重金屬類排出到外部。 (d)具有-20〜-24 0m V的氧化還原電位。 (e )含有溶存氧或活性氫。 (f)係已去除鈣離子或鎂離子的軟水。 藉由使自來水等通過離子交換樹脂，可去除水中所含 有的鈣離子及鎂離子。 -24- 201132582 實施例1 其次，以圖5爲基礎來說明本發明的氫氣之 。於說明本發明的氫氣之製造方法之前，說明其 的一例。製造裝置具有容器60與該容器之蓋61， 常係以被蓋6 1閉鎖的狀態下使用。於蓋6 1上安裝 ，該噴嘴在內部形成有連絡容器內部與容器外部 路65，於噴嘴64的途中，具備將連絡通路65開關 68。於容器60的上部安裝有測定容器60的內部氣 計71與測定容器60的內部溫度之溫度計73。容器 形狀宜爲水平截面朝向蓋6 1徐徐變窄的圓錐形狀 狀。此係爲了使容器6 0內所生成的輕氫氣積存在 上方，容易由容器60中將氫氣取出到外部。容器 之下方，具備加熱容器60用的加熱手段69。再者 段69係不限於火力，亦可藉由太陽光或電熱器等 熱手段69的配置位置係不限於在容器60的底面之 本發明中，於容器60內置入特殊水（創生水 粉末77，藉由加熱手段69來加熱創生水75與鋁粉 分增多對創生水7 5的量而言鋁粉末7 7之量，以便 75中充分浸漬鋁粉末77。爲了產生氫，所使用者 生水7 5與鋁粉末7 7的2種材料。即，於容器6 0內 鋁以外的金屬或化學物質，僅將容器6 0內的創生 粉末7 7加熱而使產生氫。 於實施例1中，以鋁的粉末爲基礎來說明。 末係使用市售者。鋁的粉末係使用大阪市西區：ί 製造方法 製造裝置 容器60通 有噴嘴6 4 的連絡通 的開關閥 壓之氣壓 60的上方 或角錐形 容器60的 6 0的底面 ，加熱手 。又’加 r方。 )75與鋁 末77。充 在創生水 係僅爲創 中不加入 水75與鋁 此鋁的粉 賣堀1 - 2 - -25- 201132582 1 2所在的大和金屬粉工業株式會社所市售者。於此實施例 1中，在容器60內加入1公升的創生水75與lOOg的鋁粉末77 ，藉由加熱手段69來加熱容器60內的創生水75與鋁粉末77 。即，創生水75與鋁的重量比係鋁10重量對創生水100重 量。加熱手段69所致的容器60內之加熱，係由常溫（例如 20°C )開始加熱，加熱到容器60內的溫度成爲30°C或其以 上爲止。在比3 0 °C稍低的溫度，氫開始產生，但在3 (TC或 其以上時，容器60內大量地產生氫。 若將容器60內的創生水75與鋁粉末77加熱到30°C或其 以上，則辨明氫的產生，但爲了具有客觀性，委託第三者 進行實驗結果的測定分析。圖6中顯示該分析結果的測定 分析成績書。本發明之圖6或其以後的圖中所示的測定分 析成績書，係由日本長野縣北佐久郡立科町芦田1 83 5所在 的株式會社信濃公害硏究所（電話0267-56-2 1 89 )來作成 〇 茲說明圖6的測定分析成績書。圖6係在容器60內加入 創生水75與鋁粉末77，藉由加熱手段69將容器60內的溫度 加熱到30°C或其以上，以10公升袋採集容器60內的空氣。 於創生水75與鋁粉末77的反應中，在以加熱手段69將容器 60加熱間，氫係產生，當停止加熱手段69的加熱過一會兒 ，氫變不產生。於30t以上且未達80°C時，產生氫的加熱 係使容器60內的溫度繼續徐徐上升。保持同一溫度的加熱 時，不久氫繼續產生，但途中氫的產生係停止。因此，產 生氫的溫度係由30°C起，以容器60內的溫度繼續徐徐上升 -26- 201132582 的方式，用弱火加熱。因此，在容器60內的溫度爲3 0。(：以 上且未達80 °C之間，可容易地進行氫的產生或停止。 容器60內所產生的氫係藉由在噴嘴64的前端所安裝的 10公升袋（未圖示）來採集。由容器60內所採集的空氣係 在測定前進行冒泡（bubbling )。冒泡係使所採集的空氣 潛入容器（未圖示）內裝有的水中。使所採集的空氣冒泡 者係具有去除所採集的空氣所含有的水分（進行氣水分離 )，同時將空氣冷卻之效果。對在3 0°C或其以上的溫度所 採集的空氣進行冒泡後，測定空氣的結果係圖6的測定分 析成績書。如圖6所示，在3 0 °C或其以上的溫度繼續使溫 度徐徐上升而加熱的空氣中，含有7 5 %的氫、5 · 2 %的氧。 即，可知若將裝有鋁粉末7 7與創生水的容器6 0在3 0 °C或其 以上的溫度繼續使溫度徐徐上升而加熱，則大量產生氫。 由於加熱溫度爲在3 0°C或其以上繼續使溫度徐徐上升的溫 度’故在圖6的實驗中，容器60內的壓力爲大氣壓（1氣壓 )。 其次，說明圖7的測定分析成績書。使容器6 0內的溫 度由30°C徐徐上升到80°C爲止，若溫度達到80°C的話，在 8 0°C以上與未達創生水的沸點之間的溫度保持容器60內的 溫度。創生水的沸點溫度係1 〇2〜1 〇4 t。於80°c以上且未 達創生水的沸點之溫度時，僅保溫而產生氫。於容器60內 的溫度爲80°C以上且未達創生水的沸點之溫度時，不需要 使溫度繼續上升。圖7的測定分析成績書係在容器60內的 空氣爲80°C以上且未達創生水的沸點之溫度，於丨〇公升袋 -27- 201132582 採集容器60內的空氣者。使採集的空氣冒泡而進行測定的 結果，含有9 8 %的氫、0.3 %的氧。由於加熱溫度爲8 0 °C以 上創生水的沸點以下’故圖7的容器60內之壓力爲大氣壓 (1氣壓）。 於容器60內的溫度爲8 Ot以上且創生水的沸點之前的 溫度時，不需要使容器60內的溫度繼續上升，但必須將容 器60內的溫度保持在80 °C以上。即，加熱狀態必須斷續地 進行。若停止加熱狀態而成爲80°C以下，則氫變不產生。 因此，若將容器60內的溫度保持在80°C以上且未達創生水 的沸點之間的溫度，則可大量地產生氫。又，停止氫的產 生時，可停止容器60的保溫或加熱，使成爲80°C以下即可 。因此，可容易地進行氫的產生或停止。 隨著溫度自30°C上升到80°C爲止，所採集的空氣中所 含有的氫之含有比率係徐徐變大。此可由30°C以上的溫度 之氫的含有率爲75%、80°C的溫度之氫的含有率爲98 %所 明知。由於30°C以上的溫度之氫的含有率亦有75%，茲認 爲氫的產生量係充分大量。由1公升的創生水75與100g的 鋁粉末77產生40分鐘至50分鐘的氫，於此實施例1中，每1 克鋁粉末77生成約2.0公升的氫。 於創生水中，含有水合氫離子（H30+)或氫氧離子（ Η3〇Γ)或氫離子（H+)或氫氧化離子（ΟΗ·)等，由彼等 水合氫離子（Η30+)或氫氧離子（Η302·)或氫離子（Η + )或氫氧化離子（ΟΙΤ)等生成氫氣，故與自來水、天然 水、鹼離子水等的水相比，茲認爲創生水可產生許多的氫 -28- 201132582 使創生水與鋁反應而產生氫者，係藉由鋁 應產生氫’而在鋁的表面上覆蓋氧化被膜，由 膜而停止氫的產生。由創生水7 5與鋁粉末7 7產 5 0分鐘的氫。使用自來水等代替創生水時，與 產生氫的時間係零或充分短。因此，可知藉由 75，可顯著延遲氧化被膜在鋁的表面上產生的 延遲氧化被膜在鋁粉末77的表面上之產生的理 確，但推測氫氧離子（Η 3 Ο 2 ·)是否長時間防 對鋁粉末7 7之表面的附著。當在鋁的表面上結 而不產生氫時，若創生水75殘留在容器60內， 末77由容器60排出或不排出，只要在容器60內 粉末7 7，則氫再度產生。 置入容器60內的鋁粉末77之重量，對創5 而言，係5重量以上（對創生水1公升而言， 5〇g以上）。置入容器60內的鋁粉末77之重量5 ，由於氫的產生量非常少，而不適合於實用。 最佳重量範圍係1 〇重量以上（對創生水1公升 末77爲l〇〇g以上）至鋁粉末77達到創生水的液 量。鋁粉末77未達10重量時，氫的產生量係比 氫產生量少。鋁粉末77超過30重量時，氫產生 量時幾乎沒有變化，耗費鋁粉末的成本7 7，故 1 0重量〜3 0重量。 如以上，於本發明中，藉由使裝有創生水 與創生水反 於該氧化被 生40分鐘〜 鋁的反應而 使用創生水 時間。顯著 由雖然末明 止氧化被膜 成氧化被膜 即使將鋁粉 追加新的鋁 三水1 0 0重量 銘粉末7 7爲 艮達5重量時 鋁粉末77的 而言，鋁粉 面爲止之重 10重量時的 量係與30重 銘粉末且爲 7 5與鋁粉末 • 29 - 201132582 77的容器60內之溫度成爲3 0。〇或其以上的溫度，可產生氫 。爲了提高容器60內的溫度，可用加熱手段69加熱容器6〇 ’或添加已加熱的創生水’任—者皆可。加熱容器6 〇內的 溫度爲3 0 °c以上且未達8 0 °c時’在加熱容器6 〇內之際必須 繼續的溫度上升’但於8 0 °C以上且未達創生水的沸點之間 ’加熱容器60內的溫度未必需要繼續的溫度上升，可在 8 〇°C以上且未達創生水的沸點之間的溫度完成保溫，加熱 手段6 9的溫度調整係簡單。再者，於8 〇 以上且未達創生 水的沸點未達之間’所產生的氫之量與在3 〇 °C以上且未達 8 〇°C的溫度的氫之產生量相比係非常多。本發明的實施例 1由於係以創生水75與鋁粉末77爲原料，將彼等在容器60 內於大氣壓下加熱而產生氫，故不需要耐高壓的裝置，裝 置係便宜而且可得到大量的氫。 藉由圖5所示的裝置，在容器60內最初加入1公升的創 生水75與100g的鋁粉末77，於80°C以上且未達創生水的沸 點之間進行加熱而保持80°C以上的溫度，出現40分鐘〜50 分鐘的氫》於氫未出現的狀態下，容器60內的鋁粉末77上 形成氧化被膜，鋁粉末77導致氫產生的作用變差，但容器 6〇內存在大量的創生水75。因此，爲了再產生氫，於氫未 出現的狀態下或即使氫繼續出現的狀態下，例如若在8(TC 以上的溫度之容器60內追加新的鋁粉末77，則創生水75與 新追加的鋁粉末77也進行反應而再度產生氫。 於氧化被膜形成在鋁粉末77上而氫不產生的狀態下’ 停止裝置的運轉，假定翌日再開始氫的產生作業。於翌曰 -30- 201132582 ，容器6 0內的創生水之溫度係下降至外氣溫度（例如丨〇乞 〜2 0°C )。容器60內的溫度雖然爲外氣溫度，但若將新的 鋁粉末7 7加入容器6 0內，則鋁粉末7 7與容器6 0內的創生水 反應’即使不進行加熱手段69的加熱，容器60內的溫度也 上升至80 °C〜90 °C。然後，即使不加熱容器60內，容器60 內的溫度也保持在80 °C〜90 °C而產生氫。 於容器60內的鋁沒有作用時，可僅追加鋁（無加熱手 段69的加熱）而使容器60內的溫度上升至8(TC〜90 °C且保 持在該溫度者，係只有鋁的粉末。當鋁爲粒狀或小片時， 必須藉由加熱手段6 9將容器6 0內的溫度經常地加熱至8 0 °C 以上創生水的沸點以下之溫度。再者，當容器60內沒有創 生水而加入新的創生水時，必須重新用加熱手段6 9由最初 來加熱容器6 0內。然而，於容器6 0內殘留創生水的狀態下 追加新的創生水時，在鋁粉末7 7的情況亦可不用加熱手段 6 9來加熱容器6 0內。 此處，說明於創生水75殘留的容器60內加入新的鋁粉 末77時，即使不用加熱手段69的加熱，容器60內的溫度也 上升至8 0 °C〜9 0 °C，氫產生的理由。於其之前，說明創生 水本身與鋁粉末7 7反應產生氫後的創生水之pH的變化。圖 8係產生氫之前的創生水之計量證明書，圖9係與鋁粉末77 反應產生氫後的創生水之計量證明書。大的變化者係pH。 如圖8所示，與鋁粉末77反應前的創生水之pH爲7.4 (中性 )。使創生水與鋁粉77反應產生氫後的創生水之pH係如圖 9中的9 · 8，創生水係成爲鹼性。即，創生水7 5與鋁粉末7 7 -31 - 201132582 反應產生氫後的水係成爲鹼性的創生水。不僅鋁粉末77， 即便使用粒狀或小片者來產生氫者’創生水也成爲鹼性的 創生水。此外，如圖8所示，創生水中所含有的鈉離子爲 26mg/L，使用創生水與鋁粉末77產生氫後的容器60內之創 生水中所含有的鈉離子係若干地上升至35mg/L。如由圖8 與圖9可知，中性的創生水係在與鋁粉末7 7反應產生氫後 ，變成驗性。 如此地，藉由在pH成爲鹼性的創生水中’追加新的鋁 粉末77，容器60內的溫度上升至80 °C〜90 °C。然後，即使 不用加熱手段來加熱容器60，容器60內的溫度也保持在 8 0 °C〜9 0 °C。若於容器6 0內殘留的創生水中，添加新的創 生水，雖然亦取決於容器60的容量或所追加的創生水之量 ，但於短時間內容器60內的溫度上升至80°C〜90°C。然後 ，即使不加熱容器60，容器60內的溫度也保持在80°C〜 9〇°C。所追加的創生水之溫度例如若爲經加熱到80°C以上 的熱水，則由於不會使容器60內的溫度暫時降低，故可高 效率地繼續氫的產生。 此處，若使用鹼離子水代替創生水，基於無法得到相 同結果的推定，使用鹼離子水進行與創生水相同的實驗° 首先，於容器60內加入鋁粉末與鹼離子水，藉由加熱手段 將容器60內加熱至3(TC以上。圖1〇中顯示結果。如圖10所 示，含有氫17%、氧18%。其次，於容器60內加入鋁粉末 與鹼離子水，藉由加熱手段將容器60內加熱至80°C以上’ 而得到圖1 1所示的結果。如圖1 1所示，含有氫1 3 %、氧 -32- 201132582 19%。由以上的結果可知’創生水75與鋁粉末77之反應所 產生的氫量係充分多於鹼離子水與鋁粉末77之反應所產生 的氫量。因此，鹼性的創生水與鹼離子水中，氫的產生量 係大不相同。 實施例2 其次，以圖1 2爲基礎來說明本發明的實施例2。圖1 2 係顯示本發明的氫之製造方法的裝置之一實施例的截面圖 。容器6 0的材料例如爲不銹鋼，但不限於不銹鋼。於此容 器60的內部在上下具備多段的棚架62，在各棚架62上載置 多數的小粒狀或小片之鋁66。於多數的各棚架62中，在鋁 66不落到下方下，設置多數的水或空氣可通過程度之大小 的孔（未圖示）。容器60內所具備的多段之棚架62係由容 器60的側面所具備的門扉（未圖示）來出入。在容器60的 底部亦具備小粒狀或小片的多數之鋁66 (亦可爲鋁粉）。 在容器60的上部設置氣體排出通路65，容器60內所產生的 氫等氣體係經由氣體排出通路65排出到外部。氣體排出通 路65係以開關閥68來開關。由容器60的外側藉由加熱器等 的加熱手段6 9來加熱。再者，由容器6 0的外側加熱容器6 0 的內部之加熱手段69 ’除了加熱器以外，亦可使用氣體等 的火力。當加熱手段69爲電熱器時，以絕熱材76覆蓋加熱 器的外側，防止容器60內的溫度朝向大氣溫度降低。 於容器60內的最上部之棚架62的上方，如淋浴方式設 置用於將水平均地噴射散佈在最上部的棚架62之全域的水 -33- 201132582 噴射手段70。加入容器60內的「水」係創生水或在創生水 中加有氫氧化鈉的氫氧化鈉水溶液之任一者。本發明中的 「氫氧化鈉水溶液」係指「創生水與氫氧化鈉的混合水溶 液」。此氫氧化鈉水溶液係鹼性（鹼性創生水）。對水噴 射手段70，經由水供給通路72供應創生水或氫氧化鈉水溶 液，於該水供給通路72的途中設置用於調整供給水量的水 量調整手段74。由容器60內的上部之水噴射手段70，如淋 浴方式使創生水或氫氧化鈉水溶液朝向下方噴射。由水噴 射手段70所噴射的創生水或氫氧化鈉水溶液係經由最上部 的棚架62上之鋁66，到達下一段的棚架62，依順序到達下 方的棚架62，最終到達容器60的底部。 於實施例2的發明中，由水噴射手段70噴射散佈到容 器60內的水係使用創生水或氫氧化鈉水溶液。即，於實施 例2的發明中，必定使用創生水。創生水係藉由與鋁66接 觸而在3(TC以上產生氫，從30°C至80°C，隨著容器60內的 溫度之上升，所產生的氫量係增大。當容器60內的溫度爲 8 0°C以上時，與未達80°C相比，氫的產生量係急劇增大》 氫氧化鈉係具有使由水產生的氫量增加的效果與使由 水產生的氧量減少的效果。使用氫氧化鈉水溶液時，氫氧 化鈉的濃度只要是0.1 %以上即可，氫氧化鈉的濃度宜爲1 % 〜1 5 %左右，因爲氫的產生量多或氫的產生開始時間短。 氫氧化鈉的濃度亦可爲1 5 %以上，但結果幾乎與1 %〜1 5 % 右左的氫氧化鈉濃度沒有變化。 亦可以由水噴射手段70向容器60內噴射散佈的水爲創 -34- 201132582 生水，在棚架62之上除了鋁66還具備氫氧化鈉 的創生水與氫氧化鈉接觸而成爲氫氧化鈉水溶 容器6 0內與鋁6 6接觸的水，若結果爲氫氧化鈉 生水與氫氧化鈉的混合水溶液），則成爲本發 氧化鈉水溶液」。 於本發明的實施例2中，在容器60內加入 氧化鈉水溶液與鋁6 6，由容器6 0的外部藉由加 容器60內加熱至30 °C以上。於使氫大量產生時 的溫度只要成爲80°C以上即可，但由於亦會無 氫的產生，故也考慮使用少量的氫產生量者。 6〇內的溫度爲30°C〜80°C，氫的產生量爲少量 產業上可利用。再者，氫的產生量係可藉由容 度與後述的氫氧化鈉水溶液之氫氧化鈉濃度來 此處，以圖1 3及圖1 4所示的測定分析成績 說明實施例2的實驗結果（測定分析成績書） 入容器60內者係創生水，圖14中加入容器60內 與氫氧化鈉混合的氫氧化鈉水溶液，此以外爲 。圖13及圖14的「試料名」之共通內容爲「創 無電氣石、鋁100%、（藉由加熱手段）加 0.07 5MPa」。此圖1 3及圖1 4的測定分析成績書 的株式會社信濃公害硏究所來作成。 此處，說明圖〗3及圖14的「無電氣石、鋁 達成本發明之前，在容器內加入自來水等的水 連同電氣石，進行生成氫的實驗。與此有關聯 ’由上落下 液。即，在 水溶液（創 明中的「氫 創生水或氫 熱手段6 9將 ，容器60內 法緊急停止 因此，容器 的情況亦爲 器60內的溫 調節。 書爲基礎， 。圖1 3中加 者係創生水 相同的條件 生水1 0 0 %、 熱、93°C、 亦藉由前述 ]0 0 %」。於 ，加入鋁66 地進行各種 -35- 201132582 實驗之結果，辨明若使創生水或氫氧化鈉水溶液僅與鋁6 6 (沒有電氣石76)接觸，與鋁66接觸的狀態之創生水或氫 氧化鈉水溶液若成爲3 0°C以上的話，則產生氫。再者，與 鋁66接觸的狀態之創生水或氫氧化鈉水溶液，係在容器內 的溫度爲3 0 °C以上時產生氫，但爲了證明藉由創生水與鋁 66係大量地產生氫，在容器內的溫度爲93 °C ( 8 0°C以上） 進行實驗。以「創生水1 00%、無電氣石、鋁1 00%、（藉 由加熱手段）加熱、溫度爲93 °C、容器內的壓力爲 0.07 5MPa」之內容進行實驗的結果之測定分析成績書係圖 1 3及圖1 4。由此等實驗可知，由於溫度爲創生水的沸點以 下，在大氣壓下大量地產生氫。若根據各種實驗，例如使 用自來水當作水時，即使在容器內與鋁66接觸，也不產生 氫。 此處，對使用創生水的測定分析成績書（圖1 3 )與使 用氫氧化鈉水溶液的測定分析成績書（圖Μ )，進行比較 檢討。於使用創生水的測定分析成績書（圖1 3 )中，在所 產生的氣體內，氫爲8 3 %，氧爲3.8 %，氫總量爲2.1公升。 於使用氫氧化鈉水溶液的測定分析成績書（圖1 4 )，在所 產生的氣體內，氫爲98%，氧爲0.3%，氫總量爲11.2公升 〇 若比較圖1 3與圖1 4，則於圖1 3之使用創生水者中，氫 爲83%，氧爲3.8%，相對於此，於圖14之使用氫氧化鈉溶 液者中，氫爲9 9 %，氧爲0.3 %。由以上可知’氫氧化鈉係 具有提高氫的產生比率，同時降低氧的產生比率之作用。 -36- 201132582 特別地，相對於圖1 3的氫總量爲2 . 1公升而言，圖1 4的氫 總量爲1 1 · 2公升，故可知藉由在創生水中混合氫氧化鈉， 可大幅增加氫產生量。 茲認爲藉由添加氫氧化鈉，氫的產生量變多，同時氧 的產生量降低，但那是在氫氧化鈉與鋁66反應之際，由氫 氧化鈉產生氫，氫氧化鈉的氧與鋁結合’而成爲氧化鋁。 再者，圖12中，於容器60內在上下具備多數的棚架62 ，在該棚架6 2上具備多數的粒狀或小片的鋁6 6，使創生水 或氫氧化鈉水溶液由上方朝下方落下。代替此，亦可於容 器60內不具備棚架62，在容器60內的底部具備粒狀或小片 狀的鋁66 (亦可爲粉），加入創生水或氫氧化鈉水溶液直 到鋁66覆蓋高度爲止。於產生氫之際，鋁66若在空氣中露 出，則在鋁66的表面上產生黑的氧化膜，隨著時間的經過 而氫產生率降低，但藉由將鋁66浸漬在創生水或氫氧化鈉 水溶液內，可抑制鋁66的氧化膜之產生。 於大量產生氫之際，鋁66與氫氧化鈉水溶液反應而繼 續產生反應熱。藉由此反應，鋁66係徐徐溶化而成爲殘留 物（80〜90 %爲氫氧化鋁，10〜20 %爲碳酸鈉）。若鋁66 溶化而成爲殘留物，由於變成不產生反應熱，故必須用新 的鋁66來替換棚架62上的殘留物。 實施例3 圖1 5係本發明的氫之製造方法所用的裝置之實施例3 的截面圖。圖1 5 (實施例3 )與圖1 2 (實施例2 )的不同點 -37- 201132582 在於省略實施例2所設置的加熱手段69之點。於實施例2中 ，藉由在容器60的外部所具備的加熱手段69來加熱容器60 內的創生水或氫氧化鈉水溶液，但於此實施例3中，省略 容器的外部之加熱手段，而藉由容器60内的反應熱，使容 器6 0內的氫氧化鈉水溶液升溫到產生氫的3 0 °C以上。 向來，爲了由水得到氫，使用加熱手段將水加熱分解 ，但於此實施例3中，不使用加熱手段。爲了使容器60內 成爲30°C以上的溫度，藉由在容器60內使氫氧化鈉水溶液 與鋁接觸的反應熱，可使容器60內的溫度上升到創生水的 蒸發溫度（約104 °C )附近爲止。容器60內的溫度，因爲 藉由反應熱而變成由與鋁66接觸的狀態之創生水產生大量 的氫之溫度（30°C )以上，故可在容器60內產生氫。此反 應熱係可將容器60內的溫度提高到氫大量產生的80 °C以上 。結果，於實施例3的發明中，即使不用外部的加熱手段 ，也可產生氫。 氫氧化鈉水溶液的氫氧化鈉之濃度只要是0.1 %以上皆 可。氫氧化鈉的濃度例如經濟上宜爲1〜1 5 %。氫氧化鈉濃 度也可爲1 5%以上，但即使氫氧化鈉濃度升高也效果相同 。氫的產生量係藉由容器60內的溫度與氫氧化鈉水溶液的 氫氧化鈉之濃度來調節。氫氧化鈉的濃度爲0. 1 %至5 %時， 一般地若濃度變濃，則氫的產生量徐徐地增加。 藉由創生水與氫氧化鈉和鋁66的反應熱，由於容器60 內的溫度變成1 00°C附近的溫度，故以由配置於容器60的 上方之水噴射手段70所噴射的氫氧化鈉水溶液，在到達容 -38- 201132582 器60的底部之鋁66的時間點’幾乎全部蒸發的方式’藉由 未圖示的控制手段控制來自水噴射手段7 0的氫氧化鈉水溶 液之噴射量。藉此，容器60內由上方所噴射的水，係在落 下到達容器6 0的底部之前後進行蒸發’容器6 0內所噴射的 氫氧化鈉水溶液之蒸發效率係良好。 再者，圖15中，於容器60內在上下具備多數的棚架62 ，在該棚架62上具備多數的粒狀或小片的鋁66，由上方朝 向下方使氫氧化鈉水溶液落下。代替此’亦可在容器6 0內 不具備棚架62，而在容器60內的底部加入粒狀或小片或粉 狀的鋁66，加入氫氧化鈉水溶液直到覆蓋鋁66的高度爲止 〇 其次，圖16至圖18顯示使用圖15的裝置，使鋁66與氫 氧化鈉水溶液（創生水與氫氧化鈉的混合水溶液）接觸以 產生氫的實驗結果。圖1 6至圖1 8係氫氧化鈉的濃度爲5 % ( 圖 1 6 )、1 0 % (圖 1 7 )、1 5 % (圖 1 8 )之結果。 圖16至圖18的「試料名」之共通內容係「容器內的氣 壓爲0.007MPa (判斷此爲〇.〇7MPa之誤） '溫度爲9 3 °C、 無電氣石、鋁九、在創生水1 0 0 %冒泡、無加熱手段」。「 試料名」的「無電氣石」之記載係爲了明確地表示除了本 發明在容器6 0內所加入的氫氧化鈉水溶液以外，僅爲鋁6 6 ’而沒有加入電氣石。 兹說明「試料名」的「銘九（aluminum shot)」之記 載。在鋁中使用鋁九與鋁球進行實驗。於圖16至圖18中， 使用鋁九。鋁九係任何成形前的鋁材料之塊或小片，鋁本 -39- 201132582 身的純度高者。鋁球係成形爲球狀’加入鐵分等而容 形者，鋁本身的純度係比鋁九低。 「試料名」的「在創生水100%冒泡」之記載係意 由容器取出在容器內產生的氫等氣體後’使通過創 1 00%的內部J 。藉由使在容器內產生的氫等氣體通過 水100 %的內部，去除氣體中所含有的水分’更提高各 體的比率之精度。 若根據圖1 6至圖1 8的測定分析成績書’於氫氧化 度5 %的氫氧化鈉水溶液之情況（圖1 6 )中’氫9 8 % 0.3%、氫總量12.1公升。於氫氧化鈉濃度的氫氧 水溶液之情況（圖17 )中，氫99%、氧0.2°/。、氫總量 公升。於氫氧化鈉濃度1 5%的氫氧化鈉水溶液之情況 1 8 )中，氫9 9 %、氧〇 · 3 %、氫總量1 2 · 3公升。若根據 測定分析成績書，可知即使不用由容器的外部來加熱 用的加熱手段，也藉由鋁6 6與氫氧化鈉水溶液的反應 自己升溫，氫以9 8 %〜9 9 %程度大量地產生’氧僅以 〜0.3 %程度極少量地產生。即，於本發明中，即使不 器的外部以加熱手段加熱，也可藉由反應熱的自己升 而使氫氧化鈉水溶液的溫度上升至創生水的氫產生溫 30°C )以上，由創生水產生氫。再者，於氫氧化鈉水 中，若溫度爲80°C以上，則可大量地產生氫。 如在圖1 6至圖1 8的測定分析成績書，使用在5%、 、1 5 %的濃度之創生水中溶解有氫氧化鈉的氫氧化鈉 液時，得到98%〜99%的氫。此處，圖19至圖23中顯 易成 味「 生水 創生 種氣 鈉濃 、氧 化鈉 12.5 (圖 此等 容器 熱而 0.2% 由容 溫， 度（ 溶液 10% 水溶 示比 -40- 201132582 較使用混合氫氧化鈉的水與使用創生水和其以外的水之比 較結果。圖1 9至圖2 3的結果係在容器內的底部加入多數的 粒狀或小片的鋁，於加入有氫氧化鈉與各種水以使得混合 者的液面成爲比鋁的最上位還上位的高度爲止之狀態下進 行實驗者。 圖1 9及圖2 0係關於創生水、自來水、鹼離子水與天然 水的4種類之水，進行6種類的實驗之表。所謂6種類的實 驗，就是氫氧化鈉的濃度爲5 %，使用鋁九的情況與使用鋁 球的場合（2種類）、氫氧化鈉的濃度爲1 0 %，使用鋁九的 情況與使用鋁球的情況（2種類），氫氧化鈉的濃度爲1 5% ，使用鋁九的情況與使用鋁球的情況（2種類）。關於4種 類的水，測定氫氧化鈉的濃度（3種類）與鋁（2種類）之 組合、氫產生之前的時間（「未反應」係指自實驗開始到 氫產生爲止有多少的時間未反應）、自氫產生起有多少的 時間繼續產生氫（「反應結束（停止）」係指繼續產生氫 的時間）。 以圖19及圖20的表之數値爲基礎作成圖表者係圖21至 圖23。圖2 1的左圖表係氫氧化鈉的濃度爲5%且使用鋁九者 。於此圖表中’鹼離子水、天然水、自來水皆不產生氫。 相對於此’創生水係在產生氫之前花費1 5分鐘，在產生氫 之後繼續產生氫，直到氫氧化鈉水溶液耗盡爲止。圖2 〇中 ’在反應結束（停止）的創生水之欄中有1 2 〇分鐘以上， 此意味直到氫氧化鈉水溶液耗盡爲止者。 圖2 1的右圖表係氫氧化鈉的濃度爲5 %且使用鋁球者。 -41 - 201132582 根據此圖表與圖19及圖20，鹼離子水、天然水、自來水係 在產生氫之前花費13分鐘、5分鐘、8分鐘的時間，繼續產 生氫的時間爲40分鐘、33分鐘、28分鐘。相對於此，創生 水係在產生氫之前爲1分鐘，繼續產生氫的時間爲90分鐘 。即與其它水相比，創生水在產生氫之前的時間係非常短 ，繼續產生氫的時間係比其它水長。如此地，由圖1 9及圖 2 0的表與圖21的圖表可知，作爲產生氫用的水，與鹼離子 水、天然水、自來水相比，較宜使用創生水。 圖22的左圖表係氫氧化鈉的濃度爲1 0%且使用鋁九者 。根據此圖表與圖19及圖20，鹼離子水、天然水、自來水 係在產生氫之前花費27分鐘、26分鐘、20分鐘的時間’繼 續產生氫的時間爲80分鐘、90分鐘、45分鐘。相對於此， 創生水係在產生氫之前爲1 〇分鐘，繼續產生氫直到氫氧化 鈉水溶液耗盡爲止。如此地，由圖19及圖20的表與圖22的 左圖表可知，作爲產生氫用的水，與鹼離子水、天然水、 自來水相比，較宜使用創生水。 圖2 2的右圖表係氫氧化鈉的濃度爲1〇%且使用鋁球者 。根據此圖表與圖19及圖20，鹼離子水、天然水、自來水 係在產生氫之前花費3分鐘、3分鐘、4分鐘的時間’繼續 產生氫的時間爲27分鐘、27分鐘、30分鐘。相對於此’創 生水係在產生氫之前爲5〇秒’繼續產生氫的時間爲75分鐘 。如此地，由圖19及圖20的表與圖22的右圖表可知’作爲 產生氫用的水’與鹼離子水 '天然水 '自來水相比’較宜 使用創生水。 -42- 201132582 圖 。根據 係在產 續產生 創生水 鈉水溶 左圖表 自來水 圖 。根據 係在產 產生氫 生水係 4 3分鐘 ，作爲 ，較宜 圖23的 生時間 其 天然水 種類， 27中顯 粒狀或 鋁的高 23的左圖表係氫氧化鈉的濃度爲15%且使 此圖表與圖19及圖20，鹼離子水、天然水 生氫之前花費12分鐘、6分鐘、12分鐘的 氫的時間爲37分鐘、45分鐘、26分鐘。相 係在產生氫之前爲3分鐘，繼續產生氫直 液耗盡爲止。如此地，由圖1 9及圖2 0的表 可知，作爲產生氫用的水，與鹼離子水、 相比，較宜使用創生水》 2 3的右圖表係氫氧化鈉的濃度爲1 5 %且使 此圖表與圖19及圖20，鹼離子水、天然水 生氫之前花費2分鐘、1分鐘、2分鐘的時 的時間爲25分鐘、28分鐘、20分鐘。