TW201114824A - Thermoplastic polymer composition - Google Patents

Abstract

A stabilizer composition which comprises 6-[3-(3-t-butyl-4-hydroxy-5-methylphenyl)propoxy]-2,4,8,10-tetra-t-butyldibenz[d,f][1,3,2]dioxaphosphepine together with allitol, iditol, galactitol, sorbitol, talitol or mannitol.

Description

201114824 VI. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to a thermoplastic polymer composition. [Prior Art] Thermoplastic polymers are widely used in food packaging containers and daily sundries because of their light weight, excellent transparency, and excellent impact resistance. As the thermoplastic polymer composition, it is known to contain a thermoplastic polymer and 6_[3_(3_t-butyl-4-(hydroxy-5-methylphenyl)propoxy]-2,4,8,l〇- A thermoplastic polymer composition of tetra-t-butyldibenzo[d,f][l,3,2]diphosphorus cycloheptane (Patent Document 1). [Patent Document 1] Japanese Laid-Open Patent Publication No. Hei 10-273494. SUMMARY OF THE INVENTION The thermoplastic polymer has a problem that the processing stability is deteriorated by the action of heat, oxygen, or the like during molding. In order to solve this problem, the inventors of the present invention conducted research and found a thermoplastic polymer composition having further improved processing stability. That is, the present invention provides the following [1] to [10]. [1] A stabilizer composition comprising the compound represented by the formula (1):

[wherein, R1, R2, R4 and R5 each independently represent a hydrogen atom, a carbon number 149241.doc 201114824 alkyl group, a cycloalkyl group having a carbon number of 5-8, and an alkylcycloalkyl group having a carbon number of 6-12. And an aralkyl group or a stupid group having a carbon number of 7 to 12, and R3 each independently represents a hydrogen atom or a carbon number 丨~^ of the dazzle group, and X represents a single bond, a sulfur atom or a divalent group represented by the formula (1_1): (wherein R6 represents a hydrogen atom, an alkyl group of carbon number 8 or a cycloalkyl group of 5 to 8 carbon atoms), and A represents a stretching group having a carbon number of 2 to 8 or a divalent group represented by the formula (i_2) : (wherein R 7 represents a single bond or an alkyl group having a carbon number of 1 to 8, and * represents a bond to the gas atom side), and any of Y and Z represents a hydroxyl group, a carbon number of 8 alkyl groups, and a mountain. Alkoxy groups of 1 to 8 or aralkyloxy groups having 7 to 12 carbon atoms, the other of which represents a gas atom or an alkyl group having a carbon number of -8 Å, and a compound represented by the formula (II):

CnH2n+2〇n (II) (wherein η represents an integer of 4 to 12). [2] The stabilizer composition according to [1], wherein the compound represented by the formula (1) is 6-[3-(3-t-butyl-4-hydroxy-5-methylphenyl)propoxy] _2,4,8,n$' Tert-butyldibenzo[d,f][l,3,2]diphosphorus cycloheptane. [3] The stabilizer composition according to [1], wherein the compound represented by the formula (π) is decitol, iditol, galactitol, sorbitol, talitol or ganol 149241 .doc 201114824 [4] The stabilizer composition as in [2] wherein the compound represented by the formula (π) is allolitol, iditol, galactitol, sorbitol, talitol or Mannitol. [5] A thermoplastic polymer composition comprising a thermoplastic polymer and a stabilizer composition according to [1], and the total weight of the compound represented by the formula (1) and the compound represented by the formula (9) is relative to the thermoplastic polymer 〇〇 0.001 to 3 parts by weight. [6]. The polymer composition according to [5], wherein the compound represented by the formula (1) is a compound of 6 to 3, a third group, a 4-amino group, a 5-methylphenyl) propoxy group.

