201014545 九、發明說明: 【發明所屬之技術領域】 本發明係有關於-種利用泡珠塗佈發泡基材的面膜及其製 法’尤指利用樹脂液的泡沐塗佈加工方法所製得具有發泡基材的 面膜。 【先前技術】 ❹ 目前’一般面膜有採用不織布、棉、螺縈(Rayon)、耐隆(Nylon) 及聚醋的材質,雖然有經過精華液的吸收,但是往往會造成敷面 時精華液赫現象,若以生物發賴成的生物賴則會造成 面膜成本的提高,上述賴的製造都是非常傳制,況且填充面 膜精華液即與臉部皮膚直接接觸,因此傳統型製得的面膜特性, 為非具有高吸收水力並能將經華液載於面膜中,且無法提高密封 性無法防止水份的蒸發’使得面膜中的水份無法保持而很快流 φ 失,進而使其功效隨時間而逐漸消失。 【發明内容】 本發明主要目的,係要提出—種彻麟塗佈發泡基材的面 膜及其製法發明案申請,主要首先進行塗佈^^調配液作為塗佈液 ’並將適當的塗佈量(50〜10_2)利用刮刀塗佈在離型布的表層並 形成〇· 3m/m〜1. 〇m/m的塗佈厚度,其中離型布係指聚酯離型布或 耐隆離型布,並以發泡比〜1:5)進行機械發泡作用並形成發泡 塗佈液主要包括有聚氣基甲酸樹脂(PU,『的丨^)或丙 5 201014545 烯酸酯(AC,acrylic resin)...............等與助劑、起泡劑、架橋 劑及觸媒,再以ll〇°Cx2min預乾及160°Cx2min下進行烘乾後即 獲得具有透濕度10000〜9000/m2/D的高保濕度與多微孔的離型織 物,再進行切成面膜形狀,另再填充面膜精華液即完成面膜成品。 為了進一步說明本發明之技術内容,茲配合簡單圖式及實施例 說明本發明; ® 【實施方式】 本發明係為一種利用泡沐塗佈發泡基材的面膜及其製法,請參 閱圖1,2’3, 4, 5所示,其中,圖丨,2, 3所示係為本發明之製法流 程圖;首先選擇離型織物(聚酯離型布或耐隆離型布从作為底層 10,經由水性樹脂作為泡沫塗佈調配液B :樹脂1〇〜1〇〇 %、助劑 M〇%、起泡劑〇.1〜丨.⑽、架橋劑〇.卜10%及觸媒〇· 1〜1· 5%,並將 泡沫塗佈調配液B以機械方法起泡c並形成泡沫體d,以5〇〜2〇〇运 ❹/m的塗佈量進行表層20的塗佈加工E如圖2, 3所示,此泡沫塗 佈係利用機械方法加入水性樹脂使產生起泡体,再塗佈於底層1〇 離型織物的表層20的發泡塗佈層F,其中所產生的微多孔薄膜ρι 會形成微孔的結構,並再經由.⑽。c之烘乾G溫度,使用之塗 佈樹脂包括;PU樹脂、AC樹脂、乳膠(丁二婦橡膠聚合物)樹脂及 矽利康彈性體樹脂,此進行表層2〇的塗佈可得透濕度9_ /Day(依jis 1099 η法測試)以上,而表層利用羅拉上刮刀 (kmfe on Roll)塗上水性樹脂並以塗佈量5〇〜咖細進行底層 6 201014545 10之塗佈’其樹脂中添加卜觸三聚氰胺綠橋劑、 =泡:、卜1()% 助劑及 0.1 〜1.5_t_〇(H6(rCx2 刀的)t、乾G ’致使賴高倾度與微纽的離麟物h並經過裁切 面臈形狀1,其中所經過的裁切面膜I中如圖4所示,面膜!裁切 域裁切眼孔3G,3G’及裁切嘴孔4〇後,如圖5所示面膜丨的側 參 視圖亦顯示底層1〇與表層2Q所組成,再經由填充面膜精華液】 後,形成面臈成品K。 兹為了使審紅作者更加明瞭本創作之發哺以實施例及比 較例說明本創作如下: 【實施例1】 取自聚酉旨離型布(單尼數40D/72fx40D/72f,經緯密I67xl38) 的規格離型布作為塗佈加工布的底層,以下列之泡珠塗佈調配液 ί ;織物以’包;末塗佈機進#底層的塗佈,*塗彳相樹脂係指聚氨 ❹基甲酸醋(PU,p〇lyurethane)樹脂選自於公司的產品 則)’以發泡比(1:5)、,塗佈量為73 g/m2,以乾燥ii〇°Cx2分鐘 進行烘乾,钱量15G g/rrf隨魏人烘箱進行⑽。Cxi分鐘固 化,即得一高保濕度與多微孔的面膜,再進行裁切面膜、填充面 膜精華液及完成面膜成品。 其所使用泡沫塗佈調配液如下: PU 樹脂(Bayer Impranil DLN) ιηΠα. 7 201014545 架橋劑M3(台灣氰特公司) 2% 起泡劑VF(晉一化工) 5% 助劑RF(晉一化工) 8% 觸媒4040(台灣氰特公司) 2% 【實施例2】 選自耐隆離型布(70Dx70D,190x190)的規格布作為塗佈加工布 的底層,以下列之泡沫塗佈液對織物以泡沫塗佈機進行底層的塗 佈’而塗佈樹脂係指丙烯醯酯樹脂(AC,acrylic)(批號:E系列產 品)選自於羅門哈斯公司,以發泡比(1:5)、塗佈量為75 ,201014545 IX. OBJECTS OF THE INVENTION: TECHNICAL FIELD The present invention relates to a mask for coating a foamed substrate by using a bead and a method for producing the same, in particular, a foam coating process using a resin liquid. A mask having a foamed substrate. [Prior Art] ❹ At present, the general mask is made of non-woven fabric, cotton, Rayon, Nylon and polyester. Although it is absorbed by the essence, it often causes the essence to be applied. Phenomenon, if the biological reliance on the organism will increase the cost of the mask, the above-mentioned manufacturing is very popular, and the filling mask essence is directly in contact with the skin of the face, so the characteristics of the mask made by the traditional type , because it has high absorption hydraulic power and can carry the Chinese liquid in the mask, and can not improve the sealing property and can not prevent the evaporation of water, so that the moisture in the