TW200949440A - Color filter and photo-sensitive coloring composition therefor - Google Patents

Abstract

The photo-sensitive coloring composition of the present invention includes a resin, a coloring agent, a photo-sensitive initiator, monomers and a solvent. The resin is a vinyl polymer, and is constituted of a constituting unit (a) with the following general formula (1), a constituting unit (b) containing a hydroxyl group, and a constituting unit (c) besides the constituting units (a) and (b). general formula (1) where R1is a hydrogen atom or a methyl group, R2 is a C2 or C3 alkylene group, R3 is a C1-C20 alkyl group containing the hydrogen atoms or phenyl ring, and 1 is an integer of 1 to 15.

Description

[Technical Field] [0001] The present invention relates to a color filter used for a color liquid crystal display device, a color image pickup device element, and the like, and a photosensitive coloring composition used for the production thereof. [Prior Art] [0002] In recent years, liquid crystal display devices have been used in television monitor applications, personal computer applications, and pulsable device applications, and as a color light-receiving film system for which a pigment-dispersed color filter is widely used. . In the production of a pigment-dispersed color filter, a photo-photographing method is widely used, which is a coloring composition obtained by dispersing a pigment in a resin (acrylic resin or the like) using a dispersing agent, a solvent, or the like, and adding a light-concentrating property. The monocalinic polymerization initiator is a photosensitive coloring composition in which a convex portion is formed on a transparent support such as a glass substrate, and a colored coating film such as a colored layer or a light shielding layer is formed and patterned. The patterned enamel is post-baked at a high temperature of 200 C or higher in order to impart tolerance to the subsequent steps.

In addition, the generalization of the liquid crystal display device product is progressing, and the cost of the product is expected to be greatly reduced. With this, the cost reduction of the color film has become a problem in recent years. Recently, attempts have been made to reproduce and reuse it. (The following is marked as "redo") A glass substrate containing a colored coating film after baking after the failure, so as to save the waste of the glass substrate having the largest proportion of the material cost of the color filter. It is one of the most effective and simple means of reducing the cost. (The following is an efficient rework, which is marked as "reworkability is good".) As a means of redoing, there is a heavy-duty liquid, which is colored from a glass substrate. The light-transfer sheet is patterned and then subjected to a color coating film, and is again a method of coating the coloring composition of the glass substrate (4). 098114711 Form number surface* 4 Ι/Λ 74 ^ n 200949440 After baking The coating film on the glass substrate has high heat resistance and solvent resistance. In order to redo, it is generally necessary to use a high-temperature, high-concentration strong alkali solution. Not only for the purpose of redoing, the film is peeled off from the glass substrate. The colored coating film of the color filter after baking after the case is also clogging the screen of the redo liquid which is recycled through the screen for capturing the peeling sheet, so that the peeling sheet is required to be finely crushed. Ο 098 098114711 Patent The present invention discloses a photosensitive coloring composition containing a resin which contains a carboxyl group but does not contain a hydroxyl group. The use of the resin makes the above-mentioned reworkability good. However, the photosensitive coloring composition containing the resin is excellent. The dispersion stability of the pigment is low, and the long-term storage stability is insufficient. Patent Document 2 discloses a photosensitive coloring composition using a resin for improving the photosensitivity of the photosensitive material in the side chain or The terminal comprises an alkylene group having a substituted benzene ring. The composition is excellent in adsorption/orientation to the surface of the pigment due to the effect of the benzene ring; and exhibits excellent pigment dispersion L, including the resin. When the photosensitive coloring thickening is baked after patterning, due to the influence of the heat hardening reaction, the coating film of the color filter after the patterning is not only not Or even if it is peeled off, the _ film becomes a large piece and exists in the redo-liquid towel, so it is a bad redoing of the sakis. Even if the mixing is as good as the above, the dispersion stability of the pigment is not good. In the case of a photosensitive coloring composition obtained by a resin and a resin having good dispersion stability and poor reworkability, reworkability is still insufficient. [Prior Art Document] [Patent Document 11 Japanese Patent Laid-Open No. 10-171119 [Patent Document 2] JP-A-2004-101728, No. 0983216981-0 Form No. A〇m Page 5 of 74 pages 200949440 [Invention] The excellent reworkability and long-term preservation are not impaired. Photosensitive property of substrate performance such as developability (problem to be solved by the invention) An object of the present invention is to provide a color filter in which black matrix is established while achieving stability. (Technical means for solving the problem) The coloring and forming "and the finely formed filter" section, and/or the inclusion of the preceding item are solved by the following coloring composition, the characteristics of the photosensitive coloring composition It is a resin containing a resin, a coloring agent photopolymerization initiator, a polymerizable single vessel, and a solvent; the resin is a vinyl-based polymer: the constituent unit represented by the following general formula (1) (a) It consists of the constituent unit (b) of the rebel group and the constituent unit (c) other than the constituent units (1) and (b); general formula (1):

The alkylene group, R3 is an alkyl group which has a hydrogen atom or a benzene ring and has a carbon number of 〜2〇, and is an integer of 1 to 15. Further, according to a preferred aspect of the present invention, the constituent unit (b) is a constituent unit (bl) and/or a constituent unit (b2), and the constituent unit (bl) is represented by the following general formula (2). Representation·· 098114711 Form No. A0I01 Page 6 of 74 Page 09321186981-0 200949440

[0005]

[0006] In the general formula (2), R4 is a hydrogen atom or a methyl group, and χ1 is a group represented by the general formula (3):

〇-〇^

0007 [0007] [In general formula (3), R5 is an alkylene group having 2 to 12 carbon atoms, and m is an integer of 1 or 2] 'Y1 is a general formula (4) [0008] ί*1 - λ r* i: .'jr τ\

[0009] In the general formula (4), R6 is an alkylene group having 2 to 2 carbon atoms in the main chain, a cycloalkylene group having 6 to 8 ring carbon atoms, or 6~ 14 arylene groups of a ring carbon atom, η is an integer of 〇 or 1]); The constituent unit (b2) is a constituent unit represented by the general formula (5) (098114711 Form No. A0101 Page 7 of 74 Page 98321281981-0 200949440 d) An unsaturated monovalent acid is added, which is obtained by adding a polyvalent acid anhydrate to the generated hydroxyl group; general formula (5) + CH 2 - ( bucket (5) C-O-R8

II 〇 [0010] (In general formula (5), R7 is a hydrogen atom or a methyl group, and R8 is a glycidyl group, a methyl glycidyl group, a 3,2-epoxypropoxyethyl group. , 3,4-epoxycyclohexyl, 3,4-epoxybutyl or 4,5-epoxy ketone). Further, as a preferred aspect of the invention, the aforementioned constituent unit (c) does not have a hydroxyl group. Further, in a preferred aspect of the present invention, the resin is constituting the unit (a) precursor (a') 1 to 35 wt%, and the constituent unit (b) precursor (b) 10~ 90% by weight and a vinyl-based polymer obtained by copolymerizing 1 to 75% by weight of the precursor (c') of the above-mentioned constituent unit (c). Further, in a preferred aspect of the present invention, the resin is used in a unit (a) before the constituent (a) is 1 to 35 wt%, and the aforementioned constituent unit (d) is a precursor (d'). 4 to 75% by weight and the above-mentioned constituent unit (c), the precursor (c') 1 to 75% by weight of a vinyl polymer obtained by copolymerization, after adding an unsaturated monovalent acid, in the form of a hydroxyl group 098114711 No. A0101 Page 8 of 74 Page 0983216981-0 200949440 A resin obtained by adding a polyvalent acid anhydride. Further, as a preferred aspect of the present invention, the precursor (a') of the constituent unit (a) comprises ethylene oxide and/or propylene oxide (mercapto) acrylic acid of p-cumylphenol. vinegar. Further, as a preferred aspect of the invention, the precursor (c') of the aforementioned constituent unit (c) contains an alkyl (meth)acrylate. Further, as a preferred aspect of the present invention, the precursor (C') of the constituent unit (C) comprises a benzyl (meth) acrylate and/or a bicyclopenta(meth) acrylate, and/or a bicyclic ring. Pentenyl (mercapto) acrylate® and/or cyclopentaethoxyethyl (decyl) acrylate. Further, the present invention provides a color filter comprising: a filter segment-and/or a black matrix formed from the photosensitive coloring composition of the present invention (effect of the invention) by use The photosensitive coloring composition excellent in reworkability of the present invention can eliminate the waste of the glass substrate in the manufacture of the color filter, and obtain a color filter of low price. [Embodiment] The photosensitive coloring composition of the present invention contains a resin, a colorant, a photopolymerization initiator, a polymerizable monomer, and a solvent. Each component is described in detail below. In addition, in the scope of this specification and the patent application, the terms "(meth)acrylic acid", "(alkyl) acrylate" and "(meth) propylene oxime" mean "acrylic acid and / or methacrylic acid" respectively. , "Acrylate and / or methacrylate" and "propylene oxime and / or methacryloxy". Similarly, the term "(meth)acrylamide" is translated as "acrylamide and/or (mercapto) acrylamide". 098114711 Form No. A0101 Page 9 of 74 0983216981-0 200949440 <Resin> The resin-based vinyl polymer contained in the photosensitive coloring composition of the present invention is represented by the following general formula (1) *The constituent unit (a),

It consists of a constituent unit (b) containing a protective base and a constituent unit (c) other than the constituent units (a) and (b). The constituent unit (a) functions as a solvent affinity portion, and the constituent unit (b) functions as a pigment adsorbing portion and a base-favorable portion, and then the constituent unit (c) is only a constituent unit (a). And the constituent unit (b) cannot be achieved, in order to obtain a constituent unit necessary for the physical properties of the colored coating film. General formula (1):

[0012]

In the general formula (1), 'R1 is a hydrogen atom or a methyl group, R2 is an alkylene group having 2 or 3 carbon atoms, and R3 is an alkyl group which may also contain a hydrogen atom or a carbon number of benzene ring 丨~2〇, 1 It is an integer from 1 to 15. ^ In the present invention, a resin which conforms to the properties of the present invention is used. (The η dispersibility can prevent the pigment condensed pigment as a coloring agent in the coloring composition from being maintained in a finely dispersed state for a long period of time. (2) The developability at the time of development can only remove the unexposed portion by the (experimental) development sword. (3)Reworkability 098114711 Form·No.Α0101 Page 10/74 Page 〇 983216981~〇200949440 Can be removed by the (strong alkaline) redo liquid after baking, the peeling of the colored coating film In order to fully comply with this type of characteristics, the focus is on the resin design so that the constituent units (a), the constituent units (b), and the constituent units (C) coexist in a balanced manner, and the pigment as a coloring agent is maintained. After the dispersion stability, (alkaline) only permeates the unexposed portion, and only the unexposed portion is swollen, reacts with the carboxyl group of the unexposed portion, and a part thereof is solubilized and removed, and when it is reworked, the (high-precision) redo liquid The exposed portion is immersed, and the exposed portion is swollen, reacted with a carboxyl group, and a part thereof is solubilized and removed. ❹ And 'in terms of production efficiency' is considered to be a constituent unit (a), a constituent unit (b), and a constituent unit (c). Balanced It is designed to remove the coating film as much as possible to flow out to the developer and the redo liquid..: Explain the constituent unit represented by the general formula (1),). The constituent unit (a) is a π-electron of a side-turning loop and an alkylene moiety of a side chain of a moderate length, and functions effectively as a sulphur peak and a moiety. The side chain benzene ring is aligned with the pigment as a coloring agent, thereby promoting the adsorption of the resin to the pigment, and further suppressing the effect of the pigment coagulation. Therefore, the dispersion stability of the pigment having the surface treatment of the wax which constitutes the unit (a) can be maintained. Further, the constituent unit (a) functions as a site for adsorbing a pigment surface when the pigment is dispersed, and if the constituent unit (b) having a carboxyl group reacts with a base to become an alkali-soluble portion during development or redoing, The 'structural unit (a) functions as a non-alkali-soluble portion, so that the portion to be removed has a good balance between hydrophilicity and hydrophobicity, and is likely to be in the form of a fine sheet.

In the general formula (1), the carbon number of the alkyl group of R3 is! ~? 〇, more preferably i — M 098114711 Form No. A0101 Page 11 of 74 • 0983216981-0 200949440 . The alkyl group includes not only a linear alkyl group but also a branched alkyl group and an alkyl group having a benzene ring as a substituent. When the number of carbon atoms of the alkyl group of R3 is from 1 to 10, the base becomes an obstacle, and the resin is inhibited from approaching each other, and the adsorption/alignment of the pigment is promoted, but the right carbon number is more than 10, and the effect of the steric barrier of the alkyl group becomes high. It also hinders the tendency of the y ring to adsorb/align the pigment. This tendency is remarkable as the rhyme of the burning base of R3 becomes longer. If the carbon number exceeds 20, the adsorption/alignment of the benzene ring is extremely lowered. Examples of the hospital base represented by # and having a benzene ring include a benzyl group and a phenyl group (iso)propyl group. Due to the increase of the side chain benzene ring (10), the solvent affinity and pigment alignment are improved, not only as the dispersibility of the pigment of (4) is improved, but also the complexity and reworkability are improved. As a constituent unit U), (a,) can be exemplified by cumbersome Ethylene Ethylene (E) denatured (methyl) propylene vinegar, E0 or Ethylene propylene ( P0) Denatured (Kaki, Dim τ soil) acrylate, nonyl phenolic E0 denatured (methyl) acrylic acid _, 壬美 lean in + D octa sulphate ΡΟ ΡΟ denatured (meth) acrylate Wait. The precursor (a,) π i ) is not limited to the above, exemplified, and may be used alone or in combination of two or more. Among the precursors U,), EO^PO denaturation of cumylbenzene (A|, The acrylate has not only the effect of the π-electron of the above benzene ring but also the complex stereoscopic effect, and it is most suitable for the pigment to form a good adsorption/alignment surface. Next, the constituent unit (b) will be described. The component (b) having a carboxyl group functions as a pigment adsorbing group when it is used as a pigment adsorbing group, and functions as a soluble group during development to function as a redo-based base. As a component of the exposure, the constituent unit of the carboxyl group is preliminarily soluble. (b) The form number A0101 098114711 -....-...~(b) can be exemplified as (200949440 methyl)acrylic acid, crotonic acid, α- A compound containing a carboxyl group and having an ethylenic unsaturated double bond, such as an unsaturated dicarboxylic acid such as alginoic acid, maleic acid, anhydrous maleic acid or fumarine or an anhydride thereof. The constituent unit (b) having a carboxyl group is particularly preferably a constituent unit (bl) represented by the following general formula (2), and/or a constituent unit (d) represented by the following general formula (5), An unsaturated monovalent acid obtained by adding a polyvalent acid anhydride to the produced hydroxyl group (b2). The constituent unit (bl) is obtained by copolymerizing its precursor (bl') with other precursors; the constituent unit (d) is obtained by copolymerizing its precursor (d') with other precursors. obtain. General formula (2):

Ch2——C—X1- 〇 (In general formula (2), R4 is a hydrogen atom or a fluorenyl group, and X1 is a group represented by the general formula (3):

[In general formula (3), R5 is an alkylene group having 2 to 12 carbon atoms, and m is 1 or 2 of 098,114,711. Form No. A0101, page 13 of 74,0983216981-0 200949440 Integer], Y1 is a general The base represented by the formula (4): [0014]