相對 在產生氫之前爲20秒，繼續產生氫的時間 。如此地，由圖19及圖20的表與圖22的右 產生氫用的水，與鹼離子水、天然水、自 使用創生水。如以上，由圖1 9及圖2 0的表 圖表可明知，產生氫之前的時間係短，氫 係長，宜使用創生水當作水。 次，以所使用的水爲創生水、自來水 '鹼 的4種類之水，氫氧化鈉的濃度爲〇 %、1 °/ 鋁爲鋁九與鋁粉末的2種類，進行實驗。 示該實驗結果。圖2 4至圖2 7係在容器內的 小片的鋁或鋁粉，於加入氫氧化鈉水溶液 度以上爲止之狀態下進行實驗的結果。 用鋁九者 、自來水 時間，繼 對於此’ 到氫氧化 與圖2 3的 天然水' 用鋁球者 、自來水 間，繼續 於此’創 爲時間爲 圖表可知 來水相比 與圖21至 的繼續產 離子水、 >、3% 的 3 圖2 4至圖 底部加入 直到覆蓋 -43- 201132582 圖24係使用鋁九，顯示以氫氧化鈉的濃度爲0%、1 % ' 3 %的3種類，以水爲創生水、自來水、鹼離子水、天然 水的4種類之實驗結果的表。圖25係顯示圖24之表的一部 分之圖表。 圖25的左圖表係氫氧化鈉的濃度爲1%且使用鋁九者。 根據此圖表與24的表，於氫氧化鈉的濃度爲1%且使用鋁九 者中，創生水、自來水、鹼離子水與天然水的4種類皆不 產生氫氣" 圖25的右圖表係氫氧化鈉的濃度爲3%且使用鋁九者。 由此圖表與圖24的表可知，自來水、鹼離子水、天然水皆 不產生氫。相對於此，創生水係在產生氫之前花費40分鐘 ，在產生氫之後繼續產生氫，直到氫氧化鈉水溶液耗盡爲 止。 圖26係使用銘粉末（使銘九成爲粉末者）^顯不以急 氧化鈉的濃度爲〇%、1%、3%的3種類，以水爲創生水、自 來水、鹼離子水、天然水的4種類之實驗結果的表。圖27 係顯示圖26之表的一部分之圖表。 圖2 7的左圖表係氫氧化鈉的濃度爲1 %且使用鋁粉末者 。根據此圖表與圖26的表，自來水、鹼離子水、天然水係 在產生氫之前無反應、花費30秒、60秒的時間，繼續產生 氫的時間爲無反應、6分鐘、4分鐘。相對於此，創生水係 在產生氫之前爲10秒，繼續產生氫的時間的爲10分鐘。如 圖27的左圖表所示，雖然繼續產生氫的時間爲10分鐘，但 此係氫產生直到容器內的氫氧化鈉水溶液耗盡爲止者。此 -44- 201132582 實驗係在容器中裝有氫氧化鈉水溶液的實驗’容器內的氫 氧化鈉水溶液耗盡的時間爲1 〇分鐘，明顯地若容器大的話 ，則繼續產生氫的時間爲1 〇分鐘以上。如此地’由圖26的 表與圖27的左圖表可知，作爲產生氫用的水’與自來水、 鹼離子水、天然水相比，宜使用創生水。再者’於氫氧化 鈉的濃度爲1 %時，氫係產生直到氫氧化鈉水溶液耗盡爲止 ，實驗的結果爲氫氧化鈉的濃度若是0.1 %以上的話，則氫 就產生。 圖2 7的右圖表係氫氧化鈉的濃度爲3 %且使用鋁粉末者 。根據此圖表與圖26，自來水、鹼離子水、天然水係在產 生氫之前花費3 0秒、1 5秒、1 5秒的時間，繼續產生氫的時 間爲40分鐘、45分鐘、45分鐘。相對於此，創生水係在產 生氫之前爲瞬間，繼續產生氫的時間爲90分鐘。如圖27的 右圖表所示，雖然繼續產生氫的時間爲90分鐘，但此係氫 產生直到氫氧化鈉水溶液耗盡爲止者。此實驗係在容器中 裝有氫氧化鈉水溶液的實驗，容器內的氫氧化鈉水溶液耗 盡的時間爲90分鐘，明顯地若容器大的話，則繼續產生氫 的時間爲90分鐘以上。由於氫氧化鈉的濃度爲3%以上時， 則瞬間產生氫，故於需要瞬間產生氫的情況中，使用創生 水的氫氧化鈉水溶液係最合適。 如此地，若根據圖26的表與圖27的右圖表來進行，與 使用鹼離子水、天然水、自來水的氫氧化鈉水溶液相比， 使用創生水的氫氧化鈉水溶液係氫的產生量多，而且僅使 用創生水的氫氧化鈉水溶液係瞬間產生氫。由此結果可知 -45- 201132582 ，作爲產生氫用的水，與鹼離子水、天然水、自來水相比 ，使用創生水者係較優異。特別地，若鋁爲粉、氫氧化鈉 濃度爲3%以上的話，就可瞬間產生氫，而且可長時間產生 氫。 鋁66與氫氧化鈉水溶液反應產生反應熱，藉由此反應 熱，由氫氧化鈉水溶液中之創生水來產生氫，氫氧化鈉水 溶液係徐徐地減少。另一方面，鋁66溶化成爲殘留物。殘 留物係80〜90%爲氫氧化鋁。鋁66溶化成殘留物，若得不 到反應熱，則必須用新的鋁6 6來替換棚架6 2上的殘留物。 實施例4 其次，說明本發明的氫製造裝置之另一實施例（實施 例4)。於實施例1的裝置（圖5)、實施例2的裝置（圖12 )、實施例3的裝置（圖1 5 )中，產生氫的結果係鋁66溶 化而在容器60內成爲殘留物殘留。因此，於容器60內若氫 不產生而殘留物大量積存，則必須由容器60內取出殘留物 ，將新的鋁66加入容器60，無法在不中斷下產生氫。例如 以氫爲汽車的燃時，若無法在不中斷下產生氫，則在途中 汽車有發生無法行駛之虞。 此處，以圖28至圖30爲基礎來說明實施例4的氫製造 裝置。此實施例4係可永續地產生氫之裝置。 此實施例4所使用的水係創生水成爲鹼性的鹼性創生 水。鹼性創生水係考慮使中性創生水與鋁粉末77反應產生 氫後的創生水，或於創生水中混合有氫氧化鈉的氫氧化鈉 -46- 201132582 水溶液。容器78係在內部容納氫氧化鈉水溶液與鋁66者。 谷益7 8爲上部開口的杯形，該上部開口部係被漏斗狀的蓋 82 (視爲容器78的一部分）所封閉。容器78的側面與底面 的外側係被絕熱材80所覆蓋，以防止容器78的溫度朝向大 氣而降低。於漏斗狀的蓋82之上方安裝第一閥手段84 ,於 第一閥手段84之上安裝筒狀的連絡管86，於該連絡管86之 上安裝第二閥手段8 8，於該第二閥手段8 8之上安裝儲存大 量的粒狀或小片之鋁66的料斗90。第一閥手段84係連絡遮 斷蓋8 2的內部空間與連絡管8 6的內部空間，第二閥手段8 8 係連絡遮斷連絡管86的內部空間與料斗90的內部。第一閥 手段84係藉由第一馬達92而作動，第二閥手段88係藉由第 二馬達9 4而作動。 蓋8 2或料斗90係成爲固定在未圖示的構件之狀態，容 器78係對於蓋82藉由螺合等的裝卸手段而可自如地裝卸。 於容器78的內部安裝有底筒狀且具有剛性的網構件96。網 構件96的底部係配置在容器78的內部之稍深的位置。網構 件96係以氫氧化鈉不侵蝕的金屬或合成樹脂爲材料。網構 件96的網目之大小係不使粒狀或小片的鋁66通過，而使鋁 66溶化後的渣之殘留物落到下方的程度之大小，例如宜爲 3〜4毫米程度的大小，但網目的大小係不受此所限定。 在漏斗狀的蓋82之內部空間（容器60的內部空間）具 備作爲冷卻手段的冷卻管98，該冷卻管98的兩端係到達蓋 82的外部。冷卻管98宜在蓋82的內部空間中成爲線圈狀。 冷卻管9 8的兩端例如連接汽車的散熱器，冷卻用的液體或 -47 - 201132582 氣體等的流體在冷卻管98的內部通過’以將蓋82的內部空 間之氣體（氫）冷卻。在蓋82的冷卻管98之安裝位置的上 方，安裝用於將容器78內所產生的氫取出到外部之氣體排 出通路100。容器78與該蓋82所包圍的容器之內部空間係 僅連絡第一閥手段84所開關的連絡管86之內部空間與氣體 排出通路1 0 0。 其次，說明將料斗90內的鋁66供應給容器78內的程序 。首先，於關閉第一閥手段84的閥（未圖示）之狀態下， 打開第二閥手段8 8的閥（未圖示）。藉此，將料斗90內的 鋁66供應給連絡管86的內部空間。然後，關閉第二閥手段 88的閥（未圖示）。於容器78內需要新的鋁66時，打開第 一閥手段84的閥，將連絡管86之內部空間所積存的鋁66投 入容器78內。已投入容器78內的鋁66，係被網構件96所接 住而積存在該網構件96的底部。然後，關閉第一閥手段84 的閥，接著打開第二閥手段88的閥，在連絡管86的內部空 間中導入料斗90內的鋁66。之後，關閉第二閥手段88的閥 。藉由重複此操作，可在容器78內的網構件96之底部上， 間歇地投入一定量的鋁66。將料斗90內的鋁66投入容器78 內的鋁投入手段，係由第一閥手段84、第二閥手段88、連 絡管86與料斗90所構成。但是，鋁投入手段的構成構件係 不受此等構成所限定。 容器7 8內的鹼性創生水之液面1 〇2係設定在比投入網 構件96的底部之鋁66的上面還高的位置。在容器78內鋁66 與鹼性創生水接觸，產生鋁6 6與鹼性的創生水的反應熱， -48- 201132582 而產生氫。 其次，圖29中顯示由容器78內所產生的氣體中取出氫 的裝置。於容器78內生成大量的氫，但含有該氫連同水蒸 氣與微量的氧。含有大量的氫之氣體係由容器78通過氣體 排出通路1〇〇而排出到外部（圖28 )。由氣體排出通路1〇〇 所排出的氣體係如圖2 9所示，與冷卻器1 〇4之內部所具備 的冷卻管1 06連絡。在冷卻器1 04內具備冷卻液（冷卻用流 體）1 08，此冷卻液1 08係藉由未圖示的循環系統（例如汽 車的散熱器等），進行往冷卻器104的外部之排出與由外 部往冷卻器1 04內的流入。再者，如圖2 8所示，在蓋8 2的 內部空間具備冷卻管98，可具備此冷卻管98與冷卻器1 04 的任一個，也可具備兩者，任一方式皆可。 接近冷卻器104，具備液體槽110。前述冷卻管106的 另一端係與在冷卻器1 04的外部之連絡管1 1 2的一端連絡’ 該連絡管1 1 2的另一端係插入液體槽1 1 〇的內部。於插入液 體槽1 1 0的內部的位置之連絡管1 1 2上，形成多數用於將氣 體放出到外部的孔（未圖示）。於液體槽Π 〇中’加入創 生水或氫氧化鈉水溶液（由創生水與氫氧化鈉所成的水溶 液）。液體槽η 〇的上部係被蓋所封閉’液體槽11 〇的內部 之上部係通過連絡管U 4的一端而與外部連絡。 鄰接於液體槽1 1 〇，具備乾燥器1 1 6。在乾燥器1 1 6的 內部容納多數的矽凝膠等的乾燥材118。前述連絡管114的 另一端係水平地配置在乾燥器1 1 6的底部附近，在連絡管 1 1 4的乾燥器1 1 6內之底部附近所水平配置的地方’形成多 -49- 201132582 數的孔（未圖示）。在乾燥器116的上部，具備連絡內部 與外部的氫取出管120。 說明圖29。容器78內所產生的氣體（高溫）係如圖16 或圖17所示，大部分是氫，但含有若干的水蒸氣與若千的 氧。用冷卻器1 〇4冷卻高溫的氣體，然後，使已冷卻的氣 體通過液體槽Π0之中。氣體中所含有的水蒸氣被此液體 槽110所吸收。氣體中所含有之若千的氧係被創生水或氫 氧化鈉水溶液所吸收。又，按照需要，亦可串聯通過幾個 液體槽110。如此地，於容器78所產生的氣體（由含有水 蒸氣與若干的氧之氫所成）中，可藉由使水蒸氣或若干的 氧通過容納有創生水或氫氧化鈉水溶液的液體槽1 1 〇內之 液體中而被去除，僅成爲氫。 藉由液體槽110去除水蒸氣與氧後的氣體，係僅成爲 氫。然後，將氫導入乾燥器116的內部，通過矽凝膠等的 乾燥材118以去除水分（通過液體槽110的氫氧化鈉水溶液 之際的水分），由氫取出管1 20取出到外部。 實施例5 其次，以圖30爲基礎來說明於不停止氫的產生下，將 容器78內所積存的殘留物由容器78內去除之裝置。此裝置 所使用的水係與前述者相同，使用創生水成爲鹼性的鹼性 創生水。於實施例5的裝置中，在容器78的底部附近，具 備與該容器78在2個地方連絡的環狀液體循環通路122。以 液體循環通路122之與容器78的一側之連絡地方爲第一連 -50- 201132582 絡點124 ’以液體循環通路122之與容器78的另—側之連絡 地方爲第二連絡點1 2 6。於由第一連絡點i 2 4到第二連絡點 126爲止的液體循環通路I22之途中，自接近第一連絡點 1 2 4的位置起，依順序具備第1電磁閥〗2 8、作爲殘留物捕 捉手段的過濾器1 3 0、第1泵1 3 2、容納鹼性創生水的槽！ 3 4 、第2泵136、第2電磁閥138。再者，第2泵136與第2電磁 閥1 3 8的位置亦可爲前後。在液體循環通路1 2 2內，鹼性創 生水係由第一連絡點124向第二連絡點126流動。此處，作 爲將鹼性創生水供應到容器7 8用的液體投入手段，係由自 槽1 3 4將鹼性創生水導入容器7 8用的第2泵1 3 6與由第2電磁 閥1 3 8所構成。再者，液體投入手段係不限於此構成。作 爲用於由容器7 8取出鹼性創生水與殘留物的液體取出手段 ’係由第1電磁閥1 2 8與第1泵1 3 2所構成。再者，液體取出 手段係不限於此構成。 藉由液體投入手段將新的鹼性創生水供應給容器7 8內 時，關閉第1電磁閥128，同時打開第2電磁閥138，使第2 泵1 3 6作動。藉此，由槽1 3 4內取出新的鹼性創生水，經由 液體循環通路122將鹼性創生水供應給容器78內。 投入容器78內的網構件96之鋁66，係與鹼性創生水反 應，溶化而變小，由網構件96的網目落下至下方，作爲殘 留物積存在容器78內的底部。茲說明由容器78內去除此殘 留物的程序。鋁66的殘留物係積蓄在容器78內的底部，當 由容器78內取出它時，打開第1電磁閥1 28，同時使第1泵 1 3 2作動。第！泵1 3 2的抽吸力係通過液體循環通路1 2 2至容 -51 - 201132582 器78內，及由容器78內將鹼性的創生水連同殘留物取出到 容器78的外部。於第1泵132所抽吸的鹼性創生水與殘留物 之中，殘留物係被殘留物捕捉手段的過濾器1 30所捕捉， 鹼性創生水係藉由過濾器130去除灰塵等而到達槽134，積 蓄在槽134中。由容器78內所取出的殘留物係被過濾器130 所捕捉，藉由交換過濾器1 3 0而去除殘留物。於此殘留物 的去除之際，容器78內的鹼性創生水之液面102 (圖28 ) 若降低到指定的高度爲止，則打開第2電磁閥138，同時使 第2泵13 6作動，以對容器78內供應新的鹼性創生水。於槽 134中，經常查核pH的濃度，視需要可供給氫氧化鈉。 於容器78內，用網構件96來保持鋁66，由於將鋁66的 殘留物積存在容器78的底部，藉由具備通過容器78的底部 附近之鹼性創生水的循環構造，可由容器7 8內排出殘留物 ，對容器78內供應新的鹼性創生水。由容器78內排出殘留 物與對容器78內供應新的鹼性創生水者，係可在不停止來 自容器78的氫產生下進行。因此，可繼續地產生氫，作爲 汽車用的燃料，可適合於不中斷地使用之情況。 【圖式簡單說明】 圖1係顯示本發明的氫之製造方法中所使用的製作特 殊水（創生水）之製造裝置的一例之構成圖。 圖2係用於圖1中所示製造裝置的水生成器之截面圖。 圖3係用於圖1中所示製造裝置的離子生成器之主要部 分截面圖。 -52- 201132582 圖4係顯示本發明的氫之製造方法中所使用的製作特 殊水之製造裝置的另一例之構成圖。 圖5係顯示本發明之產生氫的裝置之一例的截面圖。 圖6係顯示將100重量的特殊水（創生水）與1 〇重量的 鋁粉末置入容器內，於容器內的溫度爲3 〇°C以上的狀態下 ，容器內的氫之產生。/。的測定分析成績書。 圖7係顯示將1 〇 〇重量的創生水與1 〇重量的鋁粉末置入 容器內.於容器內的溫度保持8 0 °C以上的狀態下’容器內 的氫之產生％的測定分析成績書。 圖8係顯示創生水的PH値之計量證明書。 圖9係顯示一旦使創生水與鋁產生氫後之創生水的p Η 値之計量證明書。 圖10係顯示將100重量的鹼離子水與重量的鋁粉末 置入容器內，於容器內的溫度爲30°C以上的狀態下，容器 內的氫之產生％的測定分析成績書。 圖11係顯示將100重量的鹼離子水與10重量的鋁粉末 置入容器內，於容器內的溫度保持8 0 °C的狀態下，容器內 的氫之產生％的測定分析成績書。 圖丨2係顯示本發明之產生氫的裝置之另一例的截面圖 〇 圖1 3係顯示於圖1 2的裝置中，使用創生水與鋁，進行 加熱而產生的氫之產生％的測定分析成績書。 圖1 4係顯示於圖1 3的裝置中，藉由加熱手段加熱在創 生水中加有氫氧化鈉的氫氧化鈉水溶液與鋁而產生的氫之 -53- 201132582 產生％的測定分析成績書。 圖15係顯示本發明之產生氫的裝置之其它例的截面圖 〇 圖16係顯示圖15的氫產生裝置內之氫氧化鈉濃度爲5% 時所產生的氫之產生％的第1測定分析成績書。 圖17係顯示圖15的氫產生裝置內之氫氧化鈉濃度爲 10%時所產生的氫之產生％的第2測定分析成績書》 圖〗8係顯示圖15的氫產生裝置內之氫氧化鈉濃度爲 15 %時所產生的氫之產生％的第3測定分析成績書。 圖19係顯示使用氫氧化鈉濃度5%、10%、15%的各種 水（鹼離子水與天然水）與鋁，使反應時的氫產生之反應 開始時間與反應繼續時間之表。 圖20係顯示使用氫氧化鈉濃度5%、10%、15%的各種 水（創生水與自來水）與鋁，使反應時的氫產生之反應開 始時間與反應繼續時間之表。 圖2 1係使圖1 9或圖20所示的表成爲圖表者，氫氧化鈉 濃度爲5 %。 圖22係對應於圖19或圖20所示的表者，其係氫氧化鈉 濃度爲10%之圖表。 圖23係對應於圖19或圖20所示的表者，其係氫氧化鈉 濃度爲1 5 %之圖表。 圖24係顯示使用氫氧化鈉濃度爲〇%、1%、3%的氫氧 化鈉水溶液與鋁（九）時，氫產生的反應開始時間與反應 繼續時間之表。 -54- 201132582 圖2 5係以圖表顯示使用圖2 4所示的氫氧化鈉濃度爲1 % 與3 %的氫氧化鈉水溶液之氫產生的反應開始時間與反應繼 續時間之表者。 圖2 6係顯示使用氫氧化鈉濃度爲〇 %、〗％、3 %的氫氧 化鈉水溶液與鋁粉末時，氫產生的反應開始時間與反應繼 續時間之表。 圖2 7係以圖表顯示圖2 6所示的氫氧化鈉濃度爲1 %與 3 %的氫氧化鈉水溶液時氫產生的反應開始時間與反應繼續 時間之表者。 圖28係顯示本發明的氫產生裝置之實施例者，其係可 適宜供給鋁之氫產生裝置的截面圖。 圖29係由圖28顯示的氫產生裝置所產生的氣體中僅取 出氫之構造。 圖3 0係顯示本發明的氫產生裝置之另一實施例，其係 可適宜供給鹼性的創生水之氫產生裝置的系統圖。 【主要元件符號說明】 1 〇 :第一軟水生成器 1 2 :第二軟水生成器 14 :離子生成器 1 6 :岩石收納器 3 2 :離子交換樹脂 46 :電氣石 48 :金屬 -55- 201132582 54 :岩石 60 :容器 66 :鋁 6 9 :加熱手段 7 5 :創生水 7 7 :鋁粉末 78 :容器 82 :蓋 84 :第一閥手段 8 6 :連絡管 88 :第二閥手段 96 :網構件 98 :冷卻管 104 :冷卻器 106 :冷卻管 122 :液體循環通路 1 2 8 :第一·電磁閥 1 3 0 :過濾器 1 32 :第一泵 1 34 :槽 1 36 :第二泵 1 3 8 :第2電磁閥 -56Cl + e· — C1— . . . . . . (4) The Cr and the Na + system are in a stable state as ions. The so-called stable state means that the ion state is maintained for a long period of time without evaporating. Further, the hydroxide ions (Η3〇Γ) are also in a stable state as ions. By passing water through the rock 54, hydrogen hydroxide ions (Η30+) are further generated as compared with the water having passed through the ion generator 14, and hydrogen hydroxide ions (Η302·) and hydrogen ions (Η+) are further produced. H20 + Η+ — Η30+ . . . . . . ( 2 ) H30 + + H20 — H302- + 2H+ . . . . . . (3) The following reaction also occurs by passing water through the rock 54. -20- 201132582 OH' + H+ _ h20 ......(5) 2H+ + 2e' 2H2 . . . . . . (6) Further, if the water passes through the rock receiver 16, the oxidation-reduction potential of the negative electron 'water of the rock 54 is changed from +340 mV to -20 to -24 〇mV. If hot water is used instead of water, the negative redox potential is more stable. Further, the water system that has passed through the rock 54 contains a large amount of dissolved oxygen or active hydrogen. As shown in Fig. 1, the water system first passes through the ion exchange resin', passes through the tourmaline 46 (or the mixture of the tourmaline 46 and the metal 48), and then passes through the rock container 16 to make special water (created water). The creation water contains many Na+, Cl·, H+, OH. H2, hydronium ion (H3〇+), hydrogen oxygen ion (H3〇2_), active hydrogen and dissolved oxygen. The energy of this water is 0. 004 watt/cm 2 , an electromagnetic wave having a wavelength of 4 to 14 μm has an oxidation-reduction potential of -20 to -240 mV. As the water used in the method for producing hydrogen of the present invention, water is used to pass through the ion exchange resin 32, the tourmaline 46 (or a mixture of the tourmaline 46 and the metal 48), and the water of the rock 54. In Fig. 1, the water system passes through the ion exchange resin 32, the tourmaline 46 (or the mixture of the tourmaline 46 and the metal 48), and the rock 54 in this order, but the water may have been passed through the ion exchange resin 32 and the rock 54 in this order. , tourmaline 46 (or a mixture of tourmaline 46 and metal 48). That is, as shown in FIG. 4, the water may be sequentially passed through the first soft water generator 10, the second soft water generator 12, the rock receiver 16 and the ion generator 14° in FIG. 4, and the ion exchange has been performed. The water system of resin 32 then passes through rock 54. By this rock 54, an e (negative electron) is generated inside the water. • 21 - 201132582 As a result, chlorine contained in tap water is a chloride ion by a negative electron. Cl + e' -> CT . . . . . . (4) Na+ generated by this Cl· and ion exchange resin 32 is in a stable state as an ion. Further, the water which has passed through the ion exchange resin 32 may also contain Na + . In the water which has passed through the ion exchange resin 32, as shown in the above (1) and (2), H + and hydrazine and hydronium ion (H30+ ) are present. The water that has passed through the ion exchange resin 32 then passes through the rock 54 and the following reaction also occurs OPT + H+ — H20 ( 5 ) H 2 〇 + H + — H30 + ( 2 ) 2H + + 2e · 2H 2 ( 6 ) in this reaction The hydronium ion (H30+) is produced in an amount more than that produced by the ion exchange resin 32. As described above, after the ion exchange resin 32, by the passage of the rock 54, the presence of the conventionally existing Na+ and OH· and the newly produced Cl_ and hydronium ion (H30+) are formed in the water. Further, the redox potential of the water having passed through the rock 5 4 is -2 0 to -240 mV. If hot water is used instead of water, the negative redox potential is more stable. Further, the water system that has passed through the rock 54 contains a large amount of dissolved oxygen or active hydrogen. The water that has passed through the rock 54 is then passed through the interior of the ion generator 14 in which the tourmaline 46 and the metal 48 are contained. Thereby, the following reaction occurs. H20 H + + OH' . . . . . . ( 1 ) Η 2 Ο + Η + —* Η 3 Ο + . . . . . . (2) -22- 201132582 This hydronium ion (H3o+) is produced in large quantities. Further, a part of the hydrated hydrogen ion (H30+) becomes a hydroxide ion (H3021. H3〇+ + H2O ~^ Η 3 0 2 + 2 Η + . . . . . . (3) As a result, in the water which has passed through the tourmaline 46 and the metal 48, the hydrated hydrogen ion (Η30+), the hydroxide ion (Η302_), the ΟΗ· and the Η+ system are increased. As shown in Fig. 4, water has passed through the ion exchange resin 3, rock 54, tourmaline 46 (or a mixture of tourmaline 46 and metal 48) in sequence, containing Na+, Cl-, ΟΗ·, hydronium ions. (Η30+), hydroxide ion (Η302·), Η+, dissolved oxygen and active hydrogen, containing the same components as the creation water produced in Fig. 1. Furthermore, it has a flaw. 