TW201107838A - Liquid crystal display device - Google Patents

Liquid crystal display device Download PDF

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Publication number
TW201107838A
TW201107838A TW99118844A TW99118844A TW201107838A TW 201107838 A TW201107838 A TW 201107838A TW 99118844 A TW99118844 A TW 99118844A TW 99118844 A TW99118844 A TW 99118844A TW 201107838 A TW201107838 A TW 201107838A
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TW
Taiwan
Prior art keywords
light source
liquid crystal
light
film
crystal display
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Application number
TW99118844A
Other languages
Chinese (zh)
Inventor
Seiji Muro
Miho Mori
Akiyoshi Kanemitsu
Original Assignee
Sumitomo Chemical Co
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Publication of TW201107838A publication Critical patent/TW201107838A/en

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    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/1336Illuminating devices
    • G02F1/133615Edge-illuminating devices, i.e. illuminating from the side
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/0001Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
    • G02B6/0011Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
    • G02B6/0033Means for improving the coupling-out of light from the light guide
    • G02B6/0035Means for improving the coupling-out of light from the light guide provided on the surface of the light guide or in the bulk of it
    • G02B6/0038Linear indentations or grooves, e.g. arc-shaped grooves or meandering grooves, extending over the full length or width of the light guide
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/0001Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
    • G02B6/0011Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
    • G02B6/0033Means for improving the coupling-out of light from the light guide
    • G02B6/0035Means for improving the coupling-out of light from the light guide provided on the surface of the light guide or in the bulk of it
    • G02B6/0045Means for improving the coupling-out of light from the light guide provided on the surface of the light guide or in the bulk of it by shaping at least a portion of the light guide
    • G02B6/0046Tapered light guide, e.g. wedge-shaped light guide
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/0001Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
    • G02B6/0011Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
    • G02B6/0033Means for improving the coupling-out of light from the light guide
    • G02B6/005Means for improving the coupling-out of light from the light guide provided by one optical element, or plurality thereof, placed on the light output side of the light guide
    • G02B6/0053Prismatic sheet or layer; Brightness enhancement element, sheet or layer
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133504Diffusing, scattering, diffracting elements

Abstract

The present invention provides a liquid crystal display device which comprises an area light source and a liquid crystal panel arranged on the area light source, the liquid crystal panel comprising a liquid crystal cell and a polarizing plate laminated on the area light source side surface of the liquid crystal cell, wherein the polarizing plate comprises a polarizing film and a prismatic sheet having a surface formed of prismatic protrusions, the prismatic sheet being such arranged that the surface formed of the prismatic protrusions opposes to the area light source, wherein light intensity distribution of emitting light of the area light source within a plane which is orthogonal to a prismatic direction of the prismatic protrusions satisfies the following inequality (1): A2/A1> 10 (1) [Wherein A1 is an average light intensity of emitting light in the range of 0 DEG to x of emitting angle θ , if an angle formed by a normal direction to a light emitting surface of the area light source and an emitting direction of the emitting light of the area light source is defined as emitting angle θ , and A2 is an average light intensity of emitting light in the range of x to 80 DEG of emitting angle θ , wherein x is an angle (DEG) satisfying a predetermined relationship.] Thereby, the present invention provides a liquid crystal display device having high brightness and contrast, and having excellent display proprieties.

Description

201107838 六、發明說明: 【發明所屬之技術領域】 液晶螢幕、個人電腦等 本發明係關於用於液晶電視 的液晶顯示裝置。 【先前技術】 =裝:作為用於液晶電視人電 ==τ之用途係'急速擴大。液晶電視的市場 擴大尤其,W此外,低成本化的要求 … 裝置係由下述者所構成::用冷陰極 源、光擴散板'一個或複數個擴散片、集 ,片全U及貼合有偏光板的“面板。近年來,在可壁掛 式大旦面液晶電视用途等方面,由於顯現出對液晶顯示裝 置涛型化的要未,在此情形下,為了達成液晶顯示裝置的 薄型化’必須將用於該液晶_示裝置的構件予以薄壁化、 及削減構件數目。 對於此種需求,已知有藉由下列方法而除去一個或複 數個構件以削減零件數目的技術:將具有集光性的稜鏡片 (prism sheet)直接接著在配置於構成液晶面板的液晶單 元(liquid crystal cell)與面光源之間的偏光板之單免的 方法(例如 JPH11-295714-A 以及 JP2008-262132-A)、我使 用集光性稜鏡片作為配置於液晶面板的面光源側之偏光板 的保護膜的方法(例如JP2008-262132-A以及 JP2005-17355-A) 0 如上述文獻中所記載’在使用具備棱鏡片等薄片機件 4 3々12〇 201107838 的偏光板之液晶顯示裝置中,依據所使用之面光 •的光射出特性,有無法充分地發揮薄片構件所預期的年光 *功能,而造成亮度、對比度等顯示特性下降的情形。、 【發明内容】 / 本發明係為解決上述課題而研創者,本發明之 提供-種亮度及對比度高、顯示特性優異的液晶顯示褒置。、 本發明係關於一種液晶顯示裳i,其 二於該面光源上且具備液晶單元及積 層於该液…的面光源側的面之偏光板的液晶面板。 發明之液晶顯示裝置中,上述偏光板係具備:偏光膜;以 =得由稜鏡狀突起所構成的表面相對向於面光源:此 垂直晶顯示裝置’在與稜鏡狀突起的稜線方向 式⑴: ⑽出先之先強度分佈係滿足下述 Α2/Α1&gt;1〇 ⑴。 的二料⑴中’A1 m述與稜鏡狀突起 方二盘、…之平面内’將由面光源的光射出面之法線 方向與面光源的射出光之射出方向 射备 度Θ(惟〇。以$9〇。)時角又°又為射出角 的射出光之平灼弁㈣ 出角度0在『至X的範圍内 ㈣出先之千均先強度;A2為射出角 圍内的射出光之平均光強度。此 8° = 關係之角度(。)·· 係滿足下述式(2)的 322120 5 201107838 sina/[sin(180o-a_2x)/2] = n ⑵。 /於此,在上述式(2)中,α係表示稜鏡狀突起之頂角, π係表示棱鏡狀突起的折射率。 本發明之液晶顯示裝置中,上述面光源較宜由導光 板、以及配置於該導光板側方的光源裝置所構成。此外, 光源裝置較宜為將點狀光源予以線性排列而成的光源裝置 或由棒狀光源所構成的光源裝置,且光源裝置與稜鏡片係 較宜配置成使光源裝置與稜鏡狀突起之稜線平行或約略平 行。 本發明之液晶顯示裝置中,上述面光源較宜具有配置 於導光板的-邊之-個統裝置或配置於導光板相對向的 兩邊之2個光源裝置。 稜鏡狀突起的頂角α較佳為60。以上。此外,稜鏡狀 大起的剖面形狀較佳為二等邊三角形。 本發明之液晶顯示裝置在薄型化的同時,亮度及對比 度高’且顯示特性優異。本發明之液晶顯示裝置可應用為 大晝面液晶電視用液晶顯示裝置,特別是可壁掛式液晶電 視用液晶顯示裝置等。 【實施方式】 第1圖係顯示本發明液晶顯示裝置的一較佳例之概略 剖視圖。本發明第J圖所示的液晶顯示裝置100係由下列 者所構成:具備導光板22以及在導光板22側方沿著導光 板22的一邊配置的光源裝置21之面光源20 ;以及配置於 面光源20上的液晶面板1〇。液晶面板1〇係由下列者所組 322120 6 201107838 成· U70 3 ;偏光板1,其係積層於液晶單元3之面光 源20α侧的面之者面侧偏光板;以及偏光板2,其係積層於 &amp;曰曰單70 3之目視側的面之前面側偏光板。偏光板1及偏 光板2 _域著劑層Π貼合於液晶單元3。 屬於月面側偏光板的偏光板1具備 :偏光膜12 ;經由 接著劑層14積層於偏光膜12的面光源動彳表面的棱鏡片 13 ’該^鏡片13具有由稜鏡狀突起13a所構成的表面(以 下亦無為彳夂鏡面)’經由接著劑層16積層於偏光膜12的目 視側表面的樹脂膜〗c;。, 聘15。偏先板1係以其樹脂膜15側而貼 °於液曰曰單70 3 °更具體而言,液晶單元3及偏光板1係 以偏光膜12的與積層有稜鏡片13的面為相反侧的面係 相=向於液晶單元3」之方式貼合,亦即,以「稜鏡片η r 係域液晶面板1G的面光源側表面,且該稜鏡面 ^ ^於面光源2G」之方式進行貼合。再者,在本發明 膜12 η Z偏光板亦可不具有此種樹脂膜,而亦可為偏光 膜12J;岭㈣層等直接貼合於液晶單元3之構成。 偏光;s '、本^明之液晶顯示裝置係為使用背面 ==晶顯示裝置,其中該背面侧偏光板係具有經 層於偏先棋表面的棱鏡片,而如後文中所 構成之_下2用··在與稜鏡片所具有之稜鏡狀突起的 性(何種裎库’具有特定光射出特性(具體而言乃配光特 據本發明光朝何種方向射出))的面光源。根 S] 液晶顯示裝置,二種使用具有稜鏡片之背面側偏光板的 χ ,/、為亮度及對比度高之顯示特性優異的液^ 322120 7 201107838 晶顯示裝置。此外,本發明之液晶顯示裝置由於具備在液 晶單元背面侧貼合有已達成薄型化之偏光板的液晶面板, 故可達成薄壁化,且仍具有充分的機械強度,同時,由於 稜鏡片係配置於液晶面板的背面側,故可防止液晶面板與 面光源的緊在、接觸,藉此亦達成顯示特性的改善。以下係 參照適且圖式’對本發明之液晶顯示裝置予以詳細說明。 〈背面側偏光板〉 第2圖係顯示用於本發明之背面侧偏光板的一較佳例 之概略剖視圖,其構成與第1圖中的偏光板丨相同(元件符 號亦相同)》如第2圖所示的例子,用於本發明之背面側偏 光板至少具備.偏光膜12,經由接著劑層14積層於偏光 膜12的單侧表面(面光源側表面)的稜鏡片,該稜鏡片 13具有由稜鏡狀突起13a所構成的表面(稜鏡面)。如第2 圖所示的偏光板1,背面側偏光板亦可具備經由接著劑層 16而積層於與稜鏡片13所積層的面為相反側的面(液晶單 元側的面)之樹脂膜15。 (偏光膜) 具體而言,用於背面偏光板的偏光膜12係使二色性色 素吸附配向於單軸延伸後之聚乙烯醇系樹脂膜而成者。可 使用聚醋酸乙烯酯系樹脂經皂化後所得者作為構成聚乙烯 醇系樹脂膜之聚乙烯醇系樹脂。就聚醋酸乙烯酯系樹脂而 言,除了屬於醋酸乙烯酯的均聚物之聚醋酸乙烯酯之外, 可列舉醋酸乙烯酯及可與醋酸乙烯酯共聚合之其他單體的 共聚物,例如乙烯-醋酸乙稀酯共聚物等。可與醋酸乙烯酯 322120 8 201107838 乙稀 共聚合之其他單體可列舉如不飽和舰_ 醚類、不飽㈣_ '具有錄之丙__等。、 聚乙稀醇系樹月旨的矣化度通常為約85至剛草耳〇/ (mole%),較佳為 98 莫# 、 0 改暂去w 料%以上^乙_系樹脂亦可為經 f亦可使用經醛類改質之聚乙烯縮曱醛 P〇 yvinyl for.al) ^ 6^(p〇lyvinyi ^ 的聚合==一 通^為約刚^至剛⑽,較佳為約胸至5000。 將此種聚已婦醇系樹脂製膜後所得者使用作為偏光膜 的原材膜。將聚乙埽醇系樹脂製膜的方法沒有特別限定, 可利用以往公知的適宜方法進行製膜。由聚乙烯醇系樹脂 所成之原材膜的膜厚沒有特別限定,例如為約丨〇至 150 &quot; m 〇 偏光膜通常係經由下列步驟製造:將如上述由聚乙蝉 醇系樹&amp;所成之原材膜以二色性色素染色*使該二色性色 素,附的^驟(染色處理步驟);將吸附有二色性色素的聚 乙烯醇系树脂膜以硼酸水溶液處理的步驟(硼酸處理步 以及在藉由顯水溶液所進行的該處理後進行水洗的 步驟(水洗處理步驟)。 έ«ι sg 四此外’在製造偏光膜之際,通常聚乙烯醇系樹脂膜係 早軸延伸,卿軸延伸可在染色處理步驟之前進行,亦 广在染色處理步驟+進行,亦可錢色處理步驟之後進 在耗處理步社後進行科延伸的情财,該單軸 可在硼酉夂處理步驟之前進行,亦可在棚酸處理步驟中 322120 9 201107838 進仃。當然,亦可在該等複數個階段進行單軸延伸。單軸201107838 VI. Description of the Invention: [Technical Field of the Invention] Liquid crystal screen, personal computer, etc. The present invention relates to a liquid crystal display device for a liquid crystal television. [Prior Art] = Packing: As a use for LCD TVs, the use of human power ==τ is rapidly expanding. In particular, the market for LCD TVs is expanding. In addition, the requirements for cost reduction are as follows: The device is composed of: a cold cathode source, a light diffusing plate, one or a plurality of diffusing sheets, a set, a piece of U, and a bonding. "Panels with polarizing plates. In recent years, in the use of wall-mounted large-density LCD TVs, etc., due to the emergence of a liquid crystal display device, in this case, in order to achieve a thin liquid crystal display device It is necessary to thin the members of the liquid crystal display device and reduce the number of components. For such a demand, there is known a technique for removing one or a plurality of members to reduce the number of parts by the following method: A prism sheet having a condensing property is directly followed by a method of arranging a polarizing plate between a liquid crystal cell constituting a liquid crystal panel and a surface light source (for example, JPH11-295714-A and JP2008-) 262132-A), I use a light-collecting sheet as a protective film for a polarizing plate disposed on the surface light source side of a liquid crystal panel (for example, JP2008-262132-A and JP2005-17355-A). In the liquid crystal display device using a polarizing plate having a sheet member such as a prism sheet, such as a prism sheet, 3 3々12〇201107838, depending on the light emission characteristics of the surface light used, the sheet member is not expected to be sufficiently exhibited. In the case of the annual light* function, the display characteristics such as brightness and contrast are degraded. [Invention] The present invention has been developed to solve the above problems, and the present invention provides a high brightness and contrast and excellent display characteristics. The present invention relates to a liquid crystal display panel, and a liquid crystal panel comprising a liquid crystal cell and a polarizing plate laminated on a surface of the liquid source on the surface light source. In the device, the polarizing plate is provided with a polarizing film; the surface formed by the beak-like protrusions is opposite to the surface light source: the vertical crystal display device 'before the ridgeline direction of the conical protrusions (1): (10) The first intensity distribution satisfies the following Α2/Α1&gt;1〇(1). In the second material (1), 'A1 m is described in the plane of the two-disk, the plane of the 稜鏡-shaped protrusion, which will be emitted by the surface light source. The direction of the normal direction of the surface and the direction of the exit light of the surface light source are 射 (only 〇. with $9〇.) The angle of time is also the angle of the exiting light of the exit angle (4) The angle 0 is at "to X" In the range of (4) the first thousand first intensity; A2 is the average light intensity of the emitted light in the exit angle. This 8° = the angle of the relationship (.)·· is 322120 5 201107838 sina that satisfies the following formula (2) /[sin(180o-a_2x)/2] = n (2) Here, in the above formula (2), α represents the vertex angle of the dome-like protrusion, and π represents the refractive index of the prism-shaped protrusion. In the liquid crystal display device of the present invention, the surface light source is preferably composed of a light guide plate and a light source device disposed on the side of the light guide plate. Further, the light source device is preferably a light source device in which a point light source is linearly arranged or a light source device composed of a rod-shaped light source, and the light source device and the cymbal blade are preferably arranged such that the light source device and the dome-like projection are The ridgelines are parallel or approximately parallel. In the liquid crystal display device of the present invention, it is preferable that the surface light source has a device disposed on the side of the light guide plate or two light source devices disposed on opposite sides of the light guide plate. The apex angle α of the dome is preferably 60. the above. Further, the cross-sectional shape of the braided shape is preferably a equilateral triangle. The liquid crystal display device of the present invention has a high brightness and contrast while being thinned, and is excellent in display characteristics. The liquid crystal display device of the present invention can be applied to a liquid crystal display device for a large-surface liquid crystal television, in particular, a liquid crystal display device for a wall-mounted liquid crystal television. [Embodiment] Fig. 1 is a schematic cross-sectional view showing a preferred embodiment of a liquid crystal display device of the present invention. The liquid crystal display device 100 shown in Fig. J of the present invention is composed of a light guide plate 22 and a surface light source 20 of the light source device 21 disposed along one side of the light guide plate 22 on the side of the light guide plate 22; The liquid crystal panel 1 on the surface light source 20 is turned on. The liquid crystal panel 1 is composed of the following: 322120 6 201107838, U70 3 ; a polarizing plate 1 which is laminated on the surface side polarizing plate of the surface of the liquid crystal cell 3 on the surface of the light source 20α; and a polarizing plate 2 The surface side polarizing plate is laminated on the side of the visual side of the & The polarizing plate 1 and the polarizing plate 2_domain layer are bonded to the liquid crystal cell 3. The polarizing plate 1 belonging to the moon-side polarizing plate includes a polarizing film 12, and a prism sheet 13 which is laminated on the surface of the surface of the polarizing film 12 via the adhesive layer 14. The lens 13 has a dome-like projection 13a. The surface (hereinafter referred to as "mirror surface") is a resin film laminated on the visual side surface of the polarizing film 12 via the adhesive layer 16. , hire 15. The partial first plate 1 is attached to the liquid helium sheet by the resin film 15 side, and more specifically, the liquid crystal cell 3 and the polarizing plate 1 are opposite to the surface of the polarizing film 12 which is laminated with the tantalum sheet 13 The side surface phase is bonded to the liquid crystal cell 3", that is, in the manner of "the surface of the surface light source side of the ηr-rectifier liquid crystal panel 1G, and the surface of the surface is 2G" Make a fit. Further, in the film 12 η Z polarizing plate of the present invention, the resin film may not be provided, and the polarizing film 12J or the ridge layer may be directly bonded to the liquid crystal cell 3. The polarized light; s ', the liquid crystal display device of the present invention is a rear surface == crystal display device, wherein the back side polarizing plate has a prism sheet which is layered on the surface of the first chess, and is formed as follows. A surface light source that has a shape-like protrusion (which kind of banknotes) having a specific light-emitting property (specifically, in which direction the light is emitted according to the present invention). Root S] Liquid crystal display device, two types of liquid crystal display devices using 背面, /, which have excellent display characteristics with high brightness and contrast, using a back side polarizing plate having a cymbal sheet. Further, since the liquid crystal display device of the present invention includes a liquid crystal panel in which a polarizing plate that has been reduced in thickness is bonded to the back surface side of the liquid crystal cell, it is possible to achieve a reduction in thickness and sufficient mechanical strength, and at the same time, Since it is disposed on the back side of the liquid crystal panel, it is possible to prevent the liquid crystal panel from coming into contact with the surface light source, thereby achieving an improvement in display characteristics. Hereinafter, the liquid crystal display device of the present invention will be described in detail with reference to the drawings. <Back Side Polarizing Plate> Fig. 2 is a schematic cross-sectional view showing a preferred example of the back side polarizing plate of the present invention, and the configuration is the same as that of the polarizing plate 第 in Fig. 1 (the same symbol is used). In the example shown in FIG. 2, the back side polarizing plate of the present invention includes at least a polarizing film 12, and a ruthenium laminated on the one-side surface (surface light source side surface) of the polarizing film 12 via the adhesive layer 14, the cymbal sheet. 13 has a surface (facet) composed of a beak-like projection 13a. In the polarizing plate 1 shown in FIG. 2, the back side polarizing plate may include a resin film 15 which is laminated on the surface (surface on the liquid crystal cell side) on the side opposite to the surface on which the wafer 13 is laminated via the adhesive layer 16. . (Polarizing film) Specifically, the polarizing film 12 used for the back polarizing plate is obtained by adsorbing a dichroic dye to a polyvinyl alcohol-based resin film which has been uniaxially stretched. A polyvinyl alcohol-based resin constituting a polyvinyl alcohol-based resin film can be obtained by saponification using a polyvinyl acetate-based resin. In the case of the polyvinyl acetate-based resin, in addition to the polyvinyl acetate which is a homopolymer of vinyl acetate, a copolymer of vinyl acetate and another monomer copolymerizable with vinyl acetate, such as ethylene, may be mentioned. - a vinyl acetate copolymer or the like. Other monomers which can be copolymerized with vinyl acetate 322120 8 201107838 can be exemplified by unsaturated ships such as ethers, unsaturated (four) _ 'caps of C__, etc. The degree of deuteration of the polyethylene glycol is usually about 85 to fresh grass dew / (mole%), preferably 98 mo #, 0 change temporarily to w material% or more ^ B_ resin It is also possible to use an aldehyde-modified polyethylene acetal P〇yvinyl for.al) ^ 6^ (p〇lyvinyi ^ polymerization == one pass ^ is about just ^ to just (10), preferably about The method of forming a film of such a polyglycol-based resin is used as a film of a polarizing film. The method of forming a film of a polyethylene glycol-based resin is not particularly limited, and can be carried out by a conventionally known suitable method. The film thickness of the raw material film formed of the polyvinyl alcohol-based resin is not particularly limited, and for example, about 150 to 150 &quot; m 〇 polarizing film is usually produced by the following steps: polyethylene glycol as described above The raw material film formed by the phyla &amp; is dyed with a dichroic dye*, and the dichroic dye is attached (staining treatment step); the polyvinyl alcohol-based resin film to which the dichroic dye is adsorbed is boric acid The step of treating the aqueous solution (the boric acid treatment step and the step of washing with water after the treatment by the sensible aqueous solution (washing) Step )«ι sg 四其他' At the time of manufacturing the polarizing film, usually the polyvinyl alcohol resin film is extended early, and the sharp axis extension can be performed before the dyeing process step, and is also carried out in the dyeing process step + It is also possible to carry out the extension of the section after the treatment step, which can be carried out before the borax treatment step, or in the succinic acid treatment step 322120 9 201107838. Of course, Uniaxial extension can also be performed at these multiple stages. Single axis

