TW200948907A - Coloring curable resin composition, color filter, liquid-crystal display, and organic el display - Google Patents

Abstract

A coloring curable resin composition (ink) which, when used in producing a color filter by the ink-jet method, can reconcile pixel surface smoothness with wetting properties and spreadability within pixel banks. The coloring curable resin composition comprises (a) a colorant, (b) a binder resin, (c) an organic solvent, and (g) a surfactant, wherein at least 80 wt.% of the organic solvent (c) is accounted for by a solvent (c-1) having a boiling point of 180 DEG C or higher (boiling point measured at a pressure of 1,013.25 hPa). A 0.02 wt.% solution of the surfactant (g) in the solvent (c-1) has a surface tension in a specific range and a contact angle in a specific range with a glass substrate.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a colored curable resin city, a color filter, a liquid crystal display device, and an organic EL display. More specifically, it relates to a color-curable resin composition having a coating film flatness and a wet lake spreadability suitable for image formation by an inkjet method when a color filter is manufactured, and the colored curable resin is used. A color filter and a light sheet of the composition are used to provide a liquid crystal display device and an organic EL display having the color filter. [Prior Art] In the color filter manufacturing technology, it has been practical to use a inkjet method in a pixel bank (Pixel bank), that is, a region of a slightly rectangular recess surrounded by a black matrix, into which a coloring material (ink) is driven. A method of forming a pixel. As a basic quality required for color 4, for example, the coating of the pixel is good in flatness, that is, unevenness due to unevenness or offset, and wrinkle-free or secret. In addition, in order to improve the process or increase the yield, it is important that the wettability of the ink droplets is good in the surface of the liquid surface, and the droplets are regenerated, and the desired liquid can be filled in the pixel bank. The amount of ink. However, (4) the ink method _ the dry job of the tiny droplets on the substrate, has not been fully exemplified. Therefore, it is only possible to perform an empirical and trial-and-error adjustment for obtaining a surface coating process condition or an oil "face" which does not cause the above-mentioned coating film defect. 97136291 200948907 The wet expansion mechanism of the tiny droplets attached to the substrate by the inkjet method is also not fully clarified in theory. That is, the fine spreading behavior of the droplets and droplets around 1/L can be almost determined by the fine liquid properties such as contact angle or viscosity, but the number of nozzle inks is small to several tens of pL. The wetting propagation behavior of the droplets is not related to it. Therefore, there is a large trade-off between the wet spreadability and the flatness of the pixels. For example, if the fluidity of the ink is improved, coating film disturbance is likely to occur during drying. ❹ For this (4) question, for example, a special towel is provided to reveal the method of preventing the unevenness of the colored layer by adding a surfactant to suppress the change in the surface tension temperature of the ink. However, the surfactant described in this document is likely to impair the discharge stability of inkjet by lowering the surface tension of the ink itself. Further, although it is difficult to predict from general knowledge, the ink described in this document has a problem of reducing the spreadability of the fine droplets attached by the nozzle ink method. Patent Document 1: Japanese Laid-Open Patent Publication No. Hei 7-216276 (Invention) The object of the present invention is to solve the above various problems of the prior art, and in particular, to provide Y species. The coloring and hardening tree test (ink), which is formed by the method of the ink method and the color of the shirt, will satisfy the flatness and wetness of the pixel with a lot of trade-off relationship. Another object of the present invention is to provide a color filter using the color of the color-curable resin composition, and a liquid crystal display device and an organic EL display having the color filter (Resolved) The means of the problem) • The authors and others have worked hard to solve the above problems, and found that although the detailed mechanism of action is still unclear, the surface tension is moderately low and the interface with the substrate is used. The color-curable resin composition having a high tension is sufficient to satisfy both the flatness and the spreadability of the pixel. By lowering the color of the sturdy resin, the city's secret power is higher than that of the pixel, but if it is too low, it will lower the tendency of the scent of the ink nozzle. Further, by making the interfacial tension between the substrate and the substrate not excessively increased, the wet spreadability in the pixel bank can be improved. In order to satisfy such a color hardening resin composition, it is effective to use a specific surfactant. Specifically, it has been found that a thin solution of a surfactant prepared according to a certain condition has a specific range of contact angle and surface tension, and it is effective to use the surfactant. Further, it has been found that in order to obtain such a colored curable resin composition, it is effective to have a fluorine-based surfactant containing a specific structural polyether polymer having a pentagonal short fluorinated alkyl group. It has been found that by using such a surfactant, the surface tension of the composition can be prevented from being lowered too much, and the wet spreadability in the pixel bank and the surface flatness of the obtained pixel can be improved. Further, it is understood that the effect of the present invention is more remarkable particularly in the case where a partitioning agent containing a block copolymer having a specific structure is used in combination. That is, the gist of the present invention is as follows. 97136291 5 200948907 [1] A color-curable resin composition' contains at least (a) a color material, ((7) a binder resin, (C) an organic solvent, and (g) a surfactant, and has a boiling point of 180°. The solvent (c-1) of c or more (boiling point under the pressure of 1013.25 [hPa]) accounts for 80% by weight or more of (c) the organic solvent, and (g) interfacial activity prepared by using the solvent (c-1)剂2% by weight of the solution satisfies the following conditions (1) and (2): (1) The contact angle to the glass substrate is 1 〇. Below; (2) The surface tension σ is relative to the surface of the solvent (ci) (27) The colored curing resin composition of the above [1], wherein (g) the surfactant contains the following general formula (1) ) the compound shown, [Chemical 1]

