TW201114821A - Thermoplastic polymer composition - Google Patents

Thermoplastic polymer composition Download PDF

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TW201114821A
TW201114821A TW99121885A TW99121885A TW201114821A TW 201114821 A TW201114821 A TW 201114821A TW 99121885 A TW99121885 A TW 99121885A TW 99121885 A TW99121885 A TW 99121885A TW 201114821 A TW201114821 A TW 201114821A
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butyl
bis
compound
formula
alcohol
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TW99121885A
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Chinese (zh)
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Yoshikazu Kimura
Tetsuya Shintaku
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Sumitomo Chemical Co
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/13Phenols; Phenolates
    • C08K5/134Phenols containing ester groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/05Alcohols; Metal alcoholates
    • C08K5/053Polyhydroxylic alcohols

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Abstract

A stabilizer composition which comprises n-octadecyl-ss-(4'-hydroxy-3',5'-di-t-butylphenyl)propionate, 3,9-bis[2-{3-(3-t-butyl-4-hydroxy-5-methylphenyl)propionyloxy}-1,1-dimethylethyl]-2,4,8,10-tetraoxaspiro[55]undecane or pentaerythritol tetrakis[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate] together with allitol, iditol, galactitol, sorbitol, talitol or mannitol.

Description

201114821 六、發明說明: 【發明所屬之技術領域】 本發明係關於一種熱塑性聚合物組人物 【先前技術】 熱塑性聚合物由於透明性優異且耐衝擊性亦良好 也用於食品包m、日用雜貨品。作為熱塑性聚A 物組5物,已知有含有熱塑性聚合物及式⑴所表 二 物者: 13201114821 VI. Description of the Invention: [Technical Field] The present invention relates to a thermoplastic polymer group [Prior Art] Thermoplastic polymer is excellent in transparency and impact resistance, and is also used for food package m, daily groceries Product. As the thermoplastic polyA group 5, it is known that a thermoplastic polymer and a compound of the formula (1) are included: 13

⑴ (式中,R及R2分別獨立表示氫原子或碳數卜6之烷基,X 表示可含有雜原子及/或環狀基之碳數價的醇殘 基,m表示1〜4之整數;其中所謂醇殘基,表示自醇之〇ή 去掉Η後之基)(專利文獻丨〜3)。 [專利文獻1]曰本專利特開昭59_25826號公報 [專利文獻2]美國專利3644482號說明書 [專利文獻3]美國專利3330859號說明書 【發明内容】 熱塑性聚合物存在由於成形加工時之熱或氧等之作用而 加工穩定性惡化的問題。 為解決該課題,本發明者們進行了研究’結果發現了加 149242.doc 201114821 工穩定性進一步提昇之熱塑性聚合物組合物。 亦即’本發明係提供以下之[i]〜[10]。 t1]·—種穩定劑組合物,其含有式(1)所表示之化合物:(1) (wherein R and R2 each independently represent a hydrogen atom or an alkyl group of carbon number 6; X represents an alcohol residue having a carbon number which may contain a hetero atom and/or a cyclic group, and m represents an integer of 1 to 4; The term "alcohol residue" means a group derived from the oxime of the alcohol (Patent Document 丨 ~ 3). [Patent Document 1] Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. The problem of deterioration in processing stability due to the action of the like. In order to solve this problem, the present inventors conducted research and found that a thermoplastic polymer composition having further improved stability was found in 149242.doc 201114821. That is, the present invention provides the following [i] to [10]. T1]--stabilizer composition containing the compound represented by formula (1):

(式中,R及R2分別獨立表示氫原子或碳數i〜6之烷基,χ 表不可含有雜原子及/或環狀基之碳數丨〜24之η價的醇殘 土 m表示1〜4之整數;其中所謂醇殘基,表示自醇之〇Η 去掉Η後之基)、及 式(2)所表示之化合物: (2) ^·ηΗ2η + 2Οη (式中,η表示4〜12之整數)。 [2] .,如[1]之穩定劑組合物,其中式⑴所表示之化合⑹ β-(4,&-3,,5’_二-第三丁基苯基)丙酸正十八烧基酿 雙[2-{3-(3-第三丁基_4•經基_5·甲基苯基)丙醯氧基) 四_(3,5…第三丁基經基笨基)丙酸醋]。 [3] ·如[1]之穩定劑組合物,复中_ 阿洛糖醇、艾杜糖醇、半乳糖醇:所表不之化合物』 礼糖知、山梨糖醇、塔羅糖醇s 149242.doc 201114821 甘露糖醇。 [4】.如[2]之穩定劑組合物,其中 阿洛撼r· + 飞(2)所表不之化合物為 打洛搪醇、艾杜糖醇、 甘露糖醇。 山-糖醇、塔羅糖醇或 Μ ·種熱塑性聚合物組合物,其 如往 /、3有熱塑性聚合物及 〇月·"項1之穩定劑組合物,且式 ⑵ 奶1式⑴所表不之化合物與式 )斤表7F之化合物的合計重量 量份為。顧〜3重量份Ζ 對於熱塑性聚合物_重 [6]·如[5]之聚合物組合物,皇中 β_(4,_…〜第:丁/苯Si示之化合物為 3,9Hm )丙酸正十八烷基醋、 又((第二丁基-4-羥基-5· f展芏A、 I U- m ^ ^ ^ Τ暴本基)丙醯氧基}_ ,一甲土乙基]-2,4,8,1〇-四氧雜螺[5 四[3-(3 5-_筮- 烷或季戊四醇 ’第二丁基羥基苯基)丙酸酯]。 [7] .如[5]之聚合物組合物,其 阿洛辘艘叶“ > 式(2)所表示之化合物為 甘露糖醇。 山4糖醇、塔羅糖醇或 [8] .如[6]之聚合物組合物,其 阿洛糖醇、艾杜糖醇、半乳糖醇、二=示之化合物為 甘露糖醇。 山-搪•、塔羅糖醇或 [9] ♦一種熱塑性聚合物組合 塑性聚合物中混合如⑴至其包括於熱 步驟。 項之穩定劑組合物之 [10] ·—種如[1]至[4]中任—頂 係用於使熱塑性聚合物加工合物之用途,其 149242.doc 201114821 【實施方式】 以下’就本發明加以詳細說明。 本發明之熱塑性聚合物組合物含有熱塑性聚合物、上述 式(1)所表示之化合物(以下,有時記載為化合物(1))、及上 述式(2)所表示之化合物(以下,有時記載為化合物(2))。 化合物(1)中,作為碳數1〜6之烷基,可列舉:甲基乙 基、正丙基、正丁基、正戊基、正己基等碳數丨〜6之直鏈 狀烷基;異丙基、異丁基、第三丁基、異戊基、第三戊 基、第三己基等碳數3〜6之分枝狀烷基;環戊基、環己基 等碳數3〜6之環烷基。 作為碳數1〜24之1價之醇殘基,可列舉:甲醇、乙醇、 正丙醇、異丙_、正丁醇、第三丁醇、正己醇、正辛醇、 正癸醇、正十二烷醇、正十四烷醇、正十六烷醇、正十八 烷醇之殘基。 作為碳數1〜24之2價之醇殘基,可列舉:乙二醇、丨,2_丙 二醇、1,3-丙二醇、丁二醇 ’ ^ 1,5-戊一醇、1>6•己二 醇、1,8-辛二醇、^0-癸二醇 十一烷二醇、1,14- + 四院二醇、U6-十六院二醇、二乙二醇、三乙二醇、Η 曱基-2-經基乙基一。,氧雜螺Μ]十—燒 可列舉甘油之殘基。 "T列舉赤藻糖醇、季戊 β_(5-第三丁基羥基_3_ 作為碳數1〜24之3價之醇殘基 作辱碳數1〜2 4之4價之醇殘基 四醇之殘基。 作為化合物(1 ),例如可列舉. 149242.doc 201114821 甲基苯基)丙酸與甲醇、乙醇、辛醇、十八烷醇、乙二 醇、1,3-丙二醇、M_ 丁二醇、。。己二醇、1>9-壬二醇、 新戊二醇、二乙二醇、硫代乙二醇、螺二醇、三乙二醇、 季戊四醇、三(羥基乙基)異氰尿酸酯、N,N,_雙(羥基乙基) 草醯胺、3-硫雜十一烷醇、3-硫雜十五烷醇、三甲基己二 醇、三羥曱基丙烷、4-羥基甲基-1_磷雜_2,6,7_三氧雜雙環 [2,2,2]辛烷及其等之混合物等一元或多元醇之酯; β-(3,5-二-第三丁基_4_羥基苯基)丙酸與甲醇、乙醇、辛 醇、十八烷醇、乙二醇、i,3_丙二醇、Μ•丁二醇、^-己 二醇、1,9-壬二醇、新戊二醇、二乙二醇、硫代乙二醇、 螺二醇、三乙二醇、季戊四醇、三(經基乙基)異氛尿酸 S曰Ν,Ν -雙(羥基乙基)草醯胺、3_硫雜十一烷醇、硫雜 十五烷醇、三甲基己二醇、三羥甲基丙烷、4-羥基曱基-卜 麟雜_2,6,7-三氧雜雙環[2,2,2]辛烧及其等之混合物等一元 或多元醇之酯; β-(3’5-二環己基_4_羥基苯基)丙酸與甲醇、乙醇、辛 醇L十八烷醇、乙二醇、1>3·丙二醇、Μ_τ二醇、丨,6-己 一醇、1,9_壬二醇、新戊二醇、二乙二醇、硫代乙二醇、 螺二醇、三乙二醇、季戊四醇、三⑽基乙基)異氣尿酸 S曰N,N -雙(羥基乙基)草醯胺、3_硫雜十一烷醇、弘硫雜 十五烧醇、三甲基己二醇、三經甲基丙烧、4·經基甲基小 構雜-2’6,7-三氧雜雙環[2,2,2]辛烧及其等之混合物等一元 或多元醇之酯。 作為化合物(1),較好的是β-(4,-羥基-3,,5,-二-第三丁基 149242.doc 201114821 苯基)丙酸正十八烷基酯(BASF公司製造,irganox(註冊商 才承)1076,以下有時記作化合物(1-1))、3,9-雙[2-{3·(3-第 三丁基-4·羥基_5_甲基苯基)丙醯氧基}-1,卜二曱基乙基]_ 2,4,8’10-四氧雜螺[5·5]十一燒(住友化學製造, SUmihZer(註冊商標)GA-80 ’以下有時記作化合物(1·2))或 季戊四醇四[3_(3,5_二·第三丁基心羥基苯基)丙酸 S曰](BASF公司製造,Irgan〇x(註冊商標)ι〇ι〇,以下有時記 作化合物(1-3))。 化。物(2)中,11為4〜12之整數,較好的是5〜8,更好 是6 〇 〇 m (2) 們戈口口J yij ' 7〜爪哪π '節K概醇Η 拉伯糖醇、木糖醇、核糖醇、阿洛糖醇 '艾杜糖醇、半 糖醇、山梨糖醇、塔羅糖醇、甘露糖醇、倭勒米糖醇、 梨糖醇、辛糖醇等碳數4〜12之糖醇。 作為化合物(2),可為㈣(心价仏,(wherein R and R2 each independently represent a hydrogen atom or an alkyl group having a carbon number of i to 6; and the enthalpy of the carbon residue of the carbon atom number 丨 24 of the hetero atom and/or the cyclic group m 24 is represented by 1 An integer of ~4; wherein the alcohol residue is a group derived from the oxime of the alcohol, and the compound represented by the formula (2): (2) ^·ηΗ2η + 2Οη (wherein η represents 4~ 12 integer). [2]. The stabilizer composition according to [1], wherein the compound represented by the formula (1) (6) β-(4, & -3,, 5'-di-t-butylphenyl)propionic acid is ten Octa-based bis-[2-{3-(3-tert-butyl-4)-based 5-methylphenyl)propenyloxy) _(3,5...t-butyl phenyl group Base) propionic acid vinegar]. [3] · Stabilizer composition as in [1], complex _ allotitol, iditol, galactitol: a compound of the formula 』 糖糖, sorbitol, talitol 149242.doc 201114821 Mannitol. [4] The stabilizer composition according to [2], wherein the compound represented by aloin r·+ fly (2) is dalitol, iditol, mannitol. A sucrose-alcoholic, talitol or hydrazine-type thermoplastic polymer composition, such as a thermoplastic polymer and a stabilizer composition of 〇月·“1, and a formula (2) milk 1 (1) The total weight fraction of the compound represented by the formula and the compound of the formula 7F is. 〜3 parts by weight Ζ For the polymer composition of thermoplastic polymer _heavy [6]·[5], the medium-sized β_(4, _...~: butyl/benzene Si compound is 3,9Hm) Acid octadecyl vinegar, ((2nd butyl-4-hydroxy-5· f 芏A, I U- m ^ ^ ^ Τ 本 base) propyl oxime}_ , 一甲土乙Base]-2,4,8,1〇-tetraoxaspiro[5 tetra[3-(3 5-_筮-alkane or pentaerythritol 't-butylhydroxyphenyl)propionate]. [7] . The polymer composition according to [5], wherein the aloin leaf " > the compound represented by the formula (2) is mannitol. Mountain 4 sugar alcohol, talitol or [8]. [6] The polymer composition, which is a lolitol, iditol, galactitol, bis-display compound is mannitol. Shan-搪•, talitol or [9] ♦ a thermoplastic polymer combination The plastic polymer is mixed as in (1) to be included in the thermal step. [10] of the stabilizer composition, such as any of [1] to [4], is used to make a thermoplastic polymer processing compound. Use, 149242.doc 201114821 [Embodiment] The following is a detailed description of the present invention. The thermoplastic of the present invention The polymer composition contains a thermoplastic polymer, a compound represented by the above formula (1) (hereinafter, referred to as a compound (1)), and a compound represented by the above formula (2) (hereinafter, it may be described as a compound) (2)) In the compound (1), examples of the alkyl group having 1 to 6 carbon atoms include a carbon number of 甲基~6 such as methylethyl, n-propyl, n-butyl, n-pentyl or n-hexyl. a linear alkyl group; a branched alkyl group having a carbon number of 3 to 6 such as an isopropyl group, an isobutyl group, a tert-butyl group, an isopentyl group, a third pentyl group or a third hexyl group; a cyclopentyl group and a cyclohexyl group; And a cycloalkyl group having a carbon number of 3 to 6. Examples of the alcohol residue having a monovalent number of carbon atoms of 1 to 24 include methanol, ethanol, n-propanol, isopropanol, n-butanol, tert-butanol, and hexanol. a residue of an alcohol, n-octanol, n-nonanol, n-dodecanol, n-tetradecyl alcohol, n-hexadecanol or n-octadecyl alcohol as a divalent alcohol residue having a carbon number of 1 to 24 Examples thereof include ethylene glycol, hydrazine, 2-propylene glycol, 1,3-propanediol, butanediol '^ 1,5-pentanol, 1>6•hexanediol, 1,8-octanediol, ^ 0-nonanediol undecanediol, 1,14- + The diol of the diol, the U6-hexadecyl diol, the diethylene glycol, the triethylene glycol, the fluorenyl-2-ylaminoethyl group, the oxaspiro[,] decyl can be exemplified by the glycerol residue. "T enumerates erythritol, pentaerythritol β_(5-t-butylhydroxy_3_ as a carbon residue of a carbon number of 1 to 24 as an alcohol residue having a carbon number of 1 to 2 4 The residue of the tetraol. As the compound (1), for example, 149242.doc 201114821 methylphenyl)propionic acid and methanol, ethanol, octanol, stearyl alcohol, ethylene glycol, 1,3-propanediol, M_ butanediol,. . Hexanediol, 1>9-decanediol, neopentyl glycol, diethylene glycol, thioethylene glycol, spirodiol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate ,N,N,_bis(hydroxyethyl) oxazinamide, 3-thiaundecyl alcohol, 3-thiapentadecanol, trimethylhexanediol, trihydroxydecylpropane, 4-hydroxyl An ester of mono- or polyhydric alcohol such as methyl-1_phosphonium-2,6,7-trioxabicyclo[2,2,2]octane and mixtures thereof; β-(3,5-di- Tributyl-4-hydroxyphenyl)propionic acid with methanol, ethanol, octanol, stearyl alcohol, ethylene glycol, i, 3-propylene glycol, hydrazine, butanediol, ^-hexanediol, 1,9 -decanediol, neopentyl glycol, diethylene glycol, thioethylene glycol, spirodiol, triethylene glycol, pentaerythritol, tris(ylethyl)isouric acid S曰Ν, Ν-double ( Hydroxyethyl) oxalylamine, 3- thiaundecyl alcohol, thiopentadecanol, trimethyl hexane diol, trimethylolpropane, 4-hydroxyindenyl-brinze-2,6 , an ester of a monohydric or polyhydric alcohol such as a mixture of 7-trioxabicyclo[2,2,2]octane and the like; β-(3'5-dicyclohexyl-4-hydroxyphenyl)propionic acid and Alcohol, ethanol, octanol L stearyl alcohol, ethylene glycol, 1>3·propylene glycol, Μ_τ diol, hydrazine, 6-hexitol, 1,9-nonanediol, neopentyl glycol, diethylene glycol Alcohol, thioethylene glycol, spirodiol, triethylene glycol, pentaerythritol, tris(10)-ethyl) isophthalic acid S曰N,N-bis(hydroxyethyl)glucamine, 3_thia eleven Alkanol, chlorinated pentyl alcohol, trimethyl hexane diol, trimethyl propyl ketone, 4 · benzyl carbaryl-2'6,7-trioxabicyclo[2,2, 2] An ester of a monohydric or polyhydric alcohol such as a mixture of octyl alcohol and the like. As the compound (1), β-(4,-hydroxy-3,5,-di-t-butyl 149242.doc 201114821 phenyl)-n-octadecyl propionate (manufactured by BASF Corporation, Irganox (registered by registrar) 1076, sometimes referred to as compound (1-1)), 3,9-bis[2-{3·(3-tert-butyl-4.hydroxy-5-methylbenzene) )) 醯 醯 醯 } -1 , 卜 卜 卜 卜 ] ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( 80 ' or less is sometimes referred to as compound (1·2)) or pentaerythritol tetra [3_(3,5-di-t-butyl-hydroxyphenyl)propionic acid S曰] (manufactured by BASF Corporation, Irgan〇x (registered) Trademark) ι〇ι〇, sometimes referred to as compound (1-3)). Chemical. In the object (2), 11 is an integer of 4 to 12, preferably 5 to 8, more preferably 6 〇〇m (2), Gekoukou J yij '7~claw, π', K. Laprimitol, xylitol, ribitol, allotitol 'iditol, hemi-sugar alcohol, sorbitol, talitol, mannitol, sultanol, sorbitol, sim A sugar alcohol having a carbon number of 4 to 12 such as a sugar alcohol. As compound (2), it can be (four) (heart price,

