201000423201000423
I 九、發明說明： 【發明所屬之技術領域】 本發明係有關於玻璃的製造方法，且尤其有關於一種製 造可釋放遠紅外線及/或具有抗菌及抑菌功能的玻璃器里的 方法。 【先前技術】 太陽光包含人類可以用肉眼看到的光線及肉眼無法看見I. Description of the Invention: [Technical Field] The present invention relates to a method for producing glass, and more particularly to a method for producing a glassware capable of releasing far infrared rays and/or having antibacterial and bacteriostatic functions. [Prior Art] Sunlight contains light that humans can see with the naked eye and cannot be seen by the naked eye.
的紅外線及紫外線，紅外線的波長超越一般紅色光，它佔 太陽光線中的59%，其中紅外線又可分為四類，就是近紅外 線，中紅外線，遠紅外線，及超紅外線。若將近紅外線照 射在人體上，被照射的部位立刻會有灼熱的感覺；相反的 ，遠紅外線不但不會刺激人體，更可以使人體能量增加， 令身體内部溫暖起來，對人體產生治療功效，尤其以波長4 //m至14//Π1的光線對人類的健康很重要’而且已獲保健醫 學界的公認。 遠紅外線主要的功能是促進身體中血液賴環，預防酸 痛不適’ 4除疲勞，以及預防疾病，例如風濕性關節炎， 雜火’腰痛、手腳麻痺等，* —些無機物金屬尤其是奈 米化之後，更具有姉的抗該抑g效果W知自然界f 的礦石材料，如氧化鎂(_、二氧化鈦(τ、二氧化 =的^ ’如_杯子料f。而奈米銀(Ag)、奈求銅 ()列:：:⑽、奈米二氧化鈦(Ti〇2)、奈米氧化鋅 (ZnO)則疋具有極佳的抗歧抑菌效果。 201000423 =發明公告丽號揭示一種「抗菌性破璃 w方法」’其雜為在洗錢中t«數個抗菌性玻 w件’其於洗衣時會釋蚊量的銀離子，以反複地進行 杬菌處理，以防止衣服變色。 然而習知的抗«性玻璃的製造方法，補成本高，而且 製程複雜，困難度高，良率也低，實有改良的必要。 有，於此，本發明人乃藉由多年從事相關產業之經驗，The infrared and ultraviolet, infrared wavelengths exceed the general red light, which accounts for 59% of the sun's rays, and the infrared rays can be divided into four categories, namely, near-infrared rays, mid-infrared rays, far-infrared rays, and super-infrared rays. If near-infrared rays are irradiated on the human body, the irradiated parts will immediately have a burning sensation; on the contrary, far-infrared rays will not only stimulate the human body, but also increase the body's energy, warming the body and producing therapeutic effects on the human body, especially Light with a wavelength of 4 //m to 14//Π1 is important for human health' and has been recognized by the health care community. The main function of far-infrared rays is to promote blood circulation in the body, prevent soreness and discomfort. 4 Remove fatigue, and prevent diseases such as rheumatoid arthritis, miscellaneous fires, low back pain, hand and foot paralysis, etc. * Some inorganic metals, especially nano-chemical After that, it is more resistant to the effect of suppressing g. It is known that the ore material of nature f, such as magnesium oxide (_, titanium dioxide (τ, dioxide = ^ ' such as _ cup material f. and nano silver (Ag), Nai Copper () column::: (10), nano titanium dioxide (Ti〇2), nano zinc oxide (ZnO), 疋 has excellent anti-bacterial effect. 201000423 = invention announcement 丽 reveals an "antibacterial break" The glass w method "is a miscellaneous in the money laundering of a number of antibacterial glass w", which will release the amount of silver ions during the washing, to repeatedly carry out the sterilization treatment to prevent discoloration of the clothes. The invention is based on the method of manufacturing the glass, which has a high cost, a complicated process, a high degree of difficulty, and a low yield, which is necessary for improvement. Here, the inventor has experience in related industries for many years.