〇〇 4 watt / cm 2 of energy 4 ~ 14 micron electromagnetic wave with -20 ~ 24 OmV redox potential. As a result, the water produced in Figure 4 has the same effect as the created water system of Figure 1. Since the water system generated by the device of FIG. 4 is the same as the result of the water generated by the device of FIG. 1 in the water, the water generated by the device of FIG. 4 is also the water of the created water. Water quality inspection results. The water in the brackets shows the tap water compared to the created water. However, the same enthalpy in tap water as the creation water is “identical”. Nitrous acid nitrogen and nitrate nitrogen: 1 . 8mg/l (same), gas ion: 6. 8mg/l (9_0mg/l), one fine: 〇 /ml (same), cyanide: not up to O. Olmg/Ι (same), mercury: not up to 0. 0005mg/l (same), organic phosphorus: not up to 0. 1m g / Ι not reached (same), copper: not up to 〇. 〇lmg/l (same), iron: not up to 〇. 〇5mg/l (not up to 0. 08mg/l), manganese: not up to 0. 01mg/l (same), zinc: not up to 0. 005mg/l (not up to 〇. 〇54mg/l), lead: not up to 0_01mg/l (same) -23- 201132582, hexavalent chromium: not up to 〇. 〇 2mg / l (same), cadmium: not up to 〇. 005mg/l (same) 'arsenic: not reached. 〇〇 5mg / l (same), fluorine: not up to 0. L5mg / l (same), calcium ions, magnesium ions, etc. (hardness): 1. 2mg/l ( 49. 0mg/l), phenols: not up to 〇. 〇〇 5mg / l (same), anionic sea surface active agent: not up to 〇. 2mg/l (same), pH値: 6. 9 (same), odor: no odor (same), taste: no odor (same), color: 2 degrees (same), turbidity: twist (1 degree). The created water system has many of the features listed below. (a) Contains hydronium ions (H30+), hydroxide ions (h302-), hydrogen ions (H+) 'hydrogen, hydroxyl (〇『), sulfate ions (S042·), hydrogen carbonate ions (HCOT), carbonate ions ( C032·), hexamic acid (H2Si03) and free carbon dioxide (C02). (b) has an interfacial activity. It has an interfacial activity (OW type germination effect). (c) has a weak energy (cultivating light) effect. The tourmaline emits weak energy (electromagnetic waves of 4 to 14 microns wavelength). This weak energy cuts off large clusters of water, and the toxic gases or heavy metals held in the clusters are discharged to the outside by the water. (d) having an oxidation-reduction potential of -20 to -24 0 m V. (e) Containing dissolved oxygen or active hydrogen. (f) Soft water from which calcium ions or magnesium ions have been removed. By passing tap water or the like through the ion exchange resin, calcium ions and magnesium ions contained in the water can be removed. -24- 201132582 Embodiment 1 Next, the hydrogen gas of the present invention will be described based on Fig. 5 . An example of the method for producing hydrogen gas according to the present invention will be described. The manufacturing apparatus has a container 60 and a lid 61 of the container, and is usually used in a state of being closed by the lid 61. Mounted on the cover 61, the nozzle has a contact container interior and a container exterior path 65 formed therein, and a switch 68 is provided in the middle of the nozzle 64. A thermometer 73 for measuring the internal temperature of the internal gas meter 71 of the container 60 and the internal temperature of the measurement container 60 is attached to the upper portion of the container 60. The shape of the container is preferably a conical shape in which the horizontal section is gradually narrowed toward the cover 61. In order to accumulate the light hydrogen gas generated in the container 60, the hydrogen gas is easily taken out from the container 60 to the outside. Below the container, a heating means 69 for heating the container 60 is provided. Further, the segment 69 is not limited to the firepower, and the arrangement position of the thermal means 69 such as sunlight or an electric heater is not limited to the present invention in the bottom surface of the container 60, and special water (creating water powder) is built in the container 60. 77. Heating the generating water 75 and the aluminum powder by the heating means 69 to increase the amount of the aluminum powder 77 in terms of the amount of the creation water 75, so that the aluminum powder 77 is sufficiently impregnated in 75. In order to generate hydrogen, it is used. Two kinds of materials, raw water 7.5 and aluminum powder VII, that is, metal or chemical substances other than aluminum in the container 60, only the artificial powder 7 7 in the container 60 is heated to generate hydrogen. In the first example, it is described based on the powder of aluminum. The powder is used at the end. The powder of aluminum is used in the western part of Osaka City. ί The manufacturing method of the device container 60 is connected to the pressure of the on-off valve of the nozzle 6 4 Above 60 or the bottom surface of 60 of the pyramidal container 60, heat the hand. Also 'plus r square.' 75 with aluminum powder 77. Filling in the creation of water is only in the middle of the creation of water 75 and aluminum This aluminum powder sold 堀 1 - 2 - -25- 201132582 1 2 where the Yamato Metal Powder Industry Co., Ltd. is commercially available. In the first embodiment, 1 liter of the creation water 75 and 100 g of the aluminum powder 77 were placed in the vessel 60, and the water generating material 75 and the aluminum powder 77 in the vessel 60 were heated by the heating means 69. That is, the weight ratio of the water of creation 75 to aluminum is 10 weights of aluminum and 100 weights of the water for creation. The heating in the container 60 by the heating means 69 is started by heating at a normal temperature (for example, 20 ° C), and the temperature in the container 60 is heated to 30 ° C or higher. At a temperature slightly lower than 30 ° C, hydrogen starts to be generated, but at 3 (TC or more, hydrogen is generated in a large amount in the vessel 60. If the water of creation 75 and the aluminum powder 77 in the vessel 60 are heated to 30 °C or more, the generation of hydrogen is discriminated, but in order to have objectivity, the third party is commissioned to perform measurement analysis of the experimental results. The analysis and analysis results of the analysis results are shown in Fig. 6. Fig. 6 or later of the present invention The results of the analysis and analysis shown in the figure are based on the Shinano Public Health Research Center (Tel. 0267-56-2 1 89) where the No. 1 83 5, Oda-machi, Kitagawa-gun, Nagano Prefecture, Nagano Prefecture, Japan. The measurement analysis report is shown in Fig. 6. In Fig. 6, the creation water 75 and the aluminum powder 77 are added to the container 60, and the temperature in the container 60 is heated to 30 ° C or higher by the heating means 69, and the container 60 is collected in a 10 liter bag. In the reaction between the creation water 75 and the aluminum powder 77, the hydrogen is generated between the heating of the vessel 60 by the heating means 69, and the heating of the heating means 69 is stopped for a while, and hydrogen does not occur. And when it is less than 80 ° C, the heating of hydrogen is generated to make the container 60 The temperature continues to rise slowly. When heating at the same temperature, hydrogen continues to be generated, but the generation of hydrogen stops. Therefore, the temperature at which hydrogen is generated starts from 30 °C, and the temperature in the vessel 60 continues to rise -26. - The method of 201132582 is heated by a weak fire. Therefore, the temperature in the vessel 60 is 30. (: Above and less than 80 °C, hydrogen can be easily generated or stopped. Hydrogen generated in the vessel 60. It is collected by a 10 liter bag (not shown) attached to the front end of the nozzle 64. The air collected in the container 60 is bubbling before the measurement. The bubbling system allows the collected air to sneak into the air. The water contained in the container (not shown) allows the collected air bubbling to have the effect of removing the moisture contained in the collected air (to separate the gas and water) while cooling the air. The air collected by the temperature of C or higher is bubbled, and the result of measuring the air is the measurement analysis result of Fig. 6. As shown in Fig. 6, the temperature is continuously increased at a temperature of 30 ° C or higher. Heated air It contains 75 % of hydrogen and 5.2 % of oxygen. That is, it is understood that if the container 60 containing aluminum powder 7 7 and the water for creation is kept at a temperature of 30 ° C or higher, the temperature is gradually raised and heated. In the experiment of Fig. 6, the pressure in the vessel 60 is atmospheric pressure (1 atmosphere). 7 Determination and analysis of the results. The temperature in the container 60 is gradually increased from 30 ° C to 80 ° C, if the temperature reaches 80 ° C, above 80 ° C and below the boiling point of the water The temperature maintains the temperature within the vessel 60. The boiling temperature of the created water is 1 〇 2~1 〇 4 t. When the temperature is above 80 ° C and does not reach the boiling point of the water of creation, only heat is generated to generate hydrogen. When the temperature in the vessel 60 is 80 ° C or higher and the temperature of the boiling point of the water is not reached, it is not necessary to continue to increase the temperature. The measurement analysis report of Fig. 7 is such that the air in the container 60 is at a temperature of 80 ° C or higher and the boiling point of the water is not reached, and the air in the container 60 is collected in the literary bag -27 - 201132582. The measured air was bubbled and the measurement was carried out, and it contained 98% hydrogen, and 0. 3 % oxygen. Since the heating temperature is below 80 ° C above the boiling point of the generated water, the pressure in the vessel 60 of Fig. 7 is atmospheric pressure (1 atmosphere). When the temperature in the vessel 60 is 8 Ot or more and the temperature before the boiling point of the water is created, it is not necessary to continuously increase the temperature in the vessel 60, but the temperature in the vessel 60 must be maintained at 80 °C or higher. That is, the heating state must be intermittently performed. When the heating state is stopped and the temperature is 80 ° C or lower, hydrogen does not occur. Therefore, if the temperature in the vessel 60 is maintained at 80 ° C or higher and the temperature between the boiling points of the water of creation is not reached, hydrogen can be generated in a large amount. Further, when the generation of hydrogen is stopped, the heat retention or heating of the container 60 can be stopped to be 80 ° C or lower. Therefore, the generation or the stop of hydrogen can be easily performed. As the temperature rises from 30 ° C to 80 ° C, the content ratio of hydrogen contained in the collected air gradually becomes large. This is known from the fact that the content of hydrogen at a temperature of 30 ° C or higher is 75%, and the content of hydrogen at a temperature of 80 ° C is 98%. Since the hydrogen content of the temperature above 30 °C is also 75%, it is considered that the amount of hydrogen generated is sufficiently large. From 1 liter of the water of creation 75 and 100 g of the aluminum powder 77, hydrogen is generated for 40 minutes to 50 minutes. In this embodiment 1, about 2 is produced per gram of the aluminum powder 77. 