/1〇 七灰體)、L v01s〇mer,左旋體)等光學活性 / 體)等非光學活性h Μ為DL體(消〕 作為化合物(2),較好的是以Fish 洛糖醇、艾杜糖醇、半乳糖醇、山梨糖醇=下之〗 露糖醇等福6之糖醇,更好 ^知心 术椐%或甘露糖醇。 149242.doc 201114821 LI Π II Π UI Π 1_1 ΠNon-optical activity h such as /1〇7 gray body, L v01s〇mer, left-handed body, etc. h Μ is DL body (absence) as compound (2), preferably is sorbitol, Iditol, galactitol, sorbitol = the next 〗 〖 Sugar alcohol such as sugar alcohol, better ^ intimate 椐% or mannitol. 149242.doc 201114821 LI Π II Π UI Π 1_1 Π

ch2oh ΗΟ— U —Η Πΐι Π ur\ UI 1 II MU 1_| II /-Μ 1 Π c UI 1 )H2OHCh2oh ΗΟ— U —Η Πΐι Π ur\ UI 1 II MU 1_| II /-Μ 1 Π c UI 1 )H2OH

ch2oh H— U〇 —OH II mVJ ΗΠ II II MU H— c II —OH :H2OHCh2oh H— U〇 —OH II mVJ ΗΠ II II MU H— c II —OH :H2OH

-OH OH -OH -OH CH2〇H 阿洛糖醇 艾杜糖醇 半乳糖醇 ch2〇h ch2〇h Η— HO— Η— Η—-OH OH -OH -OH CH2〇H Alditol Alditol galactitol ch2〇h ch2〇h Η— HO— Η—Η—

—OH —Η —OH —OH—OH —Η —OH —OH

CH2〇H ch2oh HO— LJr\ —H II MU Llpk I 1 1」 rlU UI Π r\\-i Π ( Un 〕h2oh 塔羅糖醇 HO HO Η Η -Η Ή ΟΗ ΟΗ 山梨糖醇 CH2〇H 甘露糖醇 化合物(2)只要直接使用市售品即可。又,化合物(2)可 為無水物,或亦可為水合物。 作為熱塑性聚合物,可列舉:聚乙烯系樹脂(高密度聚 乙稀(HD-PE,High density Polyethylene)、低密度聚乙稀 (LD-PE,Low density Polyethylene)、直鏈狀低密度聚乙稀 (LLDPE,Linear Low density Polyethylene)、乙烯-乙烯醇 共聚物(EVOH,Ethylene-Vinylalcohol copolymer)、乙烯-丙烯酸乙酯共聚物、乙烯-乙酸乙烯酯共聚物(EVA, Ethylene-Vinyl acetate copolymer)等)、聚丙稀系樹脂(結晶 性丙烯均聚物、丙烯-乙浠無規共聚物、丙烯-α-稀烴無規 共聚物、丙烯-乙稀-α-稀烴共聚物、包含丙稀均聚物成分 149242.doc 201114821 或主要含有丙稀之共聚物成分及丙稀與乙烯及/或心烯烴 之共聚物成分的聚丙烯系嵌段共聚物等)、甲基戊烯聚合 物、聚苯乙烯系樹脂(聚(對甲基苯乙烯)、聚(α_甲基苯乙 烯)等聚苯乙烯 '丙烯腈_苯乙烯共聚物、丙烯腈-丁二烯_ 笨乙稀共聚物(ABS,Acrylonitrile Butadiene Styrene copolymer)、特殊丙烯酸系橡膠-丙烯腈-苯乙烯共聚物、 丙烯腈-氣化聚乙烯-苯乙烯共聚物等)、聚丁二烯系樹脂 (聚丁二稀橡膠(BR ’ Butadiene rubber)、苯乙烯-丁二烯共 t 物(SBR ’ Styrene-Butadiene rubber)、苯乙稀-丁二烯嵌 段共聚物(SBS ’ Styrene-Butadiene block copolymer)、經 BR或SBR或SBS改質而成之耐衝擊性聚苯乙烯(HI_ps, High Impact P〇lyStyrene)等)、氣化聚乙烯、聚氣丁二烯、 氣化橡膠、聚氯乙烯、聚偏二氯乙烯、曱基丙烯酸系樹 脂、氟樹脂、聚縮醛、接枝化聚苯醚樹脂、聚苯硫醚樹 脂、聚胺基曱酸酯、聚醯胺、聚酯樹脂(例如聚對苯二曱 酸乙二酯、聚對苯二甲酸丁二酯等)、聚乳酸樹脂(pLA, Polylactic acid)、聚碳酸酯、聚丙烯酸酯、聚砜、聚醚醚 酮、聚醚砜、芳香族聚酯樹脂、鄰苯二曱酸二烯丙醋預聚 物、聚矽氧樹脂、1,2-聚丁二烯、聚異戊二烯、丁二稀/丙 烯腈共聚物、乙烯-甲基丙烯酸甲酯共聚物等,就成形加 工性良好之觀點而言’較好的是聚乙烯系樹脂、聚丙歸系 樹脂、聚苯乙烯系樹脂及聚丁二烯系樹脂,更好的是聚乙 烯系樹脂及聚丁二烯系樹脂。 本發明之熱塑性聚合物組合物中之化合物(1)與化合物 149242.doc -10- 201114821 (2)之合計重量相對於熱塑性聚合物ι〇〇重量份較好的是 3重量伤’更好的是〇·〇2〜2重量份,進而好的是 曰02 1重里伤,進而更好的是〇 〇5〜〇 8重量份,特別好的 = 0.08〜0.7重量份’化合物⑴與化合物⑺之重量比較好的 疋化〇物⑴·化合物(2)=99.9:0.1〜5:95,更好的是 98:2〜10:90 〇 本發明之熱塑性聚合物組合物亦可於不損及本發明之效 果之範圍内含有添加劑(化合物⑴及化合物⑺除外)。作為 k添加劑例如可列舉:抗氧化劑、紫外線吸收劑、光穩 定劑、金屬減活劑、成核劑、潤滑劑、抗靜電劑、阻燃 刎、填充劑、顏料、無機填充劑等。 此處作為酚系抗氧化劑,例如可列舉:2,6-二-第三丁 基-4-甲基苯酚、2,4,6_三-第三丁基苯酚、2,6二·第三丁基 苯齡、2-第三丁基_4,6_二甲基苯紛、2,6_二.第三丁基冬乙 基本酴、2,6-二-第三丁基_4_正丁基苯紛、以-二-第三丁 基-4-異丁基苯紛、2,6_二環戊基冰甲基苯紛、2如甲基環 己基)-4,6·二甲基苯酚' 2,6_二-十八烷基-4-甲基苯酚、 2,4’6-三環己基苯酚、2,6_二第三丁基·"氧基甲基苯 酚、2,6-二-壬基甲基苯酚、2,4_二甲基,甲基十一 烷基-1’-基)苯酚、2,4_二甲基·6_〇·1基十七烷基十-基)苯 酚、2,4-二甲基_6_(广甲基十三院•基)苯齡及其等之混 合物等烧基化單齡; 2,4_二辛硫Μ基+第三丁基苯醅、2,4-二辛硫基甲基· 6-f基苯酚、2,4-二辛硫基甲基冬乙基苯酚、2,6-二-十二 149242.doc • 11 - 201114821 烷硫基甲基-4-壬基苯酚及其等之混合物等烧硫基甲基苯 酚; 2,2,-亞甲基雙(4-甲基-6-第三丁基苯酚)、2,2·-亞曱基雙 (4-乙基-6-第三丁基苯酚)、2,2·-亞曱基雙[4-甲基-6-(α-甲 基環己基)苯酚]、2,2,-亞甲基雙(4-甲基-6-環己基苯酚)、 2,2’-亞曱基雙(4-甲基-6-壬基苯酚)、2,2·-亞曱基雙(4,6-二-第三丁基苯酚)、2,2,-亞乙基雙(4,6-二-第三丁基苯酚)、 2,2'-亞乙基雙(4-異丁基-6-第三丁基苯酚)、2,2’-亞曱基雙 [6-(〇1-甲基苄基)-4-壬基苯酚]、2,2'-亞甲基雙[6-(〇1,〇1-二甲 基苄基)-4-壬基苯酚]、4,4’-亞甲基雙(6-第三丁基-2-甲基 苯酚)、4,4’-亞曱基雙(2,6-二-第三丁基苯酚)、4,4·-亞丁基 雙(3-曱基-6-第三丁基苯酚)、1,1-雙(4-羥基苯基)環己烷、 M-雙(5-第三丁基-4-羥基-2-甲基苯基)丁烷、2,6-雙(3-第 三丁基-5-曱基-2-羥基苄基)-4-曱基苯酚、1,1,3-三(5-第三 丁基-4-羥基-2-甲基苯基)丁烷、1,1-雙(5-第三丁基-4-羥 基-2-甲基苯基)-3-正十二烷基酼基丁烷、乙二醇丁酸雙 [3,3-雙-31-第三丁基-4’-羥基苯基]酯、雙(3-第三丁基-4-羥 基-5-曱基苯基)二環戊二烯、對笨二曱酸雙[2-(3·-第三丁 基_2'_經基- 5'-甲基卞基)-6-第三丁基-4-甲基苯基]醋、1,1_ 雙(3,5-二甲基-2-羥基苯基)丁烷、2,2-雙(3,5-二-第三丁基-4-羥基苯基)丙烷、2,2-雙(5 -第三丁基_4_羥基-2-甲基苯 基)_4·正十二烧基魏基丁烧、1,1,5,5 -四(5 -第三丁基-4-經 基-2-曱基苯基)戊烷及其等之混合物等亞烷基雙酚及其衍 生物; 149242.doc -12· 201114821 4-羥基月桂醯替苯胺、4-羥基硬脂醯替苯胺、N-(3,5-二-第三丁基-4-羥基苯基)胺基甲酸辛酯及其等之混合物等醯 基胺基苯酌·衍生物; 2,2'-硫代雙(6-第三丁基苯酚)、2,2·-硫代雙(4-甲基-6-第 三丁基苯酚)、2,2,-硫代雙(4-辛基苯酚)、4,4,-硫代雙(2-曱 基-6-第三丁基苯酚)、4,4’-(2,6-二曱基-4-羥基苯基)二硫醚 等羥化硫代二苯醚; 3,5,3’,5’-四-第三丁基_4,4'·二羥基二苄基醚、4-羥基- 3,5-二曱基苄基巯基乙酸十八烷基酯、三(3,5_二-第三丁 基-4-羥基节基)胺、二硫代對苯二甲酸雙(4_第三丁基_3_羥 基-2,6-二曱基苄基)酯、雙(3,5_二-第三丁基—4_羥基苄基) 硫謎、3,5-二-第三丁基_4-羥基苄基巯基乙酸異辛酯及其 等之混合物等〇_苄基衍生物、N_苄基衍生物、s•苄基衍生 物等苄基衍生物; 2’4-雙(正辛硫基)_6_(4_羥基_3,5_二第三丁基苯胺基)_ 1,3,5-三畊、2-正辛疏基_4,6_雙(4_羥基_3,5_二_第三丁基苯 胺基)-1,3,5-三啼、2-正辛硫基_4,6_雙(4-羥基_3,5-二-第三 丁基苯氧基)-1,3,5·三畊、2,4,6_三(3,5_二-第三丁基_4_苯 氧基)-1,3,5-三畊、三(4_第三丁基_3_羥基_2,6_二甲基苄基) 異氰尿酸酯、三(3,5_二_第三丁基_4_羥基苄基)異氰尿酸 酯、2,4,6-三(3,5-二-第三丁基_4_羥基苯基乙基广丨乂^三 啡、2,4,6-三(3’5_二-第三丁基_4_經基苯基丙基三 啡、三(3,5-二環己基-4·羥基苄基)異氰尿酸酯、三[2_ Ο。’-二-第三丁基_4,_羥基桂皮醯氧基)乙基]異氰尿酸酯及 149242.doc -13- 201114821 其等之混合物等三**井衍生物; —酸二•十八烧基CH2〇H ch2oh HO— LJr\ —H II MU Llpk I 1 1” rlU UI Π r\\-i Π ( Un 〕h2oh talitol HO HO Η Η -Η Ή ΟΗ ΟΗ sorbitol CH2〇H nectar The sugar alcohol compound (2) may be a commercially available product. The compound (2) may be an anhydride or may be a hydrate. As the thermoplastic polymer, a polyethylene resin (high density polyethylene) may be mentioned. HD-PE (High-density Polyethylene), Low Density Polyethylene (LD-PE), Linear Low-density Polyethylene (LLDPE), Ethylene-Vinyl Alcohol Copolymer (LLDPE) EVOH, Ethylene-Vinylalcohol copolymer), ethylene-ethyl acrylate copolymer, Ethylene-Vinyl acetate copolymer (EVA, etc.), polypropylene resin (crystalline propylene homopolymer, propylene-B) a random copolymer, a propylene-α-dilute hydrocarbon random copolymer, a propylene-ethylene-α-dilute hydrocarbon copolymer, a propylene-containing homopolymer component 149242.doc 201114821 or a copolymer component mainly containing acryl Copolymer of propylene with ethylene and/or heart olefin Polystyrene acrylonitrile such as a polypropylene-based block copolymer, a methylpentene polymer, a polystyrene resin (poly(p-methylstyrene), or a poly(α-methylstyrene) _styrene copolymer, acrylonitrile-butadiene_ABS, Acrylonitrile Butadiene Styrene copolymer, special acrylic rubber-acrylonitrile-styrene copolymer, acrylonitrile-gasified polyethylene-styrene Copolymer, etc., polybutadiene resin (BR ' Butadiene rubber), styrene-butadiene rubber (SBR ' Styrene-Butadiene rubber), styrene-butadiene Segment copolymer (SBS ' Styrene-Butadiene block copolymer), impact modified polystyrene (HI_ps, High Impact P〇lyStyrene) modified by BR or SBR or SBS, gasified polyethylene, gasified Diene, gasified rubber, polyvinyl chloride, polyvinylidene chloride, mercapto acrylic resin, fluororesin, polyacetal, grafted polyphenylene ether resin, polyphenylene sulfide resin, polyamino phthalate Polyamide, polyester resin (for example, polyethylene terephthalate, Polybutylene terephthalate, etc., polylactic acid resin (pLA, polylactic acid), polycarbonate, polyacrylate, polysulfone, polyether ether ketone, polyether sulfone, aromatic polyester resin, phthalic acid Diene propylene glycol prepolymer, polyoxyn epoxide, 1,2-polybutadiene, polyisoprene, butyl diene/acrylonitrile copolymer, ethylene methyl methacrylate copolymer, etc. From the viewpoint of good moldability, it is preferably a polyethylene resin, a polyacryl resin, a polystyrene resin, and a polybutadiene resin, more preferably a polyethylene resin and a polybutadiene. Resin. The total weight of the compound (1) and the compound 149242.doc -10- 201114821 (2) in the thermoplastic polymer composition of the present invention is preferably 3 weights by weight relative to the weight portion of the thermoplastic polymer ι. It is 2 to 2 parts by weight of 〇·〇, and further preferably 曰02 1 heavy wound, and more preferably 〇〇5 to 〇8 parts by weight, particularly preferably = 0.08 to 0.7 parts by weight of 'compound (1) and compound (7) The weight of the bismuth compound (1)·the compound (2)=99.9:0.1 to 5:95, more preferably 98:2 to 10:90 〇 The thermoplastic polymer composition of the present invention can also be used without damaging the present invention. The additive (except compound (1) and compound (7)) is contained in the range of the effect of the invention. Examples of the k additive include an antioxidant, an ultraviolet absorber, a photostabilizer, a metal deactivator, a nucleating agent, a lubricant, an antistatic agent, a flame retardant, a filler, a pigment, an inorganic filler, and the like. Here, examples of the phenolic antioxidant include 2,6-di-tert-butyl-4-methylphenol, 2,4,6-tri-tert-butylphenol, and 2,6-2·third. Butyl benzene, 2-tert-butyl_4,6-dimethylbenzene, 2,6-di. tert-butyl winter ethyl guanidine, 2,6-di-t-butyl _4_ n-Butylbenzene, -di-tert-butyl-4-isobutylbenzene, 2,6-dicyclopentyl glacial benzene, 2, such as methylcyclohexyl)-4,6·2 Methylphenol '2,6-di-octadecyl-4-methylphenol, 2,4'6-tricyclohexylphenol, 2,6-di-t-butyl-"oxymethylphenol, 2,6-di-decylmethylphenol, 2,4-dimethyl,methylundecyl-1'-yl)phenol, 2,4-dimethyl-6-〇·1 base Alkyl decyl phenol, 2,4-dimethyl _6 _ (polymethyl sylylene) base, and other mixtures thereof, such as a single alkyl group; 2,4_dioctylthiol +T-butylphenylhydrazine, 2,4-dioctylthiomethyl-6-f-phenol, 2,4-dioctylthiomethyl-t-ethylphenol, 2,6-di-twelve 149242. Doc • 11 - 201114821 Alkylthiomethyl-4-nonylphenol and mixtures thereof, etc., thiomethylphenol; 2,2,- Bis(4-methyl-6-tert-butylphenol), 2,2--indenylbis(4-ethyl-6-tert-butylphenol), 2,2·-indenylene [4-Methyl-6-(α-methylcyclohexyl)phenol], 2,2,-methylenebis(4-methyl-6-cyclohexylphenol), 2,2'-arylene (4-methyl-6-nonylphenol), 2,2·-indenylene bis(4,6-di-tert-butylphenol), 2,2,-ethylenebis (4,6- Di-tert-butylphenol), 2,2'-ethylenebis(4-isobutyl-6-tert-butylphenol), 2,2'-arylene-bis[6-(〇1- Methylbenzyl)-4-nonylphenol], 2,2'-methylenebis[6-(〇1,〇1-dimethylbenzyl)-4-nonylphenol], 4,4' -methylenebis(6-tert-butyl-2-methylphenol), 4,4'-fluorenylene bis(2,6-di-t-butylphenol), 4,4·-butylene Bis(3-mercapto-6-t-butylphenol), 1,1-bis(4-hydroxyphenyl)cyclohexane, M-bis(5-t-butyl-4-hydroxy-2-methyl Phenyl)butane, 2,6-bis(3-tert-butyl-5-mercapto-2-hydroxybenzyl)-4-nonylphenol, 1,1,3-tris(5-third Butyl-4-hydroxy-2-methylphenyl)butane, 1,1-bis(5-tert-butyl-4- 2-methylphenyl)-3-n-dodecyldecylbutane, ethylene glycol butyrate bis[3,3-bis-31-tert-butyl-4'-hydroxyphenyl]ester , bis(3-t-butyl-4-hydroxy-5-mercaptophenyl)dicyclopentadiene, bis(2-(3·-tert-butyl-2'-yl) - 5'-Methyl-mercapto)-6-t-butyl-4-methylphenyl]acetate, 1,1-bis(3,5-dimethyl-2-hydroxyphenyl)butane, 2, 2-bis(3,5-di-t-butyl-4-hydroxyphenyl)propane, 2,2-bis(5-t-butyl-4-yl-2-methylphenyl)_4· Alkylene bisphenols such as dodecyl sulphate, 1,1,5,5-tetrakis(5-t-butyl-4-yl-2-ylphenyl)pentane and mixtures thereof Its derivative; 149242.doc -12· 201114821 4-hydroxylauric acid aniline, 4-hydroxystearyl aniline, N-(3,5-di-t-butyl-4-hydroxyphenyl)amino group a mercaptoamine-based derivative such as octyl formate and a mixture thereof; 2,2'-thiobis(6-tert-butylphenol), 2,2·-thiobis(4-methyl -6-tert-butylphenol), 2,2,-thiobis(4-octylphenol), 4,4,-thiobis(2-mercapto-6-tributyl) Hydroxy thiodiphenyl ether such as phenol), 4,4'-(2,6-diamidino-4-hydroxyphenyl) disulfide; 3,5,3',5'-tetra-third Base 4,4'-dihydroxydibenzyl ether, octadecyl 4-hydroxy-3,5-dimercaptobenzyl decylacetate, tris(3,5-di-t-butyl-4- Alkyl hydroxy) amide, bis(4_t-butyl-3-hydroxy-2,6-dimercaptobenzyl) dithioterephthalate, bis(3,5-di-t-butyl) -4_hydroxybenzyl) sulfonic acid, 3,5-di-t-butyl- 4-hydroxybenzyl mercaptoacetic acid isooctyl ester and mixtures thereof, etc. 〇 benzyl derivative, N benzyl derivative a benzyl derivative such as a s-benzyl derivative; 2'4-bis(n-octylthio)_6_(4-hydroxy-3,5-di-t-butylanilino)_ 1,3,5-three Tillage, 2-n-octyl-based _4,6_bis(4-hydroxy-3,5-di-t-butylanilino)-1,3,5-triazine, 2-n-octylthio- 4 ,6_bis(4-hydroxy-3,5-di-t-butylphenoxy)-1,3,5·three tillage, 2,4,6_three (3,5_di-third Base_4_phenoxy)-1,3,5-three tillage, tris(4_t-butyl-3-hydroxy-2,6-dimethylbenzyl)isocyanurate, three (3 , 5_di-t-butyl _4_ hydroxy Benzyl)isocyanurate, 2,4,6-tris(3,5-di-t-butyl-4-hydroxyphenylethyl sulphate), 2,4,6-three (3'5-di-t-butyl-4-yl-p-phenylphenylpropyltrimorph, tris(3,5-dicyclohexyl-4.hydroxybenzyl)isocyanurate, tris[2_oxime. '-Di-t-butyl-4-4,_hydroxycinnaxyloxy)ethyl]isocyanurate and 149242.doc -13- 201114821 a mixture of such three ** well derivatives; Eighteen base

