TW201032830A - Cleaner - Google Patents

Abstract

Provided is a paste cleaner comprising the following components (A) to (E): (A) a fatty acid or a salt thereof (20 to 50% by weight); (B) a cationic polymer (0.02 to 0.2% by weight); (C) a nonionic polymer selected from hydroxypropyl guar gum, polyvinylpyrrolidone, and polyethylene glycol (0.02 to 0.2% by weight); (D) a polyhydric alcohol having three or more hydroxy groups in each molecule (3 to 30% by weight); and (E) water.

Description

201032830 VI. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to a paste-like detergent. [Previous technique] A fatty acid soap-based detergent is known to have a liquid form by increasing the degree of neutralization by blending a fatty acid having a short chain length, and conversely, a fatty acid having a long chain length When the degree of neutralization is lowered, it becomes a paste form.

The paste-like detergent as described above has a foamy and dense foam feeling as compared with a liquid detergent, and has good rinsing properties and low irritation to the skin. Therefore, in many cases, a paste-like detergent is used as a face wash material. Regarding the creamy detergent, the foaming performance, the rinsing performance, and the improvement of the moisturizing property of the skin after washing have been carried out (Patent Document No. 2, Patent Document 2). In the case of the above-mentioned fatty acid soap-based paste-like detergent, the change in hardness with respect to temperature change is remarkable, and the cationic polymer compound is reviewed (Patent Document 3). However, such a paste-like detergent is difficult to disintegrate and has a poor ductility even when it is used normally because the liquid property of the detergent is hard. Therefore, the creamy detergent is not suitable for use as a whole body detergent. If specified, many users use items such as towels in :=. The paste-like detergent is grasped on the hair: with: because the liquid property is hard and the ductility is poor, the detergent-stopping position cannot be uniformly spread. Therefore, the contact area of the paste-like detergent and water becomes small, and the solubility in water becomes slow, and it is expected that the problem is changed. [Patent Document 1] [Patent Document 1] Japanese Laid-Open Patent Publication No. 2005-23069 [Patent Document 2] Japanese Patent Laid-Open Publication No. Hei No. Hei No. Hei. SUMMARY OF THE INVENTION [Means for Solving the Problem] The present invention provides f K-washed sodium containing the following components (A) to (E): (A) fatty acid or a salt thereof 20 to 50% by weight; (B) cationicity Polymer 〇〇2~〇2% by weight; (C) Nonionic polymer selected from hydroxypropyl guar gum, polyethylene-based 0-bit sputum and polyethylene glycol 〇2~〇2% by weight; (D) 3 to 30% by weight of a polyol having three or more hydroxyl groups in the molecule; (E) water. (Effect of the Invention) The detergent of the present invention has high affinity with skin and towel, and is viscous, and is a paste-like detergent which is easily spread evenly on a towel. Further, in the case where the detergent of the present invention is used in the application of a towel, it is easy to appear a large amount of foam in the towel, and has a characteristic that the foam is fine and easily stretched. [Embodiment] The invention relates to a creamy detergent which has high affinity with skin and towel, is viscous, and is easy to spread on the skin and the towel, and is rich in foaming property, and has a foam of 099104683 4 201032830 A detergent that is fine and easy to stretch. The present inventors have found that by combining a cationic polymer and a specific nonionic polymer in a fatty acid salt, a paste can be obtained, and the skin and the towel are rich in affinity, which is easy to uniformly spread, and is rich in A detergent that is foaming, fine, and easy to stretch. The fatty acid constituting the fatty acid of the component (A) used in the present invention or a salt thereof is preferably a carbon number of 8 to 24. Further, a fatty acid having 15 or less carbon atoms and a fatty acid having 16 or more carbon atoms are preferred. The weight ratio of the fatty acid having a carbon number of 15 or less to the fatty acid having a carbon number of 16 or more is preferably 75:25 to 2G: 8G, and is 60:4 to 25.75, especially 40:60 to 30:70, The viewpoint that the detergent is easy to foam: it is better, and the rinsing property is also good. #为奴数15以下的脂肪 fatty acids, preferably lauric acid, nutmeg acid. Further, as