Ht*以在周速相異的滚輪(r。⑴間朝單軸進行延伸的方 式進行,亦旎以使用熱滾輪而朝單軸進行延伸的方式進 '亍此外可利用在大氣中進行延伸的乾式延伸,亦可利 用在溶劑中使其膨潤之狀態下進行延伸的濕式延伸。延伸 倍率通常為約3至8倍。 在染色處理步驟中,聚乙烯醇系樹脂膜之以二色性色 t所進行的染色,舉例而言,可藉由將聚乙烯醇系樹脂膜 次潰於含有二色性色素的水溶液中而進行。可使用例如 。一色!·生木料等作為二色性色素。二色性染料中可包含 ’由C. I. DIRECT動39等雙偶氮(disaz〇)化合物 =之一色性直接染料;由三偶氮⑹咖)、四偶氮化合 一= —色性直接染料。再者’聚乙烯醇系樹脂膜較 且在朱色處理之前先施行浸潰於水之浸潰處理。 使=作為二色性色素的情形t,通常係採用將聚乙 多’糸樹脂膜浸潰於含有蛾及峨化卸的水溶液中以進行染 曰^方法。在該水溶液中,碟的含量通常相對於每⑽重 二:㈣含㈣料目對於每 本 伤水而為〇.5至20重量份。使用蛾作為二色性色 。的清形中’用於染色的水溶液之溫度通常為2〇至靴, 於該水落液中的浸潰時間(染色時間)通常為20 322120 10 201107838 色性染料的水溶液中以進行染色之方法。在該水溶液中, —色性染料的含量通常相對於每⑽重量份水而為lxl0-至10重量曰份’較佳為重量份,特佳為祕3至 X重ΐ份。該水溶液亦可含有硫酸納等無機鹽作為染色 助劑。使用二色性染料作為二色性色素的情形中,用於染 色的染料水溶液之溫度通常為20至80Ϊ,此外,浸於該 水溶液中的浸潰時間(染色時間)通常為1〇幻8〇〇秒。人 〜餐處理步驟係藉由將經二色性色素染色後的聚乙稀 転系樹脂膜浸潰於含有爾的水溶液中而進行 酸的水麵中,爾的量財㈣於每⑽重量份水而為 重量份,較佳為5至12重量份。在上述染色處理 乂驟使用硤作為二色性色素的情形中,用於朗酸處理步 驟之含有職的水溶液較宜含㈣切。在該情形下,在 含有餐的水溶液中,峨化鉀的量通常相對於每100重量, 份水而為0. !至15重量份,較佳為5至12重量份。於含 有餐的水溶液中的浸潰時間通常為60至測秒,較佳 為50至600更佳為2〇〇至棚秒。含有觸酸的水溶 液之溫度通常為5(TC以上,較佳為5〇至85ΐ 至 80°C。 接下來的水洗處理㈣中,«由將上述㈣處理後 的聚乙烯醇系樹脂膜浸潰於例如水巾*進行水洗處理。在 水洗處理中’水的溫度通常為5至抓,浸潰㈣通常為 至120秒。水洗處理後,通常係施行乾燥處理,以獲得 偏光膜。乾燥處理可使㈣如熱風機 '遠紅外線加執 322120 201107838 器等進行。乾燥處理的溫度通常為more,較佳為50 至sot。乾燥處理的時間通當± 马 ]、吊為60至600秒’較佳為i2f) 至600秒。 υ 一以此方式,對聚乙婦醇系樹脂膜施行單軸延伸、利用 -色性色素所進行之染色、處理以及水洗處理,而押 得偏光膜。該偏光膜的厚度通常在5至4()^ 又 (稜鏡片) 用於背面側偏光板的稜鏡片13具有由稜鏡狀的突起 (稜鏡狀突起l3a)所構成的表面(複鏡面)。稜鏡片13係以 使與稜鏡面相反側的面相對向於偏光膜12之方式積層於 偏光膜12上。藉由將具有稜鏡面的稜鏡片ι3配置於背面 側偏光板的表面,使該稜鏡面相對向於後述面光源,可有 意地改變從面光源的光射出面(相對向於棱鏡面之側的面) 射出的光之方向。根據本發明,藉由上述稜鏡片,可將來 自面光源的射出光,特別是具有指向性的射出光[主要的射 出方向為與面光源的光射出面之法線方向(液晶顯示裝置 的正面方向)相異的方向之射出光]的射出方向偏向至液晶 顯示裝置的正面方向’藉此’可增進液晶顯示裝置正面的 亮度及對比度。再者,稜鏡片13亦發揮作為偏光膜12的 保護膜之功用。 此處,所謂的「稜鏡狀突起」’意指令三角形狀(可包 括於一部分含有曲線的略三角形狀、鋸齒形狀等)朝與該三 角形狀的面垂直之方向平行移動後的軌跡所顯示之柱狀體 中’被夾在非形成底面之兩個側面的邊(稜線)的部分(該三 12 322120 201107838 角形狀的底邊之對角的執跡);稜鏡面係為以相對於該柱狀 ’ 體之稜鏡狀突起的面(該三角形狀的底邊之軌跡)作為底面 , 而平行地密接複數個該柱狀體並予以配列而成者,複數個 稜鏡狀突起係朝單一方向(以使各稜鏡狀突起的稜線平行 或略平行之方式)配列。第3圖係顯示稜鏡片的表面形狀之 一例的概略斜視圖,該稜鏡狀突起的剖面形狀為二等邊三 角形。 稜鏡片13係在以所具有的稜鏡狀突起13a之頂角(頂 點的角度)可例如為30至100。,在本發明中’為了使來自 面光源的射出光,特別是具有指向性的射出光更有效率地 偏向至液晶顯示裝置的正面方向’特別較佳為60°以上、 100。以下,更佳為60。以上、80°以下。 稜鏡狀突起13a的高度可例如為100至m。此外, 稜鏡狀突起13a的間距(pitch)(相鄰的突起的棱線間之距 離)係考慮稜鏡狀突起13a的頂角及高度而適當地決定’例 如,可為5至3 0 0 // m。 構成稜鏡狀突起13a的剎面三角形狀中的突起之兩邊 可為相同長度,亦可具有相異長度,但至少在所使用的面 光源的光源裝置係配置於導光板所面對面的兩邊之情形 中,該兩邊較佳為相同長度,因此,稜鏡狀突起13a的剖 面形狀較佳為二等邊三角形。複數個稜鏡狀突起13a的高 度可全部相同,亦可相異。此外,在突起間形成的溝之形 狀可為直線,亦可為曲線。 可使用公知的各種材料作為稜鏡片13的材質。例如,丨 322120 13 201107838 可使用聚乙烯、聚丙烯等聚烯烴系樹脂;聚對笨二甲_ &amp; 二酯樹脂、聚萘二曱酸乙二酯樹脂等聚酯系樹脂;聚氣乙 烯樹脂 '聚碳酸酯系樹脂、降冰片烯系樹脂、聚胺^ (polyurethane)系樹脂、丙烯酸系樹脂、聚甲基丙稀@甲 酯樹脂、聚苯乙烯系樹脂、曱基丙烯酸曱酯—笨乙稀系共聚 物、丙烯腈-丁二烯-苯乙烯系共聚物、丙烯腈〜笨乙烯系共 聚物等合成高分子;二醋酸纖維素樹脂、三醋酸纖維素樹 脂等天然高分子。其中,從透明性、透濕性及生產性的觀 點’適宜者為聚烯烴系樹脂、聚丙烯酸系樹脂、聚碳酸醋 系樹脂、聚輻系樹脂、聚苯乙烯系樹脂、甲基丙烯酸曱酯曰一 苯%婦系共聚物、丙烯腈_丁二烯_苯乙烯系共聚物、丙烯 腈-苯乙烯系共聚物之任一種熱可塑性樹脂。此外,必要 時’此等高分子材料可含有紫外線吸收劑或抗氧化劑、可 塑劑等添加齊|J。 矛文鏡片丨3係在以以上述透明高分子材料作為基材 時’可利用光聚合物(photopolymer)製造法、異型擠屋 (profileextrusi〇n)法 '壓製成形法、射出成形法、滾筒 轉印法、雷射剝餘(laser ablation)法、機械切削法、 削Ϊ等公知的方法予以製造。此等方法可個別地單 獨使用’或者亦可組合二種以上的方法。 稜鏡=13的厚度沒有特別限定,但從偏光板的 ^點而。,較佳為約20_以上、200从m以下, 3〇#m以上、1〇〇/zm以下。 薄壁化 更佳為 (樹脂膜) 322120 14 201107838 ..t第2圖所示_子’在偏域12的與積層有稜鏡片 的面為相反侧的面,亦可積層保護祺或光學補償膜等樹脂 ’ 膜15。在此情形下,偏光板1係妞 货…二由積層於樹脂膜15上 的黏著劑層而貼合於液晶單元。此外,亦可 著 或黏著劑層賴述光學魏性_層於偏細12、或輕 護膜或光學補償膜上。 作為樹脂臈15者,可列舉三醋酸纖維素⑹⑽切 cellul〇se)膜me膜)等纖維素系樹脂膜、㈣烴系樹脂 膜、丙烯酸系樹脂膜、聚對苯二甲酸乙二酉旨等聚酉旨系樹脂 膜等。 構成上述纖維素系樹脂膜的纖維素系樹脂可列舉纖維 素的部分酯化物或完全酯化物,例如,纖維素的醋酸酯、 丙酸酯、丁酸酯,以及該等的混合酯等。更具體而言,可 列舉如三醋酸纖維素、二醋酸纖維素、醋酸丙酸纖維素、 醋酸丁酸纖維素等。在將此種纖維素系樹脂進行製膜以作 為膜時’宜使用溶劑澆鑄法、溶融播壓法等公知的方法。 纖維素酯系樹脂膜的市售品可列舉如「Fuji TacTD80」(富 士軟片(股)製造)、「Fuji Tac TD80UF」(富士軟片(股)製 造)、「Fuji Tac TD80UZ」(富士軟片(股)製造)、「KC8UX2M」 (柯尼卡美能達精密光學(Konica Minolta Opto)(股)製 造)、「KC8UY」(柯尼卡美能達精密光學(股)製造)等。 此外’由纖維素系樹脂膜所成的光學補償膜可列舉如 在上述纖維素系樹脂膜中含有具相位差調整功能之化合物 的膜;在上述纖維素系樹脂膜表面塗佈具相位羞調整功能[ 322120 15 201107838 之化合物ΠΤ3驭的脫. 伸而得 膜’將纖維素系樹脂膜單軸延伸或雙軸延 、等市售之由纖維素系樹脂膜所成的光學補償 膜可列舉如舍4_以 ^ ρ ^ 軟片(股)製造的「WV BZ 438」、「wv ΕΑ」; 柯尼卡美能遠掉#, 雄 '月φ光學(股)製造的「KC4FR-1」、「KC4HR-1」 等。 、―处 手'料月曰膜所成的保護膜或光學補償膜的厚度 沒有特別限制,伯 ΟΛ Λ 較且在20至ΘΟβιη的範圍内,更佳在 30至ΘΟβιη的筋图 難以處理,另了。在厚度未達2〇”的情形中,膜會 ...έέ. ^ 万面’在厚度超過90# m的情形中’加工 θ由上述對所得偏光板的薄壁化及輕量化會不利。 00 上述聚烯杈系樹脂膜所成的光學補償膜可列舉如經 早延伸或雙轴延伸之料烴系樹脂膜。在應用於大型液 :曰:電視用:晶面板(特別是具備 垂直配向(VA)模式的液晶 =70之液aa面板)的情形中’從光學特性及耐久性的觀點, 衣烯辽系樹月曰膜的延伸品亦宜作為上述光學補償膜。此 ,所烯烴系樹脂膜」係指例如由具有以降冰片 ,或夕f降冰片歸系單體等環狀稀烴(環烯烴)所成的單體 單:之塑性樹脂所構成的膜。環烯烴系樹脂膜可為使 用單一環稀烴的開環聚合物之氫化物 、或使用二種以上環 烯;k的開環共聚物之氫化物,亦可為環稀烴與鏈狀稀煙及/ 或具有乙稀基的芳香族化合物等的加成共聚物。此外,在 主鏈或側鏈導人有極性基者亦為有效。 市售之熱可塑性環婦烴系樹脂有德國TGPAS ADVANCED POLYMERS GmbH公司販售的「T_s」、JSR (股)販售的 16 322120 201107838 「ART0N」、日本Ze〇n (股)販售的「ZE0N0R」及「ZEONEX」、 三井化學(股)¾售的「APEL」(皆為商品名)等,該等巧*適 當地加以使用。將此種環烯烴系樹脂進行製膜’可得到環 烯座系樹脂膜。宜使用溶劑澆鑄法、熔融擠壓法等公知的 方法作為製臈方法。此外,市面上亦售有例如積水化學工 業(股)販售的「Escena」及「SCA40」、日本Zeon (股)販 售的「ZE0N0R臈」、JSR (股)販售的「ART0N膜」(皆為商 品名)等經製膜後之環烯烴系樹脂膜,此等亦可適當地加以 使用。 由於由經延伸之環烯烴系樹脂膜所構成的光學補償膜 之厚度若太厚,則加工性會變差,此外,透明性會降低、 或對偏光板的薄壁化及輕量化會不利等,故較佳為約2〇至 80 m。 用於本發明之背面側偏光板可藉由使用接著劑將上 稜鏡片貼合於上述偏光膜的單側表面而得。藉此,參昭 2圖’獲得將稜鏡片13經由接著劑層14積層於偏光膜 f面而成之偏光板。在將樹賴15積層於偏光板12之 -面的情形中,偏光膜12與樹脂膜15的貼合係同様使 接著劑來進行4接著_形成接著_ 16者 _ 膜b貼合於偏光膜12的情形中,用於稜鏡片i3的貼合^ =劑與用於樹賴15的貼合之接著劑可為 類 亦可為相異種類的接著劑。用於此等臈的貼心 :了列舉水祕著劑,亦即將接著劑成分溶解或分黄 、7而成的接著劑,以及光硬化性接著劑。 322120 17 201107838 由可使接著劑層薄化的觀點而言,較宜使用上述水系 接著劑。水系接著劑可列舉如使用聚乙烯醇系樹脂或胺醋 (urethane)樹脂作為接著劑成分的水系接著劑。 在使用聚乙埽醇系樹脂作為接著劑成分的情形中,該 聚乙烯醇系樹脂除了部分皂化聚乙烯醇、完全皂化聚乙烯 醇之外,亦可為綾基改質聚乙烯醇、乙醯乙醯基改質聚乙 稀醇、經甲基改質聚乙烯醇、胺基改質聚乙烯醇等經改質 之聚乙烯醇系樹脂。通常,以聚乙烯醇系樹脂作為接著劑 成分的水系接著劑係調製成聚乙烯醇系樹脂的水溶液。相 對於100重直份的水’接著劑中的聚乙烯醇系樹脂之濃度 通常為約1至10重量份,較佳為約1至5重量份。 以聚乙烯醇系樹脂作為接著劑成分的接著劑中,為了 提升接著性,較宜添加乙二醛、水溶性環氧樹脂等硬化性 成分或架橋劑。就水溶性環氧樹脂而言,可適當地使用例 如在藉由使一伸乙三胺、三伸乙四胺等多伸烧基多胺 (polyalkylene p〇lyamine)與己二酸等二羧酸反應所得之 聚醯胺多胺(polyamide polyamine)中使表氯醇反應所得 之聚醯胺多胺環氧樹脂。該等聚醯胺多胺環氧樹脂的市售 品可列舉住化CHEMTEX (股)販售之「Sumiraze resin 650」 及「Sumirazerasin 675」、日本 PMC (股)販售之「WS-525」 等。相對於100重量份的聚乙烯醇系樹脂,此等硬化性成 分或架橋劑的添加量(在共同添加的情形中則為合計量)通 常為1至100重量份,較佳為1至50重量份。在上述硬化 性成分、架橋劑的添加量相對於100重量份的聚乙烯醇系 322120 18 201107838 重量份的情形中’有接著性提升效果小的傾 二、二 硬化性成分、架橋劑的添加量相對於⑽ 重罝伤的I乙烯醇系樹脂係超過100重量 接著劑層脆化的傾向。 的㈣中有 此外,在使用胺酯樹脂作為接著劑成分的情形中,適 當接著劑組成物之例可列舉聚§旨系離子聚合物型胺醋樹脂 與具杨水甘油氧基(glyeidylQXy)的化合物之混合物。此 處,所谓的「聚醋系離子聚合物型胺酿樹脂」係為具有聚 醋骨架的胺|旨樹脂,且於該骨架内導人少量離子性成分⑽ 水成分)者。由於該等離子聚合物型㈣樹脂不使用乳化劑 而直接在水中乳化成乳劑,故其適宜作為水系接著劑。聚 醋系離子聚合物型聚細旨樹脂本身為公知者,例如,曰本 特開平7j7504號公報中記載用以使紛系樹脂分散於水性 媒質中的高分子分散劑之例,此外,日本特開2〇〇5_〇7〇14〇 號公報及日本特開2005_181817號公報中,揭示以聚酯系 離子聚合物型胺醋樹脂與具有縮水甘油氧基的化合物之混 合物作為接著劑,將環稀烴系樹脂膜貼合於由聚乙婦醇系 樹脂所構成之偏光膜。 作為將接著劑塗佈在偏光膜及/或貼合於該偏光膜的 構件(稜鏡片、或者保護膜或光學補償膜)的方法者,宜為 一般習知的方法,可列舉如流延法、繞線棒塗佈法(Meyer bar coat method)、凹版塗佈法(gravure c〇at 呢也⑹、 雙輥式塗布(comma Coater method)、到刀成膜法(d〇ct〇r blade method)、模具塗佈法(die c〇at meth〇d)、浸潰塗 19 322120 201107838 佈法(dip coat method)、喷霧法等。所謂的「流延法」係 使屬於被塗佈物的膜朝约略垂直方向、約略水平方向、或 兩者之間的偏斜方向移動,同時使接著劑流下並散佈於該 膜的表面之方法。塗佈接著劑後,使偏光膜及貼合於該偏 光膜的構件重疊’藉由軋輕(nip roller)等夹住,以進行 膜的貼合。舉例而言,使用軋輥之膜的貼合可採用:在塗 佈接耆劑後,利用滾輪等進行加塵而均勻地予以壓開之方 法;在塗佈接著劑後,通過滾輪與滾輪之間進行加壓而予 以壓開之方法。在前者的情形中,可使用金屬或橡膠等作 為滾輪的材質。此外’在後者的情形中,複數個滾輪可為 相同材質,亦可為相異材質。 在上述貼合後,可藉由進行乾燥使接著劑層硬化而獲 得偏光板。該乾燥處理可藉由例如吹熱風而進行,乾燥處 理的溫度通常係在40至l〇〇c的範圍内,較宜在6〇至1〇〇 C的範圍内。此外’乾燥時間通常為2〇至1200秒。 乾燥後的接著劑層厚度通常為〇. 〇〇1至5 a m,較佳為 0. 01至2# m,更佳為〇1至1 。在乾燥後的接著劑層 厚度未達0.001//m的情形中,有接著變得不充分之疑慮, 此外,若乾燥後的接著劑層厚度超過m,則有產生偏光 板的外觀不良之疑慮。再者,在乾燥、硬化前,使用上述 軋輥等貼合後的接著劑層厚度較佳為5#m以下’又,較佳 為0. 01 /z m以上。 乾燥處理之後,亦可在室溫以上的溫度施行至少半 天、通常為1天以上的熟成,以獲得充分的接著強度。典 322120 20 201107838Ht* is carried out in a way that the circumferential speeds are different (r. (1) extends toward a single axis, and also by using a hot roller to extend toward a single axis. In addition, it can be extended in the atmosphere. The dry stretching may be carried out by a wet stretching in which the film is swollen in a solvent. The stretching ratio is usually about 3 to 8 times. In the dyeing step, the polyvinyl alcohol resin film is in a dichroic color. The dyeing by t can be carried out, for example, by submerging a polyvinyl alcohol-based resin film in an aqueous solution containing a dichroic dye. For example, one color, raw wood, or the like can be used as the dichroic dye. The dichroic dye may include 'disaz〇 compound such as CI DIRECT 39, one color direct dye; triazo (6) coffee), tetrazonitride = color dye. Further, the 'polyvinyl alcohol-based resin film was subjected to impregnation treatment with water before being subjected to the tan color treatment. In the case of using = as a dichroic dye, a method of dyeing a polyethylene resin film in an aqueous solution containing moths and deuterium is usually employed. In the aqueous solution, the content of the dish is usually from about (5) to about 20 parts by weight per (10) of the (four) containing material. Use moths as a dichroic color. The temperature of the aqueous solution used for dyeing is usually 2 Torr to the boot, and the immersion time (dyeing time) in the aqueous liquid is usually 20 322 120 10 201107838 in an aqueous solution of a dye dye for dyeing. In the aqueous solution, the content of the color-developing dye is usually from 1 x 10 to 10 parts by weight per 1 part by weight of water, preferably parts by weight, particularly preferably from 3 to X parts by weight. The aqueous solution may also contain an inorganic salt such as sodium sulphate as a dyeing aid. In the case where a dichroic dye is used as the dichroic dye, the temperature of the dye aqueous solution used for dyeing is usually 20 to 80 Å, and further, the immersion time (dyeing time) immersed in the aqueous solution is usually 1 〇 8 〇 8 〇 Leap second. The human-to-meal processing step is carried out by immersing the polyethylene-based resin film dyed with the dichroic dye in an aqueous solution containing an alcohol to carry out the acid in the surface of the acid, and the amount of money is (4) per (10) parts by weight. The water is in parts by weight, preferably 5 to 12 parts by weight. In the case where hydrazine is used as the dichroic dye in the above dyeing treatment, the aqueous solution containing the acid used in the sulphuric acid treatment step preferably contains (4) cut. In this case, the amount of potassium telluride in the aqueous solution containing the meal is usually from 0.1 to 15 parts by weight, preferably from 5 to 12 parts by weight, per 100 parts by weight of the water. The impregnation time in the aqueous solution containing the meal is usually from 60 to 2 seconds, preferably from 50 to 600, more preferably from 2 to shed. The temperature of the aqueous solution containing the acid is usually 5 (TC or more, preferably 5 Torr to 85 Torr to 80 ° C. In the subsequent water washing treatment (4), « the polyvinyl alcohol resin film treated by the above (4) is impregnated For example, a water towel* is subjected to a water washing treatment. In the water washing treatment, the temperature of the water is usually 5 to scratch, and the dipping (four) is usually 120 seconds. After the water washing treatment, drying treatment is usually performed to obtain a polarizing film. (4) If the hot air blower 'far infrared ray 322120 201107838, etc., the drying treatment temperature is usually more, preferably 50 to sot. The drying treatment time is ± ± horse, hanging 60 to 600 seconds 'better For i2f) to 600 seconds. In this manner, the polyephthyl alcohol resin film is subjected to uniaxial stretching, dyeing, treatment, and water washing treatment using a coloring dye to obtain a polarizing film. The thickness of the polarizing film is usually 5 to 4 (b). The crotch sheet 13 for the back side polarizing plate has a surface composed of a beak-like projection (a dome-like projection 13a) (re-mirror surface). . The crotch panel 13 is laminated on the polarizing film 12 so that the surface opposite to the crotch surface faces the polarizing film 12. By arranging the crotch surface ι3 on the surface of the back side polarizing plate, the kneading surface is opposed to the surface light source described later, and the light exit surface from the surface light source can be intentionally changed (relative to the side of the prism surface) Face) The direction of the light that is emitted. According to the present invention, the light emitted from the surface light source, in particular, the light having the directivity can be emitted by the above-mentioned cymbal sheet [the main emission direction is the normal direction of the light exit surface of the surface light source (the front surface of the liquid crystal display device) The direction in which the light is emitted in a different direction is deflected toward the front direction of the liquid crystal display device, thereby increasing the brightness and contrast of the front surface of the liquid crystal display device. Further, the cymbal sheet 13 also functions as a protective film for the polarizing film 12. Here, the "bow-like protrusion" is intended to mean that a triangular shape (which may be included in a part of a slightly triangular shape, a zigzag shape or the like including a curve) is displayed in a direction parallel to a direction perpendicular to the surface of the triangular shape. a portion of the columnar body that is sandwiched between the sides (ridge lines) that do not form the two sides of the bottom surface (the diagonal of the bottom edge of the angular shape of the three 12 322120 201107838); the facet is relative to the column The surface of the ridge-shaped protrusion (the trajectory of the bottom edge of the triangular shape) is a bottom surface, and a plurality of the columnar bodies are closely connected in parallel and arranged, and the plurality of ridges are oriented in a single direction. (Arranged such that the ridgelines of the respective projections are parallel or slightly parallel). Fig. 3 is a schematic perspective view showing an example of the surface shape of the cymbal, and the cross-sectional shape of the ridge is a trapezoidal triangle. The crotch panel 13 may be, for example, 30 to 100 in the apex angle (the angle of the apex) of the serpentine projection 13a. In the present invention, it is particularly preferable that the light emitted from the surface light source, particularly the light having the directivity, be deflected more toward the front direction of the liquid crystal display device, and is preferably 60 or more and 100. Hereinafter, it is more preferably 60. Above, below 80°. The height of the beak 13a may be, for example, 100 to m. Further, the pitch of the beak-like projections 13a (the distance between the ridgelines of the adjacent projections) is appropriately determined in consideration of the vertex angle and height of the condylar projections 13a, for example, may be 5 to 300. // m. The two sides of the protrusion in the triangular shape of the brake surface forming the dome 13a may be the same length or may have different lengths, but at least