201102478 六、發明說明： 【發明所屬之技術領域】 本發明關於一種利用溶融狀態的含硫磺資材來製 造薄板狀硫磺固化體鑲板之硫磺固化體鑲板的製造方 法。 【先前技術】 一般來說土木、建設用資材係利用以水泥來將骨架 材料加以結合之混凝土。其中，埋設模框或後貼鑲板等 所使用之平板狀鑲板多半為砂漿(mortar)製。然而，由 於砂漿製鑲板的強度不高，且依使用環境的不同而有強 度及对久性的問題。又，大部分的砂毁製镶板為了提高 其強度及耐久性會使用鋼筋或其他的補強材料，而使得 產品的厚度或重量增加。在此種狀況下，則期望有一種 強度及耐久性高的薄板狀鑲板來作為土木、建設用 材。 針對上述情事，近年來著眼於常溫下為固體且加熱 至大約119°C〜159。(：時會溶融之硫磺的性質，嘗試在硫 石黃中添加特定的試料來作為—種土木、建設用資材而加 以使用。已知使用此種硫續的含硫績資材和使用水泥之 通常的混凝土相比’為__種強度較高、防水性良好，且 耐酸性高之材料。然後，由於含硫韻材和通常的混凝 土在成品上或處理上看起來相類似，因此有將固化後的 物品稱為硫磺混凝土或硫磺固化體(例如，參照日本特 4 201102478 開 2004-160693 號公報）。 此處，由於硫磺具有著火性，而被當作所謂的危險 物處理，因此要在現場進行溶融、灌漿之事非常困難。 為了改善此種狀況，便嘗試在溶融硫磺中混合硫磺改質 劑來作為添加劑，以改變該硫磺的性質來製造改質硫 〜。又，§ s式將該改質硫確與微細粉末混合來製造溶融 狀態的改質硫磺中間資材，以及將該改質硫磺中間資材 與骨架材料混合並將其固化來製造改質硫磺固化體(例 如’參照日本特開2005-82475號公報）。 然後’在將上述溶融狀態的含硫磺資材（包含改質 硫磺中間資材)冷卻固化以形成硫磺固化體（包含改質硫 確固化體）時，係將上述含硫磺資材倒入特定形狀的模 框内來使其冷卻固化。 然而’上述溶融狀態的含硫磺資材在低於硫磺的固 化溫度（約119°C)時’會開始固化。此時’將溶融狀態 的含硫磺資材直接倒入常溫狀態的模框時，該模框内所 充填之含硫磺資材會被急速冷卻’因此在固化過程中， 模框内的含硫磺資材會收縮’而在硫磺固化體（具體而 言為硫磺固化體鑲板）的上部或内部產生空洞，或上面 凹陷’而容易在表面產生氣泡。因此，硫磺固化體(硫 確固化體鑲板）的成品不佳，而被期望能對其成品作改 善。又’當該空洞過大時，會難以修補。 【發明内容】 201102478 本毛明4α於上述問題點，其目的在於提供一種可製 造產品的成品良好之硫續固化體鎮板的硫續固化體鎮 板之製造方法。X，其目的在於提供—種可組裝在各種 =疑土構造物之硫績固化體鑲板，以及將該硫續固化體 鑲板組裝在各種混凝土構造物之組裝方法。 /本!X明其中-樣·％之硫石黃固化體鎮板的製造方法 係利用含硫料材㈣造硫伽化贿板，其包 下步驟： 績融=二將上面具有開口之箱形模框加熱至硫 後的係絲雜f'的含剌㈣充填入加熱 徐冷步驟’係使充填有該含硫射材的模框在 中自然冷卻並徐冷； ’、 脫模步驟，係將成型於該模框内之鑲板狀物從 冷卻後的模框取出；以及 目 ,、'墙正步驟，係使從模框取出之鑲板狀物在空氣中△ 卻 f£；。 令 一本發明另一樣態之硫磺固化體鑲板係利用含硫於 資材而形成為薄板狀，餘裝於混凝土構造物的表^ 成有至少-個從鑲板表面貫穿至鑲板 階 段式貫穿孔； 白 >立階段式貫穿孔係包含有形成於該鑲板表面側之 坑。卩，以及與該柱坑部相連通且口徑較該柱坑部要小之 6 201102478 貫穿孔 本發明另一樣態之硫磺固化體鑲板的組裝方 將利用含硫4資材而形成為薄板狀之硫續固化體係 組裝於混凝土構造物，其中該硫磺固化體鑲板係形成= 至少一個階段式貫穿孔，該階段式貫穿孔係包含有形^ 於鑲板表面侧之柱坑部，以及與該柱坑部相連通且v、 較該柱坑部要小之貫穿孔； 該硫磺固化體鑲板的組裝方法包含有以下步驟. (a) 第1步驟，係於該混凝土構造物形成錨孔，並於 所形成之錨孔設置錨栓； < (b) 苐2步驟，係使該銷检插通於該階段式貫穿孔 並以耐酸性接著劑將該硫磺固化體鑲板的鑲板内面貼 附在該混凝土構造物的表面； ' (c) 第3步驟，係將其外徑較該柱坑部的口徑要小且 較該小口徑貫穿孔的口徑要大，並且其高度係較該柱坑 部的深度要小之碟塑螺帽裝設於該錨栓的頭部侧’藉由 將該碟型螺帽鎖入，以使該硫確固化體鑲板固定在該固 化構造物的表面； (d) 第4步驟，係將該錨栓中從該碟型螺帽突出的部 分裁斷；以及 (e)第5步驟，係將該耐酸性接著劑充填入該柱坑部 内而被覆該錨栓的裁切面及該碟型螺帽，並使所充填之 接著劑均勻分佈以使該硫磺固化體鑲板的銀板表面平 坦化。 7 201102478 本發明另一樣態之硫磺固化體鑲板的組裝方法係 將利用含硫續資材而形成為薄板狀之硫磺固化體鑲板 組裝在混凝土構造物； 其中該硫磺固化體鑲板形成有至少1個包含有形 成於鑲板表面側之柱坑部以及與該柱坑部相連通且較 該柱坑部要小口徑的貫穿孔之階段式貫穿孔； 並具有以下步驟： (a) 第1步驟，係於該混凝土構造物形成有錨孔，並 將陰螺絲錦打入所形成之錦孔； (b) 第2步驟，係以耐酸性接著劑將該硫磺固化體鑲 板的鑲板内面貼附在该混凝土構造物的表面，以使該階 段式貫穿孔對應於該陰螺絲錯； (c) 第3步驟’係藉由使其頭部的外徑較該柱坑部的 =徑要小並較該小口徑貫穿孔的口徑要大，且其頭部的 尚度較該硫磺固化體鑲板的該柱坑部的深度要小之低 碩螺栓插通該階段式貫穿孔並鎖入該陰螺絲錨，來將該 硫磺固化體鑲板固定在該混凝土構造物的表面； (d) 第4步驟，係將該耐酸性接著劑充填入該柱坑部 内而被覆該低頭螺栓的頭部，並使所充填之接著劑均勻 分佈以使該硫確固化體鑲板的鑲板表面平坦化。 本發明另一樣態之硫磺固化體鑲板的組裝方法係 將利用含硫4資材而形成為薄板狀之硫如化體鎮板 組裝在混凝土構造物； 其中該硫磺固化體鑲板形成有至少丨個包含有形 201102478 成於鑲板表面侧之柱坑部以及與該柱坑部相連通且較 該柱坑部要小口徑的貫穿孔之階段式貫穿孔； 又 並具有以下步驟： (a) 第1步驟，係於該混凝土構造物形成有錨孔，將 陰螺絲錨打入所形成之錨孔，並將棒型螺栓裝設在該 螺絲錯； w (b) 第2步驟，係使該棒型螺栓插通該階段式貫穿 孔，並以耐酸性接著劑將該硫磺固化體鑲板的鑲板内面 貼附在該混凝土構造物的表面； (c) 苐3步驟，係將該棒型螺检卸下； (d) 第4步驟，係藉由使其頭部的外徑較該柱坑部的 口徑要小並較該小口徑貫穿孔的口徑要大，且其頭部的 尚度較該硫續固化體镶板的該柱坑部的深度要小之低 頭螺拴插通該階段式貫穿孔並鎖入該陰螺絲錨，來將該 硫磺固化體鑲板固定在該混凝土構造物的表面； (e) 第5步驟’係將該耐酸性接著劑充填入該柱坑部 内而被覆該低頭螺栓的頭部，並使所充填之接著劑均勻 分佈以使該硫磺固化體鑲板的鑲板表面平坦化。 【實施方式】 以下，根據添附圖式加以說明本發明實施形態。 圖1係顯示用以實施本發明硫磺固化體鑲板製造 方法的生產線範例之概要圖。本實施形態之硫磺固化體 鑲板的製造方法係利用上面具有開口之箱形模框來使 201102478 加熱而溶融狀態的含硫磺資材成型並固化以製造薄 狀硫磺固化體鑲板，在圖1所示之生產線中，包含有將 模框預先加熱之預熱步驟、將溶融狀態的含硫磺資材充 填入加熱後的模框内之灌漿步驟、使充填有含硫磺資材 之模框徐冷之徐冷步驟、從模框將鑲板狀物取出之脫模 步驟、以及對取出之鑲板狀物進行矯正(curing)之矯正 步驟。 円 預熱步驟係將模框加熱至硫磺的融點（丨i 9 °c)左右 之溫度，在圖1中，係將模框2插入至模框加熱器j的 内部來進行加熱。此處，模框2係由鐵等金屬所構成， 如圖2〜圖5所示，係形成為上面具有開口之扁平箱型 形狀。 圖2為模框2之俯視圖。如圖2所示，模框2包含 有例如長方形的底板3與設置於底板3的周圍並具有特 定高度之框組件4，利用該底板3與四個框組件4來形 成上面具有開口且相對於底面積而高度尺寸較小之扁 平箱型形狀。本實施形態中，模框2的尺寸為例如 400mm(縱)x800mm(横)xl2mm(高度）。但模框2的尺寸 可配合硫磺固化體鑲板的樣式來適當地設定，例如高度 尺寸(硫磺固化體鑲板的厚度)可大至40〜50mm左右為 只。 此外’圖2中，元件符號5係為了在製品之硫磺固 化體鑲板的平面部形成開孔，亦即朝向硫磺固化體鑲板 的厚度方向延伸之貫穿孔，而在底板3設置之銷（貫穿 201102478 孔形成奶，元件符號6為運送模框2時所利用之Μ 圖3為模框2之仰視圖。如圖3所示，底极3的内面周 圍係設&有具㈣定高度而剖面R L _底部框組件 7,底板3之内面t央部的4個部位處係設置有 框2載置於後述作業台時，與該作業台上面所設置之凸 部等相卡合以防止模框2的位置偏移之卡合部卜此 外，圖4為模框2之前視圖，圖5為模框2之側面圖。 如圖2、圖3所示，在其中—框組件4裂設有二個 將加厪空氣注人之開口金屬件9。該開π金屬件9係在 將模框2内所成型之鎮板狀物從該模框2取出時，將加 壓空氣注=鎮板狀物與模框2的交界部分，如圖从、 :6::斤不’而在底板3的表面處連通至形成於框组件 反3的交界部分之空氣注人孔iQ。藉由從開口金 ^ /透過空氣注人孔1G來將加壓空氣注人模框2 °吏模忙2内所成型之鑲板狀物剝離並容易從該模 處’如圖6Β所示，與底板3表面相連接 2 士、4的内側周緣部為朝内之傾斜面。藉此，模框 部便形成㈣的平板狀側的面(镶板面)之周緣 圖7、、戶，」在預熱步驟中，將上述方式構成的模框2從 u得由鐵:形成為縱向放置的收納箱狀之模框加熱器 上、捭，金屬所構成)的上部開口部11插入至内部， 務動5二圖8所示之上蓋12的把持部13來將上蓋12 开α部U，而如圖9所示般地將上蓋12被覆在 201102478 開口部li並將周圍的螺栓14栓緊以將上蓋i2固定， 然後，使模框加熱器i動作以將模框2加熱至硫續的融 點（119C)左右之溫度。預熱結束後，在圖9中，將螺检 14鬆他以將上蓋12卸下，並把持著把手6來將插入至 ^框加熱H 1的㈣之_ 2取出後㈣送至後續步 在圖7〜®1 9所示之範例中，模框加熱器1的執源 係=利用魏’元件符號15係顯㈣氣的注入管，元 件符號16係顯示蒸氣的排出管，元件符號17係顯示用 以計測注人蒸氣_力之壓力計。又，圖ι中，元件符 號18、19係顯示用以從煮彿室（圖示省略)將蒸氣供給至 複數個模框加熱器1之配f。然後，如圖7〜圖9所示， 將模框2插人域框加絲丨内，並注人域至例如 1.5〜2大氣壓的錢氣4〜5分鐘，來賴框2加軌至 120〜130°C左右。 … 。但模框加熱器1的熱源不限於蒸氣’可利用電熱加 熱器。另夕卜’亦可利用蒸氣及電熱加熱器以外的其他熱 源0 接下來，賴步驟係將被加熱至硫確融點以上的設 定溫度範®内之溶融狀態的含料諸充填人在預熱 步驟中所加熱之模框2内，在圖i中’係從模框加熱器 1將預熱結束後的模框2取出並載置在作業台2〇的上 面，以將溶融狀態的含硫磺資材充填入該模框2内。具 體而言，如圖10所示，係以將模框2水平地載置於作 12 201102478 2〇上’來使容器21 β所容納之溶融狀態的含硫績 =22在模框2内全面地擴散之方式來充填，以進行 f 1層含硫石黃資材22(22a)的灌疑。此時 石^0振動來—邊振動模框2—邊充填溶融狀態的含Ϊ =貝材22。如此地，所充填之含硫石黃資材22的内部則 較不易形成空洞。 此外’在將含硫4資材22充填人模框2内前，亦 ^先將剝離材料塗佈在該模框2的内面。如此地，便 能容易地從該模框2將模框2内所成型之鑲板狀物取 出又，較佳地係預先使得用以注入加壓空氣之開口金 屬件9及空氣注入孔10的空氣良好地流通。 接下來，針對含硫績資材22加以說明。含硫續資 材被稱為「硫磺固化體」’其係利用在常溫下為固體且 在大約119〜159°C會溶融之硫磺的性質，而藉由在加熱 至119 C以上的設定溫度範圍内之溶融後的硫石黃中混合 石灰或砂、砂礫等，在一邊保持在大約U9〜159°C—邊 揉混後將其冷卻硬化所製造。或者，被稱為「改質硫磺 固化體」’其係同樣地藉由將加熱而成為溶融狀態的硫 磺與用以使該溶融硫磺變性之硫磺改質劑混合來製造 改質硫磺，並於該改質硫磺中混合砂或砂礫、石灰等， 而與上述同樣地一邊加熱一邊揉混後將其冷卻硬化所. 製造。亦即，含硫磺資材係包含有上述硫磺固化體與上 述改質硫磺固化體。又，本說明書中，即使是單純記載 為「琉磺固化體」者，該記載亦包含有「改質硫磺固化 13 201102478BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a sulfur-cured body panel using a sulfur-containing material in a molten state to produce a thin plate-shaped sulfur-cured body panel. [Prior Art] In general, civil engineering and construction materials use concrete that combines skeleton materials with cement. Among them, most of the flat panels used for embedding a frame or a rear panel are made of mortar. However, the strength of the mortar panel is not high, and there is a problem of strength and durability depending on the environment of use. Also, most of the sand-damaged panels use steel bars or other reinforcing materials to increase their strength and durability, resulting in an increase in the thickness or weight of the product. Under such circumstances, it is desirable to have a thin plate-like panel having high strength and durability as a civil engineering or construction material. In view of the above, in recent years, attention has been focused on solid at normal temperature and heating to about 119 ° C to 159. (: The nature of the sulfur that will melt in the case, try to add a specific sample to the pyrite yellow as a kind of civil engineering and construction materials. It is known to use such sulfur-containing sulfur-containing materials and the use of cement. Compared with concrete, it has a high strength, good water resistance and high acid resistance. Then, since the sulfur-containing material and the usual concrete look similar on the finished product or treatment, it will be cured. The latter article is called a sulphur concrete or a sulfur-cured body (for example, refer to Japanese Patent Publication No. 4 201102478, No. 2004-160693). Here, since sulfur is flammable, it is treated as a so-called dangerous substance, so it is required to be on site. It is very difficult to carry out the melting and grouting. In order to improve this situation, it is attempted to mix the sulfur modifier in the molten sulfur as an additive to change the properties of the sulfur to produce the modified sulfur~. Further, § s The modified sulfur is mixed with the fine powder to produce a modified sulfur intermediate material in a molten state, and the modified sulfur intermediate material is mixed with the skeleton material and solidified. A modified sulfur-cured body is produced (for example, 'refer to Japanese Laid-Open Patent Publication No. 2005-82475). Then, the sulfur-containing material (including the modified sulfur intermediate material) in the above-mentioned molten state is cooled and solidified to form a sulfur-cured body (including modification). When the sulfur is solidified, the sulfur-containing material is poured into a mold of a specific shape to be cooled and solidified. However, the sulfur-containing material in the above molten state is lower than the curing temperature of sulfur (about 119 ° C). 'It will start to solidify. At this time, when the molten sulfur-containing material is directly poured into the mold frame at normal temperature, the sulfur-containing material filled in the mold frame will be rapidly cooled'. Therefore, during the curing process, the mold frame is The sulphur-containing material shrinks and creates voids in the upper or inner part of the sulfur-cured body (specifically, the sulphur-cured body panel), or it is recessed on the surface to easily generate bubbles on the surface. Therefore, the sulfur-cured body (sulfur-cured body) The finished product of the panel is not good, and it is expected to improve its finished product. Also, when the cavity is too large, it will be difficult to repair. [Invention content] 201102478 Ben Maoming 4α The problem is to provide a method for producing a sulphur-reinforced body sheet of a good finished sulfur-cured body sheet which can be manufactured as a product. X, the object of the invention is to provide a kind of structure which can be assembled in various = suspected soil structures. The sulphur-hardened body panel and the assembly method of assembling the sulphur-hardened body panel in various concrete structures. /本!X 明中-%·% of the sulphur-yellow solidified slab manufacturing method is utilized Sulfur-containing material (4) sulphurization and sulphurization bribe board, the steps of the package: The smelting = 2 The stencil containing the open box-shaped mold frame heated to the sulphur after the sulphur is filled with 剌 (4) 'The frame is filled with the sulfur-containing material and is naturally cooled and quenched; ', the demolding step is to take out the panel formed in the mold frame from the cooled mold frame; , the 'wall positive step, is to remove the panel from the mold frame in the air △ but f £; Another embodiment of the sulfur-cured body panel of the present invention is formed into a thin plate shape by using sulfur as a material, and the surface of the concrete structure is at least one through the panel surface to the panel stage. Hole; White> The vertical stage through hole system includes pits formed on the surface side of the panel.