the fatty acid having a slave number of 16 or more, palmitic acid, stearic acid, iso-hardy, oleic acid, arachidic acid, camellic acid, tar tar mail (6), and the like can be cited. The composition of fatty acid is preferably 10~25 reset 〇/0 in the total fatty acid, and 12~23% by weight, especially in the range of i5~2i. (4) Hardness and washing It is better in terms of skin feel after cleansing. :, fatty acids of bismuth, with a carbon number of 2〇~24 direct bond saturated fat ^ is good' can be cited as arachidic acid (carbon number 2〇), camellic acid (broken number 22), 掬焦099104683 201032830 oleic acid (carbon The number 24) and the like, more preferably, arachidic acid and behenic acid are preferred. The counter ion constituting the fatty acid salt may, for example, be a metalloid such as sodium or potassium; a basic amino acid; an organic amine or the like. Among them, an alkali metal salt is preferred, and a potassium salt is preferred. Further, the degree of neutralization of the fatty acid is preferably 60 to 100%, and more preferably 65 to 95%, particularly 70 to 90%, from the viewpoints of foaming property and stability over time. The fatty acid and the salt thereof may be used singly or in combination of two or more kinds, and in the entire composition, the fatty acid type is contained in an amount of 20 to 50% by weight, preferably 20 to 45% by weight, more preferably 20 to 40% by weight. If it is within this range, it is preferable from the viewpoint of the hardness and ease of extension of the paste detergent. Examples of the cationic polymer of the component (B) used in the present invention include cationized cellulose, cationized starch, cationized guar gum, and cationized thorn cloud glue (^683 plus 1^80丨11〇3&811111 ), cationized locust bean gum ((^〇1^ siliquagum), cationized fenugreek gum, di-propyl dialkyl quaternary ammonium salt / acrylamide copolymer, diallyl Dialkyl quaternary salt / acrylamide / acrylic acid copolymer, etc., wherein cationized cellulose and cationized guar, diallyl dialkyl quaternary ammonium salt / acrylamide copolymerization The composition is more preferred. The diallyldialkyl quaternary ammonium salt/acrylamide copolymer is particularly preferred. Further, the copolymer of dinonyl diallyl ammonium and acrylamide is halogenated. The weight ratio of dimethyldiallyl chloride to acrylamide is 1:99~99:1, especially 5:95~95:5. As a more specific example of the cationic polymer, as two Allyl dialkyl tetra 099104683 6 201032830 grade salt (DMDAAC) / acrylamide (AM) copolymer, can be listed as Marco Polo 550 (weight Average molecular weight: 160,000, cationic charge density: 4.22 meq/g, DMDAAC: AM = 50: 50), Marco P. 2200 (weight average molecular weight: 90,000 'cation charge density: 4.22 meq/g, DMDAAC: AM=50 : 50), Marco P (S weight average molecular weight: 260,000, cationic charge density: 4.22 meq / g 'DMDAAC: AM = 50: 50) [The above is propylene amine and diallyl dimethyl by NALCO company a copolymer of a quaternary ammonium salt], POIZ ❹ C-60H (weight average molecular weight: 600,000, cationic charge density: 1.07 to 1.78 meq/g), Caticelo M-80 (weight average molecular weight: 800,000, cationic charge density: 0.93~ 1.21 meq/g), POIZ C-150L (weight average molecular weight: 1.5 million, cationic charge density: 0.71 to 1.07 meq/g) [The above is a cationized cellulose made by Kao Corporation (chlorinated 0-[2-hydroxy- 3-(trimethylammonium)propyl]hydroxyethylcellulose)], Jaguar C17 (weight average molecular weight: 300,000, cationic charge density: 1.07~1.50 meq/g), Jaguar C14 (weight average of ❹ Amount: 300,000, cationic charge density: 0.93~1.21meq/g) [The above is a cationized guar made by Rhodia (Gasified guar hydroxypropyltrimonium)], etc. 'In addition, the cationized charge density of cationized cellulose and chlorinated guar by propyl three is assumed to be 100% cationic in the polymer. And determined by the nitrogen content ratio (weight 0 / 〇) in the polymer. In particular, the weight average molecular weight of the component (B) is preferably from 90,000 to 10,000,000 from the viewpoint of the viscosity of the detergent produced by the component (C) described later, and is from 099104683 7 201032830 to 100,000 to 1.5 million. More preferably, it is 160,000 to 800,000. Further, from the viewpoint of the foam, the cationized charge of the component (B) is preferably 0.5 to 4.5 meq/g, and is 〇7 to 4.4 meq/g, more preferably 3. 