JP4247086B2 - Cleaning composition - Google Patents
Cleaning composition Download PDFInfo
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- JP4247086B2 JP4247086B2 JP2003346945A JP2003346945A JP4247086B2 JP 4247086 B2 JP4247086 B2 JP 4247086B2 JP 2003346945 A JP2003346945 A JP 2003346945A JP 2003346945 A JP2003346945 A JP 2003346945A JP 4247086 B2 JP4247086 B2 JP 4247086B2
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- weight
- alkyl
- cleaning composition
- viscosity
- fatty acid
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- 239000000203 mixture Substances 0.000 title claims description 54
- 238000004140 cleaning Methods 0.000 title claims description 27
- 125000000217 alkyl group Chemical group 0.000 claims description 23
- -1 polyoxyethylene Polymers 0.000 claims description 23
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 17
- 239000000194 fatty acid Substances 0.000 claims description 17
- 229930195729 fatty acid Natural products 0.000 claims description 17
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 150000003839 salts Chemical class 0.000 claims description 9
- 150000004665 fatty acids Chemical class 0.000 claims description 8
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 7
- 229920000570 polyether Polymers 0.000 claims description 7
- 239000003599 detergent Substances 0.000 claims description 6
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- 150000001735 carboxylic acids Chemical class 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 239000002280 amphoteric surfactant Substances 0.000 claims description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 239000006260 foam Substances 0.000 description 14
- 235000002639 sodium chloride Nutrition 0.000 description 13
- 238000005406 washing Methods 0.000 description 11
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000002253 acid Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 230000002421 anti-septic effect Effects 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- POJWUDADGALRAB-PVQJCKRUSA-N Allantoin Natural products NC(=O)N[C@@H]1NC(=O)NC1=O POJWUDADGALRAB-PVQJCKRUSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 206010015535 Euphoric mood Diseases 0.000 description 1
- BIVBRWYINDPWKA-VLQRKCJKSA-L Glycyrrhizinate dipotassium Chemical compound [K+].[K+].O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@H]1CC[C@]2(C)[C@H]3C(=O)C=C4[C@@H]5C[C@](C)(CC[C@@]5(CC[C@@]4(C)[C@]3(C)CC[C@H]2C1(C)C)C)C(O)=O)C([O-])=O)[C@@H]1O[C@H](C([O-])=O)[C@@H](O)[C@H](O)[C@H]1O BIVBRWYINDPWKA-VLQRKCJKSA-L 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241000047703 Nonion Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 229960000458 allantoin Drugs 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229960001716 benzalkonium Drugs 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- CYDRXTMLKJDRQH-UHFFFAOYSA-N benzododecinium Chemical compound CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 CYDRXTMLKJDRQH-UHFFFAOYSA-N 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229940106189 ceramide Drugs 0.000 description 1
- 150000001783 ceramides Chemical class 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 150000001841 cholesterols Chemical class 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229940101029 dipotassium glycyrrhizinate Drugs 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- 229940100608 glycol distearate Drugs 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229950001046 piroctone Drugs 0.000 description 1
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical class NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- ICUTUKXCWQYESQ-UHFFFAOYSA-N triclocarban Chemical compound C1=CC(Cl)=CC=C1NC(=O)NC1=CC=C(Cl)C(Cl)=C1 ICUTUKXCWQYESQ-UHFFFAOYSA-N 0.000 description 1
- 229960001325 triclocarban Drugs 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- 125000004417 unsaturated alkyl group Chemical group 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 229940043810 zinc pyrithione Drugs 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Description
本発明は洗浄剤組成物に関し、詳しくは、人、環境に対して温和であり、皮膚又は毛髪の洗浄時に好ましい粘度に調整可能であり、泡量、泡質及びすすぎ時の感触が良好で、且つ保存安定性に優れた洗浄剤組成物に関する。 The present invention relates to a cleaning composition, and in particular, is gentle to humans and the environment, can be adjusted to a preferred viscosity when washing skin or hair, has a good foam amount, foam quality and feel when rinsing, The present invention also relates to a cleaning composition having excellent storage stability.