烷基毓基乙酯、2,2·雙(3,5-二-第三丁基_4 -經基苄基)丙二 2,2-雙(3,5-二-第三丁基-2-羥基苄基)丙二酸二·. 酯、2-(3·第三丁基-4-羥基-5-曱基苄基)丙二酸二 酸雙[4-(1,1,3,3-四曱基丁基)苯基]酯及其等之混合物等羥Alkyl mercaptoethyl ester, 2,2·bis(3,5-di-t-butyl-4-yl-benzylidene)propane 2,2-bis(3,5-di-t-butyl- 2-hydroxybenzyl)malonic acid di-ester, 2-(3·t-butyl-4-hydroxy-5-mercaptobenzyl)malonic acid diacid bis[4-(1,1,3 , 3-tetradecylbutyl)phenyl]ester and mixtures thereof, etc.

苯、M-雙(3,5_二_第三丁基_4-羥基苄基)_2,3,5,6_四曱基 笨、2,4,6-三(3,5_第三丁基·4_羥基苄基)苯酚及其等之混合 物等芳香族羥基苄基衍生物; 3’5 - — -第三丁基-4 -經基苄基膦酸二曱酿、3,5_二_第二 丁基-4-羥基苄基膦酸二乙酯、3,5_二_第三丁基羥基苄 基膦酸二-十八烷基酯、5_第三丁基_4_羥基_3_曱基节基膦 酸二-十八烷基酯、3,5_二-第三丁基_4_羥基苄基膦酸單酯 之鈣鹽及其等之混合物等苄基膦酸酯衍生物; 3,5---第三丁基-4 -經基苯基乙酸與甲醇、乙醇、辛 醇、十八垸醇 '乙二醇、1,3-丙二醇、1,4_ 丁二醇、丨,6-己 二醇、1,9-壬二醇、新戊二醇、二乙二醇、硫代乙二醇、Benzene, M-bis(3,5-di-t-butyl-4-hydroxybenzyl)_2,3,5,6-tetradecyl, 2,4,6-tris (3,5_third An aromatic hydroxybenzyl derivative such as butyl 4-hydroxybenzyl) phenol and the like; 3'5 - - tert-butyl-4 - benzyl phenylphosphonic acid diterpene, 3, 5 _Di-t-butyl-4-hydroxybenzylphosphonic acid diethyl ester, 3,5-di-t-butylhydroxybenzylphosphonic acid di-octadecyl ester, 5_t-butyl _4 a benzyl group such as a di-octadecyl ester of hydroxyl_3_fluorenylphosphonic acid, a calcium salt of a 3,5-di-t-butyl-4-ylhydroxybenzylphosphonic acid monoester, and the like Phosphonate derivative; 3,5---t-butyl-4-p-phenylacetic acid and methanol, ethanol, octanol, octadecyl alcohol 'ethylene glycol, 1,3-propanediol, 1,4_ Butylene glycol, hydrazine, 6-hexanediol, 1,9-nonanediol, neopentyl glycol, diethylene glycol, thioethylene glycol,