〇 to 4 3 Melon is better. The component (B) contains 〇〇2 to 〇2% by weight, preferably 0.05, from the viewpoint of improving the foaming property and foaming property of the component (A) and from the viewpoint of the feeling of use. ~0.17% by weight, more preferably 〇·〇6~〇12重量〇/^ The component (C) used in the present invention is composed of hydroxypropyl guar, polyvinylpyrrolidone and polyethylene glycol. A nonionic polymer selected from the group. Among them, hydroxypropyl guar is more preferred. These weight average molecular weights are preferably from 40,000 to 3,000,000 from the viewpoint of the viscosity and foaming property of the detergent, and are from 30,000 to 2.75 million, and more preferably from 2 million to 2.5 million. good. More specific examples of the nonionic polymer include Alkox series (polyethylene glycol manufactured by Mingcheng Chemical Industry Co., Ltd.): Alk〇x E3〇 (weight average molecular weight 300,000 to 500,000), and Alkox E-45 (weight) An average molecular weight of 600,000 to 800,000), AlkoxE-60 (weight average molecular weight of 10,000 to 1.2 million), AlkoxE-75 (weight average molecular weight of 2 million to 2.5 million), and Alkox E-100 (weight average molecular weight of 2.5 million 〜 3 million); Luviskol series (polystyrene based on BASF Japan): Luviskol K30 (weight average molecular weight 40,000 to 60,000), Luviskol Κ90 (weight average molecular weight 12 million); Jaguar HP series (Hydroxypropyl guar gum manufactured by Rhodia Co., Ltd.), jaguarHP8, HP105, HP-120 (both weight average molecular weight of 220,000). 099104683 8 201032830 The component (c) contains G.G2 to G.2 4 4%', preferably (10) 5 to Q17% by weight, more preferably 0.06-%, in terms of softness and ductility of the foam. 0.12% by weight. The detergent of the present invention is a combination of the cationic polymer of the component (B) and the component (the miscellaneous dough of Q), which is not visible to the money. For example, the present invention The detergent has a good degree of dissolution for the skin and towels, has a pure 4, and is easy to spread on the skin and towel, and is easy to expand. The conventional paste-like detergent 'because of the viscosity of the agent It is a problem of poor compatibility with wet hands and towels, and it is easy to fall off (it is easy to fall by a towel or the like with a wrong action). However, the creamy detergent of the present invention is not intended to fuse skin and towels. Moreover, when the hand and the towel are stretched on the skin, 'because of the stickiness, it can be smoothly stretched like a brush. The result 'can uniformly and beautifully extend the detergent. Therefore, the thin and extended detergent can be Increasing the contact area with water, and also mentioning the dispersibility of water (dissolving ❹!·生) (5) From this point of view, the weight ratio of the components (8) to (c) is preferably 5 1 1.5. It is better to use 4:1~1:4, and it is better to use 2:1~1:2. In the case of the cationic polymer of the component (9) alone in the detergent, the cationic polymer is incremented in n steps, the beads are only hard and fine, and the beads produced by using the towel cannot be sufficiently foamed to overflow. To the extent of the towel. Therefore, the detergent is not suitable for washing the whole body. In the case of detergent +, alone with the component (c) face (tetra), if 099104683 9 201032830 further increase the nonionic polymer The foams generated at the beginning are large, so the foam generated by using the towel can be sufficiently foamed to overflow from the towel. However, the generated foam is very difficult to maintain, and the foam disappears on the way to wash the whole body. The action of the cationic polymer as the component (B) on the soap film is believed to enhance the soap film by interacting with the negative charge portion of the hydrophobic molecule toward the air side of the soap molecule via the cationic moiety of the polymer. The foam does not disappear and is fine and maintained. On the other hand, the effect of the nonionic polymer as the component (C) on the soap film is considered to be It has a water-repellent part, so it affects the gas-liquid interface, so that the soap film is inherently less stable. When these two kinds of polymers are combined in a specific ratio, the foam can be made dense, and the towel is more The characteristic that the overflow is more likely to foam, and it is considered that the foam generated in the initial stage is soft and large via the nonionic polymer of the component (C), and the effect of the membrane is stabilized by the (B) cationic polymer. With the washing, the beads can be fine and