the light source device of the surface light source used is disposed on both sides of the face of the light guide plate. Preferably, the two sides are of the same length, and therefore, the cross-sectional shape of the beak-like projection 13a is preferably a equilateral triangle. The heights of the plurality of braided projections 13a may all be the same or different. Further, the shape of the groove formed between the protrusions may be a straight line or a curved line. Various materials known in the art can be used as the material of the cymbal sheet 13. For example, 丨322120 13 201107838 may use a polyolefin resin such as polyethylene or polypropylene; a polyester resin such as a poly(p-dimethyl ester) resin or a polyethylene naphthalate resin; a polyethylene resin; 'Polycarbonate resin, norbornene based resin, polyurethane resin, acrylic resin, polymethyl propylene@methyl ester resin, polystyrene resin, decyl methacrylate - stupid B A synthetic polymer such as a rare copolymer, an acrylonitrile-butadiene-styrene copolymer, an acrylonitrile to a stupid ethylene copolymer, or a natural polymer such as a cellulose diacetate resin or a cellulose triacetate resin. Among them, from the viewpoints of transparency, moisture permeability, and productivity, it is suitable as a polyolefin resin, a polyacrylic resin, a polycarbonate resin, a poly-radiation resin, a polystyrene resin, or a methacrylate. A thermoplastic resin of any one of a benzene% styrene copolymer, an acrylonitrile-butadiene-styrene copolymer, and an acrylonitrile-styrene copolymer. Further, if necessary, these polymer materials may contain an ultraviolet absorber, an antioxidant, a plasticizer or the like. In the case of using the above-mentioned transparent polymer material as a base material, the spear lens 丨 3 is a photopolymer manufacturing method, a profile extrusion method, a press molding method, an injection molding method, and a drum rotation. It is manufactured by a known method such as a printing method, a laser ablation method, a mechanical cutting method, or a chipping method. These methods may be used individually or in combination of two or more methods. The thickness of 稜鏡 = 13 is not particularly limited, but is from the point of the polarizing plate. Preferably, it is about 20_ or more, 200 is less than m, and 3〇#m or more and 1〇〇/zm or less. Thinner walling is more preferably (resin film) 322120 14 201107838 ..t Fig. 2 shows the _ child's face on the opposite side of the facet 12 with the laminated face, and can also be laminated to protect the 祺 or optical compensation Resin such as film' film 15. In this case, the polarizing plate 1 is attached to the liquid crystal cell by the adhesive layer laminated on the resin film 15. In addition, the optical layer may be applied to the fine layer 12, or the light film or the optical compensation film. Examples of the resin crucible 15 include a cellulose resin film such as cellulose triacetate (6) (10), and a hydrocarbon resin film, an acrylic resin film, a polyethylene terephthalate, and the like. Poly" is a resin film or the like. The cellulose-based resin constituting the cellulose-based resin film may, for example, be a partially esterified or fully esterified cellulose, for example, cellulose acetate, propionate, butyrate, or a mixed ester thereof. More specifically, examples thereof include cellulose triacetate, cellulose diacetate, cellulose acetate propionate, cellulose acetate butyrate, and the like. When such a cellulose-based resin is formed into a film as a film, a known method such as a solvent casting method or a melt-casting method is preferably employed. Commercial products of the cellulose ester-based resin film include "Fuji Tac TD80" (manufactured by Fujifilm Co., Ltd.), "Fuji Tac TD80UF" (manufactured by Fujifilm Co., Ltd.), and "Fuji Tac TD80UZ" (Fuji Tray) )), "KC8UX2M" (manufactured by Konica Minolta Opto Co., Ltd.), "KC8UY" (manufactured by Konica Minolta Precision Optics Co., Ltd.). In addition, the optical compensation film formed of the cellulose resin film may include a film containing a compound having a phase difference adjustment function in the cellulose resin film; and the surface of the cellulose resin film may be adjusted with phase shading. The optical compensation film made of a cellulose-based resin film, such as a uniaxially stretched or biaxially stretched cellulose resin film, such as a compound of 322120 15 201107838, can be exemplified. "WV BZ 438" and "wv ΕΑ" made by ^ ρ ^ film (share); Konica Minolta ##, "KC4FR-1" and "KC4HR" manufactured by Xiong's φ Optical Co., Ltd. -1" and so on. The thickness of the protective film or the optical compensation film formed by the 处 ' 料 料 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有 没有It is. In the case where the thickness is less than 2 〇, the film may be... 万. ^Wan surface 'In the case where the thickness exceeds 90 # m, the processing θ is disadvantageous because the above-mentioned polarizing plate is thinned and lightened. 00 The optical compensation film formed of the above-mentioned polyolefin-based resin film may, for example, be a hydrocarbon resin film which is elongated or biaxially stretched. It is applied to a large liquid: 曰: TV: crystal panel (especially with vertical alignment) In the case of (VA) mode liquid crystal=70 liquid aa panel), from the viewpoint of optical properties and durability, an extension of the enamel-tree decidua film is also suitable as the optical compensation film. The "resin film" refers to, for example, a film composed of a plastic resin having a monomeric monomer: a ring-shaped rare hydrocarbon (cycloolefin) such as a norbornene or a fluorene-norborning monomer. The cycloolefin resin film may be a hydrogenated product of a ring-opening polymer using a single ring-dilute hydrocarbon, or a hydride of a ring-opening copolymer of two or more kinds; a ring-opening copolymer of k; And/or an addition copolymer having an aromatic compound such as an ethylene group. In addition, it is also effective to have a polar base in the main chain or side chain. Commercially available thermoplastic ring-type hydrocarbon resin is "T_s" sold by the German TGPAS ADVANCED POLYMERS GmbH, 16 322120 201107838 "ART0N" sold by JSR (shares), and "ZE0N0R" sold by Japan Ze〇n (shares) "APEL" ("MEEL" (all product names) sold by ZEONEX and Mitsui Chemicals Co., Ltd., etc., are used appropriately. The cycloolefin resin is formed into a film to obtain a cycloolefin resin film. A known method such as a solvent casting method or a melt extrusion method is preferably used as the crucible method. In addition, "Escena" and "SCA40" sold by Sekisui Chemical Industry Co., Ltd., "ZE0N0R臈" sold by Japan Zeon (shares), and "ART0N film" sold by JSR (shares) are also sold in the market. Each of the cycloolefin-based resin films which have been formed into a film, such as a product name, may be suitably used. When the thickness of the optical compensation film composed of the extended cycloolefin resin film is too thick, the workability is deteriorated, and the transparency is lowered, or the thickness of the polarizing plate is reduced and the weight is reduced. Therefore, it is preferably about 2 to 80 m. The back side polarizing plate used in the present invention can be obtained by laminating a top sheet to the one side surface of the above polarizing film by using an adhesive. Thereby, a polarizing plate obtained by laminating the ruthenium sheet 13 on the surface of the polarizing film f via the adhesive layer 14 is obtained. In the case where the tree 15 is laminated on the surface of the polarizing plate 12, the bonding of the polarizing film 12 and the resin film 15 is performed in the same manner as the bonding agent, and then the bonding is carried out, and then the film is bonded to the polarizing film. In the case of 12, the bonding agent for the crotch sheet i3 and the bonding agent for the lamination 15 may be of a different type of adhesive. Intimate for use in such enamel: A water-repellent agent, that is, an adhesive in which an adhesive component is dissolved or yellowed, and a photocurable adhesive is used. 322120 17 201107838 From the viewpoint of making the adhesive layer thin, it is preferred to use the above aqueous binder. The water-based adhesive can be, for example, a water-based adhesive using a polyvinyl alcohol-based resin or an urethane resin as an adhesive component. In the case where a polyethylene glycol-based resin is used as the adhesive component, the polyvinyl alcohol-based resin may be a thiol-modified polyvinyl alcohol or a acetonitrile-modified polyvinyl alcohol in addition to a partially saponified polyvinyl alcohol or a fully saponified polyvinyl alcohol. A modified polyvinyl alcohol-based resin such as a thiol-modified polyethylene glycol, a methyl-modified polyvinyl alcohol, or an amine-modified polyvinyl alcohol. Usually, a water-based adhesive containing a polyvinyl alcohol-based resin as an adhesive component is prepared into an aqueous solution of a polyvinyl alcohol-based resin. The concentration of the polyvinyl alcohol-based resin in the water-adhesive agent relative to 100 parts by weight is usually from about 1 to 10 parts by weight, preferably from about 1 to 5 parts by weight. In the adhesive agent containing a polyvinyl alcohol-based resin as an adhesive component, a curable component such as glyoxal or a water-soluble epoxy resin or a bridging agent is preferably added in order to improve adhesion. In the case of the water-soluble epoxy resin, for example, by reacting a polyalkylene p〇lyamine such as a polyethylenetriamine or a triethylenetetramine with a dicarboxylic acid such as adipic acid, The polyamine polyamine epoxy resin obtained by reacting epichlorohydrin in the obtained polyamide polyamine. Commercial products of such polyamine polyamine epoxy resins include "Sumiraze resin 650" and "Sumirazerasin 675" sold by CHEMITEX, and "WS-525" sold by Japan PMC (shares). . The amount of the curable component or the bridging agent added (in the case of co-addition is a total amount) is usually from 1 to 100 parts by weight, preferably from 1 to 50% by weight based on 100 parts by weight of the polyvinyl alcohol-based resin. Share. In the case where the amount of the curable component and the bridging agent added is less than 100 parts by weight of the polyvinyl alcohol-based 322120 18 201107838 parts by weight, the amount of the second curing agent, the second curing agent, and the bridging agent having a small adhesion improving effect is small. The I vinyl alcohol-based resin which is heavily scratched with respect to (10) tends to be embrittled more than 100% by weight of the adhesive layer. In addition, in the case of using an amine ester resin as an adhesive component, examples of a suitable adhesive composition may be exemplified by an ionic polymer type amine vinegar resin and a glycididylQXy group. a mixture of compounds. Here, the "polyacetate-based ionic polymer-type amine-brick resin" is an amine-based resin having a vinegar skeleton, and a small amount of ionic component (10) water component is introduced into the skeleton. Since the plasma polymer type (tetra) resin is directly emulsified into an emulsion in water without using an emulsifier, it is suitably used as a water-based adhesive. For example, Japanese Laid-Open Patent Publication No. 7J7504 discloses an example of a polymer dispersant for dispersing a viscous resin in an aqueous medium, and JP-A-2005-81817 discloses a mixture of a polyester-based ionic polymer-type amine vinegar resin and a compound having a glycidoxy group as an adhesive, and a ring is disclosed. The thin hydrocarbon resin film is bonded to a polarizing film made of a polyethylol alcohol resin. As a method of applying an adhesive to a polarizing film and/or a member (a sheet, a protective film, or an optical compensation film) bonded to the polarizing film, it is preferable to use a conventional method, such as a casting method. , Meyer bar coat method, gravure coating method (gravure c〇at also (6), comma Coater method, to knife forming method (d〇ct〇r blade method) ), die coating method (die c〇at meth〇d), impregnation coating 19 322120 201107838 dip coat method, spray method, etc. The so-called "casting method" is to belong to the coated object a method in which the film is moved in an approximately vertical direction, an approximately horizontal direction, or a skew direction therebetween, while allowing the adhesive to flow down and spread on the surface of the film. After applying the adhesive, the polarizing film and the bonding film are attached thereto. The member overlap of the polarizing film is sandwiched by a nip roller or the like to bond the film. For example, the bonding of the film using the roll may be performed by using a roller or the like after applying the binder. a method of uniformly adding a dust by applying dust; after applying the adhesive, passing In the former case, metal or rubber can be used as the material of the roller. In the latter case, the plurality of rollers can be the same material. After the above bonding, the polarizing plate can be obtained by drying the adhesive layer by drying. The drying treatment can be carried out, for example, by blowing hot air, and the drying treatment temperature is usually 40 to 1 Torr. In the range of 〇c, it is preferably in the range of 6 〇 to 1 〇〇 C. In addition, the drying time is usually 2 〇 to 1200 sec. The thickness of the adhesive layer after drying is usually 〇 1 to 5 am, It is preferably from 0.01 to 2 # m, more preferably from 1 to 1. In the case where the thickness of the adhesive layer after drying is less than 0.001 / / m, there is a concern that it becomes insufficient subsequently, and if it is dry, When the thickness of the adhesive layer exceeds m, there is a concern that the appearance of the polarizing plate may be poor. Further, before drying and curing, the thickness of the adhesive layer after bonding using the above-described roll or the like is preferably 5 #m or less. , preferably 0. 01 / zm or more. After drying, it can also be The temperature above room temperature is applied for at least half a day, usually more than one day, to obtain sufficient adhesion strength. 322120 20 201107838