酷、Ν,Ν’-雙(經基乙基)草醯胺、3_硫雜十一烷醇、%硫雜 十五烧醇、三曱基己二醇、三羥曱基丙烷、4_羥基曱基―卜 峨雜-2,6,7-三氧雜雙環[2,2,2]辛烷及其等之混合物等一元 或多元醇之酯; 149242.doc -14- 201114821 AN’-雙[3-(3,,5,-二-第三丁基-4,-經基苯基)丙醯基]肼、 Ν,Ν'-雙[3-(3·,5'_二-第三丁基-4,-羥基苯基)丙醯基]己二 胺、Ν,Ν’-雙[3_(3,,5,-二-第三丁基_4,·羥基苯基)丙醢基]丙 二胺及其等之混合物等β-(3,5-二-第三丁基-4-羥基苯基)丙 酸之醯胺等;及 α-生育酚、β_生育酚、γ_生育酚、δ-生育酚及其等之混 合物等生育酚等。 作為對苯二酚及烷基化對笨二酚之抗氧化劑,例如可列 舉.2,6---第三丁基-4-甲氧基苯紛、2,5-二-第三丁基對 笨一酚、2,5-二-第三戊基對苯二酚、2,6-二苯基-4-十八烷 氧基苯酚、2,6-二-第三丁基對苯二酚、2,5_二_第三丁基_ 4-羥基苯曱醚、硬脂酸(3,5_二·第三丁基_4•羥基苯基)酯、 己一酸雙(3,5-二·第三丁基_4-羥基苯基)酯及其等之混合物 等》 作為硫系抗氧化劑’例如可列舉:3,3,_硫代二丙酸二月 桂酯、3,3’-硫代二丙酸十三烷基酯、3,3,-硫代二丙酸二肉 且寇酯、3,3’-硫代二丙酸二硬脂酯、3,3,_硫代二丙酸月桂 基硬脂酯、新戊烷四基四(3·月桂基硫代丙酸酯)等。 作為磷系抗氧化劑,例如可列舉:亞磷酸三苯酯、亞磷 酸三(壬基苯基)醋、亞磷酸三(2,4_二_第三丁基苯基)酯、 亞镇酸三月桂醋、亞填酸三.十人炫基i旨、二硬脂基季戊 四醇一亞磷日、二異癸基季戊四醇二亞磷酸酯、雙(2,4_ 一第一丁基苯基)季戊四醇二亞磷酸酯、雙二-第三丁 基_6_曱基苯基)季戊四醇二亞磷酸酯、雙(2,6-二-第三丁 I49242.doc •15· 201114821 基-4-曱基笨基)季戊四醇二亞磷酸酯、雙(2,4,6_三-第三丁 基苯基)季戊四醇二亞磷酸酯、三硬脂基山梨糖醇三亞磷 酸醋、四(2,4-二-第三丁基苯基)_4,4,_二伸苯基二亞膦酸 西旨、2,2,-亞甲基雙(4,6_二_第三丁基苯基)_2_乙基己基亞鱗 酸酯、2,2,-亞乙基雙(4,6-二·第三丁基笨基)氟亞磷酸酯、 雙(2,4-二-第三丁基·6_曱基苯基)乙基亞磷酸酯、雙(2,4_ 二-第三丁基-6-曱基苯基)曱基亞磷酸酯、2_(2,4,6_三-第二 丁基苯基)-5-乙基-5-丁基-1,3,2-氧磷雜環己烷、2,2,,2"_氮 川基[二乙基-二(3,3’,5,5 -四-第三丁基聯苯基二 基)亞磷酸酯及其等之混合物等。 作為紫外線吸收劑,例如可列舉:水楊酸苯酯、水揚酸 4-第三丁基苯酯、3,,5,_二-第三丁基·4,_羥基苯甲酸2,4_二_ 第三丁基苯酯、水楊酸4-第三辛基苯酯、雙(4_第三丁基苯 甲醯基)間苯二酚、苯甲醯基間苯二酚、3,,5,_二-第三丁基_ 4’-羥基苯曱酸十六烷基酯、3,,5,_二_第三丁基_4,·羥基苯曱 酸十八烷基酯、3’,5,-二-第三丁基_4,_羥基苯曱酸2•甲基_ 4,6-二-第三丁基苯基酯及其等之混合物等水揚酸酯衍生 物; 2,4-二羥基二苯曱酮、2_羥基_4_曱氧基二苯甲酮、2_羥 基-4-辛氧基二笨甲酮、2,2,_二羥基_心甲氧基二苯甲酮、 雙(5-苯曱醯基_4_羥基_2•甲氧基苯基)曱烷、2,2,,4,4,四羥 基二苯甲酮及其等之混合物等2_羥基二笨甲酮衍生物; 2-(2-羥基-5-甲基苯基)笨并三唑、2·(3,,5,_二-第三丁基_ 21-羥基苯基)苯并三唑、2·(5,_第三丁基_2,_羥基苯基)苯并 149242.doc 16 - 201114821 二唑、2-(2’-羥基-5,-第三辛基苯基)笨并三唑、2·(3_第三 丁基-2-羥基-5-曱基苯基)·5_氯苯并三唑、2_(3,_第二丁基_ 21-羥基-51-第三丁基苯基)苯并三唑、2_(2,_羥基_4,_辛氧基 苯基)苯并三唑、2-(3,,5,-二-第三戊基_2,_羥基苯基)苯并三 坐2-[2 -羥基-3',5’-雙(α,α-二甲基苄基)苯基]·2Η_苯并三 唑、2-[(3,-第三丁基_2,_經基苯基)_5,_(2_辛氧基羰基乙基) 苯基]-5_氯苯并三嗤、2_[3’·第三丁基_5,_[2_(2•乙基己氧基) 幾基乙基]-2’-經基苯基]-5-氣苯并三唾、2_[3,·第三丁基_ 21-羥基-5'-(2-甲氧基羰基乙基)苯基]_5_氣苯并三唑、2_[3,_ 第二丁基-2·-羥基-5’-(2-甲氧基羰基乙基)苯基]苯并三唑、 2-[3 -第二丁基-21-羥基-5-(2-辛氧基羰基乙基)苯基]苯并三 唑、2-[3,-第三丁基_2·—羥基_5·_[2·(2_乙基己氧基)羰基乙 基]苯基]苯并三唑、2-[2-羥基-3·(3,4,5,6-四氫鄰苯二甲醯 亞胺甲基)-5 -甲基苯基]笨并三0坐、2_(3,5_二_第三丁基_2_ 羥基苯基)-5-氯苯并三唑、2-(3,-十二烷基_2,_羥基_5ι_甲基 苯基)苯并三唑及2-[3,-第三丁基_2,_羥基_5,_(2•異辛氧基羰 基乙基)苯基]苯并三唑之混合物,2,2,_亞曱基雙[6_(211_苯 并三唑-2-基)-4-(1,1,3,3-四甲基丁基)苯酚、2,2,_亞甲基雙 [4-第三丁基_6_(2Η·苯并三唑_2_基)苯酚]、聚(3〜n)(乙二 醇)與2-[3’-第三丁基_2,_羥基-5,-(2-曱氧基羰基乙基)苯基] 本并二嗤之縮合物、聚(3〜ιι)(乙二醇)與3_[3_(2h_苯并三 唑-2-基)-5-第三丁基-4-羥基笨基]丙酸甲酯之縮合物、3_ [3-第二丁基-5-(5-氣-2H-苯并三唑-2-基)_4-羥基苯基]丙酸_ 2-乙基己酯、3-[3-第三丁基_5_(5_氣_211_苯并三唑_2_基)_4_ 149242.doc •17- 201114821 經基苯基]丙酸辛r日、H3_第三丁基_5_(5_氣.苯并三唾_ 2-基)-4-羥基笨基]丙酸甲_、3_[3·第三丁基_5_(5_氣| 苯并三唑-2-基”羥|苯基]丙酸及其等之混合物 ,- 經基苯基)苯并三β坐等。 作為光穩定劑,例如可列舉:癸二酸雙(2,2,6,6_四甲基_ 4-旅。定基)醋、丁二酸雙(2,2,6,6_四曱基_4_娘咬基)酿 二酸雙(1,2,2,6,6-五曱基·4_哌啶基)酯、癸二酸雙…-辛氧 基-2,2,6,6-四曱基-4-哌啶基)酯、癸二酸雙(Ν_节氧義 2,2’6’6-四甲基-4·哌啶基)酯、癸二酸雙(Ν_環己氧美 2,2,6,6-四曱基-4-。底咬基)醋、2-(3,5-二-第=丁且/ + —』丞-4-羥基 苄基)-2-丁基丙二酸雙(ι,2,2,6,6-五曱基哌啶基)酯、 2,2-雙(3,5-二-第三丁基-4-羥基苄基)-2-丁基丙二酸雙(1_丙 烯醯基-2,2,6,6-四甲基-4-哌啶基)酯、癸二酸雙(12266 五甲基-4-哌啶基)酯、曱基丙烯酸_2,2,6,6-四甲:a , T卷-4 - η底0定 酯、4-[3-(3,5-二-第三丁基-4-羥基苯基)丙醯氧基]1[2_(3 (3,5-二-第三丁基-4-羥基苯基)丙醯氧基)乙基]_2,2,6 6四 甲基哌啶、2-曱基-2-(2,2,6,6-四曱基-4-哌啶基)胺基七 (2,2,6,6-四曱基- 4-α底。定基)丙醯胺、1,2,3,4-丁按田灿 (2,2,6,6-四曱基-4-哌啶基)酯、1,2,3,4- 丁烷四甲酸四 (1,2,2,6,6·五曱基-4-哌啶基)酯、1,2,3,4- 丁烷四甲酸與 1,2,2,6,6-五曱基-4-派。定醇及卜十三烧醇之混合g旨化物. 1,2,3,4-丁烷四甲酸與2,2,6,6-四甲基-4-哌啶醇及i十二 烷醇之混合酯化物、1,2,3,4-丁烷四甲酸與1,2,2,6,6_五甲 基-4-哌啶醇及3,9-雙(2-羥基-1,1-二曱基乙基)_2,4,8,1〇四 149242.doc •18- 201114821 氧雜螺[5.5]十一烷之混合酯化物、丁烷四甲酸與 2,2,6,6-四甲基_4·哌啶醇及3,9_雙(2_羥基。,卜二甲基乙基)· 2,4,8,1〇-四氧雜螺[5.5]十一烷之混合酯化物、丁二酸二甲 酯與1-(2-羥基乙基)_4_羥基_2,2,6,6_四甲基哌啶之聚縮合 物、聚[(6-咪啉基-1,3,5_三畊_2,4_二基)((2,2,6,6-四甲基一_ 哌啶基)亞胺基)六亞甲基((2,2,6,6-四甲基-4-派啶基)亞胺 基)]、聚[(6-(1,1,3,3-四甲基丁基)亞胺基 基((2,2,6,6-四甲基-4-哌啶基)亞胺基)六亞甲基((2,26,6-四 曱基-4-哌啶基)亞胺基))、队;^1_雙(2,2,6,6_四曱基_4_哌啶 基)己二胺與1,2-二溴乙烷之聚縮合物、队>^,4,7_四[4,6_雙 (N- 丁基-N-(2,2,6,6-四甲基_4_哌啶基)胺基)_丨,3,5_三畊_2_ 基]-4,7-二氮雜癸烷-ΐ,ι〇_二胺、队;^,,4_三[4,6_雙(>^丁基_ Ν-(2,2,6,6-四甲基_4_哌啶基)胺基)三畊_2_基]_4,7_二 氮雜癸烷-1,10-二胺、N,N,,4,7-四[4,6-雙(N- 丁基-N-(1’2,2,6,6-五曱基-4-哌啶基)胺基)-ns·三畊_2_基]_4,7-二 氮雜癸烧-1,10-二胺、N,N',4_ 三[4,6-雙(N- 丁基-N-(1,2,2,6,6-五甲基-4-哌啶基)胺基)三畊_2_基]_4,7_二 氮雜癸烷-1,10-二胺及其等之混合物等受阻胺系光穩定 劑; α-氰基-β,β-二苯基丙烯酸乙酯、α_氰基·β,β_二苯基丙烯 酸異辛酯、α-甲氧羰基桂皮酸曱酯、α_氰基_β_甲基_對曱 氧基桂皮酸曱酯' α-氰基_β_曱基_對甲氧基桂皮酸丁酯、 α-甲氧羰基-對甲氧基桂皮酸甲酯、Ν_(β_Τ氧羰基_β_氰基 乙稀基)-2-甲基叫丨哚啉及其等之混合物等丙烯酸酯系光穩 149242.doc -19· 201114821 定劑; 2,2'-硫代雙-[4-(l,l,3,3-四曱基丁基)苯酚]之鎳錯合物、 二硫胺基曱酸二丁基鎳、單烷基酯之鎳鹽、酮肟之錦錯合 物及其等之混合物等鎳系光穩定劑; 4,4'-二辛氧基草醢替苯胺、2,2’-二乙氧基草醯替笨胺、 2,2'-二辛氧基-5,5’-二-第三丁基醯替笨胺、2,2,-二-十二燒 氧基-5,5’-二-第三丁基醯替苯胺、2-乙氧基_2,_乙基草醯替 苯胺、Ν,Ν·-雙(3-二甲基胺基丙基)草醯胺、2·乙氧基_5_第 三丁基-2'-乙氧基醯替苯胺、2_乙氧基_5,4,_二-第三丁基_ 2·-乙基草醯替苯胺及其等之混合物等草醯胺系光穩定劑; 2’4,6-三(2-羥基-4-辛氧基苯基)_1,3,5_三11井、2_(2_羥基_ 4-辛氧基苯基)-4,6-雙(2,4-二甲基苯基;ρ井、2_ [2,4-二羥基苯基-4,6-雙(2,4-二曱基笨基)-1,3,5_三畊、2,4_ 雙(2-羥基-4-丙氧基苯基)-6-(2,4_二甲基苯基)^、三 畊、2-(2-羥基-4-辛氧基苯基)-4,6-雙(4-曱基苯基)_13,5_三 畊、2-(2-經基-4-十二烧氧基苯基)-4,6-雙(2,4-二曱基苯 基)-1,3,5-三嗜、2-[2-羥基-4-(2-羥基_3_ 丁氧基丙氧基)苯 基]-4,6-雙(2,4-二甲基苯基)-1,3,5-三畊、2-[2-羥基-4-(2-經 基-3-辛氧基丙氧基)苯基]-4,6-雙(2,4-二甲基苯基)_ι,3,5·三 畊及其等之混合物等2-(2-羥基苯基三吨系光穩定 劑等。 作為穩定劑,除上述以外’例如亦可列舉:N,N_二苄基 經基胺、N,N-二乙基羥基胺、N,N-二辛基羥基胺、n,N-二 月桂基經基胺、N,N-二-十四院基經基胺、ν,Ν-二-十六烧 149242.doc •20- 201114821 基經基胺、N,N-二-+八吟f 甘a 烷基羥基胺、N-十六烷基_N-十八 烷基羥基胺、N-十七p A 丄 ^ ^ 烷基-Ν-十八烷基羥基胺及其等之混 合物等經基胺等。 作為潤滑劑’例如可列舉:石埵及蟻等脂肪族烴、碳數 8〜22之高級脂肪族酸、碳數㈣之高級脂肪族酸之金屬 (A1 Ca、Mg、Ζη)鹽、碳數8〜22之脂肪族醇、聚二醇、 厌數4 22之尚級知肪酸與碳數4〜丨8之脂肪族一元醇之酯、 碳數8〜22之高級脂肪族醯胺、聚矽氧油、松香衍生物等。 該等添加劑中可較好地使用者為酚系抗氧化劑、磷系抗 氧化劑、硫系抗氧化劑、紫外線吸收劑、受阻胺系光穩定 劑。 作為更好之酚系抗氧化劑,可列舉:2,6_二-第三丁基_ 4-甲基苯酚、2,4,6-三-第三丁基苯酚、2,4-二辛硫基甲基_ 6-甲基苯酚、2,2'-硫代雙(6-第三丁基苯酚)、2,2'-亞甲基 雙(4-曱基-6-第三丁基苯酚)、2,21_亞甲基雙(4_乙基_6_第三 丁基苯酴)、2,2,-亞曱基雙[4-曱基-6-(α-甲基環己基)苯 驗]、2,2’-亞甲基雙(4_曱基_6_環己基笨酚)、2,2’-亞曱基雙 (4,6_二-第三丁基苯酚)、2,2,-亞乙基雙(4,6-二-第三丁基苯 紛)、4,4'-亞甲基雙(6_第三丁基_2-曱基苯酚)、4,4,-亞甲基 雙(2,6-二-第三丁基苯酚)、4,4'_亞丁基雙(3-曱基-6-第三丁 基苯酚)、1,1-雙(4-羥基苯基)環己烷、1,1-雙(5-第三丁基_ 4-羥基-2-甲基苯基)丁烷、1,ι,3-三(5-第三丁基-4-羥基-2-甲基苯基)丁烷、乙二醇丁酸雙[3,3-雙-3'-第三丁基-41-羥 基笨基]S旨; 149242.doc -21 - 201114821 2,4,6-三(3,5-二-第三丁基-4-苯氧基)-l,3,5-三畊、三(4-第二丁基-3-經基-2,6-二曱基节基)異氰尿酸醋、雙(3,5-二-第二丁基-4-經基苄基)異氰尿酸@旨、三[2-(3’,5’-二-第三丁 基-4'-羥基桂皮醯氧基)乙基]異氰尿酸酯、3,5-二-第三丁 基-4-經基苄基膦酸二乙酯、3,5-二-第三丁基-4-經基节基 膦酸二-正十八烷基酯、3,5-二-第三丁基-4-羥基苄基膦酸 單酯之鈣鹽、3-(3,5-二-第三丁基-4-羥基苯基)丙酸正十八 烷基酯、新戊烷四基四(3,5-二-第三丁基-4-羥基桂皮酸 醋)、硫代二伸乙基雙(3,5-二-第三丁基·4-羥基桂皮酸 醋)、1,3,5-三曱基-2,4,6-三(3,5-二-第三丁基_4_羥基苄基) 苯、3,6-二氧雜八亞甲基雙(3,5-二-第三丁基_4_羥基桂皮 酸酯)、六亞甲基雙(3,5-二-第三丁基·4_羥基桂皮酸酯)、 二乙一醇雙(5 -第二丁基-4-經基-3-曱基桂皮酸醋)、3,9-雙 [2-(3-(3-第三丁基-4-羥基-5-曱基苯基)丙醯氧基二甲 基乙基]-2,4,8,10-四氧雜螺[5.5]十一烷、n,N._ 雙[3_(3,,5,_ 二-第二丁基-4'-經基苯基)丙酿基]肼、N,N'-雙[3-(3' 5'-二· 第三丁基-4,-羥基苯基)丙醯基]己二胺等,該等可分別單獨 使用或使用兩種以上。 作為更好之磷系抗氧化劑’可列舉:亞磷酸三(壬基苯 基)酯、亞磷酸三(2,4-二-第三丁基苯基)酯、二硬脂基季戊 四醇二亞磷酸酯、雙(2,4-二-第三丁基笨基)季戊四 填酸醋、冑(2,4-二-第三丁基_6曱基苯基)季戍四醇二亞碟 酸醋、雙(2,6-二_第三丁基_4_甲基苯基)季戊四醇二亞碟酸 酉旨、四(2,4-二-第三丁基苯基)_4,4,_二伸苯基二亞鱗酸酿、 149242.doc -22· 201114821 2,2’-亞曱基雙(4,6-二-第三丁基苯基)-2-乙基己基亞磷酸 醋、2,2'-亞乙基雙(4,6-二-第三丁基苯基)氟亞磷酸酯、雙 (2,4---第三丁基-6 -曱基苯基)乙基亞填酸醋、2-(2,4,6-三_ 第二丁基苯基)-5-乙基-5 - 丁基-1,3,2-氧磷雜環己炫、 2,2',2"-氮川基[三乙基-三(3,3’,5,5'_四-第三丁基_ι,ι'_聯苯 基_2,2’-二基)亞磷酸酯等,該等可分別單獨使用或使用兩 種以上》 作為更好之紫外線吸收劑,例如可列舉:水楊 水揚酸-4-第三丁基苯酯、3,,5,-二-第三丁基_4,_羥基苯甲 酸-2,4-二-第三丁基苯酯、水揚酸_4_第三辛基苯酯、2,4_ 一羥基二苯曱酮、2-羥基-4-甲氧基二苯曱酮、2_羥基_4_辛 氧基一苯甲酮、2,2’-二羥基-4-曱氧基二苯曱酮、雙(5_苯 甲醯基-4-羥基-2-甲氧基笨基)甲烷、2,2,,4,4,_四羥基二苯 甲酮、2-(2-羥基甲基苯基)苯并三唑、2_(3·,5,-二-第三 丁基-2’-經基苯基)苯并三唾、2·(5,·第三丁基_2,_經基苯基) 苯并三唾、2-(2’-經基-5,_第三辛基笨基)苯并三。坐、2-(3-第三丁基_2_經基_5_甲基苯基)_5_氯苯并三唾、2_(3,·第二 丁基I,基-5··第三丁基苯基)笨并三唾、2-(2,_經基_4、辛 氧基苯基)苯并三峻、2_(3,,5’·二-第三戊基-2,-經基苯基)苯 并一坐2 [2 基-3,5 雙(α,α_二甲基节基)笨基]•瓜苯 并三唾等’該等可分別單獨使用或使用兩種以上。 作為更好之光穩定劑,例如可列舉H雙(2,2,Μ_ 四甲基W定基)醋、癸二酸雙(U,2,M-五f基如底咬 基)醋、癸二酸雙(N-辛氧基_2,2,Μ·四甲基-4·㈣細、 I49242.doc -23· 201114821 癸二酸雙(Ν·苄氧基-2,2,6,6-四甲基-4_哌啶基)酯、癸二酸 雙(N-環己氧基-2,2,6,6·四曱基-4-哌啶基)酯、2-(3,5-二-第 三丁基-4-羥基苄基)-2-丁基丙二酸雙(l,2,2,6,6-五曱基-4-哌啶基)酯、2,2-雙(3,5-二-第三丁基-4·羥基苄基)-2-丁基 丙二酸雙(1-丙烤酿基-2,2,6,6-四曱基-4-派。定基)酯、丁二 酸雙(2,2,6,6-四曱基-4-哌啶基)醋、甲基丙烯酸-2,2,6,6-四 曱基-4-哌啶酯、4-[3-(3,5-二-第三丁基-4-羥基苯基)丙醯 氧基]-l-[2-(3-(3,5-二-第三丁基-4-經基苯基)丙酿氧基)乙 基]-2,2,6,6-四曱基0底咬、2-曱基-2-(2,2,6,6-四曱基-4-〇底咬 基)胺基-N-(2,2,6,6-四曱基-4-哌啶基)丙醯胺、i,2,3,4-丁 烧四甲酸四(2,2,6,6-四甲基-4-派唆基)酯; 1,2,3,4-丁烷四甲酸四(1,2,2,6,6-五甲基-4-哌啶基)酯、 1,2,3,4-丁烧四曱酸與1,2,2,6,6-五甲基-4-旅咬醇及1-十三 烷醇之混合酯化物、1,2,3,4-丁烷四甲酸與2,2,6,6-四甲基-4-略咬醇及1-十三烧醇之混合酯化物、ι,2,3,4-丁院四曱酸 與1,2,2,6,6-五甲基-4-哌咬醇及3,9-雙(2-羥基-1,1-二曱基乙 基)-2,4,8,1 〇-四氧雜螺[5.5] Η--烧之混合酯化物、1,2,3,4- 丁烷四甲酸與2,2,6,6-四f基-4-哌啶醇及3,9·雙(2-羥基-1,1-二曱基乙基)-2,4,8,10-四氧雜螺[5.5]十一烷之混合酯化 物、丁 一酸二曱醋與1_(2-經基乙基)-4-經基-2,2,6,6 -四曱 基。底咬之聚縮合物、聚[(6-咪淋基-1,3,5-三畊-2,4-二 基)((2,2,6,6-四曱基-4-哌啶基)亞胺基)六亞曱基((2,2,6,6-四甲基-4-哌啶基)亞胺基)]、聚[(6-(l,l,3,3-四甲基丁基)-l,3,5-三畊-2,4-二基)((2,2,6,6-四甲基-4-哌啶基)亞胺基)六 149242.doc -24- 201114821 亞甲基(U,2,M-四甲基如底咬基)亞胺 等可分 別單獨使用或使用兩種以上。 作為本發明之熱塑性聚合物組合物之製造方法,例如可 H東熱塑性聚合物時分別調配化合物⑴、化合物 (:)及視需要之添加劑的方法;例如包括如下步驟之方法: 匕口化口物(1)、化合物⑺及視需要之添加劑而製造穩定 劑組合物之步驟;及將上述步驟中所獲得之穩定劑組合物 混合至熱塑性聚合物Φ 丰 敬σ物中之步驟。就化合物(1)及化合物(2) 於"熱塑性聚合物φ $ A # k 刀散性之觀點而言,較好的是後一種 方法。 此f,作為製造穩定劑組合物之步驟,同樣可例示後述 的穩定劑組合物之製造方法中例示的方法。 右對將穩定劑組合物混合至熱塑性聚合物中之步驟加以 更詳細之說明,則例如可列舉以下方法等:將熱塑性聚合 物與上述穩定劑組合物乾式摻合後,利用單軸或多軸擠出 機進行溶融混練,然後進行擠出而獲得熱塑性聚合物組合 物=顆粒;例如,將於環己烧等溶劑中溶解穩定劑組合物 所得之溶液添加至埶绝性聚人你 .、,、a r氷σ物之聚合結束後之聚合物溶 液中,並進行脫溶劑。 所得之熱塑性聚合物組合物亦可不加冷卻而直接以炼融 狀感供給於成形機中進行成形。成形方法並無特別限定, 例如可使用:射出成形法、擠出成形法、擠出吹塑成形 法、射出吹塑成形法、雙軸延伸吹塑成形法等成形方法。 成形後進行冷卻’藉此可獲得包含本發明之熱塑性聚合 149242.doc -25· 201114821 物.、且Q物的熱塑性聚合物成形體。作為所得之熱塑性聚合 抑成幵v體例如可列舉:繞線管、連接器、開關、電阻器 f件H繼電器、電容器外殼、保險絲、馬達、烤 箱17刷基板、1C(Integrated circuit,積體電路)製造裝 且專電子零件,排氣飾件(air outlet garnish)、引擎蓋 (h〇〇d Vent)、分電器蓋(distributoi· cap)、廢氣控制 閱等^車零件;齒輪、凸輪等機械零件;底板等鐘錶零 件’底蓋、鏡筒、撥桿(lever)等相機零件;線軸(reel)等娛 之零件,豕電機器外殼、照明配線器具、膜、瓶、 ,隹淨化槽、便槽、浴紅、整體衛浴(unit bath)、水 欣 為 藥。0箱、官、波紋板、平板、塗料、裝飾板、 電氣零件密封材料、樹脂混凝土等。 本毛明之穩定劑組合物含有化合物(1)及化合物(2)。 本發明之穩定劑組合物較好的是以99.9:0.1〜5:95(化合物 )。物(2))之重量比而含有化合物(1)與化合物(2), 的疋乂 98.2〜1〇:9〇之重量比而含有化合物⑴與化合物 ,本毛明之穩定劑组合物可直接用作㉟塑性聚合物之力, 穩疋片11。Χ ’亦可於不損及本發明之效果之範圍内含琴 述添加劑。 較好之添加劑如上述’本發明之穩定劑組合物中之小 物(3)之添加量相對於穩定劑組合物ι〇〇重量 〇〜90份,更好的是0.1〜80份。 作為本發明之穩定劑組合物之製造方法,例如可列彡 U9242.doc -26. 201114821 將化合物(1)、化合物(2)及視需要之上述添加劑利用亨舍 爾混合機(Henschel mixer)、快速混合機(super mixer)、高 速混合機(high-speed mixer)等混合機加以混合之方法;例 如對化合物(1)、化合物(2)及添加劑之混合物進一步進行 擠出成形之方法;例如對化合物(1)、化合物(2)及添加劑 之混合物進一步進行授拌造粒之方法等。 實施例 以下’列舉實施例及比較例對本發明加以更詳細之說 明。只要無特別說明,則份及%係指重量基準。又,將溶 融流動速率記載為MFR(Melt Flow Rate)。 實施例1 (穩定劑組合物之製造) 將作為化合物(1)之β-(4,-羥基-3,,5,-二-第三丁基苯基)丙 酸正十八烷酯(BASF Japan公司製造,irganox(註冊商 標)1076 ’以下有時記作化合物(!_!))〇 48份、與作為化合 物(2)之甘露糖醇〇. 12份混合,而製造穩定劑組合物。 實施例2、3 (穩定劑組合物之製造) 於實施例1中’將化合物(丨-丨)之使用量分別設定為0 3〇 份、0.12份,將甘露糖醇之使用量分別設定為〇 3〇份、 〇_48份,除此以外’與實施例1同樣地製造穩定劑組合 物。 實施例4(熱塑性聚合物組合物之製造) mm 將作為熱塑性聚合物之旭化成製造之苯乙烯-丁二烯嵌 段共聚物100份、與實施例i中所得之穩定劑組合物〇 6份 乾式摻合後’對所得之樹脂組合物使用螺桿直徑為30 149242.doc -27- 201114821 之單軸擠出機(Tanabe P丨astics公司製造,VS3〇28型擠出 機)’於230°C、螺桿轉速50 rpm下進行混練擠出而獲得繩 股’利用造粒機將該繩股切斷而獲得熱塑性聚合物組合物 之顆粒。 實施例5、6(熱塑性聚合物組合物之製造) 於實施例4中,代替實施例丨中所得之穩定劑組合物〇 6 份而使用實施例2、3中分別獲得之穩定劑組合物〇6份, 除此以外,與實施例4同樣地獲得熱塑性聚合物組合物之 顆粒。 比較例1 於實施例4中,代替實施例丨中所得之穩定劑組合物〇6 份而使用化合物(1-1)0.6份,除此以外,與實施例4同樣地 獲得熱塑性聚合物組合物之顆粒。 試驗例1 (加工穩定性試驗) 對實施例4〜6及比較例丨中獲得之各顆粒,實施滯留mfr 試驗作為擠出加工時之運轉時之加工性評價。試驗係藉由 如下方式而實施,依據JIS K 7210,將熔融指數測定儀 (L217-E14011,Techno Seven公司製造)之料缸内設定為 2 7 0 C,使熱塑性聚合物組合物於該料紅内滯留π分鐘後 測定負載2.16 kg下之MFR。結果示於表!。河^^值越大, 則加工穩定性越優異。 表1中之所謂加工穩定性提昇率,係藉由下式而求出之 值。 (加工穩定性提昇率)=(實施例中測定之MFR值—比較例i中 149242.doc -28 - 201114821 測定之MFR值)/比較例1中測定之MFR值x 100 [表1]Cool, Ν, Ν '-bis (transethyl) oxazinamide, 3_thiaundecyl alcohol, % thiopentadecanol, tridecyl hexane diol, trihydroxy decyl propane, 4_ An ester of a monohydric or polyhydric alcohol such as a mixture of hydroxyindenyl-dioxa-2,6,7-trioxabicyclo[2,2,2]octane and the like; 149242.doc -14- 201114821 AN'- Bis[3-(3,5,2-di-t-butyl-4,-pyridylphenyl)propanyl]anthracene, anthracene, Ν'-bis[3-(3·,5'_di- Tert-butyl-4,-hydroxyphenyl)propanyl]hexamethylenediamine, anthracene, Ν'-bis[3_(3,5,2-di-tert-butyl-4,hydroxyphenyl)propane a phthalic acid, a mixture of propylenediamine and the like, etc., such as decylamine of β-(3,5-di-t-butyl-4-hydroxyphenyl)propionic acid; and α-tocopherol, β-tocopherol, Tocopherol such as γ-tocopherol, δ-tocopherol, and the like. As the antioxidant of hydroquinone and alkylated p-diphenol, for example, 2,6---t-butyl-4-methoxybenzene, 2,5-di-t-butyl group can be mentioned. Stupid phenol, 2,5-di-third amyl hydroquinone, 2,6-diphenyl-4-octadecyloxyphenol, 2,6-di-t-butyl-p-phenylene Phenol, 2,5-di-t-butyl-4-hydroxyphenyl oxime ether, stearic acid (3,5-di-t-butyl-4-hydroxyphenyl) ester, bis-hexanoic acid (3, 5-di-tert-butyl-4-hydroxyphenyl) ester and the like, etc. As the sulfur-based antioxidant, for example, 3,3,-dithiogallate dilaurate, 3, 3 '-Tridecyl thiodipropionate, 3,3,-thiodipropionic acid di- and decyl ester, 3,3'-thiodipropionate distearyl ester, 3,3,-sulfur Resinyl stearyl hexapropionate, neopentyl tetrakis(4, lauryl thiopropionate), and the like. Examples of the phosphorus-based antioxidant include triphenyl phosphite, tris(nonylphenyl) vinegar phosphite, tris(2,4-di-tert-butylphenyl) phosphite, and arsenic trioxide. Laurel vinegar, sub-filled acid three. Ten people Hyunji, di-stea pentaerythritol monophosphorus day, diisodecyl pentaerythritol diphosphite, bis (2,4_-first butyl phenyl) pentaerythritol II Phosphite, bis-tertiary-t-butyl-6-nonylphenyl) pentaerythritol diphosphite, bis(2,6-di-third-butyl I49242.doc •15·201114821 base-4-mercapto Pentaerythritol diphosphite, bis(2,4,6-tri-tert-butylphenyl)pentaerythritol diphosphite, tristea sorbitol triphosphoric acid vinegar, tetrakis (2,4-di- Tert-butylphenyl)_4,4,_diphenylene diphosphinic acid, 2,2,-methylenebis(4,6-di-t-butylphenyl)_2-ethyl Hexyl sulphate, 2,2,-ethylenebis(4,6-di-t-butylphenyl)fluorophosphite, bis(2,4-di-t-butyl-6_曱Ethyl phenyl)ethyl phosphite, bis(2,4-di-tert-butyl-6-nonylphenyl) decyl phosphite 2_(2,4,6_tri-t-butylphenyl)-5-ethyl-5-butyl-1,3,2-oxaphosphine, 2,2,,2"_nitrogen Chuanji [diethyl-bis(3,3',5,5-tetra-t-butylbiphenyldiyl)phosphite and mixtures thereof and the like. Examples of the ultraviolet absorber include phenyl salicylate, 4-tert-butylphenyl salicylate, and 3,5,2-di-t-butyl- 4,-hydroxybenzoic acid 2,4_. Di-tert-butyl phenyl ester, 4-trioctylphenyl salicylate, bis(4_t-butylbenzylidene) resorcinol, benzhydryl resorcinol, 3, , 5,-di-t-butyl-4-hexadecyl 4'-hydroxybenzoate, 3,5,-di-t-butyl- 4,-octadecyl hydroxybenzoate, Salicylic acid ester derivatives such as 3',5,-di-t-butyl-4,-hydroxybenzoic acid 2/methyl-4,6-di-t-butylphenyl ester and the like 2,4-dihydroxydibenzophenone, 2-hydroxy-4-indolylbenzophenone, 2-hydroxy-4-octyloxydibenzophenone, 2,2,_dihydroxy-cardiac Oxybenzophenone, bis(5-phenylindenyl-4-hydroxy-2-phenyloxy) decane, 2,2,4,4,tetrahydroxybenzophenone and the like a mixture of 2-hydroxydibenzophenone derivatives; 2-(2-hydroxy-5-methylphenyl) benzotriazole, 2·(3,5,2-di-t-butyl- 21-hydroxyl Phenyl)benzotriazole, 2·(5,_t-butyl-2,_hydroxyl Benzo) 149242.doc 16 - 201114821 oxadiazole, 2-(2'-hydroxy-5,-trioctylphenyl) benzotriazole, 2·(3_t-butyl-2-hydroxy- 5-nonylphenyl)·5-chlorobenzotriazole, 2—(3,_t-butyl-21-hydroxy-51-t-butylphenyl)benzotriazole, 2—(2,-hydroxyl _4, _ octyloxyphenyl) benzotriazole, 2-(3,5,-di-p-pentyl 2,-hydroxyphenyl)benzotrienyl 2-[2-hydroxy-3 ',5'-bis(α,α-dimethylbenzyl)phenyl]·2Η_benzotriazole, 2-[(3,-t-butyl-2,-p-phenyl)_5, _(2_octyloxycarbonylethyl)phenyl]-5-chlorobenzotriazine, 2_[3'·t-butyl-5,_[2_(2•ethylhexyloxy) benzyl ]]-2'-p-phenylene]-5-gas benzotrisole, 2_[3,·t-butyl-21-hydroxy-5'-(2-methoxycarbonylethyl)phenyl] _5_gas benzotriazole, 2_[3,_ second butyl-2.-hydroxy-5'-(2-methoxycarbonylethyl)phenyl]benzotriazole, 2-[3 - Dibutyl-21-hydroxy-5-(2-octyloxycarbonylethyl)phenyl]benzotriazole, 2-[3,-t-butyl-2·-hydroxy_5·_[2· (2-ethylhexyloxy)carbonylethyl]phenyl]benzo Triazole, 2-[2-hydroxy-3·(3,4,5,6-tetrahydrophthaleneiminemethyl)-5-methylphenyl] stupid three-position, 2_(3 ,5_di-t-butyl-2-(hydroxyphenyl)-5-chlorobenzotriazole, 2-(3,-dodecyl-2,-hydroxy-5ι_methylphenyl)benzotriene a mixture of azole and 2-[3,-t-butyl-2,-hydroxy-5,-(2•isooctyloxycarbonylethyl)phenyl]benzotriazole, 2,2,_indenylene Bis[6_(211_benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol, 2,2,_methylenebis[4-third Base_6_(2Η·benzotriazol-2-yl)phenol], poly(3~n)(ethylene glycol) and 2-[3'-tert-butyl-2,_hydroxy-5,-( 2-曱oxycarbonylethyl)phenyl] condensate of the indane, poly(3~ιι) (ethylene glycol) and 3_[3_(2h_benzotriazol-2-yl)-5- Condensate of methyl tert-butyl-4-hydroxyindolyl]propionate, 3-[3-t-butyl-5-(5-gas-2H-benzotriazol-2-yl)-4-hydroxybenzene Propionate_2-ethylhexyl ester, 3-[3-t-butyl_5_(5_gas_211_benzotriazole_2_yl)_4_ 149242.doc •17- 201114821 Base] propionic acid xin r day, H3_third butyl _5_ (5_ gas. benzotrisole _ 2- -4-hydroxyphenyl]propionic acid methyl _, 3_[3·t-butyl _5_(5_gas | benzotriazol-2-yl) hydroxy | phenyl] propionic acid and mixtures thereof, - Phenylphenyl)benzotriazine sit and so on. Examples of the photostabilizer include bismuth (2,2,6,6-tetramethyl-4-cyclohexane) succinic acid and succinic acid bis(2,2,6,6-tetradecyl). _4_娘 bite base) bis (1,2,2,6,6-pentainyl-4-piperidinyl) ester, azelaic acid bis-octyloxy-2,2,6, 6-tetradecyl-4-piperidinyl)ester, bis(Ν_节oxy 2,2'6'6-tetramethyl-4·piperidinyl) sebacate, bismuth azelaic acid _cyclohexyloxy 2,2,6,6-tetradecyl-4-. bottom biting) vinegar, 2-(3,5-di-butylidene//+- 丞-4-hydroxybenzyl -2-butylmalonate bis(ι,2,2,6,6-pentamethylpiperidyl) ester, 2,2-bis(3,5-di-t-butyl-4-hydroxyl) Benzyl)-2-butylmalonic acid bis(1-propenyl-2-,2,6,6-tetramethyl-4-piperidinyl), sebacic acid bis(12266 pentamethyl-4) -piperidinyl)ester, methacrylic acid _2,2,6,6-tetramethyl:a, T-volume-4 - η- bottom 0-ester, 4-[3-(3,5-di-third 4-hydroxyphenyl)propanoxy]1[2_(3 (5,5-di-t-butyl-4-hydroxyphenyl)propenyloxy)ethyl]_2,2,6 6 Tetramethylpiperidine, 2-mercapto-2-(2,2,6,6-tetradecyl-4-piperidyl)amino-7 (2,2,6,6-tetradecyl-4- Alpha bottom Fixing base propylamine, 1,2,3,4-butyl saponin (2,2,6,6-tetradecyl-4-piperidyl) ester, 1,2,3,4-butane Tetrakis(1,2,2,6,6·pentamethyl-4-piperidyl) tetracarboxylate, 1,2,3,4-butanetetracarboxylic acid and 1,2,2,6,6-five曱基-4-派. a mixture of alcohol and succinyl alcohol. 