dense. Moreover, the effect of the nonionic polymer is not only the foam is fine, but also soft and well stretched, so that it is easy to clean the whole body. As the hair type (D) The molecular towel 3 can be used as a base alcohol, such as glycerin, sorbitol, mannitol, erythritol, xylitol, maltol, trehalose, sucrose, polyglycerin, etc. More preferably, glycerin or sorbitol is preferred. These polyols can be used! The above-mentioned composition contains the residual weight%, preferably 5 to 28% by weight, and is preferably in terms of the hardness of the creamy detergent and the ease of stretching of 099104683 201032830 and the skin feeling after washing. The detergent of the present invention may further contain a diol or a diol. Specific examples thereof include ethylene glycol, propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, isoprene glycol, and polyethylene glycol (having an average molecular weight of 2 Å or less). Polypropylene glycol (having an average molecular weight of 1,500 or less), diethylene glycol monoethyl ether or the like. Further, dipropylene glycol or diethylene glycol monoethyl ether is preferred. These diols or glycol ethers may be used alone or in combination with 3 to 30% by weight and more preferably 5 to 25% by weight in the total composition ,, and the solubility of the fatty acid during foaming and production. In terms of aspects, it is better. The detergent of the present invention may further contain a component used in a usual detergent, such as a surfactant other than a fatty acid salt, a moisturizing agent, an oily component, a bactericide, an anti-inflammatory agent, a preservative, a chimeric agent, a tackifier, and a salt. , pearlescent agents, scouring agents, perfumes, cold sensitizers, pigments, UV absorbers, antioxidants, plant extracts, and the like.洗 The detergent of the present invention may further contain (E) water and may be produced by mixing and mixing the components. Water preferably contains 30 to 50% by weight of the total composition. The detergent of the present invention is in the form of a paste 'specifically, it is 3 (the viscosity in TC is '10~l〇〇〇〇dPa · s. From the viewpoint of conformality, it is 100 to 9 〇〇) 〇dpa · 8 is preferred, and from the viewpoint of ease of stretching, it is more preferably 200 to 8000 dPa · s. The paste-like detergent of the present invention is more suitable as a systemic detergent. [Examples] 099104683 11 201032830 [Examples 1 to 36, Comparative Examples 1 to 16] The components shown in Tables 1 to 13 were mixed by mixing the respective components, and the viscosity of the paste and the extension and spread of the paste on the towel were evaluated and measured. The foaming property, the fineness of the foam, the ease of swelling of the foam, the rinsing property, the skin feeling after washing, and the viscosity. The results are shown in Tables 1 to 13. (Evaluation method) (1) Viscosity of the creamy detergent : 1 gram of each detergent is applied to a towel (made by MARNA, ordinary nylon towel, material: nylon 100% 'size: 30cm x 105cm). The upper part is attached to the index finger and lasts for a second. Raise the index finger 3 〇 cm. At this time, the creamy detergent attached to the finger is stretched off between the finger and the towel. The length (imn) of the detergent extending at this time is determined as the evaluation of the viscosity. The stronger the viscosity, the longer the extension of the paste. (2) The extension of the paste-like detergent on the towel: length The direction is folded into a 4 fold towel (manufactured by MARNA, ordinary nylon towel, material: nylon 100%, size: 30cmxl 〇 5cm), single-end eight extrusion of each detergent 1g. The towel is folded again to make the towel another The paste is attached to one end B. Thereafter, the end B is slid toward the front side to extend the spread on the towel, and the length (mm) of the extension and expansion at this time is measured to evaluate the stretchability on the towel. The better the stretchability is. The more uniform and long extension. (3) Foaming (suspension of foam): Put 6 grams of each detergent on a towel that is folded into 4 folds (MA RN a company 099104683 12 201032830 made of ordinary nylon towels) , Material: 100% nylon, size: 3〇cmxi〇5cm) On the top, extend the detergent with a towel. Secondly, add 20 grams of hot water (about 40 ° C) to the whole towel (a total of about 40 grams) Soak the towel 50 times in the air. Foam the surface of the towel at this time. Set to a 1 liter beaker (manufactured by IWAKI, diameter 11 cm 