針對則述遇紅外線產品(及/或包含具關功能的玻璃製品） 的問題深人探討’本麵而不捨_神與精益求精的目的 ’積極不_加以研纽良’並經過長期的努力與試驗， 終於開發出本發明。 【發明内容】 本發明之一主要目的係提供一種玻璃器皿之製造方法， 包括以下步驟：將崎放遠紅外線及/或抗纽抑菌效果之 預叹金屬及/或其氧化物材料，依預設配比研磨成奈米粉末 ，將奈米粉末均自分散於水溶液中，而成為奈綠金屬及/ 或其氧化物水溶液；再將奈米級金屬及/或其氧化物水溶液 倒入玻璃材料巾’且餅使之齡料；再將混合有奈米 級金屬及/或其氧化物水溶液之玻璃材料倒入熔爐；以 1000 C〜1300 C尚溫加熱炫融，形成溶融狀態之玻璃漿； 持續地將玻稱注人模具’賴，及再將賴之半成品玻 璃器皿輸送至降溫室；及冷卻半成品玻璃器皿至室溫，以 形成能釋放遠紅外線及/或具有抗菌及抑菌功能之玻璃器皿 201000423 主要目的係提供一種玻璃器孤之製造方法 .將能釋放遠紅外線及/或抗菌及抑菌效果 本發明之另一 j 包括以下步驟： 之預設金屬及/或絲化崎料，依淑織_成奈米粉 末’將奈米粉末均勻分散於水溶液中，而成為奈米級金屬 及/或其氧化物水/谷液，另將玻璃材料以麵。c〜酬。c高 溫加熱，使其形·融狀態之玻雜，且持續地將玻璃聚 注入模具，脫模，及再將輸送帶傳輸之半成品玻璃器皿通 過-霧化室’關時將水溶液狀態之奈米級金屬及/或其氧 化物以霧化器將之霧化成為霧態，再以風扇將霧態之奈 ^級金屬及/或其氧化物吹向持續通過霧化室之半成品玻璃 器皿；及冷卻半成品玻璃器皿至室溫，以形成能釋放遠紅 外線及/或具有抗菌及抑菌功能之玻璃器皿。 根據本發明之設金屬及/或其氧化物材料包 括：銀(Ag)為：3.1〜1〇重量百分比，氧化辞(Zn〇)為：&】 〜10重量百分比，氧化鎮(Mg0)為：0 3〜5重量百分比， 氧化納(_)為：2〜10重量百分比，氧化钟⑽)為：〇 3 〜2重量百分比’氧化组(化2〇5)為：6〜四重量百分比，氧 化歛⑽2〇〇為：3〜11重量百分比，二氧化碎⑸⑻為：⑽ 〜78重量百分比，二氧化鈦⑽2)為：6〜18重量百分比， 二氧化結⑽)為：2〜1G重量百分比，二氧化錯(Ge〇2)為 :0.06〜0.6重量百分比’三氧化二鋁(Al2〇3)為：〇 8〜 ^ ·· 1.33〜2. 88重量百分 花崗石，及矽礦石之全部 重量百分比’三氧化二鐵(Fez〇3)為·· 比’竹炭（C)，麥飯石，蛇紋石，花 或其中一部分。 201000423 以下謹以具體實翻’且佐以圖式作詳細朗，俾使審 查委員能對於本發明之技術特徵，有更進一步之了解。 【實施方式】 百先請參考圖卜其繪示根據本發明的玻璃器皿製造方法 的第一實施例流程。 首先在步驟10，將能釋放遠紅外線及/或具有抗菌及抑菌 功能的金屬及/或其氧化物材料，包括：銀⑽，氧化辞 " (ZnQ) ’氧傾（_)，氧化#3(%2〇)，氧化卸⑽）’氧化 组（Ta2〇5) ’氧化歛（_5)，二氧化石夕（Si〇2)，二氧化欽 (ΤιΟ〇 ’二氧化鍅（红⑹’二氧化鍺（⑽2)，三氧化二鋁 丨 =1办），三氧化二鐵(Fe^)，竹炭（c)，麥飯石，蛇紋石， 化崗石，及石夕礦石等的全部或其中一部分，依預設的配比 研磨成奈米狀粉末，將其倒入水溶液並使其均句分散於水 溶液中，成為奈米級金屬及/或其氧化物水溶液。 接著在步驟20 ’將該奈米級金屬及/或其氧化物水溶液倒 入玻璃材料（其主要成分是矽酸鹽（即石英妙），再加上長石 i 粉，無水硼砂，碳酸鈉’氧化鋁，氧化鋅，碳酸鉀，亞砒 酸，及石灰等）中，且分散攪拌混合均勻。 接著在步驟30 ’將混合有玻璃材料的該液態奈米級金屬 及/或其氧化物溶液倒入熔爐。 接著在步驟40，以攝氏iootrcioot的高溫加熱，使 之形成熱熔融狀態的玻璃漿。 接著在步驟50，持續地將玻璃漿注入模具（如瓶狀模具) 成型，或以其它習知方式如熱空氣吹入法，而形成瓶狀體 201000423 Ί j ，脫模後以輸送帶傳輸。 j 接著在步驟60，將脫模的半成品玻璃瓶輸送至降溫室。 最後在步驟70，該等半成品的玻璃瓶經過冷卻至室溫後 ，如此即可製造出能釋放遠紅外線及/或具有抗菌及抑菌功 | 能的玻璃瓶(玻璃器皿）。 首先請茶考圖2，其繪示根據本發明的玻璃器皿製造方法 ； 的第二實施例流程。 丨， 首先在步驟1〇〇，將能釋放遠紅外線及/或具有抗菌及抑 函的金屬及/或其氧化物材料’包括：銀（Ag)，氧化鋅 (ZnO) ’氧化鎂(MgO) ’氡化納do)，氧化釺(κ2〇)，氧化 鈒（Ta2〇5)，氧化鈥（Nb2〇5) ’二氧化矽（Si〇2)，二氧化鈦 (Ti〇2)，一氧化錯（Zr〇2)，二氧化鍺（Ge〇2)，三氧化二|呂 (Al2〇3) ’三氧化二鐵（Fe2〇3)，竹炭（C)，麥飯石，蛇紋石， 花崗石，及石夕礦石等的全部或其中一部分，依預設的配比 研磨成奈米粉末狀，將其倒入水溶液並使其均勻分散於水 溶液中，成為奈米級金屬及/或其氧化物水溶液。 I 在此同時於步驟200，將玻璃材料（其主要成分是石夕酸鹽（ 即石英砂）’再力σ上長石粉’無水观砂，碳酸鈉，氧化銘， 氧化鋅，碳酸鉀，亞砒酸’及石灰等）以攝氏1000。(3〜 1300°C的高溫加熱’使之形成熱熔融狀態的玻璃漿；且持 續地將玻璃衆注入模具（如瓶狀模具），或以其它習知方式 如熱空氣吹入法，而形成瓶狀體，脫模後以輸送帶傳輸。 接著在步驟300，將半成品的玻璃瓶經輸送帶進入及通過 一霧化室’而同時將水溶液狀態之奈米級金屬及/或其氧化 201000423 (玻璃器皿0 ::==:== 最後在步驟働，辦核品的玻麵經過冷卻至 ，如此即可製造出能觀粒外線及/或具有抗_及抑^ 能之玻璃瓶（玻璃器皿）。 