[In general formula (4), R6 is a sub-chain containing 2 to 2 carbon atoms in the main chain (4)

An alkyl group, a cycloalkylene group having 6 to 8 ring carbon atoms, or an arylene group having 6 to 14 ring carbon atoms, and 11 is an integer of 〇 or 1]). General formula (5) ... one,

(5)

II

〇—R 8

(In general formula (5), R7 is a hydrogen source or a methyl group, and R8 is a glycidyl group, a methyl glycidyl group, a 3,2-epoxypropoxyethyl group, 3, 4 - Epoxycyclohexyl, 3,4-epoxybutyl or 4,5-epoxybenzyl). In the general formula (3), specific examples of the alkylene group having 2 to 12 carbon atoms represented by R5 include, for example, -ch2 - ch2-, -ί(CH)-, -CH(CV-CH2-, —(CH2)r, _CIL —ίΗ 098114711 -ch2-,- (CV2- Form No. A0101 ch2 —ch2-ch (CH3)-, — ' -CH (CHJ -CH -CH -

ch2-Ch2-C CH (Page 14 of 74 pp 9823216981-0 200949440 ❹ 3) -CH2-CH2-, -CH (ch2ch2ch3) -CH2-CH2-, -CH (CH3) -CH2-CH2 -CH2- --CH (CH2CH3) - CH2-CH2-ch2---CH (ch2ch2ch3) -ch2-ch2-CH2---CH[ (CH_) ,CH ]- (CHJ -etc. In general formula (4), R6 a linear portion of a main chain (that is, a carbonyl carbon atom in the formula (4) bonded to a plurality of carbon atoms in the formula (2)) contains an alkylene group having 2 to 20 carbon atoms and has 6 to 8 a cyclic ring of a ring carbon atom or an arylene group having 6 to 14 ring carbon atoms. Here, the alkylene group having 2 to 20 carbon atoms in the primary bond may be used as a side chain substituent. Alkyl, alkenyl, cycloalkyl, cycloalkenyl, dialkyl, alkynyl, alkynylphenyl, alkynyl aryl, aromatic substituent, nitro, halogen, etc.; having 6 to 8 ring carbons a ring alkylene group of an atom or a sub-base group having 6 to 14 ring carbon atoms as a substituent group, or may have an alkyl group, a ring group, a cycloalkenyl group, a dialkyl group, an alkynyl group. , alkynylphenyl, alkynyl aryl, aromatic substituent, nitro, tooth element, etc. For the main chain, there are 2 to 20 carbon atomic sub-units, for example, -CH2-CH2-, -ch2-ch2Lch2-', ::ch2-ch (CH3) CH2-CH2-CH2-C% ^-^ -tH2-CH2-CH (CH3)-, -ch2-ch[ (CH2) 3ch3]---ch2-ch[ (CH: )7CH3]-, -ch "ch[ (ch2) 9ch3]- ,—ch“ch[ (cV uch3]---ch2-ch[ (ch2) i3ch3]___ CH2-CH[ (CH2) 15CH3]- ^ -CH2-CH[ (CH2) 17ch ] — etc. in the main chain The alkylene group having 2 to 20 carbon atoms preferably has a total of from j to 20 carbon atoms. 098114711 The cycloalkylene group having 6 to 8 ring carbon atoms may, for example, be represented by the following formula (6) to ( 9) The cycloalkylene group shown by the formula, wherein the cycloalkylene group represented by the formula ~ (9 Form No. A0101, page 15 / page 74, 98,321, 698, 698, 0, 2009, 494, 40) may also have the above alkyl group, alkenyl group, a cycloalkyl group, a cycloalkenyl 'dialkyl group, an alkynyl group, an alkynylphenyl group, an alkynyl aryl group, an aromatic substituent group, a nitro group, a halogen element or the like as a substituent group. As a group having 6 to 14 ring carbon atoms The arylene group may, for example, be an arylene group represented by the following formula (1〇) to (13), and the arylene groups represented by the formulas (1〇) to (13) may also have an arylene group, respectively. Burn group, alkenyl group, cycloalkyl group burning, cycloalkenyl, dialkylamino, an alkynyl group, an alkynyl group, phenyl, an alkynyl group an aromatic group, substituted aromatic group, a nitro group, a halogen element or the like as a substituent. 098114711 Form No. A0101

Page 16 of 74 0983216981-0 200949440 [0015] Equation (6):

Equation (8):

❹

Formula (10): Formula (1 1): Formula (1 2): ❹ Formula (1 3):

From the viewpoint of the balance between developability and reworkability, it is suitable to use a condensed acrylic acid dimer [R5: —CH^ — CH^—] as a constituent unit (bl') having a carboxyl group. Retinoethyl (mercapto) acrylic acid 098114711 Form No. A0101 Page 17 of 74 098321698 Bu 0 [0016] 200949440 MR .-CH2-CH2-], 2-(Methyl) propylene oxyethyl Spearic acid [R5: -CH2-CH2-, R6: _CH2 - CH2-], 2_(methyl) propylene oxiranyl succinic acid [R5: _CIj2 - c% -, r6: polystyryl], 2 —(fluorenyl) propylene oxiranyl ethyl hexahydrophthalic acid [r5 : a CH 2 —, R 6 : cyclohexenyl], 2 — (fluorenyl) propylene oxime propyl hydride acid [R5 : -CH 2 — ch (CH3) _, R6 : '

2-(fluorenyl) propylene oxime benzoic acid [R5: —CH _CH (CH )-, R6 : polyphenyl], 2-(methyl) propylene oxypropyl hexaphthalic acid [R5 : -CH2_ch (b), r6: polyphenyl], polyethylene oxide modified succinic acid (meth) acrylate [R5: -CH-CH-, 6 2 2 R · - CH2 - Qiu 2] , ω-carboxy-polycaprolactam-denatured mono(methyl)propionic acid brewing Μ: one (CH2) 5], polyepoxy epoxidized phthalic acid (mercapto) acrylate vinegar [r5: —% —CH2 —, r6: polyphenyl] and the like. The cockroach (b) is not limited to the above exemplification, and it may be used alone or in combination of two or more. The constituent unit (b2) is obtained by adding an unsaturated monovalent acid to the precursor (d'), adding a polyvalent acid anhydrate to the generated hydroxyl group, or copolymerizing the precursor (b, ), or precuring the precursor (d). ,) Polymerization is carried out to form a constituent unit (4), and an unsaturated monovalent acid is added, and a polyvalent acid anhydride is added to the formed radical. More specifically, the precursor (d,) has an epoxy group, and the epoxy group reacts with the unsaturated-valence acid (IV) to form vinegar, and forms one hydroxyl group, and the hydroxyl group and the polyvalent acid anhydrate are The carboxyl group reacts to form an ester. The constituent unit (4) represented by the general formula (5) (d) is exemplified by epoxy propyl (meth) acrylate vinegar, methyl epoxy propyl ( 098114711 methyl) propylene _, 2-glycidoxy (methyl) (tetra) acid vinegar, 3, Form No. A0101 Page 18 of 74 '0983216981-0 200949440 4 Epoxy butyl (methyl) (10) _ and 3, 4 epoxy ring Hexyl (meth) acrylate vinegar, these may be used alone or in combination of two or more. The epoxy group (meth) acrylate is preferably used in view of the reactivity with the unsaturated-valence acid in the following step. The unsaturated monovalent acid to be added to the constituent unit (4) may, for example, be (meth)propionic acid, crotonic acid, hydrazine-, or ethene-based benzoic acid or decyl (meth)acrylic acid. Tender, Oxygen, Element, Broken, Gas Replacement Zhao, etc., as a multivalent acid anhydrate for the reaction of the additional reactants, four waters of water I I hydrophthalic acid : hexahydro-anhydrous phthalic acid, anhydrous sulphur _, no yang green, etc., such as the use of two or more of them at the same time, it is possible to increase the number of carboxyl groups in the unit (b'), etc. It is necessary to use a tetrazine-free substance such as a trimellitic acid anhydride or a tetrakis(4)-dihydrate such as pyromellitic acid anhydrate, and to hydrolyze the remaining pentahydrate group.秘 The constituent unit (bl) and/or the secret of the squad (b2), for example, from the copolymer (resin) compared to the slow-acting unit of the precursor of the (mercapto) acrylic acid Main: The key is far from %, and the steric obstacle is small. Therefore, in the rework liquid (strong aqueous solution), the coating film having a bridging density of π by exposure is also excellent in compatibility, so that swelling, reaction, and dissolution proceed smoothly. Moreover, in the waste color group of the present invention, there is a s-energy group having a radical reduction reaction, even if the functional group and the constituent unit (bl) and/or the constituent unit (b2) Reaction and bridging, 098114711 Since the main chain is away from the bridging point, it does not hinder the penetration of the re-working liquid into the coating film, and the coating film can be removed smoothly. Single Number A0101 Page 19 / Total? 4 pages 0983216981-0 200949440 The functional group (c') as the constituent unit (C) is not particularly limited as long as it has a functional group reactive with a carboxyl group before the development step, and examples thereof include the following: thiol (methyl) Acrylate, ethyl (meth) acrylate, η-propyl (meth) acrylate, isopropyl (meth) acrylate, η-butyl (meth) acrylate, isobutyl (fluorenyl) ) linear or sub-components such as acrylate, t-butyl (decyl) acrylate, 2-ethylhexyl (decyl) acrylate, decyl methacrylate (meth) acrylate, and lauryl (mercapto) acrylate Dendritic alkyl (meth) acrylates; cyclohexyl (meth) acrylates, isobornyl (decyl) acrylates, and cyclic alkyl groups (fluorenyl) such as dicyclopentyl (meth) acrylate Acrylates; alkyl (meth) acrylates having an aromatic ring such as benzyl (meth) acrylate and phenyl (meth) acrylate; tetrahydroindenyl (meth) acrylate and the like Cyclopentyl acrylates; methoxy (poly) propyl Alkoxy (poly)alkylene glycol (mercapto) acrylates such as diol (mercapto) acrylate and ethoxy (poly)ethylene glycol (meth) acrylate; (mercapto) acrylic acid Bismuth, N,N-dimethyl(meth)acrylate, N,N-diethyl (meth)acrylate, N-isopropyl(meth)acrylate,diacetone (meth)acrylic acid醯 and propylene morpholine and other (methyl) acrylate phthalic acid; styrene and α-methyl styrene and other styrene; ethyl ethane mystery, π-propyl ethane mystery, isopropylethylene Mystery, η — vinyl ethers such as butyl vinyl ether and isobutyl vinyl ether; 098114711 Form No. 1010101 Page 20 of 74 0983216981-0 200949440 Fatty acid vinyls such as vinyl acetate and propionic acid; Acrylic acid, methacrylic acid a vinyl monomer having a carboxyl group other than the precursor (b,) such as itaconic acid, maleic acid, fumaric acid, and baracid; 2-hydroxyethylethyl (mercapto) acrylate 2 (or 3) - propyl propyl (meth) acrylate, 2 (or 3 or 4) monohydroxy butyl (meth) acrylate and cyclohexane a hydroxyalkyl (indenyl) acrylate such as dimercaptol (indenyl) acrylate, and an alkyl group having a hydroxyl group such as an alkyl-α-hydroxyalkyl acrylate such as ethyl-α-trans methacrylate (meth) acrylates; (poly) propylene glycol (meth) acrylate and (poly) ethylene glycol (mercapto) acrylate (poly) alkylene glycol (mercapto) acrylate; —(2_hydroxyethyl)(methyl)acrylic acid ruthenium, Ν(2-hydroxypropyl)(fluorenyl)acrylic acid ruthenium, iridium-(2-hydroxybutyl) and bismuth (meth)acrylate - (hydroxyalkyl) phosphonium (meth)acrylate, anthracene (meth)acrylate having a hydroxyl group; 2-hydroxyethyl vinyl ether, 2-(. or 3-yl vinyl ether, and

a vinyl ether having a hydroxyl group such as 2-(or 3- or 4-)hydroxybutylene ether; 2) a propyl propyl group, a 2-(or 3-) propyl group And 2-(or 3 or 4) benzylidene acetonide, etc., such as allylic ethers having a hydroxyl group via a propyl group; glycerol mono(indenyl) hydrazine, etc. having 2 Hydroxy (meth) acrylates; N,N-didecylamine ethyl (meth) acrylate, N,N-diethylamine ethyl (meth) acrylate, N, N 曱Aminopropyl propyl (mercapto) acrylic acid vinegar, N, N-diethylaminopropyl propyl (meth) acrylate vinegar, etc. 098114711 0983216981-0 Form No. A0101 Page 21 / Total 74 Page 200949440 With N, N - a dialkylamino group alkyl (mercapto) acrylate; and N,N-dimethylaminoethyl (meth) acrylate bismuth, n, n-diethylaminoethyl (fluorenyl) N,N-dioxane such as bismuth acrylate, N,N-dimethylaminopropyl (meth) acrylate, N,N-diethylaminopropyl (decyl) propionate Amino acid-based (meth)acrylic brewing, etc.; these may be used alone or in combination Two or more, but not necessarily limited to such. The constituent unit (c) is used to obtain a constituent unit necessary for the physical properties of the (4) colored coating film which cannot be achieved by the constituent unit (a) and the constituent unit (b). The constituent unit (4) should not have the secret 1 system. If the constituent unit (C) has a mercapto group, the deuterium condensation dehydration condensation reaction of the acoustic constituent unit (b) is caused by the heat treatment of the material, and as a result, the bridging density is bonded by the purpose. Going high 'reworkability is worse. From the viewpoint of film-forming property, the constituent unit U) precursor (c') should be a hospital-based (meth)acrylic acid vinegar, especially from the viewpoints of dispersibility, ampoules and coating properties. Further, it is preferably a benzyl (meth) acrylate vinegar and a 1-cyclopentyl (meth) propyl acrylate. In order to obtain the photosensitive coloring matter 098114711 of the present invention, the precursor (b,) and the precursor (c,) are co-polymerized, for the whole fore The polymerization ratio of the aforementioned precursor (a,) is preferably % by weight, more preferably 35% by weight. When the polymerization ratio of the pre-media U') is less than % by weight, the dispersing effect of the pigment as a coloring agent is lowered, and a sufficient dispersing effect cannot be obtained, and if it is more than 5 G% by weight, the hydrophobicity is increased and the sensitization is obtained. The compatibility of the other constituents in the sexually colored composition is lowered, and the developability of the sensitizing composition is lowered or occurs. Further, the monomer or light form number A0101 » ^ _ 0983216 200949440 polymerization initiator may be caused. Precipitate. A resin having a constituent unit (a) obtained by copolymerizing 1 to 35 wt% of a precursor (a), which is a balance between a ratio of constituent units (a) and constituent units (b) and constituent units (c) Good 'excellent developability and redo. In order to obtain the resin contained in the photosensitive coloring composition of the present invention, when the precursor (a'), the precursor (b,) and the precursor (c,) are copolymerized, 'for the entire precursor, the foregoing The ratio of the precursor (b') is 5 to 91% by weight, more preferably 1 to 90% by weight. When the ratio of the former prize (b') is less than 5% by weight, sufficient reaction between the developer and the regrind liquid cannot be obtained. Further, when the amount is more than 91% by weight, the amount of the slowing group in the photosensitive composition increases, and the structural viscosity is caused by hydrogen bonding, and the dispersion stability of the pigment as a coloring agent may be lowered. The resin having the precursor (b,) 1〇~90% by weight of the constituent unit (a) is the ratio of the constituent unit (a) to the constituent unit (a) and the constituent unit (c) The average board is good, and it exhibits excellent developability and reworkability. \ :·*: »jl In order to obtain the photosensitive coloring composition of the present invention, when the precursor (a,) and the precursor (br) are copolymerized, The total amount of the precursor (c,) is preferably from 1 to 80% by weight, more preferably from 1 to 75% by weight. When the ratio of the precursor (c') is less than 1% by weight, sufficient is not obtained. When the content is more than 80% by weight, the constituent unit (a) and the constituent unit (c) are small, and the pigment as a colorant cannot obtain sufficient dispersibility, developability, and reworkability. (c') 1 to 75% by weight of the resin of the constituent unit (c) obtained by copolymerization, which is the ratio of the constituent unit (a) and the constituent unit (a) and the constituent unit (b), good 098114711 form number A0101 Page 23 of 74 09932169&amp;1-0 200949440 Good, excellent developability and redo. In order to obtain this (4) field coloring (4) (10) containing the reading of the U's, the precursor U, And the precursor (c,) in the case of copolymerization, for the full precursor The polymerization ratio of the precursor (a,) is preferably from 1 to 5 (3 wt%, more preferably from 1 to 35 wt%. If the polymerization ratio of the precursor (a,) is less than one weight (four), it is used as a coloring The dispersing effect of the pigment is reduced, and the dispersion effect of the material cannot be obtained, and if it is more than 5 G weight%, the hydrophobicity is increased, and the compatibility with other constituent components in the photosensitive coloring composition is lowered, and the level is inferior. The developability of the coloring composition is lowered or the material is generated, and the step (4) may be used as a monomer or a photopolymerization initiator instead of having a composition of 35 weight (four) rows of the front correction (a,) (4) (Precursor Tree Month) 'Additional Unsaturation-Price Jun and Multivalent Acid Anhydrate: The resin obtained is the equilibrium of the ratio of its constituent units (4) to the constituent units (b2) and constituents 4 (C) It is excellent, and exhibits excellent developability and reworkability. 2. The resin obtained by the coloring composition of the present invention is obtained by copolymerizing the precursor U, the precursor, and the precursor. In the case of 'the whole pre-media, the pre-media (d') ratio is preferably 2 to 80% by weight, more preferably 4 to 75% by weight. When the ratio of the precursor $(b) is less than 2% by weight, an unsaturated-valence acid is added to the obtained copolymer (the precursor resin), and a polyvalent acid anhydride is added to the formed base. In addition, the resin of the present invention does not have sufficient effect of rework. Moreover, if it is more than 80% by weight, the amount of the carboxyl group in the photosensitive composition increases, and the structure is sticky due to hydrogen bonding, and the pigment as a coloring agent The dispersion stability is sometimes lowered. The resin form number (d) having a constituent unit (d) obtained by copolymerizing the precursor (d') 098114711 4 to 75% by weight _ 丨 ^ 24 74 H 0983: 200949440 (four) tree (5) 'Additional unsaturated-valence acid and polyvalent acid anhydrate to obtain the constituent unit (b2) 'The resin having the constituent unit (b2) is the ratio of the constituent unit (b2) and the constituent unit (a) and constituent unit ( ) A good balance of 'excellent developability and redo. In order to obtain the resin contained in the photosensitive coloring composition of the present invention, a precursor (a,) ^ „ ), a precursor (d,), and a precursor (c,) are collectively used.