(wherein, 匕 represents an alkylene group having 2 to 6 carbon atoms, R 2 represents an alkylene group having 2 to 3 carbon atoms, R 3 represents a hydroxyl group or a hydrogen atom, and G represents a fluorinated alkyl group having a carbon number of 4. 4, v, w And u each independently represent an integer of 〇~2, x and t respectively represent i or 2, s represents an integer of 0 to 10. n represents an integer of 2 to 1 ,, 97136291 6 200948907, and a complex number in one molecule When the following side chain is used, [Chemical 2]

❹ They can be the same or different bases, respectively. [3] The colored curable resin composition according to the above [2], wherein the compound represented by the above general formula (1) is a compound represented by the following general formula (0), [Chemical 3] HO one by one

广〇\xG

GHg —0~0Η2 一〇——*j-j ch3

(In the above formula, the substituent G represents a fluorinated alkyl group having 1 to 4 carbon atoms, and n represents an integer of 2 to 1 Å.) [4] The composition of the color-curable resin described in the above [2] or [3] In the above general formula (10) or the general formula (〇), the substituent G is a perfluoroalkyl group having a carbon number of 丨3, and η is an integer of 5 to 30. [5] The colored curable resin composition according to any one of the above [1], wherein the condition (2) is the following condition (3), and (3) the surface tension σ is 28 mN/m or more. And less than 30mN/m. [6] The colored curable resin composition according to any one of the above [5], wherein, in the above condition (1), the contact angle with respect to the glass substrate is less than 5. . [7]—The coloring-stable resin composition s contains at least (a) a color material, (1) a binder resin, (c) an organic solvent, and (g) a surfactant, and has a boiling point of 180 〇. The solvent (c-1) of C or more (boiling point under the pressure of 1013.25 [hPa]) accounts for 80% by weight or more of (c) the organic solvent, and (g) the surfactant contains the following general formula (1). Compound, 〇[化4] ΗΟ- •R,—0' η Ή do) h2c- -〇R2~^R3 〇 (wherein, Rl represents an alkylene group having a carbon number of 2 to 6 'R2 represents a carbon number of 2~ 3 is an alkyl group, the heart represents a secret or a hydrogen atom, and G represents a fluoride wire of carbon number 4. The v, w, and u respectively represent an integer of 〇~2, χ and t points _ stand for i or 2, s An integer of 〇~1〇 is represented. n represents an integer of 2 to 100, and when a plurality of the following side chains are contained in one molecule, [Chem. 5] 97136291 8 200948907 These may be the same or different groups, respectively. [8] The colored curable resin composition according to the above [7], wherein the compound represented by the above general formula (1〇) ❹ /V c or c ΛΓ \ 0Rz/7R3 is the following general formula (〇) Compound shown, [Chem. 6]