較佳地，在本發明的玻璃器皿製造方法的任一實施 ’該金屬及/或其氧化物材料包括：銀(知)為：3_ 重In response to the question of infrared products (and/or glass products containing related functions), we are deeply involved in the discussion of 'the whole face of _ God and the purpose of excellence' are not actively researching New Zealand' and after long-term efforts and Experiments have finally developed the present invention. SUMMARY OF THE INVENTION One main object of the present invention is to provide a method for manufacturing a glassware, comprising the steps of: pre-swinging a metal and/or an oxide material thereof with a far infrared ray and/or an antibacterial effect The nano-powder is ground into a nano-powder, and the nano-powder is self-dispersed in an aqueous solution to form a green metal and/or an aqueous oxide solution thereof; and the nano-sized metal and/or its aqueous solution of the oxide is poured into the glass material. a towel and the cake is aged; then the glass material mixed with the nano-grade metal and/or its aqueous solution of the oxide is poured into the furnace; and heated at 1000 C to 1300 C to form a molten glass slurry; Continuously transfer the glass mold to the mold, and then transport the semi-finished glassware to the greenhouse; and cool the semi-finished glassware to room temperature to form a glass that can release far-infrared rays and/or have antibacterial and antibacterial functions. The main purpose of the vessel 201000423 is to provide a method for manufacturing a glass orphan. It is capable of releasing far infrared rays and/or antibacterial and bacteriostatic effects. Another j of the present invention comprises the following steps: a preset metal and/or Or silky glutinous material, according to the woven _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ c ~ reward. c high temperature heating, making it shape and melting state, and continuously injecting glass into the mold, demoulding, and then transporting the semi-finished glassware conveyed by the conveyor belt through the -spray chamber to turn off the state of the aqueous solution The metal and/or its oxide is atomized into a fog state by an atomizer, and then the fan is used to blow the misty metal and/or its oxide to the semi-finished glassware which continuously passes through the atomization chamber; The semi-finished glassware is cooled to room temperature to form a glassware capable of releasing far infrared rays and/or having antibacterial and bacteriostatic functions. The metal and/or its oxide material according to the present invention comprises: silver (Ag): 3.1 to 1 〇 by weight, oxidation (Zn〇) is: & 〜 10% by weight, oxidized town (Mg0) is : 0 3 to 5 weight percent, sodium oxide (_): 2 to 10 weight percent, oxidation clock (10)): 〇 3 〜 2 weight percent 'oxidation group (chemical 2 〇 5): 6 to 4 weight percent, Oxidation (10) 2 〇〇 is: 3 to 11% by weight, dioxide ash (5) (8) is: (10) ~ 78% by weight, titanium dioxide (10) 2) is: 6 to 18% by weight, dioxide (10) is: 2 to 1G by weight, two Oxidation error (Ge〇2) is: 0.06~0.6 weight percent 'Al2O3>: 〇8~ ^ ·· 1.33~2. 