アルキルポリグリコシドとアルキルポリエーテルカルボン酸またはそれらの塩類は低刺激性、環境負荷が低い界面活性剤として知られているが、一般的に、皮膚及び毛髪用洗浄剤組成物に使用する濃度では低粘度である。従って、それらを含む組成物の製剤化に際し、適度な粘度に調整することが必要である。特許文献１では、アルキルポリグリコシドとアルキルポリエーテルカルボン酸またはそれらの塩類の組み合わせに塩化ナトリウム等の電解質を加えることで粘度を調整している。
また、アルキルポリグリコシドとアルキルポリエーテルカルボン酸またはそれらの塩類は生分解性に優れることから、洗濯用洗浄剤組成物にも応用されている。特許文献２は、アルキルポリグリコシドとアルキルポリエーテルカルボン酸またはそれらの塩類に石鹸を組み合わせることにより、良好な洗浄性能を持つ弱起泡性洗濯用洗浄剤組成物を開示している。
In addition, alkyl polyglycosides and alkyl polyether carboxylic acids or salts thereof are excellent in biodegradability, and thus are applied to laundry detergent compositions. Patent Document 2 discloses a weak foaming laundry detergent composition having good cleaning performance by combining soap with alkyl polyglycoside and alkyl polyether carboxylic acid or salts thereof.
アルキルポリグリコシドとアルキルポリエーテルカルボン酸またはそれらの塩類は先述の通り非常に有用な界面活性剤であるが、日本人が好むすすぎ時にぬるつかない感触を出すのは難しく、一般的な増粘剤を添加したのでは粘度調整が容易でも更にぬるつき感が高くなる問題があった。また、先述の特許文献１の技術でも適切な製剤粘度とぬるつき感の低減を両立することは難しかった。
一方、特許文献２は洗濯用洗浄剤組成物であるため、皮膚及び毛髪用洗浄剤組成物に求められる性能を明らかにしていない。また、特許文献２では石鹸をRCOOP[式中、Rは炭素原子８〜22を有する飽和または不飽和のアルキル基、Pは水素、アルカリ金属、アンモニウムまたはアルカノールアンモニウムを示す]と定義している。組成物が液状の場合、石鹸が中和塩であれば、5〜30重量％の量で含ませることは容易であるが、この範囲の量で中和塩型石鹸を含む組成物は、皮膚及び毛髪用洗浄剤組成物に使用する濃度では低粘度である。酸型であると、安定な液状とすることが困難である。
従って本発明の目的は、人、環境に対して温和であり、皮膚又は毛髪の洗浄時に好ましい粘度に調整可能であり、泡量、泡質及びすすぎ時の感触が良好で、且つ保存安定性に優れた洗浄剤組成物を提供することである。
Alkyl polyglycosides and alkyl polyether carboxylic acids or their salts are very useful surfactants as described above, but it is difficult to give a non-smooth feel when rinsing, which is preferred by Japanese people. However, there was a problem that even when the viscosity adjustment was easy, the feeling of sliminess was further increased. In addition, it has been difficult to achieve both an appropriate formulation viscosity and a reduction in the feeling of stickiness even with the technique of Patent Document 1 described above.
On the other hand, since patent document 2 is a washing | cleaning detergent composition for washing | cleaning, the performance calculated | required by the cleaning composition for skin and hair is not clarified. Patent Document 2 defines soap as RCOOP [wherein R represents a saturated or unsaturated alkyl group having 8 to 22 carbon atoms, and P represents hydrogen, an alkali metal, ammonium or alkanol ammonium]. When the composition is liquid, if the soap is a neutralized salt, it can be easily added in an amount of 5 to 30% by weight. In addition, the concentration used in the hair cleaning composition is low viscosity. If it is in the acid form, it is difficult to form a stable liquid.
Therefore, the object of the present invention is gentle to humans and the environment, can be adjusted to a preferred viscosity when washing the skin or hair, has a good foam amount, foam quality and feel when rinsing, and is stable in storage. It is to provide an excellent cleaning composition.
本発明は、次の成分（Ａ）〜（Ｄ）：
（Ａ）アルキルポリエーテルカルボン酸またはそれらの塩類
（Ｂ）アルキルポリグリコシド
（Ｃ）脂肪酸
（Ｄ）ポリオキシエチレン脂肪酸モノエタノールアミド
を含有する洗浄剤組成物を提供するものである。
The present invention includes the following components (A) to (D):
(A) Alkyl polyether carboxylic acid or salts thereof (B) Alkyl polyglycoside (C) Fatty acid (D) A cleaning composition containing polyoxyethylene fatty acid monoethanolamide is provided.
本発明の洗浄剤組成物は、人、環境に対して温和であり、粘度が適切に調整可能であり、同時にすすぎ時のぬるつきが低減され、保存安定性を有する。 The cleaning composition of the present invention is gentle to people and the environment, the viscosity can be adjusted appropriately, and at the same time, the slickness during rinsing is reduced, and the storage stability is maintained.