•G (〇) H〇--|-CH2—? A CH2 — 〇-|—ΗCH3 n (In the above formula, the substituent G represents a fluorinated alkyl group having 1 to 4 carbon atoms, and n represents an integer of 2 to 1 。.) ❹ [9] as described above [7] Or a colored hardening composition, wherein, in the above general formula (10) or the general formula (0), the substituent G is an all-gas base of carbon number 3, and η is 5 to 30 Integer. [10] The above [1] to [9] towel-n-staining curable resin composition, wherein the content of '(g) surfactant is about 5 to 5 % relative to the total solid content. % ° • [11 As described above (1) to [1咐任- slave color hardening performance composition, wherein the content of the (4) color material relative to the total solid content is 1{), the weight of 97136291 9 200948907 is the content of the binder resin is 80 4 The amount %' and (c) the content of the organic solvent is 5 〇 to 99% by weight. [12] The colored curable resin composition according to any one of the above [1] to [11], wherein the 'medium' (a) color material contains a pigment. [13] The colored curable resin composition according to the above [12], which further comprises (e) a dispersing agent. [14] The colored curable resin composition according to [13] above, wherein the hydrazine dispersant ❹ contains a ruthenium formed by an A block having an amine group in a side chain and a β block having no amine group at a side chain. a block copolymer and/or a β-Α_Β block copolymer, and the block copolymer has an amine value of 1〇mgK〇H/g or more (in terms of effective solid content). [15] As described above [1] to [14] The colored curable resin composition according to any one of [14], wherein the solvent (c-1) having a point of 180 C or more (boiling point under a pressure of 1013.25 [hPa]) is selected from the group consisting of Alcohol mono-n-butyl ether acetate, diethylene glycol monoethyl ether acetate, dipropylene glycol monomethyl ether acetate, hydrazine, 3-butanediol diacetate, © 1 '6-hexanol monoacetate And a colored curable resin composition according to any one of the above [1] to [15], wherein a boiling point of 180 C or more (pressure 1013.25 [hPa]] The solvent (c-1) of the boiling point of the solvent is a di-glycol mono-n-butyl ether acetate, wherein the color-curable resin composition of any one of the above [1] to [16], wherein ,relatively (c) The coloring-hardening resin composition of any one of the above-mentioned [1] to [17], wherein 'the glass substrate is relative to the glass substrate. The contact angle is less than 5. 97136291 10 200948907 [19] A color-curable resin composition containing the color-hardening resin composition of any of the above [^ to the mouth and used for inkjet color filter [20] The color filter is formed by using the color-curable resin composition according to any one of the above [1] to [19]. [21] A liquid crystal display device is provided with the above [20] [22] An organic EL display is provided with the color filter of the above [2〇]. (Effect of the invention) 〇 According to the present invention, color can be provided in the ink color method When the pixel of the filter is formed, the color-curable resin composition having good pixel flatness and wet spreadability can produce a color filter with good quality and good yield, and can provide a liquid crystal display device in a large amount and at low cost. [Embodiment] Hereinafter, the embodiment of the present invention will be described in detail. The description of the constituent elements described below is an example (representative example) of the embodiment of the present invention, and the present invention is not limited to the above, and is not limited thereto. [1] Composition of ochre curable resin The colored curable resin composition of the present invention is characterized by comprising at least (a) a color material, (b) a binder resin, (c) an organic solvent, and (g) a boiling point of a surfactant, and a temperature of 180 ° C or higher (pressure 1013) The solvent (cy) of the boiling point under the condition of 25 [hPa] accounts for 80% by weight or more of (c) the organic solvent, and the (§) surfactant is prepared by using the solvent (ci). The 02% by weight solution satisfies The following conditions (1) and (2). U) The contact angle to the glass substrate is 10° or less; 97136291 11 200948907 (2) The surface tension σ is the surface tension σ with respect to the solvent (cq). (σ〇-2) S ¢7 < C (J 〇〇 Further, the color hardening resin composition of the present invention is characterized by containing at least a color material, (b) a binder resin, and (C) an organic solvent. And (g) surfactant boiling