a second butyl dibenzo[d,f][1,3,2]:4^H m. A polymer composition such as m, wherein the compound represented by formula (II) is a loitol, iditol , galactitol, sorbitol, talitol or mannitol. The polymer composition according to [6], wherein the compound represented by the formula (11) is a loitol, an iditol, a galactitol, or a decyl alcohol. A method for producing a thermoplastic polymer composition of a pepper, a talitol or a sugar [9]: a polymer, a stabilizer, a stabilizer, and a stabilizer composition according to any one of (1) to [4]. The system is used to stabilize thermoplastic polymer processing. [Embodiment] Hereinafter, the present invention will be described in detail. The thermoplastic polymer composition of the present invention contains a thermoplastic polymer, a compound represented by the above I4924I.doc 201114824() (hereinafter sometimes referred to as a compound oxime), and a compound represented by the above formula () (hereinafter sometimes It is referred to as compound (II)). In the above formula (1), examples of the alkyl group of the carbon number represented by R1, R2, R4 and R5 include, for example, ethyl, n-propyl, isopropyl, n-butyl isobutyl and the second. Butyl, tert-butyl, third amyl, isooctyl, tert-octyl, 2-ethylhexyl. Examples of the cycloalkyl group having 5 to 8 carbon atoms include a cyclopentyl group, a cyclohexyl group, an anthranyl group, and a cyclooctyl group. As the alkyl group of 6 to 12 carbon atoms, for example, fluorenyl 1 fluorenylcyclopentyl, methylcyclohexyl, 1-methyl-4-isopropylate is used as the aromatic base of rabbits 7 to 12. For example, a benzyl group, a hydrazinobenzyl group, and an α,α· dimethylbenzyl group are mentioned. R, R2 and R4 are each independently an alkyl group having a carbon number of 8 or a cycloalkyl group having 5 to 8 carbon atoms or an alkylcycloalkyl group having a carbon number of 6 to 12. Rl and r4 are more preferably independently a tertiary butyl group, a third pentyl group or a third octyl group, a cyclohexyl group or a fluorene-fluorenylcyclohexyl group. R2 is preferably independently a methyl group, an ethyl group, a n-propyl group, an isopropyl 'n-butyl group, an isobutyl second butyl group, a third butyl group, a second pentyl group and the like having a carbon number of 1 to 5 The alkyl group is more preferably an anthracenyl group, a tert-butyl group or a third pentyl group. R5 is preferably a methyl group, an ethyl group, a n-propyl isopropyl n-butyl group, an isobutyl group, a second butyl group, a tert-butyl group, a third fluorenyl group, or the like, or a hydrogen atom of 1 to 5 or a hydrogen group. Atom, more preferably a sulfhydryl or a hydrogen atom. Examples of the alkyl group of the carbon number represented by R3 include a methyl group, an ethyl group, a n-propyl group, an isopropyl group, a n-butyl group, an isobutyl group, a second butyl group, a third butyl group, and a third group. Sulfhydryl, isooctyl, trioctyl, 2-ethylhexyl, preferably methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, 149241.doc 201114824 a butyl group, a second pentyl group or the like having a carbon number of 1 to 5 or a hydrogen atom, more preferably a methyl group or a hydrogen atom. Ί1, a sulfur atom or a divalent group represented by the above formula (1-1). Examples of the alkyl group having 1 to 8 carbon atoms represented by R6 in the formula (M) include a methyl group, an ethyl group, a n-propyl group, an isopropyl group, an n-butyl group, an isobutyl group, and a second butyl group. The third butyl group, the third pentyl group, the isooctyl group, the third octyl group, and the 2-ethylhexyl group are cyclized groups having a carbon number of 5 to 8, and examples thereof include a cyclopentyl group, a cyclohexyl group, and a cycloheptyl group. , cyclooctyl. R6 is preferably a carbon group, a hydrogen group such as a methyl group, an ethyl group, a n-propyl group, an isopropyl group, a n-butyl group or an isobutyl group. Preferably, X is a single bond or a divalent group represented by the formula (M), and more preferably a single bond. A represents an alkylene group having 2 to 8 carbon atoms or a divalent group represented by the above formula (1-2), preferably an alkylene group having 2 to 8 carbon atoms, and as the alkylene group, for example, Further, a propyl group, a propyl group, a butyl group, a pentamethylene group, a hexamethylene group, an octamethylene group, a 2,2-dimethyl-i, a 3-propyl group, etc., more preferably a propyl group. The divalent group represented by the formula (1-2) is bonded to the oxygen atom and the benzene nucleus '* indicates that it is bonded to the oxygen atom. Examples of the stretching group of the hindrance number 1 to 8 represented by R include an anthracene group, an exoethyl group, a propyl group, a butyl group, a pentamethylene group, a hexamethylene group octamethyl group, and 2 , 2 - a fluorenyl-1,3 - propyl group and the like. As the r7, a single bond or an ethyl group is preferred. Any of Y and Z represents a hydroxyl group, an alkyl group having a carbon number of 2, a oxy group having a carbon number of 丨8 or a compound having a slave number of 7 to 12, and the other representing a hydrogen atom or a carbon number of 1 to 8 base. Here, examples of the alkyl group having 1 to 8 carbon atoms include methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, isobutyl group, second butyl group, and third butyl group. Tripentyl, isooctyl, trioctyl, 2-ethylhexyl 149241.doc 201114824. As the alkoxy group of carbon number 8, for example, a group, a n-propoxy group, an isopropoxy group, a decyl ethoxy group, a 筮-匕τ oxy group, an isobutoxy group, a second butyl group, a second butoxide group Base, third pentyloxy, isooctyloxy, third octyloxy:=hexyloxy. Examples of the aryloxy group having 7 to 12 carbon atoms include a decyloxy group, an α-methyloxy group, and a monomethyloxy group. Among the squarianes represented by the formula (1), preferred is r, and Han 4 is a tertiary, m-based or "cyclohexyl group, and R, carbon number 5 is a base of R. Or a carbon number of 5, which is a gas atom or an alkyl group having a carbon number of Μ, Χ is a single bond, and Α is an alkylene group having a carbon number of 2 to 8. In the stabilizer composition of the present invention, the compound (1) may be used alone or in combination of two or more compounds. As the compound (1), for example, 6_[3_(3_t-butylhydroxyhydroxy-5-fluorenylphenyl)propoxy]_2,4,8,1〇_tetrabutylbutyl Benzo[d'f][ 1 '3,2]-α-disc ring-gum [sold as Sumitiizer (registered trademark) and sold by Sumitomo Chemical Co., Ltd.], 2,1〇_dimethyl_ 4,8 di-tert-butyl-6-[3-(3,5-di-t-butyl-4-yl-hydroxyphenyl)propoxy]12H-dibenzo[d'g][l,3 , 2] oxazepine, 2,4,8,10-tetra·t-butyl _6_[3_(3,5-di-t-butyl-4-hydroxyphenyl)propoxy] Dibenzo[d,f][l,3,2]disophorocycloheptane, 2,4,8,10-tetra-p-pentyl-6-[3-(3,5-di- Tributyl-4-hydroxyphenyl)propoxy]_12_fluorenyl_12H_di-p-[d,g][1,3 2]dioxaphosphorane, 2,10-dimethyl 4,8-di-t-butyl-6-[3-(3,5-di-t-butyl-4-hydroxyphenyl)propenyloxy]-12H-di-p-[d,g] [i,3,2]dioxite 4 octa-8%, 2,4,8,10-tetra-p-pentyl-6-[3-(3,5-di-t-butyl-4- Hydroxy stupyl) propionyloxy]_12·decyl-12H-di-p-[d,g][l,3,2] 149241.doc 201114824 Dioxophosphorus, 2,4,8,l〇-tetra-t-butyl_6·[3·(3,5_:β-t-butyl-4-hydroxyphenyl)propenyloxy]-dibenzo[d, f][1,3,2]diphosphorus cycloheptane, 2,10-dimethyl-4,8-di-t-butyl_6_(3,5-di-t-butyl-4-yl) Benzyl oxime)-12H-dibenzo[d,g][1,3,2]dioxaphosphorane, 2,4,8,10-tetra-tert-butyl·6_(3, 5_:_Tertiary butyl_4•hydroxybenzylideneoxy)-12-methyl-12Η-dibenzodioxime, hexamethylene, 2,1〇_dimethyl-4,8-di- Third butyl·6_[3·(3_methyl_4_hydroxy-5_t-butylphenyl)propoxy]-12Η-di-p-[d,g][1,3,2] Dioxaphosphorus, 2,4,8,10-tetra-tert-butyl_6_[3_(3,5-di-t-butyl-tertyl)-propoxy]--12-indene And [d,g][l,3,2]dioxaphosphorane, 2,1〇-diethyl-4,8-di-t-butyl-6_[3-(3,5-di -T-butyl-4-transpyridyl)propoxy]-12H-dibenzo[d,g][1,3,2]dioxapine, 2,4,8,1〇 _ IV_Tertibutyl-6-[2,2-dimethyl_3_(3_Terylene-4_trans)-5-phenylphenylpropoxy]•dibenzo[£^ ][1,3,2] two drink phosphorus cycloheptane, etc., preferably Is 6-[3·(3-tert-butyl-based-5-nonylphenyl)propoxy]_2,4,8,1〇tetra- 2,2-butyldibenzo[d,f]n , 3, 2] diphosphorus cycloheptane. The compound (I) can be produced, for example, by the method described in the publication of Japanese Laid-Open Patent Publication No. Hei No. Hei. In the compound (II), n is an integer of 4 to 12, preferably 5 to 8, more preferably 6. As the compound (I!), for example, red sugar alcohol, threitol, arabitol, xylitol, ribitol, alditol, iditol, galactitol, sorbitol, sugar Alcohol, mannitol, volemic alcohol (volemu.!), avocado alcohol (perseitQl), octanol and other carbon number Η] sugar I49241.doc 201114824 alcohol. The compound (II) may be an optically active substance such as a D body (dextroisomer) or a L body (laevoisomer), or may be a non-optical active such as a DL body (raceomer). As the compound (II), it is preferred to use Fisher's projection formula to represent a sugar alcohol having η of 6 such as aldolitol, iditol, galactitol, sorbitol, talitol or mannitol. More preferably, sorbitol or mannitol. C |_| :h2oh mi Π II υπ II II υπ II 1 I un ON UI ( UI1 )H2〇H Aloritol ch2oh HO— l_l ——H ΛΜ-Ι Π un || 1 IvJ 1 I II M c Un 3H2〇H Iditol Η HO HO Η ch2oh

OH -Η Η

OH

CH2〇H galactitol ch2〇h H— \-\r\ -- OH ll 1 IU LJ π rNLJ n |_| Un Π ( url :h2oh sorbitol HO- HO- HO- H- HO- HO- H- H- ch2oh