1,2,3,4-butanetetracarboxylic acid and 2,2,6,6-tetramethyl-4-piperidinol and i-dodecanol Mixed esterified product, 1,2,3,4-butanetetracarboxylic acid and 1,2,2,6,6-pentamethyl-4-piperidinol and 3,9-bis(2-hydroxy-1, 1-dimercaptoethyl)_2,4,8,1〇4 149242.doc •18- 201114821 Mixed ester of oxaspiro[5.5]undecane, butanetetracarboxylic acid and 2,2,6,6 -tetramethyl-4·piperidinol and 3,9-bis(2-hydroxyl.,dimethylethyl)·2,4,8,1〇-tetraoxaspiro[5.5]undecane Mixed condensate, dimethyl succinate and poly( condensate of 1-(2-hydroxyethyl)-4-hydroxy-2,2,6,6-tetramethylpiperidine, poly[(6- morpholinyl) -1,3,5_three tillage _2,4_diyl)((2,2,6,6-tetramethyl-piperidinyl)imido)hexamethylene ((2,2, 6,6-tetramethyl-4-pyridinyl)imido)], poly[(6-(1,1,3,3-tetramethylbutyl)imide) ((2,2, 6,6-tetramethyl-4-piperidinyl)imido)hexamethylene ((2,26,6-tetradecyl-4-piperidyl)imido)), team; ^1 Condensation of bis(2,2,6,6-tetradecyl_4_piperidinyl)hexanediamine with 1,2-dibromoethane , team >^,4,7_tetra[4,6_bis(N-butyl-N-(2,2,6,6-tetramethyl-4-isopiperidinyl)amino)_丨,3,5_three tillage_2_yl]-4,7-diazanonane-ΐ, ι〇_diamine, team; ^,, 4_three [4,6_double (>^butyl _ Ν-(2,2,6,6-tetramethyl_4_piperidinyl)amino)three tillage _2_yl]_4,7-diazepine-1,10-diamine, N ,N,,4,7-tetra[4,6-bis(N-butyl-N-(1'2,2,6,6-pentamethyl-4-piperidyl)amino)-ns· Three tillage _2_ yl]_4,7-diazepine sinter-1,10-diamine, N,N',4_tri[4,6-bis(N-butyl-N-(1,2, Hindered amines such as 2,6,6-pentamethyl-4-piperidinyl)amino)trinyl-2-yl]- 4,7-diazanonane-1,10-diamine and mixtures thereof Light stabilizer; α-cyano-β, β-diphenylethyl acrylate, α-cyano·β, β-diphenyl isooctyl acrylate, α-methoxycarbonyl cinnamate, α_ Cyano-β-methyl-p-methoxy cinnamic acid ' ester ' α-cyano _β 曱 _ _ p-methoxy cinnamic acid butyl ester, α-methoxycarbonyl-p-methoxy cinnamic acid methyl ester Acrylates such as Ν_(β_Τoxycarbonyl_β_cyanoethylene)-2-methyl porphyrin and mixtures thereof Stable 149242.doc -19· 201114821 定; 2,2'-thiobis-[4-(l,l,3,3-tetradecylbutyl)phenol] nickel complex, dithiol a nickel-based light stabilizer such as dibutyl nickel phthalate, a nickel salt of a monoalkyl ester, a ketoxime ruthenium complex, and the like; 4,4'-dioctyloxyxanthene, 2, 2'-diethoxylated hydrazine, strepamine, 2,2'-dioctyloxy-5,5'-di-t-butyl hydrazine, 2,2,-di-t-butyl oxide 5-,5'-di-t-butyl decyl aniline, 2-ethoxy-2, ethyl oxalic acid, hydrazine, hydrazine-bis(3-dimethylaminopropyl) Phytosamine, 2·ethoxy _5_t-butyl-2'-ethoxy oxime, 2_ethoxy _5,4,_di-tert-butyl _ 2·-ethyl A grassy amine light stabilizer such as a mixture of aniline and its like; 2'4,6-tris(2-hydroxy-4-octyloxyphenyl)_1,3,5_three 11 well, 2_( 2_hydroxy-4-octyloxyphenyl)-4,6-bis(2,4-dimethylphenyl; ρ well, 2_[2,4-dihydroxyphenyl-4,6-bis(2 , 4-dimercaptophenyl)-1,3,5_three tillage, 2,4_bis(2-hydroxy-4-propoxyphenyl)-6-(2,4-dimethylphenyl) ^, three tillage, 2-(2-hydroxy 4--4-octyloxyphenyl)-4,6-bis(4-mercaptophenyl)_13,5_three-plowed, 2-(2-pyridyl-4-dodecyloxyphenyl)- 4,6-bis(2,4-dimercaptophenyl)-1,3,5-trisophilic, 2-[2-hydroxy-4-(2-hydroxy-3-yloxypropoxy)phenyl -4,6-bis(2,4-dimethylphenyl)-1,3,5-three tillage, 2-[2-hydroxy-4-(2-pyridyl-3-octyloxypropoxy) 2-(2-hydroxyphenyl triton light stabilizer), such as phenyl]-4,6-bis(2,4-dimethylphenyl)_ι, 3,5·three tillage and the like Wait. As the stabilizer, in addition to the above, for example, N,N-dibenzyltransamine, N,N-diethylhydroxylamine, N,N-dioctylhydroxylamine, n,N-dilauric acid may also be mentioned. Base amine, N,N-di-four-fourth base transylamine, ν, Ν-di-hexa-fibene 149242.doc •20- 201114821 amide, N,N-di-+heptazone Gan a alkylhydroxylamine, N-hexadecyl-N-octadecylhydroxylamine, N-heptadecyl p- 丄^^ alkyl-fluorene-octadecylhydroxylamine, and the like Alkylamine and the like. Examples of the lubricants include aliphatic hydrocarbons such as sarcophagus and ants, higher aliphatic acids having a carbon number of 8 to 22, and metal (A1 Ca, Mg, Ζη) salts of a higher aliphatic acid having a carbon number (d 4), and carbon number. 8 to 22 of an aliphatic alcohol, a polyglycol, an aliphatic fatty acid of 4 to 22, an aliphatic monohydric alcohol of 4 to 8 carbon atoms, a higher aliphatic decylamine having a carbon number of 8 to 22, and a poly Oxygenated oil, rosin derivatives, and the like. Among these additives, a phenol-based antioxidant, a phosphorus-based antioxidant, a sulfur-based antioxidant, an ultraviolet absorber, and a hindered amine-based light stabilizer are preferably used. As a more preferable phenolic antioxidant, 2,6-di-t-butyl-4-methylphenol, 2,4,6-tri-tert-butylphenol, 2,4-dioctylsulfide Methyl 6-methylphenol, 2,2'-thiobis(6-tert-butylphenol), 2,2'-methylenebis(4-mercapto-6-tert-butylphenol ), 2,21-methylenebis(4_ethyl_6_t-butylphenylhydrazine), 2,2,-fluorenylene bis[4-mercapto-6-(α-methylcyclohexyl) Benzene], 2,2'-methylenebis(4_fluorenyl-6-cyclohexylphenol), 2,2'-arylene di(4,6-di-t-butylphenol) , 2,2,-ethylenebis(4,6-di-t-butylbenzene), 4,4'-methylenebis(6-t-butyl-2-nonylphenol), 4 , 4,-methylenebis(2,6-di-tert-butylphenol), 4,4'-butylenebis(3-mercapto-6-tert-butylphenol), 1,1-double (4-hydroxyphenyl)cyclohexane, 1,1-bis(5-tert-butyl-4-hydroxy-2-methylphenyl)butane, 1,ι,3-tri (5-third Butyl-4-hydroxy-2-methylphenyl)butane, ethylene glycol butyrate bis[3,3-bis-3'-t-butyl-41-hydroxyphenyl]S; 149242.doc -21 - 201114821 2,4,6-three (3,5-two-third -4-phenoxy)-l,3,5-three tillage, tris(4-secondbutyl-3-yl-2,6-diindenyl) isocyanuric acid vinegar, double (3, 5-di-t-butyl-4-transbenzylidene)isocyanuric acid @三,2-[3',5'-di-t-butyl-4'-hydroxycinnamateoxy)B Isocyanurate, diethyl 3,5-di-tert-butyl-4-transbenzylphosphonate, 3,5-di-t-butyl-4-trans- phenylphosphonic acid Calcium salt of di-n-octadecyl ester, 3,5-di-t-butyl-4-hydroxybenzylphosphonic acid monoester, 3-(3,5-di-t-butyl-4-hydroxyl Phenyl) n-octadecyl propionate, neopentyltetrakis(3,5-di-t-butyl-4-hydroxycinnamic acid vinegar), thiodiethylidene bis (3,5- Di-t-butyl 4-hydroxycinnamic acid vinegar, 1,3,5-trimethyl-2,4,6-tris(3,5-di-t-butyl-4-ylhydroxybenzyl) Benzene, 3,6-dioxa octamethyl bis(3,5-di-t-butyl-4- hydroxycinnamate), hexamethylene bis(3,5-di-t-butyl · 4_hydroxycinnamate), diethyl bis (5-t-butyl-4-alkyl-3-mercapto cinnamic acid), 3,9-bis[2-(3-(3- Tributyl-4-hydroxy-5-mercaptophenyl)propanoid Dimethylethyl]-2,4,8,10-tetraoxaspiro[5.5]undecane, n,N._bis[3_(3,,5,_di-secondbutyl-4 '-Phenylphenyl)propyl]N,N,N'-bis[3-(3' 5'-di-tert-butyl-4,-hydroxyphenyl)propanyl]hexanediamine, etc. These may be used alone or in combination of two or more. As a preferred phosphorus-based antioxidant, tris(nonylphenyl) phosphite, tris(2,4-di-t-butylphenyl) phosphite, and distearyl pentaerythritol diphosphoric acid may be mentioned. Ester, bis(2,4-di-tert-butylphenyl) pentaerythritol vinegar, hydrazine (2,4-di-tert-butyl-6 fluorenylphenyl) quaternary tetraol Sour vinegar, bis(2,6-di-t-butyl-4-methylphenyl)pentaerythritol di-sodium oxalate, tetrakis(2,4-di-t-butylphenyl)_4,4, _Diphenyl succinic acid brewing, 149242.doc -22· 201114821 2,2'-arylene bis(4,6-di-t-butylphenyl)-2-ethylhexyl phosphite , 2,2'-ethylenebis(4,6-di-t-butylphenyl)fluorophosphite, bis(2,4---tert-butyl-6-nonylphenyl) Kea acid vinegar, 2-(2,4,6-tri-t-butylphenyl)-5-ethyl-5-butyl-1,3,2-oxaphosphorane, 2, 2',2"-Nizawa-based [triethyl-tris(3,3',5,5'-tetra-tert-butyl_ι,ι'_biphenyl-2,2'-diyl) Phosphite, etc., these may be used alone or in combination of two or more" as a better ultraviolet absorber For example, salicyl salicylic acid-4-t-butylphenyl ester, 3,5,-di-tert-butyl-4,-hydroxybenzoic acid-2,4-di-t-butylphenyl ester, Salicylic acid_4_t-octylphenyl ester, 2,4-hydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-inocyloxybenzophenone , 2,2'-dihydroxy-4-decyloxybenzophenone, bis(5-benzylidene-4-hydroxy-2-methoxyphenyl)methane, 2,2,,4,4 ,_tetrahydroxybenzophenone, 2-(2-hydroxymethylphenyl)benzotriazole, 2_(3·,5,-di-t-butyl-2'-pyridylphenyl)benzo Tris, 2, (5, · tert-butyl-2, _p-phenyl) benzotrisene, 2-(2'-transyl-5,_t-thinylphenyl)benzotrien. Sit, 2-(3-tert-butyl_2-trans-yl-5-methylphenyl)_5-chlorobenzotrisene, 2_(3,·second butyl I, yl-5··third Butylphenyl) porphyrin tris, 2-(2,-yl-based-4,octyloxyphenyl)benzotrisyl, 2_(3,5'-di-third amyl-2,- Benzophenyl)benzone 2 [2 yl-3,5 bis(α,α-dimethyl benzyl) stupid]• melon benzotrisole etc. These can be used alone or in two the above. As a better light stabilizer, for example, H double (2, 2, Μ-tetramethyl W-based) vinegar, azelaic acid bis (U, 2, M-five-f base such as bottom bite) vinegar, bismuth Acid bis(N-octyloxy-2,2,Μ·tetramethyl-4·(tetra)fine, I49242.doc -23· 201114821 azelaic acid bis(Ν·benzyloxy-2,2,6,6- Tetramethyl-4 piperidinyl ester, bis(N-cyclohexyloxy-2,2,6,6-tetradecyl-4-piperidyl) sebacate, 2-(3,5 -di-t-butyl-4-hydroxybenzyl)-2-butylmalonic acid bis(l,2,2,6,6-pentamethyl-4-piperidyl) ester, 2,2- Bis(3,5-di-t-butyl-4-hydroxybenzyl)-2-butylmalonic acid bis(1-propene-branched-2,2,6,6-tetradecyl-4- Ethyl ester, bis(2,2,6,6-tetradecyl-4-piperidinyl) succinic acid, 2,2,6,6-tetradecyl-4-methyl methacrylate Pyridyl ester, 4-[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propenyloxy]-l-[2-(3-(3,5-di-third) 4--4-phenylphenyl)propyloxy)ethyl]-2,2,6,6-tetradecyl 0 bottom bit, 2-mercapto-2-(2,2,6,6-tetra Amino-N-(2,2,6,6-tetradecyl-4-piperidyl)propanamide, i,2,3,4-butanetetracarboxylic acid Four (2, 2, 6 ,6-tetramethyl-4-piperazinyl ester; 1,2,3,4-butanetetracarboxylic acid tetrakis(1,2,2,6,6-pentamethyl-4-piperidinyl) ester , 1,2,3,4-butane tetradecanoic acid and 1,2,2,6,6-pentamethyl-4-bridol and 1-tridecanol mixed ester, 1,2, Mixed esterified product of 3,4-butane tetracarboxylic acid with 2,2,6,6-tetramethyl-4-slightly occluded alcohol and 1-trityl alcohol; ι, 2, 3, 4-丁院四曱Acid with 1,2,2,6,6-pentamethyl-4-pipetanol and 3,9-bis(2-hydroxy-1,1-dimercaptoethyl)-2,4,8,1 〇-tetraoxaspiro[5.5] Η--mixed esterified compound, 1,2,3,4-butanetetracarboxylic acid and 2,2,6,6-tetraf-yl-4-piperidinol and 3 , 9·bis(2-hydroxy-1,1-dimercaptoethyl)-2,4,8,10-tetraoxaspiro[5.5]undecane mixed esterified product, butyric acid diterpene vinegar 1_(2-transethylethyl)-4-transyl-2,2,6,6-tetradecyl. Polydextrene at the bottom biting, poly[(6-mimilin-1,3,5-three Plowing 2,4-diyl)((2,2,6,6-tetradecyl-4-piperidinyl)imido)hexamethylene (2,2,6,6-tetramethyl) -4-piperidinyl)imido)], poly[(6-(l,l,3,3-tetramethylbutyl)-l,3,5-trinyl-2,4-diyl) ((2,2,6,6-tetramethyl-4-piperidinyl) Amino) methylene six 149242.doc -24- 201114821 (U, 2, M- bottom bite as tetramethyl-yl) imide or the like can be divided into two or more not used alone. As a method for producing the thermoplastic polymer composition of the present invention, for example, a method of formulating the compound (1), the compound (:), and an optional additive, respectively, in the case of a H-twin thermoplastic polymer; for example, a method comprising the following steps: (1) a step of producing a stabilizer composition by the compound (7) and an optional additive; and a step of mixing the stabilizer composition obtained in the above step into the thermoplastic polymer Φ 丰 σ σ. From the viewpoint of the compound (1) and the compound (2) in the "thermoplastic polymer φ $ A # k knife-scattering property, the latter method is preferred. This f, as a step of producing a stabilizer composition, can also be exemplified by the method exemplified in the method for producing a stabilizer composition to be described later. The step of mixing the stabilizer composition into the thermoplastic polymer is described in more detail. For example, the following method or the like may be mentioned: after the thermoplastic polymer is dry blended with the above stabilizer composition, the uniaxial or multiaxial is utilized. The extruder is subjected to melt-kneading, and then extruded to obtain a thermoplastic polymer composition=particles; for example, a solution obtained by dissolving a stabilizer composition in a solvent such as cyclohexane or the like is added to a crucible group. The ar ice slag is polymerized in the polymer solution after completion of the polymerization, and is subjected to solvent removal. The obtained thermoplastic polymer composition can be directly supplied to a molding machine for molding by a feeling of smelting without cooling. The molding method is not particularly limited. For example, a molding method such as an injection molding method, an extrusion molding method, an extrusion blow molding method, an injection blow molding method, or a biaxial stretching blow molding method can be used. After the forming, cooling is carried out, whereby a thermoplastic polymer molded body comprising the thermoplastic polymer 149242.doc -25·201114821 of the present invention and Q material can be obtained. Examples of the obtained thermoplastic polymerization inhibitor include a bobbin, a connector, a switch, a resistor f, a H relay, a capacitor case, a fuse, a motor, an oven, a brush substrate, and a 1C (integrated circuit). ) Manufacturing and special electronic parts, air outlet garnish, hood (h〇〇d Vent), distributor cover (distributoi·cap), exhaust control and other parts, gears, cams, etc. Parts such as the bottom part, the back cover, the lens barrel, the lever, etc.; the parts such as the reel, the motor housing, the lighting wiring device, the film, the bottle, the septic tank, and the Slot, bath red, unit bath, water Xin medicine. 0 boxes, official, corrugated board, flat, paint, decorative board, electrical parts sealing material, resin concrete, etc. The stabilizer composition of the present invention contains the compound (1) and the compound (2). The stabilizer composition of the present invention is preferably 99.9:0.1 to 5:95 (compound). The weight ratio of the compound (2) to the compound (1) and the compound (2), and the weight ratio of 疋乂98.2 to 1〇:9〇, the compound (1) and the compound are contained, and the stabilizer composition of the present invention can be used as it is. As a force of 35 plastic polymer, stabilize the sheet 11. Χ ' may also contain a modifier in the range which does not impair the effects of the present invention. The preferred additive is, as described above, in the stabilizer composition of the present invention, the amount of the small substance (3) added is from 〇 to 90 parts by weight, more preferably from 0.1 to 80 parts by weight based on the weight of the stabilizer composition. As a method for producing the stabilizer composition of the present invention, for example, U9242.doc -26. 201114821 The compound (1), the compound (2) and optionally the above additives are used in a Henschel mixer, a method of mixing a mixer such as a super mixer or a high-speed mixer; for example, a method of further extruding a mixture of the compound (1), the compound (2), and an additive; for example, A mixture of the compound (1), the compound (2) and the additive is further subjected to a method of granulation and the like. EXAMPLES Hereinafter, the present invention will be described in more detail by way of examples and comparative examples. Unless otherwise stated, parts and % refer to the weight basis. Further, the melt flow rate is described as MFR (Melt Flow Rate). Example 1 (Production of Stabilizer Composition) β-(4,-Hydroxy-3,5,2-di-t-butylphenyl)propanoic acid n-octadecyl ester (BASF) as Compound (1) Manufactured by Japan, irganox (registered trademark) 1076 'hereinafter may be referred to as a compound (!_!)) 〇 48 parts, and mixed with 12 parts of the mannitol oxime as the compound (2) to prepare a stabilizer composition. Examples 2 and 3 (Production of Stabilizer Composition) In Example 1, 'the amount of the compound (丨-丨) was set to 0.3% and 0.12 parts, respectively, and the amount of mannitol used was set to A stabilizer composition was produced in the same manner as in Example 1 except that 〇3 parts and 〇48 parts were used. Example 4 (Production of Thermoplastic Polymer Composition) mm 100 parts of a styrene-butadiene block copolymer produced as a thermoplastic polymer, and a stabilizer composition obtained in Example i, 6 parts dry After blending, the obtained resin composition was subjected to a single-axis extruder (manufactured by Tanabe P丨astics Co., Ltd., VS3〇28 type extruder) having a screw diameter of 30 149242.doc -27- 201114821 at 230 ° C, The mixture was subjected to kneading at a screw rotation speed of 50 rpm to obtain a strand. The strand was cut by a granulator to obtain pellets of a thermoplastic polymer composition. Examples 5 and 6 (Production of Thermoplastic Polymer Composition) In Example 4, the stabilizer composition obtained in each of Examples 2 and 3 was used instead of the stabilizer composition 〇 6 parts obtained in Example 〇 Particles of the thermoplastic polymer composition were obtained in the same manner as in Example 4 except for 6 parts. Comparative Example 1 A thermoplastic polymer composition was obtained in the same manner as in Example 4 except that the compound (1-1) was used in an amount of 6 parts of the stabilizer composition obtained in Example 丨. Particles. Test Example 1 (Processing Stability Test) Each of the pellets obtained in Examples 4 to 6 and Comparative Example was subjected to a retention mfr test as a workability evaluation during the operation at the time of extrusion processing. The test was carried out by setting the inside of the cylinder of the melt indexer (L217-E14011, manufactured by Techno Seven Co., Ltd.) to 270 C according to JIS K 7210, so that the thermoplastic polymer composition was red The MFR at a load of 2.16 kg was determined after π minutes of retention. The results are shown in the table! . The larger the river ^^ value, the more excellent the processing stability. The so-called processing stability improvement rate in Table 1 is obtained by the following formula. (Processing stability improvement rate) = (MFR value measured in the example - MFR value measured in 149242.doc -28 - 201114821 in Comparative Example i) / MFR value measured in Comparative Example 1 x 100 [Table 1]

