201018585 九、發明說明： 【發明所屬之技術領域】 本發明係有關一種抗靜電膠皮之製造技術，特別是指一種聚氣乙 烯抗靜電膠皮之製造方法。 【先前技術】 按，在電子工業及製藥工業之快速成長下，刺激了抗靜電材料的 需求，如電子產品之製造、運送、包裝、儲存等均需要做好靜電的防 * 護。再者電子廠或製藥廠無塵室内使用之地板、工作台面、操作工具、 防塵口軍、手套、無塵衣等，以及在其他工業如食品包裝及化學工礙 〇 的原料儲存運送等，如果有抗靜電材料的幫助，不僅可增加作業的方 便性，更可避免重大災害造成的損失。 聚氣乙稀(PVC)是人造聚合物中最重要且使用最普遍的一種，主要 是因為它具有很大的變異性，在製造聚氣乙烯產品的過程中可配合不 同的用途和需要’加入各種可塑劑及添加劑來改變其物理或化學性質。 聚氣乙烯(PVC)為絕緣體，具有很高的電阻係數，電阻係數約為 1012〜1013 Ohm/sq，其本質為良好的電氣絕緣體，所以其製品容易因 磨擦而產生靜電。但由於本公司產品所使用的加工機器，如混料器 (Mixers)、壓延機(Calendars)皆為容易產生磨擦的機器，在對非導性 © 高分子加工時，就如同靜電發電機一樣，會產生過量的電荷聚集於膠 料、加工機台表面，而影響此高分子材料之後段加工性與操作人員的 安全。所以為了解決靜電的問題，通常會以幾種方式使用：抗靜電劑 添加、賦予其他導電材料:導電碳黑、空氣離子化及提高相對濕度。 因此’本發明即提出一種聚氯乙烯抗靜電膠皮之製造方法，以有 效克服上述之該等問題，具體架構及其實施方式將詳述於下。 【發明内容】 本發明之主要目的在提供一種聚氣乙烯抗靜電膠皮之製造方法， 其係於聚氣乙稀勝料中加入内在型抗靜電劑，使製作出之聚氣乙烯抗 201018585 靜電膠皮具有良好之抗靜電效果。 本發明之另一目的在提供一種聚氣乙烯抗靜電膠皮之製造方法， 其所製造出之聚氣乙烯抗靜電膠皮之膠面無導電碳黑之污染。 為達上述之目的，本發明提供一種聚氣乙烯抗靜電膠皮之製造方 法包括下列步驟：於-底布上塗佈一層糊料，加熱烘乾後收捲成一糊 布；將-聚氣乙稀膝料加工後形成一谬布；以及將膠布與糊布貼合， 形成-聚氣乙烯壓延敎。而聚氣乙轉料之成分包含：彳⑽重量份 之塑膝粉、60重量份之可塑劑、16重量份之填充劑、17重量份之抗 靜電劑、2重量份之安定劑、以及色粒。 • 底下藉由具趙實施例詳加說明，當更容易瞭解本發明之目的、技 術内容、特點及其所達成之功效。 【實施方式】 本發明提供-種聚紅職ι靜電做之製造方法，其係針對工業 ，止塑料帶靜電需求’以織物或非織物之布種加人導電碳黑並在聚 氣乙稀(PVC)膠料中加人高分子型抗靜電劑特別配方比例相互作用配 合製程生產線^各機具，進而製造出一種聚氣乙稀抗靜電膠皮。 第-圖所福本發_程巾所使狀機具，包含裱峨1Q及膠布 機（Calendars) 12，而膠布機12中又包括高速鮮機122、萬馬力機 ϋ 124、粗、細輪126以及膝布機本趙128。 第二圖本發明應用第-圖中各機具之製造方法的流程圖，請同時 參考第-圖。步驟S10中，利用裱糊機1()於—底布上塗佈—層糊料， ，裱糊機10之上糊輪為30~120目，底布為織物或非織物糊料係以 包括溶劑糊及可塑糊之糊劑為主，上糊量為5_咖2 ;並如步驟 S12所述，將此塗佈有糊料之底布以1〇±2〇秒之加 之加工溫度加熱烘乾後收捲成一糊布。 接著為製作-聚氣乙烯勝料之步驟。首先於步驟S14中將1〇〇重 量份之塑膠粉、60重量份之可塑劑、16重量份之填充劑、17重量份 201018585 之抗靜電劑、2重量份之安定劑、以及色粒等原料於高速攪拌機122 中進行攪拌’高速攪拌機122之轉速為2000±300轉，溫度為100±20 。0，挽拌時間為4〜6分鐘；步驟S16中樣拌均勻之聚氣乙烯膠料於萬 馬力機124中混煉膠化，萬馬力機124之溫度為150±20eC，混煉膠 化過程為3〜6分鐘，隨即轉入粗、細輪126中進行步驟S18保溫控料 之步驟以利後績加工，溫度控制在140±20。(〕，保溫時間約2~4分鐘； 膠化之聚氣乙烯膠料接著如步驟S20所述，經由輸送帶送入一膠布機 本艘128中，控制宽度和厚度形成一膠布；最後步驟S22中將膠布機 12出料之膠布與糊布貼合，形成一聚氣乙烯壓延膠皮。 φ 聚氣乙烯膠料之原料中，可塑劑包含40重量份之第一可塑劑及 20重量份之第二可塑劑;抗靜電劑包含15重董份之液狀抗靜電劑及2 重量份之蠟狀抗靜電劑，且抗靜電劑為内在型抗靜電劑（丨ntemal antistatic agent);色粒包含紅色、綠色、藍色及黃色色粒；安定劑為 銷辞系（BaZn)粉態安定劑。 舉一實施例如下所述。可依成品用途特性選擇適當之布料做為底 布’如尼龍(Nylon)，此布種中加入導電碳黑準備與抗靜電劑相互作用， 並以溶液糊為糊料，使底布尼龍可與聚氣乙烯膠料相互黏著一體。以 刀裱方式於底布上塗佈糊料，經由加熱烘乾捲取而成糊布，以供膠布 G 機貼合使用。 接著將聚氣乙烯膠料之原料混合膠化後，經由膠布機測量厚度及 控制寬度形成膠布後’出料與裱糊機之糊布貼合，構成聚氣乙烯抗靜 電壓延製品。此聚氣乙晞抗靜電壓延製品之電阻係數為1〇7〇hm/sq， 且膠面並無導電碳黑污染。 綜上所述，本發明所提供之聚氣乙烯抗靜電膠皮之製造方法係於 聚氣乙稀膠料之原料中加入了内在型抗靜電劑(丨nternai副細此 agent) ’然後再慢慢擴散於塑膠表面(約經24〜72小時），故效果長久 及信賴度高，具有優越持久的抗靜電性，能將電阻係數降低至1〇7 201018585 ohm/sq，且不會有一般抗靜電劑之耐久性、耐熱性、溫度依存性等問 題，應用本發明之製造方法所製作之聚氣乙烯抗靜電膠皮可達到理想 的抗靜電效果。 唯以上所述者，僅為本發明之較佳實施例而已，並非用來限定本 發明實施之範圍。故即凡依本發明申請範圍所述之特徵及精神所為之 均等變化或修飾，均應包括於本發明之申請專利範圍内。 【圖式簡單說明】 第一圖為本發明聚氣乙烯抗靜電膠皮之製程之方塊圖。 第二圖為本發明聚氣乙烯抗靜電膠皮之製造方法之流程圓。 