•型^該熟成係在捲取成捲筒狀的 溫度係在30至50。〇的益R ,熟成溫度超過5(TC,在在35至肌的範圍。若 生^的「捲_象」。再者’熟成時的濕度沒有特別限^ ==濕度在約。_至_的範圍者。熟成時 間通吊為約1天至10天,較佳為約2天至7天。 匕此^上述光硬化性接著劑可列舉如光硬化性環 脂與光陽料聚合起始劑的混合物等。光硬化性環氧樹月旨 :列舉如1¾式壤氧樹脂、不具有脂環式構造的環氧樹 脂、以及其混合物等。光硬化性接著劑除了光硬化性環氧 樹脂之外,亦可含有丙婦酸系樹脂、氧雜環丁烧(〇Xetane) 樹脂、胺醋樹脂、聚乙婦醇樹脂等,此外,亦可同時含有 光陽離子聚合起始劑與光自由基聚合起始劑,或能以代替 光陽離子聚合起始劑之方式而含有光自由基聚合起始劑。 在使用光硬化性接著劑的情形中,將光硬化性接著劑 塗佈在偏光膜及/或貼合於該偏光膜的構件(稜鏡片、或者 保護膜或光學補償膜)’並將偏光膜及貼合於該偏光膜的構 件予以貼合後’藉由照射活性能量線而使光硬化性接著劑 硬化。光硬化性接著劑的塗佈方法以及膜的貼合方法可與 水系接著劑相同。活性能量線的光源沒有特別限定,但較 佳為在波長400 nm以下具有發光分佈的活性能量線,具體 而言,較宜使用低壓水銀燈、中壓水銀燈、高壓水銀燈、 超高壓水銀燈、化學燈、黑光燈(black iight iamp)、微 波激發水銀燈、金屬鹵化物燈等。• Type ^ The temperature at which the aging is wound into a roll is 30 to 50.益的益R, the ripening temperature exceeds 5 (TC, in the range of 35 to the muscle. If the raw ^ "volume_like". In addition, the humidity when cooked is not particularly limited ^ = = humidity is about. _ to _ The aging time is about 1 day to 10 days, preferably about 2 days to 7 days. The above photohardenable adhesive may, for example, be a photocurable cycloaliphatic and photopolymerization initiator. A mixture of photocurable epoxy resin, such as a 13⁄4 type earth oxide resin, an epoxy resin having no alicyclic structure, a mixture thereof, etc. A photocurable adhesive is other than a photocurable epoxy resin. It may also contain a bupropion acid resin, an oxime xetane resin, an amine vinegar resin, a polyethyl alcohol resin, or the like, and may also contain a photocationic polymerization initiator and photoradical polymerization. The photo-radical polymerization initiator may be contained in the form of a photo-curable adhesive instead of the photo-cationic polymerization initiator. In the case of using a photocurable adhesive, a photocurable adhesive is applied to the polarizing film and/or a member bonded to the polarizing film (strip, or protective film or optical compensation) After the polarizing film and the member bonded to the polarizing film are bonded together, the photocurable adhesive is cured by irradiation of the active energy ray. The method of applying the photocurable adhesive and the bonding method of the film The light source of the active energy ray is not particularly limited, but is preferably an active energy ray having a light-emitting distribution at a wavelength of 400 nm or less. Specifically, a low-pressure mercury lamp, a medium-pressure mercury lamp, a high-pressure mercury lamp, or the like is preferably used. Ultra high pressure mercury lamp, chemical lamp, black iight iamp, microwave excited mercury lamp, metal halide lamp, etc.