本発明の成分（Ａ）のアルキルポリエーテルカルボン酸またはそれらの塩類は、一般式（１）で表される：
R1-O-（A）p-CH2-COOX (1)
（式中、R1は炭素数8-20のアルキルまたはアルケニル基、好ましくは炭素数12-14のアルキル基を示し、Ａはエチレンオキシ基及び／またはプロピレンオキシ基を示し、pは1-20、好ましくは2-17の数を示し、ＸはＨ、ナトリウム、カリウムのようなアルカリ金属、マグネシウムのようなアルカリ土類金属、アンモニウム、又は任意にヒドロキシアルキル置換されたアンモニウムを示す）。
本発明の洗浄剤組成物中の成分（Ａ）の含有量は、1-30重量％、好ましくは1-28重量％、特に2-25重量％である。成分（Ａ）の含有量が1-30重量％であれば、成分（Ｂ）と組み合わされて、十分な泡量と良好な泡質を与えることができる。
The alkyl polyether carboxylic acid of component (A) of the present invention or a salt thereof is represented by the general formula (1):
R 1 -O- (A) p -CH 2 -COOX (1)
(Wherein R 1 represents an alkyl or alkenyl group having 8 to 20 carbon atoms, preferably an alkyl group having 12 to 14 carbon atoms, A represents an ethyleneoxy group and / or propyleneoxy group, and p represents 1-20 And preferably represents a number of 2-17, and X represents an alkali metal such as H, sodium, potassium, an alkaline earth metal such as magnesium, ammonium, or optionally hydroxyalkyl-substituted ammonium).
The content of the component (A) in the cleaning composition of the present invention is 1-30% by weight, preferably 1-28% by weight, particularly 2-25% by weight. If content of a component (A) is 1-30 weight%, it can combine with a component (B) and can provide sufficient foam amount and favorable foam quality.
本発明の成分（Ｂ）のアルキルポリグリコシドは、一般式（２）で表される：
R2-O-(CH2CH2O)m-Zx (2)
（式中、R2は炭素数8-20、好ましくは8-14のアルキル基を示し、Zは炭素数5-6の還元糖を示し、ｍは0-10、好ましくは0-5の数を示し、ｘは1-5、好ましくは1.1-2.5の数を示す）。
本発明の洗浄剤組成物中の成分（Ｂ）の含有量は0.5-10重量％、好ましくは1-7重量％、特に1-5重量％である。成分（B）の含有量が0.5-10重量％の範囲内にあると、本発明の洗浄剤組成物の安定性が良好で、更に防腐性も保つため、防腐剤フリーの組成物とすることが可能である。本発明の洗浄剤組成物の使用場面に応じて更に防腐剤を添加して防腐能を強化しても良い。
The alkylpolyglycoside of component (B) of the present invention is represented by the general formula (2):
R 2 -O- (CH 2 CH 2 O) m -Z x (2)
(Wherein R 2 represents an alkyl group having 8 to 20 carbon atoms, preferably 8 to 14 carbon atoms, Z represents a reducing sugar having 5 to 6 carbon atoms, and m is a number from 0 to 10, preferably 0 to 5). And x represents a number of 1-5, preferably 1.1-2.5).
The content of the component (B) in the cleaning composition of the present invention is 0.5 to 10% by weight, preferably 1 to 7% by weight, particularly 1 to 5% by weight. When the content of the component (B) is in the range of 0.5 to 10% by weight, the cleaning composition of the present invention has good stability and further preserves antiseptic properties. Is possible. Depending on the use situation of the cleaning composition of the present invention, an antiseptic may be further added to enhance the antiseptic ability.
本発明の成分（Ｃ）の脂肪酸は、一般式（３）で表される：
R3-COOH (3)
（式中、R3は水酸基を有してもよい炭素数7-23の直鎖もしくは分岐鎖のアルキル基もしくはアルケニル基、好ましくは炭素数11-17の分岐鎖のアルキル基もしくはアルケニル基を示す）。
本発明の洗浄剤組成物中の成分（Ｃ）の含有量は、0.1〜5重量％、好ましくは0.1〜4.5重量％、特に0.3〜3重量％である。成分（Ｃ）の含有量が0.1重量％〜5重量％であれば、安定性が良好で、粘度調整とすすぎ時のぬるつき感を両立できる。
The fatty acid of component (C) of the present invention is represented by the general formula (3):
R 3 -COOH (3)
(Wherein R 3 represents a linear or branched alkyl or alkenyl group having 7 to 23 carbon atoms which may have a hydroxyl group, preferably a branched alkyl or alkenyl group having 11 to 17 carbon atoms. ).