If Brother's, for the whole precursor, the polymerization ratio of the aforementioned precursor (c,) is preferably from 1 to 80% by weight, more preferably from 1 to 75% by weight. » When the ratio of the precursor (C) is less than 1% by weight In addition, sufficient film material is not obtained, and the right part is more than 80% by weight, and the constituent unit (a) and the constituent unit (b2) are changed as a coloring agent, and sufficient dispersibility, developability, and reworkability cannot be obtained. . a resin having a constituent unit (e) obtained by copolymerizing a precursor (e,) 75 by weight (a precursor obtained by adding an unsaturated-tannic acid and a polyvalent acid anhydride to a precursor tree) (e) The ratio of the composition to the constituent unit (a) and the constituent unit (b2) is good. 'The development and reworkability are excellent. 分 The decomposition of the pigment as a colorant', stability and coating For the nature of the property, it is suitable as a constituent unit ru) precursor (c,) of the base (meth) acrylate vinegar and / or dicyclopentyl (meth) acrylate vinegar and / or The weight ratio of dicyclopentenyl (meth) acrylate and/or bicyclopentaoxy (meth) acrylate is preferably in the total precursor (including the unsaturated form in the case of formation of component (d) 1 to 80% by weight of the valency acid and the polyvalent acid anhydride. When the amount is less than 丨% by weight, the physical properties of the coating film are insufficient. When the amount is more than 80% by weight, the constituent unit (a) and the constituent unit (b) are small. Therefore, the dispersibility, developability and redoing of the pigment as a coloring agent Poor sex. 098114711 Form No. A0101 Page 25 of 74 0983216981-0 200949440 Considering the dispersibility, stability, and coating properties of the pigment as a coloring agent, it is suitable as a constituent unit (C) precursor (C' The weight ratio of T-based (meth) acrylate and/or dicyclopentyl (meth) acrylate is preferably in the total precursor (including the unsaturated one formed from the constituent unit (d)) 1 to 65 wt% of valence acid and polyvalent acid anhydride. When the amount is less than 1% by weight, the physical properties of the coating film are insufficient. When the amount is more than 65% by weight, since the constituent unit (a) and the constituent unit (b) are small, the dispersibility, developability and redoing of the pigment as a colorant are obtained. Poor sex. The resin contained in the photosensitive coloring composition of the present invention can be made into a precursor (a' by the presence of a radical polymerization initiator in an inert gas stream at 50 to 150 ° C for 2 to 10 hours. ), the precursor (b') and the precursor (c') are obtained by radical polymerization. Alternatively, the resin contained in the photosensitive coloring composition of the present invention may be used in the presence of a radical polymerization initiator in an inert gas stream at 50 to 150 ° C for 2 to 10 hours to make a precursor. (a'), the precursor (b') and the precursor (c') are subjected to radical polymerization, and then the reaction atmosphere is replaced with air, and hydroquinone is added at 50 to 150 ° C for 2 to 10 hours. The polyvalent acid anhydride is reacted, and triethylamine is added thereto, and the polyvalent acid anhydrate is obtained by reacting at 50 to 150 ° C for 2 to 10 hours. The polymerization can be carried out in the presence of a solvent as needed. Examples of the radical polymerization initiator include benzammonium peroxide, cumene hydroperoxide, t-hydroperoxybutyl hydride, diisopropyl toluene peroxycarbonate, di-t-butyl peroxide, and t-butyl An organic peroxide such as benzoate or an azo compound such as 2,2′-azobisbutyronitrile may be used, but it is not limited thereto, and it may be used singly or in combination of two or more. The radical polymerization initiator is used for 100 parts by weight of the total precursor of the resin, and is preferably used as the above radical polymerization reaction at a ratio of 1 to 098,114,711, Form No. A0101, page 26/74, 09,321,981,981,0,0,0,048,0 When the solvent can be used, water and/or water mixed organic solvent, or ethyl acetate cellosolve, propylene glycol monoterpene acetate and other acetic acid δ can be used; cyclohexanone, methyl isobutyl ketone, etc. Ketones; mono toluene, ethylbenzene, etc. Examples of the water-miscible organic solvent include an alcohol-based solvent such as ethanol, isopropyl alcohol or η-propanol, or a single or a small amount of ethylene glycol or diethylene glycol, but are not limited thereto, and are separate. It is fine to use or use two or more types at the same time.重量 The weight average molecular weight (Mw) of the resin contained in the photosensitive coloring composition of the present invention is preferably 5 Å to 1 Å, and the dispersibility, stability, and coating film of the pigment as a coloring agent The tolerance point of tolerance should be further determined to be 7000~50. When the weight average molecular weight is less than 5, the pigment dispersion is poor and the film resistance is deteriorated, and more than 1 (10) is not only the developability and the reducibility, and the viscosity of the photosensitive coloring composition is too high, and the coating property is deteriorated.

The photosensitive coloring used in the present invention is broken (the tree tree of the present invention exhibits an excellent dispersing effect on almost all pigments, and the use of the resin dispersion as a coloring agent) When the I color is formed; in the case of the filter segment of the optical sheet, a filter block having less pigment coagulum can be obtained. The photosensitive coloring composition used in the present invention is intended for a coloring agent (pigment). 1〇〇weight part can be used at a ratio of 30 to 800 parts by weight. If it is less than 30 weight, p 'can not obtain sufficient dispersion stability, if more than just weight. P..., method simultaneously achieves color filter Required coloring agent (pigment) concentration and film thickness. 098114711 &lt;Colorant> Forms I A0101 Page 27 / Total 74 pages 98321 981 981 - 0 200949440 As a coloring agent for the photosensitive coloring composition of the present invention, it can be used alone Or a mixture of two or more kinds of organic or inorganic pigments. The pigment is preferably a pigment having high color rendering and high heat resistance, and particularly preferably a pigment having high heat decomposition resistance, and an organic pigment is usually used. The following is indexed by color (c. I.) The code represents a specific example of an organic pigment which can be used in the photosensitive coloring composition of the present invention. For the red coloring composition for forming a red color filter section, for example, CI Pigment Red 7, 9, 14 can be used as the red pigment. , 41, 48: 1, 48: 2, 48: 3, 48: 4, 81: 1, 81: 2, 81: 3, 122, 123, 146, 149, 168, 177, 178, 180, Ο 184, 185, 1 ah, 192, 200, 202, 208, 210, 215, 216, 217, 220, 223, 224, 226, 227, 228, 240, 242, 246, 254, 255, 264, and 272, etc. The composition can be used together with a yellow pigment or an orange pigment. As the yellow pigment added to the red coloring composition, for example, CI Pigment Yel low 1, 2, 4, 5, &amp; 1, 10, 12 can be used. 13, 14, 15, 16, 17, 18, 20, 24, 31, 32, 34, 35, Ί, 〇 35 : 1, 36, 36 : 1, 37, 37 : 1, 40, 42, 43, 53 , 55, 60 ' 61, 62 ' 63 ' 65, 73 ' 74 ' 77, 81, 83 ' 86 ' 93, 94, 95, 97, 98, 100, 101, 104, 106, 108, 109, 110, 113 , 114, 115, 116, 117, 118, 119, 120, 1 23, 125, 126, 127, 128, 129, 137, 138, 139, 147, 150, 151, 152, 153, 154, 155, 156, 161, 162, 164, 166, 167, 168, 169, 170, 171, 172, 173, 174, 175, 176, 177, 179, 180, 181, 182, 185, 187, 188, 193 '194 and 199, and the like. Among them, C. 098114711 Form No. A0101 Page 28 of 74 0983216981-0 200949440 ❹ Α· Pigment YeU〇w 138, 139, 150 and 185 are appropriate. As the orange pigment added to the red coloring composition, for example, C. ^ Pigment Orange 36, 43, 51, 55, 59, 61, and 71 can be used. As the green coloring composition for forming the green filter segment, for example, C.I. Pigment Green 7, 10, 36, 37, and 58 can be used. The green coloring composition can be used simultaneously with the yellow pigment. As a yellow pigment added to the green coloring composition, for example, CI Pigment Ye 1 low 1, 2, 3, 4, 5, 6, 10, 12, 13, 14 ' can be used. 15, 16, 17, 18, 20, 24, 31, 32, 34, 35, 35: 1, 36, 36: 1, 37, 37: 1., 40, 42, 43, 53, 55, 60, 61 , 62, 63, 65, 73, 74, 77, 81, 83, 86, 93, 94, 95, 97, 98, 10CP"fmi^: l〇6, 108, 109, 110, 113, 114, 115, 116, 117, 118, 119, 120, 123, 125, 126, 127, 128, 129, 137, 138, 139, 147, 150, 15 152, 153, 154, 155, 156, G 161, 162, 164 , 166, 167, 1:68, 16'9, 170, 171, Λ ff; 〆 172, 173, 174, 175, 17'r] W?, 179, 180, 181, 182, 185, 187, 188, 193, 194 and 199, etc., especially CI Pigment Yellow 138, 139, 150 and 185. The blue coloring composition for forming the blue filter segment can be used, for example, CI Pigment Blue 15 , 15 : 1 , 15 : 2 , 15 : 3 , 15 : 4 , 15 : 6, 16, 22, 60 and 64 , etc. Blue The coloring composition can be used simultaneously with violet pigments such as C.I. Pigment Violet 1, 19, 23, 27, 29, 30, 32, 37, 40, 42 and 50. 098114711 Yellow used to form the yellow filter segment The coloring composition can be used, for example, in the form number A0101, page 29, page 74, 098,321,981,081 to 0,0,0,048,0,0,048, CI Pigment Yellow 1, 2, 3, 4, 5, 6, 10, 12, 13, 14, 15, 16, 17, 18 , 20, 24, 31, 32, 34, 35, 35 : 1 ' 36 ' 36 : 1 ' 37 ' 37 : 1, 40 ' 42 ' 43 ' 53 ' 55 &gt; 60 ' 61 ' 62 ' 63 &gt; 65 ' 73 ' 74 &gt; 77 ' 81 ' 83 ' 86, 93, 94, 95, 97, 98, 100, 101, 104, 106, 108, 109, 110, 113, 114, 115, 116, 117, 118, 119, 120, 123, 125, 126, 127, 128, 129, 137, 138, 139, 147, 150, 151, 152, 153, 154, 155, 156, 161, 162, 164, 166, 167, 168, Yellow pigments such as 169, 170, 171, 172, 173, 174, 175, 176, 177, 179, 180, 181, 182, 185, 187, 188, 193, 194 and 199. ... squaring The orange coloring composition used to form the orange filter section can be, for example, an orange pigment such as C. I. Pigment Orange 36, 43, 51, 55, 59 '61 and 71. As the cyan coloring composition for forming the cyan filter section, cyan pigments such as 15:1, 15:2, 15:4, 15:3, 15:6, 16 and 81 can be used. For the magenta colored composition for forming the magenta filter segment, for example, a violet pigment such as C.I. Pigment Violet 1 and 19, and a red pigment such as C.I. Pigment Red 144, 146, 177, 169 and 81 can be used. For the magenta colored composition, the same yellow pigment as the yellow colored composition for forming the yellow filter and the light sheet section can be used at the same time. Further, in order to obtain a balance between saturation and brightness, and to ensure good coating property, sensitivity, developability, and the like, an inorganic pigment may be used in combination with the above organic pigment. As inorganic pigments, yellow lead, rhubarb, and purple 098114711 Form No. A0101 Page 30 / Total 74 pages 98321 981 981 -1 200949440 Paint (red iron oxide (111 )), tin red, ultramarine blue, indigo, chrome oxide green, Ming Metal oxides such as green, metal powder, and the like. Further, for the purpose of coloring, the dye may be contained in a range that does not lower the heat resistance. Further, the photosensitive coloring composition of the present invention can be finely dispersed and produced by various dispersing means such as a three-arm mill, a two-roll mill, a sand mill, a kneader, an attritor, or a pigment conditioner. Next, examples of the black pigment used as the light-shielding layer include carbon black #2400, #2350, #2300, #2200, #❹1 000, #980, #970, #96Q, #950, manufactured by Mitsubishi Chemical Corporation. , #900, #850, MCF88, #650, JIA600, MA7, MA8, MAI 1, MA100, MA220, IL30B, IL31B, IL7B, IL1.1B, I.t52B, #4000, #4100, #55, #52 , #50, #47, #45, #44, #40, #33, #32, #30, #20, pray 0, #5,