0 liters of hydrogen. In the creation water, it contains hydronium ions (H30+) or hydroxide ions (Η3〇Γ) or hydrogen ions (H+) or hydroxide ions (ΟΗ·), etc., from their hydronium ions (Η30+) or hydroxide ions. (Η302·) or hydrogen ion (Η + ) or hydroxide ion (ΟΙΤ) generates hydrogen, so compared with water such as tap water, natural water, alkali ion water, etc., it is considered that the generated water can produce a lot of hydrogen - 28- 201132582 The generation of hydrogen by reacting water between creation and aluminum is caused by the fact that aluminum should produce hydrogen', and the surface of the aluminum is covered with an oxide film, and the generation of hydrogen is stopped by the film. Hydrogen was produced by creating water 7 5 with aluminum powder 7 7 for 50 minutes. When tap water or the like is used instead of the creation water, the time for generating hydrogen is zero or sufficiently short. Therefore, it is understood that the retardation of the oxide film formed on the surface of the aluminum film on the surface of the aluminum powder 77 can be remarkably retarded by 75, but it is presumed whether or not the hydroxide ion (Η 3 Ο 2 ·) is long. The adhesion to the surface of the aluminum powder 7 7 is prevented. When no hydrogen is formed on the surface of the aluminum, if the generated water 75 remains in the container 60, the end 77 is discharged or not discharged from the container 60, and as long as the powder 7 7 in the container 60, hydrogen is generated again. The weight of the aluminum powder 77 placed in the container 60 is 5 weight or more for the genus 5 (5 〇 g or more for 1 liter of the creation water). The weight 5 of the aluminum powder 77 placed in the container 60 is not suitable for practical use because the amount of hydrogen generated is extremely small. The optimum weight range is 1 〇 or more (1 对g or more for 1 liter of water at the end of the creation) to the amount of liquid of the aluminum powder 77 to the creation water. When the aluminum powder 77 is less than 10% by weight, the amount of hydrogen generated is less than that of hydrogen. When the amount of the aluminum powder 77 exceeds 30%, the amount of hydrogen generation hardly changes, and the cost of the aluminum powder is 7,7, so that it is 10 to 30% by weight. As described above, in the present invention, the creation water time is used by reacting the created water with the creation water against the oxidation for 40 minutes to aluminum. Significantly, although the aluminum oxide powder is added to the aluminum oxide powder, the aluminum powder is added to the new aluminum trihydrate, and the weight of the aluminum powder is 10 weights. The amount of time is 30 with the temperature of the container 60 of 30 heavy-weight powder and 7 5 and aluminum powder • 29 - 201132582 77. At or above the temperature, hydrogen can be produced. In order to increase the temperature in the container 60, the heating means 69 may be used to heat the container 6' or to add heated wound water. When the temperature in the heating vessel 6 is above 30 °C and less than 80 °c, 'the temperature must continue to rise during the heating vessel 6 '' but above 80 °C and the water is not created. The temperature in the heating vessel 60 between the boiling points does not necessarily need to continue the temperature rise, and the temperature can be maintained at a temperature of 8 〇 ° C or more and less than the boiling point of the water, and the temperature adjustment of the heating means 6.9 is simple. Furthermore, the amount of hydrogen generated between the above 8 〇 and below the boiling point of the non-creating water is less than the amount of hydrogen generated at temperatures above 3 〇 ° C and below 8 〇 ° C. Much. In the first embodiment of the present invention, since the creation water 75 and the aluminum powder 77 are used as raw materials, they are heated in the container 60 under atmospheric pressure to generate hydrogen, so that a device resistant to high pressure is not required, and the device is inexpensive and can be obtained in a large amount. Hydrogen. By means of the apparatus shown in Fig. 5, 1 liter of the creation water 75 and 100 g of the aluminum powder 77 are initially charged in the vessel 60, and heated at 80 ° C or higher and below the boiling point of the water of creation to maintain 80 °. At a temperature higher than C, hydrogen is present for 40 minutes to 50 minutes. In the state where hydrogen does not appear, an oxide film is formed on the aluminum powder 77 in the container 60, and the aluminum powder 77 causes a hydrogen generation effect to be deteriorated, but the container 6 is inside. There is a large amount of created water 75. Therefore, in order to regenerate hydrogen, in a state where hydrogen does not occur or in a state where hydrogen continues to occur, for example, if a new aluminum powder 77 is added to the container 60 at a temperature of 8 or more, the water 75 and the new water are created. The additional aluminum powder 77 is reacted to generate hydrogen again. When the oxidized film is formed on the aluminum powder 77 and hydrogen is not generated, the operation of the device is stopped, and it is assumed that the hydrogen generation operation is resumed the next day. 201132582, the temperature of the created water in the container 60 is lowered to the outside air temperature (for example, 丨〇乞~20 ° C). Although the temperature in the container 60 is the outside air temperature, if the new aluminum powder is 7 7 When it is added to the container 60, the aluminum powder 7 7 reacts with the water-generating water in the container 60. Even if the heating means 69 is not performed, the temperature inside the container 60 rises to 80 ° C to 90 ° C. Then, even The inside of the container 60 is not heated, and the temperature in the container 60 is maintained at 80 ° C to 90 ° C to generate hydrogen. When the aluminum in the container 60 does not function, only aluminum (heating without the heating means 69) may be added to make the container The temperature in 60 rises to 8 (TC~90 °C and remains at this temperature) It is a powder of only aluminum. When the aluminum is in the form of granules or small pieces, the temperature in the container 60 must be frequently heated by the heating means 6 9 to a temperature below the boiling point of the water of creation above 80 ° C. When new water is added to the container 60 without creating water, it is necessary to reheat the container 60 by the heating means 69. However, a new one is added in the state where the water is left in the container 60. When the water is created, in the case of the aluminum powder 77, the heating means 6 9 may be used to heat the inside of the container 60. Here, when the new aluminum powder 77 is added to the container 60 remaining in the creation water 75, even if it is not used Heating by the heating means 69, the temperature in the vessel 60 is also raised to 80 ° C to 90 ° C, and the reason for the hydrogen generation. Before that, the creation of the water itself and the aluminum powder 7 7 are generated to produce hydrogen. Fig. 8 is a measurement certificate of the generated water before the generation of hydrogen, and Fig. 9 is a measurement certificate of the generated water after the reaction with the aluminum powder 77 to generate hydrogen. The large changer is pH. As shown in Fig. 8, the pH of the generated water before the reaction with the aluminum powder 77 was 7. 4 (neutral). The pH of the created water after the generation of water and aluminum powder 77 are reacted to produce hydrogen is as shown in Fig. 9 and the creation water system becomes alkaline. That is, the water in which the generated water 7 5 reacts with the aluminum powder 7 7 -31 - 201132582 to generate hydrogen becomes alkaline generation water. Not only the aluminum powder 77, but also the use of granules or small pieces to generate hydrogen, the water is made alkaline. Further, as shown in FIG. 8, the sodium ion contained in the creation water is 26 mg/L, and the sodium ions contained in the creation water in the container 60 after the generation of hydrogen by the creation water and the aluminum powder 77 are raised to a certain extent to 35mg/L. As can be seen from Fig. 8 and Fig. 9, the neutral created water system becomes inspective after reacting with aluminum powder 7 7 to generate hydrogen. As a result, by adding a new aluminum powder 77 to the water which is alkaline in pH, the temperature in the vessel 60 rises to 80 °C to 90 °C. Then, even if the container 60 is heated without heating means, the temperature in the container 60 is maintained at 80 ° C to 90 ° C. If new creation water is added to the creation water remaining in the container 60, the temperature of the container 60 rises to 80 in a short time, depending on the capacity of the container 60 or the amount of the created water. °C ~ 90 °C. Then, even if the container 60 is not heated, the temperature inside the container 60 is maintained at 80 ° C to 9 ° ° C. When the temperature of the additional generation water is, for example, hot water heated to 80 ° C or higher, the temperature in the vessel 60 is not temporarily lowered, so that the generation of hydrogen can be efficiently performed. Here, if alkali ion water is used instead of the creation water, the same experiment as the creation water is performed using alkali ion water based on the estimation that the same result cannot be obtained. First, aluminum powder and alkali ion water are added to the container 60, by The heating means heats the inside of the vessel 60 to 3 (TC or more. The result is shown in Fig. 1). As shown in Fig. 10, it contains 17% of hydrogen and 18% of oxygen. Secondly, aluminum powder and alkali ion water are added to the vessel 60, and The inside of the vessel 60 is heated to 80 ° C or higher by heating means to obtain the result shown in Fig. 11. As shown in Fig. 11, it contains 13% of hydrogen and 30% of oxygen of -32 to 201132582. From the above results, it is known. The amount of hydrogen produced by the reaction between the water of creation 75 and the aluminum powder 77 is sufficiently greater than the amount of hydrogen produced by the reaction of the alkali ionized water with the aluminum powder 77. Therefore, the alkaline generation water and the alkali ion water, hydrogen The production amount is greatly different. Embodiment 2 Next, a second embodiment of the present invention will be described based on Fig. 12. Fig. 1 2 is a cross-sectional view showing an embodiment of the apparatus for producing hydrogen according to the present invention. The material of 60 is, for example, stainless steel, but is not limited to stainless steel. A plurality of scaffolding 62 are provided on the upper and lower sides, and a plurality of small or small pieces of aluminum 66 are placed on each scaffold 62. In most of the scaffolds 62, most of the water is provided without the aluminum 66 falling below. Or a hole (not shown) of a size that can pass through the air. The plurality of scaffolding 62 provided in the container 60 is inserted and exited by a sill (not shown) provided on the side surface of the container 60. A large amount of aluminum 66 (which may be aluminum powder) having a small granular shape or a small piece is provided. A gas discharge passage 65 is provided in the upper portion of the container 60, and a gas system such as hydrogen generated in the container 60 is discharged to the outside through the gas discharge passage 65. The passage 65 is opened and closed by the on-off valve 68. The outside of the container 60 is heated by a heating means 69 such as a heater. Further, the heating means 69' of the inside of the container 60 is heated by the outside of the container 60. In addition to the device, a heating power such as a gas may be used. When the heating means 69 is an electric heater, the outside of the heater is covered with the heat insulating material 76 to prevent the temperature in the container 60 from decreasing toward the atmospheric temperature. The uppermost shed in the container 60 On the shelf 62 If the shower is provided, the water is sprayed on the uppermost scaffold 62 to spread the water-33-201132582 spray means 70. The "water" added to the container 60 is used to create water or to be added in the creation water. Any of sodium hydroxide aqueous solutions having sodium hydroxide. The "aqueous sodium hydroxide solution" in the present invention means "a mixed aqueous solution of water and sodium hydroxide". The aqueous sodium hydroxide solution is alkaline (alkaline In the water injection means 70, the water generating water or the