'height 15 cm). After the beaker was shaken to fill the bubble tightly, the bubble height (cm) collected was measured using R. The calculated height and the bubble collected from the bottom area of the beaker were calculated. Volume (cm3). The obtained bubble volume was evaluated as an indicator of Q foaming. (4) Fineness of the bubble: One part of the bubble collected in the above (3) was collected into a glass slide (MATSUNAMI '76 mm x 26 mm)' The cover was covered with a cover glass (MATSUNAMI, 18mm x l8mm). Thereafter, the foam was observed using a digital microscope (manufactured by KEYENCE, νΗχ magnification, 450 times, field of view, 680×480 μm), and the total bubble diameter in the field of view was measured, and the average value was calculated ((4). This value was used as an indicator of the fineness of the bubble. Evaluation (5) Easiness of blistering, rinsing, and skin feeling after washing: 3 professional δ grading officers use each detergent to perform the following whole body washing test, and the functional evaluation bubble is easy to extend. Degree, rinsing, and skin feeling after washing, and judged according to the following criteria for evaluation of the sensory evaluation. (Whole body washing test) Place 7 g of each washing/contenting agent in a towel that is folded into 4 folds (marna The company made a nylon towel 'material · · nylon 1〇〇%, size: 30cmxl05cm) 099104683 13 201032830 On the towel to extend the detergent extension. Secondly, the towel is added twice 20 grams of hot water (about 4 〇 °C) (a total of about 40 grams). The towel is blistered 5 times in a way that is entrained in air. After that, the whole body is washed, and the relaxation of the bubble during washing is evaluated, rinseability, and washing. After the skin feels. (B can § flat assessment The three professional reviewers rated each item as 5: very good, 4: good, 3: normal, 2: poor, and 1: very poor. Secondly, the average score of the three professional reviewers was calculated. Score, and the average score is regarded as an evaluation index for each item. (6) Viscosity of the paste: Each detergent was kept at 3 ° C for 24 hours after manufacture. 'Measured under the following conditions. Measuring device: B type viscosity计(Dongji Industry Co., Ltd.' Type: B8R)

Measurement temperature: 30 °C Rotator: T-D (8000 dPa · s or less) or T-E (8000 dPa · s or more) Number of rotations: 5 rpm Support frame: Spiral support frame Measurement time: 1 minute 099104683 14 201032830

[11❹G Comparative Example CN 〇〇3 *η § 〇wS § CN oo 0.009 | 0.01 | Residual 1 8 A »r> (Ν ο Η o <N Ο »〇1530 inch CN 00 ι〇§ 〇»〇§ Vo od 0.255 CO | Residual amount 1 8 8 OS 〇\ m § CO (N 卜 CO 1600 m CN 〇6 3 § 〇§ CS T-H o od 1 1-^ Residual amount 8 12 m 〇in Ό Τ-Η CO ο to 1490 CS Η CN 00 5 ίο § uS § CN od 0.850 1 la#tl 8 T—^ cn ON 00 οο α\ 〇cn 卜 inch·1510 〇6 5 § § CS r·*^ v〇 Oo 1 1 I residual amount | 8 1 in in CN VO VO fΗ p iH 卜 | 1510 | Example CNCN 〇6 3 ιη § § CM oo 0.0308 0.1542 I residual amount 8 T—Η On C\ s 卜σ\ m cn 1520 〇6 5 § iri cs od 0.037 0.148 I residual amount | 8 τ-^ inch &\ 00 00 m Os m CO 〇1520 CS 00 3 ιη § § CN oo 0.0617 | 0.1233 | I residual amount 8 CN ί -Η oi-H JT) oo Ch rn 〇wS | 1510 | inch CN 00 5 Ή 〇vd CS VO od 0.085 0.100 I residual amount | 8 rH <Ν 1-Η 1-Η v〇VO 8 σσ\ 〇 1530 | m (Ν 00 5 § 1-H ui 〇CS VO od 0.1 233 0.0617 I residual amount | 8 CN m V〇s 卜冢卜ο »〇| 1520 | CS CS 00 3 »η § Zi ο vd CS 06 0.148 0.037 I residual amount | 8 1-4 rH only cs in S CO vn 00 p cn 卜 1530 1-H 〇6 5 »〇§ ο v〇OO 0.1542 0.0308 I residual amount | 8 in in ρϋ 1-H 00 pp 卜 inch · "1540, composition (% by weight) lauric acid myristic acid brown櫊 硬 ^ 旨 山 山 山 山 山 山 山 山 山 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨 旨(B): (C) The extension of the adhesive paste on the towel to expand the foaming property i 5 -S3 ···, the extension of the bubble is easy to wash the skin after the washing, the skin feels the viscosity (dPa · s) <<<c< c < QQ CQ U ω ir < mH}SIJHI^: (N* ^々OUTVNOOSS 咏Jari?.: r SIS39SI660 201032830 [Table 2] Component (% by weight) Example 8 Comparative Example 实施 Example 9 Comparative Example 7 A Lauric acid 3.5 3.5 12 12 A Myristic acid 10.2 10.2 10 10 A Palmitic acid 7.6 7.6 6 6 A Stearic acid 8.5 8.5 6 6 Potassium hydroxide 5.5 5.5 6.5 6.5 F Diethylene glycol Monoethyl ether 5.0 5.0 5 5 F Dipropylene glycol 6.0 6.0 6 6 D Sorbitol 12.0 12.0 12 12 D Glycerin 8.6 8.6 8.6 8.6 B Copolymer of dimethyldiallyl chloride and acrylamide n 0.085 — 0.085 — C propyl guar 0.10 — 0.1 — E Residual amount of water residue Residual amount Residual amount 100 100 