[SI 322120 21 201107838 對光硬化n接著㈣光照射強度沒有特別 限定,係根 人I私π/接著劑的組成而適當地決定,但較佳為對聚 合起始劑的活性化右 t的波長領域之照射強度4 0.1至 反應時間不會過Γ而^度為0.1獻m2以上的情形中, 焚而在該照射強度為60〇〇mw/Cm2以下的 情形中,由從光源輕射出的熱以及光硬化性接著劑硬化時 的Uxa成之環氧樹脂黃化或偏光膜劣化的問題會較 少。對光硬化性接著劑的光照射時間沒有特別限定,係依 被硬化之光硬化性接著劑予以控制,但較宜 光量(其衫上述照射強度與照射時間之乘積)成為10^ 誦〇_。在對光硬化性接著劑進行照射的累積光量為 0 mJ/m以上的情形中’可大量生成源自聚合起始劑的活 ,=使硬化反應更確實地騎,糾,在對光硬化性接 者”汽進灯照射的累積光量為l_GmJ/m2以下的情形中,昭 射時間不會過長,可維持良好的生產性。 … w t藉f活陡此里線的照射而使光硬化性接著劑硬化的 較宜在偏光膜的偏光度、穿透率及色相、以及稜 $片、保制及光學漏料翻性等偏光板的諸功能不 會下降的條件下進行硬化。 =者在稜鏡片以及保護膜或光學補償膜貼合於偏光 膜之前,為了增,接㈣,转麵紐及/或貼合於該偏 光膜的構件之接著表面施行電漿處理、電晕處理、紫外線 照射處理、火焰處理、矣化處理等表面處理。作為皂化處 理者,可列舉如浸潰於氮氧化納或氫氧化卸等鹼性水溶液 322120 22 201107838 之方法。 此外,如上所述’背面側偏光板亦可具有積層於偏光 膜12的與積層有棱鏡片13的面為相反側的面之光學功能 性膜。光學功能性膜可列舉如:使液晶性化合物塗佈、配 向於基材表面而成的光學補償膜;讓某些種類的偏振光穿 透且將顯示出與前述偏振光為相反之性質的偏振光予以反 射之反射型偏光膜;由聚碳酸酯系樹脂所構成之相位差 膜;由環稀煙系樹脂膜所構成之相位差膜;在表面具有凹 凸形狀之附有防眩功能的膜;附有表面抗反射功能的膜; 在表面具有反射功能的膜’以及兼具反射功能與穿透功能 之半穿透反射膜等。對應於使液晶性化合物塗佈、配向於 基材表面而成的光學補償膜之市售品,可列舉如「WV膜」 (富士軟片(股)製造)、「NH膜」(新曰本石油(股)製造)、「nr 膜」(新日本石油(股)製造)等。對應於讓某些種類的偏振 光穿透且將顯示出與前述偏振光為相反之性質的偏振光予 以反射之反射型偏光膜之市售品’可列舉如「DBEF」(3M 公司製造,於日本係購自住友(股))荨。此外’對應於 由環婦炫系樹脂膜所構成之相位差膜之市售品’可列舉如 「ART0N膜」(JSR (股)製造)、「Escena」(積水化學工業(股) 製造)、「ZEONOR膜」(日本Zeon (股)製造)等。 背面側偏光板較宜在與稜鏡片相反側的表面具有用於 貼合於液晶單元之黏著劑層。就用於此種黏著劑層之黏著 劑而言,可使用以往公知的適宜黏著劑,可列舉如丙婦酸 系黏著劑、胺酯系黏著劑、聚矽氧(si 1 icone)系黏著劑等。 322120 23 201107838 =,從透明性、黏著力、可靠性、重工性等觀點而言, 父且使用丙稀酸系黏著劑。可藉由下列方法敷設黏著劑 層.將此種黏著劑作成例如有機溶劑溶液,藉由模且塗佈 或凹版塗佈等將其塗佈於基材膜(例如,偏光膜等)上,並 使其乾燥。此外,亦可藉由下列方法敷設:將經施行離型 處理之塑膠膜(稱為分離膜(separate⑴①))上所形成的 片狀黏著劑轉印至基材膜。黏著劑層的厚度沒有特別限 制’較宜在2至40 # m的範圍内。 〈前面側偏光板〉 前面側偏光板(第1圖中的偏光板2)係以液晶單元為 基準,配置於與面光源為相反之側(目視側)的偏光板。可 使用以往公知的適宜偏光板作為前面側偏光板。舉例而 言,除了在偏光膜的單面或雙面積層由三醋酸纖維素等所 成之保護膜的偏光板之外,亦可使用經施行防眩處理、硬 塗層處理、抗反射處理之偏光板等。此外,亦可為在偏光 膜的單面積層由聚對笨二曱酸乙二酯膜、丙烯酸系膜、聚 丙烯膜等所成之保護膜或光學補償膜的偏光板。 &lt;面光源〉 本發明之液晶顯示裝置具備用以均勻地照明液晶面板 之面光源20。在本發明中,為了最大限度地發揮稜鏡片的 功能(使來自面光源的射出光偏向,而將來自稜鏡狀突起之 射出光的方向朝液晶顯示裝置的正面方向修正的功能),係 使用具有特定光射出特性(配光特性)的面光源作為面光源 20,具體而言,係滿足下述式(1)者: 322120 24 201107838 A2/A1M0 ⑴ 於此,參照第4圖,上述式(1)中,A1為:在與稜鏡 片所具有的稜鏡狀突起之稜線方向垂直的平面w内,將由 面光源的光射出面之法線方向τ與面光源的射出光之射出 方向Μ所成之角度作為射出角度θ(惟時, 射出角度0在0至X的範圍内的射出光之平均光強度;A2 為.射出角度在X至80。的範圍内的射出光之平均光強 度。此外,X係滿足下述式(2)的關係之角度〇 : sina/[sin(180°-a -2x)/2]-n (2) α係表示稜鏡片所具有的稜鏡狀突起之頂角,n係表示棱 鏡狀突起的折射率。 、首先,參照第5圖,對上述式⑵進行說明。在從面光 源的光射出面射出的光係以等於滿足上述式⑵的角度X 之射出角度Θ(射出角度(9 =χ)朝稜鏡狀突起入射的情形 中該入射光之光路徑在稜鏡狀突起内係以與稜鏡狀突起 的斜邊Ρ平行的方式被折射,而不產生因棱鏡狀突起的斜 邊Ρ所致之全反射。結果,從稜鏡狀突起射出的光比起入 射至稜鏡狀突起時,朝更遠離面光源的光射出面之法線方 向Τ的方向管折(參照第5⑷圖)。對於以比滿足上述式⑵ f角度X小的射出角度Θ從面光源的光射出面射出的光而 Z相同(參照第5⑹圖)。亦即,在從面光源的光射出面 轡:先之射出角度〜為χ以下的情形中’由於該出射光 ^由稜鏡片而朝遠離液晶顯示裝置的正面方向(面光 射出面之法線方向Τ)的方向彎折(該情形令,稜鏡 322120 25 201107838 片變成具有光擴散性),而使液晶顯示裝置的正面方向之直 度及對比度下降。再者,射出角度0係滿足〇^0⑽/;; 卜〇。係意指來自面光源的射出光之方向與面光源的光射 出面之法線方向Τ同方向,Θ =90。則意指來自面光源的射 出光之方向係與面光源的光射出面平行。 另一方面,在從面光源的光射出面射出的光之射出角 度Θ大於X的情形中,入射至稜鏡狀突起的入射光會因為 由稜鏡狀突起的斜邊ρ所致之全反射而聚集,而朝液晶顯 示裝置的正面方向(面光源的光射出面之法線方向τ)彎折 (參照第5(c)圖),使液晶顯示裝置的正面方向之亮度及對 比度獲得增進。 上过式(1)中,Α2/Α1係意指在從面光源射出的射出光 之中,藉由稜鏡片而聚集於液晶顯示裝置的正面方向之射 出光的光強度(平均光強度Α2),相對於藉由稜鏡片而朝遠 離面光源的光射出面之法線方向τ的方向彎折且結果不聚 集於液晶顯示裝置的正面方向之射出光的光強度(平均光 強度Α1)之比率;經本發明者的檢討,得知該比率avaj 超過10 (較宜超過20)時,在具備已使用稜鏡片的背面側偏 光板之液晶顯示裝置中,可獲得足夠高的正面方向之亮度 及對比度。再者,為了算出Α2而將所考慮的射出角度0的 上限設為80。之原因為,超過8〇。的角度之光強度係難以精 度良好地測定而不實用之故。可藉由以面光源的光射出面 之法線方向Τ為基準,在〇。至8〇。的範圍内,測定面光源 的亮度,而分別求得〇。至χ的範圍中亮度的平均值、χ至 322120 26 201107838 80 °的範圍中亮庶的正 . 〜度的干岣值,而獲得A1及A2。 &amp;此&lt; ’可採用複數個平面作為與棱鏡狀突起的稜線方 向垂直之平面W’而在本發明中,只要在至少任一個平面^ 中滿,上14式⑴即可。不過,為了在液晶顯示裝置的整個 内達成足夠高的亮度及對比度,較宜在任二個以 上之與稜鏡狀突起的稜線方向垂直之平面w中滿足上述式 ⑴。 用使用擴散板的直下型光源、使用導光板的側邊 (edge)型光源等作為面光源,但為了實現如上述的配光特 性’較宜使用如第1圖所示之具備導光板22以及配置於導 光板22側方的光源装置21之侧邊型光源(面光源20)。可 使用例如由丙烯酸系樹脂等透明樹脂所構成之平板狀或楔 形狀構件作為導光板22。在導光板的内面或兩面,藉由使 用油墨的網版印刷或蝕刻、喷砂(blast)加工而賦予圖案。 此外’在導光板的内面或兩面,有時亦構成具有反射功能 的微小反射元件、微小折射元件等。適當地調整該等導光 板的内面或兩面的形狀或元件,可獲得所期望的配光特 性。更具體而言,可適當地利用例如T〇ray Research Center 株式會社刊「液晶背光的最新技術第4章」或CMC出版株 式會社刊「液晶顯示器用背光技術第2編第1章、第4編 第1章」中所記载的光源裝置。 可使用將LED等點狀光源予以線性排列而成的光源裝 置或由冷陰極管等棒狀光源所構成之光源裝置作為光源裝 置21。在本發明之液晶顯示裝置中,面光源可具有配置於: 27 322120 201107838 配置於導光 導光板的一邊之一個光源裝置,或者亦可且有 板相對向的兩邊之二個光源裝置。 侧邊型光源所具備的將點狀光源予以線性為 裝置或由棒狀光源所構成之光源裝置係較宜纟列而成的 稜鏡片所具有的稜鏡狀突起之稜線平行气 二配 〜-加·,、由和,π技----- #、,、、&lt;平行。依此 配置成與 配置,側邊型光源發出的光可藉由稜鏡片而Τ行。依此 集。 敢有效率地聚 在本發明之液晶顯示裝置中,關於上述說明γ 成,可採用以往公知的適宜構成。舉例而t,以外的構 晶顯示裝置亦可進一步具備光擴散板、光二散=發明之液 等。 、反射板 [實施例] 以下係列舉實施例以進一步詳細說明本發明,惟本發 明不受該等實施例所侷限。 (製造例1 :偏光膜的製作) 將平均聚合度約2400、皂化度99. 9莫耳%(mole%)以 上之厚度75 yin的聚乙烯醇膜浸潰於30°C的純水中後,在 30°C浸潰於碘/碘化鉀/水的重量比為0.02/2/100的水溶 液中。之後,在56. 5°C浸潰於峨化鉀/硼酸/水的重量比為 12/5/100的水溶液中。隨後,在8。(:的純水中洗淨後,在 65。〇:進行乾燥,獲得使碘吸附配向於聚乙烯醇的偏光膜。 延伸主要係在碘染色及硼酸處理步驟中進行,總延伸倍率 為5. 3倍。 (製造例2:紫外線硬化型接著劑的調製) 28 322120 201107838 , 將日本環氧樹脂(股)所製之屬於氫化環氧樹脂的商品 .名EpicoatYX8000」(其為核氫化雙紛A之二縮水甘油驗, 具有約205 g/當量的環氧當量)1〇.〇 g、日本曹達(股)所 製之屬於光陽離子聚合起始劑的商品名「CI5102」4.〇 g、 以及日本曰達(股)所製之屬於光敏劑的商品名「CS⑽1」 1·〇 g予以量取至1GG ml可抛棄式杯具中’使其混合、脫 泡,藉此調製紫外線硬化型接著劑。 (製造例3:稜鏡片1的製作) 將已炫融之聚丙埽樹脂塗佈於預先設計成使成形後的 稜鏡狀突起(剖面形狀為二等邊三角形)之間距為5〇_及 頂角為65°的模具,進行加熱且同時加壓。然後,從模具 剝離後’立即冷卻至6(rc,以獲得由聚丙稀樹脂所構成^ 稜鏡片1。所有稜鏡狀突起皆具有按照設計的形狀。稜鏡 片1的折射率為1.49。 (製造例4:稜鏡片2的製作) 將具有以下所示組成之紫外線硬化型樹脂組成物塗佈 於預先設計成使成形後的稜鏡狀突起(剖面形狀為二等邊 二角形)之間距為50/z m及頂角為65。的模具,使其表面平 滑化後,將厚度188/zm的聚對笨二甲酸乙二酯膜重疊於由 紫外線硬化型樹脂組成物所構成之層上。接著,以累積照 射量為1000 mJ/cm2的方式照射波長32〇至39〇 nm的紫外 線,使紫外線硬化型樹脂組成物硬化。之後,藉由從模且 剝離,而獲得在聚對苯二甲酸乙二酯膜上積層著具有稜鏡 狀突起的紫外線硬化型樹脂組成物之硬化物層的稜鏡片^ 322120 29 201107838 2。任一棱鏡狀突起皆具有按照設計的形狀。稜鏡片2之複 鏡狀突起的折射率為1. 54。 (用於製造例4的紫外線硬化型樹脂組成物之組成) FANCRYL FA-321M(日立化成公司製造環氧乙院 (ethylene oyide)改質雙酚A甲基丙烯酸酯)45重量份 NK ESTER A-BPE-4(新中村化學公司製造環氧乙炫改質雙 紛A二丙稀酸自旨) 25重量份[SI 322120 21 201107838 The photo-hardening n and (4) light irradiation intensity are not particularly limited, and are determined appropriately by the composition of the root human I π/adhesive agent, but it is preferred to activate the polymerization initiator to the right t wavelength. In the case where the irradiation intensity of the field is 4 0.1 until the reaction time is not excessive and the degree is 0.1 or more, in the case where the irradiation intensity is 60 〇〇mw/cm 2 or less, the heat emitted from the light source is lightly emitted. When the photocurable adhesive is hardened, the problem of yellowing of the epoxy resin or deterioration of the polarizing film by Uxa is less. The light irradiation time of the photocurable adhesive is not particularly limited, and is controlled by a cured photocurable adhesive. However, the optimum amount of light (the product of the above irradiation intensity and the irradiation time) is 10 诵〇 _. In the case where the cumulative amount of light irradiated to the photocurable adhesive is 0 mJ/m or more, 'a large amount of activity derived from the polymerization initiator can be generated, and the hardening reaction can be more surely rided, corrected, and cured in light. In the case where the accumulated light amount of the vapor entering lamp is less than or equal to l_GmJ/m2, the ejaculation time is not too long, and good productivity can be maintained. The hardening of the second agent is preferably carried out under the condition that the polarizing degree, the transmittance and the hue of the polarizing film, and the functions of the polarizing plate such as the ribs, the protective film, and the optical leakage are not lowered. Before the ruthenium film and the protective film or the optical compensation film are attached to the polarizing film, in order to increase, (4), the surface of the rotating surface and/or the member attached to the polarizing film is subjected to plasma treatment, corona treatment, ultraviolet irradiation. Surface treatment such as treatment, flame treatment, deuteration treatment, etc. As the saponification treatment, for example, a method of immersing in an alkaline aqueous solution such as sodium oxynitride or hydrogen chloride detachment 322120 22 201107838. Further, as described above, the back side polarizing plate Can also have An optical functional film laminated on the surface of the polarizing film 12 opposite to the surface on which the prism sheet 13 is laminated. The optical functional film may be optically compensated by applying a liquid crystal compound to the surface of the substrate. a reflective polarizing film that transmits certain types of polarized light and reflects polarized light having the opposite property to the polarized light; a retardation film composed of a polycarbonate resin; a retardation film composed of a smoke-based resin film; a film having an anti-glare function having a concave-convex shape on the surface; a film having a surface anti-reflection function; a film having a reflective function on the surface and both reflecting function and penetrating A commercially available semi-transparent reflection film, etc., which is a commercially available product of an optical compensation film obtained by coating and aligning a liquid crystal compound to a surface of a substrate, may be, for example, a "WV film" (manufactured by Fujifilm Co., Ltd.). "NH film" (manufactured by Shin Sakamoto Oil Co., Ltd.) and "nr film" (manufactured by Nippon Oil Co., Ltd.). A commercially available product of a reflective polarizing film that reflects polarized light of a certain type and reflects polarized light having the opposite property to the polarized light is exemplified as "DBEF" (manufactured by 3M Company, Japanese is purchased from Sumitomo (share)). In addition, 'a commercially available product of a retardation film composed of a ring-shaped resin film is exemplified as "ART0N film" (manufactured by JSR), "Escena" (made by Sekisui Chemical Co., Ltd.), "ZEONOR film" (made by Japan Zeon Co., Ltd.). The back side polarizing plate preferably has an adhesive layer for bonding to the liquid crystal cell on the surface opposite to the crotch sheet. As the adhesive for such an adhesive layer, a conventionally known suitable adhesive can be used, and examples thereof include a bupropion acid-based adhesive, an amine ester-based adhesive, and a poly(oxygen) (si 1 icone) adhesive. Wait. 322120 23 201107838 =, from the viewpoints of transparency, adhesion, reliability, reworkability, etc., the father uses an acrylic adhesive. The adhesive layer may be applied by, for example, an organic solvent solution, which is applied to a substrate film (for example, a polarizing film or the like) by die, coating or gravure coating, and the like. Let it dry. Further, it may be laid by transferring a sheet-like adhesive formed on a release-treated plastic film (referred to as a separation film (1) to a substrate film). The thickness of the adhesive layer is not particularly limited', and is preferably in the range of 2 to 40 #m. <Front Side Polarizing Plate> The front side polarizing plate (the polarizing plate 2 in Fig. 1) is a polarizing plate disposed on the opposite side (visual side) from the surface light source with reference to the liquid crystal cell. A conventionally known suitable polarizing plate can be used as the front side polarizing plate. For example, in addition to the polarizing plate of the protective film formed of cellulose triacetate or the like on one or both areas of the polarizing film, anti-glare treatment, hard coating treatment, and anti-reflection treatment may be used. Polarizer, etc. Further, it may be a polarizing plate made of a protective film or an optical compensation film made of a polyethylene terephthalate film, an acrylic film, a polypropylene film or the like in a single-layer layer of a polarizing film. &lt;surface light source&gt; The liquid crystal display device of the present invention is provided with a surface light source 20 for uniformly illuminating the liquid crystal panel. In the present invention, in order to maximize the function of the cymbal (the function of deflecting the light emitted from the surface light source and correcting the direction of the light emitted