卩 以及 以及 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 The sulfur continuous curing system is assembled to the concrete structure, wherein the sulfur solidified panel is formed = at least one stepped through hole, the staged through hole comprising a column portion tangible on the surface side of the panel, and the column a through hole in which the pit portion is connected and v is smaller than the column pit portion; the method for assembling the sulfur solidified body panel includes the following steps: (a) the first step is to form an anchor hole in the concrete structure, and Providing an anchor bolt to the formed anchor hole; < (b) 苐2 step of inserting the pin inspection into the stepped through hole and pasting the inner surface of the sulphur cured body panel with an acid resistant adhesive Attached to the surface of the concrete structure; '(c) The third step is to make the outer diameter smaller than the diameter of the column hole and larger than the diameter of the small diameter through hole, and the height is higher than the column a disc-shaped plastic nut having a small depth is installed in the anchor The head side ' is locked by the disc nut to fix the sulfur solidified body panel on the surface of the solidified structure; (d) in the fourth step, the anchor bolt is removed from the disc type a portion of the nut that protrudes; and (e) a fifth step of filling the column with the acid-resistant adhesive to cover the cut surface of the anchor and the disc nut, and filling the adhesive It is evenly distributed to planarize the surface of the silver plate of the sulfur cured body panel. 7 201102478 Another method of assembling a sulfur-cured body panel according to the present invention is to assemble a sulfur-solidified panel formed into a thin plate shape using a sulfur-containing continuation material in a concrete structure; wherein the sulfur-cured body panel is formed with at least a stepped through hole including a column portion formed on a surface of the panel surface and a through hole communicating with the column portion and having a smaller diameter than the column portion; and having the following steps: (a) 1st a step of forming an anchor hole in the concrete structure and driving the female screw into the formed hole; (b) in the second step, the inner surface of the panel of the sulfur solidified body is plated with an acid resistant adhesive Attached to the surface of the concrete structure such that the stepped through hole corresponds to the female screw; (c) the third step 'by making the outer diameter of the head smaller than the diameter of the column Small and larger than the diameter of the small-diameter through-hole, and the head is less than the depth of the column portion of the sulfur-cured body panel, and the low-profile bolt is inserted into the stage through-hole and locked The female screw anchor to fix the sulfur solidified panel to the a surface of the concrete structure; (d) in the fourth step, the acid-resistant adhesive is filled into the column to cover the head of the anchor bolt, and the filled adhesive is evenly distributed to make the sulfur solid The panel surface of the chemical panel is flattened. Another method for assembling a sulfur-cured body panel according to another aspect of the invention is to assemble a sulfur-like slab of a sulfur-like material into a concrete structure using a sulfur-containing material, wherein the sulfur-cured body panel is formed with at least 丨a stepped through hole having a shaped hole 201102478 formed on the surface side of the panel and a through hole communicating with the column portion and having a smaller diameter than the column portion; and having the following steps: (a) In the first step, the concrete structure is formed with an anchor hole, the female screw anchor is driven into the formed anchor hole, and the rod bolt is installed on the screw; w (b) the second step is to make the rod a type of bolt is inserted through the stepped through hole, and the inner surface of the panel of the sulfur solidified panel is attached to the surface of the concrete structure with an acid resistant adhesive; (c) 苐3 step, the rod type screw (d) The fourth step is to make the outer diameter of the head smaller than the diameter of the small hole and larger than the diameter of the small diameter through hole, and the head is more The depth of the column portion of the sulphur-reinforcing body panel is small, and the head screw is inserted a segment through hole and locking the female screw anchor to fix the sulfur solidified panel on the surface of the concrete structure; (e) the fifth step of filling the acid resistance adhesive into the column pit portion The head of the bow bolt is covered and the filled adhesive is evenly distributed to planarize the panel surface of the sulfur cured body panel. [Embodiment] Hereinafter, embodiments of the present invention will be described with reference to the accompanying drawings. BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a schematic view showing an example of a production line for carrying out the method for producing a sulfur-cured body panel of the present invention. In the method for producing a sulfur-cured body panel according to the present embodiment, a sulfur-containing material which is heated and melted in a state of 201102478 is molded and solidified by using a box-shaped mold having an opening, and a thin sulfur-cured panel is produced, as shown in FIG. The production line includes a preheating step of preheating the mold frame, a grouting step of filling the molten sulfur-containing material into the heated mold frame, and cooling the mold filled with the sulfur-containing material. The step of removing the panel from the mold frame, and the step of correcting the removed panel.円 The preheating step heats the mold frame to a temperature around the melting point of sulfur (丨i 9 °c). In Fig. 1, the mold frame 2 is inserted into the interior of the mold frame heater j for heating. Here, the mold frame 2 is made of a metal such as iron, and as shown in Figs. 2 to 5, it is formed into a flat box shape having an opening on the upper surface. 2 is a plan view of the mold frame 2. As shown in FIG. 2, the mold frame 2 includes, for example, a rectangular bottom plate 3 and a frame assembly 4 disposed around the bottom plate 3 and having a specific height, and the bottom plate 3 and the four frame assemblies 4 are formed to have openings on the upper surface and opposite to A flat box shape with a small bottom area and a small height. In the present embodiment, the size of the mold frame 2 is, for example, 400 mm (vertical) x 800 mm (horizontal) x 12 mm (height). However, the size of the mold frame 2 can be appropriately set in accordance with the pattern of the sulfur-cured body panel. For example, the height dimension (thickness of the sulfur-cured body panel) can be as large as about 40 to 50 mm. In addition, in FIG. 2, the component symbol 5 is a pin which is formed in the flat portion of the sulfur-cured body panel of the product, that is, a through-hole extending in the thickness direction of the sulfur-solidified panel, and is provided in the bottom plate 3 ( The hole is formed through the hole 201102478, and the component symbol 6 is used for transporting the mold frame 2. Fig. 3 is a bottom view of the mold frame 2. As shown in Fig. 3, the inner surface of the bottom pole 3 is tied with & On the other hand, the cross-section RL_bottom frame assembly 7 and the four parts of the inner surface of the bottom plate 3 are provided with the frame 2 placed on a work table to be described later, and are engaged with the convex portion or the like provided on the upper surface of the work table to prevent The position of the frame 2 is offset. In addition, FIG. 4 is a front view of the mold frame 2, and FIG. 5 is a side view of the mold frame 2. As shown in FIG. 2 and FIG. 3, the frame member 4 is split. There are two open metal parts 9 which are filled with air, and the open π metal parts 9 are used to take out the town plate formed in the mold frame 2 from the mold frame 2, and pressurize the air to the town. The boundary portion between the plate and the mold frame 2 is connected to the surface of the bottom plate 3 to be opposite to the frame assembly 3 as shown in the figure: :6:: The air injection hole iQ of the boundary portion is peeled off from the opening gold ^ / through the air injection hole 1G to peel the plated body formed by