100 100 (B): (C) 1 : 1.2 — 1 : 1.2 — Stickiness of paste 64 6 70 7 Extension of the paste on the towel 98 28 102 30 Foaming 997 674 1016 665 Bubble fine 95 120 99 150 Bubble extension ease 5.0 1.33 5.0 1.3 Washability 4.0 4.0 3.0 3.0 Skin feeling after washing 3.7 3.7 2.7 2.7 Viscosity (dPa. s) 1010 1000 720 710 *1 : Marco P. 550 (NALCO) *2 : JaguarHP105 (Rhodia Corporation) 16 099104683 201032830 [Table 3] Ingredient (% by weight) Example 10 Comparative Example 8 A lauric acid 2.7 2.7 A myristic acid 8.2 8.2 A palmitic acid 6.1 6.1 A stearic acid 7.5 7.5 A behenic acid 6.0 6.0 potassium hydroxide 5.1 5.1 F diethylene glycol monoethyl ether 0 0 D sorbitol 12.0 — D glycerol 8.6 — B Gasified dimethyl diallyl bond and acrylamide Compound 0.085 0.085 C Hydroxypropyl guar 42 0.10 0.10 E Residual amount of water residue 合100 100 (B) : (C) 1 : 1.2 1 : 1.2 Stickiness of paste 59 3 Paste on towel Extended extension 55 20 Foaming 712 475 Foaming degree 90 115 Foam extension ease 3.7 2.0 Flushing 5.0 4.7 Skin feeling after washing 4.0 3.0 Viscosity (dPa · s) 2000 15000 *1 : Marko 550 ( NALCO) *2 : JaguarHP105 (Rhodia Corporation)

17 099104683 201032830 [Table 4] Ingredient (% by weight) Example Comparative Example 11 12 13 9 10 A lauric acid 2.7 2.7 2.7 2.7 2.7 A myristic acid 8.2 8.2 8.2 8.2 8.2 A palmitic acid 6.1 6.1 6.1 6.1 6.1 A Hard fat Acid 7.5 7.5 7.5 7.5 7.5 A behenic acid 6.0 6.0 6.0 6.0 6.0 Hydroxide needle 5.1 5.1 5.1 5.1 5.1 Diethylene glycol monoethyl ether 5.0 5.0 5.0 5.0 5.0 Dipropylene glycol 6.0 6.0 6.0 6.0 6.0 D Sorbitol 12 12 12 12 12 D Glycerin 8.6 8.6 8.6 8.6 8.6 B Copolymer of gasified dimercaptopropylammonium and acrylamide +1 0.17 0.1 0.03 0.2 — C Polyethylene glycol +3 0.03 0.1 0.17 — 0.2 E Residual water residue Residual amount Residual amount Residual amount 100 100 100 100 100 (B) : (C) 5:1 1:1 1:5 — — Viscosity of the paste 25 46 50 20 46 Extension of the paste on the towel 44 70 68 38 66 Foaming 890 800 831 594 534 Foaming fineness 97 95 95 105 90 Easiness of foaming 3.0 3.3 3.0 3.0 1.0 Washability 4.3 4.7 4.0 4.7 4.0 Skin feeling after washing 4.7 5.0 5.0 5.0 5.0 Viscosity (dPa · s) 1510 1530 1510 1510 1500 *1 : Marko 550 (NALCO ) * 3: AlkoxE-100 (Meisei Chemical Co., Ltd.) 18 099104683 201032830L Table 5]

Ingredients (% by weight) Example Comparative Example 14 15 16 9 11 A lauric acid 2.7 2.7 2.7 2.7 2.7 A myristic acid 8.2 8.2 8.2 8.2 8.2 A palmitic acid 6.1 6.1 6.1 6.1 6.1 A stearic acid 7.5 7.5 7.5 7.5 7.5 A Camellia Acid 6.0 6.0 6.0 6.0 6.0 Potassium hydroxide 5.1 5.1 5.1 5.1 5.1 Diethylene glycol monoethyl ether 5.0 5.0 5.0 5.0 5.0 Dipropylene glycol 6.0 6.0 6.0 6.0 6.0 D Sorbitol 12 12 12 12 12 D Glycerin 8.6 8.6 8.6 8.6 8.6 B Chlorine Copolymer of dimethyl diallyl ammonium and acrylamide η 0.17 0.1 0.03 0.2 — C polyvinylpyrrolidone μ 0.03 0.1 0.17 — 0.2 E Water residual residue Residual amount Residual amount Residual amount 100 100 100 100 100 (Β) : (C) 5:1 1:1 1:5 — — Viscosity of the paste 21 25 27 20 10 Extension of the paste on the towel 40 40 35 38 20 Foaming 1187 950 831 594 831 Bubble fineness 80 85 90 105 90 Bubble extension ease 3.0 5.0 3.0 3.0 2.0 Washability 4.0 5.0 5.0 4.7 5.0 Skin feeling after washing 4.7 5.0 5.0 5.0 5.0 Viscosity (dPa · s) 1500 1530 1510 1510 1500 * 1: Marko 550 (NALCO) Q *4 : Luviskol K30 (BASF CORPORATION) 099104683 19 201032830 [Table 6] Ingredient (% by weight) Example Comparative Example 17 18 19 12 13 A Alauric acid 2.7 2.7 2.7 2.7 2.7 A Myristic acid 8.2 8.2 8.2 8.2 8.2 A Brown acid 6.1 6.1 6.1 6.1 6.1 A Stearic acid 7.5 7.5 7.5 7.5 7.5 A behenic acid 6.0 6.0 6.0 6.0 6.0 Potassium hydroxide 5.1 5.1 5.1 5.1 5.1 Diethylene glycol monoethyl ether 5.0 5.0 5.0 5.0 5.0 Dipropylene glycol 6.0 6.0 6.0 6.0 6.0 D Yamanashi Sugar alcohol 12 12 12 12 12 D Glycerin 8.6 8.6 8.6 8.6 8.6 B Gasified guar hydroxypropyl triammonium μ 0.17 0.1 0.03 0.2 — C Hydroxypropyl guar 42 0.03 0.1 0.17 — 0.2 E Residual residue of water residue Residual amount of residual amount - 100 100 100 100 100 (B) : (C) 5:1 1:1 1:5 — — Viscosity of the paste 45 61 55 41 25 Extension of the paste on the towel 65 80 75 59 42 Foaming 831 950 712 825 770 The fineness of the bubble 100 91 100 100 97 The ease of expansion of the bubble 4.3 4.7 3 3.0 1.3 Washability 4.0 5.0 5.0 3.0 5.0 Skin feeling after washing 4.7 5.0 5.0 5.0 5.0 Viscosity (dPa · s) 1490 1500 1550 1510 1510 *2 : JaguarHP105 (Rhodia Corporation) *5 : Jaguar C-17 (Rhodia Corporation) 099104683 20 201032830 [Table 7]

