TW201116186A - Multi-layer printed circuit board - Google Patents

Multi-layer printed circuit board Download PDF

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Publication number
TW201116186A
TW201116186A TW99144966A TW99144966A TW201116186A TW 201116186 A TW201116186 A TW 201116186A TW 99144966 A TW99144966 A TW 99144966A TW 99144966 A TW99144966 A TW 99144966A TW 201116186 A TW201116186 A TW 201116186A
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Taiwan
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high dielectric
layered
hole
layer
electrode
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TW99144966A
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Chinese (zh)
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TWI397362B (en
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Takashi Karitani
Shoryo Mochida
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Ibiden Co Ltd
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Abstract

Multi-layer printed circuit board (10) has: a mounting part (60) for installing a semiconductor device electrically connected to a wiring pattern (32) on a surface; and a ceramic high dielectric layer (43) and a first and second layered electrode (41,42) sandwiching the high dielectric layer (43). One side of the first and second layered electrodes (41,42) is linked to a power line of the semiconductor device and the other side is linked to layered capacitor part (40) of grounding wire. In the multi-layer printed circuit board (10), since the high dielectric layer (43) of the layered capacitor part (40) is linked between the power line and the grounding wire is ceramic, the layered capacitor part (40) has a larger static capacitance. Therefore, even under the condition that a sudden drop of electrical potential happens easily, adequate decoupling effect can still be obtained.

Description

201116186 六、發明說明: 【發明所屬之技術領域】 本發明係關於具有由利用絕緣層內之通孔 絕緣層實施複數積層之配線圖案形成電性連結 積部之多層印刷配線板。 【先前技術】 Φ 傳統上,具有由利用絕緣層內之通孔使隔 施複數積層之配線圖案形成電性連結所構成之 層印刷配線板,有各種不同構造。例如,此種 線板在以高速執行安裝之半導體元件之導通斷 會產生切換雜訊而使電源線之電位瞬間降低, 種電位之瞬間降低,有人提出在電源線及接地 電容器部來實施解耦合之方法。此種電容器部 200 1 -68 8 5 8號公報所示,係將層狀電容器部配 φ 刷配線板內。 【發明內容】 然而,前述公報之層狀電容器部因爲採用 鋇等無機塡料之有機樹脂所構成之介電質層, 大之靜電容,而容易使半導體元件之導通斷開 GHz〜數十GHz之高電位之瞬間降低之狀況, 揮充分解耦合效果之問題。 有鑑於此,本發明之目的即在提供可發揮 使隔著前述 所構成之堆 著絕緣層實 堆積部之多 多層印刷配 開時,有時 爲了抑制此 線之間連結 如曰本特開 設於多層印 由含有鈦酸 無法獲得夠 頻率出現數 故有難以發 充分解耦合 -5- 201116186 效果之多層印刷配線板。 爲了達成上述目的之至少一部份’本發明採用以下之 手段。 本發明係具有由利用絕緣層內之通孔使隔著前述絕緣 層實施複數積層之配線圖案形成電性連結所構成之堆積部 之多層印刷配線板,其特徵爲具有: 表面安裝著與前述配線圖案形成電性連結之半導體元 件之安裝部; 位於前述安裝部及前述堆積部之間,具有陶瓷製之高 介電質層、及夾著該高介電質層之第1及第2層狀電極,前 述第1及第2層狀電極之一方連結於前述半導體元件之電源 線且另一方連結於接地線之層狀電容器部。 因爲該多層印刷配線板之連結於電源線及接地線間之 層狀電容器部之高介電質層係陶瓷製,與傳統之含有無機 塡料之有機樹脂製相比,介電常數較高,故層狀電容器部 之靜電容較大。因此,即使半導體元件之導通斷開之頻率 容易出現數GHz〜數十GHz (例如3GHz〜20GHz )之高電 位之瞬間降低之狀況,亦可發揮充分解耦合效果。 本發明之多層印刷配線板之前述高介電質層,應爲將 與前述堆積部份開利用高介電質材料之燒成所製作之物接 合於前述堆積部之上。一般而言,因爲堆積部係以200 °C 以下之溫度條件進行製作,難以利用高介電質材料之燒成 來形成陶瓷,故應與堆積部份開實施高介電質材料之燒成 來形成陶瓷。此種高介電質層並無特別限制,可以爲對含 -6- 201116186 有從例如鈦酸鋇(BaTi03 )、鈦酸緦(SrTi03 )、氧化鉅 (Ta03 ' Ta205 )、锆鈦酸鉛(PZT )、锆鈦酸鑭鉛( PLZT)、锆鈦酸鈮鉛(PNZT)、銷鈦酸鈣鉛(PCZT)、 以及锆鈦酸緦鉛(PSZT )所構成之群組所選取之1種或2種 以上之金屬氧化物之原料進行燒成而製成者》 本發明之多層印刷配線板亦可如下所示,亦即,前述 第1層狀電極之前述高介電質層之下面側,配設著具有可 φ 使連結於前述第2層狀電極之棒狀端子以非接觸狀態通過 之通過孔之平塗圖案,前述第2層狀電極之前述高介電質 層之上面側,則配設著具有可使連結於前述第1層狀電極 之棒狀端子以非接觸狀態通過之通過孔之平塗圖案。如此 ,可使層狀電容器部之第1及第2層狀電極具有較大面積, 故可使該層狀電容器部具有較大之靜電容。此外,不但可 以較短配線長度從外部電源供應源對層狀電容器部實施電 荷之充電,尙可以較短配線長度從層狀電容器部對半導體 φ 元件供應電源,故導通斷開之間隔較短之數GHz〜數十 GHz (例如3GHz〜20GHz )之半導體元件時,亦可得到充 分解耦合效果,而不易出現電源不足之情形。此外,各平 塗圖案可配設於高介電質層之上面或下面之一部份,亦可 配設於全面。 本發明之印刷配線板之構成亦可如下所示,亦即,前 述安裝部具有連結於前述半導體元件之電極之複數連結墊 ,電性連結於與前述第1層狀電極爲同電位之連結墊且使 前述第2層狀電極以非接觸狀態通過之棒狀端子之數少於 201116186 與前述第1層狀電極爲同電位之連結墊之數。如此,因爲 連結於與第1層狀電極爲同電位之連結墊之棒狀端子具有 較少之用以使第2層狀電極以非接觸狀態通過之通過孔之 數,可使第2層狀電極具有較大之面積,故可使層狀電容 器部具有較大之靜電容。 本發明之印刷配線板之構成亦可如下所示,亦即,前 述安裝部具有連結於前述半導體元件之電極之複數連結墊 ,電性連結於與前述第2層狀電極爲同電位之連結墊且使 前述第1層狀電極以非接觸狀態通過之棒狀端子之數少於 與前述第2層狀電極爲同電位之連結墊之數。如此,因爲 連結於與第2層狀電極爲同電位之連結墊之棒狀端子具有 較少之用以使第1層狀電極以非接觸狀態通過之通過孔之 數,可使第1層狀電極具有較大之面積,故可使層狀電容 器部具有較大之靜電容。此時,連結於與前述第2層狀電 極爲同電位之連結墊之棒狀端子亦可以爲使第1層狀電極 及第2層狀電極皆以非接觸狀態通過。 此外,前述2種棒狀端子(亦即,電性連結於與第1層 狀電極爲同電位之連結墊且且使第2層狀電極以非接觸狀 態通過之棒狀端子、及電性連結於與第2層狀電極爲同電 位之連結墊且使第1層狀電極以非接觸狀態通過之棒狀端 子)之至少一部份亦可以爲交互並列之格子狀或十字形。 如此,因爲回路電感較低,故較容易防止電源電位之瞬間 降低。 本發明之多層印刷配線板之構成亦可如下所示,亦即 -8 - 201116186 ,前述安裝部具有連結於前述半導體元件之電源電極及接 地電極之其中任一方之第1連結墊、及連結於其另一方之 第2連結墊,前述第1連結墊當中之一部份具有使前述第2 層狀電極以非接觸狀態通過之第1棒狀端子且經由該第1棒 狀端子電性連結於前述第1層狀電極及外部電源之一方之 電極,其餘部份本身則不具有前述第1棒狀端子而電性連 結於具有該第1棒狀端子之第1連結墊,前述第2連結墊當 φ 中之一部份具有使前述第1層狀電極以非接觸狀態通過之 第2棒狀端子且經由該第2棒狀端子電性連結於前述第2層 狀電極及前述外部電極之另一方之電極,其餘部份本身則 不具有前述第2棒狀端子而電性連結於具有該第2棒狀端子 之第2連結墊。如此,因爲可減少第1棒狀端子及第2棒狀 端子之數,而可減少該棒狀端子用以使第1層狀電極及第2 層狀電極通過之通過孔之數,故可使第1及第2層狀電極具 有較大之面積,而使層狀電容器部具有較大之靜電容。例 φ 如,亦可使第1及第2層狀電極大致成爲平塗圖案。此外, 不但可以較短配線長度從外部電源供應源對層狀電容器部 實施電荷之充電,尙可以較短配線長度從層狀電容器部對 半導體元件供應電源,故導通斷開之間隔較短之數GHz〜 數十GHz (例如3GHz〜20GHz)之半導體元件時,亦可得 到充分解耦合效果,而不易出現電源不足之情形。 本發明之多層印刷配線板之構成亦可如下所示,前述 安裝部具有連結於前述半導體元件之電源電極及接地電極 之其中任一方之第1連結墊、及連結於其另一方之第2連結 -9- 201116186 墊’前述第1連結墊當中之一部份具有使前述第2層狀電極 以非接觸狀態通過之第1棒狀端子且經由該第1棒狀端子電 性連結於前述第1層狀電極及外部電源之一方之電極,其 餘部份本身則不具有前述第1棒狀端子而電性連結於具有 該第1棒狀端子之第1連結墊,前述第2連結墊當中之一部 份具有使前述第1層狀電極及前述第2層狀電極之兩方以非 接觸狀態通過之第2棒狀端子且經由該第2棒狀端子連結於 前述外部電源之另一方之電極,其餘部份本身則不具有前 述第2棒狀端子而電性連結於前述第2層狀電極及具有前述 第2棒狀端子之第2連結墊之至少一方。此時,亦因爲可減 少第1棒狀端子及第2棒狀端子之數,而可減少該棒狀端子 用以使第1層狀電極及第2層狀電極通過之通過孔之數,故 可使第1及第2層狀電極具有較大之面積,而使層狀電容器 部具有較大之靜電容。例如,亦可使第1及第2層狀電極大 致成爲平塗圖案。此外,不但可以較短配線長度從外部電 源供應源對層狀電容器部實施電荷之充電,尙可以較短配 線長度從層狀電容器部對半導體元件供應電源,故導通斷 開之間隔較短之數GHz〜數十GHz (例如3GHz〜20GHz ) 之半導體元件時,亦可得到充分解耦合效果,而不易出現 電源不足之情形。 如上之具有第1棒狀端子及第2棒狀端子之多層印刷配 線板之第1棒狀端子及第2棒狀端子之至少一部份亦可以爲 交互並列之格子狀或十字形。如此,因爲回路電感較低, 故較容易防止電源電位之瞬間降低。 -10- 201116186 本發明之多層印刷配線板之構成亦可如下所示,亦即 ,前述層狀電容器部將前述第1及第2層狀電極間之距離設 定成10/zm以下之實質上不會發生短路之距離。如此,因 爲層狀電容器部之電極間距離極小,而使該層狀電容器部 具有較大之靜電容。 本發明之多層印刷配線板之前述層狀電容器部應形成 於安裝在前述安裝部之半導體元件之正下方。如此,可以 φ 最短配線長度對半導體元件供應電源。 本發明之多層印刷配線板亦可具有設置於配設著前述 安裝部之表面側且連結於前述層狀電容器部之前述第1及 第2層狀電極之晶片電容器。如此,在靜電容因爲只有層 狀電容器部而不足時,可利用晶片電容器來補充該不足份 。此外,解耦合效果會因爲晶片電容器及半導體元件之配 線愈長而愈低,然而,此處因爲在配設著安裝部之表面側 設置晶片電容器,而縮短半導體元件之配線,故可抑制解 φ 耦合效果之降低。此外,因爲經由層狀電容器部連結晶片 電容器及半導體元件,可減少晶片電容器對半導體元件之 電源供應之損失。 本發明之多層印刷配線板之前述安裝部及前述層狀電 容器部之間亦可具有以彈性材料形成之應力緩和部。如此 ,即使安裝於安裝部之半導體元件、及層狀電容器部或堆 積部之間因爲熱膨脹差而產生應力,因爲應力緩和部會吸 收該應力,故不易發生連結信賴度降低及絕緣信賴度降低 等問題。此外,因爲層狀電容器部之高介電質層較薄且較[Technical Field] The present invention relates to a multilayer printed wiring board having an electrical connection portion formed by a wiring pattern in which a plurality of wiring layers are formed by using a via insulating layer in an insulating layer. [Prior Art] Φ Conventionally, a layer printed wiring board having a wiring pattern in which a plurality of laminated wiring layers are electrically connected by through holes in an insulating layer has various structures. For example, when such a wiring board is turned on and off by a semiconductor device mounted at a high speed, switching noise is generated, and the potential of the power supply line is instantaneously lowered, and the potential of the potential is lowered. It is proposed to perform decoupling at the power supply line and the grounded capacitor portion. The method. In the capacitor portion 200 1 - 68 8 5 8 , the layered capacitor portion is provided in the wiring board. SUMMARY OF THE INVENTION However, in the layered capacitor portion of the above-mentioned publication, a dielectric layer composed of an organic resin such as ruthenium or the like is used, and a large electrostatic capacitance is used, and the semiconductor element is easily turned off by GHz to several tens of GHz. The situation in which the high potential is instantaneously reduced is a problem of fully decoupling effects. In view of the above, it is an object of the present invention to provide a multi-layer printing which can be used to form a solid portion of a stacked insulating layer, and to prevent the connection between the wires. Multilayer printing is a multilayer printed wiring board that does not have enough frequency to appear in the presence of titanic acid, so it is difficult to fully decouple the -5-201116186 effect. In order to achieve at least a part of the above objects, the present invention employs the following means. The present invention has a multilayer printed wiring board in which a deposition portion formed by electrically connecting a wiring pattern in which a plurality of layers are laminated via the insulating layer is formed by a via hole in an insulating layer, and has a surface mounted with the wiring The pattern forming the mounting portion of the electrically coupled semiconductor element; between the mounting portion and the stacking portion, having a ceramic high dielectric layer and first and second layers sandwiching the high dielectric layer In the electrode, one of the first and second layered electrodes is connected to the power supply line of the semiconductor element, and the other is connected to the layered capacitor portion of the ground line. Since the multilayer printed wiring board is made of a high dielectric layer ceramic which is connected to the layered capacitor portion between the power supply line and the ground line, the dielectric constant is higher than that of the conventional organic resin-containing organic resin. Therefore, the static capacitance of the layered capacitor portion is large. Therefore, even if the frequency at which the semiconductor element is turned on and off is liable to be instantaneously lowered at a high potential of several GHz to several tens of GHz (e.g., 3 GHz to 20 GHz), a sufficient decoupling effect can be exhibited. The high dielectric layer of the multilayer printed wiring board of the present invention is formed by bonding an object produced by firing the high dielectric material to the deposited portion. In general, since the deposition portion is formed at a temperature of 200 ° C or lower, it is difficult to form the ceramic by firing of a high dielectric material, so that the high dielectric material should be fired with the deposited portion. Forming ceramics. Such a high dielectric layer is not particularly limited and may be, for example, from -6 to 201116186, such as barium titanate (BaTi03), barium titanate (SrTi03), oxidized giant (Ta03 'Ta205), lead zirconate titanate ( One selected from the group consisting of PZT), lead zirconate titanate (PLZT), lead zirconate titanate (PNZT), lead calcium titanate (PCZT), and lead zirconate titanate (PSZT) or A multilayer printed wiring board of the present invention may be produced by firing a raw material of two or more kinds of metal oxides, that is, a lower surface side of the high dielectric layer of the first layered electrode, a flat coating pattern having a through hole through which the rod-shaped terminal connected to the second layered electrode passes in a non-contact state is disposed, and the upper surface side of the high dielectric layer of the second layered electrode is disposed A flat coating pattern having a through hole through which the rod-shaped terminal connected to the first layered electrode can pass in a non-contact state is provided. Thus, the first and second layered electrodes of the layered capacitor portion can have a large area, so that the layered capacitor portion can have a large electrostatic capacitance. Further, not only can the charge of the layered capacitor portion be charged from the external power source with a shorter wiring length, but the power supply can be supplied from the layered capacitor portion to the semiconductor φ element with a shorter wiring length, so that the interval between the conduction and the disconnection is shorter. In the case of a semiconductor component of several GHz to several tens of GHz (for example, 3 GHz to 20 GHz), a sufficient decoupling effect can be obtained, and a power shortage is unlikely to occur. In addition, each of the flat patterns may be disposed on one of the upper or lower portions of the high dielectric layer, or may be provided in a comprehensive manner. The printed wiring board of the present invention may have a configuration in which the mounting portion has a plurality of connection pads connected to the electrodes of the semiconductor element, and is electrically connected to a connection pad having the same potential as the first layer electrode. Further, the number of the rod-shaped terminals through which the second layered electrode passes in a non-contact state is less than the number of the connection pads of the same potential as the first layered electrode of 201116186. In this manner, since the rod-shaped terminal connected to the connection pad having the same potential as the first layered electrode has a small number of passage holes through which the second layered electrode passes in a non-contact state, the second layer can be formed. Since the electrode has a large area, the layered capacitor portion can have a large electrostatic capacitance. The printed wiring board of the present invention may have a configuration in which the mounting portion has a plurality of connection pads connected to the electrodes of the semiconductor element, and is electrically connected to a connection pad having the same potential as the second layer electrode. Further, the number of the rod-shaped terminals that pass the first layered electrode in a non-contact state is smaller than the number of the connection pads that have the same potential as the second layered electrode. In this manner, since the rod-shaped terminal connected to the connection pad having the same potential as the second layered electrode has a small number of passage holes through which the first layered electrode passes in a non-contact state, the first layer can be formed. Since the electrode has a large area, the layered capacitor portion can have a large electrostatic capacitance. In this case, the rod-shaped terminals connected to the connection pads of the same potential as the second layered electrodes may be such that the first layered electrode and the second layered electrode are both in a non-contact state. Further, the two types of rod-shaped terminals (that is, the rod-shaped terminals electrically connected to the connection pads of the same potential as the first layered electrodes and passing the second layered electrodes in a non-contact state, and the electrical connection At least a portion of the rod-shaped terminal that is connected to the second layered electrode at the same potential and that allows the first layered electrode to pass in a non-contact state may be alternately arranged in a lattice shape or a cross shape. Thus, since the loop inductance is low, it is easier to prevent the instantaneous drop of the power supply potential. The multilayer printed wiring board of the present invention may be configured as follows, that is, -8 - 201116186, wherein the mounting portion has a first connection pad connected to one of a power supply electrode and a ground electrode of the semiconductor element, and is connected to In the other second connection pad, one of the first connection pads has a first rod terminal through which the second layer electrode passes in a non-contact state, and is electrically connected to the first rod terminal via the first rod terminal. The electrode of one of the first layered electrode and the external power source does not have the first rod-shaped terminal, and is electrically connected to the first connection pad having the first rod-shaped terminal, and the second connection pad One of φ has a second rod-shaped terminal through which the first layered electrode passes in a non-contact state, and is electrically connected to the second layered electrode and the external electrode via the second rod-shaped terminal The other electrode itself does not have the second rod-shaped terminal and is electrically connected to the second connection pad having the second rod-shaped terminal. In this way, since the number of the first rod-shaped terminal and the second rod-shaped terminal can be reduced, the number of the through-holes through which the first layered electrode and the second layered electrode can pass can be reduced. The first and second layered electrodes have a large area, and the layered capacitor portion has a large electrostatic capacitance. For example, φ, the first and second layered electrodes may be substantially flat-coated. Further, not only can the charge of the layered capacitor portion be charged from the external power source with a shorter wiring length, but also the power supply can be supplied to the semiconductor element from the layered capacitor portion with a shorter wiring length, so that the interval between the on and off is shorter. In the case of a semiconductor component of GHz to tens of GHz (for example, 3 GHz to 20 GHz), a sufficient decoupling effect can be obtained, and a power shortage is unlikely to occur. The multilayer printed wiring board of the present invention may have a configuration in which the mounting portion has a first connection pad connected to one of a power supply electrode and a ground electrode of the semiconductor element, and a second connection connected to the other of the semiconductor element -9- 201116186 Pad One of the first connection pads has a first rod terminal through which the second layer electrode passes in a non-contact state, and is electrically connected to the first via the first rod terminal The electrode of one of the layered electrode and the external power source does not have the first rod-shaped terminal, and is electrically connected to the first connection pad having the first rod-shaped terminal, and one of the second connection pads a part of the electrode having the second rod-shaped terminal that passes through the first layered electrode and the second layered electrode in a non-contact state, and is connected to the other external power source via the second rod-shaped terminal. The remaining portion itself does not have the second rod-shaped terminal, and is electrically connected to at least one of the second layered electrode and the second connection pad having the second rod-shaped terminal. In this case, since the number of the first rod-shaped terminal and the second rod-shaped terminal can be reduced, the number of the through-holes through which the first layered electrode and the second layered electrode pass can be reduced. The first and second layered electrodes can have a large area, and the layered capacitor portion can have a large electrostatic capacitance. For example, the first and second layered electrodes can be made substantially flat. Further, not only can the charge of the layered capacitor portion be charged from the external power source with a shorter wiring length, but also the power supply can be supplied to the semiconductor element from the layered capacitor portion with a shorter wiring length, so that the interval between the on and off is shorter. In the case of a semiconductor component of GHz to several tens of GHz (for example, 3 GHz to 20 GHz), a sufficient decoupling effect can be obtained, and a power shortage is unlikely to occur. At least a part of the first rod-shaped terminal and the second rod-shaped terminal of the multilayer printed wiring board having the first rod-shaped terminal and the second rod-shaped terminal may be alternately arranged in a lattice shape or a cross shape. Thus, since the loop inductance is low, it is easier to prevent an instantaneous drop in the power supply potential. -10- 201116186 The configuration of the multilayer printed wiring board of the present invention may be as follows, that is, the layered capacitor portion has a distance between the first and second layered electrodes of 10/zm or less. The distance from the short circuit will occur. Thus, since the distance between the electrodes of the layered capacitor portion is extremely small, the layered capacitor portion has a large electrostatic capacitance. The layered capacitor portion of the multilayer printed wiring board of the present invention should be formed directly under the semiconductor element mounted on the mounting portion. In this way, the power supply can be supplied to the semiconductor element with the shortest wiring length of φ. The multilayer printed wiring board of the present invention may have a chip capacitor which is provided on the surface of the mounting portion and which is connected to the first and second layered electrodes of the layered capacitor portion. Thus, when the electrostatic capacitance is insufficient due to only the layered capacitor portion, the wafer capacitor can be used to supplement the insufficient portion. In addition, the decoupling effect is lower because the wiring of the wafer capacitor and the semiconductor element is longer. However, since the wafer capacitor is provided on the surface side where the mounting portion is disposed, the wiring of the semiconductor element is shortened, so that the solution φ can be suppressed. The coupling effect is reduced. Further, since the wafer capacitor and the semiconductor element are connected via the layered capacitor portion, the loss of power supply to the semiconductor element by the wafer capacitor can be reduced. The mounting portion of the multilayer printed wiring board of the present invention and the layered capacitor portion may have a stress relieving portion formed of an elastic material. In this manner, even if a stress is generated due to a difference in thermal expansion between the semiconductor element mounted on the mounting portion and the layered capacitor portion or the deposition portion, the stress relieving portion absorbs the stress, so that the connection reliability is lowered and the insulation reliability is less likely to occur. problem. In addition, because the high dielectric layer of the layered capacitor portion is thinner and thinner

