TW201000409A - Method of flocculating sedimentation treatment - Google Patents
Method of flocculating sedimentation treatment Download PDFInfo
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- TW201000409A TW201000409A TW98103435A TW98103435A TW201000409A TW 201000409 A TW201000409 A TW 201000409A TW 98103435 A TW98103435 A TW 98103435A TW 98103435 A TW98103435 A TW 98103435A TW 201000409 A TW201000409 A TW 201000409A
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201000409 六、發明說明: 【發明所屬之技術領域】 本發明係關於一種被處理水之凝集沈澱處理方法,該 方法係向河水、雨水、工廠之用排水等之 " 鉦嬙娃隹破處理水中注入 …俄錢集劑,且經過用以將被處理水中人 Μ早隹秘儿 ^ 3之微細懸浮 子集塊化而形成微絮凝體(fine flocs)之微絮凝體化步 驟、及藉由與既存絮凝體之接觸而將該微絮凝體絮凝體化 之絮凝體化步驟之後,於沈澱池中將絮凝體化步驟中所形 成之絮凝體加以沈澱分離’藉此獲得沈澱水。 【先前技術】 破處理水之凝集沈澱處理,係被使用作為沙過濾之前 處理,於該凝集沈殿方4,係將無機凝集劑注入被處理水 甲,而將被處理水中所包含之微細懸浮粒子集塊化為直徑 達到可沈澱分離之程度的絮凝體(floc),並藉由重力作用對 該絮凝體進行沈澱分離。 凝集沈澱裝置大致分為傳統(conventional)方式與高 速凝集/尤澱池方式,而後者又進一步被分為泥漿循環方式 及污龙浮I (sludge bianket)方式。然而,任—方式中所 不變的疋均係經過懸浮粒子之微絮凝體化步驟與微絮凝體 之絮凝體化步驟後再進行沈澱分離。 且對於么今為止之凝集沈殿處理方法而言,主要 技術性課題在於,《索用以形成直徑更大之絮凝體所需之 凝集劑及凝集助劑之種類及量。 201000409 係基於藉由斯莫盧霍夫斯 示之下述通式。 現行之凝集沈澱處理方法, 基(Smoluchowski)方程式所表 【數學式1】 DN / dt = αβ ni · η . 凝體之個數 時之附著率, 其 Ν單位體積中之微細懸浮粒子及微絮 α .娅撞效率(係表示2個粒子發生碰撞 受到無機凝集劑之影響) 召:2個粒子之碰撞頻率 〜’單位艘積中所流入之粒子數 係表示每單位時 ’被稱作絮凝體 nj·單位體積中之既存粒子數 再者’藉由上述通式所表現之dN/dt, 間之微細懸浮粒子及微絮凝體之減少速度 形成速度) 在基於上述斯莫盧霍夫斯基方程式之凝集理論中,你' 如非專利文獻1所示,以傳統製程作為對象說明了如下惰 況:將集塊化之過程分為2個部分,被處理水中所包含之 微細懸浮粒子之電荷中和與該懸浮粒子集塊化為直徑約3 ( …冑絮凝體之微絮凝體化步驟係依賴於布朗運動 (Br〇Wnianm〇ti〇n),另一方面,直經在3〇”以上之微 絮凝體集塊化為直徑達到可沈澱分離之程度之絮凝體為止 的絮凝體化步驟之成功與否,係受到是否以規定以上之 拌力進行攪拌之影響。 報告,由於若進行高 而可知絮凝體破壞係 而另一方面,如非專利文獻2之 速搜拌,則會導致絮凝體被破壞,從 4 201000409 受到因剪力 成步驟中, 之影響,從而於絮凝體形 之低速攪拌。 而使絮凝體表面劣化 士采用了攪拌強度較弱 门速凝集沈澱池係由美國所開發, 迷’受到非專利女龢9 _ 如上所 „ 文獻之衫響,於微絮凝體化步驟俜採用 弱攪拌強度之水流攪拌。 乂騍係採用 程气中=如非專利文獻3所示,斯莫盧霍夫斯基方 式中心上述碰撞頻率Θ之上升,㈣拌強度之上升有 氣於集塊化’例如以污泥浮層型高速凝集沈澱池作為對 ,’而:试提高高速搜拌強度。然而,該報告之結論與以 』之口相同’即’於微絮凝體化步驟長時間持續較強之 :拌之情況下,亦即增大高速攪拌強度之gr值及高速攪拌 時間之tr值時’母絮凝體會遭到破壞從而導致沈殿水濁度 上升’因& ’幾乎不會採用上述之高速㈣方式。201000409 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a method for agglomerating and precipitating treatment of treated water, which is used in rivers, rainwater, and drainage of factories, etc. Injecting the Russian money collector, and passing through a microflocculation step for forming a fine flocs by agglomerating the fine suspension of the human beings in the treated water, and by After the flocculation step of flocculation of the microflocs by the contact of the existing flocs, the flocs formed in the flocculation step are precipitated and separated in the sedimentation tank, thereby obtaining precipitated water. [Prior Art] The agglomeration and sedimentation treatment of the treated water is used as a pretreatment for sand filtration, and in the agglomerated Shen Dianfang 4, an inorganic aggregating agent is injected into the treated water, and the fine suspended particles contained in the treated water are used. The flocculation is a floc having a diameter that reaches a degree of precipitable separation, and the floc is subjected to precipitation separation by gravity. The agglutination and sedimentation device is roughly divided into a conventional method and a high-speed agglutination/esthetic pool method, and the latter is further divided into a mud circulation method and a sludge bianket method. However, the intrinsic enthalpy in any mode is subjected to precipitation separation after the microflocculation step of the suspended particles and the flocculation step of the microflocs. For the agglomeration treatment method of the present day, the main technical issue is "the type and amount of aggregating agent and agglutination aid required for forming a larger diameter floc. 201000409 is based on the following general formula shown by Smolufoffs. Current agglomeration and sedimentation treatment method, based on the equation of Smoluchowski [Math 1] DN / dt = αβ ni · η . Adhesion rate at the number of gels, fine suspended particles and fine flocs per unit volume α. The efficiency of collision (representing the collision of two particles by the inorganic aggregating agent) Call: the collision frequency of two particles ~ 'the number of particles flowing in the unit of the ship indicates that each unit is called a floc Nj·the number of existing particles in the unit volume, and the speed of formation of the micro-suspended particles and microflocs by the dN/dt expressed by the above formula, based on the above-mentioned Smoluchovsky equation In the agglutination theory, as you can see, as shown in Non-Patent Document 1, the inertia of the conventional process is described as follows: The process of the agglomeration is divided into two parts, and the charge of the fine suspended particles contained in the treated water is And the agglomeration of the suspended particles into a diameter of about 3 (the microflocculation step of the floc is dependent on the Brownian motion (Br〇Wnianm〇ti〇n), on the other hand, the straight through is above 3〇” Microfloc The success of the flocculation step of the flocculation to the extent that the diameter is such that the diameter can be precipitated and separated is affected by whether or not the stirring is performed at a predetermined mixing force. Reporting, if the flocculation is high, the flocculation is broken. On the other hand, if the speed of the non-patent document 2 is mixed, the floc is destroyed, and it is affected by the shearing force step from 4 201000409, thereby causing the flocculation to be stirred at a low speed. The surface deterioration is weaker. The door speed agglutination sedimentation tank is developed by the United States. The fans are affected by the non-patented women and 9 _ as described in the literature. In the microflocculation step, the water with weak agitation intensity is used. Stirring. The enthalpy is used in the process gas. As shown in Non-Patent Document 3, the above-mentioned collision frequency Θ rises in the Smoluchovsky method center, and (4) the increase in the mixing strength is in the liquefaction of the sludge. Type high-speed agglutination sedimentation tank as a pair, 'and: try to improve the high-speed search intensity. However, the conclusion of this report is the same as the mouth of the mouth, that is, the micro-flocculation step is long. Continued stronger: in the case of mixing, that is, increasing the gr value of the high-speed stirring intensity and the tr value of the high-speed stirring time, the 'mother floc will be destroyed, causing the turbidity of the swell water to rise' due to & 'nearly Adopt the above high speed (four) method.
义廷樣’針對迄今為止之提高過濾水質之要求,係於位 於前段之凝集沈澱處理中,以促進懸浮粒子之集塊化及抑 制絮凝體破壞作為前提,而採用了非常依賴於無機凝集劑 注入率之提高的運轉法。尤其是在不具備高速攪拌之高速 凝集沈澱池之運轉過程中,最早係使無機凝集劑注入率提 向至沒有存在改善餘地之程度。 然而,對於非常依賴於無機凝集劑注入率之提高之運 轉法而言,雖然在沈澱處理中可獲得大致滿意之結果,但 在沈澱處理後續之過濾處理及污泥處理之階段,則會引起 其他技術方面之問題。 即’由於提高無機凝集劑注入率而導致絮凝體之容積 201000409 過/慮池中之微絮凝體之粗粒、低密卢化 及沈澱水中之凝聚隹地& -在度化 集塊物殘留量會上升’其結果, 必需提高過遽池之洗淨頻帛之問題。 並且一對於/可泥處理而言,同樣會因無機凝集劑之增 力導致/可泥本身發生量亦隨之增加,且污泥之濃縮、脫 水性降低,故難以進行污泥處理。 此類上述先前技術中之問題,其根本原因係在於所採 用的運轉法,該運轉法儘管將凝集m慮及污泥處 理作為-個系統加以運用,但幾乎未考慮到㈣及污泥處 理的最佳化’而僅僅重視形成直徑較大之絮凝體以達成沈 澱處理之最佳化,具體而言,由於擔心沈殿水濁度會隨著 絮疑體破壞而上升,選擇了非常不具效率之低攪拌強度之 集境化處理方法’而未考慮到要實現之後的優質過滤處理。 考慮到上述狀況,於專利文獻丨中提出了如下内容: «X置複數段之兩速攪拌槽,且於最初之第1槽,設定攪拌 強度之下限值,於第2槽以下之各槽,設定攪拌強度之上 限值,然後針對各高速攪拌槽分別注入無機凝集劑,藉此, 實現粒子分離效率之提高、所殘留之無機凝集劑濃度之降 低化之提升(參照申請專利範圍之請求項6及說明書關於 請求項6之記載事項)。 然而,在專利文獻1所提供之上述構成之情況,關於 將第2槽以下之攪拌強度設定為必要值以上之方面,上述 效果並不充分,並且,並未對整體之無機凝集劑之注入程 度進行調整’且並未設定與該調整相關之基準,從而不免 201000409 會被評價為可達成上述目的之程度非常不足 於專利文獻2中,說明藉由設置中=雜 分離細粒、高密微絮凝體,然而::觸材料層而可 而造成接觸材料層閉塞,因此 c f微絮凝體之扣留 於以連續處理作為前提之沈殿處理。们月洗,故並不適用 即’因上述細粒、高密微絮凝體 具有所殘留之無機凝集劑漢度降低化之可成雖然-方面’ 無法適用於連續處理之基本技術上的要求’因此:::: 士夕士?隹、-U .art上 因此*作為被處 理水之凝集沈澱處理方法, 於非專利文獻”,:載具有致命缺陷。 °己載有如下内容:絮凝體容易從 強产之、疑隼虛採用藉由低無機凝集劑注入率與高擾拌 =:rr法,來代替先前之低搜拌強度而提高無機 凝集劑注入率之凝集處理法。然而,儘管該凝集處理法所 形成之絮凝體會細粒、高密化,微絮凝體會大量地殘留於 沈澱水中’但用以將該微絮凝體分離之具體構成則完全不 清楚,因此不免會被評價為在技術上並未完成。 與針對以上個別之公知技術文獻之評價不同,關於被 處理水之凝集沈殿處理,雖然在絮凝體化之最後階段或該 最後階段及中途階段,設置絮凝體形成用傾斜板,從而有 助於微絮凝體之絮凝體化形成,但對於該傾斜板之絮凝體 化功能,始終被認為係辅助幫助,目前至今為止尚未有提 示或暗示將絮凝體形成用傾斜板本來所具有之絮凝體化功 能加以積極活用之技術性思想。 目前’非專利文獻4雖然有涉及關於傾斜板之說明, 201000409 但對於上述技術性思想,則未作任何揭示或暗示。 [專利文獻1]曰本特開2007-203 133 [專利文獻2]曰本特開平6-30441 1 [非專利文獻1]丹保憲仁:水處理之凝集機構之基礎研 究(1 )〜(4) ’水道協會雜誌,第361號、363號、365 號、367 號,(1964.10、1964.12、1965.2、1965.4) [非專利文獻 2]Committee Report : Capacity and Loadings of Suspended Solids Contact Units,J.AWWA,Apri 1,195 1.Yiting-like's requirement for improving the filtration of water quality to date is based on the agglomeration and sedimentation treatment in the front stage, which promotes the agglomeration of suspended particles and inhibits flocculation damage, and is highly dependent on inorganic agglutinating agent injection. The operating method of increasing the rate. In particular, in the operation of a high-speed agglomeration sedimentation tank which does not have high-speed agitation, the inorganic aggregating agent injection rate is first raised to the extent that there is no room for improvement. However, for an operation method which is highly dependent on the improvement of the injection rate of the inorganic aggregating agent, although a substantially satisfactory result can be obtained in the precipitation treatment, it may cause other stages in the subsequent filtration treatment and sludge treatment of the precipitation treatment. Technical aspects. That is, due to the increase of the inorganic aggregating agent injection rate, the volume of the floc is 201000409. The coarse particles of the microflocs in the pool, the low-densification and the agglomeration of the precipitated water are in the range of < The amount will rise. As a result, it is necessary to raise the problem of cleaning the frequency of the pool. Further, as for the sludge treatment, the amount of the sludge itself is also increased due to the increase of the inorganic aggregating agent, and the concentration and dehydration of the sludge are lowered, so that sludge treatment is difficult. The root cause of such problems in the prior art mentioned above is the operating method employed, which does not consider (iv) and sludge treatment, although the agglutination m is considered as a system for sludge treatment. Optimized' only pays attention to the formation of larger diameter flocs to achieve the optimization of precipitation treatment. Specifically, because of the fear that the turbidity of the Shendian water will rise with the destruction of the suspected body, the selection is very inefficient. The agglomeration treatment method of the agitation intensity does not take into consideration the high-quality filtration treatment after the realization. In view of the above situation, the following is proposed in the patent document: «X-stacked two-speed agitation tank, and in the first tank, the lower limit of the stirring strength is set, and the tank below the second tank The upper limit of the stirring strength is set, and then the inorganic aggregating agent is injected into each of the high-speed stirring tanks, thereby improving the particle separation efficiency and increasing the concentration of the remaining inorganic aggregating agent (refer to the patent application) Item 6 and the description of the item of claim 6). However, in the case of the above-described configuration provided in Patent Document 1, the effect of setting the stirring strength of the second groove or less to a required value or more is not sufficient, and the degree of injection of the entire inorganic aggregating agent is not obtained. The adjustment is made 'and the benchmarks related to the adjustment are not set, so that 201000409 will be evaluated as achieving the above purpose, which is very insufficient in Patent Document 2, indicating that the fine particles and high-density microflocs are separated by setting However, it is possible to cause the contact material layer to be occluded by touching the material layer, so that the cf microfloc is detained in the shoal treatment which is premised on continuous processing. Because it is not suitable for the month, it is not possible that the above-mentioned fine-grained, high-density microflocs have a residual inorganic gelling agent, which can be reduced to the basic technical requirements of continuous processing. :::: Shishi Shi?, -U.art is therefore * as a method of agglomeration and sedimentation treatment of treated water, in the non-patent literature,: contains a fatal defect. ° has contained the following content: floc easily from The strong production and doubtful use of the agglomeration treatment method of increasing the injection rate of the inorganic aggregating agent by the low inorganic agglutinating agent injection rate and the high scrambling == rr method. However, despite the agglutination The floc formed by the treatment method will be fine-grained and densified, and the micro-flocs will remain in the precipitated water in a large amount'. However, the specific composition for separating the micro-flocs is completely unclear, so it is inevitably evaluated as technically Unfinished. Unlike the evaluation of the above-mentioned individual known technical literature, the treatment of the agglomerated water of the treated water, although in the final stage of the flocculation or the final stage and the middle stage The sloping plate for floc formation is provided to contribute to the flocculation formation of the microfloc, but the flocculation function of the slanted plate is always considered to be an auxiliary help, and so far there has been no suggestion or suggestion of the floc. The technical idea of actively utilizing the flocculation function originally possessed by the inclined plate is formed. At present, the non-patent document 4 relates to the description of the inclined plate, 201000409, but the above technical idea is not disclosed or implied. [Patent Document 1] 曰本特开2007-203 133 [Patent Document 2] 曰本特开平 6-30441 1 [Non-Patent Document 1] Dan Baoxianren: Basic research on agglutination mechanism of water treatment (1)~(4 'Waterway Association Journal, Nos. 361, 363, 365, 367, (1964.10, 1964.12, 196.2.2, 1965.4) [Non-Patent Document 2] Committee Report: Capacity and Loadings of Suspended Solids Contact Units, J.AWWA, Apri 1,195 1.
[非專利文獻3]角田省吾、片岡克之:關於泥漿浮層型 高速凝集沈澱裝置之研究(2) —對泥漿浮層帶來之凝集攪 拌條件之影響一工業用水’第133號,pp 39〜47,昭44 1〇 [非專利文獻4]水道設施設計指南,日本水道協會,平 成12年發行 【發明内容】 鑒於上述先前技術之狀況,本發明之課題在於提供一 種被處理水之凝集沈殿處理方法’為了實現包含後續之過 渡處理及污泥處理之淨水處理系統整體的最佳化,作為凝 集沈澱處理方法,係藉由積極活用絮凝體形成用傾斜板本 來所具有之絮凝體化功能,來促進絮凝體化,且為了發揮 此種絮凝體形成用傾斜板之功能,比起先前技術之情況更 限定了無機凝集劑之使用量’從而實現殘留之微絮凝體及 絮凝體之高密度化及微小化,藉此獲得優質澄清水,且可 減少污泥之發生量。 8 201000409 係-種被:決上述問題,本發明之請求項1之基本構成, 注入步驟,^ 具有:無機凝集劑 驟,包括传:!::凝集劑注入被處理水中;絮凝體化步 述被處理h 槽中對注人有上述無機凝集劑之上 浮粒子預:合攪拌’而將上述被處理水中之微細懸 ' 微絮凝體化的微絮凝體化步驟,以及於沈殿池 中藉由與既存絮凝體之接觸,而將上述微絮凝體進—步絮 凝體化的步驟;及沈澱分離步驟’係於沈澱池中將上述絮 凝體加以沈澱分離’其中,於絮凝體化步驟之最後階段:、 設置間距寬度在5mm w I· 又在5職以上、50inm以下之絮凝體形成用傾 斜,’ ^對、經過微絮凝體化步驟之階段的無機凝集劑之使 用量加以限定,以使被處理水通過該傾斜板後之濁度為通 過前之濁度的4/5以下。 【實施方式】 首先,對關於上述基本構成之基本原理進行說明。 本發明中,係著眼於絮凝體形成用傾斜板8之絮凝體 形成功能,且為了實現此種功能而放置砝碼(说以卟◦,該 傾斜板8之絮凝體形成功能如圖5所示,於被處理水1浸 入絮凝體形成用傾斜板8之下側端部之階段時,產生济流, 由於該渦流’而於較絮凝體形成用傾斜板8内部之下側端 部更靠上側區域’形成有亂流。 藉由此種渦流(進而亂流),使沈澱池21中尚未沈澱之 微絮凝體及懸浮粒子相互碰撞之機率或頻率增大,從而促 9 201000409 進絮凝體化。 本發明中, 本發明中,將絮凝體形成用傾斜板 5 0mm之範圍。 8之間距限定為5mm 對上述限定之根據進行說明,當 ’當該間距非常小而未滿[Non-Patent Document 3] Kakuda Shogo, Kataoka Ke: Study on Mud Floating Layer Type High-speed Agglutination and Sedimentation Device (2) - Effect on Aggregation and Stirring Conditions Brought by Mud Floating Layer - Industrial Water 'No. 133, pp 39~ 47, 昭 44 1〇 [Non-Patent Document 4] Waterway Facilities Design Guide, Japan Waterway Association, issued in 2004. [Invention] In view of the above prior art, the object of the present invention is to provide a process for agglomeration of treated water. In order to realize the optimization of the entire water purification system including the subsequent transition treatment and the sludge treatment, the method of agglomerating and sedimentation is to actively utilize the flocculation function originally possessed by the inclined plate for floc formation. In order to promote the flocculation, and to exert the function of the inclined plate for forming a floc, the amount of the inorganic aggregating agent is limited as compared with the prior art, thereby realizing the high density of the remaining microflocs and flocs. And miniaturization, thereby obtaining high quality clarified water and reducing the amount of sludge generated. 8 201000409 The following problems are solved: the basic constitution of the claim 1 of the present invention, the injecting step, and the method: the inorganic aggregating agent, including: :: a coagulant is injected into the treated water; the flocculation step is treated in the h-slot, and the above-mentioned inorganic aggregating agent is pre-floated with the above-mentioned inorganic aggregating agent, and the fine suspension of the treated water is microflocculated. a microflocculation step, and a step of further flocculation of the microflocs by contact with an existing floc in a pond, and a step of depositing the floc in the sedimentation tank Precipitation separation', in the final stage of the flocculation step: setting the pitch width to 5mm w I· and the slope of the floc formation for the 5th or more and 50inm or less, '^, after the microflocculation step The amount of the inorganic aggregating agent used is limited such that the turbidity of the water to be treated after passing through the inclined plate is 4/5 or less of the turbidity before passing. [Embodiment] First, the basic principle of the above basic configuration will be described. In the present invention, attention is paid to the flocculation forming function of the inclined plate 8 for floc formation, and a weight is placed in order to realize such a function (say, the floc formation function of the inclined plate 8 is as shown in FIG. When the water to be treated 1 is immersed in the lower end portion of the inclined plate 8 for floc formation, a flow is generated, and the lower end of the inner side of the inclined sheet 8 for floc formation is further upper side due to the vortex ' The region 'forms a turbulent flow. With such eddy currents (and thus turbulent flow), the probability or frequency of collision of microflocs and suspended particles in the sedimentation tank 21 that have not yet precipitated increases, thereby promoting the flocculation of 201000409. In the present invention, in the present invention, the inclined plate for floc formation is in the range of 50 mm. The distance between the 8 is limited to 5 mm. The basis of the above limitation is explained, when 'the spacing is very small and not full