mask can not be maintained and the flow is quickly lost, so that its efficacy is Time gradually disappears. SUMMARY OF THE INVENTION The main object of the present invention is to provide a mask for coating a foamed substrate and a method for preparing the same, and firstly, the coating liquid is first applied as a coating liquid and the appropriate coating is applied. The amount of cloth (50~10_2) is coated on the surface layer of the release cloth by a doctor blade to form a coating thickness of 〇·3m/m~1. 〇m/m, wherein the release cloth refers to a polyester release cloth or a nylon The release cloth and the foaming ratio of the foaming ratio of ~1:5) and the formation of the foaming coating liquid mainly include a polyglycolic acid resin (PU, "丨^) or C 5 201014545 enoate ( AC,acrylic resin), etc. with additives, foaming agent, bridging agent and catalyst, pre-dried at ll ° ° C x 2 min and baked at 160 ° C x 2 min After drying, a high-moisture and microporous release fabric having a moisture permeability of 10,000 to 9000/m2/D is obtained, and then cut into a mask shape, and the mask essence is further filled to complete the mask product. In order to further explain the technical contents of the present invention, the present invention will be described with reference to the drawings and the embodiments; ® [Embodiment] The present invention is a mask for coating a foamed substrate by using a foam, and a method for preparing the same, see FIG. 2'3, 4, 5, wherein, Figures 2, 3 are the flow chart of the method of the present invention; firstly, the release fabric (polyester release cloth or the resistant fabric) is used as the bottom layer. 10, via a water-based resin as a foam coating solution B: resin 1 〇 ~ 1 〇〇%, auxiliary M 〇%, foaming agent 〇.1 ~ 丨. (10), bridging agent 〇. Bu 10% and catalyst 〇 1~1·5%, and the foam coating preparation liquid B is mechanically foamed c and formed into a foam d, and the surface layer 20 is coated and processed at a coating amount of 5 〇 2 〇〇 2 〇〇 ❹ / m E, as shown in Figs. 2 and 3, the foam coating system is mechanically added to the aqueous resin to produce a foaming body, which is then applied to the foam coating layer F of the surface layer 20 of the underlying release fabric. The microporous film ρι will form a microporous structure, and then through the drying temperature of (10).c, the coating resin used includes; PU resin, AC tree Latex (Ding Ershi Rubber Polymer) resin and yukang elastomer resin, the coating of the surface layer 2 可 can obtain the moisture permeability 9_ /Day (tested by jis 1099 η method), and the surface layer uses the roller on the roller ( Kmfe on Roll) coated with water-based resin and coated with a coating amount of 5 〇 to coffee. 