S -11 - 201116186 脆,故容易發生龜裂,然而,因爲具有應力緩和部,故可 防止龜裂之發生。此時,應力緩和部亦可只形成於安裝在 前述安裝部之半導體元件之正下方。因爲會造成問題之熱 膨脹差所導致之應力,主要係位於半導體元件之正下方, 若只在該部份形成應力緩和部,可降低材料成本。此種應 力緩和部之材料並無特別限制,可使用例如重組環氧系樹 脂薄片、聚苯醚系樹脂薄片、聚醯亞胺系樹脂薄片、氰基 酯系樹脂薄片、以及亞醯胺系樹脂薄片等有機系樹脂薄片 。該有機系樹脂薄片可含有熱可塑性樹脂之聚烯烴系樹脂 或聚醯亞胺系樹脂、熱硬化性樹脂之矽樹脂、S B R、N B R 、或胺甲酸乙酯等橡膠系樹脂,亦可含有分散之矽氧、鋁 氧、錐氧等無機系之纖維狀、塡料狀、或扁平狀之物。此 外,應力緩和部之楊氏模數應爲10〜lOOOMPa。若應力緩 和部之楊氏模數介於上述範圍,則搭載於安裝部之半導體 元件及層狀電容器部之間因爲熱膨脹係數差而產生應力時 ,亦可緩和該應力。 【實施方式】 [實施例1] 其次,參照圖面,針對本發明之實施形態進行說明。 第1圖係本發明一實施例之多層印刷配線板1 0之平面圖, 第2圖係該多層印刷配線板1 〇之縱剖面圖(只圖示中心線 之左側)’第3圖係層狀電容器部40之模式斜視圖。本實 施例之多層印刷配線板1 0如第2圖所示,具有:經由貫穿 -12- 201116186 孔導體2 4電性連結形成於正背面之配線圖案2 2之核心基板 20 '位於該核心基板20上面之利用通孔34電性連結於隔著 樹脂絕緣層36實施複數積層之配線圖案32、22之堆積部30 、由高介電質層43及夾著該高介電質層43之第1及第2層狀 電極41、42所構成之層狀電容器部40、以彈性材料形成之 應力緩和部50、用以安裝半導體元件之安裝部60、以及配 設於該安裝部60周圍之晶片電容器配置區域70。 核心基板20具有:形成於由BT ( Bismaleimide-Triazine )樹脂或玻璃環氧基板等所構成之核心基板本體 21之正背兩面之由銅所構成之配線圖案22、22、及形成於 貫通核心基板本體2 1之正背面之貫穿孔之內側面之由銅所 構成之貫穿孔導體24,兩配線圖案22、22係經由貫穿孔導 體24形成電性連結。 堆積部30係在核心基板20之正背兩面交互實施樹脂絕 緣層36及配線圖案32之積層者,各配線圖案32經由貫通樹 • 脂絕緣層36之正背面之通孔34形成電性連結。此種堆積部 3 〇係利用眾所皆知之消去法或加成法(含半加成法及全加 成法)來形成,例如,可以下述方式形成。亦即,首先, 在核心基板20之正背兩面貼附樹脂絕緣層36之樹脂薄片。 此處,樹脂絕緣層36之常溫之楊氏模數爲2〜7GPa。該樹 脂薄片係由重組環氧系樹脂薄片、聚苯醚系樹脂薄片、聚 醯亞胺系樹脂薄片、或氰基酯系樹脂薄片等來形成,其厚 度大致爲20〜80/zm。該樹脂薄片亦可含有分散之矽氧、 鋁氧、或錶氧等無機成分。其次,在已貼附之樹脂薄片利 -13- 201116186 用碳酸氣雷射、UV雷射、YAG雷射、或激生分子雷射等形 成貫穿孔並當做樹脂絕緣層3 6使用,在該樹脂絕緣層3 6之 表面及貫穿孔之內部實施無電解鍍銅而形成導體層。在該 導體層上形成抗鍍層且在未形成抗鍍層之部份實施電解鍍 銅後,以蝕刻液除去抗鍍層下之無電解鎪銅而形成配線圖 案32。此外,將貫穿孔內部之導體層當做通孔3 4使用。其 後,重複此步驟來形成堆積部30。 層狀電容器部40係由對陶瓷系高介電質材料實施高溫 燒成所形成之高介電質層43、及夾住該高介電質層43之第 1層狀電極41及第2層狀電極42所構成。該層狀電容器部40 之第1層狀電極41係銅電極,電性連結於安裝部60之接地 用連結墊6 1,第2層狀電極42係銅電極,電性連結於安裝 部60之電源用連結墊62。因此,第1及第2層狀電極41、42 係分別連結至安裝於安裝部之半導體元件之接地線及電源 線。此外,第1層狀電極4 1係形成於高介電質層43下面之 平塗圖案,具有以非接觸狀態貫通連結於電源用連結墊62 之通孔62b之通過孔41a。各電源用連結墊62分別經由通孔 62a連結於第2層狀電極42,通孔62b係以對應部份通孔62a 之方式配設。因爲各通孔62 a係用以連結至第2層狀電極42 ,故只要具有至少1個從第2層狀電極42朝下方延伸之通孔 62b,即可通過該通孔62b連結至接地線。另一方面,第2 層狀電極42係形成於高介電質層43上面之平塗圖案,具有 以非接觸狀態貫通連結於接地用連結墊6 1之通孔6 1 a之通 過孔42a。此外,第1及第2層狀電極41、42間之距離設定 -14- 201116186 成10/zm以下之實質上不會發生短路之距離。此外,高介 電質層 43係使含有從 BaTi03、SrTi03、Ta03、Ta205、PZT 、PLZT、PNZT、PCZT、以及PSZT所構成之群組所選取之 1種或2種以上之金屬氧化物之高介電質材料形成0.1〜ι〇 之薄膜狀後,進行燒成而成爲陶瓷》此外,後面會針 對層狀電容器部40之製造步驟進行詳細說明。 此處,針對層狀電容器部40進一步進行詳細說明,雖 φ 然有部份說明係與前面之說明重複。層狀電容器部40之第 1層狀電極41係經由通孔61a電性連結於安裝部60之接地用 連結墊61,第2層狀電極42係經由通孔62 a電性連結於安裝 部60之電源用連結墊62。因此,第1及第2層狀電極41、42 分別連結至安裝於安裝部60半導體元件之接地線及電源線 。此外,第1層狀電極41係形成於高介電質層43下面之平 塗圖案,具有以非接觸狀態貫通連結於第2層狀電極4 2之 通孔62b之通過孔41a。此外,通孔62b亦可以對應全部電 φ 源用連結墊62之方式配設,然而,此處係以對應部份電源 用連結墊62之方式配設。因爲第2層狀電極42係經由各通 孔62 a連結於各電源用連結墊62,故只要具有至少1個從第 2層狀電極42朝下方延伸之通孔62b ’即可通過該通孔62b 將全部電源用連結墊62連結至外部電源線。如此,以對應 部份電源用連結墊62之方式配設通孔62b ’可減少配設於 第1層狀電極41之通過孔41a之數,故第1層狀電極41具有 .較大之面積,而層狀電容器部40亦具有較大之靜電容。此 外,形成通過孔4 1 a之位置應在考慮層狀電容器部4〇之靜 -15- 201116186 電容及通孔62a之配置等後才決定。另一方面,第2層狀電 極42係形成於高介電質層43上面之平塗圖案,具有以非接 觸狀態貫通連結於接地用連結墊6 1之通孔6 1 a之通過孔42a 。通過孔42a亦可以對應全部接地用連結墊6丨之方式配設 ’然而’此處係利用第2層狀電極42在上側連結複數接地 用連結墊6 1,而只在部份接地用連結墊6 1形成通孔6 1 a, 並以非接觸狀態貫通第2層狀電極42之通過孔42a。如此, 以對應部份接地用連結墊6 1之方式配設通孔6 1 a,可減少 配設於第2層狀電極42之通過孔42a之數,故第2層狀電極 42具有較大之面積,層狀電容器部40亦具有較大之靜電容 。此外,形成通過孔42a之位置應在考慮層狀電容器部40 之靜電容及通孔62a之配置等後後再決定。 應力緩和部50係由彈性材料所形成。彈性材料並無特 別限制,可以使用例如重組環氧系樹脂薄片、聚苯醚系樹 脂薄片、聚醯亞胺系樹脂薄片、氰基酯系樹脂薄片、以及 亞醯胺系樹脂薄片等有機系樹脂薄片。該有機系樹脂薄片 可含有熱可塑性樹脂之聚烯烴系樹脂或聚醯亞胺系樹脂、 熱硬化性樹脂之矽樹脂、SBR、NBR、或胺甲酸乙酯等橡 膠系樹脂,亦可含有矽氧、鋁氧、锆氧等無機系之纖維狀 、塡料狀、或扁平狀之物。該應力緩和部50之楊氏模數應 爲10〜lOOOMpa之較低値。若應力緩和部50之楊氏模數介 於上述範圍,則搭載於安裝部60之半導體元件及層狀電容 器部之間因爲熱膨脹係數差而產生應力時,亦可緩和該應 力。 -16- 201116186 安裝部60係用以安裝半導體元件之區域,形成於多層 印刷配線板1 〇之表面。該安裝部60以格子狀或十字形配列 著接地用連結墊61、電源用連結墊62、以及訊號用連結墊 63 (參照第1圖)。此外,亦可在中央附近以格子狀或十 字形之方式配列接地用連結墊6 1及電源用連結墊62,並在 其周圍以格子狀或十字形或隨機之方式配列訊號用連結墊 6 3。接地用連結墊6 1及電源用連結墊6 2應爲交互配列。安 φ 裝部60之端子數爲1〇〇〇〜300000。該安裝部60周圍形成複 數晶片電容器配置區域70 (參照第1圖)。該晶片電容器 配置區域70形成複數對以分別連結晶片電容器73之接地用 端子及電源用端子爲目的之接地用連結墊71及電源用連結 墊72。此外,各接地用連結墊71係經由層狀電容器部40之 第1層狀電極4 1連結於外部電源之負極,各電源用連結墊 72係經由第2層狀電極42連結於外部電源之正極。 其次,針對具有此構成之多層印刷配線板1 0之使用例 φ 進行說明。首先,分別將晶片電容器73之電源用端子及接 地用端子焊接於晶片電容器配置區域70之接地用連結墊71 及電源用連結墊72。其次,將背面配列著多數焊塊之半導 體元件載置於安裝部60。此時,使半導體元件之接地用端 子、電源用端子、以及訊號用端子分別接觸安裝部60之接 地用連結墊6 1、電源用連結墊62、以及訊號用連結墊63。 其次,利用回焊焊接各端子。其後,將多層印刷配線板1 0 接合至母板等其他印刷配線板。此時,在預先形成於多層 印刷配線板1 〇背面之連結墊上形成焊塊,並以接觸其他印 -17- 201116186 刷配線板上之對應連結墊之狀態利用回焊進行接合。 其次,針對本實施例之多層印刷配線板1 0之製造步驟 進行說明。因爲核心基板20及堆積部30之製作步驟係眾所 皆知,故此處以製作層狀電容器部40及應力緩和部50之步 驟爲中心來進行說明。第4圖〜第7圖係該步驟之說明圖。 首先,如第4圖(a )所示,準備至少單面形成堆積部 30之核心基板20,利用真空層疊機以溫度50〜150°C、壓 力0.5〜1.5MPa之層疊條件將層間絕緣層410貼附於堆積部 30上。其次,利用真空層疊機以溫度50〜150 °C、壓力〇.5 〜1.5MPa之層疊條件將預先製作之高介電質薄片420貼附 於層間絕緣層4 1 0上後,實施1 5 0 °C、3小時之硬化(參照 第4圖(b))。此處,高介電質薄片4 20係以下述方式製 作。亦即,在厚度爲12 // m之銅箔422 (後來之第1層狀電 極41 ),利用輥塗器及刮刀等印刷機將含有從BaTi03、 SrTi03、Ta03、Ta205、PZT、PLZT、PNZT、PCZT、以及 PSZT所構成之群組所選取之1種或2種以上之金屬氧化物之 高介電質材料印刷成厚度爲0.1〜10ym之薄膜狀,當做未 燒成層使用。印刷後,在真空中或N2氣體等非氧化環境中 、6 00〜9 5 0 °C之溫度範圍實施該未燒成層之燒成,當做高 介電質層424使用。其後,利用濺鍍等真空蒸鍍裝置在高 介電質層424上形成銅、白金、以及金等之金屬層,並以 電解電鍍等使該金屬層上具有10// m程度之銅、鎳、錫等 之金屬,來形成上部金屬層426 (後來之第2層狀電極42之 —部份)。結果,得到高介電質薄片420。 201116186 其次,將市販之乾膜430貼附於積層著高介電質薄片 420之製作中之基板上(參照第4圖(c )),並利用多層 印刷配線板之圖案化經常使用之曝光·顯影(參照第4圖 (d ))、蝕刻(參照第4圖(e ))、以及膜剝離(參照 第4圖(f)),實施高介電質薄片420之圖案化。此外, 蝕刻步驟係使用氯化銅蝕刻液。 其次,再度將乾膜440貼附已實施高介電質薄片420之 φ 圖案化之製作中之基板上(參照第5圖(a)),並利用曝 光·顯影(參照第5圖(b )) '蝕刻(參照第5圖(c )) 、以及膜剝離(參照第5圖(d)),實施高介電質薄片 420上之金屬層426及高介電質層424之圖案化。此外,蝕 刻步驟係使用氯化銅蝕刻液,然而,係蝕刻至金屬層426 及高介電質層424後只對銅箔422進行少許蝕刻之狀態之短 時間處理。 其次,在已實施金屬層426及高介電質層424之圖案化 φ 之製作中之基板上,利用壓漿輥實施層間充塡用樹脂450 之充塡(參照第5圖(e)),並以100 °C實施20分鐘之乾 燥。此處,係在容器混合攪拌100重量份之雙酚F型環氧單 體(Japan Epoxy Resins Co.,Ltd.製、分子量 310、商品名 稱YL983 U ) 、72重量份之表面覆蓋矽烷耦合材之平均粒 徑1.6// m之最大粒子徑15y m以下之Si02球狀粒子( ADTEC Corporation 製、商品名稱 CRS1101-CE)、以及 1.5 重量份之均化劑(SAN NOPCO LIMITED製、商品名稱 PELENOL S4 )來調製層間充塡用樹脂450。其粘度在23±1 -19- 201116186 °C爲30〜60P a / s。此外,硬化劑係使用6.5重量份之咪唑 硬化劑(四國化成公司製、商品名稱2E4MZ-CN) »此外 ,充塡該樹脂450並實施乾燥後,對製作中之基板表面實 施硏磨直到高介電質薄片420之上部金屬層426表面露出爲 止,實施平坦化,其次,進行1〇〇°C之1小時及150°C之1小 時之加熱處理,實施該樹脂45 0之硬化,而形成高介電質 層間充塡層452 (參照第5圖(f))。 其次,在已形成高介電質層間充塡層452之製作中之 基板表面之特定位置利用碳酸氣雷射、UV雷射、YAG雷射 、以及激生分子雷射等,形成達到堆積部3 0之配線圖案3 2 表面之貫穿孔454 (參照第6圖(a))。其次,使無電解 電鍍觸媒附著於該製作中之基板表面後,將該基板浸漬於 無電解鍍銅水溶液中,在貫穿孔45 4之內壁、高介電質薄 片420表面、以及高介電質層間充塡層452表面形成厚度爲 0.6〜3.0"m之無電解鍍銅膜456(參照第6圖(b))。此 外,無電解電鍍水溶液係使用具有以下之組成之物。硫酸 銅:0.03mol/ L、EDTA : 0.200mol/ L、HCHO : O.lg/ L 、NaOH: 0.1mol/L、α,α’-雙妣陡:l〇〇mg/L、聚乙二 醇(PEG) : O.lg/ L。S -11 - 201116186 is brittle, so it is prone to cracking. However, because it has a stress relieving part, cracking can be prevented. In this case, the stress relieving portion may be formed only under the semiconductor element mounted on the mounting portion. The stress caused by the difference in thermal expansion caused by the problem is mainly located directly under the semiconductor element. If the stress relaxation portion is formed only in this portion, the material cost can be reduced. The material of the stress relaxation portion is not particularly limited, and for example, a recombinant epoxy resin sheet, a polyphenylene ether resin sheet, a polyimide film, a cyano ester resin sheet, and a sulfonamide resin can be used. An organic resin sheet such as a sheet. The organic resin sheet may contain a polyolefin resin of a thermoplastic resin, a polyimide resin, a thermosetting resin, a resin, a rubber resin such as SBR, NBR or urethane, or may contain a dispersion. Inorganic fibrous, tantalum, or flat material such as helium oxygen, aluminum oxide, or cone oxygen. Further, the Young's modulus of the stress relaxation portion should be 10 to 100 MPa. When the Young's modulus of the stress relaxation portion is in the above range, the stress is generated when a stress is generated between the semiconductor element and the layered capacitor portion mounted on the mounting portion due to a difference in thermal expansion coefficient. [Embodiment] [Embodiment 1] Next, an embodiment of the present invention will be described with reference to the drawings. 1 is a plan view of a multilayer printed wiring board 10 according to an embodiment of the present invention, and FIG. 2 is a longitudinal sectional view of the multilayer printed wiring board 1 (only the left side of the center line is shown). A schematic perspective view of the capacitor portion 40. As shown in FIG. 2, the multilayer printed wiring board 10 of the present embodiment has a core substrate 20' on which the wiring pattern 2 2 formed on the front and back sides is electrically connected via a through hole -12-201116186. The upper via hole 34 is electrically connected to the deposition portion 30 in which the plurality of wiring patterns 32 and 22 are laminated via the resin insulating layer 36, and the high dielectric layer 43 and the high dielectric layer 43 are interposed therebetween. The layered capacitor portion 40 composed of the first and second layered electrodes 41 and 42 , the stress relieving portion 50 formed of an elastic material, the mounting portion 60 for mounting the semiconductor element, and the wafer disposed around the mounting portion 60 Capacitor configuration area 70. The core substrate 20 has wiring patterns 22 and 22 made of copper formed on the front and back surfaces of the core substrate main body 21 made of BT (Bismaleimide-Triazine) resin or glass epoxy substrate, and formed on the through core substrate. The through-hole conductors 24 made of copper on the inner side surface of the through-holes on the front and back sides of the main body 2 are electrically connected via the via-hole conductors 24. In the stacking portion 30, the resin insulating layer 36 and the wiring pattern 32 are alternately laminated on the front and back surfaces of the core substrate 20, and the wiring patterns 32 are electrically connected via the through holes 34 penetrating the front and back sides of the resin insulating layer 36. Such a stacking portion 3 is formed by a well-known elimination method or addition method (including a semi-additive method and a full additive method), and can be formed, for example, in the following manner. That is, first, a resin sheet of the resin insulating layer 36 is attached to both front and back sides of the core substrate 20. Here, the Young's modulus of the resin insulating layer 36 at normal temperature is 2 to 7 GPa. The resin sheet is formed of a recombinant epoxy resin sheet, a polyphenylene ether resin sheet, a polyimide film, or a cyano ester resin sheet, and has a thickness of approximately 20 to 80 / zm. The resin sheet may contain an inorganic component such as deuterium oxide, aluminum oxide or oxygen. Next, in the attached resin sheet, a liquid crystal laser, a UV laser, a YAG laser, or an excited molecular laser is used to form a through hole and is used as a resin insulating layer 36 in the resin. Electroless copper plating is performed on the surface of the insulating layer 36 and the inside of the through hole to form a conductor layer. A plating resist is formed on the conductor layer, and electrolytic copper plating is performed on a portion where the plating resist is not formed, and the electroless copper under the plating resist is removed by an etching solution to form a wiring pattern 32. Further, the conductor layer inside the through hole is used as the through hole 34. Thereafter, this step is repeated to form the stacking portion 30. The layered capacitor portion 40 is a high dielectric layer 43 formed by firing a ceramic high dielectric material at a high temperature, and a first layered electrode 41 and a second layer sandwiching the high dielectric layer 43. The electrode 42 is formed. The first layered electrode 41 of the layered capacitor portion 40 is a copper electrode, and is electrically connected to the grounding connection pad 161 of the mounting portion 60. The second layered electrode 42 is a copper electrode and is electrically connected to the mounting portion 60. The power supply connection pad 62. Therefore, the first and second layered electrodes 41 and 42 are respectively connected to the ground line and the power supply line of the semiconductor element mounted on the mounting portion. Further, the first layered electrode 41 is formed in a flat coating pattern formed on the lower surface of the high dielectric layer 43, and has a through hole 41a penetrating through the through hole 62b of the power supply connection pad 62 in a non-contact state. Each of the power supply connection pads 62 is connected to the second layered electrode 42 via a through hole 62a, and the through hole 62b is disposed corresponding to the partial through hole 62a. Since each of the through holes 62 a is connected to the second layered electrode 42 , it can be connected to the ground line through the through hole 62 b as long as it has at least one through hole 62 b extending downward from the second layered electrode 42 . . On the other hand, the second layered electrode 42 is a flat coating pattern formed on the upper surface of the high dielectric layer 43, and has a through hole 42a that is connected to the through hole 6 1 a of the ground connection pad 6 1 in a non-contact state. Further, the distance between the first and second layered electrodes 41 and 42 is set to -14 to 201116186 to 10/zm or less, and substantially no short-circuit distance occurs. Further, the high dielectric layer 43 is high in one or more metal oxides selected from the group consisting of BaTi03, SrTiO3, Ta03, Ta205, PZT, PLZT, PNZT, PCZT, and PSZT. The dielectric material is formed into a film shape of 0.1 to 〇, and then fired to form a ceramic. Further, the manufacturing procedure of the layered capacitor portion 40 will be described in detail later. Here, the layered capacitor portion 40 will be further described in detail, and φ is partially described as being redundant with the above description. The first layered electrode 41 of the layered capacitor portion 40 is electrically connected to the grounding connection pad 61 of the mounting portion 60 via the through hole 61a, and the second layered electrode 42 is electrically connected to the mounting portion 60 via the through hole 62a. The power supply connection pad 62. Therefore, the first and second layered electrodes 41 and 42 are respectively connected to the ground line and the power supply line of the semiconductor element mounted on the mounting portion 60. Further, the first layered electrode 41 is formed in a flat pattern on the lower surface of the high dielectric layer 43, and has a through hole 41a penetrating through the through hole 62b of the second layered electrode 42 in a non-contact state. Further, the through hole 62b may be disposed so as to correspond to all of the connection holes 62 for the power source. However, the hole 62b is provided so as to correspond to the portion of the power supply connection pad 62. Since the second layered electrode 42 is connected to each of the power supply connection pads 62 via the respective through holes 62 a, it is sufficient to have at least one through hole 62 b ′ extending downward from the second layered electrode 42 . 62b Connect all power supply connection pads 62 to the external power line. In this way, by providing the through hole 62b' so as to correspond to the portion of the power supply connection pad 62, the number of the through holes 41a disposed in the first layered electrode 41 can be reduced, so that the first layered electrode 41 has a large area. The layered capacitor portion 40 also has a large electrostatic capacitance. Further, the position at which the through hole 4 1 a is formed should be determined after considering the arrangement of the capacitor -15 - 201116186 capacitor and the via hole 62a of the layered capacitor portion 4 . On the other hand, the second layered electrode 42 is a flat coating pattern formed on the upper surface of the high dielectric layer 43, and has a through hole 42a that is connected to the through hole 6 1 a of the grounding connection pad 6 1 in a non-contact state. The hole 42a may be disposed so as to correspond to all of the grounding connection pads 6'. However, the second layered electrode 42 is connected to the plurality of grounding connection pads 6 1 on the upper side, and only the partial grounding connection pads are used. 6 1 forms a through hole 6 1 a and penetrates the through hole 42 a of the second layered electrode 42 in a non-contact state. In this way, the through hole 6 1 a is disposed so as to correspond to the partial grounding connection pad 6 1 , so that the number of the through holes 42 a disposed in the second layered electrode 42 can be reduced, so that the second layered electrode 42 has a larger size. The area of the layered capacitor portion 40 also has a large electrostatic capacitance. Further, the position at which the through hole 42a is formed should be determined after considering the electrostatic capacitance of the layered capacitor portion 40 and the arrangement of the through holes 62a. The stress relieving portion 50 is formed of an elastic material. The elastic material is not particularly limited, and for example, an organic resin such as a recombined epoxy resin sheet, a polyphenylene ether resin sheet, a polyimide film, a cyano ester resin sheet, or a melamine resin sheet can be used. Sheet. The organic resin sheet may contain a polyolefin resin of a thermoplastic resin, a polyimide resin, a resin of a thermosetting resin, a rubber resin such as SBR, NBR, or urethane, or may contain a ruthenium oxide. An inorganic, fibrous, crucible or flat material such as aluminum oxide or zirconium oxide. The Young's modulus of the stress relieving portion 50 should be a lower 値 of 10 to 100 MPa. When the Young's modulus of the stress relaxation portion 50 is in the above range, the stress is generated when the semiconductor element and the layered capacitor portion mounted on the mounting portion 60 are inferior in thermal expansion coefficient, and the stress can be alleviated. -16- 201116186 The mounting portion 60 is a region for mounting a semiconductor element and is formed on the surface of the multilayer printed wiring board 1 . The mounting portion 60 is provided with a ground connection pad 61, a power supply connection pad 62, and a signal connection pad 63 in a lattice shape or a cross shape (see Fig. 1). Further, the grounding connection pad 6 1 and the power supply connection pad 62 may be arranged in a lattice shape or a cross shape near the center, and the signal connection pads 6 3 may be arranged in a lattice shape, a cross shape or a random manner around the center. . The grounding connection pad 6 1 and the power supply connection pad 6 2 should be arranged in an interactive manner. The number of terminals of the mounting portion 60 of the φ is 1 〇〇〇 to 300,000. A plurality of wafer capacitor arrangement regions 70 are formed around the mounting portion 60 (see Fig. 1). The wafer capacitor arrangement region 70 is formed with a plurality of pairs of ground connection pads 71 and power supply connection pads 72 for connecting the ground terminals of the wafer capacitors 73 and the power supply terminals. Further, each of the grounding connection pads 71 is connected to the negative electrode of the external power source via the first layered electrode 41 of the layered capacitor portion 40, and each of the power supply connection pads 72 is connected to the positive electrode of the external power source via the second layered electrode 42. . Next, a use example φ of the multilayer printed wiring board 10 having such a configuration will be described. First, the power supply terminal and the ground terminal of the wafer capacitor 73 are soldered to the ground connection pad 71 and the power supply connection pad 72 of the wafer capacitor arrangement region 70, respectively. Next, the semiconductor component on which the majority of the solder bumps are arranged on the back surface is placed on the mounting portion 60. At this time, the grounding terminal for the semiconductor element, the power supply terminal, and the signal terminal are respectively brought into contact with the grounding connection pad 61 of the mounting portion 60, the power supply connection pad 62, and the signal connection pad 63. Next, each terminal is soldered by reflow soldering. Thereafter, the multilayer printed wiring board 10 is bonded to another printed wiring board such as a mother board. At this time, solder bumps are formed on the bonding pads which are formed in advance on the back surface of the multilayer printed wiring board 1 and are joined by reflow in a state of being in contact with the corresponding bonding pads on the other printed wiring boards -17-201116186. Next, the manufacturing steps of the multilayer printed wiring board 10 of the present embodiment will be described. Since the steps of fabricating the core substrate 20 and the stacking portion 30 are well known, the steps of fabricating the layered capacitor portion 40 and the stress relieving portion 50 will be mainly described. Fig. 4 to Fig. 7 are explanatory diagrams of this step. First, as shown in Fig. 4(a), the core substrate 20 in which the deposition portion 30 is formed at least on one side is prepared, and the interlayer insulating layer 410 is laminated by a vacuum laminator at a temperature of 50 to 150 ° C and a pressure of 0.5 to 1.5 MPa. Attached to the stacking portion 30. Next, the pre-made high dielectric sheet 420 is attached to the interlayer insulating layer 410 by a vacuum laminator at a temperature of 50 to 150 ° C and a pressure of 55 to 1.5 MPa. Hardening at °C for 3 hours (refer to Figure 4(b)). Here, the high dielectric sheet 420 is produced in the following manner. That is, in a copper foil 422 having a thickness of 12 // m (later the first layered electrode 41), a press such as a roll coater and a doctor blade will contain BaTi03, SrTi03, Ta03, Ta205, PZT, PLZT, PNZT. A high dielectric material of one or more metal oxides selected from the group consisting of PCZT and PSZT is printed as a film having a thickness of 0.1 to 10 μm, and is used as an unfired layer. After the printing, the unfired layer is fired in a vacuum or in a non-oxidizing atmosphere such as N2 gas at a temperature of from 600 to 950 °C, and is used as the high dielectric layer 424. Thereafter, a metal layer such as copper, platinum, or gold is formed on the high dielectric layer 424 by a vacuum vapor deposition apparatus such as sputtering, and the metal layer has a copper layer of about 10/m by electrolytic plating or the like. A metal such as nickel or tin is used to form the upper metal layer 426 (the portion of the second layered electrode 42 later). As a result, a high dielectric sheet 420 is obtained. 201116186 Next, a commercially available dry film 430 is attached to a substrate on which a high dielectric sheet 420 is laminated (see FIG. 4(c)), and is often used for patterning using a multilayer printed wiring board. Patterning of the high dielectric sheet 420 is performed by development (see Fig. 4 (d)), etching (see Fig. 4 (e)), and film peeling (see Fig. 4 (f)). Further, the etching step uses a copper chloride etching solution. Next, the dry film 440 is again attached to the substrate in which the φ patterning of the high dielectric sheet 420 is performed (see Fig. 5(a)), and exposure and development are performed (refer to Fig. 5(b). The etching (see Fig. 5(c)) and the film peeling (see Fig. 5(d)) are performed to pattern the metal layer 426 and the high dielectric layer 424 on the high dielectric sheet 420. Further, the etching step uses a copper chloride etching solution, however, it is a short-time treatment in which only the copper foil 422 is slightly etched after being etched to the metal layer 426 and the high dielectric layer 424. Next, on the substrate in which the patterning φ of the metal layer 426 and the high dielectric layer 424 is formed, the interlaminar filling resin 450 is filled with a grout roll (see FIG. 5(e)). It was dried at 100 ° C for 20 minutes. Here, 100 parts by weight of a bisphenol F-type epoxy monomer (manufactured by Japan Epoxy Resins Co., Ltd., molecular weight 310, trade name YL983 U) and 72 parts by weight of a surface-covered decane coupling material were mixed and stirred in a container. SiO 2 spherical particles having a maximum particle diameter of 1.6 μm or less and a particle diameter of 15 μm or less (manufactured by ADTEC Corporation, trade name: CRS1101-CE), and 1.5 parts by weight of a leveling agent (manufactured by SAN NOPCO LIMITED, trade name PELENOL S4) The inter-layer filling resin 450 is prepared. Its viscosity is 23~1 -19-201116186 °C for 30~60P a / s. Further, 6.5 parts by weight of an imidazole curing agent (manufactured by Shikoku Kasei Co., Ltd., trade name 2E4MZ-CN) was used as the curing agent. Further, after the resin 450 was filled and dried, the surface of the substrate to be produced was honed until high. The surface of the upper metal layer 426 of the dielectric sheet 420 is exposed, and planarization is performed. Next, heat treatment is performed for 1 hour at 1 ° C and 1 hour at 150 ° C to cure the resin 45 0. The high dielectric interlayer filling layer 452 (refer to Fig. 5 (f)). Next, a specific portion of the surface of the substrate in which the high dielectric interlayer filling layer 452 is formed is formed by using a carbon dioxide laser, a UV laser, a YAG laser, and an excited molecular laser to form the stacking portion 3 Wiring pattern 0 of 0 2 through-hole 454 on the surface (refer to Fig. 6 (a)). Next, after the electroless plating catalyst is attached to the surface of the substrate to be produced, the substrate is immersed in an electroless copper plating aqueous solution, the inner wall of the through hole 45 4, the surface of the high dielectric sheet 420, and the high medium. An electroless copper plating film 456 having a thickness of 0.6 to 3.0 " m is formed on the surface of the electrically charged interlayer filling layer 452 (see Fig. 6(b)). Further, the electroless plating aqueous solution is one having the following composition. Copper sulfate: 0.03mol/L, EDTA: 0.200mol/L, HCHO: O.lg/ L, NaOH: 0.1mol/L, α, α'-biguanide: l〇〇mg/L, polyethylene glycol (PEG) : O.lg/ L.