The content of the component (C) in the cleaning composition of the present invention is 0.1 to 5% by weight, preferably 0.1 to 4.5% by weight, particularly 0.3 to 3% by weight. If content of a component (C) is 0.1 weight%-5 weight%, stability will be favorable and it can make a viscosity adjustment and the feeling of luster at the time of a rinse compatible.
本発明の成分（Ｄ）のポリオキシエチレン脂肪酸モノエタノールアミドは、一般式（４）で表される：
R4-CO-NH-CH2CH2O(CH2CH2O)nH (4)
（式中、R4は炭素数７-23、好ましくは炭素数1１-17のアルキル基を示し、ｎは1-20、好ましくは1-12の数を示す）。
本発明の洗浄剤組成物中の成分（Ｄ）の含有量は、0.1〜5重量％、好ましくは0.1〜4.5重量％、特に0.2〜3重量％である。成分（Ｄ）の含有量が0.1〜5重量であれば、組成物中で成分（C）を更に安定化させることができる。
The polyoxyethylene fatty acid monoethanolamide of component (D) of the present invention is represented by the general formula (4):
R 4 -CO-NH-CH 2 CH 2 O (CH 2 CH 2 O) n H (4)
(Wherein R 4 represents an alkyl group having 7 to 23 carbon atoms, preferably 11 to 17 carbon atoms, and n represents a number of 1 to 20, preferably 1 to 12).
The content of the component (D) in the cleaning composition of the present invention is 0.1 to 5% by weight, preferably 0.1 to 4.5% by weight, particularly 0.2 to 3% by weight. If content of a component (D) is 0.1-5 weight, a component (C) can be further stabilized in a composition.
本発明の洗浄剤組成物は、更に（Ｅ）両性界面活性剤を含むのが、組成物の泡量調整や毛髪洗浄時のきしみ感低減のために好ましい。該両性界面活性剤としては、アルキルアミノ酢酸ベタイン、アルキルアミンオキサイド、アルキルアミドプロピルベタイン、アルキルヒドロキシスルホベタイン及びイミダゾリン系ベタインが挙げられる。
本発明の洗浄剤組成物中の成分（Ｅ）の含有量は、通常0.5〜10重量％、好ましくは0.5〜9重量％、特に1〜8重量％である。成分（Ｅ）の含有量が0.5〜10重量％であれば、組成物の泡量調整や毛髪洗浄時のきしみ感の低減の観点から好ましい。
It is preferable that the cleaning composition of the present invention further contains (E) an amphoteric surfactant in order to adjust the foam amount of the composition and to reduce the squeaky feeling during hair washing. Examples of the amphoteric surfactant include alkylaminoacetic acid betaines, alkylamine oxides, alkylamidopropylbetaines, alkylhydroxysulfobetaines, and imidazoline-based betaines.
The content of component (E) in the cleaning composition of the present invention is usually 0.5 to 10% by weight, preferably 0.5 to 9% by weight, particularly 1 to 8% by weight. If content of a component (E) is 0.5 to 10 weight%, it is preferable from a viewpoint of the foam amount adjustment of a composition, and the reduction of the squeak feeling at the time of hair washing.
成分（A）及び（B）は低刺激性で生分解性良好な界面活性剤であり、これらを洗浄主基剤とすることで、低刺激性、環境負荷が小さい洗浄剤組成物とすることが出来る。成分（A）だけでは泡量不足であるが、成分（B）を加えることで泡量を増加させることが出来る。成分（A）及び（B）を単に混合しただけではすすぎ時にぬるつき感があり、すすぎの終了点が分かりにくく、しかも洗浄剤組成物から調製される製品（以下、製剤と云う）は十分な粘度が得られず、使用時に扱いにくい。しかし、成分（C）と(D)を加えることで製剤を安定に保ち、製剤の粘度を実使用に有効な範囲に調整できる。更にすすぎ時のぬるつき感を低減し、すすぎの終了点が感じられる製剤の調製が可能である。 Ingredients (A) and (B) are low-irritant and biodegradable surfactants. By using these as the main cleaning agent, a detergent composition with low irritation and low environmental impact should be obtained. I can do it. The amount of foam is insufficient with component (A) alone, but the amount of foam can be increased by adding component (B). Simply mixing components (A) and (B) gives a sensation of slickness during rinsing, the end point of rinsing is difficult to understand, and a product prepared from a detergent composition (hereinafter referred to as a formulation) is sufficient. Viscosity is not obtained and is difficult to handle during use. However, by adding components (C) and (D), the formulation can be kept stable, and the viscosity of the formulation can be adjusted to an effective range for practical use. Furthermore, it is possible to prepare a preparation that reduces the feeling of slickness during rinsing and feels the end point of rinsing.