50mm之上限值。 如上述基本構成,於通過絮凝體形成用傾斜板8之前 後,為了發揮絮凝體形成用傾斜板8之絮凝體化功能而使 濁度達到1/2以下,僅將間距寬度設定為5mm〜5〇mm,未 必能夠實現。 即’於沈澱池21中’在到達絮凝體形成用傾斜板8之 上一階段’藉由微絮凝體彼此或與既存之絮凝體之碰撞而 絮凝體化之微粒子的比例小’浸入絮凝體形成用傾斜板8 中之微絮凝體及尚未微絮凝體化之懸浮粒子的比例大,必 需藉由相互之碰撞而於該傾斜板8中進行絮凝體化,然後 從該傾斜板8落下而沈澱於沈澱池21内,因此,必需將微 絮凝體化步驟中之無機凝集劑的使用量限定在規定量以 下。 其原因在於,微絮凝體化步驟中之無機凝集劑之使用 量越多,則沈澱池2 1中,於浸入絮凝體形成用傾斜板8之 上一階段,絮凝體化已開始進行,浸入絮凝體形成用傾斜 10 201000409 板8之微絮凝體及尚未微絮凝體化之懸浮粒子所占之比例 會減少,進而,該傾斜板8中之絮凝體化之頻率會減少。 若根據背景技術中所述之斯莫盧霍夫斯基方程式,重 新對上述本發明之基本原理進行說明,則該方程式可採用 如下所述之其他表現。 【數學式2】Above 50mm limit. In the above-mentioned basic configuration, the turbidity is 1/2 or less and the pitch width is set to 5 mm to 5 in order to exhibit the flocculation function of the inclined plate 8 for floc formation before the slanting plate 8 for floc formation. 〇mm, may not be able to achieve. That is, 'in the sedimentation tank 21' is in a stage of reaching the sloping plate 8 for floc formation, and the ratio of the flocculated microparticles is small by the collision of the microflocs with each other or with the existing floc. The proportion of the microflocs in the inclined plate 8 and the suspended particles which have not been microflocculated is large, and it is necessary to flocculate in the inclined plate 8 by collision with each other, and then fall from the inclined plate 8 to precipitate In the sedimentation tank 21, it is necessary to limit the amount of the inorganic flocculating agent used in the microflocculation step to a predetermined amount or less. The reason for this is that the more the amount of the inorganic aggregating agent used in the microflocculation step, the flocculation has started in the sedimentation tank 21 in the stage of immersion in the inclined plate 8 for floc formation, and the flocculation is started. The body formation tilt 10 201000409 The proportion of the microflocs of the plate 8 and the suspended particles which have not been microflocculated is reduced, and the frequency of flocculation in the inclined plate 8 is reduced. If the basic principle of the present invention described above is re-described in accordance with the Smoluchovsky equation described in the background art, the equation can adopt other expressions as described below. [Math 2]
dN / dt = ~α{ΑβΦ I π)· N (Ν :每單位體積之粒子(微絮凝體或絮凝體)之個數 α :受到無機凝集劑之影響的碰撞效率 G *速度梯度(velocity gradient),φ :單位體積之粒 子(微絮凝體或絮凝體)之平均容積) 上述一次微分方程式之通解,可表現為Aexp ( -kt) (其中,A係t=0之階段中之每單位體積之粒子(微絮凝 體或絮凝體)的個數,k=a (4G(D/Tr))。 於微絮凝體化已結束之階段,將如本發明所述之無機 ( 凝集劑之使用量已被限定時的通解設為Na,將如先前技術 所述之無機凝集劑之使用量被限定得比上述限定量更多時 的通解設為N,a,此時,受到無機凝集劑之影響之碰撞效 率α及單位體積之絮凝體或微絮凝體之平均容積〇,滿足 對應於N,a時大於對應於Na時、Na > N,a之關係式。 另一方面,於被處理水1浸入沈澱池21,進而通過絮 凝體形成用傾斜板8之階段中,如本發明,對無機凝集劑 之使用量進行限定,另一方面,將絮凝體形成用傾斜板8 之間距設定得較小之原因在於’該傾斜板8内之渴流及亂 11 201000409 流所產生之頻率較大,因而會增大速度梯度G。 即,本發明中,與先前技術相比,將碰撞效率α、平 均容積Φ設定得較小之原因亦在於,將流出絮凝體形成用 傾斜板8之階段中的速度梯度G設定得較大,而基於此種 α、Φ、G之大小關係,於微絮凝體化已結束之階段,如上 所述’即使Na> N’a,於通過絮凝體形成用傾斜板8之階段, 將採用如本發明之間距之I凝體形成用傾斜板8時的通解 設為Nb,將通過先前技術中所採用之絮凝體形成用傾斜板 8之階段中之上述通解設為Ν’ b,此時’最後獲得NbgN, b之關係,換言之,沈澱池21中最後所形成之絮凝體及微 絮凝體之數量N可成為與先前技術之情況大致相等之狀熊。 然而,如上所述,即使沈澱池21中所形成之絮凝體及 微絮凝體之數量N大致相等,如本發明,於藉由對無機凝 集劑之使用量進行限定而使絮凝體及微絮凝體高密度化 時’澄清水中所殘留之微絮凝體之沈澱頻率將會升高,進 而,可獲得優質澄清水,且如以上所指出般,可減少污泥 之發生量。 形成高密度化之微絮凝體’亦可藉由將高速攪拌槽⑶ 之攪拌之程度設在規定級別以上,來加以實現。 著眼於此種高速攪拌之作用,於社+ . 乍用於凊求項2之實施形態 中,採用了如下構成,其特徵在於: 微絜凝體化步驟,係 於將分割成2個以上區塊之高速_槽1G串聯連接成被處 理水1可依序流過之狀態下進行處 步驟及第2凝隼劑注入步驟 龙3又置第1凝集劑注入 步驟,且分別對第^凝集劑注入步 12 / ί. 201000409 驟及第2凝集劑注入步騾之注入 第1凝集劑注入步驟# ^ 仃調整,其中,上述 區塊為止之全部或―、 逆儆兔凝體化步驟之第! ^/刀之階段的被處理水〗注入無機凝 集劑,上述第2凝集劑注入步驟 無機凝 步驟之第2區塊至絮凝體 :、向處於自微絮凝體化 ^糸鍵體化步驟為止之全部或一部分之階 奴的被處理水i注入無機凝集劑。 々之?白 若根據基於上述斯莫盧霍夫斯基方程式之通解,對請 之實施形態之基本原理進行說明,則為如下所示: 從一開始(從t == 〇之階段) <階奴)僅以V量投予無機凝集劑,且 並未將微絮凝體化步驟如上述基本構成般分為2個部分以 上’此時,將用以微絮凝體化之平均處理時間設為㈤1 + t2時的每單位時間之粒子數N】 + 2,可表現為dN / dt = ~α{ΑβΦ I π)· N (Ν : number of particles per unit volume (microflocs or flocs) α : collision efficiency affected by inorganic aggregating agent G * velocity gradient (velocity gradient ), φ : the average volume of particles per unit volume (microflocs or flocs). The general solution of the above first differential equation can be expressed as Aexp ( -kt) (wherein the unit cell in the stage of A t = 0 = 0) The number of particles (microflocs or flocs), k = a (4G (D / Tr)). At the stage where the microflocculation has ended, the inorganic (the amount of aggregating agent used) according to the present invention The general solution when it has been defined is set to Na, and the general solution when the amount of the inorganic aggregating agent used as described in the prior art is limited to be more than the above-defined amount is set to N, a, and at this time, it is affected by the inorganic aggregating agent. The collision efficiency α and the average volume 〇 of the floc or microflocs per unit volume satisfy the relationship corresponding to N, a when it corresponds to Na, Na > N, a. On the other hand, in the treated water 1 immersed in the sedimentation tank 21, and further passed through the stage of forming the inclined plate 8 for the floc, as in the present Therefore, the amount of use of the inorganic aggregating agent is limited, and on the other hand, the reason why the distance between the inclined plates 8 for floc formation is set smaller is that the flow in the inclined plate 8 and the flow of the disorder 11 201000409 are generated. The frequency is large, and thus the velocity gradient G is increased. That is, in the present invention, the reason why the collision efficiency α and the average volume Φ are set smaller as compared with the prior art is also that the slanting plate 8 for forming the effluent is formed. The velocity gradient G in the stage is set larger, and based on the magnitude relationship of α, Φ, and G, at the stage where the microflocculation has ended, as described above, 'even Na> N'a, through the floc In the stage of forming the inclined plate 8, the general solution when the inclined plate 8 for forming an I-form body according to the present invention is used is Nb, which is passed through the stage of forming the inclined plate 8 for floc formation used in the prior art. The above general solution is set to Ν'b, at which time the relationship of NbgN, b is finally obtained, in other words, the number N of the last formed flocs and microflocs in the sedimentation tank 21 can be substantially equal to that of the prior art. However, As described above, even if the number N of flocs and microflocs formed in the sedimentation tank 21 is substantially equal, as in the present invention, the floc and the microfloc are high in density by limiting the amount of the inorganic aggregating agent used. During the clarification, the precipitation frequency of the microflocs remaining in the clarified water will increase, and further, high-quality clarified water can be obtained, and as indicated above, the amount of sludge can be reduced. The formation of high-density microflocs 'It can also be achieved by setting the degree of agitation of the high-speed agitation tank (3) to a predetermined level or higher. Focusing on the effect of such high-speed agitation, it is used in the embodiment of the claim 2 The micro-coagulation step is a step of connecting the high-speed groove 1G divided into two or more blocks in series so that the water to be treated 1 can flow sequentially. 2 coagulant injection step Dragon 3 is further provided with a first agglutinating agent injection step, and respectively injecting the first agglutinating agent into the step 12 / ί. 201000409 and the second agglutinating agent injecting step into the first agglutinating agent injecting step # ^仃 adjust, where Until all of the above-described block or - the inverse of the first body watch rabbit condensate of step! ^/The treated water in the stage of the knife is injected into the inorganic aggregating agent, and the second aggregating agent is injected into the second block of the inorganic coagulation step to the floc: to the self-microflocculation keying step The treated water i of all or part of the slaves is injected into the inorganic aggregating agent. What? According to the general solution based on the above-mentioned Smoluchovsky equation, Bai Ruo explains the basic principle of the implementation form as follows: From the beginning (from the stage of t == 〇) < step slave The inorganic flocculant is administered only in an amount of V, and the microflocculation step is not divided into two or more portions as described above. In this case, the average processing time for microflocculation is set to (5) 1 + t2. The number of particles per unit time N] + 2 can be expressed as
Ni + 2= Aexp ( - kt,- kt2)。 對此在如上述基本構成般,將微絮凝體化步驟分為2 個邛刀以上,並且將無機凝集劑之注入步驟分為第1凝集 劑注入步驟與第2凝集劑注入步驟,且將前者之注入量設 為V — Δν,後者之注入量設為Λν ( Λν係比v少一位數 以上之量),將用以進行被處理水丨之第丨區塊中之微絮 凝體化的平均處理時間設為ti ’用以進行第2凝集劑注入步 驟中之微絮凝體化的平均處理時間設為“時,將第1凝集 劑庄入步驟之最後階段中之每單位體積的粒子數設為Ni + 2 = Aexp ( - kt, - kt2). In this case, as in the basic configuration described above, the microflocculation step is divided into two boring tools, and the injection step of the inorganic aggregating agent is divided into a first agglutinating agent injecting step and a second agglutinating agent injecting step, and the former is The injection amount is set to V - Δν, and the latter injection amount is set to Λν (the Λν system is less than a single digit or more than v), and is used to perform microflocculation in the third block of the treated water raft. The average processing time is set to ti 'the average processing time for performing the microflocculation in the second aggregating agent injection step is set to ", the number of particles per unit volume in the final stage of the first agglutinating agent is inserted into the step Set to
