TW201026687A - Herbicidal mixtures - Google Patents

Abstract

Herbicidal mixtures comprising (a) at least one active compound A from the group of the thaxtomin derivatives of the formula I in which the variables are as defined in the description and (b) at least one active compound B from the group of the protoporphyrinogen IX oxidase inhibitors selected from the group consisting of the formulae II, III and IV in which the variables are as defined in the description, compositions comprising them, and also methods for controlling unwanted vegetation.

Description

201026687 VI. INSTRUCTIONS OF THE INVENTION: FIELD OF THE INVENTION The present invention relates to herbicide mixtures comprising: a) at least one active compound A' from a group of thaxtomin derivatives of formula I,

Wherein A is a phenyl group or a 5- or 6-membered heteroaryl group containing 1, 2, 3 or 4 heteroatoms selected from the group consisting of ruthenium, n and S, wherein Ra is at the a-attachment point Adjacent position;

Ra SCN, N02, CVCV alkyl, Z_c3_C6_cycloalkyl, Ci_C4_i alkyl, CVCo alkoxy, Cl_C4_thiomorpho, Ci_C4_haloalkoxy, cvc:4·halothioalkyl, 0_z_C3_c6 _Cycloalkyl, S(0)nRy, C3-C6-thiol, c2_C6_dilute, Z_C3_C6_cycloalkyl, c3-c6-diloxy, c2-c6-alkynyl, C3_C6-alkynyloxy , c3-c6-thioalkynyl, nrarb, tri-Ci_C4•alkylalkyl, ZC(=0)-Rd, Z_C(=S)_Ral, z C(=N 〇rA) Ral ZC[=N( 0)-RA]-Ra丨, Z_P(=〇)(Ral)2, phenylnaphthyl, 3- to 7-membered monocyclic ring attached via carbon or nitrogen, or 9- or 1〇-membered double-ring saturated, An unsaturated or aromatic heterocyclic ring containing one, two, three or four heteroatoms selected from the group consisting of ruthenium, N and S and partially or completely substituted by the groups Raa and/or Ral and/ Or fused to another saturated, not I45027.doc -4- 201026687 saturated or aromatic carbocyclic or heterocyclic ring, ugly right R attached to a carbon atom, then

Outside the RaS can be a dentate;

Ry system (: 丨-C6-alkyl, c, Γ秘 | ^

丞 l3-c4-alkenyl, c3_C4_alkynyl, nrArB or CVCV halo-existing group and with hydrazine, J or 2;

RA and RB are each independently hydrogen, Ci_C6_formyl, C3_C6_dense or q-cv alkynyl, ever cycloalkyl, C1_C6_alkylcarbonyl, C3-CV cycloalkylcarbonyl, C3_C6-alkenylcarbonyl, C3_C6_cycloalkenyl-based group and C3_CV alkynyl group; ra, RB may also form a 5- or 6-membered saturated, partially or fully unsaturated ring together with the nitrogen atom to which it is attached, which may be in addition to carbon atoms. Containing one, two or three heteroatoms selected from the group consisting of ruthenium, N and S, the ring may be substituted by 1 to 3 groups Raa; Z-system covalent bond, CVC4-alkylene group, c2- C6-alkenyl or c2-C6-alkynyl;

Ral is hydrogen, OH, CVCV alkyl, CVC4. haloalkyl, C3-C6-cycloalkyl, c2-c8-alkenyl, c5-c6-cycloalkenyl, c2-c8-alkynyl, (VC6-alkoxy) , Ci-CV haloalkoxy, c3-c8-alkenyloxy, C3-C8-alkynyloxy, NRRAB, CVC6-alkoxyamino, Ci-C6-homo-based amine, Ci-C6 - anthranyl aryl-based amine, [di-(Ci-Ce)-andylamino]-decylamino, C3-C6-alkenylamino, C3-C6-alkynylamino, N -(C2-C6-alkenyl)-N-CG-CV alkyl)amino, n-(c2-c6-alkynyl)-N-CCi-CV alkyl)amino, N-CCVCV alkoxy) -N-CCVC6-alkyl)amino, N-(C2-C6-ene 145027.doc 201026687 alkoxy)amino, n_(C2-C6-blockyl) alkoxy)amine, Ci-C6 · burnt base, di-C^C: 4-alkyl; oxime, phenyl, benzene, stupyl or 5- or 6-membered monocyclic or 9- or 10-member a bicyclic heterocyclic ring containing i, 2, 3 or 4 heteroatoms selected from the group consisting of ruthenium, N and S, wherein the cyclic groups are unsubstituted or passed through, 2, 3 Or 4 groups of Raa substitutions;

Raa dentate, OH, CN, N02, Cl-C4-alkyl, Cl_C4_South alkyl, Ci-CV alkoxy, Ci-CV haloalkoxy, S(0)nRy, zC(=〇)- Ral , 2-C(=S).Ral , ZC(=N-〇RA)_Ra丨, Z_C[=N(〇)_RA] Ral, pendant oxy group (=〇), and tri-CrCV alkyl decyl group;

Rb is independently of each other hydrogen, CN, N〇2, _, Ci_c4_alkyl, alkyl, c2_c4_alkenyl, c3_C6-alkynyl, Ci_c4_alkoxy, Cl decyloxy, nodal Or s(o)nRy;

R and/or R itself may also form a 5- or 6-membered saturated, partially or fully unsaturated ring with a group attached to a moth-ring carbon atom or Rb or a ring-a ring nitrogen atom, in addition to a carbon atom. It may also contain 1, 2 or 3 heteroatoms selected from the group consisting of ruthenium, which may be substituted by 3 groups and/or kneaded to another saturated, unsaturated or aromatic carbocyclic ring or Heterocycle; m system 0, 1, 2 or 3;

R1 is hydrogen, hydrazine H, CN, Ci_Ci2_alkyl, C3_Ci2 dilute a, base Cl C4_alkoxy, C3-C6-cyclohexyl, C5-C6-cycloalene J 145027.doc • 6 - 201026687 NRARB, S(0)nRy, S(0)nNRARB, c(=〇)Rn, CONR R, stupid or 5- or 6-membered monocyclic or 9 or 1-membered bicyclic saturated, partially unsaturated or aromatic a heterocyclic ring containing one, two, three or four heteroatoms selected from the group consisting of ruthenium, N and S, wherein the cyclic groups are attached via Z1 and are unsubstituted or substituted, 2, 3 or 4 groups R substituted, and the following groups which may be partially or completely substituted by Ra a: Ci-CV alkyl, c3-c4-mercapto and c3_c4_ fast radical; ❹ R11 hydrogen , C]-C4-alkyl, Ci-C^alkyl, Ci_c4_alkoxy and CVCV haloalkoxy; Z1 carbonyl or group Z; wherein in the group R1, R2, R3, Ra and its In the substituent, the carbon chain and/or the cyclic group may be partially or completely substituted by Raa and/or; R2 is (^-(: 4-, CH3-C4-diyl or c3-c4-alkynyl; R3 is halogen, CN, N〇2, 〇H, NH2, Ci_C4 alkyl, Z C3_C8_ cycloalkyl, z-c5-c8-cycloalkyl, z-c7-c8-cycloalkynyl, c3-c6- • dilute , C3-C6-alkynyl, Z-[tri-(CVC6)-alkyl sulphate, ¢(=0)1111, Z-phenyl, 5- or 6-membered monocyclic or 9- or 10- Bicyclic heterocycles which are attached via Z and contain 1, 2, 3 or 4 heteroatoms selected from the group consisting of ruthenium, N and S; R hydrogen, halogen, CVCV alkyl or (VC4· Haloalkyl, or R4 and H5 together form a covalent bond; R, R6, R7, R8 are independently of each other hydrogen, halogen, hydrazine H, CN, N02, Ci-Cr alkyl, Ci_c4_ haloalkyl, C2_C6-alkenyl , c2_C6_ block, Ci-c4-alkoxy, c--c4-haloalkoxy, c3-c6-ring 145027.doc 201026687 alkyl, c3-c6-cycloalkenyl or c3-c6-cycloalkynyl; R9 ' R10 are independently of each other hydrogen, halogen, OH, haloalkyl, NRARB, NRAC(0)R91, CN, N02, CVCU-alkyl, CVC4-haloalkyl, C2-C4-alkenyl, C3-C6-alkyne a CVC4-alkoxy group, a Ci-CV haloalkoxy group, a 0-C(0)R91, a phenoxy group or a benzyloxy group, wherein in the groups R9 and R1G, a carbon chain and/or a cyclic group may be used. With i, 2, 3 or 4 substituents Raa; R91 is a core-fluorene-alkyl group or NRRAB; or an agriculturally suitable salt thereof, and b) at least one active The compound B' is derived from a group of the protoporphyrinogen IX oxidase inhibitors selected from the group consisting of

Wherein R21 is ruthenium or halogen; R22 is halogen or CN; and R23 is H, q-CV alkyl, Cl_c6_, self-alkyl, C3_C6, cycloalkyl c3-c6-sweet, c3-c6-halogen , c3-c6-blockyl, cc dentate alkynyl, cvcv alkoxy or c3-c6-cycloalkyl-c 6 group; 1 sense 6' T system 0 or N; R group R1, R11 Or R111, 145027.doc. 201026687

It is attached via # and wherein: R24 is CHF2, CF3 or S02CH3; R25 is halogen or CH3; and R26 is Η, NH2, CH3 or CH2CeCH;

R27 is Η or CH3; T1 is Ο or S;

Or formula IV

among them

R series C1-C6-alkyl, Ci_C6_l^, alkyl, C1-C6-alkoxy-C!-C6-alkyl, C1-C7-cycloalkyl, C3-C6-dilute, C3-C6- Haloalkenyl, C3-C6-alkynyl, C3-C6-haloalkynyl or C3-C6-cycloalkyl-C1-C4-alkyl; R42 halogen, CVCV alkyl, Ci-CV haloalkyl, CVC3-alkoxy, CVCV alkoxy-CVCV alkyl; and R43 is halogen, CN, N〇2, Ci-CU-alkyl, CrCV haloalkyl, CVC4-alkoxy, CVCV alkylsulfonyl, Ci-C4-alkoxy-CVC4-alkyl, C3-C6-cycloalkyl-CVC2-alkyl, or co2r44; wherein 145027.doc -9- 201026687 R44 is one of the groups mentioned for R41 X system, 1, 2 or 3 y system, 1, 2, 3 or 4. [Prior Art] In the case of a crop protection composition, it is in principle desirable to increase the specific activity and effect reliability of the active compound. It is particularly desirable that the crop protection composition be effective in controlling harmful plants' and at the same time compatible with the useful plants. It is also expected to have a broad spectrum of activity so that multiple harmful plants can be controlled simultaneously. In general, this cannot be achieved with a single herbicidal active compound. The problem with many two-way herbicides is their compatibility with useful plants (specifically, dicotyledonous crop plants (eg, cotton, canola) and grasses (eg, barley, millet, corn, glutinous rice, wheat, and sugar cane). It is not always satisfactory, that is, in addition to harmful plants, it also damages crop plants on an intolerable scale. By reducing the application rate, the damage to useful plants can be reduced. However, the degree of control over harmful plants is naturally reduced. Small. Another common problem is that herbicides can only be used in a very narrow time frame to achieve the desired herbicidal effect, and the time range can be affected by weather conditions in an unpredictable manner. It is known that specific combinations of different specific active herbicides can be enhanced in the sense of synergistic effects. The activity of the herbicidal component. In this way, the application rate of the herbicidal active compound required for controlling harmful plants can be reduced. Further, it is known that in some cases, a specific active herbicide and an organic active compound are jointly administered (some of them) It also has herbicidal activity) to achieve better crop plant compatibility. In these cases The active compound acts as a toxic agent or antagonist and is also referred to as a protective agent because it reduces or even prevents damage to crop plants. The active compounds A and B are mentioned in the opening paragraph. The preparation and its herbicidal activity are known from WO 99/55702, WO 2002/066471, WO 2007/077201, WO 2007/077247, PCT/EP2008/057329, PCT/EP2008/057330 and PCT/EP2009/059518. Active Compound A Or a mixture of B and other herbicides is described in PCT/EP2008/057330 and WO 2003/051122. SUMMARY OF THE INVENTION The object of the present invention is to provide herbicidal compositions which are highly resistant to undesirable harmful plants. It should have good compatibility with useful plants. In addition, the compositions of the invention should have a broad spectrum of activity. This can be achieved by the herbicidal active compositions of the invention comprising active ingredients a) and b) as defined in the opening paragraph. Purpose and other purposes. In particular, the present invention relates to a composition in the form of a herbicidal active crop protection composition comprising a herbicidally effective amount of a combination of active compounds comprising at least one active compound A and at least one active compound B, and at least one liquid and / or a solid carrier and / or one or more surfactants and, if desired, one or more other adjuvants conventionally used in crop protection compositions. The invention also relates to a composition in the form of a crop protection composition formulated as a component composition comprising a combination of active compounds comprising at least one active compound A and at least one active compound B, and at least one solid or liquid carrier And/or one or more surfactants and, if desired, one or more other adjuvants conventionally used in crop protection compositions. 145027.doc 201026687 The invention also relates to a composition in the form of a crop protection composition formulated as a 2-component composition comprising at least one active compound A, a body or a liquid carrier and/or one or more surfaces a first component of the active agent, and a second component comprising at least one active compound B, a solid or liquid carrier, and/or one or more surfactants, wherein the two components may additionally comprise a crop protection combination Other adjuvants for the substance. The composition of the invention comprising at least one active compound A and at least one active compound B has a herbicidal activity (synergy) which is better than the expected herbicidal activity of the individual compounds observed, that is, better resistant to harmful plant activity, or A wider spectrum of activity. Further, the compositions of the present invention comprising at least one active compound A and one active compound are extended over a range of time during which the desired herbicidal activity can be achieved. This makes it possible to use the composition of the present invention more flexibly than the individual compounds. The compositions of the present invention also have good herbicidal activity against harmful plants and good compatibility with useful plants. The compositions of the present invention have better herbicidal activity, i.e., resistance to harmful plants, based on the herbicidal activity observed for individual compounds. The invention relates in particular to a control in particular in the cultivation of crop plants, for example in the crops of the following crop plants, and in crops which are resistant to one or more herbicides or against insect attack due to genetic engineering or breeding. Methods of vegetation are not expected: AUium cepa, Ananas com〇sus, groundnuts (hyp〇gaea), Shi Xibai 145027.doc -12. 201026687

(Asparagus officinalis), Avena sativa, Beta vulgaris spec (altissima), Sugar vulgaris spec (rapa), Brassica napus var. napus, Steamed cabbage (Brassica napus var. napobrassica), Brassica rapa var. silvestris, Brassica oleracea, Brassica nigra, Camellia sinensis, Carthamus tinctorius, American thin shell pecan (Carya illinoinensis), lemon (Citrus limon), Citrus sinensis, Coffea arabica (Coffea canephora, Coffea liberica), Cucumis sativus , Cynodon dactylon, Daucus carota, Elaeis guineensis, Fragaria vesca, Glycine max, Gossypium hirsutum (Gossypium arboreum, grass) Gossypium herbaceum, Gossypium vitifolium, Helianthus annuus, Hevea brasili Ensis), Hordeum vulgare, Humulus lupulus 'Ipomoea batatas, Juglans regia, Le. ns culinaris, Linum usitatissimum, Lycopersicon lycopersicum, Malus spec., Manihot esculenta, Medicago sativa, Musa spec., Nicotiana tabacum (N. rustica), oil withdrawal ( Olea europaea), upland rice (Oryza sativa), white bean (Phaseolus lunatus), kidney bean (Phaseolus vulgaris), Norwegian spruce (Picea abies), Pinus spec. (Pinus spec.), Pistachio 145027.doc -13 - 201026687 vera), Pisum sativum, Prunus avium, Prunus persica, Pyrus communis, Prunus armeniaca, Prunus cerasus, Prunus dulcis and prunus domestica, Ribes sylvestre, Ricinus communis, sugarcane (Saccharum officinarum), rye (Secale cereale), white (Sinapis alba), Solanum tuberosum, Sorghum bicolor (s. vulgare), Theobroma cacao, Red car, Trifolium pratense, Wheat (Triticum aestivum), black Triticale, Triticum durum, Viciafaba, Vitis vinifera, Zea mays, especially cereals, corn, soybeans, glutinous rice, canola, cotton, potatoes, peanuts or perennial Crops of crops. The invention also relates to a method of drying or shedding plants. In the most recently mentioned process, the order in which the herbicidal active compounds of components A) and B) are combined or separately formulated and administered and administered in the case of separate administration is not critical. In a preferred embodiment, the designation of the compound of formula I has the following meanings, which themselves and in combination with each other, are specific aspects of the compound of formula I: In one aspect of the mixture of the invention, in formula I, the code A is a stupid base. These compounds correspond to formula 1.1

145027.doc -14- 201026687 wherein the index m is 0 or an integer from 1 to 4. In another aspect, 'in Formula I, the code tethered" is pyridine. These compounds correspond to formula 1.2,

Wherein V, W, X, γ are N, CH or C_Rb, wherein the groups are independently N to each other. The individualized samples of Equation 1.2 are I.2a, I.2b, I.2c, 1.2d and I.2e. In these formulas, the groups Rbi, Rb2, Rb3 and Rb4 in each case correspond to the group Rba preferably having the meanings mentioned below.

R9 , 10 l_2a In the formula 1.2a: R is preferably H, halogen, alkyl, halogenated fluorenyl ‘preferably jj, ci, CF3 ❿ or CH3;

Rb3 is preferably hydrazine, halogen, ch3 or och3, particularly preferably h, f, ch3 or och3; Rb4 is preferably hydrazine, halogen, CH3 or OCH3, more preferably η, F, cm, Br, CH3 or OCH3.

In Equation 1.2b: 145027.doc •15· 201026687

Rbl is better than Η;

Rb3 is preferably halogen, CH3 or OCH3, in particular F, CH3 or OCH3; Rb4 is preferably hydrazine, halogen, CH3 or OCH3, more preferably hydrazine, F, CM, Br, ch3 or 〇ch3.

In formula I.2c:

Rbl is better

Rb2 is preferably hydrazine, halogen, halogenated methyl, especially preferably hydrazine, Cl, CF3;

Rb4 is preferably hydrazine, halogen, CH3 or OCH3, and more preferably hydrazine, F, C, Br, ch3 or 〇ch3.

In Equation 1.2d:

Rbl is better,

Rb2 is preferably a hydrazine, a halogen, a halogenated methyl group, and more preferably a hydrazine, a c-CF3;

Rb3 is preferably halogen, CH3 or OCH3, in particular F, CH3 or 〇CH3. In another aspect, in Formula I, the code A is a pyrazole. These compounds correspond to formula 1.3, R6wR5 〇

145027.doc -16, 201026687 wherein Ra is attached to the ortho position of the A attachment point (carbon or nitrogen atom in A) and the index m is 0, 1 or 2. The individualized pattern of the formula 1.3 is I.3a, l.3b, ! 3e, 1.3d and I.3e° In these formulas, the radicals Rb1 and Rb2 in each case correspond to a group... and preferably have the meanings mentioned below.

In Equation 1.3a:

Rbl is preferably a fluorene, an alkyl group or a halogenated fluorenyl group, and more preferably η, CH3 or CF3; and Rb2 is preferably a fluorene, a halogen, an alkyl group or a halogenated methyl group, particularly preferably ch3 or CF3.

In formulas I.3b and I.3c:

Rbl is preferably a hydrazine, an alkyl group, a halogenated methyl group, and more preferably η or CH3;

Rb2 is preferably a hydrazine, a halogen, an alkyl group, a halogenated methyl group, and more preferably a ch3 or CF3.

In Equation 1.3d:

Rbl is preferably H, an alkyl group, a halogenated fluorenyl group, particularly preferably h, cf3 or CH3; 145027.doc • 17- 201026687

Rb2 is preferably hydrazine, halogen, CN, CH3 or OCH3, more preferably H, C, Br, I, CN, CH3 or OCH3.

In formula I.3e:

Rbl is preferably hydrazine, halogen, CN, N02, alkyl or alkoxy, especially preferably η, Cb Br, I, CN, Ν〇2, CH3 or OCH3;

Rb2 is preferably hydrazine, halogen, CN, N〇2, alkyl or alkoxy, more preferably η, Cb Br, I, CN, Ν〇2, CH3 or OCH3. In another aspect, in Formula I, the code A is an sigh. These compounds correspond to the formula 44, where Ra is attached to the ortho position of the attachment point of A and refers to i or 2. R® R5 〇

The individualized samples of Equation 1.4 are of the formulae I.4a, 1.4b and I.4c. In these formulas, the radicals Rb1 and Rb2 correspond in each case to the radical Rb and preferably have the meanings mentioned below.

In Equation 1.4a:

Rbl is preferably H'CN, N02, alkyl or alkoxy, especially preferably H; 145027.doc -18- 201026687

Rb2 is preferably hydrazine, CN, N02, alkyl or alkoxy, more preferably η.

In the formula 1.4b: preferably H, halogen, CN, N02, alkyl or alkoxy, more preferably H, Cl, Br, I, CN, N02, CH3 or 0CH3;

Rb2 is preferably hydrazine, halogen, CN, N 〇 2, alkyl or alkoxy, and particularly preferably η.

In the formula I.4c: R is preferably hydrazine, halogen, CN, N 〇 2, alkyl or alkoxy, more preferably η, Cl, Br, I, CN, Ν〇2, CH3 or OCH3;

Rb is preferably H, halogen, CN, N02, alkyl or alkoxy, more preferably η. # In a preferred aspect of one of the compounds of formula 1, the index m is 0 or 1.

Ra is preferably CN, N02, CVC4-alkyl, Z-C3-C6-cycloalkyl, q-cv halodecyl, CVCV alkoxy, CVC4-haloalkoxy or 〇-Z-C3-C6- Cycloalkyl. R1 is preferably hydrazine, CH3, (5, n-propyl, allyl, n-butyl, preferably CH3. In another aspect of the compound of formula I, R1 is alkyl, in particular A mercapto group which may be substituted with a group selected from the group consisting of CN, N02, dentate, Cl_c4_alkoxy, c(=〇)_Rai, C3_C6-cycloalkyl, and optionally substituted stupid groups. Doc 10 201026687 In another aspect, in the formula I the 'groups R2 and R3 are independently of one another alkyl, in particular C--C4_alkyl, especially preferably CH3, C2H5 and n-propyl. In another aspect, in Formula I, the groups R4 to R10 are hydrogen. In another preferred embodiment, the linkages form a bond between the formulas 'A4 and R5. These compounds correspond to Formula IA.

In a particularly preferred aspect, compound I.A has the preferred characteristics of formulas 1.1 to 1.4. Because of this, it is called Formula I.1A to I.4cA. Another embodiment of the compounds of formula I pertains to those of them and to Han 5 series.