φ 【主要元件符號說明】 10裱糊機 12膠布機 122高速攪拌機 124萬馬力機 126粗、細輪 128膠布機本體201018585 IX. Description of the Invention: [Technical Field] The present invention relates to a manufacturing technique of an antistatic rubber, and more particularly to a method for producing a polyethylene-based antistatic rubber. [Prior Art] According to the rapid growth of the electronics industry and the pharmaceutical industry, the demand for antistatic materials is stimulated. For example, the manufacture, transportation, packaging, and storage of electronic products require the protection of static electricity. In addition, the floor, work surface, operating tools, dust-proof army, gloves, dust-free clothes, etc. used in the clean room of the electronics factory or the pharmaceutical factory, as well as the storage and transportation of raw materials in other industries such as food packaging and chemical industry, etc. The help of anti-static materials not only increases the convenience of the operation, but also avoids the losses caused by major disasters. Polyethylene (PVC) is the most important and most commonly used type of man-made polymer, mainly because it has great variability. It can be used in different processes and needs in the process of manufacturing poly-glycol products. Various plasticizers and additives to change their physical or chemical properties. Polyethylene (PVC) is an insulator with a high electrical resistivity and a resistivity of about 1012~1013 Ohm/sq. It is a good electrical insulator, so its products are prone to static electricity due to friction. However, the processing machines used in our products, such as Mixers and Calans, are machines that are prone to friction. When machining non-conductive © polymers, it is like an electrostatic generator. Excessive charge will be accumulated on the surface of the rubber and processing machine, which will affect the processability of the polymer material and the safety of the operator. Therefore, in order to solve the problem of static electricity, it is usually used in several ways: antistatic agent, adding other conductive materials: conductive carbon black, air ionization and increasing relative humidity. Therefore, the present invention proposes a method for producing a polyvinyl chloride antistatic rubber to effectively overcome the above problems, and the specific structure and its embodiment will be described in detail below. SUMMARY OF THE INVENTION The main object of the present invention is to provide a method for producing a polyethylene-gas antistatic rubber, which comprises adding an intrinsic antistatic agent to a polyethylene gas smelter to make a polyethylene anti-201018585 electrostatic rubber film. Has a good antistatic effect. Another object of the present invention is to provide a method for producing a polyethylene-gas antistatic rubber, wherein the rubber surface of the polyethylene-gas antistatic rubber produced by the invention has no conductive carbon black contamination. In order to achieve the above object, the present invention provides a method for manufacturing a polyethylene-gas antistatic rubber, comprising the steps of: coating a layer of paste on a base fabric, heating and drying, and then winding into a paste; After the knee material is processed, a crepe cloth is formed; and the tape is bonded to the paste cloth to form a gas-polyethylene calendering crucible. The component of the gas-gathering material comprises: 