Nl ,第2凝集劑注入步驟之最後階段中之每單位體積之 粒子數設為N,! + 2,此時可表現為 Nif= Afexp ( — kltj ^ 13 201000409 (其中,A'係t = ki = α 1 ( 4G Φ / 7Γ ) 投予無機凝集劑相對 0之階段中之Νι,、即微絮凝體之數量, ,αι表示與僅以每單位體積ν—Δν 應的凝集效率) Ν' 1 + 2 = Nl'exp ( Κ2Ϊ2 ) A'exp ( - kjt,- k2t2) (其中’A,係t=0之階段中之n〗,,即微絮凝體之數量, α2 (4(ΪΦ/π ) ,α2係表示第2凝集劑注入步驟中, 與僅以Λν注入無機凝集劑相對應之凝集效率,①,則表_ 被處理水i自第i區塊流入至第2區塊之階段中 : 凝體容積)。 k. 若對上述K”與N’1 + 2之大小關係進行考察,則於被 處理水i自最初之時間起直至規定時間(直至hi為止之 時間),被處理水i中所存在之微絮凝體當然會在無機凝 集劑之影響下發生凝集’但並非所有所投予之無機凝集劑 均有助於微絮凝體化,而是—面依序被吸收於微絮凝體 中,一面發揮凝集作用。 於此種情況下,在最初所投予之無機凝集劑之每單位 體積之量為V時及V—(其中,Λν表示遠小於V之量) 時’對凝集作用之影響幾乎沒有不同。 、因此,於作為上述Mki之各要素之α與“之間,α ’αι成立’因此’ 丨成立。 基於相同之根據,<2与邙2成立,a%a,成立。 ^然而,於已到達第2區塊之階段,藉由第丨區塊中之 高速攪拌,微絮凝體之平均容積減少,由此φ, <φ成立。 因此,由於a2<a成立,因此,結果a (My〉心 14 201000409Nl, the number of particles per unit volume in the final stage of the second agglutinating agent injection step is set to N,! + 2, at this time, it can be expressed as Nif= Afexp (- kltj ^ 13 201000409 (where A' is t = ki = α 1 ( 4G Φ / 7Γ ) is administered to the inorganic aggregator in the phase of 0, ie The number of microflocs, αι denotes the agglutination efficiency with ν-Δν per unit volume only Ν' 1 + 2 = Nl'exp ( Κ2Ϊ2 ) A'exp ( - kjt, - k2t2) (where 'A, n in the stage of t=0, that is, the number of microflocs, α2 (4(ΪΦ/π), α2 means the second aggregating agent injection step, corresponding to the injection of the inorganic aggregating agent only by Λν The agglutination efficiency, 1, the table _ the treated water i flows from the ith block to the second block: the volume of the condensate. k. If the relationship between the above K" and N'1 + 2 is examined Then, the microflocs present in the treated water i will naturally agglomerate under the influence of the inorganic aggregating agent from the initial time until the specified time (up to hi), but not all of them The inorganic aggregating agents which are administered contribute to the microflocculation, but the surface is sequentially absorbed into the microflocs and exerts agglutination. In this case, the effect on the agglutination is almost the same when the amount of the inorganic aggregating agent initially administered is V per unit volume and V- (where Λν is much smaller than the amount of V). Therefore, α and α 'α are established between the α and the above-mentioned elements of Mki. Therefore, based on the same basis, <2 and 邙2 are established, and a%a is established. At the stage of reaching the second block, the average volume of the microflocs is reduced by the high-speed stirring in the second block, whereby φ, < φ is established. Therefore, since a2 < a holds, the result a (My 〉心14 201000409
+ a2t2 成立 ’ N、+ , ^ B+ a2t2 established ’ N, + , ^ B
Nl + 2成立。即’當投予每單位體積相 同量之無機凝集劑時,並未劃分為第i區塊與第2區塊以 後之區塊之If況及割分為第丨區塊與第2區塊以後之區塊 之情況’後者更容易凝集,且為除去對象之粒子數增多, 結果,可進行有效之凝集。 一因此,如請求項2之實施形態,對於高速㈣槽㈣ 5,劃分為2個以上之區塊,且於第2區塊以後對盔機 凝集劑進行補充時’因整體上摻合較少之無機凝集劑,從 而可媒保相同程度之 之凝集粒子數。凝集效果’即相同程度之每單位體積 於請求項2之實施形態中,如圖i所示,於2個以上 之區塊中均採用高速㈣槽1G(於圖1中,顯示於3個區 塊101、1〇2、103中採用高速攪拌槽1〇之情形 用該高繼槽10’於沈殿池21中沈殿之粒子及未㈣而 殘留於沈殿水3中之粒子之平均粒徑將會極小化,於對沈 :殿水3進行過遽之階段中被過遽之粒子之直徑亦會極:、 化,因此可實現殘留之微絮凝體之微小化。 並且’於請求項2之實施形態令,於第i凝集劑注入 步驟、及帛2凝集劑注入步驟之各步驟中,對㈣ 機凝集劑之量進行調整(限定),以使凝聚集塊^留量 在規定級別以了,因此,如先前技術&, 劑使粒子彼此結合之頻率減小,使微絮凝體高密度化,另、 一方面,可使伴隨無機凝集劑之使用的&尼之發二 減少,進而提高污泥之濃縮、脫水性’使污泥處理容I易化。 15 201000409 另如圖1所示,第2凝集劑注入位置2〇1, 2區塊102以後之高速授拌槽iq之階段, =槽1。之授掉’進行絮凝體化步驟之上—階段 請求項3之實施丨態,其特徵在於 塊物殘留量之沪押嫩如 并马表不凝集集 理水之體化步驟已結束之階段的被處 (_Π Tlme Rati。··當藉㈣同之吸取程度 ; 吸取與被處理水1同溫、等量之蒸.水 將被處理"之吸取時間設為Ts,蒸餘水之吸取時間 °又為Tv,此時以Ts/T所表 在2_5以下。 斤表現之心標)在(〇以下,較佳 請求項P 兄為,將無機凝集劑之凝聚集塊物殘留量(為 以之祕)較在規枝_下來使用, ^述STR之實施形態為佳,且處於容易利用之狀態。 理解抓之定㈣如請求項 係藉由如下之STR== Ts/Tv之比 由安裝有總計為45mm之薄膜 :、中係分別將藉 ^孔隙率38%之顧^===徑為〇.〜 Γ且Μ 〗氣之濾紙)的吸取裝置 限度為:二係具備有減磨容器'過遽器摺疊器、真空極 :W之吸取栗的裝置)對試樣水 盆 ?二等量之蒸館水分別吸取之時間設為Ts(se〇及: 之二:求項丄之實施形態:亦可不以上述之嚴格定義 乂如明求項3所§己栽之STR,充分進行上述基 16 201000409 本構成之無機凝集劑 使用之程度的調整(限定)。 如靖求項3之實祐形能 第2〜,在對第1凝集劑注入步驟及 第2凝集劑注入步驟之 料Nl + 2 is established. That is, when the same amount of inorganic aggregating agent per unit volume is administered, the condition of the block after the i-th block and the second block is not divided into the second block and the second block. In the case of the block, the latter is more likely to aggregate, and the number of particles to be removed is increased, and as a result, efficient agglutination can be performed. Therefore, as in the embodiment of claim 2, for the high speed (four) slot (four) 5, the partition is divided into two or more blocks, and when the helmet agglutinating agent is supplemented after the second block, 'the overall blending is less The inorganic aggregating agent can mediate the same degree of agglomerated particles. The agglutination effect 'is the same degree of unit volume per unit volume in the embodiment of claim 2, as shown in FIG. i, high-speed (four) slots 1G are used in two or more blocks (in FIG. 1 , shown in three regions) In the case where the high-speed stirring tank 1〇 is used in the blocks 101, 1〇2, and 103, the average particle diameter of the particles remaining in the Shen Dian water 3 by the particles of the high-storage tank 10' in the Shendian pool 21 and the (4) Minimization, the diameter of the particles that have been smashed during the stage of the shoal of the shoal of the shoal of the shoal of the shoal of the shoal of the shoal In the steps of the i-th agglutinating agent injection step and the 帛2 agglutinating agent injection step, the amount of the (four) machine aggregating agent is adjusted (limited) so that the agglomerated aggregate retention amount is at a predetermined level. Therefore, as in the prior art &, the frequency at which the particles are bonded to each other is reduced, the microflocs are densified, and on the other hand, the & The concentration and dehydration of the sludge make the sludge treatment volume easy. 15 201000 409 As shown in Fig. 1, the second aggregating agent is injected into the position 2〇1, the stage of the high-speed mixing tank iq after the block 102, = the groove 1. The 'following step' is carried out. The implementation of item 3 is characterized by the fact that the amount of residual material in the block is the same as that in the stage where the physicalization step of the water is not agglutinated (_Π Tlme Rati. The degree of absorption; draw the same temperature and the same amount of steam as the treated water. The water will be treated " the suction time is set to Ts, and the evaporation time of the distilled water is again Tv, which is represented by Ts/T. 2_5 or less. The performance of the heart of the catty) (in the following, the preferred request item P brother, the amount of agglomerated aggregates of the inorganic agglutinating agent (for the secret) is used in comparison with the regulation _, STR The embodiment is better and is in an easy-to-use state. Understanding the grasping rule (4) If the request item is installed by a film having a total of 45 mm by the ratio of STR== Ts/Tv as follows: The rate of 38% of the ^^== diameter is 〇.~ Γ and Μ 〗 〖 qi filter paper) the suction device limit is: the second series has a grinding container 'over Folding device, vacuum electrode: W device for picking up the chest) The time for the sample basin and the second amount of steaming water to be taken separately is set to Ts (se〇 and: 2: the implementation of the item: The adjustment (limitation) of the degree of use of the inorganic aggregating agent of the above-mentioned base 16 201000409 may be sufficiently performed without strictly defining the above-mentioned STR, such as the STR of the present invention. 2nd, in the first agglutinating agent injection step and the second agglutinating agent injection step
^ 4 0 -Γ ^ , 量進仃調整(限定)以使STR 在4.0以下時’與被處理 中所含之微細懸浮粒子之減少 化的同時,可減少絮 m , 坑體之破壞,且可減少藉由沈澱池之 沈厥水3取出部之澄、,杳pg· 1 ^ [之,丑凊£ 7所設置之安裝間距為5mm〜 10mm的絮凝體形成用傾 1只計板8而自沈澱池21流出之微絮 凝體量’因此與以往之方法相較,能夠藉由更小之無機凝 集劑注入率而獲得更低之濁度之沈澱水3。 尤其是在對無機凝集劑注入率進行調整以使絮凝體化 步驟入口 < STR在2 5以下時…面可反映且維持微細且 高密度化之微絮凝體性狀,—面可成長為例如3“m以上 之大型微絮凝體。 因此,雖然大型微絮凝體與先前之絮凝體相較之下, 直徑較小,但因尚密度化而具有較大之沈降速度,因此可^ 4 0 -Γ ^ , the amount is adjusted (limited) so that when the STR is below 4.0, the reduction of the fine suspended particles contained in the treatment can reduce the damage of the floc m and the pit. Reducing the take-up water of the sedimentation tank by the sedimentation tank 3, 杳pg· 1 ^ [, ugly £7, the installation pitch of 5 mm to 10 mm is set to pour the plate 8 from the sedimentation tank 21 The amount of microflocs flowing out' is therefore comparable to the conventional method, and a lower turbidity of the precipitated water 3 can be obtained by a smaller inorganic aggregating agent injection rate. In particular, when the inorganic aggregating agent injection rate is adjusted so that the flocculation step inlet < STR is 25 or less, the surface can reflect and maintain the fine and high-density microfloc trait, and the surface can be grown to, for example, 3 "Large microflocs above m. Therefore, although the large microflocs have a smaller diameter than the previous flocs, they have a larger sedimentation velocity due to the density.