the pressurized air injection molding frame 2 ° die 2 As shown in Fig. 6A, the mold portion is connected to the surface of the bottom plate 3, and the inner peripheral edge portion of the inner side of the bottom plate 3 is an inwardly inclined surface. Thereby, the mold frame portion forms a flat surface side (panel surface) of (4). In the preheating step, the mold frame 2 constructed as described above is made of iron: formed into a box-shaped mold box heater placed vertically, and made of metal. The upper opening portion 11 is inserted into the inside, and the grip portion 13 of the upper cover 12 shown in Fig. 8 is used to open the upper cover 12 to the α portion U, and the upper cover 12 is covered at the opening portion of the 102102478 as shown in Fig. 9 The surrounding bolts 14 are tightened to fix the upper cover i2, and then the frame heater i is operated to heat the mold frame 2 to a temperature around the melting point (119C) of the sulfur. After the warm-up is completed, in Fig. 9, the thread check 14 is loosened to remove the upper cover 12, and the handle 6 is held to take the _ 2 inserted into the frame heating H 1 and then (4) to the subsequent step. In the example shown in Fig. 7 to ®1, the source of the mold frame heater 1 is an injection pipe using a Wei's symbol 15 to display a (four) gas, and the component symbol 16 is a discharge pipe for displaying a vapor, and the component symbol 17 is a system. A pressure gauge for measuring the injection steam is shown. Further, in Fig. 1, the symbol numbers 18 and 19 indicate the distribution f for supplying steam from the cooking chamber (not shown) to the plurality of frame heaters 1. Then, as shown in FIG. 7 to FIG. 9, the mold frame 2 is inserted into the frame of the human body, and the human body is injected into the body for, for example, 1.5 to 2 atmospheres for 4 to 5 minutes, and the frame 2 is added to the frame. ~130 °C or so. ... . However, the heat source of the formwork heater 1 is not limited to the vapor 'heatable heater. In addition, it is also possible to use a heat source other than steam and an electric heater. 0 Next, the step is to heat up to a temperature in the set temperature range above the sulfur melting point. In the mold frame 2 heated in the step, in Fig. i, the mold frame 2 after the preheating is completed from the mold frame heater 1 is placed on the upper surface of the work table 2〇 to melt the molten sulfur. The materials are filled into the mold frame 2. Specifically, as shown in FIG. 10, the mold frame 2 is horizontally placed on the 12 201102478 2 ' 'to make the container 21 β contain the molten state of the sulfur content = 22 in the mold 2 The ground diffusion method is used to fill the fi1 stone containing sulfur stone 22 (22a). At this time, the stone ^0 vibrates - while vibrating the mold frame 2 - while filling the molten state containing Ϊ = shell material 22. Thus, the inside of the filled sulfur-containing yellow material 22 is less likely to form voids. Further, before the sulfur-containing material 22 is filled in the human mold 2, the release material is first applied to the inner surface of the mold 2. In this way, the panel member formed in the mold frame 2 can be easily taken out from the mold frame 2, and preferably, the opening metal member 9 and the air injection hole 10 for injecting pressurized air are previously made. The air is well circulated. Next, the sulfur-containing material 22 will be described. The sulfur-containing continuation material is called "sulfur curable body", which is a property of sulfur which is solid at normal temperature and melts at about 119 to 159 ° C, and is heated within a set temperature range of 119 C or more. The molten sulphur yellow is mixed with lime, sand, gravel, etc., and is kept at about U9 to 159 ° C while being mixed and then cooled and hardened. Alternatively, it is referred to as a "modified sulfur-cured body", which is similarly produced by mixing sulfur which is heated in a molten state with a sulfur-modified agent for denaturation of the molten sulfur, and produces modified sulfur. The sulphur is mixed with sand, gravel, lime, etc., and is heated and hardened by heating as in the above. That is, the sulfur-containing material contains the sulfur-cured body and the modified sulfur-cured body. In addition, in this specification, even if it is simply described as "sulfur-cured body", the description also includes "modified sulfur curing 13 201102478
針對該改質硫續固化體再更詳細地說明。改質硫續 固化體係以硫磺、硫磺改質劑、微細粉末、骨架材料作 為原料所製造。首先，將溶融後的硫磺與硫磺改質劑混 合來製造改質硫磺。硫磺為通常的單體硫磺，舉例有天 然産或利用石油或天然氣體的脫硫所產生之硫磺。硫石黃 改質劑係藉由例如將硫磺聚合來改質。硫磺改質劑只要 能聚合硫確來獲得化合物，可為例如碳數4〜20的稀煙 系碳氫或二烯烴系碳氫，具體而言有檸檬烯、一烯蒎等 環狀烯烴系碳氫、乙烯、乙烯曱苯、曱基苯乙烯等芳香 族碳氫、二環戊二烯(DCPD)及其低聚合物、環戊二婦、 四氫茚（THI)、乙烯環己稀、乙稀原冰片烯、亞乙基原 冰片烤、環辛一烯荨二稀系碳氫等之1種或2種以上的 混合物。硫磺與硫磺改質劑的混合係在硫磺為溶融狀態 (亦即119〜159°C)下，較佳為130〜150°C的溫度下進行。 該改質硫磺雖可藉由將硫磺與硫磺改質劑溶融混 合來獲得，但此時硫磺改質劑的使用比例相對於硫磺與 硫磺改質劑的總量’通常為0.1〜30質量％，較佳為 1.0〜20質量°/。。所獲得之改質硫石黃係與加溫至特定溫度 (例如150°C)的微細粉末混合而作為改質硫磺中間資 材。微細粉末可為選自石灰，>5夕砂，二氧化；ε夕煙塵，玻 璃粉末，燃料燒燼灰，電氣集塵灰及貝殼粉碎物中的j 種或2種以上。 上述方式所獲得的改質硫磺中間資材係與在被保 201102478 持於可保持溶融狀態的溫度(例如13 0〜14 0 °C)之狀態下 與加溫至例如130〜140。(：左右之骨架材料混合。該骨架 材料只要是可作為骨架材料來加以使用便無特別限 定’一般來說可使用利用在混凝土之骨架材料。此種骨 架材料可為1種或2種以上選自於例如天然石頭、砂、 礫、矽砂、鐵鋼熔渣、鐵鎳合金熔渣、銅熔渣、金屬製 造時所產生之副產物、溶融熔渣類、貝殼及該等混合物 等所組成之群。藉由將該改質硫磺中間資材與骨架材料 利用例如混練裝置來加以混合以製造改質硫磺資材，並 將其冷卻固化來製造改質硫磺固化體。此種改質硫磺固 化體例如可使用曰本專利第4007997號公報所記載之 改質硫續固化體製造系統來製造。 本實施形態中係以將該硫磺固化體或該改質硫磺 固化體加熱至設定溫度範圍（例如l30〜150°c左右）内而 成為溶融狀態者’來作為溶融狀態的含硫磺資材22而 加以使用。例如，圖1中，以設備23作為曰本專利第 4007997號公報所記載之改質硫磺固化體製造系統，將 利用該設備23所製造之改質硫柄化體加熱而成為溶 融狀態的含硫磺資材22,並將該溶融狀態的含硫磺資 材22以例如第1〜第4昆合器24來一邊加熱遇合一邊 分裝至容益21内，而如圖1〇所示般，可從容器Η使 溶融狀態的含硫磺資材22在模框2内全面地擴散來充 填。 回到灌毁步驟的說明，灌漿步驟的下一個步驟，如 15 201102478 圖11所示，係於依上述方式灌漿後的第1層含硫磺資 材22a上設置補強用網體25。該補強用網體25係用以 補強形成為薄板狀之硫磺固化體鑲板的強度，故可利用 例如強化繊維網。具體而言，使用將扁平碳繊維十字狀 地設置並將其交叉點黏著之網狀碳織維即可。 如圖12所示’灌漿步驟的再下一個步驟係如上所 述地於第1層含硫磺資材22a上設置補強用網體25後， 在該補強用網體25上再灌漿第2層含硫磺資材22b。 亦即，補強用網體25係設置於模框2内所充填之溶融 狀態的含硫績資材22整體的厚度内，將補強用網體25 挾置其中而於上層與下層的二層（22a、22b)之間充填有 含硫磺資材22 ^藉此，會成為第i層（下層）的含硫磺資 材22a、於其上之補強用網體25，以及再於其上之第2 層（上層）含硫磺資材22b的3層構造，以提高硫磺固化 體鑲板的強度。此外，模框2周圍的框組件4上之突出 的多餘含硫射材22賴由鏝刀等來去除而加以平坦 化。第2層（上層）亦與第丨層（下層）同樣地，可使作業 台20振動來—邊振動模框2 —邊充填溶融狀態的含硫 磺資材22。 此外，此處雖係將溶融狀態的含補㈣22分二 次充填人模框2内，但並未限觀種 25放置在模框2内，而一次將溶融狀態 入二：：：材22充填入模框2内’抑或將溶融狀態的 m貧22充填入模框2内後馬上將補強用網體 16 201102478 埋入於含；^磺資材22。再者，所製造之硫磺固化體鑲 板的強度本身即已非常足夠時亦可省略補強用網體25。 接下來，徐冷步驟係藉由使充填(灌漿)有含硫磺資 材22的模框2在空氣中自然冷卻來進行徐冷，圖丨'中， 係在作業台20上將充填有含硫磺資材22的模框2運送 至搬迗設備26的開始端位置，並在搬送設備％將模框 2從開始端位置移送至終止端位置的期間使模框2徐 冷亦即如圖13所示，將充填有含硫績資材22的模 框2載置在作為搬送設備％的滚輪輸送帶，並在空氣 中一，^卻—邊移送至終止端位置。具體而言，充填有 含硫石黃資材22的模框2會在3〇分鐘左右從開始端位置 移動至終止端位置，並在該移動期間冷卻至35〜50°C。 接下來，脫模步驟係從自然冷卻後的模框2將該模 框2内所成型之鑲板狀物取出，在圖1中，係將移送至 終止端位置的模框2反轉以使其内面朝上而載置於搬 送设備26之終止端位置附近所設置的脫模作業台27， 亚於該脫模作業台27上從模框2將鑲板狀物取出。此 時，在模框2内所成型之鑲板狀物與模框2的交界部分 注入加壓空氣，以從模框2使鑲板狀物剝離並取出。亦 即，如圖14所示，將自然冷卻後的模框2以框組件4 側為朝下之方式載置於脫模作業台27上，並將空氣管 28連接於開口金屬件9並注入加壓空氣。如圖6A、圖 6B所示，開口金屬件9係在模框2之底板3的表面處 與框組件4和底板3的交界部分所形成之空氣注入孔 17 201102478 10相連通，故藉由從空氣管28注入加壓空氣，如圖15 所示，則可使模框2内所成型之鑲板狀物29剝離並從 該模框2取出。 本實施形態中’如圖6A、圖6B所示，空氣注入孔 10係與框組件4之内側周緣部(連接於底板3表面之朝 内傾斜面）相連通，因此加壓空氣會被吹附在鑲板狀物 29之幵>成為倒角狀的周緣部。藉此，可容易將鑲板狀 物29從模框2卸下。此外，空氣注入孔1〇不限於圖 6A、圖6B所示者，而亦可於底板3的内面側處設置於 該底板3的垂直方向。又，並非一定要注入加壓空氣。 例如，亦可以木槌等敲打模框2的内面側來將鑲板狀物 29從該模框2取出。 依上述方式從模框2將鑲板狀物29取出後，如圖 1所示’將取出之鑲板狀物29載置於修邊作業台3〇上， 並利用研磨機等來進行鑲板狀物29周圍的修邊。 接下來，橋正步驟係使從模桓2取出之镶板狀物 29在空氣中冷卻並矯正，圖丨中係將從模框2取出之 鑲板狀物29移送(產品移送)至矯正場所31，並載置在 該矯正場所31的上面來進行鑲板狀物29的矯正。此 時，如圖16所示，將從模框2取出之鑲板 片地平放在(平坦地併排)加溫後的靖正面，來二 邊保溫該鑲板狀物29 —邊進行矯正(加熱二次矯正）。矯 正床32係將下板33及上板34利用於該等之間以特定 間IW置之I型材35來加以連結而形成為托板狀，並 201102478 藉由將蒸氣注入下板33與上板34之間所形成的空間， 來將上板34(亦即矯正床32的上面）加溫至例如 20〜40°C左右。 如此地，能避免將鑲板狀物29放置在冰冷的平 面’而藉由將鑲板狀物29 —片片地平放在加溫至 20〜40°C左右後的矯正床32上面約丨2〜24小時來進行矯 正，可防止鑲板狀物29產生翹曲。又，即使是從模框 2取出之鐵板狀物29產生有輕曲，藉由加溫後的橋正 床32溫度，則可矯正該翹曲。此時，較佳地係將鑲板 狀物29之周緣部形成為倒角狀侧的面朝矯正床32的上 面來載置。 以上述方式進行約12〜24小時的加熱二次橋正 後，在圖1所示之生產線中，將鑲板狀物29 一片片地 載置在檢查台36上，並利用極限量規等來測量該鐵板 狀物29成品的尺寸或翹曲的狀態，以進行鑲板狀物29 的製βσ 4双查。當製品檢查的結果出現不良品，若可進行 翹曲的修正，則將鑲板狀物29加熱並對該翹曲進行矯 正。若無法進行翹曲的修正則當作不良品而加以排除。 此處，除了利用上述矯正床32之加熱二次矯正以 外，其他的矯正步驟亦可將從模框2取出之複數個鑲板 狀物29 ’以該鑲板之面與面之間為密接之方式而縱向 地放置在端正場所31上聽自然冷卻錢正。較佳地 係將複數個鑲板狀物29在其表面與表面及内面與内面 為密接之狀態下縱向地放置。例如，如圓17所示，將 201102478 2根方桿37平行地併排在水平面，並將平板狀組件％ 於垂直方向站立在方桿37之一側的端部來構成鑲板台 座，而將尚有餘熱的鑲板狀物29從平板狀組件38依序 縱向地放置在該鑲板台座。藉此，可將鑲板狀物29在 鑲板的面與面彼此之間為密接之狀態（較佳為其表面與 表面及内面與内面為密接狀態）下自然冷卻，以對鑲板 狀物29進行矯正。藉此，即使是從模框2取出之鑲板 狀物29產生有翹曲，藉由將尚有餘熱的複數片鑲板狀 物29在其鑲板之面與面之間（較佳地表面與表面及内面 與内面）為密接之狀態下縱向地放置’則可橋正該趣 曲。此外’圖17中’元件符號39係顯示用以防止縱向 地放置在鑲板台座之複數個鑲板狀物29傾倒之傾倒防 止材料。 藉由實施以上的預熱步驟、灌漿步驟、徐冷步驟、 脫模步驟及績正步驟，則可製造圖18所示之硫績固化 體鑲板40。具體而言，可製造例如尺寸為 400mm(縱）><800mm(横）xi2mm(厚度）且重量為大約 8.5kg的硫續固化體鑲板40。此外，藉由調整模框2(框 組件4)的尺寸’可製造任意大小的硫確固化體鑲板4〇。 例如，亦可藉由增加模框2的深度(框組件4的高度）， 來使硫磺固化體鑲板40的厚度增加至4〇〜5〇mm左右。 此處，圖18中，元件符號43係顯示設置於底板3(亦即 模框2的内側底面）之銷5(參照圖2)所形成的貫穿孔。 又，圖1中，元件符號41係顯示以包裝材料來將所製 201102478 造之硫磺固化體鑲板40以例如2片丨組地包裹之包裝 紙捲台，元件符號42係顯示將上述包裝材料所包裹之 硫磺固化體鑲板40裝箱之梱包位置。 依上述方式製造之硫磺固化體鑲板可作為土 木、建设用資材而廣泛地利用。例如，可作為用於下水 道設施之耐腐食性資材來加以利用《又，可貼附在水道 設備荨既有的混凝土構造物表面’而作為用以對兮混凝 土構造物施予防蝕被覆之防姓被覆材料來加以利用。此 處，硫磺固化體鑲板40之周緣部形成為倒角狀側的面 (亦即模框2之内側底面側的面）係作為鑲板表面。 以上說明的硫磺固化體鑲板製造方法係將模框2 預先加熱至硫續融點左右的溫度’並將溶融狀態的含硫 石s貢材22充填入加熱後的模框2内，故被充填入模框 2内的含硫磺資材22不會被急速冷卻而固化，且可抑 制所製造之硫項固化體镶板40的上部或内部產生空 洞、上面凹陷或表面產生氣泡。藉此，可製造產品的成 品良好之硫續固化體鑲板。又，由於含硫續資材具有高 強度’因此可不使用鋼筋等補強材來製造鑲板，且與砂 聚製鑲板等習知的鑲板相比，可使鑲板的厚度較小並輕 量化。亦即，可製造強度及耐久性高之薄板狀鑲板。 又’在預熱步驟中，係將模框2插入至以蒸氣或電 熱加熱器作為熱源之模框加熱器1的内部來對該模框2 進行加熱’故可容易地將模框2整體加熱至硫磺融點左 右之溫度。 21 201102478 此處’在灌毁步驟中，—邊振動加熱後的模框2一 邊將溶融狀態的含硫料材22充填人該模框2内，則 可抑制所充填之含硫4資材22的内部產生空洞。、 又，軸含硫辟材本身即具有非常高的強度，但 在本贯施形態之轉步驟中，由於在模框2 _充填之 溶融狀態的含硫射材22的厚度内設置有補強用網體 25 ’故可更加提高硫石黃固化體鑲板4〇的強度(特別 壞強度）。 