CF9, #3050, #3150, #3250, #3950, DIABLACK A, DIABLACK N220M, DIABLACK N234, DIABLACK I wi I _ §, DIABLACK LI, DIAPLACK: I IWMllBMcK N339, DIA DIABLACK SH vPIABLACK SHA - ΌIABLACK LH &gt; DIAB -LACK H, DIABLACK HA, DIABLACK SF, DIABLACK N550M, DIABLACK E, DIABLACK G, DIABLACK R, DIABLACK N760M, DIABLACK LR; carbon black THERMAX N990, N991, N907, N908, N990, N991, N908; ASAHI CARBON company's carbon black Asahi #80, Asahi #70, Asahi #70L, Asahi F-200, Asahi #66, Asahi #66HN, Asahi #60H, Asahi #60U, Asahi #55, Asahi #50H, Asahi #51 , Asahi #50U, Asahi #50, Asahi #35, Asahi #15, ASAHI THERMAL; DEGUSSA company's carbon black Color Black Fw200, Color 098114711 Form No. A0101 Page 31 / Total 74 Page 09321186981-0 200949440

Black Fw2, Color Black Fw2V, Color Black Fwl 'Color Black Fwl8, Color Black S170, C〇lor Black S160, Special Black 6, Special Black 5, Special Black 4, Special Black 4A, Special Black 250 'Special Black 350, Printex U, Printex V'Printex 140U, Printex 14〇V (any one is a product name), etc. The photosensitive coloring composition of the present invention may contain a dispersing agent for dispersing a pigment as a coloring agent. Since the dispersion of the dispersant is good for the pigment, the effect of re-coagulation of the pigment after dispersing is greatly enhanced. Therefore, a color filter excellent in transparency can be obtained by dispersing the pigment in the coloring composition using a dispersing agent. . As the dispersion, a resin type dispersing agent, a dye derivative, an interfacial detergent or the like is used. The amount of the dispersing agent is not particularly limited, and it is preferably used in an amount of 0.1 to 30 parts by weight of the weight of the coloring agent (pigment). . The resin type pigment dispersant has a pigment affinity site adsorbed to the pigment and a site compatible with the colorant carrier, and has a function of adsorbing the pigment to stabilize the dispersion of the pigment to the colorant carrier. As a resin type pigment, M can be used: poly(tetra), (iv) dilute acid vinegar, polyglycolic acid vinegar, unsaturated polyamidoamine, poly-wei, poly-wei (partial) amine salt, poly-inspection (four), poly-minus (four) salt, 14-nucleus a long-chain polyamine ruthenate, a transbasic polycarboxylic acid or a denatured product thereof, formed by reacting with a polycondensate having a polymerization (lower-grade imine) and a free money base An amine or a salt thereof or the like. Moreover, (meth)acrylic acid-(meth)(tetra)acid-copolymer, styrene-maleic acid copolymer, 098114711, Form No. A0101, page 32/74, 200949440, polyvinyl alcohol, polyvinylpyrrole A water-soluble resin such as an alcohol or a water-soluble polymer compound, a polyester-based, a modified polyacrylate-based compound, an ethylene oxide/propylene oxide-added compound, or a phthalate-based compound. These may be used singly or in combination of two or more. The commercially available resin type pigment dispersant is exemplified by Disperbyk-101, 103, 107, 108, 110, 111, 116, 130, 140, 154, 161, 162, 163, 164 manufactured by BYK-Chemie. , 165, 166, 170, 171, 174, 180, 181, 182, 183, ❹ 184 '185, 190, 2000, 2001 or Anti-Terra-U, 203, 204 or BYK - P104 'P104S, 220S or Lactimon, Lac-timon — WS or Bykumen et al.; SOLSPERSE-3000, 9000, 13240, 13650, 13940, 17000, 18000, 20000, 21000, 24000, 26000, 27000, 28000, 31845, 32000, manufactured by L-ubrizo.l, Japan. , 32500, 32600, 34750, 36600, 38500, 41000, 41090, 53095, etc.; EFKA-4St 丨52, LP4008, - , :5 _ 5 4009, L, 10, LP4050, LP4055, 400, made by EFKA Brothers. 401, 402, Ο -r-&quot;?. __ git , ι'ι' 403, 450, 451, 453, 4540, 4550, LP4560, LP4560, 120, 150, 1501, 1502, 1503, and the like. The dye derivative is a compound in which a substituent is introduced into an organic dye, and the organic dye also contains a pale yellow aromatic polycyclic compound such as a naphthalene or an anthracene which is not generally called a dye. As a pigment derivative, it is described in JP-A-63-305173, JP-A-57-1 5620, JP-A-59-40172, JP-A-63-171 〇2, and Sakamoto Japanese Patent Publication No. 5-9469, etc., may be used alone or in combination of two or more. 098114711 Form No. Α〇1〇1 Page 33 of 74 pages 9832198681-0 200949440 <Photopolymerization initiator> In the present invention The photosensitive coloring composition contains a photopolymerization initiator. Used as a photopolymerization initiator: 4-phenoxydichloroacetophenone, 4-t-butyldichloroacetophenone, diethoxyphenylethyl I, 1-(4-isopropyl Phenyl phenyl) _ — 2 — via benzyl-2-mercaptopropan-1-one, 1-hydroxycyclohexyl phenyl ketone, 2-benzyl dimethyl decylamine 1 - (4- lylphenyl) Benzene-based photopolymerization initiator, such as benzo, benzoanisole, stupid ethyl ether, benzoisopropyl ether, benzyl didecyl ketal, etc. ; benzophenone, benzoquinone benzoic acid, benzoquinone benzoic acid methyl, 4-phenyl benzophenone, hydroxybenzophenone, propylene bismuth ketone, 4-benzoquinone - 4' _ a diphenylmethyl network photopolymerization initiator such as diphenyl sulfide; thioxanthone, 2-oxethione, 2-methylthioxanthone, isopropylthioxanthone, 2,4 diisopropyl Thiophenone ketone ketone photopolymerization initiator; 2,4,6 - tri-gas primary triazine, 2-phenyl- 4,6-bis(trichloromethyl) primary triazine, 2_ (p-methoxyphenyl) 4,6-bis(trimethylmethyl)_secondary triazine, 2_(p-toluene 4,6 - bis(trimethyl)methyl-triazine, 2-pipeline- 4,6-bis(trichloroindenyl)-secondary triazine, 2,4-bis(tris) a 6-styrene-based primary triazine, 2-(naphtho-l-yl)-4,6-bis(trichloromethyl)-secondary triterpene, 2-(4-methoxynaphthalene) And a 1-yl)-4,6-bis(triseofluorenyl) primary triazine, 2,4-trichlorodecyl-(piperidyl)-6-triazine, 2,4-trimethylmethyl a triazine-based photopolymerization initiator such as (4'-methoxystyryl)- 6-triazine; a borate-based photopolymerization initiator; 098114711 Form No. A0101 Page 34 of 74 9813216981-0 200949440 A carbazole photopolymerization initiator; and a spectroscopy photopolymerization initiator. The photopolymerization initiator is used in an amount of from 5 to 200 parts by weight, more preferably from 10 to 150 parts by weight, per 100 parts by weight of the coloring agent (pigment) in the photosensitive coloring composition. The above photopolymerization initiator may be used singly or in combination of two or more. As the sensitizer, α-methoxyl ether, mercaptophosphoric acid hydroxide, fluorenyl phenylglyoxylic acid, benzyl group, 9, may be used at the same time. 10 - compounds such as phenanthrene, 3, 3', 〇 4, 4' _ tetra (t-butyl peroxycarboxy) benzophenone, 4,4-didecylamine benzophenone. The sensitizer can be used in an amount of 0.1 to 60 parts by weight based on 100 parts by weight of the photopolymerization initiator in the photosensitive coloring composition. <Polymerizable monomer> Addition of polymerizability to the photosensitive coloring composition of the present invention monomer. As the polymerizable monomer, it can be used: ❹ (meth)acrylic acid, styrene, vinyl acetate, cerium (mercapto) acrylate, acrylonitrile, cyclohexyl (meth) acrylate, and tricyclodecyl decyl acrylate Monofunctional monomer; 1,4-butylene di(meth)acrylate, diethylene glycol bis(indenyl)acrylate, hexamethylene di(meth)acrylate, neopentyl Diol (mercapto) acrylate, polyethylene glycol di(meth) acrylate, polypropylene glycol di(meth) acrylate, bis(indenyl) acrylate of other alkylene glycol, various polyesters Diterpenoid (mercapto) acrylate, various urethane dimercapto (meth) acrylate, EO denatured bisphenol A bis (meth) acrylate and various difunctional epoxy compounds of di(methyl) a difunctional monomer such as acrylate; and 098114711 Form No. A0101 Page 35 of 74 0983216981-0 200949440 Trihydroxydecylpropane tris(decyl) acrylate, dimethylolpropane tetrakis(meth) acrylate, Various tris (meth) acrylates of isocyanuric acid Pentaerythritol tris(mercapto) acrylate, pentaerythritol tetra(meth) acrylate, dipentaerythritol penta(indenyl) acrylate, dipentaerythritol hexa(meth) acrylate, various polyfunctional epoxy resin (meth) acrylate The ester or caprolactone denatures a polyfunctional monomer such as dipentaerythritol hexaacrylate, but is not limited thereto, and may be used singly or in combination of two or more. The polymerizable monomer can be used in a ratio of 20 to 200 weight portions for 100 parts by weight of the colorant (pigment). <Solvent> The organic solvent contained in the photosensitive coloring composition of the present invention includes 1,2,3-trimethylpropane, 1,3-butanediol diacetate, 2-heptanone, and 3,3. ,5-trimethyl phenyl- 2 -cyclohexan-1 - hydrazine, 3,5,5 trimethylcyclohexanone, 3-ethoxypropionic acid ethyl, 3-methoxyoxy-3-methylacetic acid Butyl ester, 3-methoxybutanol, butyl 3-methoxyacetate, 4-heptanone, m-diphenylbenzene, m-diethylbenzene, m-benzene, N,N-dimethylacetamide , n-butylbenzene, n-propyl acetate, N-pyrrolidone, o-xylene, o-toluene, o-diethylbenzene, o-dichlorobenzene, p-chlorophenylene, p-diethylbenzene, di-n-butylbenzene, tertiary Butylbenzene, isophorone, ethylene glycol diethyl ether, ethylene glycol dibutyl ether, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether, ethylene glycol monobutyl ether acetate, ethylene glycol single Propyl ether, diisobutyl ketone, cyclohexanol acetate, dipropylene glycol dimethyl ether, dipropylene glycol methyl ether acetate, dipropylene glycol monobutyl ether, diacetone alcohol, propylene glycol diacetate, propylene glycol phenyl ether, propylene glycol monoethyl ether Propylene glycol monopropyl Ether, propylene glycol monoterpene ether, propylene glycol monoterpene ether acetate, propylene glycol monomethyl ether propionate, phenyl alcohol, 曱 098114711 Form No. A0101 Page 36 / Total 74 pages 0983216981-0 200949440 Isobutyl ketone, methyl ring Hexyl alcohol, n-amyl acetate, n-butyl acetate, isoamyl acetate, isobutyl acetate, propyl acetate, dibasic acid ester, etc., but not limited thereto, and may be used alone or in combination of two or more. . The organic solvent can be used in an amount of from 800 to 4,000 parts by weight, more preferably from 1,000 to 2,500 parts by weight, based on 100 parts by weight of the coloring agent (pigment) in the photosensitive coloring composition. In order to stabilize the viscosity of the composition over time, the photosensitive coloring composition of the present invention may further contain a storage stabilizer. Examples of the storage stabilizer include: 4 4-ammonium vapor such as benzyltrimethyl vapor or dimercaptohydroxylamine; organic acids such as lactic acid and oxalic acid; methyl ether of the above organic acid; t-butylpyrene tea Catechol such as phenol and pyrocatechol; organic phosphine such as tetraethylphosphine and tetraphenylphosphine; and phosphite. The storage stabilizer is used in an amount of 0.1 to 10 parts by weight based on 100 parts by weight of the coloring agent in the photosensitive coloring composition. Further, in order to improve the adhesion to the transparent substrate, a adhesion promoter such as a decane coupling agent may be contained. Examples of the decane coupling agent include ethylene methoxide such as ethylene tris(/3-methoxyoxy group) decane, ethylene ethoxy decane, and ethylene trimethoxy decane; τ_methacryloxy propylene trioxane (decyl) decyl phthalate; (3,4-epoxycycloalkyl)ethyltrimethoxy decane,/5-(3,4-epoxycycloalkyl)decyltrimethoxy Decane, stone _ (3,4_ 098114711 Form No. A0101 Page 37 / Total 74 pages 0983216981-0 200949440 Epoxycycloalkyl)ethyltriethoxydecane, /S—(3,4-epoxycycloalkyl Epoxy decane such as mercaptotriethoxy decane, T-glycidoxypropyltrimethoxy decane, 7-glycidoxypropyltriethoxydecane; Ν-yS (amine B Aminopropyl trimethoxy decane, Ν-yS (amine ethyl) r-aminopropyl triethoxy decane, Ν-yS (amine ethyl) r_aminopropyl methyl diethoxy decane, R_Aminopropyltriethoxydecane, τ-aminopropyltrimethoxydecane, N-phenyl-τ-aminopropyltrimethoxy decane, N-phenyl-r-aminopropyltriethoxy Amino decanes such as decanes; 7 &quot; - M trimethylammonium methoxy cornerstone evening burning, 7 &quot; _ sparse ethyl trimethoxy Silane broken alkyl thio and other classes. The decane coupling agent can be used in an amount of 0.1 to 10 parts by weight, more preferably in an amount of 0.05 to 5 parts by weight, based on 100 parts by weight of the coloring agent (pigment) in the photosensitive coloring composition. The photosensitive coloring composition of the present invention can be prepared as a printing ink for intaglio printing, a horizontal printing ink, a screen printing ink, a solvent developing type or an alkali developing type resist material. The solvent developing type or alkali developing type resist material is a composition containing a resin, a photopolymerization initiator, a polymerizable monomer, and an organic solvent, and a coloring agent is dispersed. The photosensitive coloring composition of the present invention preferably removes coarse particles of 5/m or more by means of centrifugation, a sintered filter or a membrane filter, and more preferably removes coarse particles of 1 / zm or more, and particularly preferably removes 0.5/ΖΙΠ. The above coarse particles and the mixed dust. <Color Filter> Next, a color filter relating to the present invention will be described. 098114711 Form No. A0101 Page 38 of 74 0983216981-0 200949440 彩色 The color filter of the present invention has a color filter using a filter segment formed by the photosensitive coloring composition of the present invention. The color filter has the following types: an additive color mixing type having at least one red filter segment, one less green filter segment, and at least one blue filter segment; or at least 1 A subtractive color mixing type of magenta filter segments, at least one cyan filter segment, and at least one yellow filter segment. The color filter of the present invention can be formed by photolithography using the photosensitive coloring composition of the present invention to form color filter segments on a transparent substrate. As the transparent substrate, a glass plate or a resin plate such as polycarbonate, polymethyl methacrylate or polyethylene glycol is used. The formation of the respective color filter segments by photolithography is carried out in the following manner. That is, a photosensitive coloring composition which is prepared as a solvent-based or alkali-developing colored photoresist material by a coating method such as spray coating or spin coating, slit coating or roll coating on a transparent substrate The coating was applied to a dry film thickness of 0.2 to 5 μm. Ultraviolet exposure is carried out on the dried film as needed through a mask having a specific pattern which is placed in contact or non-contact with the film. Thereafter, the color filter is produced by dipping in a solvent or an alkali developer, or by spraying a developer by spraying or the like to remove the uncured portion to form a desired pattern, and repeating the same operation for other colors. Further, in order to promote the polymerization of the colored photoresist material, heating may be applied as needed. If the photolithography method is used, a color filter or a light sheet having a higher precision than the printing method can be formed. At the time of development, an aqueous solution such as sodium carbonate or sodium hydroxide may be used as the alkali developer, and an organic base such as dimercaptobenzylamine or triethanolamine may also be used. Further, an antifoaming agent or a surfactant may be added to the developer. 098114711 Form No. A0101 Page 39 / Total 74 Page 98321186981-0 200949440 In addition, 'for the sensitivity of the UV exposure of the South, the above colored photoresist material can also be coated and dried after the 'water-soluble or alkali-soluble resin such as polyethylene or The water-soluble acrylic resin or the like is coated and dried to form a film which prevents the polymerization from being inhibited by the gas, and then exposed to ultraviolet light.