6 Coating of 201014545 10 'Addition of melamine green bridge agent to the resin, = bubble:, Bu 1 ()% auxiliary and 0.1 ~ 1.5_t_〇 (H6 (rCx2 knife) t, dry G ' causes the Lai high inclination and the micro-nucleus to separate from the forest h and passes through the cut surface shape 1, wherein the cut mask I passes through 4, the mask! The cutting field cuts the eye hole 3G, 3G' and the cutting mouth hole 4〇, as shown in Fig. 5, the side view of the mask 亦 also shows the bottom layer 1〇 and the surface layer 2Q, and then After filling the mask essence, the finished product K is formed. In order to make the author of the redprint more clear, the creation of the present invention is described by the following examples and comparative examples: [Example 1] taken from the cloth (Single number 40D/72fx40D/72f, warp and weft density I67xl38) specification release cloth as the bottom layer of the coated fabric, with the following Bead coating formulation liquid; fabric is coated with 'package; final coating machine into # bottom layer, * coated phase resin means polyurethane, p〇lyurethane resin selected from the company's products Then) 'to the foaming ratio (1:5), the coating amount is 73 g / m2, drying ii 〇 ° Cx2 minutes, the amount of money 15G g / rrf with Weiren oven (10). Cxi minute curing A high-moisture and microporous mask is obtained, and then the mask is cut, the mask essence is filled, and the mask is finished. The foam coating solution used is as follows: PU resin (Bayer Impranil DLN) ιηΠα. 7 201014545 Bridging agent M3 (Taiwan Cytec) 2% Foaming agent VF (Jinyi Chemical) 5% Auxiliary RF (Jinyi Chemical) 8% Catalyst 4040 (Taiwan Cytec) 2% [Example 2] The specification cloth of the diametric release cloth (70Dx70D, 190x190) is used as the bottom layer of the coating processing cloth, and the undercoating is applied to the fabric by the foam coating machine with the following foam coating liquid. The coating resin refers to acryl oxime ester. Resin (AC, acrylic) (batch number: E series) is selected from Rohm and Haas Company, with foaming ratio (1:5), coating 75,
再以羅拉上刮刀(knife Qn rG⑴之塗佈加卫方法進行表層塗佈 之親水性塗佈加工,塗佈量15Q g/rrf隨後進入供箱進行. °Cx2分鐘固化’即得一高保濕度與多微孔的面膜,再進行裁切面 臈、填充面膜精華液及完成面膜成品。 其所使用泡沫塗佈調配液如下:Then use the roller on the roller (knife Qn rG (1) coating and curing method for the surface coating of the hydrophilic coating process, the coating amount of 15Q g / rrf then enter the box for. °Cx2 minutes of curing' to get a high moisture retention With the microporous mask, cut the mask, fill the mask essence and finish the mask. The foam coating solution used is as follows:
Ac樹脂(美商羅門哈斯公司E系列產品) j⑽g 二聚氰胺系架橋劑M3(台灣氰特公司) 4% 起泡劑VF(晉一化工) 5〇/〇 助劑RF(晉一化工) 8% 【實施例3】 觸媒4040(台灣氰特公司)2% 8 201014545 取自聚酯離型布(40D/72x40D/72,167x138)作為塗佈加工布 的底層,以下列之發泡塗佈液對織物以泡珠塗佈機的浮游到刀 (knife on air)進行底層的表層塗佈,而其中塗佈液中樹脂係指 乳膠(丁一稀型聚合物)(Latex Butadiene-base Polymers)樹脂,以發 泡比(1: 4. 5 )、塗佈量為70 g/rrf,以乾燥85°Cxl分鐘進行烘 乾’即得一高保濕度與多微孔的面膜,再進行裁切面膜、填充面 膜精華液及完成面膜成品。 其所使用泡洙塗佈調配液如下: 乳膠(丁二烯型聚合物)樹脂 100g 架橋劑 2.5% 助劑 8 % 觸媒 1.5% 【實施例4】 以聚酯離型布(40DX40D,167x138)作為塗佈加工布的底層,以 下列之發泡塗佈液對織物以泡沫塗佈機的羅拉上到刀(比丨^加 roll)進行底義表驗佈,而其巾塗佈液帽脂係指判康彈性 體(Silicone Elastomers)樹脂,以發泡比(1: 3· 5)、塗佈量為 90g/rri ’以乾燥1G(TCx2分鐘進機乾,即得—高保_與多微 孔的面膜,再進行裁切賴、碰精華液及完成面膜成品。 其所使用泡沐塗佈調配液如下: 9 201014545 矽利康彈性體樹脂 100g 架橋劑 5% 助劑 5% 觸媒 1.5% 上述實施例1,2, 3, 4所產生的實施的數據經由測試獲得表(一 ),即得知濕度數據愈高愈佳,可知實施例1係以聚酯離型布作為 泡沫加工所獲得的面膜優於實施例2係以耐隆離型布作為泡沫加 工所獲得的賴,即聚_型布作為基材的面_保濕度優於以 耐隆離型布作基材的面膜,又實施例3〜4係以聚g旨離型布為底層, 而所採的不同泡沫塗佈㈣主要樹脂亦不同,惟實施例3〜4所獲 得的透濕度亦不優於實施例1。另依據表㈡得知本發明面膜與市 售面膜的物性比較,得知除了生物纖維面臈係考量成本昂貴外, 本發明的發泡面膜在於物性表現上較不織布面膜優。 表(-)Ac resin (American Rohm and Haas company E series products) j (10) g melamine bridging agent M3 (Taiwan Cytec) 4% Foaming agent VF (Jinyi Chemical) 5 〇 / 〇 auxiliaries RF (Jinyi Chemical) 8% [Example 3] Catalyst 4040 (Taiwan Cytec) 2% 8 201014545 Taken from a polyester release cloth (40D/72x40D/72, 167x138) as the bottom layer of the coated fabric, with the following foam coating The cloth liquid is coated on the fabric by the bubble on air of the bead coater, and the resin in the coating liquid refers to Latex Butadiene-base Polymers. Resin, with a foaming ratio (1: 4. 5), a coating amount of 70 g/rrf, and drying at 85 ° C for 1 minute to obtain a high moisturizing and microporous mask, and then cutting Cut the mask, fill the mask essence and finish the mask. The foam coating formulation used is as follows: Latex (butadiene type polymer) resin 100 g Bridging agent 2.5% Auxiliary 8% Catalyst 1.5% [Example 4] Polyester release cloth (40DX40D, 167x138) As the bottom layer of the coated processing cloth, the following foaming coating liquid is used to apply the fabric of the foam coating machine to the knife (in comparison with the roll), and the towel coating liquid is used for the coating. Refers to the silicone elastomer (Silicone Elastomers) resin, with a foaming ratio (1: 3.5), a coating amount of 90g / rri ' to dry 1G (TCx2 minutes into the machine, that is, get high-protection _ and micro The mask of the hole is then cut, touched with the essence and finished with the mask. The foam coating solution used is as follows: 9 201014545 Silicone elastomer resin 100g bridging agent 5% auxiliary 5% catalyst 1.5% The data of the implementations produced in Examples 1, 2, 3, and 4 were obtained by the test (1), that is, the higher the humidity data, the better, the Example 1 was obtained by using a polyester release cloth as a foam processing. The mask is superior to the embodiment 2 in that the diaper-resistant cloth is used as the foam processing, that is, the poly-type cloth is used as the The surface of the material _ hydration is better than the mask with the diaper-resistant fabric as the substrate, and the examples 3 to 4 are based on the poly-g release fabric as the bottom layer, and the different foam coatings (4) are different. However, the moisture permeability obtained in Examples 3 to 4 is also not superior to that in Example 1. According to Table (2), the physical properties of the mask of the present invention and the commercially available mask are compared, and it is found that in addition to the high cost of the biofibrous facial mask system, The foaming mask of the present invention is superior in texture performance to the non-woven mask. Table (-)