其次,將市販之乾膜460貼附於無電解鍍銅膜4 5 6上( 參照第6圖(c )),並實施曝光·顯影、及蝕刻,形成貫 穿孔462 (參照第6圖(d )),而在該貫穿孔462表面形成 厚度爲25 /Z m之電解鍍銅膜464 (參照第6圖(e ))。此外 ,電解鍍銅液使用具有以下之組成之物。硫酸:2 00g/ L 201116186 、硫酸銅:80g/ L、添加劑:1 9.5ml / L ( ATOTECH JAPAN公司製、KAPAROSHIDO GL )。此外,電解鍍銅係 在以下之條件下實施。電流密度1 A/ dm2、時間1 15分、溫 度23±2t。其次,剝離乾膜460,對殘留著該乾膜460之部 份,亦即,對存在於電解鍍銅膜464間之無電解鍍銅膜456 及高介電質薄片420之上部金屬層426之露出部份,以硫 酸-過氧化氫系蝕刻液進行蝕刻(參照第6圖(f))。經過 φ 此步驟,可在堆積部30上形成層狀電容器部40。亦即,銅 箔422係相當於第1層狀電極41,高介電質層424係相當於 高介電質層43,上部金屬層426、無電解鍍銅膜456、以及 電解鍍銅膜464係相當於第2層狀電極42。 其次,對已形成電解鑛銅膜464之製作中之基板實施 將含有 NaOH ( 10g/L) 、NaC102 ( 40g/L)、及 Na3P〇4 (6g/ L )之水溶液當做黑變液(氧化液)之黑變處理、 及將含有NaOH(10g/L)及NaBH4(6g/L)之水溶液當 φ 做還原液之還原處理,使電解鍍銅膜464表面成爲粗化面 (圖上未標示)。其後,利用真空層疊機以溫度50〜150 °C、壓力0.5〜1.5MPa之層疊條件將樹脂絕緣薄片470貼附 於層狀電容器部40上後,實施150°C、3小時之硬化(參照 第7圖(a))。該樹脂絕緣薄片470係重組環氧系樹脂薄 片、聚苯醚系樹脂薄片、聚醯亞胺系樹脂薄片、氰基酯系 樹脂薄片、或亞醯胺系樹脂薄片,亦可含有熱可塑性樹脂 之聚烯烴系樹脂或聚醯亞胺系樹脂、熱硬化性樹脂之矽樹 月旨、SBR、NBR、或胺甲酸乙酯等之橡膠系樹脂,亦可含 -21 - 201116186 有分散之矽氧、鋁氧、锆氧等無機系之纖維狀、塡料狀、 或扁平狀之物。此外,該樹脂絕緣薄片470之楊氏模數應 爲10〜lOOOMPa。若樹脂絕緣薄片470之楊氏模數介於該範 圍,可緩和半導體元件及基板間之熱膨脹係數差所導致之 應力。Next, the commercially available dry film 460 is attached to the electroless copper plating film 456 (refer to Fig. 6 (c)), and exposed, developed, and etched to form a through hole 462 (refer to Fig. 6 (d) )), an electrolytic copper plating film 464 having a thickness of 25 /Z m is formed on the surface of the through hole 462 (refer to Fig. 6 (e)). Further, the electrolytic copper plating solution uses a composition having the following composition. Sulfuric acid: 2 00 g / L 201116186 , copper sulfate: 80 g / L, additive: 1 9.5 ml / L (ATOTECH JAPAN company, KAPAROSHIDO GL). Further, electrolytic copper plating was carried out under the following conditions. The current density is 1 A/dm2, the time is 1 15 minutes, and the temperature is 23±2t. Next, the dry film 460 is peeled off, and the portion of the dry film 460 remains, that is, the electroless copper plating film 456 existing between the electrolytic copper plating film 464 and the upper metal layer 426 of the high dielectric sheet 420. The exposed portion was etched with a sulfuric acid-hydrogen peroxide-based etching solution (see Fig. 6(f)). After the step φ, the layered capacitor portion 40 can be formed on the stacking portion 30. That is, the copper foil 422 corresponds to the first layered electrode 41, and the high dielectric layer 424 corresponds to the high dielectric layer 43, the upper metal layer 426, the electroless copper plating film 456, and the electrolytic copper plating film 464. It corresponds to the second layered electrode 42. Next, an aqueous solution containing NaOH (10 g/L), NaC102 (40 g/L), and Na3P〇4 (6 g/L) is used as a blackening liquid (oxidizing liquid) on the substrate in which the electrolytic copper film 464 has been formed. The blackening treatment and the reduction treatment of the aqueous solution containing NaOH (10 g/L) and NaBH4 (6 g/L) as φ as the reducing solution, so that the surface of the electrolytic copper plating film 464 becomes a roughened surface (not shown) . Then, the resin insulating sheet 470 is attached to the layered capacitor portion 40 by a vacuum laminator at a temperature of 50 to 150 ° C and a pressure of 0.5 to 1.5 MPa, and then cured at 150 ° C for 3 hours (refer to Figure 7 (a)). The resin insulating sheet 470 is a recombined epoxy resin sheet, a polyphenylene ether resin sheet, a polyimide film, a cyanoester resin sheet, or a melamine resin sheet, and may also contain a thermoplastic resin. A rubber-based resin such as a polyolefin resin, a polyimide resin, a thermosetting resin, or a rubber resin such as SBR, NBR, or urethane may contain a dispersed oxygen of -21 to 201116186. An inorganic, fibrous, crucible, or flat material such as aluminum oxide or zirconium oxide. Further, the resin insulating sheet 470 should have a Young's modulus of 10 to 100 MPa. If the Young's modulus of the resin insulating sheet 470 is in this range, the stress caused by the difference in thermal expansion coefficient between the semiconductor element and the substrate can be alleviated.

在該樹脂絕緣薄片470上,利用C02雷射以0 1.4mm之 遮罩直徑、2. Omj之能量密度、1冲程之條件形成0 65 μ m 之貫穿孔472 (參照第7圖(b ))。其後,浸漬於60g/ L 之含有過錳酸之80 °C溶液內10分鐘,實施樹脂絕緣薄片 4 70表面之粗化。其次,將已實施粗化之製作中之基板浸 漬於中和溶液(Shipley公司製、商品名稱Circuit Board MLB NEUTRALIZER)進行水洗。此外,將基板浸漬於含 有二氯化鈀(PbCl2)及氯化亞鍚(SnCl2)之觸媒液中, 析出鈀金屬,使鈀觸媒附著於樹脂絕緣薄片470表面(含 貫穿孔472之內壁在內)。其次,將基板浸漬於無電解鍍 銅水溶液中,以34°C之液溫度進行40分鐘之處理,在樹脂 絕緣薄片470表面及貫穿孔472之壁面形成厚度爲0.6〜3.0 //m之無電解鍍銅膜(圖上未標示)。此外,無電解鍍銅 水溶液使用具有以下之組成之物。硫酸銅:〇.〇3mol/ L、 EDTA : 0.200mol/ L、HCHO : 0 · 1 g / L、N a Ο Η : 0 · 1 m ο 1 / L、雙砒啶:l〇〇mg/L、聚乙二醇(PEG) : 〇.lg / L。其次,在無電解鍍銅膜上形成乾膜,並以以下之條 件形成厚度爲25/zm之電解鍍銅膜(圖上未標示)。此外 ,電解鍍銅液使用具有以下之組成之物。硫酸:200g/ L 201116186 ' 硫酸銅:80g/L、添加劑:19.5ml/L (ATOTECH JAPAN公司製、KAPAROSHIDO GL )。此外,電解鑛銅係 在以下之條件實施。電流密度1 A/ dm2、時間1 1 5分、溫度 23 ± 2 °C。其次,剝離乾膜460,得到相當於第1圖及第2圖 之多層印刷配線板1 0 (參照第7圖(c ))。此外,樹脂絕 緣薄片470相當於應力緩和部50。此外,塡滿貫穿孔472之 鍍銅膜474則相當於各種端子61、62、63。 亦可以在其後,塗布市販之抗焊組成物並進行乾燥處 理後,以使形成鉻層之側密合於抗焊層之方式載置利用鉻 層描繪著抗焊開口部之圓形圖案(遮罩圖案)之鹼石灰玻 璃基板,以紫外線進行曝光·顯影後進行加熱處理,形成 使各種端子61、62、63上面形成開口之抗焊層之圖案,其 後,實施無電解鍍鎳並進一步實施無電解鍍金,形成鍍鎳 層及鍍金層,再印刷焊膏並利用回焊來形成焊塊。此外, 可以形成抗焊層,亦可以不形成抗焊層。 依據以上詳細說明之多層印刷配線板1 〇,因爲連結於 電源線及接地線間之層狀電容器部40之高介電質層43係陶 瓷製,與傳統之含有無機塡料之有機樹脂製時相比,具有 較高之介電常數,故層狀電容器部40亦具有較大之靜電容 。因此,半導體元件之導通斷開之頻率爲較高之數GHz〜 數十GHz (3GHz〜20GHz)之狀況下,亦可發揮充分解耦 合效果,故不易發生電位之瞬間降低。 此外,一般而言,因爲堆積部30通常係以200 °C以下 之溫度條件進行製作,在形成堆積部30之途中很難實施高 -23- 201116186 介電質材料之燒成來使其成爲陶瓷,上述實施例中,因爲 層狀電容器部40之高介電質層43係與堆積部30分開之實施 高介電質材料之燒成來形成陶瓷,故很容易使其具有夠高 之介電常數。 此外,用以構成層狀電容器部40之第1層狀電極41, 係形成於高介電質層43之兩面當中之距離安裝部60較遠之 第1面之平塗圖案,亦即,係形成於高介電質層43下面之 平塗圖案,第2層狀電極42係形成於距離安裝部60較近之 第2面之平塗圖案,亦即,係形成於高介電質層43上面之 平塗圖案,且爲具有可使連結於第1層狀電極41之通孔61a 以非接觸狀態通過之通過孔42a之形狀,故各層狀電極41 、42具有夠大之面積,而該層狀電容器部40亦具有較大之 靜電容。此處,連結於第1層狀電極41之通孔61a及連結第 2層狀電極42之通孔62a因係格子狀之交互並列,回路電感 會較低,故較容易防止電源電位之瞬間降低。此外,通孔 6 1 a及通孔62 a亦可以爲十字形之交互並列,亦可得到相同 效果。 此外,層狀電容器部40之第1及第2層狀電極41、42間 之距離,因爲設定成10/zm以下之實質上不會發生短路之 距離,層狀電容器部40之電極間距離極小,故該層狀電容 器部40亦具有較大之靜電容。 其次,在靜電容因爲只有層狀電容器部40而不足時, 可利用晶片電容器73來補充該不足份。亦即,只要配合需 要來搭載晶片電容器73即可。此外,解耦合效果會因爲晶 201116186 片電容器73及半導體元件之配線愈長而愈低,然而,此處 因爲安裝部60之表面側設置著晶片電容器73,而縮短半導 體元件之配線,故可抑制解耦合效果之降低。 此外,即使安裝於安裝部60之半導體元件、及層狀電 容器部40或堆積部30之間因爲熱膨脹差而產生應力,因爲 應力緩和部50可吸收該應力而不會造成問題。此外,應力 緩和部50亦可只形成於安裝在安裝部60之半導體元件之正 φ 下方。因爲會造成問題之熱膨脹差所導致之應力,主要係 位於半導體元件之正下方,若只在該部份形成應力緩和部 50,可降低材料成本。 此外,本發明並未受限於上述實施例,只要屬於本發 明之技術範圍內,可以爲各種實施形態。 [實施例2] 第8圖係實施例2之多層印刷配線板1 1 0之縱剖面圖( φ 只圖示中心線之左側)。本實施例之多層印刷配線板1 1 0 如第8圖所示,具有:和實施例1相同之核心基板20、位於 該核心基板20上面之利用通孔34電性連結於隔著樹脂絕緣 層36實施積層之配線圖案22及配線圖案32之堆積部30、積 層於該堆積部3 0之層間絕緣層1 2 0、由積層於該層間絕緣 層120之高介電質層143及夾著該高介電質層143之第1及第 2層狀電極141及142所構成之層狀電容器部140、積層於該 層狀電容器部1 4 0之以彈性材料形成之應力緩和部1 5 0、用 以安裝半導體元件之安裝部160、以及配設於該安裝部160 -25- 201116186 周圍之晶片電容器配置區域1 7 0。 本實施例之層狀電容器部140之第1層狀電極141係銅 電極,經由通孔1 6 1 a電性連結於安裝部1 60之接地用連結 墊161,第2層狀電極142係銅電極,經由通孔162a電性連 結於安裝部160之電源用連結墊162。因此’第1及第2層狀 電極141、142係分別連結至安裝於安裝部160之半導體元 件之接地線及電源線。 此外,第1層狀電極141係形成於高介電質層143下面 之平塗圖案,具有以非接觸狀態貫通連結於第2層狀電極 142之通孔162b之通過孔141a。通孔162b亦可以對應全部 電源用連結墊1 62之方式配設,此處,係以對應部份電源 用連結墊1 62之方式配設。其理由如下所示。亦即,全部 電源用連結墊162之數個電源用連結墊162係經由通孔162a 電性連結於第2層狀電極142,其餘之電源用連結墊162則 係利用經由通孔162 a電性連結於第2層狀電極142之其他電 源用連結墊1 62、及圖示未標示之配線(例如,配設於安 裝部1 60之配線)形成電性連結,故全部電源用連結墊1 62 皆連結於第2層狀電極142,只要具有至少1個從第2層狀電 極142朝下方延伸之通孔162b,即可經由該通孔162b將全 部電源用連結墊1 62連結至外部電源線。其次,對應部份 電源用連結墊1 62來配設通孔1 62b,可減少配設於第1層狀 電極141之通過孔141a之數,第1層狀電極141具有較大之 面積,層狀電容器部140亦具有較大之靜電容。此外,通 過孔141 a之數及形成通過孔141 a之位置應在考慮層狀電容 201116186 器部140之靜電容及通孔162a之配置等後才決定。 另一方面,第2層狀電極142係形成於高介電質層143 上面之平塗圖案,具有以非接觸狀態貫通連結於接地用連 結墊161之通孔161a之通過孔142a。通孔161a亦可以對應 全部接地用連結墊1 6 1之方式配設,然而,此處係以對應 部份接地用連結墊161之方式配設。其理由如下所示。亦 即,接地用連結墊1 6 1間係利用圖上未標示之配線(例如 φ ,配設於安裝部160之配線)形成電性連結’只要具有至 少1個不接觸從接地用連結墊161朝下方延伸之第2層狀電 極142之接觸第1層狀電極141之通孔161a ’即可經由該通 孔161a將全部接地用連結墊161連結至外部接地線》其次 ,對應部份接地用連結墊1 6 1來配設通孔1 6 1 a ’可減少配 設於第2層狀電極142之通過孔142a之數’第2層狀電極142 具有較大之面積,層狀電容器部14 0亦具有較大之靜電容 。此外,通過孔142a之數及形成通過孔142a之位置應在考 φ 慮層狀電容器部140之靜電容及通孔161a之配置等後才決 定。 如此,因爲可使層狀電容器部140具有較大之靜電容 ,故可發揮充分之解耦合效果,安裝於安裝部160之半導 體元件(1C )之電晶體不易發生電源不足之情形。此外’ 用以電性連結正下方沒有通孔之接地用連結墊161及正下 方具有通孔之接地用連結墊1 6 1之配線、及用以電性連結 正下方沒有通孔之電源用連結墊162及正下方具有通孔之 電源用連結墊1 6 2之配線,亦可配設於安裝部6 0,或者, -27- 201116186 亦可配設於核心基板20之表面或堆積部30。亦可在層狀電 容器部140及安裝部160間進一步配設配線層來連結該層。 應力緩和部1 50係由與實施例1相同之彈性材料所形成 。此外,配設於安裝部160之接地用連結墊161、電源用連 結墊162、以及訊號用連結墊163係以格子狀或十字形之方 式配列(參照第1圖)。此外,亦可在中央附近以格子狀 或十字形之方式配列接地用連結墊1 6 1及電源用連結墊1 62 ,並在其周圍以格子狀或十字形或隨機之方式配列訊號用 連結墊163。安裝部160之端子數爲1〇〇〇〜300000。在該安 裝部1 60周圍形成複數晶片電容器配置區域1 70,並在該晶 片電容器配置區域170形成複數對以分別連結晶片電容器 173之接地用端子及電源用端子爲目的之接地用連結墊171 及電源用連結墊172。 各接地用連結墊171係經由層狀電容器部140之第1層 狀電極141連結至外部電源之負極,各電源用連結墊172則 經由第2層狀電極1 4 2連結至外部電源之正極。本實施例之 接地用連結墊1 6 1及電源用連結墊1 62係分別相當於申請專 利範圍第8項之第1連結墊及第2連結墊,通孔161a及通孔 162b分別相當於申請專利範圍第8項之第1棒狀端子及第2 棒狀端子》 其次,參照第9圖〜第11圖,針對本實施例之多層印 刷配線板1 1 〇之製造步驟進行說明。 首先,如第9圖(a)所示,準備至少在核心基板20之 單面形成堆積部30之基板500,利用真空層疊機以溫度50 201116186 〜150°C、壓力〇·5〜1.5MPa之層疊條件將層間絕緣層510 (成爲第8圖之層間樹脂層120之熱硬化性絕緣膜’ AJINOMOTO公司製、ABF-45SH)貼附於堆積部30上。其 次,利用真空層疊機以溫度50〜150°C、壓力0.5〜105MPa 之層疊條件將預先製作之以銅箔5 22及銅箔5 26夾住高介電 質層524之構造之高介電質薄片5 20貼附於層間絕緣層510 上,其後,實施1 5 0 °C、1小時之乾燥(參照第9圖(b )) φ 。層疊時之高介電質薄片520之兩銅箔522、526應皆爲未 形成電路之平塗層。若以蝕刻等除去兩銅箔5 22、5 26之一 部份,(i )正背面之金屬殘存率會改變,或者,以除去 部份爲起點,高介電質薄片會形成曲折狀,(ii)若除去 部份銅箔而形成角部(參照第12圖),則層疊壓力會集中 於該部份’ (iii)因爲層疊機直接接觸高介電質層等原因 ’高介電質層容易產生龜裂,在後面之電鍍步驟中,若對 該龜裂部份進行電鍍,則兩銅箔間會形成短路。此外,在 • 層疊前若除去部份電極,則會導致高介電質薄片之靜電容 減少之問題’且實施該高介電質薄片之層疊時,必須實施 高介電質薄片及堆積部之位置對準再貼合。此外,高介電 質薄片因爲較薄而不具剛性,故除去部份銅箔時之位置精 度會較差。此外’若考慮調正精度就必須除去部份銅箔, 因此必須除去較多銅箔,調正精度亦會因爲高介電質薄片 較薄而變差。基於以上之理由,層疊時之高介電質薄片 520之兩銅箱522、526應皆爲未形成電路之平塗層。 其次’針對高介電質薄片52〇之製作步驟進行說明。 -29- 201116186 (1) 在乾燥氮中,將濃度l.o莫耳/公升之二乙氧基 鋇及雙四異丙氧基鈦溶解於經過脫水之甲醇及2 -甲基乙二 醇之混合溶媒(體積比3: 2),在室溫之氮環境下實施3 曰之攪拌,調整成鋇及鈦之烷氧化物前驅組成物溶液。其 次,在〇 °C下實施該前驅體組成物溶液之攪拌,以0.5微升 /分之速度在氮氣流中實施預先經過脫羧處理之水之噴霧 ,進行加水分解。 (2) 以0.2微米之過濾器濾出以此方式製作之溶凝膠 溶液之析出物等。 (3 )將上述(2 )製作之過濾液以1 500rpm、1分鐘之 方式旋塗於厚度12/im之銅箔522 (後來之第1層狀電極141 )上。將旋塗著溶液之基板置於保持150 °C之熱板上,實 施3分鐘之乾燥。其後,將基板置入保持於850 °C之電爐中 ,實施15分鐘之燒成。此處,以1次旋塗/乾燥/燒成可 得到膜厚〇.〇3 之方式調整溶凝膠液之粘度。此外,第1 層狀電極141除了可採用銅以外,尙可採用鎳、白金、金 、銀等。 (4) 重複實施40次旋塗/乾燥/燒成’得到1.2/zm 之高介電質層524。 (5) 其後,利用濺鍍等真空蒸鍍裝置在高介電質層 5 24上形成銅層,並以電解電鍍等使該銅層上具有程 度之銅,形成銅箔526 (後來之第2層狀電極142之一部份 )。如此,可得到高介電質薄片520。介電特性係利用 INPEDANCE / GAIN PHASE ANALYZER ( HEWLETT- 201116186 PACHARD公司製、品名:4194A)以頻率1kHz、溫度25°C 、Ο SC電平IV之條件進行檢測,該相對介電係數爲1.8 5 0。 此外,亦可利用真空蒸鍍形成銅以外之白金及金等之金屬 層,或者,亦可利用電解電鍍形成銅以外之鎳及錫等之金 屬層。此外,高介電質層係鈦酸鋇,然而,使用其他溶凝 膠溶液,高介電質層亦可以爲鈦酸緦(SrTi03 )、氧化鉬 (Ta03、Ta205 )、锆鈦酸鉛(PZT )、锆鈦酸鑭鉛( φ PLZT )、銷鈦酸鈮鉛(PNZT )、锆鈦酸鈣鉛(PCZT )、 以及銷鈦酸緦鉛(P S ZT )之其中任一方。 此外,高介電質薄片520亦可以其他方法來製作。亦 即’使鈦酸鋇粉末(FUTI TITANIUM INDUSTRY製、 HPBT系歹IJ )分散於以相對於鈦酸鋇粉末之全重量爲5重量 份之聚乙烯醇、5 0重量份之純水、及1重量份之當做溶劑 系可塑劑使用之鄰苯二甲酸二異辛酯或鄰苯二甲酸二丁酯 之比例進行混合之黏結劑溶液,並利用輥塗器、刮刀、及 φ α塗布器等之印刷機將厚度12 // m之銅箔522 (後來之第1 層狀電極141)印刷成厚度爲5〜7μιη程度之薄膜狀,實施 6CTC之1小時、80°C之3小時、100°C之1小時、120°C之1小 時、以及1 5 0 °C之3小時乾燥,當做未燒成層使用。亦可利 用輥塗器及刮刀等等印刷機將含有BaTi〇3以外之從SrTi03 、Ta03、Ta205、PZT、PLZT、PNZT、PCZT、以及 PSZT 所構成之群組所選取之1種或2種以上之金屬氧化物之膏印 刷成厚度爲0.1〜10 之薄膜狀’進行乾燥並當做未燒成 層使用。印刷後,對該未燒成層實施600〜950 °c之溫度範 -31 - 201116186 圍之燒成,得到高介電質層524。其後,利用濺鍍等真空 蒸鍍裝置在高介電質層5 24上形成銅層,並以電解電鍍等 使該銅層上具有10从m程度之銅,形成銅箔526 (後來之第 2層狀電極142之一部份)。此外,亦可利用真空蒸鍍形成 銅以外之白金及金等之金屬層,或者,亦可利用電解電鍍 形成銅以外之鎳及錫等之金屬層。其他,亦可以採用將鈦 酸鋇當做標靶之濺鍍法。 其次,在已積層著高介電質薄片5 20之製作中之基板 之特定位置利用碳酸氣雷射、UV雷射、YAG雷射、以及激 生分子雷射等,形成貫穿孔530、531 (參照第9圖(c)) 。深度較深之貫穿孔5 3 0係貫通高介電質薄片5 20及層間絕 緣層5 1 0之到達堆積部3 0之配線圖案3 2表面之貫穿孔。深 度較淺之貫穿孔531係實通銅箔526及高介電質層524之到 達銅箔522表面之貫穿孔。此處之貫穿孔形成上,係先形 成深貫穿孔53 0,然後再形成淺貫穿孔53 1 »以變更雷射冲 程數之方式來實施深度之調整。具體而言’貫穿孔53 1係 利用 Hitachi Via Mechanics, Ltd.製 UV雷射,以輸出 3 〜 10W、頻率30〜60kHz、冲程數4之條件實施,貫穿孔530 則除了冲程數爲3 1以外,其餘條件相同。其後’將後述之 貫穿孔充塡用樹脂532充塡至貫穿孔530、531內’實施80 t之1小時、120°C之1小時、150°C之30分鐘之乾燥(參照 第9圖(d))。此外,貫穿孔530、531並未以對應第8圖 所示之電源用連結墊162及接地用連結墊161之全部( 3000000個)之方式形成。 201116186 貫穿孔充塡用樹脂係以下述方法製作。係混合1 00重 量份之雙酚F型環氧單體(Japan Epoxy Resins Co.,Ltd.製 、分子量:3 10、商品名稱:E-8 07 )、及6重量份之咪唑 硬化劑(四國化成製、商品名稱:2E4MZ-CN ),此外, 將170重量份之平均粒徑1.6a m之Si02球狀粒子混合至該 混合物,以3支滾筒進行混練而將該混合物之23 ± 1 °C時之 粘度調整45000〜49000cps,而得到貫穿孔充塡用樹脂。 φ 其次,在前步驟完成充塡之貫穿孔充塡用樹脂532形 成貫穿孔530a、531a,並浸漬過錳酸溶液實施粗化,其後 ,實施1 70 °C之3小時乾燥硬化,使其完全硬化(參照第9 圖(e ))。貫穿孔5 3 0a係貫通貫穿孔充塡用樹脂5 3 2之到 達堆積部30之配線圖案32表面之貫穿孔。另一方之貫穿孔 53 la則係貫通貫穿孔充塡用樹脂5 3 2、銅箔522、以及層間 絕緣層510之到達堆積部30之配線圖案32表面之貫穿孔。 此外,貫穿孔5 30a係利用C02雷射以0 1.4mm之遮罩直徑 0 、2.Omj之能量密度、2冲程之條件形成,貫穿孔53 la之形 成上,除了以UV雷射實施5 2冲程以外,其餘條件相同( 輸出:3〜10w、頻率:30〜60kHz) 〇 其後,使無電解鍍銅用觸媒附著於基板表面並浸漬於 如下之無電解鑛銅液,在基板表面形成0.6〜3 ·0 v m之無 電解鍍銅膜5 40 (參照第10圖(a))。此外,無電解鍍銅 水溶液使用具有以下之組成之物。硫酸銅:〇.〇3mol/L、 EDTA: 0.200mol/L' HCHO: 0.1g/L' NaOH: O.lmol/ 匕、〇:,^’-雙砒啶:1〇〇1^/[、聚乙二醇(?£0)0_18/1^ -33- 201116186 其次,將市販之乾膜貼附於無電解鍍銅膜540上,並 實施曝光·顯影,形成抗鍍層541 (參照第10圖(b)), 在未形成抗鍍層之部份形成厚度爲25/zm之電解鑛銅膜542 (參照第1〇圖(c))。此外,電解鍍銅液使用具有以下 之組成之物。硫酸:200g/ L、硫酸銅:80g/ L、添加劑 :19.5ml/ L ( ATOTECH J A P AN 公司製、K A P A R 0 S ΗID Ο GL )。此外,以如下之條件實施電解鍍銅。電流密度1 A /dm2、時間115分、溫度23±2°C。其次,剝離抗鍍層541 ,對殘留著該抗鍍層541之部份以硫酸-過氧化氫系蝕刻液 進行蝕刻,亦即,以硫酸-過氧化氫系蝕刻液對存在於電 解鍍銅膜542間之無電解鍍銅膜540進行蝕刻(快速蝕刻) ,形成連結於上部電極543及銅箔5 22之成形段544 (參照 第 10圖(d ))。 其次,以溫度50〜150°C、壓力〇·5〜1.5MPa之層疊條 件將下述之應力緩和薄片5 5 0 (第8圖之應力緩和部150 ) 貼附於上部電極543及成形段544上,實施150度之1小時乾 燥(參照第10圖(e))。 應力緩和薄片5 5 0係以如下所示之方法製作。亦即, 使用輥塗器(CERMA TRONICS貿易製),將溶解著100重 量份之萘型環氧樹脂(日本化藥(股)製、商品名稱: NC-7000L ) 、20重量份之酚-二甲苯乙二醇縮合樹脂(三 井化學製、商品名稱:XLC-LL) 、90重量份之當做架橋 橡膠粒子之Tg爲-50°C之羧酸變性NBR ( JSR (股)製、商 201116186 品名稱:XER-91)、以及4重量份之1-氰乙基-2-乙基-4-甲 基咪唑之300重量份之乳酸乙酯之樹脂組成物,塗布於聚 甲基戊烯(TPX )(三井石油化學工業製、商品名稱: OPULENT X88 )製之42〜45// m厚度之薄膜上,其後,實 施8 0 °C之2小時、1 2 0 °C之1小時、1 5 0 °C之3 0分鐘乾燥,得 到厚度40/zm之應力緩和薄片。此外,該應力緩和薄片之 楊氏模數在30°C時爲500MPa。 φ 其次,在應力緩和薄片5 50之特定位置,利用C02雷射 以靟.1.4mm之遮罩直徑、2.0mj之能量密度、1冲程形成通 孔560 (參照第1 1圖(a ))。其次,實施粗化處理及150 °C之3小時乾燥硬化,使應力緩和薄片5 50完全硬化。其後 ,實施附著觸媒、化學銅、抗鍍層形成、電鍍銅、抗鍍層 剝離、快速蝕刻之步驟,將金屬充塡至通孔560,且在最 表層之各通孔560上面形成連結墊(接地用連結墊161、電 源用連結墊1 62、訊號用連結墊1 63 ),得到具有安裝部 φ 1 60之多層印刷配線板1 1 0 (第1 1圖(b ))。此外,連結 於成形段544及銅箔5 42之接地用連結墊161係連結至接地 線,連結於上部電極543之電源用連結墊1 62係連結至電源 線。此外,訊號用連結墊1 63係連結於信號線。此處,銅 箔522相當於第1層狀電極141,銅箔526及上部電極543相 當於第2層狀電極142,高介電質層524相當於高介電質層 143,利用上述形成層狀電容器部140。 其後,亦可在安裝部60之各端子上形成焊塊(形成方 法參照實施例1 )。此外,如第8圖所示之安裝著晶片電容 •35- 201116186 器173時,在第9圖(b )步驟後,實施以利用導體5 62電性 連結晶片電容器1 73之一方端子及第1層狀電極1 4 1之蝕刻 步驟(所謂掩蔽法)。該蝕刻步驟係使用氯化銅蝕刻液, 然而,係蝕刻至銅箔526及高介電質層524後只對銅箔522 進行少許蝕刻之短時間處理。最後,將連結於該銅箔522 之金屬層配設於應力緩和薄片5 5 0,而將連結墊1 7 1配設於 該金屬層之上面。此外,以連結晶片電容器1 7 3之另一方 端子爲目的之連結墊1 72係形成於充塡至形成於應力緩和 薄片550之一個通孔560之金屬之上面。 依據以上詳細說明之實施例2之多層印刷配線板1 1 0, 可得到與上述實施例1相同之效果。本實施例中,係以模 組正下方之層狀電容器部140之靜電容C爲0.5/zF之方式來 決定第1層狀電極141及第2層狀電極142之相對面積S,並 依據該相對面積S來決定第1層狀電極141之通過孔141a之 數及位置、以及第2層狀電極142之通過孔142a之數及位置 。此處,相對面積S係利用C= e Q · ε r · d/ S來計算。亦 即,因爲高介電質層142之相對介電係數ε··爲1850、其厚 度d爲1.2/zm,將該値代入上式,且靜電容C以0.5yF代入 ,即可計算相對面積S。此外,ε 〇係真空時之介電常數( 定數)。 [實施例3] 第1 3圖係實施例3之多層印刷配線板2 1 0之縱剖面圖( 只圖示中心線之左側)。本實施例之多層印刷配線板2 1 0 -36- 201116186 如第1 3圖所示,具有:和實施例1相同之核心基板2 0、位 於該核心基板20上面之利用通孔34電性連結於隔著樹脂絕 緣層36實施積層之配線圖案22及配線圖案32之堆積部30、 積層於該堆積部30之層間絕緣層220、由積層於該層間絕 緣層220之高介電質層243及夾著該高介電質層243之第1及 第2層狀電極241及242所構成之層狀電容器部240、積層於 該層狀電容器部240之層間絕緣層245、積層於該層間絕緣 φ 層245之以彈性材料形成之應力緩和部2 5 0、用以安裝半導 體元件之安裝部260、以及配設於該安裝部260周圍之晶片 電容器配置區域270。 本實施例之層狀電容器部240之第1層狀電極241係形 成於高介電質層243下面之平塗圖案之銅電極,電性連結 於安裝部260之接地用連結墊261。在說明上,將接地用連 結墊261分成接地用連結墊261χ及接地用連結墊261y之2種 類。其中,接地用連結墊26 lx係經由通孔26 la電性連結於 φ 成形段266x。該成形段266x之正下方沒有通孔。此外,接 地用連結墊261 y係經由通孔26 la連結於成形段2 66y,該成 形段266y則經由通孔26 lb電性連結於第1層狀電極241.及-堆 積部3 0之配線圖案3 2之接地用配線。此外,連結於通孔 261b之成形段268與第2層狀電極242爲電性分離。此外, 連結於接地用連結墊26 lx之成形段266x及連結於接地用連 結墊261y之成形段266y係利用配線246 (參照第14圖)形 成電性連結。結果,全部接地用連結墊26 1會成爲同電位 。如此,第1層狀電極241除了連結於各接地用連結墊26 1 -37- 201116186 以外,尙連結於堆積部30之配線圖案32之接地用配線,而 經由該接地用配線連結至外部接地線。此外,第1層狀電 極24 1則具有以非接觸狀態貫通後述通孔262c之通過孔 241a,然而,通孔262c如後面所述,係以對應有限電源用 連結墊262y之方式來配設,故只需要較少之通過孔24 la之 數。結果,第1層狀電極24 1具有較大之面積,層狀電容器 部240亦具有較大之靜電容。此外,通過孔241 a之數及形 成通過孔241 a之位置,應在考慮層狀電容器部240之靜電 容等後才決定。 另一方面,第2層狀電極242係形成於高介電質層243 上面之平塗圖案之銅電極,電性連結於安裝部2 60之電源 用連結墊262。在說明上,將電源用連結墊262分成電源用 連結墊262x及電源用連結墊262y之2種類。其中,電源用 連結墊262x係經由通孔262a連結於成形段267x,該成形段 267x則經由通孔262b電性連結於第2層狀電極242。此外’ 電源用連結墊262y係經由通孔262a連結於成形段267y ’該 成形段267y則經由通孔262c以未接觸第1及第2層狀電極 241、242之方式電性連結於堆積部30之配線圖案32當中之 電源用配線。此外’連結於電源用連結墊2 62x之成形段 267x及連結於電源用連結墊262y之成形段267y係利用配線 2 4 7 (參照第1 4圖)形成電性連結。結果,全部電源用連 結墊262會成爲同電位。如此’第2層狀電極242除了連結 於各電源用連結墊2 6 2以外’尙連結於堆積部3 0之配線圖 案3 2之電源用配線,而經由該電源用配線連結至外部電源 201116186 線。因此,可從堆積部3 0之配線圖案3 2之電源用配線經由 通孔262c、配線247、以及通孔262b對第2層狀電極242供 應電源。此外,第2層狀電極242具有以非接觸狀態貫通孔 262c之通過孔242a、及以確保與成形段268絕緣爲目的之 通過孔242b,然而,通孔262c係配設於電源用連結墊262 之一部份之電源用連結墊262y,通過孔242b則係以對應於 接地用連結墊26 1之一部份之接地用連結墊26 1 y之方式配 φ 設,故只要較少之通過孔242a、242b之數。結果,第2層 狀電極2 42具有較大之面積,層狀電容器部240亦具有較大 之靜電容。此外,通過孔242a、242b之數及形成通過孔 2 42a、242b之位置,應在考慮層狀電容器部240之靜電容 等後才決定。 如此,因爲層狀電容器部240可具有較大之靜電容, 故具有充分之解耦合效果,安裝於安裝部2 60之半導體元 件(1C )之電晶體不易出現電源不足之情形。此外,接地 φ 用連結墊261x及接地用連結墊261y係經由層間絕緣層245 上之配線246形成連結,電源用連結墊262x及電源用連結 墊262y係經由層間絕緣層24 5上之配線247形成連結,然而 ,亦可將此種配線配設於比第2層狀電極更上方之其中任 一層(安裝部亦可)、核心基板20之表面、以及堆積部30 。此外,以任一層之配線連結接地用連結墊26 1 X及接地用 連結墊261y、以及電源用連結墊262x及電源用連結墊262y ,則無需將通孔261 a配設於全部接地用連結墊261之正下 方、及無需將通孔262a配設於全部電源用連結墊262之正 -39- 201116186 下方。如此,亦可減少安裝部正下方之層之成形段數。因 此,因爲可減少必須配設之通孔數及成形段數,故可實現 高密度化。 應力緩和部2 5 0與以與實施例1相同之彈性材料來形成 。此外,配設於安裝部2 60之接地用連結墊261、電源用連 結墊262、以及訊號用連結墊263與實施例1相同,係以格 子狀或十字形之方式配列(參照第1圖)’此外,其數亦 與實施例1相同。此處,訊號用連結墊263未接觸層狀電容 器部240之第1及第2層狀電極241、242之其中任一電極。 此外,亦可在中央附近以格子狀或十字形之方式配列接地 用連結墊261及電源用連結墊262,並在其周圍以格子狀或 十字形或隨機之方式配列訊號用連結墊263。該安裝部260 周圍形成複數晶片電容器配置區域270 ’該晶片電容器配 置區域270則形成複數對以分別連結晶片電容器273之接地 用端子及電源用端子爲目的之接地用連結墊271及電源用 連結墊272。 各接地用連結墊271係經由層狀電容器部240之第1層 狀電極241連結於外部電源之負極,各電源用連結墊272則 經由第2層狀電極242連結於外部電源之正極。本實施例之 接地用連結墊26 1及電源用連結墊262係分別相當於申請專 利範圍第9項之第1連結墊及第2連結墊,通孔261b及通孔 262c係分別相當於申請專利範圍第9項之第1棒狀端子及第 2棒狀端子。 各接地用連結墊271係經由層狀電容器部240之第1層 201116186 狀電極241連結於外部電源之負極,各電源用連結墊272則 係經由第2層狀電極242連結於外部電源之正極。本實施例 之接地用連結墊261及電源用連結墊262係分別相當於申請 專利範圍第6項之第1連結墊及第2連結墊,通孔261a、 2 61b及通孔2 62 a、262b則係分別相當於申請專利範圍第6 項之第1棒狀端子及第2棒狀端子。 其次,參照第15圖〜第17圖,針對本實施例之多層印 φ 刷配線板2 1 0之製造步驟進行說明。此外,第1 3圖及第1 4 圖係半導體元件之正下方(亦即,模組正下方)之電源用 連結墊261及接地用連結墊262之交互配列成格子狀或十字 形之部份之切割剖面圖,第1 5圖〜第1 7圖係交互配置著電 源用連結墊261及接地用連結墊262之部份之切割剖面圖。On the resin insulating sheet 470, a CO 2 laser is used to 0. 4mm mask diameter, 2.  The energy density of Omj and the condition of one stroke form a through hole 472 of 0 65 μm (refer to Fig. 7(b)). Thereafter, it was immersed in a 60 g/L solution containing permanganic acid at 80 ° C for 10 minutes to carry out roughening of the surface of the resin insulating sheet 4 70. Next, the substrate which was subjected to roughening was immersed in a neutralizing solution (manufactured by Shipley Co., Ltd., trade name Circuit Board MLB NEUTRALIZER) and washed with water. Further, the substrate is immersed in a catalyst liquid containing palladium chloride (PbCl 2 ) and lanthanum chloride (SnCl 2 ) to precipitate palladium metal, and the palladium catalyst is attached to the surface of the resin insulating sheet 470 (including the through hole 472). Wall). Next, the substrate was immersed in an electroless copper plating aqueous solution, and treated at a liquid temperature of 34 ° C for 40 minutes to form a thickness of 0 on the surface of the resin insulating sheet 470 and the wall surface of the through hole 472. 6~3. 