These compounds correspond to formula I.B

R9 10 〇 R7, r8

I.B

In a particularly good way, the compound! · Β has the preferred characteristics of the formula ^ to. Therefore, it is called Ι·1Β to I.4cB. Preferred among the formula compounds in which the R9 group is different from the group of H are those in which R9 is located between the attachment points and is preferably a auxin, specifically. In another, but preferred embodiment, the R9 system is Η. In another embodiment, the ruler 9 and the ruler are 〇.

R10 is preferably a ruthenium or a ruthenium such as C1 or F, in particular F. In the aspect, 'Rl° is in the ortho or para position. More preferably, Ri is H.

In the first preferred embodiment of the invention, the group attached to the carbon atom V 145027.doc • 20- 201026687 dentate (e.g., α or F), or CN, N〇2, Ci_C4_ alkyl Ci_C4. alkoxy, c丨-c4-haloalkoxy, specifically CF3, 〇CH3, 〇C2H5, oc3h7, ocf3, 〇chf2. In another preferred embodiment of the invention, a caliper 3 or a hydrazine, a Ci-CV alkyl group or a CVCV haloalkyl group, specifically ch3, c2h5, chf2 or cf3, is attached via a nitrogen atom. In the formula I and in particular in the sub-formula derived therefrom, the radicals R1, R2, R3, R6, R7, R8, R9, rW, Ra& Rb independently of each other (but preferably in combination) have the following meanings: R1 is H, CH3' C2H5, CH2CH2CH3, CH2CH2CH2CH3, 〇CH3, 〇C2H5, OCH2CH2CH3, NH2, S02CH3, CH2C02CVC4-alkyl, CH2CeCH, CH2CH=CH2, CH2CH2CeCCH3, CH2C(CH3)=CH2, CH2CH=CHCH3, C3- C4-ii alkenyl, CH2-c-C3H5, optionally substituted benzyl, CN_, 〇CH3-, ci-, F-substituted Ci-CV alkyl, specifically CH3; R2 is CH3; R3 ^-0: 4-alkyl, OH, CH2OH, NH2, C(0)Rn, wherein Rii is 匸丨-匕-alkoxy, specifically ch3 or C2H5; R6 is Η, CH3 or C2H5, preferably R7, R8 is H; R9 is H, halogen, OH, CVCU-alkyl, CVCV alkylcarbonyloxy, especially hydrazine or 3-halo, OH, CH3, OCOCH3, especially hydrazine or 3-F R10 system or F;

Ra when attached via nitrogen: CN, C^CV alkyl, CVCV alkyl thiol, 145027.doc .21 - 201026687

Ci-(V thioalkyl, NRRAB, haloalkyl, haloalkoxy, specifically cn, CN, CH3, 〇CH3, oc2H5, SCH3 and NRaRB, wherein RA and rb together with the nitrogen atom form a 6-membered saturated impurity a ring, for example, N-morpholinyl; and if Ra is attached via carbon, Ra may additionally be a element (specifically C1 and F), and n〇2;

Rb is a core I, CM, Br, CH3, 〇ch3, halomethyl, in particular, the position of the terminal group Rb, which is further referred to above for RbI & Rb2. The compound of formula I has a palmitic center at the carbon atom bearing the group R3. A preferred embodiment of the invention relates to the pure enantiomer of formula I-S as indicated below, a r6r5 ο

-S

Or?Ar8 R wherein the code has one of the meanings indicated above, specifically one of the meanings indicated as preferred or as preferred, and is also related to the enantiomeric excess having the formula A mixture of enantiomers of the enantiomers. The preferred compounds correspond to those of the formulae I.A1 and I.B1, -

Wherein V is CH or N and V and Ri have the meanings specifically mentioned for the formula or its subformulae and in particular the preferred meaning. 145027.doc -22· 201026687 Specifically, in view of its use, it is preferred to formulate the compounds of formula i in the following table, which correspond to formulas I.A1 and I.B1, respectively. Further, the groups mentioned in the table which are suitable as the substituents themselves (independent of the combinations in which the groups are mentioned) are particularly preferred for the substituents.

Table A No. V Ra R1 A-1 I.A1 CH N〇2 H A-2 I.A1 CH N〇2 ch3 A-3 I.A1 CH N〇2 CH2CH3 A-4 I.A1 CH N〇2 Ch2ch2ch3 A-5 I.A1 CH N〇2 ch2ch=ch2 A-6 I.A1 CH N〇2 ch2c=ch A-7 I.A1 CH N〇2 ch2cn A-8 I.A1 CH N〇2 ch2och3 A -9 I.A1 CH CN H A-10 I.A1 CH CN ch3 A-11 I.A1 CH CN ch2ch3 A-12 I.A1 CH CN CH2CH2CH3 A-13 I.A1 CH CN ch2ch=ch2 A-14 I .A1 CH CN ch2c=ch A-15 I.A1 CH CN ch2cn A-16 I.A1 CH CN CH20CH3 A-17 I.A1 CH cf3 H A-18 I.A1 CH cf3 ch3 A-19 I.A1 CH Cf3 CH2CH3 A-20 I.A1 CH cf3 ch2ch2ch3 A-21 I.A1 CH cf3 ch2ch=ch2 A-22 I.A1 CH cf3 ch2c=ch A-23 I.A1 CH cf3 ch2cn A-24 I.A1 CH cf3 CH20CH3 A-25 I.A1 CH och3 H A-26 I.A1 CH OCH3 ch3 A-27 I.A1 CH OCH3 CH2CH3 A-28 I.A1 CH OCH3 ch2ch2ch3 A-29 I.A1 CH OCH3 ch2ch=ch2 A- 30 I.A1 CH OCH3 ch2c=ch A-31 I.A1 CH OCH3 ch2cn A-32 I.A1 CH OCH3 ch2och3 145027.doc •23- 201026687

No. V Ra R1 A-33 I.A1 CH OCH2CH3 H A-34 I.A1 CH OCH2CH3 ch3 A-35 I.A1 CH OCH2CH3 ch2ch3 A-36 I.A1 CH OCH2CH3 ch2ch2ch3 A-37 I.A1 CH OCH2CH3 ch2ch =ch2 A-38 I.A1 CH OCH2CH3 ch2c=ch A-39 I.A1 CH OCH2CH3 ch2cn A-40 I.A1 CH OCH2CH3 CH20CH3 A-41 IA] CH c(=o)ch3 H A-42 I.A1 CH c(=o)ch3 ch3 A-43 I.A1 CH c(=o)ch3 CH2CH3 A-44 I.A1 CH C(=0)CH3 ch2ch2ch3 A-45 I.A1 CH c(=〇)ch3 ch2ch =ch2 A-46 I.A1 CH C(=0)CH3 ch2c=ch A-47 I.A1 CH c(=o)ch3 ch2cn A-48 I.A1 CH c(=o)ch3 ch2och3 A-49 I .A1 NN〇2 H A-50 I.A1 NN〇2 ch3 A-51 I.A1 NN〇2 CH2CH3 A-52 I.A1 NN〇2 CH2CH2CH3 A-53 I.A1 NN〇2 ch2ch=ch2 A- 54 I.A1 NN〇2 ch2c=ch A-55 I.A1 NN〇2 ch2cn A-56 I.A1 NN〇2 ch2och3 A-57 I.A1 N CN H A-58 I.A1 N CN ch3 A- 59 I.A1 N CN ch2ch3 A-60 I.A1 N CN ch2ch2ch3 A-61 I.A1 N CN ch2ch=ch2 A-62 I.A1 N CN CH2CeCH A-63 I.A1 N CN ch2cn A-64 I. A1 N CN CH20CH3 A-65 I.A1 N cf3 H A-66 I.A1 N cf3 ch3 A-67 I.A1 N cf3 CH2CH3 A-68 I.A1 N cf3 ch2ch2ch3 A-69 I.A1 N cf3 ch2ch= Ch2 A-70 I.A1 N cf3 CH2C Tri CH A-71 I.A1 N cf3 ch2cn A-72 I.A1 N cf3 ch2och3 A-73 I.A1 N och3 H 145027.doc -24- 201026687 No. y Ra R1 A-74 I.A1 N 〇ch3 ch3 A-75 I.A1 N och3 CH2CH3 A-76 I.A1 N och3 ch2ch2ch3 A-77 I.A1 N och3 ch2ch=ch2 A-78 I.A1 N 〇ch3 CH2C III CH A-79 I.A1 N 〇CH3 ch2cn A-80 I.A1 N 〇ch3 ch2och3 A-81 I.A1 N OCH2CH3 H A-82 I.A1 N OCH2CH3 ch3 A-83 I.A1 N OCH2CH3 ch2ch3 A- 84 I.A1 N och2ch3 CH2CH2CH3 A-85 I.A1 N och2ch3 ch2ch=ch2 A-86 I.A1 N och2ch3 CH2C Tri-CH A-87 I.A1 N och2ch3 ch2cn A-88 I.A1 N OCH2CH3 ch2och3 A-89 I.A1 NC(=0)CH3 H A-90 I.A1 N c(=o)ch3 ch3 A-91 I.A1 NC(=0)CH3 CH2CH3 A-92 I.A1 N c(=o)ch3 Ch2ch2ch3 A-93 I.A1 N c(=o)ch3 ch2ch=ch2 A-94 I.A1 N c(=o)ch3 ch2och A-95 I.A1 NC(=0)CH3 ch2cn A-96 I.A1 N c(=o)ch3 ch2och3 A-97 I.B1 CH N〇2 H A-98 I.B1 CH N〇2 ch3 A-99 I.B1 CH N〇2 CH2CH3 A-100 I.B1 CH N〇 2 ch2ch2ch3 A-101 I.B1 CH N〇2 ch2ch=ch2 A-102 I.B1 CH N〇2 ch2c=ch A-103 I.B1 CH N〇2 ch2cn A-104 I.B1 CH N 2 ch2och3 A-105 I.B1 CH CN H A-106 I.B1 CH CN ch3 A-107 I.B1 CH CN CH2CH3 A-108 I.B1 CH CN ch2ch2ch3 A-109 I.B1 CH CN ch2ch=ch2 A -110 I.B1 CH CN ch2c=cu A-lll I.B1 CH CN ch2cn A-112 I.B1 CH CN CH20CH3 A-113 I.B1 CH cf3 H A-114 I.B1 CH cf3 ch3 145027.doc - 25- 201026687 No. V Ra R1 A-115 I.B1 CH cf3 ch2ch3 A-116 I.B1 CH cf3 CH2CH2CH3 A-117 I.B1 CH cf3 ch2ch=ch2 A-118 I.B1 CH cf3 ch2och A-119 I .B1 CH cf3 ch2cn A-120 I.B1 CH cf3 ch2och3 A-121 I.B1 CH och3 H A-122 I.B1 CH och3 ch3 A-123 I.B1 CH och3 CH2CH3 A-124 I.B1 CH och3 ch2ch2ch3 A-125 I.B1 CH och3 ch2ch=ch2 A-126 I.B1 CH och3 ch2c=ch A-127 I.B1 CH och3 ch2cn A-128 I.B1 CH och3 CH20CH3 A-129 I.B1 CH OCH2CH3 H A -130 I.B1 CH OCH2CH3 ch3 A-131 I.B1 CH OCH2CH3 CH2CH3 A-132 I.B1 CH OCH2CH3 ch2ch2ch3 A-133 I.B1 CH OCH2CH3 ch2ch=ch2 A-134 I.B1 CH OCH2CH3 ch2c=ch A- 135 I.B1 CH OCH2CH3 ch2cn A-136 I.B1 CH OCH2CH3 ch2och3 A-137 I.B1 CH C(=0)CH3 H A-138 I.B1 CH C(=0)CH3 ch3 A-139 I.B1 CH c(=o)ch3 CH2CH3 A-140 I.B1 CH c(=〇)ch3 CH2CH2CH3 A-141 I.B1 CH c(=o)ch3 ch2ch=ch2 A-142 I.B1 CH C(=0)CH3 ch2och A-143 I.B1 CH C(=0)CH3 ch2cn A-144 I.BJ CH c(=〇)ch3 ch2och3 A-145 I.B1 NN〇2 H A-146 I.B1 NN〇2 ch3 A-147 I.B1 NN〇 2 ch2ch3 A-148 I.B1 NN〇2 ch2ch2ch3 A-149 I.B1 NN〇2 ch2ch=ch2 A-150 I.B1 NN〇2 ch2c^ch A-151 I.B1 NN〇2 ch2cn A-152 I .B1 NN〇2 ch2och3 A-153 I.B1 N CN H A-154 I.B1 N CN ch3 A-155 I.B1 N CN CH2CH3 145027.doc -26- 201026687 No. V Ra R1 A-156 I. B1 N CN CH2CH2CH3 A-157 I.B1 N CN ch2ch=ch2 A-158 I.B1 N CN ch2c=ch A-159 I.B1 N CN ch2cn A-160 I.B1 N CN CH20CH3 A-161 I.B1 N cf3 H A-162 I.B1 N cf3 ch3 A-163 I.B1 N cf3 ch2ch3 A-164 I.B1 N cf3 CH2CH2CH3 A-165 I.B1 N cf3 ch2ch=ch2 A-166 I.B1 N cf3 ch2c =ch A-167 I.B1 N cf3 ch2cn A-168 IB* N cf3 ch2och3 A-169 I.B1 N och3 H A-170 I.B1 N och3 ch3 A-171 I.B1 N och3 ch2ch3 A-172 I .B1 N och3 CH2CH2CH3 A-173 I.B1 N och3 ch2ch=ch2 A-174 I.B1 N och3 ch2c=ch A-175 I.B1 N och3 ch2cn A-17 6 I.B1 N och3 ch2och3 A-177 I.B1 N OCH2CH3 H A-178 I.B1 N OCH2CH3 ch3 A-179 I.B1 N OCH2CH3 CH2CH3 A-180 I.B1 N OCH2CH3 CH2CH2CH3 A-181 I.B1 N OCH2CH3 ch2ch=ch2 A-182 I.B1 N OCH2CH3 ch2c=ch A-183 I.B1 N OCH2CH3 ch2cn A-184 I.B1 N OCH2CH3 CH20CH3 A-185 I.B1 N c(=o)ch3 H A-186 I.B1 N c(=o)ch3 ch3 A-187 I.B1 NC(=0)CH3 ch2ch3 A-188 I.B1 N c(=o)ch3 CH2CH2CH3 A-189 I.B1 NC(=0)CH3 Ch2ch=ch2 A-190 I.B1 N c(=〇)ch3 CH2C Triple CH A-191 I.B1 NC(=0)CH3 ch2cn A-192 I.B1 NC(=0)CH3 CH20CH3 A-193 I. A1 CH OCF3 H A-194 I.A1 CH OCF3 CH3 A-195 I.A1 CH OCF3 CH2CH3 A-196 I.A1 CH OCF3 CH2CH2CH3 145027.doc -27- 201026687 No. V Ra R1 A-197 I.A1 CH OCF3 CH2CH=CH2 A-198 I.A1 CH OCF3 CH2C Tri-CH A-199 I.A1 CH OCF3 CH2CN A-200 I.A1 CH OCF3 CH20CH3 A-201 I.A1 N OCF3 H A-202 I.A1 N OCF3 CH3 A-203 I.A1 N OCF3 CH2CH3 A-204 I.A1 N OCF3 CH2CH2CH3 A-205 I.A1 N OCF3 CH2CH=CH2 A-206 I.A1 N OCF3 CH2C=CH A-207 I.A1 N OCF3 CH2CN A-208 I.A1 N OCF3 CH20CH3 A-209 I.A1 CH OCHF2 H A-210 I .A1 CH OCHF2 CH3 A-211 I.A1 CH OCHF2 CH2CH3 A-212 I.A1 CH OCHF2 CH2CH2CH3 A-213 I.A1 CH OCHF2 CH2CH=CH2 A-214 I.A1 CH OCHF2 CH2C=CH A-215 I. A1 CH OCHF2 CH2CN A-216 I.A1 CH OCHF2 CH20CH3 A-217 I.A1 N OCHF2 H A-218 I.A1 N OCHF2 CH3 A-219 I.A1 N OCHF2 CH2CH3 A-220 I.A1 N OCHF2 CH2CH2CH3 A -221 I.A1 N OCHF2 CH2CH=CH2 A-222 I.A1 N OCHF2 CH2C Tri-CH A-223 I.A1 N OCHF2 CH2CN A-224 I.A1 N OCHF2 CH20CH3 A-225 I.B1 CH OCF3 H A- 226 I.B1 CH OCF3 CH3 A-227 I.B1 CH OCF3 CH2CH3 A-228 I.B1 CH OCF3 CH2CH2CH3 A-229 I.B1 CH OCF3 CH2CH=CH2 A-230 I.B1 CH OCF3 CH2C=CH A-231 I.B1 CH OCF3 CH2CN A-232 I.B1 CH OCF3 CH20CH3 A-233 I.B1 N OCF3 H A-234 I.B1 N OCF3 CH3 A-235 I.B1 N OCF3 CH2CH3 A-236 I.B1 N OCF3 CH2CH2CH3 A-237 I.B1 N OCF3 CH2CH=CH2 145027.doc • 28 - 201026687 No. V Ra R1 A-238 I.B1 N OCF3 CH2C=CH A-239 I.B1 N OCF3 CH2CN A-240 I.B1 O O O - O - - - - - 1 CH OCHF2 CH2CH=CH2 A-246 I.B1 CH OCHF2 CH2CCH A-247 I.B1 CH OCHF2 CH2CN A-248 I.B1 CH OCHF2 CH20CH3 A-249 I.B1 N OCHF2 Η A-250 I.B1 N OCHF2 CH3 A-251 I.B1 N OCHF2 CH2CH3 A-252 I.B1 N OCHF2 CH2CH2CH3 A-253 I.B1 N OCHF2 CH2CH=CH2 A-254 I.B1 N OCHF2 CH2C=CH A-255 I.B1 N OCHF2 CH2CN A-256 I.B1 N OCHF2 CH20CH3 In a particularly preferred embodiment, the active compound A is selected from the group consisting of compounds A-2, A-8, A-9, A-10, A-11, A-50, A-58. A-60, A-64, A-82 and A-180 ° In a further preferred embodiment, the active compound A is selected from the group consisting of the compounds A-57, A-90 and Α·218. In a preferred embodiment, the code of the active compound oxime has the following meanings, both in itself and in combination with each other, in a particular aspect of the compound of formula II, III and IV: In a preferred embodiment of the compound of formula II, R21 Is CH3. In a preferred embodiment of the compound of formula III, R21 is halogen, in particular F. In another preferred embodiment of the compound of formula II, R22 is i, in particular C1. In another preferred embodiment of the compounds of formula II and III, R23 is C3-C6-alkyne 145027.doc -29- 201026687 or c3-c6-cyclone-cvcv alkyl, in particular propyl or cyclic Propylmethyl. In another preferred embodiment of the compound of Formula 11, R24 is CHF2. In another preferred embodiment of the compound of formula II, r25 is a dentate, in particular Br. R26 is a CVC4-alkane in another preferred embodiment of the compounds of formula II and III, specifically CH3. In another preferred embodiment of the compounds of formula II and III, R27 is a system. In a preferred embodiment of the compound of formula IV, is Ci_c6 alkyl, ◎ CVC6-dentoalkyl, or specifically C3_C6_cycloalkyl-Ci_c^alkyl. In Formula IV, X preferably has a value of 1. R is preferably a hospital base and is preferably located at the 6-position. The index y preferably has a value of 3. The groups R43 are different from each other and are preferably located at the 2, 3, 5 position. The group R43 is halogen or alkyl and is preferably located at the 3 or 5 position. The group R43 is preferably COOR44 and is preferably located at the 2_ position. R44 is preferably an alkyl group.较佳 A preferred aspect of the invention relates to a combination of a compound of formula I (particularly one of compounds A-1 to A-256) and a compound of formula π corresponding to formula IL1

Wherein the code has the meaning mentioned above for the formula „, specifically 145027.doc • 30· 201026687 meaning 'excellent and structural formula (Bq) 7_(4_bromo-5-difluoromethoxy)丨_Methyl_1H-pyrazole_3_yl)·4,6·dichloro-2-ethylbenzoxazole or 4-gas-7-(4-gas- of formula (B-2) Combination of 5-difluoromethoxy 4 _methyl 1 Η-pyrazol-3-yl)-2-ethyl-6-fluorobenzoxazole:

Another preferred aspect of the invention is a combination of a compound of the formula (specifically one of the compounds A-1 to A-256) and a compound of the formula π corresponding to the formula IL2.

Wherein the code has the meanings mentioned above for formula II, in particular the preferred ® meaning 'preferably' and 3-(4- gas-2-cyclopropyl fluorenyl-6-fluoride of formula (B-3) Stupid and °°°-7-yl)-1-mercapto-6-trifluoromethyl-1H-pyrimidine-2,4-dione or 3-(7-) with the formula (B-4) a combination of gas-5-fluoro-2-trifluoromethyl-3H-benzomole, 4 yl)-1,6-monomethyl-1H-penetration-2,4-di

Another preferred aspect of the invention is a combination of a compound of formula I (specifically, one of eight 145027.doc-31-201026687, one of A-1 to eight-144) and a compound of formula 111 corresponding to formula 1111.

R26 wherein the code has the meaning mentioned above for the formula m, in particular the preferred meaning 'preferably and the structural formula (B_5) 3_(7-fluoro_3_sideoxy_4_prop-2-ynyl) _ 3,4-Dihydro-2H- benzo[1,4]oxazin-6-yl)-15-diindenyl-6-thio-[13 5]-nitrogen-heterocyclohexane-2 4 - a combination of two.