10 201014545 耐隆離型布(底層) (70DX70D > 190x190) 【實施例2】 疋涵l〇〇g-- 三聚氟胺系架橋劑 5% 起泡劑 1% 整泡劑 8% 觸媒 1.5% ~~9000 ~ 聚酯離型布(底層) 乳膠(丁二烯型聚合物)樹脂l〇〇g 8500 (40D/72x40D/72,167x138) 三聚氰胺系架橋劑 5% 【實施例3】 助劑 8% 觸媒 1.5% 聚酯離型布(底層) 矽利康彈性體樹脂 100g ^8300 ' (40DX40D, 167x138) 三聚氟胺系架橋劑 5% 【實施例4】 助劑 8¾ 觸媒 1.5¾ ❹ 註 L布之規格:經紗支數X緯紗支數,經密X緯密。 U mpran i 1 DLN (Bayer公司商品名),E系列產品(羅門哈斯公 司商品名)。 > 、、 L實施例1〜4中底層10的表層20的气濕度係為塗佈後之測 試數據。(依據JIS1099 A-1法測試)。 11 20101454510 201014545 Nylon release fabric (bottom layer) (70DX70D > 190x190) [Example 2] 疋 〇〇 l〇〇g-- tripoly fluorocarbon bridging agent 5% foaming agent 1% foaming agent 8% catalyst 1.5% ~~9000 ~ Polyester release cloth (bottom layer) Latex (butadiene type polymer) resin l〇〇g 8500 (40D/72x40D/72, 167x138) melamine bridging agent 5% [Example 3] Additive 8% Catalyst 1.5% Polyester release cloth (bottom layer) Silicone elastomer resin 100g ^8300 ' (40DX40D, 167x138) Tripolyfluoroamide bridging agent 5% [Example 4] Additive 83⁄4 Catalyst 1.53⁄4 ❹ Note L cloth specifications: warp count X weft count, through dense X weft. U mpran i 1 DLN (trade name of Bayer), E series (trade name of Rohm and Haas company). >, L The gas moisture of the surface layer 20 of the primer layer 10 in Examples 1 to 4 is the test data after coating. (Tested according to JIS1099 A-1 method). 11 201014545
表(一)係為本發明實施例測試表。 表(二) 係為本發明面膜與市售面膜的物性比較表 圖1 係為本發明之加工流程圖。 圖2 係為本發明之結構分解圖。 圖3 係為本發明之實施例部份圖。 圖4 係為本發明之裁切面膜視意圖。 圖5 係為本發明之面膜結構圖。 【主要元件符號說明】 1 面膜 10 底層 20 表層 A 離型織物 B 水性樹脂(泡沫塗佈調配液) 12 201014545 c 機械方法起泡 D 泡沬體 E 塗佈加工 F 發泡塗佈層 F1 微孔薄膜層 G 烘乾 Η 高保濕度與多微孔的離型織物 ® I 裁切面膜形狀 J 填充面膜精華液 Κ 面膜成品Table (1) is a test table of an embodiment of the present invention. Table (2) is a comparison of the physical properties of the mask of the present invention and a commercially available facial mask. Fig. 1 is a processing flow chart of the present invention. Figure 2 is an exploded view of the structure of the present invention. Figure 3 is a partial view of an embodiment of the present invention. Figure 4 is an illustration of the cut mask of the present invention. Figure 5 is a structural view of the mask of the present invention. [Main component symbol description] 1 Mask 10 Bottom layer 20 Surface layer A Release fabric B Water-based resin (foam coating formulation) 12 201014545 c Mechanical method foaming D Bubble body E Coating process F Foam coating layer F1 Micro hole Film Layer G Drying Η High Moisture and Microporous Release Fabric® I Cut Mask Shape J Filled Mask Essence Κ Finished Mask
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