0 //m electroless copper plating film (not shown). Further, an electroless copper plating aqueous solution is used having the following composition. Copper sulfate: 〇. 〇3mol/L, EDTA: 0. 200mol/L, HCHO: 0 · 1 g / L, N a Ο Η : 0 · 1 m ο 1 / L, acridine: l〇〇mg/L, polyethylene glycol (PEG): 〇. Lg / L. Next, a dry film was formed on the electroless copper plating film, and an electrolytic copper plating film (not shown) having a thickness of 25/zm was formed under the following conditions. Further, the electrolytic copper plating solution uses a composition having the following composition. Sulfuric acid: 200g / L 201116186 ' Copper sulfate: 80g / L, additive: 19. 5 ml/L (manufactured by ATOTECH JAPAN, KAPAROSHIDO GL). Further, electrolytic copper is carried out under the following conditions. Current density 1 A/dm2, time 1 15 minutes, temperature 23 ± 2 °C. Then, the dry film 460 is peeled off to obtain a multilayer printed wiring board 10 corresponding to Figs. 1 and 2 (see Fig. 7(c)). Further, the resin insulating sheet 470 corresponds to the stress relieving portion 50. Further, the copper plating film 474 of the through hole 472 is equivalent to the various terminals 61, 62, and 63. After that, the commercially available solder resist composition is applied and dried, and then the side on which the chrome layer is formed is adhered to the solder resist layer so that a circular pattern in which the solder resist opening portion is drawn by the chrome layer is placed. The soda-lime glass substrate of the mask pattern is subjected to heat treatment after exposure and development with ultraviolet rays, and a pattern of a solder resist layer having openings formed on the upper surfaces of the various terminals 61, 62, 63 is formed, and then electroless nickel plating is performed and further Electroless gold plating is performed to form a nickel plating layer and a gold plating layer, and the solder paste is printed and reflowed to form a solder bump. Further, a solder resist layer may be formed or a solder resist layer may not be formed. According to the multilayer printed wiring board 1A described in detail above, the high dielectric layer 43 of the layered capacitor portion 40 connected between the power supply line and the ground line is made of ceramic, and is made of a conventional organic resin-containing organic resin. In comparison, since the dielectric constant is high, the layered capacitor portion 40 also has a large electrostatic capacitance. Therefore, in the case where the frequency at which the semiconductor element is turned on and off is a high number of GHz to several tens of GHz (3 GHz to 20 GHz), a sufficient decoupling effect can be exhibited, so that an instantaneous drop in potential is less likely to occur. Further, in general, since the deposition portion 30 is usually produced under a temperature condition of 200 ° C or lower, it is difficult to perform the firing of the high--23-201116186 dielectric material on the way to form the deposition portion 30 to become a ceramic. In the above embodiment, since the high dielectric layer 43 of the layered capacitor portion 40 is formed by firing a high dielectric material separately from the deposition portion 30, it is easy to make it have a high dielectric. constant. Further, the first layered electrode 41 constituting the layered capacitor portion 40 is formed by a flat coating pattern on the first surface of the high dielectric layer 43 which is located farther from the mounting portion 60, that is, The flat coating pattern formed on the lower surface of the high dielectric layer 43 is formed by a flat coating pattern of the second surface closer to the mounting portion 60, that is, formed on the high dielectric layer 43. The upper flat pattern has a shape in which the through hole 42a that can be connected to the first layered electrode 41 passes through the hole 42a in a non-contact state, so that each of the layered electrodes 41 and 42 has a large enough area. The layered capacitor portion 40 also has a large electrostatic capacitance. Here, the through hole 61a connected to the first layered electrode 41 and the through hole 62a connecting the second layered electrode 42 are arranged in a lattice-like manner, and the loop inductance is low, so that it is easy to prevent the instantaneous decrease of the power supply potential. . In addition, the through holes 6 1 a and the through holes 62 a may also be cross-shaped and juxtaposed, and the same effect can be obtained. Further, since the distance between the first and second layered electrodes 41 and 42 of the layered capacitor portion 40 is set to be substantially no distance of 10/zm or less, the distance between the electrodes of the layered capacitor portion 40 is extremely small. Therefore, the layered capacitor portion 40 also has a large electrostatic capacitance. Next, when the static capacitance is insufficient due to only the layered capacitor portion 40, the wafer capacitor 73 can be used to supplement the insufficient portion. That is, the wafer capacitor 73 can be mounted as needed. In addition, the decoupling effect is lower because the wiring of the chip 201116186 chip capacitor 73 and the semiconductor element is longer. However, since the wafer capacitor 73 is provided on the surface side of the mounting portion 60, the wiring of the semiconductor element is shortened, so that it can be suppressed. The decoupling effect is reduced. Further, even if the semiconductor element mounted on the mounting portion 60 and the layered capacitor portion 40 or the stacking portion 30 are subjected to stress due to a difference in thermal expansion, the stress relieving portion 50 can absorb the stress without causing a problem. Further, the stress relieving portion 50 may be formed only under the positive φ of the semiconductor element mounted on the mounting portion 60. The stress caused by the difference in thermal expansion which causes problems is mainly located directly under the semiconductor element, and if the stress relieving portion 50 is formed only in this portion, the material cost can be reduced. Further, the present invention is not limited to the above embodiments, and may be various embodiments as long as it falls within the technical scope of the present invention. [Embodiment 2] Fig. 8 is a longitudinal sectional view of a multilayer printed wiring board 1 of Example 2 (φ is only shown on the left side of the center line). As shown in FIG. 8, the multilayer printed wiring board 1 10 of the present embodiment has a core substrate 20 similar to that of the first embodiment, and a through-hole 34 on the upper surface of the core substrate 20 is electrically connected to the resin insulating layer. 36. The stacked portion 30 of the wiring pattern 22 and the wiring pattern 32, the interlayer insulating layer 1200 laminated on the deposition portion 30, and the high dielectric layer 143 laminated on the interlayer insulating layer 120 and sandwiched therebetween The layered capacitor portion 140 composed of the first and second layered electrodes 141 and 142 of the high dielectric layer 143, and the stress relieving portion 150 formed of an elastic material laminated on the layered capacitor portion 1400 A mounting portion 160 for mounting a semiconductor element, and a wafer capacitor arrangement region 170 disposed around the mounting portion 160 - 25 - 201116186. The first layered electrode 141 of the layered capacitor portion 140 of the present embodiment is a copper electrode, and is electrically connected to the grounding connection pad 161 of the mounting portion 160 via the through hole 161a, and the second layered electrode 142 is copper. The electrode is electrically connected to the power supply connection pad 162 of the mounting portion 160 via the through hole 162a. Therefore, the first and second layered electrodes 141 and 142 are respectively connected to the ground line and the power supply line of the semiconductor element mounted on the mounting portion 160. Further, the first layered electrode 141 is formed in a flat coating pattern on the lower surface of the high dielectric layer 143, and has a through hole 141a penetrating through the through hole 162b of the second layered electrode 142 in a non-contact state. The through hole 162b may be disposed corresponding to all of the power supply connection pads 1 62, and is disposed to correspond to a part of the power supply connection pads 1 62. The reason is as follows. In other words, the plurality of power supply connection pads 162 of the power supply connection pads 162 are electrically connected to the second layered electrodes 142 via the through holes 162a, and the remaining power supply connection pads 162 are electrically connected via the through holes 162a. The other power supply connection pads 1 62 connected to the second layered electrode 142 and the unillustrated wirings (for example, the wirings disposed on the mounting portion 1 60) are electrically connected, so that all the power supply connection pads 1 62 are provided. Each of the power supply connection pads 1 62 is connected to the external power supply line via the through hole 162b as long as it has at least one through hole 162b extending downward from the second layered electrode 142. . Then, the number of the through holes 162a disposed in the first layered electrode 141 can be reduced by the number of the through holes 162a corresponding to the portion of the power supply connection pads 162, and the first layered electrode 141 has a large area. The capacitor portion 140 also has a large electrostatic capacitance. Further, the number of the through holes 141a and the position at which the through holes 141a are formed should be determined in consideration of the arrangement of the electrostatic capacitance of the layered capacitors 201116186 and the through holes 162a. On the other hand, the second layered electrode 142 is a flat coating pattern formed on the upper surface of the high dielectric layer 143, and has a through hole 142a that is connected to the through hole 161a of the grounding connection pad 161 in a non-contact state. The through hole 161a may be disposed so as to correspond to all of the grounding connection pads 161. However, the hole 161a is provided so as to correspond to the portion of the grounding connection pad 161. The reason is as follows. In other words, the grounding connection pads 161 are electrically connected by wires (for example, φ and wirings disposed on the mounting portion 160) which are not shown in the drawing, as long as they have at least one non-contact grounding connection pad 161. The through hole 161a' of the second layered electrode 142 which is extended downward is in contact with the first layered electrode 141, and all of the grounding connection pads 161 can be connected to the external grounding wire via the through hole 161a, and the corresponding portion is grounded. The connection pad 161 is provided with a through hole 1 6 1 a 'the number of the through holes 142a disposed in the second layered electrode 142 is reduced. The second layered electrode 142 has a large area, and the layered capacitor portion 14 is provided. 0 also has a large static capacitance. Further, the number of the through holes 142a and the position at which the through holes 142a are formed should be determined after the arrangement of the electrostatic capacitance of the layered capacitor portion 140 and the arrangement of the through holes 161a. As described above, since the layered capacitor portion 140 can have a large electrostatic capacitance, a sufficient decoupling effect can be exerted, and the transistor mounted on the semiconductor device (1C) of the mounting portion 160 is less likely to be insufficient in power supply. In addition, the wiring for the grounding connection pad 161 having no through hole directly underneath, and the wiring for the grounding connection pad 161 having the through hole directly underneath, and the power supply for electrically connecting the via hole without the through hole directly The pad 162 and the wiring for the power supply connection pad 162 having the through hole directly under the pad 162 may be disposed on the mounting portion 60, or -27-201116186 may be disposed on the surface of the core substrate 20 or the stacking portion 30. Further, a wiring layer may be further disposed between the layered capacitor portion 140 and the mounting portion 160 to connect the layers. The stress relieving portion 150 is formed of the same elastic material as in the first embodiment. Further, the grounding connection pads 161, the power supply connection pads 162, and the signal connection pads 163 disposed in the mounting portion 160 are arranged in a lattice shape or a cross shape (see Fig. 1). In addition, the grounding connection pad 161 and the power supply connection pad 1 62 may be arranged in a lattice shape or a cross shape near the center, and the signal connection pads may be arranged in a lattice shape, a cross shape or a random manner around the center. 163. The number of terminals of the mounting portion 160 is 1 〇〇〇 to 300,000. A plurality of wafer capacitor arrangement regions 1 70 are formed around the mounting portion 1 60, and a plurality of ground connection pads 171 for connecting the ground terminal and the power supply terminal of the wafer capacitor 173 are formed in the wafer capacitor arrangement region 170, and The power supply connection pad 172. Each of the grounding connection pads 171 is connected to the negative electrode of the external power source via the first layer electrode 141 of the layered capacitor portion 140, and each of the power source connection pads 172 is connected to the positive electrode of the external power source via the second layered electrode 142. The grounding connection pad 161 and the power supply connection pad 1 62 of the present embodiment correspond to the first connection pad and the second connection pad of the eighth item of the patent application, respectively, and the through hole 161a and the through hole 162b respectively correspond to the application. The first rod terminal and the second rod terminal of the eighth item of the patent range Next, the manufacturing steps of the multilayer printed wiring board 1 1 本 of the present embodiment will be described with reference to Figs. 9 to 11 . First, as shown in Fig. 9(a), a substrate 500 having a deposition portion 30 formed on at least one side of the core substrate 20 is prepared, and a vacuum laminator is used at a temperature of 50 201116186 to 150 ° C and a pressure of 5 5 to 1. In the lamination condition of 5 MPa, the interlayer insulating layer 510 (the thermosetting insulating film which is the interlayer resin layer 120 of Fig. 8 'ABF-45SH, manufactured by AJINOMOTO Co., Ltd.) is attached to the deposition portion 30. Secondly, the vacuum laminator is used at a temperature of 50 to 150 ° C and a pressure of 0. The lamination condition of 5 to 105 MPa is applied to the interlayer insulating layer 510 by preliminarily forming a high dielectric sheet 520 having a structure in which a copper foil 5 22 and a copper foil 5 26 sandwich the high dielectric layer 524, and thereafter, Dry at 150 ° C for 1 hour (see Figure 9 (b)) φ . The two copper foils 522, 526 of the high dielectric sheet 520 during lamination should all be flat coatings that do not form an electrical circuit. If one of the two copper foils 5 22 and 5 26 is removed by etching or the like, (i) the metal residual ratio of the front side or the back surface is changed, or the high dielectric sheet is formed into a meandering shape by using the removed portion as a starting point. Ii) If a part of the copper foil is removed to form a corner (refer to Fig. 12), the lamination pressure will concentrate on the portion '(iii) because the laminator is in direct contact with the high dielectric layer, etc. 'high dielectric layer Cracks are likely to occur, and in the subsequent plating step, if the cracked portion is plated, a short circuit is formed between the two copper foils. In addition, if some of the electrodes are removed before stacking, the static capacitance of the high dielectric sheet is reduced. When the stack of the high dielectric sheets is performed, it is necessary to implement a high dielectric sheet and a stack. Position and fit again. In addition, since the high dielectric sheet is thin and not rigid, the positional accuracy of removing a part of the copper foil is inferior. In addition, it is necessary to remove a part of the copper foil in consideration of the precision of the alignment. Therefore, it is necessary to remove a large amount of copper foil, and the accuracy of the alignment is also deteriorated due to the thinness of the high dielectric sheet. For the above reasons, the two copper boxes 522, 526 of the high dielectric sheet 520 at the time of lamination should all be flat coatings without forming an electrical circuit. Next, the production steps of the high dielectric sheet 52A will be described. -29- 201116186 (1) In dry nitrogen, the concentration will be l. o Moule / liter of diethoxy hydrazine and bis tetraisopropoxy titanium dissolved in dehydrated methanol and 2-methyl glycol mixed solvent (3: 2 by volume), nitrogen atmosphere at room temperature The stirring of 3 Torr was carried out to adjust the alkoxide precursor composition solution of bismuth and titanium. Next, the stirring of the precursor composition solution is carried out at 〇 ° C, to 0. At a rate of 5 μl/min, a pre-decarburized water spray was applied to the nitrogen stream to effect hydrolysis. (2) to 0. A 2-micron filter filters out precipitates and the like of the sol-gel solution prepared in this manner. (3) The filtrate prepared in the above (2) was spin-coated at 1,500 rpm for 1 minute on a copper foil 522 (hereinafter, the first layered electrode 141) having a thickness of 12/im. The substrate coated with the solution was placed on a hot plate maintained at 150 ° C and dried for 3 minutes. Thereafter, the substrate was placed in an electric furnace maintained at 850 ° C and fired for 15 minutes. Here, the film thickness can be obtained by spin coating/drying/sintering once. Adjust the viscosity of the molten gel solution in the manner of 〇3. Further, in addition to copper, the first layered electrode 141 may be made of nickel, platinum, gold, silver or the like. (4) Repeat 40 times of spin coating/drying/burning' to obtain 1. A high dielectric layer 524 of 2/zm. (5) Thereafter, a copper layer is formed on the high dielectric layer 524 by a vacuum vapor deposition apparatus such as sputtering, and copper is formed on the copper layer by electrolytic plating or the like to form a copper foil 526 (later) One of the two layered electrodes 142). In this way, a high dielectric sheet 520 can be obtained. The dielectric properties were measured using INPEDANCE / GAIN PHASE ANALYZER (manufactured by HEWLETT-201116186 PACHARD, product name: 4194A) at a frequency of 1 kHz, a temperature of 25 ° C, and a Ο SC level of IV. The relative dielectric constant was 1. 