88% by weight of granite, and the total weight of bismuth ore The percentage 'ferric oxide (Fez〇3) is · than the 'bamboo charcoal (C), medical stone, serpentine, flower or part of it. 201000423 The following is a detailed description of the actual implementation of the present invention, so that the review committee can have a further understanding of the technical features of the present invention. [Embodiment] Referring to the drawings, a flow chart showing a first embodiment of a method for manufacturing a glassware according to the present invention will be described. First, in step 10, the metal and/or its oxide material capable of releasing far infrared rays and/or having antibacterial and bacteriostatic functions, including: silver (10), oxidation word " (ZnQ) 'oxygen (_), oxidation # 3 (%2〇), oxidative unloading (10)) 'oxidation group (Ta2〇5) 'oxidation convergence (_5), dioxide dioxide (Si〇2), dioxin (ΤιΟ〇' dioxide (red (6)' Cerium oxide ((10)2), aluminum oxide lanthanum = 1), iron oxide (Fe), bamboo charcoal (c), medical stone, serpentine, granitic stone, and Shixia ore, etc. A part of the mixture is ground to a nanometer-like powder according to a predetermined ratio, and poured into an aqueous solution to be uniformly dispersed in an aqueous solution to form a nano-sized metal and/or an aqueous solution of the same. Next, in step 20' The nano-grade metal and / or its oxide aqueous solution is poured into the glass material (the main component is bismuth citrate (ie quartz), plus feldspar i powder, anhydrous borax, sodium carbonate 'alumina, zinc oxide, potassium carbonate , arsenic acid, and lime, etc., and dispersed and mixed uniformly. Then in step 30 'mixed glass The liquid nano-grade metal and/or its oxide solution is poured into the furnace. Then, in step 40, it is heated at a high temperature of iootrcioot to form a glass slurry in a hot molten state. Next, in step 50, the glass is continuously dried. The slurry is injected into a mold (such as a bottle mold), or formed into a bottle body 201000423 Ί j by other conventional means such as hot air blowing, and is transferred by a conveyor belt after demolding. j Next, at step 60, the mold is released. The semi-finished glass bottles are transported to the greenhouse. Finally, in step 70, the semi-finished glass bottles are cooled to room temperature, so that glass bottles capable of releasing far-infrared rays and/or having antibacterial and antibacterial properties can be produced. (Glassware) First, please refer to Figure 2, which illustrates the flow of the second embodiment of the method for manufacturing a glassware according to the present invention. 