In addition to the photolithography method, the color filter of the present invention can be manufactured by an electric isolator method, a transfer method, or the like. Further, the electrodeposition method utilizes a transparent conductive film formed on a transparent substrate by Electrophoresis of colloidal particles, which is formed by electrodeposition of color filter segments on a transparent conductive film to produce a color filter. Moreover, the transfer method is based on the surface of a transferable transfer sheet, and a color filter layer is formed in advance, and the color filter layer is transferred onto a desired transparent substrate. The color filter of the present invention When the film is found to be defective in the production process, it can be peeled off from the substrate surface by using a stripping solution containing a high concentration of a strong alkaline solution (hereinafter referred to as a redo liquid), and the substrate can be reused (rework ). The basis for redo performance is for the 65 °C redo liquid l〇〇g, 23 〇. (:,

The solubility of the coating film of the photosensitive coloring composition fired for 60 minutes was 3 〇 to 120 mg. If it is less than 30 mg', it is not peeled off or the release sheet is large, and the recycled redo liquid causes liquid clogging, which is inefficient. If it is more than 12 〇 mg, it will peel even if it is a weak alkali solution. Therefore, the development is too fast, and a high-definition color filter or a light sheet cannot be formed. According to the multiplying effect of the constituent unit (a) of the resin of the present invention and the constituent unit (b) and the constituent unit (c), if the solubility is 30 to 120 mg', the release sheet is finely crushed, and the sheet can be efficiently reworked. The redo liquid used here has a high pH (pH 11 or more) and contains Κ0Η and/or NaOH, an organic test, a hydrophilic solvent, a surfactant, and water. Specifically, PK-098114711 manufactured by PARKER CORPORATION, Form No. A0101, No. 40, No. 74, 98,321,981,981, 0, 2009,494, CFR, 310, PK-CFR320, PK-CFR370, manufactured by Yokohama Oily Industrial Co., Ltd. SEMICLEAN DF — 7, ΕΡ 10, MITSUKAWA Pure Chemical Research Institute, UNLASTCLEANER — 22, etc. [Examples] Hereinafter, the present invention will be described in further detail by way of examples, but the following examples do not limit the present invention. The range of benefits. In addition, "parts" and "%" of the examples mean "weight parts" and "% by weight". First, the preparation of the acrylic resin solution used in the examples and the comparative examples will be described. The molecular weight of the acrylic resin in the acrylic resin solution is a polystyrene-equivalent weight average molecular weight measured by a gel permeation chromatography (GPC). <Preparation of Acrylic Resin Solution 1> 370 parts of propylene glycol monomethyl ether acetate were placed in a reaction vessel, and nitrogen gas was injected into the container while heating to 80 ° C. At the same temperature, the following monomers and heat were dropped over 1 hour. The polymerization is carried out by a mixture of polymerization initiators. Phenylphenol oxirane acrylate acrylate 10. 0 ("ARONIX M110" manufactured by Toagosei Co., Ltd.) 2 - decyl acryloyloxyethyl succinic acid 50.0 ("Naka Nakamura Chemical Co., Ltd." "NK ESTER CB- 1") benzyl decyl acrylate 40. 0 azobisisobutyronitrile 3. After 5 drops, further reacted at 100 ° C for 3 hours, then added cyclohexanone 50 parts dissolved in azo double The 1.0 part of nitrile was further reacted at 100 ° C for 1 hour to obtain a solution of an acrylic resin. The acrylic resin has a weight average molecular weight of about 15,000. 098114711 Form No. A0101 Page 41 / Total 74 pages 09831186981-0 200949440 After cooling to room temperature, sample about 2g of the resin solution, heat and dry at 180 °C for 20 minutes, determine the non-volatile content, according to the measured value, previously synthesized The resin solution 1 was prepared by adding cyclohexanone to the resin solution and making the nonvolatile component 30% by weight. <Preparation of Acrylic Resin Solution 2> 370 parts of propylene glycol monomethyl ether acetate were placed in a reaction vessel, and nitrogen gas was injected into the vessel while heating to 80 ° C. At the same temperature, the following monomers and heat were dropped over 1 hour. The polymerization is carried out by a mixture of polymerization initiators. P-cumyl phenol ethylene oxide modified acrylate 20.0 epoxy acrylate acrylate 24. 5 benzyl methacrylate acrylate 16.8 azobisisobutyronitrile 3. 5 parts after dripping, further l〇〇 After reacting for 3 hours at ° C, a portion of the cyclohexanone 50 portion was dissolved in 1.0 part of azobisisobutyronitrile, and the reaction was further continued at 1 ° C for 1 hour. Next, the atmosphere in the container was replaced with air, and 12.4 parts of the acrylic acid (1. The reaction was continued at 120 ° C for 6 hours, and the reaction was terminated when the acid value of the solid component became 0.5 mg K0H / g to obtain a solution of an acrylic resin. Then, tetrahydroanthracene succinic acid 26. 3 parts (100 mol% of the generated hydroxyl group) and triethylamine 0. 3 parts were added, and the reaction was carried out at 120 ° C for 3.5 hours to obtain a solution of an acrylic resin. The acrylic resin has a weight average molecular weight of about 15,000. After cooling to room temperature, about 2 g of the resin solution was sampled, and dried by heating at 180 ° C for 20 minutes, and the non-volatile component was measured. According to the measured value, propylene glycol monomethyl ether acetate was added to the previously synthesized resin solution to make non-volatile matter. The component was made into a resin solution 2 at 30% by weight. 098114711 Form No. A0101 Page 42 of 74 0983216981-0 200949440 &lt;Preparation of Acrylic Resin Solution 3 In addition to the preparation of the acrylic resin solution 2, the benzyl propylene vinegar was changed to dicyclopentan The methacrylic acid vinegar ("FAN-RYL FA 513M" manufactured by Kyori Chemical Co., Ltd.) was prepared in the same manner as the propylene glycol resin solution 2 in the same manner to prepare a solid component of the propylene glycol resin solution 3 . The acrylic acid resin has a weight average molecular weight of about 15 Å. <Preparation of Acrylic Resin Solution 4> e; The reaction device is placed in a propanol monomethyl hydrazide acetate portion, and a nitrogen gas is injected into the container while heating to 8 G c ' at the same temperature, and H is dripped under the following conditions. The polymerization is carried out by mixing a monomer and a thermal polymerization initiator. For cumyl sulphate, ethylene sulphate, sulphate, sulphate, sulphate, sulphate, sulphate, sulphate, sulphate, sulphate, sulphate After the dropwise addition, the reaction was further carried out at 10 0 °c for 3 hours, and then azobisisobutyronitrile was dissolved in the 50 parts of cyclohexanone. 1. The scorpion: the scorpion ^ further held at 1 〇〇 '%. Continue to react for 1 hour. 5和对对。 The octadecylamine phenol is added to the above-mentioned container. Stupid base 〇. 1 part, to 120. (: The reaction was continued for 6 hours, and the reaction was terminated when the acid value of the solid component became 〇. 5 mg K0H/S, and a solution of the acrylic resin was obtained. Further '36.5 parts of tetrahydroanhydrous adipic acid were further added (the resulting hydroxyl group was 10 mol) %), triethylamine 0.5 parts, reacted at 120 ° C for 3.5 hours to obtain a solution of acrylic resin. The weight average molecular weight of the acrylic resin is about 1 5000. After cooling to room temperature, the resin solution is sampled. 2g 'heated and dried at 180 for 20 minutes, and determined the non-volatile content. According to the measured value, propylene glycol monomethyl ether acetate was added to the previously synthesized 098114711 Form No. A0101 Page 43 / 74 Bake 9832198681-0 200949440 resin solution. The non-f glow component was made up to 30% by weight to prepare a resin solution 4. <Preparation of Acrylic Resin Solution 5> In the reaction vessel, propylene glycol monomethyl ether acetate 370 was added but A. 丨, nitrogen was injected into the container. Simultaneously heating to 8 (TC, at the same temperature, through J), a mixture of the following monomers and a thermal polymerization initiator to carry out the polymerization reaction of p-cumyl epoxide ethylene oxide denatured acrylate 3. C Base acrylate 36.9 benzyl methacrylate 2.0 azobisisobutyronitrile Ϊ. 5 after the dropwise addition, further reacted at 3 ° C for 3 +, then added azo in the ring Double isobutyronitrile 1. The contents of the clams were further subjected to a reaction of 10 (remains for 1 hour. Then, the atmosphere in the container was replaced with air, in the above-mentioned apparatus, 18.7 parts of acrylic acid (the epoxy group) 〇m〇i%) rose into _ dimethylamine phenolphthalein · 5 parts and p-phenylenediamine 〇. 1 part of the reaction was continued for 2 hours at 1203⁄4, and the reaction was terminated when the acid value of the solid component became 〇-5mSK〇H7g. A solution of an acrylic resin was obtained, followed by 'addition of 39.4 parts of tetrahydroanhydrous adipic acid (1〇〇111〇1% of the generated hydroxyl group), and 5 parts of triethylamine oxime, and 120T: reaction for 3.5 hours. a solution of an acrylic resin having a weight average molecular weight of about 15000 °. After cooling to room temperature, a sample of the resin solution is about 2 g, dried by heating at 18 Torr for 2 minutes, and the non-volatile component is determined according to the measured value. Adding propylene glycol monoterpene ether acetate vinegar to the previously synthesized resin solution to make the non-volatile component 3 0% by weight and prepared into a resin solution 5 ° <Preparation of Acrylic Resin Solution 6 370 parts of propylene glycol monomethyl ether acetate vinegar were placed in the reaction container, and 098114711 was injected into the container. Form No. A0101 Page 44 / Total 74 pages 0 281 321 819 200949440 Nitrogen, At the same time, the mixture was heated to 80 ° C, and a mixture of the following monomers and a thermal polymerization initiator was dropped over 1 hour at the same temperature to carry out polymerization. P-cumyl oxirane oxiran acrylate 50.0 epoxy propyl group Acrylate 0. 8 parts benzyl methacrylate 48. 0 parts of azobisisobutyronitrile 3.5 parts after dropping, further reacted at 100 ° C for 3 hours, then added cyclohexanone 50 parts dissolved in azo double Isobutyronitrile 1. The contents of the clams were further reacted for 1 hour at io °c. The first part and the second part of the bismuth phenol are added to the above-mentioned argon. The reaction was continued at 120 ° C for 6 hours, and the reaction was terminated when the acid value of the solid component became 0.5 mg K0H/g to obtain a solution of an acrylic resin. Then, a solution of an acrylic resin was obtained by adding 0.8 parts of tetrahydroanthracene acid (100 mol% of the generated hydroxyl group) and 0.1 part of triethylamine. The reaction was carried out at 120 ° C for 3.5 hours. The acrylic resin has a weight average molecular weight of about 15,000. After cooling to room temperature, about 2 g of the resin solution was sampled, and dried by heating at 180 ° C for 20 minutes, and the non-volatile component was measured. According to the measured value, propylene glycol monomethyl ether acetate was added to the previously synthesized resin solution to make non-volatile matter. The component was made into a resin solution 6 at 30% by weight. <Preparation of Acrylic Resin Solution 7> 370 parts of propylene glycol monomethyl ether acetate were placed in a reaction container, nitrogen gas was injected into the container, and heated to 80 ° C, and the following monomers and heat were dropped over 1 hour at the same temperature. The polymerization is carried out by a mixture of polymerization initiators. P-cumyl phenol ethylene oxide denatured acrylate 20. 0 methacrylic acid 15.0 parts 098114711 Form No. A0101 Page 45 / Total 74 pages 0983216981-0 200949440 Benzyl methacrylate 65.0 azobisisobutyronitrile 3.5 After the reaction, the mixture was further reacted for 3 hours, and then azobisisobutyronitrile was dissolved in the 5 oxime portion of the cyclohexanone. The reaction was further continued at 1 ° C for 1 hour. , a solution of an acrylic resin is obtained. The acrylic resin has a weight average molecular weight of about 15,000. After cooling to room temperature, about 2 g of the resin solution was sampled, and dried by heating at 18 ° C for 2 minutes, and the non-volatile component was measured. According to the measured value, cyclohexanone was added to the previously synthesized resin solution to make the non-material component into a ruthenium. The resin solution 7 was prepared in a weight %. <Preparation of Acrylic Resin Solution 8> Except that in the preparation of the acrylic resin solution 7, the f-group methyl propyl vinegar was changed to the bicyclo ketone methyl propylene (four), and the same (s) acid resin solution 7 was used in the same green saki It was synthesized and prepared into a 30% acrylic resin solution 8 as a component. The weight average molecular weight of the C__ is about 0 Ο I . , £ :;;| &lt; Ϊ fltp^l I ic- ^i .. '.... <modulation of the acrylic resin solution 9> except in acrylic acid The resin solution 2 was replaced with a methyl A-based system, and the benzyl methacrylate was changed to a methacrylate, and the mixture was synthesized to prepare a solid == acid resin solution 2 in the same manner. The amount of the "Resin's Weight Flat Acid TreeTM J knife is about 15,000. <Preparation of Acrylic Resin Solution 1> In addition to the use of denatured acrylic acid in acrylic resin solution 2, it will be used in the "Essence of Essence", "Visc〇At^B-modified acrylated vinegar" (Osaka 098114711)