Point 180 (: above (the boiling point under the pressure of 1013. 25 [hPa]) solvent (CD accounts for 8% by weight or more of (c) organic solvent, (4) the surfactant contains the following general formula (1) Compound. 〇[化7]

(1〇) ❹ (wherein, the wire showing the carbon number of 2 to 6 indicates that the carbon number is 2, and the base is hydrogen or a hydrogen atom, and G is the carbon of the carbon number w. v, w And u each independently represent an integer of 0 to 2, χ and t are respectively represented independently] or 2, s represents not (an integer of M0. n represents an integer of 2 to 1 ,, and further, the following includes a complex number in one molecule Side key [化8] 97136291 12 200948907

or

• J U can be the same or different bases. In the following, each constituent component of the colored curable resin composition of the present invention is described, and "(meth)acrylic acid" or "(meth)acrylate" means "acrylic acid and/or mercaptoacrylic acid", for example, " (Mercapto) acrylic means "acrylic and/or methacrylic". Further, "(co)polymer" means "single polymer (homopolymer) and/or copolymer (copolymer)". The "total solid content" means the total component in the curable resin composition of the present invention other than the solvent component described later. The weight average molecular weight (Mw) of the resin (co)polymer is a value in terms of polystyrene measured by GPC (gel permeation chromatography). The "amine price" is, unless otherwise specified, the value of the amine in terms of the effective solid content, expressed as the weight of the solid content of the dispersant per lg of alkali and the weight of the equivalent K〇H. Further, the measurement method will be described later. Further, in the following, the colored curable resin composition may be simply referred to as "ink". (g) surfactant The (g) surfactant of the present invention is prepared by using the above solvent (6)) (g) 97136291 200948907 The 0.02% by weight solution of the surfactant satisfies the following conditions (1) and (2) By. (1) The contact angle to the glass substrate is 1 〇. (2) The surface tension σ is relative to the surface tension of the solvent (ci), which satisfies -2) ^ σ < σ 〇 ° by using the (g) surfactant which satisfies the above conditions (1) and (2) In addition, the interfacial tension and surface tension of the colored curable resin composition with the substrate can be suppressed within an appropriate range, and as a result, the wet spreadability of the colored curable resin composition in the pixel bank and the surface flatness of the resulting pixel can be improved. . It is a matter of course that the surfactant used for the pixel-forming composition for a color filter has an effect of lowering the surface tension of the composition containing the composition, thereby improving the coating property of the composition or The surface smoothness of the obtained coating film is enhanced. However, the 'other aspect' has almost no effect of increasing the interfacial tension between the substrate and the substrate. An increase in the interfacial tension between the composition and the substrate results in wet extensibility in the pixel bank of the composition. ❹ This & Ming coloring curable resin group a system is a 0.02% by weight solution containing (g) surfactant prepared by using solvent (c-1) (hereinafter referred to as "(4) interface active solution" The contact angle with respect to the glass substrate is 1 "the following surfactant, and the wettability in the pixel bank is remarkably improved. (g) Interface The contact angle of the biocant's solution with respect to the glass substrate is preferably less than 5. . (g) The surface tension of the surfactant solution (the surface tension of the 7-mesh to the solvent (c") is (.-2). When it is below (below), it is spouted from the inkjet nozzle. The fine droplets cannot be formed smoothly, and the spit out property becomes 97136291 200948907. The surface tension σ of the surfactant solution is less than the surface tension σ 溶剂 of the solvent (C4) of the solvent. σ is preferably 28 mN/m or more and less than 30 mN/m. As the (g) surfactant in the color-curable resin composition of the present invention, the compound represented by the following formula ((8)) can be exemplified.