例如，藉由將溶融狀態的含硫磺資材22充填至模 框2内的大約—半高度位置而形成下層瓜，並於該下 層22a上設置補強用網體25，再於所設置之補強用網體 25上充填溶融狀態的含硫磺資材22而形成上層22b， 則可容㈣製造強度更加提高之硫仙化體鑲板4〇, 此外，亦可抑制所製造之硫磺固化體鑲板4〇之間的強 度不均勻。 再者，脫模步驟中’係將加壓空氣注入模框2内所 成型之鑲板狀物29與該模框2的交界部分來使鑲板狀 物29從模框2剝離，故可容易地將模框2内所成型之 鑲板狀物29從該模框2取出。 又再者，矯正步驟中，係將鑲板狀物29 一片片地 平放在加溫後的矯正床32上面，故可一邊保溫鑲板狀 物29 —邊進行矯正。藉此’可防止鎮板狀物29產生翹 曲，即使是鑲板狀物29產生有翹曲，藉由加溫後的矯 正床32溫度，則可矯正該翹曲。 22 201102478 此外’矯正步驟中，亦可將從模框2取出之複數個 鑲板狀物29在其鑲板之面與面之間（例如，鑲板表面與 表面及鑲板内面與内面）為密接之狀態下縱向地放置來 將該鑲板狀物29自然冷卻並矯正。此時，可利用鑲板 狀物29的餘熱來矯正鑲板狀物29的翹曲。此處，圖 17中係將鑲板狀物29縱向地放置（亦即垂直放置），但 例如亦可使平板狀組件38只傾斜特定的角度來構成鑲 板台座’而將鑲板狀物29斜向地放置。 又’由於模框2之底板3(亦即模框2的内侧底面） 設置有銷（貫穿孔形成部)5，故可於硫磺固化體鑲板4〇 處形成有沿其厚度方向延伸之貫穿孔43。因此，例如， 藉由以貫穿孔43用作為將固定在混凝土構造物之錨栓 插通的插通孔，並將螺帽鎖入錫检，則可將硫續固化體 鑲板40裝設在混凝土構造物表面並對該混凝土構造物 施予防姓被覆。此外，此處係於硫續固化體镶板4〇處 形成有二個貫穿孔43(參照圖18)，但貫穿孔43的個數 可任意設定’而亦可於硫磺固化體鑲板4〇形成一個貫 穿孔43。 然而’如上所述地將硫磺固化體鑲板4〇裝設於混 凝土構造物表面時，用以固定硫磺固化體鑲板4〇的螺 帽等會突出於硫磺固化體鑲板40的鑲板表面。因而有 了以下的課題。 亦即’硫續固化體鐵板40雖然其鑲板面本身的粗 度係數很低’但會因在裝設於混凝土構造物時所產生之 201102478 突出於鑲板表面的突出部而使得粗度係數變高，故可適 用的混凝土構造物會受到限制。特別是無法作為要求= 粗度係數之水道荨混凝土構造物的防银被覆材料來加 以使用。 又，即使是在無法將硫磺固化體鑲板4〇用作為混 凝土構造物之防蝕被覆材料的情況，由於從鑲板表面^ 出之部位容易附著有髒污或灰塵，因此必須定 在此，為了解決上述問題而將模框2如以下所述地 改良。 圖19A、圖19B係顯示改良後的模框200。圖19A 為改良後之模框200的俯视圖，圖19B為圖i9a之 剖面放大圖。 如圖19A、圖19B所示，改良後之模才匡200的底板 3 (亦即模框200的内側底面)係設置有階段式銷5丨來取 代銷5。由於其他的構成要素皆與模框2相同，故賦予 相同的符號而省略其說明。階段式銷51係於模框2〇〇 内所成型之鑲板狀物(硫磺固化體鑲板)處形成有沿其厚 度方向延伸之階段式貫穿孔’並包含有設置於模框2〇〇 的内側底面之大徑部51a與設置於大徑部51a的上面之 小徑部5ib。此處，大徑部51a的口徑較佳為小徑部5比 口徑的2倍以上^例如，可將大徑部5la形成為 φ32ππη(直徑）χ3〜4mm(高度）的圓柱狀，而將小徑部训 形成為(直徑）x8〜9mm(高度）的圓柱狀。此外，此 處係使階段式銷51的高度與模框200的高度（12mmMg 24 201102478 等，但不限於此’只要能在硫磺固化體鑲板形成有階段 式貫穿孔即可。但為了抑制硫磺固化體鑲板的強度降 低，大徑部51a的高度為模框200高度（亦即硫礦固化 體鑲板的厚度）的1/3以下，較佳為1/4以下。 圖20A、圖20B係顯示利用模框200，並藉由實施 上述預熱步驟、灌漿步驟、徐冷步驟、脫模步驟及矯正 步驟所製造之硫磺固化體鑲板400。如圖20A、圖20B 所示’硫確固化體鑲板400形成有沿其厚度方向延伸之 二個階段式貫穿孔430。該階段式貫穿孔430之模框200 内侧底面側的開口 口徑係較模框200上面側的開口口 徑要大。換言之，硫磺固化體鑲板400形成有階段式貫 穿孔430，該階段式貫穿孔430係包含有形成於鑲板表 面400a側而具有柱坑孔功能的柱坑部430a與和該柱坑 部430a相連通且較該柱坑部430a要小口徑之貫穿孔 430b。此外，本實施形態中，枉坑部43〇&為(|)32皿11(直 徑)χ3〜4mm(深度)之圓柱孔，小口徑貫穿孔43〇b則為 (直徑）《> 此種硫磺固化體鑲板400，例如藉由於既有的混凝 土構造物設置錨栓並利用該錨栓及螺帽，則可將硫磺固 化體鑲板400確實地固定在該混凝土構造物表面。又， 若使該螺帽的高度較柱坑部430a的深度要小，則可將 該螺帽容納於柱坑部430内，而藉由將該錯栓中從該螺 帽突出的部分裁斷並去除，則可消除從鑲板表面（例如 水道面）突出的部分。藉此，即使是各種混凝土構造物（包 25 201102478 含所要求之粗度係數較低的水道等）亦可裝設疏磺固化 體鑲板，並拓展硫磺固化體鑲板作為防蝕被覆材料的使 用範圍。 此處，針對用以將硫磺固化體鑲板400裝設於例如 作為防蝕被覆材料之水道設備等混凝土構造物的硫磺 固化體鑲板組裝方法加以說明。 圖21〜圖24係顯示硫磺固化體鑲板組裝方法的第1 實施形態。 首先，如圖21所示，利用鑽孔器等來於混凝土構 造物500表面形成特定深度的錨孔501，該錨孔501設 置有錨栓。具體而言，係於混凝土構造物500表面形成 與硫磺固化體鑲板400的階段式貫穿孔430相對應之錨 孔501 ’並於所形成之錨孔501處打入陰螺絲錨503(其 内周面形成有陰螺絲部（例如M8))，而於被打入之陰螺 絲錨503處裝設作為錨栓的棒型螺栓505(例如M8)。但 不限於上述方式，可不使用陰螺絲錨503，而是使用直 接固定於錨孔501方式的錨栓。 接下來，如圖22所示，於硫續固化體鑲板400的 鑲板内面及混凝土構造物500表面的至少其中一者塗 佈接著劑507,並使錨栓(棒型螺栓505)插通硫磺固化體 鑲板400的階段式貫穿孔430(小口徑貫穿孔430b)，以 將硫確固化體鑲板400的鑲板内面貼附在混凝土構造 物500表面。此處，接著劑507為财酸性接著劑，可利 用例如樹脂系接著劑。較佳地係使用於耐酸環氧樹脂 26 201102478 (主 =:硬化劑υ以混合比…之比例所混練有石夕砂 之接者劑。如此地藉由於耐酸環氧樹脂混人卿，則可 增加接著劑507的黏性並防止接著劑5㈣出而 工性。 接下來’如g 23所示’藉由從棒型螺检5〇5的頭 部側來將碟型螺帽鎖入，則可—邊將硫續固化體鑲 板400壓接於混凝土構造物5〇〇表面一邊固心此處， 碟型螺帽509為其外徑較硫續固化體鑲板彻的柱坑部 430a 口徑要小且較小口徑貫穿孔43肋的口徑要大而 其高度較硫磺固化體鑲板4〇〇的柱坑部43〇a深度要小 之特殊螺帽，較佳地係其外徑為螺絲口徑（此處為M8) 的2倍以上，其高度為2.5mm左右之特殊螺帽。藉由 從棒型螺栓505的頭部側來將此種碟型螺帽5〇9鎖入， 則可一邊將硫磺固化體鑲板4〇〇壓接於混凝土構造物 500表面一邊固定，並且該碟型螺帽5〇9會將硫磺固化 體鑲板400的小口徑貫穿孔43%塞住同時容納於柱坑 部430a内。 接下來’如圖24所示，將棒型螺栓505中從碟型 螺帽509突出的部分裁斷後，將上述接著劑5〇7充填入 硫石黃固化體鑲板400的柱坑部430a内，並將棒型螺栓 505的頭部側（裁切面）及碟型螺帽5〇9被覆，使接著劑 507均勻分布以使硫磺固化體鑲板4〇〇的鑲板表面平坦 化0 以上述方式將複數個硫磺固化體鑲板400裝設於 27 201102478 混凝土構造物500表面，並於相鄰硫磺固化體鑲板400 彼此之間的接合部分亦塗佈有上述接著劑507以實施 目標處理。然後，g接著劑507硬化時，則結束將硫石黃 固化體鑲板4〇〇裝設於混凝土構造物5〇〇的步驟。 上述硫磺固化體鑲板組裝方法（第丨實施形態）可將 硫磺固化體鑲板400確實地固定在既有的混凝土構造 物，且可將為了固定琉磺固化體鑲板4〇〇所使用之碟型 螺帽509容納在硫磺固化體鑲板的柱坑部43〇a内以使 鑲板表面乎坦化。藉此，可對各種混凝土構造物（包含 所要求之粗度係數較低的水道等）施予防钱被覆，並延 長該混凝土構造物的哥命。又，鑲板表面為平坦的，因 此可抑制髒污或灰塵的附著，而可不需要或大幅減少維 修保養頻率。 此處’在將碟型螺帽509從棒型螺栓505的頭部側 鎖入前或鎖入時’亦可藉由從鎮板表面側一邊按壓硫石黃 固化體鑲板400 —邊振動，來使硫續固化體鑲板4〇〇的 镶板内面與混凝土構造物500表面之間的接著劑507均 勻地擴散。 例如’亦可在將碟型嫘帽509從棒型螺栓505的頭 部側鎖入前，藉由於硫磺固化體鑲板400的鑲板表面侧 設置壓接組件（圖示省略），並從棒型螺栓505的頭部側 將特定螺帽(M8)鎖入，而以該壓接組件來將硫磺固化體 鑲板400壓接於混凝土構造物500表面以暫時固定硫項 固化體鑲板400。依上述方式則可使硫磺固化體鑲板 28 201102478 40〇的鎮板内面與混凝土構造物500表面之間的接著劑 5〇7更加均勻地擴散。此時’將該特定的螺帽及該壓接 乡且件卸下後，從棒型嫘栓505的頭部側將碟型螺帽509 鎖入以將硫磺固化體鑲板400固定在混凝土構造物500 表面。 圖25〜圖28係顯示硫磺固化體鑲板組裝方法的第2 實施形態。此外，與上述第1實施形態相同的構成要素 則賦予相同的符號而省略詳細說明。 首先’如圖2 5所示，利用鑽孔器專來於混凝土構 造物500表面形成錦孔501，並於所形成之銷孔501打 入陰螺絲錨503(其内周面形成有陰螺絲部(例如M8))。 接下來，如圖26所示’在硫磺固化體鑲板400的 鑲板内面及混凝土構造物500表面的至少其中一者塗 佈接著劑507，並使硫磺固化體鑲板400的階段式貫穿 孔430(小口徑貫穿孔430b)與陰螺絲錨503對齊，以將 硫續固化體鑲板400的鑲板内面貼附在混凝土構造物 500表面。 接下來’如圖27所示’使低頭螺栓511(例如M8) 插通硫磺固化體鑲板400的階段式貫穿孔430並鎖入於 陰螺絲錯503 ’來一邊將硫續固化體镶板4〇〇壓接於混 凝土構造物500表面一邊固疋。此處，低頭螺检511頭 部的外徑係較硫磺固化體鑲板400的;j：主坑部43〇a 口徑 要小且較小口徑貫穿孔430b的口徑要大，而其頭部的 高度係較硫罐固化體鑲板400的柱坑部4%a深度要 29 201102478 小。較佳地，低頭螺栓5ll係使用其頭部的外徑為 口徑(M8)的2倍以上(例如，φ24ιηιη) ’其頭部的高 2.5mm左右，其頭下長度為4〇mm左右者。當利用 低頭螺栓511來將硫磺固化體鑲板4〇〇壓接於混凝土 造物500表面並固定時，則低頭螺栓511的頭部會將硫 磺固化體鑲板400的小口徑貫穿孔43〇b塞住，並同= 容納於柱坑部430a内。 然後，如圖28所示，將上述接著劑507充填入硫 石灵固化體鑲板400的柱坑部430a内，並將低頭螺检511 的頭部被覆，使接著劑507均勻分布以使硫磺固化體鑲 板400的鑲板表面平坦化。 以上述方式將複數個硫磺固化體鑲板4〇〇裝設於 混凝土構造物500表面’並於相鄰硫磺固化體鑲板4〇〇 彼此之間的接合部分亦塗佈有上述接著劑507以實施 目標處理。然後，當接著劑507硬化時，則結束將硫磺 固化體鑲板400裝設於混凝土構造物500的步驟。 上述硫磺固化體鑲板的組裝方法（第2實施形態）可 將硫磺固化體鑲板400確實地固定在既有的混凝土構 造物，且可將為了固定硫磺固化體鑲板4〇〇所使用之低 頦螺栓511的頭部容納在硫磺固化體鑲板的柱坑部 430a内以使鑲板表面平坦化。藉此，與上述第1實施形 態同樣地，可對各種混凝土構造物（包含所要求之粗度 #數較低的水道等）施予防蝕被覆，並延長該混凝土構 造物的壽命。又，鑲板表面為平坦的，因此可抑制辦污 201102478 或灰塵的附著，而可不需要或大幅減少維修保養頻率。 此處，本實施形態（第2實施形態）中與上述第1實 施形態同樣地，亦可將棒型螺栓(例如M8)505裝設在被 打入於混凝土構造物500之陰螺絲錨503。此時，使棒 型螺栓505插通硫磺固化體鑲板400的階段式貫穿孔 430(小口徑貫穿孔430b)，以將硫磺固化體鑲板400的 鑲板内面貼附在混凝土構造物500表面。如此地硫磺固 化體鑲板400便會藉由棒型螺栓505而被加以支撐，因 此可容易地進行硫磺固化體鑲板400在混凝土構造物 500的貼附。此外’此情況下，將硫磺固化體鑲板4〇〇 貼附在混凝土構造物500表面後，將棒型螺检505卸 下’之後再利用低頭螺栓511來將硫磺固化體鑲板400 加以固定。 又’在將棒型螺栓505裝設於陰螺絲錨503時，與 上述第1實施形態同樣地，亦可利用該壓接組件來將硫 磺固化體鑲板400壓接於混凝土構造物5〇〇表面，以使 硫磺固化體鑲板400的鑲板内面與混凝土構造物5〇〇表 面之間的接著劑507均勻地擴散。此時，將該特定螺 帽、該壓接組件及棒型螺栓5〇5卸下後再利用低頭螺栓 511來固定硫磺固化體鑲板4〇〇。 【圖式簡單說明】 圖1係顯示用以實施本發明硫磺固化體鑲板製造 方法的生產線範例之概要圖。 31 201102478 圖2為在上述硫橫固化體鑲板的製造方法中所使 用之模框的俯視圖。 圖3為該模框之仰視圖。 圖4為該模框之前視圖。 圖5為該模框之側面圖。 圖6A為圖2之A部放大圖。 圖6B為圖2之B-B剖面放大圖。 圖7係顯示在該硫磺固化體鑲板的製造方法中所 使用之模框加熱器及其使用狀態之立體圖。 圖8係顯示該模框加熱器及其使用狀態之立體圖。 圖9係顯示該模框加熱器及其使用狀態之立體圖。 圖10係顯示將溶融狀態的含硫磺資材（第1層）充填 入該模框内的狀態之立體圖。 圖11係顯示在該充填之含硫磺資材（第1層）上設置 補強用網體的狀態之立體圖。 圖12係顯示將溶融狀態的含硫續資材（第2層）充填 於該補強用網體上的狀態之立體圖。 圖13係顯示使充填有該含硫磺資材之該模框藉由 在空氣中自然冷卻來進行徐冷的狀態之立體圖。 圖14係顯示從該自然冷卻後的該模框將成型於該 模框内之鑲板狀物剝離的狀態之立體圖。 圖15係顯示從該自然冷卻後的該模框將成型於該 模框内之鑲板狀物取出的狀態之立體圖。 圖16係顯示使從該模框所取出之鑲板狀物在續正 32 201102478 床上一邊保溫一邊靖正（加熱二次矯正）的狀態之立體 圖。 圖17係顯示將從該模框所取出之複數個鑲板狀物 以鑲板之面與面之間（例如表面與表面及内面與内面）為 密接之方式而縱向地放置來自然冷卻並矯正的狀態之 立體圖。 圖18係顯示利用本發明之硫磺固化體鑲板製造方 法所製造之硫磺固化體鑲板的立體圖。 圖19 A為改良後之模框的俯視圖。 圖19B為圖19A之C-C剖面放大圖。 圖20A為利用該改良後的模框所製造之硫磺固化 體鑲板的俯視圖。 圖20B為圖20A之D-D剖面放大圖。 圖21係用以說明硫磺固化體鑲板蜂裝方法的第1 實施形態之圖式。 圖22係用以說明硫磺固化體鑲板的組裝方法的第 1貫施形態之圖式。 圖23係用以說明硫磺固化體鑲板組裝方法的第1 實施形態之圖式。 圖24係用以說明硫磺固化體鑲板組裝方法的第1 實施形態之圖式。 圖25係用以說明硫磺固化體鑲板組裝方法的第2 實施形態之圖式。 圖26係用以說明硫磺固化體鑲板組裝方法的第2 33 201102478 實施形態之圖式。 圖27係用以說明硫磺固化體鑲板組裝方法的第2 實施形態之圖式。 圖28係用以說明硫磺固化體鑲板組裝方法的第2 實施形態之圖式。 【主要元件符號說明】 1模框加熱器 2模框 3底板 4框組件 5銷（貫穿孔形成部） 6把手 7底部框組件 8卡合部 9開口金屬件 10空氣注入孔 11開口部 12上蓋 13把持部 14螺栓 15注入管 16排出管 17壓力計 34 201102478 18、19配管 20作業台 21容器 22含硫磺資材 22a第1層含硫磺資材 22b第2層含硫磺資材 23設備 24混合器 25補強用網體 2 6搬送設備 27脫模作業台 28空氣管 29鑲板狀物 30修邊作業台 31矯正場所 32矯正床 33下板 34上板 35 I型材 36檢查台 37方桿 38平板狀組件 39傾倒防止材料 40硫磺固化體鑲板 35 201102478 41包裝紙捲台 42梱包位置 43貫穿孔 51階段式銷 51a大徑部 51b小徑部 200模框 400硫磺固化體鑲板 430階段式貫穿孔 400a镶板表面 430a柱坑部 430b貫穿孔 500混凝土構造物 501錨孔 503陰螺絲錨 505棒型螺栓 507接著劑 509碟型螺帽 511低頭螺栓 36This modified sulfur sinter solidified body will be described in more detail. The modified sulfur continuous curing system is made of sulfur, sulfur modifier, fine powder and skeleton material. First, the sulfur after the fusion is mixed with a sulfur modifier to produce a modified sulfur. Sulfur is a usual monomeric sulfur, and sulphur is naturally produced or desulfurized by using oil or natural gas. The pyrithion yellow modifier is modified by, for example, polymerizing sulfur. The sulfur modifier may be, for example, a sulfur-based hydrocarbon or a diolefin-based hydrocarbon having a carbon number of 4 to 20 as long as it can be obtained by polymerizing sulfur, and specifically, a cyclic olefin hydrocarbon such as limonene or monoene. , aromatic hydrocarbons such as ethylene, vinyl benzene, decyl styrene, dicyclopentadiene (DCPD) and its low polymers, cyclopentadienyl, tetrahydroanthracene (THI), ethylene cyclohexane, ethylene One or a mixture of two or more kinds of norbornene, ethylene borneol, and cyclooctene olefin. The mixing of the sulfur and the sulfur modifier is carried out at a temperature in which the sulfur is molten (i.e., 119 to 159 ° C), preferably 130 to 150 ° C. The modified sulfur can be obtained by melt-mixing sulfur and a sulfur modifier, but the ratio of use of the sulfur modifier is usually 0.1 to 30% by mass relative to the total amount of sulfur and sulfur modifier. It is preferably 1.0 to 20 mass% /. . The modified sulphur yellow line obtained is mixed with a fine powder heated to a specific temperature (e.g., 150 ° C) to serve as a modified sulfur intermediate material. The fine powder may be j or more than two selected from the group consisting of lime, > 5 sand, dioxide, ash, glass powder, fuel burnt ash, electric dust ash and shell crush. The modified sulfur intermediate material obtained in the above manner is heated to a temperature of, for example, 130 to 140 in a state in which it is maintained at a temperature (e.g., 13 0 to 140 ° C) which can be maintained in a molten state. (The left and right skeleton materials are mixed. The skeleton material is not particularly limited as long as it can be used as a skeleton material. Generally, a skeleton material used in concrete can be used. One or two or more kinds of the skeleton materials can be used. For example, natural stone, sand, gravel, strontium