Resin solution 2 was carried out in the same manner as a 192"), both with propylene glycol form number Αοιοι 4β 百丁. Into, prepared into a solid component of 30% of the 0983216981-0 200949440 acrylic resin solution ΐ〇. The acrylic resin has a weight average molecular weight of about 1 500 Å. <Preparation of Acrylic Resin Solution 11> In addition to the conversion of the p-cumylphenol ethylene oxide-modified acrylate and the decyl methacrylate to the methacrylic acid in the preparation of the acrylic resin solution 7, both the acrylic resin solution and the acrylic resin solution were used. 7 Synthesis was carried out in the same manner to prepare an acrylic resin solution 11 having a solid content of 30%. The acrylic resin has a weight average molecular weight of about 15,000. 〇<Modulation of Acrylic Resin Solution 12> In addition to the preparation of the acrylic resin solution 7, the p-cumyl epoxy Ethylene &amp; decacryl acrylate was modified with phenol oxirane modified acryl vinegar, and the lower thiol propyl acrylate was used. The dilute vinegar is changed to 2 - ethylidylmethyl and: decanoic acid is used in the same manner as the acrylic acid resin solution 7 to satisfy the content of the method, and the mixture is prepared into a solid component of 30%. Resin solution 12. The acrylic acid has a weight average molecular weight of about 15,000. <Preparation of Acrylic Resin Solution 13> In addition to the modification of the propanol acid resin solution 7, the phenolic ethylene oxide modified vinegar is changed to the chlorhexidine modified vinegar, and the acrylic acid is changed. In the same manner as the acrylic acid resin solution 7, except that the bicyclopentameric acrylate was used, it was prepared into an acrylic acid or fat solution 13 having a solid content of 3% by weight. The propionate resin has a weight average molecular weight of about 15,000. <Preparation of Acrylic Resin Solution 14> Except for the preparation of the acrylic resin solution 2, the same method as the acrylic resin solution 2 was used except that the fluorenyl epoxide-modified acrylate was changed to bicyclopentamethyl acrylate. The synthesis was carried out to prepare a solid component 3〇098114711 Form No. A0101 Page 47 / Total 74 Page 09321186981-0 200949440 % Acrylic resin solution 14. The acrylic resin has a weight average molecular weight of about 15,000. <Preparation of Acrylic Resin Solution 15> 370 parts of propylene glycol monoterpene ether acetate were placed in a reaction vessel, and nitrogen gas was injected into the vessel while heating to 80 ° C. At the same temperature, the following monomers and heat were dropped over 1 hour. The polymerization is carried out by a mixture of polymerization initiators. Phenyl phenol oxime acrylate acrylate 30. 0 ("ARONIX M110" manufactured by Toagosei Co., Ltd.) 2 - decyl acryloyloxyethyl phthalate 20. CB-1") benzyl methacryl carboxylate 50. 0 parts of azobisisobutyronitrile 3.5 after dropping, further reacted at 100 ° C for 3 hours, then added cyclohexanone 50 parts dissolved in azo double Isobutyronitrile 1. The contents of the crotch were further reacted at 10 ° C for 1 hour to obtain a solution of an acrylic resin. The acrylic resin has a weight average molecular weight of about 15,000. After the temperature was reached to room temperature, about 2 g of the resin solution was sampled, and dried by heating at 180 ° C for 20 minutes, and the nonvolatile matter was measured. According to the measured value, cyclohexanone was added to the previously synthesized resin solution to make the nonvolatile component 30. The resin solution 15 was prepared in a weight %. <Preparation of Acrylic Resin Solution 16> 370 parts of propylene glycol monomethyl ether acetate were placed in a reaction container, nitrogen gas was injected into the container, and heated to 80 ° C, and the following monomers and heat were dropped at the same temperature for 1 hour. The polymerization is carried out by a mixture of polymerization initiators. P- phenol oxirane acrylate acrylate 30. 0 ("ARONIX M110" manufactured by Toagosei Co., Ltd.) 098114711 Form No. A0101 Page 48 / Total 74 pages 0983216981-0 200949440 2 - Mercapto acryloyloxyethyl stupid Diacid 20.20 ("NK ESTER CB-1" manufactured by Shin-Nakamura Chemical Co., Ltd.) benzyl methacrylate 35. 0 2-hydroxyethyl decyl acrylate 15.0 azobisisobutyronitrile 3.5 parts After the dropwise addition, the mixture was further reacted at 100 ° C for 3 hours, and then 1.0 part of azobisisobutyronitrile was dissolved in 50 parts of cyclohexanone, and further reacted at 100 ° C for 1 hour to obtain a solution of an acrylic resin. . The acrylic resin has a weight average molecular weight of about 15,000.