皮膚への負担をより少なくするため、本発明の洗浄剤組成物を弱酸性〜中性領域に調整できる。本発明の洗浄剤組成物のｐHを5.0〜8.0の領域に調整することで、弱酸性〜中性のより低刺激の組成物にすることが出来る。更に好ましいｐHは5.0〜7.0である。この場合も上記成分（Ａ）〜（Ｄ）の組み合わせはその性能を十分に発揮でき、安定な製剤が得られる。ｐＨ調整は、乳酸、コハク酸、リンゴ酸、クエン酸等の酸、アルカリ金属水酸化物、エタノールアミン等のアルカリを用いて行うことができる。 In order to reduce the burden on the skin, the cleaning composition of the present invention can be adjusted to a weakly acidic to neutral region. By adjusting the pH of the cleaning composition of the present invention to a range of 5.0 to 8.0, a weakly acidic to neutral and less irritating composition can be obtained. A more preferred pH is 5.0 to 7.0. Also in this case, the combination of the components (A) to (D) can sufficiently exhibit the performance, and a stable preparation can be obtained. The pH can be adjusted using an acid such as lactic acid, succinic acid, malic acid or citric acid, or an alkali such as an alkali metal hydroxide or ethanolamine.
本発明の洗浄剤組成物の実使用に有効な粘度は、Ｂ型粘度計を用い、２５℃における測定で150〜8000mPa・s、好ましくは200〜5000mPa・s、更に好ましくは200〜3000mPa・sである。この粘度は製剤を手で泡立てて身体をなでる様に洗浄する場合、タオル・スポンジ等の道具で泡立て、道具で身体を洗浄する場合、手にとって毛髪に塗布し泡立てて洗浄する場合を想定している。この粘度より低い時は手及び道具からしたたり落ちやすく、高い時は温水とのなじみに時間がかかり、容易に泡立てられない。 The viscosity effective for actual use of the cleaning composition of the present invention is 150 to 8000 mPa · s, preferably 200 to 5000 mPa · s, more preferably 200 to 3000 mPa · s as measured at 25 ° C. using a B-type viscometer. It is. This viscosity is based on the assumption that the product is foamed by hand and is washed like a stroke with a tool. Yes. When it is lower than this viscosity, it tends to fall off from hands and tools, and when it is high, it takes time to become familiar with warm water and it cannot be easily foamed.
成分（Ｂ）と（Ｃ）の重量比が（Ｂ）：（Ｃ）＝１：１〜１０：１の範囲内にあると本発明の洗浄剤組成物の安定性が良好となる。 When the weight ratio of the components (B) and (C) is in the range of (B) :( C) = 1: 1 to 10: 1, the stability of the cleaning composition of the present invention is improved.
成分（Ｃ）を使用しないで一般的な増粘剤、例えば塩化ナトリウム等の電解質、ジエタノールアミド、モノエタノールアミド等の脂肪酸アルカノールアミド、ジステアリン酸ポリエチレングリコール等のポリエチレングリコール脂肪酸エステル、カルボキシビニルポリマー等の水溶性ポリマーを添加し、製剤の粘度を調整可能である。しかし、これらの増粘剤だけで粘度調整した場合、使用感の改善はなく、更にぬるつき感が高くなることがある。従って、これらの増粘剤は、本発明の効果を損なわない量で成分（Ｃ）と共に本発明の洗浄剤組成物に配合して、該組成物の粘度を調整することは可能である。 General thickeners without using component (C), for example, electrolytes such as sodium chloride, fatty acid alkanolamides such as diethanolamide and monoethanolamide, polyethylene glycol fatty acid esters such as polyethylene glycol distearate, and carboxyvinyl polymers A water-soluble polymer can be added to adjust the viscosity of the preparation. However, when the viscosity is adjusted only with these thickeners, the feeling of use is not improved, and the slimy feeling may be further increased. Therefore, these thickeners can be blended in the cleaning composition of the present invention together with the component (C) in an amount that does not impair the effects of the present invention to adjust the viscosity of the composition.