sand, iron steel slag, iron-nickel alloy slag, copper slag, by-products produced by metal production, molten slag, shells and these mixtures The modified sulfur sulfur-cured body is produced by mixing the modified sulfur intermediate material and the skeleton material by, for example, a kneading device to produce a modified sulfur material, which is cooled and solidified. It can be produced by using the modified sulfur continuous solid body production system described in Japanese Patent No. 4007997. In the present embodiment, the sulfur cured body or the modified sulfur cured body is heated to a set temperature range (for example, l30~ The sulphur-containing material 22 which is in a molten state is used in a molten state of about 150 ° C. For example, in Fig. 1, the device 23 is used as a 曰 patent. In the modified sulfur-cured body production system described in the publication No. 4007997, the sulfur-containing material 22 in a molten state is heated by the modified sulfur-handled body produced by the apparatus 23, and the sulfur-containing material 22 in the molten state is For example, the first to fourth kneading devices 24 are separately dispensed into the container 21 while being heated, and as shown in FIG. 1A, the molten sulfur-containing material 22 can be completely immersed in the mold frame 2 from the container. The ground is diffused to fill. Returning to the description of the filling step, the next step of the grouting step, as shown in Fig. 11 of 201102478, is to provide a reinforcing mesh body 25 on the first layer of sulfur-containing material 22a after grouting in the above manner. The reinforcing mesh body 25 is used to reinforce the strength of the sulfur-solidified panel formed into a thin plate shape, and for example, a reinforcing mesh can be used. Specifically, a flat carbon carbon is used in a cross shape and intersected. Adhesive mesh carbon weaving can be used. As shown in Fig. 12, the next step of the grouting step is to provide the reinforcing net 25 on the first layer of sulfur-containing material 22a as described above, in the reinforcing net. Re-grout the second layer on body 25 The sulphur material 22b. That is, the reinforcing mesh body 25 is disposed in the entire thickness of the molten sulfur-containing material 22 filled in the mold frame 2, and the reinforcing mesh body 25 is placed therein to be in the upper layer and the lower layer. The second layer (22a, 22b) is filled with a sulfur-containing material 22, whereby the sulfur-containing material 22a of the i-th layer (lower layer), the reinforcing mesh body 25 thereon, and the The two-layer (upper layer) three-layer structure of the sulfur-containing material 22b is used to increase the strength of the sulfur-cured body panel. Further, the protruding excess sulfur-containing material 22 on the frame assembly 4 around the mold frame 2 depends on a file or the like. The second layer (upper layer) can also vibrate the work table 20 in the same manner as the second layer (upper layer), while filling the molten sulfur-containing material 22 while vibrating the mold frame 2. In addition, although the supplemental (four) 22 points in the molten state are twice filled in the mold frame 2, the seed 25 is not placed in the mold frame 2, and the molten state is once filled into the second::: 22 filling In the mold frame 2, or after filling the m-lean 22 in the molten state into the mold frame 2, the reinforcing mesh body 16 201102478 is buried in the containing material; Further, the reinforcing mesh body 25 can be omitted when the strength of the manufactured sulfur-cured body panel itself is sufficiently high. Next, the cold step is performed by cooling (filling) the mold 2 containing the sulfur-containing material 22 in the air to cool, and in the figure, the work table 20 is filled with sulfur-containing materials. The mold frame 2 of 22 is transported to the start end position of the transfer device 26, and the mold frame 2 is cooled during the period in which the transfer device 2 transfers the mold frame 2 from the start end position to the end end position, that is, as shown in FIG. The mold frame 2 filled with the sulfur-containing material 22 is placed on a roller conveyor as a transporting device%, and is transported to the end position in the air. Specifically, the mold frame 2 filled with the sulfur-containing yellow material 22 is moved from the start end position to the end end position in about 3 minutes, and is cooled to 35 to 50 ° C during the movement. Next, the demolding step takes out the panel formed in the mold frame 2 from the naturally cooled mold frame 2, and in Fig. 1, the mold frame 2 transferred to the end position is reversed so that The mold release workbench 27, which is placed on the side of the end of the transfer device 26, is placed on the mold release workbench 27, and the panel is taken out from the mold frame 2. At this time, pressurized air is injected into the boundary portion between the panel formed in the mold frame 2 and the mold frame 2 to peel off and take out the panel from the mold frame 2. That is, as shown in FIG. 14, the naturally cooled mold frame 2 is placed on the demolding work table 27 with the frame assembly 4 side facing downward, and the air tube 28 is attached to the open metal member 9 and injected. Pressurized air. As shown in FIG. 6A and FIG. 6B, the opening metal member 9 is connected to the air injection hole 17 201102478 10 formed at the interface between the frame assembly 4 and the bottom plate 3 at the surface of the bottom plate 3 of the mold frame 2, so that The air tube 28 is filled with pressurized air. As shown in Fig. 15, the panel 29 formed in the mold frame 2 can be peeled off and taken out from the mold frame 2. In the present embodiment, as shown in Figs. 6A and 6B, the air injection hole 10 communicates with the inner peripheral edge portion of the frame assembly 4 (the inwardly inclined surface connected to the surface of the bottom plate 3), so that the pressurized air is blown off. The edge of the panel 29 is a chamfered peripheral portion. Thereby, the panel member 29 can be easily detached from the mold frame 2. Further, the air injection hole 1 is not limited to those shown in Figs. 6A and 6B, and may be provided in the vertical direction of the bottom plate 3 at the inner surface side of the bottom plate 3. Also, it is not necessary to inject pressurized air. For example, the panel 29 may be taken out from the mold frame 2 by hitting the inner surface side of the mold frame 2 or the like. After the panel 29 is taken out from the mold frame 2 in the above manner, as shown in Fig. 1, the removed panel 29 is placed on the trimming table 3, and the panel is polished by a grinder or the like. Trimming around the object 29. Next, the bridge step is to cool and correct the panel 29 taken out from the mold 2 in the air, and the panel 29 taken out from the mold frame 2 is transferred (product transfer) to the correction site. 31, and placed on the upper surface of the correction site 31 to correct the panel 29. At this time, as shown in FIG. 16, the panel sheets taken out from the mold frame 2 are placed flat (side-by-side) with the heated front surface, and the panel-like objects 29 are thermally insulated to be corrected (heated). Secondary correction). In the orthosis bed 32, the lower plate 33 and the upper plate 34 are connected to each other by the I-shaped material 35 placed between the specific spaces IW to form a pallet shape, and 201102478 is injected into the lower plate 33 and the upper plate by steam. The space formed between the 34s is used to warm the upper plate 34 (i.e., the upper surface of the conditioned bed 32) to, for example, about 20 to 40 °C. In this way, it is possible to avoid placing the panel 29 on the icy plane 'by placing the panel 29 on top of the orthopedic bed 32 after heating to about 20 to 40 ° C. Correction is performed for ~24 hours to prevent warpage of the panel member 29. Further, even if the iron plate 29 taken out from the mold frame 2 is slightly curved, the warpage can be corrected by the temperature of the bridged bed 32 after heating. At this time, it is preferable that the peripheral edge portion of the panel 29 is formed such that the chamfered side faces the upper surface of the orthosis bed 32. After heating the secondary bridge for about 12 to 24 hours in the above manner, in the production line shown in Fig. 1, the panel 29 is placed on the inspection table 36 piece by piece, and the limit gauge or the like is used. The size or warpage of the finished product of the iron plate 29 was measured to perform a double check of the β σ 4 of the panel 29 . If a defective product appears as a result of the inspection of the product, if the warpage is corrected, the panel 29 is heated and the warpage is corrected. If it is impossible to correct the warpage, it will be excluded as a defective product. Here, in addition to the secondary correction by heating of the above-mentioned orthodontic bed 32, other correction steps may also take a plurality of panels 29' taken out from the mold frame 2 to be in close contact with the face and the face of the panel. The method is placed longitudinally on the correct position 31 to listen to the natural cooling money. Preferably, the plurality of panels 29 are placed longitudinally in a state in which their surfaces are in close contact with the surface and the inner and inner faces. For example, as shown by the circle 17, two poles 37 of 201102478 are arranged side by side in parallel with the horizontal plane, and the flat component is placed at the end of one side of the square rod 37 in the vertical direction to form a panel pedestal. The panel 29 having residual heat is placed longitudinally from the flat assembly 38 in the panel pedestal. Thereby, the panel 29 can be naturally cooled in a state in which the surface and the surface of the panel are in close contact with each other (preferably, the surface and the surface and the inner surface and the inner surface are in close contact with each other) to face the panel. 