TW201109321A

TW201109321A - Herbicidally active composition comprising benzoxazinones

Info

Publication number: TW201109321A
Application number: TW99127178A
Authority: TW
Inventors: Rapado Liliana Parra; William Karl Moberg; Trevor William Newton; Thomas Seitz; Anja Simon; Bernd Sievernich; Matthias Witschel; Helmut Walter; Richard Roger Evans
Original assignee: Basf Se
Priority date: 2009-08-14
Filing date: 2010-08-13
Publication date: 2011-03-16
Also published as: WO2011018486A2; AR077926A1; WO2011018486A3; UY32838A

Abstract

(A) at least one benzoxazinone compound of the formula I wherein the variables are as defined as given in the specification; and at least one further active compound selected from (B) herbicides of class (b1) to (b15) as defined in the specification, and (C) safeners.

Description

201109321 六、發明說明：【發明所屬之技術領域】本發明係關於除草活性組合物，其包含至少一種式工之苯并十井酮及至少-種選自除草活性化合物及安㈣之另一化合物。【先前技術】在農作物保護組合物之情形中，原則上期望增加活性化合物之比活性及效應可靠性。尤其期望農作物保護組合物可有效控制有害植物，#同時可與所述有用植物相容。亦期望其具有廣譜活性，從而可同時控制各種有害植物。通常’使用單·除草活性化合物*能達成此目的。許多咼效除草劑之問題在於其與有用植物（特定而言，雙子葉農作物植物(例如，棉花、油菜)及禾本科植物(例士大夕粟玉米、粳米、小麥及甘蔗））之相容性並不總是令人滿意，亦即除有害植物外，其亦以無法容忍之規模損害農作物植物。藉由降低施科，可降低對有用植物之知害’然而’對有害植物之控制程度自然亦有所減小。通㊉，為達成期望除草作用，僅可在較窄時間範圍内施加除草劑亦成問題，該時間範圍可不可預測地受天氣條件影響。已知不同特異活性除草劑之特定组合可在協同效應意義上增強除草劑組份的活性。以此方式，可降低控制有害植物所需之除草活性化合物的施用率。另外，已知在一些情形中，聯合施加特異活性除草劑與 150107.doc 201109321 有機活性化合物（其中之一些亦可具有除草活性）使得可達成較佳之農作物植物相容性《在該等情形中，活性化合物用作解毒劑或拮抗劑且亦稱作安全劑，此乃因其可降低或甚至防止對農作物植物之損害。一些式I之苯并11号畊酮已闡述於（例如）W〇 02/066471及 EP 〇64〇 600中。WO 09/115490係關於包含派羅克殺草砜 (pyr〇xasuIfone)及ppo之除草組合物。w〇 1〇/66677揭示包含式I之赛克斯托敏（thaxtomine)及式Π、in或IV之PPO之除卓組合物。【發明内容】本發明目的係提供可高效抵抗不期望有害植物之除草組合物。同時，該等組合物應與有用植物具有良好相容性。此外’本發明之組合物應具有廣譜活性。此目的及其他目的係藉由下文之除草活性組合物來達成。因此，本發明係關於除草活性組合物，其包含： A)至少—種式I之苯并$ 化合物：201109321 VI. Description of the Invention: [Technical Field] The present invention relates to a herbicidal active composition comprising at least one benzoxanthone of the formula and at least one compound selected from the group consisting of herbicidal active compounds and anthracene . [Prior Art] In the case of a crop protection composition, it is in principle desirable to increase the specific activity and effect reliability of the active compound. It is particularly desirable that the crop protection composition be effective in controlling harmful plants, and that it is compatible with the useful plants. It is also expected to have a broad spectrum of activity so that various harmful plants can be controlled simultaneously. This can usually be achieved by using a single herbicidal active compound*. The problem with many herbicides is that they are compatible with useful plants (specifically, dicotyledonous crop plants (eg, cotton, canola) and gramineous plants (eg, corn, glutinous rice, wheat, and sugar cane) Sex is not always satisfactory, that is to say, in addition to harmful plants, it also damages crop plants on an intolerable scale. By reducing the number of sci-fi, it is possible to reduce the knowledge of useful plants. However, the degree of control over harmful plants is naturally reduced. In order to achieve the desired herbicidal action, it is also problematic to apply herbicides only in a narrower time frame, which can be unpredictably affected by weather conditions. It is known that specific combinations of different specific active herbicides enhance the activity of the herbicidal component in the sense of synergistic effects. In this way, the application rate of the herbicidal active compound required to control harmful plants can be reduced. In addition, it is known that in some cases, the combined application of a specific active herbicide with 150107.doc 201109321 organic active compounds, some of which may also have herbicidal activity, allows for better crop plant compatibility to be achieved. The active compounds are useful as antidote or antagonists and are also referred to as safeners because they reduce or even prevent damage to crop plants. Some of the benzoin 11 ketones of formula I have been described, for example, in W〇 02/066471 and EP 〇64〇 600. WO 09/115490 relates to herbicidal compositions comprising pyroxaxasuone and ppo. W〇 1〇/66677 discloses a composition comprising a thaxtomine of formula I and a PPO of the formula in, in or IV. SUMMARY OF THE INVENTION The object of the present invention is to provide a herbicidal composition which is highly resistant to undesirable harmful plants. At the same time, the compositions should have good compatibility with useful plants. Furthermore, the compositions of the invention should have a broad spectrum of activity. This and other objects are achieved by the herbicidal active compositions below. Accordingly, the present invention relates to herbicidal active compositions comprising: A) at least one of the benzoic compounds of formula I:

其中： R係氫或c^-cv烷基； R2係氫、NH^Ci-CV烧基或C3-C6-炔基； R係氫或_素； 150107.doc 201109321 R係氫、CVCV烷基、（VCV鹵代烷基、C3_C6•環烷基、C3-C6-烯基、C3-C6-_ 代稀基、c3_c6_炔基、c3_ c6-鹵代炔基、CVCV烷氧基或c3_c6_環烷基_Ci_c6_ 烷基； X 係Ο或S ; Y 係Ο或S ; 及至少一種選自以下之另一活性化合物： B) bl)至bl5)類之除草劑： b 1) 脂質生物合成抑制劑； b2)乙醯乳酸合酶抑制劑（ALS抑制劑）； b3) 光合作用抑制劑； b4>原卟啉原-IX氧化酶抑制劑； b5)色素抑制型除草劑； 6)烯醇丙酮醯莽草酸_3_磷酸合酶抑制劑（EpSp抑制劑）； b7)麵醯胺酸合成酶抑制劑； b8) 7,8·二氫蝶酸合酶抑制劑（DHp抑制劑）； b9)有絲分裂抑制劑； bl〇)極長鏈脂肪酸合成抑制劑（vlcfa抑制劑）； bU)纖維素生物合成抑制劑； bl2)去偶合除草劑； b13)生長素除草劑； b14)生長素轉運抑制劑；及 b )選自由以下組成之群之其他除草劑：溴丁草 I50107.doc 胺（bromobutide)、整形醇（chlorflurenol)、整形醇-甲基（chlorflurenol-methyl)、環庚草鍵 (cinmethylin)、节草隆（cumyluron)、茅草枯 (dalapon)、棉隆（dazomet)、燕麥枯（difenzoquat)、燕麥枯-甲硫酸鹽（difenzoquat-metilsulfate)、 °塞節因（dimethipin)、DSMA、殺草隆（dymron)、橋氧酜鈉（endothal)及其鹽、乙氧苯草胺 (etobenzanid)、麥草氟（flamprop)、麥草氟-異丙基（flamprop-isopropyl)、麥草氟-曱基 (flamprop-methyl)、麥草氟-M-異丙基 (flamprop-M-isopropyl)、麥草氟-Μ-甲基 (flamprop-M-methyl)、芴丁酯（flurenol)、芴丁醋-丁基（flurenol-butyl)、吱鳴醇（flurprimidol)、殺木膦（fosamine)、殺木膦-敍 '草酮 (indanofan)、茚茲弗蘭（indaziflam)、馬來醯肼 (maleic hydrazide)、氟草續（mefluidide)、美坦 (metam)、疊氮基甲烧、溴曱院、甲基-殺草隆、蛾甲院、MSMA、油酸、去稗安（oxaz|ci〇mefone)、壬酸、稗草丹（pyributicarb)、滅藻西昆 (quinoclamine)、三氟草胺（triaziflarn)、滅草環（tridiphane)及6-氯-3-(2-環丙基-6-甲基苯氧基）-4-噠畊醇（pyridazinol) (CAS 499223-49-3) 及其鹽及酯； 201109321 c)安全劑。特定而言，本發明係關於呈除草活性農作物保護組合物形式之組合物，其包含除草有效量之活性化合物組合^其包含至少一種式I之苯并噚啤酮化合物及至少— 裡選自除草劑B及安全劑C之另一化合物，如上文所定義）、以及至少一種液體及/或固體載劑及/或一或多種表面活性劑及（若需要）一或多種常用於農作物保護組合物之其他輔助劑。本發明亦係關於呈調配成單組份組合物之農作物保護組合物形式的組合物，其包含活性化合物組合（其包含至少 -種式I之苯并十井酮化合物及至少—種選自除草劑B及安全劑C之另-活性化合物）、及至少-種固體或液體載劑及/ 或-或多種表面活性劑及(若需要)一或多種常用於農作物保護組合物之其他輔助劑。本發明亦係關於呈調配成雙組份組合物之農作物保護組合物形式的組合物，其包含含有至少一種式!之苯并十井 _化合物、固體或液體載劑及，或一或多種表面活性劑之 :-組份、及含有至少一種選自除草劑B及安全劑C之另 :活性化合物、固體或液體載劑及/或一或多種表面活性第一、’且伤’其中兩種組份亦可另外包含常用於農作物保護組合物之其他辅助劑。 I驚冴的是，包含至少一種式I苯并嘮畊酮化合物及至少-種除草劑B之本發明組合物具有較基於所觀測個別匕合物之除草活性作出之預期更佳的除草活性，亦即，更佳之抵抗有害植物之活性，或更寬活性譜。可使用⑽y 150107.doc 201109321 △式（參見下文）計算基於個別化合物之混合物之預期的除草活！·生。右所觀測之活性超過個別化合物之預期相加活性’則可認為存在協同效應。另外，可藉由本發明組合物擴展可達成期望除草作用之時間範圍，該等組合物包含至少一種式丨之苯并嘮畊酮化合物及至少一種除草劑B及視需要安全劑C。此使得本發明組合物與單一化合物相比具有更靈活之定時施加性。包含至少一種式〖之苯并崎畊酮化合物及至少一種c下所提及化合物二者的本發明組合物亦具有抵抗有害植物之良好除草活性及與有用植物之較佳相容性。令人驚訝的是，包含至少一種式〗苯并噚畊酮化合物、至少一種除草劑B及至少一種c下所提及化合物的本發明組合物具有較基於所觀測個別化合物之除草活性作出之預期更佳之除草活性，亦即，更佳之抵抗有害植物之活性，或具有更寬活性谱，且顯示與有用植物之相容性優於僅包含一種化合物I及一種除草劑B之组合物。本發明另外係關於（特定而言）在種植農作物植物之處（例如在以下農作物植物之農作物中）、以及在由於基因工程或育種而抵抗一或多種除草劑或抵抗昆蟲攻擊之農作物中控制不期望植被之方法：洋E (Allium cepa)、菠蘿（Ananas comosus)、落花生（Arachis hypogaea)、石刁柏（Asparagus officinalis)、燕麥（Avena sativa)、糖料作物甜菜（Beta vulgans spec. aItissima)、砂糖甜菜（BeU 邛仏 rapa)、歐洲油菜（原變種）(Brassica napus var⑽口⑽）、蕪 150107.doc 201109321 菁甘藍（Brassica napus var. napobrassica)、席氏蕪菁 (Brassica rapa var. silvestris)、甘藍（Brassica oleracea)、黑芥（Brassica nigra)、山茶（Camellia sinensis)、紅花 (Carthamus tinctorius)、美國薄殼山核桃（Carya illinoinensis)、檸檬（Citrus limon) ' 甜橙（Citrus sinensis)、小果咖 °非 (Coffea arabica)(中果咖啡（Coffea canephora)、大果咖啡 (Coffea liberica))、黃瓜（Cucumis sativus)、狗牙根 (Cynodon dactylon)、野胡蘿蔔（Daucus carota)、油棕 (Elaeis guineensis)、白花草莓(Fragaria vesca)、大豆 (Glycine max)、陸地棉（Gossypium hirsutum)(樹棉 (Gossypium arboreum)、草棉（Gossypium herbaceum)、木棉 (Gossypium vitifolium))、向曰葵（Helianthus annuus)、巴西三葉膠（Hevea brasiliensis)、青棵（Hordeum vulgare)、啤酒花 (Humulus lupulus)、甘薯（Ipomoea batatas)、胡桃（Juglans regia)、小扁豆（Lens culinaris)、普通亞麻（Linum usitatissimum)、番％ (Lycopersicon lycopersicum)、頻果屬 (Malus spec.)、木薯（Manihot esculenta)、紫花苜稽 (Medicago sativa)、芭蕉屬（Musa spec.)、角蒿（Nicotiana tabacum)(黃花終草（N.rustica))、油橄禮（Olea europaea)、旱稻（Oryza sativa)、白扁豆（Phaseolus lunatus)、菜豆 (Phaseolus vulgaris)、挪威雲杉（Picea abies)、松屬（Pinus spec.)、阿月渾子（Pistacia vera)、婉豆（Pisum sativum)、歐洲甜櫻桃（Prunus avium)、桃子（Prunus persica)、矮生西洋梨（Pyrus communis)、杏李（Prunus armeniaca)、歐洲酸 150107.doc -10- 201109321 櫻桃（Prunus cerasus)、扁桃（Prunus dulcis)及杏梅（prunus domestica)、紅穗醋栗（Ribes sylvestre)、蓖麻（Ricinus communis)、甘蔗（Sacchanmi officinarum)、黑麥（Secale cereale)、白芥（Sinapis alba)、普通馬鈴薯（Solanum tuberosum)、高粱（Sorghum bicolor)(蜀黍（s. vulgare))、可可果（Theobroma cacao)、紅車軸草（Trifolium pratense)、小麥（Triticum aestivum)、黑小麥（Triticale)、硬粒小麥 (Triticum durum)、蠶豆（Vicia faba)、葡萄（Vitis vinifera)、玉米黍（Zea mays) ’尤其是穀類、玉米、大豆、粳米、油菜、棉彳b、馬鈐薯、花生或多年生農作物之農作物。本發明亦係關於使植物乾燥或脫落之方法。在最近提及之方法中’組份A)及B)及（若適當）c之除草活性化合物是聯合亦或分開調配並施加以及在分開施加情形中進行施加之順序並不重要。【實施方式】變量R1至R11之定義中所提及之有機部分（例如術語「_ 素」）係單獨列舉群中個別成員之統稱。在每一情形下，術語「i素」冑表示1、氣、1以。所有烴鏈（即所有烷基）皆可為直鏈或具支鏈，前綴Cn_Cm在每—情形下皆表示基團中可能之碳原子數。該等含義之實例係：及 CH(CH3)2 ; -G-C3-烧基：ch3、C2H5、正丙基 C1-C4-烷基之Ci_c4_烷基以及正丁基、ch(ch3)- -Ci-cv烷基以及C3_C6•環烷基部分：如上所述之CrCr烷基， 150107.doc • 11 · 201109321 C2H5、CH2-CH(CH3)2及 c(ch3)3 ; -Ci-C6-烷基以及c3-c6-環烷基-c丨-C6-烷基之crc6·烷基部分：如上所述之CrC4-烷基以及（例如）正戊基、丨·甲基丁基、2-甲基丁基、3-曱基丁基、2,2-二甲基丙基、^乙基丙基、正己基、1，1-二曱基丙基、12·二甲基丙基、厂甲基戊基、2-曱基戊基、3-曱基戊基、4_甲基戊基、1}1-二甲基丁基、1，2-二甲基丁基' L3-二甲基丁基、2,2·二甲基丁基、2,3-二甲基丁基、3,3_二甲基丁基、卜乙基丁基、2_ 乙基丁基、1，1，2-三甲基丙基、i，2,2_三曱基丙基卜乙基· 1-甲基丙基或1-乙基-2-曱基丙基’較佳係甲基、乙基、正丙基、1-曱基乙基、正丁基、U_二曱基乙基、正戊基或正己基； • C1-C3 -鹵代烧基：部分或完全由氣兀王田氟、氣、溴及/或碘取代之如上所述之C丨-(：3_烷基，亦即，如（曱基、三氣曱基、氟甲基、二氟甲基、基、風1氣曱基、氣·一氟ί曱基、演甲基、2 -乳乙基、2 ->臭乙基 1 例如，氣曱基、二氣 -氟曱基、氣氟甲基、碘曱基、2-氟乙峨乙基、22 -二氟乙其、 2,2,2-三氟乙基、2-氣-2-氟乙基、2 ’ ^ 2,虱二氟乙基、2,2_ 二氣-2·氟乙基、2,2,2-三氣乙基、五氟乙基、2-氟丙基、 3 - IL丙基、2，2 -二氟丙基、2,3 -二g# 乳丙基、2-氯丙基、3-氣丙基、2，3-二氣丙基、2-溴丙基、3、、自 -屬丙基、3,3,3-三氟丙基、3,3,3-三氯丙基、2,2,3,3,3-五氣而| 紙•内基、七氟丙基； -Cl-C4-鹵代烧基.如上所述之C p L. 鹵代烷基，以及（例如）1-(氟曱基）-2-氟乙基、1-(氣曱基 T暴）_2-氣乙基、i•(溴曱 150107.doc -12- 201109321 基）·2·漠乙基、4_氟丁基、4_氯丁基、4_漠丁基、九氣丁基、1，1，2,2，-四氟乙基及卜三氟甲基_12,2,2_四氟乙基； _ Ci_C6—鹵代烷基：如上所述之（^-(：4-鹵代烷基，以及（例如）5-氟戊基、5-氯戊基、5-溴戊基、5-碘戊基、十一氟戊基、6-氟己基、6-氯己基、6-溴己基、6-碘己基及十二氟己基； _ c3-c6-環烷基以及C3_C6_環烷基·C]_C4_烷基及C3_C6_環烷基-C^-C6-烷基之環烷基部分：具有3至6個環成員之單環飽和烴’例如環丙基、環丁基、環戊基及環己基； _ C3-C6_烯基··例如，1-丙烯基、2-丙烯基、1-甲基乙烯基、1-丁烯基、2-丁烯基、3-丁烯基、1-甲基_ι_丙烯基、 2-甲基-1-丙烯基、〖_甲基_2_丙烯基、2_甲基_2_丙烯基、^ 戊烯基、2-戊烯基、3_戊烯基、4_戊烯基、丨_曱基_丨_ 丁烯基、2-曱基_1_ 丁烯基、3 -甲基-卜丁烯基、ι_曱基_2_丁稀基、2-甲基-2-丁烯基、3 -曱基-2-丁稀基、1-曱基_3-丁烯基、2-曱基-3-丁烯基、3-曱基-3-丁烯基、1，1-二甲基_2-丙稀基 1，2 - 一曱基-1-丙稀基、ι，2 -二曱基-2-丙烯基、1_乙基-1-丙烯基、1-乙基·2-丙烯基、1-己烯基、2-己烯基、3_ 己烯基、4-己烯基、5-己烯基、1-曱基-1-戊烯基、2-曱基_ 1-戊烯基、3-曱基-1-戊烯基、4-曱基-1-戊烯基、1-曱基戊烯基、2·曱基-2-戊烯基、3-甲基-2-戊烯基、4-曱基-2-戊烯基、甲基-3·戊烯基、2-甲基-3-戊烯基、3-曱基-3-戊烯基、4-曱基-3-戊烯基、曱基_4_戊烯基、2-曱基-4_ 戍稀基、3 -甲基-4-戊烯基、4 -甲基-4-戊稀基' 1，1-二甲基_ 150107.doc -13· 201109321 2-丁烯基、1，1-二甲基·3_丁稀基、ι，2_二甲基丁烯基、 1，2-二曱基-2-丁烯基'1，2_二曱基_3-丁烯基、1，3_二曱基_ 1- 丁稀基、1，3-二甲基·2-丁烯基、ι，3-二曱基_3-丁浠基、 2.2- 二曱基-3-丁烯基、2,3-二甲基-1-丁烯基、2,3-二曱基_ 2- 丁烯基、2,3-二曱基_3_ 丁烯基、3,3-二曱基·ι_ 丁烯基、 3,3_ 一曱基_2_ 丁烯基、1-乙基-1-丁稀基、1-乙基-2-丁烯基、1-乙基-3-丁烯基、2-乙基-1-丁烯基、2_乙基_2-丁烯基、2-乙基-3-丁烯基、丨山八三曱基_2_丙烯基、丨_乙基l 甲基-2-丙烯基、1·乙基_2_曱基_丨_丙烯基及丨·乙基曱基-2-丙烯基； -C3-C6-鹵代烯基：如上所述之c3-C6-烯基，其經氟、氯、溴及/或碘部分或完全取代，例如，2·氯丙-2-烯-1-基、3-氣丙-2-烯_1_基、2,3-二氯丙-2-烯-1-基、3,3-二氣丙-2-烯-1-基、2,3,3-三氣-2-烯-1-基、2,3-二氣丁-2-烯-1-基、2-溴丙-2-烯-1-基、3-溴丙-2-稀-1-基、2,3-二溴丙-2-烯-1-基、3,3-二溴丙-2-烯-1-基、2,3,3-三溴-2-烯-1-基或 2.3- 二溴丁-2-烯-1-基； -C3-C6_炔基：例如，1-丙炔基、2-丙炔基、1-丁炔基、 2_ 丁快基、3 -丁快基、1-甲基_2_丙快基、1-戊快基、2 -戊炔基、3-戊炔基、4-戊炔基、1-曱基-2-丁炔基、1-曱基-3-丁炔基、2-曱基-3-丁炔基、3-曱基-1-丁炔基、1，1-二曱基-2-丙炔基、1-乙基-2-丙炔基、1-己炔基、2-己炔基、3-己炔基、4-己炔基、5-己炔基、1-曱基-2-戊炔基、1-曱基-3-戊炔基、1-甲基-4-戊炔基、2-曱基-3-戊炔基、2-曱基-4- 150107.doc -14- 201109321 戊炔基、3-曱基-丨_戊炔基、3_甲基_4_戊炔基、4曱基戊炔基、4-甲基-2-戊炔基、1，1-二甲基-2·丁炔基、丨，^二甲基-3-丁块基、1，2-二甲基-3-丁块基、2,2-二甲基-3-丁块基、3,3-二甲基-1-丁炔基、i_乙基丁炔基、丨_乙基_3_丁快基、2 -乙基-3-丁块基及1-乙基-1-甲基_2_丙快基； -CVC6-鹵代块基：如上所述之C3_c6_炔基，其經氟、氣、溴及/或硬部分或完全取代’例如，]，丨_二氟丙_2_块、 1-基、3-碘丙-2-炔-1-基、4-氟丁-2-炔_ι_基、4-氣丁-2-炔_ 1-基、Μ-二氟丁-2-炔-1-基、4-碘丁 ·3·炔基、5_氟戊、 3-炔-1-基、5-碘戊-4-炔-1-基、6-1己_4-快-1-基或6-碘己_ 5-炔-1-基； 'Cl_C3_烷氧基：甲氧基、乙氧基、丙氧基、1-曱基乙氣基； _ C〗-C4_烷氧基：如上所述之Cl_C3·烷氧基，以及（例如）丁氧基、1-甲基丙氧基、2-甲基丙氧基及u•二甲基乙氧基； -q-C6·烷氧基：如上所述之Cl_c4•烷氧基，以及（例如）戊氧基、1-曱基丁氧基、2-曱基丁氧基、3 -甲氧基丁氧基、1，1-二甲基丙氧基、1，2-二甲基丙氧基、2,2_二甲基丙氧基、1-乙基丙氧基、己氧基、丨_甲基戊氧基、2_甲基戊氧基、3 -曱基戊氧基、4-曱基戊氧基、；ι，^二曱基丁氧基、1，2-二曱基丁氧基、L3-二甲基丁氧基、2,2_二甲基丁氧基、2,3-二曱基丁氧基、3,3-二甲基丁氧基、卜乙基丁氧基、2-乙基丁氧基、l，i，2-三甲基丙氧基、丨，2,2_三甲基丙 150107.doc •15· 201109321 氧基、1-乙基-1-甲基丙氧基及卜乙基_2_曱基丙氧基；以下本文提及之本發明較佳實施例必須理解為較佳彼此獨立承彼此組合。根據本發明之第一較佳實施例，組合物包含至少一種、較佳L好一種式I · 1之笨并p号畊酮化合物（對應於r1及R2係 q-cv烷基、…係_素、R、$C3_C6_炔基' χ係§且丫係〇之式I之笨并呤。井酮化合物）作為活性化合物Α或組份A :Wherein: R is hydrogen or c^-cv alkyl; R2 is hydrogen, NH^Ci-CV alkyl or C3-C6-alkynyl; R is hydrogen or _; 150107.doc 201109321 R hydrogen, CVCV alkyl , (VCV haloalkyl, C3_C6•cycloalkyl, C3-C6-alkenyl, C3-C6--), c3_c6-alkynyl, c3_c6-haloalkynyl, CVCV alkoxy or c3_c6_cycloalkane a group of _Ci_c6_alkyl; X Ο or S; Y Ο or S; and at least one other active compound selected from the group consisting of: B) bl) to bl5) herbicides: b 1) Lipid biosynthesis inhibitors B2) acetamidine lactate synthase inhibitor (ALS inhibitor); b3) photosynthesis inhibitor; b4> protoporphyrinogen-IX oxidase inhibitor; b5) pigment inhibiting herbicide; 6) enol acetone oxime Shikimic acid _3_phosphate synthase inhibitor (EpSp inhibitor); b7) face valerine synthase inhibitor; b8) 7,8·dihydropteroate synthase inhibitor (DHp inhibitor); b9) mitosis Inhibitor; bl〇) very long chain fatty acid synthesis inhibitor (vlcfa inhibitor); bU) cellulose biosynthesis inhibitor; bl2) decoupled herbicide; b13) auxin herbicide; b14) auxin transport inhibitor; And b) Other herbicides of the group consisting of: bromobutide I50107.doc bromobutide, chlorflurenol, chlorflurenol-methyl, cinmethylin, turfgrass Cumyluron), dalapon, dazomet, difenzoquat, difenzoquat-metilsulfate, dimethipin, DSMA, dymron, Endothal and its salts, etobenzanid, flamprop, flamprop-isopropyl, flamprop-methyl, wheat straw Fluor-M-isopropyl, flamprop-M-methyl, flurenol, flureneol-butyl, hydrazine Flurprimidol, fosamine, indonefan, indanofan, indaziflam, maleic hydrazide, mefluidide, beauty Metam, azido-methyl, bromine, methyl-aluron, moth, MMA, oleic acid, deuterium An (oxaz|ci〇mefone), citric acid, pyributicarb, quinoclamine, triaziflarn, tridiphane and 6-chloro-3-(2 -cyclopropyl-6-methylphenoxy)-4-pyridinol (CAS 499223-49-3) and its salts and esters; 201109321 c) Safeners. In particular, the present invention relates to a composition in the form of a herbicidal active crop protection composition comprising a herbicidally effective amount of an active compound combination comprising at least one benzoxanthone compound of formula I and at least - selected from the group consisting of weeding Another compound of agent B and safener C, as defined above, and at least one liquid and/or solid carrier and/or one or more surfactants and, if desired, one or more commonly used in crop protection compositions Other adjuvants. The invention also relates to a composition in the form of a crop protection composition formulated as a one-component composition comprising an active compound combination comprising at least one of the benzoxanthone compounds of the formula I and at least one selected from the group consisting of weeding Agent B and another active compound of Safener C), and at least one solid or liquid carrier and/or - or multiple surfactants and, if desired, one or more other adjuvants commonly used in crop protection compositions. The present invention is also directed to a composition in the form of a crop protection composition formulated as a two-component composition comprising at least one benzoxanthene compound, a solid or liquid carrier, and one or more surfaces. The active agent:-component, and at least one selected from the group consisting of herbicide B and safener C: active compound, solid or liquid carrier and/or one or more surface active first, 'and wound' The components may additionally comprise other adjuvants commonly used in crop protection compositions. I am horrified that the composition of the invention comprising at least one benzoxanthone compound of the formula I and at least herbicide B has a better herbicidal activity than expected based on the herbicidal activity of the observed individual chelates, That is, it is better to resist the activity of harmful plants, or to broaden the spectrum of activity. The expected weeding based on the mixture of individual compounds can be calculated using (10) y 150107.doc 201109321 △ (see below)! · Health. A synergistic effect can be considered if the activity observed on the right exceeds the expected additive activity of the individual compounds. Additionally, the time frame for achieving the desired herbicidal action can be achieved by extending the compositions of the present invention comprising at least one benzoxanthene compound of the formula and at least one herbicide B and an optional safener C. This allows the compositions of the present invention to have more flexible timing applicability compared to a single compound. The compositions of the present invention comprising at least one of the benzoxanthone compounds of the formula and at least one of the compounds mentioned under c also have good herbicidal activity against harmful plants and good compatibility with useful plants. Surprisingly, the compositions of the invention comprising at least one of the compounds of the formula benzoxanthone, at least one herbicide B and at least one of the compounds of c have an expectation based on the herbicidal activity of the individual compounds observed. More preferred herbicidal activity, i.e., better resistance to harmful plant activity, or a broader spectrum of activity, and compatibility with useful plants is shown to be superior to compositions comprising only one compound I and one herbicide B. The invention is additionally (in particular) controlled in the cultivation of crop plants (for example in the crops of the following crop plants), and in crops that are resistant to one or more herbicides or insect attackes due to genetic engineering or breeding. Methods of vegetation are expected: Allium cepa, Ananas comosus, Arachis hypogaea, Asparagus officinalis, Avena sativa, Beta vulgans spec. a Itissima, Sugar beet (BeU 邛仏rapa), Brassica napus (original variety) (Brassica napus var (10) mouth (10)), 芜150107.doc 201109321 broccoli (Brassica napus var. napobrassica), Brassica rapa var. silvestris, cabbage (Brassica oleracea), black mustard (Brassica nigra), Camellia sinensis, Carthamus tinctorius, Carya illinoinensis, Citrus limon 'Citrus sinensis', small fruit coffee °Coffea arabica (Coffea canephora, Coffea liberica), yellow Cucumber (Cucumis sativus), Cynodon dactylon, Daucus carota, Elaeis guineensis, Fragaria vesca, Glycine max, Gossypium hirsutum (tree cotton) Gossypium arboreum), Gossypium herbaceum, Gossypium vitifolium, Helianthus annuus, Hevea brasiliensis, Hordeum vulgare, Humulus lupulus, sweet potato Ipomoea batatas), Juglans regia, Lens culinaris, Linum usitatissimum, Lycopersicon lycopersicum, Malus spec., Manihot esculenta, Alfalfa Medicago sativa), Musa spec., Nicotiana tabacum (N.rustica), Olea europaea, Oryza sativa, Phaseolus lunatus, Bean (Phaseolus vulgaris), Norwegian spruce (Picea abies), Pinus spec. (Pistacia vera), Pistocia vera (Pisum sativum), Europe Cherry (Prunus avium), Prunus persica, Pyrus communis, Prunus armeniaca, European acid 150107.doc -10- 201109321 Cherry (Prunus cerasus), almond (Prunus dulcis) and apricot Prunus domestica, Ribes sylvestre, Ricinus communis, Sacchanmi officinarum, Secale cereale, Sinapis alba, Solanum tuberosum, sorghum (Sorghum bicolor) (蜀黍. s. vulgare), Theobroma cacao, Trifolium pratense, Wheat (Triticum aestivum), Triticale, Triticum durum, Broad Bean ( Vicia faba), Vitis vinifera, Zea mays 'especially crops of cereals, corn, soybeans, glutinous rice, canola, cotton aphid b, horse yam, peanuts or perennial crops. The invention also relates to a method of drying or shedding plants. The order in which the herbicidal active compounds of the components A) and B) and (if appropriate) c are combined or applied separately and applied in the case of separate application is not critical in the most recently mentioned method. [Embodiment] The organic part (for example, the term "_") mentioned in the definition of the variables R1 to R11 is a collective name for individual members of the group. In each case, the term "i prime" denotes 1, gas, and 1 . All hydrocarbon chains (i.e., all alkyl groups) may be straight or branched, and the prefix Cn_Cm, in each case, indicates the number of possible carbon atoms in the group. Examples of such meanings are: and CH(CH3)2; -G-C3-alkyl: ch3, C2H5, n-propyl C1-C4-alkyl Ci_c4_alkyl and n-butyl, ch(ch3)- -Ci-cv alkyl and C3_C6•cycloalkyl moiety: CrCr alkyl as described above, 150107.doc • 11 · 201109321 C2H5, CH2-CH(CH3)2 and c(ch3)3; -Ci-C6- Alkyl and crc6.alkyl moiety of c3-c6-cycloalkyl-c丨-C6-alkyl: CrC4-alkyl as described above and, for example, n-pentyl, fluorenylmethylbutyl, 2- Methyl butyl, 3-mercaptobutyl, 2,2-dimethylpropyl, ethyl propyl, n-hexyl, 1,1-dimercaptopropyl, 12 dimethyl propyl, plant Methylpentyl, 2-mercaptopentyl, 3-mercaptopentyl, 4-methylpentyl, 1}1-dimethylbutyl, 1,2-dimethylbutyl' L3-dimethyl Butyl, 2,2·dimethylbutyl, 2,3-dimethylbutyl, 3,3-dimethylbutyl, ethyl ethyl butyl, 2-ethylbutyl, 1,1,2- Trimethyl propyl, i, 2, 2 - tridecyl propyl ethyl 1-methyl propyl or 1-ethyl-2-mercaptopropyl 'preferably methyl, ethyl, n-propyl , 1-mercaptoethyl, n-butyl, U-didecylethyl, n-pentyl Or n-hexyl; • C1-C3 - haloalkyl: C丨-(:3_alkyl, as described above, partially or completely substituted by fluorocarbon, gas, bromine and/or iodine Such as (fluorenyl, trimethyl sulfhydryl, fluoromethyl, difluoromethyl, hydrazine, wind 1 gas sulfhydryl, gas · fluoro fluorenyl, methyl, 2-ethylidene, 2 -> stinky Ethyl 1 for example, gas fluorenyl, di-halo-fluoroindolyl, fluorofluoromethyl, iodonium, 2-fluoroethenylethyl, 22-difluoroethane, 2,2,2-trifluoroethyl , 2-Gas-2-fluoroethyl, 2 '^ 2, fluorinated difluoroethyl, 2,2_di- 2 -fluoroethyl, 2,2,2-trisylethyl, pentafluoroethyl, 2-fluoropropyl, 3-ethoxypropyl, 2,2-difluoropropyl, 2,3-di g# propylpropyl, 2-chloropropyl, 3-apropylpropyl, 2,3-dipropane Base, 2-bromopropyl, 3, self-propyl, 3,3,3-trifluoropropyl, 3,3,3-trichloropropyl, 2,2,3,3,3-five Gas | paper • internal group, heptafluoropropyl; -Cl-C4-haloalkyl. C p L. Haloalkyl as described above, and (for example) 1-(fluoroindolyl)-2-fluoroethyl Base, 1-(gas thiol T storm) _2-gas ethyl, i•(bromine 曱150107.doc -12- 201109321 基)·2· Base, 4_fluorobutyl, 4-dichlorobutyl, 4-dibutylbutyl, nona-butylbutyl, 1,1,2,2,-tetrafluoroethyl and trifluoromethyl_12,2,2 _tetrafluoroethyl; _ Ci_C6-haloalkyl: as described above (^-(: 4-haloalkyl, and, for example, 5-fluoropentyl, 5-chloropentyl, 5-bromopentyl, 5- Iodopentyl, undecafluoropentyl, 6-fluorohexyl, 6-chlorohexyl, 6-bromohexyl, 6-iodohexyl and dodecafluorohexyl; _ c3-c6-cycloalkyl and C3_C6_cycloalkyl a cycloalkyl moiety of C]_C4_alkyl and C3_C6_cycloalkyl-C^-C6-alkyl: a monocyclic saturated hydrocarbon having from 3 to 6 ring members, such as cyclopropyl, cyclobutyl, cyclopentane And cyclohexyl; _C3-C6-alkenyl. For example, 1-propenyl, 2-propenyl, 1-methylvinyl, 1-butenyl, 2-butenyl, 3-butenyl , 1-methyl_ι_propenyl, 2-methyl-1-propenyl, _methyl-2-propenyl, 2-methyl-2-propenyl, pentenyl, 2-pentene Base, 3-pentenyl, 4-pentenyl, 丨_曱yl_丨-butenyl, 2-mercapto-1-1-butenyl, 3-methyl-butenyl, ι_曱基_ 2_butanyl, 2-methyl-2-butenyl, 3-mercapto-2-butylenyl, 1- Base 3-butenyl, 2-mercapto-3-butenyl, 3-mercapto-3-butenyl, 1,1-dimethyl-2-propanyl 1,2 - fluorenyl 1-propenyl, iota, 2-dimercapto-2-propenyl, 1-ethyl-1-propenyl, 1-ethyl-2-propenyl, 1-hexenyl, 2-hexene , 3-hexenyl, 4-hexenyl, 5-hexenyl, 1-decyl-1-pentenyl, 2-mercapto-1-pentenyl, 3-mercapto-1-pentene , 4-mercapto-1-pentenyl, 1-decylpentenyl, 2-decyl-2-pentenyl, 3-methyl-2-pentenyl, 4-mercapto-2- Pentenyl, methyl-3.pentenyl, 2-methyl-3-pentenyl, 3-mercapto-3-pentenyl, 4-mercapto-3-pentenyl, fluorenyl-4 _pentenyl, 2-mercapto-4_ fluorenyl, 3-methyl-4-pentenyl, 4-methyl-4-pentyl ' 1,1-dimethyl-150107.doc -13 · 201109321 2-butenyl, 1,1-dimethyl-3-butanyl, iota, 2-dimethylbutenyl, 1,2-dimercapto-2-butenyl '1,2 _Dimercapto-3-3-butenyl, 1,3-diindenyl-1-butanyl, 1,3-dimethyl-2-butenyl, iota, 3-didecyl-3-but Sulfhydryl, 2.2-dimercapto-3-butenyl, 2,3-dimethyl-1-butenyl, 2,3-diindenyl-2-butenyl , 2,3-dimercapto_3_butenyl, 3,3-diindenyl·ι_butenyl, 3,3_monodecyl-2-butenyl, 1-ethyl-1-butenyl, 1-ethyl-2-butenyl, 1-ethyl-3-butenyl, 2-ethyl-1-butenyl, 2-ethyl-2-butenyl, 2-ethyl-3 -butenyl, 丨山八三曱基_2_propenyl, 丨_ethyl l methyl-2-propenyl, 1·ethyl_2_fluorenyl-丨-propenyl and 丨·ethyl hydrazine -C3-C6-haloalkenyl: a c3-C6-alkenyl group as described above which is partially or completely substituted by fluorine, chlorine, bromine and/or iodine, for example, 2·chloropropane -2-en-1-yl, 3-aceto-2-ene-1-yl, 2,3-dichloroprop-2-en-1-yl, 3,3-dipropane-2-ene- 1-yl, 2,3,3-tris-2-en-1-yl, 2,3-dioxabut-2-en-1-yl, 2-bromoprop-2-en-1-yl, 3-bromopropan-2-ylidene-1-yl, 2,3-dibromoprop-2-en-1-yl, 3,3-dibromoprop-2-en-1-yl, 2,3,3 -Tribromo-2-en-1-yl or 2.3-dibromobut-2-en-1-yl; -C3-C6-alkynyl: for example, 1-propynyl, 2-propynyl, 1- Butynyl, 2-butanyl, 3-butanyl, 1-methyl-2-propanyl, 1-pentyl, 2-pentynyl, 3-pentynyl, 4-pentynyl, 1-mercapto-2-butyne , 1-mercapto-3-butynyl, 2-mercapto-3-butynyl, 3-mercapto-1-butynyl, 1,1-didecyl-2-propynyl, 1 -ethyl-2-propynyl, 1-hexynyl, 2-hexynyl, 3-hexynyl, 4-hexynyl, 5-hexynyl, 1-decyl-2-pentynyl , 1-mercapto-3-pentynyl, 1-methyl-4-pentynyl, 2-mercapto-3-pentynyl, 2-mercapto-4-150107.doc -14- 201109321 pentyne , 3-mercapto-oxime-pentynyl, 3-methyl-4-cyclopentynyl, 4-decylpentynyl, 4-methyl-2-pentynyl, 1,1-dimethyl- 2. Butynyl, hydrazine, dimethyl-3-butanyl, 1,2-dimethyl-3-butanyl, 2,2-dimethyl-3-butanyl, 3,3 - dimethyl-1-butynyl, i-ethylbutynyl, 丨_ethyl_3_butanyl, 2-ethyl-3-butanyl and 1-ethyl-1-methyl _2_丙快基; -CVC6-halogen block: C3_c6-alkynyl as described above, which is partially or completely substituted by fluorine, gas, bromine and/or hard 'for example, 丨-difluoropropene _ 2_block, 1-yl, 3-iodoprop-2-yn-1-yl, 4-fluorobut-2-yne_ι-yl, 4-cyclobut-2-yne-1-yl, fluorene-di Fluor-2-ynyl-1-yl, 4-iodobutyl-3-alkynyl, 5-fluoropenta, 3-yn-1-yl, 5-iodopent-4-yn-1- , 6-1, 4-cyclo-1-yl or 6-iodohexyl-5-yn-1-yl; 'Cl_C3_alkoxy: methoxy, ethoxy, propoxy, 1-anthracene Ethyl group; _C-C4_alkoxy: Cl_C3·alkoxy as described above, and, for example, butoxy, 1-methylpropoxy, 2-methylpropoxy and u • dimethylethoxy; -q-C6·alkoxy: Cl_c4•alkoxy as described above, and, for example, pentyloxy, 1-decylbutoxy, 2-mercaptobutoxy , 3-methoxybutoxy, 1,1-dimethylpropoxy, 1,2-dimethylpropoxy, 2,2-dimethylpropoxy, 1-ethylpropoxy , hexyloxy, hydrazine-methylpentyloxy, 2-methylpentyloxy, 3-mercaptopentyloxy, 4-mercaptopentyloxy, iota, dimercaptobutoxy, 1, 2-Dimercaptobutoxy, L3-dimethylbutoxy, 2,2-dimethylbutoxy, 2,3-didecylbutoxy, 3,3-dimethylbutoxy , ethenyloxy, 2-ethylbutoxy, l,i,2-trimethylpropoxy, hydrazine, 2,2-trimethylpropene 150107.doc •15· 201109321 oxy, 1-B 1-methylpropoxy and puethyl-2-indolyl propoxy; mentioned in the following Preferred embodiment of the present invention must be understood as preferably combined with one another independently of one another bearing. According to a first preferred embodiment of the present invention, the composition comprises at least one, preferably L, of a stupid and p-cultivated compound of formula I.1 (corresponding to r1 and R2 systems q-cv alkyl, ...素, R, $C3_C6_ alkynyl' χ and 丫〇〇式呤呤呤呤呤呤呤呤呤呤呤呤呤呤呤呤呤呤呤呤呤呤

Ci-Cr烧基Ci-Cr base

根據本發明之第二貫施例，組合物包含至少一種、較佳恰好一種式Ι·2之苯并嘮畊酮化合物（對應於尺3係C3_C6_函代炔基且Y係〇之式〗化合物）作為組份AAccording to a second embodiment of the present invention, the composition comprises at least one, preferably exactly one, benzoxanthene compound of the formula (2 (corresponding to the C3_C6_complex alkynyl group of the ulnar 3 system and the formula of the Y system) Compound) as component A

其中：among them:

Rl係氫或Ci-CV烷基，較佳係c〗-cv烷基，更佳係ch3 ; R2係氫、NHrCVCV燒基或C3_C6_块基，較佳係C^-C6·烧基，更佳係ch3 ; R 係氫或齒素， 150107.doc •16- 201109321 較佳係鹵素，平乂住你囹京，更佳係F ;且 X 係0或S，較佳係S。R1 is hydrogen or Ci-CV alkyl, preferably c-cv alkyl, more preferably ch3; R2 hydrogen, NHrCVCV alkyl or C3_C6_block, preferably C^-C6·alkyl, more Good system ch3; R is hydrogen or dentate, 150107.doc •16-201109321 It is preferably halogen, which is better for you, and better for F; and X is 0 or S, preferably S.

c0-炔基之式I化合物）作為組份A &至少一種、較佳應於R2係ΝΗ2或C3-a compound of formula I of c0-alkynyl) as component A & at least one, preferably in R2 system ΝΗ2 or C3-

y\ \\ U NH2 或(：3<：6·炔基其中：y\ \\ U NH2 or (:3<:6· alkyne)

Rl係氳或CVC6-烷基，較佳係C^-Cr烷基，更佳係ch3 ; R 係氫或鹵素，較佳係鹵素，更佳係F ; R係氫、q-cv烧基、q-cv _代烧基、c3-c6-環烷基、c3-c6-稀基、c3-c6-鹵代烯基、c3-C6-块基、C,-c6-燒氧基或c3-c6-環烷基_Cl_c6-烷基，較佳係C3-C6-炔基’更佳係ch2C=CH; x係ο或s，較佳係s ;且 γ係〇或s，較佳係0。根據本發明之第四實施例，組合物包含至少一種、較佳 150107.doc •17· 201109321Rl is hydrazine or CVC6-alkyl, preferably C^-Cr alkyl, more preferably ch3; R is hydrogen or halogen, preferably halogen, more preferably F; R is hydrogen, q-cv alkyl, Q-cv _ alkylene, c3-c6-cycloalkyl, c3-c6-dilute, c3-c6-haloalkenyl, c3-C6-blockyl, C,-c6-alkoxy or c3- C6-cycloalkyl-Cl_c6-alkyl, preferably C3-C6-alkynyl' is more preferably ch2C=CH; x is ο or s, preferably s; and γ is 〇 or s, preferably 0 . According to a fourth embodiment of the invention, the composition comprises at least one, preferably 150107.doc • 17· 201109321

洽好種式L4之苯并啰畊酮化合物（對應於¥係s之式τ化合物）作為組份AThe benzoxanthone compound of the formula L4 (corresponding to the τ compound of the formula s) is used as the component A.