sodium hydroxide aqueous solution is supplied through the water supply path 72, and the water amount adjusting means 74 for adjusting the amount of the supplied water is provided in the middle of the water supply path 72. The upper water spraying means 70, such as a shower method, causes the creation water or the sodium hydroxide aqueous solution to be sprayed downward. The water generated by the water spraying means 70 or the aqueous sodium hydroxide solution passes through the aluminum 66 on the uppermost scaffolding 62 to the scaffold 62 of the next stage, sequentially reaches the lower scaffold 62, and finally reaches the container 60. bottom of. In the invention of the second embodiment, the water which is sprayed into the container 60 by the water jet means 70 is made of a builder water or an aqueous sodium hydroxide solution. That is, in the invention of the second embodiment, the created water is necessarily used. The created water system generates hydrogen at 3 (TC or higher) by contact with aluminum 66, and the amount of hydrogen generated increases from 30 ° C to 80 ° C as the temperature inside the vessel 60 rises. When the internal temperature is 80 ° C or higher, the amount of hydrogen generated is sharply increased as compared with less than 80 ° C. The sodium hydroxide system has an effect of increasing the amount of hydrogen generated by water and causing water to be produced. The effect of reducing the amount of oxygen. When using an aqueous solution of sodium hydroxide, the concentration of sodium hydroxide is as long as 0. More than 1% may be sufficient, and the concentration of sodium hydroxide is preferably about 1% to about 15%, because the amount of hydrogen generated is large or the generation time of hydrogen is short. The concentration of sodium hydroxide may also be 15% or more, but the result is almost unchanged from 1% to 15% of the right and left sodium hydroxide concentration. The water sprayed into the container 60 by the water jetting means 70 may be raw water of No. 34-201132582. On the scaffold 62, in addition to the aluminum 66, the water of the sodium hydroxide is contacted with sodium hydroxide to become hydrogen. When the water in contact with the aluminum 6 6 in the sodium hydroxide water-soluble container 60 is a mixed aqueous solution of sodium hydroxide raw water and sodium hydroxide, it becomes a sodium hydroxide aqueous solution. In the second embodiment of the present invention, an aqueous solution of sodium oxide and aluminum 6 6 are placed in the vessel 60, and the inside of the vessel 60 is heated to 30 ° C or higher by the inside of the vessel 60. The temperature at which hydrogen is generated in a large amount may be 80 ° C or higher. However, since hydrogen generation is also caused, it is considered that a small amount of hydrogen is used. The temperature in 6 〇 is 30 ° C to 80 ° C, and the amount of hydrogen generated is a small amount which is industrially available. In addition, the amount of hydrogen generated can be obtained by the capacity and the sodium hydroxide concentration of the sodium hydroxide aqueous solution described later, and the experimental results of the second embodiment will be described with reference to the measurement and analysis results shown in FIG. 13 and FIG. (Measurement Analysis Report) The inside of the container 60 is made of water, and the sodium hydroxide aqueous solution mixed with sodium hydroxide in the container 60 is added to Fig. 14 . The common content of the "sample name" in Fig. 13 and Fig. 14 is "created without tourmaline, aluminum 100%, (by heating means) plus 0. 07 5MPa". This is a summary of the analysis and analysis of the results of Figure 13 and Figure 14. Here, in the description of Fig. 3 and Fig. 14 "Before, the tourmaline and aluminum have reached the present invention, and water such as tap water is added to the container together with tourmaline to carry out an experiment for generating hydrogen. That is, in the aqueous solution (in the case of creation, "hydrogen-created water or hydrogen-heating means 69, the internal combustion of the vessel 60 is urgently stopped. Therefore, the condition of the vessel is also the temperature regulation in the vessel 60. Based on the book, Fig. 1 3 The Chinese and Canadians have the same conditions for creating water, 100% raw water, heat, 93 °C, and also by the above-mentioned] 0 0%. The results of various -35-201132582 experiments were carried out by adding aluminum 66. When the water for creation or the aqueous solution of sodium hydroxide is only brought into contact with aluminum 6 6 (without tourmaline 76), if the water of creation or the aqueous sodium hydroxide solution in contact with aluminum 66 becomes 30 ° C or more, hydrogen is generated. Further, the water of creation or the aqueous sodium hydroxide solution in contact with the aluminum 66 generates hydrogen when the temperature in the container is 30 ° C or higher, but in order to prove that the water is generated in a large amount by the creation of water and aluminum 66 Hydrogen was produced and the temperature was 93 ° C (above 80 ° C) in the vessel. "Year raw 100%, no tourmaline, aluminum 100% heated (by means of heating means), a temperature of 93 ° C, the pressure in the vessel is zero. Contents of 07 5MPa" The results of the experimental results of the analysis of the results are shown in Figure 1 3 and Figure 14. From these experiments, it was found that hydrogen was generated in a large amount at atmospheric pressure because the temperature was below the boiling point of the created water. According to various experiments, for example, when tap water is used as water, hydrogen is not generated even if it is in contact with aluminum 66 in the container. Here, a comparative review is made on the measurement and analysis of the use of the created water (Fig. 13) and the measurement and analysis of the aqueous solution using sodium hydroxide (Fig. 。). In the measurement and analysis of the use of the created water (Fig. 13), in the gas produced, hydrogen was 83% and oxygen was 3. 8 %, the total amount of hydrogen is 2. 1 liter. In the analysis of the use of sodium hydroxide aqueous solution analysis (Figure 14), in the gas produced, hydrogen is 98%, oxygen is 0. 3%, the total amount of hydrogen is 11. 2 liters 〇 If Figure 1 3 and Figure 14 are compared, then in the water used in Figure 13, the hydrogen is 83% and the oxygen is 3. 8%, in contrast, in the case of using sodium hydroxide solution in Fig. 14, hydrogen is 99%, and oxygen is 0. 3 %. From the above, it has been found that the sodium hydroxide system has an effect of increasing the ratio of generation of hydrogen and reducing the ratio of generation of oxygen. -36- 201132582 In particular, the total amount of hydrogen relative to Figure 13 is 2. In the case of 1 liter, the total amount of hydrogen in Fig. 14 is 1 1 · 2 liters, so that it is known that the amount of hydrogen generated can be greatly increased by mixing sodium hydroxide in the creation water. It is considered that by adding sodium hydroxide, the amount of hydrogen generated is increased, and the amount of oxygen generated is lowered, but when sodium hydroxide reacts with aluminum 66, hydrogen is generated from sodium hydroxide, and oxygen of sodium hydroxide is Aluminum combines to become alumina. Further, in Fig. 12, a plurality of scaffolding 62 are provided in the upper and lower sides of the container 60, and the scaffolding 6 2 is provided with a plurality of granular or small pieces of aluminum 6 6 so that the generated water or the aqueous sodium hydroxide solution is directed upward. Fall below. Instead of this, the scaffold 62 may not be provided in the container 60, and the bottom of the container 60 may be provided with granular or small pieces of aluminum 66 (which may also be powder), and added to the water of creation or sodium hydroxide until the aluminum 66 Cover the height. When hydrogen is generated, if aluminum 66 is exposed in the air, a black oxide film is formed on the surface of the aluminum 66, and the hydrogen generation rate is lowered as time passes, but the aluminum 66 is immersed in the created water or In the aqueous sodium hydroxide solution, the generation of an oxide film of aluminum 66 can be suppressed. When a large amount of hydrogen is generated, aluminum 66 reacts with an aqueous sodium hydroxide solution to continuously generate heat of reaction. By this reaction, the aluminum 66 is slowly dissolved to form a residue (80 to 90% of aluminum hydroxide and 10 to 20% of sodium carbonate). If the aluminum 66 is dissolved and becomes a residue, since the reaction heat is not generated, it is necessary to replace the residue on the scaffold 62 with a new aluminum 66. Embodiment 3 Fig. 1 is a cross-sectional view showing a third embodiment of the apparatus used in the method for producing hydrogen of the present invention. Fig. 15 (Embodiment 3) is different from Fig. 1 2 (Example 2) -37-201132582 in that the heating means 69 provided in the second embodiment is omitted. In the second embodiment, the generating water or the aqueous sodium hydroxide solution in the container 60 is heated by the heating means 69 provided outside the container 60. However, in the third embodiment, the external heating means of the container is omitted. On the other hand, the aqueous solution of sodium hydroxide in the vessel 60 is heated to a temperature of 30 ° C or more in which hydrogen is generated by the heat of reaction in the vessel 60. In the past, in order to obtain hydrogen from water, the water was heated and decomposed by heating means, but in the third embodiment, no heating means was used. In order to bring the inside of the vessel 60 to a temperature of 30 ° C or higher, the temperature in the vessel 60 can be raised to the evaporation temperature of the water (about 104 °) by the reaction heat of bringing the aqueous sodium hydroxide solution into contact with the aluminum in the vessel 60. C) So far. Since the temperature in the container 60 becomes a temperature (30 ° C) or more in which a large amount of hydrogen is generated by the generation of water in contact with the aluminum 66 by the reaction heat, hydrogen can be generated in the container 60. This reaction heat increases the temperature in the vessel 60 to above 80 °C which is produced by a large amount of hydrogen. As a result, in the invention of the third embodiment, hydrogen can be generated even without an external heating means. The concentration of sodium hydroxide in the aqueous sodium hydroxide solution is as long as 0. More than 1% can be. The concentration of sodium hydroxide is, for example, economically preferably from 1 to 15%. The concentration of sodium hydroxide can also be more than 1 5%, but the effect is the same even if the concentration of sodium hydroxide is increased. The amount of hydrogen produced is adjusted by the temperature in the vessel 60 and the concentration of sodium hydroxide in the aqueous sodium hydroxide solution. The concentration of sodium hydroxide is 0. When it is 1% to 5%, generally, if the concentration becomes rich, the amount of hydrogen generated is gradually increased. The heat of reaction between the water and the sodium hydroxide and the aluminum 66 causes the temperature in the vessel 60 to become a temperature in the vicinity of 100 ° C. Therefore, the hydroxide is sprayed by the water spraying means 70 disposed above the vessel 60. In the sodium aqueous solution, the amount of the sodium hydroxide aqueous solution from the water injection means 70 is controlled by a control means (not shown) at the time point of reaching the aluminum 66 at the bottom of the volume -38 - 201132582 . Thereby, the water sprayed from above in the container 60 is evaporated before falling to the bottom of the container 60. The evaporation efficiency of the aqueous sodium hydroxide solution sprayed into the container 60 is good. Further, in Fig. 15, a plurality of scaffolding 62 are provided in the upper and lower sides of the container 60, and a plurality of granular or small pieces of aluminum 66 are provided on the scaffolding 62, and the aqueous sodium hydroxide solution is dropped downward from the upper side. Instead of this, the scaffold 62 may not be provided in the container 60, and the granular or small piece or powdery aluminum 66 may be added to the bottom of the container 60, and the aqueous sodium hydroxide solution is added until the height of the aluminum 66 is covered. 