有助於在沈澱池21中之沈澱分離,進而有助於沈澱水3之 濁度之降低。 請求項4之實施形態,其特徵在於:於已結束微絮凝 體化步驟之階段’對凝集條件進行設定,即,使沈澱水3 中所殘留之直徑在3.0/zm以下的粒子數量在1〇萬個/mL 以下’較佳在40000個/mL以下,然後於處於結束絮凝體形 成用傾斜板8之通過之上一階段的絮凝體化步驟中,於作 為表示絮凝體之濃縮性之指標的SDI值(使用1 OOmL之量 筒’對進行30分鐘沈澱後之絮凝體容積濃度進行測量,然 17 201000409 =求出該樣品之固形物濃度,並且作為每w絮凝體容積 ί智、&之固形物量(mg) ’藉由樣品中之固形物量(mg/ 凝體容積(mL) X樣品中數量丨之式所算出之污泥密度 指標值)在0mg/mL以上,較佳在8mg/mL以上之凝集條件 下’進行絮凝體化。 ,請求項4之實施形態中,必需設定如下之凝集條件, 戔留於沈殿池21之直控在3.0//Π1以下之粒子數量 在10萬個/mL以下,較佳在40000個/mL以下,但本來係 八有…、機凝集劑越多則此種微絮凝體之每單位體積之個數 越少之關係。 二而,根據上述基本構成可知,微絮凝體化步驟中所 使2之無機凝集劑受到限定,從而無法保證上述微絮凝體 之每單乜體積之數值要件。 儘管如此,若要滿足該數值要件,則必需於請求項4 之實施形態中’根據請求項2之實施形態,將高速攪拌之 程度設定得較高。 另一方面,於請求項4之實施形態中,如上所述,於 結束絮凝體形成用傾斜板8之通過的上—階段,要件為随 值在6mg/mL以上,較佳在8mg/mL以上。 為了可實現此種SDI值之要件,如上所述,係指藉由 將同速攪拌之程度設定得較高,而使浸入沈澱池21内之微 絮凝體達到咼密度,從而於相互碰撞且凝集時,容易沈澱。 如此,於請求項4之實施形態之情況,藉由將高速攪 掉之程度設定得較高’而實現了微絮凝體之高密度化因 18 201000409 此’於絮凝體形成用傾斜板8中,微絮凝體彼此碰撞而絮 凝體化之後’會從該傾斜板8落下,並於沈澱池21内極其 谷易沈殿’從而藉由被處理水1通過絮凝體形成用傾斜板8 之刖後’成為非常容易實現減少至4/5以下之要件的狀態。 於用以實現絮凝體化之沈澱池21之方式中,主要係採 用背景技術所說明之各方式中的污泥浮層方式及傳統方 式。 於兩種方式中,如請求項5之實施形態所示,當然可 採用於沈澱池2 1中僅於澄清水流出之出口附近設置絮凝體 形成用傾斜板8之構成。 J而於傳統方式之情況下’如請求項6之實施形態, 係採用傳統方式作為絮凝體化步驟,然後如圖3所示,可 採用具有如下特徵之方式,即,將絮凝體形成用傾斜板8 設置於低速攪拌槽191、192、193後續之沈澱池21的被處 理水1所流入之入口附近及澄清水所流出之出口附近此2 個階段。 如此,於入口及出口此2個階段設置絮凝體形成用傾 斜板8之情況下,\口附近之絮凝體形成用傾斜板8之絮 凝體=功能尤為顯著,且將於實施例2中對該點加以敍述。 請求項7之實施形態,其特徵在於:絮凝體化步驟被 分為2個以上之區塊,將各區塊之高速攪拌強度之Gr值(當 將攪拌係數設為c,攪拌翼之面積設為A(m2),攪拌翼之 周邊速度設為v(m/sec),動黏性係數設為^ (^/似), 攪拌槽之體積(容量)設為V(m3)時,藉由 19 201000409 【數學式3】It contributes to the separation of the precipitate in the sedimentation tank 21, thereby contributing to the reduction of the turbidity of the precipitated water 3. The embodiment of claim 4 is characterized in that the agglutination condition is set at the stage of the completion of the microflocculation step, that is, the number of particles having a diameter of 3.0/zm or less remaining in the precipitated water 3 is 1〇. 10,000/mL or less 'preferably at 40,000 /mL or less, and then in the flocculation step at the stage of ending the passage of the inclined plate 8 for floc formation, as an index indicating the concentration of the floc. The SDI value (using a cylinder of 100 mL) was measured for the floc volume concentration after 30 minutes of precipitation, and then 17 201000409 = the solid concentration of the sample was determined and used as the solid volume per w floc volume, & Quantity (mg) 'The amount of solid matter in the sample (mg/condensate volume (mL) The amount of sludge density calculated in the X sample) is above 0 mg/mL, preferably above 8 mg/mL. Under the agglutination conditions, the flocculation is carried out. In the embodiment of claim 4, the following agglutination conditions must be set, and the number of particles directly controlled in the Shendian pool 21 at 3.0//Π1 or less is 100,000/mL. Hereinafter, preferably at 40,000 / mL Next, but originally there are eight... The more the machine agglomerating agent, the smaller the number of such micro-flocs per unit volume. Second, according to the above basic configuration, the microflocculation step 2 The inorganic aggregating agent is limited so that the numerical requirements of the volume of each of the microflocs described above cannot be ensured. However, in order to satisfy the numerical requirements, it is necessary to implement the method according to claim 2 in the embodiment of claim 4. In the embodiment of the claim 4, as described above, in the upper stage of the passage of the inclined plate 8 for forming a floc, the requirement is a value. 6 mg / mL or more, preferably 8 mg / mL or more. In order to achieve such a SDI value, as described above, it means to immerse into the sedimentation tank 21 by setting the degree of stirring at the same speed to be higher. The microflocs reach the density of the crucible so as to be easily precipitated when colliding with each other and agglutinating. Thus, in the case of the embodiment of claim 4, the microfloc is realized by setting the degree of high-speed agitation to be high. High Densification Factor 18 201000409 In the inclined plate 8 for floc formation, the microflocs collide with each other and flocculate, and then fall from the inclined plate 8 and are extremely dense in the sedimentation tank 21 The state in which the treated water 1 passes through the inclined plate 8 for forming the floc is very easy to achieve a condition of reducing to 4/5 or less. In the manner of the sedimentation tank 21 for realizing flocculation, the main method is adopted. BACKGROUND OF THE INVENTION The sludge floating layer method and the conventional method in each of the modes described above. Of the two modes, as shown in the embodiment of claim 5, it is of course possible to use the outlet of the sedimentation tank 21 only for the clarified water to flow out. The configuration of the inclined plate 8 for floc formation is provided in the vicinity. In the case of the conventional method, as in the embodiment of claim 6, the conventional method is employed as the flocculation step, and then, as shown in FIG. 3, a method may be employed in which the floc formation is inclined. The plate 8 is disposed in the vicinity of the inlet into which the water to be treated 1 of the subsequent sedimentation tank 21 of the low-speed agitation tanks 191, 192, and 193 flows, and the outlet near which the clarified water flows out. In the case where the inclined plate 8 for forming a floc is provided in the two stages of the inlet and the outlet, the floc = function of the inclined plate 8 for floc formation in the vicinity of the port is particularly remarkable, and will be described in the second embodiment. Point to describe. The embodiment of claim 7 is characterized in that the flocculation step is divided into two or more blocks, and the Gr value of the high-speed stirring strength of each block is set (when the stirring coefficient is c, the area of the stirring wing is set) For A (m2), the peripheral speed of the stirring blade is set to v (m/sec), the dynamic viscosity coefficient is set to ^ (^/like), and the volume (capacity) of the stirring tank is set to V (m3). 19 201000409 [Math 3]
Gt> = l(c»A»v3) \ 2·γ·Υ 所表示之數值)設在150sec-i以上,將高速攪拌時間之 Tr值設在3分鐘以上。 一般而言,於進行高速攪拌之各區塊中,藉由將攪拌 強度GR設定得較大,且將攪拌時間Tr設定得較大,藉此 可減少微細懸洋粒子之數量,使微絮凝體高密度化。此時, 凝集集塊物一面於懸浮粒子及微絮凝體碰撞時附著面 被消耗,藉此使STR逐漸降低。然而,於高速攪拌後,若 採用STR超過規定之數值、無機凝集劑大量殘留之高凝集 劑注入率時,於之後之絮凝體化步驟之階段,由於無法避 免凝集集塊物之粗粒化、低密度化,因此特地以高速攪拌 使其微細化、高密度化之微絮凝體必然會粗粒化且低密度 化。 因此,尤其如請求項3之實施形態,藉由將微絮凝體 化步驟已結束之階段之被處理水的STR設在4·〇以下,較 佳在2.5以下,更佳為儘可能接近丨〇,從而在之後的絮凝 體化步驟中,可防止絮凝體之粗粒狀態化且低密度化,從 而可有效地達成本發明之課題。 即,為了實現上述之數值要件之STR,可藉由注入較 先前技術更少量之凝集劑,使微絮凝體高密度化,且有效 地實現微絮凝體之沈澱分離,並且可一併使後續之過濾處 理及污泥處理最佳化。 20 201000409 請求項8之實施形態,其特徵在於:絮凝體形成用傾 斜板8之上下寬度在30mm以上、lOOmm以下,且在上下 方向上取20mm以上、200mm以下之間隔而設為多段。 如上述實施形態,當將上下寬度設在3 〇mm以上時,會 較多地出現亂流形成過程,從而可有助於絮凝體化。 其中’考慮到當上下寬度超過l〇〇mm時,無法有助於 形成亂流’從而如上述設定1 〇〇inrn之上限值。 將絮凝體形成用傾斜板8設為多段之根據在於,於各 段之下端附近形成有渦流,可有效地促進絮凝體化。 而且,必需對各段設置20mm以上之間隔之原因在於, 在通常之被處理水1之流速狀態下,若未滿2〇mm時,則絮 凝體形成用傾斜板8之下端的流動狀況會成為接近該傾斜 板8彼此連接狀態時的流動狀態,從而不易於上側之絮凝 體形成用傾斜板8之下端部產生渦流,因此設定了上述下 限值,而另一方面,即使超過2〇〇mm,在技術上亦無實際 意義,因此設定了上述上限值。 ί : 一般’大多情況下通常將相對於絮凝體形成用傾斜板8 之水平方向的角度設定為3〇t:〜80。(:。 請求項9之實施形態,其特徵在於:如圖2所示,於 高速攪拌步驟與絮凝體化步驟之間,設置接觸材料堆積槽 12、15,該接觸材料堆積槽對於微絮凝體之流通會形成障 壁狀態,藉此可使新流入之微絮凝體與既存微絮凝體進行 接觸及碰撞’從而藉由使被處理水1通過該接觸材料堆積 槽12、15而進一步促進微絮凝體化。 21 201000409 成為障壁之具體的接觸 如上述,對於微絮凝 材料堆積層13、16之形狀,大多情況下係採用藉由形成渴 流而可扣留微絮凝體之中空圓筒形狀作為典型範例,在圖2 中,係於3個區塊ΗΠ、102、而中之高速授拌槽1〇與用 以實現絮凝體化步驟之污泥浮層槽5 <间5又置有早個或 複數個(圖i中為2個)内部設置 复有如上述之形態的接觸 材料堆積層13、16之接觸材料堆積槽12、15。 藉由插入此種接觸材料堆積槽12、15,而於接觸材料 、隹積槽中之各個接觸材料之内外空隙,形成有無數個微小 渦流’最初微小渦流將微絮凝體以既存絮凝體狀態扣留於 接觸材料之内外空隙…輸送後續之微絮凝體以使其成 為既存絮凝體,從而能夠以極高之頻率進行碰撞、扣留。 :現基於此種碰撞、扣留之微絮凝體化所帶來的效果,遠 過提高GRHR值之高速攪拌槽1〇中的微絮凝體化之 =,因此能夠進一步提高後續之絮凝體化步驟之集塊化 :,結果,能夠提高沈搬池21中之細粒、高密度之微絮 的刀離效果。即’可同時達成過濾步驟中所流入之微 :凝體之細粒、高密度化與粒子數之她,因此可同時 成所有經《之被處理水丨中的微絮凝體 數量之 減少化。 關於與上述效果相伴之現象’於【數學式^中,碰撞 頻率召會受到上述渦流晋 述心洲*置之衫響而成為較大之值(比起由 才 ^ 半槽内之授拌所產生之亂流,因上述满流而引起之碰 里革特別大),進而,可使既存絮凝體數量^上升,因 22 201000409 此可增大來自尚速授拌槽ίο之位於出口階段之被處理水 中單位體積之微絮凝體的減少率(dN/dt ),且可增加來 自接觸材料堆積層之位於出口階段之被處理水1中的微絮 凝體平均直徑,並且可減少該微絮凝體之數量。 因此,相比於未插入上述接觸材料堆積槽12、1 $之情 況,於插入有上述之接觸材料堆積槽12、15之情況,為了 獲得相同之微絮凝體形成速度,可基於更低之碰撞效率 α,即,可將受到無機凝集劑之影響的碰撞效率設定為較 小值,結果,可獲得更高密度之微絮凝體,而另一方面, 因為加強高速授拌槽中之授拌,故亦可錢拌強度W、及 授拌時間TR設定為更小值。 請求項H)之實施形態中,如圖2所示,其特徵在於, 將接觸材料堆積槽設置為複數段(其中,於圖2, 2 2之情況),如此,藉由使被處理水i通過複數段之 材料堆積槽12、15,而可進一步促進上 凝體化處理。 述之兩雄度之微絮 其中,於設置有如請求項9、1〇 實施形態中,會產生如下技術方面之困難觸槽之 ,微絮凝體會堆積或駐留於接觸材料堆積肖Η、:度化 部,從而對被處理水i之流通造成阻礙。 之壁Gt> = l(c»A»v3) \ 2·γ·Υ The numerical value) is set to 150 sec-i or more, and the Tr value of the high-speed stirring time is set to 3 minutes or longer. In general, in each block where high-speed stirring is performed, by setting the stirring strength GR to be large and setting the stirring time Tr to be large, the number of fine suspended particles can be reduced, and the microflocs can be made. High density. At this time, the aggregated surface of the aggregated aggregate is consumed when the suspended particles and the microflocs collide, whereby the STR is gradually lowered. However, when the STR exceeds a predetermined value and the high aggregating agent injection rate of the inorganic aggregating agent is large after the high-speed stirring, the coarse granulation of the aggregated aggregate is unavoidable at the stage of the subsequent flocculation step. Since the density is reduced, the microflocs which are specifically refined by high-speed stirring and which are denser and higher in density are inevitably coarsened and reduced in density. Therefore, in particular, in the embodiment of claim 3, the STR of the water to be treated at the stage where the microflocculation step has been completed is set to be 4 or less, preferably 2.5 or less, and more preferably as close as possible to 丨〇. Therefore, in the subsequent flocculation step, the coarse grain state of the floc can be prevented and the density can be reduced, and the object of the present invention can be effectively achieved. That is, in order to realize the STR of the above numerical requirements, the microflocs can be densified by injecting a smaller amount of aggregating agent than the