Another preferred aspect of the present invention relates to a compound of the formula j (specifically, one of the compounds A-1 to A-144) and a compound of the formula 1V, particularly preferably a 6-gas-2 of the formula (Β_6) a combination of -{[2-(cyclopropylmethyl-aminocarbamimidyl)-6-methylpyridine-3-carbonyl]amino}-3-mercaptobenzoic acid oxime;

The particularly preferred binary combinations of the active compounds Α and Β are listed in Table β: 145027.doc -32- 201026687

Table B No. Active Compound A Active Compound B B-1 A-1 B-1 B-2 A-1 B-2 B-3 A-1 B-3 B-4 A-1 B-4 B-5 A- 1 B-5 B-6 A-1 B-6 B-7 A-7 B-1 B-8 A-7 B-2 B-9 A-7 B-3 B-10 A-7 B-4 B -11 A-7 B-5 B-12 A-7 B-6 B-13 A-8 B-1 B-14 A-8 B-2 — B-15 A-8 B-3 B-16 A- 8 B-4 B-17 A-8 B-5 B-18 A-8 B-6 B-19 A-9 B-1 B-20 A-9 B-2 B-21 A-9 B-3 B -22 A-9 B-4 B-23 A-9 B-5 B-24 A^9 B-6 B-25 A-43 B-1 B-26 Ϊ43 B-27 Ϊ43 B-3 B-28 A ^3 B-4 B-29 A-43 B-5 B-30 A^43~~ Γ B-6 B-31 A^5〇B-1 No. Active Compound A Active Compound B-32 A-50 B- 2 B-33 A-50 B-3 B-34 A-50 B-4 B-35 A-50 B-5 B-36 A-50 B-6 B-37 A-52 B-1 B-3 8 A-52 B-2 B-39 A-52 B-3 B-40 A-52 B-4 B-41 A-52 B-5 B-42 A-52 B-6 B-43 A-56 B- 1 B-44 A-56 B-2 B-45 A-56 B-3 B-46 A-56 B-4 B-47 A-56 B-5 B-48 A-56 B-6 B-49 A -71 B-1 B-50 A-71 B-2 B-51 A-71 B-3 B-52 A-71 B-4 B-53 A-71 B-5 B-54 A-71 B-6 B-55 "A-157 B-1 B-56 A-157 B-2 B-57 A-157 B-3 B-58 A-157 B-4 B-59 A-157 B-5 B-60 A -157 B-6 The binary combination of the present invention can be The case includes another active ingredient. The ternary combination may comprise at least one of the active ingredients c) and preferably a herbicide C and/or at least one and preferably a protective agent D. In one aspect The composition of the invention comprises at least one of the third component c) and preferably a herbicide selected from the group eimel 5) below. In the case of another ill, the 'third component ^) is at least one and preferably protected 145027.doc • 33- 201026687 agent D. In another aspect, the third component c) is selected from the group consisting of herbicides of groups cl) to cl5) and the fourth component is at least one and preferably one protectant D. Among the ternary compositions of the present invention, preferred are those which comprise at least one herbicide C selected from the group consisting of photosynthesis inhibitors, VLCFA inhibitors and pigment-inhibiting herbicides. Examples of herbicides c which may be used in combination with the binary mixtures of the invention are as follows: cl) from the following groups of lipid biosynthesis inhibitors: and alloxydim, and chlorfenapyr, butroxydim , clethodim, clodinafop, cl〇dinafop-propargyl, cycloxydim, cyhalofop, cyhalofop-butyl , diclofop, diclofop-methyl, fenoxaprop, fenoxaprop-ethyl, fenoxaprop-ethyl Haloxyfop-P, refined ethyl, and fenoxaprop-P-ethyl. Fluazifop, butyl D, fluazifop-butyl, fluazifop-P, butyl, fluazifop-P- Butyl), fluorine ° haloxyfop, fluoro 0 to haloxyfop-methyl, sulphur D haloxyfop-P, fine H 0 than methicillin, ° σ 醯 醯 grass Amine (metamifop), ° oxa vinegar (pinoxaden), profoxydim, propaquizafop, quizalofop, quizalofop-ethyl, 喧禾糠Vinegar (quizalofop-tefuryl), quizalofop-P, quizalofop-P-ethyl, 喧 禾 145027.doc -34- 201026687 ❹

Quizalofop-P-tefuryl, sethoxydim, tepraloxydim, tralkoxydim, benfuresate, butamate Cycloactite, dalapon, dimepiperate, EPTC, esprocarb, ethofumesate, flupropanate, grasses ), orbencarb, pebulate, prosulfocarb, TCA, chlorpyrifos, tiocarbazil, triallate, and vernolate; C2) Groups from the following ALS inhibitors: amidosulfuron, azimsulfuron, bensulfuron, bensulfuron-methyl, bis-oxalate (bispyribac), bismuth sodium, chlorimuron, chlorimuron-ethyl, chlorsulfuron, cinosulfuron, cloransulam ), cloransulam-methyl, cyclosulfamuron, double Diclosulam, ethametsulfuron' ethametsulfuron-methyl, ethoxysulfuron, flazasulfuron, florasulam , flucarbazone, fluoroketone sulphonate, flucetosulfuron, flumetsulam, flupyrsulfuron, flufensulfuron-purine Base-sodium, methotrexate, halosulfuron, halosulfuron-methyl, imazamethabenz, imazamethabenz-methyl , methoxymethasone (imazamox), thiol β rice grass (imazapic), yam 145027.doc -35- 201026687 (imazapyr), ° m β 喧 喧 acid (imazaquin), taste Acid (imazethapyr), imazosulfuron, iodosulfuron, moth-methyl-nano, mesosulfuron, metosulam, resuscitation (metsulfuron), metsulfuron-methyl, end

Niosulfuron, orthosulfamuron, oxasulfuron, penoxsulam, primisulfuron, primasulfuron -methyl), propoxycarbazone, propofol sodium, prosulfuron, propyrisulfuron, pyrazosulfuron, pyrazosulfuron- Ethyl), pyribenzoxim, pyrimisulfan, pyrifalid, pyriminobac, pyriminobac-methyl, sulphur (pyrithiobac), sodium sulphate, pyroxsulam, rim 0^ rim sulfur on, sulfometuron, sulfeneturon-methyl , sulfosulfuron, thiencarbazone, thiencarbazone-methyl, thiophene. Thifensulfuron, thifensulfuron-methyl, triasulfuron, tribenuron, tribenuron-methyl, tri-gas TriHoxysulfuron, triflusulfuron, triflusulfuron-methyl, and tritosulfuron; c3) from the following group of photosynthesis inhibitors: ametryn ), amicarbazone, atrazine, bentazone, bentazon sodium, bromcil, 145027.doc -36- 201026687 bromofenoxim ), bromoxynil and its salts and singly, chlorobromuron, chloridazone, chlorotoluron, chloroxuron, cyanazine, beet Desmedipham, desmetryn, dimefuron, dimethametryn, diquat, diquat, dibromide, diuron , fluometuron, hexazinone, benzene (ioxynil) and its salts and vinegar, isoproturon, isouron, karbutilate, lenacil, linuron, benzopyrone ( Metamitron), metabenzthiazuron, metab.enzuron, metoxuron, °qin 0) 3⁄4 (metribuzin), green ur (monolinuron), 草不隆 ( Neburon), paraquat, paraquat-dichloride, paraquat-dimethylsulfate, pentanochlor, phenmedipham, phenmedipham-ethyl, extinguish Prometon, prometryn, propanil, propazine, pyridafol, pyridate, siduron, simazine ), simetryn, tebuthiuron, terbacil, terbumeton, terbuthylazine, terbutryn, sulphur (thidiazuron) and trietazine; c4) from protoporphyrinogen IX oxidase inhibitor : acifluorfen, axifenfen, azafenidin, bencarbazone, benzfendizone, bifenox, chlorfenapyr ( Butafenacil), carfentrazone, 145027.doc -37- 201026687 car 酿 1 草 car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car car Fluazolate, flufenpyr, flufenpyr-ethyl, flumiclorac, flumethacin-pentyl, flumioxazin, B Fluorine fenglycofen, fluoroglycofen-ethyl, fluthiacet, fluthiacet-methyl, fomesafen, halo Ether (halosafen), lactofen, oxadiargyl, oxadiazon, oxyfluorfen, pentoxazone, gas. Profluazol, pyraclonil, beta il (pyraflufen), pyraflufen-ethyl, biting grass thief, sulfentrazone, thiadiazole Thidiazimin, 2-gas·5-[3,6-dihydro-3-methyl-2,6-di-oxo-4-(trifluoromethyl)-1(2//)-pyrimidine 4-fluoro-N-[(isopropyl)decylamine sulfonyl]benzamide (Dl; CAS 372137-3 5-4), [3-[2-chloro-4-fluoro- 5-(l-Mercapto-6-trifluoromethyl-2,4-di-oxy-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2· »bipyridine Ethyloxy]ethyl acetate (D-2; CAS 353292-31-6), Ν-ethyl-3-(2,6-dioxa-4-trifluoromethylphenoxy)-5- Base-1//-pyrazole-1-carboxamide (D-3; CAS 452098-92-9), N-tetrahydrofuranyl-3-(2,6-di-gas-4-trifluoromethylphenoxy 5-)-5-methyl-1//-°bazol-1-decylamine (D-4; CAS 915396-43-9), N-ethyl-3-(2-chloro-6-fluoro- 4-trifluoromethylphenoxy)-5-methyl-1 ugly-pyrazole-1-decylamine (D-5; CAS 452099-05-7) and N-tetrahydrofuranyl-3-(2- Gas-6-fluoro-4-trifluoromethylphenoxy)-5-mercapto-li/-pyrazole-1-carboxamide (D-6; CAS 45100-03-7); c5) Group of pigment-inhibiting herbicides: 145027.doc -38· 201026687 Aceclofen, amitrol, flufenacet, benzobisketone, benzofenap, can be eliminated (clomazone), diflufenican, fluridone, flurochloridone, flurtamone, iso-quot; isoxaflutole, sputum Mesotrione, norflurazon, picolinafen, pyrasulfutole, pyrazzolynate, pyrazoxyfen, chlorpyrifos (pyrazoxyfen) Sulcotrione), tefuryltrione, tembotrione, topramezone, 4-carbyl-3-[[2-[(2-methoxyethoxy)methyl]- 6-(Trifluoromethyl)-3-"pyridyl]carbonyl]bicyclo[3.2.1]oct-3-en-2-one (D-7; CAS 352010-68-5) and 4- (3-Trifluoromethylphenoxy)-2-(4-trifluorodecylphenyl)pyrimidine (D-8; CAS 180608-33-7); c6) from the following EPSP synthase inhibitors: Glyphosate, glufosinate-isopropylammonium and glufosinate-three Base sulphate (sulfosate); c7) from glutamine amine synthase inhibitors: bialaphos or bialaphos, dipropylamine, glufosinate and grass Glufosinate-ammonium; c8) from DHP synthase inhibitors: asulam; c9) from the following mitotic inhibitors: amiprophos, amiprophos -methyl), benfluralin, butamiphos, butralin, carbetamide, chlorpropham, chlorthal, gram grass - Chlorthal-dimethyl, 挞乃安145027.doc -39- 201026687 (dinitramine), dithiopyr, ethalfluralin, fluchloralin, olyllium Oryzalin), pendimethalin, prodiamine, propham, propyzamide, tebutam, thiazopyr, and trifluralin; elO) from the following VLCFA inhibitors: acetochlor r), alachlor, anilofos, butachlor, cafenstrole, dimethachlor, dimethanamid, fine Dimethenamid-P, diphenamid, fentrazamide, flufenacet, mefenacet, metazachlor, modoc (metolachlor), momophyl-S, naproanilide, napropamide, pethoxamid, piperophos, pretilachlor, propachlor, Propisochlor, pyroxasulfone (KIH-485) and thenylchlor; compound of formula 2:

Wherein the code has the following meaning: Y is a phenyl or 5- or 6-membered heteroaryl group as defined in the opening paragraph, and these groups may be substituted with 1 to 3 groups of Raa; R21, R22, R23, R24 are Η , halogen or CVCV alkyl; X system Ο or ΝΗ; η system 0 or 1. 145027.doc -40- 201026687 Specifically, the compound of formula 2 has the following meanings:

Y is a group wherein # represents a bond to the molecular skeleton; and R21, R22, R23, R24 is H, Cl, F or CH3; R25 is a halogen, C^-Cc alkyl or CVCV haloalkyl; R26 is CVC4-alkyl; R27 is halogen, Ci-C4-alkoxy or Cl_c4-haloalkoxy; R28 is hydrazine, halogen, CVCV alkyl, CrCV haloalkyl or Ci-CV haloalkoxy; m is 0, 1, 2 or 3; X Oxygen; η system 0 or 1. Preferred compounds of formula 2 have the following meanings:

φ R21 is Η ; R22, R23 is F; R24 is Η or F; X is oxygen; η is 0 or 1. The preferred compound of formula 2 is as follows: 3-[5-(2,2-difluoroethoxy)-1-indolyl-3-trifluoromethyl-1Η-pyrazole-4-ylmethanesulfonyl ]-4-fluoro-5,5-dimethyl-4,5-dihydroisoxazole (2-1); 3-{[5-(2,2-difluoroethoxy)-1-methyl 3--3-trifluoromethyl-1H-pyrazol-4-yl] fluorodecanesulfonyl}-5,5-dimethyl-4,5-dihydroisoxazole (2-2); 4 -(4-fluoro-5,5-dimercapto-4,5-dihydroisoxazole-3-sulfonylfluorenyl)-2-methyl-5-trifluoromethyl-2H-[1, 2,3]triazole (2-3); 4-[(5,5-dimethyl-4,5-dihydroisoxazole·3-sulfonyl)fluoroindolyl]-2-methyl- 5-trifluoromethyl-2H-[1,2,3]triazole 145027.doc •41 - 201026687 (2-4) ; 4-(5,5-dimercapto-4,5-dihydroisoxine Azole_3_sulfonylhydrazino)_2_mercapto-5-difluoroindolyl-211-[1,2,3]triazole (2-5); 3-{[5-(2,2- Difluoroethoxy)-1-indolyl-3-difluoromethyl·m•pyrazole_4_yl]difluorodecanesulfonyl}-5,5-dimethyl-4,5-di Hydroisoxazole (2_6); 4[(5,5-didecyl-45_dihydroisoxazole-3-indanyl)difluoroindenyl]_2_indolyl_5-trifluoromethyl _ 2H-[ 1,2,3]diazole (2-7); 3-{[5-(2,2-difluoroethoxy)decyl_3_trifluoromethyl-1Η-pyrazole-4- Difluoromethanesulfonyl}_4_fluoro,5-diyl-4,5-dihydroisoxazole (2-8); 4-[difluoro-(4_fluoro·5,5_dioxin Base_4,5-dihydroisoxazole-3-sulfonyl)indenyl]_2_mercapto_5_trifluoromethyl_2Η_Π, 2,3]triazole (2-9); c 11) Groups from the following cellulosic biosynthesis inhibitors: chlorthiamid, dichl〇benil, flupoxam and isoxaben; cl 2) from the following decoupling Herbicide group: dinoseb, din〇terb and DNOC and its salts; cl3) from the following auxin herbicides: 2,4-ϋ and its salts and vinegar, 2 , 4_DB and its salts and esters, aminopyralid and its salts (such as amiodazolate (2hydroxypropyl) ammonium and its esters), benzallin, ethyl chlorpyrifos (benaz〇lin_ethyl), chloramben and its salts and vinegar, chloramphenicol (cl〇mepr〇p), clopyralid and its salts and esters, dicamba and Salts and esters thereof, 2,4-dipropionic acid and its salts and esters, dichloroprop-P and its salts and Flur〇xypyr, fluroxypyr-butometyl, fluorine gas ratio (fluroxypy 145027.doc -42- 201026687 meptyl), MCPA and its salts and esters, MCPA-thioethyl ester, MCPB and its salts and S, 2-(4- gas-2-mercaptooxy)propionic acid (mec〇pr〇p) and its salts and vinegar, (211)-2 -(4-孰1-2-fluorenyloxy)propionic acid (1116(;〇01»〇口_?) and its salts and esters, picloram and its salts and esters, quinclorac , quinmerac, TBA (2,3,6) and its salts and esters, triclopyr and its salts and esters, and 5,6-dichloro-2-cyclopropyl- 4-pyrimidine decanoic acid (D-9; CAS 858956-08-8) and its salts and esters; ©cl4) from the following group of auxin transport inhibitors: diflufenzopyr, diflupiron sodium, Naptaiain and sedative sodium; cl5) from the following other herbicides: bromobutide, chlorflurenol, chlorflurenol-methyl, cycloheptyl ether Cinmethylin), cumyluron, thatch, dazomet, oatmeal (difenzoquat), oat dry-salt sulfate, dimethipin, DSMA, dymron, endothal and its salts, etobenzanid, wheat straw (flamprop), wheat straw gas - isopropyl, wheat grass gas - methyl, wheat grass gas - M-isopropyl, wheat grass fluorine - M · thiol, flureneol, butyl butyl butyl, butyl Flurprimidol, fosamine, chloramphenicol-ammonium, indanofan, maleic hydrazide, mefluidide, metam, azide Methane, methyl bromide, methyl-azachlor, methyl iodide, MMA, oleic acid, oxaziclomefone, citric acid, pyributicarb, quinoclamine, trifluoro Oxalamine (1:1^21£1&111), oxacillin (1;14(^卩11&1^) and 6-chloro-3-(2-cyclopropyl-6-mercaptophenoxy) -4-pyridazinol (D-10; CAS 499223-49-3) and 145027.doc -43- 201026687 salts and esters thereof. Specifically, suitable protective agent D is as follows: benoxacor, cloquintocet, cyometrinil, cyprosulfamide, dichlormid, two Dicyclonone, dithyl phenylthiophosphate, diet, fenchlorazole, fenclorim, flurazole, fluxofenim, sputum (furilazole), isoxadifen, mefenpyr, mephenate, naphthalic anhydride, oxabetrinil, 4_(dichloroacetic acid)