化合物(1-1) 份數[重量比] 甘露糖醇 份數[重量比1 MFR值 加工 f〇/n\ 實施例4 0.48 [8] 0.12 P] 14.8 279s-— 實施例5 0.30 [5] 0.30 [5] 14.9 一-__ 282l~~~~~~~~ 實施例6 0.12 Μ 0.48 [8] 14.1 ~261 s 比較例1 0.60 [10] 0.00 [〇] 3.9 —____fOl.J 實施例7(穩定劑組合物之製造) 將作為化合物(1)之3,9-雙[2-(3-(3-第三丁基_4_羥基_5•曱 基苯基)丙醯氧基二曱基乙基]_2,4,8,1〇_四氧雜螺 [、5·5]十一院(住友化學製造,SumUizer(註冊商標)ga_8〇 以下有時記作化合物(1-2))0.1份、與作為化合物(2)之甘露 糖醇0.1份混合,而製造穩定劑組合物。 實施例8(穩定劑组合物之製造) 於實施例7中,使用山梨糖醇作為化合物(2),除此以 外,與實施例7同樣地製造穩定劑組合物。 實施例9(熱塑性聚合物組合物之製造) 將作為熱塑性聚合物之住友化學製造之聚丙烯1〇〇份、 與實施例7中所得之穩定劑組合物〇·2份乾式摻合後,對所 得之樹脂組合物使用螺桿直徑為3〇 mm之單軸擠出機 (Tanabe Plastics公司製造’ VS3〇_28型擠出機),於 23〇°C、螺桿轉速50 rpm下混練擠出而獲得繩股,利用造 粒機將該繩股切斷而獲得熱塑性聚合物組合物之顆粒 實施例10(熱塑性聚合物組合物之製造) 於實施例9中,代替實施例7中 戶斤知'之穩定劑組合物而使 149242.doc -29- 201114821 用0.2份之實施例8中所得之穩定劑組合物,除此以外,與 實施例9同樣地獲得熱塑性聚合物組合物之顆粒。 比較例2 於實施例9中’代替實施例7中所得之穩定劑組合物而使 用0.1份之化合物(1-2) ’除此以外’與實施例9同樣地獲得 熱塑性聚合物組合物之顆粒。 試驗例2(加工穩定性試驗) 對實施例9、10及比較例2中獲得之各顆粒,實施滯留 MFR試驗作為擠出加工時之運轉時之加工性評價。試驗係 藉由如下方式而實施,依據JIS K 721〇,將熔融指數測定 儀(L217-E14011,Techno Seven公司製造)之料缸内設定為 2 7 0 C ’於該料缸内填充熱塑性聚合物組合物,使熱塑性 聚合物組合物於該料缸内滯留30分鐘後測定負載2.丨6 kg下 之MFR。結果示於表2。 於聚丙烯之情形時,滞留30分鐘後之MFR越小則加工性 越好。 [表2] 化合物(1-2) 份數[重量比1 化合物(2) 份數丨重量比] 滯留30分鐘後 MFR值 實施例9 0.1 [5] 甘露糖醇 0.1 「51 16.6 實施例10 0.1 [5] 山梨糖醇 0.1 Γ51 17.9 比較例2 0.1 [10] ο Γ01 「22.8 實施例11 (穩定劑組合物之製造) 將作為化合物(1)之季戊四醇四[3-(3,5-二-第三丁基_4_羥 基本基)丙酸g旨](BASF Japan公司製造’ Irganox(註冊商 149242.doc •30- 201114821 標)1010 ’以下有時記作化合物(1_3))0丨份、與作為化合 (2)之甘露糖醇G.G1份混合,而製造穩定劑組合物。 實施例12(穩定劑組合物之製造) 於實施例11中,使用山梨糖醇作為化合物(2),除此以 外,與實施例11同樣地製造穩定劑組合物。 以 實施例13(熱塑性聚合物組合物之製造) 將作為熱塑性聚合物之住友化學製造之聚乙烯1〇〇份、 與實施例11中獲得之穩定劑組合物〇丨丨份乾式摻合後,對 所得之樹脂組合物使用螺桿直徑為3〇 mm之單軸擠出機 (Tanabe Plastics公司製造,VS3〇_28型擠出機),於 230°C、螺桿轉速50 rpm下混練擠出而獲得繩股,利用造 粒機將該繩股切斷而獲得熱塑性聚合物組合物之顆粒。 實施例14(熱塑性聚合物組合物之製造) 於實施例13中,代替實施例丨丨中所得之穩定劑組合物而 使用0.11份之實施例12中所得之穩定劑組合物,除此以 外’與實施例13同樣地獲得熱塑性聚合物組合物之顆粒。 比較例3 於實施例13中,代替實施例丨丨中所得之穩定劑組合物而 使用0.1份之化合物(1 -3),除此以外,與實施例13同樣地 獲得熱塑性聚合物組合物之顆粒。 試驗例3(加工穩定性試驗) 對實施例12、13及比較例3中獲得之各顆粒,實施滞留 MFR試驗作為擠出加工時之運轉時之加工性評價。試驗係 藉由如下方式而實施,依據JIS K 7210,將熔融指數測定 149242.doc •31- 201114821 儀(L217-E14011,Techno Seven公司製造)之料缸内設定為 270°C,使熱塑性聚合物組合物於該料缸内滯留30分鐘後 測定負載2.16 kg下之MFR。結果示於表3。 於聚乙烯之情形時,MFR之變化之保持率越大則加工穩 定性越優異。Compound (1-1) Parts [weight ratio] mannitol parts [weight ratio 1 MFR value processing f〇/n\ Example 4 0.48 [8] 0.12 P] 14.8 279s-- Example 5 0.30 [5] 0.30 [5] 14.9 I-__ 282l~~~~~~~~ Example 6 0.12 Μ 0.48 [8] 14.1 ~261 s Comparative Example 1 0.60 [10] 0.00 [〇] 3.9 —____fOl.J Example 7 ( Manufacture of Stabilizer Composition) 3,9-bis[2-(3-(3-t-butyl-4-hydroxyl-5)nonylphenyl)propoxy quinone as compound (1) Ethylethyl]_2,4,8,1〇_tetraoxaspiro[,5·5] Eleventh Institute (manufactured by Sumitomo Chemical Co., Ltd., SumUizer (registered trademark) ga_8〇 is sometimes referred to as compound (1-2)) 0.1 part and 0.1 part of mannitol as the compound (2) were mixed to prepare a stabilizer composition. Example 8 (Production of Stabilizer Composition) In Example 7, sorbitol was used as the compound (2) A stabilizer composition was produced in the same manner as in Example 7. Example 9 (Production of Thermoplastic Polymer Composition) Polypropylene manufactured by Sumitomo Chemical Co., Ltd. as a thermoplastic polymer, and Example 7 Stabilizer composition obtained in 〇· After 2 parts of dry blending, a uniaxial extruder having a screw diameter of 3 mm (a VS3〇_28 type extruder manufactured by Tanabe Plastics Co., Ltd.) was used for the obtained resin composition at 23 ° C, screw rotation speed. The strands were obtained by kneading at 50 rpm, and the strands were cut by a granulator to obtain pellets of the thermoplastic polymer composition. Example 10 (Production of Thermoplastic Polymer Composition) In Example 9, instead of implementation A thermoplastic polymer was obtained in the same manner as in Example 9 except that the stabilizer composition obtained in Example 8 was used in Example 197242.doc -29-201114821. Granules of the composition. Comparative Example 2 In the same manner as in Example 9, except that the stabilizer composition obtained in Example 7 was used instead of the stabilizer composition obtained in Example 7, except that 0.1 part of the compound (1-2) was used. Particles of the composition of the composition. Test Example 2 (Processing Stability Test) Each of the pellets obtained in Examples 9, 10 and Comparative Example 2 was subjected to a retention MFR test as a workability evaluation during the operation at the time of extrusion processing. Implemented as follows According to JIS K 721, a melt indexer (L217-E14011, manufactured by Techno Seven Co., Ltd.) is set in a cylinder of 270 C' to fill the cylinder with a thermoplastic polymer composition to make a thermoplastic polymer composition. After staying in the tank for 30 minutes, the MFR at a load of 2. 6 kg was measured. The results are shown in Table 2. In the case of polypropylene, the smaller the MFR after 30 minutes of residence, the better the processability. [Table 2] Compound (1-2) Parts [Weight ratio 1 Compound (2) Parts 丨 Weight ratio] MFR value after retention for 30 minutes Example 9 0.1 [5] Mannitol 0.1 "51 16.6 Example 10 0.1 [5] Sorbitol 0.1 Γ 51 17.9 Comparative Example 2 0.1 [10] ο Γ 01 "22.8 Example 11 (Production of Stabilizer Composition) Pentaerythritol tetra[3-(3,5-di-) as Compound (1) Third butyl 4-(hydroxyl-hydroxy)propionic acid g] (manufactured by BASF Japan Corporation 'Irganox (Registry 149242.doc • 30- 201114821) 1010 'hereinafter sometimes referred to as compound (1_3)) 0 丨And a stabilizer composition was prepared by mixing with mannitol G.G1 as a compound (2). Example 12 (Production of Stabilizer Composition) In Example 11, sorbitol was used as the compound (2) A stabilizer composition was produced in the same manner as in Example 11. The same procedure as in Example 11 was carried out. Example 13 (Production of Thermoplastic Polymer Composition) Polyethylene manufactured by Sumitomo Chemical Co., Ltd. as a thermoplastic polymer, and Examples After the dry blending of the stabilizer composition obtained in 11 is carried out, a screw is used for the obtained resin composition. A single-axis extruder with a diameter of 3 mm (manufactured by Tanabe Plastics Co., Ltd., VS3〇_28 extruder), which was kneaded and extruded at 230 ° C and a screw speed of 50 rpm to obtain strands, which were granulated by a granulator. The strands were cut to obtain pellets of the thermoplastic polymer composition. Example 14 (Production of Thermoplastic Polymer Composition) In Example 13, 0.11 part was used instead of the stabilizer composition obtained in Example The particles of the thermoplastic polymer composition were obtained in the same manner as in Example 13 except that the stabilizer composition obtained in Example 12 was used. Comparative Example 3 In Example 13, the stabilizer combination obtained in the following Example 代替 was used. Particles of the thermoplastic polymer composition were obtained in the same manner as in Example 13 except that 0.1 part of the compound (1-3) was used. Test Example 3 (Processing Stability Test) For Examples 12 and 13 and Comparative Example Each of the particles obtained in 3 was subjected to a retention MFR test as a workability evaluation during the operation at the time of extrusion processing. The test was carried out by the following method, and the melt index was measured according to JIS K 7210, 149242.doc • 31-201114821 (L 217-E14011, manufactured by Techno Seven Co., Ltd., was set at 270 ° C, and the thermoplastic polymer composition was retained in the tank for 30 minutes, and the MFR at a load of 2.16 kg was measured. The results are shown in Table 3. In the case of ethylene, the greater the retention of the change in MFR, the more excellent the processing stability.