prior art, and the precipitation and separation of the microflocs can be effectively achieved, and the subsequent Optimization of filtration treatment and sludge treatment. The embodiment of the present invention is characterized in that the upper and lower widths of the inclined plate 8 for forming a floc are 30 mm or more and 100 mm or less, and the interval between the upper and lower sides is 20 mm or more and 200 mm or less. According to the above embodiment, when the upper and lower widths are set to be 3 〇 mm or more, the turbulent flow forming process is more likely to occur, which contributes to flocculation. Wherein 'considering that when the upper and lower widths exceed l〇〇mm, it is not possible to contribute to the formation of turbulent flow' and the upper limit value of 1 〇〇inrn is set as described above. The slanting plate 8 for floc formation is divided into a plurality of stages in that eddy current is formed in the vicinity of the lower end of each stage, and flocculation can be effectively promoted. Further, it is necessary to provide an interval of 20 mm or more for each of the segments, and the flow state at the lower end of the inclined plate 8 for floc formation becomes the case when the flow rate of the water to be treated 1 is normally less than 2 mm. The flow state when the inclined plates 8 are connected to each other is approached, so that the eddy current is not easily generated at the lower end portion of the inclined plate 8 for floc formation on the upper side, so that the above lower limit value is set, and on the other hand, even if it exceeds 2 mm It is technically meaningless, so the above upper limit is set. ί : Generally, in many cases, the angle with respect to the horizontal direction of the inclined plate 8 for floc formation is generally set to 3 〇 t: 〜80. (An embodiment of claim 9, characterized in that, as shown in Fig. 2, between the high-speed stirring step and the flocculation step, contact material stacking grooves 12, 15 are provided, the contact material stacking grooves for microflocs The flow will form a barrier state whereby the newly influent microflocs can be brought into contact and collide with the existing microflocs' to further promote microflocs by passing the treated water 1 through the contact material stacking grooves 12, 15. 21 201000409 The specific contact of the barrier is as described above. For the shape of the microflocclic material accumulation layers 13, 16, in many cases, a hollow cylindrical shape capable of retaining microflocs by forming a thirsty flow is taken as a typical example. In Fig. 2, the high-speed mixing tank 1〇 in the three blocks ΗΠ, 102, and the sludge floating layer tank 5 < 5 used to realize the flocculation step are further placed early or plural The contact material accumulation grooves 12 and 15 of the contact material deposition layers 13 and 16 having the above-described form are provided inside (two in FIG. i). The contact material stacking grooves 12 and 15 are inserted into the contact material. Hoarding trough The inner and outer gaps of each contact material are formed with innumerable small eddy currents. The initial micro vortex traps the microflocs in the inner and outer gaps of the contact material in the state of existing flocculation... and transports the subsequent microflocs to become existing flocs, thereby It is possible to collide and detain at a very high frequency. The effect of micro-flocculation based on such collision and detainment is far beyond the microflocculation in the high-speed agitation tank 1 which increases the GRHR value. Therefore, the clogging of the subsequent flocculation step can be further improved: as a result, the knife-off effect of the fine-grained, high-density micro-float in the sinking tank 21 can be improved. That is, the inflow of the filtration step can be simultaneously achieved. Micro: the fine particles of the condensate, the high density and the number of particles, so it can simultaneously reduce the number of microflocs in all the treated leeches. About the phenomenon associated with the above effect In the formula ^, the collision frequency call is swayed by the above-mentioned eddy current, and it becomes a larger value (compared to the turbulent flow generated by the mixing in the half tank, due to the above full flow The resulting leather is particularly large), and in turn, the number of existing flocs can be increased, as 22 201000409 can increase the reduction of microflocs per unit volume in the treated water from the still-feeding tank. Rate (dN/dt), and the average diameter of the microflocs in the treated water 1 at the outlet stage from the contact material buildup layer can be increased, and the number of the microflocs can be reduced. Therefore, compared to the above In the case of contacting the material stacking grooves 12, 1 $, in the case where the above-mentioned contact material stacking grooves 12, 15 are inserted, in order to obtain the same microfloc forming speed, it is possible to be based on a lower collision efficiency α, that is, it can be subjected to The collision efficiency of the influence of the inorganic aggregating agent is set to a small value, and as a result, a higher density microfloc is obtained, and on the other hand, since the mixing in the high speed mixing tank is enhanced, the strength W can be mixed. And the mixing time TR is set to a smaller value. In the embodiment of the request item H), as shown in FIG. 2, the contact material accumulation groove is provided in a plurality of stages (in the case of FIGS. 2 and 22), and thus, by treating the water i The upper gelation treatment can be further promoted by the plurality of material stacking grooves 12 and 15. The micro-fistles of the two males, in the embodiment provided in the request item 9, 1 ,, will result in the following technical difficulties, the micro-flocs will accumulate or reside in the contact material accumulation, Department, which hinders the circulation of treated water i. Wall
付此種狀況,於請求項u之實施形態中,W 有如下特徵之構成,來解決上述技術上之困難: ’藉由對接觸材料堆積層間歇或連續地注,、 將駐留且堆積於該接觸材料堆 二而可 场微絮凝體加以除 23 201000409 去。 如請求項^^",於設置接觸材料堆積槽^、^ 時,尤其如請求項12之實施形態,將接觸材料堆積槽中之 空塔通水速度設在3 Gm/h以上,滯留時間設在Μ分鐘以 上,在此特徵情況下,可同時達成過滤步驟結束之階段 的微絮凝體直徑之縮小及微絮凝體數量之減少&,尤^可 大幅度地減少平均直徑在3 〇 # m以上之微絮凝體數量 助於過濾水濁度之降低。 請求項13之實施形態,其特徵在於:係_伴隨低速 攪拌步驟之傳統方式來作為絮凝體化步驟,將低速攪拌強 度之〇8值(當將攪拌係數設為c,攪拌翼之面積設 (V),㈣翼之周邊速度設為v(m/see),動黏性係數 設為r (m2/sec),攪拌槽之體積(容量)設為v(m3) 藉由 【數學式4】In this embodiment, in the embodiment of the claim u, W has the following characteristics to solve the above technical difficulties: 'By intermittent or continuous injection of the contact material accumulation layer, it will reside and accumulate in the Contact material stack 2 and field micro-flocs to remove 23 201000409. If the request item ^^" is set in the contact material stacking groove ^, ^, especially in the embodiment of the request item 12, the water passing speed of the empty tower in the contact material stacking tank is set at 3 Gm/h or more, and the residence time is Set in more than Μ minutes, in this case, the reduction of the microfloc diameter and the reduction of the number of microflocs at the end of the filtration step can be achieved simultaneously, and the average diameter can be greatly reduced at 3 〇# The number of microflocs above m contributes to the reduction in turbidity of the filtered water. The embodiment of claim 13 is characterized in that the conventional method of the low-speed stirring step is used as the flocculation step, and the value of the low-speed stirring strength is 〇8 (when the stirring coefficient is c, the area of the stirring wing is set ( V), (4) The peripheral speed of the wing is set to v (m/see), the dynamic viscosity coefficient is set to r (m2/sec), and the volume (capacity) of the stirring tank is set to v (m3) by [Math 4]
所表不之數值)設在2〇sec-i以上,低速攪拌時間之Ts 值設在5分鐘以上,藉由既存絮凝體與微絮凝體之接觸而 進行絮凝體化。 具體之構成’如圖4所示,於3個區塊ι〇1、1〇2、ι〇3 之咼速攪拌槽ίο後,為了形成絮凝體,而於4個區塊191、 192、193、194中的3個區塊192 ' 193、194設置低速攪拌 機20,從而於上述3個區塊192、193、194内實現絮凝體 24 201000409 化’當經過最後之區塊194€,流人具有傾斜裝置8及澄 清區7之沈殿池21,之後進行過遽(另,雖然於最初之區 棟m設置有第!接觸材料堆積槽12,但設置該接觸材料 堆積槽並非必需之要件)。 於採用有低速援授拌機20之傳統方式中,在先前技術 之情況下’於比起請求項3之實施形態之str值之4 〇更 高的凝聚集塊物殘留量之下,亦將上述〇s值設定為20sec-] 左右之較小數值’ ’而以此種先前技術所進行之集塊化處理 方法’絮凝體形成槽19中之絮凝體’會在低密度之狀態下 變大(粗粒化),方面,因搜拌強度較低,碰撞頻率 減小,因此並無法避免會產生尚未沈澱分離之大量的微絮 凝體殘留量。 $ 對此,如請求項13之實施形態,當將低速㈣強度g 值及低速授拌時間Ts值以上述方式設定時,可提高微絮凝 體彼此之碰撞頻率,並且,有效地實現微絮凝體對既存絮 凝體之接觸,藉此可降低直徑在^心以下之微絮凝體殘 留量,並且將微絮凝體集塊化(凝集化)&直㈣3〇 “ 以上之狀態,藉此可有助於形成可進行沈澱分離之狀態。 請求項Μ之實施形態,其特徵在於:係採用污泥浮居 方式作為絮凝體化步驟,且使污泥浮層6之高度在5心 上、以下’其中上述污泥浮層方式係藉由堆積於污泥 吁層6内之母絮凝體群與微絮凝體之接觸,來實現絮凝體 化。 具體而言,如圖i、圖2所示,於設置有污泥浮“之 25 201000409 污泥浮層槽5内,實現了微絮凝體之絮凝體化,而藉由請 求項1〜請求項7、及請求項9〜12之實施形態之微絮凝體 化步驟,可達成微絮凝體直徑之增大及微絮凝體數量之減 少化(實際上大多情況下發現,直徑在3 〇//m以下之微絮 凝體之減少化及因此種減少化而使直徑在3〇 # m以上之微 絮凝體之增大),據此可減小污泥浮層槽5之容量。 即,於先前技術中,流入污泥浮層槽5中之微絮凝體 之數3:(尤其疋直徑在3.下之微絮凝體之數量)較 多,因此 >可泥浮層6之高度通常需要設為2〇〇Cm〜 3〇〇cm, 相對於此,基於上述各請求項之實施形態之請求項Μ的實 施形態中,可於該高度設為5〇cm〜 2〇〇cm之範圍進行絮凝 體化。 並且,由於到達污泥浮層6之微絮凝體為細粒化、高 密度化,故基於微絮凝體之堆積之母絮凝體亦可達到細粒 化、高密度。 進而,由於沈澱水3中所殘留之微絮凝體為細粒化、 问密度,故可達成因過濾水中所殘留之直徑在3.0 // m以上 之微絮凝體流出量的減少化而使清洗頻率(次數)之降低 化及可防止因過濾池的堵塞所造成之洗淨功能上的障 礙,並且可藉由上述之母絮凝體的細粒化、高密度化,而 達成所產生之污泥之濃縮、脫水性的提高。 以下’根據具體資料對各實施例進行說明。 (實施例1 ) 如圖1所示,採用3個區塊101、1〇2、1〇3之高速攪 26 201000409 拌槽10及沈澱池21之後,將各高速攪拌槽10之攪拌強度 之GR值設為1250s·1,攪拌時間之TR值設為7.3分鐘,將 第1凝集劑注入步驟之注入率設為1 8.9mg/L,於此條件下, 在進行高速攪拌之後,藉由設置為2段之安裝間距為1 0mm 之傾斜板之有無,對將第2凝集劑注入步驟之注入率設為 Omg/L、9.44mg/L及1 8.9mg/L此3個條件進行比較。 其結果如表1之記載所示(其中,上側之表中,上段 側之數值表示設置有絮凝體形成用傾斜板8之情況,下段 側之數值則表示未設置絮凝體形成用傾斜板8之情況,下 側之表係表示根據各PACB之注入率,關於24小時處理後 之母絮凝體之性狀的各項目之資料)。 [表1] PACb 0.5-1.0 1.0—3.0 3.0-7.0 7.0以上 濁度 (度) 注入率 μιη fim (個/mL) βτη 仁m 濁度之比率 (mg/L) (個/mL) (個/mL) (個/mL) 0 22369 1742 355 77 0.040 1/5.3 20430 1954 808 703 0.211 9.44 11978 908 150 26 0.018 1/2.4 10261 725 236 135 0.044 18.9 6653 387 95 20 0.014 1/1.4 6640 338 139 46 0.020 PACb 注入率 (mg/L) 處理時間 ⑻ STR (-) 絮凝體容積濃度 (%) 固形物濃度 (mg/L) SDI值 (mg/mL) 0 24 1.18 20.2 2000 9.90 9A4 24 3.35 24.8 1624 6.55 18.9 24 5.60 27,0 1548 5.43 27 201000409 從表1之上側之表可知,未設置有傾斜裝置時之直徑 在以上的微絮凝體數量,會隨著第2凝集劑注入步 驟之無機凝集劑注入率之上升,而從7〇 3個/mL減少為1 3 5 個/mL、45個/mL,從而消除了母絮凝體之破壞,其數量降 低’而其他直徑之粒子亦同樣地,其數量大幅降低。