Stuffed)-1-oxa-4-azaspiro[4. 5] decane (D-ll; MON4660, CAS 71520-〇7-3) and 2,2,5-trimethyl-3_(dioxalyl H,3-oxazolidine (D-12; R -29148, CAS 52836-3 1-4). The preferred herbicide c can be used in combination with the active compound of the present invention: ... from the following group of lipid biosynthesis inhibitors: acetylene vinegar, chlorhexidine vinegar , Ethyl ethyl oxalate, _ oxalic acid, benzophenone, chlorpyrifos, valerian, oxalochlor, chlorpyrifos and wild wheat awns. Groups from the following ALS inhibitors: Section ^ Cyclosulfuron , Flunarsulfuron-A A34 'sodium sulphate, methyl sulphate, oxadiazide ethyl, methoxy oxachloramide, jade spray team, continuous snail, shunlong _ 腙 and Triflusulfuron-methyl; sulfonate-sulfonate, methylthiazide-carbamate c3) from the following photosynthesis of flurazepam, hexazinone, isopropyl group: atrazine, diuron, 145027. Doc ° 秦草_, 百草, paraquat two-gas ·44 · 201026687 compound, herbicide, butazolam and chlorhexidine; C4) from the following protoporphyrinogen IX oxidase inhibitor group: propargyl fluoride Amine, rifampicin, pyrithione, acesulfame, 2_gas_5_[3,6-dihydro·3_methyl-2,6-di-oxo_4_(trifluoromethyl)_1 (2) _pyrimidinyl]_4_fluoro_N-[(isopropyl)decylamine sulfonyl]benzamide (CAS 372ΐ37·35_4) and [3-[2-chloro-4-fluoro- 5-(1-methyl-6-trifluoromethyl 2,4-di-oxyl_---tetrahydro(tetra)-t-phenoxyphenoxy bromide-oxygen acetate ethyl acetate (CAS 353292-3 1 -6); C5) from the following pigment-inhibiting herbicides ··············································································· Anthrone, pamidron and 4-carbyl, (2-methoxyethoxy)methyl (CW5); run]: Qing. 2. 1]W, c: from the following group of EPSP synthase inhibitors: oxaamine scale, glufosinate _ isopropylammonium and glufosinate-trimethylsulfonate (phosphophosphonate C7) from the face amidoxime A group of amine synthase inhibitors: glufosinate, glufosinate; c8) from the following mitotic inhibition Λλ.  Comment on I group. Shi Deyi and Sanfu; fek.  〇 from the following VLCFA inhibitors:, phosphorus, butyl oxalate, salivamine, dimethyl, [Zhuoamine, Lacao, Shakespeare (four), amlalamine, fentanyl, grass reduction: Zhuo =, Jing dimethyl Phenochlor, serrata, pyrocene, s-modoca, 2-3' 2-4 > 2-5 > 2 6 > 2 7 , evil ° sitting compound 2 small 2 · 2, 2-6 2_7, 2-8 and 2_9 ; cl〇) from the following cellulosic bio-aspartate; group of P preparations: diquat nitrile, iso 145027. Doc -45- 201026687 ell) from the following group of auxin herbicides: 2,4-D and its salts and esters, clopidogrel and its salts (eg uridine pyridinium-zinc (z-hydroxypropyl) ammonium And its ester), dichloro-pyridic acid and its salts and esters, dicamba and its salts and esters, fluorine to gas ratio, dihaloquinoic acid, chloromethylquinic acid and 5,6-dichloro-2- Cyclopropyl-4-pyrimidinecarboxylic acid (CAS 85 8956-08-8) and its salts and esters; c 12) from the following groups of auxin transport inhibitors: diflupiron and diflupiron sodium; cl3) from The following groups of other herbicides: chlorpyrifos (daimuron), oxaloin and chlorpyrifos. Examples of preferred protectant D are oxaloacetone, detoxified quinine, sulforaphane, dichloropropenylamine, oxazolidine, chlorpyrifos, chlorhexidine, valerian, dibenzoxazole, pyrazole Herbicide, naphthalene anhydride, oxalic acid, D-11 and D-12. Youjia's protective agent D is oxaloacetone, detoxified quinine, chlorfenapyr, dichloropropenylamine, oxazolidine, dibenzoxazole acid, pyrazolyl ester, D-11 and D-12. The active compounds A, B, C and D are known as herbicides and protective agents, for example, see, The Compendium of Pesticide Common Names (http://www. Alanwood. Net/pesticides/) ; Farm Chemicals Handbook 2000 Vol. 86, Meister Publishing, 2000; B.  Hock, C.  Fedtke, R.  R.  Schmidt, Herbizide [Herbicides], Georg Thieme Verlag, Stuttgart 1995; W.  H.  Ahrens, Herbicide Handbook, 7th edition, Weed Science Society of America, 1994; and K.  K.  Hatzios, Herbicide Handbook, Rev. 7 edition, Weed Science Society of America, 1998 ° 2,2,5-trimethyl-3-(dichloroacetamido)-1,3-oxazolidine [CAS No. 52836 -3 1-4] 145027. Doc -46- 201026687 Also known as R-29148. 4-(dioxaethyl)-1-oxa-4-azaspiro[4. 5] brothel [CAS No. 71526-07-3] is also known as AD_67 and MON 4660. Other herbicidal active compounds are from "WO 96/26202, WO 97/41116, WO 97/41117, WO 97/41118 and WO 01/83459 and from w.  "ModernCropProtection Compounds" by Kramer et al. (eds.), Vol. 1, Wiley VCH, 2007 and the references cited therein. The mechanism of action of the respective active compounds is determined based on prior knowledge. If the dry action mechanism applies to an active compound, then only the substance is assigned to a mechanism of action. If the herbicide and/or protecting agent is capable of forming geometric isomers (e.g., E/z isomers)' then both pure isomers and mixtures thereof can be used in the compositions of the present invention. Pure enantiomers and diastereomers if the herbicide and/or protecting agent has one or more pairs of palmar centers and is thus present as enantiomers or diastereomers Both mixtures and mixtures thereof can be used in the compositions of the invention.除 If the herbicide and/or protectant has an ionizable functional group, it can also be used in the form of its agriculturally acceptable salt. In general, suitable cations and anions are salts of their cations or acid addition salts of such acids which do not adversely affect the activity of the active compound. Preferred cations are alkali metal ions, preferably lithium, sodium and potassium; alkaline earth metal ions, preferably calcium and magnesium; and transition metal ions, preferably manganese, copper, zinc and iron; and ammonium and substituted ammonium. , wherein one to four hydrogen atoms are replaced by an alkyl group, a base -cvc4_alkyl group, a Cl_c4_homolyl_Ci_C4_house group, a hydroxy-Cl Cc alkoxy group _Ci_C4_alkyl group, a phenyl group or a benzyl group, Preferably ammonium, 145027. Doc 47· 201026687 曱-ammonium, isopropylammonium, decyl ammonium, diisopropylammonium, trimethyl ketone, tetradecylammonium, tetraethylammonium, tetrabutylammonium, 2-hydroxyethylammonium , 2_(2-hydroxylethyl-1-oxy)eth-1-ylammonium, bis(2-hydroxyethyl-4-yl)ammonium, benzyltrimethylammonium, benzyltriethylammonium, and scale ions The cerium ion is preferably tris(C decyl) fluorene (e.g., trimethyl hydrazine) and oxonium ion, preferably triterpene. 1 The anion of the applicable acid addition salt is mainly gas ion, bromide ion, gas ion, iodide ion, hydrogen sulfate ion, methyl sulfate ion, sulfate ion, dihydrogen phosphate ion, hydrogen phosphate ion, nitric acid Root ion, hydrogencarbonate ion, carbonate ion, hexafluoroantimonate ion, hexafluorophosphate ion, bismuth citrate ion, and anion of C1-C4-chain succinic acid (preferably formate ion, acetate ion, Propionate ion and butyrate ion). The active compound having a carboxyl group can be used in the present invention in the form of an acid, in the form of an agriculturally suitable salt or in the form of an agriculturally acceptable derivative, for example in the form of a guanamine (for example, mono- and di-Cl_C6-alkyl). In the form of a guanamine or aryl decylamine, an ester (eg, allyl ester, propargyl ester, C1-C1Q-alkyl ester, alkoxyalkyl ester, and thioester (eg, q-Cw alkane) The thiol ester)) form is used. Preferred are mono- and di-CrC6·alkyl amide amine methyl amine and dimethyl amine. Preferred are arylamines such as nonylaniline and 2-chloromercaptoaniline. Preferred alkyl esters are, for example, methyl esters, ethyl esters, propyl esters, isopropyl esters, butyl groups, isobutyl esters, amyl esters, isoheptyl groups (l-yl) Hexyl) ester or isooctyl (2-ethylhexyl) ester. Preferably, the Ci_C4_alkoxy/polyalkylene ester is a straight bond or a branched C^C:4-alkoxyethyl ester such as methoxyethyl ester, ethoxyethyl vinegar or butyl Oxyethyl ester. Straight or branched Ci_Ci()_alkylsulfide 145027. Doc -48 - 201026687 An example of a base ester is ethyl thioester. The term "binary composition" as used herein and hereinafter includes a composition comprising one or more active compounds A and one or more active compounds B. Accordingly, the term "ternary composition" includes compositions comprising one or more active compounds A, one or more active compounds B, and one or more herbicides C and/or protectant D. In a binary composition comprising at least one active compound A as component A and at least one active compound B, the weight ratio of active compound A:B is usually in the range from 1:1 1000 to 1000:1, preferably In the range of 1:500 to 500:1, it is in the range of 1:25 〇 to 25 〇:1 and particularly preferably in the range of 1:75 to 75:1. In a ternary composition comprising at least one active compound A, at least one active compound B and at least one herbicide C and/or protectant D, the relative parts by weight of component A:B is as described for the binary combination The weight ratio of component a)w) is usually in the range of 1:1000 to 1000:1, preferably in the range of 1:5 〇〇 to 5 〇〇:1, specifically 1:250 to 250:1. Within the range and particularly preferably in the range of 1:75 to 75:1, and the weight ratio of component b):c) is usually in the range of 1:1 〇〇〇 to 1 〇〇〇:1, 〇 preferably in I : in the range of 500 to 500:1, specifically in the range of 1:250 to 250:1 and particularly preferably in the range of 1:75 to 75:1. Preferably, the weight ratio of component a)+b) to component e) is in the range from 1:500 to 500], in particular in the range from 1:25 〇 to '250:1 and especially preferably 1: 75 to 75:1 range. • Other preferred embodiments relate to a ternary composition corresponding to a binary composition and additionally comprising a protective agent D selected in particular from the group consisting of: oxakonium, detoxification, chlorpyrifos, Air propylene amine, herbicide saliva, bis-benzoic acid, pyrazole oxalate, D_u and D_12. Another aspect of the invention pertains to the compositions listed in Table c below. To 145027. Doc • 49- 201026687 C-l227, wherein in each case one of the tables C corresponds to a herbicidal composition comprising a mixture of the following: an individualized compound of formula 1, in particular a preferred active compound A (component a) And an active compound B (component b) selected from the group consisting of B-1, B-2, B-3, B-4, B-5 and B-6, particularly preferably as disclosed in Table B One of the combination B-1 to B-60; and, in each case, another component c) consisting of one or two herbicides C and/or a protective agent D as described in the above-mentioned column. The active compounds in the binary and ternary compositions are preferably present in synergistically effective amounts in each case. Table C: No. Herbicide C Protectant D C-1 Vinyl Acetate-C-2 Ring-killing Grass - C-3 Cyhalofop-C-4 - Ethyl Acetazol - C-5 ° Sit Lincao ester-C-6 Cyclopentanone-C-7 to kill grass - C-8 3-methylidene ketone - C-9 Herbicide - C-10 Benzodan - C-11 Herbicide - C- 12 野麦畏—C-13 Bensulfuron-C-14 Bisodium oxalate-C-15 环屈隆—C-16 oxasulfuron-C-17 Flunarsulfuron-mercapto-sodium — C-18 曱醯amine indeed - C-19 imazamox - C-20 曱基咪草 - C-21 灭草 - C-22 σ 啥 啥 — - C-23 Imidazolium - C-23 145027. Doc -50- 201026687 No. Herbicide c Protectant D C-24 Essence - C-25 Iodsulfuron-methyl-sodium - C-26 Methyldisulfuron - C-27 in the mouth - C- 28 penoxsulam - C-29 propyl sulfonamide - C-30 百速隆-ethyl - C-31 曱 oxicillin - C-32 rimsulfuron - C-33 sulfonamide —C-34 Methylthianecarbazide — C-35 Trifluorosulfuron-C-36 2,4-D and its salts and esters — C-37 Amicyclic pyridine acid and its salts and esters — C-38 Dihydropyridine acid and its salts and esters - C-39 dicamba and its salts and esters - C-40 fluorine gas ratio - C-41 dioxetane acid - C-42 gas phthalic acid - C-43 D -9 — C-44 Difluoropyrene - C-45 Difluoro π Billund sodium - C-46 Can be traced - C-47 Fluramide - C-48 Fluorine oxalicone - C-49 Oxygen oxalicone - C-50 Mesotrione - C-51 Fluoride. Ratio of acetochlor - C-52 sulcotrione - C-53 fluorenone - C-54 telobone - C-55 tepamidazole - C-56 D-7 - C-57 atrazine - C- 58 diuron 1 C-59 fluroxypyr - C-60 hexaphenone - 145027. Doc -51 - 201026687 No. Herbicide c Protectant D C-61 Isoproturon ~ C-62 Cyclohexanone - C-63 Herbicin - C-64 Caojing - C-65 Paraquat Dihydrate - C- 66 Propynefluramine - C-67 Fulufen - C-68 Mesotrione - C-69 D-1 - C-70 D-2 - C-71 Glufosinate - C-72 Glufosinate - Isopropylammonium - C-73 glufosinate-trimethylsulfate (phosphosulfony) - C-74 glufosinate - C-75 glufosinate - C-76 Schmidt - C-77 C-78 Acetochlor - C-79 Oxachlor - C-80 Dihydrohexamethylene oxalate - C-81 Si Salicin I - C-82 Fluramide - C-83 Exterminator - C-84 Oxalamine - C-85 Modotope-S - C-86 Parox sulfasyrene - C-87 Isoxachlor - C-88 Herbicide - C-89 oxalicone - C-90 C-91 trifluoxymethane - C-92 atrazine + D-1 - C-93 atrazine + glufosinate - C-94 atrazine + mercapto - C-95 Trakai + Nicosulfuron - C-96 Atrazine + Tebuxozone - C-97 Atrazine + Tepami - 145027. Doc ·52· 201026687 No. Herbicide c Protectant D C-98 Can be traced + glufosinate - C-99 Fluramide + clodinafop - C-100 Fluramide + refined ethyl oxazolyl — C-101 Fluroxypyrazine + Flunarizine-Methyl-Sodium—C-102 Fluramide + Glufosinate-C-103 Flurazine + Methyl Dihydro-Methyl - C-104 Fluorine Oxalate + oxazolinol - C-105 Fluroxypyrazine + oxicillin - C-106 oxasulfuron + glufosinate - C-107 propargyl flufenamide + phosphinothricin - C-108 Methyl imazethapyr + glufosinate C-109 imidazolium nicotinic acid + glufosinate - C-110 iso-β oxazolone + D-1 — C-lll isoxaflutole + glufosinate — C-112 Oxalamide + D-1 — C-113 imazachlor + glufosinate — C-114 chlorfenapyr + mercapto ketone — C-115 chlorfenapyr + in π 密 隆 — C-116 chlorfenapyr +草净津 — C-117 chlorfenapyr + tepami knee — C-118 oxazinone + glufosinate — C-119 Shi Dezhen + D-1 — C-120 Shi Deyu + acetylene ester — C-121 Shi Dezhen + Refined Ethyloxazolone - C-122 Schmidt + Flunarsulfuron-sulfonyl-sodium-C-123 Schmidt + glufosinate - C-124 Schmidt + thiol隆-曱基- C-125 施德圃+曱- sulcotrione — C-126 Shi De 圃 + Nicosulfuron - C-127 Shi De 圃 + oxazoline - C-128 Shi De 圃 + 曱 确 确 — - C-129斯德圃+特博酮 — C-130 施德圃+特帕米腙 — C-131 派罗克杀草草+特博酮—C-132 派罗克草草飒+特帕米腙—C-133 Oxalamine + glufosinate - C-134 Caojingjin + D-1 — 145027. Doc -53- 201026687 No. Herbicide c Protectant D C-135 Caojing + Shimisulfuron - C-136 Caojing + Glufosinate - C-137 Caojing + Mesotrione - C -138 草净津+烟素sulfuron C-139 草净津+特博酮— C-140 草净津+特帕米腙—C-141 三福林+草胺磷—C-142 —草草Ketone C-143 — detoxified quinone C-144 — sulfasalazine C-145 — di- propylene acrylate C-146 — oxazolidine C-147 — bis-phenylene, ° sit-acid C-148 — 0 to 0草草醋 C-149 — D-11 C-150 — D-12 C-151 acetylene oxalate ketone ketone C-152 Cycloheximide C-153 cyhalofoprin oxalate C-154 Oxazol and chlorpyrifos C-155 ° sitting on the grass, the grass, the grass, the ketone, the C-156, the ketone, the ketone, the C-157, the herbicide, the ketone, the ketone, the ketone, the ketone C-159 valerate oxalofen C-160 benzyl oxadiazepine C-161 chlorpyrifos ketone ketone C-162 wild wheat oxalofen C-163 bensulfuron-methyl ketone C-164 double Sodium oxalate, ketone, C-165, sulfonate, ketone, C-166, oxasulfuron, oxalyl ketone, C-167, flurazepam - sulfhydryl- Benoxacor Amides C-168 A C-169 Yue Metsulfuron oxygen imazethapyr benoxacor C-170 Yue yl imazethapyr benoxacor C-171 solution by herbicides mesotrione 145,027 benoxacor. Doc -54- 201026687 No. Herbicide c protectant D C-172 M. Take the 喧 酸 酸 酸 C C C C C-173 taste. Sodium bisulphate C-174 acesulfame C-175 Iodosulfuron-methyl-sodium oxaloacetone C-176 methyl disulfuron oxalofen C-177 Yuming continued to solve the problem Ketone C-178 penoxsulam-based oxaloacetone C-179 propylbenzamide sodium oxaloacetone C-180 Baishoulong-ethyl oxaloacetone C-181 methoxy oxalate ketone ketone C-182 jade Sulfasalazine ketone ketone C-183 Continued brewing ketone ketone ketone C-184 methyl thianecarbazone oxaloacetone C-185 trifluorosulfonium sulfonate C-186 2,4-D and its salts And esterified ketone ketone C-187 chloramine pyridine acid and its salt and ester oxalate ketone C-188 cloperidic acid and its salt and ester ketone ketone C-189 dicamba and its salt and ester oxalate C- 190 fluorochlorobenzene ketone ketone C-191 diclofenacic acid ketone ketone C-192 chloromethyl salicyl oxalate ketone C-193 D-9 oxaloacetone C-194 difluoropyrrolidone C- 195 diflupirone sodium oxaloacetone C-196 can be used to kill oxaloacetone C-197 flufenacetin c-198 fluoxalone oxalofen C-199 iso oxa oxazin C-200 mesotrione ketone ketone C-201 fluoro ° ratio of chlorfenapyr C-202 sulfoxerone oxalofen C-203 fluorenone Oxalofenone C-204 telbone ketone ketone C-205 tepamidone oxaloacetone C-206 D-7 oxaloacetone C-207 atrazine oxaloacetone C-208 diuron oxaloquinone 145027 . Doc -55- 201026687 No. Herbicide c Protectant D C-209 Fluroxypyrazine C-210 Hexazone Ketoxene C-211 Isoproterone C-212 Oxazinone Kusalone C- 213 Herbicin, oxaloacetone C-214, oxazin, C-215, paraquat, dichloromethane, C-216, propargyl, flufenacetin, C-217, rifampicin, C-218, 曱Sulfachlor ketone C-219 D-1 oxaloacetone C-220 D-2 oxaloacetone C-221 glufosinate oxaloacetone C-222 glufosinate-isopropylammonium oxalate C-223 Glufosinate-trimethylsulfanium salt (oxathiophosphine) oxalochlorone C-224 glufosinate oxalochlorin C-225 glufosinate phosphinone C-226 schneider ketone ketone C-227 Ketone C-228 Acetochlor ketone ketone C-229 Azulamide oxaloacetone C-230 Dihydropterin oxalyl ketone C-231 Tetramethyl ketone ketoxime C-232 Fluramide C-233 灭分军草草酮 C-234 chlorfenapyr C-235 莫多草-S oxaloacetone C-236 派罗克草草酮草草酮 C-237 Isoxachlor Ketone C-238 chlorfenapyr C-239 oxaloquinone C-240 稗 解 解 解 C C-241 trifluoro Amidoxan C-242 atrazine + D-1 oxaloacetone C-243 Atra call + glufosinate oxaloacetone C-244 Atrazine + mesotrione ketone Ketone C- 245 atrazine + nicosulfuron oxalate 145027. Doc -56- 201026687 No. Herbicide c Protectant D C-246 Atrazine + Tebukenone Kusalone C-247 Atlas + Tepami 腙 Kusalone C-248 Can be sterilized + oxalate Phosphavone C-249 Flurazine + Herba Effluent Ketone C-250 Fluroxypyramine + Ethyl Ethyl Oxazin and Herbicide C-251 Fluroxypyramine + Fluoropyrimidine - Sulfhydryl -Sodium oxaloacetate C-252 Fluroxypyramine + glufosinate oxaloacetate C-253 Fluroxypyramine + decyl disulfuron-mercapto ketone ketone C-254 Flurazine + β sitle Ketone C-255 Fluroxypyrazine + sulfoxamide oxaloacetone C-256 oxasulfuron + glufosinate oxaloacetone C-257 propargyl flucarbamate + glufosinate oxaloacetone C-258 Gemis in + glufosinate oxaloacetone C-259 imidazolium nicotinic acid + glufosinate oxalofenone C-260 isoxaflutole + D-1 oxaloacetone C-261 isoxaflutole + glufosinate solution Oxalone C-262 chlorfenapyr + D-1 oxaloacetone C-263 chlorfenapyr + glufosinate oxaloacetone C-264 chlorfenapyr + mesotrione ketone ketone C-265 mesalamine +啸 确 确 隆 解 C C C - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - C-269 斯德圃+D-1 oxaloacetone C-270 schide 炔 acetylene oxalate ketone ketone C-271 schide 精 + refined ethyl oxazolyl grass ketone ketone C-272 Shi De 圃 + fluridine sulfonamide - 曱Base-sodium oxaloacetone C-273 Schmidt + glufosinate oxaloacetone C-274 Schmidt + methyl disulfuron - methyl oxalofen C-275 Schmidt + mesotrione ketone ketone C-276 + Nicosulfuron-Lipulinone C-277 Shi Dezhen + D sitting on the grass 酉 酉 解 解 C C - - - - - - 圃 圃 圃 圃 圃 圃 圃 圃 - - - - - - - - - - - - - - - - - - - - +Tepamis oxadiazepine C-281 Pyrolinosone sulfone + trebutone ketone ketone C-282 Pyroic oxalic acid sulfone + tepamidone oxalate 145027. Doc -57- 201026687 No. Herbicide c Protectant D C-283 Isosulfamide + glufosinate oxaloacetone C-284 Caojing + D-1 Kusalone C-285 Caojing + methotrexate Rhodone C-286 Caojing + glufosinate oxaloacetone C-287 Caojing + 曱 续 草 草 解 解 C C C - - - - + + + + + + + + + +净津+特博酮草草酮 C-290 草净津+特帕米腙草草酮 C-291 三福林+草胺磷草草酮 C-292 acetylene ester detoxification 啥C-293 环草Detoxification quinone C-294 cyhalofopyl ester detoxification 啥C-295 refined ethyl oxazoline grass extract detoxification quinolin C-296. Separation of Lin oxalate detoxification quinone C-297 Cyclohexazone detoxification quinone C-298 Detoxification detoxification quinone C-299 Tetramethoxam detoxification quinone C-300 Herbicide detoxification quinone C-301 Benzyl dandan detoxification 啥 C- 302 杀草丹解毒-C-303 野麦畏解毒奎C-304 Bensulfuron-methyl detoxification quinolin C-305 bis-oxalate sodium detoxification 啥C-306 环Continuous detoxification 啥C-307 oxasulffenamide detoxification 啥C-308 Flunarsulfuron-methyl-sodium detoxification wow C-309 methotrexate sulfonate detoxification quinone C-310 methoxyacetice detoxification