-H -H -H -OH CH2〇H talitol

CH2〇H -H -H -OH -OH

CH2〇H mannitol The compound (II) can be used as it is. Further, the compound (II) may be an anhydride or may be a hydrate. Examples of the thermoplastic polymer include a polyethylene resin (high density poly 149241.doc -10- 201114824 ethylene (HD-PE, High density Polyethylene), low density polyethylene (LD-PE, low density Polyethylene), and a linear chain. LLDPE 'Linear Low Density Polyethylene, Ethylene-Vinylalcohol copolymer, Ethylene-Acrylate Copolymer, Ethylene-Ethyl Acetate Copolymer (EVA, Ethylene-Vinyl acetate copolymer), a polypropylene resin (crystalline propylene homopolymer, propylene-ethylene random copolymer, propylene/α-olefin random copolymer, propylene-ethylene-α-olefin copolymer, and a propylene homopolymer component or a polypropylene-based block copolymer mainly comprising a copolymer component of propylene and a copolymer component of propylene and ethylene and/or a heart olefin, a methylpentene polymer or a polystyrene resin ( Poly (p-nonyl styrene), poly(α-decyl styrene) and other polystyrene, acrylonitrile-styrene copolymer 'acrylonitrile-butadiene _ present ethylene copolymer (ABS ' Acrylonitrile Butadiene Styrene copolymer), special acrylic rubber-acrylonitrile-styrene copolymer, acrylonitrile-chlorinated polyethylene-styrene copolymer, etc., polybutadiene rubber (BR, Butadiene rubber) , Styrene-Butadiene rubber (SBR), Styrene-Butadiene block copolymer (SBS, modified by BR or SBR or SBS) Impact polystyrene (HI-PS, High Impact Polystyrene), chlorinated polyethylene, polybutadiene, gasified rubber, polyethylene, polyvinylidene chloride, fluorenyl acrylic resin, I resin, polycondensation road, grafted polyphenylene resin, polyphenylene sulfide resin, polyamino phthalate, polyamide, polyester resin (such as polyethylene terephthalate, poly-p-phenylene) Butyl formate, etc., polylactic acid resin (PLA, • 11 - 149241.doc 201114824 P〇lylactlc acid), polycarbonate, polyacrylate, polyphenol, polyketone, polyethersulfone, aromatic polyester resin , diallyl phthalate, : oxime oxy-resin, ls2-polybutadiene, polyiso A diene, a butyl hydride/acrylonitrile copolymer, a ethylene-methyl propyl methacrylate copolymer, etc., are preferably formed by adding a good property, and are preferably a polyethylene resin or a polypropylene resin. The resin, the polystyrene resin, and the polybutadiene resin are more preferably a polyethylene resin or a polybutadiene resin. The total weight of the compound (1) and the compound (II) in the thermoplastic polymer composition of the present invention is preferably 疋0.001 to 3 in terms of the weight of the thermoplastic polymer (10), and φ is superior to β λ. 0·02 2 parts by weight, further preferably 0.02 to 1 part by weight 'and more preferably 〇〇5 to 〇8 parts by weight particularly excellent 〇.〇8 0.7 weight damage 'compound (1) and compound (1)) The weight is preferably compound (1): compound (11) = 99 9: 〇 1 to 5: 95 is more preferably 98 2 to 10:90. The thermoplastic polymer composition of the present invention may contain an additive (except for the compound (1) and the compound (Η)) within a range not impairing the effects of the present invention. As the additive, for example, it can be listed as a rebel. 祆 & η &. 』 magic lift. Antioxidant 'UV absorber, light stabilizer, metal deactivator, nucleating lubricant, antistatic agent, flame retardant, Fillers, pigments, inorganic fillers, and the like. Here, 'as a lanthanide antioxidant, for example, 2,6-di-t-butyl-4-methylbenzene, 2,4,6-tri-tert-butylphenol, 2,6-di - tert-butylphenol, 2-tert-butyl-4,6-dimethylphenol, 2,6-di-t-butyl Iethylphenol, 2,6-di-di-buty 4 t Le-butyl-4-n-butylphenol, 2,6-di-t-butyl-4-isobutylbenzene, hydrazine, pentoyl-4, nonylphenol, 2_(α-fluorenyl ring 149241.doc •12- 201114824 Hexyl)-4,6-dimethylphenol, 2,6-di-octadecyl _4-methylbenzene, 2,4,6-tricyclohexylphenol, 2, 6-di-t-butyl-4-tomoxymethylphenol, 2,6·di-indenyl-4-methylphenol, 2,4-dimethyl-6_(1,_ylyl eleven Alkyl-1 '-yl)phenol, 2,4-dimethylmethylheptadecyl-poly-yl)phenol, 2,4-dimethylmethyltridecyl-indenyl-phenol And a mixture thereof and the like are alkylated; 2,4-octylthiomethyl-6-t-butylbenzene, 2,4-dioctylthiononyl-6-nonylphenol, 2 , 4-dioctylthiomethyl-6-ethylphenol, 2,6-di-dodecylsulfomethyl-4-mercaptobenzene, and mixtures thereof, etc. Methylphenol; 2,2'-methylenebis(4-methyl-6-tert-butylphenol), 2,2,-methylenebis(4-ethyl-6-tert-butylphenol ), 2,2,-fluorenylene bis[4-methyl-6-(α-mercaptocyclohexyl)phenol], 2,2'-methylenebis(4-methyl-6-cyclohexylphenol) ), 2,2'-fluorenylene bis(4-mercapto-6-nonylphenol), 2,2,-fluorenylene bis(4,6-di-t-butylphenol), 2,2 ,-ethylenebis(4,6-di-tert-butylphenol), 2,2·-ethylenebis(4-isobutyl-6-tert-butylphenol), 2,2,- Methylene bis[6-(α-mercaptobenzyl)-4-nonyl phenol], 2,2·-methylene bis[6-(α,α-dimercaptobenzyl)-4-oxime Phenolic], 4,41-arylene dibis(6-tert-butyl-2-methylphenol), 4,4'-methylenebis(2,6-di-t-butylphenol), 4,4,-butylidene bis(3-mercapto-6-tert-butylphenol), 1,1-bis(4-hydroxyphenyl)cyclohexane, U-bis(5-t-butyl- 4-hydroxy-2-methylphenyl)butane, 2,6-bis(3-secondbutyl-5-methyl-2-pyridyl)-4-mercaptobenzene powder, 1,1 ,3-tris(5-t-butyl-4-hydroxy-2-indolylphenyl)butane, 1,1- Bis(5-tert-butyl-4-hydroxy-2-indolylphenyl)-3-n-dodecyldecylbutane, ethylene glycol butyrate double 149241.doc •13· 201114824 [3,3- Bi-3'-tert-butyl-4,hydroxyphenyl]ester, bis(hongt-butyl{hydroxy-5-methylphenyl)dicyclopentadiene, terephthalic acid bis[2( 3·_Terbutyl- 2'-carbyl-5,-fluorenyl)-6-t-butyl-4-methylphenyl]acetate, u·bis(3,5-dimethyl- 2-hydroxyphenyl)butane, 2,2-bis(3,5-di-t-butyl-4-hydroxyphenyl)propane, 2,2-bis (5-t-butylhydroxy-_2) Methylphenyl)-4-n-dodecyldecylbutane, u,5,5tetrakis(5-t-butylhydrazinehydroxy-2-methylphenyl)pentane, etc. Alkyl bisphenol and its derivatives; 4-hydroxylauric anilide, 4-hydroxystearyl aniline, octyl N-(3,5-di-t-butyl-4-hydroxyphenyl)carbamate And a mixture thereof, etc.; a mercaptoamine benzene derivative; β-(3,5-di-t-butyl-4-hydroxyphenyl)propionic acid and methanol, ethanol, octanol, stearyl alcohol, Ethylene glycol, i'3-propanediol, Μ-τ diol, hydrazine, 6 hexanediol, 1, 9-decanediol, neopentyl glycol, diethylene glycol, thioethylene glycol, spirodiol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, guanidine, Ν'- Bis(transethylethyl) oxalylamine, % thiadodecyl alcohol ' 3 thia pentadecanol, tridecyl hexane diol, trihydroxy decyl propane, 4 hydroxy fluorenyl _ 卜An ester of a monohydric or polyhydric alcohol such as a mixture of 2,6,7-trioxabicyclo[2,2,2]octane and the like; 2,2·-thiobis(6-tert-butylphenol) , 2,2,-thiobis(4-methyl-6-tert-butylphenol), 2,2,-thiobis(4-octylphenol), 4,4,-thiobis (2 Hydroxy thiodiphenyl ether such as _methyl-6-tert-butylphenol) or 4,4,-(2,6-dimethyl-4-hydroxyphenyl)disulfide; 3,5,3 ,5-tetra-t-butyl- 4,4'-di-dibenzyldibenzyl scale, 4-hydroxyl 149241.doc -14· 201114824 _3,5-dimethylbenzyl decyl acetic acid octadecyl Cool 'three w tert-butyl-4-yl-f-yl)amine, dithioterephthalic acid bis (4_t-butyl-% hydroxy-2,6-dimethylbenzyl) vinegar, double (3,5_di_t-butyl_4_ via benzyl) thiopurine, 3'5-di-t-butyl _4_ a benzyl derivative such as a base derivative such as a thioglycolic acid isooctyl vinegar and a mixture thereof, an N-? derivative, or a s-based derivative; 2,4-bis(n-octylthio)· 6·(4-hydroxy-3,5-di-t-butylanilino)-1,3,5-three tillage, 2_n-octylthio". Bis(hydroxy)_3,5_di-t-butylanilino)·1,3,5·three-spray, 2·n-octylthio- 4,6_double (cardiac bromine dibutyl phenoxy) Base)-1,3,5-three tillage, 2,4,6-tris(3,5-di-t-butylbenzyl)isocyanurate, tris(3,5·di-t-butyl · 4-hydroxybenzyl) isocyanuric acid vinegar, 2,4,6-tris(3,5-di-t-butyl-p-phenylphenylethyl)-1,3,5-three tillage, 2,4 ,6-tris(3,5-di-t-butyl-4-ylhydroxyphenylpropyl)-1,3,5-diplough, bis(3,5-dicyclohexyl-4-hydroxyl) Isocyanurate tris(2-(3',5'-di-t-butyl-41-hydroxycinnaxyloxy)ethyl]isocyanurate and mixtures thereof 2,2-bis(3,5-di-t-butyl-2-hydroxyl-hydroxy)dioctadecylate, 2-(3-tert-butyl-4-hydroxy-5 -methylbenzyl)m-octadecyl malonate, 2,2-bis(3,5-di-t-butyl-4-hydroxybenzyl)malonate di-dodecylfluorenyl Ethyl ester, 2,2-bis(3,5-di-t-butyl-4-ylhydroxyl)malonate [4-(1,1,3,3-tetradecylbutyl)phenyl Hydroxybenzylation of esters and mixtures thereof Diacid ester derivative; 1,3,5-mercapto-2,4,6-di(3,5-mono-t-butyl- 4-yl-yl-yl) 14924I.doc -15- 201114824 Benzene, Μ-bis(3,5-di-t-butyl-4-ylhydroxybenzyl)·2,3 5,6-tetramethylbenzene, 2,4,6-tris(3,5-t-butyl An aromatic hydroxybenzyl derivative such as a mixture of hydroxybenzyl) phenol and the like; a dimethyl 3,5-di-t-butyl-4- hydroxybenzylphosphonate, 3,5-di-third Diethyl 4-hydroxybenzylphosphonate, di-octadecyl 3,5-di-t-butylhydroxybenzylphosphonate, 5-tert-butyl-4-hydroxy-3-methyl a benzylphosphonate derivative such as a di-octadecyl phosphinate, a calcium salt of a 3,5-di-t-butyl-4-hydroxybenzylphosphonic acid monoester, and the like; -(5-Tertiary-4-4_hydroxy-3-methylphenyl)propionic acid with methanol, ethanol, octanol, stearyl alcohol, ethylene glycol, propylene glycol, hydrazine-butanediol, hydrazine, Hexanediol, 1,9-nonanediol, neopentyl glycol, diethylene glycol, thioethylene glycol, spirodiol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, Ν,Ν,-bis(transethylethyl) oxazamide, 3_ Thiaphenanthrolol, 3-sulfopentadecanol, trimethylhexanol, trimethylmethylpropyl-l-yttrium-2,6,7-trioxabicyclo[2, 2,2] Mixture of octane 9 and its equivalents such as esters of monohydric or polyhydric alcohols; alcohols, octadecyl alcohol, ethylene glycol, propylene glycol, hydrazine diol, monohydric alcohol, 1,9-nonanediol, new Pentanediol, triethylene glycol, thioethadiolol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyano vinegar, ν'ν, bis(ylethyl) oxazamide , 3_thiazepine-alcohol, pentadecanol, dimercaptohexanediol, trihydroxydecylpropane, hydroxy hydroxy fluorenyl-2,6,7-trioxabicyclo[2,2 , 2] Xinchao and its mixture, etc.: or an ester of a polyhydric alcohol; 149241.doc -16- 201114824 3,5-di-t-butyl-4-hydroxy strep-acetic acid with decyl alcohol, ethanol, octanol , stearyl alcohol, ethylene glycol, hydrazine, 3· propylene glycol, 1,4-butanediol, ι, 6-hexanediol, .1,9-nonanediol, neopentyl glycol, diethylene glycol , thioethylene glycol, spirodiol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N,-bis(hydroxyethyl)oxacin 3-thiaundecyl alcohol, 3- thiapentadecanol, trimethyl hexane diol, trimethylolpropane, 4-hydroxymethylphosphono-2,6,7-trioxabicyclo[ 2,2,2] an ester of a monohydric or polyhydric alcohol such as a mixture of octane and the like; N,N'-bis[3-(3',5,-di-t-butyl-4,-hydroxyphenyl) ) 醯, Ν, :ΝΓ-bis[3-(3·,5·-di-t-butyl-4·-hydroxyphenyl)propanyl]hexanediamine, hydrazine, Ν'- Β-(3,5-di-t-butyl group) such as bis[3-(3,5i-di-t-butyl-4,-hydroxyphenyl)propanyl]propanediamine and mixtures thereof - 4, hydroxyphenyl) propionate, guanamine, etc.; and tocopherol such as α-fertility, β-tocopherol, γ-tocopherol, δ-tocopherol, and the like. Examples of the antioxidant of hydroquinone and alkylated hydroquinone include '2,6-di-t-butyl-4-indolylphenol and 2,5-di-t-butyl group. Stupid phenol, 2,5-di-third-pentyl hydroquinone, 2,6-diphenyl_4_octadecyloxyphenol, 2,6-di-t-butyl hydroquinone , 2,5-two-third