16 to 18 show the results of an experiment in which aluminum 66 was contacted with an aqueous sodium hydroxide solution (a mixed aqueous solution of water and sodium hydroxide) to produce hydrogen using the apparatus of Fig. 15. Figure 1 6 to Figure 8 shows the results of sodium hydroxide concentrations of 5% (Figure 16), 10% (Figure 17), and 15% (Figure 18). The common content of the "sample name" in Fig. 16 to Fig. 18 is "the gas pressure in the container is 0. 007MPa (Judged this is 〇. 〇7MPa error) 'The temperature is 9 3 °C, no tourmaline, aluminum nine, 100% foaming in the creation water, no heating means." The "no tourmaline" in the "sample name" is used to clearly indicate that only the aluminum hydroxide 6' is added to the container 60 in the present invention, and no tourmaline is added. The description of the "aluminum shot" of the "sample name" is explained. Experiments were carried out using aluminum nine and aluminum balls in aluminum. In Figs. 16 to 18, aluminum nine is used. Aluminium Nine is a piece or piece of aluminum material before forming, aluminum is -39- 201132582. The aluminum ball system is formed into a spherical shape. When the iron is added and the shape is formed, the purity of the aluminum itself is lower than that of the aluminum nine. The description of "100% bubbling in the creation water" of the "sample name" means that the gas such as hydrogen generated in the container is taken out from the container, and the internal J is made to pass 100%. By passing a gas such as hydrogen generated in the container through 100% of the inside of the water, the moisture contained in the gas is removed, and the precision of the ratio of each body is further increased. If the results of the analysis according to Fig. 16 to Fig. 18 are analyzed in the case of a 5% hydroxide aqueous solution of sodium hydroxide (Fig. 16), 'hydrogen 9 8 % 0. 3%, the total amount of hydrogen 12. 1 liter. In the case of an aqueous solution of sodium hydroxide in the concentration of sodium hydroxide (Fig. 17), hydrogen is 99% and oxygen is 0. 2°/. The total amount of hydrogen is liters. In the case of a sodium hydroxide aqueous solution having a sodium hydroxide concentration of 1 5%, 8 9 %, hydrogen 〇 3 %, and total hydrogen 1 2 · 3 liters. According to the analysis of the results of the analysis, it is understood that the heating is carried out by the reaction of aluminum 6 6 with an aqueous sodium hydroxide solution without using a heating means for heating the outside of the container, and hydrogen is generated in a large amount of from 98% to 99%. 'Oxygen only ~0. It is produced in a very small amount of 3%. That is, in the present invention, even if the outside of the apparatus is heated by the heating means, the temperature of the aqueous sodium hydroxide solution can be raised to 30 ° C or higher in the hydrogen generation temperature of the generated water by the self-rise of the reaction heat. The created water produces hydrogen. Further, in the sodium hydroxide water, if the temperature is 80 ° C or more, hydrogen can be generated in a large amount. As shown in the measurement analysis report of Fig. 16 to Fig. 18, 98% to 99% of hydrogen is obtained when sodium hydroxide solution in which sodium hydroxide is dissolved in the creation water at a concentration of 5%, and 15% is used. . Here, in Fig. 19 to Fig. 23, it is easy to taste "the raw water creates a seed gas, sodium, and sodium oxide. 5 (Figure, these containers are hot and 0. 2% by temperature, degree (solution 10% water solubility ratio -40-201132582 compared to the use of mixed sodium hydroxide water and the use of the creation of water and other water comparison results. Figure 19 9 to 2 3 results A large amount of granular or small piece of aluminum is added to the bottom of the container, and the experiment is carried out in a state where sodium hydroxide and various kinds of water are added so that the liquid level of the blender becomes higher than the uppermost position of the aluminum. 1 9 and Fig. 2 0 are four types of waters for water, tap water, alkali ion water and natural water, and 6 types of experiments are performed. The so-called 6 kinds of experiments are that the concentration of sodium hydroxide is 5%. In the case of using aluminum nine, the case where aluminum balls are used (two types), the concentration of sodium hydroxide is 10%, the case of using aluminum nine and the case of using aluminum balls (two types), the concentration of sodium hydroxide is 15 %, the case of using aluminum nine and the case of using aluminum balls (two types). For the four types of water, the combination of the concentration of sodium hydroxide (three types) and aluminum (two types) and the time before hydrogen generation (" "Unreacted" means that from the beginning of the experiment to the generation of hydrogen There is a small amount of time unreacted), and how much time continues to generate hydrogen from the hydrogen generation ("reaction end (stop)" means the time at which hydrogen continues to be produced.) The graph is based on the number of tables in Fig. 19 and Fig. 20. Figure 21 to Figure 23. The left graph of Figure 21 is a concentration of 5% sodium hydroxide and uses aluminum nine. In this chart, 'alkaline ionized water, natural water, and tap water do not produce hydrogen. 'The created water system takes 15 minutes before hydrogen is produced, and hydrogen continues to be produced after the hydrogen is produced until the aqueous sodium hydroxide solution is exhausted. Figure 2 〇中' in the column of the creation water at the end of the reaction (stop) 1 2 以上 minutes or more, this means that the sodium hydroxide solution is exhausted. The right graph of Figure 2 is the concentration of sodium hydroxide of 5% and the use of aluminum balls. -41 - 201132582 According to this chart and Figure 19 In Fig. 20, alkali ion water, natural water, and tap water take 13 minutes, 5 minutes, and 8 minutes before hydrogen is generated, and the time for continuing to generate hydrogen is 40 minutes, 33 minutes, and 28 minutes. In contrast, the water is created. It is 1 minute before the hydrogen is produced, followed by The time for generating hydrogen is 90 minutes. That is, the time before the generation of hydrogen is very short compared to other waters, and the time for continuing to produce hydrogen is longer than other waters. Thus, from Fig. 19 and Fig. 20 The table and the graph of Fig. 21 show that it is preferable to use the water as the water for generating hydrogen, compared with the alkali ion water, the natural water, and the tap water. The left graph of Fig. 22 is a concentration of sodium hydroxide of 10%. According to this graph and FIG. 19 and FIG. 20, the alkali ion water, the natural water, and the tap water take 27 minutes, 26 minutes, and 20 minutes before the hydrogen is generated, and the time for continuing to generate hydrogen is 80 minutes. 90 minutes, 45 minutes. In contrast, the created water system was 1 minute before hydrogen generation, and hydrogen continued to be produced until the aqueous sodium hydroxide solution was exhausted. As described above, from the tables of Figs. 19 and 20 and the left graph of Fig. 22, it is preferable to use the make water as the water for generating hydrogen as compared with the alkali ion water, the natural water, and the tap water. The right graph of Figure 2 is the concentration of sodium hydroxide of 1% and the use of aluminum balls. According to this graph and Fig. 19 and Fig. 20, alkali ionized water, natural water, and tap water were taken for 3 minutes, 3 minutes, and 4 minutes before hydrogen generation. The time for continuing hydrogen generation was 27 minutes, 27 minutes, and 30 minutes. The time for which the 'creative water system continued to generate hydrogen for 5 sec seconds before hydrogen generation was 75 minutes. As described above, it can be seen from the tables of Figs. 19 and 20 and the right graph of Fig. 22 that "water for generating hydrogen" is more preferably used as the water than the alkali ion water 'natural water' tap water. -42- 201132582 Picture. According to the system, the production of water, sodium, and water is produced in the left. According to the system, the hydrogen generation system is produced for 43 minutes, as the natural water type of the living time of Fig. 23 is preferred, and the left graph of the grainy or aluminum 23 of 27 is the concentration of sodium hydroxide of 15%. The time taken for hydrogen, which takes 12 minutes, 6 minutes, and 12 minutes before alkali ion water and natural hydrogen hydrogen in this graph and FIG. 19 and FIG. 20 is 37 minutes, 45 minutes, and 26 minutes. The phase is 3 minutes before hydrogen is produced and continues to produce hydrogen straight. As can be seen from the graphs of Fig. 19 and Fig. 20, the water used to generate hydrogen is preferably used in the right graph of the water of the generator water compared with the alkali ion water. 5 % and this graph and FIG. 19 and FIG. 20, the time of 2 minutes, 1 minute, and 2 minutes before alkali ion water and natural hydrogenic hydrogen were 25 minutes, 28 minutes, and 20 minutes. The time to continue to produce hydrogen relative to 20 seconds before hydrogen is produced. Thus, the water for hydrogen generation from the table of Figs. 19 and 20 and the right of Fig. 22, and alkali ion water, natural water, and self-created water are used. As described above, it can be understood from the graphs of Figs. 19 and 20 that the time before the generation of hydrogen is short and the hydrogen system is long, and it is preferable to use the creation water as water. The experiment was carried out in the case where the water to be used was water of four types of water for creation and tap water, and the concentration of sodium hydroxide was 〇%, 1 °/ aluminum was aluminum and aluminum powder. Show the results of the experiment. Fig. 24 to Fig. 2 7 shows the results of experiments conducted on a small piece of aluminum or aluminum powder in a container, in the state in which the aqueous solution of sodium hydroxide was added. The use of aluminum nine, tap water time, for this 'to the hydrogen hydroxide and the natural water of Figure 2' with aluminum balls, tap water, continue to this 'creation time for the chart to see the water compared with Figure 21 to Continue to produce ionized water, >, 3% of 3 Figure 2 4 to the bottom of the figure until the cover -43- 201132582 Figure 24 is the use of aluminum nine, showing a concentration of sodium hydroxide of 0%, 1% ' 3 % of 3 The table of the results of the four types of water, water, alkali ion water, and natural water. Figure 25 is a diagram showing a portion of the table of Figure 24. The left graph of Fig. 25 is a concentration of sodium hydroxide of 1% and aluminum nine is used. According to this chart and the table of 24, in the case where the concentration of sodium hydroxide is 1% and aluminum is used, hydrogen is generated in all four types of water, tap water, alkali ion water and natural water. The concentration of sodium hydroxide was 3% and aluminum was used. From the graph and the table of Fig. 24, it is understood that hydrogen is not generated in tap water, alkali ionized water or natural water. In contrast, the created water system takes 40 minutes before the hydrogen is generated, and hydrogen is continuously generated after the hydrogen is generated until the aqueous sodium hydroxide solution is exhausted. Figure 26 shows the use of Ming powder (which makes Mingjiu a powder). The concentration of acute sodium oxide is 〇%, 1%, and 3%. Water is used as water, tap water, alkali ion water, and natural. A table of experimental results for four types of water. Figure 27 is a diagram showing a portion of the table of Figure 26. The left graph of Figure 2 is the concentration of sodium hydroxide of 1% and the use of aluminum powder. According to this graph and the table of Fig. 26, tap water, alkali ionized water, and natural water system did not react before hydrogen