, J U ❹ R 1 n represents a carbonic acid base of 2 to 6 and the core represents a carbon number of 2 to 3, and 〇

Correction: The second is the gasification of the carbon number. " and U shows the integer number of (4), ... divided into two or two, 3 table, the main sigh. η represents an integer of 2 to 100, and, in the case where the 1 [Chemical 10] knife contains a plurality of the following side keys, 97136291 15 200948907

They may be the same or different bases, respectively.

In J U ❹ ), 匕 is a stretching base having a carbon number of 2 to 6. If the number of breaks is too large, there is a possibility that the hydrophilicity of the chemical substance is lowered. As &, preferably, an alkylene group having 2 to 4 carbon atoms. In the above formula (10), Ra represents a trans group or a chlorine atom. When the value of s described later is 0, R3 is preferably a hydrogen atom, and when S is an integer of 10, R3 is preferably a meridine. In the above general formula (10), v, W, and U each independently represent an integer of 〇~2, and x and t are independently 1 or 2, and 3 represents an integer of 0 to 1 。. Both t and u are 2 in the lower part. However, if the value is 3 or more, the steric hindrance may occur and the desired performance may not be obtained. In the above general formula (10), n represents an integer of 2 to 1 Å, preferably an integer of 5 to 3 Å. If η exceeds 1 Torr, the molecular weight is too large, which may impair the possibility of solubility. Further, if η is less than 2, the molecular weight is too small, which may impair the stability in the solution. Among the compounds represented by the above general formula (10), a compound represented by the following general formula (0) is particularly preferable. 97136291 16 200948907 H〇+ch2—Bu called—Bu H HCh3 n In the above formula (8), the substituent G represents a fluorinated base of carbon number 4, and n represents an integer of 2 to exemplified. In the compound represented by the above formula (0), the substituent G represents a gasification group having a carbon number of 4 and a carbon number of 3. When the carbon number is 5 or more, the volume of the substituent portion becomes too high, and the possibility of alignment with the interface (4) is impaired. Among them, preferred is a perfluoro group in which all hydrogen atoms are replaced by fluorine atoms. Further, the number of carbon atoms substituted by fluorine is difficult to be three, more preferably two or two. When four or more carbon sources are replaced by fluorine, there is a case where the harmfulness accumulated in the human body is exhibited. Specific examples of such a substituent G include _CF3, _CF2CF3, _CF2C2Fs®, and the like, and particularly preferably -CF3 or -CF2CF3. In the general formula (0), η represents an integer of 2 to 1 ,, and preferably represents an integer of 5 to 3 。. If η exceeds 100', the molecular weight is too large, which may impair the solubility. Further, if η is less than 2, the molecular weight is too small, which may impair the stability in the solution. Among the compounds represented by the general formula (0), the most preferred compound is, for example, the following compound. [Chem. 12] 97136291 17 200948907 o-ch2- O~CH, och2cf3 ch2 —ch2-ch3 (i) ?ch2cf3 ch2 , -OH H-