from the ridge protrusion toward the front surface of the liquid crystal display device) The surface light source having the specific light-emitting characteristics (light distribution characteristics) is the surface light source 20, and specifically, it satisfies the following formula (1): 322120 24 201107838 A2/A1M0 (1) Here, referring to FIG. 4, the above formula ( In 1), A1 is a direction in which the normal direction τ of the light exit surface of the surface light source and the light emitted from the surface light source are emitted in a plane w perpendicular to the ridgeline direction of the meandering protrusion of the cymbal. The angle formed is the emission angle θ (only the average light intensity of the emitted light whose emission angle 0 is in the range of 0 to X; and A2 is the average light intensity of the emitted light in the range of the emission angle of X to 80. Further, the X system satisfies the relationship of the following formula (2): sina/[sin(180°-a - 2x)/2]-n (2) α represents the ridges of the cymbal The apex angle, n is the refractive index of the prismatic protrusion. First, refer to the 5, the above formula (2) will be described. The light emitted from the light exit surface of the surface light source is incident at an angle Θ equal to the angle X satisfying the above formula (2) (the exit angle (9 = χ) is incident on the dome-shaped projection. In this case, the light path of the incident light is refracted in a manner corresponding to the oblique side of the bead-like protrusion in the condyle without causing total reflection due to the bevel of the prism-like protrusion. The light emitted from the ridge-shaped projection is folded in a direction away from the normal direction of the light-emitting surface of the surface light source when it is incident on the ridge-shaped projection (see Fig. 5(4)). The above equation (2) is satisfied. The angle of incidence f at which the angle X is small is the same as the light emitted from the light exit surface of the surface light source, and Z is the same (see Fig. 5 (6)). That is, the light exiting the surface from the surface light source: the first angle of incidence is χ or less. In the case, 'the exit light is bent by the cymbal in a direction away from the front direction of the liquid crystal display device (the normal direction of the surface light exit surface) (in this case, 稜鏡322120 25 201107838 becomes light diffusion) Sex), and make the liquid crystal display device positive The straightness and contrast of the surface direction are reduced. Furthermore, the angle of incidence 0 is 〇^0(10)/;; 〇 〇 means that the direction of the emitted light from the surface light source is different from the normal direction of the light exit surface of the surface light source. The direction, Θ = 90, means that the direction of the emitted light from the surface light source is parallel to the light exit surface of the surface light source. On the other hand, the angle of incidence of light emitted from the light exit surface of the surface light source is greater than X. The incident light incident on the condyle is concentrated by the total reflection caused by the oblique side ρ of the conical protrusion, and is directed toward the front direction of the liquid crystal display device (the normal direction τ of the light exit surface of the surface light source) ) Bending (refer to Fig. 5(c)) improves the brightness and contrast in the front direction of the liquid crystal display device. In the above formula (1), Α2/Α1 means the light intensity (average light intensity Α2) of the emitted light concentrated in the front direction of the liquid crystal display device by the ruthenium in the emitted light emitted from the surface light source. The ratio of the light intensity (average light intensity Α1) of the light emitted from the direction of the normal direction of the light-emitting surface of the light-emitting surface of the liquid crystal display device by the ruthenium According to the review by the inventors of the present invention, when the ratio avaj exceeds 10 (more preferably 20), a sufficiently high front side brightness and contrast can be obtained in a liquid crystal display device having a back side polarizing plate using a cymbal sheet. . Further, in order to calculate Α2, the upper limit of the emission angle 0 to be considered is set to 80. The reason is more than 8〇. The light intensity of the angle is difficult to measure accurately and is not practical. It can be based on the normal direction Τ of the light exit surface of the surface light source. To 8 baht. Within the range, the brightness of the surface light source is measured, and 〇 is obtained separately. The average value of the brightness in the range of χ, χ to 322120 26 201107838 80 ° in the range of bright positive ~ ~ degree of dry value, and get A1 and A2. &lt;This &lt; ' can use a plurality of planes as the plane W' perpendicular to the ridgeline direction of the prism-shaped protrusions. In the present invention, the above formula (1) may be used as long as it is full in at least one plane. However, in order to achieve a sufficiently high brightness and contrast throughout the liquid crystal display device, it is preferable to satisfy the above formula (1) in a plane w which is perpendicular to the ridge direction of the ridges of any two or more. A direct-type light source using a diffusing plate, an edge type light source using a light guide plate, or the like is used as the surface light source. However, in order to realize the light distribution characteristics as described above, it is preferable to use the light guide plate 22 as shown in FIG. 1 and A side light source (surface light source 20) disposed on the light source device 21 on the side of the light guide plate 22. As the light guide plate 22, a flat plate-like or wedge-shaped member made of a transparent resin such as an acrylic resin can be used. The pattern is imparted on the inner surface or both sides of the light guide plate by screen printing using etching or etching or blast processing. Further, on the inner surface or both surfaces of the light guide plate, a minute reflection element or a minute refractive element having a reflection function may be formed. The desired light distribution characteristics can be obtained by appropriately adjusting the shape or elements of the inner or both sides of the light guide plates. More specifically, for example, T〇ray Research Center Co., Ltd., "The Latest Technology of Liquid Crystal Backlight, Chapter 4" or CMC Publishing Co., Ltd., "Backlight Technology for Liquid Crystal Display, Chapter 2, Chapter 1, Series 4" The light source device described in Chapter 1". A light source device in which a point light source such as an LED is linearly arranged or a light source device including a rod-shaped light source such as a cold cathode tube can be used as the light source device 21. In the liquid crystal display device of the present invention, the surface light source may have one light source device disposed on one side of the light guiding light guide plate, or may be provided with two light source devices on opposite sides of the plate. The side light source is provided with a linear light source device or a light source device composed of a rod light source, and the ridge line of the ridge piece which is preferably arranged is arranged in parallel with the ridge line of the ridge. Plus, , and ,, π----- #,,,, &lt; parallel. According to this configuration and configuration, the light emitted by the side light source can be carried by the cymbal. According to this collection. In order to efficiently gather the liquid crystal display device of the present invention, a conventionally known suitable configuration can be employed for the above description of γ formation. For example, other configurations of the crystal display device may further include a light diffusing plate, a light dispersion, a liquid for the invention, and the like. Mirrors [Examples] The following examples are given to further illustrate the present invention, but the present invention is not limited by the examples. (Production Example 1: Preparation of Polarizing Film) A polyvinyl alcohol film having an average polymerization degree of about 2,400 and a saponification degree of 99.9 mol% or more and a thickness of 75 yin was immersed in pure water at 30 ° C. It was immersed in an aqueous solution of iodine/potassium iodide/water in a weight ratio of 0.02/2/100 at 30 °C. Thereafter, it was immersed in an aqueous solution of potassium bromide/boric acid/water in a weight ratio of 12/5/100 at 56.5 °C. Subsequently, at 8. (: After washing in pure water, at 65. 〇: drying, obtaining a polarizing film for iodine adsorption to polyvinyl alcohol. The elongation is mainly carried out in the iodine dyeing and boric acid treatment steps, and the total stretching ratio is 5. (Manufacturing Example 2: Preparation of ultraviolet curable adhesive) 28 322120 201107838 , a product of hydrogenated epoxy resin manufactured by Japan Epoxy Resin Co., Ltd., Epicoat YX8000 (which is a nuclear hydrogenation double A) The second glycidol test, having an epoxy equivalent of about 205 g / equivalent), 〇g, a product of the photocationic polymerization starter manufactured by Japan Soda Co., Ltd., "CI5102" 4.〇g, and The product name "CS(10)1" manufactured by Japan Minda Co., Ltd. is measured in a 1GG ml disposable cup. It is mixed and defoamed to prepare an ultraviolet curing type adhesive. (Production Example 3: Production of cymbal sheet 1) The glazed polypropylene resin is applied to a predetermined distance such that the formed ridges (cross-sectional shape of the equilateral triangle) are 5 〇 _ and a mold with a apex angle of 65°, heated and simultaneously added Then, after peeling from the mold, it was immediately cooled to 6 (rc to obtain a crucible sheet composed of polypropylene resin. All the domes had a shape according to the design. The refractive index of the sheet 1 was 1.49. Production Example 4: Production of the crepe sheet 2) An ultraviolet curable resin composition having the composition shown below was applied in advance so that the distance between the formed dome-shaped projections (the cross-sectional shape is a two-sided square) was A mold having a thickness of 188/zm and a polyethylene terephthalate film having a thickness of 188/zm were superposed on a layer composed of an ultraviolet curable resin composition, and the mold having a 50/zm and a apex angle of 65 was smoothed. Ultraviolet rays having a wavelength of 32 〇 to 39 〇 nm were irradiated so as to accumulate an irradiation amount of 1000 mJ/cm 2 to cure the ultraviolet curable resin composition. Thereafter, by removing from the mold, the polyethylene terephthalate was obtained. A film of a cured layer of an ultraviolet curable resin composition having a dome-like protrusion is laminated on the diester film. 322120 29 201107838 2. Any of the prism-like protrusions has a shape according to the design. Burst The refractive index is 1.54. (Composition of the ultraviolet curable resin composition used in Production Example 4) FANCRYL FA-321M (Hitachi Chemical Co., Ltd. manufactures ethylene oyide modified bisphenol A methacrylate 45 parts by weight of NK ESTER A-BPE-4 (Nippon Nakamura Chemical Co., Ltd. manufactures epoxy Ethylene modified double A A diacrylic acid) 25 parts by weight