彳 (10) parts by weight of the plastic knee powder, 60 parts by weight of the plasticizer, 16 parts by weight of the filler, 17 parts by weight of the antistatic agent, 2 parts by weight of the stabilizer, and color grain. • The purpose, technical content, features, and effects achieved by the present invention will be more readily understood by the detailed description of the embodiment. [Embodiment] The present invention provides a method for manufacturing a kind of poly red job, which is directed to the industry, and the static electricity requirement of the plastic belt is added to the fabric or the non-woven fabric to add conductive carbon black and to be in the polyethylene ( In the PVC) compound, the special formula of the polymer type antistatic agent is added to cooperate with the process production line, and each machine tool is manufactured to produce a polyethylene-dioxide antistatic rubber. The picture shows the machine tool, including the 裱峨1Q and the tapes machine 12, and the tape machine 12 includes the high speed fresh machine 122, the 10,000 horsepower machine 124, the thick and thin wheels 126, and Knee cloth machine Zhao Zhao 128. Fig. 2 is a flow chart showing the method of manufacturing each of the implements in the first embodiment of the present invention. Please refer to Fig. In step S10, the paste paste is applied to the base fabric by using the paste machine 1 (), and the paste wheel on the paste machine 10 is 30-120 mesh, and the base fabric is a woven or non-woven paste system to include a solvent paste. And the paste of the plastisable paste is mainly, the amount of the paste is 5_coffee 2; and as described in step S12, the base cloth coated with the paste is heated and dried at a processing temperature of 1 〇 ± 2 〇 seconds. Roll it into a paste. Followed by the steps to make - polygas to win the material. First, in step S14, 1 part by weight of the plastic powder, 60 parts by weight of the plasticizer, 16 parts by weight of the filler, 17 parts by weight of the antistatic agent of 201018585, 2 parts by weight of the stabilizer, and the color particles are used. Stirring was carried out in a high speed mixer 122. The speed of the high speed mixer 122 was 2000 ± 300 rpm and the temperature was 100 ± 20. 0, the mixing time is 4~6 minutes; in step S16, the mixed gas-mixed vinyl rubber is mixed and cemented in the 10,000 horsepower machine 124, and the temperature of the 10,000 horsepower machine is 150±20eC, the mixing and gelling process For 3~6 minutes, it is transferred to the thick and thin wheels 126 to carry out the step of insulating and controlling the material in step S18 to facilitate the processing, and the temperature is controlled at 140±20. (〕, the holding time is about 2~4 minutes; the gelled gas-gas vinyl compound is then fed into a tape machine 128 by a conveyor belt as described in step S20, and the width and thickness are controlled to form a tape; finally step S22 The adhesive tape discharged from the tape