Ingredient (% by weight) Example Comparative Example 20 21 22 10 12 A lauric acid 2.7 2.7 2.7 2.7 2.7 A Bean 8.2 8.2 8.2 8.2 8.2 A Palmitic acid 6.1 6.1 6.1 6.1 6.1 A Stearic acid 7.5 7.5 7.5 7.5 7.5 A Camelliic acid 6.0 6.0 6.0 6.0 6.0 Potassium hydroxide 5.1 5.1 5.1 5.1 5.1 Diethylene glycol monoethyl ether 5.0 5.0 5.0 5.0 5.0 Dipropylene glycol 6.0 6.0 6.0 6.0 6.0 D Sorbitol 12 12 12 12 12 D Glycerin 8.6 8.6 8.6 8.6 8.6 B Vaporized guar hydroxypropyltrimonium μ 0.17 0.1 0.03 — 0.2 C polyethylene glycol” 0.03 0.1 0.17 0.2 — E Water residual residue Residual amount Residual amount Residual amount 100 100 100 100 100 (Β) : ( C) 5:1 1:1 1:5 — — Viscosity of the paste 50 102 35 46 41 Extension of the paste on the towel 68 120 55 66 59 Foaming 772 1070 831 534 825 Fineness of the bubble 100 85 92 90 100 bubble extension ease 3.0 3.3 3.0 1.0 3.0 rinsing 4.0 4.0 5.0 4.0 3.0 Skin feeling after washing 4.7 5.0 5.0 5.0 5.0 Viscosity (dPa · s) 1500 1530 1510 1510 1510 *5 ·· Jaguar C-17 (Rhodia Company) *3 : AlkoxE-100 (Mingcheng Chemical Industry Co., Ltd. Limited company) 099104683 21 201032830 [Table 8] Ingredient (% by weight) Example Comparative Example 23 24 25 11 12 A lauric acid 2.7 2.7 2.7 2.7 2.7 A myristic acid 8.2 8.2 8.2 8.2 8.2 A palmitic acid 6.1 6.1 6.1 6.1 6.1 A Stearic acid 7.5 7.5 7.5 7.5 7.5 A Camelliic acid 6.0 6.0 6.0 6.0 6.0 Potassium hydroxide 5.1 5.1 5.1 5.1 5.1 Diethylene glycol monoethyl ether 5.0 5.0 5.0 5.0 5.0 Dipropylene glycol 6.0 6.0 6.0 6.0 6.0 D Sorbitol 12 12 12 12 12 D Glycerin 8.6 8.6 8.6 8.6 8.6 B Gasified guar hydroxypropyl triammonium μ 0.17 0.1 0.03 — 0.2 C polyvinylpyrrolidone*4 0.03 0.1 0.17 0.2 — E Water residual residue Residual residue Residual residue Measured t" 100 100 100 100 100 (B) : (C) 5:1 1:1 1:5 — — Viscosity of the paste 70 122 35 10 41 Extension of the paste on the towel 88 140 55 20 59 Foaming Sexuality 950 1000 831 831 825 Fineness of foam 80 90 92 90 100 Easiness of swelling of the bubble 4.0 5.0 3.0 2.0 3.0 Washability 4.0 5.0 5.0 5.0 3.0 Skin feeling after washing 4.7 5.0 5.0 5.0 5.0 Viscosity (dPa · s) 1510 1530 1510 1500 1510 *5 : Jaguar C-17 (Rhodia Company) *4 : Luviskol K30 (BASF CORPORATION) 099104683 22 201032830 [Table 9] Ingredient (% by weight) Example Comparative Example 26 27 28 13 14 A Lauric acid 2.7 2.7 2.7 2.7 2.7 A Myristic acid 8.2 8.2 8.2 8.2 8.2 A Palmitic acid 6.1 6.1 6.1 6.1 6.1 A Stearic acid 7.5 7.5 7.5 7.5 7.5 A Camelliic acid 6.0 6.0 6.0 6.0 6.0 Potassium hydroxide 5.1 5.1 5.1 5.1 5.1 Diethylene glycol monoethyl ether 5.0 5.0 5.0 5.0 5.0 Dipropylene glycol 6.0 6.0 6.0 6.0 6.0 D Sorbitol 12 12 12 12 12 D Glycerin 8.6 8.6 8.6 8.6 8.6 B Barium chloride-[2-hydroxy-3-(triammonium)propyl]hydroxyethylcellulose% 0.17 0.1 0.03 — 0.2 C Hydroxypropyl guar = 0.03 0.1 0.17 0.2 — E Water residual residue Residual amount Residual amount Residual amount 100 100 100 100 100 (B) : (C) 5:1 1:1 1:5 — — Paste Adhesive 31 62 60 25 20 Extension extension on the towel 51 80 80 42 38 Foaming 890 830 830 770 700 Fineness of the bubble 83 95 90 97 100 Easiness of expansion of the bubble 3.3 5.0 3.0 1.3 3.0 Flushing 5.0 5.0 5.0 5.0 3.0 Skin feeling after washing 4.7 5.0 5.0 5.0 5.0 Viscosity (dPa · s) 1510 1500 1490 1510 1510 *6 : CaticeloM-80 (Kao Corporation) 〇*2 : Jaguar HP 105 (Rhodia Corporation) 23 099104683 201032830 [Table ί ] Ingredient (% by weight) Example Comparative Example 29 30 31 10 14 A lauric acid 2.7 2.7 2.7 2.7 2.7 A myristic acid 8.2 8.2 8.2 8.2 8.2 A palmitic acid 6.1 6.1 6.1 6.1 6.1 A stearic acid 7.5 7.5 7.5 7.5 7.5 A catechin 6.0 6.0 6.0 6.0 6.0 Potassium hydroxide 5.1 5.1 5.1 5.1 5.1 Diethylene glycol monoethyl ether 5.0 5.0 5.0 5.0 5.0 Dipropylene glycol 6.0 6.0 6.0 6.0 6.0 D Sorbitol 12 12 12 12 12 D Glycerin 8.6 8.6 8.6 8.6 8.6 B Barium chloride-[2-hydroxy-3-(triammonium) Base) propyl] hydroxyethyl cellulose% 0.17 0.1 0.03 — 0.2 C Polyethylene glycol ^ 0.03 0.1 0.17 0.2 — E Water residual residue Residual amount Residual amount Residual amount Total 100 100 100 100 100 (B) : ( C) 5:1 1:1 1:5 — — Viscosity of the paste - 70 70 45 46 20 Extension of the paste on the towel 85 86 64 66 38 Foaming 1070 1000 830 534 700 Fineness of the bubble 80 80 90 90 100 bubble extension ease 3.0 3.3 3.0 1.0 3.0 rinsing 3.3 4.0 4.0 4.0 3 .0 Skin feeling after washing 4.7 5.0 5.0 5.0 5.0 Viscosity (dPa · s) 1530 1530 1500 1500 1510 *6 : CaticeloM-80 (Kao Corporation) *3 : AlkoxE-100 (Ming Shing Chemical Industry Co., Ltd.) 24 099104683 201032830