MFR保持率(%) =滯留30分鐘後之MFR/滞留前之MFRxlOOMFR retention rate (%) = MFR after retention for 30 minutes / MFRx100 before retention

[表3] 化合物(1-3) 份數[重量比] 化合物(2) 份數[重量比] 滯留前之 MFR 滯留30分鐘 後之MFR MFR保持率 (%) 實施例13 0.1 [10] 甘露糖醇 0.01 [0.11 9.2 8.8 95 實施例14 0.1 [10] 山梨糖醇 0.01 [0.11 9.4 8.8 94 比較例3 0.1 [10] 0 [0] 9.7 8.7 90 產業上之可利用性 本發明之熱塑性聚合物組合物由於具有優異之加工穩定 性,故可合適地用於食品包裝容器、日用雜貨品。 149242.doc 32-[Table 3] Compound (1-3) Parts [weight ratio] Compound (2) Parts [weight ratio] MFR retention before retention MFR MFR retention rate after 30 minutes retention Example 13 0.1 [10] Manna Sugar alcohol 0.01 [0.11 9.2 8.8 95 Example 14 0.1 [10] Sorbitol 0.01 [0.11 9.4 8.8 94 Comparative Example 3 0.1 [10] 0 [0] 9.7 8.7 90 Industrial Applicability The thermoplastic polymer of the present invention Since the composition has excellent processing stability, it can be suitably used for food packaging containers and daily sundries. 149242.doc 32-