本発明の洗浄剤組成物に、本発明の効果を損なわない程度に次の成分を適宜配合出来る。
界面活性剤としては、成分（Ａ）、（Ｂ）、（Ｄ）以外のアニオン、ノニオン又はカチオン性界面活性剤が挙げられる。
アニオン性界面活性剤としては、次のものが挙げられる：アルキル硫酸エステル塩、ポリオキシアルキレンアルキルエーテル硫酸エステル塩、ポリオキシアルキレンアルキルエーテルリン酸塩、アルキルリン酸塩、N-アシルメチルタウリン塩、アシルグルタミン酸塩、アシロイル-β-アラニン塩、アルキルスルホコハク酸塩、ポリオキシアルキレンアルキルスルホコハク酸塩、アルキルイセチオン酸塩等。
ノニオン性界面活性剤としては、次のものが挙げられる：ポリオキシアルキレンアルキルまたはアルケニルエーテル、ポリオキシアルキレンソルビタン脂肪酸エステル、ソルビタン脂肪酸エステル、ポリオキシアルキレンソルビトール脂肪酸エステル、ポリオキシアルキレングリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、脂肪酸モノグリセリド、ポリエチレングリコール脂肪酸エステル、成分（Ｄ）以外の脂肪酸アルカノールアミド等。
カチオン性界面活性剤としては、次のものが挙げられる：直鎖又は分岐鎖のモノ−又はジ−アルキル第４級アンモニウム塩、アルキル鎖長にエーテル基、エステル基、アミド基等の官能基を導入した直鎖又は分岐鎖のモノ−又はジ−アルキル第４級アンモニウム塩。
油剤・脂質としては、次のものが挙げられる：
高級アルコール、シリコーン、第三級アミン、脂肪酸エステル、セラミド類、コレステロール類等。
パール化剤としては、次のものが挙げられる：
エチレングリコールジステアレート、魚鱗箔等。
カチオン化ポリマーとしては、次のものが挙げられる：
カチオン化グアガム、カチオン化セルロース、ポリクオタニウム-7、-22、-52等。
水溶性ポリマーとしては、次のものが挙げられる：
メチルセルロース、ヒドロキシエチルセルロース、アクリル酸・メタクリル酸アルキル共重合体、キサンタンガム等。
溶剤としては、次のものが挙げられる：
グリセリン、ソルビトール、エタノール、プロピレングリコール等。
電解質としては、次のものが挙げられる
塩化ナトリウム、塩化カリウム、硫酸ナトリウム等。
キレート剤としては、次のものが挙げられる：
エチレンジアミン四酢酸塩、ホスホン酸塩等。
殺菌剤・抗フケ剤としては、次のものが挙げられる：
塩化ベンザルコニウム、アルキルリン酸ベンザルコニウム、トリクロサン、トリクロカルバン、オクトピロックス、ジンクピリチオン等。
抗炎症剤としては、次のものが挙げられる：
グリチルリチン酸ジカリウム、アラントイン等。
防腐剤としては、次のものが挙げられる：
パラベン、安息香酸塩、ケーソンCG（商品名）等。
その他、酸化防止剤、紫外線吸収剤、色素、香料、植物エキス等が挙げられる。
The following components can be appropriately blended with the cleaning composition of the present invention to such an extent that the effects of the present invention are not impaired.
Examples of the surfactant include anions other than components (A), (B), and (D), nonions, and cationic surfactants.
Examples of the anionic surfactant include: alkyl sulfate ester salt, polyoxyalkylene alkyl ether sulfate ester salt, polyoxyalkylene alkyl ether phosphate salt, alkyl phosphate salt, N-acylmethyl taurine salt, Acyl glutamate, acyloyl-β-alanine salt, alkyl sulfosuccinate, polyoxyalkylene alkyl sulfosuccinate, alkyl isethionate and the like.
Nonionic surfactants include the following: polyoxyalkylene alkyl or alkenyl ether, polyoxyalkylene sorbitan fatty acid ester, sorbitan fatty acid ester, polyoxyalkylene sorbitol fatty acid ester, polyoxyalkylene glycerin fatty acid ester, polyglycerin Fatty acid esters, fatty acid monoglycerides, polyethylene glycol fatty acid esters, fatty acid alkanolamides other than component (D), and the like.