8 5 0. Further, a metal layer such as platinum or gold other than copper may be formed by vacuum deposition, or a metal layer such as nickel or tin other than copper may be formed by electrolytic plating. In addition, the high dielectric layer is barium titanate. However, with other lyophilized solutions, the high dielectric layer may also be barium titanate (SrTi03), molybdenum oxide (Ta03, Ta205), lead zirconate titanate (PZT). ), lead zirconate titanate (φ PLZT ), lead barium titanate (PNZT), lead zirconate titanate (PCZT), and pin strontium titanate (PS ZT ). In addition, the high dielectric sheet 520 can also be fabricated by other methods. In other words, 'the barium titanate powder (manufactured by FUTI TITANIUM INDUSTRY, HPBT system IJ) was dispersed in 5 parts by weight of polyvinyl alcohol, 50 parts by weight of pure water, and 1 with respect to the total weight of the barium titanate powder. a part by weight of a binder solution in which a solvent-based plasticizer is used in a ratio of diisooctyl phthalate or dibutyl phthalate, and a roll coater, a doctor blade, a φ α coater, or the like is used. The printing machine prints a copper foil 522 having a thickness of 12 // m (later the first layered electrode 141) into a film having a thickness of about 5 to 7 μm, and performing 6 hours of 6 CTC, 3 hours of 80 ° C, and 100 ° C. It was dried for 1 hour, 1 hour at 120 ° C, and 3 hours at 150 ° C, and used as an unfired layer. One or more selected from the group consisting of SrTi03, Ta03, Ta205, PZT, PLZT, PNZT, PCZT, and PSZT other than BaTi〇3 may be used by a printer such as a roll coater or a doctor blade. The metal oxide paste is printed to a thickness of 0. The film shape of 1 to 10 was dried and used as an unfired layer. After the printing, the unfired layer was fired at a temperature of from 600 to 950 ° C to a high dielectric layer 524. Thereafter, a copper layer is formed on the high dielectric layer 524 by a vacuum vapor deposition apparatus such as sputtering, and copper is formed on the copper layer by 10 or more degrees by electrolytic plating or the like to form a copper foil 526 (later) One of the two layered electrodes 142). Further, a metal layer such as platinum or gold other than copper may be formed by vacuum evaporation, or a metal layer such as nickel or tin other than copper may be formed by electrolytic plating. In addition, sputtering using barium titanate as a target can also be used. Next, through holes 530, 531 are formed at specific positions of the substrate in which the high dielectric sheet 520 has been laminated by using a carbon dioxide laser, a UV laser, a YAG laser, and an excited molecular laser. Refer to Figure 9(c)). The through hole 305 having a deep depth penetrates the through hole of the surface of the wiring pattern 3 2 of the high dielectric sheet 520 and the interlayer insulating layer 5 10 to the stacking portion 30. The deeper through hole 531 is a through hole of the copper foil 526 and the high dielectric layer 524 reaching the surface of the copper foil 522. Here, the through hole is formed by forming a deep through hole 53 0 and then forming a shallow through hole 53 1 » to adjust the depth by changing the number of laser strokes. Specifically, the through hole 53 1 utilizes Hitachi Via Mechanics, Ltd. The UV laser was applied under the conditions of an output of 3 to 10 W, a frequency of 30 to 60 kHz, and a stroke number of 4. The through hole 530 was the same except that the number of strokes was 3 1 . Then, the through-hole filling resin 532, which will be described later, is filled into the through-holes 530 and 531. The drying is carried out for one hour at 80 t, one hour at 120 ° C, and 30 minutes at 150 ° C (refer to Fig. 9). (d)). Further, the through holes 530 and 531 are not formed so as to correspond to all of the power supply connection pads 162 and the ground connection pads 161 shown in Fig. 8 . 201116186 A resin for through-hole filling was produced by the following method. Mix 100 parts by weight of bisphenol F-type epoxy monomer (Japan Epoxy Resins Co.) ,Ltd. Preparation, molecular weight: 3 10, trade name: E-8 07), and 6 parts by weight of imidazole hardener (four countries, product name: 2E4MZ-CN), in addition, 170 parts by weight of the average particle size of 1. 6O m of SiO 2 spherical particles were mixed into the mixture, and the mixture was kneaded by three rolls to adjust the viscosity of the mixture at 23 ± 1 ° C to 45,000 to 49000 cps to obtain a through-hole filling resin. φ Next, the through-holes 530a and 531a are formed by the resin 532 for filling the through-hole filling in the previous step, and the permanganic acid solution is immersed for roughening, and then dried and hardened at 1 70 ° C for 3 hours. Completely hardened (see Figure 9 (e)). The through hole 530a penetrates the through hole of the surface of the wiring pattern 32 of the stacking portion 30 through the resin 5323 for the through hole. The other through hole 53 la penetrates through the through hole hole filling resin 5 3 2, the copper foil 522, and the through hole of the interlayer insulating layer 510 reaching the surface of the wiring pattern 32 of the stacking portion 30. In addition, the through hole 5 30a uses a CO 2 laser to 0. 4mm mask diameter 0, 2. Omj's energy density and two-stroke conditions are formed, and the formation of the through hole 53 la is the same except that the UV laser is used for the 52 stroke, and the other conditions are the same (output: 3 to 10 w, frequency: 30 to 60 kHz). The electroless copper plating catalyst is attached to the surface of the substrate and immersed in the following electroless copper liquid to form a surface of 0. 6 to 3 · 0 v m No electrolytic copper plating film 5 40 (refer to Fig. 10 (a)). Further, an electroless copper plating aqueous solution is used having the following composition. Copper sulfate: 〇. 〇3mol/L, EDTA: 0. 200mol/L' HCHO: 0. 1g/L' NaOH: O. Lmol / 匕, 〇:, ^'-bisacridine: 1〇〇1^/[, PEG (?£0)0_18/1^ -33- 201116186 Secondly, the dry film of the market is attached to The electrolytic copper plating film 540 is subjected to exposure and development to form a plating resist 541 (see FIG. 10(b)), and an electrolytic copper film 542 having a thickness of 25/zm is formed in a portion where the plating resist is not formed (refer to 1〇图(c)). Further, the electrolytic copper plating solution uses a composition having the following composition. Sulfuric acid: 200g / L, copper sulfate: 80g / L, additives: 19. 5 ml/L (manufactured by ATOTECH J A P AN, K A P A R 0 S ΗID Ο GL ). Further, electrolytic copper plating was carried out under the following conditions. Current density 1 A / dm2, time 115 minutes, temperature 23 ± 2 °C. Next, the plating resist 541 is peeled off, and a portion of the plating resist 541 remaining thereon is etched with a sulfuric acid-hydrogen peroxide-based etching solution, that is, a sulfuric acid-hydrogen peroxide-based etching solution is present between the electrolytic copper plating film 542. The electroless copper plating film 540 is etched (rapidly etched) to form a molding section 544 that is coupled to the upper electrode 543 and the copper foil 522 (see Fig. 10(d)). Secondly, the temperature is 50~150 °C, the pressure is 〇·5~1. Lamination condition of 5 MPa The following stress relieving sheet 550 (stress relief portion 150 of Fig. 8) is attached to the upper electrode 543 and the molding section 544, and dried at 150 degrees for one hour (refer to Fig. 10 (e) )). The stress relieving sheet 550 was produced by the method shown below. In other words, 100 parts by weight of a naphthalene type epoxy resin (manufactured by Nippon Kayaku Co., Ltd., trade name: NC-7000L) and 20 parts by weight of phenol-two are dissolved by a roll coater (manufactured by CERMA TRONICS Trading Co., Ltd.). Toluene glycol condensed resin (manufactured by Mitsui Chemicals, trade name: XLC-LL), 90 parts by weight of carboxylic acid denatured NBR (JSR (stock) system, business 201116186 name) as a bridge rubber particle with a Tg of -50 °C : XER-91), and a resin composition of 300 parts by weight of ethyl lactate of 4 parts by weight of 1-cyanoethyl-2-ethyl-4-methylimidazole, coated on polymethylpentene (TPX) (Mitsubishi Petrochemical Industry, trade name: OPULENT X88) made of 42~45//m thick film, then 2 hours at 80 °C, 1 hour at 1 20 °C, 1 50 After drying at °C for 30 minutes, a stress relaxation sheet having a thickness of 40/zm was obtained. Further, the Young's modulus of the stress relieving sheet was 500 MPa at 30 °C. φ Next, at a specific position of the stress relieving sheet 550, a C02 laser is used. 1. 4mm mask diameter, 2. The energy density of 0 mj and the one-stroke forming via 560 (refer to Fig. 1 (a)). Next, the roughening treatment and the dry hardening at 150 ° C for 3 hours were carried out to completely cure the stress relieving sheet 505. Thereafter, a step of attaching a catalyst, chemical copper, plating formation, electroplating copper, plating peeling, and rapid etching is performed to fill the metal to the via 560, and a bonding pad is formed on each of the via holes 560 of the outermost layer ( The grounding connection pad 161, the power supply connection pad 1 62, and the signal connection pad 1 63 ) are used to obtain a multilayer printed wiring board 1 1 0 having a mounting portion φ 1 60 (Fig. 1 (b)). Further, the grounding connection pad 161 connected to the forming section 544 and the copper foil 540 is connected to the grounding wire, and the power supply connecting pad 162 connected to the upper electrode 543 is connected to the power supply line. Further, the signal connection pad 163 is connected to the signal line. Here, the copper foil 522 corresponds to the first layered electrode 141, the copper foil 526 and the upper electrode 543 correspond to the second layered electrode 142, and the high dielectric layer 524 corresponds to the high dielectric layer 143. Capacitor portion 140. Thereafter, solder bumps may be formed on the respective terminals of the mounting portion 60 (see Embodiment 1 for the formation method). Further, when the wafer capacitor 35-201116186 is mounted as shown in FIG. 8, after the step (b) of FIG. 9, the one terminal and the first terminal of the wafer capacitor 1 73 are electrically connected by the conductor 5 62. An etching step of the layered electrode 141 (so-called masking method). This etching step uses a copper chloride etching solution. However, after etching to the copper foil 526 and the high dielectric layer 524, only a small amount of etching of the copper foil 522 is performed for a short time. Finally, the metal layer bonded to the copper foil 522 is disposed on the stress relaxation sheet 550, and the connection pad 177 is disposed on the upper surface of the metal layer. Further, a bonding pad 1 72 for the purpose of connecting the other terminal of the wafer capacitor 173 is formed on the metal which is filled to a through hole 560 formed in the stress relaxation sheet 550. According to the multilayer printed wiring board 110 of the second embodiment described in detail above, the same effects as those of the above-described first embodiment can be obtained. In this embodiment, the electrostatic capacitance C of the layered capacitor portion 140 directly under the module is 0. The relative area S of the first layered electrode 141 and the second layered electrode 142 is determined by the method of 5/zF, and the number and position of the through holes 141a of the first layered electrode 141 are determined based on the relative area S, and The number and position of the through holes 142a of the two layered electrodes 142. Here, the relative area S is calculated using C = e Q · ε r · d / S. That is, since the high dielectric constant 142 has a relative dielectric constant ε·· of 1850 and a thickness d of 1. 2/zm, the 値 is substituted into the above formula, and the static capacitance C is 0. By substituting 5yF, the relative area S can be calculated. In addition, the dielectric constant (fixed number) of ε 〇 is vacuum. [Embodiment 3] Fig. 3 is a longitudinal sectional view of a multilayer printed wiring board 2 of Embodiment 3 (only the left side of the center line is shown). The multilayer printed wiring board 2 1 0 - 36 - 201116186 of the present embodiment has the same core substrate 20 as that of the first embodiment, and is electrically connected by the through hole 34 on the core substrate 20 as shown in FIG. The stacked portion 30 of the wiring pattern 22 and the wiring pattern 32 which are laminated via the resin insulating layer 36, the interlayer insulating layer 220 laminated on the deposition portion 30, and the high dielectric layer 243 laminated on the interlayer insulating layer 220 and The layered capacitor portion 240 including the first and second layered electrodes 241 and 242 sandwiching the high dielectric layer 243, the interlayer insulating layer 245 laminated on the layered capacitor portion 240, and the interlayer insulating layer φ The layer 245 has a stress relaxing portion 250 formed of an elastic material, a mounting portion 260 for mounting the semiconductor element, and a wafer capacitor arrangement region 270 disposed around the mounting portion 260. The first layered electrode 241 of the layered capacitor portion 240 of the present embodiment is formed on the copper electrode of the flat pattern on the lower surface of the high dielectric layer 243, and is electrically connected to the ground connection pad 261 of the mounting portion 260. In the description, the grounding connection pad 261 is divided into two types of a ground connection pad 261 and a ground connection pad 261y. The grounding connection pad 26 lx is electrically connected to the φ forming section 266x via the through hole 26 la. There is no through hole directly below the forming section 266x. In addition, the grounding connection pad 261 y is connected to the forming section 2 66y via the through hole 26 la, and the forming section 266y is electrically connected to the first layered electrode 241 via the through hole 26 lb. And the grounding wiring of the wiring pattern 3 2 of the stacking portion 30. Further, the forming section 268 connected to the through hole 261b and the second layered electrode 242 are electrically separated. Further, the forming section 266x connected to the grounding connection pad 26 lx and the forming section 266y connected to the grounding connection pad 261y are electrically connected by a wiring 246 (see Fig. 14). As a result, all of the grounding connection pads 26 1 will have the same potential. In this way, the first layered electrode 241 is connected to the grounding wiring of the wiring pattern 32 of the deposition unit 30, and is connected to the external ground line via the grounding wiring, in addition to the grounding connection pads 26 1 - 37 to 2011 16186. . In addition, the first layered electrode 24 1 has a through hole 241a that penetrates the through hole 262c described later in a non-contact state. However, the through hole 262c is disposed so as to correspond to the finite power supply connection pad 262y as will be described later. Therefore, only a small number of holes 24 la are required. As a result, the first layered electrode 24 1 has a large area, and the layered capacitor portion 240 also has a large electrostatic capacitance. Further, the number of the holes 241a and the position of the through holes 241a should be determined after considering the electrostatic capacitance of the layered capacitor portion 240 or the like. On the other hand, the second layered electrode 242 is a copper electrode formed in a flat pattern on the upper surface of the high dielectric layer 243, and is electrically connected to the power supply connection pad 262 of the mounting portion 260. In the description, the power supply connection pad 262 is divided into two types of the power supply connection pad 262x and the power supply connection pad 262y. The power supply connection pad 262x is coupled to the molding section 267x via the through hole 262a, and the molding section 267x is electrically connected to the second layered electrode 242 via the through hole 262b. Further, the power supply connecting pad 262y is connected to the forming section 267y via the through hole 262a. The forming section 267y is electrically connected to the stacking section 30 via the through hole 262c so as not to contact the first and second layered electrodes 241 and 242. The power supply wiring among the wiring patterns 32. Further, the forming section 267x connected to the power supply connection pad 2 62x and the molding section 267y connected to the power supply connection pad 262y are electrically connected by the wiring 247 (see Fig. 14). As a result, all of the power supply connection pads 262 will have the same potential. The second layer electrode 242 is connected to the power supply wiring of the wiring pattern 3 2 of the deposition unit 30 in addition to the connection pads 2 6 2 of the power supply, and is connected to the external power source 201116186 via the power supply wiring. . Therefore, the second layered electrode 242 can be supplied with power from the power supply wiring of the wiring pattern 3 of the stacking portion 30 via the through hole 262c, the wiring 247, and the through hole 262b. Further, the second layered electrode 242 has a through hole 242a that penetrates the through hole 262c in a non-contact state, and a through hole 242b for the purpose of ensuring insulation with the forming section 268. However, the through hole 262c is disposed in