丨, first in step 1, it will release far infrared rays and/or have antibacterial And suppression of metals and / or their oxide materials 'including: silver (Ag), zinc oxide (ZnO) 'magnesium oxide (MgO) '氡化纳 do), yttrium oxide (κ2〇), yttrium oxide (Ta2〇 5), yttrium oxide (Nb2〇5) Cerium dioxide (Si〇2), titanium dioxide (Ti〇2), oxidized (Zr〇2), cerium (Ge〇2), bis(Al2〇3), ferric oxide Fe2〇3), all or part of bamboo charcoal (C), medical stone, serpentine, granite, and Shixia ore, ground to a nanometer powder according to the preset ratio, and poured into an aqueous solution It is uniformly dispersed in an aqueous solution to become a nano-sized metal and/or an aqueous solution of the oxide thereof. I at the same time in step 200, the glass material (the main component is the stone salt (ie quartz sand) 're- σ feldspar powder' anhydrous view sand, sodium carbonate, oxidation Ming, zinc oxide, potassium carbonate, Asia Tannins and limes are at 1000 Celsius. (heating at a high temperature of 3 to 1300 ° C to form a glass paste in a hot molten state; and continuously injecting the glass into a mold (such as a bottle mold) or forming it by other conventional means such as hot air blowing The bottle-shaped body is transferred by a conveyor belt after demolding. Next, in step 300, the semi-finished glass bottle is passed through a conveyor belt into and through a spray chamber' while simultaneously neutralizing the nano-grade metal in an aqueous state and/or its oxidation 201000423 ( Glassware 0 ::==:== Finally, in the step 働, the glass surface of the nuclear product is cooled to, so that a glass bottle (glassware) capable of viewing the granules and/or having anti- and anti-function can be produced. Preferably, in the implementation of the glassware manufacturing method of the present invention, the metal and/or its oxide material comprises: silver (known): 3_ heavy
量百分比(wt%)，氧化鋅⑽)為：3·卜1()重量百分比，氣 化鎖(_為：〇.3〜5重量百分比，氧化鋼(％2〇)為：2〜 1〇重量百分比，氧化鉀_為：〇· 3〜2重量百分比，氧化 组(Ta2〇5)為：6〜22重量百分比，氧化歛(_5)為：3〜u 重量百分比，二氧化矽(Si〇2)為：6〇〜78重量百分比，二 氧化鈦(Τι〇2)為：6〜18重量百分比，二氧化錯伽〇為：2 〜1〇重量百分比’二氧化錯(⑽)為：〇. 06〜〇. 6重量百分 比，三氧化二鋁（A^〇3)為：〜6重量百分比，三氧化二 鐵(㈣3)為：1.33〜2. 88重量百分比，竹炭(c)，麥飯石’ 蛇紋石，花g石’及矽礦石之全部或其中_部分。 