從下 側之表可知’伴隨無機凝集劑之注入率之上升,S tr從丨.j 8 上升為3.35、5.60,一方面,使用表示母絮凝體之濃縮性之 SDI值(使用l〇〇mL之量筒,對經過3〇分鐘沈澱後之絮凝 ,令積濃度進行測量,纟出該樣品之固形物濃度後,作為 母lmL絮凝體容積中所含之固形物量(mg),根據樣品中 之固形物量(mg/ {絮凝體容積(mL ) X樣品數量}之式所 算出之巧泥密度指標)從9.90mg/mL惡化為6.55mg/mL、 5.43mg/mL。 從表1可知,未設置絮凝體形成用傾斜板8,將第2凝 集劑'主入步驟之無機凝集劑注入率設為9_44mg/L時的濁度 為0.044度’相對於此,未進行第2凝集劑注人步驟之無機 凝集劑注入而設置有傾斜裝置時的濁度,大致等於0.040 度。 P可也明即使第2凝集劑注入率為〇,藉由上述設 2個階段之安裝間距為1Qmm之絮凝體形成用傾斜板8的 置,亦可獲得與第2凝集劑注人率為9 44mg/k情況相 程度的澄清水。 當第2凝集劑注 凝體形成用傾斜极8 入率為18_9mg/L時,有無通過上述絮 之濁度的比率為1/14,並不滿足本發 28 201000409 明之基本要件,而當凝集劑之注入量超過規定量時,證明 絮凝體形成用傾斜板8所發揮之功能相對降低。 當上述注入率為l8.9mg/L時,通過絮凝體形成用傾斜 板8時之濁度為0.014,而即使當上述注入率為 時,該濁度為0.018,不僅無產生較大之差異,且當注入率 為18_9mg/L時,顯示出比未設置絮凝體形成用傾斜板8時 之濁度0.020更好的結果。 即,可證明即使將第2凝集劑注入步驟中之注入率設 為約1/2,藉由上述絮凝體形成用傾斜板8之微絮凝體、懸 浮粒子之碰撞(由與該傾斜板8内中之渦流相伴之亂流所造 成)’而能夠充分促進絮凝體化。 若對與上述表1之濁度相關之現象進行考察,則於絮 凝體化步驟中注入凝集劑而使STR上升之方法之情況下, 絮凝體一面粗粒子化,—面低密度化從而消除了絮凝體破 壞,降低沈澱水濁度。如果考慮此種結果,則雖然若提升 尚速攪拌後之STR,則可使母絮凝體破壞得以消除,但由 於表示母絮凝體之濃縮性之SDI值降低,故而母絮凝體之 破壞/肖除會伴隨母絮凝體之粗粒化、低密度化,而不利於 後續之過濾處理、污泥處理,關於此方面與先前方法幾乎 無不同。而相對於此,藉由採用上述絮凝體形成用傾斜板 8首先如表1所示,由於能夠以較高之效率將直徑在3.0 "m以上之微絮凝體加以分離,因此沈澱水濁度亦與絮凝體 破壞消除法大致相同,可實現直徑在3.〇"m以下之粒子數 " 降民結果證明無需進行第2凝集劑注入步驟之無機 29 201000409 凝集劑之注入,便可使沈澱處理最佳化。 再者,根據表1亦可知,第2凝集劑注入步驟中之注 入量,可藉由絮凝體化步驟入口之STR來控制,若考慮str 與沈澱水濁度之相關關係,則亦能夠藉由沈澱水濁度來控 制第2凝集劑注入步驟中之注入量。 (實施例2) 如圖1及圖2所示,設置3個區塊之高速授掉槽1〇, 且連接於該高速攪拌槽10而設置接觸材料堆積槽,然後針 對第1區塊、第2區塊、第3區塊,分別將各區塊中之搜 拌強度之GR值設為1500s*1、i5〇〇s-丨、booy,針對第j 區塊、第2區塊、帛3區塊,分別將攪拌時間之Tr值設為 0.96分鐘、〇_96分鐘、2.93分鐘,將低速授拌槽中之授拌 強度之Gs值設為25S“,將攪拌時間之Ts值設為Μ分鐘 然後將第1凝集劑注入步驟之注入率設為26.4mg/L,第2 凝集劑注入步驟之注入率設為〇,於此微絮凝體化之條件 下,如圖3所示,採用傳統方式作為絮凝體化步驟,並且 將絮凝體形成用傾斜板8設置於沈搬池21 t被處理水卜斤 流入之入口附近及澄清水所流出之出口附近的二個地方, 將上述入口附近之該傾斜板8之間距設為24_,並改變上 迷出口附近之該傾斜板8的間距時,果如表2所示。 30 201000409The numerical value shown in the figure is set to 2 sec-i or more, and the Ts value of the low-speed stirring time is set to 5 minutes or more, and flocculation is performed by contact of the existing floc with the micro-floc. The specific configuration 'as shown in FIG. 4, after three idle blocks ι〇1, 1〇2, ι〇3, the idling tank ίο, in order to form flocs, in four blocks 191, 192, 193 The three blocks 192 '193, 194 of 194 are provided with a low speed agitator 20, so that the flocculation 24 201000409 is realized in the above three blocks 192, 193, 194 'when passing the last block 194 €, the flow person has The slanting device 8 and the sump pool 21 of the clarification zone 7 are then smashed (although, although the first contact zone stacking groove 12 is provided in the first zone m, it is not necessary to provide the contact material stacking groove). In the conventional manner of using the low-speed assist mixer 20, in the case of the prior art, it will be lower than the agglomerated block residue of the fourth value of the str value of the embodiment of claim 3 The above 〇s value is set to a small value of about 20 sec-] and the lumping treatment method of the prior art 'flocs in the floc forming groove 19' becomes large in a low density state. (Coarse granulation), in terms of the low mixing strength and the reduction of the collision frequency, it is unavoidable that a large amount of microfloc residue which has not been precipitated and separated will be produced. In this regard, as in the embodiment of claim 13, when the low speed (four) intensity g value and the low speed mixing time Ts value are set in the above manner, the collision frequency of the microflocs can be increased, and the microfloc is effectively realized. Contact with existing flocs, thereby reducing the amount of microflocs remaining below the diameter of the core, and agglomerating the microflocs (aggregation) & straight (four) 3 〇 "the above state, which can help In a state in which sedimentation and separation can be formed. The embodiment of the present invention is characterized in that the sludge floating method is employed as a flocculation step, and the height of the sludge floating layer 6 is at 5 cents or less. The sludge floating layer method achieves flocculation by contacting the parent floc group deposited in the sludge layer 6 with the microflocs. Specifically, as shown in FIG. With the sludge floating "25 201000409 sludge floating layer tank 5, the flocculation of the microfloc is achieved, and the microflocs of the embodiment of claim 1 to claim 7 and claims 9 to 12 are realized. Step to achieve an increase in the diameter of the microflocs And the reduction in the number of microflocs (in fact, in most cases, the reduction of microflocs having a diameter of 3 〇//m or less and the reduction of the microflocs having a diameter of 3 〇# m or more were found. Increase), according to which the capacity of the sludge floating layer tank 5 can be reduced. That is, in the prior art, the number of microflocs flowing into the sludge floating layer tank 5 is 3: (especially, the number of microflocs having a diameter of 3.), and therefore, the mud floating layer 6 The height is usually set to 2 〇〇 Cm 〜 3 〇〇 cm. In contrast, in the embodiment of the request item 实施 according to the embodiment of each of the above claims, the height can be set to 5 〇 cm to 2 〇〇 cm. The range is flocculated. Further, since the microflocs reaching the sludge floating layer 6 are finely granulated and highly densified, the mother floc based on the accumulation of the microflocs can also be finely granulated and high in density. Further, since the microflocs remaining in the precipitated water 3 are finely granulated and have a density, the cleaning frequency can be reduced by reducing the amount of microflocs flowing out of the filtered water having a diameter of 3.0 // m or more. The reduction in the number of times and the prevention of the cleaning function caused by the clogging of the filter tank, and the sludge generated by the above-mentioned fine flocculation and high density of the mother floc can be achieved. Concentration and improvement of dehydration. Hereinafter, each embodiment will be described based on specific materials. (Example 1) As shown in Fig. 1, after the high-speed stirring 26 201000409 mixing tank 10 and the sedimentation tank 21 of the three blocks 101, 1〇2, and 1〇3, the stirring strength of each high-speed stirring tank 10 is GR. The value was set to 1250 s·1, the TR value of the stirring time was set to 7.3 minutes, and the injection rate of the first aggregating agent injection step was set to 1 8.9 mg/L. Under these conditions, after high-speed stirring, it was set to The presence or absence of the inclined plate having a mounting pitch of 10 mm in the second stage was compared with the three conditions of the injection rate of the second aggregating agent injection step of Omg/L, 9.44 mg/L, and 1 8.9 mg/L. The results are shown in Table 1. (In the upper table, the value on the upper side indicates the case where the inclined plate 8 for floc formation is provided, and the value on the lower side indicates that the inclined plate 8 for floc formation is not provided. In the case, the lower side shows the data of each item regarding the properties of the parent floc after 24 hours of treatment according to the injection rate of each PACB. [Table 1] PACb 0.5-1.0 1.0-3.0 3.0-7.0 7.0 or more turbidity (degrees) Injection rate μιη fim (pieces/mL) βτη ratio of kernels turbidity (mg/L) (units/mL) mL) (pieces/mL) 0 22369 1742 355 77 0.040 1/5.3 20430 1954 808 703 0.211 9.44 11978 908 150 26 0.018 1/2.4 10261 725 236 135 0.044 18.9 6653 387 95 20 0.014 1/1.4 6640 338 139 46 0.020 PACb Injection rate (mg/L) Treatment time (8) STR (-) Floc volume concentration (%) Solid concentration (mg/L) SDI value (mg/mL) 0 24 1.18 20.2 2000 9.90 9A4 24 3.35 24.8 1624 6.55 18.9 24 5.60 27,0 1548 5.43 27 201000409 It can be seen from the table on the upper side of Table 1 that the number of microflocs having a diameter above that is not provided with the tilting device increases with the injection rate of the inorganic aggregating agent in the second aggregating agent injection step. From 7〇3/mL to 135/mL and 45/mL, the destruction of the mother floe is eliminated, and the number thereof is reduced, and the particles of other diameters are similarly reduced in number. As can be seen from the lower table, the increase in the injection rate of the inorganic aggregating agent increases the S tr from 丨.j 8 to 3.35 and 5.60. On the other hand, the SDI value indicating the concentration of the mother floe is used (using l〇〇mL The measuring cylinder, after flocculation after 3 minutes of precipitation, the accumulated concentration is measured, and the solid content of the sample is taken out as the solid content (mg) contained in the volume of the parent lmL, according to the solid form in the sample. The amount of material (mg/{floc volume (mL) X sample number} calculated by the formula) was deteriorated from 9.90 mg/mL to 6.55 mg/mL, 5.43 mg/mL. From Table 1, it is known that flocculation is not provided. In the body forming inclined plate 8, the turbidity when the inorganic aggregating agent injection rate of the second aggregating agent 'priming step is 9 to 44 mg/L is 0.044 degrees'. In contrast, the inorganic agent in which the second aggregating agent is injected is not performed. The turbidity when the agglutinating agent is injected and the tilting device is provided is substantially equal to 0.040 degrees. P can also be used to form the floc forming slope by the above-described two-stage mounting pitch of 1Qmm even if the second aggregating agent injection rate is 〇. The plate 8 can also be obtained with the second agglutinating agent injection rate of 9 44m The clarified water of the g/k case phase. When the second aggregating agent is formed with an inclined pole 8 input ratio of 18_9 mg/L, the ratio of the turbidity of the floc is 1/14, which does not satisfy the present invention. 