the power supply connection pad 262. One of the power supply connection pads 262y and the through holes 242b are provided with φ corresponding to the ground connection pads 26 1 y of a portion of the ground connection pads 26 1 , so that fewer pass holes are provided. The number of 242a, 242b. As a result, the second layered electrode 2 42 has a large area, and the layered capacitor portion 240 also has a large electrostatic capacitance. Further, the number of the through holes 242a, 242b and the position at which the through holes 2 42a, 242b are formed should be determined after considering the static capacitance of the layered capacitor portion 240 or the like. Thus, since the layered capacitor portion 240 can have a large electrostatic capacitance, it has a sufficient decoupling effect, and the transistor mounted on the semiconductor element (1C) of the mounting portion 2 60 is less likely to be insufficient in power supply. Further, the grounding φ connection pad 261x and the ground connection pad 261y are connected via the wiring 246 on the interlayer insulating layer 245, and the power supply connection pad 262x and the power supply connection pad 262y are formed via the wiring 247 on the interlayer insulating layer 245. Although it is connected, such a wiring may be disposed on any one of the layers above the second layered electrode (the mounting portion may be), the surface of the core substrate 20, and the deposition portion 30. In addition, when the grounding connection pad 26 1 X and the grounding connection pad 261y, and the power supply connection pad 262x and the power supply connection pad 262y are connected to each other, it is not necessary to arrange the through holes 261a in all the ground connection pads. Immediately below 261, it is not necessary to arrange the through holes 262a under the positive-39-201116186 of all the power supply connection pads 262. In this way, the number of forming segments of the layer directly below the mounting portion can also be reduced. Therefore, since the number of through holes and the number of forming sections that must be disposed can be reduced, the density can be increased. The stress relaxing portion 250 is formed of the same elastic material as in the first embodiment. In addition, the grounding connection pad 261, the power supply connection pad 262, and the signal connection pad 263 which are disposed in the mounting portion 260 are arranged in a lattice shape or a cross shape in the same manner as in the first embodiment (see FIG. 1). In addition, the number is also the same as that of the first embodiment. Here, the signal connection pad 263 does not contact any of the first and second layer electrodes 241 and 242 of the layered capacitor portion 240. Further, the grounding connection pad 261 and the power supply connection pad 262 may be arranged in a lattice shape or a cross shape near the center, and the signal connection pads 263 may be arranged in a lattice shape, a cross shape or a random manner around the center. A plurality of wafer capacitor arrangement regions 270 are formed around the mounting portion 260. The wafer capacitor arrangement region 270 forms a plurality of pairs of ground connection pads 271 and power supply connection pads for connecting the ground terminal and the power supply terminal of the wafer capacitor 273. 272. Each of the grounding connection pads 271 is connected to the negative electrode of the external power supply via the first layered electrode 241 of the layered capacitor portion 240, and each of the power supply connection pads 272 is connected to the positive electrode of the external power supply via the second layered electrode 242. The grounding connection pad 26 1 and the power supply connection pad 262 of the present embodiment correspond to the first connection pad and the second connection pad of claim 9 of the patent application, respectively, and the through hole 261b and the through hole 262c are respectively equivalent to the patent application. The first rod terminal and the second rod terminal of the ninth item. Each of the grounding connection pads 271 is connected to the negative electrode of the external power supply via the first layer 201116186 electrode 241 of the layered capacitor portion 240, and each of the power supply connection pads 272 is connected to the positive electrode of the external power supply via the second layered electrode 242. The grounding connection pad 261 and the power supply connection pad 262 of the present embodiment correspond to the first connection pad and the second connection pad of the sixth item of the patent application, the through holes 261a and 2 61b, and the through holes 2 62 a and 262b, respectively. It is equivalent to the first rod terminal and the second rod terminal of the sixth item of the patent application. Next, a manufacturing procedure of the multilayer printed φ brush wiring board 210 of the present embodiment will be described with reference to Figs. 15 to 17 . In addition, in the first and third embodiments, the power supply connection pad 261 and the ground connection pad 262 directly under the semiconductor element (that is, directly below the module) are arranged in a lattice or cross shape. In the cut sectional view, the sectional views of the power supply connection pad 261 and the ground connection pad 262 are alternately arranged in the first to fifth embodiments.

首先,如第1 5圖(a )所示,準備至少在核心基板20 之單面形成堆積部30之基板600,利用真空層疊機以溫度 5 0〜1 5 0 °C、壓力〇 . 5〜1 . 5 Μ P a之層疊條件將層間絕緣層 • 610 (熱硬化性絕緣膜、AJINOMOTO公司製、ABF-45SH )貼附於堆積部30上。其次,利用真空層疊機以溫度50〜 150°C、壓力0.5〜1.5MPa之層疊條件將預先製作高介電質 薄片620 (製作步驟與實施例2之高介電質薄片520相同) 貼附於層間絕緣層6 1 0 (成爲第1 3圖之層間絕緣層220 )上 ’其後,實施1 5 0 °C之1小時乾燥(參照第1 5圖(b ))。 高介電質薄片620之銅箔622、626皆爲未形成電路之平塗 層。其後,利用掩蔽法實施高介電質薄片620之蝕刻。該 蝕刻步驟係使用氯化銅蝕刻液,然而,係蝕刻至銅箔626 -41 - 201116186 及高介電質層624後只對銅箔62 2進行少許蝕刻之狀態之短 時間處理(參照第1 5圖(c ))。第1 5圖(c )中,利用蝕 刻將銅箔626之一部份隔離成孤立之成形段626a (成爲第 1 3圖之成形段268 )。其後,將層間絕緣層(成爲第1 3圖 之層間絕緣層245,熱硬化性絕緣膜、ΑΠΝΟΜΟΤΟ公司製 、ABF-45SH) 628層疊於高介電質薄片620上(第15圖(d ))。其次,在已積層著層間絕緣層628之製作中之基板 之特定位置利用碳酸氣雷射、UV雷射、YAG雷射、以及激 生分子雷射等形成貫穿孔630 (參照第15圖(e))。形成 貫通層間絕緣層62 8、高介電質薄片620、以及層間絕緣層 610之到達堆積部30之配線圖案32表面之貫穿孔630。雷射 條件係利用Hitachi Via Mechanics,Ltd.製UV雷射,其條 件爲輸出3〜1 OkW、頻率30〜60kHz、冲程數54。 形成貫穿孔63 0後,將貫穿孔充塡用樹脂640 (製作步 驟與實施例2之貫穿孔充塡用樹脂5 3 2相同)充塡至該貫穿 孔63 0並進行乾燥(參照第16圖(a))。其次,在該製作 中之基板之特定位置利用碳酸氣雷射、UV雷射、YAG雷射 、以及激生分子雷射等形成貫穿孔651、6 5 2、65 3 (參照 第1 6圖(b ))。貫穿孔65 1係以貫通貫穿孔充塡用樹脂 640之到達堆積部30之配線圖案32表面之方式形成,貫穿 孔652則係以貫通層間絕緣層628之到達銅箔626表面之方 式形成,貫穿孔65 3係以貫通層間絕緣層628、高介電質薄 片620 (成形段626a、高介電質層624、及銅箔622 )、以 及層間絕緣層6 1 0之到達堆積部3 0之配線圖案3 2表面之方 201116186 式形成。該貫穿孔651、652、653之形成上,係依先形成 貫穿孔651再依序形成貫穿孔652、653之方式形成。該貫 穿孔之深度調整係以變更雷射種類及雷射冲程數來進行調 整。例如,貫穿孔65 1係利用C02雷射並採用辈.1.4mm之遮 罩直徑、2. Omj之能量密度、3冲程之條件,貫穿孔65 2則 係採用除了 1冲程以外與前述條件相同之條件,貫穿孔653 係利用UV雷射並採用除了 5 6冲程以外與前述條件相同之 φ 條件(輸出:3〜10W、頻率:30〜60kHz)。此外,貫穿 孔63 0並非以對應第13圖所示之全部電源用連結墊262之方 式而以只對應部份之方式(亦即,對應電源用連結墊2 62y )來形成,貫穿孔653則並非以對應第1 3圖所示之全部接 地用連結墊26 1之方式而以只對應部份之方式(亦即,對 應接地用連結墊26 ly)來形成。 其後,實施1 7 (TC之3小時乾燥硬化,使其完全硬化。 其次,使觸媒附著於基板表面並實施通常之半加成法,而 φ 分別將金屬充塡至貫穿孔651、652、65 3來形成通孔2 62c 、262b、 261b,且在該通孔262c' 262b、 261b之上面形成 成形段267y、267x、266y ’並進一步形成用以連結成形段 267x及成形段2 67y之配線247 (參照第16圖(c ))。堆積 部30之配線圖案32及銅箔626 (第2層狀電極242 )經由該 配線2々7形成連結。此外,亦同時形成此處省略圖示之第 1 4圖之成形段2 6 6 X及配線2 4 6。其次,實施應力緩和薄片 670 (成爲第13圖之應力緩和部25〇之物,製作步驟參照實 施例2之應力緩和薄片5 5 0 )之層疊(參照第1 6圖(d )) -43- 201116186 其次,在應力緩和薄片670之各成形段267y、267χ、 266y之正上方位置分別形成貫穿孔680 (參照第17圖(a ) ),並實施粗化、完全硬化、附著觸媒、化學銅、抗鍍層 、電鍍銅、抗鍍層剝離、快速蝕刻’將金屬充塡至各貫穿 孔68 0並在充塡之金屬上面形成連結墊(參照第17圖(b ) )。因此,在成形段267y上形成通孔262a及電源用連結墊 262y,在成形段267x上形成通孔262a及電源用連結墊262x ,在成形段266y上形成通孔261a及接地用連結墊261y。此 外,亦在第13圖及第14圖之成形段266x上形成此處省略圖 示之通孔261a及接地用連結墊261x。如此,可得到第13圖 之多層印刷配線板2 1 0。此外,銅箔622相當於第1層狀電 極241,銅箔626相當於第2層狀電極242,高介電質層6 24 相當於高介電質層243,利用上述構成層狀電容器部240。 實施例3之接地用連結墊26 lx利用任一層(例如安裝部260 )連結於接地用連結墊261 y時,不需要通孔26 la及成形段 2 66x。同樣的,電極用連結墊262x利用任一層(例如安裝 部260 )連結於電極用連結墊262y時,亦不需要電源用連 結墊262x之正下方之通孔262a、成形段267x、以及通孔 2 62b。如此,可減少通孔及成形段。 其後’亦可在安裝部260之各端子上形成焊塊(形成 方法參照實施例1 )。此外’如第1 3圖所示,安裝晶片電 容器273時,亦可與實施例2相同,形成連結墊271、272。 依據以上詳細說明之實施例3之多層印刷配線板1 1 〇, 201116186 可得到與上述實施例1相同之效果。此外,本實施例中, 因爲不是從堆積部30繞過層狀電容器部240而係經由通孔 262c、262b從外部電源供應源對高介電質薄片620實施電 荷充電,而可縮短外部電源供應源用以連結層狀電容器部 240之電源電極之第2層狀電極20之配線長度、及用以連 結接地電極之第1層狀電極241之配線長度’故即使將高速 驅動之半導體元件(1C)安裝於安裝部260’層狀電容器 φ 部240亦不易發生充電不足之情形。此外,本實施例中, 係以模組正下方之層狀電容器部24〇之靜電容C爲0.5 y F之 方式來決定第1層狀電極241及第2層狀電極242之相對面積 S,並依據該相對面積S來決定第1層狀電極241之通過孔 241 a之數及位置、以及第2層狀電極242之通過孔242a、 242b之數及位置。此處,相對面積S係利用C= ε Q ♦ ε r · d /S來計算。亦即,因爲高介電質層242之相對介電係數 ε^1850、其厚度d爲1.2/zm,將該値代入上式,且靜電 φ 容C以〇 . 5 // F代入,即可計算相對面積S。此外,ε 〇係真 空時之介電常數(定數)。 此外,上述製造步驟中,係在第15圖(c)之步驟後 才實施層間絕緣層6 2 8之層疊(參照第1 5圖(d )),並在 該層間絕緣層628之特定位置形成貫穿孔63 0 (參照第15圖 (e)),且對貫穿孔630充塡貫穿孔充塡用樹脂640並實 施乾燥後(參照第1 6圖(a )),再在該貫穿孔充塡用樹 脂640形成貫穿孔65 1(參照第16圖(b)),然而,亦可 採用如下所示之方法。亦即,在第1 5圖(c )之步驟後, -45- 201116186 將市販之乾膜貼附於基板表面,然後,利用掩蔽法對形成 通孔262c (參照第16圖(c))之位置之高介電質薄片620 進行蝕刻除去,形成大於通孔262c之擴大孔632 (參照第 18圖(a)),其後,將層間絕緣層628層疊至高介電質薄 片620上,並對剛才利用蝕刻除去所形成之擴大孔632充塡 層間絕緣層628,然後進行乾燥(第18圖(b ))。其次, 其後亦可實施用以形成實施例3之貫穿孔651、652、653之 步驟以後之步驟》因此,可刪除針對貫穿孔63 0進行充塡 之步驟。 [實施例4] 係在對應於全部電源用連結墊及接地用連結墊之位置 形成實施例2之貫穿孔530及貫穿孔531。結果,層狀電容 器部之靜電容成爲0.4/ZF。 [實施例5] 係在對應於全部電源用連結墊及接地用連結墊之位置 形成實施例3之貫穿孔63 0及貫穿孔65 3。結果,層狀電容 器部之靜電容成爲0.4/i F。 [實施例6] 係將實施例2之高介電質薄片之製作步驟(4)之旋塗 /乾燥/燒成之重複次數變更成20次,得到0.6/z m之高介 電質層。其餘與實施例2相同。結果,模組正下方之層狀 -46- 201116186 電容器部之靜電容成爲1.0// F。 [實施例7] 係將實施例3之高介電質薄片之製作步驟(z /乾燥/燒成之重複次數變更成20次,得到0.6/ 電質層。其餘與實施例3相同。結果,模組正下 電容器部之靜電容成爲1.0/z F。 [實施例8] 係將實施例2之高介電質薄片之製作步驟(< /乾燥/燒成之重複次數變更成1次,得到0.03 / 電質層。其餘與實施例2相同》結果,模組正下 電容器部之靜電容成爲20/z F。 [實施例9] 係將實施例3之高介電質薄片之製作步驟 /乾燥/燒成之重複次數變更成1次,得到0.03/ 電質層。其餘與實施例3相同。結果,模組正下 電容器部之靜電容成爲20/z F。 [實施例1〇] 係將實施例2之高介電質薄片之製作步驟(z /乾燥/燒成之重複次數變更成4次’得到〇·12Α 電質層。其餘與實施例2相同。結果,模組正下 )之旋塗 m之高介 方之層狀 )之旋塗 m之高介 方之層狀 )之旋塗 m之高介 方之層狀 )之旋塗 m之高介 方之層狀 -47 - 201116186 電容器部之靜電容成爲5/zF。 [實施例1 1] 係將實施例3之高介電質薄片之製作步驟(4)之旋塗 /乾燥/燒成之重複次數變更成4次,得到之高介 電質層。其餘與實施例3相同。結果,模組正下方之層狀 電容器部之靜電容成爲5/zF。 [實施例I2] 係將實施例2之高介電質薄片之製作步驟(4)之旋塗 /乾燥/燒成之重複次數變更成2次,得到0.06// m之高介 電質層。其餘與實施例2相同。結果,模組正下方之靜電 容成爲10// F。 [實施例I3] 係將實施例3之高介電質薄片之製作步驟(4)之旋塗 /乾燥/燒成之重複次數變更成2次,得到0.06# m之高介 電質層。其餘與實施例3相同。結果,模組正下方之靜電 容成爲10/Z F。 [實施例M] 係在對應於全部電源用連結墊及接地用連結墊之位置 形成實施例8之貫穿孔530及貫穿孔531。結果,靜電容爲 I 6 μ Έ。 -48- 201116186 [實施例15] 係在對應於全部電源用連結墊及接地用連結墊之位置 形成實施例9之貫穿孔630及貫穿孔653。結果,靜電容爲 1 6 # F。 [實施例16] 係將實施例2之高介電質薄片之製作步驟(4)之旋塗 /乾燥/燒成之重複次數變更成330次,得到10/zm之高介 電質層。其餘與實施例2相同。結果,模組正下方之靜電 容成爲0.06 # F。 [實施例17] 係將實施例3之高介電質薄片之製作步驟(4)之旋塗 /乾燥/燒成之重複次數變更成3 30次’得到1〇 β m之高介 φ 電質層。其餘與實施例3相同。結果’模組正下方之靜電 容成爲0.06 " F。 [實施例18] 係將實施例2之高介電質薄片之製作步驟(4)之旋塗 /乾燥/燒成之重複次數變更成10次’得到〇.3#m之高介 電質層。其餘與實施例2相同。結果’模組正下方之靜電 容成爲2.0 v F。 -49- 201116186 [實施例19] 係將實施例3之高介電質薄片之製作步驟(4)之旋塗 /乾燥/燒成之重複次數變更成10次,得到0.3从m之高介 電質層。其餘與實施例3相同。結果,模組正下方之靜電 容成爲2.0 /Z F。 [實施例20] 係將實施例2之高介電質薄片之製作步驟(4)之旋塗 /乾燥/燒成之重複次數變更成25次,得到0.75 e m之高 介電質層。其餘與實施例2相同。結果,模組正下方之靜 電容成爲0.8 β F。 [實施例21] 係將實施例3之高介電質薄片之製作步驟(4)之旋塗 /乾燥/燒成之重複次數變更成25次’得到〇_75 // m之高 介電質層。其餘與實施例3相同。結果’模組正下方之靜 電容成爲0.8# F。 [實施例22] 係預先對實施例3之高介電質薄片實施触刻處理’除 去部份銅箔626及高介電質層624 »其後’利用層間絕緣層 610將該高介電質薄片貼附至形成堆積部30之基板600上。 亦即’置換實施例3之高介電質薄片貼附步驟及高介電質 薄片之蝕刻步驟。其後之步驟與實施例3相同。 -50- 201116186 [實施例2 3 ] 將晶片電容器安裝於實施例4之多層印刷配線板。 [實施例24] 將晶片電容器安裝於實施例5之多層印刷配線板。 [實施例25] 以層間絕緣層5 1 0 (參照第9圖(a ))取代實施例2之 應力緩和部1 50。其餘與實施例2相同。 [實施例26] 以層間絕緣層6 1 0 (參照第1 5圖(a ))取代實施例3 之應力緩和部2 5 0。其餘與實施例3相同。 φ [實施例27〜49] 實施例27〜49係以層間絕緣層取代實施例2〜24之各 應力緩和部之方式來製作多層印刷配線板。 [比較例] 比較例之高介電質薄片係以實施例2記載之高介電質 薄片之其他形態製作步驟來進行製作。但是’不進行燒成 ,而在乾燥後之未燒成層上形成電極。其餘與實施例2相 同。結果,模組正下方之靜電容爲0.001 // F以下。 -51 - 201116186 評估試驗1 在實施例2〜49及比較例之多層印刷配線板安裝驅動 頻率3.6GHz、FSB 1 066MHZ之1C晶片,同時重複實施100次 之開關切換,利用 Pulse Pattern Generator / Error Detector ( ADVANTEST公司製、商品名稱:D3 1 8 6 / 32 8 6 ),確認有無錯誤動作。 [評估試驗2、HAST試驗] 對實施例2〜49之多層印刷配線板之第1層狀電極及第 2層狀電極間施加3 . 3 V之電壓,同時置於8 5 °C X 8 5 %之環境 試驗機內50小時。其間,每2小時實施放電。其後,安裝 驅動頻率3.6〇1^、?3810661^1^之1(:晶片,同時重複實施 100次之開關切換,利用前述Pulse Pattern Generator/ Error Detector,確認有無錯誤動作。 [評估試驗3、HAST試驗] 以和評估試驗2相同之方式,對完成評估試驗2後之多 層印刷配線板之第1層狀電極及第2層狀電極間施加3.3 V之 電壓,同時置於8 5 °C X8 5 %之環境試驗機內5 0小時。其間 ,每2小時實施放電。其後,搭載驅動頻率3.6GHz、 FSB 1 066MHZ之1C晶片,同時重複實施100次之開關切換, 利用前述 Pulse Pattern Generator / Error Detector,確認 有無錯誤動作。 -52- 201116186 [評估試驗4、熱循環試驗] 對實施例2〜2 6之多層印刷配線板實施以下之熱循環 試驗。 熱循環試驗條件:100次或500次之-55°CX30分鐘、 1251又30分鐘後,安裝驅動頻率3.6〇112、?3810661^1^之 1C晶片,同時重複實施1〇〇次之開關切換’利用前述Pulse Pattern Generator / Error Detector,確認有無錯誤動作。 [評估試驗5] 安裝驅動頻率5.7〇112、[381066]^112之1(:晶片而非評 估試驗1之驅動頻率3.6GHz、FSB 1 066MHZ之1C晶片,實施 與評估試驗1相同之試驗。結果,模組正下方之靜電容爲 1 .0 V F以上之多層印刷配線板不會發生錯誤動作。 φ [評估結果] 表1係評估試驗1〜4之結果。未觀察到錯誤動作時爲 〇、觀察到錯誤動作時爲X。此外,表1未刊載實施例27〜 49之模組正下方之靜電容及評估試驗1〜3之評估結果,然 而,結果分別與實施例2〜24相同。 -53- 201116186 表1 實施例 對應端 子之 TH數 高介電 質層膜 厚(//m) 模組正 下方之 電容(#F) 崁1 C/C安裝 之有無 評估試驗結果 1 2 3 4*2 5*3 實施例2 部份 1.2 0.5 IIM 〇 〇 X 〇 X 實施例3 部份 1.2 0.5 /far ΤΐιΓ j\\\ 〇 〇 X 〇 X 實施例4 全部 1.2 0.4 ifrrt im: yns 〇 X X 〇 X 實施例5 全部 1.2 0.4 /frTf. ΤΠΤ y»\N 〇 X X 〇 X 實施例6 部份 0.6 1.0 /fnr. ΤΠΓ 〇 〇 〇 〇 〇 實施例7 部份 0.6 1.0 4ττγ. illl: 〇 〇 〇 〇 〇 實施例8 部份 0.03 20 fnT- mt: y\\\ 〇 — — 〇 X 實施例9 部份 0.03 20 /fnt- 1111: J\\\ 〇 — — 〇 X 實施例10 部份 0.12 5 -fm: Mi!: V、 〇 〇 〇 〇 〇 實施例11 部份 0.12 5 /fnr ΤΤΤΠ 〇 〇 〇 〇 〇 實施例12 部份 0.06 10 ΤΤΓΓ />\N 〇 〇 X 〇 X 實施例13 部份 0.06 10 Ι1ΙΓ y\\\ 〇 〇 X 〇 X 實施例14 全部 0.03 16 4rrr. IiH: y\\\ 〇 X X 〇 X 實施例15 全部 0.03 16 ifrrr lilt! 〇 X X 〇 X 實施例16 部份 10 0.06 irrr ΠιΤΤ 〇 X X 〇 X 實施例Π 部份 10 0.06 4rrr TtrT 〇 X X 〇 X 實施例18 部份 0.3 2.0 AnL ιιΙΓ j\\\ 〇 〇 〇 〇 〇 實施例19 部份 0.3 2.0 4πτ. tilt 〇 〇 〇 〇 〇 實施例20 部份 0.75 0.8 /fnr Tttr 〇 〇 〇 〇 〇 實施例21 部份 0.75 0.8 inn J\\\ 〇 〇 〇 〇 〇 實施例22 部份 1.2 0.3 >fnt- ΤΤΤΠ 〇 — — 〇 X 實施例23 全部 1.2 0.4 有 〇 〇 〇 〇 〇 實施例24 全部 1.2 0.4 有 〇 〇 〇 〇 〇 實施例25 部份 1.2 0.5 4γγγ wr /»\\ 〇 — 一 〇 X 實施例26 部份 1.2 0.5 /frrr ΤΤΓΓ 〇 — — 〇 X 比較例1 部份 5 <0.01 4γττ τΓΓΓ jw\ X — — X — ※l c/c=晶片電容器 ※之100循環後 ※3 500循環後First, as shown in Fig. 15 (a), a substrate 600 having a deposition portion 30 formed on at least one side of the core substrate 20 is prepared, and a vacuum laminator is used at a temperature of 50 to 150 ° C and a pressure of 〇. 5~ 1. 5 Μ P a lamination condition The interlayer insulating layer • 610 (thermosetting insulating film, AJINOMOTO Co., Ltd., ABF-45SH) was attached to the deposition unit 30. Next, a high dielectric sheet 620 is prepared in advance by a vacuum laminator at a temperature of 50 to 150 ° C and a pressure of 0.5 to 1.5 MPa (the production steps are the same as those of the high dielectric sheet 520 of the second embodiment). The interlayer insulating layer 610 (becomes the interlayer insulating layer 220 of Fig. 3) is then dried at 150 ° C for 1 hour (see Fig. 15 (b)). The copper foils 622, 626 of the high dielectric foil 620 are all flat layers that do not form an electrical circuit. Thereafter, etching of the high dielectric sheet 620 is performed by a masking method. In the etching step, a copper chloride etching solution is used. However, after etching to the copper foils 626-41 to 201116186 and the high dielectric layer 624, only a small amount of etching is performed on the copper foil 62 2 (refer to the first step). 5 Figure (c)). In Fig. 15(c), a portion of the copper foil 626 is etched into an isolated shaped section 626a (which becomes the forming section 268 of Fig. 3). Then, an interlayer insulating layer (which is an interlayer insulating layer 245 of Fig. 3, a thermosetting insulating film, ABF-45SH, manufactured by Azbil Corporation) 628 is laminated on the high dielectric sheet 620 (Fig. 15(d) ). Next, a through hole 630 is formed at a specific position of the substrate in which the interlayer insulating layer 628 is laminated, using a carbon dioxide laser, a UV laser, a YAG laser, and an excited molecular laser (see FIG. 15 (e). )). A through hole 630 penetrating the interlayer insulating layer 62 8 , the high dielectric sheet 620 , and the interlayer insulating layer 610 on the surface of the wiring pattern 32 of the stacking portion 30 is formed. The laser conditions were obtained by using a UV laser manufactured by Hitachi Via Mechanics, Ltd., which was an output of 3 to 1 OkW, a frequency of 30 to 60 kHz, and a stroke number of 54. After the through hole 63 0 is formed, the through hole filling resin 640 (the manufacturing step is the same as the through hole filling resin 5 3 2 of the second embodiment) is filled in the through hole 63 0 and dried (refer to Fig. 16). (a)). Next, a through hole 651, 6 5 2, 65 3 is formed at a specific position of the substrate in the fabrication by using a carbon dioxide laser, a UV laser, a YAG laser, and an excited molecular laser (see FIG. b)). The through hole 65 1 is formed to penetrate the surface of the wiring pattern 32 of the through-hole filling resin 640 to reach the deposition portion 30, and the through hole 652 is formed so as to penetrate the surface of the copper foil 626 through the interlayer insulating layer 628. The hole 65 3 penetrates the interlayer insulating layer 628, the high dielectric sheet 620 (the forming section 626a, the high dielectric layer 624, and the copper foil 622), and the wiring of the interlayer insulating layer 610 to the stacking portion 30. The pattern 3 2 surface is formed in the form of 201116186. The through holes 651, 652, and 653 are formed by forming the through holes 651 and forming the through holes 652 and 653 in order. The depth adjustment of the perforation is adjusted by changing the type of laser and the number of laser strokes. For example, the through hole 65 1 is formed by using a CO 2 laser and adopting a mask diameter of 1.4 mm, an energy density of 2. Omj, and a 3-stroke condition, and the through hole 65 2 is the same as the foregoing except for one stroke. The through hole 653 is a UV laser and uses the same φ condition (output: 3 to 10 W, frequency: 30 to 60 kHz) other than the above-described conditions except for the 56 stroke. Further, the through hole 63 0 is not formed so as to correspond to only all of the power supply connection pads 262 shown in FIG. 13 (that is, corresponding to the power supply connection pad 2 62y ), and the through hole 653 is formed. It is not formed so as to correspond to only the corresponding portion (that is, the grounding connection pad 26 ly) so as to correspond to all of the grounding connection pads 26 1 shown in FIG. Thereafter, 1 7 (TC was dried and hardened for 3 hours to completely harden it. Next, the catalyst was attached to the surface of the substrate and subjected to a usual semi-additive method, and φ was respectively filled with metal to the through holes 651, 652. The through holes 2 62c , 262b , 261b are formed at 65 3 , and the forming segments 267 y , 267 x , 266 y ' are formed on the through holes 262 c 262 b , 261 b and further formed to join the forming segments 267 x and the forming