quinolin C-311 曱基咪草烟毒毒 奎C-312 Grass detoxification C-313 σ meters. Sitting on the leaching acid detoxification quinolin C-314 imidazolium niacin detoxification 啥C-315 速速隆解毒啥C-316 iodine sulfonate-methyl-sodium detoxification 啥C-317 sulfhydryl disulfuron-detoxifying quinolin C-318 nicosulfuron Detoxification 啥C-319 penoxsulam detoxification quinol 145027. Doc -58 - 201026687 No. Herbicide c Protectant D C-320 Propylsulfuron sodium Detoxification C-321 Baishoulong-Ethyl detoxification quinone C-322 Sulfoxacillin detoxification quinone C-323 Detoxification quinone C-324 Continued 醯 醯 解 解 噎 - C-325 Methyl thiazene carbaquinone detoxification quinone C-326 trifluorosulfonate detoxification 啥 C-321 2,4-D and its salt and ester detoxification quinolin C-328 Chloramphenic acid and its salts and esters detoxification 喧C-329 cloperidic acid and its salts and esters detoxification 喧C-330 dicamba and its salts and esters detoxification quinolin C-331 locomotive detoxification C-332 dichloropurine Lin acid detoxification 喧C-333 gas 曱啥 酸 解 啥 啥 - C-334 D-9 detoxification quinolin C-335 diflupiron detoxification quinolin C-336 difluoro 11 pirone sodium detoxification 喧 C-337 can destroy the detoxification quin C-338 Fluroxypyramine detoxification quinone C-339 Fluroxypyrazine detoxification 喧C-340 °°°°草草酮解噎C-341 Methyl oxaprofen detoxification quinone C-342 Fluramide on detoxification quin -343 sulcotrim detoxification quinone C-344 anthrone detoxification quinone C-345 telbone detoxification 1 Ί: C-346 tepamidi detoxification quinolin C-347 D-7 detoxification 嘻C-348 atrazine detoxification 啥C -349 歒草隆解Toadstool C-350 Fluroxypyrine Detoxification Quino C-351 Hexazinone Detoxification C-352 Isoproturon Detoxification Qu-C-353 D-Qincaone Detoxification Quino C-354 Herbicin Detoxification Qu-C-355 Caojing Detoxification C-356 Paraquat dichloride detoxification saliva 145027. Doc -59- 201026687 No. Herbicide c Protectant D C-357 Propargyl Fluoxamide Detoxification C-358 Fu Lufen Detoxification C-359 Mesotrichlor Detoxification Saliva C-360 D-1 Detoxification Saliva C-361 D-2 detoxification 喧C-362 glufosinate detoxification quinone C-363 glufosinate-isopropylammonium detoxification quinone C-364 glufosinate-trimethyl sulfonate (phosphophos) detoxification quinone C-365 pudding Phospholysis detoxification quinone C-366 glufosinate detoxification quine C-367 Schmidt detoxification quine C-368 bisflurin detoxification 啥C-369 acetochlor detoxification quinone C-370 β oxalyl detoxification 啥C-371 精二曱Amine-detoxifying quinone C-372 Tetra-ketone detoxification C-373 Fluroxypyramine detoxification 喧C-374 %JL· Determining herbicide detoxification Sodium C-375 Methionamine detoxification quinone C-376 Modotope-S Detoxification 喧C -377 Parox chlorpyrifos detoxification 喧C-378 Isoxachlor detoxification 喧C-379 杀草隆解毒啥C-380 ketoxime detoxification 喧C-381 Detoxification detoxification C-382 trimethoprim detoxification Quino C-383 atrazine + D-1 detoxification quinone C-384 atrazine + glufosinate detoxification quine C-385 atrazine + mesotrione detoxification 啥 C-386 Atra 嗓 + Nicosulfuron detoxification quinone C-387 Atla + + 特博酮 detoxification 01 C-388 atrazine + tepami 腙 detoxification quinone C-389 can be traced + glufosinate detoxification 啥 C-390 flufenazone + acetylene ester detoxification 喧 C-391 flu Amine + refined ethyl oxazolyl grass detoxification quine C-392 Fluroxypyrazine + fluridine sulfonamide - methyl - sodium detoxification 啥 C-393 Flurazine + glufosinate detoxification quinol 145027. Doc -60- 201026687 No. Herbicide c Protectant D C-394 Fluroxypyramine + Mercapto Disulfuron - Methyl Detoxification C-395 Fluroxypyrazine + Zymphalloate Detoxification C-396 Fluramine + 曱Oxymatamide detoxification quinone C-397 oxasulfuron + glufosinate detoxification 喧C-398 propargyl flufenacetate + glufosinate detoxification quinone C-399 methyl imazethin + glufosinate detoxification 啥 C- 400 imidazolium nicotinic acid + glufosinate detoxification 喧 C-401 is not evil. Sitting grass + D-1 detoxification 啥 C-402 isoxaflutole + glufosinate detoxification 喧 C-403 chlorfenapyr + D-1 detoxification 喧 C-404 chlorfenapyr + glufosinate detoxification 啥 C-405 Moxachlor + sulfhydryl ketone detoxification 喧C-406 chlorfenapyr + Yumingzhenglong detoxification quinone C-407 chlorfenapyr + chlorpyrifos detoxification 啥C-408 chlorpyrifos + tepami 腙 detoxification quin -409 oxazinone + glufosinate detoxification 喧C-410 Shi De 圃+D-1 detoxification 啥C-411 Shi De 圃 + acetylacetoate detoxification 啥C-412 Shi Dezhen + refined ethyl oxazoline and grass detoxification 喧C-413 Shi Dezhen +Fluorosulfuron-methyl-sodium detoxification saliva C-414 Shidezhen + glufosinate detoxification quinone C-415 Shi Dezhen + sulfhydryl disulfuron-methyl detoxification quinone C-416 Shi Deyu + methyl oxaprofen detoxification C-417 施德圃+End Mouth Renewal Detoxification C-418 Shi Dezhen + Salicylate Detoxification Quino C-419 Shi Dezhen + Oxygen oxalate Detoxification Quino C-420 Shi Dejing + Tebolone Detoxification C-421 Shi Deyu + Special Pami Yuezong Detoxification C-422 Pyrocarb Sodium Sulfate + Tebukenone Detoxification Quino C-423 Pyroside Killing Grass + Tepamidin Detoxification C-424 Mesalamine + Glufosinate Detoxification C-425 Caojingjin+D-1 solution Quinoa C-426 Caojingjin + acesulfame sulfonate detoxification quinone C-427 Caojingjin + glufosinate detoxification 喧C-428 Caojingjin + 曱 base oxalicone detoxification quinone C-429 Caojingjin + nicotin Sulfuric acid detoxification quinone C-430 Caojingjin + trebutone detoxification 01 145027. Doc -61 · 201026687 No. Herbicide c Protectant D C-431 Caojingjin + Tepami 腙Detoxification C-432 Sanfolin + glufosinate detoxification 啥C-433 acetylene oxalate- propyl allysine C -434 Cycloheximide dichloropropenylamine C-435 cyhalofoprene di- propylene acrylate C-436 refined ethyl oxazolyl oxalic acid dichloropropenylamine C-437 chlorpyrifos dichloropropenylamine C-438 ring Benzorone-chloropropanol C-439 oxalic acid dichloropropenylamine C-440 triterpenal ketone dichloropropenylamine C-441 pentosandan dichloropropenylamine C-442 benzalkonium dichloropropenamide C-443 杀草丹-乳乳胺胺C-444 野麦畏二氯丙胺 C-445 苯菌磺隆二氯丙胺 C-446 双草乙钠二气丙烯胺 C-447 环气隆二气Acrylamine C-448 oxasulfuron diamine propylene amine C-449 fluridine sulfonamide-methyl-sodium dipropylene propylene amine C-450 methotrexate chlorination propylene amine C-451 oxime imazeth Dichloropropenylamine C-452 Dimethoprim Tobacco Dichloropropene Amine C-453 Desiccated Dioxyl Acrylamine C-454 Miso-dichloropropenylamine C-455 Imidazolium Nicotinamide C-456速速隆-一Propylene amine C-457 Iodosulfuron-methyl-sodium dichloropropene amine C-458 sulfhydryl disulfuron-methyl acetophenone C-459 in cancer continuation of dichloropropenylamine C-460 pentafluorosulfonamide Chloropropenylamine C-461 Propylbenzene ronol dichloropropenylamine C-462 百速隆-ethyldichloropropenylamine C-463 acesulfame dichloropropenylamine C-464 rimsulfuron dichloropropenamide C-465 醯 醯 二 二 二 propylene amine C-466 曱 噻 噻 卡 卡 卡 腙 腙 - - - - - - 145 145 145 145 145 145 145 145 145 145 145 145 145 145 145 145 145 145 145 Doc -62- 201026687 No. Herbicide c Protectant D C-468 2,4-D and its salts and esters Dichloropropenylamine C-469 Chloramidolinic acid and its salts and esters Dichloropropenylamine C-470 Dichloro Pyridic acid and its salts and esters · Dichloropropenylamine C-471 dicamba and its salts and esters dichloropropenylamine C-472 gas rat than dichloropropenylamine C-473 diclofenac dihydropropene amine C- 474 chloromethyl hydrazide dichloropropenylamine C-475 D-9 di- propylene acrylate C-476 diflupiron di propylene amide C-477 diflupirone sodium dichloropropene amine C-478 can eliminate two gases Propylamine C-479 Gasoline Dichloropropenylamine C-480 Fluoridone Dioxyl Acrylamine C-481 Isoxame _ Dioxyl Acrylamine C-482 Methyloxadone Di-Acrylamine C -483 fluroxypyramine dichloropropenylamine C-484 sulcotrione di- propylene amide C-485 糠 two-gas propylene amine C-486 telbone di- propylene amide C-487 Tepamis bis 2 propylene Dilute amine C-488 D-7 di-mole propylamine C-489 atrazine dichloropropenamine C-490 diuron dioxane propylene amine C-491 fluroxypyrazine propylene amine C-492 hexazinone two gas Propylene amine C-493 isoproturon Enamine C-494 Cyclohexanone Dipropylene Acrylamine C-495 Herbicin Dioxyl Acrylamine C-496 Caojing Diqi Acrylamine C-497 Paraquat Dihydrate Two Air Acrylamine C-498 Propyne Fluorene Amine Dioxyl Acrylamine C-499 Fulufen Dioxyl Acetamide C-500 Mesalamine Dioxyl Acrylamine C-501 D-1 Dipropylene Acrylamine C-502 D-2 Dipropylene Acrylamine C-503 Glufosinate di- propylene amide C-504 glufosinate-isopropyl ammonium di- propylene 145027. Doc -63- 201026687 C-505 Glufosinate-trimethylsulfonate (phosphosulfony) Dipropylene acrylate C-506 Glufosinate dichloropropanol C-507 Glufosinate dichloropropionamide C- 508 Schmidt Dichloropropenylamine C-509 Difosin Dichloropropenylamine C-510 Acetochlor Dioxyl Acrylamine C-511 Oxachlor Dichloropropanol C-512 Dimensed Dioxaniline Dichloropropenamine C-513 tetradecyl ketone dichloropropenylamine C-514 oxalate-wind "acrylamide C-515" - tfr chlorfenapyr C-516 chlorfenapyr dichloride 517 莫多草-S Dichloropropenylamine C-518 Parox chlorpyrifos dichloropropanol C-519 Isoxachlor dichloropropenamine C-520 chlorpyrifos dichloropropenylamine C-521 oxaloxane Chloropropenylamine C-522 deuterated dichloropropenylamine C-523 trimethoprim dichloropropenamine C-524 atrazine + D-1 dichloropropionamide C-525 atrazine + oxalate Phosphonium dichloropropenylamine C-526 Atraxane+mercaptosone dichloropropanol C-527 Atra Sigma+ Yuming Xianglong Dichloropropenylamine C-528 Atrax + Tebuxozone Dichloropropenylamine C-529 atrazine + tepamidime dichloropropenylamine C-5 30 extrinsic + glufosinate dichloropropenylamine C-531 fluroxypyr + acetylene oxalate dichloropropenylamine C-532 fluramide + refined ethyl oxazolyl oxalic acid dichloropropide amine C-533 fluoride Oxalamide + Flunarsulfuron-mercapto-sodium dichloropropanol C-534 Flurazine + glufosinate dichloropropenylamine C-535 Flurazine + methyl disulfuron - decyl dichloropropane Baked amine C-536 fluroxypyr + salicylate dichloropropenylamine C-537 fluroxypyr + sulfoxamide dichloropropenylamine C-538 oxasulfuron + glufosinate di- propylene amine C -539 propargylamine + glufosinate di- propylene amide C-540 methyl imazethin + glufosinate di- propylene amide C-541 imidazolium nicotinic acid + glufosinate di- propylene amide C-542 Sitting on the grass brewed I + D-1 - a mess of propyl amine 145027. Doc -64- 201026687 C-543 Isoxaflutole + glufosinate dichloropropenylamine C-544 mesalamine + D-1 dichloropropenylamine C-545 herbicide + glufosinate dichloropropenylamine C -546 chlorfenapyr + mesotrione dichloropropenylamine C-547 chlorfenapyr + σ 密 隆 一 & & 乱 & & & & & & 乱 乱 乱 乱 乱 C C 乱 C C C 灭 灭 灭 + + + + + + + + 549 chlorfenapyr + tepamidone diclofenac C-550 oxazinone + glufosinate di- propylene amine C-551 Schmidt + D-1 dichloropropenylamine C-552 Schmidt + acetylene dichloride Acetone C-553 Shidezhen + refined ethyl oxazolyl oxalic acid isopropylamine C-554 Shi Dexi + fluridine sulfuron-methyl-sodium dichloropropanol C-555 Shi Deyu + glufosinate II Chloropropenylamine C-556 Schmidt+Methyldisulfuron-methyldichloropropenylamine C-557 Schmidt+Methylalcodone Dichloropropenylamine C-558 Shidezhen+Nicosulfuron Dichloropropenylamine C-559 Shi Dezhen Sitting on the grass, the purpose of the dichloropropenylamine C-560 Schmidt + sulfoxamide - 'chloropropanol C-561 Schmidt + trebutone dichloropropene amine C-562 Shi Deyi + Tepadic '" milk Acetone C-563 Pyrokiller Dichloropropenylamine C-564 Parrocicide herbicide + Tepamidone 'I wind* acrylamide C-565 Mesalamine + glufosinate dichloropropanol C-566 Caojingjin + D- 1 Dichloropropenylamine C-567 Caojingjin + methotrexate-l-acrylamide C-568 Caojingjin + glufosinate dichloropropenamine C-569 Caojingjin + mesotrione dichloride Acrylamine C-570 Caojingjin + Nicosulfuron-air propylene amine C-571 Caojingjin + Tebuxozone-"Milk acrylamide C-572 Caojingjin+Tepamidone Dichloropropenylamine C -573 Sanfulin + glufosinate dichloropropenylamine C-574 clodinafyl oxazolidine C-575 Cyclohexazone C-576 Cyhalofopyrazine C-577 Ethyl oxazolyl Caojingxazol C-578. Sitting on the herbicide, glufosin C-579, cyclobenzamide, oxazolidine C-580, killing grass, oxacillin 145027. Doc -65- 201026687 C-581 Triterpenoidone, oxacillin, C-582, valerate, oxacillin, C-583, benzalkonium, oxacillin, C-584, chlorpyrifos, grass, C-585, wild wheat嗤草嗤C-586 bensulfuron-methyl oxacillin C-587 bis-oxalate sodium solution oxazolidine C-588 sulfonate-oxazolidine C-589 oxasulfuron-methyl oxazolidine C-590 flurazepam Long-methyl-sodium oxazolidine C-591 methotrexate sulfamethoxazole C-592 oxazepam oxazolidine C-593 曱基咪草烟草. Sitting on C-594 灭 草 解 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C Coxazin C-599 methyl disulfuron-methyl oxacillin C-600 nicosulfuron-methyl oxazolidine C-601 penflufenacil oxazolidine C-602 propyl sulfonate sodium oxazolidine C-603速隆-ethylxoxacillin C-604 sulfasalazine oxacillin C-605 sulfomesulfuron-oxazolyl C-606 酿 确 解 解 解 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C Oxazole C-608 trifluorosulfonium oxazolazine C-609 2,4-D and its salt and ester oxazolidine C-610 chloramine pyridine acid and its salt and ester oxazolidine C-611 dipyridyl acid And its salt and esterified oxazolidine C-612 dicamba and its salt and ester oxazolidine C-613 fluorine gas than oxazolidine C-614 diazepam oxazolidine C-615 gas carbazide acid solution Oxazolidine C-616 D-9 oxazolidine C-617 diflupirtium oxazolidine C-618 difluoron pirone sodium oxacillin 145027. Doc -66- 201026687 C-619 Can be wiped out. S-C-620 fluroxypyrazine C-621 fluroxypyrazine oxazolidine C-622 iso- oxa oxazolone C-623 mesotrione oxazolidine C-624 fluorine ratio Valeric acid oxazolidine C-625 sulcotrien oxazolidine C-626 ketone ketoxime C-627 telbone oxazolidine C-628 tepamidone oxazolidine C-629 D-7 Oxazol C-630 Atrazine oxazolidine C-631 Diuron oxacillin C-632 Fluroxypyrazine C-633 Hexazinone oxazolidine C-634 Isoproxil "• Sitting C -635 oxazinone, oxacillin C-636, herbicidal oxazolidine C-637, chlorpyrifos C-638, paraquat dichloride, oxacillin C-639, propargyl fluoxetine, oxacillin C-640 Fulufen's oxazolidine C-641 Mesotricarbalazine C-642 D-1 oxazolidine C-643 D-2 oxazolidine C-644 phosphinothricin oxalate C-645 phosphinothricin Isopropylammonium oxalate. S-C-646 glufosinate-trimethylsulfate (oxathiophosphine), oxacillin C-647 glufosinate, oxacillin, C-648, glufosinate, oxazolidine C-649, schizoprost, C-650 Folin oxazolidine C-651 acetochlor oxazolidine C-652 oxazolamide oxazolidine C-653 refined dioxen chlorfenapyr scent C-654 four sage brewing I oxacillin C-655 flu Amlalazine C-656 fenfenin solution grass stalk 145027. Doc -67- 201026687 C-657 chlorfenapyr C-658 莫多草-s, oxacillin C-659, pyrocene, oxasulfone, oxacillin, C-660, isoxachlor, oxacillin C-661 Herbicide oxacillin C-662 oxadiazolidine C-663 稗 解 解 oxacillin C-664 trimethoprim oxazolidine C-665 atrazine + D-1 oxazolidine C-666 Atratropine + glufosinate, oxacillin C-667, atrazine, mesotrione, oxacillin, C-668, atrazine, nicosulfuron, chlorpyrifos C-669, Atra嗓 + Tebo Ketoxate C-670 Atlas + Tepami 腙 oxacillin C-671 Can be traced + glufosinate oxazolidine C-672 Fluramide + acetylene oxazolidine C-673 Fluorene Amine + refined ethyl oxazolyl grass chlorazol C-674 flufenazone + fluridine sulfonamide - methyl-sodium solution chlorpyrifos C-675 flufenacetate + glufosinate oxazolidine C-676 flufenamide + mercapto disulfuron-sulfonyl herbicide saliva C-677 fluroxypyramine + oxazolin ester lycopene C-678 fluroxypyr + methicillin herb η sit C-679 oxasulfuron + grass Amine phosphatidylcholine C-680 propargyl flufenacetate + glufosinate solution C-681 曱 咪 草 + + glufosinate oxazolidine C-682 imidazolium nicotinic acid + Amine phosphinoxazole C-683 嗯 σ 坐 嗣 + D-1 solution oxazolidine C-684 isoxaflutole + glufosinate oxazolidine C-685 chlorfenapyr + D-1 oxazolidine C -686 Metochlor + glufosinate, oxacillin C-687, chlorfenapyr + methyl oxazolone, oxacillin C-688, mesalamine + nicosulfuron, oxacillin, C-689, mesalamine + grass Triazepam C-690 chlorfenapyr + tepamida oxacillin C-691 oxazinone + glufosinate oxazolidine C-692 schide 圃 + D-1 oxazolidine C-693 schide 炔 + acetylene vinegar Xanthozol C-694 Shidezhen + refined ethyl oxazolyl and oxacillin 145027. Doc -68- 201026687 C-695 Sterling + Flunarsulfuron-sulfonyl-sodium oxazolidine C-696 Schmidt + glufosinate oxazolidine C-697 Schmidt + methyl disulfuron - methyl oxazolidine C-698 Shi Dezhen + mesotrione oxazolidine C-699 Shi Dezhen + Yuzui sylvestre C-700 Shi Dezhen +. Sitting on the grass, oxacillin, C-701, Shidezhen + sulfoxamide, oxacillin, C-702, Shidezhen + trebutone, oxazolidine C-703, Shi Deyu + Tepadi, 腙草, S, C-704, Pyroc Grasshopper + trebutone oxazolidine C-705 Pyrocene sulfone sulfone + tepamida oxacillin C-706 mesalamine + glufosinate oxazolidine C-707 Caojingjin + D-1 Xeroxazole C-708 Caojingjin + methotrexate sulforazepam C-709 Caojingjin + glufosinate oxazolidine C-710 Caojingjin + sulfosyl ketox oxacillin C-711 Jingjin + Nicosulfuron-loxacillin C-712 Caojingjin + Tebukenone Xanthozole C-713 Caojingjin + Tepami 腙 oxacillin C-714 Sanfulin + glufosinate C-715 acetylene oxalate dibenzoxazole C-716 ring chlorfenapyr C-717 cyhalofoprene benzene 11 oxalic acid C-718 refined ethyl oxazolyl oxalic acid benzene . Sour acid C-719. Sitting on the grass vinegar bis-oxazolyl C-720 Cyclohexanone dibenzoxazole C-721 to kill the grass dibenzoxazole C-722 toluene oxazolidine C-723 pento-dan Dibenzoxazole C-724 benzylidene bisbenzoic acid C-725 chlorpyrifos dibenzoxazole C-726 wild wheat dibenzoxazole C-727 bensulfuron-methyl benzoxazole C-728 bis-oxalate sodium dibenzoxazole C-729 sulfonate benzene 11 evil. Sour acid C-730 ° sitting pain glucosamine dibenzoxazole C-731 fluridine sulfasulfuron-methyl-n-bisbenzoxazole C-732 methotrexate bismuth acetophenone. Sitting acid 145027. Doc -69- 201026687 C-733 曱 咪 烟 双 双 双 双 - - - - - - - - - - C C C C C C C C C C C C C C C C C C C C C C C C喧 酸 双 双 双 - - - - - - - - - - - C C C C - C C C C C C C C C C C C C C C C C C C C C C C C C - - - - - - - - - - - Sulfonated benzene is evil. Guaic acid C-741 Nicosulfuron dibenzoxazole C-742 Pentafluorosulfonamide Diphenyl oxalic acid C-743 Propyl phthalocyanine Sodium dibenzoxazole C-744 Persian-Ethyl Bis-benzoxazole C-745 Methsulfuron dibenzoxazole C-746 Nicosulfuron-bisbenzoxazole C-747 Shiqi continued to double benzene. Sour acid C-748 methyl thianecarbazone dibenzoxazole C-749 trifluoromethanesulfonate dibenzoxazole C-750 2,4-D and its salt and ester bisoxazolyl C-751 Glycine pyridine acid and its salt and ester bisbenzene odor acid C-752 dipyridyl acid and its salt and ester bisbenzene 11 oxalate C-753 dicamba and its salt and ester bisoxazol C- 754 规 i gas ratio dibenzoxazole C-755 two gas 01 linoleic acid benzene oxalic acid C-756 chloroformin 'lead acid dibenzoxazole C-757 D-9 dibenzoxazole C -758 diflupiron dibenzophenone oxalic acid C-759 diflupironate dibenzoxazole C-760 can be traced dibenzoxazole C-761 fluroxypyrene benzene. Sour acid C-762 Fluorine 0 grasses Dibenzoxazole C-763 is not evil. Sputum bismuth oxazolidine C-764 曱 绩 绩 绩 双 双 双 双 - C C C C 氟 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C Anthrone bisoxazolchoic acid C-768 telbone dibenzoxazole C-769 Tepamidoxime dibenzoxazole C-770 D-7 Dibenzoxazole 145027. Doc -70- 201026687 C-771 Atrazine Dibenzoxazole C-772 Diuron Dibenzoxazole C-773 Fluroxypyrazine Dibenzoxazole C-774 Hexazone Dibenzoxazole C-775 Isoproturon dibenzoxazole C-776 oxaprofen dibenzoxazole C-777 herbicide bisphenol benzoate sit acid C-778 grass net bisoxazolidine C-779 paraquat Dichloride dibenzoxazole C-780 propargyl flufenate dibenzoxazole C-781 Fulufen dibenzoxazole C-782 acesulfame dibenzoxazole C-783 D-1 Diphenyl acetonin " siting acid C-784 D-2 dibenzoxazole C-785 glufosinate dibenzoxazole C-786 glufosinate-isopropylammonium dibenzoxazole C-787 grass Amine phosphine-trimethyl sulphate (phosphophos) dibenzoxazole C-788 glufosinate dibenzoxazole C-789 glufosinate dibenzoxazole C-790 Schmidt dibenzoxazole C -791 福福林 benzoxazole C-792 acetochlor dibenzoxazole C-793 oxacillin dibenzoxazole C-794 dimethenamid dibenzoxazole C-795 four 0 ketone bisbenzoxazole C-796 fluroxypyrene benzoic acid C-797 fentanyl dibenzoxazole C-798 Amine dibenzoxazole C-799 Motox-S dibenzoxazole C-800 Pyrocarb oxasulfone dibenzoxazole C-801 Isoxachlor benzene dibenzoic acid C-802 Kill Caolong double benzene ° oxalic