上述瓶子只是範例，本發明的方法當然也可以應用製造 出其它器皿，如玻璃水壺、玻璃水杯、破璃茶葉罐、玻璃 茶壺，、玻璃茶海、玻璃茶杯、玻璃酒器、破璃調酒棒、玻 璃酒瓶、玻璃藥酒瓶、玻璃酒壺、玻璃酒盅、玻 酒杯、紅酒杯、高脚杯、烈酒杯、啤酒杯）、破璃缴忠、玻 璃鍋、玻璃甕、玻璃盆、玻璃盤、玻璃湯碗、玻璃碗、玻 10 201000423The percentage of percentage (wt%), zinc oxide (10)) is: 3 · b 1 (% by weight), gasification lock (_ is: 〇. 3~5 weight percent, oxidized steel (%2〇) is: 2~1〇 Percent by weight, potassium oxide _ is: 〇 · 3 to 2 weight percent, oxidation group (Ta2 〇 5) is: 6 to 22 weight percent, oxidation concentrating (_5) is: 3~u weight percentage, cerium oxide (Si 〇 2) is: 6〇~78% by weight, titanium dioxide (Τι〇2) is: 6~18% by weight, and dioxins are: 2~1〇% by weight 'dioxide error ((10)) is: 〇. 06 ~ 〇. 6 weight percent, aluminum oxide (A ^ 〇 3) is: ~ 6 weight percent, ferric oxide (4) 3: 1.33 ~ 2. 88 weight percent, bamboo charcoal (c), medical stone 'snake Stone, flower g stone 'and all or part of 矽 ore. The above bottle is only an example, the method of the invention can of course also be applied to manufacture other utensils, such as glass water bottle, glass water glass, broken tea tea can, glass teapot, Glass tea sea, glass cup, glass wine, broken glass bar, glass bottle, glass bottle, glass jug, glass cellar Wine glass, red glasses, goblets, spirits, beer cups), loyalty payment broken glass, glass pot, jar glass, glass bowl, glass plate, glass soup bowls, glass bowl, glass 10201000423
II
I ；j i 璃湯匙、玻璃碟、玻璃調味瓶、玻璃微波調理盤、玻璃解I ;j i glass spoon, glass dish, glass cruet, glass microwave conditioning plate, glass solution
I I 凍盤、玻璃乾料（儲物）罐、嬰兒玻璃奶瓶、玻璃藥瓶、玻 ：| 璃花器、玻璃花盆、玻璃魚缸、玻璃珠、玻璃香於濾嘴、 玻璃香菸罐、玻璃板、玻璃桌面、玻璃燈罩、玻璃燈泡、 1 及玻璃眼鏡片等各種不同的玻璃製品。 2 上述實施例僅為說明本發明之原理及功效，並非用以限 制本發明之主要技術特徵及範圍。因此習於此技術之人士 , 對上述實施例進行修改及變化仍不脫離本發明之精神。本 發明已具備產業上利用性、新穎性及進步性，並符合發明 專利要件，爰依法提起申請。 ! 【圖式簡單說明】 圖1是本發明製造玻璃器皿方法的第一實施例的流程圖； 及 圖2是本發明製造玻璃器皿方法的第二實施例的流程圖。 【主要元件符號說明】II Frozen plate, glass dry material (storage) can, baby glass bottle, glass bottle, glass: | glass flower, glass flower pot, glass fish tank, glass beads, glass incense in filter, glass cigarette can, glass plate, Various glass products such as glass table tops, glass lampshades, glass bulbs, 1 and glass glasses. 2 The above embodiments are merely illustrative of the principles and effects of the present invention and are not intended to limit the main technical features and scope of the present invention. Therefore, those skilled in the art can make modifications and changes to the above embodiments without departing from the spirit of the invention. The invention has the industrial applicability, novelty and progress, and conforms to the invention patent requirements, and files an application according to law. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a flow chart showing a first embodiment of the method for producing a glassware of the present invention; and Fig. 2 is a flow chart showing a second embodiment of the method for producing a glassware according to the present invention. [Main component symbol description]
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