29 for correction. Thereby, even the panel 29 taken out of the mold frame 2 is warped by placing a plurality of panels 29 having residual heat between the face and the face of the panel (preferably the surface). If it is placed in a state of close contact with the surface and the inner surface and the inner surface, it can be bridged. Further, the 'unit symbol 39' in Fig. 17 shows a pouring prevention material for preventing the plurality of panels 29 placed longitudinally on the panel pedestal from falling over. By performing the above preheating step, grouting step, cold rolling step, demolding step, and performance step, the fine solidified body panel 40 shown in Fig. 18 can be produced. Specifically, for example, a sulphur-reinforcing body panel 40 having a size of 400 mm (vertical) >< 800 mm (horizontal) xi 2 mm (thickness) and having a weight of about 8.5 kg can be produced. Further, a sulfur-cured panel 4 of any size can be manufactured by adjusting the size of the frame 2 (frame assembly 4). For example, the thickness of the sulfur-cured body panel 40 can be increased to about 4 〇 to 5 〇 mm by increasing the depth of the mold frame 2 (the height of the frame assembly 4). Here, in Fig. 18, the reference numeral 43 indicates a through hole formed by a pin 5 (see Fig. 2) provided on the bottom plate 3 (i.e., the inner bottom surface of the mold frame 2). Further, in Fig. 1, reference numeral 41 denotes a wrapper for wrapping a sulfur-cured body panel 40 made of 201102478, for example, in a package of two sheets, and a component symbol 42 showing the above-mentioned packaging material. The package position of the wrapped sulfur solidified panel 40 is packaged. The sulfur-cured body panel manufactured by the above method can be widely used as a material for construction and construction. For example, it can be used as a corrosion-resistant material for sewer facilities, and can be attached to the surface of a concrete structure of a waterway equipment and used as an anti-corrosion coating for a concrete structure. Cover materials for use. Here, the peripheral portion of the sulfur-cured body panel 40 is formed into a chamfered side surface (that is, a surface on the inner bottom surface side of the mold frame 2) as a panel surface. The method for producing a sulfur-cured body panel described above is a method in which the mold frame 2 is heated in advance to a temperature of about the sulfur melting point, and the sulfur-containing slag material 22 in the molten state is filled in the heated mold frame 2, so that The sulfur-containing material 22 filled in the mold frame 2 is not solidified by rapid cooling, and it is possible to suppress voids, depressions, or bubbles on the surface of the upper or inner portion of the sulfur-cured body panel 40 to be produced. Thereby, it is possible to manufacture a product of a good sulfur-cured panel. Moreover, since the sulfur-containing continuation material has high strength, it is possible to manufacture the panel without using reinforcing materials such as steel bars, and the thickness of the panel can be made smaller and lighter than conventional panels such as sand-concrete panels. . That is, a thin plate-like panel having high strength and durability can be manufactured. Further, in the preheating step, the mold frame 2 is inserted into the inside of the mold frame heater 1 which uses steam or an electric heater as a heat source to heat the mold frame 2, so that the mold frame 2 can be easily heated as a whole. The temperature to the point around the melting point of sulfur. 21 201102478 Here, in the filling step, the mold 2 which is heated by vibration is filled into the mold frame 2 while the molten sulfur-containing material 22 is filled, thereby suppressing the filling of the sulfur-containing 4 material 22 There is a void inside. Further, the shaft sulfur-containing material itself has a very high strength, but in the transfer step of the present embodiment, the reinforcing material is provided in the thickness of the sulfur-containing target 22 in the molten state of the mold frame 2_filled state. The mesh body 25' can further increase the strength (especially bad strength) of the sulphur yellow solidified panel. For example, the lower layer melon is formed by filling the molten sulfur-containing material 22 into the approximately half height position in the mold frame 2, and the reinforcing mesh body 25 is disposed on the lower layer 22a, and the reinforcing mesh is provided. The body 25 is filled with the sulphur-containing material 22 in a molten state to form the upper layer 22b, so that the sulphur-solidified panel 4 of which the strength is further improved can be produced, and the sulphur-cured panel of the sulphur-cured body can be suppressed. The intensity between the two is uneven. Further, in the demolding step, the pressurized air is injected into the interface portion of the panel 29 formed in the mold frame 2 and the mold frame 2 to peel the panel 29 from the mold frame 2, so that it is easy The panel 29 formed in the mold frame 2 is taken out from the mold frame 2. Further, in the correcting step, the panel 29 is placed flat on the heated orthodontic bed 32, so that the panel 29 can be heated while being corrected. Thereby, the warpage of the townboard 29 can be prevented, and even if the panel 29 is warped, the warpage can be corrected by the temperature of the heated bed 32 after heating. 22 201102478 In addition, in the 'correction step, a plurality of panels 29 taken out from the mold frame 2 may be between the face and the face of the panel (for example, the panel surface and the surface and the inner and inner faces of the panel) The panel 29 is naturally cooled and corrected in a state of close contact. At this time, the residual heat of the panel 29 can be utilized to correct the warpage of the panel 29. Here, in Fig. 17, the panel 29 is placed longitudinally (i.e., vertically), but for example, the panel assembly 38 can also be tilted at a specific angle to form the panel pedestal. Place it diagonally. Further, since the bottom plate 3 of the mold frame 2 (that is, the inner bottom surface of the mold frame 2) is provided with a pin (through hole forming portion) 5, a penetration portion extending in the thickness direction thereof can be formed at the sulfur-cured body panel 4A. Hole 43. Therefore, for example, by using the through hole 43 as an insertion hole through which the anchor bolt fixed to the concrete structure is inserted, and locking the nut into the tin inspection, the sulfur continuous solidification panel 40 can be mounted on The surface of the concrete structure is subjected to an anti-surname coating of the concrete structure. Further, here, two through holes 43 are formed in the sulphur-reinforcing body panel 4 (see FIG. 18), but the number of the through holes 43 can be arbitrarily set, and the sulphur-cured panel 4 can also be used. A through hole 43 is formed. However, when the sulfur-cured panel 4 is mounted on the surface of the concrete structure as described above, the nut or the like for fixing the sulfur-cured panel 4 protrudes from the panel surface of the sulfur-cured panel 40. . Therefore, the following problems have been made. That is, the 'sulphur-cured iron plate 40 has a very small thickness coefficient of the panel surface itself, but the thickness is caused by the protrusion of the 201102478 protruding from the surface of the panel when it is installed in the concrete structure. The coefficient becomes higher, so the applicable concrete structure is limited. In particular, it cannot be used as an anti-silver coating material for waterway concrete structures requiring a thickness coefficient. In addition, even in the case where the sulfur-cured body panel 4 cannot be used as an anti-corrosion coating material for a concrete structure, it is necessary to adhere to dirt or dust from the surface of the panel surface, and therefore it is necessary to The above problem is solved and the mold frame 2 is improved as described below. 