Bismuth-acid bis(3,5-di-t-butyl-4-hydroxyphenyl) ester and its likes, bis, stearic acid (3,5-di-t-butyl- 4-hydroxyphenyl) compound and the like.

The hungering agent may, for example, be 3,3'-thiodipropionic acid tridecyl thiodipropionate or 3,3,-thiodipropionic acid 149241.doc 201114824 Myristyl ester 3,3'-thio- _ _ stearyl stearate, neopentyl vinegar, a thiodipropionic acid laurel as a phosphorus system 丄 丄 ( 3 (3 · lauryl thiopropionate vinegar) and the like. Acid tris(nonylphenyl): agent Ya! For example, linolenic acid triphenyl vinegar, arsenic acid trilauric acid ^, (2,4 · di-t-butylphenyl) vinegar, tetraol bis-heart "θ s phosphate tri-eight-octave Vinegar 'distearyl pentylene-first*= know, diisodecyl pentaerythritol diphosphite, bis(2,4-butylphenyl)pentaerythritol diphosphite, double (K-di- Tributyl: methylphenyl) pentaerythritol diphosphite, bis(2,6-di-tertiary tert-butyl 4-methylphenyl)pentaerythritol diphosphite, bis (2,4,6_three third Lithylene pentaerythritol diphosphite, tristea sorbitol triphosphoric acid, tetrakis(2,4-di-t-butylphenyl)-4,4,di-diphenylphosphinic acid S曰, 2,2'-methylenebis(4,6-di-t-butylphenylethylhexyl-subspan IS曰, 2,2'-ethylene bis (4,6_di_third Butylphenyl)fluorophosphite, ('first butyl-6-nonylphenyl)ethyl succinic acid bismuth, bis(2,4_--second butyl-6-nonyl benzene Hydrazinyl phosphite, 2-(2,4,6-tri-tert-butylphenyl)-5-ethyl-5-butyl-l,3,2-oxaphospholane, 2,2,,2"-Nizawa base [ Triethyl-tris(3,3·,5,5'-tetra-t-butyl-1,1'-biphenyl-2,2·-diyl) phosphite and mixtures thereof and the like. Examples of the ultraviolet absorber include phenyl salicylate, 4-tert-butylphenyl salicylate, and 3,5,-di-t-butyl-4,-hydroxybenzoic acid-2. ,4-di-t-butylphenyl ester, salicylic acid-4-trioctylphenyl ester, bis(4-t-butylbenzylidene) resorcinol, benzhydrazine-diphenylene Phenol, 3,5,-di-t-butyl-tert-butyl-4-hydroxybenzoate, octadecyl 3,5-di-tert-butylhydroxybenzoate, 3' ,5匕二-T-butylhydroxy 149241.doc -18· 201114824 Salicylic acid ester derivatives such as 2-methyl-4,6·di-t-butylphenyl benzoate and mixtures thereof 2,4-dihydroxydiphenyl ketone, 2-hydroxy-4-yl benzophenone, hydrazine hydroxy-4-octyloxybenzophenone, 2,2-dihydroxyoxydiphenyl鲷, bis(5-benzylidene-4)-based 2_f-oxyphenyl)-methyl, 2,2,4,4|-tetrahydroxybenzophenone and mixtures thereof, etc. 2_ Bis-benzoic hydrazine derivative; 2-(2-hydroxy-5-methyl Benzotriazole, 2_(3,5,2-di-yl-2'-pyridylphenyl)benzotrien. Sit, 2_(5,m-based·2,•p-phenyl) Triazole, 2·(2·-trans group·5._T-octylphenyl)benzotriene. Sit, 2 servant tert-butyl 2-1-transmethylphenyl)·5-gas benzo Triazole, 2_(3._2nd butyl 2-H5-t-butylphenyl)benzotrimide, 2·(2,-yl-octyloxyphenyl)benzotrisole, 2_(3 ,, 5, two third pentyl 2, _ phenyl group) stupid:. Sitting, 2-[2·-ready base_3',5'·bis(α,α2f-based)phenyl]. stupid and saliva, 2-[(3|-t-butyl-2- '_Phenylphenyl)_5'_(2-octyloxyethyl)phenyl fluorene.纟, 2_[3,_帛三了基_5,_[2_(2_ethylhexyloxymylethyl)_2,-p-phenylene]_5•chlorobenzotrisene, 2 [3| _Tertiary butyl 2 group _5 _(2-methoxy arylethyl) phenyl]-5 chlorobenzotriene. Sit, 2 · [3 first butyl 2 · inclusion group _5, (2-methoxyethylethyl)phenyl]benzotriene, a 2 [3 f _ butyl _21 _ _ _5_(2 octyloxyethyl) phenyl] benzene And triazole, 2-[3,-第=丁其?, γ甘丁暴_2 _ 翘基-5'-[2-(2-ethylhexyloxy)carbonylethyl] benzyl] Three saliva, 2_[2_ carbyl_3_(3,4,5,6-tetrahydrophthalic acid imidomethylmethylphenyl)benzotrien. Sit, 2_(3,5_二· Third butyl-2-based basic group >5 • gas benzotriazole, 2 _, dodecyl hydroxy fluorenyl methyl phenyl) stupid and three money 2 said third butyl _2. ·5|_(2_isooctyloxy 149241.doc -19- 201114824 carbonylcarbonyl) phenyl]benzotriazole mixture, 2,2,-methylene bis[6_(211-benzotriazole) -2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol, 2,2,·-indenyl bis[4-tert-butyl_6_(2Η·benzotriazine) · 2_base) benzene age], poly (3~11) (ethylene glycol) and 2_ a condensate of [3,_t-butyl-2,hydroxy-5,-(2-methoxycarbonylethyl)phenyl]benzotriazole, poly(3~11) (ethylene glycol) and Condensate of 3_[3_(2Η-benzobisazole-2-yl)_5_t-butyl-4-hydroxyphenyl]propanoate, 3-[3-t-butyl_5_(5-gas · 2Η•benzotriazol-2-yl)_4hydroxyphenyl]propionic acid-2-ethylhexyl ester, 3_[3_t-butyl_5_(5_gas_211 benzobisoxazol-2-yl )-4-hydroxyphenyl]propionic acid octyl ester, 3_[3_t-butyl_5_(5_gas-2H-benzotriazole·2_*)_4_hydroxyphenyl]propionic acid methyl ester, 3-[ 2-(2'-hydroxyphenyl) such as 3_t-butyl-5-(5-aero-2-indole-benzotriazol-2-yl)-4-hydroxyphenyl]propionic acid and the like Benzotriazine, etc. As the light stabilizer, for example, bis(2,2,6,6-tetramethyl-4-piperidyl) phthalate or bis(2,2,6 succinate) can be cited. , 6_tetramethyl-4(piperidinyl) ester, bis(1,2,2,6,6-pentamethyl-4-piperidinyl) sebacate, adipic acid bis(N-xin Oxy-2,2,6,6-tetramethyl-4-pyrylene) vinegar, azelaic acid bis(n-benzyloxy-2,2,6,6-tetradecyl-4-piperidine Ester, azelaic acid bis(N-cyclohexyloxy-2,2,6,6-tetradecyl- 4-piperidinyl)ester, 2-(3,5-di-t-butyl-4-hydroxyl-based)-2-butylmalonic acid bis(ι,2,2,6,6-pentaquinone Benzyl-4-piperidinyl) vinegar, I2-bis(3,5~--second butyl_4_ mercaptobenzyl)_2_butylmalonic acid bis(l-acryloyl-2,2, 6,6-tetradecyl-4-piperidinyl), bis(n-6 6-pentamethyl-4-piperidinyl) sebacate, _2,2,6,6-tetramethyl