After cooling to room temperature, about 2 g of the resin solution was sampled, and dried at 18 (TC for 20 minutes, and the non-volatile component was measured. According to the measured value, cyclohexanone was added to the previously synthesized resin solution to make the non-volatile component 30 weight. % was prepared into a resin solution 16. <Preparation of Acrylic Resin Solution 17 ❹ 370 parts of propylene glycol monomethyl ether acetate were placed in a reaction container, and nitrogen gas was injected into the container while heating to 80 ° C at the same temperature. The polymerization reaction was carried out by dropping a mixture of the following monomers and a thermal polymerization initiator for 1 hour. Phenol oxirane acrylate acrylate 17. 5 parts (VISCOAT #192" manufactured by Osaka Organic Chemical Co., Ltd.) Epoxy propyl acrylate 28. Part 0 of τ-mercapto acrylate 10.5 parts of azobisisobutyronitrile was added, and after further reacting at 100 ° C for 3 hours, azobisisobutyronitrile was dissolved in 50 parts of cyclohexanone. The contents were further reacted at 100 ° C for 1 hour. Then, the atmosphere in the container was replaced with air, and 14.2 parts of acrylic acid (100 mol% of epoxy propyl group) was placed in the above container to be placed in three 098114711. Form No. A0101 No. 49 And the end of the reaction is obtained when the acid value of the solid component is 0.5 at the end of the reaction. The reaction is completed at 120 ° C for 6 hours. The solution of the acrylic resin was obtained by adding 29.9 parts of tetrahydroanhydrophthalic acid (100% of the generated hydroxyl group) and 0.5 part of triethylamine, and reacting at 120 ° C for 3.5 hours to obtain a solution of a propionate resin. The acrylic acid resin has a weight average molecular weight of about 15,000. After cooling to room temperature, about 2 g of the resin solution is sampled, and dried by heating at 180 ° C for 20 minutes, and the nonvolatile matter is measured, and the previously synthesized resin is determined based on the measured value. To the solution, propylene glycol monomethyl ether acetate was added to prepare a non-volatile component to 30% by weight to prepare a resin solution 17. <Preparation of Acrylic Resin Solution 18> A propylene glycol monomethyl ether acetate 3Y0 portion was placed in a reaction container. The container was filled with nitrogen gas while heating to 80 ° C, and the polymerization reaction was carried out by dropping a mixture of the following monomers and a thermal polymerization initiator at the same temperature for 1 hour. The p-cumyl epoxide ethylene oxide denatured acrylate was 18. 3 parts:: (Osaka has "V#315" manufactured by Seiki Co., Ltd.) Epoxypropyl acrylate 29. 3 parts of benzyl methacrylate 11.0 parts of azobisisobutyronitrile 2.0 after dropping, further reacted at 100 ° C for 3 hours, 50 parts of cyclohexanone were dissolved in azobisisobutyronitrile, and further reacted at 100 ° C for 1 hour. Then, the atmosphere in the container was replaced with air, and 14.8 parts of acrylic acid was placed in the above container. 5小时。 When the solid content acid value becomes 0. 5 when the solid content acid value is 0.5. The reaction was terminated to obtain a solution of an acrylic resin. Next, 26.6 parts of tetrahydroanhydrous phthalic acid (formed 098114711 Form No. A0101, page 50/74 pages 09321, 982, 819, 0,940,940, hydroxy, 85%), triethylamine, 0.1 part, reacted at 120 ° C 5 hours, a solution of the acrylic resin was obtained. The acrylic resin has a weight average molecular weight of about 15,000. After cooling to room temperature, about 2 g of the resin solution was sampled, and dried by heating at 180 ° C for 20 minutes, and the non-volatile component was measured. According to the measured value, propylene glycol monomethyl ether acetate was added to the previously synthesized resin solution to make non-volatile matter. The component was made into a resin solution 18 at 30% by weight. <Preparation of Acrylic Resin Solution 19> 370 parts of propylene glycol monomethyl ether acetate were placed in a reaction container, nitrogen gas was injected into the container, and heated to 80 ° C, and the following monomers were dropped at the same temperature for 1 hour. The polymerization is carried out by thermally polymerizing a mixture of initiators. 5. pentyl phenol oxirane acrylate 5.3 parts ("V#315" manufactured by Osaka Organic Chemical Co., Ltd.) Epoxy propyl acrylate 37. 0 τ methacrylate 5.3 azobisisobutyl After the 1.7 parts of the nitrile was dropped, the mixture was further reacted at 100 ° C for 3 hours, and then 1.0 part of azobisisobutyronitrile was dissolved in 50 parts of cyclohexanone, and the reaction was further continued at 100 ° C for 1 hour. 5份和苯苯酚。 0. 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 The reaction was continued at 120 ° C for 6 hours, and the reaction was terminated when the acid value of the solid component became 0.5 to obtain a solution of an acrylic resin. Next, a solution of 33. 7 parts of tetrahydroanthracene acid (85% of the generated hydroxyl group) and 0.5 parts of triethylamine was added, and the reaction was carried out at 120 ° C for 3.5 hours to obtain a solution of an acrylic resin. The acrylic resin has a weight average molecular weight of about 15,000. 098114711 Form No. A0101 Page 51 / Total 74 pages 09831186981-0 200949440 After the cold part to room temperature, sample the resin solution about 2g, add it to 18 〇, and measure the non-volatile content of h *, , , dry 2 〇 According to the measured value, propylene glycol monomethyl ether was added to the previously obtained solution, and the non-wafer was made up to 30% by weight to prepare a resin solution 19. <Preparation of the Propionate Resin Solution 20> Into the reaction vessel, 37 parts of propylene glycol monomethyl ether acetate was placed, and nitrogen was rolled while heating to 80. 〇, at the same temperature, a mixture of the early body and the thermal polymerization initiator is dropped over a period of time to carry out a polymerization reaction. The oxime oxime is modified with acryl vinegar 50. 〇 (Osaka Organic Chemical Co., Ltd. "V #315") Epoxypropyl acrylate 3. 3 parts of methyl acrylate acrylate 42.1 parts: azobisisobutyronitrile 3. 3 parts after dripping, further l〇 (TC reaction 3 hours later Add 匕 匕 〇 〇 1.0 1.0 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解For 1.7 parts of acrylic acid (100% of epoxidized acetonide), bismuth amide phenol 0.1 part and hydroquinone hydrazine: 1 part, reacted with 1 2 0 铋 L for 6 hours, in solid When the acid value of the component is 0.5, the reaction is terminated to obtain a solution of the two acid esters. Then, 'the addition of tetrahydroanhydrous phthalic acid 3. 〇 (85% of the base) and 0.1 part of triethylamine are used. 120. (: A solution of acrylic resin is obtained at a reaction time of 35 ° C. The amount is about 15000. The weight average molecular weight of the acrylic resin is 098114711 after cooling to room temperature, Approximately 2 g of the resin solution was sampled, heated and dried for several minutes at i8 〇t, and the non-volatile component was measured. According to the measured value, propylene glycol monomethyl ether acetate was added to the previously formed resin solution to make the non-volatile form 80% Form No. A0101 Page 52 of 74 pages 0 129 281 981 200949440 Ο 30% by weight to prepare a resin solution 20. <Modulation of Acrylic Resin Solution 21> In addition to the preparation of the acrylic resin solution 2 In addition to dicyclopentyl methacrylate ("Cream-CRYLFA-513M" manufactured by Hitachi Chemical Co., Ltd.), it is synthesized in the same manner as the propionate tree, and it is prepared into a solid component of 30% acrylic resin. Solution 21. The weight average molecular weight of the acrylic resin is about 15 〇〇〇 <The plough of the acrylic resin solution 22> In addition to the preparation of the propylene-lipid solution 17, the acetal-modified acrylate is modified. In the same manner as in the case of using phenol EO-denatured propionate vinegar ("ARomMm" manufactured by Toei Seisakusho Co., Ltd.), the acrylic resin solution 22 was prepared into a solid component. The weight average molecular weight of the acrylic resin is about 15 〇〇〇 ο <Modulation of Acrylic Resin Solution 23> In addition to the modulation in the acrylic resin solution 20, the modified acrylate acrylate is modified. The ash pentane methacrylate was used in the same manner as the acrylic resin solution 20 to prepare an acrylic resin solution 23 having a solid content of 30%. The weight average molecular weight of the acrylic resin was about 15,000. 098114711 <Acrylic resin Modulation of Solution 24 > In addition to the preparation of the acrylic resin solution 16, the p-cumyl epoxide oxime acrylate was changed to a phenol E0 denaturing acrylate, and the dicyclopentyl decyl acrylate was changed to acrylic acid. The acrylic resin solution 16 was synthesized in the same manner to prepare an acrylic resin solution 24 having a solid content of 30%. The weight average molecular weight of the propylene glycol resin is about Form No. A0101 Page 53 of 74 0983216981-0 200949440 15000. <Modulation of Acrylic Resin Solution 25> In addition to the preparation of the acrylic resin solution 15, the p-cumylphenol ethylene oxide-modified acrylate was changed to phenol E0-modified acrylate, and 2-methacryloyloxyethyl group was added. The benzenedicarboxylic acid was changed to the acrylic resin solution 15 in the same manner as in the case of the dicyclopentyl decyl acrylate, and the acrylic resin solution 25 having a solid content of 30% was prepared. The acrylic resin has a weight average molecular weight of about 15,000. <Preparation of photosensitive coloring composition> First, a pigment, a dispersing agent, an acrylic resin solution, and a solvent shown in Tables 1A to 1E are mixed in a planetary ball mill using cerium oxide beads to disperse the pigment to prepare a pigment dispersion ( R-1 to R-19, G-1 to G-19, B-1 to B-19, CR_11 CR-7, CG_1 to CG-7, and CB_1 to CB-7. Further, in Table 1, the amount of each component added was a ratio (% by weight) in the following coloring composition. Next, as shown in Table 2A to Table 2E, in the pigment dispersion R (R-1 to R-19, G-1 to G_19, B-1 to B-19, CR-1 to CR_7, CG -l~CG-7^CB-l~CB-7), the acrylic resin solution, the polymerizable monomer and the solvent are stirred and mixed, and then filtered by a filter of 1 /im to prepare a photosensitive coloring composition (R01 to R19). , G01 to G19, B01 to B19, CR01 to CR07, CG01 to CG07, and CB01 to CB07). 098114711 Form No. A0101 Page 54 / Total 74 Page 98321186981-0 200949440 οο 098114711 ✓-Ν Μ 铡 Μ 实 实 实 实 ? Solvent 1 24.40 1 1 24.40 1 1 24.40 j 1 24.40 | 24.40 1 [24.40 j 24.40 | 24.40 1 24.40 I 24.40 | v£) 丨27.56 1 | 27.56 | | 27.56 1 [27.56 ] [27.56 1 27,56 ! 27.56 27.56 27.56 Resin solution 6.80 , 1 6.80 : 6.80 1 6.80 j | 6.80 ; 6.80 ί 6.80 6.80 : 6 ,80 | | 6.80 i 〇\ vo 卜 Os Ό 〇 〇 \ v〇 〇 \ \ \or~ 〇 \ vo 丨 丨 7.69 ON Ό 卜 1 7.69 | 〇 \ &lt; 〇: 7.69 1 Resin solution 1 Resin solution 2 Resin Solution 3 Resin solution 4 Resin solution 5 Resin solution 6 Bu Huan resin solution 8 Resin solution 9 ί Resin solution 10 Resin solution 1 1 Resin solution 2 | Resin solution 3 j Resin solution 4 ! Resin solution 5 Resin solution 6 Resin solution 7 1 Resin solution 8 1 Resin solution 9 Resin solution 1 0 Dispersant! L〇.-87j 0.87 0.87 ! 1 0.87 1 1 0.87 1 1 0.87 ! 0.87 £ Ο 0.87 1 0.87 1 0.99 ! 0.99 | 0.99 | ;0.99 0.99 | 0.99 099 1 0.99 ! 0.99 0,99 m ψ L 〇-5i_J 0.51 1 0-51 ! r—to 0.51 ; ί—* 〇〇1 Ρ·5ΐ J ο 1 0.51 I »rv 埏PY150 : PY150 PY150 ί | PY150 i PY150 | | PY150 1 | PY150 ί 1 PY150 ! 1 PY150 1 Ρ.Υ.150ι it 1 2.20 1 | 2.20 1 2.20 1 | 2.20 | 2.20 | 2.20 1 1 2.20 1 1 2.20 1 [2.20 I 1 2·20. 1 ο r—· 〇^ -1 〇1—Η Ο Η—Η 羝 羝PR177 PR177 : 1 PR177 1 | PR177 1 PR177 1 ________j | PR177 | IP-R-17TJ 1 PR177 ] I PR177J PR177 1 1 PY150 1 | Ρ.Υ.150 1 1 PY150 丨PY150 1 PY150 Ρ.Υ.150 I Ρ.Υ.150 1 PY150 i PY150 PY150 r-&lt; ψ v 〇ν〇v〇Ό Ό r—H o \〇*—t Ό VD VD so VO Ό v〇r-η 5; ΓΟ L 3.94 1 S; tn cn 1 to 1 3.94 1 羝1 PR254J PR254 PR254 1 PR254 j 1 PR254J | PR254 1 1 PR254 I 1 PR254 ! PR-254 I 1 PR254 JI P.G36 J 1—P.G3 6 —I | P.G36 1 P.G36 1 P.G36 II P.G36 II P.G36 1 | P.G36 I P.G36 P.G36 Pigment Dispersionψ^ 4 CS I to pci pci PC; PC; 〇〇¢ 4 〇 Pi Pi Pi Pi Pi Pi Pi Pi Pi N N N 〇Ο 〇Ο 〇Ο 〇Ο 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 1 Example 3 | | Example 4" | Example 5 I | Example 6" | Example 7 | | Example 8 I | Example 9 I | Example io | 1 Example 111 Example 12 Example 13] 1 Example 14| 1 Example 15| Example 16 Example I 7 | Example 18| | Example 19| Example 20 Form No. 1010101 Page 55/74: 0983216981-0 200949440 [0017] The composition of the pigment dispersion based on the colored resin composition as a reference (% by weight) "Tanning agent I CN r-1 f-I CN CS r-^ &lt;N &lt;S p-* ΟΪ r···* &lt;s CNl cs Cv| 04 fN (Ν ·—* «—I Resin solution CO ΓΛ CO mmm ΡΛ ΓΛ CO fO cn m ΓΛ fO C&lt;) Resin solution 1 Resin solution 2 'Resin solution 3 | Resin solution 4 1 Resin Solution 5 | Resin Solution 6 1 | Resin Solution 7 1 Resin Solution 8 | Resin Solution 9 1 1 Tree Solution ι〇1 Dispersant! 0.40 ! 0.40 1 ! 0.40 0.40 '0.40 0.40 0.40 0.40 0.40 0.40 m 言&lt;s ψ 1 0.66 1 o Ι〇·66| \〇〇! 0.66 1 0.66 1 0.66 1 1 0.66 0.66 0.66 Forging 1 PV23 1 PV23 | 1 PV23 1 |P^23j 'PV23 i PV23 1 PV23 I 1 PV23 ;PV23 PV23 vr> *—« m VT) r^tr~&lt;Ti ^T) κη ΓΛ r—Η ΓΟ r^-t VV£&gt; V〇Ό NO *〇v〇m cC Ul CQ cC |PB15: PB15: PB15: CQ cu m I-1 cd PB15 : PQ Ο; CQ a: pigment dispersion»—H PQ CQ CQ inch m CQ Ό PQ 卜 PQ 00 m 〇\ 05 O tH 1 0Q | Example 2 11 | Example 22 | Example 23 Example 24 Example 25| Example 26|Embodiment 27| Example 28 Example 29 Example 3 0 098114711 Form No. A0101 Page 56/74 Page 09321186981-0 200949440[0018] 〇:31硌(次¥«) Enough W槊 令 令 实 * * * * ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( S 卜 卜 Ο Ο & Ν — 1—* 1—♦ r~-« SSS ο 00 7,69 1 σ\ v〇Ον Ό σ\ Ό m CO I—· cn m •ο v〇Ό 卜卜 cn m ro Γ 4 tH »··&quot;&lt; m »-H &lt;N »—4 »-Η 1-1 m rH CS 1—« Pigeons are very good for you. 焕 Μ Μ 荜 m m m 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 As 〇 〇 Ο K Ο K K K K K K K K K K K K K K K K K K » » » » » » » » » » » » » » » » » » » » » » » » » » » » » » » » » » » » » » 2.20 2.20 1 2.20 ο ο Ο 〇0.66 3.66 ν〇νο 3.66 CS 实卜卜卜卜卜ο w^&gt; ο *η tn &lt;sm &lt;s ΓΛ &lt;Ν &gt;&gt;&gt;&gt; Oi Pk cu α. 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OS On Φ 〇〇〇〇〇Ο 〇Ο 〇〇d Ο o ο 〇Ο Ο Ο Φ 1— 1 to ir&gt; 1-^ ν*&gt; τ—^ 〇ο d Ο 〇Ο Ο ο ο Deben W 埯〇«Λ ο Vi »ρ»4 1—&lt; s 1—* ο ν〇&gt;ί&gt;- cw cu 〇·: so CN s Ο (Μ ο &lt;Ν 〇Ο r~t Ο o ο § ο F~H Ο ο CN CN &lt;N tN CS Οϊ Οί cs (Μ «-η T—· R—ι rH ( CS 馊Μ 坻 τ τ Μ τ τ τ — — — τ τ τ τ yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr yr Q&lt; Pi pi οί oi pi a&gt; cu Cu Pu ol 0k &quot;α; cC (ΰ &: (ΰ di (ΰ CL&gt; ai cC pigment 1 SO v〇VO v〇VO Ό Ό »~4 ο \ 〇νο ο Ό Ό r-^ VO Ό ν〇2: fn CT) ΓΛ S; CO S: 5 m ro ΓΟ : CO inch &lt;n &lt;N ?: &lt;N inch*r&gt;&lt;N 5: &lt;Ν (SU·) &lt;Ν inch fN «Ν v〇cn Ό mm VO cn ν〇Γ**&gt; v〇ΓΛ v〇 m ν〇m cn c4 οί ού ά oi Ρ 〇Ο Ο 〇Ο Ο 〇Ο 〇 cC (X oi £ (3⁄4 cC (-U 〇i UU a Cu Mh CU 〇-i pigment dispersion r-i I-&lt i Pi (S ! c&lt; CO 1 P&lt; r»· 1 Pi »η i Ρύ ν〇1 卜1—^· 1 αύ 00 f fti 〇\ r—l 1 Ρύ r*&quot;&lt; ^-4 1 o cs 1 o ΓΛ 1—( 1 ο 寸 1 ϋ w-) 1 ϋ ο 1 Ο 卜 1 a 00 1 Ο σ\ 1 a (N m ΓΛ ro ~χ W*1 ν〇00 ΓΛ Os CO o &quot ;Tt &lt;Ν 寸 inch 寸 〇 〇 寸 oo 苳 苳 苳 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 098 31 31 31 31 31 31 31御.3⁄4 W ΓΜ &lt;s 1—« &lt;N CN (Ν &lt;S (N CN f-H CS &lt;N cs CN &lt;N &lt;N &lt;N CS C4 r-&lt; ο ο 〇Ό l〇卜π Ό to V£&gt; νπ 卜C^J &lt;N «Ν Οί I—« &lt;S| cs »-H paddle rn m cn m cn cn ΓΛ m 二ΓΛ SS SO S VO Cs \〇r- 〇\ vo os v〇卜ro mm ΓΛ rate钕u 卜r-^ Μ 00 quite lacking ύα 〇, 鹊Μ 焕 & N N N N N N N N N N N N -) CN 痛的carboxy薄W~i &lt;s 姨@ 3? »n 钕% 硖回m 寒寒v-&gt; Μ Μ 钕 钕 Μ o o o o o o o o o o o o o o o o o o o o o o o o 〇〇Ο Ο ο ο ο Ο 〇〇 C C C C C C C C C C C Ψ Ψ Ψ ο ο ο ο ο & & & & & & & & & & & & & & & & & & & & & & & & & & & & & & & & & & 〇Ό 〇ν〇Ο &lt;s〇v〇o Ό Ο νο \〇ο v〇ν〇〇VO ο ο CS CS s CS o 〇〇T&quot;~&lt; ν〇s〇Ο &lt;c ν〇Ο V〇Ό Ο 贱ro CS oi cn &lt;N &gt;d; C4 &gt;Ο; m (N ΓΛ &lt;Ν &gt; CU &lt;s &gt;CL; ΓΟ CS &gt; PU fn &gt;Ο; ΓΟ CS &gt;&amp;; 卜cC 卜卜0ί (C port cC o \n a F-« - ο Ό 1—tm &gt; 13⁄4 ίΛ &lt;s &gt; cC ΓΛ ΟΊ &gt;' CU home κη ro ΚΠ mmm ΓΟ »—&lt; ν-ϊ m V) ίΛ t&quot;4 ΙΛ &lt;·Λ VO v〇**H Ό VO \〇ΓΛ s; z ΓΛ «Λ m » » m ί^ί r-* iTi to .·—&lt;珉ν〇\£&gt; χ〇V〇Ό ν〇SO ν〇VO Tf tn ew &lt;Ν ¢4 ?: cs Pu v〇mo il· ΓΛ 〇Pk Ό m 〇Cu Ό ν〇ΙΛ CO cC mt··' CQ in PQ CU ^T) ρά cu W> W α; Ό CQ cC w&gt; m pC m Ρη· u-ϊ CU »n CQ ai m Ι—i ¢0 Oh' »η CQ r~i 1 m cs I CQ ΓΟ [ 0Q for f«—1 t 1 CQ ν〇[ m 卜 1 ffi 〇〇1 m 〇\ i CO «Λ 1 oi u νο i Cd u 卜 i Di u tn 1 ou V£) fau 卜 1 ooma Ό iu 卜 1 ο 〇 \ read IK ¥ &lt;N W&quot;&gt; shame m *T) w ν〇in ¥ &lt;k ί; ΓΛ £ inch冢l〇i5 V〇卜-£ 00 1-^ On j〇莩M Leather Jj [0021] The components in Table 1A to Table 1E are as follows. <Pigment> P.R.254: C. I. Pigment Red 254 098114711 Form No. A0101 Page 59 of 74 0983216981-0 200949440

IMGACURE RED BCF PR177 : CI Pigment Red 177 manufactured by Chiba Specialty Chemicals Co., Ltd. CHR0M0PHTAL RED A2B PY·150: CI Pigment Yellow 150 E4GN PG36 from LANXESS: CI Pigment Green 36 Lionol Green 6YK PB manufactured by Toyo Ink Co., Ltd. 15:6 :C· I. Pigment B.lue 15:6 Lionol Blue ES PV23: CI Pigment Violet manufactured by Toyo Ink Co., Ltd. 23 Toyo Ink _7jc Manufacturing Co., Ltd. L i onogen Vi ο 1 et.., RL Agent> 'Solsparz 20000" manufactured by Lubrizol, Japan <Resin solution> Acrylic resin solution prepared as described above <Solvent> Propylene glycol monomethyl ether acetate <Polymerizable monomer> Dipentaerythritol hexaacrylate <Photopolymerization Starting agent 〉 2-(dimethylamine)-2—[(4-methylphenyl)methyl]-1-[4-(4-morpholinyl)phenyl]-1 butyl sulfonate Agent 2,4 -Diethylthioxanthone 098114711 Form No. A0101 Page 60 of 74 page 98321186911-0 200949440 098114711 Application &lt;1 ηρΐ Rong 43⁄4 Solvent 53.90 53.90 53.90 53.90 I 53.90 I 1 53.90 1 53.90 53.90 53.90 53.90 52.30 52.30 52.30 52.30 ! 52.30 i 52.30 52.30 52.30 52.30 52.30 Sensitizer 0.27 0.27 0.27 &lt;N Ο 0.27 ο 0.27 卜o 0.27 0.27 0.27 0.27 ! 0.27 0.27 | ! 0.27 ο 0.27 0.27 0.27 0.27 Photopolymerization initiator OQ 〇00 〇 |_.丨丨· 〇〇〇οο 00 FH 00 οο OO 00 s 00 o 00 ο 00 00 〇00 〇οο 1—&lt; 00 οο ο *—« 〇〇οο τ—· Polymeric monomer 00 &lt; n 00 ΓΟ 00 m οο ΓΛ ro 3.38 ; οο ΓΛ ΓΛ οο 00 mm 00 cn CO OO cn 00 ΓΛ fO 00 m ro OO m 00 en ΓΛ 00 m (Ti 00 ΓΛ 00 ΓΛ ΓΛ 00 mm 00 cn m 3.38 Resin solution 4.95 1 4.95 4.95 4.95 4.95 1 4.95 4. 4.95 I 4-95 ; 4.95 "4.95 | S &gt; · -IS % % Ο ΟΟ r-» S Ο 00 «—* S r·^ Ο 00 S Resin solution 1 Resin solution 2 Resin solution 3 ! Resin solution 4 1 Resin solution 5 | 1 Resin solution 6 Resin solution 7 i Resin solution 8 | Resin solution 9 I Resin solution 10 | Resin solution ii | Resin solution 2 1 | Resin solution 3 1 i Resin solution 4 Resin Solution 5 1 ! Resin solution 6 Resin solution 7 Resin solution 8 Resin solution 9 Resin solution 1 0 Pigment dispersion 36.45 36.45 | 36.45] 36.45 1 . j | 36.45 | 1 36.45 Π I 36.45 II 36.45 I | 36.45 II 36.45Π 00 tH ΟΟ οο inch〇〇ϊ-1 οο «-Η οο 00 00 inch οο τ—&lt; 00 1 1 Ρύ CO i inch I νο 1 卜 i Pi 00 IC^i Os I 〇I »—H 1 〇CN ioi Ο inch 1 〇ο ν〇ο 卜 i Ο 00 1 ο 〇\ 1 Ο ο 1 Ο R01 | R02 1 R03 1 R04 1 1 R05 ·| 1 R06 1 | R07 | | R08 | R09 ] I Rio I | G01 | | G02 | G03 G04 1 G05 G06 GO 7 G08 G09 G10 Example 1 Example 2 Example 3 1 Implementation Example 4, 1 Example 5 i β Example 6| Example 7 j | Example 8 II Example 9 I 丨 Example l〇j | Example 12| #例13| Example 14 1 Example 15| 1Example 16| 1 Example 17| 1 Example 18| 丨 Example 19| 1 Example 20| Form No. 1010101 Page 61/74 page 09321 981 981-0 200949440 [0022] :s&lt;Cai «3 Liu solvent 60.40 60.40 60.40 60.40 60.40 60,40 60.40 60.40 60.40 60.40 Sensitizer 0.27 0,27 1 0.27 0.27 : Bu ci ο 0.27 0.27 ! 0.27 0.27 0.27 Photopolymerization initiator 00 〇r-&lt; ΘΟ ο 00 ο 〇〇00 ο 00 »—x oo 00 o »—1 00 1.08 Polymeric monomer op mm 00 m QO m 3.38 00 m 00 mm CO CO CO 00 m 00 CO cn 3.38 Resin solution 1 18.08 1 1 18.08 1 [18-08 1 00 o 00 1 18.08 1 oo Oo 1 18.08 I 00 00 lH LIS·. , -1 ! 18.08 | Resin solution 1 Resin solution 2 1 Resin solution 3 Resin solution 4 : Resin solution 5 i Resin solution 6 @脂溶液7 | Resin solution 8 Resin solution 9 Resin solution 1 0 Pigment dispersion boat 1 16.76 1 1 16.76 1 1 16.76 i 1 16.76 1 1 16.76 1 1 16.76 1 | 16.76 1 i 16.76 | ! 16.76 16.76 1 CQ &lt;N PQ 1 © inch 1 CQ ΙΓ&gt; 1 CQ 1 m oo 1 CQ Os 1 CQ ο j 03 Sensitivity Coloring composition B01 1 B02 1 B03 B04 1 BOS i [B06 | | B07 | | B08 I | B09 1 B10 | Example 2 11 1 Example 22 | Example 23: Example 24: | Example 25 | Example 26| |Example 27| 丨Example 28| |Example 29| |Example 30| 098114711 Form No. A0101 Page 62 of 74 0983216981-0 200949440[0023] ° ° 098114711 Form No. A0101 oo