19A and 19B show the modified mold frame 200. Fig. 19A is a plan view of the modified mold frame 200, and Fig. 19B is an enlarged cross-sectional view of Fig. i9a. As shown in Figs. 19A and 19B, the bottom plate 3 (i.e., the inner bottom surface of the mold frame 200) of the modified mold 200 is provided with a stage pin 5 to replace the pin 5. Since the other components are the same as those of the frame 2, the same reference numerals will be given thereto, and the description thereof will be omitted. The stage pin 51 is formed in a panel-shaped plate (sulfur curable body panel) formed in the mold frame 2, and has a stepped through hole ' extending in the thickness direction thereof and is provided in the mold frame 2〇〇. The large diameter portion 51a of the inner bottom surface and the small diameter portion 5ib provided on the upper surface of the large diameter portion 51a. Here, the diameter of the large-diameter portion 51a is preferably two or more times the diameter of the small-diameter portion 5. For example, the large-diameter portion 51a can be formed into a cylindrical shape of φ32ππη (diameter) χ3 to 4 mm (height), and will be small. The diameter training is formed into a cylindrical shape of (diameter) x8 to 9 mm (height). In addition, here, the height of the stage pin 51 and the height of the mold frame 200 (12 mmMg 24 201102478, etc. are not limited thereto), as long as a stepped through hole can be formed in the sulfur solidified panel, but in order to suppress sulfur The strength of the solidified panel is lowered, and the height of the large-diameter portion 51a is 1/3 or less, preferably 1/4 or less, of the height of the mold frame 200 (that is, the thickness of the sulfide-solidified panel). Fig. 20A, Fig. 20B The sulphur-cured body panel 400 manufactured by using the mold frame 200 and performing the above-described preheating step, grouting step, quenching step, demolding step and correcting step is shown in Fig. 20A and Fig. 20B. The chemical panel 400 is formed with two stepped through holes 430 extending in the thickness direction thereof. The opening diameter of the inner bottom side of the mold frame 200 of the staged through hole 430 is larger than the opening diameter of the upper surface of the mold frame 200. In other words, the sulfur-cured body panel 400 is formed with a stepped through hole 430 including a column portion 430a having a function of a column hole formed on the side of the panel surface 400a and the column portion 430a. Connected and compared to the pit portion 430a In the present embodiment, the crater portion 43 〇 & is a cylindrical hole having a (|) 32 dish 11 (diameter) χ 3 to 4 mm (depth), and the small-diameter through hole 43 〇 b is (Diameter) "> Such a sulfur-cured body panel 400, for example, by providing an anchor bolt due to an existing concrete structure and using the anchor bolt and the nut, the sulfur-cured body panel 400 can be surely fixed thereto. The surface of the concrete structure. Further, if the height of the nut is smaller than the depth of the column portion 430a, the nut can be accommodated in the column portion 430, and the bolt is removed from the nut If the protruding part is cut and removed, the part protruding from the surface of the panel (for example, the waterway surface) can be eliminated. Thus, even various concrete structures (including 25, 201102478, which have a required water channel with a low coefficient of coarseness, etc.) It is possible to install a sulphur-solidified panel and expand the range of use of the sulphur-cured panel as an anti-corrosion coating material. Here, the sulphur-cured panel 400 is installed in, for example, a waterway device as an anti-corrosion coating material. Sulfur-cured body paneling for concrete structures Fig. 21 to Fig. 24 show a first embodiment of a method for assembling a sulfur-cured body panel. First, as shown in Fig. 21, a anchor having a specific depth is formed on the surface of the concrete structure 500 by using a drill or the like. The hole 501 is provided with an anchor. Specifically, the anchor hole 501' corresponding to the stepped through hole 430 of the sulfur solidified panel 400 is formed on the surface of the concrete structure 500 and the anchor is formed. A female screw anchor 503 is inserted into the hole 501 (the inner peripheral surface thereof is formed with a female screw portion (for example, M8)), and a bar bolt 505 (for example, M8) as an anchor is installed at the inserted female screw anchor 503. . However, the anchor bolt 503 is not limited to the above, and the anchor bolt fixed to the anchor hole 501 is used instead. Next, as shown in FIG. 22, the adhesive 507 is applied to at least one of the inner surface of the panel of the sulfur-reinforcing body panel 400 and the surface of the concrete structure 500, and the anchor bolt (rod bolt 505) is inserted. The stepped through hole 430 (small diameter through hole 430b) of the sulfur solidified body panel 400 is attached to the surface of the concrete structure 500 by the inner surface of the panel of the sulfur solidified body panel 400. Here, the adhesive 507 is an acid-based adhesive, and for example, a resin-based adhesive can be used. Preferably, it is used in an acid-resistant epoxy resin 26 201102478 (main =: hardener υ mixed with a ratio of mixing ratio of shisha sand shovel. So by acid-resistant epoxy resin mixed with Increasing the viscosity of the adhesive 507 and preventing the adhesive 5 (4) from working out. Next, as shown by g 23, by locking the disc nut from the head side of the bar screw 5〇5, Alternatively, the sulphur-reinforcing body panel 400 may be crimped to the surface of the concrete structure 5 while being solidified. The disc nut 509 is a cylinder 430a having an outer diameter that is more rigid than the sulphur-hardened body panel. The special nut having a small and small diameter through hole 43 rib having a large diameter and a height smaller than that of the sulphur solidified panel 4 〇〇, preferably having an outer diameter of a screw A special nut having a height of about 2.5 mm or more of a caliber (here, M8). By locking the disc nut 5〇9 from the head side of the bar bolt 505, The sulfur-cured body panel 4 is fixed while being pressed against the surface of the concrete structure 500, and the dish nut 5〇9 will be a sulfur-cured body. The small-diameter through hole 43 of the plate 400 is plugged and accommodated in the column pit portion 430a. Next, as shown in Fig. 24, after the portion of the bar bolt 505 protruding from the disk nut 509 is cut, the above-mentioned The agent 5〇7 is filled into the column portion 430a of the pyrite-solidified body panel 400, and the head side (cut surface) of the bar bolt 505 and the disk nut 5〇9 are covered to make the adhesive 507 uniform. The distribution is such that the surface of the panel of the sulfur-cured body panel 4 is flattened. 0 A plurality of sulfur-cured panel 400 are mounted on the surface of the concrete structure 500 in the above manner, and are plated adjacent to the sulfur-cured body. The bonding portion between the 400s is also coated with the above-mentioned adhesive 507 to perform the target treatment. Then, when the g adhesive 507 is hardened, the pyrite yellow solidified panel 4 is attached to the concrete structure. The step of assembling the sulfur-cured body panel (the third embodiment) can securely fix the sulfur-cured body panel 400 to an existing concrete structure, and can be used to fix the sulfonate-cured body panel. The disc nut 509 used in the crucible is contained in sulfur Curing the inside of the column portion 43〇a of the solid body panel to make the surface of the panel rough, thereby providing a money-proof coating for various concrete structures (including water channels having a low required coarseness coefficient, etc.) Extending the life of the concrete structure. Moreover, the surface of the panel is flat, so that the adhesion of dirt or dust can be suppressed, and the maintenance frequency can be eliminated or greatly reduced. Here, the disc nut 509 is removed from the rod. When the head side of the stud bolt 505 is locked before or when locked, it is also possible to vibrate by pressing the chalcogenite solidified panel 400 from the side of the surface of the inner panel to make the sulfur-cured panel 4 The adhesive 507 between the inner surface of the panel and the surface of the concrete structure 500 is uniformly diffused. For example, before the disc-type cap 509 is locked from the head side of the bar bolt 505, a crimping assembly (not shown) is provided on the panel surface side of the sulfur-cured body panel 400, and the rod is removed from the rod. The head side of the stud bolt 505 locks a specific nut (M8), and the crimping assembly is used to crimp the sulfur-cured body panel 400 to the surface of the concrete structure 500 to temporarily fix the sulfur-cured body panel 400. In the above manner, the adhesive 5 〇 7 between the inner surface of the sulphur-cured body panel 28 201102478 40 与 and the surface of the concrete structure 500 can be more uniformly diffused. At this time, after the specific nut and the crimping member are removed, the disc nut 509 is locked from the head side of the bar type plug 505 to fix the sulfur-cured body panel 400 to the concrete structure. Object 500 surface. Fig. 25 to Fig. 28 show a second embodiment of the method for assembling a sulfur-cured body panel. The same components as those in the above-described first embodiment are denoted by the same reference numerals and will not be described in detail. First, as shown in FIG. 25, a hole 501 is formed on the surface of the concrete structure 500 by using a drill, and a female screw anchor 503 is inserted into the formed pin hole 501 (the inner peripheral surface is formed with a female screw portion). (eg M8)). Next, as shown in FIG. 26, at least one of the inner surface of the panel of the sulfur-cured body panel 400 and the surface of the concrete