其中： R1係氫或cvcv烷基，較佳係Ci-CV烷基，更佳係ch3; R2係氫、nh2、q-cv烷基或c3-c6-炔基，較佳係CVC6-烷基，更佳係ch3; R 係氫或_素，較佳係_素，更佳係F ; R 係風、Ci-cv烧基、c!-c6-鹵代烧基、c3-c6-環烧基、c3-c6-烯基、c3-c6-鹵代烯基、c3-c6-炔基、c3-c6-鹵代炔基、C「C6-烷氧基或c3-c6-環烷基-CVCV 烧基，較佳係c3-c6-炔基，更佳係CH2C^CH;且 X 係Ο或S，較佳係S » 作為組份A係本發明組合物之成份之較佳式I化合物係如上所定義之1.1至1.4化合物；尤其係下文所列示之1.1.1、 1.2.1、1.2.2、1.3.1、1.3.2及 1.4.1 之化合物： 1.1.1 3-[7-氟-3-側氧基-4-(丙-2-炔基）-3,4-二氫-2H-苯并 150107.doc •18- 201109321 [1，4]噚畊-6-基]-1，5-二曱基-6-硫代-[1,3,5]氫化三畊 2,4-二酮，Wherein: R1 is hydrogen or cvcv alkyl, preferably Ci-CV alkyl, more preferably ch3; R2 is hydrogen, nh2, q-cv alkyl or c3-c6-alkynyl, preferably CVC6-alkyl More preferably, ch3; R is hydrogen or _, preferably _, better, F; R, wind, Ci-cv, c!-c6-halogen, c3-c6-ring , c3-c6-alkenyl, c3-c6-haloalkenyl, c3-c6-alkynyl, c3-c6-haloalkynyl, C"C6-alkoxy or c3-c6-cycloalkyl- CVCV alkyl, preferably c3-c6-alkynyl, more preferably CH2C^CH; and X is hydrazine or S, preferably S» is a preferred compound of formula I as component A of the composition of the invention. A compound of 1.1 to 1.4 as defined above; especially a compound of 1.1.1, 1.2.1, 1.2.2, 1.3.1, 1.3.2 and 1.4.1 listed below: 1.1.1 3-[7 -fluoro-3-oxo-4-(prop-2-ynyl)-3,4-dihydro-2H-benzo-150107.doc •18- 201109321 [1,4]噚耕-6-基] -1,5-dimercapto-6-thio-[1,3,5] hydrogenated three-plow 2,4-dione,

1.2.1 3-[4-(3-氣丙-2-炔基）-7-氟-3-側氧基-3,4-二氫-2H-苯并[b][l,4]吟畊-6-基]-1,5-二曱基-6-硫代-1，3,5-氫化三畊-2,4-二酮，1.2.1 3-[4-(3-Aceto-2-ynyl)-7-fluoro-3-indolyl-3,4-dihydro-2H-benzo[b][l,4]吟Plough-6-yl]-1,5-dimercapto-6-thio-1,3,5-hydrogenated trinyl-2,4-dione,

CI 1.2.1; 1.2.2 3-[4-(3-溴丙-2-炔基）-7-氟-3-側氧基-3,4-二氫-2H-苯并[b][l,4p号畊-6-基]-1，5-二曱基-6-硫代-1，3,5-氫化三畊-2,4-二酮，CI 1.2.1; 1.2.2 3-[4-(3-Bromoprop-2-ynyl)-7-fluoro-3-indolyl-3,4-dihydro-2H-benzo[b][ l, 4p cultivable-6-yl]-1,5-dimercapto-6-thio-1,3,5-hydrogenated trinyl-2,4-dione,

HXHX

Br 1.2.2; 1.3.1 1-丙炔-2-基-3-[7-氟-3-側氧基-4-(丙-2-炔基）-3,4-二氫-2H-苯并[1,4]呤畊-6-基]-5-曱基-6-硫代-[1,3,5]氫化三畊-2,4-二酮， 150107.doc •19· 201109321Br 1.2.2; 1.3.1 1-propyn-2-yl-3-[7-fluoro-3-o-oxo-4-(prop-2-ynyl)-3,4-dihydro-2H- Benzo[1,4]indole-6-yl]-5-mercapto-6-thio-[1,3,5]hydrogenated tri-n- 2,4-dione, 150107.doc •19· 201109321

1.3.2卜胺基·3-(7-氟-3-側氧基-4_(丙_2_炔基）_3,4_二氫-2H-苯并[b][i，4]«»号井-6-基）-5·甲基 _6_硫代-1，3,5 -氫化三°井-2,4-二綱，1.3.2 Amino 3-(7-fluoro-3-indolyl-4_(prop-2-ynyl)_3,4-dihydro-2H-benzo[b][i,4]«» No.-6-yl)-5·methyl_6_thio-1,3,5-hydrogenated three-well-2,4-two,

ch3 η2νCh3 η2ν

S I·4·1 3-[7-氟-3-硫基-4-丙-2-炔基-3,4-二氫-2H-苯并 [1，4]>»号'1井_6-基]-1，5-二甲基_6-硫代_[1，3,5]氫化三》»井_ 2,4-二酮，SI·4·1 3-[7-fluoro-3-thio-4-prop-2-ynyl-3,4-dihydro-2H-benzo[1,4]> 6-yl]-1,5-dimethyl-6-thio-[1,3,5]hydrogenated three»» Well _ 2,4-dione,

h3c SH3c S

1.4.1. 根據本發明一尤佳實施例，組合物含有式1.1 · 1之苯并《号畊酮作為組份A。根據本發明另一尤佳實施例，組合物含有式1.2· 1之苯并井綱作為組份A。根據本發明另一尤佳實施例，組合物含有式Ι.2·2之苯并井酮作為組份Α。根據本發明另一尤佳實施例，組合物含有式Ι·.3· 1之苯并 150107.doc -20- 201109321 号π井酮作為組份A。根據本發明另一尤佳實施例，組合物含有式1.3.2之苯并啰畊酮作為組份A。根據本發明另一尤佳實施例，組合物含有式1.4.1之苯并噚畊酮作為組份A。自WO 02/066471已熟知式1.1之苯并呤畊酮化合物。式、1.3及1.4之苯并$畊酮化合物係新穎化合物，且同樣亦形成本發明之標的物之一部分。因此，本發明另外係關於式Ι·2、1.3及1.4之苯并哼畊酮化合物：1.4.1. According to a particularly preferred embodiment of the invention, the composition comprises benzohexanone of formula 1.1.1 as component A. According to another particularly preferred embodiment of the invention, the composition contains benzoxene of formula 1.2·1 as component A. According to another particularly preferred embodiment of the invention, the composition contains benzoxanone of the formula 2.6. 2 as component hydrazine. According to another particularly preferred embodiment of the present invention, the composition contains Benzene 150107.doc -20-201109321 π ketene of the formula Ι·········· According to another particularly preferred embodiment of the invention, the composition comprises benzoxanthone of formula 1.3.2 as component A. According to another particularly preferred embodiment of the invention, the composition contains benzoxanthene of the formula 1.4.1 as component A. The benzoxanthone compound of the formula 1.1 is well known from WO 02/066471. The benzoxanthene compounds of the formulae, 1.3 and 1.4 are novel compounds and likewise form part of the subject matter of the present invention. Accordingly, the present invention is also directed to benzoxanthene compounds of the formula: Ι, 2, 1.3 and 1.4:

其中：among them:

Rl係氫或CVCV烷基； R2係氩、NH^CVCV烷基或C3-C6-炔基； R3係氫或鹵素；且 X 係〇或s ;R1 is hydrogen or CVCV alkyl; R2 is argon, NH^CVCV alkyl or C3-C6-alkynyl; R3 is hydrogen or halogen; and X is hydrazine or s;

nh2 或(：3-(：6-炔基其中： 150107.doc -21 - 201109321 R1係氫或cvcv烷基； R 係氫或鹵素； r4係氫、CVC6-烷基、CrCV鹵代烷基、c3-c6-環烷基、C3-C6-烯基、c3-c6-鹵代烯基、C3-C6-炔基、C!-c6-烷氧基或c3-C6-環烷基-CrCV烷基； X 係Ο或S ;且 γ 係〇或s ;Nh2 or (: 3-(:6-alkynyl which: 150107.doc -21 - 201109321 R1 is hydrogen or cvcv alkyl; R is hydrogen or halogen; r4 is hydrogen, CVC6-alkyl, CrCV haloalkyl, c3- C6-cycloalkyl, C3-C6-alkenyl, c3-c6-haloalkenyl, C3-C6-alkynyl, C!-c6-alkoxy or c3-C6-cycloalkyl-CrCV alkyl; X system or S; and γ system or s;

R2 其中： R係氫或Ci-C6-烷基； r2係氫、ΝΗ2、（ν(：6-烷基或C3-C6-炔基； R係氫或ii素； r4係氫、c,-c6-烷基、CVC6·鹵代烷基、c3-c6-環烷基、c3-c6-烯基、c3-C6-鹵代烯基、c3-c6-炔基、c3- c6-函代炔基、Cl_c6_烷氧基或c3_c6_環烷基_Cl_c6-烷基； x 係0或S。較佳者為彼等式Ι·2、1.3及1.4之化合物，其中變量R1、 2 3 R R、x及Y具有如上所定義之較佳含義。尤佳者係式1_2.1、丨2.2、1.3.1、1.3.2及1.4.1之化合物： 150107.doc -22- 201109321R2 wherein: R is hydrogen or Ci-C6-alkyl; r2 is hydrogen, hydrazine 2, (ν(:6-alkyl or C3-C6-alkynyl; R is hydrogen or ii; r4 is hydrogen, c, - C6-alkyl, CVC6.haloalkyl, c3-c6-cycloalkyl, c3-c6-alkenyl, c3-C6-haloalkenyl, c3-c6-alkynyl, c3-c6-hoxoalkynyl, Cl_c6_alkoxy or c3_c6_cycloalkyl_Cl_c6-alkyl; x is 0 or S. Preferred are compounds of the formula Ι·2, 1.3 and 1.4, wherein the variables R1, 2 3 RR, x and Y has the preferred meaning as defined above. Particularly preferred are compounds of formulas 1_2.1, 丨2.2, 1.3.1, 1.3.2 and 1.4.1: 150107.doc -22- 201109321

式I之笨并噚啫酮化合物且尤其彼等式I 2、13及14之化合物可藉由各種途徑製得，例如藉由下列方法製得：· 方法A) ^ 類似於 J_ Chem. Soc. perkin Trans.(1982)，第 1321頁Compounds of the formula I, and especially the compounds of the formulae I, 13 and 14, can be prepared by various routes, for example by the following methods: Method A) ^ Similar to J_Chem. Soc. Perkin Trans. (1982), p. 1321

I其中R2係CH3 如所述公開案中所規定來實施該反應。方法B) 使異氰酸醋1V與脲III進行反應，隨後對反應產物V實施環化：I wherein R2 is CH3 is carried out as specified in the publication. Process B) The isocyanate 1V is reacted with urea III, followed by cyclization of the reaction product V:

RxRx

NIRNIR

150107.doc150107.doc

V 23· 201109321 較佳在活化羰基源（例如羰二咪唑、光氣、雙光氣、三光氣及氯曱酸酯）存在下，使異氰酸酯IV與脲m發生反應0 較佳在不分離中間體v之情形下實施環化。可進而自相應胺VI獲得異氰酸酯iv :V 23· 201109321 It is preferred to react isocyanate IV with urea m in the presence of an activated carbonyl source (eg, carbonyldiimidazole, phosgene, diphosgene, triphosgene, and chlorodecanoate). 0 Preferably, the intermediate is not isolated. Cyclization is carried out in the case of v. The isocyanate iv can be obtained further from the corresponding amine VI:

R3=氟且r4=炔丙基之胺¥1及其各種製備途徑亦在pr〇fR3=Fluorine and r4=Alkynylamine ¥1 and its various preparation routes are also in pr〇f

Boger之文章：「Peroxidizing Herbicides」，Springer-Verlag 1999，第32頁中為人所熟知。可以類似方式獲得其他胺 VI 〇方法C) 使R係氫之式I化合物以本身已知之方式烧基化，從而產生R4係（VCV烷基、CVCV鹵代烷基、c3-C6-環烧基、 C3-C6-稀基、C3-C6-函代稀基、c3_c6_快基、c3_c6_齒代快基或C3-C0-環院基-Ci-CV烧基之式I化合物。以本身已知方式（例如）使用烷基化試劑（例如，鹵化物R4-Ha]l)在驗存在下在溶劑中實施烷基化。方法A)、B)及C)較佳係在適宜反應輔助劑存在下實施。通常’適宜反應物係常用無機或有機鹼及酸受體。該等反應物較佳包括鹼金屬及鹼土金屬之乙酸鹽、醯胺、碳酸鹽、碳酸氫鹽、氫化物、氫氧化物及醇鹽，亦即，例如， 150107.doc •24· 201109321 乙酸鈉、乙酸鉀、乙酸鈣、醯胺鋰、醯胺鈉、醯胺鉀、醯胺約、碳酸納、碳酸鉀、碳酸辦、碳酸氫鈉、碳酸氫卸、碳酸氫鈣、氫化鋰、氫化鈉、氫化鉀、氫化鈣、氫氧化鐘、氫氧化鈉、氫氧化鉀、氫氧化鈣、甲醇鈉、乙醇鈉、正丙醇鈉、異丙醇鈉、正丁醇鈉、異丁醇鈉、第二丁醇鈉、第三丁醇鈉、甲醇卸、乙醇鉀、正丙醇鉀、異丙醇鉀、正丁醇鉀、異丁醇鉀、第二丁醇鉀、第三丁醇鉀；另外亦包括鹼性有機氮化合物，例如，三甲胺、三乙胺、三丙胺、三丁胺、乙基二異丙胺、NN_二甲基環己胺、雙環己胺、乙基二異丙胺、N，N-二曱基笨胺、Ν,Ν-二曱基苄胺、吼啶、2-甲基吡啶、3-曱基吡啶、4-甲基吡啶、2,4-一曱基°比°定、2,6-二甲基1>比0定、3,4-二甲基。比。定及3,5-二甲基吡啶、5-乙基-2-甲基吡啶、4-二甲基胺基吡啶、Ν_甲基六氫》比。定、1，4-二氮雜雙環[2,2,2]辛烷（DabC0)、丨，5_二氮雜雙環[4,3,0]壬-5-烯（DBN)或1,8-二氮雜雙環[5,4,0] Η--- 7-烯（DBU)。方法A)、Β)及C)通常係在惰性稀釋劑存在下實施，適宜稀釋劑通常為常用有機溶劑。該等稀釋劑較佳包括脂肪族、脂環族及芳族、視需要_代烴，例如，戊烷、己烷、庚烷、石油醚、輕石油、苯、曱苯、二曱苯、氣苯、二氣苯、環己烧、曱基環己烧、二氣甲烧、三氣甲院、四氣甲烧、二烧基醚（例如，二乙醚、二異丙醚、曱基第三丁基鱗（ΜΤΒΕ)、乙基第三丁基酸、审真笛—丄、甘》 J丞吸肀暴第二戍基醚（TAME)、乙基第三戊基醚、四氫呋喃、i，4_二„号烷、乙二醇二曱 150107.doc •25· 201109321 醚、乙一醇—乙醚、二乙二醇二甲醚、二乙二醇二乙醚），一烷基酮（例如，丙酮、丁酮（甲基乙基酮）、甲基異丙基酮及甲基異丁基酮）；腈（例如，乙腈、丙腈、丁猜及卞腈），醯胺（例如，N，N_:甲基甲醯胺、N，N•二甲基乙醯胺、N·甲基甲醯笨胺、N_甲基吼洛咬嗣及六甲基碟酸三酿胺）；酯(例如’乙酸甲酯、乙酸乙酯、乙酸正丙酯、乙酸異丙S曰、乙酸正丁酯、乙酸異丁酯及乙酸第二丁酯广亞砜類（例如，二甲亞砜）；烷醇（例如，甲醇、乙醇、正丙醇異丙醇、正丁醇、異丁醇、第二丁酵及第三丁醇）；一醇，醚（例如，乙二醇單甲醚、乙二醇單乙醚、二乙二醇早曱醚及二乙二醇單乙醚）；其與水或純水之混合物。田實把方法A)、B)及C)時，反應溫度可在大致範圍（例士）0 200 C内有所變化。該等方法較佳係在下、尤其20°C至所述反應混合物之沸點下實施。通韦，以大約等莫耳量使用起始材料。然而，亦可使用各反應物過量至高達另一反應物之莫耳量的約兩倍。方法A)、B)及C)係在大氣壓下或在所述反應混合物之固有壓力下方便地實施。然@，亦可在高壓或低壓下（通常在〇·1巴至10巴下）實施該等方法。通常’藉由本身已知方法來處理所述反應混合物以得到產物，例如，使用水稀釋反應溶液且隨後藉助過濾、結晶或溶劑萃取分離產物；或去除溶劑，將殘留物分配於水與適宜有機溶劑之混合物之間，並處理有機相。根據本發明之第一實施例，組合物含有至少一種脂質生 150107.doc •26· 201109321 物合成抑制劑（除草劑b l)。該等抑制劑係抑制脂質生物合成之化合物。可經由抑制乙醯基C〇a竣化酶（下文稱作acC 除草劑）或經由不同作用模式（下文稱作非ACC除草劑）來抑制月曰質生物合成。ACC除草劑屬於HRAC分類系統之a 類，而非ACC除草劑屬於HRAC分類系統之N類。根據本發明之第二實施例，組合物含有至少一種ALS抑制劑（除草劑b2)。該等化合物之除草活性係基於對於乙醯乳酸合酶之抑制且因而基於對於具支鏈胺基酸生物合成之抑制。該等抑制劑屬於HRAC分類系統中之B類。根據本發明之第三實施例，組合物含有至少一種光合作用抑制劑（除草劑b3)。該等化合物之除草活性係基於對於植物中之光系統π之抑制（所謂削抑制劑，hrac分類之 Cl、C2及C3類）或基於使植物巾之光i纟41之電子轉移轉向 (所謂PSI抑制劑，HRAC分類之D類）且因而基於對於光合作用之抑制。其中，PSII抑制劑較佳。根據本發明之第四實施例，組合物含有至少一種原卟啉原-IX_氧化酶抑制劑（除草劑M)。該等化合物之除草活性系土於對於原外琳原_ΙΧ1化酶之抑制。該等抑制劑屬於 HRAC分類系統中之Ε類。據本發明之第五實施例，組合物含有至少一種色素抑 _除草d (除草劑b5)。該等化合物之除草活性係基於對於_’^素生物合成之抑制。該等抑制劑包括藉由抑制八虱田番加紅素去飽和酶抑制類胡蘿葡素生物合成之化合物 (“PDS抑制劑’ HRAC分類中之以類）、抑制心經基苯基 150107.doc •27. 201109321 丙酮酸·雙氧化酶之化合物（HPPD抑制劑，HRAC分類中之 F 2類）及藉由未知作用方式抑制類胡蘿蔔素生物合成之化合物（色素抑制型-未知靶標，HRAC分類中之^類卜根據本發明之第六實施例，組合物含有至少一種EPSP 合酶抑制劑（除草㈣）。料化合物之除草活性係基於對於稀醇丙酮醯莽草酸_3_填酸合酶之抑似因而基於對於植物中之胺基st生物合成的抑制。該等抑制劑屬於hrac分類系統中之G類。根據本發日月之第七實施例，组合物含有至少一種麵酿胺酸合成酶抑制劑（除草劑…）。該等化合物之除草活性係基於對於麩醯胺酸合成酶之抑制且因而基於對於植物中之胺基酸生物合成的抑制。該等抑制劑屬於HRAC分類系統中之Η類。根據本發明之第八實施例，組合物含有至少一種合酶抑制劑（除草劑b8)。該等化合物之除草活性係基於對於 7,8- 一氫蝶酸合成酶之抑制。該等抑制劑屬於hraC分類系統中之I類。板據本發明之第九實施例，組合物含有至少一種有絲分裂抑制劑（除草劑b9)。該等化合物之除草活性係基於微^ 形成或組織之紊亂或抑制且因而基於有絲分裂抑制。該等抑制劑屬於HRAC分類系統中之Κ1&Κ2類。其中，K1類化合物（尤其二硝基苯胺）較佳。根據本發明之第十實施例，組合物含有至少— 抑制劑（除草劑blO)。該等化合物之除草活性係基於對於極 •28* 150107.doc 201109321 長鏈脂肪酸合成之抑制且因而基於植物中之細胞分裂的齋亂或抑制。該等抑制劑屬於HRAC分類系統中之κ3類。根據本發明之第十—實施例，組合物含有至少—種纖維素生物合成抑制劑（除草劑bll)。該等化合物之除草活性係土於對於纖維素生物合成之抑制且因而基於對於植物中之，’·田胞J生物合成的抑制。該等抑制劑屬於hrac分類系統中之L類。根據本發明之第十二貫施例，組合物含有至少一種去偶〇除草劑（除草劑M2)。該等化合物之除草活性係基於細胞膜之破壞。該等抑制劑屬於HRAC分類系統中類。根據本發明之第十三實施例，組合物含有至少一種生長素除草劑（除草劑M3)。該等除草劑包括如生長素（即，植物激素）起作用且抑制植物生長之化合物。該等化合物屬於HRAC分類系統中之〇類。根據本發明之第十四實施例，組合物含有至少一種生長素轉運抑制劑（除草劑b丨句。該等化合物之除草活性係基於對於植物中生長素轉運之抑制。該等化合物屬於Hrac分類系統中之p類。關於給定作用機制及活性物質之分類，參見（例如）「HRAC，Boger's article: "Peroxidizing Herbicides", Springer-Verlag 1999, page 32 is well known. Other amines VI can be obtained in a similar manner. C) The compounds of formula I wherein R is hydrogen are alkylated in a manner known per se to give R4 (VCV alkyl, CVCV haloalkyl, c3-C6-cycloalkyl, C3) -C6-dilutyl, C3-C6-complex, c3_c6_fast, c3_c6-dentate or C3-C0-ring-based-Ci-CV-based compound of formula I. Alkylation is carried out, for example, in a solvent using an alkylating agent (for example, a halide R4-Ha). The methods A), B) and C) are preferably in the presence of a suitable reaction adjuvant. Implementation. Generally, the appropriate reactants are commonly used as inorganic or organic bases and acid acceptors. The reactants preferably include alkali metal and alkaline earth metal acetates, guanamines, carbonates, hydrogencarbonates, hydrides, hydroxides and alkoxides, that is, for example, 150107.doc •24·201109321 sodium acetate , potassium acetate, calcium acetate, lithium amide, sodium decylamine, potassium guanamine, guanamine, sodium carbonate, potassium carbonate, carbonate, sodium hydrogencarbonate, hydrogencarbonate, calcium hydrogencarbonate, lithium hydride, sodium hydride, Potassium hydride, calcium hydride, hydrazine hydroxide, sodium hydroxide, potassium hydroxide, calcium hydroxide, sodium methoxide, sodium ethoxide, sodium n-propoxide, sodium isopropoxide, sodium n-butoxide, sodium isobutoxide, second Sodium butoxide, sodium butoxide, methanol, potassium ethoxide, potassium n-propoxide, potassium isopropoxide, potassium n-butoxide, potassium isobutoxide, potassium dibutoxide, potassium t-butoxide; Including basic organic nitrogen compounds, for example, trimethylamine, triethylamine, tripropylamine, tributylamine, ethyldiisopropylamine, NN-dimethylcyclohexylamine, dicyclohexylamine, ethyldiisopropylamine, N, N-dimercaptoamine, anthracene, fluorenyl-dibenzylbenzylamine, acridine, 2-methylpyridine, 3-mercaptopyridine, 4-methylpyridine, 2 , 4-anthracene ratio, 2,6-dimethyl 1> ratio 0, 3,4-dimethyl. ratio. The ratio of 3,5-dimethylpyridine, 5-ethyl-2-methylpyridine, 4-dimethylaminopyridine, and hydrazine-methylhexahydro was determined. Ding, 1,4-diazabicyclo[2,2,2]octane (DabCO), hydrazine, 5-diazabicyclo[4,3,0]non-5-ene (DBN) or 1,8 - Diazabicyclo[5,4,0] fluorene---7-ene (DBU). Processes A), Β) and C) are usually carried out in the presence of an inert diluent, usually a customary organic solvent. The diluents preferably include aliphatic, alicyclic and aromatic, optionally hydrocarbons, for example, pentane, hexane, heptane, petroleum ether, light petroleum, benzene, toluene, diphenylbenzene, gas. Benzene, two-gas benzene, cyclohexene, decyl cycline, two gas carbs, three gas, three gas, two alkyl ether (for example, diethyl ether, diisopropyl ether, sulfhydryl third Butyl scale (ΜΤΒΕ), ethyl tert-butyl acid, trial flute - 丄, Gan" J丞肀戍 second base ether (TAME), ethyl third amyl ether, tetrahydrofuran, i, 4 _Dioxane, ethylene glycol dihydrazide 150107.doc •25· 201109321 ether, ethyl alcohol-diethyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether), monoalkyl ketone (eg, acetone, Butanone (methyl ethyl ketone), methyl isopropyl ketone and methyl isobutyl ketone); nitrile (for example, acetonitrile, propionitrile, dibutyl phthalonitrile), guanamine (for example, N, N_: Methylformamide, N,N-dimethylacetamide, N-methylformamidine, N-methylindole, and hexamethyldissolvate; esters (eg 'acetic acid') Methyl ester, ethyl acetate, acetic acid , isopropyl sulfonium acetate, n-butyl acetate, isobutyl acetate and second butyl sulfoxide (for example, dimethyl sulfoxide); alkanol (eg, methanol, ethanol, n-propanol isopropanol) , n-butanol, isobutanol, second butyrate and third butanol); monools, ethers (eg, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, diethylene glycol early ether and two Glycol monoethyl ether); a mixture with water or pure water. When the methods A), B) and C) are used, the reaction temperature can be varied within a range of approx. 0 200 C. Preferably, it is carried out underneath, in particular at a temperature of from 20 ° C to the boiling point of the reaction mixture. The starting materials are used in an amount of about the same molar amount. However, it is also possible to use an excess of each reactant up to another reactant. About twice the amount of the ear. Methods A), B) and C) are conveniently carried out at atmospheric pressure or under the inherent pressure of the reaction mixture. However, @, can also be under high pressure or low pressure (usually at 〇·1) The method is carried out at a rate of up to 10 bar. Usually, the reaction mixture is treated by a method known per se to obtain a product, for example Diluting the reaction solution with water and then separating the product by filtration, crystallization or solvent extraction; or removing the solvent, dispensing the residue between a mixture of water and a suitable organic solvent, and treating the organic phase. According to the first embodiment of the present invention The composition contains at least one lipid 150107.doc •26·201109321 synthesis inhibitor (herbicide bl). These inhibitors are compounds that inhibit lipid biosynthesis by inhibiting acetamyl C〇a oxidase ( The sputum biosynthesis is inhibited by different modes of action (hereinafter referred to as non-ACC herbicides). ACC herbicides belong to the class A of the HRAC classification system, and non-ACC herbicides belong to the HRAC classification system. Class N. According to a second embodiment of the invention, the composition contains at least one ALS inhibitor (herbicide b2). The herbicidal activity of these compounds is based on inhibition of acetamidine lactate synthase and thus on inhibition of branched chain amino acid biosynthesis. These inhibitors belong to class B of the HRAC classification system. According to a third embodiment of the invention, the composition contains at least one photosynthesis inhibitor (herbicide b3). The herbicidal activity of these compounds is based on the inhibition of π on the photosystem in plants (so-called inhibitors, Cl, C2 and C3 in hrac classification) or on the transfer of electrons in the light of plant towels (so-called PSI) Inhibitors, class D of the HRAC classification) and thus based on inhibition of photosynthesis. Among them, PSII inhibitors are preferred. According to a fourth embodiment of the invention, the composition contains at least one protoporphyrinogen-IX_oxidase inhibitor (herbicide M). The herbicidal activity of these compounds is in the inhibition of the original liningerase. These inhibitors belong to the genus of the HRAC classification system. According to a fifth embodiment of the invention, the composition contains at least one pigment inhibiting herbicide d (herbicide b5). The herbicidal activity of these compounds is based on inhibition of biosynthesis of _'. The inhibitors include a compound which inhibits the biosynthesis of carotenoids by inhibiting the scutellarin serotonin desaturase ("PDS inhibitors" in the HRAC classification), inhibiting cardiophenyl phenyl 150107.doc •27.201109321 Pyruvate·dioxygenase compounds (HPPD inhibitors, F 2 in the HRAC classification) and compounds that inhibit carotenoid biosynthesis by an unknown mode of action (pigment-inhibiting-unknown target, HRAC classification) According to a sixth embodiment of the present invention, the composition contains at least one EPSP synthase inhibitor (herbicid (IV)). The herbicidal activity of the compound is based on the linoleic acid synthase It is thus determined to be based on the inhibition of the amino-based st biosynthesis in plants. These inhibitors belong to the G class in the hrac classification system. According to the seventh embodiment of the present invention, the composition contains at least one face-loading amino acid synthesis. Enzyme inhibitors (herbicides...) The herbicidal activity of these compounds is based on inhibition of glutamyl synthase and thus on inhibition of amino acid biosynthesis in plants. The agent belongs to the genus of the HRAC classification system. According to an eighth embodiment of the invention, the composition contains at least one synthase inhibitor (herbicide b8). The herbicidal activity of the compounds is based on the 7,8-hydrogen butterfly Inhibition of acid synthase. These inhibitors belong to class I of the hraC classification system. Plate According to a ninth embodiment of the invention, the composition contains at least one mitotic inhibitor (herbicide b9). The herbicidal activity of the compounds Based on microstructural or tissue disorder or inhibition and thus mitotic inhibition. These inhibitors belong to the Κ1 & Κ2 class in the HRAC classification system. Among them, K1 compounds (especially dinitroaniline) are preferred. In a tenth embodiment, the composition contains at least an inhibitor (herbicide blO). The herbicidal activity of the compounds is based on inhibition of long-chain fatty acid synthesis by the poles and thus based on cell division in plants. Insufficiency or inhibition. These inhibitors belong to the κ3 class in the HRAC classification system. According to the tenth embodiment of the present invention, the composition contains at least one type of cellulose. Biosynthesis inhibitors (herbicide bll). The herbicidal activity of these compounds is in the inhibition of cellulose biosynthesis and is therefore based on inhibition of the biosynthesis of T. J. in plants. These inhibitors belong to hrac Class L in the classification system. According to a twelfth embodiment of the invention, the composition contains at least one de-halogen herbicide (herbicide M2). The herbicidal activity of the compounds is based on the destruction of cell membranes. According to the thirteenth embodiment of the present invention, the composition contains at least one auxin herbicide (herbicide M3). The herbicides include, for example, auxins (ie, plant hormones) act and inhibit A compound that grows in plants. These compounds belong to the steroids of the HRAC classification system. According to a fourteenth embodiment of the present invention, the composition contains at least one auxin transport inhibitor (herbicide b. The herbicidal activity of the compounds is based on inhibition of auxin transport in plants. These compounds belong to the Hrac classification Class p in the system. For a given mechanism of action and classification of active substances, see (for example) "HRAC,

Classification 〇f Herbicides According to Mode of Action」， http_//www.plantprotection.org/hrac/MOA.html。較佳者係包含至少一種選自類別b2、b3、b4、b5、b6、 b9及bl〇之除草劑之除草劑b的本發明彼等化合物。尤佳者係包含至少一種選自類別b4、b6及blO之除草劑 150107.doc •29· 201109321 之除草劑B的本發明彼等化合物。可與本發明式Ϊ之苯并喝呼酮化合物組合使用之除草劑B 的實例係： bl)來自以下脂質生物合成抑制劑之群： ACC-除草劑，例如，和草滅（all〇xydim)、和草滅鈉、丁苯草酮（butroxydim)、烯草酮（clethodim)、草酯（cl〇dinaf〇p) ' 炔草酯（clodinafop-propargyl)、環殺草（cycl〇xydim)、丁基赛伏草（cyhalofop)、氰氟草酯（cyhal〇f〇p_butyl)、二氣苯氧基丙酸（diclofop)、禾草靈（dici〇f〇p_methyl)、„号唑禾草靈 (fen〇xaprop)、乙基噚唑禾草靈（fen〇xapr〇p ethyl)、精噚唑禾草靈（haloxyfop-P)、精乙基α号唑禾草靈（fen〇xapr〇p_p_ ethyl)、吡氟禾草靈（fiuazif〇p)、丁基吡氟禾草靈 (fluazifop-butyl)、精吡氟禾草靈（fluazif〇p_P)、丁基精吡氟禾草靈（fluazifop-P-butyl)' 氟吡禾靈（hal〇Xyfop)、氟吡甲禾靈（haloxyfop-methyl)、精氟吡禾靈（hal〇Xyfop-P)、精氟吡曱禾靈（haloxyfop-P-methyl)、噚唑醯草胺（metamifop)、唑啉草酯（pinoxaden)、環苯草酮（profoxydim)、普拔草 (propaquizafop)、喹禾靈（quizalofop)、乙基喹禾靈 (quizalofop-ethyl)、喹禾糠酯（quizalofop-tefuryl)、精喹禾靈（quizalofop-P)、乙基精喹禾靈（quizalofop-P-ethyl)、精喹禾糠酯（quizalofop-P-tefuryl)、西殺草（sethoxydim)、得殺草（tepraloxydim)及三甲苯草酮（tralkoxydim);及非 ACC 除草劑，例如，°夫草黃（benfuresate)、丁草敵（butylate)、環草敵（cycloate)、茅草枯（dalapon)、派草丹（dimepiperate)、 150107.doc -30- 201109321 EPTC、戊草丹（esprocarb)、乙氧 D夫草黃（ethofumesate)、氟丙酸（flupropanate)、禾草敵（molinate)、坪草丹 (orbencarb)、克草敵（pebulate)、苄草丹（prosulfocarb)、 TCA、殺草丹（thiobencarb)、仲草丹（tiocarbazil)、野麥畏 (triallate)及滅草敵（vernolate); b2)來自以下ALS抑制劑之群：石黃酿脲類，例如，醯°密績隆（amidosulfuron)、四°坐°密續隆（azimsulfuron)、°密石黃隆酸（bensulfuron)、节 σ密項隆 (bensulfuron-methyl)、氯。密績隆（c.hlorimuron)、乙基氣。密石黃隆（chlorimuron-ethyl)、氯磺隆（chlorsulfuron)、西速隆 (cinosulfuron)、環項隆（cyclosulfamuron)、胺苯績隆 (ethametsulfuron)、胺苯石黃隆-甲基（ethametsulfuron-methyl)、亞速隆（ethoxysulfuron)、伏速隆（flazasulfuron)、氟。比績隆 (flucetosulfuron)、氟°定。密續隆（flupyrsulfuron)、敗咬。密石黃隆-甲基-鈉、曱醒胺石黃隆（foramsulfuron)、氣0比°密績隆 (halosulfuron)、曱基氯。比嘴石黃隆（halosulfuron-methyl)、依速隆（imazosulfuron)、峨石黃隆（iodosulfuron)、峨石黃隆-曱基-鈉、甲基二石黃隆（mesosulfuron)、雙醚氯°比〇密績隆 (metazosulfuron)、曱石黃隆（metsulfuron)、曱基甲石黃隆 (metsulfuron-methyl)、於 α密續隆（nicosulfuron)、°密苯胺石黃隆（orthosulfamuron)、環氧 α密磺隆（oxasulfuron)、氟 °密石黃隆 (primisulfuron)、曱基氣°密石夤隆（primisulfuron-methyl)、丙瑞績隆（propyrisulfuron)、三氟丙石黃隆（prosulfuron)、百速隆（pyrazosulfuron)、乙基百速隆（pyrazosulfuron-ethyl)、 150107.doc -31 - 201109321 玉喊續隆（rimsulfuron)、嘴續隆（sulfometuron)、甲基嘴績隆（sulfometuron-methyl)、確醯續隆（sulfosulfuron)、。塞石黃隆（thifensulfuron)、噻石黃隆-甲基（thifensulfuron-methyl)、醚苯石黃隆（triasulfuron)、苯續隆（tribenuron)、甲基苯項隆 (tribenuron-methyl)、三氟啶石黃隆（trifloxysulfuron)、氟胺確隆（triHusulfuron)、曱基氟胺磺隆（triHusulfuron-methyl) 及三氟甲續隆（tritosulfuron);咪嗤。林酮類，例如，咪草酸 (imazamethabenz)、曱基咪草酸（imazamethabenz-methyl)、甲氧咪草菸（imazamox)、甲基咪草於（imazapic)、依滅草 (imazapyr)、咪唑喹啉酸（imazaquin)及咪唑乙菸酸 (imazethapyr);三唑并嘧啶除草劑及磺醯苯胺類，例如氣酯磺草胺（cloransulam)、甲基氣酯磺草胺（ci〇ransuiam_ methyl)、雙氣績草胺（diclosulam)、《坐鳴項草胺 (flumetsulam)、雙氟續草胺（florasulam)、磺草唑胺 (metosulam)、五敗績草胺（penoxsulam)、〇密咬硫燒 (pyrimisulfan)及曱氧確草胺（pyroxsulam)，嘴咬基苯曱酸類’例如，雙草謎（bispyribac)、雙草喊鈉、嘴咬肪草喊 (pyribenzoxim)、環酯草醚（pyriftalid)、嘧草醚 (pyriminobac)、曱基喷草鍵（pyriminobac-methyl)、。密草硫醚（？丫1*^1^(^&(〇、嘧草硫醚鈉、4-[[[2-[(4,6-二曱氧基-2_。密啶基）氧基]苯基]甲基]胺基]-苯甲酸-1-甲基乙基酯（CAS 420138-41-6)、4-[[[2-[(4,6-二曱氧基-2-癌啶基）氧基]苯基] 曱基]胺基]-苯曱酸丙基酯（CAS 420138-40-5)、Ν-(4-漠苯基）-2·[(4,6-二曱氧基-2·嘧啶基）氧基]苯甲胺（CAS 420138- 150107.doc -32· 201109321 01 - 8)及確醯基胺基幾基-三唾琳酮除草劑，例如，酮續隆（flucarbazone)、氟酮石黃隆納、丙苯續隆（propoxycarbazon)、丙苯續隆鈉、嗟浠卡巴膝（1；11丨611031^&20116)及曱基°塞烯卡巴月宗（thiencarbazone-methyl)。其中，本發明之一較佳實施例係關於彼等包含至少一種β米°坐琳酮除草劑之組合物； b3)來自以下光合作用抑制劑之群：胺。坐草酮（amicarbazone)、光系統II之抑制劑，例如，三畊除草劑，包括氣三畊、三畊酮、三畊啶酮、甲基硫代三p井及°荅p井酮，例如，殺草淨（ametryn)、阿特拉15井 (atrazine)、殺草敏（chloridazone)、氰乃淨（cyanazine)、地蔓盡（desmetryn)、異戊乙淨（dimethametryn)、環 p井酮 (hexazinone)、p井草 _ (metribuzin)、撲滅通（prometon)、撲草淨（prometryn)、撲滅津（propazin)、草滅淨（simazin)、西草淨（simetryn)、曱氧去草淨（terbumeton)、草淨津 (terbuthylazin)、去草淨（terbutryn)及草達津（trietazin)、芳基脲，例如，氣溴隆（chlorobromuron)、綠麥隆（chlorotoluron)、枯草隆（chloroxuron)、>»号嗤隆（dimefuron)、敵草隆 (diuron)、伏草隆（fluometuron)、異丙隆（isoproturon)、異 p号隆（isouron)、利穀隆（linuron)、苯畊草酮（metamitron)、甲基苯。塞隆（methabenzthiazuron)、0比喃隆（metobenzuron) ' 曱氧隆（metoxuron)、綠縠隆（monolinuron)、草不隆 (neburon)、環草隆（siduron)、特丁噻草隆（tebuthiuron)及 »塞苯隆（thiadiazuron)、胺基曱酸笨基酯，例如，甜菜安 (desmedipham)、卡靈草（karbutilat)、甜菜寧（phenmedipham)、 150107.doc •33· 201109321 甜菜寧-乙基（phenmedipham-ethyl)、腈除草劑，例如，殺草全（bromofenoxim)、溴苯腈（bromoxynii)及其鹽及醋、職苯腈（ioxynil)及其鹽及酯、尿嘧啶，例如除草定 (brornacil)、ί衣草疋（lenacil)及特草定（terbacil)、及苯達松 (bentazon)及苯達松-鈉、噠草特（pyridatre)、噠畊醇 (pyridafol)、疏草滅（pentanochlor)及除草寧（pr〇panii)及光系統I抑制劑’例如，敵草快（diquat)、敵草快二濱化物 (diquat-dibromide) ' 對草快（paraqUat)、對草快二鹽酸鹽 (paraquat-dichloride)及對草快二甲硫酸鹽（paraquat_ dimetilsulfate)。其中，本發明之一較佳實施例係關於彼等包含至少一種^•基腺除草劑之組合物。其中，同樣，本發明之一較佳實施例係關於彼等包含至少一種三p井除草劑之組合物。其中，同樣，本發明之一較佳實施例係關於彼等包含至少一種腈除草劑之組合物； b4)來自以下原外琳原-IX氧化酶抑制劑之群：亞喜芬（acifluorfen)、亞喜芬_鈉、草芬定（azafenidin)、苯卡巴腙（bencarbazone)、雙苯嘧草酮（benzfendiz〇ne)、必芬諾（bifenox)、氟丙嘧草酯（butafenacU)、唑草酮 (carfentrazone)、唑草酮.乙基（carfentraz〇ne ethyl)、曱氧除草醚（chlomethoxyfen)、酮草酯（cinid〇n ethyl)、異丙草酯（fluazo丨ate)、氟噠啩酯（flufenpyr)、氟噠啡草酯 (flufenpyr-ethyl)、氟烯草酸（flumicl〇rac)、氟烯草酸戊基 (flumiclorac-pentyl)、丙炔氟草胺（flumi〇xazin)、乙羧氟草醚（fluoroglycofen)、乙基乙羧氟草醚（flu〇r〇glyc〇fen_ 150107.doc -34· 201109321 ethyl)、畊草酸酯（fluthiacet)、口井草酸甲酯（fluthiacet-methyl)、氟石黃胺草喊（fomesafen)、鹵草 it(halosafen)、乳氟禾草靈（lactofen)、丙炔号草酮（oxadiargyl)、p号草鲷 (oxadiazon)、複祿芬（oxyfluorfen)、環戊号草酮（pentoxazone)、氣 α坐草胺（profluazol)、雙 ^坐草（pyraclonil)、°比醚 (pyraflufen)、吡草醚（pyraflufen-ethyl)、嘧咬肟草醚 (saflufenacil)、甲石黃草胺（sulfentrazone)、°塞二唑草胺 (thidiazimin)、[3-[2-氣-4-氟-5-(1-曱基-6-三氟曱基-2,4-二側氧基-1，2,3,4-四氫嘧啶-3-基）苯氧基]-2-吼啶基氧基]乙酸乙酯（CAS 3 53292-31-6; S-3 100)、N-乙基-3-(2,6-二氯-4-三氟甲基苯氧基）-5-曱基-1H-吡唑-1-曱醯胺（CAS 452098-92-9)、N-四氫呋喃基-3-(2,6-二氣-4-三氟甲基苯氧基）-5-甲基-1H-吡唑-1·曱醯胺（C AS 915 396-43-9)、N-乙基-3-(2-氣_ 6-氟-4-三氟甲基苯氧基）·5 -曱基-1Η-η比〇坐-1-曱酿胺（CAS 452099-05-7)及N-四氫呋喃基-3-(2-氣-6-氟-4-三氟甲基苯氧基）-5-曱基-1Η-° 比。坐-1-曱醯胺（CAS 45100-03-7); b5)來自以下色素抑制型除草劑之群： PDS抑制劑：氟丁草胺（beflubutamid)、氟草胺 (diflufenican)、氟啶草酮（fluridone)、氟咯草酮（flurochloridone)、呋草酮（flurtamone)、達草滅（norflurazon)、氟吡醯草胺 (picolinafen)、及4-(3-三氟甲基苯氧基）-2-(4-三氟曱基苯基）嘧啶（CAS 180608-3 3-7) ; HPPD抑制劑：苯并雙環綱、 0比草酉同（benzofenap)、異p号〇坐草酮（isoxaflutole)、曱基確草酮（mesotrione)、達磺特（pyrasulfotole)、苄草唑（Pyraz〇iynate)、 150107.doc •35· 201109321 匹唑芬（pyrazoxyfen)、磺草酮（sulc〇trione)、糠酮 (tefuryltrione)、特博 _ (tembotrione)、特帕米腙 (topramezone)及雙環吡酮（bicyclopyrone)、色素抑制型未知目標：苯草鍵（aclonifen)、殺草強（amitrole)、可滅蹤 (clomazone)及伏草隆； b6)來自以下EPSP合酶抑制劑之群：草甘膦（glyphosate)、草甘膦-異丙基銨（giyph〇sate_ isopropylammonium)及草甘膦-三曱基硫鹽（glyph〇sate_ trimesium)(草硫膦（sulfosate)); b7)來自以下麵醯胺酸合成酶抑制劑之群：雙丙胺醯膦（bilanaphos或bialaphos)、雙丙胺醯膦鈉、草丁膦（glufosinate)、草丁膦 _p(giufosinate_p)及草銨膦 (glufosinate-ammonium)； b8)來自DHP合酶抑制劑之群：石黃草靈（asulam); b9)來自以下有絲分裂抑制劑之群： K1類化合物.二硝基苯胺類，例如，倍尼芬 (benfluralin)、比達寧（butralin)、撻乃安（dinitramine)、丁氟消草（ethalfluralin)、氣乙氟靈（fluchl〇ralin)、歐拉靈 (oryzalin)、施德圃（pendimethalin)、胺氟樂靈（prodiamine) 及三福林（trifluralin)，胺基磷酸酯類，例如，胺草磷 (amiprophos)、曱基胺草磷（amipr〇ph〇s-methyl)及抑草磷 (butamiphos)，苯甲酸除草劑，例如，大克草（chl〇rthal)、大克草-二甲基（chlorthal- dimethyl)，吡啶類，例如，汰硫 150107.doc -36- 201109321 草（dithiopyr)及噻草咬（thiazopyr)，苯甲醯胺類，例如，块苯草胺（propyzamide)及牧草胺（tebutam); K2類化合物：氣苯胺靈（chlorpropham)、苯胺靈（pr〇pha.m)及雙草胺 (carbetamide)，其中’ K1類化合物、尤其二硝基笨胺類較佳； blO)來自以下VLCFA抑制劑之群：氣乙醢胺類，例如’乙草胺（acetochlor)、拉草（alachlor)、丁基拉草（butachlor)、二曱草胺（dimethachlor)、二甲吩草胺（dimethenamid)、精二甲吩草胺（dimethenamid-P)、滅草胺（metazachlor)、莫多草（metolachlor)、莫多草-S、烯草胺（pethoxamid)、普拉草（pretilachlor)、毒草胺（propachlor)、異丙草胺（propisochlor)及曱氧草胺（thenylchlor);氧基乙醯苯胺類，例如’氟草胺（flufenacet)及滅芬草（mefenacet); 乙酿苯胺類，例如’大芬滅（diphenamide)、滅落脫 (napropamide)及萘丙胺（naproanilide);四唾琳酮類，例如，四唑酮（fentrazamide);及其他除草劑，例如，莎稗磷 (amlofos)、唑草胺（cafenstr〇ie)、芬諾克殺草砜（fen〇xasulf〇ne)、艾芬卡巴膝（ipfencarbazone)、草填（piperophos)及不同於派羅克殺草颯之式II之異嘮唑啉類化合物，Classification 〇f Herbicides According to Mode of Action", http_//www.plantprotection.org/hrac/MOA.html. Preferred are the compounds of the invention comprising at least one herbicide b selected from the group consisting of the classes b2, b3, b4, b5, b6, b9 and bl〇. Particularly preferred are those compounds of the invention comprising at least one herbicide B selected from the group consisting of the classes b4, b6 and blO 150107.doc • 29. 201109321. An example of a herbicide B that can be used in combination with a benzoxanthone compound of the formula: bl) is from the group of lipid biosynthesis inhibitors: ACC-herbicide, for example, and grass (all〇xydim) And sodium chlorfenapyr, butroxydim, clethodim, cl〇dinaf〇p' clodinafop-propargyl, cycl〇xydim, diced Cyhalofop, cyhal〇f〇p_butyl, diclofop, dici〇f〇p_methyl, ž oxacillin (fen 〇xaprop), ethyl oxazole (fen〇xapr〇p ethyl), haloxyfop-P, fine ethyl alpha oxacillin (fen〇xapr〇p_p_ ethyl), Fipazif〇p, fluazifop-butyl, fluazif〇p_P, fluazifop-P-butyl ) 'hal〇Xyfop, haloxyfop-methyl, hal〇Xyfop-P, haloxyfop-P-methyl, Oxazin Metamifop), pinoxaden, profoxydim, propaquizafop, quizalofop, quizalofop-ethyl, quizolofop -tefuryl), quizalofop-P, quizalofop-P-ethyl, quizalofop-P-tefuryl, sethoxydim, kill Grass (tepraloxydim) and tralkoxydim; and non-ACC herbicides, for example, benfuresate, butabutate, cycloate, dalapon, pie Dimepiperate, 150107.doc -30- 201109321 EPTC, esprocarb, ethofumesate, flupropanate, molase, pingcao Orbencarb), pebulate, prosulfocarb, TCA, thiobencarb, tiocarbazil, triallate and vernolate; b2) The following group of ALS inhibitors: sulphate urea, for example, amidosulfuron, four Continued long sit tight ° (azimsulfuron), ° dense Danhuang Long acid (bensulfuron), long term adhesion section σ (bensulfuron-methyl), chloro. C.hlorimuron, ethyl gas. Chlorimuron-ethyl, chlorsulfuron, cinosulfuron, cyclosulfamuron, ethametsulfuron, ethametsulfuron- Methyl), ethoxysulfuron, flazasulfuron, fluorine. Compared with flucetosulfuron and fluorine. Flupyrsulfuron, bite. Miststone Huanglong-methyl-sodium, foramsulfuron, gas 0 to ° halosulfuron, sulfhydryl chloride. Halosulfuron-methyl, imazosulfuron, iodosulfuron, vermiculite-mercapto-sodium, methosulfuron, diether chloride Metazosulfuron, metsulfuron, metsulfuron-methyl, nicosulfuron, orthosulfamuron, epoxy Oxa oxasulfuron, primisulfuron, primisulfuron-methyl, propyrisulfuron, prosulfuron, gamma Pyrazosulfuron, pyrazoosulfuron-ethyl, 150107.doc -31 - 201109321 jade rumsulfuron, sulfometuron, sulfometuron-methyl, indeed Sulf 隆隆 (sulfosulfuron),. Thifensulfuron, thifensulfuron-methyl, triasulfuron, tribenuron, tribenuron-methyl, trifluoro Trifloxysulfuron, triHusulfuron, triHusulfuron-methyl and tritosulfuron; Lin Ketones, for example, imazamethabenz, imazamethabenz-methyl, imazamox, imazapic, imazapyr, imidazoquinoline Acid (imazaquin) and imidazolium (imazethapyr); triazolopyrimidine herbicides and sulfonium anilines, such as cloransulam, methyl sulfonamide (ci〇ransuiam_ methyl), double-grass Amine (diclosulam), "flumetsulam", florasulam, metosulam, penoxsulam, pyrimisulfan and sputum Pyroxsulam, mouth bite-based benzoic acid', for example, bispyribac, double-grass sodium, pyribenzoxim, pyrifalid, pyrimethanil Pyriminobac), pyriminobac-methyl, pyridinium. Mitosulfuric acid (?丫1*^1^(^&(〇, sodium pyrithione, 4-[[[2-[(4,6-dimethoxy-2-).)) Benzyl]methyl]amino]-benzoic acid-1-methylethyl ester (CAS 420138-41-6), 4-[[[2-[(4,6-didecyloxy-2) -Cymphidino)oxy]phenyl]indolyl]amino]-benzoic acid propyl ester (CAS 420138-40-5), Ν-(4- desert phenyl)-2·[(4,6 -Dimethoxy-2-(pyrimidinyl)oxy]benzylamine (CAS 420138-150107.doc -32·201109321 01 - 8) and alkoxyl-yl-saphedrine herbicide, for example, Flucarbazone, fluoroketone huanglongna, propoxycarbazon, propofol sodium, 嗟浠卡巴 (1;11丨611031^&20116) and 曱基°塞卡巴Thiencarbazone-methyl. Among them, a preferred embodiment of the present invention relates to a composition comprising at least one beta-salmone herbicide; b3) a group from the following photosynthesis inhibitors: an amine. Amicarbazone, inhibitor of photosystem II, for example, three tillage herbicides, including gas three tillage, three tillage, tricotyl ketone, methyl thiotrim well and °荅p Well ketones, for example, ametryn, atrazine, chloridazone, cyanazine, desmetryn, dimethametryn, Hexainone, p. rib _ (metribuzin), prometon, prometryn, propazin, simazin, simetryn, helium oxygen Terbumeton, terbuthylazin, terbutryn and trietazin, aryl urea, for example, chlorobromuron, chlorotoluron, haystow (chloroxuron), >, dimefuron, diuron, fluometuron, isoproturon, isouron, linuron, Metamtron, methotrex, metabenzthiazuron, metobenzuron 'metoxuron, monolinuron, neburon, cyclopsone (siduron), tebuthiuron and »thiadiazuron, amine Acidic acid esters, for example, desmedipham, karbutilat, phenmedipham, 150107.doc • 33· 201109321 benzen-ethyl, cyano herbicide, for example, Bromofenoxim, bromoxynii and its salts and vinegar, ioxynil and its salts and esters, uracil, such as bristacil, lenacil and special Terbacil, and bentazon and bentazon-sodium, pyridatre, pyrifafol, pentanochlor, and pr〇panii and light System I inhibitors 'eg, diquat, diquat-dibromide' paraqUat, paraquat-dichloride, and grass fast Methyl sulfate (paraquat_ dimetilsulfate). Among them, a preferred embodiment of the present invention relates to a composition comprising at least one of the herbicides. Among other things, a preferred embodiment of the invention relates to compositions comprising at least one triple-p herbicide. Wherein, likewise, a preferred embodiment of the invention relates to a composition comprising at least one nitrile herbicide; b4) from the group of the following proto-lin-IX oxidase inhibitors: acifluorfen, Yaxifen_sodium, azafenidin, bencarbazone, benzefendiz〇ne, bifenox, butafenacU, oxadiazon (carfentrazone), oxazolone, ethyl (carfentraz〇ne ethyl), chlomethoxyfen, cinid〇n ethyl, fluazo丨ate, fluorodecyl ester ( Flufenpyr), flufenpyr-ethyl, flumicl rac, flumiclorac-pentyl, flumi〇xazin, flufenacetate (fluoroglycofen), ethyl acesulfame (flu〇r〇glyc〇fen_ 150107.doc -34· 201109321 ethyl), fluthiaacetate, fluthiacet-methyl, fluorspar Fomesafen, halosafen, lactofen, propargyl (oxadiargyl), oxadiazon, oxyfluorfen, pentoxazone, profluazol, pyraclonil, pyraflufen ), pyraflufen-ethyl, saflufenacil, sulfentrazone, thidiazimin, [3-[2-gas-4-fluoro 5-(1-mercapto-6-trifluoromethyl-2,4-di-oxy-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-acridine Ethyloxy]acetate (CAS 3 53292-31-6; S-3 100), N-ethyl-3-(2,6-dichloro-4-trifluoromethylphenoxy)-5- Mercapto-1H-pyrazole-1-decylamine (CAS 452098-92-9), N-tetrahydrofuranyl-3-(2,6-dioxa-4-trifluoromethylphenoxy)-5- Methyl-1H-pyrazole-1·decylamine (C AS 915 396-43-9), N-ethyl-3-(2-gas-6-fluoro-4-trifluoromethylphenoxy) ·5-mercapto-1Η-η ratio 〇曱曱曱曱 (CAS 452099-05-7) and N-tetrahydrofuranyl-3-(2- gas-6-fluoro-4-trifluoromethylbenzene Oxy)-5-mercapto-1Η-° ratio.曱醯-1-decylamine (CAS 45100-03-7); b5) from the following pigment-inhibiting herbicides: PDS inhibitors: beflubutamid, diflufenican, fluridazine Fluridone, flurochloridone, flurtamone, norflurazon, picolinafen, and 4-(3-trifluoromethylphenoxy) -2-(4-Trifluorodecylphenyl)pyrimidine (CAS 180608-3 3-7) ; HPPD inhibitor: benzobicyclic, 0 benzofenap, iso-p-oxazin ( Isoxaflutole), mesotrione, pyrasulfotole, pyraz〇iynate, 150107.doc •35· 201109321 pyrazoxyfen, sulc〇trione , tefuryltrione, tembotrione, topramezone and bicyclopyrone, pigment-inhibiting unknown target: aclofen, amitre, amitre Clomazone and oxalate; b6) from the following EPSP synthase inhibitors: glyphosate, glyphosate-isopropylammonium (gi) Yph〇sate_ isopropylammonium) and glyphosate-trisyl-sulphate (sulfosate); b7) from the following group of proline synthase inhibitors: dipropylamine phosphine ( Bilanaphos or bialaphos), sodium bisphosphonate, glufosinate, glufosinate_p and glufosinate-ammonium; b8) from DHP synthase inhibitors: shihuangcaoling ( Asulam); b9) from the following mitotic inhibitors: K1 compounds. Dinitroanilines, for example, benfluralin, butralin, dinitramine, butyl fluoride (ethalfluralin), fluchl〇ralin, oryzalin, pendimethalin, prodiamine, and trifluralin, amino phosphates, for example, amines Ampichos, amipr〇ph〇s-methyl and butamiphos, benzoic acid herbicides, for example, chl〇rthal, gram grass-dimethyl Chlorthal- dimethyl, pyridine, for example, sulfur sulphide 150107.doc -36-2 01109321 Dithiopyr and thiazopyr, benzoguanamines, for example, propyzamide and tebutam; K2 compounds: chlorpropham, aniline (pr 〇pha.m) and carbamide, wherein 'K1 compounds, especially dinitro amides; blO) are from the following groups of VLCFA inhibitors: gas acetylamines such as 'acetochlor (acetochlor), alachlor, butachlor, dimethachlor, dimethenamid, dimethenamid-P, chlorfenapyr (metazachlor), metolachlor, mometas-s, pethoxamid, pretilachlor, propachlor, propisochlor, and oxacillin ( Thenylchlor); oxyacetanilides, such as 'flufenacet and mefenacet; aniline, such as 'diphenamide, napropamide, and naphthylamine ( Naproanilide); tetrahydrolinone, for example, fentrazamide; Other herbicides, for example, amlofos, cafenstr〇, fen〇xasulf〇ne, ipfencarbazone, piperophos and An isoxazoline compound of the formula II different from the genus

其中Ru、R12、R丨3、R14、W、z及η具有以下含義： R11、R12、R13 ' R14彼此獨立地係氫、鹵素或Ci_C4_烷 150107.doc •37· 201109321 基； W係苯基或單環5-、6·、7_ 甘^ 8_、9-或10員雜環美八除碳環成員外亦含有1個、2個或3個相同二，之選自氧、氮及硫之雜原子作為環成員，发= 基及雜環基未經取代或帶有1、2或3個選自南素Wherein Ru, R12, R丨3, R14, W, z and η have the following meanings: R11, R12, R13' R14 are independently hydrogen, halogen or Ci_C4_alkane 150107.doc •37·201109321 base; W series benzene The base or monocyclic 5-, 6-, 7-g-[8], 9- or 10-membered heterocyclic ring contains one, two or three identical two, which are selected from the group consisting of oxygen, nitrogen and sulfur. a hetero atom as a ring member, a hair base and a heterocyclic group unsubstituted or having 1, 2 or 3 selected from the group

Cl-c4-烧基、q-cv院氧基、C,_C4•齒代貌基及k C4·齒代烧氧基之取代基Ryy，· 較佳係苯基或5_或6-員芳族雜環基（雜芳基卜其除碳環成員外亦含有Η固、2個或3個氮原子作為環成員，其二笨基及雜芳基未經取代或帶有〗、2或3個取代基Ryy，· Z 係氧或NH ;且 η 為0或1 ; 在式11之異十坐琳化合物中，較佳者係式Π之異十坐啉化合物，其中： R R R 、R彼此獨立地係Η、F、Cl或曱基； Z 係氧； n 為0或1 ;且 W係本基'°比0坐基、或12,3-三唑基，其中最後提及之3個基團未經取代或帶有1、2或3個取代基Ryy、尤其以下基團中之—者： 15Cl-c4-alkyl, q-cv, oxime, C, _C4, dentate, and k C4, substituent of the alkoxy group, Ryy, preferably phenyl or 5 or 6-member a heterocyclic group (heteroaryl group which also contains oxime, 2 or 3 nitrogen atoms as a ring member in addition to a carbon ring member, and its di- and heteroaryl groups are unsubstituted or have a gram, 2 or 3 a substituent Ryy, · Z is oxygen or NH; and η is 0 or 1; among the iso-isolated compounds of the formula 11, the preferred isospin compound, wherein: RRR, R are independent of each other Earth's Η, F, Cl or sulfhydryl; Z is oxygen; n is 0 or 1; and W is the base '° ratio of 0, or 12,3-triazolyl, of which the last 3 bases The group is unsubstituted or carries 1, 2 or 3 substituents Ryy, especially among the following groups: 15