L Record 11J Ingredient (% by weight) Example Comparative Example 32 33 34 11 14 A Lauric acid 2.7 2.7 2.7 2.7 2.7 A Carnitine acid 8.2 8.2 8.2 8.2 8.2 A Palmitic acid 6.1 6.1 6.1 6.1 6.1 A Stearic acid 7.5 7.5 7.5 7.5 7.5 A behenic acid 6.0 6.0 6.0 6.0 6.0 Potassium hydroxide 5.1 5.1 5.1 5.1 5.1 Diethylene glycol monoethyl ether 5.0 5.0 5.0 5.0 5.0 Dipropylene glycol 6.0 6.0 6.0 6.0 6.0 D Sorbitol 12 12 12 12.0 12.0 D Glycerin 8.6 8.6 8.6 8.6 8.6 B Chloro[0-[2-hydroxy-3-(triammonium)propyl]hydroxyethylcellulose% 0.17 0.1 0.03 — 0.2 C polyvinylpyrrolidone 0.03 0.1 0.17 0.2 — E Water Residual amount Residual amount Residual amount Residual amount Total 100 100 100 100 100 (B) : (C) 5:1 1:1 1:5 — — Viscosity of the paste 30 35 20 10 20 Extension of the paste on the towel 55 42 64 20 38 Foaming 890 1130 830 831 700 Foaming detail 82 80 90 90 100 Foaming ease 4.0 5.0 3.0 2.0 3.0 Washing 4.0 5.0 4.0 5.0 3.0 Skin feeling after washing 4.7 5.0 5.0 5.0 5.0 Viscosity (dPa · s) 1510 1530 1500 1500 1510 *6 : CaticeloM-80 (Kao Wang Division) Q *4 : Luviskol K30 (BASF CORPORATION) 25 099104683 201032830 [Table 12] Ingredient (% by weight) Example Comparative Example 35 13 15 A Lauric acid 2.7 2.7 2.7 A Myristic acid 8.2 8.2 8.2 A Brown acid 6.1 6.1 6.1 A stearic acid 7.5 7.5 7.5 A behenic acid 6.0 6.0 6.0 potassium hydroxide 5.1 5.1 5.1 diethylene glycol monoethyl ether 5.0 5.0 5.0 dipropylene glycol 6.0 6.0 6.0 D sorbitol 12 12 12.0 D glycerol 8.6 8.6 8.6 B gasification 〇-[2-hydroxy-3-(triammonium)propyl]hydroxyethylcellulose" 0.1 - 0.2 C Hydroxypropyl guar = 0.1 0.2 - E Residual amount of water residue Residual amount 100 100 100 (9): (C) 1:1 — Grease of the paste 40 25 30 Extension of the paste on the towel 50 42 40 Foaming 1000 770 700 Fineness of the bubble 80 97 100 Easiness of expansion of the bubble 5.0 1.3 3.0 Flushing 4.7 5.0 5.0 Skin feeling after washing 5.0 5.0 5.0 Viscosity (dPa · s) 1530 1510 1510 *7 : POIZC-150L (Kao company) *2 : Jaguar HP105 (Rhodia company) 26 099104683 201032830 [Table 13] Ingredients (weight %) Example Comparative Example 36 13 16 A lauric acid 2.7 2.7 2.7 A myristic acid 8.2 8.2 8.2 A palmitic acid 6.1 6.1 6.1 A stearic acid 7.5 7.5 7.5 A Camelliic acid 6.0 6.0 6.0 Potassium hydroxide 5.1 5.1 5.1 Diethylene glycol monoethyl ether 5.0 5.0 5.0 Dipropylene glycol 6.0 6.0 6.0 D Yamanashi Sugar alcohol 12 12 12 D Glycerin 8.6 8.6 8.6 B Copolymerized gas dimethyl diallyl diallyl ammonium and acrylamide ί8 0.1 A 0.2 C Hydroxypropyl guar 0.1 0.2 — E Residual residue of water residue Total 100 100 100 (B) : (C) 1:1 — — Viscosity of the paste 60 25 18 Extension of the paste on the towel 90 42 33 Foaming 940 770 600 Fineness of the bubble 90 97 100 Extension of the bubble Easiness 5.0 1.3 3.0 Rinse 5.0 5.0 4.7 Skin feeling after washing 5.0 5.0 5.0 Viscosity (dPa · s) 1530 1510 1510 *8 : Marco Pico 2200 (NALCO) *2 : JaguarHP105 (Rhodia) ❹ 27 099104683

Claims (1)

201032830 VII. Patent application scope: 1. A paste-like detergent containing the following components (A) to (E): (A) 20 to 50% by weight of a fatty acid or a salt thereof; (B) Cationic polymer 〇 .〇2~〇.2% by weight; (C) A nonionic polymer selected from the group consisting of hydroxypropyl guar gum, polyethylidene «pyrrolidone and polyethylene glycol 2咄2 % of soil; 4 (D) 3~3〇% by weight of polyol having 3 or more hydroxyl groups in the molecule. (E) Water. . , ❹ 2. For example, the patent application is a detergent of the formula, wherein the component (8) has a cationic polymer having an average molecular weight of 90,000 to 1 GG. 3. The detergent according to claim 1 or 2, wherein the component is a cationic polymer having a charge density of 0.5 to 4.5 meq/g. 4. If you apply for a full-time cleaning agent, the weight ratio of ingredient (8) to (C) is 5:1~丨:5. ◎ 5· If you apply for a patent scope! The detergent of the present invention, wherein the component (8) is a cationic polymer selected from the group consisting of a copolymer of dinonyl diallyl halide and acrylamide, a cationized cellulose, and a cationized guar. 6. 6. For the detergent according to the patent application (4), the component (c) is propyl guar. 7. The detergent according to claim 1, wherein among the fatty acids of the component (4), the fatty acid having 15 or less carbon atoms and the fatty acid having 16 or more carbon atoms are 099104683 28 201032830 in a weight ratio of 75: 25 to 20: 80 . 8. The detergent according to claim 1, wherein the detergent further contains a diol or a glycol ether. ❹ 099104683 29 201032830 IV. Designated representative map: (1) The representative representative of the case is: None (2) The symbol of the symbol of the representative figure is simple: No. 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention. : without 099104683