•O-CH OCH2CF2CF3 ch2 -ch2-

OH CHa (ii) OCH2CF2CF3 ch2 ch2-

• OH 〇~ΌΗ2- *ch2-

.OH Ο In addition, CHs ”20 L CH3(m) (iv) The compound represented by the general formula (0) is commercially available. For example, “PF-636” and “PF-656” manufactured by OjUNOva 20 Co., Ltd. can be used. "PF-6320" and "pf-6520" (both are product names). Further, from the viewpoint of wet spreadability in the pixel bank, the coloring curable resin composition preferably has a small contact angle with a transparent substrate of a color filter to be described later. For example, in the case of the colored curable resin composition of the present invention, the contact angle with respect to the glass substrate (cleaning glass) is less than that. From the viewpoint of easily achieving such a contact angle, for example, among the above four kinds of compounds, (ii), (iii), and ((iv) are preferable. The compound of the general formula (0) can be used alone. The content of the surfactant (4) of the color-curable dendritic tissue of the present invention is usually in the form of Q- 5% by weight, preferably Q·(iv)% by weight, More preferably 0. 05~0. 5 wt%. If the content of the (8) surfactant is too large, 97136291 18 200948907 may have precipitation or the surface tension may be excessively reduced. If the amount of the surfactant is too small, the pixel flatness may be poor. (g) interface activity _, shirt loss and the yarn of the present invention may also contain a surfactant other than the above. In this case, it is preferred to replace the content of the compound represented by the above formula (8). Specific examples of the surfactant which can be used in combination will be described later. [1-2] (a) Color material (4) The color material refers to a coloring resin composition of the present invention which is colored. As the (4) color material, dyes can be used, but heat resistance and light resistance are used. From the viewpoint of s', it is preferably a pigment. As the pigment, various color pigments such as a blue pigment, a green pigment, a red pigment, a yellow pigment, a purple pigment, a dial pigment, a color pigment, a black pigment, etc. can be used. The structure may utilize an organic system such as an azo system, a phthalocyanine system, a guanidine system, a ruthenium system, a benzene (four) marriage system, an heterogeneous introduction system, a second well system, an indanthrene system, a ratio system, or the like. Inorganic pigments, etc. Hereinafter, a specific example of a pigment which can be used is indicated by a dye number. The "c. ^" listed below means a color index (c. I. ). · ·" As a red pigment, for example, α1 _Color red, 2, 3, 4, 5, 6 small 8, 9, 12, 14, 15, 16, 17, 2, 22, 23, 3, 32, 37, 38, 4, 47, 48, 48: 1, 48:2, 4δ: 3, 48:4, 49, 49: ΐ 49:2 5〇:ι, 52:1 '52:2> 53 ' 53:1 ^ 53-2', J bd.3 , 57, 57: b57:2, 58:4, 60, 63, 63:1, 63:2, 64, 64.1, R8 β〇01 04.丄b8, 69, 8b 8M, 81:2, 81: 3, 81:4, 83, 88, 90:1, m ι ιλ and 101: Bu 104, ι〇8, i〇8:; l, 97136291 19 200948907 109 112, 113, 114, 122, 123, 144, 146, 147, 149, 151, 166, 168, 169, 170, 172, 173, 174, 175, 176, 177, 178, 179, 181, 184, 185, 187, 188, 190, 193, 194, 200, 202, '206, 207, 208, 209, 210, 214, 216, 220, 221, 224, 230, '231, 232, 233, 235, 236, 237, 238, 239, 242, 243, 245, 247, 249, 250, 251, 253, 254, 255, 256, 257, 258, 259, 260, 262, 263, 264, 265, 266, 267, 268, 269, 270, 271, 272 272, 273, 274, 275, 276. Of these, C. I. Pigment Red 48:1, 122, 168, 177, 202, 206, 207, 209, 224, 242, 254, more preferably C. I. Pigment Red 177, 209, 224, 254. Examples of the blue pigment include CI Pigment Blue 1, 1:2, 9, 14, 15, and 15: Bu 15:2, 15:3, 15:4, 15:6, 16, 17, 19, and 25. 