RR

N N-R16 R VN ^、vVr16 # R， 150107.doc -38- 201109321 其中： R 係鹵素、C1-C4-烧基或Ci-Cf鹵代烧基； R16 係(^-(：4-烷基； R17係鹵素、CVCV烷氧基或^弋^鹵代烷氧基； R18係鹵素、（VCV烷基、Ci-CV鹵代烷基或CVC4-鹵代烷氧基； m 為〇、1、2或3 ;且 # 表示連接至基團CR13R14之點；在式II之異咩唑啉化合物中，尤佳者係彼等式π之異哼 °坐琳化合物，其中： R11係氫； R12係氟； R13係氫或氟； R14係氫或氟； W係式W1、W2、W3或W4基團中之—者：N N-R16 R VN ^, vVr16 # R, 150107.doc -38- 201109321 where: R is halogen, C1-C4-alkyl or Ci-Cf halogenated alkyl; R16 is (^-(: 4-alkane) R17 is a halogen, CVCV alkoxy or haloalkoxy; R18 is halogen, (VCV alkyl, Ci-CV haloalkyl or CVC4-haloalkoxy; m is deuterium, 1, 2 or 3; # indicates the point of attachment to the group CR13R14; among the isoxazoline compounds of the formula II, particularly preferred are those of the formula π, which are: R11 hydrogen; R12 fluorine; R13 hydrogen Or fluorine; R14 is hydrogen or fluorine; W system is one of the W1, W2, W3 or W4 groups:

其中#表示連接至基團CR13r〗4之點； Z 係氧； η 為0或1、尤其1 ;且其中，尤佳者係式IL1、„ 2、π 3、π 4、π 5、η 6、 ΙΙ.7、ΙΙ_8及ΙΙ.9之異β号嗤琳化合物： 150107.doc •39- 201109321Where# represents the point of attachment to the group CR13r]; Z is oxygen; η is 0 or 1, especially 1; and among them, especially preferred are IL1, „2, π3, π4, π5, η6 , ΙΙ.7, ΙΙ_8 and ΙΙ.9 different β 嗤 Lin compound: 150107.doc •39- 201109321

11.111.1

ΙΙ.2ΙΙ.2

ΗΧ H3C H-C H3CΗΧ H3C H-C H3C

II.4II.4

II.6 II.5II.6 II.5

h3c h3cH3c h3c

H3C h3c II.7H3C h3c II.7

II.9 自（例如）WO 2006/024820、WO 2006/037945、WO 2007/071900 及WO 2007/096576在業内已知式之異哼唑啉化合物；在VLCFA抑制劑中，較佳者係氣乙醯胺及氧基乙醯胺； bl 1)來自以下纖維素生物合成抑制劑之群：草克樂（chlorthiamid)、敵草腈（dichi〇benil)、氟胺草唑 (flupoxam)、異1草胺（is〇xaben)&卜環己基-5五氟笨氧基_14-[1，2,4,6]噻三畊_3_基胺； b 1 2)來自以下去偶合劑除草劑之群：達諾叙（dinoseb)、地樂消盼（dinGtert^DN〇c及其鹽； bl3)來自以下生長素除草劑之群： 2,4-D及其鹽及酯、2 4 ’ B及其鹽及醋、氯胺。比n定酸 150107.doc 201109321 (aminopyralid)及其鹽（例如氯胺Dtb D定酸-卷（2-經丙基）錄及其酯）、草除靈（benazolin)、乙基草除靈（benazolin-ethyl)、草滅平（chloramben)及其鹽及酯、氯甲酿草胺 (clomeprop)、二氯°比咬酸（clopyralid)及其鹽及醋、麥草畏 (〇1泌311^3)及其鹽及酯、2,4-滴丙酸（£1丨(；111〇印1*0卩）及其鹽及醋、精2,4-滴丙酸（dichlorprop-P)及其鹽及醋、I草於 (fluroxypyr)、氟草菸·丁氡基曱基乙基（fiuroxypyr_ butometyl)、氣氣比（fluroxypyr-meptyl)、MCPA及其鹽及酯、MCPA-硫乙基、MCPB及其鹽及酯、2甲4氯丙酸 (mecoprop)及其鹽及酯、精2甲4氣丙酸（mecoprop-P)及其鹽及酯、毒莠定（picloram)及其鹽及酯、二氣喧琳酸 (quinclorac)、氣曱啥琳酸（qUinmerac)、tbA (2,3,6)及其鹽及醋、三氣比（triclopyr)及其鹽及酯、及環丙嘧啶酸 (aminocyclopyrachlor)及其鹽及酯； b 14)來自以下生長素轉運抑制劑之群：二氟吡隆 (diflufenzopyr)、二氟吡隆_鈉、抑草生（naptalam)及抑草生-納； b 1 5)來自以下其他除草劑之群：溴丁草胺、整形醇、整形醇-甲基、環庚草醚、苄草隆、茅草枯、棉隆、燕麥枯、热麥枯-甲硫酸鹽、噻節因、DSMA、殺草隆、橋氧酞鈉及其鹽、乙氧苯草胺、麥草氟、麥草氟_異丙基、麥草氟-甲基、麥草氟-M_異丙基、麥草氟_M_甲基、芴丁酯、芴丁酯-丁基、呋嘧醇、殺木膦、殺木膦_銨、草酮、茚茲弗蘭、馬來醯肼、氟草磺、美坦、疊氮基曱烷、溴甲烷、 150107.doc 201109321 甲基-殺草隆、峨甲貌、MSMA、油酸、去稗安、壬酸、稗卓丹 ' 滅_、三氟草胺、滅草環及6_氣·3·(2·環丙基甲基苯氧基）·4制醇（CAS 499223專3)及其鹽及酿。 H本發明式！之笨并十井_化合物組合使用之較佳除草劑B係： bl)來自以下脂質生物合成抑制劑之群·· „稀_、快草醋'環殺草、氰氟草醋、禾草靈、精乙基 ^坐禾草靈、丁基精。比氣禾草靈、精氟吼甲禾靈、十坐醜草胺、㈣草酿、環苯草酮、普拔草、乙基精啥禾靈、精啥禾糠醋、西殺草、得殺草、三甲苯草，、吱草黃丹、EPTC、戊草丹、乙氧咳草黃、禾草敵、坪草丹草丹、殺草丹及野麥畏； b2)來自以下ALS抑制劑之群：一酿°密項隆 '四°坐対隆、㈣續隆、雙草I納、乙基氣嘴石黃隆、氣石黃隆、甲某备基虱自日^草胺、環磺隆、雙氯磺草胺、胺苯續隆-甲某、25、击卩交 . 丞s迷隆'伏速隆、雙氟續草胺、氟酮石黃隆鈉、氣㈣隆、心„草胺士定。㈣隆-甲基鈉、甲酿胺績隆、甲基氣。比。密續隆、甲基咪草酸、甲氧t米草於、甲基料於、依滅草 '咪㈣㈣、㈣乙㈣、依速隆、料隆、㈣隆·甲基·鈉、甲基二替、雙喊氯 °比鳴石黃隆、石黃草。坐胺、甲基甲續隆、終嘯續隆、癌笨胺績隆、環氧條、…草胺、？基_隆、丙苯續隆-鈉、丙瑞續隆、三敦丙績隆、乙基百速隆、㈣月亏草謎…密°定硫烧、環酯草㈣、甲基鱗㈣、”躺-鈉、 150107.doc -42· 201109321 甲氧磺草胺、玉嘧磺隆、甲基丞嘴石兴隆、磺醯磺隆、曱基噻烯卡巴腙、噻磺隆-甲基、μ笑气本硕隆、甲基苯磺隆、三氟 11定磺隆、氟胺磺隆及三氟甲石黃隆； b3)來自以下光合作用抑制劑之群：殺草淨、胺唑草酮、阿拉牲岵 —土干』租特_、苯達松、苯達松-鈉、溴苯腈及其鹽及酯、殺草敏、峥i ^ 、，求麥隆、氰乃淨、甜菜安、敵草快二溴化物、敵草隆、伏笪坑早隆、壤畊酮、碘苯腈及其鹽及酯、異丙隆、環草定、利榖奸 ’、刃秋隆、苯畊草酮、甲基苯噻隆“井草酮、對草快、料快二鹽㈣、甜菜甯、除草寧·、.健草特、草滅淨、去草淨、草淨津及嘆笨隆 (thidiazuron)； b4)來自以下原卟啉原_IX氧化酶抑制劑之群：亞喜芬·鈉、笨卡巴腙、雙苯嘧草酮、氟丙嘧草酯、唑酮草酯、酮草酯、氟噠畊草冑、氟烯草酸-戊基、丙炔氟草胺、乙基乙羧氟草醚、畊草酸甲酯、乳氟禾草靈、丙炔 S草酮、樂滅草、複祿芬、環戊噚草酮、吡草醚、嘧啶肟草醚、曱磺草胺、[3-[2-氯-4-氟-5-(1_曱基_6_三氟曱基_ 2,4-二側氧基-1，2,3,4-四氫嘧啶-3-基）苯氧基]_2_吡啶基氧基]乙酸乙酯（CAS 353292-3 1-6 ; S-31〇0)、N_ 乙基_3_(2,6_ 一氯-4-二乱甲基苯氧基）-5-甲基-1H-。比。坐_ 1 _曱醯胺（cAs 452〇98-92-9)、Ν-四氫呋喃基-3-(2,6-二氣_4_三氟曱基苯氧基）-5-曱基-1Η-吡唑-1-甲醯胺（CAS 915396-43-9)、Ν-乙基-3-(2-氣-6-氟-4-三氟曱基苯氧基）-5·甲基_出_。比。坐小甲醯胺（CAS 452099-05-7)及N-四氫呋喃基_3-(2_氣_6_敗_4_三 150107.doc • 43· 201109321 氟甲基苯氧基）-5-甲基 7)；比坐-I·甲醯胺(CAS觀魯 b5)來自以下色素抑制型除草劑之群：笨草醚、氟丁草胺、笨并 0. ^ sn ^ 雙衣锕、可滅蹤、氟草胺、氟各草酮、呋卓酮、異咩唑草 π., ^ 土甲基嶒卓酮、達草滅、氟吼醯草胺、達磺特、苄草 %卓酮、糠酮、特博酮、特帕未脎、雙環吡酮、4_(3·=患氟甲基本氧基）-2-(4-三氟甲基本基）°㈣（CAS18_8-33·7)、殺草強及伏草隆； b6)來自以下EPSP合酶抑制劑之群·· 曱基硫鹽（草硫草甘膦、草甘膦-異丙基鑄及草甘膦· .膦）； b7)來自以下麩醯胺酸合酶抑制劑之群：草丁膦、草丁膦-P、草銨膦； b8)來自DHP合酶抑制劑之群：續草靈. b9)來自以下有絲分裂抑制劑之群：施德圃、嗟草咬倍尼芬、汰硫草、丁 I消草、歐拉靈、及三福林； bl〇)來自以下VLCFA抑制劑之群：哇草胺、二罗吩草滅芬草、滅草胺、普拉草、芬諾克殺乙草胺、拉草、莎稗磷、丁基拉草胺精一甲吩草胺、四唑酮、氟草胺 :多草、S·莫多草、蔡丙胺、滅落脫…、殺草石風、艾芬卡巴腙'甲氧草胺及式m Π 气、ττ /Γ 、ΙΙ·4、述1…11·8及Π.9之異十坐琳化合物，如上所 150107.doc • 44 · 201109321 bll)來自以下纖維素生物人胺草坤… 成抑制劑之群：敵草腈、氟胺草唑、異。亏卓胺及^環喧…-基胺； Μ本氧基 bl3)來自以下生長素除草劑之群：及其鹽及自旨 '氯胺_酸及其鹽（例如氣胺吼唆酸_ 畚（2 -經丙基）錄及盆酷、、_备 … 虱。比啶酸及其鹽及醋 '麥草畏及一風及酯、精2,4·滴丙酸及其_ 及其鹽及醋、_…及氟氣比、MCPA ffib主某― 及/、皿及酉曰、精2甲4氯丙酸及其鹽及曰、广及其鹽及醋、二氣啥琳酸、氯甲㈣、三氣及其鹽及醋、及環丙嘧啶酸及其鹽及錯； ' bl4)來自以下生長素轉運吡隆-鈉；以之群.—氟吡隆及二氟 bl5)來自以下其他除草劑之群爷苴％ ^ ^ 臭丁卓胺、環庚草醚、乐茅卓枯、燕麥枯、燕麥括·甲硫酸鹽、_ =香草隆(―)、麥草氟、麥草氟-異丙基、麥草二甲基、麥草氟*異丙基、麥草…基、草_、節卓胺、滅草環及6|3_(2_環丙基二:既 (CAS 499223_49_3)及其鹽及醋。土本乳基Η-噠口井醇可與本發明式I之苯并呤畊草劑B係：彳了㈣化合物组合使用之尤佳除二來二？，物合成抑制劑既§日、精乙基号唾禾草$、 _、得殺草、三甲苯草綱、单S…本草早什卞卓丹、殺草丹及野 150107.doc -45- 201109321 麥畏； b2)來自以TALS抑制劑之群：节。密項降、雙草趟-納、環績隆、雙氣續草胺、哇嘯續草胺、H密續隆甲基鈉、甲酿胺續隆、甲氧咪草於、甲基咪草終、依滅草…米唑喹啉酸、咪唑乙菸酸、依速隆、碘磺隆、碘磺隆-甲基_ 鈉、甲基二磺隆、雙醚氣吡嘧磺隆、菸嘧磺隆、五氟卢^ 胺、丙碌隆务百速隆·乙基、甲料草胺、玉嘴項:、磺醯磺隆、甲基噻烯卡巴腙及三I甲確:隆. b3)來自以下光合作用抑制劑之群：殺草淨、阿特拉喷、敵草隆、氣草隆…井酮、異丙隆、利榖隆"井草酮、百草枯、百草枯二氯化物、料寧、去草淨及草淨津； M)來自以下原外啉原_IX氧化酶抑制劑之群 ' 丙快說草胺、複祿芬、㈣料驗、曱項草胺及[叫氣_4_氣邻甲基-6-三氣甲基-2,4-二側氧基从认四氫㈣_3_基）苯氧基]-2+定氧基]乙酸乙醋（CAS 353292 316; 8_雇）； b5)來自以下色素抑制型除草劑之群：可滅縱、氣草胺、氟洛草酮、異十坐草酉同、甲基續草綱、“酿草胺、續草嗣、糠酮、特博嗣、特帕米腙、雙環吼酮、殺草強及伏草隆； ⑽來自以下膽合酶抑制劑之群：草甘膦、草甘膦_ 異丙基銨及草甘膦-三甲基硫鹽（草硫膦）； W來自以下麵醯胺酸合酶抑制劑之群：草丁膦、草丁膦-P及草銨膦； ^來自以下有絲分裂抑制劑之群：施德圃及三福林； 150107.doc -46 - 201109321 bl0)來自以下vlcfa抑制劑之群精二甲吩草胺、四唾酮、氟草胺、、：茉。坐草胺、草、S-莫多草、芬諾克殺草碾及艾芬卡巴肸：胺、莫多者係如上所述之式Π>1、π 2 不，5樣，較佳II.9 Isoxazoline compounds of the type known in the art from, for example, WO 2006/024820, WO 2006/037945, WO 2007/071900 and WO 2007/096576; among VLCFA inhibitors, preferred gas Ethylamine and oxyethylamine; bl 1) from the following group of cellulosic biosynthesis inhibitors: chlorthiamid, dichi〇benil, flupoxam, iso 1 Oxalamine (is〇xaben) & cyclohexyl-5 pentafluorooctyloxy_14-[1,2,4,6]thiatris _3_ylamine; b 1 2) from the following decoupling agent weeding Group of agents: dinoseb, dinGtert^DN〇c and its salt; bl3) from the following group of auxin herbicides: 2,4-D and its salts and esters, 2 4 ' B and its salts and vinegar, chloramine. Specific acid 150107.doc 201109321 (aminopyralid) and its salts (such as chloramine Dtb D acid-volume (2-propyl) and its ester), benzallin, ethyl chlorpyrifos ( Benazolin-ethyl), chloramben and its salts and esters, clomeprop, clopyralid and its salts and vinegar, dicamba (〇1 secretion 311^3) And its salts and esters, 2,4-D-propionic acid (£1丨(;111〇印1*0卩) and its salts and vinegar, 2,4-dipropionic acid (dichlorprop-P) and its salts And vinegar, fluroxypyr, fiuroxypyr-butometyl, fluroxypyr-meptyl, MCPA and its salts and esters, MCPA-thioethyl, MCPB and its salts And esters, mecoprop and its salts and esters, mecoprop-P and its salts and esters, picloram and its salts and esters, dioxins Quinclorac, qUinmerac, tbA (2,3,6) and its salts and vinegar, triclopyr and its salts and esters, and aminocyclopyrachlor and Its salts and esters; b 14) from the following auxin transport inhibition Groups: diflufenzopyr, diflupiron-sodium, naptalam and oxalate-nano; b 1 5) from the following other herbicides: bromobutamol, rectifying alcohol, shaping Alcohol-methyl, cycloheptyl ether, benzalkonium, thatch, cotton, oat, hot wheat, methyl sulfate, thiophene, DSMA, chlorpyrifos, sodium oxonium and its salts, B Oxalamide, wheat straw fluoride, wheat straw fluoride-isopropyl, wheat straw fluoride-methyl, wheat straw fluoride-M_isopropyl, wheat straw fluoride_M_methyl, butyl butyl ester, butyl butyl ester-butyl, fur Pyrimidine, phosphinothricin, chlordane _ ammonium, oxaloin, oxime frank, malazone, flufensulfonate, metan, azido decane, methyl bromide, 150107.doc 201109321 methyl-killing grass Long, 峨貌, MMA, oleic acid, 稗稗, 壬稗, 稗 Zhuo Dan ' 灭 _, trimethoprim, chlorpyrifos and 6 qi · 3 · (2 · cyclopropyl methyl phenoxy Base) · 4 alcohol (CAS 499223 special 3) and its salt and brewing. H the invention! The best herbicide B system used in combination with compounds: bl) from the following lipid biosynthesis inhibitors · „稀_, 快草醋' 环草草, cyanofluoride vinegar, 禾草灵, refined ethyl ^ sit grass spirit, butyl essence. than gas grass extract, fine fluorine 吼禾禾灵, ten sit ugly amine, (four) grass brewing, benzophenone, pupa, ethyl quinone Heling, fine glutinous glutinous vinegar, western herbicide, grass killing, toluene grass, valerian yellow dan, EPTC, pentosandan, ethoxylated cough grass, grass grass enemy, Pingcao Dancao Dan, kill Cao Dan and Wild Maid; b2) From the following groups of ALS inhibitors: one brewing ° Mi Xianglong 'four ° sitting Qianlong, (four) continuous long, double grass I nano, ethyl gas mouth stone yellow, gas yellow Long, A, a base for the preparation of 虱草草草草草草草草草 ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ 迷迷迷迷迷迷迷迷迷迷迷迷迷迷迷Amine, fluoroketone huanglong sodium, gas (four) long, heart icosinide. (4) Long-methyl sodium, ketone amine, methyl gas. ratio. Milong, methyl oxalic acid, methoxy t-mist, methyl meth, yuecao 'mi (four) (four), (four) B (four), yawlong, material, (four) long · methyl · sodium, methyl two Replace, double shout chlorine ° than Mingshi Huanglong, Shihuangcao. Sitting on the amine, methyl sulphide, the end of the stagnation, cancer, stupid amine performance, epoxy strip, ... grass amine,? _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ "Lat-sodium, 150107.doc -42· 201109321 Methionine, rimsulfuron, methyl gargle, sulfonate, sulfhydryl carbene, thiasulfuron-methyl, μ Laughing Qisuolong, methamphetsulfuron, trifluoro 11 sulfonate, flucarbazone and trifluoromethine; b3) from the following photosynthesis inhibitors: chlorpyrifos, amiodarone , Ala Zhan 岵 - 土干" rent _, bentazon, bentazon-sodium, bromoxynil and its salts and esters, chlorpyrifos, 峥i ^,, mailong, cyanide, beet , Diquat, dibromide, diuron, Fuxikeng, Long, linoleum, iodobenzonitrile and its salts and esters, isoproturon, cyclosporine, sorghum, scutellaria, benzene grass Ketone, methamphetamine "well oxatone, fast grass, quick salt (four), beet ning, herbicide ning ·, health grass, grass net, go grass, grass net and sigh thidiazuron ); b4) from the following protoporphyrinogen _IX oxidase inhibitor Group of preparations: azophene sodium, benzocarbazide, dibenzyl ketone, flufenacetate, oxazolone, ketoxime, flubendiate, flufenic acid-pentyl, propyne Fluramide, ethyl acetophenone, methyl oxalate, flufenacil, propane sulphonone, lythrazine, phloem, cyclopentyl ketone, pyriprene, pyrimidine Ether, acesulfame, [3-[2-chloro-4-fluoro-5-(1_fluorenyl-6-trifluoromethyl] 2,4-di-oxy-1,2,3,4 -tetrahydropyrimidin-3-yl)phenoxy]_2-pyridyloxy]acetate (CAS 353292-3 1-6; S-31〇0), N_ethyl_3_(2,6_ monochloro -4-Dipyridylmethylphenoxy)-5-methyl-1H-. ratio. _ 1 _ decylamine (cAs 452〇98-92-9), Ν-tetrahydrofuranyl-3-(2,6-dioxa_4_trifluorodecylphenoxy)-5-mercapto-1Η -pyrazole-1-carboxamide (CAS 915396-43-9), Ν-ethyl-3-(2-gas-6-fluoro-4-trifluorodecylphenoxy)-5.methyl_ Out _. ratio. Sitting on small formamide (CAS 452099-05-7) and N-tetrahydrofuranyl_3-(2_gas_6_ defeat_4_three 150107.doc • 43· 201109321 fluoromethylphenoxy)-5- Methyl 7); than sit-I·carbamamine (CAS Guanlu b5) from the following group of pigment-inhibiting herbicides: oxalic acid ether, flufenamate, stupid and 0. ^ sn ^ double coat, can Exclusion, fluroxypyramine, fluroxypyr, furazolidone, isoxacilin π., ^ oxamethyl ketone, chlorfen, flufenic acid, darsert, benzylidene , anthrone, telcodone, tepapyr, bicyclopyridone, 4_(3·=affinated fluoromethyl- oxy)-2-(4-trifluoromethylbenyl) ° (d) (CAS 18_8-33·7) , chlorpyrifos and humulus; b6) from the following EPSP synthase inhibitors · sulfhydryl sulphate (aspartate glyphosate, glyphosate-isopropyl cast and glyphosate · phosphine); B7) from the following branamine synthase inhibitor groups: glufosinate, glufosinate-P, glufosinate; b8) from the DHP synthase inhibitor group: chlorhexidine. b9) from the following mitotic inhibition Group of agents: Shi Dezhen, valerian bite benifen, thiophene, dimethoate, eucalyptus, and triptyline; bl〇 ) from the following VLCFA inhibitors: acetochlor, diclofenac, imazachlor, prasin, fennox, acetochlor, lavender, samarium phosphate, butyl alachlor Monomethyl acetophenone, tetrazolone, fluramide: sorghum, S. modoc, cypromine, chlorpyrifos, chlorpyrifos, effluent, methoxyform and m , ττ /Γ, ΙΙ·4, the description of 1...11·8 and Π.9 of the different ten sitting compound, as above 150107.doc • 44 · 201109321 bll) from the following cellulose bio-human amine grass Kun... Group: diquat nitrile, fluoxazole, different. Deficient amines and hydrazines...-ylamines; oxime oxy bl3) are from the following group of auxin herbicides: and their salts and from the 'chloramine-acids and their salts (eg aniline citrate _ 畚(2 - by propyl) recorded and potted cool, _ prepared... 虱. pyridine acid and its salt and vinegar ' dicamba and a wind and ester, fine 2,4 · drip propionic acid and its _ and its salts and Vinegar, _... and fluorine gas ratio, MCPA ffib main - and /, dish and sputum, fine 2 A 4 chloropropionic acid and its salts and sputum, broad and its salt and vinegar, dioxin, acid, chlorine (d), three gases and their salts and vinegar, and cyprodinil and its salts and wrong; 'bl4) from the following auxin transporter pyronium-sodium; group of. - flupiron and difluoro bl5) from the following Herbicide group ^% ^ ^ odorin, cycloheptyl ether, oleracea, oats, oatmeal, methyl sulfate, _ = vanilla (-), wheat straw fluoride, wheat straw fluoride - isopropyl Base, wheat straw dimethyl, wheat straw fluoride * isopropyl, wheat grass ... base, grass _, zoic amine, chlorpyrifos and 6|3_(2_cyclopropyl two: both (CAS 499223_49_3) and its salt and vinegar土本乳基Η-哒井井醇 and the benzopyrene grass of the formula I of the present invention B series: 彳四四四化合物化合物化合物化合物化合物化合物化合物化合物化合物化合物化合物化合物 , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , As early as Zhuo Dan, killing grass and wild 150107.doc -45- 201109321 Mai Wei; b2) from the group of TAALS inhibitors: section.密项降,双草趟-纳, 环绩隆, 气续续、, 哇续续草 , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , End, according to the grass... mirazoquine acid, imidazolium, acesulfame, iodosulfuron, iodosulfuron-methyl-sodium, methyl disulfuron, diether gas pyrazosulfuron, nicosulfuron, Pentafluorolumine, acetaminophen, acesulfame, ethyl, acetochlor, and jade mouth: sulfonium sulfonate, methyl thiazyl carbazide, and tri-I-carriage: 隆. b3) from Groups of photosynthesis inhibitors: chlorpyrifos, atrazine, diuron, turfate, ketone, isoproturon, lilong, "well ketone, paraquat, paraquat dichloride, ning , 去草净和草净津; M) from the following original protoporphyrinogen _IX oxidase inhibitors group 'C-fast oxalic acid, Fulufen, (four) test, oxalin and [called gas _4 _ gas o-methyl-6-tris-methyl-2,4-dioxy group from tetrahydro(tetra)-3-yl)phenoxy]-2+oxy]acetic acid ethyl acetate (CAS 353292 316; 8_ Employed; b5) from the following group of pigment-inhibiting herbicides: extrudate, amlal, fluroxypyr , 10 different from the grass, the same as the methyl sylvestris, "strawamine, chlorpyrifos, fluorenone, terbolin, tepamimid, bicyclononanone, chlorpyrifos and humulus; (10) from the following gallbladder a group of synthase inhibitors: glyphosate, glyphosate _ isopropylammonium and glyphosate-trimethylsulfanium salt (phosphophos); W from a group of valerine synthase inhibitors below: grass Butylated phosphine, glufosinate-P and glufosinate; ^ from the following group of mitotic inhibitors: Schindler and triptrine; 150107.doc -46 - 201109321 bl0) Group of dimethenamid from the following vlcfa inhibitors , tetrahexylidene, fluramide, and: molybdenum, oxaliplatin, grass, S-momoda, fenocin, and fentancapa: amine, modo, as described above> 1, π 2 no, 5, better

i13 、 ΙΙ·4 、 11,5 、 TT A ΙΙ·7、ΙΙ·8及ΙΙ·9之異4嗤琳化合物， . bll)來自以下纖維素生物合胺；物〇成抑制劑之群：異呤草 =3)來自以下生長素除草劑之群：2,4_d及其鹽心比°定酸及其鹽及其醋、二氯。比咬酸及其鹽及醋、麥草汉及其鹽及S旨、氟氣比、二氣啥吸辦虱室啉酸、氯甲喹啉酸及環丙嘧啶酸及其鹽及酯；叫來自以下生長素轉運抑制劑之群：…隆及二氟。比隆鈉， M5)來自以下其他除草狀群：殺草隆㈣草隆）'草 _、茚茲弗蘭、稗安及三氟草胺。較佳安全劑c之實例係解草酮（ben〇xac〇r)、解毒喹 (cloquintocet)、解草胺腈（cy〇metHnil)、解草磺醯胺 (cyprosulfamide)、二氣丙烯胺（dichl〇rmid)、雙環酮 (dicyclonone)、苯基硫磷酸二乙醋（dieth〇iate)、解草唑 (fenchlorazole)、解草咬（fencl〇rim)、解草胺（fluraz〇le)、將草女（fluxofenim)、解草崎嗤（furiiaz〇ie)、雙苯号。坐酸 (isoxadifen) 、°比哇解草醋（mefenpyr)、美芬酉旨 (mephenate)、秦二甲酸針、解草腈（oxabetrinil)、4-(二氯乙醯基）-1-氧雜-4-氮雜螺[4.5]癸烷（MON4660，CAS 71526- 150107.doc 47- 201109321 07-3)及 2，2,5-三甲基- 3- (二氣乙酿基）-1,3 -〇号〇坐13定（r_ 2 9 14 8 CAS 52836-3 1-4)。尤佳之安全劑C係解草酮、解毒喹、解草磺醯胺、二氣丙烯胺、解草唑、解草啶、解草胺、肟草安、解草„号唑、雙本°号°坐酸、α比。坐解草醋、萘二甲酸酐、解草猜、4-(.-氣乙酿基）-1-氧雜-4-氮雜螺[4.5]癸烧（ΜΟΝ4660，CAS 71526-07-3)及2,2,5-三甲基- 3- (二氣乙酿基）-1，3-。号哇11定（尺_29148, CAS 52836-31-4)。尤佳之安全劑C係解草酿I、解毒喹、解草續醯胺、二氣丙烯胺、解草。坐、解草°定、解草崎《•坐、雙笨·»号吨酸、η比。坐解草酯、4-(二氯乙醯基）-1-氧雜-4-氮雜螺[4.5]癸烷 (ΜΟΝ4660，CAS 71526-07-3)及 2,2,5-三甲基-3-(二氣乙醯基）-1，3-噚唑啶（R-29148, CAS 52836-31-4)。尤佳之安全劑C亦係解草酮、解毒喹、解草磺醯胺、二氣丙稀胺、解草嗤、解草σ定、解草°号°坐、雙苯17号。生酸、。比唑解草酯、4-(二氣乙醯基）-1-氧雜-4-氮雜螺[4.5]癸烷 (ΜΟΝ4660, CAS 71526-07-3)及 2,2,5-三甲基-3-(二氣乙醯基）-1，3-噚唑啶（11-29148,0八8 5 283 6-31-4)及萘二曱酸酐。 b 1)至b 15)類之活性化合物Β及活性化合物C係已知除草劑及安全劑，例如，參見The Compendium of Pesticide Common Names (http://www.alanwood.net/pesticides/); Farm Chemicals Handbook 2000，第 86 卷’ Meister Publishing公司，2000 ; Β· Hock, C· Fedtke，R. R. Schmidt, Herbizide [Herbicides], Georg Thieme Verlag, Stuttgart I50i07.doc -48· 201109321 1995 ; W_ H. Ahrens，Herbicide Handbook，第 7版，Weed Science Society of America，1994 ;及 Κ· K. Hatzios， Herbicide Handbook，第 7版修訂版，Weed Science Society of America，1998。2,2,5-三曱基-3-(二氣乙醯基）-1，3-嘮唑啶[CAS第52836-3 1-4號]亦稱作R-29148。4-(二氣乙醯基）-卜氧雜-4-氮雜螺[4.5]癸烷[CAS第71526-07-3號]亦稱作AD-67 及 MON 4660 。其他除草活性化合物係自 WO 96/26202 、 WO 97/41116、WO 97/41117、WO 97/41118及WO 01/83459以及自 W. Kramer 等人（編輯）之「Modern Crop Protection C Compounds」’第1卷’ Wiley VCH，2〇〇7及本文所引用參考文獻中已知。根據現有知識來綠定活性化合物各自之作用機制。若若干作用機制適用於一種活性化合物，則僅將一種作用機制指派至此物質。若除草劑B及/或安全劑C能夠形成幾何異構體（例如e/z 同分異構體），則純同分異構體及其混合物二者均可用於本發明組合物中。若除草劑B及/或安全劑c具有一或多個對掌性中心且由此係以對映異構體或非對映異構體形式存在，則純對映異構體及非對映異構體及其混合物均可用^ 本發明組合物中。若除草劑B及/或安全劑C具有可離子化官能團，則其亦可以其農業上可接受之鹽形式使用。通常，適宜者係陽離子及陰離子分別對活性化合物之活性無不利作用之離子之鹽及彼等酸之酸加成鹽。 150107.doc -49- 201109321 車父佳1%離子係：驗金屬離子，較佳為链、納及卸；驗土金屬離子，較佳為鈣及鎂；及過渡金屬離子，較佳為猛、銅、鋅及鐵；以及銨及經取代銨，其中一至四個氩原子由 Ci-C4-烧基、經基-Ci-C4-烧基、CVC4-烧氧基燒基、經基-CVC4-烧氧基-C1-C4-烧基、苯基或苄基取代，車交佳為銨、甲基銨、異丙基銨、二甲基敍、二異丙基錄、二曱基銨、四曱基銨、四乙基銨、四丁基銨、2_羥乙基錄、 2-(2-羥基乙-1-氧基）乙-丨-基銨、二（2_羥基乙_丨_基）銨、苄基三曱基銨、苄基三乙基銨，以及鱗離子、銃離子，較佳為二（C〗-C4·烷基）銃（例如三甲基銃），及氧錡離子，較佳為二（Cl-烧基）氧疏。有用酸加成鹽之陰離子主要係氯離子、溴離子、氣離子、碘離子、硫酸氫根離子、甲基硫酸根離子、硫酸根離子、磷酸二氫根離子、磷酸氫根離子、硝酸根離子、碳酸氫根離子、碳酸根離子、六氟矽酸根離子、六氟磷酸根離子、苯甲酸根離子以及Cl_C4_鏈烷酸之陰離子（較佳為甲酸根離子、乙酸根離子、丙酸根離子及丁酸根離子）。具有羧基之活性化合物B及c可以酸形式、農業上適宜之鹽形式或者以農業上可接受之衍生物形式用於本發明組合物中，例如以醯胺（例如單-及二/广匕-烷基醯胺^芳基醯胺）形式、以酯（例如，烯丙基酯、炔丙基酯、俨基醋、烧氧基烧基酯以及硫基醋（例如，Ci_Ci〇_烧基硫基酯））形式使用。較佳單_及-Γ Γ γ I β 子乂狂早及一-C丨-CV烷基醯胺係甲基醯胺及二甲基醯胺。較佳芳基醯胺係(例如)醯基苯胺及2'氯醯基 I50I07.doc •50· 201109321 苯胺。較佳烷基酯係（例如）甲基酯、乙基酯、丙基酯、異丙基酯、丁基酯、異丁基酯、戊基酯、異庚基（mexy】）（1_ 甲基己基）酯或異辛基（2-乙基己基）酯。較佳Ci_C4_烷氧基_ q-C4-烧基酯係直鏈或具支鏈Ci_C4_烷氧基乙基酯，例如甲氧基乙基酯、乙氧基乙基酯或丁氧基乙基酯。直鏈或具支鏈CrCM-炫基硫基酯之實例係乙基硫基酯。根據本發明之一較佳實施例，該組合物包含至少一種、較佳恰好一種除草劑B作為除草活性化合物B或組份B。根據本發明之另一較佳實施例，該組合物包含至少兩種、較佳恰好兩種彼此不同之除草劑B作為除草活性化合物B或組份B。根據本發明之另一較佳實施例，該組合物包含至少三種、較佳恰好三種彼此不同之除草劑B作為除草活性化合物B或組份b。根據本發明之另一較佳實施例，該組合物包含至少一種、較佳恰好一種安全劑C作為保護組份C。根據本發明之另一較佳實施例，該組合物包含至少一種、較佳恰好一種除草劑;5作為組份B、及至少—種、較佳恰好一種安全劑C。根據本發明之另—較佳實施例’該組合物包含較佳恰好兩種彼此不同之除草劑B作為組份b、及至._ • 夕—檀、較伟恰好一種安全劑C。根據本發明之另一較佳實施例，該組合物包含至少三種、較佳恰好三種彼此不同之除草劑B作為組份B' 150l07.doc •51 - 201109321 少一種、較佳恰好一種安全劑c。根據本發明之另一較佳實施例，該組合物包含至少— ^較佳恰好一種Si、較佳式^之苯并十井綱化合物作為 71 A及至少一種、較佳恰好一種除草劑B作為組份B。根據本發明之另一較佳實施例，該組合物包含至少— 種、較佳恰好一種式1、較佳式之笨并十井酮化合物作為、且伤A、及至少兩種、較佳恰好兩種彼此不同之除草 B作為組份B。根據本發明之另一較佳實施例該組合物包含至少〜種、教佳恰好一種式ί、較佳式M之苯并噚畊酮化合物作為，-且伤A、及至少三種、較佳恰好三種彼此不同之除草 B作為組份B。根據本發明之另一較佳實施例，該組合物僅包含至少〜種、較佳恰好—種式卜較佳式Ι·1之笨并十井_化合物、及至少一種、較佳恰好一種除草劑Β作為活性組份。根據本發明之另-較佳實施例’該組合物僅包含至少〜種、較佳恰好—種式卜較佳式1.1之苯并$相化合物、 ;>'兩種較佳恰好兩種彼此不同之除草劑β作為組份。 '性根據本發明之另一較佳實施例，該組合物僅包含至少— 種、較佳恰好—種式卜較佳式L1之笨并十井酮化合物、及至少三種、較佳恰好三種彼此不同之除草劑β作為組份。改根據本發明之另一較佳實施例，該組合物僅包含至少〜 150107.doc •52- 201109321 佳恰好-種式ϊ、較佳式L1之苯并十井酮化合物、 /種、争乂佳恰好一種安全劑c作為活性組份。根據本發明之另—較佳實施例，該組合物僅包含至少— 種^佳恰好-種式卜較佳式1.1之笨并十㈣化合物、至種、較佳恰好—種除草劑B及至少一種、較佳恰好一種安全劑C作為活性組份。康本土明之另-較佳實施例，該組合物僅包含至少一 I車又佳好種式I、較佳式J 1之苯并嘮畊嗣化合物、至y兩種、較佳恰好兩種彼此不同之除草劑B及至少一種較佳恰好一種安全劑c作為活性組份。根據本發明之另―較佳實施例該組合物僅包含至少一種j較佳恰好"'種式1、較佳式I·]之苯并十井酮化合物、 >'—種、較佳恰好二種彼此不同之除草劑B及至少一種較佳恰好一種安全劑C作為活性組份。本I明之第一較佳實施例係關於本發明組合物，其除式 I之苯并3 p井酮化合物、尤其來自由[I」、1.2 1、m L3’l、1_3.2及Ι_4·1組成之群之活性化合物外，亦包含至少種且尤其恰好一種來自b丨）類、特定而言選自由以下組成之群之除草活性化合物：炔草酯、環殺草、氰氟草酯、精乙基嘩唑禾草靈、唑啉草酯、環苯草酮、得殺草、三曱笨草酮 '戊草丹、苄草丹、殺草丹及野麥畏。本發明之第二較佳實施例係關於本發明組合物，其除式 I之苯并号，井酮化合物、尤其來自由U 1、Γ 21、J 2 2、 L3_l、1.3.2及1.4.1組成之群之活性化合物外，亦包含至少 150107.doc -53· 201109321 一種且尤其恰好一種來自b2)類、特定而言選自由以下組成之群之除草活性化合物··苄嘧磺隆、雙草醚鈉、環石立隆、笨氣磺草胺、唑嘧磺草胺、氟啶嘧磺隆-甲基-鈉、s 酿胺石黃隆、甲氧味草終、甲基咪草終、依滅草、味唾啥I 酸、味唑乙於酸、依速隆' 破磺隆、峨磺隆_甲基，、甲基二磺隆、雙醚氣吡嘧磺隆、菸嘧磺隆、五氟磺草胺、丙料隆-鋼、乙基百速隆、甲氧續草胺、玉料隆、項酿蟥隆、甲基噻烯卡巴腙及三氟甲磺隆。本發明之第二較佳實施例係關於本發明組合物，其除 1之苯并十井酮化合物、尤其來自由1.1.1、Ι.2.Ϊ、二：、。二及以.〗組成之群之活性化合物外，亦包含至，丨、 -種且尤其恰好一種來自b3)類、特定而言選自由以下：成之群之除草活性化合物：殺草淨、阿拉特_、敵草隆、伏草隆、環仙、異丙隆、利縠隆、料酮、對草协草快二鹽㈣、除草寧、去草淨及H卜、本發明之第四較佳實施例係關於本發明組合物， 1之苯并十井酮化合物、尤其來自由LU、山' 1.3.1 ' 1.3.2及L4」組成之群之活性化合物外，_包含至，卜 -種且尤其恰好一種來自b4)類、特定而言選自： ^之群之除草活性化合物：丙块氣草胺、複祿芬月卓鍵、曱料胺及[叫氣_4•氣·5·("基_6_三氟甲^ 2,4·—㈣基_1，2’3,4.四氫㈣+請氧基]H定氧^ ^S^SKCAS 353292-31.6; s.31〇〇)o 氣基] 本發明之第五較佳實施例係關於本發明組合物，其除式 150107.doc -54- 201109321 1之苯并十井酮化合物、尤其來自由1.1.1、L2」、L2.2' t·1、L3·2及U·1組成之群之活性化合物外，亦包含至少 -種且尤其恰好—種來自b5)類特定而言選自由以下組成t群之除草活性化合物：可滅蹤、氟草胺、氟°各草_、異％ °坐草酮、甲基4草酮K醯草胺、續草酮、糠酮、特博嗣特帕米月宗、雙環π比嗣、殺草強及伏草隆。本發明之第六較佳實施例係關於本發明組合物，其除式 1之苯并十井酮化合物、尤其來自由I.U、m、;:2.2、 1’3’1、1.3.2及1.4.1組成之群之活性化合物外，亦包含至少種且尤其恰好一種來自b6)類、特定而言選自由草甘膦、草甘膦-異丙基銨及草甘膦_三曱基硫鹽（草硫膦）組成之群之除草活性化合物。本發明之第七較佳實施例係關於本發明組合物，其除式 I之苯并％哨:嗣化合物、尤其來自由J 1 1、^ 2 1、I 2 2、工·3· 1、1.3.2及1.4.1組成之群之活性化合物外，亦包含至少種且尤其恰好一種來自b7)類、特定而言選自由草丁膦、草丁膦-P及草敍膦組成之群之除草活性化合物。本發明之第八較佳實施例係關於本發明組合物，其除式 I之苯并$呼酮化合物、尤其來自由j丨1、】2 1、！ 2 2、 J.3’1、1.3.2及I·4.1組成之群之活性化合物外，亦包含至少種且尤其恰好一種來自b9)類、特定而言選自由施德圃及三福林組成之群之除草活性化合物。本發明之第九較佳實施例係關於本發明組合物，其除式 I之苯并噚畊酮化合物、尤其來自由〗丨1、j 2.1、〗2 2、 150l07.doc -55- 201109321 1.3.1、 1.3.2及1.4.1組成之群之活性化合物外，亦包含至少 -種且尤其恰好-種來自blG)類、特定而言選自由以下组成之群之除草活性化合物：乙草胺、㈣胺、精二甲吩草胺、四0坐嗣、說草胺、滅芬草、滅草胺、莫多草、S_莫多草及芬諾克殺草砜。㈣，較佳者係如下組合物：其除式 I之笨并十井酮化合物、尤其來自由〗丨丨、Μ丨、】Μ、 1.3.1、 1.3.2及1.4.1組成之群之活性化合物外，亦包含至少一種且尤其恰好—種來自_)類、特定而言選自由由如上文所定義式 Π.9之異㊉㈣化合物組成之群之除草活性化合物。本發明之第十較佳實施例係關於本發明組合物，i除式 1之苯并十井酮化合物'尤其來自由u」、mm 1.3.2及1.4.1組成之群之活性化合物外，亦包含至少種且尤其③好-種來自bu)類、特定而言異吟草胺之除卓活性化合物。 ' 本發明之第十-較佳實施例係關於本發明組合物，立除式!之苯并十井酮化合物、尤其來自由、山、 1.2.2、^、[3.2及1 4」組成之群之活性化合物外，亦包含至少-種且尤其恰好一種來自bl3)類特定而言選自由以下組成之群之除草活性化合物：2,4-D及其鹽及醋、氯 ^^及其鹽（例女〇 ’氯胺0比咬酸-卷（2-經丙基）銨及其 Μ ㈣及其鹽及§旨、麥草畏及其鹽及醋、氣氯比、-風㈣酸、氣f喧琳酸及環㈣㈣及其鹽及醋。本發明之第十二較佳實施例係關於本發明組合物，其除 150107.doc •56· 201109321 式i之笨并咩哺酮化合物、尤其來自由t a i^、 1.2.2 I·3.1、1.3.2及I·4.1組成之群之活性化合物外，亦包名至>、種且尤其恰好一種來自bl4)類、特定而言選自由二氟吡隆及二氟吡隆-鈉組成之群之除草活性化合物。本發明之第十三較佳實施例係關於本發明組合物，其除式I之苯并呵啩酮化合物、尤其來自由：丨丨^〗2 i、 1.2.2、1.3.1、以二及以」組成之群之活性化合物外，亦包含至少一種且尤其恰好一種來自bl5)類、特定而言選自由殺草隆（=香草隆）、草_、茚兹弗蘭、去轉安及三氣草胺組成之群之除草活性化合物。本發明之第十四較佳實施例係關於本發明組合物，其除式I之苯并啰畊酮化合物、尤其來自由】丨」、ι2」、 Ι·2·2、Ι，3·1、1.3.2及Ι·4.1組成之群之活性化合物外，亦包 3至乂種且尤其恰好一種來自安全劑c、特定而言選自由以下組成之群之除草活性化合物：解草嗣、解毒啥、解草確醯胺、二氯丙稀胺、解草哇、解草咬、解草十坐、雙苯十坐酸、対解草3旨、4•(二氯乙醯基）小氧雜_4_氮雜螺癸烧（MON466〇, CAS 71526·〇7 3)及 2,2,5 三甲基小 (二氯乙醯基）-1，3_号„坐咬（R_29148, cas 52836_3ι·4)。其他較佳實施例係關於對應於實施例】至14之二元组合物且另外包含(特定而言)選自由以下組成之群之安全劑：的三元組合物：解草綱、解毒啥、解草石黃醯胺、二氯丙稀 ^解草哇、解草唆、解草$ °坐、雙苯十坐酸、吼唾解草酉曰、4·(二氯乙醯基）小氧雜_4•氮雜螺[45】癸炫⑽⑽楊 150J07.doc •57- 201109321 CAS 71526-07-3)及 2,2,5-三曱基-3-(二氯乙醯基）-1，3-口号唑啶（R-29148, CAS 52836-31-4)。此處及下文之術語「二元組合物」包括含有一或多種 (例如，1種、2種或3種）式I活性化合物及一或多種（例如， 1種、2種或3種）除草劑B或一或多種安全劑之組合物。相應地’術語「三元組合物」包括含有一或多種（例如，1 種、2種或3種）式I活性化合物、一或多種（例如，1種、2種或3種）除草劑B及一或多種（例如，！種、2種或3種）安全劑 C之組合物。在包含至少一種式I化合物作為組份A及至少一種除草劑 B之一元組合物令，活性化合物A:B之重量比通常在1:1 〇〇〇至1000:1範圍内’較佳在1:5〇〇至5〇〇:1範圍内，特定而言在1:250至250:1範圍内且尤佳在i:75至75:1範圍内。在包含至少一種式I化合物作為組份A及至少一種安全劑 C之一元組合物中，活性化合物A:C之重量比通常在ι:ι〇〇〇至1000:1範圍内，較佳在1:5〇〇至500:1範圍内，特定而言在1··250至250:1範圍内且尤佳在1:75至75:1範圍内。在包含至少一種式I之苯并噚啩酮化合物作為組份A、至少一種除草劑B及至少一種安全劑c的三元組合物中，組份A:B之相對重量比例通常在丨：丨〇〇〇至丨〇〇〇:】範圍内，較佳在1:500至500:1範圍内，特定而言在1:25〇至25〇:1範圍内且尤佳在1:75至75:1範圍内，組份a:c之重量比通常在 1:1000至1000:1範圍内’較佳在i :500至5〇〇:1範圍内，特疋而s在1:250至250:1範圍内且尤佳在1:75至75:1範圍 150107.doc -58 - 201109321 内，且組份B:C之重量比通常在1:1000至1000:1範圍内，較佳在1:500至500:1範圍内，特定而言在1:250至250:1範圍内且尤佳在1:75至75:1範圍内。組份A + B與組份C之重量比較佳在1:500至500:1範圍内，特定而言在1:250至250:1 範圍内且尤佳在1:75至75:1範圍内。尤佳之除草劑B係如上文所定義之除草劑B、尤其下表B 中所列舉之除草劑B.l - B.139 : 表B : 除草劑B B.1 稀草酮 B.2 炔草酯 B.3 環殺草 B.4 氰氟草酯 B.5 精乙基哼唑禾草靈 B.6 11号。坐醯草胺 B.7 °坐琳草西旨 B.8 環苯草酮 B.9 西殺草 B.10 得殺草 B.11 三甲苯草酮 B.12 戊草丹 B.13 乙氧呋草黃 B.14 禾草敵 B.15 苄草丹 B.16 殺草丹 B.17 野麥畏 B.18 苄嘴績隆 B.19 雙草醚鈉 B.20 氯酯磺草胺 B.21 氣績隆 B.22 氣嘧磺隆 B.23 環磺隆除草劑B B.24 雙氯磺草胺 B.25 雙氟磺草胺 B.26 唑嘧磺草胺 B.27 氟咬嘴績隆-甲基-納 B.28 甲醯胺磺隆 B.29 甲氧咪草菸 B.30 甲基咪草菸 B.31 依滅草 B.32 »米坐啥琳酸 B.33 咪唑乙菸酸 B.34 依速隆 B.35 碘磺隆-甲基-鈉 B.36 曱基二磺隆 B.37 雙醚氯°比°密績隆 B.38 甲磺隆 B.39 磺草唑胺 B.40 於。密確隆 B.41 五氟續草胺 B.42 丙笨績隆納 B.43 乙基百速隆 B.44 嘧啶肟草醚 B.45 環酯草醚 B.46 曱氧續草胺 150107.doc -59- 201109321 除草劑B B.47 玉嘧磺隆 B.48 磺醯磺隆 B.49 曱基噻烯卡巴腙 B.50 噻磺隆 B.51 苯磺隆 B.52 三氟曱磺隆 B.53 殺草淨 B.54 阿拉特畊 B.55 苯達松 B.56 溴苯腈 B.57 敵草隆 B.58 伏草隆 B.59 環畊酮 B.60 異丙隆 B.61 利穀隆 B.62 苯畊草酮 B.63 畊草酮 B.64 除草寧 B.65 草滅淨 B.66 草淨津 B.67 去草淨 B.68 對草快二鹽酸鹽 B.69 亞喜芬 B.70 氟丙嘧草酯 B.71 唑草酮-乙基 B.72 丙炔氟草胺 B.73 氟續胺卓喊 B.74 丙炔》号草酮 B.75 複祿芬 B.76 嘧啶肟草醚 B.77 甲磺草胺 B.78 [3-[2-氣-4-氟-5-(1-曱基-6-三氟甲基-2,4-二側氧基-1，2,3,4-四氫嘧啶-3-基）苯氧基]-2-«比啶基氧基]乙酸乙酯(CAS 353292-31-6) B.79 苯并雙環酮I13, ΙΙ·4, 11,5, TT A ΙΙ·7, ΙΙ·8, and ΙΙ·9 嗤4嗤琳 compound, . bll) from the following cellulosic bioamines; Valerian = 3) from the following group of auxin herbicides: 2, 4_d and its salt core ratio ° acid and its salts and its vinegar, dichloro. It is better than biting acid and its salt and vinegar, wheat grass and its salt, and S, fluorine gas ratio, dioxonic acid, chloroformic acid and cyprodinil and its salts and esters; The following groups of auxin transport inhibitors: ... and difluoro. Billund sodium, M5) comes from the following other herbicidal groups: chlorpyrifos (four) turf) 'grass _, 茚zfran, 稗安 and trimethoprim. Examples of preferred safeners c are becumin xac〇r, cloquintocet, cy〇metHnil, cyprosulfamide, dioxyl propylene (dichl) 〇rmid), dicyclonone, dieth〇iate, fenchlorazole, fencl〇rim, fluraz〇le, grass Female (fluxofenim), 草草崎嗤 (furiiaz〇ie), double benzene. Isoxadifen, mefenpyr, mephenate, qindicarboxylic acid, oxabetrinil, 4-(dichloroacetyl)-1-oxa -4-Azaspiro[4.5]decane (MON4660, CAS 71526-150107.doc 47-201109321 07-3) and 2,2,5-trimethyl-3-(dihydroethane)-1, 3 - 〇〇 sit 13 (r_ 2 9 14 8 CAS 52836-3 1-4). Youjia's safener C is ketone, detoxification quinone, sulforaphane, di- propylene amide, oxazolidine, oxadiazepine, sulforaphane, valerian, lycopene, double bis No. ° sitting acid, α ratio. Sitting on the grass vinegar, naphthalic anhydride, Jiecao guess, 4- (.- gas acetyl)-1-oxa-4-azaspiro[4.5] 癸 ΜΟΝ (ΜΟΝ 4660 , CAS 71526-07-3) and 2,2,5-trimethyl- 3- (diethylene b-aryl)-1,3-. No. Wow 11 (foot _29148, CAS 52836-31-4) Youjia's safety agent C is a solution of grass brewing I, detoxification quinone, chlorpyrifos, acetophenone, di- propylene amide, and turfgrass. Sit, seduce, sedative, sedative, sedative, sedative , η ratio. Solvent, 4-(dichloroethenyl)-1-oxa-4-azaspiro[4.5]decane (ΜΟΝ4660, CAS 71526-07-3) and 2,2,5 - Trimethyl-3-(dioxaethyl)-1,3-oxazolidine (R-29148, CAS 52836-31-4). The safener C is also a ketone, detoxification quinone, Sulfosamine, di- propylene amide, chlorpyrifos, sputum sputum, sedum ° ° ° sit, double benzene 17 . acid, carbazole oxalate, 4- (diqi acetyl ))-1-oxa-4-azaspiro[4.5]decane (ΜΟΝ4660, CAS 71526-07-3) and 2,2,5-trimethyl-3-(dioxaethyl)-1,3-oxazolidine (11-29148, 0 8 8 5 283 6-31-4 And naphthalic anhydride. b 1) to b 15) active compounds Β and active compound C are known herbicides and safeners, for example, see The Compendium of Pesticide Common Names (http://www.alanwood. Net/pesticides/); Farm Chemicals Handbook 2000, Volume 86 'Meister Publishing, 2000; Β·Hock, C· Fedtke, RR Schmidt, Herbizide [Herbicides], Georg Thieme Verlag, Stuttgart I50i07.doc -48· 201109321 1995 W_ H. Ahrens, Herbicide Handbook, 7th Edition, Weed Science Society of America, 1994; and K. Hatzios, Herbicide Handbook, 7th Edition, Weed Science Society of America, 1998. 2, 2, 5 -Tridecyl-3-(dioxaethyl)-1,3-oxazolidine [CAS No. 52836-3 1-4] Also known as R-29148. 4-(dioxaethyl)- Oxaxo-4-azaspiro[4.5]decane [CAS No. 71526-07-3] is also known as AD-67 and MON 4660. Other herbicidal active compounds are those of "Modern Crop Protection C Compounds" from WO 96/26202, WO 97/41116, WO 97/41117, WO 97/41118 and WO 01/83459, and from W. Kramer et al. Volume 1 'Wiley VCH, 2' 7 and the references cited herein are known. The respective mechanisms of action of the active compounds are determined according to the prior knowledge. If a mechanism of action is applied to an active compound, only one mechanism of action is assigned to the substance. If herbicide B and/or safener C are capable of forming geometric isomers (e.g., e/z isomers), both pure isomers and mixtures thereof can be used in the compositions of the present invention. If the herbicide B and/or the safener c have one or more pairs of palmar centers and thus exist as enantiomers or diastereomers, then pure enantiomers and diastereoisomers Isomers and mixtures thereof can be used in the compositions of the invention. If herbicide B and/or safener C have an ionizable functional group, they can also be used in the form of their agriculturally acceptable salts. In general, suitable salts of the cations and anions which do not adversely affect the activity of the active compound, and acid addition salts of the same are preferred. 150107.doc -49- 201109321 Car father good 1% ion system: metal ions, preferably chain, nano and unloading; soil metal ions, preferably calcium and magnesium; and transition metal ions, preferably fierce, Copper, zinc and iron; and ammonium and substituted ammonium, wherein one to four argon atoms are composed of Ci-C4-alkyl, via-Ci-C4-alkyl, CVC4-alkoxy, and base-CVC4- Alkoxy-C1-C4-alkyl, phenyl or benzyl substituted, car-crossing is ammonium, methylammonium, isopropylammonium, dimethyls, diisopropyl, diammonium, tetra Mercaptoammonium, tetraethylammonium, tetrabutylammonium, 2-hydroxyethylate, 2-(2-hydroxyethyl-1-oxy)ethylidene-ammonium, bis(2-hydroxyethyl-hydrazine) Ammonium, benzyltrimethylammonium, benzyltriethylammonium, and scaly ions, cerium ions, preferably di(C-C4.alkyl) hydrazine (eg, trimethylhydrazine), and oxindole The ion is preferably a di(Cl-alkyl) oxygen sparging. The anion of a useful acid addition salt is mainly chloride ion, bromide ion, gas ion, iodide ion, hydrogen sulfate ion, methyl sulfate ion, sulfate ion, dihydrogen phosphate ion, hydrogen phosphate ion, nitrate ion , anions of carbonate, carbonate, hexafluoroantimonate, hexafluorophosphate, benzoate and Cl_C4_alkanoic acid (preferably formate, acetate, propionate and Butyrate ion). The active compounds B and c having a carboxyl group can be used in the compositions of the invention in acid form, in agriculturally suitable salt forms or in the form of agriculturally acceptable derivatives, for example in the form of indoleamines (for example mono- and di-/poly- In the form of alkyl oxime aryl amides, esters (eg, allyl esters, propargyl esters, mercapto vinegars, alkoxy succinates, and thio vines (eg, Ci_Ci 〇烧 sulphur) The base)) form is used. Preferably, _ and - Γ γ γ I β 乂早早 and a-C丨-CV alkyl amide amine methyl decylamine and dimethyl decylamine. Preferred aryl amides are, for example, mercaptoaniline and 2'chloroindolyl I50I07.doc • 50· 201109321 Aniline. Preferred alkyl esters are, for example, methyl esters, ethyl esters, propyl esters, isopropyl esters, butyl esters, isobutyl esters, pentyl esters, isoheptyl groups (1) methyl groups. Hexyl) ester or isooctyl (2-ethylhexyl) ester. Preferred Ci_C4_alkoxy_q-C4-alkyl ester is a linear or branched Ci_C4_alkoxyethyl ester such as methoxyethyl ester, ethoxyethyl ester or butoxy B Base ester. An example of a linear or branched chain CrCM-homothioester is ethylthioester. According to a preferred embodiment of the invention, the composition comprises at least one, preferably exactly one, herbicide B as herbicidal active compound B or component B. According to another preferred embodiment of the invention, the composition comprises at least two, preferably exactly two, different herbicides B as herbicidal active compound B or component B. According to another preferred embodiment of the invention, the composition comprises at least three, preferably exactly three, different herbicides B as herbicidal active compound B or component b. According to another preferred embodiment of the invention, the composition comprises at least one, preferably exactly one, safe agent C as the protective component C. According to another preferred embodiment of the invention, the composition comprises at least one, preferably exactly one herbicide; 5 as component B, and at least one, preferably just one safener C. According to another preferred embodiment of the present invention, the composition comprises preferably two herbicides B which are different from each other as component b, and to. _ 夕檀檀檀檀。。。。。。。。。。。。。。。。。。。。。。。。。 According to another preferred embodiment of the present invention, the composition comprises at least three, preferably exactly three, different herbicides B as components B' 150l07.doc • 51 - 201109321 one less, preferably just one safener c . According to another preferred embodiment of the present invention, the composition comprises at least - preferably, preferably, a Si, a preferred benzoxanthene compound as 71 A and at least one, preferably just one herbicide B. Component B. According to another preferred embodiment of the present invention, the composition comprises at least one, preferably exactly one, of the formula 1, the preferred formula, and the ketone compound, and the wound A, and at least two, preferably Two kinds of weeding B different from each other are used as component B. According to another preferred embodiment of the present invention, the composition comprises at least a kind of benzoxanthene compound of the formula M, preferably M, and - and at least three, preferably at least Three kinds of weeding B different from each other are used as component B. According to another preferred embodiment of the present invention, the composition comprises only at least ~, preferably just one of the formulas of the formula 化合物1, and at least one, preferably just one type of weeding The oxime is used as an active ingredient. According to another preferred embodiment of the present invention, the composition comprises only at least ~, preferably just one, of the benzo-phase compound of the preferred formula 1.1; and > two preferably two Different herbicides β are used as components. According to another preferred embodiment of the present invention, the composition comprises only at least one, preferably just one, of the formula L1, and at least three, preferably exactly three, of each other. Different herbicides β are used as components. According to another preferred embodiment of the present invention, the composition comprises only at least ～150107.doc •52-201109321 佳佳好-type ϊ, the preferred formula L1 benzoxanthone compound, / species, dispute It is just a safe agent c as an active ingredient. According to another preferred embodiment of the present invention, the composition comprises only at least one of the compounds of the formula (1), the compound of the formula (1), the seed, preferably the herbicide B, and at least One, preferably just one, safe agent C is used as the active ingredient. In a preferred embodiment, the composition comprises only at least one I car, preferably a good type I, a benzoindene compound of the preferred formula J1, two to y, preferably two Different herbicides B and at least one preferably have just one safener c as the active component. According to another preferred embodiment of the present invention, the composition comprises only at least one benzoxanthone compound, preferably > There are exactly two different herbicides B and at least one preferably just one safener C as the active component. The first preferred embodiment of the present invention relates to the composition of the present invention, which comprises, in addition to the benzo-3-po ketone compound of the formula I, especially from [I", 1.2 1, m L3'l, 1_3.2 and Ι_4· In addition to the active compound of the group, it comprises at least one and in particular one of the herbicidal active compounds from the group of b丨), in particular selected from the group consisting of: clodinafop, Cycloheximide, cyhalofoprin, Ethyl oxazolamide, oxazolin, benzophenone, chlorpyrifos, triterpenoids, pentofuran, benzathine, chlorpyrifos and wild wheat. A second preferred embodiment of the invention relates to a composition of the invention, which comprises, in addition to the benzoic acid of formula I, a ketone compound, especially from U 1, Γ 21, J 2 2, L3_l, 1.3.2 and 1.4. In addition to the active compound of the group, it also comprises at least 150107.doc -53·201109321 one and especially one of the herbicidal active compounds from the group b2), in particular selected from the group consisting of bensulfuron-methyl, double Sodium oxalate, cyclatile, sulfasalazine, oxaflufenamide, flurazine-methyl-sodium, s urethane huanglong, methoxy-grass, methyl imazeth, According to the herb, the taste of saliva I acid, the oxazolidine acid, the acesulfame acesulfuron, sulfuron-methyl, methyl disulfuron, diether gas pyrazosulfuron, nicosulfuron , penoxsulam, propane-steel-steel, ethyl acesulfame, methoxyxantamine, jade granules, granules, methyl thiazide, and trifluoromethanesulfuron. A second preferred embodiment of the present invention relates to a composition of the present invention which comprises, in addition to 1, a benzoxanthone compound, especially from 1.1.1, Ι.2.Ϊ, 二:. In addition to the active compounds of the group consisting of 〗, 亦, -, and especially just one from b3), specifically selected from the following: herbicidal active compounds in the group: chlorpyrifos, allah Special_, Diuron, Fucaolong, Huanxian, Isoproturon, Lilong, ketone, Cao Cao Cao fast two salt (four), weeding, decoction and H, the fourth comparison of the present invention A preferred embodiment relates to a composition of the present invention, a benzoxanthone compound, especially an active compound of the group consisting of LU, Shan ' 1.3.1 ' 1.3.2 and L4 ′, _includes to, And especially one kind of herbicidal active compound from the group b4), specifically selected from: ^ group: propane azate, phloem, ruthenium amine and [called gas _4 • gas · 5 ·("基_6_Trifluoromethyl 2,4·-(tetra)yl_1,2'3,4.tetrahydro(tetra)+enoxy]H-oxygen ^ ^S^SKCAS 353292-31.6; s. 31 〇〇) o gas base] A fifth preferred embodiment of the invention relates to a composition of the invention, which comprises a benzoxanthone compound of the formula 150107.doc-54-201109321 1, especially from 1.1.1 L2", L2.2' t·1, L3·2 and U In addition to the active compound of the group of 1 constituents, it also comprises at least one species and, in particular, the species from the group of b5), in particular selected from the group consisting of the following herbicidal active compounds: extrinsic, fluramide, fluorine _, iso% ° oxaloin, methyl 4-oxaketone K valeramine, oxaloquinone, fluorenone, terboliptam, bismuth bismuth, chlorpyrifos and oxacilon. A sixth preferred embodiment of the invention relates to a composition of the invention in addition to the benzoxanthone compound of formula 1, especially from IU, m,;:2.2, 1'3'1, 1.3.2 and 1.4 In addition to the active compound of the group consisting of at least one species and especially one from the group b6), in particular selected from the group consisting of glyphosate, glyphosate-isopropylammonium and glyphosate-trimethylsulfonium salt A herbicidal active compound of the group consisting of (oxathione). A seventh preferred embodiment of the present invention relates to a composition of the present invention, which comprises a benzofluoranthene compound of the formula I, especially from J 1 1 , ^ 2 1 , I 2 2, 3·1, In addition to the active compounds of the group consisting of 1.3.2 and 1.4.1, it also comprises at least one species, and in particular one from the group b7), in particular selected from the group consisting of glufosinate, glufosinate-P and glufosinate. Herbicidally active compounds. An eighth preferred embodiment of the invention relates to a composition of the invention, which comprises a benzoxanthone compound of formula I, especially from j 丨 1, 2 21, ! 2 2. In addition to the active compounds of the group consisting of J.3'1, 1.3.2 and I.4.1, it also contains at least one species, and in particular one from the group b9), specifically selected from the group consisting of Schmidt and Samflin. Herbicidally active compound. A ninth preferred embodiment of the present invention relates to a composition of the present invention, which comprises a benzoxanthene compound of the formula I, especially from 丨1, j2.1, 〖2 2, 150l07.doc-55-201109321 1.3 In addition to the active compounds of the group consisting of 1.1, 1.3.2 and 1.4.1, it also comprises at least one and especially just one species derived from blG), in particular selected from the group consisting of herbicidal active compounds: acetochlor (4) Amine, dimethenamid, tetrahydroquinone, oxalic acid, fentanyl, mesalamine, modoc, S_momoda and fenocin. (d) Preferably, the composition is a compound of the formula I, except for the group consisting of 笨, Μ丨, Μ, 1.3.1, 1.3.2 and 1.4.1. In addition to the active compound, it also comprises at least one, and in particular preferably, a herbicidal active compound from the group _), in particular selected from the group consisting of the compounds of the decimal (tetra) compound of the formula -9 as defined above. A tenth preferred embodiment of the present invention relates to the composition of the present invention, i, except for the benzoxanthone compound of the formula 1, in particular from the active compound of the group consisting of u", mm 1.3.2 and 1.4.1, Also included are at least one and especially three good species of the active compound from the class of bu), in particular, isoxachlor. The tenth preferred embodiment of the present invention relates to a composition of the present invention, a benzoxanthone compound of the present invention, especially from the group consisting of: y, yam, 1.2.2, ^, [3.2 and 14" In addition to the active compound of the group, it also comprises at least one and in particular one of the herbicidal active compounds from the group bl3), in particular selected from the group consisting of 2,4-D and its salts and vinegar, chlorine and its salts (Examples of 〇〇 'chloramine 0 than bite acid-volume (2-propyl) ammonium and its bismuth (four) and its salts and §, dicamba and its salts and vinegar, gas to chlorine ratio, - wind (four) acid, gas a twelfth preferred embodiment of the present invention relates to a composition of the present invention, which comprises, in addition to 150107.doc • 56·201109321 formula, a stupid and ketamine compound, especially In addition to the active compound of the group consisting of tai^, 1.2.2 I·3.1, 1.3.2 and I·4.1, it is also packaged to >, and especially one of the classes from bl4), specifically selected from two A herbicidal active compound of the group consisting of flupiron and diflupiron-sodium. A thirteenth preferred embodiment of the invention relates to a composition of the invention, which comprises a benzoxanthone compound of formula I, especially from: 丨丨^〗 2 i, 1.2.2, 1.3.1, And in addition to the active compound of the group consisting of at least one and especially one of the classes from bl5), in particular selected from the group consisting of chlorpyrifos (= vanilla), grass _, 茚兹弗兰, 转安安A herbicidal active compound of the group consisting of trisalin. A fourteenth preferred embodiment of the present invention relates to a composition of the present invention, which comprises a benzoxanthene compound of the formula I, especially from 丨", ι2", Ι·2·2, Ι, 3-1 In addition to the active compounds of the group consisting of 1.3.2 and Ι4.1, it is also included in the herbicides, in particular from a safener c, in particular a herbicidal active compound selected from the group consisting of: herbicides, detoxification啥, 草醯醯醯、、、、、、、、、、、、、、、、、、、、、醯醯醯醯醯醯醯醯醯醯醯醯醯醯醯醯醯醯解解解解解解Miscellaneous _4_aza snail (MON466〇, CAS 71526·〇7 3) and 2,2,5 trimethyl smear (dichloroethinyl)-1,3_ „ sit bite (R_29148, cas 52836_3ι·4). Other preferred embodiments relate to a binary composition corresponding to the embodiments] to 14 and additionally comprising (particularly) a safener selected from the group consisting of: a turmeric, Detoxification, chlorpyrifos, guanidin, dichloropropene, chlorpyrifos, turfgrass, turfgrass, sitting, benzophenone, acid, sputum, 4 (dichloroethane) Oxygen_4•nitrogen Miscellaneous snail [45] 癸 Hyun (10) (10) Yang 150J07.doc • 57- 201109321 CAS 71526-07-3) and 2,2,5-trimethyl -3- (dichloroethyl fluorenyl)-1,3- oxazole Acridine (R-29148, CAS 52836-31-4). The term "binary composition" as used herein and hereinafter includes one or more (eg, one, two or three) active compounds of formula I and one or A plurality (for example, 1, 2 or 3) of herbicide B or a combination of one or more safeners. Correspondingly, the term 'ternary composition' includes one or more (eg, 1, 2 or 3) active compounds of formula I, one or more (eg, 1, 2 or 3) herbicides B. And a composition of one or more (eg, !, 2 or 3) safeners C. In a composition comprising at least one compound of the formula I as component A and at least one herbicide B, the weight ratio of active compound A:B is usually in the range from 1:1 1000 to 1000:1, preferably in 1 : 5 〇〇 to 5 〇〇: 1 range, specifically in the range of 1:250 to 250:1 and particularly preferably in the range of i: 75 to 75:1. In the composition comprising at least one compound of the formula I as component A and at least one safener C, the weight ratio of active compound A: C is usually in the range from ι: ι to 1000: 1, preferably 1 : 5〇〇 to 500:1, in particular in the range of 1.250 to 250:1 and particularly preferably in the range of 1:75 to 75:1. In a ternary composition comprising at least one benzoxanthone compound of formula I as component A, at least one herbicide B and at least one safener c, the relative weight ratio of component A:B is usually in 丨:丨〇〇〇至丨〇〇〇:], preferably in the range of 1:500 to 500:1, specifically in the range of 1:25〇 to 25〇:1 and especially preferably 1:75 to 75 Within the range of 1:1, the weight ratio of component a:c is usually in the range of 1:1000 to 1000:1, preferably in the range of i:500 to 5〇〇:1, especially in the range of 1:250 to 250. Within the range of 1:1 and particularly preferably in the range of 1:75 to 75:1 150107.doc -58 - 201109321, and the weight ratio of component B:C is usually in the range of 1:1000 to 1000:1, preferably 1 : in the range of 500 to 500:1, in particular in the range of 1:250 to 250:1 and particularly preferably in the range of 1:75 to 75:1. The weight of component A + B and component C is preferably in the range of 1:500 to 500:1, in particular in the range of 1:250 to 250:1 and particularly preferably in the range of 1:75 to 75:1. . Particularly preferred herbicide B is a herbicide B as defined above, in particular the herbicides Bl-B.139 listed in Table B below: Table B: Herbicide B B.1 Ches ketone B.2 acetylacetoate B.3 Ring-killing grass B.4 Cyhalofop-butyl ester B.5 Refined ethyl oxazoline and grass extract B.6 No. 11.醯草amine B.7 °坐琳草西purpose B.8 Cyclopentanone B.9 chlorpyrifos B.10 得草草 B.11 dimethylidene B.12 pentazin B.13 ethoxy Furose Yellow B.14 Grass Enemy B.15 Benzodan B.16 Herbicide B.17 Wild Mai B.18 Benzylphenidate B.19 Sodium Bisporin B.20 Chlorosulfonate B .21 qi jilong B.22 sulfuron-methyl B.23 sulfonate herbicide B B.24 chlorsulfuron B.25 diflufenacil B.26 sulfometrimine B.27 fluorine bite Mouth performance - methyl - nano B.28 methotrexate B.29 imazamox B.30 methyl imazeth B.31 依草草 B.32 »米坐啥琳酸 B.33 Imidazolium nicotinate B.34 Essence B.35 Iodosulfuron-methyl-sodium B.36 sulfhydryl disulfuron B.37 diether chlorine ° ° 密隆 B.38 metsulfuron B.39 sulfazolamide Amine B.40.密真隆B.41 pentafluoro chlorfenide B.42 propyl stupid Lunda B.43 ethyl carbaryl B.44 pyrimidine valerate B.45 cyclic ester grass B.46 oxime oxalic acid 150107 .doc -59- 201109321 Herbicide B B.47 Nisulfuron-methyl B.48 Sulfasulfuron-methyl B.49 Mercapto-thiene Carbene B.50 Thiasulfuron B.51 Bensulfuron B.52 Trifluoromethane Sulfuric acid B.53 chlorpyrifos B.54 Alat plough B.55 Bentazon B.56 bromoxynil B.57 diuron B.58 oxacilon B.59 cyclamate B.60 isoproturon B.61 利谷隆 B.62 Benzene ketone B.63 Phytosin B.64 Herbicin B.65 Grass deficiency B.66 Caojingjin B.67 Desiccated B.68 Acid salt B.69 Yaxifen B.70 flupropionate B.71 oxazolone-ethyl B.72 propargyl flufenacetate B.73 flurene sulphate B.74 propyne oxalicone B.75 Fulufen B.76 pyrimidine ether B.77 mesochloramide B.78 [3-[2- gas-4-fluoro-5-(1-mercapto-6-trifluoromethyl- Ethyl 2,4-di-oxy-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-«pyridyloxy]acetate (CAS 353292-31-6) B.79 benzobiscycloketone