machine 12 is bonded to the paste cloth to form a gas-gathered ethylene calendered rubber. In the raw material of the φ gas-glycol rubber compound, the plasticizer contains 40 parts by weight of the first plasticizer and 20 parts by weight. The second plasticizer; the antistatic agent comprises a 15 weight Dong liquid antistatic agent and 2 parts by weight of a waxy antistatic agent, and the antistatic agent is an intrinsic antistatic agent; the color particles include red , green, blue and yellow color particles; stabilizer is BaZn powder stabilizer. One implementation is as follows. The appropriate fabric can be selected as the base fabric according to the characteristics of the finished product, such as nylon (Nylon) ), the conductive carbon black is added to the cloth to prepare an interaction with the antistatic agent, and the solution paste is used as a paste, so that the base fabric nylon and the gas-gas rubber compound are adhered to each other. Cloth paste, which is rolled up by heating and dried to form a paste It is used for bonding G machine. Then, the raw material of the gas-polymerized vinyl compound is mixed and gelled, and then the thickness and the control width are measured by a tape machine to form a tape, and then the material of the material is mixed with the paste machine to form a gas mixture. The anti-static voltage extension product has a resistivity of 1〇7〇hm/sq, and the rubber surface is not contaminated with conductive carbon black. In summary, the polyethylene resistance of the present invention is provided. The method for manufacturing the electrostatic rubber is to add an intrinsic antistatic agent (丨nternai deputy agent) to the raw material of the polyethylene compound, and then slowly diffuse on the surface of the plastic (about 24 to 72 hours). Long-lasting effect and high reliability, with excellent anti-static properties, can reduce the resistivity to 1〇7 201018585 ohm/sq, and there is no problem with the durability, heat resistance and temperature dependence of general antistatic agents. The polystyrene antistatic rubber produced by the manufacturing method of the present invention can achieve a desired antistatic effect. The above is only the preferred embodiment of the present invention and is not intended to limit the scope of the practice of the present invention. All the changes and modifications of the features and spirits described in the scope of the application of the present invention should be included in the scope of the patent application of the present invention. [Simplified description of the drawings] The first figure is a polyethylene-based antistatic rubber of the present invention. The block diagram of the process. The second figure is the flow circle of the manufacturing method of the polystyrene antistatic rubber of the invention. φ [Main component symbol description] 10 paste machine 12 tape machine 122 high speed mixer 1.24 million horsepower machine 126 thick, thin wheel 128 tape machine body