generation, and it took 30 seconds and 60 seconds to continue generating hydrogen for 6 minutes and 4 minutes. On the other hand, the creation water system was 10 seconds before the generation of hydrogen, and the time for continuing to generate hydrogen was 10 minutes. As shown in the left graph of Fig. 27, although the time for continuing to generate hydrogen is 10 minutes, this hydrogen generation occurs until the aqueous sodium hydroxide solution in the container is exhausted. This -44- 201132582 experiment is carried out in a container containing an aqueous solution of sodium hydroxide. The aqueous solution of sodium hydroxide in the container is depleted for 1 〇 minutes. Obviously, if the container is large, the time for hydrogen generation continues to be 1 Minutes or more. As can be seen from the table of Fig. 26 and the left graph of Fig. 27, it is preferable to use the water as the water for generating hydrogen as compared with the tap water, the alkali ion water, and the natural water. Further, when the concentration of sodium hydroxide is 1%, hydrogen is generated until the aqueous sodium hydroxide solution is exhausted, and as a result, the concentration of sodium hydroxide is 0. When 1% or more, hydrogen is produced. The right graph of Figure 2 is the concentration of sodium hydroxide of 3% and the use of aluminum powder. According to this graph and Fig. 26, it takes 30 seconds, 15 seconds, and 15 seconds for the tap water, the alkali ion water, and the natural water system to generate hydrogen for 40 minutes, 45 minutes, and 45 minutes. On the other hand, the creation water system was instantaneous until the generation of hydrogen, and the time for continuing to generate hydrogen was 90 minutes. As shown in the right graph of Fig. 27, although the time for continuing to generate hydrogen was 90 minutes, this hydrogen generation was continued until the aqueous sodium hydroxide solution was exhausted. This experiment is an experiment in which a sodium hydroxide aqueous solution is placed in a container, and the sodium hydroxide aqueous solution in the container is depleted for 90 minutes. Obviously, if the container is large, the time for continuing to generate hydrogen is 90 minutes or longer. When the concentration of sodium hydroxide is 3% or more, hydrogen is generated instantaneously. Therefore, in the case where hydrogen is required to be generated instantaneously, an aqueous sodium hydroxide solution using the water is most suitable. As described above, according to the table of FIG. 26 and the right graph of FIG. 27, the amount of hydrogen generated by using a sodium hydroxide aqueous solution of the generated water is higher than that of the aqueous sodium hydroxide solution using alkali ion water, natural water, or tap water. Many, and only the sodium hydroxide aqueous solution using the creation water instantaneously generates hydrogen. From this result, it can be seen that -45-201132582 is superior to alkali water, natural water, and tap water as water for generating hydrogen. In particular, when aluminum is a powder and the sodium hydroxide concentration is 3% or more, hydrogen can be generated instantaneously, and hydrogen can be generated for a long period of time. Aluminum 66 reacts with an aqueous sodium hydroxide solution to generate heat of reaction, whereby hydrogen is generated from the generated water in the aqueous sodium hydroxide solution, and the aqueous sodium hydroxide solution is gradually reduced. On the other hand, aluminum 66 dissolves into a residue. The residue is 80 to 90% of aluminum hydroxide. The aluminum 66 dissolves into a residue, and if the heat of reaction is not obtained, the residue on the scaffold 62 must be replaced with a new aluminum 66. (Embodiment 4) Next, another embodiment (Embodiment 4) of the hydrogen producing apparatus of the present invention will be described. In the apparatus (Fig. 5) of the first embodiment, the apparatus of the second embodiment (Fig. 12), and the apparatus of the third embodiment (Fig. 15), the result of hydrogen generation was that aluminum 66 was dissolved and remained as residue in the vessel 60. . Therefore, if hydrogen is not generated in the container 60 and a large amount of residue remains, the residue must be taken out from the container 60, and new aluminum 66 must be added to the container 60, so that hydrogen cannot be generated without interruption. For example, when hydrogen is used as the burning time of a car, if hydrogen cannot be generated without interruption, the car may not be able to travel on the way. Here, the hydrogen production apparatus of the fourth embodiment will be described based on Figs. 28 to 30. This embodiment 4 is a device which can continuously generate hydrogen. The aqueous system-created water used in this Example 4 became an alkaline alkaline creation water. The alkaline creation water system considers the creation water in which the neutral generation water is reacted with the aluminum powder 77 to generate hydrogen, or the sodium hydroxide-46-201132582 aqueous solution in which sodium hydroxide is mixed in the creation water. The container 78 is one in which an aqueous sodium hydroxide solution and aluminum 66 are accommodated inside. The valley benefit 7 8 is a cup shape having an upper opening, and the upper opening portion is closed by a funnel-shaped cover 82 (which is regarded as a part of the container 78). The sides of the container 78 and the outside of the bottom surface are covered by the heat insulating material 80 to prevent the temperature of the container 78 from being lowered toward the atmosphere. A first valve means 84 is mounted above the funnel-shaped cover 82, a cylindrical connecting pipe 86 is mounted on the first valve means 84, and a second valve means 8 is mounted on the connecting pipe 86. Above the valve means 88, a hopper 90 for storing a large amount of granular or small piece of aluminum 66 is mounted. The first valve means 84 is connected to the inner space of the cover 8 2 and the internal space of the connecting pipe 86, and the second valve means 8 is connected to interrupt the inner space of the connecting pipe 86 and the inside of the hopper 90. The first valve means 84 is actuated by the first motor 92 and the second valve means 88 is actuated by the second motor 94. The cover 8 2 or the hopper 90 is fixed to a member (not shown), and the container 78 is detachably attachable to the cover 82 by means of attachment or detachment means such as screwing. A mesh member 96 having a bottomed cylindrical shape and having rigidity is attached to the inside of the container 78. The bottom of the mesh member 96 is disposed at a slightly deeper position inside the container 78. The mesh member 96 is made of a metal or a synthetic resin which is not corroded by sodium hydroxide. The size of the mesh of the mesh member 96 is such that the granular or small piece of aluminum 66 does not pass, and the residue of the slag after the melting of the aluminum 66 falls to the extent of, for example, about 3 to 4 mm, but The size of the mesh is not limited by this. The inner space of the funnel-shaped cover 82 (the inner space of the container 60) has a cooling pipe 98 as a cooling means, and both ends of the cooling pipe 98 reach the outside of the cover 82. The cooling pipe 98 is preferably coiled in the internal space of the cover 82. Both ends of the cooling pipe 98 are connected, for example, to a radiator of a car, a liquid for cooling, or a fluid such as -47 - 201132582 gas passes through the inside of the cooling pipe 98 to cool the gas (hydrogen) inside the cover 82. Above the mounting position of the cooling pipe 98 of the cover 82, a gas discharge passage 100 for taking out hydrogen generated in the container 78 to the outside is attached. The internal space of the container 78 and the container surrounded by the cover 82 is only connected to the internal space of the connecting pipe 86 where the first valve means 84 is opened and the gas discharge passage 100. Next, a procedure for supplying the aluminum 66 in the hopper 90 to the container 78 will be described. First, a valve (not shown) of the second valve means 88 is opened in a state where the valve (not shown) of the first valve means 84 is closed. Thereby, the aluminum 66 in the hopper 90 is supplied to the internal space of the connecting pipe 86. Then, the valve (not shown) of the second valve means 88 is closed. When a new aluminum 66 is required in the container 78, the valve of the first valve means 84 is opened, and the aluminum 66 accumulated in the internal space of the connecting pipe 86 is placed in the container 78. The aluminum 66 that has been introduced into the container 78 is caught by the mesh member 96 and accumulates at the bottom of the mesh member 96. Then, the valve of the first valve means 84 is closed, and then the valve of the second valve means 88 is opened, and the aluminum 66 in the hopper 90 is introduced into the internal space of the connection pipe 86. Thereafter, the valve of the second valve means 88 is closed. By repeating this operation, a certain amount of aluminum 66 can be intermittently applied to the bottom of the mesh member 96 in the container 78. The aluminum input means for introducing the aluminum 66 in the hopper 90 into the container 78 is constituted by the first valve means 84, the second valve means 88, the connection pipe 86, and the hopper 90. However, the constituent members of the aluminum input means are not limited by these constitutions. The level 1 〇 2 of the alkali-generating water in the container 78 is set to be higher than the upper surface of the aluminum 66 which is fed to the bottom of the mesh member 96. In the vessel 78, aluminum 66 is contacted with the alkaline creation water to produce a heat of reaction between the aluminum 6 6 and the alkaline build-up water, -48-201132582 to produce hydrogen. Next, a device for taking out hydrogen from the gas generated in the vessel 78 is shown in FIG. A large amount of hydrogen is generated in the vessel 78, but contains the hydrogen together with water vapor and a trace amount of oxygen. The gas system containing a large amount of hydrogen is discharged from the vessel 78 through the gas discharge passage 1 to the outside (Fig. 28). The gas system discharged from the gas discharge passage 1A is connected to the cooling pipe 106 provided inside the cooler 1 to 4 as shown in Fig. 29. A coolant (cooling fluid) 080 is provided in the cooler 104, and the coolant 108 is discharged to the outside of the cooler 104 by a circulation system (for example, a radiator of an automobile) (not shown). The flow from the outside into the cooler 104. Further, as shown in Fig. 28, the cooling pipe 98 may be provided in the internal space of the cover 8 2, and any one of the cooling pipe 98 and the cooler 104 may be provided, or both may be provided. The liquid cooler 110 is provided close to the cooler 104. The other end of the aforementioned cooling pipe 106 is connected to one end of the connecting pipe 112 of the outside of the cooler 104. The other end of the connecting pipe 1 12 is inserted into the inside of the liquid tank 1 1 . A plurality of holes (not shown) for discharging the gas to the outside are formed in the connecting pipe 1 1 2 inserted into the inside of the liquid tank 110. Add a make-up water or an aqueous solution of sodium hydroxide (an aqueous solution of water and sodium hydroxide) in the liquid tank. The upper portion of the liquid tank η 封闭 is closed by the lid. The upper portion of the inside of the liquid tank 11 is connected to the outside through one end of the connecting tube U 4 . Adjacent to the liquid tank 1 1 〇, a dryer 1 16 is provided. A plurality of dry materials 118 such as a ruthenium gel or the like are accommodated inside the dryer 1 16 . The other end of the aforementioned connecting pipe 114 is horizontally disposed near the bottom of the dryer 1 16 , and is disposed at a horizontal position near the bottom of the dryer 1 16 of the connecting pipe 1 14 to form a multi-49-201132582 number. Hole (not shown). In the upper portion of the dryer 116, a hydrogen take-out pipe 120 that connects the inside and the outside is provided. Explain Figure 29. The gas (high temperature) generated in the vessel 78 is as shown in Fig. 16 or Fig. 17, and is mostly hydrogen, but contains a plurality of water vapors and thousands of oxygen. The high temperature gas is cooled by the cooler 1 〇 4, and then the cooled gas is passed through the liquid tank Π0. The water vapor contained in the gas is absorbed by the liquid tank 110. The thousands of oxygen contained in the gas are absorbed by the water of creation or the aqueous solution of sodium hydroxide. Further, several liquid tanks 110 may be passed in series as needed. Thus, in the gas generated by the vessel 78 (made of hydrogen containing water vapor and a plurality of oxygen), the water vapor or a plurality of oxygen can be passed through a liquid tank containing the water of creation or the aqueous solution of sodium hydroxide. 