structure 500 is coated with the adhesive 507, and the stepped through-hole of the sulfur-cured body panel 400 is formed. A 430 (small-diameter through hole 430b) is aligned with the female screw anchor 503 to attach the inner surface of the panel of the sulfur-hardened body panel 400 to the surface of the concrete structure 500. Next, as shown in FIG. 27, the lower bolt 511 (for example, M8) is inserted into the stepped through hole 430 of the sulfur solidified panel 400 and locked into the female screw error 503' to swell the sulfur cured body panel 4 The crucible is bonded to the surface of the concrete structure 500 and solidified. Here, the outer diameter of the head of the lower head screw 511 is smaller than that of the sulfur solidified body panel 400; j: the main pit portion 43〇a has a smaller aperture and the smaller diameter through hole 430b has a larger diameter, and the head portion thereof The height is less than the depth of 4 2011a of the pit portion of the sulfur can solidified panel 400 to 29 201102478. Preferably, the head bolt 511 is formed such that the outer diameter of the head portion is twice or more (e.g., φ24ιηιη) of the diameter (M8), and the height of the head is about 2.5 mm, and the length of the head is about 4 mm. When the sulphur-cured body panel 4 is crimped to the surface of the concrete reinforced fabric 500 by the lower bolt 511, the head of the ram 511 is inserted into the small-diameter through hole 43〇b of the sulfur-cured body panel 400. Live, and the same = accommodated in the column pit 430a. Then, as shown in Fig. 28, the above-mentioned adhesive 507 is filled into the column portion 430a of the sulfur stone solidified panel 400, and the head of the lower screw test 511 is covered to uniformly distribute the adhesive 507 to make sulfur. The panel surface of the cured body panel 400 is flattened. The plurality of sulfur-cured body panels 4 are mounted on the surface of the concrete structure 500 in the above manner, and the bonding portion 507 is also applied to the joint portion between the adjacent sulfur-solidified panels 4 Implement target processing. Then, when the adhesive 507 is cured, the step of attaching the sulfur-cured body panel 400 to the concrete structure 500 is completed. The method for assembling the sulfur-cured body panel (second embodiment) can securely fix the sulfur-cured body panel 400 to an existing concrete structure, and can be used for fixing the sulfur-cured body panel 4 The head of the low-cut bolt 511 is housed in the column portion 430a of the sulfur-cured body panel to planarize the surface of the panel. As a result, in the same manner as in the first embodiment described above, it is possible to apply an anti-corrosion coating to various concrete structures (including water channels having a required low degree of roughness) and to extend the life of the concrete structure. Moreover, the surface of the panel is flat, so that the contamination of the 201102478 or the dust can be suppressed, and the maintenance frequency can be eliminated or drastically reduced. In the present embodiment (second embodiment), a bar bolt (for example, M8) 505 may be attached to the female screw anchor 503 that is driven into the concrete structure 500, as in the first embodiment. At this time, the rod-shaped bolt 505 is inserted into the stepped through hole 430 (small-diameter through-hole 430b) of the sulfur-solidified panel 400 to adhere the inner surface of the panel of the sulfur-cured body panel 400 to the surface of the concrete structure 500. . Thus, the sulfur-solidified panel 400 is supported by the rod-shaped bolts 505, so that the attachment of the sulfur-solidified panel 400 to the concrete structure 500 can be easily performed. Further, in this case, after the sulfur-cured body panel 4 is attached to the surface of the concrete structure 500, the rod-type screw inspection 505 is removed, and then the sulfur-solidified panel 400 is fixed by the lower bolt 511. . Further, when the rod-shaped bolt 505 is attached to the female screw anchor 503, the sulfur-cured body panel 400 can be pressure-bonded to the concrete structure by the pressure-bonding unit as in the first embodiment. The surface is such that the adhesive 507 between the inner surface of the panel of the sulfur-cured body panel 400 and the surface of the concrete structure 5 is uniformly diffused. At this time, the specific nut, the crimping unit, and the bar bolt 5〇5 are removed, and the sulphur-cured panel 4 is fixed by the stud bolt 511. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view showing an example of a production line for carrying out the method for producing a sulfur-cured body panel of the present invention. 31 201102478 Fig. 2 is a plan view of a mold frame used in the method for producing a sulfur cross-solidified panel. Figure 3 is a bottom plan view of the mold frame. Figure 4 is a front view of the mold frame. Figure 5 is a side view of the mold frame. Fig. 6A is an enlarged view of a portion A of Fig. 2; Figure 6B is an enlarged cross-sectional view taken along line B-B of Figure 2; Fig. 7 is a perspective view showing a mold frame heater used in the method for producing the sulfur-cured body panel and its use state. Fig. 8 is a perspective view showing the mold frame heater and its use state. Fig. 9 is a perspective view showing the mold frame heater and its use state. Fig. 10 is a perspective view showing a state in which a sulfur-containing material (layer 1) in a molten state is filled in the mold frame. Fig. 11 is a perspective view showing a state in which a reinforcing mesh body is provided on the filled sulfur-containing material (first layer). Fig. 12 is a perspective view showing a state in which a sulfur-containing continuation material (second layer) in a molten state is filled on the reinforcing mesh body. Fig. 13 is a perspective view showing a state in which the mold frame filled with the sulfur-containing material is quenched by natural cooling in the air. Fig. 14 is a perspective view showing a state in which the panel formed in the mold frame is peeled off from the naturally cooled mold frame. Fig. 15 is a perspective view showing a state in which the panel formed in the mold frame is taken out from the naturally cooled mold frame. Fig. 16 is a perspective view showing a state in which the panel member taken out from the mold frame is kept warm while being conditioned (heated secondary correction) on the bed of 32 201102478. Figure 17 is a view showing that a plurality of panels taken out from the mold frame are longitudinally placed in close contact with each other between the face and the face of the panel (for example, the surface and the surface and the inner face and the inner face) to be naturally cooled and corrected. A perspective view of the state. Fig. 18 is a perspective view showing a sulfur-cured body panel manufactured by the method for producing a sulfur-cured body panel of the present invention. Figure 19A is a plan view of the improved mold frame. Figure 19B is an enlarged cross-sectional view taken along line C-C of Figure 19A. Fig. 20A is a plan view of a sulfur-cured body panel manufactured by using the improved mold frame. Figure 20B is an enlarged cross-sectional view taken along line D-D of Figure 20A. Fig. 21 is a view for explaining the first embodiment of the sulfur solidified panel mounting method. Fig. 22 is a view for explaining a first embodiment of a method of assembling a sulfur-cured body panel. Fig. 23 is a view for explaining the first embodiment of the method for assembling a sulfur-cured body panel. Fig. 24 is a view for explaining the first embodiment of the method for assembling a sulfur-cured body panel. Fig. 25 is a view for explaining a second embodiment of the method for assembling a sulfur-cured body panel. Fig. 26 is a view for explaining a second embodiment of the embodiment of the method for assembling a sulfur-cured body panel. Fig. 27 is a view for explaining a second embodiment of the method for assembling a sulfur-cured body panel. Fig. 28 is a view for explaining a second embodiment of the method for assembling a sulfur-cured body panel. [Main component symbol description] 1 mold frame heater 2 mold frame 3 bottom plate 4 frame assembly 5 pin (through hole forming portion) 6 handle 7 bottom frame assembly 8 engaging portion 9 opening metal member 10 air injection hole 11 opening portion 12 cover 13 gripping part 14 bolt 15 injection pipe 16 discharge pipe 17 pressure gauge 34 201102478 18, 19 pipe 20 work table 21 container 22 containing sulfur material 22a first layer containing sulfur material 22b second layer containing sulfur material 23 equipment 24 mixer 25 reinforcement With mesh body 2 6 conveying device 27 demoulding work table 28 air tube 29 panel 30 trimming table 31 correcting place 32 correcting bed 33 lower plate 34 upper plate 35 I profile 36 inspection table 37 square rod 38 flat assembly 39 pouring prevention material 40 sulfur solidified panel 35 201102478 41 wrapping paper winding table 42 bag position 43 through hole 51 stage pin 51a large diameter portion 51b small diameter portion 200 mold frame 400 sulfur solidified panel 430 stage through hole 400a Panel surface 430a pillar 430b through hole 500 concrete structure 501 anchor hole 503 female screw anchor 505 rod bolt 507 adhesive 509 disc nut 511 bow bolt 36