methacrylate Methyl 4-4_bite ester, 4-[3-(3,5-di-t-butyl-4-hydroxyphenyl)propenyloxy (3,5-di-t-butyl _4_ Hydroxyphenyl)propoxycarbonyl)ethyl]_2,2,6,6 four 149241.doc •20· 201114824 methyl-bite, 2-methyl-2·(2,2,6,6_four Alkyl-4(piperidinyl)amino N-(2,2,6,6-tetradecyl-trinyl) propylamine, ι,2,3,4_ 丁烧四曱酉文四(2,2 ,6,6-tetramethyl-4-piperidinyl), 1,2,3,4-butanetetracarboxylic acid tetrakis(1,2'2,6,6-pentamethyl-4-piperidinyl a mixed esterified ester of butane tetracarboxylic acid with 1,2,2,6,6-pentamethyl-4-piperidinol and hydrazine-tridecyl alcohol; 1,2,3,4-butane IV Mixed esterified product of formic acid with 2,2,6,6-tetramethyl-4-piperidinol and tridecane, 1,2,3,4-butanetetracarboxylic acid and hydrazine , 2,2,6,6-pentamethyl-4-piperidinol and 3,9-bis(2-hydroxy-ι,ι-didecylethyl)indole-tetraoxaspiro[5.5] eleven Mixed admixture of alkane, butane tetracarboxylic acid and 2,2,6,6-tetradecyl-4-piperidinol and 3,9-bishydroxyindole dimethylethyl)-2,4,8, Mixed esterified product of 10-tetraoxaspiro[5.5]undecane, dimethyl succinate and 1-(2-hydroxyethyl)-4-hydroxy-2,2,6,6-tetramethylper Polycondensate of pyridine, poly[(6-carboline-1,3,5-trinyl-2,4-diyl)((2,2,6,6-tetramethyl-4-piperidinyl) Imino)hexamethylene ((2,2,6,6-tetradecyl-4-piperidyl)imido)], poly[(6-(1,1,3,3-tetra) Methylbutyl)imido-_ι,3,5-trisole-2,4-diyl((2,2,6,6-tetramethyl-4-piperidinyl)imido)hexa Methyl ((2,2,6,6-tetradecyl-4-piperidyl)imino)), ν, Ν,-bis(2,2,6,6-tetramethyl-4-piperidin Polycondensate of hexyl)hexanediamine with 1,2-dibromoethane, ν,Ν,,4,7-tetra[4,6-bis(Ν-butyl-Ν-(2,2,6) ,6-tetramethyl-4-0 bottom 0-amino)amino-1,3,5-trin-2-yl]-4,7-diazanonane-1,10-diamine, team 1^,4-tri[4,6-double (Ν-丁-Ν-(2,2,6,6-tetramethyl-4-piperidinyl)amino)-1,3,5-trin-2-yl]-4,7-diazadecane 〗,! 〇_Diamine, ν, Ν,, 4,7-tetra[4,6-bis(Ν-butyl-N-(l,2,2,6,6-pentamethyl-4-piperidinyl) Amino)-1,3,5-trin-2-yl]-4,7-diazadecane-!,! 〇_Diamine, ν,Ν',4- 149241.doc •21· 201114824 Three [4,6-bis(N-butyl_N_(1,2,2,6,6-pentamethyl_4 piperazine) a hindered amine light stabilizer such as a fixed alkyl)amino)-1,3,5-tripent-2-yl]-4,7-diazadecane], a quinone diamine, and the like; --Nitro-indenyl, β-diphenylacrylic acid ethyl acetonate, α_gas-based _p, p-diphenyl acrylate isooctyl vinegar, α-曱 oxycarbonyl cinnamic acid brewing, α_敦基_β_ Methoxy-p-methoxycinnamic acid m decyl-p-oxy cinnamic acid butyl vinegar, cx-methoxyl-p-methoxy lauric acid methyl hydrazine, N, methoxyhistyl I nitrovinyl Acrylic vinegar-based light stabilizer such as 2-methyl decadoline and the like; 2,2,-thiobis-[called 丄仏 tetramethyl butyl phantom (10) recording complex, disulfide a nickel-based light stabilizer such as a dibutyl sulfamate, a salt of a single county, a mixture of a salt and a mixture thereof, etc.; 4,4'-dioctyloxyxanthene, 2, 2, _Diethoxyoxalatine aniline, 2,2·-dioctyloxy-5,5i-di-t-butyl hydrazinyl, 2,2,-docosyloxy-5,5i -di-t-butyl decyl aniline, 2-ethoxylated 2,-ethyl Phytoaniline, N,N,-bis(3-didecylaminopropyl) oxazamide, 2-ethoxy-3-5t-butyl-2'-ethoxy oxime, 2_ Oxalylamine light stabilizer such as ethoxy_5,4,-di-t-butyl-2'-ethyl oxalic acid anilide and the like; 2,4,6-tris(2- 4--4-octyloxyphenyl yu, % tritonic, 2_(2·hydroxy-4-octyloxyphenyl)_4,6-bis(2,4-dimercaptophenyl)_1,3,5 _三11 well, 2_[2,4-dihydroxyphenyl_4,6-bis(2,4-dimethylphenyl)-1,3,5-three'• well, 2,4-double ( 2-hydroxy-4-propoxyphenyl)_6-(2,4-didecylphenyl) 十^-three tillage, 2-(2-hydroxy-4-octyloxyphenyl)-4,6 - bis(4-methylphenyl)-l,3,5-tris 149241.doc -22- 201114824 tillage, 2-(2-hydroxy-4-dodecyloxyphenyl)-4,6-double (2,4-dimethylphenyl)-1,3,5-three tillage, 2-[2-hydroxy-4-(2-hydroxy-3-butoxypropoxy)phenyl]-4, 6-bis(2,4-dimethylphenyl)_ι,3,5-three tillage, 2-[2-hydroxy-4-(2-hydroxy-3-octyloxypropoxy)phenyl]- 2-(2-Phenylphenyl)-1,3,5-three tillage of 4,6-bis(2,4-dimercaptophenyl)= 0 well and other mixtures thereof A light stabilizer or the like. As the stabilizer, in addition to the above, for example, N,N-dihydroxylamine, N,N-diethylhydroxylamine, N,N-dioctylhydroxylamine, N, N-dilauryl hydroxylamine, N,N-di-tetradecylhydroxylamine, N,N•di-hexadecylhydroxylamine, N,N-di-octadecylhydroxylamine, N_ten Hydroxylamines such as hexaalkyl hydrazine-octadecylhydroxylamine, N-heptadecyl-N-octadecylhydroxylamine, and the like, and the like. Examples of the lubricant include an aliphatic hydrocarbon such as paraffin wax and wax, a higher aliphatic acid having 8 to 22 carbon atoms, a metal of a higher aliphatic acid having 8 to 22 carbon atoms (A, Ca, Mg, and Mn). An aliphatic alcohol having a carbon number of 8 to 22, a polyglycol, an ester of a higher fatty acid having a carbon number of 4 to 22, an aliphatic monohydric alcohol having a carbon number of 4 to 18, a higher aliphatic decylamine having a carbon number of 8 to 22, and a polyfluorene Oxygen oil, rosin derivatives, and the like. Among these additives other than the compound (I) and the compound (I), the phenol-based antioxidant, the phosphorus-based antioxidant, the sulfur-based antioxidant, the ultraviolet absorber, and the hindered amine-based light stabilizer are preferably used. . As a better phenolic antioxidant, it can be exemplified by 2,6·di-third