除草劑B B.80 可滅蹤 B.81 氟草胺 B.82 氟B各草酮 B.83 異崎〇坐草酮 B.84 甲基磺草酮 B.85 達草滅 B.86 氟°比醯草胺 B.87 磺草酮 B.88 糖酮 B.89 特博酮 B.90 特帕米膝 B.91 雙環"比酮 B.92 殺草強 B.93 伏草隆 B.94 草甘膦 B.95 草甘膦-異丙基銨 B.96 草甘膦-三曱基硫鹽（草硫膦） B.97 草丁膦 B.98 草丁膦-Ρ B.99 草銨膦 B.100 施德圃 B.101 三福林 B.102 乙草胺 B.103 丁基拉草 B.104 唑草胺 B.105 精二曱吩草胺 B.106 四<7坐酮 B.107 氟草胺 B.108 滅芬草 B.109 滅草胺 13.110 莫多草 B.lll S-莫多草 B.112 普拉草 B.113 芬諾克殺草颯 B.114 異α号草胺 B.115 2,4-D 150107.doc -60- 201109321 除草劑B B.116 氯胺吡啶酸 B.117 二氣吡啶酸 B.118 麥草畏 B.119 氟氯比 B.120 MCPA B.121 二氯喹淋酸 B.122 氣曱σ奎琳酸 B.123 環丙嘧啶酸 B.124 二氟吡隆 B.125 二氟吡隆-鈉 B.126 殺草隆 B.127 草酮 B.128 茚茲弗蘭除草劑Β Β.129 去稗安 Β.130 三氟草胺 Β.131 II. 1 Β.132 ΙΙ.2 Β.133 ΙΙ.3 Β.134 ΙΙ.4 Β.135 ΙΙ.5 Β.136 ΙΙ.6 Β.137 ΙΙ.7 Β.138 ΙΙ.8 Β.139 ΙΙ.9 尤佳之安全劑c(其作為組份c係本發明組合物之成份）係如上文所定義之安全劑C、尤其下表C中所列舉之安全劑 C.l- C.11 ：Herbicide B B.80 can be traced B.81 Fluramide B.82 Fluorine B oxaloacetone B.83 Isozepva oxalicone B.84 Mesotrione B.85 Dacaoca B.86 Fluoride ° 醯胺 B B.87 sulcotrione B.88 ketone B.89 TB ketone B.90 Tepami knee B.91 double ring " ketone B.92 kill grass strong B.93 voltazone B .94 glyphosate B.95 glyphosate-isopropylammonium B.96 glyphosate-trimethylsulfuric acid (oxaphosphin) B.97 glufosinate B.98 glufosinate-Ρ B.99 Glufosinate B.100 Scheider B.101 Sanforin B.102 Acetochlor B.103 Butyloxacilz B.104 Azuramide B.105 Dimensed diamylamine B.106 Four <7 ketone B.107 Fluroxychlor B.108 Mifendris B.109 Metochlor 13.110 Moduo grass B.lll S-Modo grass B.112 Pula grass B.113 Fennox herbicide B.114 iso α Acetochlor B.115 2,4-D 150107.doc -60- 201109321 Herbicides B B.116 chlorpyridinic acid B.117 Dihydropyridine acid B.118 dicamba B.119 chlorofluorocarbon ratio B.120 MCPA B.121 Dichloroquinoline B.122 gas 曱奎奎酸 B. 123 Cyclopropyl pyrimidine B.124 diflupiron B.125 diflupiron-sodium B.126 chlorpyrifos B.127 oxatone B.128 Zfran herbicide Β Β.129 to 稗安Β.130 trifluoxetine Β.131 II. 1 Β.132 ΙΙ.2 Β.133 ΙΙ.3 Β.134 ΙΙ.4 Β.135 ΙΙ.5 Β .136 ΙΙ.6 Β.137 ΙΙ.7 Β.138 ΙΙ.8 Β.139 ΙΙ.9 优佳的安全剂c (which as component c is a component of the composition of the invention) is as defined above. Agent C, especially the safener Cl-C.11 listed in Table C below:

表C 安全劑c C.1 解草酮 C.2 解毒喹 C.3 解草磺醯胺 C.4 二氣丙稀胺 C.5 解草啶 C.6 解草唑 C.7 解草σ号唑 C.8 雙苯σ号唑酸 C.9 °比°坐解草酉旨 C.10 4-(二氣乙醯基)-1-氧雜-4-氮雜螺[4.5]癸烷(ΜΟΝ4660, CAS 71526-07-3) C.11 2,2,5-三甲基-3-(二氣乙醯基)·1,3-口号唑啶(R-29148, CAS 52836-31-4) 下文所提及較佳混合物中個別組份之重量比在上述限值内、尤其在較佳限值内。尤佳者係如下所述之組合物，包含所定義之苯并呤畊酮化合物及表1之相應列中所定 150107.doc -61 - 201109321 義之物質；尤佳地’僅包浙·令 ^ 3所疋義之笨并呤畊酮化合物及表1之相應列中所定義之物質作為除草活性化合物；最佳地，僅包含所定義之笨并嘮畊酮化合物及表1之相應列中所定義之物質作為活性化合物。尤佳者係組合物1.1至1.1668，其包含苯并嘮畊酮化合物 1.1 · 1及表1之相應列中所定義之物質：表1(組合物1.1至1.1668): 化合物除草安全編號劑Β 劑c 1.1 Β.1 1.2 Γβ.2 -- 1.3 Β.3 -· 1.4 hB.4 — 1.5 B.5 1.6 B.6 — 1.7 B.7 _ 1.8 B.8 —— 1.9 B.9 __ 1.10 B.10 ·· 1.11 B.ll ·_ 1.12 B.12 __ 1.13 B.13 __ 1.14 B.14 1.15 B.15 __ 1.16 B.16 ·· 1.17 B.17 ·· 1.18 B.18 ·_ 1.19 B.19 · 1.20 B.20 1 ·· 1.21 B.21 —· 1.22 B.22 · 1.23 B.23 · 1.24 B.24 ·· 1.25 B.25 — 化合物除草安全编號劑Β 劑C 1.26 Β.26 1.27 Β.27 1.28 Β.28 ~ 1.29 Γβ.29 偷· 1.30 Β.30 __ 1.31 Β.31 ·· 1.32 [Β_32 · 1.33 Β.33 1.34 Β.34 1.35 Β.35 __ 1.36 Β.36 1.37 Β.37 ·· 1.38 Β.38 零· 1.39 Β.39 1.40 Β.40—~ 1.41 Β.41 ·· 1.42 Β.42 1.43 Β.43~~ 1.44 Β.44 · 1.45 1 ΒΑ5~~ · 1.46 Β.46 擎一 1.47 Β‘47 ·· 1.48 Β.48 ·· 1.49 Β.49~~ · 1.50 Β.50 — 化合物編號除草劑B Γ^全劑C 1.51 B.51 -· 1.52 B.52 ·· 1.53 B.53 1.54 B.54 ·· 1.55 B.55 ·— 1.56 B.56 1.57 B.57 — 1.58 B.58. —— 1.59 B.59 — 1.60 B.60 -- 1.61 B.61 — 1.62 B.62 ·_ 1.63 B.63 — 1.64 B.64 __ 1.65 B.65 -- 1.66 B.66 — 1.67 B.67 __ 1.68 B.68 爾 1.69 B.69 1.70 B.70 _ 1.71 B.71 __ 1.72 B.72 ·— 1.73 B.73 — 1.74 B.74 ·· 1.75 B.75 — 150107.doc •62· 201109321 化合物除草安全編號劑B 劑C 1.76 B.76 — 1.77 B.77 — 1.78 B.78 — 1.79. B.79 —— 1.80 B.80 — 1.81 B.81 —— 1.82 B.82 — 1.83 B.83 — 1.84 B.84 — 1.85 B.85 — 1.86 B.86 — 1.87 B.87 — 1.88 B.88 — 1.89 B.89 — 1.90 B.90 — 1.91 B.91 — 1.92 B.92 — 1.93 B.93 — 1.94 B.94 — 1.95 B.95 — 1.96 B.96 — 1.97 B.97 — 1.98 B.98 — 1.99 B.99 — 1.100 B.100 — 1.101 B.101 — 1.102 B.102 — 1.103 B.103 — 1.104 B.104 — 1.105 B.105 -- 1.106 B.106 — 1.107 B.107 — 1.108 B.108 — 1.109 B.109 — 1.110 B.110 — 1.111 B.111 — 1.112 B.112 — 1.113 B.113 — 1.114 B.114 — 1.115 B.115 — 1.116 B.116 — 化合物編號除草劑B 安全劑C 1.117 B.117 — 1.118 B.118 -- 1.119 B.119 1.120 B.120 — 1.121 B.121 — 1.122 B.122 — 1.123 B.123 —- 1.124 B.124 — 1.125 B.125 1.126 B.126 1.127 B.127 -- 1.128 B.128 1.129 B.129 -- 1.130 B.130 —— 1.131 B.131 — 1.132 B.132 -- 1.133 B.133 1.134 B.134 1.135 B.135 -- 1.136 B.136 — 1.137 B.137 — 1.138 B.138 1.139 B.139 -- 1.140 B.1 C.1 1.141 B.2 C.1 1.142 B.3 C.1 1.143 B.4 C.1 1.144 B.5 C.1 1.145 B.6 C.1 1.146 B.7 C.1 1.147 B.8 C.1 1.148 B.9 C.1 1.149 B.10 C.1 1.150 B.11 C.1 1.151 B.12 C.1 1.152 B.13 C.1 1.153 B.14 C.1 1.154 B.15 C.1 1.155 B.16 C.1 1.156 B.17 C.1 1.157 B.18 C.1 化合物編號除草劑B 安全劑C 1.158 B.19 C.1 1.159 B.20 C.1 1.160 B.21 C.1 1.161 B.22 C.1 1.162 B.23 C.1 1.163 B.24 C.1 1.164 B.25 C.1 1.165 B.26 C.1 1.166 B.27 C.1 1.167 B.28 C.1 1.168 B.29 C.1 1.169 B.30 C.1 1.170 B.31 C.1 1.171 B.32 C.1 1.172 B.33 C.1 1.173 B.34 C.1 1.174 B.35 C.1 1.175 B.36 C.1 1.176 B.37 C.1 1.177 B.38 C.1 1.178 B.39 C.1 1.179 B.40 C.1 1.180 B.41 C.1 1.181 B.42 C.1 1.182 B.43 C.1 1.183 B.44 C.1 1.184 B.45 C.1 1.185 B.46 C.1 1.186 B.47 C.1 1.187 B.48 C.1 1.188 B.49 C.1 1.189 B.50 C.1 1.190 B.51 C.1 1.191 B.52 C.1 1.192 B.53 C.1 1.193 B.54 C.1 1.194 B.55 C.1 1.195 B.56 C.1 1.196 B.57 C.1 1.197 B.58. C.1 1.198 B.59 C.1 150107.doc -63- 201109321 化合物編號除草劑B 安全劑C 1.199 B.60 C.1 1.200 B.61 C.1 1.201 0.62 C.1 1.202 B.63 C.1 1.203 B.64 C.1 1.204 B.65 C.1 1.205 B.66 C.1 1.206 B.67 C.1 1.207 B.68 C.1 1.208 B.69 C.1 1.209 B.70 C.1 1.210 B.71 C.1 1.211 B.72 C.1 1.212 B.73 C.1 1.213 B.74 C.1 1.214 B.75 C.1 1.215 B.76 C.1 1.216 B.77 C.1 1.217 B.78 C.1 1.218 B.79 C.1 1.219 B.80 C.1 1.220 B.81 C.1 1.221 B.82 C.1 1.222 B.83 C.1 1.223 B.84 C.1 1.224 B.85 C.1 1.225 B.86 C.1 1.226 B.87 C.1 1.227 B.88 C.1 1.228 B.89 C.1 1.229 B.90 C.1 1.230 B.91 C.1 1.231 B.92 C.1 1.232 B.93 C.1 1.233 B.94 C.1 1.234 B.95 C.1 1.235 B.96 C.1 1.236 B.97 C.1 1.237 B.98 C.1 1.238 B.99 C.1 1.239 B.100 C.1 化合物編號除草劑B 安全劑C 1.240 B.101 C.1 1.241 B.102 C.1 1.242 B.103 C.1 1.243 B.104 C.1 1.244 B.105 C.1 1.245 B.106 C.1 1.246 B.107 C.1 1.247 B.108 C.1 1.248 B.109 C.1 1.249 B.110 C.1 1.250 B.111 C.1 1.251 B.112 C.1 1.252 B.113 C.1 1.253 B.114 C.1 1.254 B.115 C.1 1.255 B.116 C.1 1.256 B.117 C.1 1.257 B.118 C.1 1.258 B.119 C.1 1.259 B.120 C.1 1.260 B.121 C.1 1.261 B.122 C.1 1.262 B.123 C.1 1.263 B.124 C.1 1.264 B.125 C.1 1.265 B.126 C.1 1.266 B.127 C.1 1.267 B.128 C.1 1.268 B.129 C.1 1.269 B.130 C.1 1.270 B.131 C.1 1.271 B.132 C.1 1.272 B.133 C.1 1.273 B.134 C.1 1.274 B.135 C.1 1.275 B.136 C.1 1.276 B.137 C.1 1.277 B.138 C.1 1.278 B.139 C.1 1.279 B.1 C.2 1.280 B.2 C.2 化合物編號除草劑B 安全劑C 1.281 B.3 C.2 1.282 B.4 C.2 1.283 B.5 C.2 1.284 B.6 C.2 1.285 B.7 C.2 1.286 B.8 C.2 1.287 B.9 C.2 1.288 B.10 C.2 1.289 B.11 C.2 1.290 B.12 C.2 1.291 B.13 C.2 1.292 B.14 C.2 1.293 B.15 C.2 1.294 B.16 C.2 1.295 B.17 C.2 1.296 B.18 C.2 1.297 B.19 C.2 1.298 B.20 C.2 1.299 B.21 C.2 1.300 B.22 C.2 1.301 B.23 C.2 1.302 B.24 C.2 1.303 B.25 C.2 1.304 B.26 C.2 1.305 B.27 C.2 1.306 B.28 C.2 1.307 B.29 C.2 1.308 B.30 C.2 1.309 B.31 C.2 1.310 B.32 C.2 1.311 B.33 C.2 1.312 B.34 C.2 1.313 B.35 C.2 1.314 B.36 C.2 1.315 B.37 C.2 1.316 B.38 C.2 1.317 B.39 C.2 1.318 B.40 C.2 1.319 B.41 C.2 1.320 B.42 C.2 1.321 B.43 C.2 150107.doc -64- 201109321 化合物編號除草劑B 安全劑C 1.322 B.44 C.2 1.323 B.45 C.2 1.324 B.46 C.2 1.325 B.47 C.2 1.326 B.48 C.2 1.327 B.49 C.2 1.328 B.50 C.2 1.329 B.51 C.2 1.330 B.52 C.2 1.331 B.53 C.2 1.332 B.54 C.2 1.333 B.55 C.2 1.334 B.56 C.2 1.335 B.57 C.2 1.336 B.58. C.2 1.337 B.59 C.2 1.338 B.60 C.2 1.339 B.61 C.2 1.340 B.62 C.2 1.341 B.63 C.2 1.342 B.64 C.2 1.343 B.65 C.2 1.344 B.66 C.2 1.345 B.67 C.2 1.346 B.68 C.2 1.347 B.69 C.2 1.348 B.70 C.2 1.349 B.71 C.2 1.350 B.72 C.2 1.351 B.73 C.2 1.352 B.74 C.2 1.353 B.75 C.2 1.354 B.76 C.2 1.355 B.77 C.2 1.356 B.78 C.2 1.357 B.79 C.2 1.358 B.80 C.2 1.359 B.81 C.2 1.360 B.82 C.2 1.361 B.83 C.2 1.362 B.84 C.2 化合物編號除草劑B 安全劑C 1.363 B.85 C.2 1.364 B.86 C.2 1.365 B.87 C.2 1.366 B.88 C.2 1.367 B.89 C.2 1.368 B.90 C.2 1.369 B.91 C.2 1.370 B.92 C.2 1.371 B.93 C.2 1.372 B.94 C.2 1.373 B.95 C.2 1.374 B.96 C.2 1.375 B.97 C.2 1.376 B.98 C.2 1.377 B.99 C.2 1.378 B.100 C.2 1.379 B.101 C.2 1.380 B.102 C.2 1.381 B.103 C.2 1.382 B.104 C.2 1.383 B.105 C.2 1.384 B.106 C.2 1.385 B.107 C.2 1.386 B.108 C.2 1.387 B.109 C.2 1.388 B.110 C.2 1.389 B.111 C.2 1.390 B.112 C.2 1.391 B.113 C.2 1.392 B.114 C.2 1.393 B.115 C.2 1.394 B.116 C.2 1.395 B.117 C.2 1.396 B.118 C.2 1.397 B.119 C.2 1.398 B.120 C.2 1.399 B.121 C.2 1.400 B.122 C.2 1.401 B.123 C.2 1.402 B.124 C.2 1.403 B.125 C.2 化合物編號除草劑B 安全劑C 1.404 B.126 C.2 1.405 B.127 C.2 1.406 B.128 C.2 1.407 B.129 C.2 1.408 B.130 C.2 1.409 B.131 C.2 1.410 B.132 C.2 1.411 B.133 C.2 1.412 B.134 C.2 1.413 B.135 C.2 1.414 B.136 C.2 1.415 B.137 C.2 1.416 B.138 C.2 1.417 B.139 C.2 1.418 B.1 C.3 1.419 B.2 C.3 1.420 B.3 C.3 1.421 B.4 C.3 1.422 B.5 C.3 1.423 B.6 C.3 1.424 B.7 C.3 1.425 B.8 C.3 1.426 B.9 C.3 1.427 B.10 C.3 1.428 B.11 C.3 1.429 B.12 C.3 1.430 B.13 C.3 1.431 B.14 C.3 1.432 B.15 C.3 1.433 B.16 C.3 1.434 B.17 C.3 1.435 B.18 C.3 1.436 B.19 C.3 1.437 B.20 C.3 1.438 B.21 C.3 1.439 B.22 C.3 1.440 B.23 C.3 1.441 B.24 C.3 1.442 B.25 C.3 1.443 B.26 C.3 1.444 B.27 C.3 150107.doc -65- 201109321 化合物編號除草劑B 安全劑C 1.445 B.28 C.3 1.446 B.29 C.3 1.447 B.30 C.3 1.448 B.31 C.3 1.449 B.32 C.3 1.450 B.33 C.3 1.451 B.34 C.3 1.452 B.35 C.3 1.453 B.36 C.3 1.454 B.37 C.3 1.455 B.38 C.3 1.456 B.39 C.3 1.457 B.40 C.3 1.458 B.41 C.3 1.459 B.42 C.3 1.460 !Β·43 C.3 1.461 Β.44 C.3 1.462 Β.45 C.3 1.463 Β.46 C.3 1.464 Β.47 C.3 1.465 Β.48 C.3 1.466 Β.49 C.3 1.467 Β.50 C.3 1.468 Β.51 C.3 1.469 Β.52 C.3 1.470 Β.53 C.3 1.471 Β.54 C.3 1.472 Β.55 C.3 1.473 Β.56 C.3 1.474 Β.57 C.3 1.475 Β.58. C.3 1.476 Β.59 C.3 1.477 Β.60 C.3 1.478 Β.61 C.3 1.479 Β.62 C.3 1.480 Β.63 C.3 1.481 Β.64 C.3 1.482 Β.65 C.3 1.483 Β.66 C.3 1.484 Β.67 C.3 1.485 Β.68 C.3 化合物編號除草劑Β 安全劑C 1.486 Β.69 C.3 1.487 Β.70 C.3 1.488 Β.71 C.3 1.489 Β.72 C.3 1.490 Β.73 C.3 1.491 Β.74 C.3 1.492 Β.75 C.3 1.493 Β.76 C.3 1.494 Β.77 C.3 1.495 Β.78 C.3 1.496 Β.79 C.3 1.497 Β.80 C.3 1.498 Β.81 C.3 1.499 Β.82 C.3 1.500 Β.83 C.3 1.501 Β.84 C.3 1.502 Β.85 C.3 1.503 Β.86 C.3 1.504 Β.87 C.3 1.505 Β.88 C.3 1.506 Β.89 C.3 1.507 Β.90 C.3 1.508 Β.91 C.3 1.509 Β.92 C.3 1.510 Β.93 C.3 1.511 Β.94 C.3 1.512 Β.95 C.3 1.513 Β.96 C.3 1.514 Β.97 C.3 1.515 Β.98 C.3 1.516 Β.99 C.3 1.517 Β.100 C.3 1.518 Β.101 C.3 1.519 Β.102 C.3 1.520 Β.103 C.3 1.521 Β.104 C.3 1.522 Β.105 C.3 1.523 Β.106 C.3 1.524 Β.107 C.3 1.525 Β.108 C.3 1.526 Β.109 C.3 化合物編號除草劑Β 安全劑C 1.527 Β.110 C.3 1.528 Β.111 C.3 1.529 Β.112 C.3 1.530 Β.113 C.3 1.531 Β.114 C.3 1.532 Β.115 C.3 1.533 Β.116 C.3 1.534 Β.117 C.3 1.535 Β.118 C.3 1.536 Β.119 C.3 1.537 Β.120 C.3 1.538 Β.121 C.3 1.539 Β.122 C.3 1.540 Β.123 C.3 1.541 Β.124 C.3 1.542 Β.125 C.3 1.543 Β.126 C.3 1.544 Β.127 C.3 1.545 Β.128 C.3 1.546 Β.129 C.3 1.547 Β.130 C.3 1.548 Β.131 C.3 1.549 Β.132 C.3 1.550 Β.133 C.3 1.551 Β.134 C.3 1.552 Β.135 C.3 1.553 Β.136 C.3 1.554 Β.137 C.3 1.555 Β.138 C.3 1.556 Β.139 C.3 1.557 Β.1 C.4 1.558 Β.2 C.4 1.559 Β.3 C.4 1.560 Β.4 C.4 1.561 Β.5 C.4 1.562 Β.6 C.4 1.563 Β.7 C.4 1.564 Β.8 C.4 1.565 Β.9 C.4 1.566 Β.10 C.4 1.567 Β.11 C.4 150107.doc -66- 201109321 化合物編號除草劑B 安全劑C 1.568 B.12 C.4 1.569 B.13 C.4 1.570 B.14 C.4 1.571 B.15 C.4 1.572 B.16 C.4 1.573 B.17 C.4 1.574 B.18 C.4 1.575 B.19 C.4 1.576 B.20 C.4 1.577 B.21 C.4 1.578 B.22 C.4 1.579 B.23 C.4 1.580 B.24 C.4 1.581 B.25 C.4 1.582 B.26 C.4 1.583 B.27 C.4 1.584 B.28 C.4 1.585 B.29 C.4 1.586 B.30 C.4 1.587 B.31 C.4 1.588 B.32 C.4 1.589 B.33 C.4 1.590 B.34 C.4 1.591 B.35 C.4 1.592 B.36 C.4 1.593 B.37 C.4 1.594 B.38 C.4 1.595 B.39 C.4 1.596 B.40 C.4 1.597 B.41 C.4 1.598 B.42 C.4 1.599 B.43 C.4 1.600 B.44 C.4 1.601 B.45 C.4 1.602 B.46 C.4 1.603 B.47 C.4 1.604 B.48 C.4 1.605 B.49 C.4 1.606 B.50 C.4 1.607 B.51 C.4 1.608 B.52 C.4 化合物編號除草劑B 安全劑C 1.609 B.53 C.4 1.610 B.54 C.4 1.611 B.55 C.4 1.612 B.56 C.4 1.613 B.57 C.4 1.614 B.58. C.4 1.615 . B.59 C.4 1.616 B.60 C.4 1.617 B.61 C.4 1.618 B.62 C.4 1.619 B.63 C.4 1.620 B.64 C.4 1.621 B.65 C.4 1.622 B.66 C.4 1.623 B.67 C.4 1.624 B.68 C.4 1.625 B.69 C.4 1.626 B.70 C.4 1.627 B.71 C.4 1.628 B.72 C.4 1.629 B.73 C.4 1.630 B.74 C.4 1.631 B.75 C.4 1.632 B.76 C.4 1.633 B.77 C.4 1.634 B.78 C.4 1.635 B.79 C.4 1.636 B.80 C.4 1.637 B.81 C.4 1.638 B.82 C.4 1.639 B.83 C.4 1.640 B.84 C.4 1.641 B.85 C.4 1.642 B.86 C.4 1.643 B.87 C.4 1.644 B.88 C.4 1.645 B.89 C.4 1.646 B.90 C.4 1.647 B.91 C.4 1.648 B.92 C.4 1.649 B.93 C.4 化合物編號除草劑B 安全劑C 1.650 B.94 C.4 1.651 B.95 C.4 1.652 B.96 C.4 1.653 B.97 C.4 1.654 B.98 C.4 1.655 B.99 C.4 1.656 B.100 C.4 1.657 B.101 C.4 1.658 B.102 C.4 1.659 B.103 C.4 1.660 B.104 C.4 1.661 B.105 C.4 1.662 B.106 C.4 1.663 B.107 C.4 1.664 B.108 C.4 1.665 B.109 C.4 1.666 B.110 C.4 1.667 B.111 C.4 1.668 B.112 C.4 1.669 B.113 C.4 1.670 B.114 C.4 1.671 B.115 C.4 1.672 B.116 C.4 1.673 B.117 C.4 1.674 B.118 C.4 1.675 B.119 C.4 1.676 B.120 C.4 1.677 B.121 C.4 1.678 B.122 C.4 1.679 B.123 C.4 1.680 B.124 C.4 1.681 B.125 C.4 1.682 B.126 C.4 1.683 B.127 C.4 1.684 B.128 C.4 1.685 B.129 C.4 1.686 B.130 C.4 1.687 B.131 C.4 1.688 B.132 C.4 1.689 B.133 C.4 1.690 B.134 C.4 150107.doc -67- 201109321 化合物編號除草劑B 安全劑C 1.691 B.135 C.4 1.692 B.136 C.4 1.693 B.137 C.4 1.694 B.138 C.4 1.695 B.139 C.4 1.696 B.1 C.5 1.697 β.2 C.5 1.698 Β.3 C.5 1.699 Β.4 C.5 1.700- Β.5 C.5 1.701 Β.6 C.5 1.702 Β.7 C.5 1.703 Β.8 C.5 1.704 Β.9 C.5 1.705 Β.10 C.5 1.706 Β.11 C.5 1.707 Β.12 C.5 1.708 Β.13 C.5 1.709 Β.14 C.5 1.710 Β.15 C.5 1.711 Β.16 C.5 1.712 Β.17 C.5 1.713 Β.18 C.5 1.714 Β.19 C.5 1.715 Β.20 C.5 1.716 Β.21 C.5 1.717 Β.22 C.5 1.718 Β.23 C.5 1.719 Β.24 C.5 1.720 Β.25 C.5 1.721 Β.26 C.5 1.722 Β.27 C.5 1.723 Β.28 C.5 1.724 Β.29 C.5 1.725 Β.30 C.5 1.726 Β.31 C.5 1.727 Β.32 C.5 1.728 Β.33 C.5 1.729 Β.34 C.5 1.730 Β.35 C.5 1.731 Β.36 C.5 化合物除草安全編號劑Β 劑C 1.732 Β.37 C.5 1.733 Β.38 C.5 1.734 Β.39 C.5 1.735 Β.40 C.5 1.736 Β.41 C.5 1.737 Β.42 C.5 1.738 Β.43 C.5 1.739 Β.44 C.5 1.740 Β.45 C.5 1.741 Β.46 C.5 1.742 Β.47 C.5 1.743 Β.48 C.5 1.744 Β.49 C.5 1.745 Β.50 C.5 1.746 Β.51 C.5 1.747 Β.52 C.5 1.748 Β.53 C.5 1.749 Β.54 C.5 1.750 Β.55 C.5 1.751 Β.56 C.5 1.752 Β.57 C.5 1.753 Β.58. C.5 1.754 Β.59 C.5 1.755 Β.60 C.5 1.756 Β.61 C.5 1.757 Β.62 C.5 1.758 Β.63 C.5 1.759 Β.64 C.5 1.760 Β.65 C.5 1.761 Β.66 C.5 1.762 Β.67 C.5 1.763 Β.68 C.5 1.764 Β.69 C.5 1.765 Β.70 C.5 1.766 Β.71 C.5 1.767 Β.72 C.5 1.768 Β.73 C.5 1.769 Β.74 C.5 1.770 Β.75 C.5 1.771 Β.76 C.5 1.772 Β.77 C.5 化合物編號除草劑Β 安全劑C 1.773 Β.78 C.5 1.774 Β.79 C.5 1.775 Β.80 C.5 1.776 Β.81 C.5 1.777 Β.82 C.5 1.778 Β.83 C.5 1.779 Β.84 C.5 1.780 Β.85 C.5 1.781 Β.86 C.5 1.782 Β.87 C.5 1.783 Β.88 C.5 1.784 Β.89 C.5 1.785 Β.90 C.5 1.786 Β.91 C.5 1.787 Β.92 C.5 1.788 Β.93 C.5 1.789 Β.94 C.5 1.790 Β.95 C.5 1.791 Β.96 C.5 1.792 Β.97 C.5 1.793 Β.98 C.5 1.794 Β.99 C.5 1.795 Β.100 C.5 1.796 Β.101 C.5 1.797 Β.102 C.5 1.798 Β.103 C.5 1.799 Β.104 C.5 1.800 Β.105 C.5 1.801 Β.106 C.5 1.802 Β.107 C.5 1.803 Β.108 C.5 1.804 Β.109 C.5 1.805 Β.110 C.5 1.806 Β.111 C.5 1.807 Β.112 C.5 1.808 Β.113 C.5 1.809 Β.114 C.5 1.810 Β.115 C.5 1.811 Β.116 C.5 1.812 Β.117 C.5 1.813 Β.118 C.5 150I07.doc -68* 201109321 化合物編號除草劑B 安全劑C 1.814 B.119 C.5 1.815 B.120 C.5 1.816 B.121 C.5 1.817 B.122 C.5 1.818 B.123 C.5 1.819 B.124 C.5 1.820 B.125 C.5 1.821 B.126 C.5 1.822 B.127 C.5 1.823 B.128 C.5 1.824 B.129 C.5 1.825 B.130 C.5 1.826 B.131 C.5 1.827 B.132 C.5 1.828 B.133 C.5 1.829 B.134 C.5 1.830 B.135 C.5 1.831 B.136 C.5 1.832 B.137 C.5 1.833 B.138 C.5 1.834 B.139 C.5 1.835 B.1 C.6 1.836 B.2 C.6 1.837 B.3 C.6 1.838 B.4 C.6 1.839 B.5 C.6 1.840 B.6 C.6 1.841 B.7 C.6 1.842 B.8 C.6 1.843 B.9 C.6 1.844 B.10 C.6 1.845 B.11 C.6 1.846 B.12 C.6 1.847 B.13 C.6 1.848 B.14 C.6 1.849 B.15 C.6 1.850 B.16 C.6 1.851 B.17 C.6 1.852 B.18 C.6 1.853 B.19 C.6 1.854 B.20 C.6 化合物編號除草劑B 安全劑C 1.855 B.21 C.6 1.856 B.22 C.6 1.857 B.23 C.6 1.858 B.24 C.6 1.859 B.25 C.6 1.860 B.26 C.6 1.861 B.27 C.6 1.862 B.28 C.6 1.863 B.29 C.6 1.864 B.30 C.6 1.865 B.31 C.6 1.866 B.32 C.6 1.867 B.33 C.6 1.868 B.34 C.6 1.869 B.35 C.6 1.870 B.36 C.6 1.871 B.37 C.6 1.872 B.38 C.6 1.873 B.39 C.6 1.874 B.40 C.6 1.875 B.41 C.6 1.876 B.42 C.6 1.877 B.43 C.6 1.878 B.44 C.6 1.879 B.45 C.6 1.880 B.46 C.6 1.881 B.47 C.6 1.882 B.48 C.6 1.883 B.49 C.6 1.884 B.50 C.6 1.885 B.51 C.6 1.886 B.52 C.6 1.887 B.53 C.6 1.888 B.54 C.6 1.889 B.55 C.6 1.890 B.56 C.6 1.891 B.57 C.6 1.892 B.58. C.6 1.893 B.59 C.6 1.894 B.60 C.6 1.895 B.61 C.6 化合物編號除草劑B 安全劑C 1.896 B.62 C.6 1.897 B.63 C.6 1.898 B.64 C.6 1.899 B.65 C.6 1.900 B.66 C.6 1.901 B.67 C.6 1.902 B.68 C.6 1.903 B.69 C.6 1.904 B.70 C.6 1.905 B.71 C.6 1.906 B.72 C.6 1.907 B.73 C.6 1.908 B.74 C.6 1.909 B.75 C.6 1.910 B.76 C.6 1.911 B.77 C.6 1.912 B.78 C.6 1.913 B.79 C.6 1.914 B.80 C.6 1.915 B.81 C.6 1.916 B.82 C.6 1.917 B.83 C.6 1.918 B.84 C.6 1.919 B.85 C.6 1.920 B.86 C.6 1.921 B.87 C.6 1.922 B.88 C.6 1.923 B.89 C.6 1.924 B.90 C.6 1.925 B.91 C.6 1.926 B.92 C.6 1.927 B.93 C.6 1.928 B.94 C.6 1.929 B.95 C.6 1.930 B.96 C.6 1.931 B.97 C.6 1.932 B.98 C.6 1.933 B.99 C.6 1.934 B.100 C.6 1.935 B.101 C.6 1.936 B.102 C.6 150107.doc -69- 201109321 化合物編號除草劑B 安全劑C 1.937 B.103 C.6 1.938 B.104 C.6 1.939 B.105 C.6 1.940 B.106 C.6 1.941 B.107 C.6 1.942 B.108 C.6 1.943 B.109 C.6 1.944 B.110 C.6 1.945 B.111 C.6 1.946 B.112 C.6 1.947 B.113 C.6 1.948 B.114 C.6 1.949 B.115 C.6 1.950 B.116 C.6 1.951 B.117 C.6 1.952 B.118 C.6 1.953 B.119 C.6 1.954 B.120 C.6 1.955 B.121 C.6 1.956 B.122 C.6 1.957 B.123 C.6 1.958 B.124 C.6 1.959 B.125 C.6 1.960 B.126 C.6 1.961 B.127 C.6 1.962 B.128 C.6 1.963 B.129 C.6 1.964 B.130 C.6 1.965 B.131 C.6 1.966 B.132 C.6 1.967 B.133 C.6 1.968 B.134 C.6 1.969 B.135 C.6 1.970 B.136 C.6 1.971 B.137 C.6 1.972 B.138 C.6 1.973 B.139 C.6 1.974 B.1 C.7 1.975 B.2 C.7 1.976 B.3 C.7 1.977 B.4 C.7 化合物編號除草劑B 安全劑C 1.978 B.5 C.7 1.979 B.6 C.7 1.980 B.7 C.7 1.981 B.8 C.7 1.982 B.9 C.7 1.983 B.10 C.7 1.984 B.11 C.7 1.985 B.12 C.7 1.986 B.13 C.7 1.987 B.14 C.7 1.988 B.15 C.7 1.989 B.16 C.7 1.990 B.17 C.7 1.991 B.18 C.7 1.992 B.19 C.7 1.993 B.20 C.7 1.994 B.21 C.7 1.995 B.22 C.7 1.996 B.23 C.7 1.997 B.24 C.7 1.998 B.25 C.7 1.999 B.26 C.7 1.1000 B.27 C.7 1.1001 B.28 C.7 1.1002 B.29 C.7 1.1003 B.30 C.7 1.1004 B.31 C.7 1.1005 B.32 C.7 1.1006 B.33 C.7 1.1007 B.34 C.7 1.1008 B.35 C.7 1.1009 B.36 C.7 1.1010 B.37 C.7 1.1011 B.38 C.7 1.1012 B.39 C.7 1.1013 B.40 C.7 1.1014 B.41 C.7 1.1015 B.42 C.7 1.1016 B.43 C.7 1.1017 B.44 C.7 1.1018 B.45 C.7 化合物編號除草劑B 安全劑C 1.1019 B.46 C.7 1.1020 B.47 C.7 1.1021 B.48 C.7 1.1022 B.49 C.7 1.1023 B.50 C.7 1.1024 B.51 C.7 1.1025 B.52 C.7 1.1026 B.53 C.7 1.1027 B.54 C.7 1.1028 B.55 C.7 1.1029 B.56 C.7 1.1030 B.57 C.7 1.1031 B.58. C.7 1.1032 B.59 C.7 1.1033 B.60 C.7 1.1034 B.61 C.7 1.1035 B.62 C.7 1.1036 B.63 C.7 1.1037 B.64 C.7 1.1038 B.65 C.7 1.1039 B.66 C.7 1.1040 B.67 C.7 1.1041 B.68 C.7 1.1042 B.69 C.7 1.1043 B.70 C.7 1.1044 B.71 C.7 1.1045 B.72 C.7 1.1046 B.73 C.7 1.1047 B.74 C.7 1.1048 B.75 C.7 1.1049 B.76 C.7 1.1050 B.77 C.7 1.1051 B.78 C.7 1.1052 B.79 C.7 1.1053 B.80 C.7 1.1054 B.81 C.7 1.1055 B.82 C.7 1.1056 B.83 C.7 1.1057 B.84 C.7 1.1058 B.85 C.7 1.1059 B.86 C.7 150107.doc -70- 201109321 化合物編號除草劑B 安全劑C 1.1060 B.87 C.7 1.1061 B.88 C.7 1.1062 B.89 C.7 1.1063 B.90 C.7 1.1064 B.91 C.7 1.1065 B.92 C.7 1.1066 B.93 C.7 1.1067 B.94 C.7 1.1068 B.95 C.7 1.1069 B.96 C.7 1.1070 B.97 C.7 1.1071 B.98 C.7 1.1072 B.99 C.7 1.1073 B.100 C.7 1.1074 B.101 C.7 1.1075 B.102 C.7 1.1076 B.103 C.7 1.1077 B.104 C.7 1.1078 B.105 C.7 1.1079 B.106 C.7 1.1080 B.107 C.7 1.1081 B.108 C.7 1.1082 B.109 C.7 1.1083 B.110 C.7 1.1084 B.111 C.7 1.1085 B.112 C.7 1.1086 B.113 C.7 1.1087 B.114 C.7 1.1088 B.115 C.7 1.1089 B.116 C.7 1.1090 B.117 C.7 1.1091 B.118 C.7 1.1092 B.119 C.7 1.1093 B.120 C.7 1.1094 B.121 C.7 1.1095 B.122 C.7 1.1096 B.123 C.7 1.1097 B.124 C.7 1.1098 B.125 C.7 1.1099 B.126 C.7 1.1100 B.127 C.7 化合物編號除草劑B 安全劑C 1.1101 B.128 C.7 1.1102 B.129 C.7 1.1103 B.130 C.7 1.1104 B.131 C.7 1.1105 B.132 C.7 1.1106 B.133 C.7 1.1107 B.134 C..7 1.1108 B.135 C.7 1.1109 B.136 C.7 1.1110 B.137 C.7 1.1111 B.138 C.7 1.1112 B.139 C.7 1.1113 B.1 C.8 1.1114 B.2 C.8 1.1115 B.3 C.8 1.1116 B.4 C.8 1.1117 B.5 C.8 1.1118 B.6 C.8 1.1119 B.7 C.8 1.1120 B.8 C.8 1.1121 B.9 C.8 1.1122 B.10 C.8 1.1123 B.11 C.8 1.1124 B.12 C.8 1.1125 B.13 C.8 1.1126 B.14 C.8 1.1127 B.15 C.8 1.1128 B.16 C.8 1.1129 B.17 C.8 1.1130 B.18 C.8 1.1131 B.19 C.8 1.1132 B.20 C.8 1.1133 B.21 C.8 1.1134 B.22 C.8 1.1135 B.23 C.8 1.1136 B.24 C.8 1.1137 B.25 C.8 1.1138 B.26 C.8 1.1139 B.27 C.8 1.1140 B.28 C.8 1.1141 B.29 C.8 化合物編號除草劑B 安全劑C 1.1142 B.30 C.8 1.1143 B.31 C.8 1.1144 B.32 C.8 1.1145 B.33 C.8 1.1146 B.34 C.8 1.1147 B.35 C.8 1.1148 B.36 C.8 1.1149 B.37 C.8 1.1150 B.38 C.8 1.1151 B.39 C.8 1.1152 B.40 C.8 1.1153 B.41 C.8 1.1154 B.42 C.8 1.1155 B.43 C.8 1.1156 B.44 C.8 1.1157 B.45 C.8 1.1158 B.46 C.8 1.1159 B.47 C.8 1.1160 B.48 C.8 1.1161 B.49 C.8 1.1162 B.50 C.8 1.1163 B.51 C.8 1.1164 B.52 C.8 1.1165 B.53 C.8 1.1166 B.54 C.8 1.1167 B.55 C.8 1.1168 B.56 C.8 1.1169 B.57 C.8 1.1170 B.58. C.8 1.1171 B.59 C.8 1.1172 B.60 C.8 1.1173 B.61 C.8 1.1174 B.62 C.8 1.1175 B.63 C.8 1.1176 B.64 C.8 1.1177 B.65 C.8 1.1178 B.66 C.8 1.1179 B.67 C.8 1.1180 B.68 C.8 1.1181 B.69 C.8 1.1182 B.70 C.8 150107.doc -71 - 201109321 化合物編號除草劑Β 安全劑C 1.1183 Β.71 C.8 1.1184 Β.72 C.8 1.1185 Β.73 C.8 1.1186 Β.74 C.8 1.1187 Β.75 C.8 1.1188 Β.76 C.8 1.1189 Β.77 C.8 1.1190 Β.78 C.8 1.1191 Β.79 C.8 1.1192 Β.80 C.8 1.1193 Β.81 C.8 1.1194 Β.82 C.8 1.1195 Β.83 C.8 1.1196 Β.84 C.8 1.1197 Β.85 C.8 1.1198 Β.86 C.8 1.1199 Β.87 C.8 1.1200 Β.88 C.8 1.1201 Β.89 C.8 1.1202 Β.90 C.8 1.1203 Β.91 C.8 1.1204 Β.92 C.8 1.1205 Β.93 C.8 1.1206 Β.94 C.8 1.1207 Β.95 C.8 1.1208 Β.96 C.8 1.1209 Β.97 C.8 1.1210 Β.98 C.8 1.1211 Β.99 C.8 1.1212 Β.100 C.8 1.1213 Β.101 C.8 1.1214 Β.102 C.8 1.1215 Β.103 C.8 1.1216 Β.104 C.8 1.1217 Β.105 C.8 1.1218 Β.106 C.8 1.1219 Β.107 C.8 1.1220 Β.108 C.8 1.1221 Β.109 C.8 1.1222 Β.110 C.8 1.1223 Β.111 C.8 化合物編號除草劑Β 安全劑C 1.1224 Β.112 C.8 1.1225 Β.113 C.8 1.1226 Β.114 C.8 1.1227 Β.115 C.8 1.1228 Β.116 C.8 1.1229 Β.117 C.8 1.1230 Β.118 C.8 1.1231 Β.119 C.8 1.1232 Β.120 C.8 1.1233 Β.121 C.8 1.1234 Β.122 C.8 1.1235 Β.123 C.8 1.1236 Β.124 C.8 1.1237 Β.125 C.8 1.1238 Β.126 C.8 1.1239 Β.127 C.8 1.1240 Β.128 C.8 1.1241 Β.129 C.8 1.1242 Β.130 C.8 1.1243 Β.131 C.8 1.1244 Β.132 C.8 1.1245 Β.133 C.8 1.1246 Β.134 C.8 1.1247 Β.135 C.8 1.1248 Β.136 C.8 1.1249 Β.137 C.8 1.1250 Β.138 C.8 1.1251 Β.139 C.8 1.1252 Β.1 C.9 1.1253 Β.2 C.9 1.1254 Β.3 C.9 1.1255 Β.4 C.9 1.1256 Β.5 C.9 1.1257 Β.6 C.9 1.1258 Β.7 C.9 1.1259 Β.8 C.9 1.1260 Β.9 C.9 1.1261 Β.10 C.9 1.1262 Β.11 C.9 1.1263 Β.12 C.9 1.1264 Β.13 C.9 化合物編號除草劑Β 安全劑C 1.1265 Β.14 C.9 1.1266 Β.15 C.9 1.1267 Β.16 C.9 1.1268 Β.17 C.9 1.1269 Β.18 C.9 1.1270 Β.19 C.9 1.1271 Β.20 C.9 1.1272 Β.21 C.9 1.1273 Β.22 C.9 1.1274 Β.23 C.9 1.1275 Β.24 C.9 1.1276 Β.25 C.9 1.1277 Β.26 C.9 1.1278 Β.27 C.9 1.1279 Β.28 C.9 1.1280 Β.29 C.9 1.1281 Β.30 C.9 1.1282 Β.31 C.9 1.1283 Β.32 C.9 1.1284 Β.33 C.9 1.1285 Β.34 C.9 1.1286 Β.35 C.9 1.1287 Β.36 C.9 1.1288 Β.37 C.9 1.1289 Β.38 C.9 1.1290 Β.39 C.9 1.1291 Β.40 C.9 1.1292 Β.41 C.9 1.1293 Β.42 C.9 1.1294 Β.43 C.9 1.1295 Β.44 C.9 1.1296 Β.45 C.9 1.1297 Β.46 C.9 1.1298 Β.47 C.9 1.1299 Β.48 C.9 1.1300 Β.49 C.9 1.1301 Β.50 C.9 1.1302 Β.51 C.9 1.1303 Β.52 C.9 1.1304 Β.53 C.9 1.1305 Β.54 C.9 150107.doc ·72· 201109321 化合物編號除草劑B 安全劑C 1.1306 B.55 C.9 1.1307 B.56 C.9 1.1308 B.57 C.9 1.1309 B.58. C.9 1.1310 B.59 C.9 1.1311 B.60 C.9 1.1312 B.61 C.9 1.1313 B.62 C.9 1.1314 B.63 C.9 1.1315 B.64 C.9 1.1316 B.65 C.9 1.1317 B.66 C.9 1.1318 B.67 C.9 1.1319 B.68 C.9 1.1320 B.69 C.9 1.1321 B.70 C.9 1.1322 B.71 C.9 1.1323 B.72 C.9 1.1324 B.73 C.9 1.1325 B.74 C.9 1.1326 B.75 C.9 1.1327 B.76 C.9 1.1328 B.77 C.9 1.1329 B.78 C.9 1.1330 B.79 C.9 1.1331 B.80 C.9 1.1332 B.81 C.9 1.1333 B.82 C.9 1.1334 B.83 C.9 1.1335 B.84 C.9 1.1336 B.85 C.9 1.1337 B.86 C.9 1.1338 B.87 C.9 1.1339 B.88 C.9 1.1340 B.89 C.9 1.1341 B.90 C.9 1.1342 B.91 C.9 1.1343 B.92 C.9 1.1344 B.93 C.9 1.1345 B.94 C.9 1.1346 B.95 C.9 化合物編號除草劑B 安全劑C 1.1347 B.96 C.9 1.1348 B.97 C.9 1.1349 B.98 C.9 1.1350 B.99 C.9 1.1351 B.100 C.9 1.1352 B.101 C.9 1.1353 B.102 C.9 1.1354 B.103 C.9 1.1355 B.104 C.9 1.1356 B.105 C.9 1.1357 B.106 C.9 1.1358 B.107 C.9 1.1359 B.108 C.9 1.1360 B.109 C.9 1.1361 B.110 C.9 1.1362 B.111 C.9 1.1363 B.112 C.9 1.1364 B.113 C.9 1.1365 B.114 C.9 1.1366 B.115 C.9 1.1367 B.116 C.9 1.1368 B.117 C.9 1.1369 B.118 C.9 1.1370 B.119 C.9 1.1371 B.120 C.9 1.1372 B.121 C.9 1.1373 B.122 C.9 1.1374 B.123 C.9 1.1375 B.124 C.9 1.1376 B.125 C.9 1.1377 B.126 C.9 1.1378 B.127 C.9 1.1379 B.128 C.9 1.1380 B.129 C.9 1.1381 B.130 C.9 1.1382 B.131 C.9 1.1383 B.132 C.9 1.1384 B.133 C.9 1.1385 B.134 C.9 1.1386 B.135 C.9 1.1387 B.136 C.9 化合物編號除草劑B 安全劑C 1.1388 B.137 C.9 1.1389 B.138 C.9 1.1390 B.139 C.9 1.1391 B.1 C.10 1.1392 B.2 C.10 1.1393 B.3 C.10 1.1394 B.4 C.10 1.1395 B.5 C.10 1.1396 B.6 C.10 1.1397 B.7 C.10 1.1398 B.8 C.10 1.1399 B.9 C.10 1.1400 B.10 C.10 1.1401 B.11 C.10 1.1402 B.12 C.10 1.1403 B.13 C.10 1.1404 B.14 C.10 1.1405 B.15 C.10 1.1406 B.16 C.10 1.1407 B.17 C.10 1.1408 B.18 C.10 1.1409 B.19 C.10 1.1410 B.20 C.10 1.1411 B.21 C.10 1.1412 B.22 C.10 1.1413 B.23 C.10 1.1414 B.24 C.10 1.1415 B.25 C.10 1.1416 B.26 C.10 1.1417 B.27 C.10 1.1418 B.28 C.10 1.1419 B.29 C.10 1.1420 B.30 C.10 1.1421 B.31 C.10 1.1422 B.32 C.10 1.1423 B.33 C.10 1.1424 B.34 C.10 1.1425 B.35 C.10 1.1426 B.36 C.10 1.1427 B.37 C.10 1.1428 B.38 C.10 150107.doc •73- 201109321 化合物編號除草劑B 安全劑C 1.1429 B.39 C.10 3.1430 B.40 C.10 1.1431 B.41 C.10 1.1432 B.42 C.10 1.1433 ιΒ.43 C.10 1.1434 B.44 C.10 1.1435 B.45 C.10 1.1436 B.46 C.10 1.1437 B.47 C.10 1.1438 B.48 C.10 1.1439 B.49 C.10 1.1440 B.50 C.10 1.1441 B.51 C.10 1.1442 B.52 C.10 1.1443 B.53 C.10 1.1444 B.54 C.10 1.1445 B.55 C.10 1.1446 B.56 C.10 1.1447 B.57 C.10 1.1448 B.58. C.10 1.1449 B.59 C.10 1.1450 B.60 C.10 1.1451 B.61 C.10 1.1452 B.62 C.10 1.1453 B.63 C.10 1.1454 B.64 C.10 1.1455 B.65 C.10 1.1456 B.66 C.10 1.1457 B.67 C.10 1.1458 B.68 C.10 1.1459 B.69 C.10 1.1460 B.70 C.10 1.1461 B.71 C.10 1.1462 B.72 C.10 1.1463 B.73 C.10 1.1464 B.74 C.10 1.1465 B.75 C.10 1.1466 B.76 C.10 1.1467 B.77 C.10 1.1468 B.78 C.10 1.1469 B.79 C.10 化合物編號除草劑B 安全劑C 1.1470 B.80 C.10 1.1471 B.81 C.10 1.1472 B.82 C.10 1.1473 B.83 C.10 1.1474 B.84 C.10 1.1475 B.85 C.10 1.1476 B.86 C.10 1.1477 B.87 C.10 1.1478 B.88 C.10 1.1479 B.89 C.10 1.1480 B.90 C.10 1.1481 B.91 C.10 1.1482 B.92 C.10 1.1483 B.93 C.10 1.1484 B.94 C.10 1.1485 B.95 C.10 1.1486 B.96 C.10 1.1487 B.97 C.10 1.1488 B.98 C.10 1.1489 B.99 C.10 1.1490 B.100 C.10 1.1491 B.101 C.10 1.1492 B.102 C.10 1.1493 B.103 C.10 1.1494 B.104 C.10 1.1495 B.105 C.10 1.1496 B.106 C.10 1.1497 B.107 C.10 1.1498 B.108 C.10 1.1499 B.109 C.10 1.1500 B.110 C.10 1.1501 B.111 C.10 1.1502 B.112 C.10 1.1503 B.113 C.10 1.1504 B.114 C.10 1.1505 B.115 C.10 1.1506 B.116 C.10 1.1507 B.117 C.10 1.1508 B.118 C.10 1.1509 B.119 C.10 1.1510 B.120 C.10 化合物編號除草劑B 安全劑C 1.1511 B.121 C.10 1.1512 B.122 C.10 1.1513 B.123 C.10 1.1514 B.124 C.10 1.1515 B.125 C.10 1.1516 B.126 C.10 1.1517 B.127 C.10 1.1518 B.128 C.10 1.1519 B.129 C.10 1.1520 B.130 C.10 1.1521 B.131 C.10 1.1522 B.132 C.10 1.1523 B.133 C.10 1.1524 B.134 C.10 1.1525 B.135 C.10 1.1526 B.136 C.10 1.1527 B.137 C.10 1.1528 B.138 C.10 1.1529 B.139 C.10 1.1530 B.1 C.11 1.1531 B.2 C.11 1.1532 B.3 C.11 1.1533 B.4 C.11 1.1534 B.5 C.11 1.1535 B.6 C.11 1.1536 B.7 C.11 1.1537 B.8 C.11 1.1538 B.9 C.11 1.1539 B.10 C.11 1.1540 B.11 C.11 1.1541 B.12 C.11 1.1542 B.13 C.11 1.1543 B.14 C.11 1.1544 B.15 C.11 1.1545 B.16 C.11 1.1546 B.17 C.11 1.1547 B.18 C.11 1.1548 B.19 C.11 1.1549 B.20 C.11 1.1550 B.21 C.11 1.1551 B.22 C.11 150107.doc -74- 201109321 化合物編號除草劑B 安全劑C 1.1552 B.23 C.11 1.1553 B.24 C.11 1.1554 B.25 C.11 1.1555 B.26 C.11 1.1556 B.27 C.11 1.1557 B.28 C.11 1.1558 B.29 C.11 1.1559 B.30 C.11 1.1560 B.31 C.11 1.1561 B.32 C.11 1.1562 B.33 C.11 1.1563 B.34 C.11 1.1564 B.35 C.11 1.1565 B.36 C.11 1.1566 B.37 C.11 1.1567 B.38 C.11 1.1568 B.39 C.11 1.1569 B.40 C.11 1.1570 B.41 C.11 1.1571 B.42 C.11 1.1572 B.43 C.11 1.1573 B.44 C.11 1.1574 B.45 C.11 1.1575 B.46 C.11 1.1576 B.47 C.11 1.1577 B.48 C.11 1.1578 B.49 C.11 1.1579 B.50 C.11 1.1580 B.51 C.11 1.1581 B.52 C.11 1.1582 B.53 C.11 1.1583 B.54 C.11 1.1584 B.55 C.11 1.1585 B.56 C.11 1.1586 B.57 C.11 1.1587 B.58. C.11 1.1588 B.59 C.11 1.1589 B.60 C.11 1.1590 B.61 C.11 1.1591 B.62 C.11 1.1592 B.63 C.11 化合物編號除草劑B 安全劑C 1.1593 B.64 C.11 1.1594 B.65 C.11 1.1595 B.66 C.11 1.1596 B.67 C.11 1.1597 B.68 C.11 1.1598 B.69 C.11 1.1599 B.70 C.11 1.1600 B.71 C.11 1.1601 B.72 C.11 1.1602 B.73 C.11 1.1603 B.74 C.11 1.1604 B.75 C.11 1.1605 B.76 C.11 1.1606 B.77 C.11 1.1607 B.78 C.11 1.1608 B.79 C.11 1.1609 B.80 C.11 1.1610 B.81 C.11 1.1611 B.82 C.11 1.1612 B.83 C.11 1.1613 B.84 C.11 1.1614 B.85 C.11 1.1615 B.86 C.11 1.1616 B.87 C.11 1.1617 B.88 C.11 1.1618 B.89 C.11 1.1619 B.90 C.11 1.1620 B.91 C.11 1.1621 B.92 C.11 1.1622 B.93 C.11 1.1623 B.94 C.11 1.1624 B.95 C.11 1.1625 B.96 C.11 1.1626 B.97 C.11 1.1627 B.98 C.11 1.1628 B.99 C.11 1.1629 B.100 C.11 1.1630 B.101 C.11 1.1631 B.102 C.11 1.1632 B.103 C.11 1.1633 B.104 C.11 化合物編號除草劑B 安全劑C 1.1634 B.105 C.11 1.1635 B.106 C.11 1.1636 B.107 C.11 1.1637 B.108 C.11 1.1638 B.109 C.11 1.1639 B.110 C.11 1.1640 B.111 C.11 1.1641 B.112 C.11 1.1642 B.113 C.11 1.1643 B.114 C.11 1.1644 B.115 C.11 1.1645 B.116 C.11 1.1646 B.117 C.11 1.1647 B.118 C.11 1.1648 B.119 C.11 1.1649 B.120 C.11 1.1650 B.121 C.11 1.1651 B.122 C.11 1.1652 B.123 C.11 1.1653 B.124 C.11 1.1654 B.125 C.11 1.1655 B.126 C.11 1.1656 B.127 C.11 1.1657 B.128 C.11 1.1658 B.129 C.11 1.1659 B.130 C.11 1.1660 B.131 C.11 1.1661 B.132 C.11 1.1662 B.133 C.11 1.1663 B.134 C.11 1.1664 B.135 C.11 1.1665 B.136 C.11 1.1666 B.137 C.11 1.1667 B.138 C.11 1.1668 B.139 C.11 150I07.doc -75- 201109321 可按如下所述來推導各單一組合物之具體編號：舉例而言，組合物1.777包含苯并噚畊酮I. Μ、氟咯草酮 (Β·82)及解草咬（c.5)(參見表1，條目1.777 ;以及表Β，條目B.82及表c ’條目c.5)。舉例而言，組合物2 777包含笨并噚畊酮121(參見下文針對、’且δ物2.1至2.1668之定義）、氟π各草酮（b.82)及解草咬 (C.5)(參見表i，條目i 777 ;以及表Β，條目Β 82及表c，條目C.5)。舉例而5，組合物7.777包含草酯（Β2)(參見下文針對組合物7.1至7.1668之定義）、及苯并十井酮【hl、氣略草明 (Β.82)及解草啶（C.5)(參見表1，條目1.777 ;以及表Β，條目Β·82及表C，條目c.5)。 ' 亦尤佳者係組合物2.1至2.1668，其與相應组合物^至 1.1668之區別僅在於其包含苯并嘮畊酮化合物12丨作性化合物Α。 / 亦尤佳者係組合物H 3.1668，其與相應组合物！」至 Μ 668之區別僅在於其包含苯并啰畊酮化合物i 作性化合物Α。亦尤佳者係組合物至4.1668，其與相應組合⑹ 1.1668之區別僅在於其包含苯并十井嗣化合物！ 3 性化合物A。兩亦尤佳者係組合物5.1至5.1668 s其與相應組合％ΐι 1.1668之區別僅在於其包含苯并十井酮化合物〗」发至性化合物A。 '、、南 150107.doc •76- 201109321 亦尤佳者係組合物“至6.1668，其與相應組合物π 1.1668之區別僅在於其包含苯并十井酮化合物m作為活性化合物Α。亦尤佳者係組合物7·1至7.刪，其與相應組合物hl至 1.1668之區別僅在於其另外包含B 2作為另—除草劑b。亦尤佳者係組合物8」至8.刪，其與相應組合物"至 1.1668之區別僅在於其另外包含B.7作為另一除草劑B。亦尤佳者係組合物9]至9.麗，其與相應組合物ι」至 1.1668之區別僅在於其另外包含Β·為另—除草劑卜亦尤佳者係組合物1(Μ至1〇 1668，其與相應組合物丄」至1.1668之區別僅在於其料包含B 3()作為另—除草劑b。亦尤佳者係組合物mu.1668，其與相應組合物i」至1.1668之區別僅在於其另外包含B 31作為另—除草劑b。亦尤佳者係組合物12」至12.1668，其與相應組合物！」至1.1668之區別僅在於其另外包含B 32作為另—除草劑b。亦尤佳者係組合物m 13.1668，其與相應組合物i」至1.1668之區別僅在於其另外包含B 33作為另—除草劑b。亦尤佳者係組合物，其與相應組合物丄( 至1.1668之區別僅在於其另外包含B 4〇作為另一除草劑b。亦尤佳者係組合物!5.U15_1668’其與相應組合❸^ 至1.福之區別僅在於其另外包含B 44作為另—除草劑b。. 亦尤佳者係組合物16.116·1668 ,其與相應組合物^ ^ 至1.1668之區別僅在於其另外包含丨45作為另一除草劑b。· 亦尤佳者係組合物17_H7_1668，其與相應組合物】【 150107.doc -77- 201109321 至1.1668之區別僅在於其另外包含B 52作為另—除草劑b。亦尤佳者係組合物18」至18.議，丨與相應組合物i」至1.1668之區別僅在於其另外包含B53作為另—除草劑b。亦尤佳者係組合物19」至19,1668，其與相應組合物i」至1.1668之區別僅在於其另外包含B 54作為另—除草劑b。亦尤佳者係組合物’其與相應組合^ 至1.1668之區別僅在於其另外包含B 55作為另一除草劑b。亦尤佳者係組合物21.1至21.1668，#與相應組合物hl 至1.1668之區別僅在於其另外包含B 56作為另一除草劑b。亦尤佳者係組合物22·β22·1668，其與相應組合」至1.1668之區別僅在於其另外包含B 57作為另一除草劑b。亦尤佳者係組合物⑴至认·，其與相應組合物“ 至1.1668之區別僅在於其另外包含B 65作為另一除草劑b。亦尤佳者係組合物24.1至24.1668，其與相應組合物hl 至1.1668之區別僅在於其另外包含B 66作為另一除草劑b。亦尤佳者係組合物25.1至25.1668，其與相應組合物“ 至1.1668之區別僅在於其另外包含B 69作為另一除草劑b。亦尤佳者係組合物26.1至26.1668，其與相應組合物^ 至1.1668之區別僅在於其另外包含B 72作為另一除草劑B。亦尤佳者係組合物27.1至27.1668，其與相應組合物以至1.1668之區別僅在於其另外包含B 73作為另一除草劑b。亦尤佳者係組合物，其與相應組合」至1.1668之區別僅在於其另外包含B 76作為另一除草劑b。亦尤佳者係组合物29.1至29.1668，其與相應組合物。 150107.doc -78- 201109321 至1.1668之區別僅在於其另外包含B77作為另_除草劑b。亦尤佳者係組合物，其與相應組合物1」至1.1668之區別僅在於其另外包含B 79作為另一除草劑b。亦尤佳者係組合物31」至31·1668，其與相應組合物i i 至1.1668之區別僅在於其另外包含B 8〇作為另一除草劑b。亦尤佳者係組合物32.1至32.1668 ,其與相應組合物" 至1.1668之區別僅在於其另外包含B 83作為另一除草劑b。亦尤佳者係組合物33.1至33.1668，其與相應組合物i」至1.1668之區別僅在於其另外包含B 83及B 54作為其他除草劑B。亦尤佳者係組合物34_1至34.1668，其與相應組合^ 至1.1668之區別僅在於其另外包含B83及B6〇作為其他除草劑B。、亦尤佳者係組合物35^1 35 1668，其與相應組合物“ 至1.1668之區別僅在於其另外包含B83及B66作為其他除草劑B。亦尤佳者係組合物36.1至36 1668，其與相應組合物丄^ 至1.1668之區別僅在於其另外包含B 84作為另一除草劑b。亦尤佳者係組合物”.丨至叨1668，其與相應組合物“ 至1.1668之區別僅在於其另外包含B84及B54作為其他除草劑B。 * 亦尤佳者係組合物“.丨至刊1668，其與相應組合物工i 至1.1668之區別僅在於其另外包含B84及B6〇作為其他除草劑B。 150107.doc -79- 201109321 亦尤佳者係組合物3H39.難，其與相應組合物M 至1.1668之區別僅在於其另夕卜包含B84及請作為其草劑B。 ” 亦尤佳者係組合物40.1至40.1668，其與相應组合物！」至1.1668之區別僅在於其另外包含B 86作為另一除草劑b。亦尤佳者係組合物41」至41.1668，其與相應組合物^ ^ 至1.1668之區別僅在於其另外包含B 87作為另一除草劑b。亦尤佳者係組合物42Μ42_1668 ’其與相應組合物hi 至1.1668之區別僅在於其另外包含B87及BM作為其他除草劑B ^ ,、亦尤佳者係組合物4H43_1668 ’其與相應組合物至1.1668之區別僅在於其另外包含B87及B6〇作為其他除草劑B。亦尤佳者係組合物44·；^44·1668，其與相應乡且合物丄」至1.1668之區別僅在於其另外包含B 87及B 66作為其他除草劑B。亦尤佳者係組合物45.1至45 1668，其與相應組合物i i 至1.1668之區別僅在於其另外包含B 89作為另一除草劑b。亦尤佳者係組合物4H 46 1668，其與相應組合物m 至1.1668之區別僅在於其另外包含B 9〇作為另一除草劑b。亦尤佳者係組合物47.U 47 1668，其與相應組合物η 至1.1668之區別僅在於其另外包含Β 9〇及Β54作為其他除草劑Β。亦尤佳者係組合物4H 48 1668，其與相應組合物i」 150107.doc •80- 201109321 至1.1668之區別僅在於其另外包含B 9〇及B 6〇作為其他除草劑B。亦尤佳者係組合物49.1至49.1 668，其與相應組合物j j 至1.1668之區別僅在於其另外包含B9〇及B66作為其他除草劑B。亦尤佳者係組合物50.1至50.1668，其與相應組合物" 至1.1668之區別僅在於其另外包含B 94作為另一除草劑b。亦尤佳者係組合物5 1 · 1至5 1.1 668，其與相應組合物j j 至1.1668之區別僅在於其另外包含B 94及B M作為其他除草劑B。亦尤佳者係組合物52· 1至52.1668，其與相應組合物以至丨.1668之區別僅在於其另外包含B94及B76作為其他除草劑B。亦尤佳者係組合物53.1至53.1668，其與相應組合物} ^ 至1.1668之區別僅在於其另外包含B94及B83作為其他除草劑B。亦尤佳者係組合物54.1至54.1668，其與相應組合物" 至H668之區別僅在於其另外包含請纽1〇2作為其他除草劑B。亦尤佳者係組合物55]至55.觸，纟與相應組合物以至1.1668之區別僅在於其另外包含B94及請作為其他除草劑Β。 μ 亦尤佳者係組合物56.1至56.1668 ’其與相應組合物工！至Μ668之區別僅在於其另外包含β94及謂作為其他除 150107.doc • 81 - 201109321 草劑B。亦尤佳者係組合物57·β57·1668 ’其與相應組合^」至1 · 1668之區別僅在於其另外包含B 94及B 9〇作為其他除草劑B。亦尤佳者係組合物5H 58.1668,其與相應組合物^至 1.166S之區職在於其另外包含B 97作為另—除草劑亦尤佳者係組合物5H 59.1668，其與相應組合物i」至 1.1668之區別僅在於其另外包含B1〇〇作為另—除草劑b。亦尤佳者係組合物60.α6〇.1668，其與相應組合物i」至 1.1668之區別僅在於其另外包含B1Q2作為另—除草劑b。亦尤佳者係組合物61_β61·1668，其與相應組合物i」至 1.1668之區別僅在於其另外包含B1Q5作為另—除草劑b。亦尤佳者係組合物62.1至62_1668，其與相應組合物i」至 1.1668之區別僅在於其另外包含B1〇6作為另一除草劑b。亦尤佳者係組合物63_1至63.1668，其與相應組合物丨^至 1.1668之區別僅在於其另外包含B1〇7作為另一除草劑B。亦尤佳者係組合物6d 64.1668，其與相應組合物hl至 1.1668之區別僅在於其另外包含B1〇9作為另一除草劑b。亦尤佳者係組合物65.1至65.1668，其與相應組合物丨^至 1.1668之區別僅在於其另外包含5111作為另一除草劑b。亦尤佳者係組合物，其與相應組合物丨」至 1.1668之區別僅在於其另外包含3115作為另一除草劑b。亦尤佳者係組合物67·1至67.1668，其與相應組合物丨丨至 1.1668之區別僅在於其另外包含&117作為另一除草劑B。 150107.doc -82- 201109321 亦尤佳者係組合物68.1至68.1668，其與相應組合物u 至1.1668之區別僅在於其另外包含8118作為另一除草劑B。亦尤佳者係組合物69.1至69.1668，其與相應組合物u 至1.1668之區別僅在於其另外包含B12〇作為另一除草劑B。亦尤佳者係組合物70.1至70.1668 ’其與相應組合物1」至1.1668之區別僅在於其另外包含B12H，為另一除草劑B。亦尤佳者係組合物71.1至71·1668，其與相應組合物1 ^ 至1.1668之區別僅在於其另外包含BU2作為另一除草劑Β。亦尤佳者係組合物72.1至72.1668，其與相應組合物hl至 1.1668之區別僅在於其另外包含Β128作為另一除草劑Β。亦尤佳者係組合物73.1至73.1668，其與相應組合至1.1668之區別僅在於其另外包含派羅克殺草颯作為另— 除草劑。亦尤佳者係組合物74.1至74.1668，其與相應組合物hl 至1·1668之區別僅在於其另外包含派羅克殺草砜作為另— 除卓劑及Β.54作為另一除草劑β。亦尤佳者係組合物75_1至75.1668，其與相應組合物i 1 至1.1 668之區別僅在於其另外包含派羅克殺草砜作為另— 除草劑及Β·60作為另一除草劑β。亦尤佳者係組合物76.1至76.1668，其與相應組合物】i 至1.1668之區別僅在於其另外包含派羅克殺草砜作為另— 除草劑及B.66作為另一除草劑β。亦尤佳者係組合物77.1至77.1668，其與相應組合物j 1 至1.1668之區別僅在於其另外包含派羅克殺草砜作為另— 150107.doc • 83 - 201109321 除草劑及B.76作為另一除草劑B。亦尤佳者係組合物78.1至78.1668，其與相應la合物至1.1668之d別僅在於其另外包含派羅克殺草颯作為另一除草劑及B.83作為$ _料劑B。亦尤佳者係組合物79丨至79 1668，其與相應組合物L1 至1.1668之區別僅在於其另外包含派羅克殺草石風作為另一除草劑及B.84作為另一除草劑B。亦尤佳者係組合物80.1至80.1668，其與相應組合物hl 至1.1668之區別僅在於其另外包含派羅克殺草礙作為另一除草劑及B.87作為另一除草劑Ββ 亦尤佳者係組合物81」至81.1668，其與相應組合物^ 8之區別僅在於其另外包含派羅克殺草碾作為另一除草劑及Β.90作為另一除草劑Β。亦尤佳者係組合物82.m1668，纟與相應組合物i」至1.1668之區別僅在於其另外包含派羅克殺草颯作為另一除草劑及B.94作為另一除草劑B。亦尤佳者係組合物⑴㈣上，其包含笨并十井綱化合物L1作為活性化合物A)及表C之相應列中所定義之物質二為另一化合物：Table C Safety agent c C. 1 oxaloacetone C. 2 detoxification quine C. 3 sulforaphane C. 4 di-propylene amide C. 5 oxadiadine C. 6 oxazolidine C. 7 Jiecao σ azole C. 8 diphenyl sigma oxalic acid C. 9 ° than ° sitting on the grass 10 4-(dioxaethyl)-1-oxa-4-azaspiro[4. 5] decane (ΜΟΝ4660, CAS 71526-07-3) C. 11 2,2,5-trimethyl-3-(dioxaethyl)-1,3-oxazolyl (R-29148, CAS 52836-31-4) Individual groups of preferred mixtures mentioned below The weight ratio of parts is within the above limits, especially within preferred limits. Particularly preferred are the compositions described below, including the defined benzoxanthene compounds and the corresponding columns in Table 1 set to 150107. Doc -61 - 201109321 The substance of the righteousness; especially the substance of the stupid and stalking compound and the substance defined in the corresponding column of Table 1 as the herbicidal active compound; optimally, only The materials defined in the corresponding columns of Table 1 and the corresponding columns of Table 1 are used as the active compounds. Particularly preferred is a composition 1. 1 to 1. 1668, which comprises a benzoxanthone compound. 1 · 1 and the substances defined in the corresponding columns of Table 1: Table 1 (composition 1. 1 to 1. 1668): Compound weeding Safety No. Β Agent c 1. 1 Β. 1 1. 2 Γβ. twenty one. 3 Β. 3 -· 1. 4 hB. 4 — 1. 5 B. 5 1. 6 B. 6 — 1. 7 B. 7 _ 1. 8 B. 8 —— 1. 9 B. 9 __ 1. 10 B. 10 ·· 1. 11 B. Ll ·_ 1. 12 B. 12 __ 1. 13 B. 13 __ 1. 14 B. 14 1. 15 B. 15 __ 1. 16 B. 16 ·· 1. 17 B. 17 ·· 1. 18 B. 18 ·_ 1. 19 B. 19 · 1. 20 B. 20 1 ·· 1. 21 B. 21 —· 1. 22 B. 22 · 1. 23 B. 23 · 1. 24 B. 24 ·· 1. 25 B. 25 — Compound Weeding Safety No. Agent Β Agent C 1. 26 Β. 26 1. 27 Β. 27 1. 28 Β. 28 ~ 1. 29 Γβ. 29 stealing 1. 30 Β. 30 __ 1. 31 Β. 31 ·· 1. 32 [Β_32 · 1. 33 Β. 33 1. 34 Β. 34 1. 35 Β. 35 __ 1. 36 Β. 36 1. 37 Β. 37 ·· 1. 38 Β. 38 zero· 1. 39 Β. 39 1. 40 Β. 40~~ 1. 41 Β. 41 ·· 1. 42 Β. 42 1. 43 Β. 43~~ 1. 44 Β. 44 · 1. 45 1 ΒΑ5~~ · 1. 46 Β. 46 Qingyi 1. 47 Β‘47 ·· 1. 48 Β. 48 ·· 1. 49 Β. 49~~ · 1. 50 Β. 50 — Compound No. Herbicide B Γ^ Full Agent C 1. 51 B. 51 -· 1. 52 B. 52 ·· 1. 53 B. 53 1. 54 B. 54 ·· 1. 55 B. 55 ·— 1. 56 B. 56 1. 57 B. 57 — 1. 58 B. 58. -- 1. 59 B. 59 — 1. 60 B. 60 -- 1. 61 B. 61 — 1. 62 B. 62 ·_ 1. 63 B. 63 — 1. 64 B. 64 __ 1. 65 B. 65 -- 1. 66 B. 66 — 1. 67 B. 67 __ 1. 68 B. 68 er 1. 69 B. 69 1. 70 B. 70 _ 1. 71 B. 71 __ 1. 72 B. 72 ·— 1. 73 B. 73 — 1. 74 B. 74 ·· 1. 75 B. 75 — 150107. Doc •62· 201109321 Compound Weeding Safety No. Agent B Agent C 1. 76 B. 76 — 1. 77 B. 77 — 1. 78 B. 78 — 1. 79. B. 79 —— 1. 80 B. 80 — 1. 81 B. 81 —— 1. 82 B. 82 — 1. 83 B. 83 — 1. 84 B. 84 — 1. 85 B. 85 — 1. 86 B. 86 — 1. 87 B. 87 — 1. 88 B. 88 — 1. 89 B. 89 — 1. 90 B. 90 — 1. 91 B. 91 — 1. 92 B. 92 — 1. 93 B. 93 — 1. 94 B. 94 — 1. 95 B. 95 — 1. 96 B. 96 — 1. 97 B. 97 — 1. 98 B. 98 — 1. 99 B. 99 — 1. 100 B. 100 — 1. 101 B. 101 — 1. 102 B. 102 — 1. 103 B. 103 — 1. 104 B. 104 — 1. 105 B. 105 -- 1. 106 B. 106 — 1. 107 B. 107 — 1. 108 B. 108 — 1. 109 B. 109 — 1. 110 B. 110 — 1. 111 B. 111 — 1. 112 B. 112 — 1. 113 B. 113 — 1. 114 B. 114 — 1. 115 B. 115 — 1. 116 B. 116 — Compound No. Herbicide B Safety Agent C 1. 117 B. 117 — 1. 118 B. 118 -- 1. 119 B. 119 1. 120 B. 120 — 1. 121 B. 121 — 1. 122 B. 122 — 1. 123 B. 123 —- 1. 124 B. 124 — 1. 125 B. 125 1. 126 B. 126 1. 127 B. 127 -- 1. 128 B. 128 1. 129 B. 129 -- 1. 130 B. 130 —— 1. 131 B. 131 — 1. 132 B. 132 -- 1. 133 B. 133 1. 134 B. 134 1. 135 B. 135 -- 1. 136 B. 136 — 1. 137 B. 137 — 1. 138 B. 138 1. 139 B. 139 -- 1. 140 B. 1 C. 1 1. 141 B. 2 C. 1 1. 142 B. 3 C. 1 1. 143 B. 4 C. 1 1. 144 B. 5 C. 1 1. 145 B. 6 C. 1 1. 146 B. 7 C. 1 1. 147 B. 8 C. 1 1. 148 B. 9 C. 1 1. 149 B. 10 C. 1 1. 150 B. 11 C. 1 1. 151 B. 12 C. 1 1. 152 B. 13 C. 1 1. 153 B. 14 C. 1 1. 154 B. 15 C. 1 1. 155 B. 16 C. 1 1. 156 B. 17 C. 1 1. 157 B. 18 C. 1 Compound No. Herbicide B Safety Agent C 1. 158 B. 19 C. 1 1. 159 B. 20 C. 1 1. 160 B. 21 C. 1 1. 161 B. 22 C. 1 1. 162 B. 23 C. 1 1. 163 B. 24 C. 1 1. 164 B. 25 C. 1 1. 165 B. 26 C. 1 1. 166 B. 27 C. 1 1. 167 B. 28 C. 1 1. 168 B. 29 C. 1 1. 169 B. 30 C. 1 1. 170 B. 31 C. 1 1. 171 B. 32 C. 1 1. 172 B. 33 C. 1 1. 173 B. 34 C. 1 1. 174 B. 35 C. 1 1. 175 B. 36 C. 1 1. 176 B. 37 C. 1 1. 177 B. 38 C. 1 1. 178 B. 39 C. 1 1. 179 B. 40 C. 1 1. 180 B. 41 C. 1 1. 181 B. 42 C. 1 1. 182 B. 43 C. 1 1. 183 B. 44 C. 1 1. 184 B. 45 C. 1 1. 185 B. 46 C. 1 1. 186 B. 47 C. 1 1. 187 B. 48 C. 1 1. 188 B. 49 C. 1 1. 189 B. 50 C. 1 1. 190 B. 51 C. 1 1. 191 B. 52 C. 1 1. 192 B. 53 C. 1 1. 193 B. 54 C. 1 1. 194 B. 55 C. 1 1. 195 B. 56 C. 1 1. 196 B. 57 C. 1 1. 197 B. 58. C. 1 1. 198 B. 59 C. 1 150107. Doc -63- 201109321 Compound No. Herbicide B Safety Agent C 1. 199 B. 60 C. 1 1. 200 B. 61 C. 1 1. 201 0. 62 C. 1 1. 202 B. 63 C. 1 1. 203 B. 64 C. 1 1. 204 B. 65 C. 1 1. 205 B. 66 C. 1 1. 206 B. 67 C. 1 1. 207 B. 68 C. 1 1. 208 B. 69 C. 1 1. 209 B. 70 C. 1 1. 210 B. 71 C. 1 1. 211 B. 72 C. 1 1. 212 B. 73 C. 1 1. 213 B. 74 C. 1 1. 214 B. 75 C. 1 1. 215 B. 76 C. 1 1. 216 B. 77 C. 1 1. 217 B. 78 C. 1 1. 218 B. 79 C. 1 1. 219 B. 80 C. 1 1. 220 B. 81 C. 1 1. 221 B. 82 C. 1 1. 222 B. 83 C. 1 1. 223 B. 84 C. 1 1. 224 B. 85 C. 1 1. 225 B. 86 C. 1 1. 226 B. 87 C. 1 1. 227 B. 88 C. 1 1. 228 B. 89 C. 1 1. 229 B. 90 C. 1 1. 230 B. 91 C. 1 1. 231 B. 92 C. 1 1. 232 B. 93 C. 1 1. 233 B. 94 C. 1 1. 234 B. 95 C. 1 1. 235 B. 96 C. 1 1. 236 B. 97 C. 1 1. 237 B. 98 C. 1 1. 238 B. 99 C. 1 1. 239 B. 100 C. 1 Compound No. Herbicide B Safety Agent C 1. 240 B. 101 C. 1 1. 241 B. 102 C. 1 1. 242 B. 103 C. 1 1. 243 B. 104 C. 1 1. 244 B. 105 C. 1 1. 245 B. 106 C. 1 1. 246 B. 107 C. 1 1. 247 B. 108 C. 1 1. 248 B. 109 C. 1 1. 249 B. 110 C. 1 1. 250 B. 111 C. 1 1. 251 B. 112 C. 1 1. 252 B. 113 C. 1 1. 253 B. 114 C. 1 1. 254 B. 115 C. 1 1. 255 B. 116 C. 1 1. 256 B. 117 C. 1 1. 257 B. 118 C. 1 1. 258 B. 119 C. 1 1. 259 B. 120 C. 1 1. 260 B. 121 C. 1 1. 261 B. 122 C. 1 1. 262 B. 123 C. 1 1. 263 B. 124 C. 1 1. 264 B. 125 C. 1 1. 265 B. 126 C. 1 1. 266 B. 127 C. 1 1. 267 B. 128 C. 1 1. 268 B. 129 C. 1 1. 269 B. 130 C. 1 1. 270 B. 131 C. 1 1. 271 B. 132 C. 1 1. 272 B. 133 C. 1 1. 273 B. 134 C. 1 1. 274 B. 135 C. 1 1. 275 B. 136 C. 1 1. 276 B. 137 C. 1 1. 277 B. 138 C. 1 1. 278 B. 139 C. 1 1. 279 B. 1 C. twenty one. 280 B. 2 C. 2 Compound No. Herbicide B Safety Agent C 1. 281 B. 3 C. twenty one. 282 B. 4 C. twenty one. 283 B. 5 C. twenty one. 284 B. 6 C. twenty one. 285 B. 7 C. twenty one. 286 B. 8 C. twenty one. 287 B. 9 C. twenty one. 288 B. 10 C. twenty one. 289 B. 11 C. twenty one. 290 B. 12 C. twenty one. 291 B. 13 C. twenty one. 292 B. 14 C. twenty one. 293 B. 15 C. twenty one. 294 B. 16 C. twenty one. 295 B. 17 C. twenty one. 296 B. 18 C. twenty one. 297 B. 19 C. twenty one. 298 B. 20 C. twenty one. 299 B. 21 C. twenty one. 300 B. 22 C. twenty one. 301 B. 23 C. twenty one. 302 B. 24 C. twenty one. 303 B. 25 C. twenty one. 304 B. 26 C. twenty one. 305 B. 27 C. twenty one. 306 B. 28 C. twenty one. 307 B. 29 C. twenty one. 308 B. 30 C. twenty one. 309 B. 31 C. twenty one. 310 B. 32 C. twenty one. 311 B. 33 C. twenty one. 312 B. 34 C. twenty one. 313 B. 35 C. twenty one. 314 B. 36 C. twenty one. 315 B. 37 C. twenty one. 316 B. 38 C. twenty one. 317 B. 39 C. twenty one. 318 B. 40 C. twenty one. 319 B. 41 C. twenty one. 320 B. 42 C. twenty one. 321 B. 43 C. 2 150107. Doc -64- 201109321 Compound No. Herbicide B Safety Agent C 1. 322 B. 44 C. twenty one. 323 B. 45 C. twenty one. 324 B. 46 C. twenty one. 325 B. 47 C. twenty one. 326 B. 48 C. twenty one. 327 B. 49 C. twenty one. 328 B. 50 C. twenty one. 329 B. 51 C. twenty one. 330 B. 52 C. twenty one. 331 B. 53 C. twenty one. 332 B. 54 C. twenty one. 333 B. 55 C. twenty one. 334 B. 56 C. twenty one. 335 B. 57 C. twenty one. 336 B. 58. C. twenty one. 337 B. 59 C. twenty one. 338 B. 60 C. twenty one. 339 B. 61 C. twenty one. 340 B. 62 C. twenty one. 341 B. 63 C. twenty one. 342 B. 64 C. twenty one. 343 B. 65 C. twenty one. 344 B. 66 C. twenty one. 345 B. 67 C. twenty one. 346 B. 68 C. twenty one. 347 B. 69 C. twenty one. 348 B. 70 C. twenty one. 349 B. 71 C. twenty one. 350 B. 72 C. twenty one. 351 B. 73 C. twenty one. 352 B. 74 C. twenty one. 353 B. 75 C. twenty one. 354 B. 76 C. twenty one. 355 B. 77 C. twenty one. 356 B. 78 C. twenty one. 357 B. 79 C. twenty one. 358 B. 80 C. twenty one. 359 B. 81 C. twenty one. 360 B. 82 C. twenty one. 361 B. 83 C. twenty one. 362 B. 84 C. 2 Compound No. Herbicide B Safety Agent C 1. 363 B. 85 C. twenty one. 364 B. 86 C. twenty one. 365 B. 87 C. twenty one. 366 B. 88 C. twenty one. 367 B. 89 C. twenty one. 368 B. 90 C. twenty one. 369 B. 91 C. twenty one. 370 B. 92 C. twenty one. 371 B. 93 C. twenty one. 372 B. 94 C. twenty one. 373 B. 95 C. twenty one. 374 B. 96 C. twenty one. 375 B. 97 C. twenty one. 376 B. 98 C. twenty one. 377 B. 99 C. twenty one. 378 B. 100 C. twenty one. 379 B. 101 C. twenty one. 380 B. 102 C. twenty one. 381 B. 103 C. twenty one. 382 B. 104 C. twenty one. 383 B. 105 C. twenty one. 384 B. 106 C. twenty one. 385 B. 107 C. twenty one. 386 B. 108 C. twenty one. 387 B. 109 C. twenty one. 388 B. 110 C. twenty one. 389 B. 111 C. twenty one. 390 B. 112 C. twenty one. 391 B. 113 C. twenty one. 392 B. 114 C. twenty one. 393 B. 115 C. twenty one. 394 B. 116 C. twenty one. 395 B. 117 C. twenty one. 396 B. 118 C. twenty one. 397 B. 119 C. twenty one. 398 B. 120 C. twenty one. 399 B. 121 C. twenty one. 400 B. 122 C. twenty one. 401 B. 123 C. twenty one. 402 B. 124 C. twenty one. 403 B. 125 C. 2 Compound No. Herbicide B Safety Agent C 1. 404 B. 126 C. twenty one. 405 B. 127 C. twenty one. 406 B. 128 C. twenty one. 407 B. 129 C. twenty one. 408 B. 130 C. twenty one. 409 B. 131 C. twenty one. 410 B. 132 C. twenty one. 411 B. 133 C. twenty one. 412 B. 134 C. twenty one. 413 B. 135 C. twenty one. 414 B. 136 C. twenty one. 415 B. 137 C. twenty one. 416 B. 138 C. twenty one. 417 B. 139 C. twenty one. 418 B. 1 C. 3 1. 419 B. 2 C. 3 1. 420 B. 3 C. 3 1. 421 B. 4 C. 3 1. 422 B. 5 C. 3 1. 423 B. 6 C. 3 1. 424 B. 7 C. 3 1. 425 B. 8 C. 3 1. 426 B. 9 C. 3 1. 427 B. 10 C. 3 1. 428 B. 11 C. 3 1. 429 B. 12 C. 3 1. 430 B. 13 C. 3 1. 431 B. 14 C. 3 1. 432 B. 15 C. 3 1. 433 B. 16 C. 3 1. 434 B. 17 C. 3 1. 435 B. 18 C. 3 1. 436 B. 19 C. 3 1. 437 B. 20 C. 3 1. 438 B. 21 C. 3 1. 439 B. 22 C. 3 1. 440 B. 23 C. 3 1. 441 B. 24 C. 3 1. 442 B. 25 C. 3 1. 443 B. 26 C. 3 1. 444 B. 27 C. 3 150107. Doc -65- 201109321 Compound No. Herbicide B Safety Agent C 1. 445 B. 28 C. 3 1. 446 B. 29 C. 3 1. 447 B. 30 C. 3 1. 448 B. 31 C. 3 1. 449 B. 32 C. 3 1. 450 B. 33 C. 3 1. 451 B. 34 C. 3 1. 452 B. 35 C. 3 1. 453 B. 36 C. 3 1. 454 B. 37 C. 3 1. 455 B. 38 C. 3 1. 456 B. 39 C. 3 1. 457 B. 40 C. 3 1. 458 B. 41 C. 3 1. 459 B. 42 C. 3 1. 460 !Β·43 C. 3 1. 461 Β. 44 C. 3 1. 462 Β. 45 C. 3 1. 463 Β. 46 C. 3 1. 464 Β. 47 C. 3 1. 465 Β. 48 C. 3 1. 466 Β. 49 C. 3 1. 467 Β. 50 C. 3 1. 468 Β. 51 C. 3 1. 469 Β. 52 C. 3 1. 470 Β. 53 C. 3 1. 471 Β. 54 C. 3 1. 472 Β. 55 C. 3 1. 473 Β. 56 C. 3 1. 474 Β. 57 C. 3 1. 475 Β. 58. C. 3 1. 476 Β. 59 C. 3 1. 477 Β. 60 C. 3 1. 478 Β. 61 C. 3 1. 479 Β. 62 C. 3 1. 480 Β. 63 C. 3 1. 481 Β. 64 C. 3 1. 482 Β. 65 C. 3 1. 483 Β. 66 C. 3 1. 484 Β. 67 C. 3 1. 485 Β. 68 C. 3 Compound No. Herbicide Β Safety Agent C 1. 486 Β. 69 C. 3 1. 487 Β. 70 C. 3 1. 488 Β. 71 C. 3 1. 489 Β. 72 C. 3 1. 490 Β. 73 C. 3 1. 491 Β. 74 C. 3 1. 492 Β. 75 C. 3 1. 493 Β. 76 C. 3 1. 494 Β. 77 C. 3 1. 495 Β. 78 C. 3 1. 496 Β. 79 C. 3 1. 497 Β. 80 C. 3 1. 498 Β. 81 C. 3 1. 499 Β. 82 C. 3 1. 500 Β. 83 C. 3 1. 501 Β. 84 C. 3 1. 502 Β. 85 C. 3 1. 503 Β. 86 C. 3 1. 504 Β. 87 C. 3 1. 505 Β. 88 C. 3 1. 506 Β. 89 C. 3 1. 507 Β. 90 C. 3 1. 508 Β. 91 C. 3 1. 509 Β. 92 C. 3 1. 510 Β. 93 C. 3 1. 511 Β. 94 C. 3 1. 512 Β. 95 C. 3 1. 513 Β. 96 C. 3 1. 514 Β. 97 C. 3 1. 515 Β. 98 C. 3 1. 516 Β. 99 C. 3 1. 517 Β. 100 C. 3 1. 518 Β. 101 C. 3 1. 519 Β. 102 C. 3 1. 520 Β. 103 C. 3 1. 521 Β. 104 C. 3 1. 522 Β. 105 C. 3 1. 523 Β. 106 C. 3 1. 524 Β. 107 C. 3 1. 525 Β. 108 C. 3 1. 526 Β. 109 C. 3 Compound No. Herbicide Β Safety Agent C 1. 527 Β. 110 C. 3 1. 528 Β. 111 C. 3 1. 529 Β. 112 C. 3 1. 530 Β. 113 C. 3 1. 531 Β. 114 C. 3 1. 532 Β. 115 C. 3 1. 533 Β. 116 C. 3 1. 534 Β. 117 C. 3 1. 535 Β. 118 C. 3 1. 536 Β. 119 C. 3 1. 537 Β. 120 C. 3 1. 538 Β. 121 C. 3 1. 539 Β. 122 C. 3 1. 540 Β. 123 C. 3 1. 541 Β. 124 C. 3 1. 542 Β. 125 C. 3 1. 543 Β. 126 C. 3 1. 544 Β. 127 C. 3 1. 545 Β. 128 C. 3 1. 546 Β. 129 C. 3 1. 547 Β. 130 C. 3 1. 548 Β. 131 C. 3 1. 549 Β. 132 C. 3 1. 550 Β. 133 C. 3 1. 551 Β. 134 C. 3 1. 552 Β. 135 C. 3 1. 553 Β. 136 C. 3 1. 554 Β. 137 C. 3 1. 555 Β. 138 C. 3 1. 556 Β. 139 C. 3 1. 557 Β. 1 C. 4 1. 558 Β. 2 C. 4 1. 559 Β. 3 C. 4 1. 560 Β. 4 C. 4 1. 561 Β. 5 C. 4 1. 562 Β. 6 C. 4 1. 563 Β. 7 C. 4 1. 564 Β. 8 C. 4 1. 565 Β. 9 C. 4 1. 566 Β. 10 C. 4 1. 567 Β. 11 C. 4 150107. Doc -66- 201109321 Compound No. Herbicide B Safety Agent C 1. 568 B. 12 C. 4 1. 569 B. 13 C. 4 1. 570 B. 14 C. 4 1. 571 B. 15 C. 4 1. 572 B. 16 C. 4 1. 573 B. 17 C. 4 1. 574 B. 18 C. 4 1. 575 B. 19 C. 4 1. 576 B. 20 C. 4 1. 577 B. 21 C. 4 1. 578 B. 22 C. 4 1. 579 B. 23 C. 4 1. 580 B. 24 C. 4 1. 581 B. 25 C. 4 1. 582 B. 26 C. 4 1. 583 B. 27 C. 4 1. 584 B. 28 C. 4 1. 585 B. 29 C. 4 1. 586 B. 30 C. 4 1. 587 B. 31 C. 4 1. 588 B. 32 C. 4 1. 589 B. 33 C. 4 1. 590 B. 34 C. 4 1. 591 B. 35 C. 4 1. 592 B. 36 C. 4 1. 593 B. 37 C. 4 1. 594 B. 38 C. 4 1. 595 B. 39 C. 4 1. 596 B. 40 C. 4 1. 597 B. 41 C. 4 1. 598 B. 42 C. 4 1. 599 B. 43 C. 4 1. 600 B. 44 C. 4 1. 601 B. 45 C. 4 1. 602 B. 46 C. 4 1. 603 B. 47 C. 4 1. 604 B. 48 C. 4 1. 605 B. 49 C. 4 1. 606 B. 50 C. 4 1. 607 B. 51 C. 4 1. 608 B. 52 C. 4 Compound No. Herbicide B Safety Agent C 1. 609 B. 53 C. 4 1. 610 B. 54 C. 4 1. 611 B. 55 C. 4 1. 612 B. 56 C. 4 1. 613 B. 57 C. 4 1. 614 B. 58. C. 4 1. 615 . B. 59 C. 4 1. 616 B. 60 C. 4 1. 617 B. 61 C. 4 1. 618 B. 62 C. 4 1. 619 B. 63 C. 4 1. 620 B. 64 C. 4 1. 621 B. 65 C. 4 1. 622 B. 66 C. 4 1. 623 B. 67 C. 4 1. 624 B. 68 C. 4 1. 625 B. 69 C. 4 1. 626 B. 70 C. 4 1. 627 B. 71 C. 4 1. 628 B. 72 C. 4 1. 629 B. 73 C. 4 1. 630 B. 74 C. 4 1. 631 B. 75 C. 4 1. 632 B. 76 C. 4 1. 633 B. 77 C. 4 1. 634 B. 78 C. 4 1. 635 B. 79 C. 4 1. 636 B. 80 C. 4 1. 637 B. 81 C. 4 1. 638 B. 82 C. 4 1. 639 B. 83 C. 4 1. 640 B. 84 C. 4 1. 641 B. 85 C. 4 1. 642 B. 86 C. 4 1. 643 B. 87 C. 4 1. 644 B. 88 C. 4 1. 645 B. 89 C. 4 1. 646 B. 90 C. 4 1. 647 B. 91 C. 4 1. 648 B. 92 C. 4 1. 649 B. 93 C. 4 Compound No. Herbicide B Safety Agent C 1. 650 B. 94 C. 4 1. 651 B. 95 C. 4 1. 652 B. 96 C. 4 1. 653 B. 97 C. 4 1. 654 B. 98 C. 4 1. 655 B. 99 C. 4 1. 656 B. 100 C. 4 1. 657 B. 101 C. 4 1. 658 B. 102 C. 4 1. 659 B. 103 C. 4 1. 660 B. 104 C. 4 1. 661 B. 105 C. 4 1. 662 B. 106 C. 4 1. 663 B. 107 C. 4 1. 664 B. 108 C. 4 1. 665 B. 109 C. 4 1. 666 B. 110 C. 4 1. 667 B. 111 C. 4 1. 668 B. 112 C. 4 1. 669 B. 113 C. 4 1. 670 B. 114 C. 4 1. 671 B. 115 C. 4 1. 672 B. 116 C. 4 1. 673 B. 117 C. 4 1. 674 B. 118 C. 4 1. 675 B. 119 C. 4 1. 676 B. 120 C. 4 1. 677 B. 121 C. 4 1. 678 B. 122 C. 4 1. 679 B. 123 C. 4 1. 680 B. 124 C. 4 1. 681 B. 125 C. 4 1. 682 B. 126 C. 4 1. 683 B. 127 C. 4 1. 684 B. 128 C. 4 1. 685 B. 129 C. 4 1. 686 B. 130 C. 4 1. 687 B. 131 C. 4 1. 688 B. 132 C. 4 1. 689 B. 133 C. 4 1. 690 B. 134 C. 4 150107. Doc -67- 201109321 Compound No. Herbicide B Safety Agent C 1. 691 B. 135 C. 4 1. 692 B. 136 C. 4 1. 693 B. 137 C. 4 1. 694 B. 138 C. 4 1. 695 B. 139 C. 4 1. 696 B. 1 C. 5 1. 697 β. 2 C. 5 1. 698 Β. 3 C. 5 1. 699 Β. 4 C. 5 1. 700- Β. 5 C. 5 1. 701 Β. 6 C. 5 1. 702 Β. 7 C. 5 1. 703 Β. 8 C. 5 1. 704 Β. 9 C. 5 1. 705 Β. 10 C. 5 1. 706 Β. 11 C. 5 1. 707 Β. 12 C. 5 1. 708 Β. 13 C. 5 1. 709 Β. 14 C. 5 1. 710 Β. 15 C. 5 1. 711 Β. 16 C. 5 1. 712 Β. 17 C. 5 1. 713 Β. 18 C. 5 1. 714 Β. 19 C. 5 1. 715 Β. 20 C. 5 1. 716 Β. 21 C. 5 1. 717 Β. 22 C. 5 1. 718 Β. 23 C. 5 1. 719 Β. 24 C. 5 1. 720 Β. 25 C. 5 1. 721 Β. 26 C. 5 1. 722 Β. 27 C. 5 1. 723 Β. 28 C. 5 1. 724 Β. 29 C. 5 1. 725 Β. 30 C. 5 1. 726 Β. 31 C. 5 1. 727 Β. 32 C. 5 1. 728 Β. 33 C. 5 1. 729 Β. 34 C. 5 1. 730 Β. 35 C. 5 1. 731 Β. 36 C. 5 compound weeding safety number agent Β agent C 1. 732 Β. 37 C. 5 1. 733 Β. 38 C. 5 1. 734 Β. 39 C. 5 1. 735 Β. 40 C. 5 1. 736 Β. 41 C. 5 1. 737 Β. 42 C. 5 1. 738 Β. 43 C. 5 1. 739 Β. 44 C. 5 1. 740 Β. 45 C. 5 1. 741 Β. 46 C. 5 1. 742 Β. 47 C. 5 1. 743 Β. 48 C. 5 1. 744 Β. 49 C. 5 1. 745 Β. 50 C. 5 1. 746 Β. 51 C. 5 1. 747 Β. 52 C. 5 1. 748 Β. 53 C. 5 1. 749 Β. 54 C. 5 1. 750 Β. 55 C. 5 1. 751 Β. 56 C. 5 1. 752 Β. 57 C. 5 1. 753 Β. 58. C. 5 1. 754 Β. 59 C. 5 1. 755 Β. 60 C. 5 1. 756 Β. 61 C. 5 1. 757 Β. 62 C. 5 1. 758 Β. 63 C. 5 1. 759 Β. 64 C. 5 1. 760 Β. 65 C. 5 1. 761 Β. 66 C. 5 1. 762 Β. 67 C. 5 1. 763 Β. 68 C. 5 1. 764 Β. 69 C. 5 1. 765 Β. 70 C. 5 1. 766 Β. 71 C. 5 1. 767 Β. 72 C. 5 1. 768 Β. 73 C. 5 1. 769 Β. 74 C. 5 1. 770 Β. 75 C. 5 1. 771 Β. 76 C. 5 1. 772 Β. 77 C. 5 Compound No. Herbicide Β Safety Agent C 1. 773 Β. 78 C. 5 1. 774 Β. 79 C. 5 1. 775 Β. 80 C. 5 1. 776 Β. 81 C. 5 1. 777 Β. 82 C. 5 1. 778 Β. 83 C. 5 1. 779 Β. 84 C. 5 1. 780 Β. 85 C. 5 1. 781 Β. 86 C. 5 1. 782 Β. 87 C. 5 1. 783 Β. 88 C. 5 1. 784 Β. 89 C. 5 1. 785 Β. 90 C. 5 1. 786 Β. 91 C. 5 1. 787 Β. 92 C. 5 1. 788 Β. 93 C. 5 1. 789 Β. 94 C. 5 1. 790 Β. 95 C. 5 1. 791 Β. 96 C. 5 1. 792 Β. 97 C. 5 1. 793 Β. 98 C. 5 1. 794 Β. 99 C. 5 1. 795 Β. 100 C. 5 1. 796 Β. 101 C. 5 1. 797 Β. 102 C. 5 1. 798 Β. 103 C. 5 1. 799 Β. 104 C. 5 1. 800 Β. 105 C. 5 1. 801 Β. 106 C. 5 1. 802 Β. 107 C. 5 1. 803 Β. 108 C. 5 1. 804 Β. 109 C. 5 1. 805 Β. 110 C. 5 1. 806 Β. 111 C. 5 1. 807 Β. 112 C. 5 1. 808 Β. 113 C. 5 1. 809 Β. 114 C. 5 1. 810 Β. 115 C. 5 1. 811 Β. 116 C. 5 1. 812 Β. 117 C. 5 1. 813 Β. 118 C. 5 150I07. Doc -68* 201109321 Compound No. Herbicide B Safety Agent C 1. 814 B. 119 C. 5 1. 815 B. 120 C. 5 1. 816 B. 121 C. 5 1. 817 B. 122 C. 5 1. 818 B. 123 C. 5 1. 819 B. 124 C. 5 1. 820 B. 125 C. 5 1. 821 B. 126 C. 5 1. 822 B. 127 C. 5 1. 823 B. 128 C. 5 1. 824 B. 129 C. 5 1. 825 B. 130 C. 5 1. 826 B. 131 C. 5 1. 827 B. 132 C. 5 1. 828 B. 133 C. 5 1. 829 B. 134 C. 5 1. 830 B. 135 C. 5 1. 831 B. 136 C. 5 1. 832 B. 137 C. 5 1. 833 B. 138 C. 5 1. 834 B. 139 C. 5 1. 835 B. 1 C. 6 1. 836 B. 2 C. 6 1. 837 B. 3 C. 6 1. 838 B. 4 C. 6 1. 839 B. 5 C. 6 1. 840 B. 6 C. 6 1. 841 B. 7 C. 6 1. 842 B. 8 C. 6 1. 843 B. 9 C. 6 1. 844 B. 10 C. 6 1. 845 B. 11 C. 6 1. 846 B. 12 C. 6 1. 847 B. 13 C. 6 1. 848 B. 14 C. 6 1. 849 B. 15 C. 6 1. 850 B. 16 C. 6 1. 851 B. 17 C. 6 1. 852 B. 18 C. 6 1. 853 B. 19 C. 6 1. 854 B. 20 C. 6 Compound No. Herbicide B Safety Agent C 1. 855 B. 21 C. 6 1. 856 B. 22 C. 6 1. 857 B. 23 C. 6 1. 858 B. 24 C. 6 1. 859 B. 25 C. 6 1. 860 B. 26 C. 6 1. 861 B. 27 C. 6 1. 862 B. 28 C. 6 1. 863 B. 29 C. 6 1. 864 B. 30 C. 6 1. 865 B. 31 C. 6 1. 866 B. 32 C. 6 1. 867 B. 33 C. 6 1. 868 B. 34 C. 6 1. 869 B. 35 C. 6 1. 870 B. 36 C. 6 1. 871 B. 37 C. 6 1. 872 B. 38 C. 6 1. 873 B. 39 C. 6 1. 874 B. 40 C. 6 1. 875 B. 41 C. 6 1. 876 B. 42 C. 6 1. 877 B. 43 C. 6 1. 878 B. 44 C. 6 1. 879 B. 45 C. 6 1. 880 B. 46 C. 6 1. 881 B. 47 C. 6 1. 882 B. 48 C. 6 1. 883 B. 49 C. 6 1. 884 B. 50 C. 6 1. 885 B. 51 C. 6 1. 886 B. 52 C. 6 1. 887 B. 53 C. 6 1. 888 B. 54 C. 6 1. 889 B. 55 C. 6 1. 890 B. 56 C. 6 1. 891 B. 57 C. 6 1. 892 B. 58. C. 6 1. 893 B. 59 C. 6 1. 894 B. 60 C. 6 1. 895 B. 61 C. 6 Compound No. Herbicide B Safety Agent C 1. 896 B. 62 C. 6 1. 897 B. 63 C. 6 1. 898 B. 64 C. 6 1. 899 B. 65 C. 6 1. 900 B. 66 C. 6 1. 901 B. 67 C. 6 1. 902 B. 68 C. 6 1. 903 B. 69 C. 6 1. 904 B. 70 C. 6 1. 905 B. 71 C. 6 1. 906 B. 72 C. 6 1. 907 B. 73 C. 6 1. 908 B. 74 C. 6 1. 909 B. 75 C. 6 1. 910 B. 76 C. 6 1. 911 B. 77 C. 6 1. 912 B. 78 C. 6 1. 913 B. 79 C. 6 1. 914 B. 80 C. 6 1. 915 B. 81 C. 6 1. 916 B. 82 C. 6 1. 917 B. 83 C. 6 1. 918 B. 84 C. 6 1. 919 B. 85 C. 6 1. 920 B. 86 C. 6 1. 921 B. 87 C. 6 1. 922 B. 88 C. 6 1. 923 B. 89 C. 6 1. 924 B. 90 C. 6 1. 925 B. 91 C. 6 1. 926 B. 92 C. 6 1. 927 B. 93 C. 6 1. 928 B. 94 C. 6 1. 929 B. 95 C. 6 1. 930 B. 96 C. 6 1. 931 B. 97 C. 6 1. 932 B. 98 C. 6 1. 933 B. 99 C. 6 1. 934 B. 100 C. 6 1. 935 B. 101 C. 6 1. 936 B. 102 C. 6 150107. Doc -69- 201109321 Compound No. Herbicide B Safety Agent C 1. 937 B. 103 C. 6 1. 938 B. 104 C. 6 1. 939 B. 105 C. 6 1. 940 B. 106 C. 6 1. 941 B. 107 C. 6 1. 942 B. 108 C. 6 1. 943 B. 109 C. 6 1. 944 B. 110 C. 6 1. 945 B. 111 C. 6 1. 946 B. 112 C. 6 1. 947 B. 113 C. 6 1. 948 B. 114 C. 6 1. 949 B. 115 C. 6 1. 950 B. 116 C. 6 1. 951 B. 117 C. 6 1. 952 B. 118 C. 6 1. 953 B. 119 C. 6 1. 954 B. 120 C. 6 1. 955 B. 121 C. 6 1. 956 B. 122 C. 6 1. 957 B. 123 C. 6 1. 958 B. 124 C. 6 1. 959 B. 125 C. 6 1. 960 B. 126 C. 6 1. 961 B. 127 C. 6 1. 962 B. 128 C. 6 1. 963 B. 129 C. 6 1. 964 B. 130 C. 6 1. 965 B. 131 C. 6 1. 966 B. 132 C. 6 1. 967 B. 133 C. 6 1. 968 B. 134 C. 6 1. 969 B. 135 C. 6 1. 970 B. 136 C. 6 1. 971 B. 137 C. 6 1. 972 B. 138 C. 6 1. 973 B. 139 C. 6 1. 974 B. 1 C. 7 1. 975 B. 2 C. 7 1. 976 B. 3 C. 7 1. 977 B. 4 C. 7 Compound No. Herbicide B Safety Agent C 1. 978 B. 5 C. 7 1. 979 B. 6 C. 7 1. 980 B. 7 C. 7 1. 981 B. 8 C. 7 1. 982 B. 9 C. 7 1. 983 B. 10 C. 7 1. 984 B. 11 C. 7 1. 985 B. 12 C. 7 1. 986 B. 13 C. 7 1. 987 B. 14 C. 7 1. 988 B. 15 C. 7 1. 989 B. 16 C. 7 1. 990 B. 17 C. 7 1. 991 B. 18 C. 7 1. 992 B. 19 C. 7 1. 993 B. 20 C. 7 1. 994 B. 21 C. 7 1. 995 B. 22 C. 7 1. 996 B. 23 C. 7 1. 997 B. 24 C. 7 1. 998 B. 25 C. 7 1. 999 B. 26 C. 7 1. 1000 B. 27 C. 7 1. 1001 B. 28 C. 7 1. 1002 B. 29 C. 7 1. 1003 B. 30 C. 7 1. 1004 B. 31 C. 7 1. 1005 B. 32 C. 7 1. 1006 B. 33 C. 7 1. 1007 B. 34 C. 7 1. 1008 B. 35 C. 7 1. 1009 B. 36 C. 7 1. 1010 B. 37 C. 7 1. 1011 B. 38 C. 7 1. 1012 B. 39 C. 7 1. 1013 B. 40 C. 7 1. 1014 B. 41 C. 7 1. 1015 B. 42 C. 7 1. 1016 B. 43 C. 7 1. 1017 B. 44 C. 7 1. 1018 B. 45 C. 7 Compound No. Herbicide B Safety Agent C 1. 1019 B. 46 C. 7 1. 1020 B. 47 C. 7 1. 1021 B. 48 C. 7 1. 1022 B. 49 C. 7 1. 1023 B. 50 C. 7 1. 1024 B. 51 C. 7 1. 1025 B. 52 C. 7 1. 1026 B. 53 C. 7 1. 1027 B. 54 C. 7 1. 1028 B. 55 C. 7 1. 1029 B. 56 C. 7 1. 1030 B. 57 C. 7 1. 1031 B. 58. C. 7 1. 1032 B. 59 C. 7 1. 1033 B. 60 C. 7 1. 1034 B. 61 C. 7 1. 1035 B. 62 C. 7 1. 1036 B. 63 C. 7 1. 1037 B. 64 C. 7 1. 1038 B. 65 C. 7 1. 1039 B. 66 C. 7 1. 1040 B. 67 C. 7 1. 1041 B. 68 C. 7 1. 1042 B. 69 C. 7 1. 1043 B. 70 C. 7 1. 1044 B. 71 C. 7 1. 1045 B. 72 C. 7 1. 1046 B. 73 C. 7 1. 1047 B. 74 C. 7 1. 1048 B. 75 C. 7 1. 1049 B. 76 C. 7 1. 1050 B. 77 C. 7 1. 1051 B. 78 C. 7 1. 1052 B. 79 C. 7 1. 1053 B. 80 C. 7 1. 1054 B. 81 C. 7 1. 1055 B. 82 C. 7 1. 1056 B. 83 C. 7 1. 1057 B. 84 C. 7 1. 1058 B. 85 C. 7 1. 1059 B. 86 C. 7 150107. Doc -70- 201109321 Compound No. Herbicide B Safety Agent C 1. 1060 B. 87 C. 7 1. 1061 B. 88 C. 7 1. 1062 B. 89 C. 7 1. 1063 B. 90 C. 7 1. 1064 B. 91 C. 7 1. 1065 B. 92 C. 7 1. 1066 B. 93 C. 7 1. 1067 B. 94 C. 7 1. 1068 B. 95 C. 7 1. 1069 B. 96 C. 7 1. 1070 B. 97 C. 7 1. 1071 B. 98 C. 7 1. 1072 B. 99 C. 7 1. 1073 B. 100 C. 7 1. 1074 B. 101 C. 7 1. 1075 B. 102 C. 7 1. 1076 B. 103 C. 7 1. 1077 B. 104 C. 7 1. 1078 B. 105 C. 7 1. 1079 B. 106 C. 7 1. 1080 B. 107 C. 7 1. 1081 B. 108 C. 7 1. 1082 B. 109 C. 7 1. 1083 B. 110 C. 7 1. 1084 B. 111 C. 7 1. 1085 B. 112 C. 7 1. 1086 B. 113 C. 7 1. 1087 B. 114 C. 7 1. 1088 B. 115 C. 7 1. 1089 B. 116 C. 7 1. 1090 B. 117 C. 7 1. 1091 B. 118 C. 7 1. 1092 B. 119 C. 7 1. 1093 B. 120 C. 7 1. 1094 B. 121 C. 7 1. 1095 B. 122 C. 7 1. 1096 B. 123 C. 7 1. 1097 B. 124 C. 7 1. 1098 B. 125 C. 7 1. 1099 B. 126 C. 7 1. 1100 B. 127 C. 7 Compound No. Herbicide B Safety Agent C 1. 1101 B. 128 C. 7 1. 1102 B. 129 C. 7 1. 1103 B. 130 C. 7 1. 1104 B. 131 C. 7 1. 1105 B. 132 C. 7 1. 1106 B. 133 C. 7 1. 1107 B. 134 C. . 7 1. 1108 B. 135 C. 7 1. 1109 B. 136 C. 7 1. 1110 B. 137 C. 7 1. 1111 B. 138 C. 7 1. 1112 B. 139 C. 7 1. 1113 B. 1 C. 8 1. 1114 B. 2 C. 8 1. 1115 B. 3 C. 8 1. 1116 B. 4 C. 8 1. 1117 B. 5 C. 8 1. 1118 B. 6 C. 8 1. 1119 B. 7 C. 8 1. 1120 B. 8 C. 8 1. 1121 B. 9 C. 8 1. 1122 B. 10 C. 8 1. 1123 B. 11 C. 8 1. 1124 B. 12 C. 8 1. 1125 B. 13 C. 8 1. 1126 B. 14 C. 8 1. 1127 B. 15 C. 8 1. 1128 B. 16 C. 8 1. 1129 B. 17 C. 8 1. 1130 B. 18 C. 8 1. 1131 B. 19 C. 8 1. 1132 B. 20 C. 8 1. 1133 B. 21 C. 8 1. 1134 B. 22 C. 8 1. 1135 B. 23 C. 8 1. 1136 B. 24 C. 8 1. 1137 B. 25 C. 8 1. 1138 B. 26 C. 8 1. 1139 B. 27 C. 8 1. 1140 B. 28 C. 8 1. 1141 B. 29 C. 8 Compound No. Herbicide B Safety Agent C 1. 1142 B. 30 C. 8 1. 1143 B. 31 C. 8 1. 1144 B. 32 C. 8 1. 1145 B. 33 C. 8 1. 1146 B. 34 C. 8 1. 1147 B. 35 C. 8 1. 1148 B. 36 C. 8 1. 1149 B. 37 C. 8 1. 1150 B. 38 C. 8 1. 1151 B. 39 C. 8 1. 1152 B. 40 C. 8 1. 1153 B. 41 C. 8 1. 1154 B. 42 C. 8 1. 1155 B. 43 C. 8 1. 1156 B. 44 C. 8 1. 1157 B. 45 C. 8 1. 1158 B. 46 C. 8 1. 1159 B. 47 C. 8 1. 1160 B. 48 C. 8 1. 1161 B. 49 C. 8 1. 1162 B. 50 C. 8 1. 1163 B. 51 C. 8 1. 1164 B. 52 C. 8 1. 1165 B. 53 C. 8 1. 1166 B. 54 C. 8 1. 1167 B. 55 C. 8 1. 1168 B. 56 C. 8 1. 1169 B. 57 C. 8 1. 1170 B. 58. C. 8 1. 1171 B. 59 C. 8 1. 1172 B. 60 C. 8 1. 1173 B. 61 C. 8 1. 1174 B. 62 C. 8 1. 1175 B. 63 C. 8 1. 1176 B. 64 C. 8 1. 1177 B. 65 C. 8 1. 1178 B. 66 C. 8 1. 1179 B. 67 C. 8 1. 1180 B. 68 C. 8 1. 1181 B. 69 C. 8 1. 1182 B. 70 C. 8 150107. Doc -71 - 201109321 Compound No. Herbicide Β Safety Agent C 1. 1183 Β. 71 C. 8 1. 1184 Β. 72 C. 8 1. 1185 Β. 73 C. 8 1. 1186 Β. 74 C. 8 1. 1187 Β. 75 C. 8 1. 1188 Β. 76 C. 8 1. 1189 Β. 77 C. 8 1. 1190 Β. 78 C. 8 1. 1191 Β. 79 C. 8 1. 1192 Β. 80 C. 8 1. 1193 Β. 81 C. 8 1. 1194 Β. 82 C. 8 1. 1195 Β. 83 C. 8 1. 1196 Β. 84 C. 8 1. 1197 Β. 85 C. 8 1. 1198 Β. 86 C. 8 1. 1199 Β. 87 C. 8 1. 1200 Β. 88 C. 8 1. 1201 Β. 89 C. 8 1. 1202 Β. 90 C. 8 1. 1203 Β. 91 C. 8 1. 1204 Β. 92 C. 8 1. 1205 Β. 93 C. 8 1. 1206 Β. 94 C. 8 1. 1207 Β. 95 C. 8 1. 1208 Β. 96 C. 8 1. 1209 Β. 97 C. 8 1. 1210 Β. 98 C. 8 1. 1211 Β. 99 C. 8 1. 1212 Β. 100 C. 8 1. 1213 Β. 101 C. 8 1. 1214 Β. 102 C. 8 1. 1215 Β. 103 C. 8 1. 1216 Β. 104 C. 8 1. 1217 Β. 105 C. 8 1. 1218 Β. 106 C. 8 1. 1219 Β. 107 C. 8 1. 1220 Β. 108 C. 8 1. 1221 Β. 109 C. 8 1. 1222 Β. 110 C. 8 1. 1223 Β. 111 C. 8 Compound No. Herbicide Β Safety Agent C 1. 1224 Β. 112 C. 8 1. 1225 Β. 113 C. 8 1. 1226 Β. 114 C. 8 1. 1227 Β. 115 C. 8 1. 1228 Β. 116 C. 8 1. 1229 Β. 117 C. 8 1. 1230 Β. 118 C. 8 1. 1231 Β. 119 C. 8 1. 1232 Β. 120 C. 8 1. 1233 Β. 121 C. 8 1. 1234 Β. 122 C. 8 1. 1235 Β. 123 C. 8 1. 1236 Β. 124 C. 8 1. 1237 Β. 125 C. 8 1. 1238 Β. 126 C. 8 1. 1239 Β. 127 C. 8 1. 1240 Β. 128 C. 8 1. 1241 Β. 129 C. 8 1. 1242 Β. 130 C. 8 1. 1243 Β. 131 C. 8 1. 1244 Β. 132 C. 8 1. 1245 Β. 133 C. 8 1. 1246 Β. 134 C. 8 1. 1247 Β. 135 C. 8 1. 1248 Β. 136 C. 8 1. 1249 Β. 137 C. 8 1. 1250 Β. 138 C. 8 1. 1251 Β. 139 C. 8 1. 1252 Β. 1 C. 9 1. 1253 Β. 2 C. 9 1. 1254 Β. 3 C. 9 1. 1255 Β. 4 C. 9 1. 1256 Β. 5 C. 9 1. 1257 Β. 6 C. 9 1. 1258 Β. 7 C. 9 1. 1259 Β. 8 C. 9 1. 1260 Β. 9 C. 9 1. 1261 Β. 10 C. 9 1. 1262 Β. 11 C. 9 1. 1263 Β. 12 C. 9 1. 1264 Β. 13 C. 9 Compound No. Herbicide Β Safety Agent C 1. 1265 Β. 14 C. 9 1. 1266 Β. 15 C. 9 1. 1267 Β. 16 C. 9 1. 1268 Β. 17 C. 9 1. 1269 Β. 18 C. 9 1. 1270 Β. 19 C. 9 1. 1271 Β. 20 C. 9 1. 1272 Β. 21 C. 9 1. 1273 Β. 22 C. 9 1. 1274 Β. 23 C. 9 1. 1275 Β. 24 C. 9 1. 1276 Β. 25 C. 9 1. 1277 Β. 26 C. 9 1. 1278 Β. 27 C. 9 1. 1279 Β. 28 C. 9 1. 1280 Β. 29 C. 9 1. 1281 Β. 30 C. 9 1. 1282 Β. 31 C. 9 1. 1283 Β. 32 C. 9 1. 1284 Β. 33 C. 9 1. 1285 Β. 34 C. 9 1. 1286 Β. 35 C. 9 1. 1287 Β. 36 C. 9 1. 1288 Β. 37 C. 9 1. 1289 Β. 38 C. 9 1. 1290 Β. 39 C. 9 1. 1291 Β. 40 C. 9 1. 1292 Β. 41 C. 9 1. 1293 Β. 42 C. 9 1. 1294 Β. 43 C. 9 1. 1295 Β. 44 C. 9 1. 1296 Β. 45 C. 9 1. 1297 Β. 46 C. 9 1. 1298 Β. 47 C. 9 1. 1299 Β. 48 C. 9 1. 1300 Β. 49 C. 9 1. 1301 Β. 50 C. 9 1. 1302 Β. 51 C. 9 1. 1303 Β. 52 C. 9 1. 1304 Β. 53 C. 9 1. 1305 Β. 54 C. 9 150107. Doc ·72· 201109321 Compound No. Herbicide B Safety Agent C 1. 1306 B. 55 C. 9 1. 1307 B. 56 C. 9 1. 1308 B. 57 C. 9 1. 1309 B. 58. C. 9 1. 1310 B. 59 C. 9 1. 1311 B. 60 C. 9 1. 1312 B. 61 C. 9 1. 1313 B. 62 C. 9 1. 1314 B. 63 C. 9 1. 1315 B. 64 C. 9 1. 1316 B. 65 C. 9 1. 1317 B. 66 C. 9 1. 1318 B. 67 C. 9 1. 1319 B. 68 C. 9 1. 1320 B. 69 C. 9 1. 1321 B. 70 C. 9 1. 1322 B. 71 C. 9 1. 1323 B. 72 C. 9 1. 1324 B. 73 C. 9 1. 1325 B. 74 C. 9 1. 1326 B. 75 C. 9 1. 1327 B. 76 C. 9 1. 1328 B. 77 C. 9 1. 1329 B. 78 C. 9 1. 1330 B. 79 C. 9 1. 1331 B. 80 C. 9 1. 1332 B. 81 C. 9 1. 1333 B. 82 C. 9 1. 1334 B. 83 C. 9 1. 1335 B. 84 C. 9 1. 1336 B. 85 C. 9 1. 1337 B. 86 C. 9 1. 1338 B. 87 C. 9 1. 1339 B. 88 C. 9 1. 1340 B. 89 C. 9 1. 1341 B. 90 C. 9 1. 1342 B. 91 C. 9 1. 1343 B. 92 C. 9 1. 1344 B. 93 C. 9 1. 1345 B. 94 C. 9 1. 1346 B. 95 C. 9 Compound No. Herbicide B Safety Agent C 1. 1347 B. 96 C. 9 1. 1348 B. 97 C. 9 1. 1349 B. 98 C. 9 1. 1350 B. 99 C. 9 1. 1351 B. 100 C. 9 1. 1352 B. 101 C. 9 1. 1353 B. 102 C. 9 1. 1354 B. 103 C. 9 1. 1355 B. 104 C. 9 1. 1356 B. 105 C. 9 1. 1357 B. 106 C. 9 1. 1358 B. 107 C. 9 1. 1359 B. 108 C. 9 1. 1360 B. 109 C. 9 1. 1361 B. 110 C. 9 1. 1362 B. 111 C. 9 1. 1363 B. 112 C. 9 1. 1364 B. 113 C. 9 1. 1365 B. 114 C. 9 1. 1366 B. 115 C. 9 1. 1367 B. 116 C. 9 1. 1368 B. 117 C. 9 1. 1369 B. 118 C. 9 1. 1370 B. 119 C. 9 1. 1371 B. 120 C. 9 1. 1372 B. 121 C. 9 1. 1373 B. 122 C. 9 1. 1374 B. 123 C. 9 1. 1375 B. 124 C. 9 1. 1376 B. 125 C. 9 1. 1377 B. 126 C. 9 1. 1378 B. 127 C. 9 1. 1379 B. 128 C. 9 1. 1380 B. 129 C. 9 1. 1381 B. 130 C. 9 1. 1382 B. 131 C. 9 1. 1383 B. 132 C. 9 1. 1384 B. 133 C. 9 1. 1385 B. 134 C. 9 1. 1386 B. 135 C. 9 1. 1387 B. 136 C. 9 Compound No. Herbicide B Safety Agent C 1. 1388 B. 137 C. 9 1. 1389 B. 138 C. 9 1. 1390 B. 139 C. 9 1. 1391 B. 1 C. 10 1. 1392 B. 2 C. 10 1. 1393 B. 3 C. 10 1. 1394 B. 4 C. 10 1. 1395 B. 5 C. 10 1. 1396 B. 6 C. 10 1. 1397 B. 7 C. 10 1. 1398 B. 8 C. 10 1. 1399 B. 9 C. 10 1. 1400 B. 10 C. 10 1. 1401 B. 11 C. 10 1. 1402 B. 12 C. 10 1. 1403 B. 13 C. 10 1. 1404 B. 14 C. 10 1. 1405 B. 15 C. 10 1. 1406 B. 16 C. 10 1. 1407 B. 17 C. 10 1. 1408 B. 18 C. 10 1. 1409 B. 19 C. 10 1. 1410 B. 20 C. 10 1. 1411 B. 21 C. 10 1. 1412 B. 22 C. 10 1. 1413 B. 23 C. 10 1. 1414 B. 24 C. 10 1. 1415 B. 25 C. 10 1. 1416 B. 26 C. 10 1. 1417 B. 27 C. 10 1. 1418 B. 28 C. 10 1. 1419 B. 29 C. 10 1. 1420 B. 30 C. 10 1. 1421 B. 31 C. 10 1. 1422 B. 32 C. 10 1. 1423 B. 33 C. 10 1. 1424 B. 34 C. 10 1. 1425 B. 35 C. 10 1. 1426 B. 36 C. 10 1. 1427 B. 37 C. 10 1. 1428 B. 38 C. 10 150107. Doc •73- 201109321 Compound No. Herbicide B Safety Agent C 1. 1429 B. 39 C. 10 3. 1430 B. 40 C. 10 1. 1431 B. 41 C. 10 1. 1432 B. 42 C. 10 1. 1433 ιΒ. 43 C. 10 1. 1434 B. 44 C. 10 1. 1435 B. 45 C. 10 1. 1436 B. 46 C. 10 1. 1437 B. 47 C. 10 1. 1438 B. 48 C. 10 1. 1439 B. 49 C. 10 1. 1440 B. 50 C. 10 1. 1441 B. 51 C. 10 1. 1442 B. 52 C. 10 1. 1443 B. 53 C. 10 1. 1444 B. 54 C. 10 1. 1445 B. 55 C. 10 1. 1446 B. 56 C. 10 1. 1447 B. 57 C. 10 1. 1448 B. 58. C. 10 1. 1449 B. 59 C. 10 1. 1450 B. 60 C. 10 1. 1451 B. 61 C. 10 1. 1452 B. 62 C. 10 1. 1453 B. 63 C. 10 1. 1454 B. 64 C. 10 1. 1455 B. 65 C. 10 1. 1456 B. 66 C. 10 1. 1457 B. 67 C. 10 1. 1458 B. 68 C. 10 1. 1459 B. 69 C. 10 1. 1460 B. 70 C. 10 1. 1461 B. 71 C. 10 1. 1462 B. 72 C. 10 1. 1463 B. 73 C. 10 1. 1464 B. 74 C. 10 1. 1465 B. 75 C. 10 1. 1466 B. 76 C. 10 1. 1467 B. 77 C. 10 1. 1468 B. 78 C. 10 1. 1469 B. 79 C. 10 Compound No. Herbicide B Safety Agent C 1. 1470 B. 80 C. 10 1. 1471 B. 81 C. 10 1. 1472 B. 82 C. 10 1. 1473 B. 83 C. 10 1. 1474 B. 84 C. 10 1. 1475 B. 85 C. 10 1. 1476 B. 86 C. 10 1. 1477 B. 87 C. 10 1. 1478 B. 88 C. 10 1. 1479 B. 89 C. 10 1. 1480 B. 90 C. 10 1. 1481 B. 91 C. 10 1. 1482 B. 92 C. 10 1. 1483 B. 93 C. 10 1. 1484 B. 94 C. 10 1. 1485 B. 95 C. 10 1. 1486 B. 96 C. 10 1. 1487 B. 97 C. 10 1. 1488 B. 98 C. 10 1. 1489 B. 99 C. 10 1. 1490 B. 100 C. 10 1. 1491 B. 101 C. 10 1. 1492 B. 102 C. 10 1. 1493 B. 103 C. 10 1. 1494 B. 104 C. 10 1. 1495 B. 105 C. 10 1. 1496 B. 106 C. 10 1. 1497 B. 107 C. 10 1. 1498 B. 108 C. 10 1. 1499 B. 109 C. 10 1. 1500 B. 110 C. 10 1. 1501 B. 111 C. 10 1. 1502 B. 112 C. 10 1. 1503 B. 113 C. 10 1. 1504 B. 114 C. 10 1. 1505 B. 115 C. 10 1. 1506 B. 116 C. 10 1. 1507 B. 117 C. 10 1. 1508 B. 118 C. 10 1. 1509 B. 119 C. 10 1. 1510 B. 120 C. 10 Compound No. Herbicide B Safety Agent C 1. 1511 B. 121 C. 10 1. 1512 B. 122 C. 10 1. 1513 B. 123 C. 10 1. 1514 B. 124 C. 10 1. 1515 B. 125 C. 10 1. 1516 B. 126 C. 10 1. 1517 B. 127 C. 10 1. 1518 B. 128 C. 10 1. 1519 B. 129 C. 10 1. 1520 B. 130 C. 10 1. 1521 B. 131 C. 10 1. 1522 B. 132 C. 10 1. 1523 B. 133 C. 10 1. 1524 B. 134 C. 10 1. 1525 B. 135 C. 10 1. 1526 B. 136 C. 10 1. 1527 B. 137 C. 10 1. 1528 B. 138 C. 10 1. 1529 B. 139 C. 10 1. 1530 B. 1 C. 11 1. 1531 B. 2 C. 11 1. 1532 B. 3 C. 11 1. 1533 B. 4 C. 11 1. 1534 B. 5 C. 11 1. 1535 B. 6 C. 11 1. 1536 B. 7 C. 11 1. 1537 B. 8 C. 11 1. 1538 B. 9 C. 11 1. 1539 B. 10 C. 11 1. 1540 B. 11 C. 11 1. 1541 B. 12 C. 11 1. 1542 B. 13 C. 11 1. 1543 B. 14 C. 11 1. 1544 B. 15 C. 11 1. 1545 B. 16 C. 11 1. 1546 B. 17 C. 11 1. 1547 B. 18 C. 11 1. 1548 B. 19 C. 11 1. 1549 B. 20 C. 11 1. 1550 B. 21 C. 11 1. 1551 B. 22 C. 11 150107. Doc -74- 201109321 Compound No. Herbicide B Safety Agent C 1. 1552 B. 23 C. 11 1. 1553 B. 24 C. 11 1. 1554 B. 25 C. 11 1. 1555 B. 26 C. 11 1. 1556 B. 27 C. 11 1. 1557 B. 28 C. 11 1. 1558 B. 29 C. 11 1. 1559 B. 30 C. 11 1. 1560 B. 31 C. 11 1. 1561 B. 32 C. 11 1. 1562 B. 33 C. 11 1. 1563 B. 34 C. 11 1. 1564 B. 35 C. 11 1. 1565 B. 36 C. 11 1. 1566 B. 37 C. 11 1. 1567 B. 38 C. 11 1. 1568 B. 39 C. 11 1. 1569 B. 40 C. 11 1. 1570 B. 41 C. 11 1. 1571 B. 42 C. 11 1. 1572 B. 43 C. 11 1. 1573 B. 44 C. 11 1. 1574 B. 45 C. 11 1. 1575 B. 46 C. 11 1. 1576 B. 47 C. 11 1. 1577 B. 48 C. 11 1. 1578 B. 49 C. 11 1. 1579 B. 50 C. 11 1. 1580 B. 51 C. 11 1. 1581 B. 52 C. 11 1. 1582 B. 53 C. 11 1. 1583 B. 54 C. 11 1. 1584 B. 55 C. 11 1. 1585 B. 56 C. 11 1. 1586 B. 57 C. 11 1. 1587 B. 58. C. 11 1. 1588 B. 59 C. 11 1. 1589 B. 60 C. 11 1. 1590 B. 61 C. 11 1. 1591 B. 62 C. 11 1. 1592 B. 63 C. 11 Compound No. Herbicide B Safety Agent C 1. 1593 B. 64 C. 11 1. 1594 B. 65 C. 11 1. 1595 B. 66 C. 11 1. 1596 B. 67 C. 11 1. 1597 B. 68 C. 11 1. 1598 B. 69 C. 11 1. 1599 B. 70 C. 11 1. 1600 B. 71 C. 11 1. 1601 B. 72 C. 11 1. 1602 B. 73 C. 11 1. 1603 B. 74 C. 11 1. 1604 B. 75 C. 11 1. 1605 B. 76 C. 11 1. 1606 B. 77 C. 11 1. 1607 B. 78 C. 11 1. 1608 B. 79 C. 11 1. 1609 B. 80 C. 11 1. 1610 B. 81 C. 11 1. 1611 B. 82 C. 11 1. 1612 B. 83 C. 11 1. 1613 B. 84 C. 11 1. 1614 B. 85 C. 11 1. 1615 B. 86 C. 11 1. 1616 B. 87 C. 11 1. 1617 B. 88 C. 11 1. 1618 B. 89 C. 11 1. 1619 B. 90 C. 11 1. 1620 B. 91 C. 11 1. 1621 B. 92 C. 11 1. 1622 B. 93 C. 11 1. 1623 B. 94 C. 11 1. 1624 B. 95 C. 11 1. 1625 B. 96 C. 11 1. 1626 B. 97 C. 11 1. 1627 B. 98 C. 11 1. 1628 B. 99 C. 11 1. 1629 B. 100 C. 11 1. 1630 B. 101 C. 11 1. 1631 B. 102 C. 11 1. 1632 B. 103 C. 11 1. 1633 B. 104 C. 11 Compound No. Herbicide B Safety Agent C 1. 1634 B. 105 C. 11 1. 1635 B. 106 C. 11 1. 1636 B. 107 C. 11 1. 1637 B. 108 C. 11 1. 1638 B. 109 C. 11 1. 1639 B. 110 C. 11 1. 1640 B. 111 C. 11 1. 1641 B. 112 C. 11 1. 1642 B. 113 C. 11 1. 1643 B. 114 C. 11 1. 1644 B. 115 C. 11 1. 1645 B. 116 C. 11 1. 1646 B. 117 C. 11 1. 1647 B. 118 C. 11 1. 1648 B. 119 C. 11 1. 1649 B. 120 C. 11 1. 1650 B. 121 C. 11 1. 1651 B. 122 C. 11 1. 1652 B. 123 C. 11 1. 1653 B. 124 C. 11 1. 1654 B. 125 C. 11 1. 1655 B. 126 C. 11 1. 1656 B. 127 C. 11 1. 1657 B. 128 C. 11 1. 1658 B. 129 C. 11 1. 1659 B. 130 C. 11 1. 1660 B. 131 C. 11 1. 1661 B. 132 C. 11 1. 1662 B. 133 C. 11 1. 1663 B. 134 C. 11 1. 1664 B. 135 C. 11 1. 1665 B. 136 C. 11 1. 1666 B. 137 C. 11 1. 1667 B. 138 C. 11 1. 1668 B. 139 C. 11 150I07. Doc -75- 201109321 The specific numbering of each individual composition can be derived as follows: For example, composition 1. 777 contains benzoxanthene I. Μ, Fluroxylysone (Β·82) and grass bite (c. 5) (See Table 1, entry 1. 777 ; and the form, item B. 82 and table c ’ entry c. 5). For example, composition 2 777 contains stupid and arsenic ketone 121 (see below for, and δ, 2. 1 to 2. Definition of 1668), fluoroπ oxalicone (b. 82) and grass bites (C. 5) (See Table i, entry i 777; and Table Β, entry Β 82 and table c, entry C. 5). For example, 5, composition 7. 777 contains oxalate (Β2) (see below for composition 7. 1 to 7. Definition of 1668), and benzoxanthene [hl, gas slightly grass Ming (Β. 82) and oxadiadine (C. 5) (See Table 1, entry 1. 777 ; and performance, item Β 82 and table C, entry c. 5). ' Also preferred is the composition 2. 1 to 2. 1668, which is associated with the corresponding composition ^ to 1. The only difference between 1668 is that it contains a benzoxanthene compound. / Also especially good for the composition H 3. 1668, its corresponding composition! The only difference to Μ 668 is that it contains a benzoxanthene compound. Also especially preferred is the composition to 4. 1668, and its corresponding combination (6) 1. The only difference between 1668 is that it contains benzophenazine compounds! 3 compound A. Two are also preferred compositions. 1 to 5. 1668 s and its corresponding combination %ΐι 1. The only difference between 1668 is that it contains a benzoxanthone compound. ',, South 150107. Doc •76- 201109321 Also the best combination is “to 6.” 1668, which is associated with the corresponding composition π 1. The only difference between 1668 is that it contains the benzoxanthone compound m as the active compound hydrazine. Also especially preferred are compositions 7·1 to 7. Deleted, with the corresponding composition hl to 1. The difference between 1668 is that it additionally contains B 2 as the additional herbicide b. Also preferred are compositions 8" to 8. Delete, and its corresponding composition " to 1. The difference between 1668 is that it contains B. 7 as another herbicide B. Also preferred are compositions 9] to 9. Li, and its corresponding composition ι" to 1. The difference between 1668 is that it additionally contains Β· is another herbicide, and is also preferred to composition 1 (Μ1 to 1668, which is associated with the corresponding composition) to 1. The difference between 1668 is that the material contains B 3 () as another herbicide b. Also preferred is the composition mu. 1668, which is associated with the corresponding composition i" to 1. The difference between 1668 is that it additionally contains B 31 as another herbicide b. Also preferred are compositions 12" to 12. 1668, its corresponding composition! To 1. The difference between 1668 is that it additionally contains B 32 as the additional herbicide b. Also preferred is the composition m 13. 1668, which is associated with the corresponding composition i" to 1. The difference between 1668 is that it additionally contains B 33 as the additional herbicide b. Also preferred are compositions which are associated with the corresponding compositions (to 1. 1668 differs only in that it additionally contains B 4 〇 as another herbicide b. Also especially good for the composition! U15_1668' and its corresponding combination ❸^ to 1. The only difference is that it additionally contains B 44 as another herbicide b. . Also preferred is the composition of the composition 16. 116·1668, which is associated with the corresponding composition ^ ^ to 1. The difference of 1668 is only that it additionally contains 丨45 as another herbicide b. · Also preferred is the composition 17_H7_1668, which is associated with the corresponding composition] [150107. Doc -77- 201109321 to 1. The difference between 1668 is that it additionally contains B 52 as the additional herbicide b. Also preferred are compositions 18" to 18. Discussion, 丨 and the corresponding composition i" to 1. The difference between 1668 is that it additionally contains B53 as another herbicide b. Also preferred are compositions 19" to 19, 1668, which are associated with the corresponding compositions i" to 1. The difference between 1668 is that it additionally contains B 54 as the additional herbicide b. Also preferred is the composition 'which is combined with the corresponding ^ to 1. The difference between 1668 is that it additionally contains B 55 as another herbicide b. Also preferred is the composition 21. 1 to 21. 1668, # and the corresponding composition hl to 1. 1668 differs only in that it additionally contains B 56 as another herbicide b. Also preferred is the composition 22·β22·1668, which is combined with the corresponding one to 1. The difference between 1668 is that it additionally contains B 57 as another herbicide b. Also preferred is the composition (1) to the recognition, and the corresponding composition "to 1. 1668 differs only in that it additionally contains B 65 as another herbicide b. Also preferred is the composition 24. 1 to 24. 1668, which is associated with the corresponding composition hl to 1. The difference between 1668 is that it additionally contains B 66 as another herbicide b. Also preferred is the composition of the composition 25. 1 to 25. 1668, which is associated with the corresponding composition "to 1. 1668 differs only in that it additionally contains B 69 as another herbicide b. Also preferred is the composition 26. 1 to 26. 1668, which is associated with the corresponding composition ^ to 1. 1668 differs only in that it additionally contains B 72 as another herbicide B. Also preferred is the composition 27. 1 to 27. 1668, which is associated with the corresponding composition to 1. The difference of 1668 is only that it additionally contains B 73 as another herbicide b. Also preferred are compositions, which are combined with corresponding ones to 1. 1668 differs only in that it additionally contains B 76 as another herbicide b. Also preferred is the composition 29. 1 to 29. 1668, which is associated with the corresponding composition. 150107. Doc -78- 201109321 to 1. The difference between 1668 is that it additionally contains B77 as another herbicide b. Also preferred are compositions, which are associated with the corresponding compositions 1" to 1. 1668 differs only in that it additionally contains B 79 as another herbicide b. Also preferred are compositions 31" to 31·1668, which are associated with the corresponding compositions i i to 1. 1668 differs only in that it additionally contains B 8 〇 as another herbicide b. Also preferred is the composition 32. 1 to 32. 1668, which is associated with the corresponding composition " to 1. 1668 differs only in that it additionally contains B 83 as another herbicide b. Also preferred is the composition 33. 1 to 33. 1668, which is associated with the corresponding composition i" to 1. The difference between 1668 is that it additionally contains B 83 and B 54 as other herbicides B. Also preferred are compositions 34_1 to 34. 1668, which is combined with the corresponding ^ to 1. The difference between 1668 is that it additionally contains B83 and B6 as the other herbicide B. Also preferred is a composition 35^1 35 1668 which is associated with the corresponding composition "to 1. The difference between 1668 is that it additionally contains B83 and B66 as other herbicides B. Also preferred is the composition 36. 1 to 36 1668, which is associated with the corresponding composition 丄^ to 1. The difference between 1668 is that it additionally contains B 84 as another herbicide b. Also especially good for the composition." 丨 to 叨 1668, which is associated with the corresponding composition "to 1. The difference between 1668 is that it additionally contains B84 and B54 as other herbicides B. * Also preferred is the composition ". 丨至刊1668, which corresponds to the corresponding composition i to 1. The difference between 1668 is that it additionally contains B84 and B6 as the other herbicide B. 150107. Doc -79- 201109321 Also the best combination is 3H39. Difficult, with the corresponding composition M to 1. The difference between 1668 is that it contains B84 and please as its herb B. Also preferred is the composition 40. 1 to 40. 1668, its corresponding composition! To 1. The difference between 1668 is that it additionally contains B 86 as another herbicide b. Also preferred are compositions 41" to 41. 1668, which is associated with the corresponding composition ^ ^ to 1. 1668 differs only in that it additionally contains B 87 as another herbicide b. Also preferred is the composition 42Μ42_1668' and its corresponding composition hi to 1. The difference between 1668 is that it additionally contains B87 and BM as other herbicides B ^ , and is also preferred to be the composition 4H43_1668 ' and its corresponding composition to 1. The difference between 1668 is that it additionally contains B87 and B6 as the other herbicide B. Also preferred is the composition 44·; ^44·1668, which is associated with the corresponding township” to 1. The difference between 1668 is that it additionally contains B 87 and B 66 as other herbicides B. Also preferred is the composition of the composition 45. 1 to 45 1668, which corresponds to the corresponding composition i i to 1. The difference between 1668 is that it additionally contains B 89 as another herbicide b. Also preferred is the composition 4H 46 1668, which is associated with the corresponding composition m to 1. The difference between 1668 is that it additionally contains B 9 〇 as another herbicide b. Also preferred is the composition 47. U 47 1668, which is associated with the corresponding composition η to 1. The difference between 1668 is that it additionally contains Β 9〇 and Β 54 as other herbicides. Also preferred is the composition 4H 48 1668, which is associated with the corresponding composition i" 150107. Doc •80- 201109321 to 1. The difference between 1668 is that it additionally contains B 9〇 and B 6〇 as other herbicides B. Also preferred is the composition of the composition 49. 1 to 49. 1 668, which corresponds to the corresponding composition j j to 1. The difference between 1668 is that it additionally contains B9 and B66 as other herbicides B. Also preferred is a composition 50. 1 to 50. 1668, which is associated with the corresponding composition " to 1. 1668 differs only in that it additionally contains B 94 as another herbicide b. Also preferred is the composition 5 1 · 1 to 5 1. 1 668, which corresponds to the corresponding composition j j to 1. The difference between 1668 is that it additionally contains B 94 and B M as other herbicides B. Also preferred are compositions 52·1 to 52. 1668, which is associated with the corresponding composition. The difference between 1668 is that it additionally contains B94 and B76 as other herbicides B. Also preferred is the composition of the composition 53. 1 to 53. 1668, which is associated with the corresponding composition} ^ to 1. The difference between 1668 is that it additionally contains B94 and B83 as other herbicides B. Also preferred is a composition 54. 1 to 54. 1668, which differs from the corresponding composition " to H668 only in that it additionally contains 〇1〇2 as the other herbicide B. Also preferred are compositions 55] to 55. Touch, 纟 and the corresponding composition to 1. The only difference between 1668 is that it additionally contains B94 and is intended as another herbicide. μ is also particularly preferred for the composition 56. 1 to 56. 1668 ‘The work with the corresponding composition! The difference between Μ668 is that it additionally contains β94 and is said to be other than 150107. Doc • 81 - 201109321 Grass B. It is also preferred that the composition 57·β57·1668' differs from the corresponding combination ^" to 1 · 1668 only in that it additionally contains B 94 and B 9 as other herbicides B. Also preferred is the composition 5H 58. 1668, which is associated with the corresponding composition ^ to 1. The area of 166S is that it additionally contains B 97 as a further herbicide and is also preferred as a composition 5H 59. 1668, which is associated with the corresponding composition i" to 1. The difference between 1668 is that it additionally contains B1 〇〇 as the other herbicide b. Also preferred is the composition 60. 〇6〇. 1668, which is associated with the corresponding composition i" to 1. The difference between 1668 is that it additionally contains B1Q2 as the additional herbicide b. Also preferred is a composition 61_β61·1668 which is associated with the corresponding composition i" to 1. The difference between 1668 is that it additionally contains B1Q5 as the additional herbicide b. Also preferred is the composition 62. 1 to 62_1668, which is associated with the corresponding composition i" to 1. 1668 differs only in that it additionally contains B1〇6 as another herbicide b. Also preferred are compositions 63_1 to 63. 1668, which is associated with the corresponding composition 至^ to 1. The difference between 1668 is that it additionally contains B1〇7 as another herbicide B. Also preferred is the composition 6d 64. 1668, which is associated with the corresponding composition hl to 1. 1668 differs only in that it additionally contains B1〇9 as another herbicide b. Also preferred is the composition of the composition 65. 1 to 65. 1668, which is associated with the corresponding composition 至^ to 1. 1668 differs only in that it additionally contains 5111 as another herbicide b. Also preferred are compositions, which are associated with the corresponding compositions. 1668 differs only in that it additionally contains 3115 as another herbicide b. Also especially preferred are compositions 67·1 to 67. 1668, which is associated with the corresponding composition. The difference between 1668 is that it additionally contains & 117 as another herbicide B. 150107. Doc -82- 201109321 Also preferred is the composition 68. 1 to 68. 1668, which is associated with the corresponding composition u to 1. The difference between 1668 is that it additionally contains 8118 as another herbicide B. Also preferred is the composition 69. 1 to 69. 1668, which is associated with the corresponding composition u to 1. The difference between 1668 is that it additionally contains B12〇 as another herbicide B. Also preferred is the composition 70. 1 to 70. 1668' and its corresponding composition 1" to 1. The difference between 1668 is that it additionally contains B12H, which is another herbicide B. Also preferred is the composition 71. 1 to 71·1668, which corresponds to the corresponding composition 1 ^ to 1. The difference between 1668 is that it additionally contains BU2 as another herbicide. Also preferred is the composition 72. 1 to 72. 1668, which is associated with the corresponding composition hl to 1. The difference between 1668 is that it additionally contains Β128 as another herbicide Β. Also preferred is the composition 73. 1 to 73. 1668, which is combined with the corresponding to 1. The only difference between 1668 is that it additionally contains Paros chlorpyrifos as another herbicide. Also preferred is the composition 74. 1 to 74. 1668, which differs from the corresponding composition hl to 1·1668 only in that it additionally comprises pyroxasulfone as an additional agent and a hydrazine. 54 as another herbicide β. Also preferred are compositions 75_1 to 75. 1668, which is associated with the corresponding composition i 1 to 1. The difference between 1 668 is that it additionally contains pyroxasulfone as another herbicide and Β60 as another herbicide β. Also preferred is the composition 76. 1 to 76. 1668, which is associated with the corresponding composition] i to 1. The difference between 1668 is that it additionally contains pyroxasulfone as another herbicide and B. 66 as another herbicide β. Also preferred is the composition 77. 1 to 77. 1668, which is associated with the corresponding composition j 1 to 1. The only difference between 1668 is that it additionally contains Parox sulfone as another - 150107. Doc • 83 - 201109321 Herbicides and B. 76 as another herbicide B. Also preferred is the composition 78. 1 to 78. 1668, which is associated with the corresponding la compound to 1. The 1668 d is only because it additionally contains Paros chlorpyrifos as another herbicide and B. 83 as $ _ material B. Also preferred are compositions 79丨 to 79 1668, which are associated with the corresponding compositions L1 to 1. The difference between 1668 is that it additionally contains Paros herbaceous stone as another herbicide and B. 84 as another herbicide B. Also preferred is the composition 80. 1 to 80. 1668, which is associated with the corresponding composition hl to 1. The difference between 1668 is that it additionally contains Paros to kill grass as another herbicide and B. 87 as another herbicide Ββ is also particularly preferred for the composition 81" to 81. 1668, which differs from the corresponding composition ^8 only in that it additionally comprises Parox grass as another herbicide and cockroach. 90 as another herbicide Β. Also preferred is the composition 82. M1668, 纟 and the corresponding composition i" to 1. The difference between 1668 is that it additionally contains Paros chlorpyrifos as another herbicide and B. 94 as another herbicide B. Also preferably, the composition (1) (IV) contains the compound B of the benzoate and the genus compound L1 as the active compound A) and the corresponding column of the table C is another compound:

表C 化合物編號安全劑C 83.1 C.1 83.2 C.2 83.3 C.3 83.4 C.4 化合物 --1 編號安全劑C 83.5 ------ C.5 83.6 -——^ 一 C.6 83.7 C.7 83.8 C.8 ----- 150107.doc •84· 201109321 化合物編號安全劑C 83.9 C.9 ---- C.10 83.10 化合物編號安全劑C 83.11 c.ll 亦尤佳者係組合物83a.l至83a.ll，其包含笨并咩畊酮化合物1.1.1作為活性化合物A)及表C.a之相應列中所定義之物質作為另一化合物：表C.a 化合物編號安全劑C 83a.1 c.l 83a.2 C.2 83a.3 C.3 83a.4 C.4 83a.5 C.5 83a.6 C.6 83a.7 C.7 化合物編號安全劑C 83a.8 C.8 83a.9 C.9 83a.10 C.10 83a.11 C.ll 亦尤佳者係組合物84.1至84.11，其與相應組合物831至 83.11之區別僅在於其包含苯并嘮畊酮化合物12丨作為活性化合物A。亦尤佳者係組合物“.丨至以一丨，其與相應組合物83」至 83.11之區別僅在於其包含苯并噚畊酮化合物122作為活性化合物A。亦尤佳者係組合物，其與相應組合物μ」至 83.11之區別僅在於其包含苯并十井酮化合紅3 ι作為活性化合物A。亦尤佳者係組合物8H87.U，其與4目應組合物^ ^至 83.11之區別僅在於其包含苯并，井酮化合物[η作為活性 150107.doc -85- 201109321 化合物A。亦尤佳者係組合物m8.u，其與相應組合物83」至 83.11之區別僅在於其包含笨㈣相化合物⑷作為活性化合物A。亦尤佳者係組合物84a.i至84a u，其與相應組合物 83a. 1至83a. 11之區別僅在於其包含苯并呤畊酮化合物〖2.i 作為活性化合物A。亦尤佳者係組合物85a.l至85a ll，其與相應組合物 83a.l至83a.ll之區別僅在於其包含苯并嘮畊酮化合物〗2 2 作為活性化合物A。亦尤佳者係組合物86以至86a.u，其與相應組合物 83a.l至83a.ll之區別僅在於其包含苯并嘮畊酮化合物ΐ3ι 作為活性化合物A。亦尤佳者係組合物87a.1至87a.u，其與相應組合物 83a. 1至83a.l 1之區別僅在於其包含苯并啰畊酮化合物丨3 2 作為活性化合物A。亦尤佳者係組合物88a.〗至88a.u，其與相應組合物 83a. 1至83a.丨1之區別僅在於其包含苯并呵喑酮化合物i 4^ 作為活性化合物A。亦尤佳者係組合物89a.l至89a.u ’其與相應組合物 833.1至833.11之區別僅在於其另外包含派羅克殺草砜作為另一除草劑。本發明之式1.2、1.3及1.4之化合物及組合物適於用作除草劑。其以如此狀態或作為適當經調配組合物使用係適宜 150107.doc • 86 · 201109321 的。本發明之式L2、L3及L4之化合物及組合物可非常有效地（尤其在高施用率下）控制非農作物區域中之植被。其用於抵抗诸如小麥、鐘半不虫 I — ττ 梗水、玉未、大五及棉花等農作物中之闊葉雜草及禾本科雜I，0 合# 打雜皁且不會對農作物植物造成任何月㉝損α Θ效應主要係、在低施用率下所觀測。端視所討論之施加方法乃永本發明之式厂2、^及^之化合物及組合物可另外田# & J另外用於其他數量之農作物植物中來去除不期望植物。適宜鳶你'、過且晨作物之實例如下：洋惠、疲蘿、欠；^ 藍、黑芬、山η ,)無普甘藍、席氏蒸菁、甘 f m A 化、美國薄殼山核桃、擰檬、甜橙、小果咖啡（令果咖啡、大果甜橙葡、油综、白花^ 瓜、狗牙根、野胡蘿棉）、向日葵、巴而_、大丑、陸地棉（樹棉、草棉、木桃、小扁豆、、普：三葉膠、青稞、啤酒花'甘著、胡蓿、爸蕉屬、角蒿二：加、蘋果屬、木薯、紫花首菜豆、挪威雲杉、：：)、油橄欖、旱稻、白扁豆、私屬、阿月渾早_ 桃、矮生西洋梨、琬丑、歐洲甜櫻桃、 Λ ''杏、歐洲酸樓Μ、6丄，栗、蓖麻、甘兹扁桃及杏梅、紅德醋黍）、可可果、务、普通馬鈐薯、高粱（蜀 _ 紅車輛草、小來豆、葡萄、玉米黍。、黑小麥、硬粒小麥 '蠶較佳農作物如 — (原變種）、甘藍、糖料作物甜菜、歐洲油菜知樣、甜於义、. 咖啡）、狗牙根、 ^小果咖啡（中果咖啡、大果大且、陸地棉（樹棉、草棉、木棉）、向曰 150107.doc -87· 201109321 奏、月棵、胡桃、小扁豆、普通凸府、采— “ s通亞麻番茄、蘋果屬、紫化备宿、角蒿（黃花菸草）、油橄欖、旱稻、白扁豆、 =阿月渾子、豌豆、扁桃、甘薦、黑麥、普通馬：薯、蜀黍）、黑小麥、小麥、硬粒小麥 '蠶豆、葡萄及玉此外，本發明之式及L4之化合物及組合物亦可亦可用於因育種（包括基因工程方法）可耐受除草劑作用之農作物中。此外’本發明組合物亦可用於因育種(包括基因程方法）可财受昆蟲或真菌侵襲之農作物令。本發明之式Ι·2、L3及L4之化合物及組合物亦可用於經基因改造之植物中。術語「基因改造之植物”冑理解為以下植物：其基因材料已使用重組DNA技術加以改造，從而在天然環境下不易於由雜交育種、突變或天然重組獲得。通常’已將-或多個基因整合至基因改造植物之基因材料中’從而改善該植物之某些性質。該等基因改造亦包括 (但不限於）藉由（例如）糖基化或聚合物加成（例如異戊二烯化、乙醯化或法呢基化部分或pEG部分）實施之蛋白質、寡-或多肽的靶向轉譯後改造。舉例而言，已藉由育種、誘變或基因工程改造之㈣已藉由育種或基因工程之習用方法獲得對施加特定種類除草劑之耐受力，該等除草劑係 (例如）.羥基苯基丙酮酸雙氧化酶（HppD)抑制劑；乙醯乳酸合酶（ALS)抑制劑，例如磺酸脲（參見（例如）us 6,222,100 ' WO 01/82685 ' WO 00/26390 ' WO 97/41218 > WO 98/02526、WO 98/02527、WO 04/106529、WO 05/20673、 150107.doc -88- 201109321 WO 03/14357、WO 03/13225、WO 03/14356、WO 04/16073)或Table C Compound number safener C 83.1 C.1 83.2 C.2 83.3 C.3 83.4 C.4 Compound--1 Number safener C 83.5 ------ C.5 83.6 -——^ One C.6 83.7 C.7 83.8 C.8 ----- 150107.doc •84· 201109321 Compound number safener C 83.9 C.9 ---- C.10 83.10 Compound number safener C 83.11 c.ll Also preferred Compositions 83a.l to 83a.ll which comprise as a further compound a compound of the active compound A) and the corresponding column of Table Ca as the other compound: Table Ca Compound Number Safener C 83a.1 cl 83a.2 C.2 83a.3 C.3 83a.4 C.4 83a.5 C.5 83a.6 C.6 83a.7 C.7 Compound number safener C 83a.8 C. 8 83a.9 C.9 83a.10 C.10 83a.11 C.ll Also preferred are compositions 84.1 to 84.11 which differ from the corresponding compositions 831 to 83.11 only in that they comprise a benzoxanthone compound. 12 丨 as the active compound A. It is also preferred that the composition "." is different from the corresponding compositions 83" to 83.11 only in that it contains the benzoxanthene compound 122 as the active compound A. Also preferred are compositions which differ from the corresponding compositions [mu] to 83.11 only in that they comprise benzoxanthone red 3 ι as the active compound A. Also preferred is the composition 8H87.U which differs from the 4-mesh composition from ^^ to 83.11 only in that it comprises a benzo- ketone compound [η as an active 150107.doc-85-201109321 compound A. Also preferred is the composition m8.u which differs from the corresponding compositions 83" to 83.11 only in that it contains the stupid (tetra) phase compound (4) as the active compound A. Also preferred are compositions 84a.i to 84a u which differ from the corresponding compositions 83a. 1 to 83a. 11 only in that they comprise a benzoxanthone compound [2.i] as the active compound A. Also preferred are compositions 85a.l to 85all which differ from the corresponding compositions 83a.l to 83a.11 only in that they comprise the benzoxanthene compound 2 as the active compound A. Also preferred is composition 86 to 86a.u, which differs from the corresponding compositions 83a.l to 83a.11 only in that it comprises the benzoxanthene compound ΐ3ι as the active compound A. Also preferred are compositions 87a.1 to 87a.u which differ from the corresponding compositions 83a.1 to 83a.l1 only in that they comprise the benzoxanthene compound 丨3 2 as the active compound A. Also preferred are compositions 88a. to 88a.u which differ from the corresponding compositions 83a.1 to 83a.丨1 only in that they comprise the benzoxanthone compound i 4^ as the active compound A. Also preferred are compositions 89a.l to 89a.u' which differ from the corresponding compositions 833.1 to 833.11 only in that they additionally comprise pyroxasulfone as another herbicide. The compounds and compositions of the formulae 1.2, 1.3 and 1.4 of the present invention are suitable for use as herbicides. It is suitable for use in such a state or as a suitable formulated composition 150107.doc • 86 · 201109321. The compounds and compositions of the formulae L2, L3 and L4 of the present invention are very effective (especially at high application rates) for controlling vegetation in non-crop areas. It is used to resist broadleaf weeds and gramineous miscellaneous I, 0 and # miscellaneous soaps in crops such as wheat, mid-half insects I-ττ stalk water, jade, big five and cotton, and does not cause crop plants. The 33-day alpha Θ effect of any month is mainly observed at low application rates. Depending on the method of application discussed, the compounds and compositions of the formula 2, ^ and ^ can be used in other quantities of crop plants to remove undesirable plants. Examples of suitable crops for you, and morning crops are as follows: Yang Hui, tired, owed; ^ blue, black fen, mountain η,) no pudding, siemen steamed cyanine, gan fm A, American thin shell pecan , lemon, sweet orange, small fruit coffee (fruit coffee, big fruit sweet orange Portuguese, oil comprehensive, white flower ^ melon, dog tooth root, wild carrot cotton), sunflower, Ba and _, big ugly, upland cotton (tree Cotton, grass cotton, wood peach, lentils, Pu: Hevea, barley, hops 'Gan, Husong, Dadica, Artemisia two: Add, apple, cassava, purple first bean, Norwegian spruce ,::), olive, dry rice, white lentils, private, ayurvedic _ peach, dwarf pear, ugly, European sweet cherry, Λ ''apricot, European sour oyster, 6 丄, chestnut, 蓖Hemp, Ganzi almond and apricot plum, red vinegar vinegar, cocoa fruit, glutinous rice, common horse yam, sorghum (蜀 _ red vehicle grass, small Bean, grape, corn glutinous rice, black wheat, durum wheat ' Silkworms are better crops such as - (original varieties), cabbage, sugar crop beets, European rapeseed, sweet and sweet, coffee), Bermudagrass, ^ Small fruit coffee (medium fruit coffee, large fruit big, land cotton (tree cotton, grass cotton, kapok), Xiangxi 150107.doc -87· 201109321 playing, moon tree, walnut, lentils, ordinary convex house, mining — “s-lined tomato, apple genus, purple sulphate, sage (yellow flower tobacco), olive oil, upland rice, white lentils, = pistachio, peas, almonds, ginseng, rye, common horses: potato, glutinous ), black wheat, wheat, durum wheat 'broad bean, grape and jade. In addition, the compounds and compositions of the present invention and L4 can also be used for crops that are tolerant to herbicides by breeding (including genetic engineering methods) In addition, the composition of the present invention can also be used for crops which can be infested by insects or fungi due to breeding (including the gene path method). The compounds and compositions of the formulas 2, L3 and L4 of the present invention can also be used for In genetically modified plants, the term "genetically modified plant" is understood to mean the following plants: their genetic material has been engineered using recombinant DNA technology to be less susceptible to cross-breeding, mutation or natural recombination in the natural environment. . Typically, ' or more genes have been integrated into the genetic material of a genetically modified plant' to improve certain properties of the plant. Such genetic modifications also include, but are not limited to, proteins, oligos, for example, by glycosylation or polymer addition (eg, prenylation, acetamylation or farnesylation or pEG moieties) - or post-translational modification of the polypeptide. For example, (4) having been bred, mutagenized, or genetically engineered to obtain tolerance to the application of a particular class of herbicides by conventional methods of breeding or genetic engineering, such as hydroxybenzene. a pyruvate dioxygenase (HppD) inhibitor; an acetaminolate lactase (ALS) inhibitor, such as a sulfonic acid urea (see, for example, us 6,222,100 'WO 01/82685 'WO 00/26390 'WO 97/41218 &gt ; WO 98/02526, WO 98/02527, WO 04/106529, WO 05/20673, 150107.doc -88-201109321 WO 03/14357, WO 03/13225, WO 03/14356, WO 04/16073) or