Cationic surfactants include the following: linear or branched mono- or di-alkyl quaternary ammonium salts, alkyl groups with functional groups such as ether groups, ester groups, amide groups, etc. Introduced linear or branched mono- or di-alkyl quaternary ammonium salts.
Oils and lipids include the following:
Higher alcohols, silicones, tertiary amines, fatty acid esters, ceramides, cholesterols, etc.
Examples of pearlizing agents include:
Ethylene glycol distearate, fish scale foil, etc.
Cationic polymers include the following:
Cationized guar gum, cationized cellulose, polyquaternium-7, -22, -52, etc.
Water-soluble polymers include the following:
Methyl cellulose, hydroxyethyl cellulose, acrylic acid / alkyl methacrylate copolymer, xanthan gum and the like.
Solvents include the following:
Glycerin, sorbitol, ethanol, propylene glycol, etc.
Examples of the electrolyte include sodium chloride, potassium chloride, sodium sulfate and the like.
Chelating agents include the following:
Ethylenediaminetetraacetate, phosphonate, etc.
Examples of fungicides and antidandruff agents include:
Benzalkonium chloride, benzalkonium alkyl phosphate, triclosan, triclocarban, octopirox, zinc pyrithione, etc.
Anti-inflammatory agents include the following:
Dipotassium glycyrrhizinate, allantoin, etc.
Preservatives include the following:
Paraben, benzoate, caisson CG (trade name), etc.
In addition, antioxidants, ultraviolet absorbers, pigments, fragrances, plant extracts and the like can be mentioned.
実施例１〜９及び比較例１〜９
表１及び２に示す組成の成分を配合して、実施例１〜９及び比較例１〜９の各組成物を得た。これらの組成物を、専門パネラー３人により、下記の基準で泡量、泡質、すすぎ時の感触及びタオルドライ時の感触に関する手洗い評価、保存安定性、粘度および皮膚刺激性について評価した。但し、評点は３人の平均値の小数点以下を四捨五入した値である。
手洗い評価
各組成物を１ｍＬ手に取り、水道水を使って約２０秒間手を擦り合せ、その後水道水で十分すすぐ。すすいだ後、タオルで水分をふき取る。泡量、泡質、すすぎ時の感触、タオルドライ時の感触を評価した。
５：優れる
４：やや優れる
３：標準（実施例１）
２：やや劣る
１：劣る
なお、手洗い評価においては、実施例１の組成物を標準（３）とした。
保存安定性
１００ｍＬのガラス容器（内径３５ｍｍ、高さ１０５ｍｍ）に各組成物９０ｍＬを充填し、４０℃、２５℃、５℃の恒温器に保存し、１日後の状態を観察した。
○：変化なし
×：変化あり（結晶析出、にごり、２相分離等）
粘度測定
Ｂ型粘度計を用いて２５℃での粘度を測定した。製剤の粘度に合わせてＮＯ．１〜Ｎｏ．２のローターを使い分けた。
皮膚刺激性
手洗い評価後、十分に手を乾燥させた時の肌の状態を観察した。
○：異常なし
×：異常あり（過乾燥等）
評価結果を表１及び２に示す。
表１及び２の結果から、実施例１〜９の組成物はすべて適度な粘度をもち、使用感が良好で、保存安定性も良好であることが分かる。これに対して、比較例１〜４の組成物は粘度が低く、手洗い評価も実施例１の組成物と同等又はそれ以下であり、比較例１の組成物は低温（５℃）での保存安定性が良くない。また比較例５〜９の組成物ではすすぎ時にぬるつき感が高く、比較例５及び７〜９の組成物では保存安定性が良くない。
Examples 1-9 and Comparative Examples 1-9
The components of the compositions shown in Tables 1 and 2 were blended to obtain each composition of Examples 1 to 9 and Comparative Examples 1 to 9. These compositions were evaluated by three professional panelists for foam washing, foam quality, hand rinse evaluation and towel dry feel, storage stability, viscosity and skin irritation according to the following criteria. However, the rating is a value obtained by rounding off the decimal point of the average value of three people.
Hand washing evaluation Take 1 mL of each composition, rub your hands with tap water for about 20 seconds, and then rinse thoroughly with tap water. After rinsing, wipe off moisture with a towel. The amount of foam, foam quality, feel during rinsing, and feel during towel drying were evaluated.
5: Excellent 4: Slightly excellent 3: Standard (Example 1)
2: Slightly inferior 1: Inferior In the hand-washing evaluation, the composition of Example 1 was used as the standard (3).