Bis-(4-methyl-6-tris, 2,4-dioctylthio-2,2'-thiobis(6-t-butylphenol), 2,2·-methylenetetrabutyl Phenol), 2,2'-methylenebis(4_ethyl_6_I49241.doc • 23·201114824 tributylphenol), 2,2·-methylenebis[4-methyl-6 -(α-decylcyclohexyl)phenol], 2,2·-methylenebis(4-mercapto-6-cyclohexylphenol), 2,2'-arylene di(4,6-di- Tert-butylphenol), 2,2·-ethylenebis(4,6-di-t-butylphenol), 4,4'-methylenebis(6-tert-butyl-2-methyl Phenol), 4,4,-methylenebis(2,6-di-t-butylphenol), 4,4,-butylenebis(3-mercapto-6-tert-butylphenol), 1,1-bis(4-hydroxyphenyl)cyclohexane, 1,1-bis(5-t-butyl-4-hydroxy-2-methylphenyl)butane, ι,ΐ,3-three (5-Tertibutyl-4-hydroxy-2-mercaptophenyl)butane, ethylene glycol butyrate bis[3,3-bis-3,-tert-butyl-4.-hydroxy stupyl] Ester; 2,4,6-bis(3,5-mono-t-butyl-4-phenoxy)-1,3,5-trisole, tris(4-tert-butyl-3-hydroxy- 2,6-Dimethylbenzyl)isocyanurate, double (3,5• Di-t-butyl-4-hydroxybenzyl)isocyanurate, tris[2-(3,5,2-di-tert-butyl-4'-hydroxycinnaxyloxy)ethyl]isocyanuric acid Acid ester, diethyl 3,5-di-t-butyl-4-hydroxybenzylphosphonate, 3,5-di-t-butyl-4-yl-4-hydroxybenzylphosphonic acid di-n-octadecyl Calcium salt of ester, 3,5•di-t-butyl-4-yl-hydroxyl-phosphonic acid monoester, 3-(3,5-di-t-butyl-4-yl-hydroxyphenyl)propionic acid八烧基西曰, 新戊烧四基四(3 5 - - -r λ ^ «· U,:)-一-second butyl _4· basal cinnamic acid vinegar), thiodiethylidene Double s __potential -π * , (,5·--second butyl-4-trans cinnamate), 1,3,5-dimethyl- 2,4,6_=f3 5 - @ - τ··» I 4* —(·3,5-a-second butyl_4_hydroxyl group) benzene, 3,6-dioxa octamethylene soil (3,5_a- Second butyl _4_hydroxy cinnamic acid brewing), hexamethylene bis (3,5-one-second-butyl-4-hydroxycinnamate), triethylene glycol bis (5-di-but| Λ monobutyl-4-hydroxy-3-indolyl cinnamate _ [2-(3-(3-tert-butyl-4-yloxy)-methyl-based propyloxy)-hydrazine, 1-two Methyl ethyl]-2,4,8,10-tetraoxaspiro[5 5]11 courtyard 'N,N,·double [3_(3,,5,_ 149241.doc -24. 201114824 one _Secondyl -4-4'-transphenylyl propyl]], ν, Ν'-bis[3-(3,5·-_ tert-butyl-4'-hydroxyphenyl)propanoid The hexamethylenediamine or the like may be used alone or in combination of two or more. Examples of the antioxidants to be filled are: tris(nonylphenyl) sulfite, tris(2,4·di-t-butylphenyl) phosphite, and distearyl pentaerythritol. Phosphate ester, bis(2,4-di-tert-butylphenyl) pentaerythritol dilinaric acid, bis(2,4-di-t-butyl-6-fylphenyl) pentaerythritol dilutite, Bis(2,6-di-t-butyl-4-ylphenyl)pentaerythritol di-hisic acid, tetrakis(2,4•di-t-butylphenyl)_4,4,_di-extension Phenyl di sulphite, methyl bis(4'6-di-t-butylphenyl)_2-ethylhexyl sulphate, 2,2,-ethylene bis (4,6_ Di-t-butylphenyl) fluoro-disc vinegar, bis(2,4-di-t-butyl-6-methylphenyl)ethyl phosphite, 2<2'6-three_ Tributylphenyl)-5-ethyl·5-butyl-caffeylphosphorane, Nizide-based [triethyl·tris(3,3.,5,5,winter tert-butyl), The bisphenyl-2,2,-diyl phthalate ester or the like may be used alone or in combination of two or more. As a preferred ultraviolet absorber, for example, salicylic acid phenylacetic acid, salicylic acid-4-t-butylphenyl ester, 3,5丨_ - _坌__ second butyl-4,-hydroxyl group Benzene-one =, _di-t-butyl benzene vinegar, salicylic acid, 4_t-octyl benzene vinegar, 2,4·= benzophenone (tetra), 2 _ methoxy benzoquinone嗣, 2-Phenyl-4_octyloxy-benzoyl-, 2,2|-di-based _4•-methyl benzene, bis (5-benzene: fluorenyl-4)-2-methoxy Phenyl)), 2,2,,4, tetramethylenediphenyl 2 M2-transpy-5-methylphenyl)benzotrimide, 2_(3,5,·di-third Soil-based phenyl)benzotriene, 2_(5,_t-butyl-2-, phenyl-phenyl) 149241.doc -25· 201114824 Benzotriazole, 2-(2'-hydroxy-5' -T-octylphenyl) benzotriazole, 2·(3_t-butyl-2-hydroxy-5.nonylphenyl)chlorobenzotriazole, 2(3,_second butyl-2 ,-hydroxy-5,-t-butylphenyl) benzotriazole, 2(2,-hydroxy-4,-octyloxyphenyl)benzotriazole, 2-(3·,5,_2 -third amyl 2,-hydroxyphenyl)benzotriazole, 2-[2,-hydroxy-3.,5,_bis(α,α-dimethylphenyl)phenyl In the case of benzotriazole or the like, these may be used alone or in combination of two or more. As a better light stabilizer, for example, bis(2,2,6,6-tetramethyl-4-piperidinyl) sebacate and bismuth azelaic acid (1, 2, 2, 6, 6) may be mentioned. • pentamethyl piperidinyl) ester, bis(indolyl-octyloxy-2,2,6,6-tetradecyl-4-piperidinyl) sebacate, bismuth-benzyloxy Base 2,2,6,6-tetramethyl-4(piperidinyl) ester, bismuth-cyclohexyloxy-2,2,6,6-tetradecyl-4-piperidine Stuffed, 2_(3,5-di-t-butyl-4-hydroxybenzyl)-2-butyronic acid bis(mg/·pentamethyl_4_piperidinyl) ester, 2,2_ Bis(3,5-di-t-butyl-4-ylhydroxybenzyl)_2_butylmalonic acid bis(1-propenyl-2-,2,6,6-tetradecyl-4-piperidinyl Ester, bis(2,2,6'6-tetramethyl-4-isopiperidinyl) succinate, 2,2,6,6-tetramethylpiperidine methacrylate, 4-[3 -(3,5·di-t-butyl-4-hydroxyphenyl)propanoxy]-l-[2-(3-(3,5-di-t-butyl-4-yl-hydroxyphenyl) ) propionyloxy)ethyl]_2,2,6,6-tetramethylpiperidine, 2-methyl-2-(2,2,6,6-tetramethyl-4 piperidinyl)-amino- N-(2,2,6,6-tetramethyl_4_piperidinyl)propanamide, i,2,3,4-butanetetracarboxylic acid tetrakis(2,2,6,6-tetramethyl _4_ Pyridyl) 1,1,3,4-butyrolidinetetracarboxylic acid tetrakis(1,2,2,6 6-pentamethyl-4-piperidinyl), 1,2,3,4-butane Mixture of tetracarboxylic acid with pentadecyl- 4 piperidinol and decyl tridecyl alcohol, 12,3,4-butane tetradecanoic acid and 2,2,6,6-tetradecyl-4-Break Mixed ester of sterol and 1_tridecanol, i, 2,3,4 butane IV 149241.doc -26- 201114824 W with 1,2,2,6,6-pentamethyl as the bottom. Alcohol and 3,9_bis(2_ylidylethyl)-2,4,8,10-tetraoxaspiro[5.5] decocted mixed vinegar, 1,2,3,4-butyl Burning tetracarboxylic acid spot 296/^17„37<*-,,,6,6-tetramethyl·4_N-steryl alcohol and 3,9·bis(2-I-based 1,1 - f-ethyl) _2,4,8,1〇_tetraoxaspiro[5.5] eleven-burning full..., succinic acid dimethyl vinegar and hydrazine...ethyl)·peric acid base-2'2,6,6-four a polycondensate of piperidine, a phthalocyanine group, a 3,5-trisole-2,4-diyl) ((2,2,6,6-tetramethyl) group) Methylene ((2,2,6-fine methyl) group)), (1, Mt. tetramethylbutyl)-1,3,5-tri-p--2 4-- I, "., - soil) ((2,2,6,6·tetradecyl-4-pyro-based) sub, base) hexa-f-group ((2,2,6,6•tetramethyl) For example, the method for producing the thermoplastic polymer composition of the present invention may, for example, be a compound (1) prepared by kneading a thermoplastic polymer. a compound (8) and a method of an additive as needed; and, for example, a method comprising the steps of: mixing a compound (1) Compound (9) and an additive as needed to prepare a compound to be mixed with a thermoplastic P: the dispersibility of the compound (1) and the compound i in the step 1 of the stabilizer group TO obtained in the step In view of the above, the latter method is preferred. The step of producing a stabilizer composition is also exemplified by the method exemplified in the method for producing a compound described later. ^ ^ ^ π 〇 The step in the main plastic polymer is given == Ming, for example, the following method can be cited: after the thermoplastic polymerization agent composition is dry blended, using uniaxial or multiaxial extrusion 149241.doc -27- 201114824 Machine melt-kneading, and then extrusion to obtain particles of a thermoplastic polymer composition; for example, a solution obtained by dissolving a stabilizer composition in a solvent such as cyclohexane is added to a thermoplastic polymer after polymerization is completed In the polymer solution, the solvent is removed. The obtained thermoplastic polymer composition can be directly supplied to the molding machine in a molten state without being cooled, and formed. It is not particularly limited, and for example, a molding method such as an injection molding method, an extrusion molding method, an extrusion blow molding method, an injection blow molding method, or a biaxial stretching blow molding method can be used. A thermoplastic polymer molded article comprising the thermoplastic polymer composition of the present invention. Examples of the obtained thermoplastic polymer molded body include a bobbin, a connector, a switch, a resistor: a member, a plug, a relay, and a capacitor case. Fuse, motor, baked phase printed circuit board, IC (Integrated circuh) manufacturing equipment, lamps and other electronic parts; exhaust trim (airgarnish), hood ventilation: (hood vent), distributor cover (4) secret coffee ), exhaust gas control valves and other automotive parts '· gears, cams and other mechanical parts; bottom plate and other clocks and clocks =; bottom cover, lens barrel, lever (lever) and other camera parts; line pumping ((10)) and other entertainment products; Machine casing, lighting wiring device, membrane, bottle, f-dimensional, septic tank, toilet, bathtub, unh bath, water phase, ship, medicine box, tube, corrugated board Plates, coatings, decorative panels, the electrical components of the sealing material, resin concrete and the like. The stabilizer composition of the present invention contains the compound (I) and the compound (II). The stabilizer composition of the present invention is preferably contained in a weight ratio of 99.9:0.1 to 5:95 (compound (1) compound (11)). The compound (I) and the compound (II), 149241. doc -28- 201114824 more preferably contain the compound (1) and the human (II) in a weight ratio of 98:2 to 10:90. , . The stabilizer composition of the present invention can be directly used as a processing stabilizer for thermoplastic polymers. Further, the above additives may be contained within a range that does not impair the effects of the present invention. As a method for producing the stabilizer composition of the present invention, for example, a compound (1), a compound (11), and optionally the above-mentioned additives are used in a Henschel mixer or a super mixer. a method of mixing a mixer such as a high-speed mixer; for example, a method of further extruding a mixture containing the compound (I) and the compound (11); for example, containing the compound (1) and the compound (π) The mixture is further subjected to a method of stirring granulation or the like. EXAMPLES Hereinafter, the present invention will be described in more detail by way of examples and comparative examples. Unless otherwise stated, parts and % refer to the weight basis. Further, the melt flow rate is described as MFR (Melt Flow Rate). Example 1 (Production of Stabilizer Composition) 6_[3_(3_Tertiary-4-4-hydroxymethylphenyl)propanyl]-2,4,8,10-tetra- as Compound (1) Third butyl dibenzo[d,f][1,3,2]: phosphine cycloheptane ["Sumilizer (registered trademark) Gp" manufactured by Sumitomo Chemical Co., Ltd., the following s And a mixture of 0 to 12 parts of mannitol as a compound was used to manufacture a stabilizer composition. Example 2 (Production of Stabilizer Composition) In Example 1, the amount of the compound (Γ) was set to 〇12 parts, and the amount of 149241.doc -29·201114824 mannitol was set to 0.48 parts. A stabilizer composition was produced in the same manner as in Example 除 except for the above. Example 3 (Production of Thermoplastic Polymer Composition) 100 parts of a styrene-butadiene block copolymer produced as a thermoplastic polymer, and a stabilizer composition obtained in Example 1 were dry blended. After that, the obtained resin composition was subjected to kneading extrusion using a single-axis extruder (manufactured by Tanabe Plastics Co., Ltd., VS30-28 extruder) having a screw diameter of 3 Torr at 230 C and a screw rotation speed of 50 rpm. The strands were obtained, and the strands were cut by a pelletizer to obtain pellets of the thermoplastic polymer composition. Example 4 (Production of Thermoplastic Polymer Composition) In Example 3, the stabilizer composition obtained in Example 2 was used instead of 6 parts of the stabilizer composition obtained in Example ,, except for 6 parts. Granules of the thermoplastic polymer composition were obtained in the same manner as in Example 3 except for the above. Comparative Example 1 A thermoplastic 4-combination combination was obtained in the same manner as in Example 3 except that the compound (1,) was used in place of 6 parts of the stabilizer composition obtained in Example 丨. Particles of matter. Test Example 1 (Processing Stability Test) For each of the particles obtained in Examples 3 and 4 and Comparative Example, a retention test was carried out as an evaluation of the workability at the time of extrusion addition: In the case of JIS κ 721 〇, the inside of the cylinder of the melt indexer (U17-E14011, manufactured by Techn 〇 8 company) was set to 70 C, and the thermoplastic polymer composition was retained in the cylinder for 3 minutes, 149,241. .doc 201114824 Determines the MFR at a load of 2.16 kg. The results are shown in Table 1. The larger the value of ^1^, the more excellent the processing stability under static conditions. The so-called processing stability and the rate of increase in Table 1 are obtained by the following formula. (Processing stability improvement rate) = (MFR value measured in the example - MFR value measured in Comparative Example 2) / MFR value measured in Comparative Example 1 X 1 〇〇 [Table 1] Compound 〇〇 parts [weight Ratio] mannitol fraction [weight ratio] MFR value-----1 Processing stability improvement rate Example 3 0.48 [8]. 0.12 [2] 12.3 284.3 Example 4 0.12 [2] 0.48 [8] 13.2 312.5 Comparative Example 1 0.60 [10] 0.00 [0] 3.2 to 0 Example 5 (Production of Stabilizer Composition) A compound composition was prepared by mixing 0.1 part of the compound (Ι-Α) with 1 part of mannitol 〇. Things. Example 6 (Production of Stabilizer Composition) A compound composition was prepared by mixing 0.1 part of a compound (Ι·Α) with 1 part of sorbitol 〇. Example 7 (Production of Thermoplastic Polymer Composition) The entire amount of the ethylene/vinyl alcohol copolymer [Kuraray (manufactured by Kuraray)) and the comparative composition obtained in Example $ was dry-blended, and the obtained The resin composition used had a screw diameter of 3. The shaft single-axis extruder (4), such as the Plastics company, VS3〇_28 extruder), was extruded at 23 〇, screw speed 50 rpm to obtain the strands, and the strands were cut by a granulator. I49241.doc -31- 201114824 A granule of a thermoplastic polymer composition is obtained by break. Example 8 (Production of Thermoplastic Polymer Composition) In Example 7, the stabilizer composition obtained in Example 4 was used instead of the stabilizer composition obtained in Example 5, and Example 7 was additionally used. The particles of the thermoplastic polymer composition are likewise obtained. Comparative Example 2 A thermoplastic polymer composition was obtained in the same manner as in Example 7 except that in the same manner as in Example 7, except that the compound (!) was used instead of the total amount of the stabilizer composition obtained in Example 5. Particles. Test Example 2 (Processing Stability Test) Each of the pellets obtained in Examples 7 and 8 and Comparative Example 2 was subjected to a retention MFR test as a workability evaluation during the operation at the time of extrusion processing. The test was carried out by setting the thermoplastic polymer composition in the material of the melt indexer (L217-E14011, manufactured by Techno Seven Co., Ltd.) in accordance with JIS 〇 721 '. In the cylinder, the MFR at a load of 2.16 kg was measured, and then the thermoplastic polymer composition was retained in the tank for 30 minutes, and the MFR at a load of 2.16 kg was measured. In the shackles - recognition, , ·. The value of the so-called MFR variation rate in Table 2 is the value obtained by the following formula. In the case of the ethylene-vinyl alcohol copolymer, the smaller the MFR variation rate, the better the processability. MFR variation rate (%) = (MFR value after retention for 30 minutes - MFR value before retention) Absolute value / MFR value before retention 149 149241.doc -32· 201114824 [Table 2] Compound (Γ) Copies [ Weight ratio] Compound (II) Parts [weight ratio] MFR value MFR variation rate (%) after retention for 30 minutes before retention Example 7 0.1 [100] Mannitol 0.01 [10] 12.2 8.8 28 Example 8 0.1 [100] Sorbitol 0.01 [10] 12.2 9.8 19 Comparative Example 2 0.1 [100] 0 [0] 14.5 35.7 147 Industrial Applicability The thermoplastic polymer composition of the present invention is excellent in processing stability, and thus can be suitably used. It is used in food packaging containers, daily sundries, etc. 149241.doc •33·