咪唑啉酮（參見（例如）US 6,222，100、WO 01/82685、WO 00/026390、WO 97/41218、WO 98/002526、WO 98/02527、WO 04/106529、WO 05/20673、WO 03/014357、WO 03/13225、WO 03/14356、WO 04/16073);烯醇丙酮醯莽草酸-3-磷酸合酶 (EPSPS)抑制劑，例如草甘膦（參見（例如）W〇 92/00377); 麩醯胺酸合成酶（GS)抑制劑，例如草丁膦（參見（例如）EP-A 242 236、EP-A 242 246)或蛾苯腈（oxynil)除草劑（參見（例如）US 5,559,024)。已藉由習用育種方法（誘變）使若干栽培植物獲得對除草劑之耐受力，例如Clearfield®夏播油菜 (Canola, BASF SE，德國）已而ί受味嗤琳鲷，例如曱氧咪草菸。基因工程方法已用於使栽培植物（例如大豆、棉花、玉米、甜菜及油菜）对受除草劑，例如草甘膦及草丁膦，其中一些係以商品名RoundupReady®(耐草甘膦， Monsanto, U_S_A)及 LibertyLink®(财草丁膦，Bayer CropScience，德國）購得。另外，亦包括藉由使用重組DNA技術能夠合成以下產物之植物：一或多種殺昆蟲蛋白，尤其彼等已知來自細菌屬芽抱桿菌（bacillus)、特定而言來自蘇雲金芽孢桿菌 (bacillus thuringiensis)者’例如 δ-内毒素，例如Imidazolinones (see, for example, US 6,222,100, WO 01/82685, WO 00/026390, WO 97/41218, WO 98/002526, WO 98/02527, WO 04/106529, WO 05/20673, WO 03 /014357, WO 03/13225, WO 03/14356, WO 04/16073); enol acetone oxalic acid-3-phosphate synthase (EPSPS) inhibitors, such as glyphosate (see, for example, W〇92/ 00377); branide synthase (GS) inhibitors, such as glufosinate (see, for example, EP-A 242 236, EP-A 242 246) or oxynil herbicides (see, for example) US 5,559,024). Several cultivated plants have been rendered tolerant to herbicides by conventional breeding methods (mutagenesis), such as Clearfield® summer rapeseed (Canola, BASF SE, Germany), which has been subjected to a variety of flavors, such as oxime Grass smoke. Genetic engineering methods have been used to treat cultivated plants (eg, soybeans, cotton, corn, sugar beets, and canola) against herbicides such as glyphosate and glufosinate, some of which are under the trade name RoundupReady® (Glyphosate-tolerant, Monsanto) , U_S_A) and LibertyLink® (Bayer CropScience, Germany). Also included are plants which are capable of synthesizing the following products by using recombinant DNA techniques: one or more insecticidal proteins, especially those known from the genus Bacillus, in particular from Bacillus thuringiensis For example, δ-endotoxin, for example

CrylA(b)、CrylA(c)、CrylF、CryIF(a2)、CryIIA(b)、CrylA (b), CrylA (c), CrylF, CryIF (a2), CryIIA (b),

CrylllA、CrylllB(bl)或 Cry9c ;植物性殺昆蟲蛋白（vip)，例如VIP1、VIP2、VIP3或VIP3A ;細菌聚居線蟲類之殺昆蟲蛋白，例如發光桿菌屬（Photorhabdus spp.)或致病桿菌 150107.doc •89- 201109321 屬(Xenorhabdus spD山去，素、虫知蛛毒素、黃蜂毒 /產生之母素’例如嫩子毒由真菌產生之毒素，二或其他昆蟲特異性神經毒素；物凝集素(例如碗豆或I:鏈：劑，例如胰蛋白酶抑^ 素l凝集素；蛋白酶抑制恥抑制劑、絲胺酸蛋白酶抑制劑、帕他汀CrylllA, CrylllB (bl) or Cry9c; plant insecticidal protein (vip), such as VIP1, VIP2, VIP3 or VIP3A; insecticidal proteins of bacterial nematodes, such as Photorhabdus spp. or pathogenic bacilli 150107 .doc •89- 201109321 Genus (Xenorhabdus spD mountain, genus, insect toxin, venom/producing mother's such as toxins produced by fungi, two or other insect-specific neurotoxins; lectin (eg, pea or I: chain: agents such as trypsin inhibitor l lectin; protease inhibitor shame inhibitor, serine protease inhibitor, statin

Pa a丨η “胱胺酸蛋自酶抑制劑或木核糖體鈍化蛋白rRTp、畔抑制劑，毒素、絲瓜素、矣草素素、玉米·⑽、相思豆 H冑根毒蛋自（birodin);類固站減_類固醇氧化酶 '脫皮素挪_糖義轉移私、膽固醇氧化酶、蜆皮激素抑制劑或HMG-C。/還原轉；離子通道阻滞劑，例如鈉或辦通道阻滯素醋酶；利尿激素受體（海裏科肽（helicoklnin)受體广二= 乙稀合酶、聯f合酶、殼多糖酶或葡聚糖酶。在本發明2 主文中。亥等殺昆蟲蛋白或毒素應明確地理解為亦係前毒素 '雜化蛋白、截短或以其他方式改良之蛋白。雜化蛋白之特徵在於蛋白結構域之新組合（參見（例如则〇2/(H57〇1)。該等毒素或能夠合成該等毒素之基因改造植物之其他實例揭示於（例如）Ερ·Α 374 753、w〇 93/007278 > W〇 95/34656 ^ ΕΡ-Α 427 529 ^ ΕΡ-Α 451 878、W0 03/1881〇及彻〇3/52〇73中。產生該等基因改造植物之方法通常為熟習此項技術者所熟知且闡述於（例如）上文提及之公開案中。該等基因改造植物中所含之殺昆蟲蛋白賦予產生該等蛋白之植物對來自全部分類學節：動= 種群之害蟲的耐受性，尤其係對甲蟲（鞘翅目（c〇eb卜 150107.doc •90· 201109321 tera))、兩翅昆蟲（雙翅目（Diptera))、及蛾（鱗翅目 (Lepidoptera))與線蟲（線蟲綱（Nema-toda))之耐受性。能夠合成一或多種殺昆蟲蛋白之基因改造植物闡述於（例如）上述公開案中，且其中之一些市面有售，例如YieldGard®(產生CrylAb毒素之玉米栽培品種）、YieidGard® pius(產生 CrylAb及Cry3Bbl毒素之玉米栽培品種）、starlink®(產生 Cry9c毒素之玉米栽培品種）、Herculex® RW(產生 Cry34Abl、Cry35Abl及酵素草丁碟-N-乙酸基轉移酶 (Phosphinothricin-N-Acetyltransferase) [PAT]之玉米栽培品種）；NuCOTN® 33B(產生CrylAc毒素之棉花栽培品種）' Bollgard® 1(產生CrylAc毒素之棉花栽培品種）、Bollgard® II(產生CrylAc及Cry2Ab2毒素之棉花栽培品種）； VIPCOT®(產生VIP-毒素之棉花栽培品種）；NewLeaf®(產生 Cry3A毒素之馬鈴薯栽培品種）；來自SyngentaSeeds SAS, France 之 Bt-Xtra® 、NatureGard® 、KnockOut® 、 BiteGard® ' Protecta®、Btl 1(例如，Agrisure® CB)及 Bt 176(產生CrylAb毒素及PAT酵素之玉米栽培品種）、來自 Syngenta Seeds SAS，France之 MIR604(產生 Cry3A毒素之改良形式的玉米栽培品種，參見WO 03/018810)、來自 Monsanto Europe S.A.，Belgium之MON 863(產生 Cry3Bbl 毒素之玉米栽培品種）、來自Monsanto Europe S.A., Belgium之IPC 53 1(產生CrylAc毒素之改良形式的棉花栽培品種）及來自Pioneer Overseas公司，Belgium之1 507(產生 CrylF毒素及PAT酵素之玉米栽培品種）。 150107.doc •91 - 201109321 另f ,亦包括藉由使用重組1)!^八技術能夠合成_或多種蛋白質U増加彼等植物對細菌、病毒或真菌病原體之抗性或耐党性之植物。該等蛋白質之實例係所謂的「致病相關 1生蛋白」（PR蛋白’參見（例如）Ερ·Α 392 225)、 :因(例如馬鈴薯栽培品種，其表現用於抵抗源自墨西哥予生馬鈴薯（Solanum bulbocastanum)之致病疫黴菌 (^hytophthora infestans)的抗性基因）或丁4溶菌酶（例如，施夠合成該等對諸如梨火疫病⑽咖叫等細菌具有增強抗性之蛋白質的馬鈴薯栽培品種）。產生該等基因改造植物之方法通常為熟習此項技術者所熟知且闡述於（例如）上述公開案中。另外，亦包括如下植物：其藉由使用重組DNA技術能夠合成一或多種蛋白質以增加彼等植物之生產能力（例如生物質生產、籽粒產率、澱粉含量、油含量或蛋白質含量）、對乾旱、鹽度或其他生長限制環境因素之耐受性、或對害蟲及真菌、細菌或病毒性病原體之耐受性。另外，亦包括如下植物：其藉由使用重組DNA技術而含有數量改變之内含物或新内含物，以特定改良人類或動物營養，例如，產生促進健康的長鏈ω_3脂肪酸或不飽和ω_9 脂肪酸之油料農作物（例如Nexera®油菜，DOW Agro Sciences，加拿大）。另外，亦包括如下植物：其藉由使用重組DNA技術而含有數量改變之内含物或新内含物，以特定改良原材料生產，例如可產生增加支鏈澱粉含量的馬鈴薯（例如 150107.doc •92- 201109321Pa a丨η "Cysteine egg self-enzyme inhibitor or wood ribosome inactivating protein rRTp, inhibitor, toxin, loofah, valerulin, corn · (10), acacia Bean H胄 root poison (birodin) ; classy station minus _ steroid oxidase 'pelletin _ sugar transfer transfer private, cholesterol oxidase, ecdysone inhibitor or HMG-C. / reduction transfer; ion channel blockers, such as sodium or channel block A vaginase; a diuretic hormone receptor (helicokinin receptor guangji = ethylene synthase, conjugated f synthase, chitinase or glucanase. In the main text of the present invention. Proteins or toxins should be clearly understood as proteins that are also protoxins 'hybrid proteins, truncated or otherwise modified. Hybrid proteins are characterized by a new combination of protein domains (see (eg 〇2/(H57〇) 1) Other examples of such toxins or genetically modified plants capable of synthesizing such toxins are disclosed, for example, in Ερ·Α 374 753, w〇93/007278 > W〇95/34656 ^ ΕΡ-Α 427 529 ^ ΕΡ - Α 451 878, W0 03/1881〇 and 〇3/52〇73. Producing these genetically modified plants The methods are generally well known to those skilled in the art and are set forth, for example, in the publications mentioned above. The insecticidal proteins contained in such genetically modified plants confer plant species from which these proteins are derived from all taxonomy Section: Mobility = tolerance of population pests, especially to beetles (Coleoptera (c〇eb) 150107.doc •90·201109321 tera), two-winged insects (Diptera), and moths ( Tolerance of Lepidoptera and nematodes (Nema-toda). Genetically modified plants capable of synthesizing one or more insecticidal proteins are described, for example, in the above publication, and some of them are commercially available. For sale, such as YieldGard® (a corn cultivar producing CrylAb toxin), YieidGard® pius (a corn cultivar producing CrylAb and Cry3Bbl toxin), starlink® (a corn cultivar producing Cry9c toxin), Herculex® RW (generating Cry34Abl, Cry35Abl) And corn cultivar of Phosphinothricin-N-Acetyltransferase [PAT]; NuCOTN® 33B (cotton cultivar producing CrylAc toxin)' Bollg Ard® 1 (cotton cultivar producing CrylAc toxin), Bollgard® II (cotton cultivar producing CrylAc and Cry2Ab2 toxin); VIPCOT® (cotton cultivar producing VIP-toxin); NewLeaf® (potato cultivation producing Cry3A toxin) Variety); Bt-Xtra® from SyngentaSeeds SAS, France, NatureGard®, KnockOut®, BiteGard® ' Protecta®, Btl 1 (eg Agrisure® CB) and Bt 176 (corn cultivar producing CrylAb toxin and PAT enzyme) MIR604 from Syngenta Seeds SAS, France (a maize cultivar producing a modified form of Cry3A toxin, see WO 03/018810), MON 863 from Monsanto Europe SA, Belgium (a corn cultivar producing Cry3Bbl toxin), from Monsanto Europe SA, Belgium's IPC 53 1 (a cotton cultivar that produces a modified form of CrylAc toxin) and 1 507 from Pioneer Overseas, Belgium (a corn cultivar that produces CrylF toxin and PAT enzyme). 150107.doc •91 - 201109321 Another f, also includes the use of recombinant 1)! ^ eight technology to synthesize _ or a variety of proteins U plus their plants against bacterial, viral or fungal pathogens or resistance to party plants. Examples of such proteins are the so-called "pathogenic related proteins" (PR protein 'see, for example, Ερ·Α 392 225), : (for example, potato cultivars, which are used to resist the potato from Mexico) (Solanum bulbocastanum) Phytophthora infestans (the resistance gene of Phytophthora infestans) or Ding 4 lysozyme (for example, a potato that is capable of synthesizing such proteins with enhanced resistance to bacteria such as pear fire disease (10) Cultivar). Methods of producing such genetically modified plants are generally well known to those skilled in the art and are described, for example, in the above publication. In addition, it also includes plants which are capable of synthesizing one or more proteins by using recombinant DNA technology to increase the productivity of their plants (eg biomass production, grain yield, starch content, oil content or protein content), on drought Tolerance to environmental factors such as salinity or other growth limitations, or tolerance to pests and fungal, bacterial or viral pathogens. In addition, it also includes plants which contain a modified amount of inclusions or new inclusions by using recombinant DNA technology to specifically improve human or animal nutrition, for example, to produce healthy long-chain ω_3 fatty acids or unsaturated ω_9 Fatty oil crops (eg Nexera® canola, DOW Agro Sciences, Canada). In addition, it also includes plants which, by using recombinant DNA techniques, contain varying amounts of inclusions or new inclusions, are produced in specific modified raw materials, for example, to produce potatoes having increased amylopectin content (eg, 150107.doc • 92- 201109321

Amflora®馬鈐薯，BASF SE，德國）。另外’已發現，本發明之式Ι·2、1.3及1.4之化合物及組合物亦適用於植株部分之脫落及/或乾燥’適用於諸如棉化、馬铃薯、油菜、向曰葵、大豆或蠶豆（尤指棉花）等農作物植物。在此方面，已發現用於使植物乾燥及/或脫落之組合物、用於製備該等組合物之方法、及使用本發明組合物使植物乾燥及/或脫落之方法。作為乾燥劑時，本發明之式Ι·2、1.3及1.4之化合物及組合物尤其適用於使農作物植物（例如馬鈴薯、油菜、向日蔡及大豆 '以及穀物）之地上部分乾燥。此使得可完全機械化收穫該等重要農作物植物。亦有經濟價值的是有利於收穫柑橘類水果、撖欖及仁果、核果及堅果之其他種類友變種，其可藉由使集中於某個時期内開裂或降低對樹之附著性來達成。此相同機制，亦即促進植物果實部分或葉部分與莖幹部分之間形成離層組織亦係控制有用植物（尤其棉花）之脫落所必需。另外，縮短個體棉花植物成熟之時間間隔，可增加收穫後之纖維品質。本發明之式1.2、I.3AL4之化合物及組合物或包含其或自其調配之農作物保護組合物可（例如）以水溶液、現成可用之喷灑Amflora® horse yam, BASF SE, Germany). In addition, it has been found that the compounds and compositions of the formula 2、·2, 1.3 and 1.4 of the present invention are also suitable for the shedding and/or drying of plant parts. Suitable for applications such as cotton, potato, rapeseed, hollyhock, soybean Or crop plants such as broad beans (especially cotton). In this regard, compositions for drying and/or exfoliating plants, methods for preparing such compositions, and methods of using the compositions of the present invention to dry and/or exfoliate plants have been discovered. As a desiccant, the compounds and compositions of the formulas of the present invention, 2, 1.3 and 1.4 are especially useful for drying the aerial parts of crop plants such as potatoes, canola, yoghurt and soybeans, and cereals. This allows for the complete mechanical harvesting of these important crop plants. Also of economic value are other varieties of citrus fruits, saplings and pome fruits, stone fruits and nuts that can be achieved by focusing on cracking or reducing adhesion to trees in a certain period of time. This same mechanism, i.e., promoting the formation of a detached layer between the plant fruit portion or the leaf portion and the stem portion, is also necessary to control the shedding of useful plants, especially cotton. In addition, shortening the time interval between individual cotton plants can increase the fiber quality after harvest. The compounds and compositions of formula 1.2, I.3AL4 of the present invention, or crop protection compositions comprising or formulated therefrom, can be sprayed, for example, in aqueous solution, ready-to-use

或處理種子或與種子混合來使用。使用形式端視預浮液或分. 用物質、洗水， 150107.doc •93· 201109321 期目的而定；在任一情形φ 间办中’其應確保本發明活性化合物之最可能之均勻分佈。農作物保護組合物包含除草有效量之本發明之式1.2、 1:3及1.4之化合物及組合物(亦即至少一種化合物⑷之農業上有用之鹽)及至少一種選自除草劑Β及上述安全劑。之另-活性化合物、以及常用於調配農作物保護劑之辅助劑。吊用於調配農作物保護劑之輔助劑的實例係惰性輔助劑固體或液體載劑、表面活性劑（例如，分散劑、保護 )生膠體、乳化劑、潤濕劑及增黏劑）、有機及無機增稠劑、殺菌劑、防;東劑、消泡劑、視需要著色劑及、用於種子調配之黏著劑。土曰稍劑（即賦予調配物改良之流動性質（即在靜止時具有问黏度且在運動時具有低黏度）之化合物）的實例係多糖，例如黃原膠（來自 Kelco之Kelzan®)，Rhodopol® 23 (Rhone Poulenc)或 Veegum®(來自 R.T. Vanderbilt);以及有機及無機片狀礦物質’例如Attaclay®(來自Engelhardt)。消泡劑之實例係聚矽氧乳液（例如，來自Rh〇dia之 Silikon SRE、Wacker 或 Rhodorsil®)、長鏈醇、脂肪酸、脂肪酸鹽、有機氟化合物及其混合物。可添加殺細菌劑以穩定水性除草調配物。殺菌劑之實例係基於氣酚及笨甲醇半甲縮醛（來自ICI之Proxel®或來自 Thor Chemie 之 Acticide® RS 及來自 Rohm & Haas 之 Kathon® MK)以及異噻唑啉酮衍生物（例如烷基異噻唑淋，] 150107.doc -94· 201109321 菌齊、塞坐琳嗣（來自Th〇r Chemie之Acticide MBS))之殺 =劑之㈣係乙二醇、丙二醇、尿素或甘油。色劑之貫例係微水溶性 r顏枓及水洛性染料二者。染料及·J钕及實例係名稱為 mr 尸之水科·羅丹明B (Rhodamin 广u ·顏料紅112及c I交恭丨4 , g 1ς . ·々J '工1、以及顏料藍1 5:4、顏料Or use seeds or mix with seeds to use. The use of the form depends on the pre-floating liquid or fraction. The substance, washing water, 150107.doc •93·201109321 purpose; in any case φ, it should ensure the most likely uniform distribution of the active compounds of the invention. The crop protection composition comprises a herbicidally effective amount of a compound and composition of the formula 1.2, 1:3 and 1.4 of the present invention (i.e., an agriculturally useful salt of at least one compound (4)) and at least one selected from the group consisting of herbicides and the above-mentioned safety. Agent. Further - active compounds, as well as adjuvants commonly used in the formulation of crop protection agents. Examples of auxiliaries for the deployment of crop protection agents are inert adjuvant solid or liquid carriers, surfactants (for example, dispersants, protective), colloids, emulsifiers, wetting agents and tackifiers, organic and Inorganic thickeners, fungicides, anti-fouling agents; east agents, antifoaming agents, coloring agents as needed, and adhesives for seed preparation. Examples of soil astringents (i.e., compounds which impart improved flow properties to the formulation (i.e., compounds which have a viscosity at rest and have a low viscosity upon movement) are polysaccharides such as xanthan gum (Kelzan® from Kelco), Rhodopol ® 23 (Rhone Poulenc) or Veegum® (from RT Vanderbilt); and organic and inorganic flake minerals such as Attaclay® (from Engelhardt). Examples of antifoaming agents are polyoxynizing emulsions (for example, Silikon SRE, Wacker or Rhodorsil® from Rh〇dia), long chain alcohols, fatty acids, fatty acid salts, organofluorine compounds, and mixtures thereof. A bactericide can be added to stabilize the aqueous herbicidal formulation. Examples of fungicides are based on gaseous phenols and stupid methanol hemiacetal (Proxel® from ICI or Acticide® RS from Thor Chemie and Kathon® MK from Rohm & Haas) and isothiazolinone derivatives (eg alkanes) Isothiazolidine,] 150107.doc -94· 201109321 Bacteria, sputum (from Acturized MBS of Th〇r Chemie)) The agent (4) is ethylene glycol, propylene glycol, urea or glycerol. The example of the toner is a micro-water-soluble r 枓 and a water-dye dye. Dyes and J钕 and examples are named mr 尸水科·罗丹明B (Rhodamin 广u · Pigment Red 112 and c I 交交丨4 , g 1ς . ·々J '工1, and Pigment Blue 1 5 :4, pigment

監15:3、顏料藍15:2、顏料轳μ·】^ M 顏料* ^ 现15」、顏料藍80、顏料黃1、願枓頁13、顏料紅112、顏 57.彳紅願枓紅48·2、顏料紅48:1、顏料紅以.1、顏料紅53:1、顏料橙43、缚以七願科橙34、顏料橙5、顏料、·录36、顏料綠7、顏料白6 ' 』钟棕25、鹼性紫10、鹼性紫馱性紅5 1、酸性紅52、酸性& M a ^ 文性、江14、酸性藍9、酸性黃 ^、驗性紅10、鹼性紅1〇8。、黏著劑之實例係聚乙烯吡咯啶接舻a 』眾乙酸乙烯酯、聚乙埽知及甲基纖維素。適宜之惰性輔助劑尤其係液體會㈣一體載劑。液體載劑之貫例係·中至咼沸點之礦物油館份 m 例如煤油及柴油；以及煤焦油及植物油或動物油；脂肪 ’、， , &狀烴及芳族烴， S’石^四氯寮、烧基化蔡及其街生物、院基化苯及八讨生物，醇，例如，甲醇、乙醇、 ^ 丙醇、丁醇及環己醇；酮，例如，環己酮；強極性溶劑，〜 1歹》』如，古名田# 料咬酮等胺；及水。固體載劑係（例如）礦物土例如ς 土、石夕膝、石夕酸鹽、滑石粉、高嶺土、石夜石、石灰、白堊、紅玄武土、黃土、黏土、白雲石、夕4 土、硫酸鈣、石现酸鎂及氧化鎂，經研磨合成材料；肥枓，例如硫酸銨、 150l07.doc •95· 201109321 磷酸銨、硝酸銨及尿素；及植物來源產品，例如縠類粗粉、樹皮粗粉、木粉及堅果殼粉、纖維素粉或其他固體載劑。適宜表面活性劑（佐劑、潤濕劑、增黏劑、分散劑以及乳化劑）係芳族磺酸（例如木質素磺酸（例如Borrespers型，Supervisor 15:3, Pigment Blue 15:2, Pigment 轳μ·]^ M Pigment*^ Now 15”, Pigment Blue 80, Pigment Yellow 1, Wishing Page 13, Pigment Red 112, Yan 57. Blushing Red 48·2, pigment red 48:1, pigment red to 1.1, pigment red 53:1, pigment orange 43, bind to seven wishaceae orange 34, pigment orange 5, pigment, record 36, pigment green 7, pigment white 6 ' 』Chen Brown 25, Alkaline Violet 10, Alkaline Purpura Red 5 1, Acid Red 52, Acid & M a ^ literacy, Jiang 14, Acid Blue 9, Acid Yellow ^, Verification Red 10, Alkaline red 1〇8. Examples of the adhesive are polyvinylpyrrolidine, a vinyl acetate, polyethylene glycol, and methyl cellulose. Suitable inert adjuvants are especially liquids (iv) one carrier. Examples of liquid carriers are medium to medium boiling point mineral oils such as kerosene and diesel; and coal tar and vegetable oil or animal oil; fat ',, & hydrocarbons and aromatic hydrocarbons, S' stone ^ four Chloroquinone, chlorinated Cai and its street organisms, phenyl and octagonal organisms, alcohols, such as methanol, ethanol, ^ propanol, butanol and cyclohexanol; ketones, for example, cyclohexanone; strong polarity Solvent, ~ 1 歹 "", such as, Gu Mingtian # material ketone and other amines; and water. Solid carrier systems (for example) mineral soils such as rammed earth, shixi knee, lithograph, talcum powder, kaolin, stone night stone, lime, white peony, red basalt, loess, clay, dolomite, Xi 4 soil, Calcium sulphate, magnesium sulphate and magnesium oxide, ground synthetic materials; fertilizer, such as ammonium sulphate, 150l07.doc • 95· 201109321 ammonium phosphate, ammonium nitrate and urea; and plant-derived products, such as glutinous meal, bark Coarse, wood flour and nut shell powder, cellulose powder or other solid carrier. Suitable surfactants (adjuvants, wetting agents, tackifiers, dispersants, and emulsifiers) are aromatic sulfonic acids (eg, lignin sulfonic acid (eg, Borrespers type,

Borregaard)、苯紛基績酸、萘續酸（M〇rvVet型，AkzoBorregaard), benzoic acid, naphthalene acid (M〇rvVet type, Akzo

Nobel)及二丁基萘磺酸（Nekal型，BASF AG))之驗金屬鹽、鹼土金屬鹽及銨鹽；及脂肪酸、烷基_及烷基芳基磺酸鹽、院基硫酸鹽、月桂基醚硫酸鹽及脂肪醇硫酸鹽、及硫酸化十六_、十七-及十八烷醇鹽；以及脂肪醇二醇醚、磺化萘及其衍生物與甲醛之縮合物、萘或萘磺酸與酚及甲駿之縮合物、聚氧伸乙基辛基酚醚、乙氧基化異辛基_、辛基-或壬基酚、烷基苯基或三丁基苯基聚乙二醇醚、烧基芳基聚醚醇、異十三烷基醇、脂肪醇/環氧乙烷縮合物、乙氧基化蓖麻油、聚氧伸乙基烷基醚或聚氧伸丙基烷基醚、聚乙二醇月桂醇醚乙酸酯、山梨醇酯、木質素亞硫酸鹽廢液及蛋白質、變性蛋白質、多糖（例如甲基纖維素）、經疏水修飾之澱粉、聚乙烯醇（M〇wi〇i型，Metal salts, alkaline earth metal salts and ammonium salts of Nobel) and dibutylnaphthalenesulfonic acid (Nekal type, BASF AG); and fatty acids, alkyl- and alkylarylsulfonates, yard sulfates, laurel Ethyl ether sulfate and fatty alcohol sulfate, and sulfated hexadecane, hepta- and octadecyl alkoxide; and fatty alcohol glycol ether, sulfonated naphthalene and its derivatives and formaldehyde condensate, naphthalene or naphthalene a condensate of sulfonic acid with phenol and methyl benzoate, polyoxyethylene ethyl octyl phenol ether, ethoxylated isooctyl _, octyl- or nonyl phenol, alkyl phenyl or tributyl phenyl polyethylene Glycol ether, alkyl aryl polyether alcohol, isotridecyl alcohol, fatty alcohol/ethylene oxide condensate, ethoxylated castor oil, polyoxyethylene ethyl ether or polyoxypropyl propyl Alkyl ether, polyethylene glycol lauryl ether acetate, sorbitol ester, lignin sulfite waste liquid and protein, denatured protein, polysaccharide (such as methyl cellulose), hydrophobically modified starch, polyvinyl alcohol (M〇wi〇i type,