acid C-803 grass _ bis benzene 嗤 嗤 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C D-1 Biphenyl 11 Oxalic acid C-807 Atla call + glufosinate bisphenol ° evil. Sitting acid C-808 Atla. Qin + mercapto sulfonate dibenzoxazole acid 145027. Doc •71 - 201026687 C-809 Atrazine + Nicosulfuron Dibenzophene. Sour acid C-810 Atrazine + trebutone dibenzoxazole C-811 Atratropine + Tepamidazole Dibenzoxazole C-812 Can be traced + glufosinate dibenzoxazole C-813 Fluroxypyrazine + clodinafop-butyl benzoxazole C-814 Flurazine + refined ethyl oxazolyl and oxazolidine C-815 Flurazine + Flunarsulfuron-methyl -Sodium bisbenzene phthalic acid C-816 Flurazine + glufosinate dibenzoxazole C-817 Fluramide + methyl disulfuron - methyl bisoxazol C-818 Fluramide + Oxazolamide dibenzoxazole C-819 Flurazine + sulfoxamide dibenzoxazole C-820 Azoxysulfuron + glufosinate bisbenzoquinone succinic acid C-821 Propyne fluoride Amine + glufosinate bisphenol oxime >> Sodium oxalate C-822 oxadiazone + glufosinate dibenzoxazole C-823 Imidazolium nicotinate + glufosinate dibenzoxazole C-824 Evil oxalicone + D-1 dibenzophenone. Oxyacid C-825 Isoxaflutole + glufosinate dibenzoxazole C-826 Moxachlor + D-1 Dibenzoxazole C-827 Metochlor + glufosinate dibenzoxazole C -828 chlorfenapyr + methyl chlorfenapyr dibenzoxazole C-829 chlorfenapyr + in the mouth of succinyl benzoxazole C-830 herbicide + oxazin dibenzoxazole C-831 Metochlor + tepamidazole bisbenzene decanoic acid C-832 oxazinone + phosphinothricin dibenzoxazole C-833 Schmidt + D-1 dibenzoxazole C-834 Schmidt + acetylene ester Dibenzoxazole C-835 Schmidt + refined ethyl oxazolyl and oxazolidine C-836 Schmidt + flonica sulfuron-methyl-sodium bisphenol oxalic acid C-837 Schmidt + grass Amine phosphine dibenzoxazole C-838 Schmidt + methyl disulfuron-mercapto bisphenylhydrazine. Sour acid C-839 Shi Dezhen + methyl oxalofen bisbenzene 11 oxalic acid C-840 Shi De 圃 + nicosulfuron bisbenzene ° evil. Sour acid C-841 Shi De 圃 + ° sitle oxalate dibenzoxazole C-842 Shi De 圃 + 曱 绩 绩 草 双 双 坐 C C C C C C 圃 特 特 特 特 特 特 特 特 特 特 特Tepami bis-benzoxazole C-845 Parox chlorpyrifos + trebutone dibenzoxazole C-846 Parox killing machine + tepamidone dibenzoxazole 145027. Doc -72- 201026687 C-847 Metotriamide + glufosinate dibenzoxazole C-848 Caojin + D-1 Diphenyl 11 oxalic acid C-849 Caojing + sulfonamide Benzoic acid C-850 Caojin + glufosinate dibenzoxazole C-851 Caojingjin + 曱 绩 绩 双 双 双 oxazoline C-852 Caojingjin + Nicosulfuron Chromoic acid C-853 oxazin + telobone dibenzoxazole C-854 Caojing + tepamidoxime dibenzoxazole C-855 Sanfolin + glufosinate dibenzoxazole C- 856 acetylene ester ° ratio. Sitting on the grass, C-857, chlorpyrifos, C-858, cyhalofop-butyl ester, °°°° solution, oxalic acid, C-859, refined ethyl oxazolyl, grass, 0, °, solution, grass, C-860 . Sitting on the grassy ester 0 to 0 sitting on the grass vinegar C-861 fenfenone ° ratio. Sitting on the herbicide C-862 to kill grass 0 to 0 sitting on the grass vinegar C-863 triterpenesone 0 to ° sitting grass vinegar C-864 pentosaurin pyrethroid C-865 benzyl oxacillin Zoloxacillin C-866 herbicide dapyrazol oxalate C-867 wild wheat ecstasy than the grass vinegar C-868 benzyl.密 隆 吡 吡 唑 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C隆隆-Methyl-Napyrazol oxalate C-873 Methionamine Clonopyrazole oxalate C-874 Methoxybutazone Pyrazole oxalate C-875 Methyl imazethapyrazole Ester C-876 is herbicide. C-877 β 喧 喧 喧 喧 C C C - - C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C隆-Methyl-sodium pyrazole oxalate C-881 methyl disulfuron-pyrazyl ester C-882 Yu Ming Zhun pyrazol solution C-883 pentafluorosulfonamide ° ratio 0 Vinegar C-884 propyl phenoxylate sodium ° than 0 sitting oxalate 145027. Doc -73- 201026687 C-885 Hundred-speed-ethylpyrazyl oxalate C-886 methoxyparacerine ° than 0 sitting vinegar C-887 acetal sulfonate " than ° sitting grass vinegar C -888 酿 项 隆 隆 隆 C C - - - - - - - - - - - - - C C C 比 比 比 比 比 比 比 比 比 比 - - - - - - - - - - - - - - - - - - And its salt and ester D ratio 0 解 草 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C 894 dicamba and its salt and ester 0 ratio. Sodium oxalate C-895 chlorofluoro ratio. Ratio ° ° lyophilized C-896 diclofenac pyrazole solution C-897 gas quinolinic acid pyrazole oxalate C-898 D-9 pyrazole oxalate C-899 diflupiron Pyrazole oxalate C-900 diflupirone sodium. Ratio ° ° lyophilized C-901 can be traced pyrazole oxalate C-902 fluroxypyrazine pyrethroid C-903 fluoro π grass _ pyrazole oxalate C-904 different ° evil grass _ ° ratio 0 oxalate ester C-905 mesotrione pyrazole oxalate ester C-906 flupirtine ° ratio ° sitting grass 酉 酉 C C-907 sulcotrione ° than the grass vinegar C-908 糠Ketone 0 than salivary vinegar C-909 telbone pyrazole oxalate C-910 Tepamid 腙 n ratio 0 圭 草 草 C C-911 D-7 pyrazole oxalate C-912 atrazine Pyrazole oxalate C-913 Diuron ° ° ° ° solution grass vinegar C-914 Fluroxypyrene 0 to 0 sitting on the grass 6 C-915 Six ° Qinkesin pyrazole solution C-916 Isoprolong D is 0 to sit the grass vinegar C-917 oxaprofen pyrazole ester C-918 herbicide chlorpyrifos ester C-919 grass net pyrazole oxalate ester C-920 paraquat dichloride pyrazole solution Herbyl ester C-921 propargyl fluramide pyrazole oxalate C-922 Fulufen ° 嗤 嗤 解 S 145027. Doc -74· 201026687 C-923 Methionine ° ratio. Sodium oxalate C-924 D-l pyrazole oxalate C-925 D-2. C-926 glufosinate pyrazyl ester C-927 glufosinate-isopropyl ammonium ° ratio. Sitting on the grass vinegar C-928 glufosinate-trimethylsulfanium salt (phosphosulfate) ° ° ° solution grass vinegar C-929 glufosinate 0 to ° sitting grass ester C-930 glufosinate σ ratio 0坐草草酯C-931 施德圃0比峻草草醋 C-932 二福林 0～0坐解草醋C-933 acetochlor 0°°坐草草酯 C-934 oxacillin 0-0解草S的C-935 精二曱参草胺0～0坐解草醋 C-936 四零坐_ pyrazolyl ester C-937 fluroxypyrazine pyrethroid C-938 ,is ·* ± chlorfenapyr C-939 chlorfenapyr ° ° lyophilized C-940 莫多草-S 0 than α 坐草草 S-C-941 Pyroside sulfone sulfone pyrazole Herbyl ester C-942 isoxachlor 0 is more than salivary vinegar C-943 chlorpyrifos 0 to 0 sitting on the grass S-C-944 oxazolidine pyridoxine C-945 de-pyrazole C-946 triflucloprium pyrazole oxalate C-947 atrazine + D-1 ° ratio lysine C-948 Atra call + glufosinate pyrazole oxalate C-949 Trauric acid + mesotrione pyrazole oxalate C-950 Atla call + Nicosulfuron-pyrazole herbicide C-951 Atrazine + telbone pyrazole oxalate C-952 Atrazine + Tepami腙pyrazolyl ester C-953 can be traced + glufosinate 0 to 0 sitting grass vinegar C-954 fluroxypyr + acetylene ester D ratio 0 sitting grass vinegar C-955 fluramide + refined ethyl Oxazole and Herbaceous 0 峻 草 草 C C - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - C-958 Fluroxyl + methyl disulfuron - methyl pyrazole herbicide C-959 Fluroxysporine + Junlin grass ester pyrazole herbicide C-960 Fluramide + methoxyoxalamine. Sitting on the grass vinegar than 0. 145027. Doc -75- 201026687 C-961 oxasulfuron + glufosinate pyrazole oxalate C-962 propargyl flufenacetate + glufosinate pyrazole oxalate C-963 methyl imazeth + oxalic acid Phosphonium pyridoxate C-964 imidazolium nicotinic acid + glufosinate 0 to 0 sitting grass vinegar C-965 iso ° evil ° sitting grass _ + Dl 0 to 0 sitting grass vinegar C-966 isoxaflutole + grass Amine phosphatidazole oxalate C-967 chlorfenapyr + D-1 pyrazolium ester C-968 chlorfenapyr + glufosinate pyrazole oxalate C-969 chlorfenapyr + methyl chlorpyrifos Zoloxacillin C-970 Metochlor + Nicosulfuron-Pyrylpyrimidine C-971 Metochlor + oxazolidine oxalate C-972 Metochlor + Tepamidazole Pyrimethamine Ester C-973 oxazinone + glufosinate 0 ratio.解草酯C-974 施德圃+D-1 0～0坐解草晔C-975 施德圃+Acetylpyrazole pyridoxate C-976 施德圃+精ethyloxazocilin and pyrazole oxalate C- 977 施德圃+Fluorite bite 隆 曱-曱-Nyprazole oxalate C-978 Shi De 圃 + glufosinate pyrazole oxalate C-979 Shi De 圃 + sulfhydryl disulfuron-purine pyrazole oxalate C -980 施德圃+Metsulfame ketone pyrethroid C-981 Shi Dezhen + 喷 确 隆 吡 吡 C C C C C - - - - 圃 圃 圃 圃 圃 - - - - - - - - - - - - - - - - - - - Phytopyrazine pyridyl ester C-984 Schmidt + terbolone ° ratio 0 sedative C-985 Shi Dezhen + tepamidoxib oxalate C-986 Pyrokiller grass 风 wind + trebutone Pyrazole oxalate C-987 Pyroside herbicide + Tepamidazole pyrazole ester C-988 Sulfenachlor + glufosinate pyrazole oxalate C-989 Caojingjin + D-1 Pyrazole oxalate C-990 Caojing + methotrexate sulfonium pyridoxine C-991 Caojingjin + glufosinate pyrazole oxalate C-992 Caojingjin + mesotrione Zoloxacillin C-993 Caojingjin + Yu Xiaoxiang Long Pyrazole oxalate C-994 Caojingjin + Tebufenone Pyrazol solution C-995 Caojingjin + Tepamidazole Pyrazole ester C-996 Sanfolin + glufosinate pyrazole oxalate C-991 acetylene ester D-12 C-998 ring kill Grass D-12 145027. Doc ·76· 201026687 C-999 Cyhalofoprin D-12 C-1000 Refined Ethyloxacillin D-12 C-1001. Sitting grass vinegar D-12 C-1002 Cyclohexanone D-12 C-1003 得草草 D-12 C-1004 三豆草酮 D-12 C-1005 戊草丹 D-12 C-1006 苯草Dan D-12 C-1007 herbicide D-12 C-1008 wild wheat D-12 C-1009 bensulfuron D-12 C-1010 bis-oxalate sodium D-12 C-1011 sulfonate D- 12 C-1012 Azoxysulfuron D-12 C-1013 Fluorine.定π密强隆-曱基-纳D-12 C-1014 甲 醯 续 续 D -12 D-12 C-1015 methoxyacetate D-12 C-1016 methyl imazeth D-12 C-1017灭草 D-12 C-1018 嗤喧 嗤喧 酸 D-12 C-1019 咪 π sit in acid D-12 C-1020 依速隆D-12 C-1021 蛾Continue-曱基-纳D- 12 C-1022 Methyl disulfuron D-12 C-1023 in the mouth continued to D-12 C-1024 pentafluorosulfonamide D-12 C-1025 propyl phenanthrene sodium D-12 C-1026 Bai Sulong -Ethyl D-12 C-1027 Methionine D-12 C-1028 Nisulfuron D-12 C-1029 Item Brewing D-12 C-1030 Methylthiane Carbachol D-12 C -1031 trifluorosulfuron D-12 C-1032 2,4-D and its salts and esters D-12 C-1033 guanamine pyridine acid and its salts and esters D-12 C-1034 clopyral acid and Salt and ester D-12 C-1035 dicamba and its salts and esters D-12 C-1036 chlorofluoro ratio D-12 145027. Doc -77- 201026687 C-1037 Diclofenac D-12 C-1038 gas quinolinic acid D-12 C-1039 D-9 D-12 C-1040 diflupiron D-12 C-1041 II Flurazine sodium D-12 C-1042 can be traced D-12 C-1043 Fluramine D-12 C-1044 Fluoridone D-12 C-1045 Isotox °Doxacin D-12 C- 1046 methyl oxaloacetone D-12 C-1047 fluorine ° valerin D-12 C-1048 continuous grass brewing I D-12 C-1049 sugar ketone D-12 C-1050 telobone D-12 C- 1051 Tepamidin D-12 C-1052 D-7 D-12 C-1053 Atrazine D-12 C-1054 Diuron D-12 C-1055 Flurazine D-12 C-1056 Hexazine Ketone D-12 C-1057 Isoproturon D-12 C-1058 °Qincaone D-12 C-1059 Herbicin D-12 C-1060 Caojing D-12 C-1061 Paraquat Dihydrate D- 12 C-1062 Propargyl fluoxetine D-12 C-1063 Fulufen D-12 C-1064 Methionine D-12 C-1065 D-1 D-12 C-1066 D-2 D-12 C -1067 glufosinate D-12 01068 glufosinate-isopropylammonium D-12 C-1069 glufosinate-trimethylsulfonate (phosphophos) D-12 C-1070 glufosinate D-12 C -1071 glufosinate D-12 C-1072 Shi Dezhen D-12 C-1073 二福林D-12 C-1074 Acetochlor D-12 145027. Doc -78* 201026687 C-1075 Azulamide D-12 C-1076 Dimethena D-12 C-1077 Tetrapropion D-12 C-1078 Fluramine D-12 C-1079 D-12 C-1080 Metochlor D-12 C-1081 Motox-S D-12 C-1082 Parox sulfone D-12 C-1083 Isoxachlor D-12 C-1084隆D-12 C-1085 oxatone D-12 C-1086 稗安D-12 C-1087 trimethoprim D-12 C-1088 atrazine + D-1 D-12 C-1089 Lahu + glufosinate D-12 C-1090 Atrazine + mercaptosulfone D-12 C-1091 Atrazine + nicosulfuron D-12 C-1092 Atra嗓 + Tebo Ketone D-12 C-1093 atrazine + tepamidazole D-12 C-1094 can be traced + glufosinate D-12 C-1095 fluramide + acetylene D-12 C-1096 fluroxypyr Amine + refined ethyl oxazolyl D-12 C-1097 fluroxypyr + flurizine - methyl - sodium D-12 C-1098 fluramide + glufosinate D-12 C-1099 fluoride Oxalamide + methyl disulfuron - methyl D-12 C-1100 fluroxypyr + t sitting on the grass D-type C-12101 fluroxypyr + oxime o-chlorin D-12 C-1102 Sulfosin + glufosinate D-12 C-1103 propargyl flufenacetate + glufosinate D-12 C-1104 methyl imazethin + glufosinate D-12 C-1105 Imidazoic acid + glufosinate D-12 C-1106 Isoformin _+D-1 D-12 C-1107 Isooxazolone + glufosinate D-12 C-1108 Metochlor + D -1 D-12 C-1109 chlorpheniramine + glufosinate D-12 C-1110 chlorfenapyr + thiol oxalate D-12 C-llll chlorfenapyr + rinsing D-12 C-1112 Metochlor + Caojingjin D-12 145027. Doc -79- 201026687 C-1113 Metochlor + Tepamidin D-12 C-1114 Oxazolone + Glufosinate D-12 C-1115 Schmidt + D-1 D-12 C-1116 Schmidt + acetylene Ester D-12 C-1117 Schmidt + refined ethyl oxazolyl D-12 C-1118 Schmidt + fluridine sulfonamide-mercapto-sodium D-12 C-1119 Schmidt + glufosinate D-12 C -1120 施德圃+Methyldisulfuron-methyl D-12 C-1121 施德圃+曱 sulfenate D-12 C-1122 Shi Deqi + Nicosulfuron D-12 C-1123 Shi Dezhen + Salicylate D -12 C-1124 施德圃+曱氧司草胺 D-12 C-1125 施德圃+特博酮D-12 C-1126 施德圃+特帕米腙D-12 C-1127 派罗克草草飒+特博Ketone D-12 C-1128 Parox sulfoxide + Tepamidin D-12 C-1129 Mesalamine + glufosinate D-12 C-1130 Caojing + D-1 D-12 C- 1131 Caojingjin + methotrexate D-12 C-1132 Caojingjin + glufosinate D-12 C-1133 Caojingjin + mesotrione D-12 C-1134 Caojingjin + Nico Sulfuric acid D-12 C-1135 Caojing + Tebufenone D-12 C-1136 Caojingjin + Tepamidin D-12 C-1137 Sanfulin + glufosinate D-12 C-1138 2- 1 —— C-1139 2-2 —— C-1140 2-3 C-1141 2-4 — C-1142 2-5 — C-1143 2-6 — C-1144 2-7 — C-1145 2-8 — C-1146 2-9 — C-1147 2-1 Sulfone C -1148 2-2 oxaloacetone C-1149 2-3 oxaloacetone C-1150 2-4 oxaloacetone C-1151 2-5 oxaloacetone 145027. Doc -80- 201026687 C-1152 2-6 oxaloacetone C-1153 2-7 oxaloacetone C-1154 2-8 oxaloacetone C-1155 2-9 oxaloacetone C-1156 2-1 detoxification 喧C -1157 2-2 detoxification 喧C-1158 2-3 detoxification 喧C-1159 2-4 detoxification quinolin C-1160 2-5 detoxification quinone C-1161 2-6 detoxification 啥C-1162 2-7 detoxification 喧C-1163 2-8 detoxified quinone C-1164 2-9 detoxification 喧C-1165 2-1 solution sulfonamide C-1166 2-2 sulforaphane C-1167 2-3 solution sulfonamide C-1168 2 -4 oxasulfonamide C-1169 2-5 sulforaphane C-1170 2-6 sulforaphane C-1171 2-7 sulforaphane C-1172 2-8 Amine C-1173 2-9 oxasulfonamide C-1174 2-1 dichloropropenylamine C-1175 2-2 dichloropropenylamine C-1176 2-3 dichloropropenylamine C-1177 2-4 dichloro Acrylamine C-1178 2-5 Dichloropropenylamine C-1179 2-6 Dichloropropenylamine C-1180 2-7 Dichloropropenylamine C-1181 2-8 Dichloropropenylamine C-1182 2-9 Dichloro Propylene amine C-1183 2-1 solution oxazolidine C-1184 2-2 oxacillin C-1185 2-3 solution oxazolidine C-1186 2-4 solution oxazolidine C-1187 2-5 oxacillin C-1188 2-6 oxacillin C-1189 2-7 oxacillin 145027. Doc •81 - 201026687 C-1190 2-8 Coxazin C-1191 2-9 Coxazin C-1192 2-1 Dibenzoxazole C-1193 2-2 Dibenzoxazole C-1194 2- 3 Dibenzoxazole C-1195 2-4 Dibenzoxazole C-1196 2-5 Dibenzoxazole C-1197 2-6 Dibenzoxazole C-1198 2-7 Dibenzoxazole C-1199 2-8 Dibenzoxazole C-1200 2-9 Dibenzoxazole C-1201 2-1 0 to 0 sitting grass vinegar C-1202 2-2 0 to 0 sitting grass vinegar C- 1203 2-3 pyrazolium ester C-1204 2-4 pyrazolyl ester C-1205 2-5 pyrazole herbicide C-1206 2-6 0 ratio 0 sitting grass vinegar C-1207 2-7 Pyrazole oxalate C-1208 2-8 . More than 0 sitting grass vinegar C-1209 2-9 ° than 嗤 草 vinegar C-1210 2-1 D-11 C-1211 2-2 D-11 C-1212 2-3 D-11 C-1213 2- 4 D-11 C-1214 2-5 D-11 C-1215 2-6 D-11 C-1216 2-7 D-11 C-1217 2-8 D-11 C-1218 2-9 D-11 C -1219 2-1 D-12 C-1220 2-2 D-12 C-1221 2-3 D-12 C-1222 2-4 D-12 C-1223 2-5 D-12 C-1224 2-6 D-12 C-1225 2-7 D-12 C-1226 2-8 D-12 C-1227 2-9 D-12 145027. Doc • 82 - 201026687 The combination of active compounds A and B and their agriculturally useful salts is suitable as a herbicide in the form of a mixture of isomers and in the form of pure isomers. It is suitable as such or as a suitable formulated composition. Herbicidal compositions comprising a combination of active compounds A and B, in particular preferred aspects thereof, are extremely effective in controlling vegetation on non-crop areas, particularly at high application rates. It acts as a broadleaf weed and grass weed in crops (eg, wheat, glutinous rice, corn, soybeans, and cotton) and does not cause any significant damage to crop plants. φ was observed mainly at low application rates. Depending on the method of application, combinations of active compounds 8 and 3 and optionally c and/or D, in particular preferred embodiments thereof, or compositions comprising the same may additionally be used in a large number of crop plants. To remove undesired stolen goods. Examples of suitable crops are those mentioned in the opening paragraphs. [Embodiment] The term "crop plant" also includes plants modified by breeding, mutagenesis or genetic engineering. Genetically modified plant line genetic material has been modified by hybridization, mutation or natural recombination (i.e., recombination of genetic information) in a manner that would not occur under natural conditions. In general, one or more genes are integrated into plant genetic material to improve plant characteristics. Accordingly, the term "crop plant" also includes plants which have been rendered tolerant to certain classes of herbicides by breeding and genetic engineering, such as hydroxyphenylpyruvate magnesium oxide (HppD) inhibitors; Acetyl lactate synthase (ALS) inhibitors, such as sulfonylureas (Ερ_Α 257 993, μ 5,013,659) or imidazolinones (for example, see us 6 222 i〇(), w〇01/82685 ^ WO 00/26390 ^ WO 97/41218 ^ WO 98/02526, 145027. Doc • 83· 201026687 WO 98/02527, WO 04/106529, WO 05/20673, WO 03/14357, WO 03/13225, WO 03/14356, WO 04/16073); enol acetone oxalic acid-3· Phosphate synthase (EPSPS) inhibitors, such as glufosinate (see, for example, WO 92/00377); glutamine amine synthase (GS) inhibitors, such as glufosinate (see, for example, EP-A 242 236, EP) -A 242 246); or ioxynil herbicide (see, for example, US 5,559, 〇 24). Various crop plants that tolerate imidazolinones (e.g., imazamox) (e.g., Clearfield® canola) have been produced by conventional breeding methods (mutagenesis). Plants (eg, soybean, cotton, corn, sugar beet, and canola) that are commercially available under the trade names RoundupReady® (liphthylphosphine) and Liberty Link® (glyphosate) have been genetically engineered (eg, soybean, cotton, corn, sugar beet, and canola) Engineering methods are produced. Thus, the term "crop plant" also includes plants which are genetically engineered to produce one or more toxins, such as the toxins of their bacterial strain Bacillus ssp. Toxins produced by such genetically modified plants include, for example, Bacillus (in particular, Bacillus thuringiensis (B.  Thuringiensis)) insecticidal proteins such as endotoxin CrylAb, CrylAc, CrylF, CrylFa2, Cry2Ab, Cry3A, Cry3Bbl, Cry9c, Cry34Abl or Cry35Abl; or vegetative insecticidal proteins (VIP) such as VIP1, VIP2, VIP3, or VIP3A An insecticidal protein of a nematode colonizing bacterium, such as Photorhabdus spp. ) or pathogenic genus (Xenorhabdus spp. Insect protein; toxins of animal organisms, such as wasps, spiders or toxins; mycotoxins, such as from Streptomycete; plant lectins, such as from cowpea or barley; lectins; Inhibitors, such as trypsin inhibitors, 145027. Doc •84- 201026687 A serine protease inhibitor, a potato storage protein (patatin), a cysteine protease inhibitor or a papain inhibitor; a ribosome inactivating protein (RIP), such as ricin, corn-RIP, Acacia, leukol, saporin or xanthine; steroid metabolism enzymes such as 3-hydroxysteroid oxidase, ecdysone-IDP glycosyltransferase, cholesterol oxidase, ecdysone inhibitor, Or HMG-CoA reductase; ion channel blockers, such as nanochannel or feeder channel inhibitors; juvenile hormone g enzyme; diuretic hormone receptor (helicokinin receptor); diphenylethylene synthase , bibenzyl synthase, chitinase and glucanase. In plants, the toxins may also be produced in the form of protoxins, hybrid proteins or truncated proteins or proteins modified in other ways. Hybrid proteins are characterized by novel combinations of different protein domains (see, for example, WO 2002/015701). Further examples of such toxins or genetically modified plants which produce such toxins are disclosed in EP-A 374 753, WO 93/007278, WO 95/34656, EP-A 427 529, EP-A 451 8 78, WO 03/ 0188 10 and WO 03/052073. Methods of producing such genetically modified plants are known to those skilled in the art and are disclosed, for example, in the above publication. A variety of these toxins confer tolerance to all arthropod-classified pests of plants producing such toxins, specifically against aphids • (Coeleropta), double-winged insects (Diptera) And the financial acceptability of butterflies (Lepidoptera) and nematodes (Nematoda). Genetically modified plants capable of producing one or more genes encoding insecticidal toxins are described, for example, in the above publications, and some of which are commercially available, such as YieldGard® (a corn variety that produces toxin CrylAb), YieldGard ® 145027. Doc • 85 - 201026687