segments 2 67 y Wiring 247 (refer to Fig. 16 (c)). The wiring pattern 32 of the deposition portion 30 and the copper foil 626 (the second layered electrode 242) are connected via the wiring 2々7. The forming section 2 6 6 X and the wiring 2 4 of Fig. 14 are second. Next, the stress relieving sheet 670 is formed (the object of the stress relieving portion 25 of Fig. 13 is formed, and the manufacturing step is referred to the stress relieving sheet 5 of the second embodiment. Lamination of the layer 5 (see Fig. 16 (d)) - 43 - 201116186 Next, a through hole 680 is formed at a position directly above each of the forming sections 267y, 267, and 266y of the stress relieving sheet 670 (refer to Fig. 17 (refer to Fig. 17 ( a)), and carry out roughening, complete hardening, adhesion catalyst, chemical copper, anti- The layer, the electroplated copper, the plating resist peeling, the rapid etching 'fills the metal to each of the through holes 68 0 and forms a joint pad on the filled metal (refer to Fig. 17 (b)). Therefore, it is formed on the forming section 267y. The through hole 262a and the power supply connection pad 262y form a through hole 262a and a power supply connection pad 262x in the molding section 267x, and a through hole 261a and a ground connection pad 261y are formed in the molding section 266y. The through hole 261a and the grounding connection pad 261x (not shown) are formed in the forming section 266x of Fig. 14. Thus, the multilayer printed wiring board 2110 of Fig. 13 can be obtained. Further, the copper foil 622 is equivalent to the first one. The layered electrode 241, the copper foil 626 corresponds to the second layered electrode 242, and the high dielectric layer 624 corresponds to the high dielectric layer 243, and the layered capacitor portion 240 is configured as described above. When the l lx is connected to the grounding connection pad 261 y by any layer (for example, the mounting portion 260 ), the through hole 26 la and the forming portion 2 66x are not required. Similarly, the electrode connecting pad 262x uses any layer (for example, the mounting portion 260). When it is connected to the electrode connection pad 262y, electricity is not required. The through hole 262a, the forming section 267x, and the through hole 2 62b directly under the bonding pad 262x are used. Thus, the through hole and the forming section can be reduced. Thereafter, a solder bump can be formed on each terminal of the mounting portion 260 (formed) The method is as described in the first embodiment. Further, as shown in Fig. 3, when the wafer capacitor 273 is mounted, the connection pads 271 and 272 may be formed in the same manner as in the second embodiment. According to the multilayer printed wiring board 1 1 〇, 201116186 of the embodiment 3 described in detail above, the same effects as those of the above-described first embodiment can be obtained. Further, in the present embodiment, since the layered capacitor portion 240 is not bypassed from the stacking portion 30, the high dielectric sheet 620 is electrically charged from the external power source via the through holes 262c, 262b, and the external power supply can be shortened. The source is used to connect the wiring length of the second layer electrode 20 of the power supply electrode of the layered capacitor portion 240 and the wiring length of the first layer electrode 241 for connecting the ground electrode. Therefore, even if the semiconductor element is driven at a high speed (1C) The mounting of the layered capacitor φ portion 240 in the mounting portion 260' is also less likely to cause insufficient charging. Further, in the present embodiment, the relative area S of the first layered electrode 241 and the second layered electrode 242 is determined such that the electrostatic capacitance C of the layered capacitor portion 24 directly below the module is 0.5 y F. Based on the relative area S, the number and position of the through holes 241a of the first layered electrode 241 and the number and position of the through holes 242a and 242b of the second layered electrode 242 are determined. Here, the relative area S is calculated using C = ε Q ♦ ε r · d / S. That is, since the relative dielectric constant ε^1850 of the high dielectric layer 242 and the thickness d thereof are 1.2/zm, the enthalpy is substituted into the above formula, and the electrostatic φ capacitance C is substituted by 〇. 5 // F. Calculate the relative area S. In addition, ε 〇 is the dielectric constant (fixed number) of the space. Further, in the above manufacturing step, the lamination of the interlayer insulating layer 6 2 8 is performed after the step of the step (c) of FIG. 15 (refer to FIG. 15 (d )), and is formed at a specific position of the interlayer insulating layer 628. The through hole 63 0 (see Fig. 15 (e)), and the through hole 630 is filled with the through hole filling resin 640 and dried (see Fig. 16 (a)), and then filled in the through hole. The through hole 65 1 is formed by the resin 640 (refer to Fig. 16 (b)). However, the method shown below can also be employed. That is, after the step of Fig. 15(c), -45-201116186 attaches a dry film of a commercially available product to the surface of the substrate, and then forms a through hole 262c by a masking method (refer to Fig. 16(c)). The position of the high dielectric sheet 620 is etched away to form an enlarged hole 632 larger than the through hole 262c (refer to FIG. 18(a)), and thereafter, the interlayer insulating layer 628 is laminated on the high dielectric sheet 620, and The enlarged insulating hole 632 which has just been formed by etching is filled with the interlayer insulating layer 628, and then dried (Fig. 18(b)). Next, the step of forming the through holes 651, 652, and 653 of the third embodiment may be carried out thereafter. Therefore, the step of filling the through holes 63 0 may be deleted. [Embodiment 4] The through hole 530 and the through hole 531 of the second embodiment are formed at positions corresponding to all of the power supply connection pads and the ground connection pads. As a result, the electrostatic capacitance of the layered capacitor portion becomes 0.4/ZF. [Example 5] The through hole 63 0 and the through hole 65 3 of the third embodiment were formed at positions corresponding to all of the power supply connection pads and the ground connection pads. As a result, the electrostatic capacitance of the layered capacitor portion was 0.4/i F. [Example 6] The number of repetitions of spin coating/drying/firing in the production step (4) of the high dielectric sheet of Example 2 was changed to 20 times to obtain a high dielectric layer of 0.6/z m. The rest is the same as in Embodiment 2. As a result, the static capacitance of the capacitor portion of the layered -46-201116186 directly under the module becomes 1.0//F. [Example 7] The procedure for producing the high dielectric sheet of Example 3 (z/the number of repetitions of drying/firing was changed to 20 times to obtain 0.6/electrolyte layer. The rest was the same as in Example 3. As a result, The electrostatic capacitance of the module lower capacitor portion was 1.0/z F. [Example 8] The procedure for producing the high dielectric sheet of Example 2 (</drying/firing repetition number was changed to 1 time) The result is 0.03 / electric layer. The rest is the same as in the second embodiment. As a result, the electrostatic capacitance of the capacitor portion of the module is 20/z F. [Example 9] The manufacturing procedure of the high dielectric sheet of Example 3 was carried out. The number of repetitions of the drying/baking was changed to one time to obtain a 0.03/electrolyte layer, and the rest was the same as in the third embodiment. As a result, the electrostatic capacitance of the positive-capacitor portion of the module was 20/z F. [Example 1] The procedure for producing the high dielectric sheet of Example 2 (z/the number of repetitions of drying/firing is changed to 4 times) gives the 〇12Α electric layer. The rest is the same as in the embodiment 2. As a result, the module is directly under ) The spin coating of the high-medium layer of the spin coating, the spin coating of the high-medium layer of the spin coating, the spin coating of the high-medium layer of the spin coating The layer of high dielectric layer -47 - 201116186 The capacitance of the capacitor is 5/zF. [Example 1 1] The high dielectric layer was obtained by changing the number of repetitions of spin coating/drying/firing in the production step (4) of the high dielectric sheet of Example 3 to four times. The rest is the same as in the third embodiment. As a result, the electrostatic capacitance of the layered capacitor portion directly under the module becomes 5/zF. [Example I2] The number of repetitions of spin coating/drying/firing in the production step (4) of the high dielectric sheet of Example 2 was changed to two times to obtain a high dielectric layer of 0.06 / m. The rest is the same as in Embodiment 2. As a result, the electrostatic capacitance directly under the module becomes 10//F. [Example I3] The number of repetitions of spin coating/drying/firing in the production step (4) of the high dielectric sheet of Example 3 was changed to two times to obtain a high dielectric layer of 0.06 #m. The rest is the same as in the third embodiment. As a result, the electrostatic capacitance directly under the module becomes 10/Z F . [Example M] The through hole 530 and the through hole 531 of the eighth embodiment were formed at positions corresponding to all of the power supply connection pads and the ground connection pads. As a result, the electrostatic capacitance is I 6 μ Έ. -48-201116186 [Embodiment 15] The through hole 630 and the through hole 653 of the ninth embodiment are formed at positions corresponding to all of the power supply connection pads and the ground connection pads. As a result, the electrostatic capacitance is 16 6 F. [Example 16] The number of repetitions of spin coating/drying/firing in the production step (4) of the high dielectric sheet of Example 2 was changed to 330 times to obtain a high dielectric layer of 10/zm. The rest is the same as in Embodiment 2. As a result, the electrostatic capacitance directly under the module becomes 0.06 #F. [Example 17] The number of repetitions of spin coating/drying/firing in the production step (4) of the high dielectric sheet of Example 3 was changed to 3 30 times to obtain a high dielectric φ of 1 〇β m Floor. The rest is the same as in the third embodiment. As a result, the electrostatic capacitance immediately below the module became 0.06 " F. [Example 18] The number of repetitions of spin coating/drying/firing in the production step (4) of the high dielectric sheet of Example 2 was changed to 10 times to obtain a high dielectric layer of 〇.3#m. . The rest is the same as in Embodiment 2. As a result, the electrostatic capacitance immediately below the module became 2.0 v F. -49-201116186 [Example 19] The number of repetitions of spin coating/drying/firing in the production step (4) of the high dielectric sheet of Example 3 was changed to 10 times to obtain a high dielectric of 0.3 m. Quality layer. The rest is the same as in the third embodiment. As a result, the electrostatic capacitance directly under the module becomes 2.0 /Z F. [Example 20] The number of repetitions of spin coating/drying/firing in the production step (4) of the high dielectric sheet of Example 2 was changed to 25 times to obtain a high dielectric layer of 0.75 em. The rest is the same as in Embodiment 2. As a result, the static capacitance directly below the module becomes 0.8 β F. [Example 21] The number of repetitions of spin coating/drying/firing in the production step (4) of the high dielectric sheet of Example 3 was changed to 25 times to obtain a high dielectric of 〇_75 //m. Floor. The rest is the same as in the third embodiment. As a result, the static capacitance immediately below the module becomes 0.8#F. [Example 22] A high-dielectric sheet of Example 3 was subjected to a etch processing in advance to remove a portion of the copper foil 626 and the high dielectric layer 624. Thereafter, the high dielectric was utilised by the interlayer insulating layer 610. The sheet is attached to the substrate 600 forming the stacking portion 30. That is, the high dielectric sheet attaching step of the third embodiment and the etching step of the high dielectric sheet are replaced. The subsequent steps are the same as in the third embodiment. -50-201116186 [Example 2 3] A wafer capacitor was mounted on the multilayer printed wiring board of Example 4. [Example 24] A wafer capacitor was mounted on the multilayer printed wiring board of Example 5. [Example 25] The stress relaxing portion 1 50 of Example 2 was replaced with an interlayer insulating layer 5 10 (refer to Fig. 9 (a)). The rest is the same as in Embodiment 2. [Example 26] The stress relaxation portion 250 of Example 3 was replaced with an interlayer insulating layer 610 (refer to Fig. 15 (a)). The rest is the same as in the third embodiment. φ [Examples 27 to 49] In Examples 27 to 49, a multilayer printed wiring board was produced by replacing the stress relaxation portions of Examples 2 to 24 with an interlayer insulating layer. [Comparative Example] The high dielectric sheet of the comparative example was produced by the other production steps of the high dielectric sheet described in Example 2. However, the electrode was formed on the unfired layer after drying without firing. The rest is the same as in Embodiment 2. As a result, the static capacitance directly below the module is 0.001 // F or less. -51 - 201116186 Evaluation Test 1 A 1C wafer having a drive frequency of 3.6 GHz and FSB 1 066 MHz was mounted on the multilayer printed wiring boards of Examples 2 to 49 and Comparative Example, and switching was repeated 100 times, using Pulse Pattern Generator / Error Detector. (Manufactured by ADVANTEST, trade name: D3 1 8 6 / 32 8 6 ), confirm whether there is any wrong operation. [Evaluation Test 2, HAST Test] A voltage of 3.3 V was applied between the first layered electrode and the second layered electrode of the multilayer printed wiring boards of Examples 2 to 49, and placed at 85 ° C X 8 5 %. The environment test machine was 50 hours. In the meantime, discharge was performed every 2 hours. After that, install the drive frequency 3.6〇1^,? 3810661^1^1 (: wafer, switching is performed 100 times at the same time, and the above-mentioned Pulse Pattern Generator/Error Detector is used to confirm the presence or absence of an erroneous operation. [Evaluation Test 3, HAST Test] In the same manner as Evaluation Test 2, A voltage of 3.3 V was applied between the first layered electrode and the second layered electrode of the multilayer printed wiring board after the evaluation test 2 was completed, and placed in an environmental tester at 85 ° C X 8 5 % for 50 hours. The discharge was performed every 2 hours. Then, a 1C wafer having a drive frequency of 3.6 GHz and FSB 1 066 MHz was mounted, and switching was repeated 100 times, and the pulse pattern generator / Error Detector was used to confirm the presence or absence of an erroneous operation. -52- 201116186 [Evaluation Test 4, Thermal Cycle Test] The following thermal cycle tests were carried out on the multilayer printed wiring boards of Examples 2 to 26. Thermal cycle test conditions: 100 times or 500 times - 55 ° C X 30 minutes, 1251 and 30 minutes later Install a 1C chip with a drive frequency of 3.6〇112 and ?3810661^1^ and repeat the switch of 1〇〇 times. Use the Pulse Pattern Generator / Error Detector to confirm the presence or absence. [Evaluation test 5] Install the drive frequency of 5.7〇112, [381066]^1121 (: wafer instead of the 1C wafer of the test frequency of 3.6 GHz, FSB 1 066 MHz, and the same test as the evaluation test 1 As a result, the multilayer printed wiring board having a static capacitance of 1.0 VF or more directly under the module does not malfunction. φ [Evaluation result] Table 1 is the result of evaluating the tests 1 to 4. When no malfunction is observed, 〇, when the erroneous action is observed, it is X. Further, Table 1 does not disclose the electrostatic capacitance immediately below the modules of Examples 27 to 49 and the evaluation results of the evaluation tests 1 to 3, however, the results are the same as those of Examples 2 to 24, respectively. -53- 201116186 Table 1 TH number of the corresponding terminal TH film high dielectric layer film thickness (//m) Capacitor directly below the module (#F) 崁1 C/C installation presence evaluation test results 1 2 3 4*2 5*3 Example 2 Part 1.2 0.5 IIM 〇〇X 〇X Example 3 Part 1.2 0.5 /far ΤΐιΓ j\\\ 〇〇X 〇X Example 4 All 1.2 0.4 ifrrt im: yns 〇XX 〇X Example 5 All 1.2 0.4 /frTf. ΤΠΤ y»\N 〇XX 〇X Example 6 0.6 1.0 /fnr. ΤΠΓ 〇〇〇〇〇 Example 7 Part 0.6 1.0 4ττγ. illl: 〇〇〇〇〇 Example 8 Part 0.03 20 fnT- mt: y\\\ 〇— 〇X Example 9 Part 0.03 20 /fnt- 1111: J\\\ 〇— 〇X Example 10 Part 0.12 5 -fm: Mi!: V, 〇〇〇〇〇Example 11 Part 0.12 5 /fnr ΤΤΤΠ 〇〇 〇〇〇Example 12 Part 0.06 10 ΤΤΓΓ />\N 〇〇X 〇X Example 13 Part 0.06 10 Ι1ΙΓ y\\\ 〇〇X 〇X Example 14 All 0.03 16 4rrr. IiH: y\ \\ 〇XX 〇X Example 15 All 0.03 16 ifrrr lilt! 〇XX 〇X Example 16 Part 10 0.06 irrr ΠιΤΤ 〇XX 〇X Example 部份 Part 10 0.06 4rrr TtrT 〇XX 〇X Example 18 Part 0.3 2.0 AnL ιιΙΓ j\\\ 〇〇〇〇〇 Example 19 Part 0.3 2.0 4πτ. tilt 〇〇〇〇〇 Example 20 Part 0.75 0.8 /fnr Tttr 〇〇〇〇〇 Example 21 Part 0.75 0.8 Inn J\\\ 〇〇〇〇〇Example 22 Part 1.2 0.3 >fnt- ΤΤΤΠ 〇 — —〇X Example 23 All 1.2 0.4 〇〇〇〇〇 Example 24 All 1.2 0.4 〇〇〇〇〇 Example 25 Part 1.2 0.5 4γγγ wr /»\\ 〇 - 一〇X Example 26 Part 1.2 0.5 / Frrr ΤΤΓΓ 〇 - 〇X Comparative Example 1 Part 5 <0.01 4γττ τΓΓΓ jw\ X — — X — ※lc/c=Wafer Capacitor ※100 cycles after ※3 500 cycles