28 201000409 The basic requirements are as follows. When the amount of the aggregating agent is more than a predetermined amount, the function of the inclined plate 8 for floc formation is relatively reduced. When the above injection rate is 18.9 mg/L, it is formed by floc formation. The turbidity when the plate 8 was inclined was 0.014, and even when the above injection rate was used, the turbidity was 0.018, which not only did not cause a large difference, but when the injection rate was 18_9 mg/L, it showed a ratio of flocculation. The turbidity of the slanting plate 8 is more preferably 0.020. That is, it can be confirmed that even if the injection rate in the second aggregating agent injection step is about 1/2, the slanting plate 8 for forming the floc is fine. The flocculation and the collision of the suspended particles (caused by the turbulent flow accompanying the eddy current in the inclined plate 8) can sufficiently promote the flocculation. If the phenomenon related to the turbidity of Table 1 above is examined, Injecting a coagulant into the flocculation step to make the STR In the case of the ascending method, the floc is coarsely granulated on one side, and the surface is low in density, thereby eliminating flocculation damage and reducing the turbidity of the precipitated water. If such a result is considered, although the STR after the agitation is increased, The mother floc destruction can be eliminated, but since the SDI value indicating the concentration of the mother floe is lowered, the destruction/shadow removal of the parent floc is accompanied by the coarse granulation and low density of the parent floc, which is unfavorable for subsequent The filtration treatment and the sludge treatment are almost the same as the previous method in this respect. On the other hand, by using the above-described inclined plate 8 for floc formation, as shown in Table 1, the diameter can be made with higher efficiency. The micro-flocs above 3.0 "m are separated, so the turbidity of the precipitated water is also substantially the same as the method of eliminating the flocculation damage, and the number of particles having a diameter of 3.〇"m can be achieved" The inorganic solution of the second aggregating agent injection step 29 201000409 The injection of the aggregating agent optimizes the precipitation treatment. Furthermore, according to Table 1, it is also known that the amount of injection in the second aggregating agent injection step can be controlled by the STR of the inlet of the flocculation step, and if the correlation between str and the turbidity of the precipitated water is considered, The turbidity of the precipitated water is used to control the amount of injection in the second aggregating agent injection step. (Example 2) As shown in Fig. 1 and Fig. 2, a high-speed transfer tank 1〇 of three blocks is provided, and a contact material accumulation tank is provided in the high-speed stirring tank 10, and then the first block and the first block are provided. In Block 2 and Block 3, the GR values of the search intensity in each block are set to 1500s*1, i5〇〇s-丨, booy, for the jth block, the second block, and the third block. In the block, the Tr value of the stirring time is set to 0.96 minutes, 〇_96 minutes, and 2.93 minutes, and the Gs value of the mixing strength in the low-speed mixing tank is set to 25S", and the Ts value of the stirring time is set to Μ. In the minute, the injection rate of the first aggregating agent injecting step is set to 26.4 mg/L, and the injection rate of the second aggregating agent injecting step is set to 〇, and under the condition of microflocculation, as shown in FIG. The method is a flocculation step, and the inclined plate 8 for floc formation is disposed in two places near the inlet of the sinking tank 21 t where the treated water is poured into the inlet and the outlet where the clarified water flows out, and the vicinity of the inlet is The distance between the inclined plates 8 is set to 24 mm, and the pitch of the inclined plate 8 near the upper exit is changed as shown in Table 2. 0 201000409
根據表2可知,絮凝體形成用傾斜板8之間距越小, 則被處理水1之通過前與通過後的濁度之比率越小,進入 絮凝體形成用傾斜板8時,微絮凝體及懸浮粒子相互碰撞 而形成絮凝體,從而可得知沈澱池21中沈澱之機率上升。 於間距為48mm之情況下,藉由通過前後,濁度減少了 1/1.3左右,其滿足作為本發明之基本要件之4/5以下的要 件’但減少之程度並不需要很大。 出現a亥結果之原因在於,於上述入口附近,藉由間距 寬度為24mm之絮凝體形成用傾斜板8(上述間距寬度滿足 本發明之絮凝體化之最後階段中所設置之絮凝體形成用傾 斜板之間距寬度的數值要件),可進一步促進案凝體化。 由此’除了上述表2所示之測量以外,對經過具備低 速攪拌機20之絮凝體形成槽19之第3區塊(低速攪拌槽 之第3區塊)19 3之階段的濁度進行測量,該濁度之數值為 85.4,上述表2中,未設置上述出口附近之絮凝體形成用傾 斜板8之情況下之濁度為0.098,考慮到上述情況,可知藉 由上述入口附近之絮凝體形成用傾斜板8可使濁度大幅減 少〇 31 201000409 發明之效果 於上述基本構成之本發明中,發揮絮凝體形成用傾斜 板之絮凝體形成功能,以使通過絮凝體形成用傾斜板後之 被處理水之渴度為通過前之濁度的4/5以下,但此種功能之 發揮不僅藉由將間距寬度設為5mm〜50mm,且藉由對微絮 凝體化步驟中之無機凝集劑之使用量進行限定,來加以實 現其結果’澄清水中所殘留之微絮凝體比起先前技術之 h况更微細,且更高密度化,因此可獲得優質澄清水另 、方面’可使伴隨無機凝集劑之使用的污泥發生量減少, 並且由於該減少而可使污泥處理之繁雜度降低。 [產業上之可利用性] 本發明可應用於使用無機凝集劑之污水及污泥處理產 業之所有領域。 【圖式簡單說明】 圖1 ’係表示採用污泥浮層方式之情況時的本發明之基 本概念之方塊圖。 圖2,孫志-p 货'表不採用污泥浮層方式之情況時設置接觸材料 堆積槽之實施形態的方塊圖。 圖3’係表示基於傳統方式而採用低速攪拌槽,另— 面’於沈撕,1 吧21之入口附近及出口附近此2個階段設罟知 凝體形成用猫a , 夏系 战用傾斜板之實施形態的方塊圖。 圖4,後主- A 乐表不基於傳統方式而採用低速攪拌槽之實施來 態的方塊圖。 32 201000409 圖5 ’係表示於絮凝體形成用傾斜板之間,被處理水在 該傾斜板之下端附近形成渦流,且之後形成亂流,同時向 上側"丨!_動之狀況的剖面圖。 【主要元件符號說明】 被處理水 第1凝集劑注入步驟中之無機凝集劑(第1無 機凝集劑)之第1注入位置 沈澱水 污泥浮層槽 污泥浮層 澄清區 絮凝體形成用傾斜板 高速攪拌槽 高速攪拌機 I 12 13 15 16 19 21 第1接觸材料堆積槽 第1接觸材料堆積層 第2接觸材料堆積槽 第2接觸材料堆積層 絮凝體形成槽 低速攪拌機 沈澱池 101 高速攪拌槽之第i區塊 102 高速攪拌糟之第2區塊 33 201000409 103 高速攪拌糟之第3區塊 191 低速攪拌糟之第1區塊 192 低速攪拌曹之第2區塊 193 低速攪拌槽之第3區塊 194 低速攪拌槽之第4區塊 201 第2凝集劑注入步驟中之注入位置 34According to Table 2, the smaller the distance between the inclined plates 8 for floc formation, the smaller the ratio of the turbidity before and after the passage of the treated water 1 to the sloping plate for forming the floc, the microfloc and The suspended particles collide with each other to form a floc, and it is known that the probability of precipitation in the sedimentation tank 21 rises. In the case where the pitch is 48 mm, the turbidity is reduced by about 1/1.3 by the front and the rear, which satisfies the requirements of 4/5 or less which are the basic requirements of the present invention, but the degree of reduction does not need to be large. The reason for the occurrence of the a-Hay is that the inclined plate 8 for floc formation is formed by the floc width of 24 mm in the vicinity of the above-mentioned inlet (the above-mentioned pitch width satisfies the inclination for forming the floc formed in the final stage of the flocculation of the present invention) The numerical requirements of the width between the plates can further promote the coagulation. Thus, in addition to the measurement shown in Table 2 above, the turbidity of the third block (the third block of the low-speed stirring tank) 193 having the floc forming groove 19 of the low-speed agitator 20 is measured, The value of the turbidity is 85.4. In the above Table 2, the turbidity of the floc-forming inclined plate 8 in the vicinity of the outlet is not set to 0.098. In view of the above, it is understood that the floc is formed by the vicinity of the inlet. The slanting plate 8 can greatly reduce the turbidity. 201031 201000409 OBJECTS OF THE INVENTION In the present invention having the above-described basic configuration, the floc formation function of the inclined plate for forming a floc is exerted so that the inclined plate for forming the floc is formed The thirst of the treated water is 4/5 or less of the turbidity before the passage, but this function is exerted not only by setting the pitch width to 5 mm to 50 mm but also by the inorganic aggregating agent in the microflocculation step. The amount of use is limited to achieve the result 'clearing the microflocs remaining in the water is finer than the prior art h, and the density is higher, so that high quality clarified water can be obtained. Generation amount of sludge with an inorganic coagulant used in the reduction, and since this can reduce the complexity of the reduction of sludge treatment. [Industrial Applicability] The present invention is applicable to all fields of sewage and sludge treatment industries using inorganic aggregating agents. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1' is a block diagram showing the basic concept of the present invention in the case of using a sludge floating layer method. Fig. 2 is a block diagram showing the embodiment of the stacking tank when the Sun Zhi-p goods' table is not in the form of a sludge floating layer. Fig. 3' shows that the low-speed agitation tank is used based on the conventional method, and the other side is set at the vicinity of the entrance of the bar 21 and the vicinity of the exit. A block diagram of an embodiment of the board. In Fig. 4, the rear main-A music table is not based on the conventional method and uses a block diagram of the implementation of the low-speed stirring tank. 32 201000409 Fig. 5 ' is shown between the inclined plates for forming flocs, the treated water forms a vortex near the lower end of the inclined plate, and then forms a turbulent flow, and at the same time, the upper side is a cross-sectional view of the condition . [Description of main component symbols] The first injection position of the inorganic aggregating agent (first inorganic aggregating agent) in the first agglutinating agent injection step of the treated water, the sedimentation water sludge floating layer tank, the sludge floating layer, the clarification area, the formation of the floc Plate high speed agitation tank high speed mixer I 12 13 15 16 19 21 1st contact material accumulation tank 1st contact material accumulation layer 2nd contact material accumulation tank 2nd contact material accumulation layer floc formation tank low speed mixer sedimentation tank 101 high speed stirring tank Block i 102 Block 2 of high-speed agitation tanks 201000409 103 Block 3 of high-speed agitation tanks Section 1 of low-speed agitation tanks 192 Low-speed mixing Cao's second block 193 Zone 3 of low-speed agitation tank Block 194, Block 4 of the low speed agitation tank, injection location 34 in the second aggregating agent injection step
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