Plus (corn varieties producing toxins Cry 1 Ab and Cry3Bbl), Starlink® (corn varieties producing toxin Cry9c), Herculex® RW (production of toxin Cry; 34Abl, Cry35Abl and enzymatic glufosinate-N-acetyltransferase [ pAT] corn variety); NuCOTN® 33B (cotton variety producing toxin CrylAc), Bollgard® 1 (cotton variety producing toxin CrylAc), Bollgard® Π (cotton variety producing toxin CrylAc and Cry2Ab2); VIPCOT® (generating Vlp) Tobacco varieties of toxins; NewLeaf® (potato varieties producing toxin Cry3A); Bt-Xtra®, NatureGard®, KnockOut®, BiteGard®, Protecta® 'Btll (eg Agrisure® CB) and Btl76 from Syngenta Seeds SAS, France (Maize varieties producing toxin CrylAb and PAT enzymes), MIR604 from Syngenta Seeds SAS, France (modified corn varieties producing toxin Cry3 A, see WO 03/018810), MON 863 from Monsanto Europe SA, Belgium Producing toxin

Cry3Bb 1 corn variety), IPC 531 from Monsanto Europe S. A., Belgium (modified cotton variety producing toxin CrylAc) and

From Pioneer Overseas, Belgium, 1507 (a corn variety that produces toxins such as CrylF and PAT). Thus, the term "crop plant" also includes plants which can be genetically engineered to produce one or more proteins which are enhanced or enhanced by resistance to bacterial, viral or fungal pathogens, such as pathogen-associated proteins (PR protein, see EP-A). 0 3 92 225), resistance proteins (eg, a potato variety that produces two resistance genes against Phytophthora infestan, derived from wild type Mexican potato (Solanum bulbocastanum)) or T4 lysozyme (eg A potato variety that is resistant to P. infestans 145027.doc -86-201026687 (Erwinia amylV0ra) by producing this protein. Therefore, the term "crop plant" also includes plants that have been genetically engineered to improve productivity, for example by increasing potential yields (eg biomass, porphyrin yield, starch, oil or protein content), for drought, salt or other Tolerance to restrictive environmental factors, or resistance to pests and fungal, bacterial and viral pathogens. The term "crop plant" also includes plants which have been modified by means of the gene I-way method for the purpose of improving human or kinetics, for example by producing health promoting long-chain (10) fatty acids or mono-saturated fatty acids. Plants (eg Nexera® canola). The term "crop plant" also includes plants which have been modified by genetic engineering for the purpose of improving the yield of raw materials, for example by increasing the amylopectin content in potato (Amflora® potato). Furthermore, it has been found that the combination of active compounds VIII and 5 is also suitable for the shedding and/or drying of plant parts, and is suitable for crop plants such as cotton, potato, oil Φ, sunflower, soybean or cowpea, in particular cotton. In this regard, it has been found that there are compositions for using the formula for drying and/or shedding of plants, methods for preparing such compositions, and methods for drying and/or shedding plants. As a desiccant, the compounds of formula I are particularly useful for detaching the aerial parts of crop plants such as potatoes, canola, sunflower and soybeans, and loquat. This makes it possible to fully mechanize the harvesting of these important crop plants. Also of economic value are other varieties and varieties that are beneficial for harvesting citrus fruits, rituals and pome fruits, stone fruits and nuts, which can be reduced by concentrating the 145027.doc -87- 201026687 within a certain period or reducing the tree The adhesion is achieved. The same mechanism, i.e., promoting the formation of the detachment tissue between the plant fruit portion or the leaf portion and the stem portion, is also critical to the easy controlled release of useful plants, in particular cotton. In addition, shortening the time interval between individual cotton plant maturation can improve post-harvest fiber quality. The active compound or the herbicidal composition comprising the same can, for example, be an instant spray of an aqueous solution, a powder, a suspension, and a high concentration aqueous, oily or other suspension or dispersion, emulsion, oil dispersion, paste, powder, The substance, or particulate form, is applied by spraying, spraying, dusting, spreading, watering or treating the seed or mixing with the seed. The use of the form depends on the intended purpose, and in each case it should ensure the finest possible distribution of the active compound of the invention. The herbicidal compositions comprise a herbicidally effective amount of at least one active compound hydrazine and at least one active compound B or an agriculturally useful salt thereof, and an adjuvant conventionally used in the formation of a crop protection agent. Examples of adjuvants useful for forming crop protection agents are inert adjuvants, solid carriers, surfactants (eg, dispersants, protective colloids, emulsifiers, wetting agents, and tackifiers), organic and inorganic thickeners. , fungicides, antifreezes, defoamers, optionally colorants and adhesives formed with seeds. Examples of thickeners (i.e., compounds which impart improved flow characteristics to the formulation (i.e., compounds having high viscosity at rest and low viscosity when in motion) are polysaccharides such as xanthan gum (Kelzan® from Kelco). , Rhodopol® 23 (Rhone Poulenc) 4Veegum® (from RT Vanderbi and 145027.doc 201026687 machine and inorganic sheet material 'eg Attaclay® (from Engelhardt). Examples of defoamers are polyoxyl emulsions (eg from Rhodia) Silik〇n® SRE, Wacker or Rhodorsil®), long-chain alcohols, fatty acids, fatty acid salts, organofluorine compounds and mixtures thereof. "T add an analgesic to stabilize aqueous herbicide formulations. Examples of fungicides are double Phenol and benzyl alcohol hemiacetal (Proxel® from ICI or from

Actitech® RS from Thor Chemie and Kathon® MK from R〇hm & Haas) and isothiazolinone derivatives (eg alkylisothiazolinone and benzopyrene _ (from Th〇r chemie) Aeticide MBS) is a main fungicide. Examples of anti-reinforcing agents are ethylene glycol, propylene glycol, urea or glycerin. Examples of coloring agents are both micro-water-soluble pigments and water-soluble dyes. The following dyes: Rh damin B, CI Pigment Red 112 and cI·Solvent Red 1, and Pigment Blue 15:4, Pigment Blue U:3, Pigment Blue 15:2, Pigment Blue i5:i , Pigment Blue 8〇, Pigment Astragalus, Yan® Material Yellow 13, Pigment Red 112, Pigment Red 48:2, Pigment Red 48:1, Pigment Red 57:1, Pigment Red 53:1, Pigment Orange 43, Pigment Orange 34, Pigment Orange 5, Pigment Green, Pigment Green 7, Pigment White Pigment, Pigment Brown 25, Alkaline Violet 1〇, Alkaline Violet 49, Acid F Health, Work 5 1 , Acid Red 5 2, Acid Red 14 Acid blue 9, acid yellow 2 3, test red 1 〇, test red 1 〇 8. Examples of adhesives are polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol and sulfhydryl Cellulose. Suitable inert adjuvant system (for example;) below: mineral oil fraction from medium to rain point, such as kerosene and diesel oil; and coal char 145027.doc -89· 201026687 oil and vegetable oil or animal oil; aliphatic hydrocarbon, ring Hydrocarbons and aromatics, for example, stellite, tetrahydronaphthalene, alkylated naphthalene and its derivatives, alkylated benzene and its derivatives; alcohols such as 'decanol, ethanol, propanol, butanol and cyclohexanol Ketones, for example, cyclohexanone or a highly polar solvent 'for example, amines such as N-methyl ketone and water 0 solid carrier-based mineral earth powder, kaolin, limestone soil, dolomite, diatomaceous earth such as alumina , 矽 gel, citrate, talc lime, chalk, red basalt, loess, calcium sulfate, magnesium sulfate and magnesium oxide, after grinding a into a material month & Ammonium and urea, and plant-derived products such as cereal meal, bark meal, wood flour and nut shell powder, cellulose powder or other solid carrier. Suitable surfactants (adjuvants, wetting agents, tackifiers) , dispersant and emulsifier) are aromatic sulfonic acids (example Lignosulfonic acid (eg B〇rrespers type, Borregaard), phenolic sulfonic acid, naphthalenesulfonic acid (M〇rwet type, Akz〇Ν〇ι^) and dibutylnaphthalenesulfonic acid (Nekal type, BASF SE) And alkali metal salts, alkaline earth metal salts and ammonium salts of fatty acids, alkyl groups and alkyl aryl sulfonates, alkyl sulfates, lauryl ether sulfates and fatty alcohol sulfates, and sulfated hexagrams, Hexa- and octadecanol alkoxides, and fatty alcohol glycol ethers, condensates of sulfonated naphthalenes and their derivatives with formaldehyde, condensates of naphthalene or naphthalenesulfonic acid with phenol and formaldehyde, polyoxyethylene ethyl octyl phenol Ether, ethoxylated isooctyl, octyl or nonylphenol, alkylphenyl or dibutylphenyl polyglycol ether, alkyl aryl polyether alcohol, isododecyl alcohol, Fatty alcohol/ethylene oxide condensate, ethoxylated castor oil, polyoxyethylene ethyl ether or polyoxypropyl propyl ether, polyethylene glycol lauryl ether acetate, sorbitol ester, Lignin sulfite waste liquid and protein, change 145027.doc •90· 201026687 Sex protein, polysaccharide (such as methyl cellulose), hydrophobically modified starch, polyvinyl alcohol Mowiol type Clariant), polycarboxylate (BaSF SE, Sokolan type), poly(Alkoxide), polyvinylamine (BASF SE, Lupamine type), polyethylenimine (BASF SE 'Lupasol type), poly Vinyl" pirone and its copolymers. Powders, spreadable materials and dusts can be prepared by mixing or simultaneously grinding the active ingredient with a solid carrier. φ can be prepared by incorporating the active compound into a solid carrier, such as coated granules, impregnated granules, and granules. Aqueous use forms can be prepared by adding water from emulsion concentrates, suspensions, pastes, wettable powders or water-dispersible granules. For the preparation of emulsions, pastes or oil dispersions, the compounds of the formula I or I a can be homogenized in the original state or dissolved in oils or solvents by means of wetting agents, tackifiers, dispersants or emulsifiers in water. . Alternatively, concentrates containing active substances, wetting agents, tackifiers, knife or emulsifiers and, if desired, solvents or oils may be prepared, such concentrates being suitable for dilution with water. The concentration of the compound of formula I in the ready-to-use formulations can vary over a wide range. In general, the formulation comprises from 0.001 to 98% by weight, preferably from 1 to 95% by weight, based on the J active compounds. The purity of the active compound used is from 90 ° / 〇 to 100%, preferably from 95% to 1% by weight (according to NMR spectrum). The combination of the invention can be formulated, for example, as follows: 1 - Product A diluted in water A water-soluble concentrate 1 part by weight of the active compound is dissolved in 90 parts by weight of water or water 145027.doc -91 - 201026687 Solubility In the solvent. As an alternative, a wetting agent or other adjuvant may be added. The active compound is dissolved after dilution with water. Thereby, a formulation having an active compound content of 1 〇 weight / 〇 is formed. B dispersible concentrate 20 parts by weight of the active compound is dissolved in 7 q parts by weight of the ring, while adding 10 parts by weight of the dispersing agent (for example, polyvinylpyrrolidone diluted by water to form a dispersion The active compound is contained in an amount of 2% by weight. c. Emulsifying concentrate 15 parts by weight of the active compound is dissolved in 75 parts by weight of an organic solvent (for example, an alkyl aromatic compound) while adding twelve Calcium alkylbenzene sulfonate and ethoxylated castor oil (add 5 parts by weight in each case). Dilute with water to form an emulsion. This formulation has an active compound content of 15% by weight. 25 parts by weight of the active compound are dissolved in 35 parts by weight of an organic solvent (for example an alkylaromatic compound) with the addition of calcium dodecylbenzenesulfonate and ethoxylated castor oil (added in each case) 5 parts by weight. The mixture was introduced into 3 parts by weight of water by means of an emulsifier (for example Ultraturrax) and made into a homogeneous emulsion. The emulsion was diluted with water. The formulation had an active compound content of 25% by weight. Ε The suspension is pulverized in an agitating ball mill to 20 parts by weight of the active compound, and 10 parts by weight of a dispersing agent and a wetting agent and 70 parts by weight of water or an organic solvent are added to form a fine active compound suspension. A stable suspension of the active compound is formed. The content of the active compound in the formulation is 2〇145027.doc -92- 201026687% by weight. The F water dispersible granules and the water-soluble granules are finely ground by 50 parts by weight of the active compound, Adding 50 parts by weight of dispersant and wetting agent, and making it into water dispersible granules or water-soluble granules by means of technical instruments (such as extruder, spray tower, fluidized bed). Stable dispersion or solution of the active compound. The formulation has an active compound content of 50% by weight. G water dispersible powder and water-soluble powder 75 parts by weight of active compound are ground in a rotor-stator grinder while adding 25 Parts by weight of dispersing agent, wetting agent and silicone gel. After dilution with water, a stable dispersion or solution of the active compound is formed. The content is 75% by weight. Η Gel formulation Grinding 20 parts by weight of active compound, 1 part by weight of dispersant, 1 part by weight of gelling agent and 70 parts by weight of water or organic solvent in a ball mill Tanning agent to form a fine suspension. Dilution with water to form a stable suspension with an active compound content of 20% by weight 2. Product I can be applied without dilution I Dust finely grind 5 parts by weight of active compound and make it with 95 weight The fine kaolin is mixed well to form a powdered powder having an active compound content of 5 wt./j. J particles (GR, FG, GG, MG) finely grind 0.5 parts by weight of the active compound and make it 99.5 Parts by weight 145027.doc •93· 201026687 A mixture of carriers. The current process here is extrusion, spray drying or fluidized bed. Thereby, particles which can be applied without dilution at an active compound content of 0.5% by weight are formed. K ULV solution (UL) 10 parts by weight of the active compound is dissolved in 9 parts by weight of an organic solvent such as diphenylbenzene. Thereby, a product which can be applied without dilution at an active compound content of 1% by weight is formed. The active compound or the herbicidal composition comprising the same can be applied pre-emergence or post-emergence or with crop seeds. The herbicidal composition or active compound can also be applied by applying a crop plant seed pretreated with the herbicidal composition or the active compound. If some of the crop plants are less tolerant to the active compound, application techniques for spraying the herbicidal compositions by means of a spray device can be used, such that the herbicidal compositions are as close as possible to the sensitive crop plant leaves. At the same time, the active compound can reach the surface of the leaves or bare soil of the undesired plants grown under the plants of the crops (after directional spraying, loose soil). In the examples, the active compound or the herbicidal composition can be applied by treating the seed. Human seed treatment comprises a formula based on the present invention or a preparation prepared therefrom, which is well known to those skilled in the art (seed dressing, seed coating, seed dusting, seed soaking, seed film coating, seed multi-layer coating). Cloth, seed coating seed drip and seed pelleting). Here, the herbicidal composition can be applied dilutely or without dilution. The term seed encompasses all types of seeds, for example, grains, seeds, fruits, I45027.doc 201026687 rhizomes, cuttings and the like. Preferably, the term seed herein refers to granules and seeds. The seed used may be the seed of the above useful plant, and the seed of the plant obtained by the transgenic plant or the self-cultivation breeding method. The required application rate of the pure active compound composition (ie A and B) and, if appropriate, the C/D of the formulation-free adjuvant, depends on the composition of the plant stand, the stage of development of the plant, and the climatic conditions at the site of use. And depending on the application technique. In general, the application rates of ❿ A and B and, if appropriate, c/D are 0.001 to 3 kg/ha, preferably 0.005 to 2.5 kg/ha and in particular 〇·〇ι to 2 kg/ha active substance (as). The required application rate of the active compound A is usually in the range of from 0.0005 kg/ha to 2.5 kg/ha a_s. and preferably from 〇〇〇5 kg/ha to 2 kg/ha or from 0.01 kg/ha to 1·5 kg/ Within the h as range. The required application rate of the active compound B is usually in the range of 0.0005 kg/ha to 2.5 kg/ha as and preferably in the range of 0.005 kg/ha to 2 kg/ha or 0.01 kg/ha to 1,5 kg/h as . _ The required application rate of active compound C is usually in the range of 0.0005 kg/ha to 2.5 kg/ha as and preferably in the range of 0.005 kg/ha to 2 kg/ha or 0_01 kg/ha to 1.5 kg/h as . The required application rate of the protective agent D is usually in the range of 〇〇〇〇5 kg/ha to 2.5 kg/ha as and preferably from 0〇〇5 kg/ha to 2 kg/ha or 0.01 kg/ha to 1.5 kg. Within the range of /h as. The composition is applied to the plant primarily by spraying on the leaves. Here, application can be carried out using, for example, water as a carrier by a conventional spraying technique using a spray amount of about 1 Torr to 丨〇〇〇 Ι /ha (for example, 300 to 400 Ι / ha). Herbicidal compositions 145027.doc • 95- 201026687 can also be applied by low volume or ultra low volume methods or in the form of microparticles. The active compound or the herbicidal composition comprising the same can be applied pre-emergence or post-emergence or with crop seeds. The compositions can also be applied by applying the seeds of the crop plants pretreated with the compositions of the invention. If some of the crop plants are less tolerant to the active compounds A and B and, if appropriate, C, application techniques for spraying the herbicidal compositions by means of a spray device can be used, such that the herbicidal compositions are as low as possible Contact with leaves of sensitive crop plants, while the active compound can reach the surface of the leaves or bare soil of undesired plants grown under the plants of the crops (after directional spray, loose soil). In another embodiment, the composition can be applied by treating the seed. Seed treatment comprises essentially all procedures well known to those skilled in the art based on the formula [compounds or compositions prepared therefrom (seed dressing, seed coating, seed dusting, seed soaking, seed film coating, seed multi-layering) Coating, seed coating, seed dripping and seed pelleting). Here, the herbicidal composition can be applied dilutely or without dilution. The term seed encompasses all types of seeds, for example, grains, seeds, fruits, rhizomes, cuttings and the like. Preferably, the term seed herein refers to grains and seeds. The seed used may be the seed of the above useful plant, and the seed of the plant obtained by the transgenic plant or the self-cultivation breeding method. The application rate of the active compound is 0.001 to 3.0, preferably 0.01 to 1.0 kg/ha, and the active compound (aS) is the treated seed. The amount of the compound I is usually 0.001. Up to 10 kg / 100 kg of seed. 145027.doc 201026687 Furthermore, it may be useful to apply the active compound alone or in combination with other crop protection compositions, such as 'in combination with a composition for controlling pests or phytopathogenic fungi or bacteria, or with a population of growth regulating active compounds. of. Also of concern are the miscibility with mineral salt solutions used to alleviate nutrient and trace element deficiency. Other additives such as phytotoxic oils and oil concentrates may also be added. The active compounds and compositions of the invention may also have a plant strengthening effect. Φ Therefore, it is suitable for defensive systems that mobilize plants against undesired microbes (eg, harmful fungi, as well as viruses and bacteria). Plant-fortified (resistance-inducing) substances are understood to mean, in the context of the present invention, substances which are capable of stimulating the defense system of the treated plant, in such a way that, upon subsequent inoculation by undesired microorganisms, the treated plants Microorganisms exhibit a significant degree of resistance. The active compound can be used to protect plants from attack by undesirable microorganisms for a specific period of time after treatment. The protection effective period is usually from 1 day to 28 days, preferably from 1 day to 14 days after treatment with the compound worker #, or up to 9 months after the seed is treated and sown. The active compounds and compositions of the invention are also suitable for increasing harvest yield. Furthermore, it has low toxicity and the plants are well tolerated. The following examples are intended to illustrate the invention. EXAMPLES The herbicidal activity of the active compound combination was confirmed by the following greenhouse experiments. The medium container used was a plastic bottle containing about 5.8% of humus sandy soil as a smile. Seeds of the test plant seeds are separately sown. 145027.doc •97· 201026687 For pre-emergence treatment, the active compound suspended or emulsified in water is applied directly after sowing by means of a finely distributed nozzle. The container is slowly washed to promote germination and growth and then covered with a clear plastic shield until the plants are rooted. Unless the cover has been damaged by the active compound, it will allow the test plant to germinate evenly. For post-emergence treatment, the test plants were initially grown to a height of 1 _ 5 to 15 cm and then treated with an active compound suspended or emulsified in water. For this purpose, the test plants can be directly sown and grown in the same container, or they are initially grown separately from the seedlings and transplanted into the test container a few days prior to treatment. Depending on the type of plant, keep plants at 10 °C to 25 °C or 20 °C to 35 °C. The test period is extended by 1 to 4 weeks. During this time, the plants are taken care of and their response to each treatment is assessed. Evaluations were performed using a scale of 0 to 100. 100 means that the plant is not budding or at least the aerial part is completely destroyed, and 0 means no damage or the growth process is normal. Good herbicidal activity is obtained at a value of at least 70 and excellent herbicidal activity is obtained at a value of at least 85. The plants used in the greenhouse test belong to the following varieties: Bayer Code name Scientific name ALOMY Alopecurus myosuroides Rattle blackgrass CONAR Convolvulus arvensis Arrow leaf Field bindweed) MATIN Xinjiang Matricaria inodora scentless chamomile SETFA Setaria faberi big foxtail SETVI Setaria viridis green foxtail STEME 繁体) common chickweed THLAR Salary (Thlaspi arvense) field pennycress 145027.doc • 98 - 201026687 The results of these tests are listed below using the tables in Examples 1 to 9 and confirmed to contain at least one A synergistic effect of a mixture of active compound A and at least one active compound B. Here, a.s. = active substance, based on 100% active compound. In the following Examples 1 to 9, the value E calculated according to Colby is listed in parentheses (). 'Use Example 1: The application rate of the synergistic herbicidal active compound as in combination with A-9 and B-1 obtained by the pre-emergence method, and the resistance to the herbicidal activity SETVI t after 20 days in g/ha % indicates STEME A-9 63 50 - 125 70 65 30 B-1 16 45 80 20 31 65 80 30 A-9 + B-1 63 + 16 75 (73) - - 125 + 16 100(93) 65 (44 125 + 31 98 (89.5) 100(93) 75 (51) Use example 2: Application rate of synergistic herbicidal active compound as in combination of A-10 and B-1 obtained by pre-emergence method, expressed in g/ha 20 days later, resisting J MATIN following weeding SETVI t, expressed in % STEME A-10 63 60 50 10 125 - 95 30 B-1 16 - 80 20 31 - 80 - 63 80 - - 125 80 - A-10 + B-1 63 + 16 - - 65 (28) 63 + 31 - 100(90) - 63 + 63 95 (92) - 63 + 125 98(92) - - 125 + 16 - 100(99) 50 (44 145027.doc -99- 201026687 Use example 3: Application rate of synergistic herbicidal active compound as in combination of A-180 and Β-l obtained by pre-emergence method, in g/ha, resistance to i ALOMY under 20 days Herbicide 7 SETVI t, expressed in % STEME A-180 63 80 65 0 125 - 85 30 B-1 16 - 80 - 31 65 80 30 63 75 - A-180 + B-1 63+31 98 (93) 100 (93) 80 (30) 63 + 63 98 (95) - 125 + 16 - 100 (97) - 125 + 31 - - 90 (51) Use Example 4: Application rate of synergistic herbicidal active compound as in combination of A-9 and Β-l obtained by the post-emergence method (GS 11/12), In g/ha, after 20 days, the herbicidal activity of A % Ί % % % % % % % % % % % % % % % % % % % % % (60) 98 (94) 125 + 31 75 (72) 100 (97.8) Use example 5: synergistic herbicidal active compound as in combination with A-10 and B-1 obtained by post-emergence method (GS 11/12) Application #, g/ha indicates resistance to weeding after 20 days: ALOMY 'tongue, SETVI Α-10 63 10 75 125 10 90 Β-1 16 50 85 31 60 85 Α-10 + Β-1 63 + 31 80 (64) 100 (96) 125 + 16 70 (55) 100 (98.5) 145027.doc -100- 201026687 Use example 6: A-180 with the post-emergence method (GS 11/12) Bl application rate of synergistic herbicidal active compound as·, expressed in g/ha, after 20 days, resisting the following β ALOMY preparation Sex, expressed in % SETVI A-180 63 75 0 B-1 31 85 60 A-180 + B-1 63 + 31 100 (96) 80 (60)