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SS 905 61 f f 壬 ί [ 0026 0026 [0026] The photosensitive coloring composition obtained in the above examples and comparative examples was evaluated for dispersion stability, developability, and reworkability by the following methods. The results are shown in Table 3. 098114711 Form No. Α0101 Page 65 of 74 0983216981-0 200949440 <Dispersion Stability Evaluation> Using an E-type viscometer (TUE-20L type manufactured by TOKI SANGY0 Co., Ltd.), the photosensitive coloring composition was measured at a rotation number of 20 rpm. Viscosity at °C. The viscosity of the photosensitive coloring composition was measured as the initial viscosity (7? 〇 · mPa · s), and the photosensitive coloring composition was measured at 4 Torr. The viscosity of the thermostat chamber of 0 was stored for 7 days (777:1!^&.3), and the viscosity ratio (7? 7/;? 0) was calculated. Then, the following criteria were used to evaluate the dispersion stability. 〇:7?7/;?〇 is less than 1.20, almost no increase in viscosity, good dispersion stability △: β 7/ π 0^. 2〇 or more, less than 丨.5〇, slightly observed viscosity increase, dispersion stability Some poor I, X: Above 1.50, the viscosity increases significantly and the dispersion is not stable. <Evaluation of developability> On a transparent glass substrate of 1〇Xl〇Cm, the photosensitive coloring composition was spin-coated, and the film was baked for 2 minutes in (10) to form a dry film thickness and a film thickness (Tl). . Next, the ultraviolet rays were exposed at an exposure amount of 5 〇 mj, developed with a developing solution for 50 seconds, and the film after development (T2) was measured to calculate a film thickness ratio (T2/Tl). The evaluation criteria are as follows. Ο. Film thickness ratio (Τ2/Τ1) 0.95 or more X: Film thickness ratio (Τ2/Τ1) is less than 〇. 95 <Reworkability evaluation> The film formation substrate for the above-mentioned developability evaluation is carried out at 23 CTC for 90 minutes. After the post-baking, the cut was 1. 5 cm square and used as a sample. In the culture dish, add 2 mL of re-doping solution (materials 098114711 Form No. A0101, page 66/74 pages 0983216981-0 200949440 SEMICLEAN DF —7), and immerse the sample in the redo liquid for 5 minutes. After 5 o'clock, the redo liquid and the sample were transferred from the culture dish to the round bottom test tube, and the rework liquid containing the peeled coating film was filtered by a 5&quot;«η aperture, diameter 3 cm filter paper, and the size was used. An optical microscope for measuring the function, and measuring the size of the peeling sheet spread out on the filter paper. The measurement conditions are measured by an optical microscope at a magnification of 5 〇〇 at an interval of 4 points from the center of the filter paper at a distance of 1 cm from the center of the filter paper, totaling 5 points, and the length from the longest part of the release sheet is the largest. The point is measured one by one, and the average value of the longest part is obtained. The evaluation criteria are as follows. ◎: Dissolved (no peeling sheet confirmed by optical microscope) 〇: The longest part of the peeling sheet is less than 300 △: The longest part of the peeling sheet is 30 〇 or more and less than 500/zm X : The longest part of the peeling sheet is 5 0 0 is more than m, less than 1 〇〇〇# m XX : The longest part of the peeling piece is 1000 / zm or more 098114711 Form No. A0101

Page 67 of 74 0983216981-0 200949440[0027] Table 3A:

Initial viscosity (r|0:mPa · s) 40〇C ' 7曰 Promoted viscosity: “7: mPa · s) (η7/η0) Dispersion stability developability evaluation Reworkability evaluation Example 1 3.0 3.0 1.00 〇〇 ◎ Example 2 3.1 3.1 1.00 〇〇 ◎ Example 3 3.1 3.1 1.00 〇〇 ◎ Example 4 3.2 3.2 1.00 〇〇 ◎ Example 5 3.1 3.3 1.06 〇〇 ◎ Example 6 3.1 3.1 1.00 〇〇 Δ Example 7 3.1 3.1 1.00 〇〇 Δ Example 8 3.1 3.1 1.00 〇〇 Δ Example 9 3.1 3.5 1, 13 〇〇 ◎ Example 1 0 3.2 3.5 1.09 〇〇 ◎ Example 11 3.0 3.0 1.00 〇〇 ◎ Example 1 2 3.1 3.1 1.00 〇〇 ◎ Example 1 3 3.1 3.1 1.00 〇〇 ◎ Example 14 3.2 3.2 1.00 〇〇 ◎ Example 1 5 3.1 3.3 1.06 〇〇 ◎ Example 16 3.1 3.1 1.00 〇〇 Δ Example 1 7 3.1 3.1 1 , 00 〇〇 Δ Example 1 8 3.1 3.1 1.00 实施 Example 1 9 3.1 3.5 1.13 〇〇 ◎ Example 20 3.2 3.5 1.09 〇〇 ◎ Example 21 2.9 2.9 1.00 〇〇 ◎ Example 22 3.0 3.0 1.00 〇 〇◎ Example 23 3.0 3.0 1.00 〇〇◎ Example 24 3.1 3.1 1.00 〇〇 ◎ Example 25 3.0 3.2 1.07 〇〇 ◎ Example 26 3.0 3.0 1.00 〇〇 Δ Example 27 3.0 3.0 1.00 〇〇 Δ Example 28 3.0 3.0 1.00 〇〇 Δ Example 29 3.0 3.4 1.13 〇〇 ◎ Example 30 3.1 3.4 1.10 〇〇 ◎ Comparative Example 1 3.5 4.2 1.20 Δ 〇 Δ Comparative Example 2 3.2 3.8 Κ 19 〇〇 XX Comparative Example 3 3.4 4.1 1.21 Δ 〇 XX Comparative Example 4 3.2 3.9 1.22 Δ 〇 XX Comparison Example 5 3.5 4.2 1,20 Δ 〇Δ Comparative Example 6 3.3 3.9 1.18 〇〇XX Comparative Example 7 3.4 4.1 1.21 Δ 〇XX Comparative Example 8 3.2 3.9 1.22 Δ 〇XX Comparative Example 9 3.4 4.1 1.21 Δ 〇Δ Comparative Example 1 0 3.1 3.6 1.16 〇〇XX Comparative Example 11 3.3 * 4.0 1.21 Δ 〇 XX Comparative Example 1 2 3.1 3.8 1.23 Δ 〇 XX 098114711 Form No. A0101 Page 68 of 74 0983216981-0 200949440 Table 3B:

Initial viscosity (ηΟ: ΓηΡβ · s) 40〇C, 7曰 promoted viscosity (“7: mPa · s) (η7/η0) Dispersion stability spectacles evaluation Redo evaluation Example 3 1 3.0 3.0 1.00 〇〇 ◎ Example 32 3.0 3.0 1.00 〇〇〇 Example 3 3 . 3.1 3.1 1.00 〇〇. ◎ Example 34 3.1 3.3 1.06 〇〇© ★ Example 3 5 _ 3.1 3.1 1.00 〇〇〇 Example 36 3.1 3.3 1.06 〇 〇© Example. 37. 3.1 3.1 1.00 〇0 厶 ★ Example 38. 3.1 3.4 1.10 〇〇〇 Example 39 3:2 3.7 1.16 〇. 〇〇 Example 40 3.1 3.1 1.00 〇〇 ◎ Example 4 1 3.1 3.1 1.00 〇〇〇 Example 42 3.2 3.2 1.00 〇〇 ◎ Example 43 3, 2 3.4 1.06 〇〇 ◎ Example 44 3.2 3.2 1.00 〇〇〇 Example 4.5 3.2 3.4 1.06 ◎ ◎ Example 46 _ 3.2 3.2 1.00 〇〇 "〇例例47 3.2 3.5 1.09 〇〇〇Example 48 3.3 3.8 1.15 旄Example _ 4 9 2.9 2.9 1.00 〇〇 ◎ 实 _ Example 50 2.9 2.9 1.00 〇〇〇 Example 5 1 3.0 3,0 1.01 〇〇◎ Example 52 3.0 3.2 1.07 〇〇◎ Female Example 53 3.0 3.0 1.00 〇〇〇 Example 54 3,0 3.2 1.07 〇〇◎ Example 5 5 3,0 3.0 1.00 〇〇〇Example 56 3.0 3.3 ι.ια 〇〇〇Example 57 3.1 3.6 1.16 〇〇〇Comparative Example 1 3 3.5 5.3 1.51 X 〇Δ Comparative Example 14 3.2 3.9 1.22 Δ X XX Comparative Example 1 5 3.2 3.9 1.22 Δ 〇X Comparative Example 16 3,5 5.3 1.51 X 〇〇 _ Comparative Example 1_7 3.3 4.0 1.21 Δ X XX Comparative Example 1 8 3.2 3.9 1.22 △ 〇X Comparative Example 19 3.4 5, 2 1.53 X 〇〇 Comparative Example 20 3.1 3.8 1.23 AX XX Comparative Example 21 3.1 3.8 1.23 Δ 〇X ❹ [0028] Relative to Comparative Example 1 The photosensitive coloring composition of ～21 is excellent in long-term storage property and developability, but the reworkability is not good, and it is understood that the photosensitive coloring compositions of Examples 1 to 5 of the present invention maintain long-term storage stability and developability as they are. Excellent redo. [Simple description of the diagram] [Explanation of main component symbols] 098114711 Form No. A0101 Page 69 of 74 0983216981-0

Claims (1)

200949440 VII. Patent application scope: 1. A photosensitive coloring composition characterized in that it contains a resin, a coloring agent, a photopolymerization initiator, a polymerizable monomer and a solvent; the resin is a vinyl polymer It consists of a constituent unit (a) represented by the following general formula (1), a constituent unit (b) containing a carboxyl group, and a constituent unit (c) other than the constituent units (a) and (b); General formula (1): (1) 3 (In general formula (1), R1 is hydrogen i: 1 or methyl, and R2 is an alkylene group having 2 or 3 carbon atoms. R3 is a carbon number which may also contain a hydrogen atom or a benzene ring. ~2〇 of the alkyl ' 1. is an integer of 1 ^ 1 5). 2. The photosensitive coloring composition of claim 1, wherein the constituent unit (b) is a constituent unit (bl) and/or a constituent unit (b2); and the constituent unit (bl) is a general formula (2) expressed as: 098114711 Form No. A0101 Page 70 / Bing · 74 pages 0983216981-0 200949440 (In general formula (2), R4 is a hydrogen atom or a methyl group, and X1 is a group represented by the general formula (3): [In the general formula (3), R5 is an alkylene group having 2 to 12 carbon atoms, m is an integer of 1 or 2], and Y1 is a group represented by the general formula (4): ❹ [In general formula (4), R6 is a sub-alkyl group containing 2 to 20 carbon atoms in the main chain, a cyclic alkylene group containing 6 to 8 ring carbon atoms, or 6 to 14 rings. An arylene group of a carbon atom, η is an integer of 0 or 1]); the constituent unit (b2) is a constituent unit represented by the general formula (5) (d) an unsaturated monovalent acid is added, and a hydroxyl group is added Obtained by polyvalent acid anhydrate; general formula (5) 098114711 Form No. A0101 Page 71 of 74 page 09831186981-0 (5) ?7200949440 c—O—R8 II 〇 (In general formula (5), R7 is a hydrogen atom or a fluorenyl group, and R8 is a glycidyl group, methyl glycidyl group, 3, 2~j裒oxy^ | Ethyl ethyl, 3,4 epoxycyclohexyl, 3,4-epoxybutyl or 4 5 epoxybenzyl). 3. The photosensitive coloring composition of claim 1, wherein the aforementioned constituent unit (c) does not have a hydroxyl group. 4. The photosensitive coloring composition of claim 1, wherein the resin is constituting a unit (a) precursor (a') 丨 〜 35 wt%, and the constituting unit (b) b)) 10 to 90% by weight and a vinyl-based polymer obtained by copolymerizing the material (c,) 丨 to 75% by weight before the constituent unit (c). The photosensitive coloring composition according to claim 1, wherein the resin is 1 to 35 wt% of the precursor (a) before the constituent unit (a), and the precursor (d) is a precursor (d) ') 4 to 75 wt% and the above-mentioned constituent unit (c) precursor (c') 1 to 75 wt% of a vinyl polymer obtained by copolymerization of an unsaturated monovalent acid, followed by formation of a hydroxyl group A resin obtained by adding a polyvalent acid anhydride. Such as the scope of patent application! The photosensitive coloring composition, wherein the aforementioned constituent unit (a) precursor (a,) comprises p-cumylphenol ethylene oxide 098114711, the form number is deleted, page 72 of 74 pages '200949440 and/or Propylene oxide denatured (meth) acrylate. 7. The photosensitive coloring composition of claim 1, wherein the precursor (C) of the aforementioned constituent unit (C) comprises an alkyl (meth)acrylate. The photosensitivity of the scope of the patent application is as follows. a coloring composition wherein the aforementioned constituent unit (C) precursor (c,) comprises benzyl (meth) acrylate and/or bicyclopenta(indenyl) acrylate, and/or dicyclopentenyl (fluorenyl) Acrylate and/or cyclopentaoxyethyl (fluorenyl) acrylate. An I color filter characterized by comprising a light-receiving sheet section and/or a black matrix formed from the photosensitive coloring composition of any one of items 1 to 8 of the patent application. 098114711 Form No. A0101 Page 73 of 74 0983216981-0