Claims (1)

201114821 七、申請專利範圍: 1. 一種穩定劑組合物,其含有式(1)所表示之化合物:201114821 VII. Patent Application Range: 1. A stabilizer composition containing the compound represented by formula (1): (1) (式中,R1及R2分別獨立表示氫原子或碳數丨〜6之烷基, X表示可含有雜原子及/或環狀基之碳數〗〜242n價的醇 殘基,m表示1〜4之整數;其中所謂醇殘基,表示自醇之 OH去掉Η後之基)、及 式(2)所表示之化合物: (2) ^ηΗ.2η+ 2〇η (式中,η表示4〜12之整數)。 2.如請求❸之穩㈣組合物,其中式⑴所表示之化合物 為P(4沒基_3,,5,_二_第三丁基苯基)丙酸正十八炫基 部第三丁基领基·5·甲基苯基)丙酿氧 2 广一甲基乙基]_2,4,8’1〇_四氧雜螺[5·5]十-烷或季 戍四醇四[3-(3 5 -兹-丁 I , 3如抹本(,5·一 ·第二丁基經基苯基)丙酸醋]。 月項1之穩定劑組合物,立中 為阿洛糖醇一…t 表示之化合物 醇或甘露糖醇。 山采糖転、塔羅糖 4.如請求jg 1 之穩定劑組合物,盆中々 為阿洛糖& ^ f式(2)所表示之化合物 w %、艾杜糖醇、半 礼糖知、山梨糖醇、塔羅糖 149242.doc 201114821 醇或甘露糖醇。 5_ 6. 種熱塑性聚合物組合物,复 求項1之籍^ 〇物〃 3有熱塑性聚合物及如請 所表_〜劑組合物’且式⑴所表示之化合物與式⑺ 量份為〜3重量份 熱塑性聚合物_重 項5之聚合物組合物,其中式⑴所表示 =广基一第三丁基苯基)丙酸正十八烧基 曰 ,9-雙[2·(3,(3_第=丁其 4 Μ_ | 基}-1 1弟—丁基羥基巧-甲基苯基)丙醯氧 ,—甲基乙基]-2,4,8,10-四氧雜螺[5.5]十一烷或 戍四醇四[3_(3 s -势_ (,一·弟二丁基_4-羥基苯基)丙酸酯]。 奮求項5之聚合物組合物,其中式⑺所表示之化合物 醇:各糖醇、艾杜糖醇、半乳糖醇、山梨糖醇、塔羅糖 和或甘露糖醇。 8 ^永項6之聚合物組合物’其中式⑺所表示之化合物 醢二各糖醇、艾杜糖醇、半乳糖醇、山梨糖醇、塔羅糖 醇或甘露糖醇。 9. 熱塑性聚合物組合物之製造方法其包括於熱塑性 聚口物中混合如請求項1之穩定劑組合物之步驟。 1 0. 一 如士主出 叫,項1之穩定劑組合物之用途,其係用於使熱 塑性聚合物加工穩定化。 149242.doc 201114821 四、指定代表圖·· (一) 本案指定代表圖為:(無) (二) 本代表圖之元件符號簡單說明: 五、本案若有化學式時,請揭示最能顯示發明特徵的化學式: (無) 149242.doc(1) (wherein R1 and R2 each independently represent a hydrogen atom or an alkyl group having a carbon number of 丨~6, and X represents an alcohol residue having a carbon number of ~2422 n which may contain a hetero atom and/or a cyclic group, m An integer of 1 to 4; wherein the alcohol residue represents a group derived from the OH of the alcohol, and a compound represented by the formula (2): (2) ^ηΗ.2η+ 2〇η (wherein, η represents an integer of 4 to 12). 2. The composition of the stable (four) composition, wherein the compound represented by the formula (1) is P (4 meryl _3, 5, _ _ _ _ butyl phenyl) propionic acid Alkyl-5·methylphenyl)propanol 2 broad monomethylethyl]_2,4,8'1〇_tetraoxaspiro[5·5]deca-alkane or quaternary tetral tetraol 3-(3 5 -z-but I, 3 such as smear (5·1·t-butyl phenylphenyl) propionic acid vinegar]. Stabilizer composition of the monthly item 1, the middle is the allose Alcohol-...t represents a compound alcohol or mannitol. Mountain sugar lozenge, tarotose 4. If a stabilizer composition of jg 1 is requested, the pot in the pot is aloeose & ^ f formula (2) Compound w%, iditol, saponin, sorbitol, talose 149242.doc 201114821 Alcohol or mannitol. 5_ 6. Thermoplastic polymer composition, resolving item 1 〃 3 has a thermoplastic polymer and a polymer composition represented by the formula (1) and a compound represented by the formula (7) in an amount of 〜3 parts by weight of the thermoplastic polymer _ weight 5, wherein the thermoplastic polymer and the formula (1) Represented = broad base - tert-butylphenyl) Acid is an octadecyl ruthenium, 9-bis[2·(3,(3_第=丁其4 Μ_ | 基}-1 1 —-butyl hydroxy-methylphenyl) propyl oxime, - A Ethylethyl]-2,4,8,10-tetraoxaspiro[5.5]undecane or perylenetetraol tetra[3_(3 s -potential _ (, 1,4-dibutyl-4-hydroxyphenyl) Propionate. The polymer composition of claim 5, wherein the compound alcohol represented by formula (7): each sugar alcohol, iditol, galactitol, sorbitol, talose, and or mannitol 8 ^ The polymer composition of the permanent 6 'wherein the compound represented by the formula (7) is disaccharide, iditol, galactitol, sorbitol, talitol or mannitol. A method of making a polymer composition comprising the step of mixing a stabilizer composition of claim 1 in a thermoplastic dispenser. 1 0. The use of the stabilizer composition of item 1, the use of the stabilizer composition of item 1, It is used to stabilize the processing of thermoplastic polymer. 149242.doc 201114821 IV. Designation of representative drawings (1) The representative representative of the case is: (none) (2) Simple description of the symbol of the representative figure: When the case if the formula, please reveal the best features of the invention show a chemical formula: (None) 149242.doc
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