Use Example 7: Application rate of synergistic herbicidal active compound as in combination of A-57 and B-5 obtained by post-emergence method, in g/ha, resistance to herbicidal activity SETFA t under J CONAR a after 20 days % indicates THLAR Α-57 31 60 - 63 70 0 125 25 - 70 250 40 - - Β-5 13 0 95 70 A-57 + Β-5 31 + 13 100 (98) - 63 + 13 - 100 (99) 98 (70) 125 + 13 30 (25) 100(91) 250+ 13 65 (40) - - Use example 8: Synergistic herbicidal active compound A of combination of A-90 and B-5 obtained by post-emergence method Application rate, expressed in g/ha, resists J CONAR after 20 days, and weeded seven SETFA under the armpit, expressed as % THLAR A-90 31 45 50 - 63 45 - 25 125 - 98 B-5 13 0 95 70 A- 90 + B-5 31 + 13 70 (45) 100(98) - 63 + 13 50 (45) - 100(78) 125 + 13 - ' - 100 (99) 145027.doc -101 - 201026687 Use case 9: The application rate of the synergistic herbicidal active compound as in combination with A-218 and B-5 obtained by the post-emergence method, expressed as g/ha after 20 days of resistance to the herbicidal activity of 1 CONAR under the arm. SETFA good, expressed as THLAR in % A-218 63 - 70 0 125 0 - 35 250 25 B-5 13 0 95 7 0 A-218 + B-5 63 + 13 100 (99) 100 (70) 125 + 13 40 (0) - 100(81) 250+ 13 70 (25) - 145027.doc 102-

Claims (1)

201026687 VII. Scope of Application: 1. A herbicide mixture comprising: a) at least one active compound A from a group of thaxtomin derivatives of formula I, Wherein A is a phenyl group or a 5- or 6-membered heteroaryl group containing 1, 2, 3 or 4 heteroatoms selected from the group consisting of ruthenium and NAS, wherein Ra is at the ortho position of the A attachment point And Ra is CN, N02, CVCV alkyl, Z-C3-C6-cycloalkyl, Ci_C4·dialkyl, alkoxy, cvcv thioalkyl, Ci_C4_haloalkoxy, (VC4·halogenated sulfur) Alkenyl, alkyl, S(0)nRy, C2-C6-alkenyl, Z-C3-C6-cyclyl, C3_C6_alkenyloxy, C3-C6-thioalkenyl, c2_c6-alkynyl, C3 -C6_quivalent oxy, CVCV thioalkynyl, NRRAB, tri-q_c4_alkyl fluorenyl, zc(=o)-Ral, z_c(=s>Rai, z_c(=N QRA) Ral, z_p (=〇) (Ral) 2, phenylnaphthyl, 3_ to 7_M monocyclic or 9- or 1G•bicyclic saturated, unsaturated or aromatic heterocyclic ring attached via carbon or nitrogen, which contains 2, or 4 heteroatoms selected from the group consisting of 0, N々S and may be partially or completely substituted via the groups Raa and/or Ral and/or coupled to another saturated 'unsaturated or aromatic carbon a ring or a heterocyclic ring, and if Ra is attached to the carbon source 145027.doc 201026687, Ra may additionally be a halogen; K/ is a Ci_C6_alkyl group, C3- C4-thinyl, C3-C4-fast, nrarb or 匸丨-匚 wide haloalkyl and η 〇, 1 or 2; Ra, Rb are independently of each other hydrogen, CnCV alkyl, C3-C6-dense or C3-C6-alkynyl, C3-C6-cycloalkyl, CrC-alkylcarbonyl, c3-c6-cycloalkylcarbonyl, c3-c6-alkenylcarbonyl, c3-c6-cycloalkenylcarbonyl and C3- C6-alkynylcarbonyl; Ra, rb may also form a 5- or 6-membered saturated, partially or fully unsaturated ring together with the nitrogen atom to which it is attached, which may contain 1, 2 or 3 in addition to carbon atoms. a hetero atom selected from the group consisting of ruthenium, N and S, which ring may also be substituted with 1 to 3 groups Raa; z-covalent bond, q-cv alkylene group, c2-c6-alkenyl group or c2 -c6-alkynyl; R-based hydrogen, OH, Ci-Cs. alkyl, CVCV functional alkyl, c3-C6-cyclononyl, C2-C8-alkenyl, c5-C6-cycloalkenyl, c2_c8- Block group, CViV alkoxy 'CVC 4-haloalkoxy, C3_cv exemplified oxy, C3-C8-blockoxy, NRarb, Ci_C6_alkoxyamino, c^-C6·alkylsulfonylamino , Ci_C6_alkylaminosulfonylamino, [di-(Cl_C6)-alkylamino]sulfonylamino, (VC6-alkenylamino, C3_C6-alkynylamino, N (C2- C6-women Amino group, Ν·Ά-(ν alkynylalkyl)amino group, N-(c--C6-alkoxy)_N_(Cl_c6_alkyl)amine group, N (C2-C6-dilute base) Oxy)amino group, 145027.doc -2 - 201026687 N-(C2-C6-alkynyl hN-CCVCe-alkyloxy)amine, CVC6-alkylsulfonyl, tri-Ci-C4-alkylnonane a phenyl group, a phenoxy group, a phenylamino group or a 5- or 6-membered monocyclic ring or a 9- or 10-membered bicyclic heterocyclic ring which contains 1, 2, 3 or 4 selected from the group consisting of a hetero atom of a group consisting of N and S, wherein the cyclic group is unsubstituted or substituted with 1, 2, 3 or 4 groups of Raa; Raa is an element, OH, CN, N02, CVC4- Hyun, Cl_c4_ φ haloalkyl, Cl-C4·decyloxy, CVC4-haloalkoxy, S(〇)nRy, ZC(=〇)-Ral, ZC(=s)-Ral, ZC(=N-ORA )-Ral, Z_c[=N(〇)_RA] Ral, pendant oxy (=0) and tri-CrCV alkyl decyl; Rb is independently hydrogen, CN, N〇2, dentate, Ci_C4• alkane , cvc4-haloalkyl, C2_C4_alkenyl, C3_C6-alkynyl, Ci_c^, oxime, CVC4·halomorphoxy, benzyl or S(〇)nRy; R and/or Rb itself Attached to the adjacent ring carbon a group ... or ... or together with the adjacent ring nitrogen atom to form a 5- or 6-membered saturated, partially or fully unsaturated ring, which may contain 1, 2 or 3, in addition to a carbon atom, selected from a hetero atom of a group consisting of N&s, which ring may be substituted with 1 to 3 groups of Raa and/or fused to another saturated, unsaturated or aromatic carbocyclic or heterocyclic ring; m system 0, 1, 2 Or 3; R1 is hydrogen, OH, CN, Cl_Cl2_yard, C3_Ci2, C3_Ci2_ alkynyl 'CVCV alkoxy, c3_c6_cycloalkyl, c5_c6_cycloalkenyl, NRRAB, S(〇)nRy, s(9)nNRARB , c(=〇)Rll, 145027.doc 201026687 CONRARB, phenyl or 5- or 6-membered monocyclic or 9- or 1〇-membered bicyclic saturated, partially unsaturated or aromatic heterocyclic ring containing 2, 3 or 4 heteroatoms selected from the group consisting of hydrazine, N&S, wherein the cyclic groups are attached via Z1 and are unsubstituted or singly, 2, 3 or 4 a group substituted; and the following groups which may be partially or completely substituted by Raa: C^-C4.alkyl, c3-c4-alkenyl and C3-C4-fast; R11 hydrogen, CVC4-alkyl, Cl_C4 • halogenated alkyl, Ci_C4_ alkoxy a C1-C4-halogenated alkoxy group; a Z1 group carbonyl group or a group Z; wherein in the groups and their subsubstituents, the rabbit bonds and/or the cyclic groups are via Raa and/or Or Ra] partially or completely substituted; R series. 々-alkyl, C3-C4-wolk or C3_C4_alkynyl; R3 is i, CN, and 2, OH, Nh2, Ci_C4•alkyl, Z_C3_C8 decyl, Z-C5-C8-ring , z_c7_c84 alkynyl, C3_C6_alkenyl, C3-C6-alkynyl, z_[tri-(Ci_c6)alkyldecanealkyl], ginseng C(=〇)Ru, Z-phenyl, 5- or 6-membered single ring Or a 9- or 10-membered bicyclic heterocycle, which is attached via Z and which contains one, two, three or four heteroatoms selected from the group consisting of ruthenium, N and S; R-hydrogen, halogen, Cvov alkyl or Cl_C4_haloalkyl, or R4 and R5 together form a covalent bond; R, R, R, R8 are independently of each other hydrogen, halogen, hydrazine H, CN, no2, cvcv alkyl, Cl_C4 • tooth generation Alkyl, C2_C6_ dilute, 145027.doc 201026687 C2-C6-fast radical, C1-C4-alkoxy, C1-C4-haloalkoxy, C3_C6_cycloalkyl, 〇3_(^6-bad Dilute or C3-C6-ring fast radical; R9, R10 are independently of each other hydrogen, worm, OH, dentate alkyl, NRARB, NRAC(0)R91, CN, N02, CVCV alkyl, (VC4-haloalkane) a group, a c2-c4-alkenyl group, a C3-C6-alkynyl group, a CVCV alkoxy group, a (VC4.haloalkoxy group, a fluorene-C(0)R91, a phenoxy group or a hydroxy group] In the groups R9 and R10, the carbon chains and/or the cyclic groups may carry 1, 2, 3 or 4 substituents Raa; R91 is a C1-C4-alkyl or NRRB Or an agriculturally suitable salt thereof, and b) at least one active compound B derived from a group of the original 11 lining IX oxidase inhibitors selected from the group consisting of: Formulas 11 and 111 Wherein R21 is ruthenium or halogen; R22 is halogen or CN; and R23 is ruthenium, (VC6-alkyl, Cl_c6_dentate alkyl, c3_C6_cycloalkyl, c3-c6-alkenyl, c3-c6__ene) , C3_C6-alkynyl, c3-c6· _alkynyl, Cl_c6-alkoxy or C3_C6_cycloalkyl-C 1 -C6·alkyl; 145027.doc 201026687 T system Ν or Ν; R group R1, R11 or R11!, It is attached via # and wherein: R24 is CHF2, CF3 or S02CH3; R25 is halogen or CH3; and R26 is Η, NH2, CH3 or CH2C tri-CH; and R27 is Η or CH3; T1 is ο or s; IV Wherein R41 is a core-fluorene-alkyl group, a CVCV haloalkyl group, a CrCV alkoxy group-CVC6-alkyl group, a CVC7-cycloalkyl group, a c3-c6-alkenyl group, a c3-c6-haloalkenyl group, a c3-c6- group. Alkynyl, c3-c6-haloalkynyl or c3-c6-bad alkyl _ C 1 - C 4 _ Hyun group, R42 halogen, CrC-calcinyl, CVC3-haloalkyl, Ci-C3 -^ oxy, CVC4-alkoxy-CVC4-alkyl; and R43 is halogen, CN, N〇2, CVC4-alkyl, CVCV halogenated, CVC4-alkoxy, CVC4-alkylsulfonate Base, Ci-Cr, oxy 145,027.doc -6 - 201026687 -Ci-CV alkyl, c3-C6-cycloalkyl-(VC2-alkyl, or co2R44; wherein R44 is the group mentioned for R41 One of the group; X is 〇, 1, 2 or 3, and y is 〇, 1, 2, 3 or 4; the compounds are present in synergistically effective amounts. 2. A mixture of claim 1 wherein The active compound A corresponds to the formula I, wherein the codes have the following meanings: Ra system CN, N02, CVCV, Z-C3_C6-cycloalkyl, Ci_Cp i alkyl, CVC4-alkoxy, Cl_C4 _haloalkoxy, 〇-z_c3-c6-cycloalkyl, s(o)nRy, C2_C6-alkenyl, z_c ί 5 'cycloalkenyl, C3-C6-enoxy , c2_c6_alkynyl, C3_C6_alkynyloxy, NRARB, tri-CVC4-alkyldecylalkyl, zC(=0)-Rai, ZP(=0)(Ral)2, phenyl, naphthyl, via carbon or a nitrogen-attached 3- to 7-membered monocyclic or 9- or 10-membered bicyclic saturated, unsaturated or aromatic heterocyclic ring, • containing 1, 2, 3 or 4 selected from 〇, ;^ And a hetero atom of the group consisting of 8 and which may be partially or completely substituted via the groups Raa and/or Ral, and if Ra is attached to a carbon atom, Ra may be a halogen; RA, rb are independently hydrogen, Cl_c6_alkyl, C3_c6_ dilute or (VCV alkynyl; RA, RB may also form a 5- or 6-membered saturated, partially or fully unsaturated ring together with the nitrogen atom to which it is attached, in addition to carbon atoms May contain i, 2 or 3 heteroatoms selected from the group consisting of 0, N and S, which ring can be substituted with 3 groups of Raa; 145027.doc 201026687 Raa halogen, OH, CN, N02 , CrCr alkyl, Ci-Cc haloalkyl, CVCV alkoxy, CVCV haloalkoxy, S(〇)nRy, ZC(=0)-Ral or tri-C"C4-alkyl group; R are independent of each other Terrestrial chlorine, CN, N〇2, halogen, C1-C4·· burnt base, C1-C4- Haloalkyl, C2-C4-alkenyl, c3-c6-alkynyl, CVC4-alkoxy, Ci-cv haloalkoxy, benzyl or s(〇)nRy; Rl, nitrogen, oh, cn, (^ -(:12•alkyl, c3-c12-dense, c3-c12-alkynyl, CVCV alkoxy, c3-C6-cycloalkyl, c5-c6-cycloalkenyl, NRARB, S(0)nRy , S(0)nNRARB, C(=0)R", CONRARB, phenyl or 5- or 6-membered monocyclic or 9- or 10-membered bicyclic aromatic heterocyclic ring containing 1, 2, 3 Or 4 heteroatoms selected from the group consisting of ruthenium, N and S, wherein the cyclic groups are attached via Z1 and are unsubstituted or substituted by 1, 2, 3 or 4 groups of Raa And the following groups which may be partially or completely substituted by Raa: CrC4-alkyl, C3-C4-alkenyl and C3-C4-fast. 3. A mixture according to claim 1 or 2, wherein the active compounds A correspond to formula I.1A Wherein V is c_Rb or N and the index m is 0 or an integer from 1 to 4. A mixture of items 1 or 2 as in the month, wherein the active compounds a correspond to I.2a, J 145027.doc 201026687 5. The mixture of claim 4, wherein the active compound a corresponds to formula I.2aB Ra D6 ^ Wherein Rb2, Rb3&Rb4 are each a group Rb. 6. A mixture of claim 1 or 2 which comprises a compound of formula 作为1 as an active compound Β 11.1 R240 I- 7. A mixture according to claim 6 which comprises 7-(4_bromo-5-difluoromethoxy-indolyl-1H-biazole-3-yl)_4,6-dichloro-2-ethylbenzene And oxazole or 'chlorine_7_(4_chloro-5-difluoromethoxy-1·methyl-1H-pyrazol-3-yl)-2-ethyl_6-fluorobenzophene Active Compound B. 8. A mixture of claim 1 or 2 which comprises a compound of formula 112 as the active compound B 145027.doc 201026687 9. A mixture of claim 8 which comprises 3-(4-gas-2-cyclopropylmethyl-6-fluorobenzoxan-7-yl)-1-indenyl-6-trifluoromethyl -1H-pyrimidine-2,4-dione or 3-(7-fluorofluoro-2-trifluoromethyl _311_benzimidazole _4-yldimethyl-1H-pyrimidine_2,4_2 a ketone as the active compound b. A mixture of the compounds 1 or 2 comprising the compound of the formula III.1 as the active compound B ο. A mixture of claim 10 comprising 3-(7-fluoro_3_sideoxy_4-prop-2-ynyl-3,4-dihydro-2H•benzo[14]oxazine_6• 15) dimethyl athio[1'3,5]diazepine-2,4-dione as the active compound 3. 12'A mixture of claim 1 or 2 comprising a third active ingredient c) selected from the group consisting of: at least one herbicide c el) a lipid biosynthesis inhibitor selected from the group consisting of: C2) B-lactate lactase inhibitor; c3) photosynthesis inhibitor; c4) pro-porphyrinogen IX oxidase inhibitor; c5) pigment-inhibiting herbicide; 145027.doc 201026687 c6) enol acetone oxalic acid- 3-phosphate synthase inhibitor; c7) glutamine indole synthase inhibitor; c8) 7,8-dihydropteroate synthase inhibitor (DHP inhibitor); c9) mitotic inhibitor; clO) VLCFA-like inhibition Inhibitor of the agent; ell) cellulose biosynthesis inhibitor; cl2) decoupled herbicide; cl3) auxin herbicide; cl4) auxin transport inhibitor; and cl 5) other herbicides selected from the group consisting of : bromobutide, chlorflurenol, chlorflurenol-methyl, cinmethylin, cumyluron, dalapon, cotton ( Dazomet), ofenzaquat, oatmeal, methyl sulfate, Dimethipin, DSMA, dymron, endothal and its salts, etobenzanid, flamprop, fluprop -isopropyl), Hamprop-methyl, flamprop-M-isopropyl, wheat straw gas - flamprop-M-methyl, butyl vinegar Flurenol), flurenol-butyl, flurprimidol, fosamine, sulphate-ammonium, indanofan, maleic hydrazide , mefluidide, metam, 145027.doc -11- 201026687 azido decane, methyl bromide, methyl-dymron, moth, MMA, Oleic acid, oxaziclomefone, citric acid, pyributicarb, quinoclamine, triaziflam, tridiphane and 6-chloro-3-(2) - cyclopropyl-6-methylphenoxy)-4-pyridinol and its salts and esters; and a protective agent selected from the group consisting of: benoxacor, Clocintocet, cyometrinil, cyprosulfamide, dichlormid, dicyclonone, dietholate, solution The grass "fenchlorazole", fenclorim, flurazole, fluxofenim, and sorrel. Sitting (furilazole), bisbenzene, stagnation acid (isoxadifen), ° ratio 0, mefenpyr, mephenate, naphthalene dicarboxylic acid needle, oxabetrinil, 4- (two Ethyl acetyl)-1-oxa-4-oxaspiro[4.5]decane and 2,2,5-trimethyl-3-(dichloroacetamido)-1,3-oxazolidine. 13. The herbicide mixture of claim 1 or 2 wherein the weight ratio of component A to component B is in the range of from 100:1 to 1:100. A herbicidal composition comprising the mixture of any one of claims 1 to 13 and at least one solid or liquid carrier and/or one or more surfactants. A method of controlling undesired vegetation, which comprises applying a herbicidal effective amount of the mixture of any one of claims 1 to 13 to a plant, its habitat or a seed. 145027.doc -12- 201026687 IV. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbolic symbol of the representative figure is simple: 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: 145027.doc