Claims (1)

201114824 VII. Patent application scope: 1. A stabilizer composition containing the compound represented by formula (I): [wherein, R, R, R4 and r5 each independently represent a hydrogen atom, a carbon number of a burnt group, a ring-burning group of an anisotropic number of 5 to 8, a pyridyl group having a carbon number of 6 to 12, and a carbon number of 7 ~ 12 aralkyl or phenyl, r3 independently represents a hydrogen atom or a carbon number of 1 to 8 'X' represents a single bond, a ruthenium atom or a valence group represented by the formula (ι_ι): Rlc 丨Η In the formula, R represents a hydrogen atom, an alkyl group of a carbon number of 8 or a ring of a carbon number of 5 to 8). A represents an alkylene group having a carbon number of 2 to 8 or a divalent group represented by the formula (1-2). : ^ — C —R7" (1—2) Ο (wherein R7 represents a single bond or an alkylene group having a carbon number of 1 to 8, and * represents a bond to the oxygen atom side) Y, Any one of Z represents a hydroxyl group, a carbon group having 1 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms or an aralkyloxy group having 7 to 12 carbon atoms, and the other one represents a hydrogen atom or a carbon number of 1 to Alkyl group of 8] and compound represented by formula (II): I49241.doc 201114824 CnH2ll + 2〇n (II) (wherein n represents an integer of 4 to 12). 2. The stabilizer composition according to claim 1, wherein the compound represented by the formula (1) is 6-[3-(3•tert-butyl-4-hydroxy-5,methylphenyl)propoxyb. (7) T-butyl dibenzo (IV) (1) (10) diphosphorus cycloheptane 3. A stabilizer composition as claimed in the formula (8), wherein the compound 2 is lozenol, iditol, galactitol, sorbitol, Taritol or mannitol. Shi. The stabilizer composition of the luxury item 2, wherein the helmet is μ μ, and the compound represented by the formula (11). , sugar alcohol, iditol, semi-library _ alcoholic holly sugar, sorbitol, talose or mannitol. 5. A thermoplastic polymer which is determined by the formula 杳 U σ , έ has a thermoplastic polymer and a compound represented by the formula ( Ι 所 表示 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋The amount of the formula (II) is 0 001 ·; the total weight is 0.001 to 3 parts by weight relative to the thermoplastic polymer 100. 6. The polymer composition of claim 5 is 6-[3-η· lean-'. The compound represented by the formula (1) is dibutyl-4- via its oxime «base]_2,4,8'1〇-four _Third-based fluorenylphenyl)propane. —Butyl-benzo[d,f][l,3,2]diphosphorus cyclohepta-7. The polymer composition of claim 5 is albendol, μ compound represented by formula (II). Sugar alcohol, Fengshen 丨p alcohol or mannitol. Cellulose, sorbitol, talose 149241.doc 201114824 8. The polymer composition of claim 6, wherein the eight compounds represented by Yin (H) are allolitol, μ』 ▲ Yidu Sugar alcohol, galactitol, sorbitol, talitol or mannitol. 9. Very thermoplastic 10, - a method for producing a composition of the composition, ... a step of mixing the stabilizer composition of claim 1 with heat at a temperature of 2 °. The use of the stabilizer composition of claim 1 for stabilizing the processing of the thermal polymer. 149241.doc 201114824 IV. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbolic symbol of the representative figure is simple: 5. If there is a chemical formula in this case, please reveal the best indication of the characteristics of the invention. Chemical formula: (none) 149241.doc