Sartomer 285(Sartomer公司製造丙烯酸四氫。夫喃曱酉旨) 30重量份Sartomer 285 (manufactured by Sartomer, tetrahydrogen acrylate) 30 parts by weight

Darocur-1173(Ciba公司製造 2-經基-2-曱基-卜笨基丙 3重量份 烷-1-酮) 〈實施例1&gt; (a)偏光板的製作 經由製造例2中獲得之紫外線硬化型接著劑,將製造 例3中獲得之棱鏡#丨,以與其稜鏡面為相反之綱面作 為貼合面,予以貼合於製造例丨中獲得之偏光膜之單側的 面此外,經由製造例2中獲得之紫外線硬化型接著劑, 將二醋酸纖維素膜⑽#m,K〇nica Mi⑽工乜〇pt〇公司製 貼合於偏光膜的另―面、然後’在日本電池(股)製造之 紫外線照射I置(紫外線燈係以謂使用“HAL4GGNL”,照 射距離為50 cm)中,传装以綠、♦奋】 以鏵猓且古白 吏其乂線速度L 〇 m/分鐘通過!次, 獲侍八有良好外觀的偏光板。屬 外線硬化型接著南丨&amp; 衣虱树月曰組成物之枭 主接者劑的硬化性良好。此外, §己载的棋盤格法評 捷鏡片1 —顿時,未剝離之媒盤 322120 30 201107838 格數相對 著丨生 ]所形成的棋盤格數為100/100,顯示良好的密 者 在該偏光板的三醋酸纖維素膜之外表面敷設厚度 25 β m的丙稀酸系黏著劑層。 (b)液晶顯示裝置的製作 經由丙稀酸系黏著劑層將上述偏光板配置於液晶單元 的背面,並將市售的偏光板配置於液晶單元的前面,以組 裝液晶面板。將該液晶面板與導光板方式(側邊型光源)的 面光源A (在Sony公司製造的VAIO VGN-FE32B/W中所使 用者)予以組合,以製作液晶顯示裝置。目視觀察液晶顯示 裝置的顯示時’從正面觀看可獲得明亮的影像,辨識度 (visibility)良好。使用 EZContrast(ELDIM 製造 LX88W) 測定之面光源A的光強度分佈係顯示於第6圖。 〈實施例2&gt; 除了使用製造例4中獲得之稜鏡片2代替製造例3中 獲得之稜鏡片1以外,以與實施例1相同的方式製作偏光 板,繼而製作液晶顯示裝置。目視觀察液晶顯示裝置的顯 示時,從正面觀看可獲得明亮的影像,辨識度良好。 〈比較例1&gt; 除了使用導光板方式(側邊型光源)的面光源B(在 Nanao公司製造的Flexscan EV2411W-H中所使用者)代替 面光源A以外,以與實施例1相同的方式製作液晶顯示裝 置。目視觀察液晶顯示裝置的顯示時,從正面觀看之影像 暗,對比度低,辨識度不良。使用EZContrast (ELDIM製 造LX88W)測定之面光源B的光強度分佈係顯示於第7圖。 31 322120 201107838 〈比較例2&gt; 除了使用製造例4中獲得之稜鏡片2代替製造例3中 獲得之稜鏡片1以外,以與比較例1相同的方式製作液晶 顯示裝置。目視觀察液晶顯示裝置的顯示時,從正面觀看 之影像暗,對比度低,辨識度不良。 用於上述實施例及比較例之稜鏡片所具有的稜鏡狀突 起的頂角、折射率、及從該等值依據式(2)而算出的角度X; 藉由面光源的亮度測定算出的A1及A2之值;以及所製作 的液晶顯示裝置之辨識度評估結果係總結於表1。液晶顯 示裝置的亮度及對比度係使用EZContrast(ELDIM製造 LX88W)在暗室中從正面測定液晶顯示裝置的中央部而求 得。實施例1及比較例1中製作的液晶顯示裝置之光強度 分佈(亮度分佈)係顯示於第8圖及第9圖。 [表1] 頂角 稜鏡片 折射率 X 面光源 光源裝置 A1 A2 液晶顯示裝置 目視評估 亮度 對比度 實施例1 65。 1.49 20.0 面光源A 1.51 6639 良好 389 896 實施例2 65。 1.54 21.5 面光源A 166 6849 良好 360 749 比較例1 65。 1.49 20.0 面光源B 1534 1956 不良 92 650 比較例2 65。 1.54 21.5 面光源B 1543 1967 不良 83 573 應瞭解此處揭示的實施形態及實施例在各方面皆為例 示而不構成限制。本發明的範圍非為前述的說明,而係由 申請專利範圍所界定,且其意圖包含與申請專利範圍均等 的意義以及範圍内的所有變更。 32 322120 201107838 % 【圖式簡單說明】 略剖=_顯不本發明之液晶顯示裝置的—較佳例之概 較佳例 第2圖係顯示用於本發明之背面侧偏光板的一 之概略剖視圖。 圖 第3圖係顯示稜鏡片的表面形狀之一 例的概略斜視 一 0係為了 5兒明用於本發明之面光源的光射出特性 之示意性斜視圖。 第5(a)圖至第5(c)圖係為了說明入射至稜鏡片所具 有的稜鏡狀突起的光之路徑的模式圖。 第6圖係顯示用於實施例丨及2之面光源a的光強度 分佈之圖。 第7圖係顯示用於比較例1及2之面光源6的光強度 分佈之圖。 第8圖係顯示實施例1中製作的液晶顯示裝置之光強 度分佈(亮度分佈)之圖。 第9圖係顯示比較例1中製作的液晶顯示裝置之光強 度分佈(亮度分佈)之圖。 【主要元件符號說明】 1、2偏光板 10 液晶面板 13 稜鏡片 14、16接著劑層 3 液晶早疋 12 偏光膜 13a棱鏡狀突起 15 樹脂膜 r 33 322120 201107838 17 黏著劑層 20 面光源 21 光源裝置 22 導光板 100 液晶顯示裝置 W 與稜鏡狀突起之稜線方向垂直的平面 T 面光源的光射出面之法線方向 Μ 面光源的射出光之射出方向 Θ 由面光源的光射出面之法線方向與面光源的射出光 之射出方向所成之角度 Ρ 稜鏡狀突起的斜邊 α 稜鏡狀突起的頂角 34 322120Darocur-1173 (manufactured by Ciba Co., Ltd. 2-Ethyl-2-mercapto-bromopropyl 3 lbute alkyl-1-one) <Example 1> (a) Preparation of polarizing plate Ultraviolet rays obtained in Production Example 2 In the hardening type adhesive, the prism #丨 obtained in the production example 3 is bonded to the surface of one side of the polarizing film obtained in the production example by using the surface opposite to the kneading surface as a bonding surface. The ultraviolet curable adhesive obtained in Production Example 2 was bonded to the other side of the polarizing film by a cellulose diacetate film (10) #m, K〇nica Mi (10), and then in the Japanese battery. ) Manufactured by ultraviolet irradiation I (UV light is "HAL4GGNL", the irradiation distance is 50 cm), and it is green, ♦ 奋 】 铧猓 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古 古by! In this case, I received a polarizer with a good appearance. It is an external hardening type and then the composition of the 丨 丨 & 虱 曰 曰 曰 枭 枭 枭 枭 枭 枭 枭 枭 枭 枭 枭 枭 枭 枭 枭In addition, § has a checkerboard method to evaluate the lens 1 - suddenly, the unpeeled media disk 322120 30 201107838 grid number relative to the twins formed by the number of checkers is 100 / 100, showing good secrets in the An acrylic-based adhesive layer having a thickness of 25 μm was applied to the surface of the triacetylcellulose film of the polarizing plate. (b) Production of liquid crystal display device The polarizing plate was placed on the back surface of the liquid crystal cell via an acrylic adhesive layer, and a commercially available polarizing plate was placed on the front surface of the liquid crystal cell to assemble the liquid crystal panel. The liquid crystal panel and the surface light source A of the light guide plate type (side type light source) (used by VAIO VGN-FE32B/W manufactured by Sony Corporation) were combined to fabricate a liquid crystal display device. When the display of the liquid crystal display device is visually observed, a bright image can be obtained from the front, and the visibility is good. The light intensity distribution of the surface light source A measured using EZ Contrast (ELDIM manufactured LX88W) is shown in Fig. 6. <Example 2> A polarizing plate was produced in the same manner as in Example 1 except that the ruthenium sheet 2 obtained in Production Example 4 was used instead of the ruthenium sheet 1 obtained in Production Example 3, and a liquid crystal display device was produced. When the display of the liquid crystal display device is visually observed, a bright image can be obtained from the front, and the visibility is good. <Comparative Example 1> A surface light source B (a user of a Flexscan EV2411W-H manufactured by Nanao Co., Ltd.) using a light guide plate method (side light source) was used in the same manner as in Example 1 except that the surface light source A was used. Liquid crystal display device. When the display of the liquid crystal display device was visually observed, the image viewed from the front was dark, the contrast was low, and the visibility was poor. The light intensity distribution of the surface light source B measured using EZ Contrast (ELDIM manufactured LX88W) is shown in Fig. 7. 31 322120 201107838 <Comparative Example 2> A liquid crystal display device was produced in the same manner as in Comparative Example 1, except that the ruthenium sheet 2 obtained in Production Example 4 was used instead of the ruthenium sheet 2 obtained in Production Example 3. When the display of the liquid crystal display device was visually observed, the image viewed from the front was dark, the contrast was low, and the visibility was poor. The apex angle, the refractive index, and the angle X calculated from the equivalent value (2) obtained from the ridges of the above-described examples and comparative examples are calculated by the luminance measurement of the surface light source. The values of A1 and A2; and the results of the evaluation of the liquid crystal display device produced are summarized in Table 1. The brightness and contrast of the liquid crystal display device were determined by measuring the center portion of the liquid crystal display device from the front side in a dark room using EZ Contrast (manufactured by ELDIM LX88W). The light intensity distribution (brightness distribution) of the liquid crystal display devices produced in Example 1 and Comparative Example 1 is shown in Figs. 8 and 9. [Table 1] Vertex angle Sepal index Refractive index X-surface source Light source device A1 A2 Liquid crystal display device Visual evaluation Brightness Contrast Example 1 65. 1.49 20.0 Surface light source A 1.51 6639 Good 389 896 Example 2 65. 1.54 21.5 Surface Light Source A 166 6849 Good 360 749 Comparative Example 1 65. 1.49 20.0 Surface light source B 1534 1956 Bad 92 650 Comparative example 2 65. 1.54 21.5 Surface Light Source B 1543 1967 Bad 83 573 It is to be understood that the embodiments and examples disclosed herein are illustrative and not restrictive. The scope of the present invention is defined by the scope of the claims, and is intended to include all modifications within the meaning and scope of the claims. 32 322120 201107838 % [Simplified illustration of the drawings] A section of the liquid crystal display device of the present invention - a preferred embodiment of the preferred embodiment Fig. 2 is a schematic view showing a back side polarizing plate used in the present invention. Cutaway view. Fig. 3 is a schematic perspective view showing an example of the surface shape of the cymbal sheet. The squint of the smear is a schematic oblique view of the light-emitting characteristics of the surface light source used in the present invention. Figs. 5(a) to 5(c) are schematic views for explaining the path of light incident on the ridges having the ridges. Fig. 6 is a view showing the light intensity distributions of the surface light sources a used in the examples 丨 and 2. Fig. 7 is a view showing the light intensity distributions of the surface light sources 6 for Comparative Examples 1 and 2. Fig. 8 is a view showing the light intensity distribution (brightness distribution) of the liquid crystal display device produced in Example 1. Fig. 9 is a view showing the light intensity distribution (brightness distribution) of the liquid crystal display device produced in Comparative Example 1. [Main component symbol description] 1, 2 polarizing plate 10 liquid crystal panel 13 cymbal sheet 14, 16 adhesive layer 3 liquid crystal early 12 polarizing film 13a prismatic protrusion 15 resin film r 33 322120 201107838 17 adhesive layer 20 surface light source 21 light source Device 22 Light guide plate 100 The liquid crystal display device W is perpendicular to the ridge line direction of the ridge line. The normal direction of the light exit surface of the surface light source Μ The direction in which the light source emits light Θ The light exit surface of the surface light source The angle between the line direction and the direction in which the surface light source emits light 斜 the beveled edge of the beak-like protrusion α the vertex angle of the conical protrusion 34 322120