-54- 201116186 由評估試驗1之結果可知,在堆積部以外,另行以高 介電質材料之燒成來形成陶瓷並當做高介電質層使用,可 具有夠高之介電常數,結果,可抑制電位之瞬間降低。 此外,由評估試驗4之結果可知,比較例無法對應1 00 循環後之1C晶片之電位瞬間降低。其原因雖然不明,然而 ,依據推斷,可能係因爲高介電質粒子間之接合較弱,故 會從該處產生龜裂,而使其喪失電容器之機能。 Φ 此外,對在貼附於堆積部前先對高介電質薄片形成電 路之實施例22實施熱循環試驗,無法對應1C晶片之電位瞬 間降低。其原因雖然不明,然而,依據推斷,可能係層疊 時之壓力集中部因爲熱循環試驗而發生龜裂。 此外,亦對沒有應力緩和部之實施例25、2 6實施熱循 環試驗,無法對應1C晶片之電位瞬間降低。其原因雖然不 明,然而,依據推斷,可能係因爲沒有應力緩和部,1C晶 片及多層印刷配線板間之熱膨脹係數差所導致之應力,會 φ 導致高介電質層之龜裂或成爲龜裂之起點。因爲熱循環試 驗而出現龜裂之起點,則在同時開關切換試驗時,因爲高 介電質層會重複充電及放電,故該時之粒子位移可能導致 龜裂。 此外,模組正下方之靜電容爲0.4 // F以下之實施形態 4、5時,實施評估試驗2後,無法對應1C晶片之電位瞬間 降低。其原因雖然不明,然而,依據推斷,可能係hast 試驗導致高介電質層之劣化,其相對介電係數降低而無法 獲得充分解耦合效果。此外,模組正下方之靜電容爲0.5 -55- 201116186 // F以下時,實施評估試驗2後,無法對應IC晶片之電位瞬 間降低’相對於此,具有與實施例4、5相同之模組正下方 之靜電容之實施例23、24則不會發生問題。其原因雖然不 明’然而,依據推斷,可能係因爲利用晶片電容器實施電 源供應而可對應1C晶片之電位瞬間降低。此外,對靜電容 較大之實施形態1 4、1 5實施評估試驗2後,無法對應1C晶 片之電位瞬間降低。其原因雖然不明,然而,依據推斷, 可能係因爲靜電容較大而更容易受到HAST試驗之影響, 故高介電質層出現絕緣劣化或絕緣破壞。 靜電容較大之實施例12〜15,評估試驗4s5 3之結果爲X 。推斷係因爲介電質在重複充電及放電時會產生結晶位移 ,熱循環時所蓄積之應力會加至該位移所導致之應力上, 故高介電質層之相對介電係數會劣化而成爲X。此外,靜 電容相對較小之實施例2〜5、1 6、1 7之評估試驗4 58 3結果 也是X。推斷係熱循環試驗使介電質產生伸縮,故高介電 質層之相對介電係數劣化、模組正下方之靜電容減少而成 爲X。 由表1之結果可知,模組正下方之靜電容若爲0.8〜5 # F,在環境試驗後亦可對應1C之電晶體之瞬間電壓降低 ,此外,HAST試驗及熱循環試驗後亦不會發生問題,故 具有極佳之絕緣信賴度及連結信賴度。 此外,全部實施例皆以第1層狀電極做爲接地、以第2 層狀電極做爲電源,然而,亦可相反。 本發明之多層印刷配線板可用以搭載1C晶片等之半導 -56- 201116186 體元件’例如,可應用於電氣相關產業及通信相關產業等 【圖式簡單說明】 第1圖係實施例1之多層印刷配線板10之平面圖。 第2圖係多層印刷配線板丨〇之縱剖面圖(只圖示中心 線之左側)。 第3圖係層狀電容器部40之模式斜視圖。 第4圖係多層印刷配線板丨〇之製造步驟之說明圖。 第5圖係多層印刷配線板10之製造步驟之說明圖。 第6圖係多層印刷配線板1 〇之製造步驟之說明圖。 第7圖係多層印刷配線板1 0之製造步驟之說明圖。 第8圖係實施例2之多層印刷配線板1 1 〇之縱剖面圖。 第9圖係多層印刷配線板1 1 〇之製造步驟之說明圖。 第1 〇圖係多層印刷配線板1 1 0之製造步驟之說明圖。 第11圖係多層印刷配線板1 1 0之製造步驟之說明圖。 第12圖係具有角部之高介電質薄片520之說明圖。 第13圖係實施例3之多層印刷配線板210之縱剖面圖。 第14圖係層狀電容器部240之模式斜視圖。 第1 5圖係多層印刷配線板2 1 0之製造步驟之說明圖。 第1 6圖係多層印刷配線板2 1 0之製造步驟之說明圖。 第17圖係多層印刷配線板210之製造步驟之說明圖。 第1 8圖係其他多層印刷配線板2 1 0之製造步驟之說明 -57- 201116186 【主要元件符號說明】 1 0 :多層印刷配線板 2 0 :核心基板 2 1 :核心基板本體 2 2 :配線圖案 24 :貫穿孔導體 30 :堆積部 3 2 :配線圖案 3 4 :通孔 3 6 :樹脂絕緣層 40 :層狀電容器部 41 :第1層狀電極 4 1 a :通過孔 42 :第2層狀電極 4 2 a :通過孔 43 :高介電質層 6 0 :安裝部 6 1 :接地用連結墊 6 1 a :通孔 6 2 a :通孔 6 2 b :通孔 62 :電源用連結墊 63 :訊號用連結墊 -58- 201116186 70 :晶片電容器配置區域 71 :接地用連結墊 72 :電源用連結墊 7 3 :晶片電容器 1 1 0 :多層印刷配線板 1 2 0 :層間絕緣層 140 :層狀電容器部 141 :第1層狀電極 1 4 1 a :通過孔 1 4 2 :第2層狀電極 1 4 2 a :通過孔 143 :高介電質層 1 5 0 :應力緩和部 1 6 0 :安裝部 1 6 1 :接地用連結墊 1 6 1 a :通孔 1 6 2 a :通孔 1 6 2 b :通孔 162 :電源用連結墊 163 :訊號用連結墊 170 :晶片電容器配置區域 1 7 1 :接地用連結墊 172 :電源用連結墊 173 :晶片電容器 -59 201116186 2 1 0 :多層印刷配線板 2 2 0 :層間絕緣層 240 :層狀電容器部 241 :第1層狀電極 2 4 1 a :通過孔 242 :第2層狀電極 2 42a :通過孔 242b :通過孔 243 :高介電質層 2 4 5 :層間絕緣層 246 :配線 247 :配線 2 5 0 :應力緩和部 260 :安裝部 261 :接地用連結墊 261x :接地用連結墊 2 6 1 y :接地用連結墊 2 6 1 a :通孔 2 6 1 b :通孔 2 6 2 a :通孔 262b:通孔 2 6 2 c :通孔 262 :電源用連結墊 262x :電源用連結墊 -60- 201116186 262y:電源用連結墊 263 :訊號用連結墊 266x :成形段 266y :成形段 267x :成形段 2 6 7 y :成形段 2 6 8 :成形段 270 :晶片電容器配置區域 2 7 1 :接地用連結墊 272 :電源用連結墊 2 7 3 :晶片電容器 4 1 0 :層間絕緣層 420 :高介電質薄片 422 :銅箔 424 :高介電質層 426:上部金屬層 43 0 :乾膜 440 :乾膜 45 0 :層間充塡用樹脂 452 :高介電質層間充塡層 4 5 4 :貫穿孔 456 :無電解鍍銅膜 460 :乾膜 462 :貫穿孔 -61 - 201116186 464 :電解鑛銅膜 470 :樹脂絕緣薄片 472 :貫穿孔 474 :鍍銅膜 500 :基板 5 1 0 :層間絕緣層 520 :高介電質薄片 522 :銅箔 524 :高介電質層 526 :銅箔 5 3 0 :貫穿孔 5 3 0a :貫穿孔 5 3 1 :貫穿孔 5 3 1 a :貫穿孔 5 3 2 :貫穿孔充塡用樹脂 540 :無電解鑛銅膜 541 :抗鍍層 542 :電解鍍銅膜 5 4 3 :上部電極 544 :成形段 5 5 0 :應力緩和薄片 5 6 0 :通孔 5 62 :導體 6 0 0 :基板 -62- 201116186 6 1 0 :層間絕緣層 620 :高介電質薄片 622 :銅箔 624 :高介電質層 6 2 6 a :成形段 626 :銅箔 6 2 8 :層間絕緣層 • 63 0 :貫穿孔 63 2 :擴大孔 640 :貫穿孔充塡用樹脂 6 5 1 :貫穿孔 6 5 2 :貫穿孔 6 5 3 :貫穿孔 670 :應力緩和薄片 6 8 0 :貫穿孔 -63-54- 201116186 It can be seen from the results of the evaluation test 1 that, in addition to the deposition portion, the ceramic is formed by firing of a high dielectric material and used as a high dielectric layer, and has a high dielectric constant. As a result, It can suppress the instantaneous decrease of the potential. Further, as a result of the evaluation test 4, it was found that the comparative example could not instantaneously lower the potential of the 1C wafer after the 100-cycle. Although the reason is unknown, however, it is estimated that the bonding between the high dielectric particles is weak, so that cracks are generated therefrom, and the function of the capacitor is lost. Φ In addition, the thermal cycle test was carried out on Example 22 in which a high dielectric sheet forming circuit was applied before being attached to the deposition portion, and the potential transient of the 1C wafer could not be lowered. Although the reason is not clear, it is estimated that the pressure concentration portion at the time of lamination may be cracked due to the heat cycle test. Further, in the examples 25 and 26 in which the stress relieving portion was not provided, the thermal cycle test was carried out, and the potential of the 1C wafer could not be instantaneously lowered. Although the reason is unknown, however, it is estimated that there is no stress relaxation portion, and the stress caused by the difference in thermal expansion coefficient between the 1C wafer and the multilayer printed wiring board causes φ to cause cracking or cracking of the high dielectric layer. The starting point. Since the starting point of the crack occurs due to the thermal cycle test, the particle displacement may cause cracking at this time because the high dielectric layer is repeatedly charged and discharged during the simultaneous switching test. Further, when the electrostatic capacitance immediately below the module is 0.4 // F or less, in the case of the fourth and fifth embodiments, after the evaluation test 2 is performed, the potential of the 1C chip cannot be instantaneously lowered. Although the reason is unknown, it is estimated that the hast test may cause deterioration of the high dielectric layer, and the relative dielectric constant may be lowered to obtain a sufficient decoupling effect. In addition, when the static capacitance directly under the module is 0.5 - 55 - 201116186 / / F or less, after the evaluation test 2 is carried out, the potential of the IC chip cannot be instantaneously lowered. In contrast, the same mode as in the fourth and fifth embodiments is obtained. Embodiments 23 and 24 of the electrostatic capacitance immediately below the group do not cause problems. The reason for this is unknown. However, it is estimated that the potential of the 1C wafer can be instantaneously lowered by performing power supply using the wafer capacitor. Further, after performing the evaluation test 2 on the embodiments 14 and 15 in which the electrostatic capacitance is large, the potential of the 1C wafer cannot be instantaneously lowered. Although the reason is unknown, however, it is estimated that the electrostatic capacitance is large and it is more susceptible to the HAST test, so the dielectric degradation or insulation breakdown occurs in the high dielectric layer. In Examples 12 to 15 in which the electrostatic capacitance was large, the result of the evaluation test 4s5 3 was X. It is inferred that the dielectric displacement occurs during repeated charging and discharging of the dielectric, and the stress accumulated during thermal cycling is added to the stress caused by the displacement, so that the relative dielectric constant of the high dielectric layer is degraded. X. Further, the evaluation test 4 58 3 of Examples 2 to 5, 16 and 17 in which the electrostatic capacitance was relatively small was also X. It is inferred that the thermal cycle test causes the dielectric to expand and contract, so that the relative dielectric constant of the high dielectric layer is degraded and the electrostatic capacitance directly under the module is reduced to X. It can be seen from the results of Table 1 that if the static capacitance directly under the module is 0.8~5 #F, the instantaneous voltage of the transistor corresponding to 1C can be reduced after the environmental test, and the HAST test and the thermal cycle test will not If there is a problem, it has excellent insulation reliability and connection reliability. Further, in all of the embodiments, the first layered electrode is used as the ground and the second layered electrode is used as the power source. However, the reverse may be applied. The multilayer printed wiring board of the present invention can be used to mount a semiconductor device such as a semiconductor chip of a 1C wafer, for example, and can be applied to an electric related industry and a communication-related industry, etc. [FIG. 1] FIG. A plan view of the multilayer printed wiring board 10. Fig. 2 is a longitudinal sectional view of a multilayer printed wiring board (only the left side of the center line is shown). Fig. 3 is a schematic perspective view of the layered capacitor portion 40. Fig. 4 is an explanatory view showing a manufacturing procedure of the multilayer printed wiring board. Fig. 5 is an explanatory view showing a manufacturing procedure of the multilayer printed wiring board 10. Fig. 6 is an explanatory view showing a manufacturing procedure of the multilayer printed wiring board 1 . Fig. 7 is an explanatory view showing a manufacturing procedure of the multilayer printed wiring board 10; Fig. 8 is a longitudinal sectional view showing a multilayer printed wiring board of the second embodiment. Fig. 9 is an explanatory view showing a manufacturing procedure of the multilayer printed wiring board 1 1 . Fig. 1 is an explanatory view showing a manufacturing procedure of the multilayer printed wiring board 110. Fig. 11 is an explanatory view showing a manufacturing procedure of the multilayer printed wiring board 110. Fig. 12 is an explanatory view of a high dielectric sheet 520 having corners. Fig. 13 is a longitudinal sectional view showing a multilayer printed wiring board 210 of the third embodiment. Fig. 14 is a schematic perspective view of the layered capacitor portion 240. Fig. 15 is an explanatory view showing a manufacturing procedure of the multilayer printed wiring board 210. Fig. 16 is an explanatory view showing a manufacturing procedure of the multilayer printed wiring board 210. Fig. 17 is an explanatory view showing a manufacturing procedure of the multilayer printed wiring board 210. Fig. 18 is a description of the manufacturing steps of other multilayer printed wiring boards 2 - 10 - 201116186 [Description of main components] 1 0 : multilayer printed wiring board 2 0 : core substrate 2 1 : core substrate body 2 2 : wiring Pattern 24: through-hole conductor 30: deposition portion 3 2 : wiring pattern 3 4 : via hole 3 6 : resin insulating layer 40 : layered capacitor portion 41 : first layered electrode 4 1 a : through hole 42 : second layer Electrode 4 2 a : through hole 43 : high dielectric layer 60 : mounting portion 6 1 : grounding connection pad 6 1 a : through hole 6 2 a : through hole 6 2 b : through hole 62 : power supply connection Pad 63: Signal connection pad - 58 - 201116186 70 : Wafer capacitor arrangement area 71 : Ground connection pad 72 : Power supply connection pad 7 3 : Wafer capacitor 1 1 0 : Multilayer printed wiring board 1 2 0 : Interlayer insulation layer 140 : layered capacitor portion 141 : first layered electrode 1 4 1 a : through hole 1 4 2 : second layered electrode 1 4 2 a : through hole 143 : high dielectric layer 1 50 : stress relieving portion 1 6 0 : Mounting part 1 6 1 : Grounding connection pad 1 6 1 a : Through hole 1 6 2 a : Through hole 1 6 2 b : Through hole 162 : Power supply connection pad 163 : Signal connection pad 170 : Crystal Capacitor arrangement area 1 7 1 : Ground connection pad 172 : Power supply connection pad 173 : Wafer capacitor - 59 201116186 2 1 0 : Multilayer printed wiring board 2 2 0 : Interlayer insulating layer 240 : Layered capacitor part 241 : 1st layer Electrode 2 4 1 a : through hole 242 : 2nd layered electrode 2 42a : through hole 242b : through hole 243 : high dielectric layer 2 4 5 : interlayer insulating layer 246 : wiring 247 : wiring 2 5 0 : stress Relaxing portion 260: mounting portion 261: grounding connection pad 261x: grounding connection pad 2 6 1 y : grounding connection pad 2 6 1 a : through hole 2 6 1 b : through hole 2 6 2 a : through hole 262b: Through hole 2 6 2 c : Through hole 262 : Power supply connection pad 262x : Power supply connection pad - 60 - 201116186 262y : Power supply connection pad 263 : Signal connection pad 266x : Forming section 266y : Forming section 267x : Forming section 2 6 7 y : forming section 2 6 8 : forming section 270 : wafer capacitor arrangement area 2 7 1 : grounding connection pad 272 : power supply connection pad 2 7 3 : wafer capacitor 4 1 0 : interlayer insulating layer 420 : high dielectric Sheet 422: Copper foil 424: High dielectric layer 426: Upper metal layer 43 0: Dry film 440: Dry film 45 0 : Interlayer filling resin 452 : high dielectric interlayer filling layer 4 5 4 : through hole 456 : electroless copper plating film 460 : dry film 462 : through hole -61 - 201116186 464 : electrolytic copper film 470 : resin insulating sheet 472 : through hole 474 : copper plating film 500 : substrate 5 1 0 : interlayer insulating layer 520 : high dielectric sheet 522 : copper foil 524 : high dielectric layer 526 : copper foil 5 3 0 : through hole 5 3 0a : through hole 5 3 1 : through hole 5 3 1 a : through hole 5 3 2 : through hole filling resin 540 : electroless copper film 541 : plating resist 542 : electrolytic copper plating film 5 4 3 : upper electrode 544 : forming section 5 5 0: stress relaxation sheet 5 6 0 : through hole 5 62 : conductor 6 0 0 : substrate - 62 - 201116186 6 1 0 : interlayer insulating layer 620 : high dielectric sheet 622 : copper foil 624 : high dielectric layer 6 2 6 a : forming section 626 : copper foil 6 2 8 : interlayer insulating layer • 63 0 : through hole 63 2 : enlarged hole 640 : through hole filling resin 6 5 1 : through hole 6 5 2 : through hole 6 5 3: through hole 670: stress relieving sheet 6 8 0 : through hole - 63

Claims (1)

201116186 七、申請專利範圍: 1 ·—種多層印刷配線板的製法,是爲製造具備有堆積 部、安裝部、以及層狀電容器部之多層配線板的方法;該 堆積部,乃是藉著前述絕緣層內的通孔來將介隔著樹脂絕 緣層做複數層積的配線圖案彼此予以電性連接,如此來構 成;該安裝部,乃是將與前述配線圖案做電性連接的半導 體元件,安裝到表面:該層狀電容器部,乃是在前述堆積 部與前述安裝部之間,具有陶瓷製之高介電質層、和夾著 該高介電質層之第1及第2層狀電極,前述第1及第2層狀電 極之其中一方連接到前述半導體元件的電源線且另一方連 接到接地線;其特徵爲包含: 在作爲前述第1層狀電極的金屬箔上形成高介電質材 料的薄膜,經由燒成該高介電質材料來形成前述高介電質 層,在該高介電質層上經由形成作爲前述第2層狀電極的 金屬層來得到高介電質薄片之工程; 準備已形成前述堆積部的核心基板之工程; 在前述堆積部上接合前述高介電質薄片之工程。 2.—種多層印刷配線板的製法,是爲製造具備有堆積 部、安裝部、以及層狀電容器部之多層配線板的方法;該 堆積部,乃是藉著前述絕緣層內的通孔來將介隔著樹脂絕 緣層做複數層積的配線圖案彼此予以電性連接,如此來構 成於核心基板的兩面:該安裝部,乃是將與前述配線圖案 做電性連接的半導體元件,安裝到表面;該層狀電容器部 ,乃是在前述堆積部與前述安裝部之間,具有陶瓷製之高 -64- 201116186 介電質層、和夾著該高介電質層之第1及第2層狀電極,前 述第1及第2層狀電極之其中一方連接到前述半導體元件的 電源線且另一方連接到接地線;其特徵爲包含: 在作爲前述第1層狀電極的金屬箔上形成高介電質材 料的薄膜,經由燒成該高介電質材料來形成前述高介電質 層,在該高介電質層上經由形成作爲前述第2層狀電極的 金屬層來得到高介電質薄片之工程; φ 準備已在兩面上形成前述堆積部的核心基板之工程; 在前述堆積部中與前述核心基板爲相反側的面上接合 前述高介電質薄片之工程。 3 .如申請專利範圍第1或2項所記載之多層印刷配線板 的製法,其中,前述高介電質材料,係含有從鈦酸鋇( BaTi〇3 )、鈦酸緦(SrTi03 )、氧化钽(Ta03,Ta203 ) 、鉻鈦酸鉛(PZT)、锆鈦酸鑭鉛(PLZT)、锆鈦酸鈮鉛 (ΡΝΖΤ )、锆鈦酸鈣鉛(PCZT )、以及鉻鈦酸緦鉛( φ PSZT)所構成之群組所選取之1種或2種以上之金屬氧化物 之原料者。 -65-201116186 VII. Patent application scope: 1 . The method for manufacturing a multilayer printed wiring board is a method for manufacturing a multilayer wiring board having a deposition portion, a mounting portion, and a layered capacitor portion; the deposition portion is by the foregoing a through hole in the insulating layer is electrically connected to a plurality of wiring patterns interposed by a resin insulating layer, and the mounting portion is a semiconductor element electrically connected to the wiring pattern. Mounted to the surface: the layered capacitor portion has a ceramic high dielectric layer and first and second layers sandwiching the high dielectric layer between the deposition portion and the mounting portion In the electrode, one of the first and second layered electrodes is connected to the power supply line of the semiconductor element and the other is connected to the ground line; and the method includes: forming a high dielectric on the metal foil as the first layered electrode a thin film of an electroless material, the high dielectric layer is formed by firing the high dielectric material, and a high dielectric layer is formed on the high dielectric layer by forming a metal layer as the second layer electrode Engineering of an electric sheet; preparation of a core substrate on which the above-mentioned deposition portion has been formed; and bonding of the high dielectric sheet to the deposition portion. 2. A method of manufacturing a multilayer printed wiring board for manufacturing a multilayer wiring board including a deposition portion, a mounting portion, and a layered capacitor portion; the deposition portion is formed by a through hole in the insulating layer A wiring pattern in which a plurality of layers are laminated via a resin insulating layer is electrically connected to each other, and is formed on both surfaces of the core substrate: the mounting portion is a semiconductor element electrically connected to the wiring pattern, and is mounted to The layered capacitor portion has a ceramic high-64-201116186 dielectric layer between the deposition portion and the mounting portion, and first and second layers sandwiching the high dielectric layer a layered electrode, wherein one of the first and second layered electrodes is connected to a power supply line of the semiconductor element and the other is connected to a ground line; and the method includes: forming a metal foil as the first layered electrode a thin film of a high dielectric material, wherein the high dielectric layer is formed by firing the high dielectric material, and a high dielectric layer is formed on the high dielectric layer by forming a metal layer as the second layer electrode Engineering of the electro-chemical sheet; φ Preparation of a core substrate on which the deposition portion is formed on both surfaces; and a process of joining the high-dielectric sheet to the surface on the opposite side of the core substrate in the deposition portion. The method for producing a multilayer printed wiring board according to claim 1 or 2, wherein the high dielectric material contains bismuth titanate (BaTi〇3), barium titanate (SrTi03), and oxidation.钽(Ta03,Ta203), lead chromite titanate (PZT), lead zirconate titanate (PLZT), lead zirconate titanate (ΡΝΖΤ), lead zirconate titanate (PCZT), lead bismuth chromite titanate (φ A raw material of one or more metal oxides selected from the group consisting of PSZT). -65-
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103915456A (en) * 2013-01-08 2014-07-09 株式会社东芝 Solid-state Imaging Device

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JPH0536857A (en) * 1991-07-30 1993-02-12 Toshiba Corp Semiconductor integrated circuit mounting board
US6068782A (en) * 1998-02-11 2000-05-30 Ormet Corporation Individual embedded capacitors for laminated printed circuit boards
JP2001308222A (en) * 2000-04-21 2001-11-02 Hitachi Ltd Mounting board
TW593207B (en) * 2003-09-09 2004-06-21 Walsin Technology Corp Ceramic dielectric composition for capacitor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103915456A (en) * 2013-01-08 2014-07-09 株式会社东芝 Solid-state Imaging Device

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