1 1 is removed from the liquid in the crucible and becomes only hydrogen. The gas after removing water vapor and oxygen by the liquid tank 110 is only hydrogen. Then, the hydrogen is introduced into the inside of the dryer 116, and the moisture (the water which passes through the sodium hydroxide aqueous solution of the liquid tank 110) is removed by the drying material 118 such as a gel or the like, and taken out from the hydrogen takeout pipe 120 to the outside. [Embodiment 5] Next, a device for removing the residue accumulated in the container 78 from the inside of the container 78 without stopping the generation of hydrogen will be described based on Fig. 30. The water system used in this apparatus is the same as the above, and alkaline water is used to make alkaline alkaline water. In the apparatus of the fifth embodiment, in the vicinity of the bottom of the container 78, there is provided an annular liquid circulation path 122 which is connected to the container 78 at two places. The contact point of the liquid circulation path 122 with the side of the container 78 is the first connection -50-201132582, the point 124' is the second connection point of the liquid circulation path 122 and the other side of the container 78. 6. In the middle of the liquid circulation path I22 from the first connection point i 2 4 to the second connection point 126, the first electromagnetic valve is provided in order from the position close to the first connection point 1 2 4 as a residue. The filter of the object capture means 130, the first pump 1 3 2, the tank containing the alkaline creation water! 3 4, the second pump 136, and the second electromagnetic valve 138. Further, the positions of the second pump 136 and the second electromagnetic valve 138 may be front and rear. Within the liquid circulation path 12 2, the alkaline creation water system flows from the first contact point 124 to the second connection point 126. Here, as the liquid input means for supplying the alkali-generating water to the container 780, the second pump 1 3 6 for introducing the alkaline creation water into the container 7 from the tank 1 34 and the second The solenoid valve is composed of 13 8 . Further, the liquid input means is not limited to this configuration. The liquid take-out means for taking out the alkali-generating water and the residue from the container 78 is composed of the first electromagnetic valve 1 2 8 and the first pump 1 32. Further, the liquid take-out means is not limited to this configuration. When the new alkaline creation water is supplied to the container 78 by the liquid input means, the first electromagnetic valve 128 is closed, and the second electromagnetic valve 138 is opened to operate the second pump 136. Thereby, new alkali-generating water is taken out from the tank 134, and the alkaline creation water is supplied into the container 78 via the liquid circulation path 122. The aluminum 66 introduced into the mesh member 96 in the container 78 reacts with the alkali-generating water to be melted and becomes small, and falls from the mesh of the mesh member 96 to the lower portion, and is accumulated as a residue in the bottom portion of the container 78. The procedure for removing this residue from the container 78 is illustrated. The residue of aluminum 66 is accumulated in the bottom of the container 78. When it is taken out from the container 78, the first solenoid valve 1 28 is opened and the first pump 133 is actuated. The first! The suction force of the pump 1 3 2 is passed through the liquid circulation path 1 2 2 to the volume -51 - 201132582 78, and the alkaline creation water together with the residue is taken out of the container 78 from the inside of the container 78. Among the alkaline creation water and the residue sucked by the first pump 132, the residue is captured by the filter 130 of the residue capturing means, and the alkaline creation water system removes dust by the filter 130, etc. The tank 134 is reached and accumulated in the tank 134. The residue taken from the container 78 is captured by the filter 130, and the residue is removed by exchanging the filter 130. When the residue is removed, the liquid level 102 (Fig. 28) of the alkali-generating water in the container 78 is opened to the predetermined height, the second electromagnetic valve 138 is opened, and the second pump 13 6 is actuated. To supply new alkaline creation water to the container 78. In the tank 134, the pH concentration is often checked, and sodium hydroxide can be supplied as needed. In the container 78, the aluminum member 66 is held by the mesh member 96. Since the residue of the aluminum 66 is accumulated in the bottom portion of the container 78, the container 7 can be provided by a circulating structure through the alkali-generating water near the bottom of the container 78. The residue is discharged in 8 to supply new alkaline creation water to the container 78. The discharge of the residue from the container 78 and the supply of new alkaline water in the container 78 can be carried out without stopping the hydrogen generation from the container 78. Therefore, hydrogen can be continuously produced, and as a fuel for automobiles, it can be suitably used without interruption. [Brief Description of the Drawings] Fig. 1 is a configuration diagram showing an example of a manufacturing apparatus for producing special water (created water) used in the method for producing hydrogen according to the present invention. Figure 2 is a cross-sectional view of a water generator for the manufacturing apparatus shown in Figure 1. Fig. 3 is a cross-sectional view showing the main part of an ion generator used in the manufacturing apparatus shown in Fig. 1. -52-201132582 Fig. 4 is a view showing the configuration of another example of the apparatus for producing a special water used in the method for producing hydrogen of the present invention. Fig. 5 is a cross-sectional view showing an example of the apparatus for generating hydrogen of the present invention. Fig. 6 is a view showing the generation of hydrogen in a container in which 100 parts by weight of special water (creative water) and 1 part by weight of aluminum powder are placed in a container at a temperature of 3 〇 ° C or more in the container. /. Analytical analysis of the grade book. Figure 7 shows the creation of 1 〇 的 of the creation of water and 1 〇 of aluminum powder into the container. The measurement and analysis of the % of hydrogen produced in the container in a state where the temperature in the container is maintained at 80 ° C or higher. Figure 8 is a measurement certificate showing the pH of the created water. Figure 9 is a measurement certificate showing the p Η 创 of the created water once the hydrogen is generated from the created water and aluminum. Fig. 10 is a graph showing the measurement and analysis of the % of hydrogen generated in the container in a state where the weight of the alkali ion water and the weight of the aluminum powder in the container is 30 ° C or higher. Fig. 11 is a graph showing the measurement and analysis of the % of hydrogen produced in the container in a state where 100 parts by weight of alkali ion water and 10 parts by weight of aluminum powder are placed in a container while the temperature in the container is maintained at 80 °C. Figure 2 is a cross-sectional view showing another example of the apparatus for generating hydrogen of the present invention. Figure 13 is a measurement of the % of hydrogen produced by heating using water and aluminum in the apparatus of Figure 12 Analyze the grade book. Fig. 1 is a diagram showing the measurement and analysis of the % produced by heating a sodium hydroxide aqueous solution of sodium hydroxide and aluminum in a water-generating water by a heating means-53-201132582 . Figure 15 is a cross-sectional view showing another example of the apparatus for generating hydrogen of the present invention. Figure 16 is a first measurement analysis showing the % of hydrogen generated when the concentration of sodium hydroxide in the hydrogen generating apparatus of Figure 15 is 5%. Grade book. Fig. 17 is a second measurement analysis report showing the % of hydrogen generated when the sodium hydroxide concentration in the hydrogen generator of Fig. 15 is 10%. Fig. 8 shows the oxidation of hydrogen in the hydrogen generator of Fig. 15. The third measurement analysis report of the % of hydrogen produced when the sodium concentration is 15%. Fig. 19 is a graph showing the reaction start time and the reaction continuation time of hydrogen generation at the time of reaction using various concentrations of sodium hydroxide (5%, 10%, 15%) of water (alkaline ionized water and natural water) and aluminum. Fig. 20 is a graph showing the reaction start time and the reaction continuation time of hydrogen generation at the time of reaction using various concentrations of sodium hydroxide (creature water and tap water) and aluminum with sodium hydroxide concentration of 5%, 10%, and 15%. Fig. 2 is a graph showing the table shown in Fig. 19 or Fig. 20 with a sodium hydroxide concentration of 5%. Fig. 22 is a graph corresponding to the table shown in Fig. 19 or Fig. 20, which is a graph showing a sodium hydroxide concentration of 10%. Fig. 23 is a chart corresponding to the table shown in Fig. 19 or Fig. 20, which is a graph showing a sodium hydroxide concentration of 15%. Fig. 24 is a graph showing the reaction initiation time and reaction duration of hydrogen generation using an aqueous solution of sodium hydroxide having a sodium hydroxide concentration of 〇%, 1%, 3% and aluminum (n). -54- 201132582 Fig. 2 is a graph showing the reaction start time and reaction duration of hydrogen produced by using hydrogen having a sodium hydroxide concentration of 1% and 3% of an aqueous sodium hydroxide solution as shown in Fig. 24 . Fig. 2 is a table showing the reaction start time and reaction duration of hydrogen generation using an aqueous solution of sodium hydroxide having a sodium hydroxide concentration of 〇 %, 〗 3%, and 3%, and aluminum powder. Fig. 2 is a graph showing the reaction start time and reaction continuation time of hydrogen generation when the sodium hydroxide concentration of sodium hydroxide having a sodium hydroxide concentration of 1% and 3% is shown in Fig. 26. Fig. 28 is a cross-sectional view showing an embodiment of a hydrogen generating apparatus of the present invention which is suitable for supplying hydrogen to aluminum. Fig. 29 is a view showing a structure in which only hydrogen is taken out from the gas generated by the hydrogen generator shown in Fig. 28. Fig. 30 is a view showing another embodiment of the hydrogen generating apparatus of the present invention, which is a system diagram of a hydrogen generating apparatus which can appropriately supply alkaline generated water. [Main component symbol description] 1 〇: first soft water generator 1 2 : second soft water generator 14 : ion generator 1 6 : rock storage device 3 2 : ion exchange resin 46 : tourmaline 48 : metal - 55 - 201132582 54: Rock 60: Container 66: Aluminum 6 9: Heating means 7 5: Created water 7 7 : Aluminum powder 78: Container 82: Cover 84: First valve means 8 6 : Connection tube 88: Second valve means 96: Net member 98: cooling pipe 104: cooler 106: cooling pipe 122: liquid circulation path 1 2 8 : first · solenoid valve 1 3 0 : filter 1 32 : first pump 1 34 : tank 1 36 : second pump 1 3 8 : 2nd solenoid valve -56