Claims (1)

201107838 七、申請專利範圍: 1. 一種液晶顯示裝置,其係由下列者所構成: • 面光源;以及 配置於前述面光源上且具備液晶單元及積層於前 述液晶單元的面光源側的面之偏光板的液晶面板; 其中,前述偏光板係具備:偏光膜、以及經由接著 劑層積層於前述偏光膜的表面之稜鏡片,該棱鏡片具有 由稜鏡狀突起所構成的表面, 前述稜鏡片係配置成使得由前述稜鏡狀突起所構 成的表面相對向於前述面光源; 在與則述稜鏡狀突起的稜線方向垂直之平面内之 前述面光源的射出光之光強度分佈係滿足下述式(1): A2/A1&gt;10 (1) [於此,在上述式(1)中,A1為··在前述平面内, 將由前述面光源的光射出面之法線方向與前述面光源 的射出光之射出方向所成之角度設為射出角度0 (惟 〇 = 6^90 )时’射出角度0在〇。至X的範圍内的射 出光之平均錢度,A2為射出角度^在乂至⑽。的範圍 内的射出光之平均光強度; x係滿足下述式(2)的關係之角度(。): sina/[sin(180°-a-2x)/2]-n ⑵ ^上述式(2)中,α係表示前述稜鏡狀突起之頂角,n 係表示前述稜鏡狀突起的折射率]。 .如申明專利|ϋ圍f 1項所述之液晶顯示裝置,其中,前, 322120 35 201107838 述面光源係由導光板、以及配置於前述導光板側方的光 源裝置所構成。 3.如申請專利範圍第2項所述之液晶顯示裝置,其中,前 述光源裝置係為將點狀光源予以線性排列而成的光源 裝置或由棒狀光源所構成的光源裝置, 前述光源裝置與前述稜鏡片係配置成使前述光源 裝置與前述稜鏡狀突起之稜線平行或約略平行。 如申切專利範圍第1至3項中任一項所述之液晶顯示裝 置,其中,前述光源裝置係配置於前述導光板的一邊或 相對向的兩邊。 5.如申請專利範圍第丨至4項中任—項所述之液晶顯示裝 置,其中,前述稜鏡狀突起的頂角α為6〇。以上。 322120 36201107838 VII. Patent application scope: 1. A liquid crystal display device comprising: a surface light source; and a surface light source disposed on the surface light source and having a liquid crystal cell and a surface laminated on a surface light source side of the liquid crystal cell a liquid crystal panel of a polarizing plate, wherein the polarizing plate comprises: a polarizing film; and a ruthenium layer laminated on a surface of the polarizing film via an adhesive, the prism sheet having a surface formed by a dome-shaped protrusion, the cymbal The surface of the surface light source is opposite to the surface light source; the light intensity distribution of the light emitted by the surface light source in a plane perpendicular to the ridgeline direction of the ridge line is satisfied. (1): A2/A1 &gt; 10 (1) [In the above formula (1), A1 is a normal direction of the light exit surface of the surface light source and the surface in the plane When the angle of the exit direction of the light emitted by the light source is set to the exit angle 0 (only 〇 = 6^90), the exit angle 0 is 〇. The average amount of light emitted to the range of X, A2 is the angle of incidence ^ to ( to (10). The average light intensity of the emitted light in the range of x; x is the angle (.) satisfying the relationship of the following formula (2): sina/[sin(180°-a-2x)/2]-n (2) ^ In 2), α represents the apex angle of the above-mentioned ridge, and n represents the refractive index of the ridge. The liquid crystal display device of the above-mentioned Japanese Patent Application No. 322120 35 201107838, the front surface light source is composed of a light guide plate and a light source device disposed on the side of the light guide plate. 3. The liquid crystal display device according to claim 2, wherein the light source device is a light source device in which point light sources are linearly arranged, or a light source device including a rod light source, and the light source device The cymbal is configured such that the light source device is parallel or approximately parallel to the ridgeline of the aforementioned dome. The liquid crystal display device according to any one of claims 1 to 3, wherein the light source device is disposed on one side or opposite sides of the light guide plate. The liquid crystal display device according to any one of the preceding claims, wherein the apex angle α of the aforementioned dome is 6 〇. the above. 322120 36
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TWI659247B (en) * 2012-02-17 2019-05-11 學校法人慶應義塾 Liquid crystal display device

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