Clariant)、聚缓酸醋（BASF AG，Sokolan型）、聚烧氧基化物、聚乙烯基胺（BASF AG，Lupamin型）、聚伸乙基亞胺 (BASF AG，Lupasol型）、聚乙稀基η比洛咬明及其共聚物。粉劑、撒播用材料及粉塵劑可藉由一起混合或研磨活性成份與固體載劑來製備。可藉由使活性成份結合固體載劑來製備顆粒，例如經塗 150107.doc -96· 201109321 佈顆粒、經浸潰顆粒及勻質顆粒。可藉由添加水自乳液濃縮物、懸浮液、糊劑、可散顆粒來製備水性使用形式。為製備乳液·、’’： μ或油性为散液，可在水中藉助潤濕劑、或乳化劑使式工、尤其La及Lb之化合刀散月j ^ , 甥从原狀態或溶於油或：：中之形式均質化。另一選擇為’亦可製備包含活性化』、潤濕劑、增黏劑、分散劑或乳化劑及（若需要）溶劑或油之濃縮物，該等濃縮物適於用水稀釋。命活性化合物在即用製劑中之濃度可在寬範圍令有所變化。通常’調配物包含0_001，重量％、較佳〇〇ι·95重量之至少-種活性化合物。所用活性化合物之純度為嫩_ 100°/。’較佳95%-1〇〇%(根據]^11譜）。本發明之式L2、L3及L4之化合物及組合物可（例如）調配為以下形式： 1.用水稀釋之產品 Α 水溶性濃縮物將10重量份數之活性化合物溶於90重量份數之水或水溶性溶劑中。作為替代方案，添加潤濕劑或其他佐劑。經水稀釋後，該活性化合物發生溶解。藉此形成活性化合物含量為10重量°/。之調配物。 B 可分散性濃縮物將20重量份數之活性化合物溶於7〇重量份數之環己酮中，同時添加10重量份數之分散劑（例如聚乙烯吡咯啶酮）。使用水稀釋以形成分散液。活性化合物含量為2〇重 150107.doc •97· 201109321 量〇/〇。 c 可乳化性濃縮物將1 5重量份數之活性化合物溶於7 5重量份數之有機溶劑 (例如烷基芳族化合物）中，同時添加十二烷基苯磺酸約及乙氧基化蓖麻油（在各情形中皆添加5重量份數）。使用水稀釋以形成乳液。此調配物之活性化合物含量為15重量〇/0。 D 乳液將25重量份數之活性化合物溶於3 5重量份數之有機溶劑 (例如烷基芳族化合物）中’同時添加十二烷基苯磺酸鈣及乙氧基化蓖麻油（在各情形中皆添加5重量份數）。藉助乳化機（例如Ultraturrax)將此混合物引入3〇重量份數之水中且將其製成均質乳液。使用水稀釋以形成乳液。此調配物之活性化合物含量為25重量％。 E 懸浮液在攪拌球磨機中粉碎20重量份數之活性化合物，且添加 1 〇重量份數之分散劑及潤濕劑以及7 〇重量份數之水或有機溶劑，從而得到精細活性化合物懸浮液。使用水稀釋以得到該活性化合物之穩定懸浮液。此調配物中之活性化合物含Έ為20重量％。 F 水可分散性顆粒及水溶性顆粒精細研磨50重量份數之活性化合物，同時添加5〇重量份數之分散劑及潤濕劑，且藉助技術器械（例如擠壓器、喷霧塔、流化床）將其製成水可分散性或水溶性顆粒。使用水稀釋以得到該活性化合物之穩定分散液或溶液。此調配 150107.doc -98- 201109321 物之活性化合物含量為50重量。/〇。 G 水可分散性粉末及水溶性粉末將75重量份數之活性化合物在轉子-定子研磨機中研磨’同時添加25重量份數之分散劑、潤濕劑及矽膠。使用水稀釋以得到該活性化合物之穩定分散液或溶液。此調配物之活性化合物含量為75重量。/〇。 Η凝膠調配物在球磨機中，混合20重量份數之活性化合物、1〇重量份數之分散劑、1重量份數之膠凝劑及7〇重量份數之水或有機〉谷劑以得到精細懸浮液。使用水稀釋以得到活性化合物含量為20重量％之穩定懸浮液。 2.不稀釋即可施加之產品 I 粉塵劑精細研磨5重量份數之活性化合物且使其與％重量份數之精細粉碎之高嶺土充分混合。藉此得到活性化合物含量為5重量％之粉末化粉劑。 J 顆粒（GR，FG，GG，MG) 使其與99·5重量份嘴霧乾燥或流化 /〇之不稀釋即可施精細研磨0.5重量份數之活性化合物且數之載劑混合。此處現行方法係擠出、床。藉此得到活性化合物含量為〇 5會旦王里加之顆粒。 ULV 溶液（UL) 將10重量份數之活性化合物溶於90重量\ (例如二甲苯)中。藉此得到活性化：數之有機溶劑 3量為1 0重量％之 150107.doc •99· 201109321 不稀釋即可施加之產品。在即用製劑中，亦即在呈農作物保護組合物形式之本發明組合物中，組份A及B及/或C可呈現為以懸浮、乳化或 /谷解形式聯合或分開調配。使用形式完全取決於預期癖、用0 因此’本發明之第一實施例係關於呈調配為單組份組合物之農作物保護組合物形式的組合物，其包含至少一種式 I活性化合物（活性化合物Α)及至少一種選自除草劑β及安全劑C之另一活性化合物以及固體或液體載劑及（若適當）一或多種表面活性劑。因此’本發明之第二實施例係關於呈調配為雙組份組合物之農作物保護組合物形式的組合物，其包含含有至少一種活性化合物A、固體或液體載劑及（若適當）一或多種表面活性劑之第一調配物（組份）、及含有至少一種選自除草劑B及安全劑C之另一活性化合物、固體或液體载劑及（若適當）一或多種表面活性劑之第二組份。活性化合物A及至少一種另一活性化合物b及/或C可聯合或分開施加、同時或連續施加、在植物萌發之前、期間或之後施加。活性化合物A、B及/或C之施加順序不甚重要。唯一重要之處在於至少一種活性化合物A及至少一種另一活性化合物B及/或C同時存在於作用位點處，即，同時與欲控制植物接觸或由欲控制植物吸收。純活性化合物組合物（亦即A及B)及（若適當）無調配物輔助劑之C的所需施用率取決於植物林分之組成、植物之發 150107.doc •100· 201109321 展階段、使用地點處之氣候條件及施加技術。通常，A及 B及（若適當）c之施用率係〇〇〇1_3 kg/ha、較佳〇〇〇5 2 5 kg/ha且特定而言0.01-2 kg/ha活性物質（a.s.)。化合物1之所需施用率通常在0.0005 kg/ha至2.5 kg/ha a.s_範圍内且較佳在〇〇〇5 4/}^至2 kg/ha或〇〇1 ]^/1^至1 5 kg/h a.s.範圍内。化合物B之所需施用率通常在〇〇〇〇5 kg/h^2 5 kg/ha a.s.範圍内且較佳在〇〇〇5 kg/ha至2 kg/ha或〇〇l kg/以至^ $ kg/h a.s.範圍内。化合物C之所需施用率通常在〇〇〇〇5 kg/ha至2 5 kg/ha a_s.範圍内且較佳在〇〇〇5 kg/ha至2 或〇〇ι ^化汪至i 5 kg/h a.s.範圍内。主要藉由喷灑葉片來將本發明之式I 2、13及L4之化合物及組合物施加至植物上。此處，可使用（例如）水作為載劑藉由常用喷霧技術使用約100-1000 Ι/ha(例如300-400 Ι/ha)之噴灑液置進行施加。除草組合物亦可藉由低體積或超低體積方法或以微顆粒形式施加。本發月之式1.2、I.3及I.4之化合物及除草組合物可在萌前或萌後施加或與農作物植物種子一起施加。亦可藉由施、、里本lx月組σ物預處理之農作物植物的種子來施加該等化合物及組合物。若某些農作物植物對活性化合物Α及Β 及(*右適* )(：之耐$性較差，則可使用借助喷霧設備喷灑示草”且口物之把加技術，此一施加方式使得該等除草组合物盡可能不與敏感農作物植物葉片接觸，同時活性化合物 150107.doc -101 - 201109321 可到達生長於該等農作物植物下方之不期望植物之葉片戋裸土表面（定向喷灑後，鬆土）。在另一實施例中，可藉由處理種子來施加本發明之式 I · 2、1.3及1.4之化合物及組合物。種子處理包含基於本發明之式合物或自其製備之組合物之基本上所有熟習此項技術者熟知的程序（拌種 '種子塗佈、種子撒粉、浸種、種子膜塗佈、種子多層塗佈、種子包衣、種子滴漏及種子丸化）。此處，除草組合物可在經豨釋或不經稀釋下施加。術語「種子」包含所有類型種子，例如’榖粒、種子、水果、根莖類、秧苗及類似形式。此處，較佳地，術語「種子」闡述穀物及種子。所用種子可為如上所述之有用植物之種子、以及轉基因植物或自常用育種方法獲得之植物的種子。活性化合物之施用率為0.001_3·0、較佳〇〇1-1 〇 kg/ha 之活性物質（a.s.)，此取決於控制目標、季節、目標植物及生長階段。為處理種子，化合物][之使用量通常係〇〇〇ΐ ι〇 kg/100 kg種子。另外，較佳地，可單獨或與其他農作物保護劑組合來施加本發明之化合物I或組合物，例如與用於控制害蟲或植物致病真菌或細菌之試劑或與調節生長之活性化合物群組合施加。同樣受關注的是其與用於治療營養缺乏及痕量元素缺乏之礦物鹽溶液之混溶性。亦可添加無植物毒性油及油濃縮物。 150107.doc -102· 201109321 下列實例用於闡釋本發明。 A製備實例實例1 : ((氯丙·2·块基）-7-氟-3-側氧基_3,4-二氫-2H-苯并二酮Clariant), polyamic acid vinegar (BASF AG, Sokolan type), polyoxyalkylate, polyvinylamine (BASF AG, Lupamin type), polyethylenimine (BASF AG, Lupasol type), polyethylene The base η is a bite and its copolymer. Powders, spreading materials and dusting agents can be prepared by mixing or grinding the active ingredient with a solid carrier. The granules can be prepared by combining the active ingredient with a solid carrier, for example, coated with granules, impregnated granules and homogenous granules, 150107.doc-96·201109321. The aqueous use form can be prepared by adding water from the emulsion concentrate, suspension, paste, and dispersible granules. In order to prepare the emulsion·, '': μ or oily is a dispersion, the wetting agent, especially the La and Lb compounding knife can be used in the water by means of a wetting agent, or an emulsifier, and the compound is dissolved in the original state or dissolved in oil. Or the form of :: is homogenized. Alternatively, a concentrate comprising an activation, a wetting agent, a tackifier, a dispersing or emulsifying agent and, if desired, a solvent or oil may be prepared, the concentrate being suitable for dilution with water. The concentration of the active compound in the ready-to-use preparation can vary widely. Typically, the formulation comprises from 0 to 001, % by weight, preferably from 1.00 by weight, of at least one active compound. The purity of the active compound used is tender _ 100 ° /. 'It is preferably 95%-1%% (according to the ^11 spectrum). The compounds and compositions of the formulae L2, L3 and L4 of the present invention can, for example, be formulated in the following forms: 1. Products diluted with water 水溶性 Water-soluble concentrates 10 parts by weight of the active compound are dissolved in 90 parts by weight of water Or in a water soluble solvent. As an alternative, a wetting agent or other adjuvant is added. Upon dilution with water, the active compound is dissolved. Thereby, the active compound content was 10 weight%. Formulations. B Dispersible Concentrate 20 parts by weight of the active compound are dissolved in 7 parts by weight of cyclohexanone while 10 parts by weight of a dispersing agent (e.g., polyvinylpyrrolidone) is added. Dilute with water to form a dispersion. The active compound content is 2 150 150107.doc •97· 201109321 〇/〇. c Emulsifiable concentrates 15 parts by weight of the active compound are dissolved in 75 parts by weight of an organic solvent (for example an alkylaromatic compound) with the addition of decylbenzenesulfonic acid and ethoxylation Castor oil (5 parts by weight in each case). It is diluted with water to form an emulsion. The active compound content of this formulation was 15% 〇/0. D Emulsion 25 parts by weight of the active compound is dissolved in 35 parts by weight of an organic solvent (for example, an alkyl aromatic compound) while adding calcium dodecylbenzenesulfonate and ethoxylated castor oil (in each In the case, 5 parts by weight were added). This mixture was introduced into 3 parts by weight of water by means of an emulsifier (e.g., Ultraturrax) and made into a homogeneous emulsion. Dilute with water to form an emulsion. The formulation had an active compound content of 25% by weight. E Suspension 20 parts by weight of the active compound are pulverized in a stirring ball mill, and 1 part by weight of a dispersing agent and a wetting agent and 7 parts by weight of water or an organic solvent are added to obtain a fine active compound suspension. Dilution with water to obtain a stable suspension of the active compound. The active compound in this formulation contained 20% by weight of hydrazine. F water dispersible granules and water-soluble granules finely grind 50 parts by weight of active compound, while adding 5 parts by weight of dispersant and wetting agent, and by means of technical equipment (eg extruder, spray tower, flow) The bed is made into water-dispersible or water-soluble particles. Dilution with water to obtain a stable dispersion or solution of the active compound. This formulation 150107.doc -98- 201109321 has an active compound content of 50% by weight. /〇. G Water-dispersible powder and water-soluble powder 75 parts by weight of the active compound were ground in a rotor-stator grinder while adding 25 parts by weight of a dispersant, a wetting agent and a silicone rubber. Dilution with water to obtain a stable dispersion or solution of the active compound. The active compound content of this formulation was 75 weight. /〇. Η Gel formulation in a ball mill, mixing 20 parts by weight of the active compound, 1 part by weight of the dispersant, 1 part by weight of the gelling agent and 7 parts by weight of water or organic granules to obtain Fine suspension. It was diluted with water to give a stable suspension having an active compound content of 20% by weight. 2. A product which can be applied without dilution I Dust agent 5 parts by weight of the active compound are finely ground and thoroughly mixed with % by weight of finely divided kaolin. Thereby, a powdered powder having an active compound content of 5% by weight was obtained. The J particles (GR, FG, GG, MG) can be finely ground with 0.5 part by weight of the active compound and mixed with a carrier, by drying with 99. 5 parts by weight of the mist or by fluidization. The current method here is extrusion, bed. Thereby, the active compound content is obtained as a granule. ULV solution (UL) 10 parts by weight of the active compound is dissolved in 90% by weight (for example xylene). Thereby, the activation is carried out: the amount of the organic solvent 3 is 10% by weight of 150107.doc • 99· 201109321 The product can be applied without dilution. In ready-to-use formulations, i.e., in the compositions of the invention in the form of crop protection compositions, components A and B and/or C may be present in combination or separately in suspension, emulsification or /glutination. The use form depends entirely on the expected enthalpy, with 0. Thus the first embodiment of the invention relates to a composition in the form of a crop protection composition formulated as a one-component composition comprising at least one active compound of the formula I (active compound) And at least one other active compound selected from the group consisting of herbicide β and safener C, and a solid or liquid carrier and, if appropriate, one or more surfactants. Thus, a second embodiment of the invention relates to a composition in the form of a crop protection composition formulated as a two-component composition comprising at least one active compound A, a solid or liquid carrier and, if appropriate, one or a first formulation (component) of a plurality of surfactants, and at least one other active compound selected from the group consisting of herbicide B and safener C, a solid or liquid carrier, and, if appropriate, one or more surfactants The second component. The active compound A and at least one further active compound b and/or C may be applied in combination or separately, simultaneously or continuously, before, during or after germination of the plant. The order of application of the active compounds A, B and/or C is not critical. The only important point is that at least one active compound A and at least one other active compound B and/or C are present at the site of action, i.e. at the same time in contact with the plant to be controlled or by the plant to be controlled. The required application rates of pure active compound compositions (i.e., A and B) and, if appropriate, no formulation adjuvant C, depend on the composition of the plant stand, the plant's hair 150107.doc •100·201109321 stage, The climatic conditions and application techniques at the location of use. In general, the application rates of A and B and, if appropriate, c are 〇1_3 kg/ha, preferably 〇5 2 5 kg/ha and in particular 0.01-2 kg/ha active substance (a.s.). The desired application rate of Compound 1 is usually in the range of 0.0005 kg/ha to 2.5 kg/ha a.s_ and preferably in the range of 〇〇〇5 4/}^ to 2 kg/ha or 〇〇1]^/1^ Up to 1 5 kg/h as range. The required application rate of Compound B is usually in the range of 〇〇〇〇5 kg/h^2 5 kg/ha as and preferably from 〇〇〇5 kg/ha to 2 kg/ha or 〇〇l kg/to ^ Within the range of $ kg/h as. The required application rate of Compound C is usually in the range of 〇〇〇〇5 kg/ha to 25 kg/ha a_s. and preferably 〇〇〇5 kg/ha to 2 or 〇〇ι ^化汪至i 5 Within the range of kg/h as. The compounds and compositions of the formulae I, 13, and L4 of the present invention are applied to plants primarily by spraying the leaves. Here, application can be carried out using, for example, water as a carrier by a spray technique of about 100 to 1000 angstroms/ha (e.g., 300 to 400 angstroms/ha) by a conventional spraying technique. Herbicidal compositions can also be applied by low volume or ultra low volume methods or in the form of microparticles. The compounds of formula 1.2, I.3 and I.4 and herbicidal compositions of this month may be applied before or after germination or with crop plant seeds. The compounds and compositions can also be applied by the seeds of the crop plants pretreated with the sigma and the sigma. If some crop plants have active compound Α and Β and (* right fit*) (: the resistance to $ is poor, you can use the spray equipment to spray the grass) and the application of the mouth, this application method Making the herbicidal compositions as close as possible to the leaves of sensitive crop plants, while the active compound 150107.doc -101 - 201109321 can reach the surface of the bare soil of the undesired plants grown under the crop plants (after targeted spraying) In another embodiment, the compounds and compositions of the formula I, 2, 1.3 and 1.4 of the invention may be applied by treating the seed. The seed treatment comprises or is prepared from a formula according to the invention The composition is essentially all procedures well known to those skilled in the art (seed dressing 'seed coating, seed dusting, seed soaking, seed film coating, seed multi-layer coating, seed coating, seed drip, and seed pelletization) Here, the herbicidal composition can be applied with or without dilution. The term "seed" encompasses all types of seeds, such as 'glutinous grains, seeds, fruits, rhizomes, seedlings and the like. Preferably, the term "seed" describes grains and seeds. The seed used may be a seed of a useful plant as described above, and a seed of a transgenic plant or a plant obtained by a conventional breeding method. The application rate of the active compound is 0.001 Å. · 0, preferably 〇〇 1-1 〇 kg / ha of active substance (as), depending on the control target, season, target plant and growth stage. For the treatment of seeds, the compound [usually used] 〇 ι〇kg/100 kg of seed. Further, preferably, the compound I or composition of the invention may be applied alone or in combination with other crop protection agents, for example with a reagent for controlling pests or phytopathogenic fungi or bacteria. Or in combination with a population of active compounds that regulate growth. Also of interest is its miscibility with mineral salt solutions for the treatment of nutritional deficiencies and trace element deficiencies. Non-phytotoxic oils and oil concentrates may also be added. Doc -102· 201109321 The following examples are provided to illustrate the invention. A Preparation Example 1 : ((Chloropropionyl 2)yl-7-fluoro-3-oxo- 3,4-dihydro-2H-benzene Diketone

在-78C下向存於四氫呋喃（無水）中之3(7_氟_3_側氧基_ 4-(丙-2-炔基）-3,4-二氫-2H-苯并[b][l，4]噚畊-6-基）-1，5-二甲基-6-硫代-1，3,5-氫化三畊 _2,4-二酮（5〇〇 mg，1.329 mmol) 中逐滴添加存於THF中之1 Μ六曱基二矽基胺基鋰（LHMDS) (2_66 ml，2.66 mmol)。將所得混合物在_78°(：下攪拌15分鐘，隨後逐份添加N-氣-琥珀醯亞胺（NCS) (213 mg，1.594 mmol)。將混合物在-78°C下授拌2h且隨後以此狀態（-78。〇傾倒至NH4C1飽和水溶液中。使用EtOAc萃取，使用 Na2S〇4乾燥並濃縮，得到510 mg標題化合物。丨H NMR (CDC13): δ= 3.80 (6H，s)，4.66 (2H，s), 4.71 (2H， s)，6.94 (1Η，d)，7.06 (1Η，d)。實例2 : 3-(4-(3-溴丙-2-炔基）-7-氟-3-側氧基-3,4-二氫-2H-苯并[b]-[1，4]哼畊-6-基）-1，5-二甲基-6-硫代-1,3,5-氫化三畊-2,4-二酮 150107.doc -103 - 2011093213 (7-Fluor_3_sideoxy-4- 4-(prop-2-ynyl)-3,4-dihydro-2H-benzo[b] in tetrahydrofuran (anhydrous) at -78C [l,4]噚耕-6-yl)-1,5-dimethyl-6-thio-1,3,5-hydrogenated three-till 2,4-dione (5〇〇mg, 1.329 mmol Lithium hexamethylene decylamino lithium (LHMDS) (2_66 ml, 2.66 mmol) in THF was added dropwise. The resulting mixture was stirred at _78 ° (: 15 min, then N-gas-succinimide (NCS) (213 mg, 1.594 mmol) was added portionwise. The mixture was stirred at -78 ° C for 2 h and then In this state (-78), EtOAc (EtOAc: EtOAc: EtOAc (EtOAc) (2H, s), 4.71 (2H, s), 6.94 (1Η, d), 7.06 (1Η, d). Example 2: 3-(4-(3-bromoprop-2-ynyl)-7-fluoro -3-Sideoxy-3,4-dihydro-2H-benzo[b]-[1,4]indole-6-yl)-1,5-dimethyl-6-thio-1, 3,5-hydrogenated three tillage-2,4-dione 150107.doc -103 - 201109321

在室溫及N2氣氛下’將5 g (13.26 mmol) 3-(7-氟-3-側氧基-4-(丙-2-炔基）-3,4-二氫-2H-苯并问[1，4]噚畊-6-基Η 5_ 二甲基-6-硫代- l，3,5 -氫化三畊-2,4-二酮、3.55 g (19 93 mmol)N-溴-琥珀醯亞胺及0.451 g (2.99 mmol)硝酸銀溶於 N，N-二甲基甲醯胺中並攪拌過夜。在攪拌下將原材料傾倒至水/EtOAc中。分離各層且使用Et〇Ac萃取水層。使用 10% NaCl水溶液洗滌合併之有機層，使用Na2S〇4乾燥並濃縮以得到約6 g標題產物。藉由層析實施純化（DCM ·· THF 99·· 1，二氧化矽）以得到 2.26 g黃色粉末形式之標題化合物。 NMR (CDC13): δ= 3.80 (6H，s)’ 4_67 (2H，s)，4.71 (2H, s)，6·93 (1Η，d)，7·〇7 (1Η，d)。實例3 : 1-胺基-3-(7-氟-3-側氧基·4_(丙·2_炔基）_3,4_二氫_2H_苯并井-6-基）·5_甲基_6_硫代H5·氮化三呼_2,4_二酮'5 g (13.26 mmol) 3-(7-fluoro-3-oxo-4-(prop-2-ynyl)-3,4-dihydro-2H-benzoate at room temperature under N2 atmosphere [1,4] 噚耕-6-yl Η 5_ dimethyl-6-thio-l,3,5-hydrogenated three-till-2,4-dione, 3.55 g (19 93 mmol) N-bromine - Amber succinimide and 0.451 g (2.99 mmol) of silver nitrate were dissolved in N,N-dimethylformamide and stirred overnight. The starting material was poured into water / EtOAc with stirring. The layers were separated and extracted with Et. The aqueous layer was washed with aq. 10% aq. EtOAc (EtOAc) (EtOAc) 2.26 g of the title compound are obtained as a yellow powder. NMR (CDC13): δ = 3.80 (6H, s)' 4_67 (2H, s), 4.71 (2H, s), 6.93 (1Η, d), 7·〇 7 (1Η, d). Example 3: 1-amino-3-(7-fluoro-3-indolyl.4_(propan-2-ynyl)_3,4_dihydro-2H_benzo-well- 6-yl)·5_methyl_6_thio H5·nitriding trihd-2,4_dione

向存於曱苯（無水）中之7-氟-6-異氰酸基-4-(丙-2-炔基）-2Η-苯并[b][l’4]十井 _3(4Η)酮 2。31 麵。1) 2(甲基 150107.doc •104· 201109321 胺甲硫醯基）肼曱酸第三丁基酯（5.00 g，24.37 mmol)及三乙胺（0·849 ml，6.09 mmol)中添加羰基二咪唑（CDI) (6 59 g， 40.6 mmol)。將所得混合物在80它及A氣氛下攪拌過夜。隨後，在真空中濃縮並使用EtOAc研磨。藉由玻璃渡器去除不溶性物質且濃縮濾液以得到6.26 g黃色油狀標題化合物。 H NMR (d6-DMSO): δ= 3.44 (3Η, s), 4.68 (2H, s), 4.75 (2H, s), 7.109 (1H, br d), 7.26 (1H, br d), 9.31 (1H, br s), 12.12 (1H, br s)。 B部分：使用實例藉由下列溫室實驗證實本發明化合物及組合物之除草作用：所用培養容器係含有約3 ·〇%腐殖質之壤質砂土作為基質的塑膠盆。將測試植物種子之各品種單獨播種。對於萌别處理而言，在播種後，藉助精細分佈喷嘴直接施加懸浮或乳化於水中之活性化合物。向容器緩緩澆水，以促進發芽及生長，隨後使用透明塑膠護罩覆蓋，直至植物生根。除非活性化合物對此覆蓋產生負面影響，否則其可使測試植物均勻發芽。對於萌後處理而言，使測試植物依植物習性生長至3_i5 咼，且隨後僅用懸浮或乳化於水中之活性化合物處理。為此，測試植物可直接播種並在相同容器中生長，或其先分開生長成幼田，然後在處理前幾天才移植至測試容器中。端視物種而定，分別將植物保持於l〇r至25T：及20。(：至 150107.doc -105- 201109321 35 C下。測試時間長達2-4週。在此期間，照管該等植物，且評估其對各處理之反應。使用〇至1〇〇之等級進行評估。1〇〇意指植物未出芽或至少地上部分被完全破壞，而〇意指無破壞或生長過程正常°良好除草活性應得到至少7〇之數值，且極佳除草活性應得到至少85之數值。將各種所述組份A及B及（若適當）C調配為1〇重量％強度乳液濃縮物’且添加指定量溶劑系統，將其引入用於施加活性化合物之噴灑液中。在該等實例中，所用溶劑為水。測試時間分別長達20及21天。在此期間，照管該等植物並監測其對用活性化合物處理之反應。在下文實例中’若個別活性化合物之活性僅具有加和性，則使用 S. R. Colby (1967)「Calculating synergistic and antagonistic responses of herbicide combinations」，Weeds 15，第22頁及之後各頁之方法來計算預期e值。 E= X + Y - (X-Y/100) 其中： X=以施用率a使用活性化合物A之百分比活性；以施用率b使用活性化合物B之百分比活性； E=以施用率a + b使用A + B之預期活性（％)。若實驗觀測到之數值高於根據Colby計算之數值e，則存在協同效應。已測試以下活性化合物：式1.1.1之苯并哼畊酮 150107.doc -106· 201109321 式L2.1之苯并啰畊酮式1.2.2之笨并井酮 °密°定肪草醚（b4類）：除草劑B.76 阿拉特啩（b3類）：除草劑B.54 特帕米腙（b5類）：除草劑B.90 草甘膦-異丙基銨（b6類）：除草劑B.95 施德圃（b9類）：除草劑B ·丨〇〇乙草胺（bl〇類）：除草劑B.102 精二曱吩草胺（bi〇類）：除草劑B.105 氟草胺（bl〇類）：除草劑β·ι〇7 派羅克殺草石風雙苯噚唑酸：安全劑C.8 溫室實驗中所用之植物係以下物種：拜耳代碼 (Bayer code 學名稱英文名稱 AMARE 反枝寬(Amaranthus retroflexus) 宽菜(common amaranth) APESV 阿彼拉草(Apera spica-venti) 知風草(windgrass) COMBE 圓葉鴨疏草(Commenline benghalensis) 孟加拉鴨疏草(bengal commenlina) ELEIN 螺蟀草(Eleusine indica) 牛筋草(wiregrass) LAMPU 圓齒野芝麻(Lamium purpureum) 紅色野蓴麻(red deadnettle) SETVE 倒刺狗尾草(Setaria verticillata) 剛毛狗尾草(bristly foxtail) SOLNI 龍葵草(Solanum nigrum) 天論草(black nightshade) VERPE 臺北水苦賈(Veronica persica) 婆婆納屬植物(speedwell) 該等測試之結果在下文使用實例中給出，且證實本發明化合物之除草效應及包含至少一種式I之苯并σ号V»井酮化合物及至少一種除草劑Β之混合物的協同效應。在此上下文中’ a.s_意指活性物質，其基於1〇〇%活性成份。 150107.doc -107· 201109321 使用實例1 :藉由萌前方法施加之混合物1.1.76的協同除草作用活性物質之施用率（以g/ha表不）抗以下物質之除草活性 COMBE ELEIN 1.1.1 B.76 實驗值計算值實驗值計算值 6.25 — 70 ―― 60 — —— 6.25 80 —— 30 — 6.25 6.25 98 94 98 72 使用實例2 : 在100 g/ha之施用率下，化合物1.2.1展示抵抗以下不期望植物之極佳萌前作用：反枝莧、阿披拉草、圓齒野芝麻、倒刺狗尾草、龍葵草及臺北水苦賈。使用實例3 : 另外，在100 g/ha之施用率下，藉由萌前方法施加之化合物1.2.2可實現極佳地控制以下有害植物：反枝莧、阿彼拉草、圓齒野芝麻、倒刺狗尾草、龍葵草及臺北水苦賈。使用實例4 :藉由萌前方法施加之混合物1.54(1.1.1 + B.54之混合物）的協同除草作用活性物質之施用率(以g/ha表示）抗以下物質之除草活性 DIGSA ABUTH 1.1.1 B.54 實驗值計算值實驗值計算值 13 — 90 — 70 — — 250 10 — 40 — 13 250 100 91 100 82 150107.doc -108- 201109321 Β·54之混合使用實例5 :藉由萌後方法施加之混合物1 物）的協同除草作用活性物質之施用率(以g/ha表示）草活性7-Fluoro-6-isocyanato-4-(prop-2-ynyl)-2Η-benzo[b][l'4] 十井_3(4Η) stored in toluene (anhydrous) ) ketone 2.31 face. 1) 2 (methyl 150107.doc •104·201109321 methionine) butyl decanoate (5.00 g, 24.37 mmol) and triethylamine (0·849 ml, 6.09 mmol) with carbonyl added Diimidazole (CDI) (6 59 g, 40.6 mmol). The resulting mixture was stirred overnight under 80 atmosphere of A. It was then concentrated in vacuo and triturated with EtOAc. The insoluble material was removed by a glass frit and the filtrate was concentrated to give 6.26 g of the title compound. H NMR (d6-DMSO): δ = 3.44 (3Η, s), 4.68 (2H, s), 4.75 (2H, s), 7.109 (1H, br d), 7.26 (1H, br d), 9.31 (1H , br s), 12.12 (1H, br s). Part B: Example of Use The herbicidal action of the compounds and compositions of the present invention was confirmed by the following greenhouse experiments: The culture vessel used was a plastic pot containing about 3·〇% of humus loamy sand as a substrate. Seeds of the test plant seeds were individually sown. For the germination treatment, after sowing, the active compound suspended or emulsified in water is directly applied by means of a finely distributed nozzle. Slowly water the container to promote germination and growth, then cover with a clear plastic cover until the roots of the plant. Unless the active compound negatively affects this coverage, it allows the test plants to germinate evenly. For post-emergence treatment, the test plants were grown to 3_i5 依 according to plant habits and subsequently treated only with the active compound suspended or emulsified in water. To this end, the test plants can be directly sown and grown in the same container, or they can be separately grown into young fields and then transplanted into the test container a few days before the treatment. Depending on the species, the plants were maintained at l〇r to 25T: and 20, respectively. (: to 150107.doc -105- 201109321 35 C. The test period is up to 2-4 weeks. During this period, the plants are taken care of and their response to each treatment is evaluated. Use 〇 to 1〇〇 Assessment. 1〇〇 means that the plant is not germinated or at least the aerial part is completely destroyed, and 〇 means no damage or normal growth process. Good herbicidal activity should be at least 7〇, and excellent herbicidal activity should be at least 85 The various components A and B and, if appropriate, C are formulated as 1% by weight strength emulsion concentrate' and a specified amount of solvent system is added and introduced into the spray liquor for application of the active compound. In the examples, the solvent used was water. The test time was as long as 20 and 21 days, during which time the plants were taken care of and monitored for their response to treatment with the active compound. In the examples below, 'if the activity of the individual active compounds is only For additive, use the method of SR Colby (1967) "Calculating synergistic and antagonistic responses of herbicide combinations", Weeds 15, page 22 and subsequent pages to calculate the expected e E = X + Y - (XY/100) where: X = percentage activity of active compound A at application rate a; percentage activity of active compound B at application rate b; E = use at application rate a + b Expected activity (%) of A + B. If the experimentally observed value is higher than the value e calculated according to Colby, there is a synergistic effect. The following active compounds have been tested: Benzoindolizin 150107.doc - 106· 201109321 Benzene hydrazine formula of formula L2.1 1.2.2 benzoate ketone ° dense acesulfame (b4): herbicide B.76 Alat 啩 (b3): herbicide B .54 Tepamid (b5): Herbicide B.90 Glyphosate-Isopropylammonium (b6): Herbicide B.95 Schmidt (b9): Herbicide B · Acetochlor (bl〇): Herbicide B.102 Dihydropterin (bi〇): Herbicide B.105 Fluramide (bl〇): Herbicide β·ι〇7 Pyrokiller Wind bis-benzoxazole acid: safener C.8 The following plant species used in greenhouse experiments: Bayer code (Bayer code name English name AMARE anti-branch width (Amaranthus retroflexus) wide dish (comm On amaranth) APESV Apera spica-venti windgrass COMBE Commenline benghalensis Bengal commenlina ELEIN Eleusine indica Goosegrass ) LAMPU Lamium purpureum red deadnettle SETVE Setaria verticillata bristly foxtail SOLNI Solanum nigrum black nightshade VERPE Taipei water Veronica persica tempera (speedwell) The results of these tests are given in the following examples of use, and demonstrate the herbicidal effect of the compounds of the invention and the inclusion of at least one benzo-Z-V» ketone compound of formula I And a synergistic effect of a mixture of at least one herbicide. In this context 'a.s_ means an active substance based on 1% active ingredient. 150107.doc -107· 201109321 Use example 1: Synergistic herbicidal action of the mixture applied by the pre-emergence method 1.1.76 The application rate of the active substance (in g/ha) The herbicidal activity against the following substances COMBE ELEIN 1.1.1 B.76 Calculated values of experimental values Calculated values of experimental values 6.25 — 70 — 60 — — 6.25 80 — 30 — 6.25 6.25 98 94 98 72 Use example 2 : Compound 1.2.1 at an application rate of 100 g/ha Shows excellent pre-emergence effects against the following undesired plants: Amaranthus retroflexus, Abraham, scalloped sesame, barbed foxtail, Solanum nigrum and Taipei water. Use Example 3: In addition, under the application rate of 100 g/ha, the following harmful plants can be optimally controlled by the compound 1.2.2 applied by the pre-emergence method: Amaranthus retroflexus, A. aconite, scalloped sesame , barbed foxtail, longan grass and Taipei water bitter Jia. Use Example 4: Co-herbicidal active substance application rate (expressed in g/ha) of a mixture of 1.54 (1.1.1 + B.54 mixture) applied by pre-emergence method. Herbicidal activity against the following substances DIGSA ABUTH 1.1. 1 B.54 Experimental value calculated value Experimental value calculated value 13 — 90 — 70 — — 250 10 — 40 — 13 250 100 91 100 82 150107.doc -108- 201109321 Β·54 mixed use example 5: by Meng Meng Method for the synergistic herbicidal action of the mixture (applied by g/ha)

PAKDI 1.1.1 3.1 B.54 3.1 250 250 實驗值 80 45 100PAKDI 1.1.1 3.1 B.54 3.1 250 250 Experimental value 80 45 100

COMBE 實驗值計算值 70 89 使用實例6:藉由萌前方法施加之混合物176(I1」+ I%之混合物）的協同除草作用活性物質之施用率(以g/ha表示) 草活性COMBE experimental value Calculated value 70 89 Use example 6: Synergistic herbicidal action of mixture 176 (I1" + I% mixture) applied by pre-emergence method Application rate of active substance (expressed in g/ha) Grass activity

使用實例7:藉由萌前方法施加之混合物19〇(11 i + B9〇之混合物）的協同除草作用活性物質之施用率(以g/ha表示） in'.ART ΙΤΜ ΐΐόκ. ΐί .'i. 1.1.1 B.90 實驗值古4·览植 13 — ____ 70 δΤ并谓· __ — 10 _____ 30 13 10 ___ 85 79 150107.doc •109· 201109321 使用實例8 :藉由萌後方法施加之混合物丨,9〇(ι_ 1.1 + B 9〇之混入物）的協同除草作用活性物質之施用率(以g/ha表示）抗 SETVI 之： 1.1.1 B.90 ----- 實驗值 ------ _„計算值一 6.25 -- 75 — 5 85 | 6.25 5 98 — 96 使用實例9 :藉由萌後方法施加之混合物1.95(1.1.1 + B95之混人物）的協同除草作用活性物質之施用率(以g/ha表示）抗以下物質之险草活性Use Example 7: Application rate of synergistic herbicidal active substance (expressed in g/ha) of a mixture of 19 〇 (a mixture of 11 i + B9 藉) applied by a pre-emergence method in'.ART ΙΤΜ ΐΐόκ. ΐί .'i 1.1.1 B.90 Experimental value Ancient 4·Viewing 13 — ____ 70 δΤ and __ — 10 _____ 30 13 10 ___ 85 79 150107.doc •109· 201109321 Use example 8: Apply by post-emergence method The application rate of the synergistic herbicidal active substance (expressed in g/ha) of the mixture 〇, 9〇 (mixture of ι_ 1.1 + B 9〇) is resistant to SETVI: 1.1.1 B.90 ----- Experimental value - ----- _„ Calculated value 6.25 - 75 — 5 85 | 6.25 5 98 — 96 Example 9: Synergistic herbicidal action of a mixture 1.95 (1.1.1 + B95 mixed character) applied by post-emergence method Application rate of active substance (expressed in g/ha)

COMBE 1.1.1 3.1 B.95 3.1 135 135 實驗值 80 60 100 CASOB 計算值 92COMBE 1.1.1 3.1 B.95 3.1 135 135 Experimental value 80 60 100 CASOB Calculated value 92

使用實例10 ··藉由萌前方法施加之混合物LiOOG.I.l +B.100之混合物）的協同除草作用抗以下物質之除苴任活性物質之施用率(以g/ha表不） SE1 rvi ----—. _ echcg 1.1.1 B.100 實驗值計算值實驗值計算值 13 —— 90 — 60 600 90 ~ ---- 70 — 13 600 100 99 Ί 95 ------ 88 150107.doc • 110· 201109321 使用實例11 :藉由萌前方法施加之混合物^02(1. Μ +B.102之混合物）的協同除草作用活性物質之施用率(以g/ha表示）抗以下物質之除箪活柹 DIGSA SETVI 1.1.1 B.102 實驗值計算值實驗值計算值 13 — 90 — 90 — 300 30 — 65 13 300 100 93 100 97 使用實例12 :藉由萌前方法施加之混合物1.105(1丨丨+ Β 1〇5之混合物）的協同除草作用活性物質之施用率（以g/ha表示） 1.1.1 B.105 25 —— 31 25 31 實驗值 40 95 草活性Use Example 10 · Synergistic herbicidal action of the mixture of LiOOG.Il + B.100 by the pre-emergence method) The application rate of the active substance to the following substances (in g/ha) SE1 rvi - ----. _ echcg 1.1.1 B.100 Calculated value of experimental value Calculated value of experimental value 13 —— 90 — 60 600 90 ~ ---- 70 — 13 600 100 99 Ί 95 ------ 88 150107 .doc • 110· 201109321 Use example 11: Synergistic herbicidal action rate (in g/ha) of synergistic herbicidal action of mixture 02 (1. Μ + B.102 mixture) applied by pre-emergence method DIGSA SETVI 1.1.1 B.102 Calculated value of experimental value Calculated value of experimental value 13 — 90 — 90 — 300 30 — 65 13 300 100 93 100 97 Use example 12 : Mixture applied by pre-emergence method 1.105 Synergistic herbicidal action rate of active substance (in g/ha) of 1.1 B.105 25 —— 31 25 31 Experimental value 40 95 Grass activity

BRAPLBRAPL

ERBVI 計算值 _實驗值 70 計算值 94 25 95 使用實例π :藉由萌前方法施加之混合物丨1〇7(1丄工合物）的協同除草作用活性物質之施用率(以g/ha表示） 1.1.1 B.107 25 ·· -- 60 25 60 78 B.107之混草活性ERBVI calculated value _ experimental value 70 calculated value 94 25 95 use example π : synergistic herbicidal active substance application rate (expressed in g/ha) of the mixture 丨1〇7 (1 丄 complex) applied by the pre-emergence method 1.1.1 B.107 25 ·· -- 60 25 60 78 B.107 mixed grass activity

150107.doc •⑴- 201109321 使用實例14:藉由萌後方法施加之混合物28.95(1.1.1 + b.76+ B.95之混合物）的協同除草作用活性物質之施用率(以g/ha表示）抗以下物質之除草法忡 COMBE ER] CA 406 B.76 B.95 實驗值計算值實驗值計算值 3.1 — — 75 — 75 — 1.56 — 30 — 45 — — 68 35 一 80 --- 3.1 1.56 68 100 89 — 100 97 使用實例15 :藉由萌前方法施加之LU與派羅克殺草砜之混合物的協同除草作用活性物質之施用率(以g/ha表示) 派羅克殺草硬150107.doc • (1)- 201109321 Use Example 14: Co-herbicidal active substance application rate (in g/ha) of a mixture of 28.95 (1.1.1 + b.76 + B.95 mixture) applied by post-emergence method ) Weeding method against 忡 COMBE ER] CA 406 B.76 B.95 Calculated value of experimental value Calculated value of experimental value 3.1 — — 75 — 75 — 1.56 — 30 — 45 — — 68 35 80 --- 3.1 1.56 68 100 89 — 100 97 Use Example 15: Synergistic herbicidal action rate of active substance (in g/ha) of a mixture of LU and pyroxasulfone applied by pre-emergence method.

6.25 6.25 1.1.1 6.25 6.25 使用實例1藉由碰方法施加之Lu與派羅克殺草狀混合物的協同除草作用 6.25 6.25 6.25 6.25 活性物質之施用率(以g/ha表示） 111 派羅克殺草砜6.25 6.25 1.1.1 6.25 6.25 Use example 1 Synergistic herbicidal action of Lu and Parox herbicide mixture by collision method 6.25 6.25 6.25 6.25 Application rate of active substance (expressed in g/ha) 111 Pyrokiller Grass sulfone

14、派羅克殺草碾與C.814, Parrot kills grass and C.8

使用實例17:藉由萌前方法施加之L 之混合物的協同除草作用 _質之施用率(以g/ha表示^ 1.1.1 C.8 派羅克殺箪石思 13 75 — 3.12 13 75 _ 3.12 50 值 150107.doc -112·Use Example 17: Synergistic herbicidal action of a mixture of L applied by a pre-emergence method _ Quality application rate (expressed in g/ha) 1.1.1 C.8 Pyrocent Killing Stones 13 75 — 3.12 13 75 _ 3.12 50 value 150107.doc -112·

Claims

201109321 VII. Patent application scope: 1 · A herbicidal composition comprising: A) at least one benzoxanthone compound of formula I

R2 wherein: R1 is hydrogen or CVCV alkyl; R2 is hydrogen, NHyC^CV alkyl or C3-C6-alkynyl; R3 is hydrogen or halogen; R4 is hydrogen, CVCV alkyl, CVCV haloalkyl, C3-C6- Cycloalkyl, C3-C6-alkenyl, c3-C6-haloalkenyl, C3-C6-alkynyl, C3-C6-haloalkynyl, Ci_c6-alkoxy or c3_c6_cycloalkyl_Ci_C6_ a base; X system or S; Y system or S; and at least another '/ tongue compound selected from: B) M) to M5) herbicides: bl) lipid biosynthesis inhibitors; B2) acetamidine lactate synthase inhibitor (ALS inhibitor); b3) photosynthesis inhibitor; b4) protoporphyrinogen-IX oxidase inhibitor; b5) pigment inhibiting herbicide; 150107.doc 201109321 b6) Alcohol acetone oxalic acid 3-phosphate synthase inhibitor (EPSP inhibitor); b7) branamine synthase inhibitor; b8) 7,8-dihydropteroate synthase inhibitor (DHP inhibitor); b9 Mitotic inhibitors; b 10) very long chain fatty acid synthesis inhibitors (VLCFA inhibitors); bll) cellulose biosynthesis inhibitors; bl2) decoupled herbicides; bl3) auxin herbicides; bl4) auxin transporters Formulations; and b 1 5) other herbicides selected from the group consisting of bromobutide, chlorflurenol, chlorflurenol-methyl, cinmethylin ), cumyluron, dalapon, dazomet, difenzoquat, oat-methyl-methyl sulfate, dimethipin, DSMA, dymron , endothal and its salts, etobenzanid, flamprop, flamprop-isopropyl, flamprop-methyl, Flavo-M-isopropyl, flamprop-M-methyl, flurenol, flurenol-butyl, ° husband. Flurprimidol, fosamine, chlorhexidine-x, oxatone 150107.doc 201109321 (indanofan), indziflam, maleic hydrazide, fluroxypyr (mefluidide), metam (metham), azido methane, methyl bromide, sulfhydryl-aluron, methyl iodide, MSMA, oleic acid, oxaziclomefone, citric acid 'pyributicarb' , quinoclamine, triaziflam, chlorpyrifos (by (^1^116) and 6-chloro-3-(2-cyclopropyl-6-methylphenoxy)- 4-pyridazinol (CAS 499223-49-3) and its salts and esters; and C) full dose. 2. The composition of claim i, wherein the variables R1, R2, R3, r4, χ and γ in formula I have the following meanings: R1 and H2 are ^-匕-alkyl; R3 is halogen; r4 is c3- C6-alkynyl; x is S; and y is 〇. 3. The composition of claim 1 or 2, which has 4 persons s, m having at least one herbicide B selected from the group consisting of the following: a group derived from a lipid biosynthesis inhibitor: ―), 黯草黯(cl〇dinaf〇p_pr〇pargyi), 环杀卓(10)loxydim) H 草 s (cyhai〇f〇p_一1), 禾草灵(dlCl〇f〇p-methyl), fine Ethyl ten sitting grass grass (--P-150107.doc 201109321 ethyl), butyl fine 0 fluazifop-P-butyl, fluorinated 0 haloxyfop-P-methyl , p number. Sitting on methamphet (metamifop). Sitting on the grass, Spirulina _ (profoxydim), Propaquizafop, ethyl quinone (quizalofop-P-ethyl), Jing 0 奎禾糠 S (quizalofop-P) -ethyl), sethoxydim, tepraloxydim, tralkoxydim, benfuresate, dimepiperate, EPTC, esprocarb ), ethofumesate, grass, orbencar, prosulfocarb, thiobencarb, and triallate; b2) The following groups of ALS inhibitors: 醯"amidosulfuron", four. Sitting on azimsulfuron, bensulfuron-methyl, bispyribac-sodium, chlorimuron-ethyl, chlorsulfuron, strontium Cloransulam-methyl, cyclosulfamuron, diclosulam, ethametsulfuron-methyl, ethoxysulfuron, volts Flazasulfuron, flavosulam, flucarbazone-sodium, flucetosulfuron, flumetsulam, bite Flupyrsulfuron-methyl-sodium 'foramsulfuron, 曱 base gas 0 than halosulfuron-methyl, methyl 0 oxalic acid (imazamethabenz-methyl), A Oxyza 0x (imazamox), methyl glutinosa end (imazapic), yoghurt 150107.doc 201109321 (imazapyr), imidaquinacic acid (imazaquin), imidazolidin (imazethapyr), ezosulfuron, Iodosulfuron, vermiculite-methyl-sodium (i〇d) Osulfuron-methyl-sodium), mesosulfuron, double mystery. Metazosulfuron, metosulam, metsulfuron-methyl, y. Nicosulfuron, orthosulfamuron, oxasulfuron, penoxsulam, primisulfuron-methyl, propylbenzene Propoxycarbazon-sodium, propyrisulfuron, prosulfuron, pyrazoosulfuron-ethyl, pyribenzoxim, ° Pyrimisulfan, pyrifalid, pyriminobac-methyl, pyrithiobac-sodium, pyroxsulam, jade mouth Mimstone rimsulfuron, sulfameturon-methyl, sulfosulfuron, thiencarbazone-methyl, 0 sequel-sulphur Thifensulfui'on-methyl), triasulfuron, tribenuron-methyl, triHoxysulfuron, triflusulfuron-methyl and trigaspene Shitolong (tritosulfuron); b3) from the following photosynthesis Group of preparations: ametryn, amine amicarbazone, atrazine, bentazone, bentazon-sodium, bromoxynil 150107.doc 201109321 (bromoxynil) And its salts and vinegar, chloridazone, chlorotoluron, cyanazine, desmedipham, diquat-dibromide, diuron ), fluometuron, hexazinone, ioxynil and its salts, and S, isoproturon, lenacil, linuron , benzophenone (11161311111^011), methylbenzene ° sialon (11161; 113561121; 111 & 2111 '011), mesopurin (metribuzin), paraquat (paraquat), turf fast dihydrochloride (paraquat-dichloride), phenmedipham, propanil, pyridate, simazine, terbutryn, terbuthylazine, and alpha phenylephrine (thidiazuron); b4) from the following group of proto-lin-IX oxidase inhibitors: Axifen (acifluorfen-sodium), bencarbazone, benzfendizone, butafenacil, carfentrazone-ethyl, ketoxime Cinidon-ethyl), Dun. 1114 flufenpyr-ethyl, flumiclorac-pentyl, flumioxazin, fluoroglycofen-ethyl, oxalic acid (fomesafen) 'lac.tofen, oxadiargyl, oxadiazon, oxyfluorfen, pentoxazone, D ratio Grass ether (pyraflufen-ethyl), ° dense. Saflufenacil, sulfentrazone, [3-[2- gas-4-fluoro-5-(1-mercapto-6-trimilyl)-150107.doc 201109321 2, 4 - alkoxy-1,2,3,4-tetrahydro-densate, ethyl-3-yl)phenoxy]_2-t> nt decyloxy]acetate (CAS 353292-31-6 ;S-3100), Ν-ethyl-3-(2,6-dioxa-4-trifluoromethylphenoxy)-5-mercapto-1H-0 than 嗤-1-carboxamide (CAS 45 2098-92-9), N-tetrahydrofuranyl-3-(2,6-dichloro-4-tridommethylphenoxy)-5-mercapto-1H-. ratio.曱醯-1-decylamine (CAS 915396-43-9), N-ethyl-3-(2- gas-6-fluoro-4-trifluoromethylphenoxy)_5·decyl-1H-pyridyl Oxazol-1-decylamine (C AS 45 2099-05-7) and N-tetrahydrofuranyl-3-(2- gas-6-fluoro-4-trifluoromethylphenoxy)-5- Base-1H-" than sal-1-amine (CAS 45100-03-7); b5) from the following group of pigment-inhibiting herbicides: aclonifen, beflubutamid, Benzobicyclon, clomaz〇ne, diflufenican, fiurochl〇rid〇ne, flurtamone, isoxaflut 〇ie), mesotrione, norflurazon, picolinafen, pyrasulfotole, pyrazoonate, sulcotrione , 糠_ (tefuryltri〇ne), tembotrione, tppramez〇ne, bicyclopyrone, 4-(3-trifluoromethylphenoxy)_2_ (4·Trifluoromethylphenyl) 'bite (CAS 180608-33-7), arnitrole and flumeturon; B6) Groups from the following EPSP synthase inhibitors: glyphosate, glyphosate-isopropylammonium, and glyphosate-trimethylsulfate (glyph〇sate·I50107. Doc 201109321 trimesium) (sulfate Sate) · b7) from the following group of cucurbitin synthase inhibitors; glufosinate giufosinate, grass U (giuf〇sinate p), Glufosinate-ammonium); b8) from the DHP synthase inhibitor group: chlorhexidine ((iv) iam); b9) from the following mitotic inhibitors: benfluralin, dithi〇pyr, diced i ethalfluralin, oryzalin, pendimethaUn, thiazopyr, and trifluralin; b 10) from the following VLCFA inhibitors: acetochlor , aiachl〇r, anU〇f〇s, butachlor, cafenstr〇ie, dimethenamid, dithiophene Dimethenamid (p), tetrazolone, fiufenacet, mefenacet, Metazachlor, metolachlor, S-momoda, naproanilide, napropamide, pretilachlor, fenoxasulfone, Ipfencarbazone, thenylchlor, and the 11th oxazoline compound of formula 11.1, 11.2, 11.3, 11.4, 11.5, 11.6, 11.7, 11.8, and 11.9;

150107.doc 201109321

Bl 1) from the following group of cellulosic biosynthesis inhibitors: valeronitrile (dichioben H), muramoxazole (flup〇xam), isovaleramide (is〇xaben) and 1-cyclohexyl-5-pentafluoro Benzyloxy Yu#]嚷三呼_3_ylamine; bl3) from the following auxin herbicides: 2,4-D and its salts and brewing, gas amine D than bite acid (amin〇pyraiid) and a salt (for example, a gas amine, a ratio of acid-indole (2-hydroxypropyl) ammonium and its ester), clopyralid and its salts, vinegar, dicarnba and its salts, and Dichlorprop-P and its salts and esters, fluorine ratio (fluroxypyr-meptyl), MCPA and its salts and esters, MCPB and its salts, and vinegar, refined 2曱4 propionic acid ( Me coprop-P) and its salts and vinegar, picloram and its salts and g, quinclorac, quinmerac, triclopyr and its salts and Vinegar, and cyanoacrylate. "aminocyclopyrachlor" and its salts and S; bl4) from the following group of auxin transport inhibitors: diflupirone 150107.doc 201109321 (diflufenzopy) and diflupiron sodium; Chuan) from the following other weeding Group of agents: chlorpyrifos, chlorpyrifos, valerian, thatch 'oat gluten, oat glutamate-methyl sulfate, DSMA, chlorpyrifos (=dahn Uron), wheat straw fluoride, wheat straw fluoroisopropyl Base, wheat straw fluorine-f base, wheat straw fluoride _M_isopropyl, wheat straw fluoride _M_methyl, oxaloin, jiezifu g, Meitan, Mocha, MSMA, decoan, valerian, Trifluoperazone, chlorpyrifos and 6-chloro-3-(2-cyclopropyl-6-methylphenoxy)-4-indolyl alcohol (CAS 499223-49-3) and its salts and esters. The composition according to any one of items 1 to 3, which comprises at least one herbicide B selected from the group consisting of b2, b3, b4, b5, b6 'b9 and blO herbicides. The composition according to any one of claims 1 to 4, which comprises at least one safener selected from the group consisting of: benzoxadone (ben〇xac〇r), detoxified quinine (cloquintocet), chloracetamide ( Cy〇metrjnii), cyprosulfamide, dichlormid, dicyclonone, phenylthiosulphonic acid, dithyl, and herbicide. Fenchlorazole, fendorim, furilazole, fluxofenim, furilazole, isoxadifen, pyrazole oxalate ( Mefenpyr), mephenate, naphthalene dicarboxylic acid needle, oxabetrinil, 4-(dichloroethenyl)-1-oxa-4-azaspiro[4.5]decane (MON4660, CAS 71526-07-3) and 2,2,5-trimethyl 3-(dioxaethyl)-1,3-oxazolidine (R-29148, CAS 52836-3 1-4) » 6 The composition of any one of claims 1 to 5, wherein the weight ratio of component A to component B is between 1:1000 and 1000:1. The composition of any one of items 1 to 6, wherein the weight ratio of component a to component c is between 1:1000 and 1000:1. 8. The composition of any one of claims 1 to 7 in the form of a crop protection composition' which further comprises an adjuvant commonly used in the formulation of crop protection agents. A method of controlling undesired vegetation, wherein a herbicidal effective amount of the composition according to any one of claims 1 to 8 is applied to a plant, its habitat or a seed. The method of claim 9, wherein the composition of any one of claims 1 to 8 is applied before, during and/or after the germination of the undesired plants, wherein the herbicidal active components are A) and B) and / or c) are applied simultaneously or sequentially. The method of claim 9, wherein the crop plants and the leaves of the undesired plants are treated. 12. Use of a composition according to any one of claims 1 to 8 for controlling undesired vegetation. 150107.doc 201109321 IV. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbol of the symbol of the representative figure is simple: 5. If there is a chemical formula in this case, please reveal the best indication of the characteristics of the invention. Chemical formula:

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