Storage stability A 100 mL glass container (inner diameter 35 mm, height 105 mm) was filled with 90 mL of each composition, stored in a thermostat at 40 ° C., 25 ° C., and 5 ° C., and the state after one day was observed.
○: No change ×: Change (crystal precipitation, dust, two-phase separation, etc.)
Viscosity measurement The viscosity at 25 ° C. was measured using a B-type viscometer. NO. According to the viscosity of the preparation. 1-No. Two rotors were used properly.
Skin irritation After hand washing evaluation, the skin condition when the hands were sufficiently dried was observed.
○: No abnormality ×: Abnormal (over-drying, etc.)
The evaluation results are shown in Tables 1 and 2.
From the results of Tables 1 and 2, it can be seen that the compositions of Examples 1 to 9 all have moderate viscosities, good usability, and good storage stability. On the other hand, the compositions of Comparative Examples 1 to 4 have low viscosity, and the hand washing evaluation is equal to or less than that of Example 1, and the composition of Comparative Example 1 is stored at a low temperature (5 ° C.). Stability is not good. Further, the compositions of Comparative Examples 5 to 9 have a high feeling of luster when rinsed, and the compositions of Comparative Examples 5 and 7 to 9 have poor storage stability.
Claims (4)
（Ａ）アルキルポリエーテルカルボン酸またはそれらの塩類 ２〜２５重量％
（Ｂ）アルキルポリグリコシド １〜７重量％
（Ｃ）次の一般式（３）で表される脂肪酸 ０．３〜３重量％：
R 3 -COOH (3)
（式中、R 3 は水酸基を有してもよい炭素数7-23の直鎖もしくは分岐鎖のアルキル基もしくはアルケニル基を示す）
（Ｄ）ポリオキシエチレン脂肪酸モノエタノールアミド ０．１〜５重量％
を含有する皮膚又は毛髪用洗浄剤組成物。 The following components (A) to (D):
(A) Alkyl polyether carboxylic acid or a salt thereof 2 to 25% by weight
(B) Alkyl polyglycoside 1-7% by weight
(C) 0.3 to 3 % by weight of a fatty acid represented by the following general formula (3) :
R 3 -COOH (3)
(Wherein R 3 represents a linear or branched alkyl or alkenyl group having 7 to 23 carbon atoms which may have a hydroxyl group)
(D) 0.1-5% by weight of polyoxyethylene fatty acid monoethanolamide
A cleansing composition for skin or hair.
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| JP2003346945A JP4247086B2 (en) | 2003-10-06 | 2003-10-06 | Cleaning composition |
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| JP2005112946A JP2005112946A (en) | 2005-04-28 |
| JP4247086B2 true JP4247086B2 (en) | 2009-04-02 |
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Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI434703B (en) * | 2007-05-14 | 2014-04-21 | Kao Corp | Skin cleansing composition |
| JP5399576B2 (en) * | 2012-03-02 | 2014-01-29 | 花王株式会社 | Skin cleanser composition |
| TWI465254B (en) * | 2012-03-02 | 2014-12-21 | Kao Corp | Skin detergent composition |
| JP5891074B2 (en) * | 2012-03-07 | 2016-03-22 | 花王株式会社 | Method for producing cleaning composition |
| JP6121098B2 (en) * | 2012-03-07 | 2017-04-26 | 花王株式会社 | Skin cleanser composition |
| JP6389029B2 (en) * | 2013-05-31 | 2018-09-12 | ホーユー株式会社 | Hair cleaning composition |
| JP6320180B2 (en) * | 2014-06-05 | 2018-05-09 | 花王株式会社 | Skin cleanser composition |
| JP2021147568A (en) * | 2020-03-23 | 2021-09-27 | 株式会社マンダム | Cleanser composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| DE4016819A1 (en) * | 1990-05-25 | 1991-12-19 | Huels Chemische Werke Ag | Low foam liq. or powder machine washing compsn. with surfactant - comprising alkyl-poly:glycoside, alkanol ether carboxylate and soap |
| JPH07305091A (en) * | 1994-05-10 | 1995-11-21 | Kao Corp | Cleaning agent composition |
| JPH09302381A (en) * | 1996-05-15 | 1997-11-25 | Lion Corp | Nonionic surfactant and cleanser composition containing the same |
| JP3998819B2 (en) * | 1998-07-02 | 2007-10-31 | 花王株式会社 | Liquid detergent composition |
| JP3740054B2 (en) * | 2000-12-28 | 2006-01-25 | 花王株式会社 | Cleaning composition |
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