27, 28, 29, 33, 35, 36, 56, 56: 1, 60, 61, 61: 1, 62, 63, 66, 67, 68, 7 Bu 72, 73, 74, 75, 76, 78, 79. Among them, preferred is C. I. ® Pigment Blue 15, 15::1, 15:2, 15:3, 15:4, 15:6, more preferably C. I. Color Blue 15:6. As the green pigment, for example, c. L pigment green 1, 2, 4, 7, 8, 1 , 13, U, 15, 17, 18, 19, 26, 36, 45, 48, 50, 51, 54 55, 58. Among them, preferred are c. L-pigment green 7, 祁, and 58. As the yellow pigment, for example, c. L pigment yellow 1, 1:1, 2, 3, 4, 5, 6, 9, 10, 12, 13, 14, 16, 17, 24, 31, 32, 34, 35, 35: Bu 36, 36: Bu 37, 37: 1, 4 〇, 4 Bu 42, 43, 48, 53, 55, 6 Bu 62, 97136291 20 200948907 62: 1, 63, 65, 73, 74, 75, 81, 83, 87, 93, 94, 95, 97, 100, 1 (Π, 104, 105, 108, 109, 110, 11 Bu 116, 117, 119, 120, 126, 127, 127:1 128, 129, 133, 134, 136, 138, 139, '142, 147, 148, 150, 151, 153, 154, 155, 157, 158, 159, '160, 16 162, 163, 164, 165, 166, 167, 168, 169, 170, 172, 173, 174, 175, 176, 180, 18, 182, 183, 184, 185, 188, 189, 190, 191, 191: 1, 192, 193, 194, 195, 196, 197, 198 198, 199, 200, 202, 203, 204, 205, 206, 207, 208. Among them, CI Pigment Yellow 83, 117, 129, 138, 139, 150, 154 are preferable. More preferably, 155, 180, 185, for example, c. I. Pigment Yellow 83, 138, 139, 150, 180. As the orange pigment, for example, c. I. Pigment Orange 1, 2, 5, 13, 16, 17, 19, 20, 2, 22, 23, 24, 34, 36, 38, 39, 43, 46, 48, 49, 6 and 62, 62, 65, 67, 68, 69, 70, 7 b 72, 73, 74, 75, 77, ❹ 78, 79. Among them, CI color orange 38 and 71 are preferable, and as a purple pigment, for example, c. L color purple 1, 1, 1, 2, 2: 2, 3, 3: Bu 3:3, 5, 5:1, 14, 15, 16, 19, 23, 25, 27, 29, 31, 32 37, 39, 42, 44 47, 49, 5G. Preferably, for example, cj pigment purple 19, 23' is more preferably CI pigment purple 23. The above various pigments may be used in combination with a plurality of weights. For example, in order to adjust the chromaticity, it may be colored green. The pigment and the yellow pigment, or a combination of the blue pigment and the violet pigment. The average particle diameter of the pigment is usually i _, preferably 〇 · below, 97136291 21 200948907 more preferably 0. 25 #111 or less. y ; bucket average particle # is the value obtained by the particle size of the pigment measured by dynamic light scattering DLS. The granules 1 are used to measure the color hard resin composition of the mixed (four) release (usually diluted, lightly the pigment concentration G. GG5~G. 2% by weight. However, if there is a concentration of the measured & machine H) The concentration of the test is carried out and measured under the muscle. In addition, examples of the dye that can be used as the color material include an odor dye, a g quinone dye, a phthalocyanine dye, a (iv) amine dye, a Wei dye, a nitro dye, and a carbonyl dye. Amidene-based dyes and the like. As the azo dye, for example, C. !•acid yellow n, c. ! Acidic dial 7, "acid red ^ heart - acid red (10) (8) acid blue about heart red 28, C. I · direct red 83, CI Direct Yellow 12, CM Ancient & Shizhao K u C. L Direct Orange 26, CI Direct Green 28, α I. Direct Green 59, C· I. Reaction Sound? Γ τ Γ τ c ^ Han Ying 2 CI reaction red 17, I. Reaction red 120, CI reaction black 5, c丨no r T V4i • Knife plate 5, c. I. Disperse red 58, CI ^ Ml65, CIj 7 p T 丄ul Basic red 18, CI medium miscellaneous red WU. mordant yellow 5, ai. mordant black 7, etc. As a lanthanide dye, for example, c丨η τ, · I 5 4, c. I. Acid Table 4 ί!, C. Ι· I Sex Green 25, C·I. Reaction Blue 19, c丨n. ui • Reaction Blue 49, CI Gong Xin 6〇, ci Disperse Blue 56, αι. Disperse Blue 6〇, etc. .. scattered, work The material may, for example, be a sub-type dye such as αι. Indigo 5, and may, for example, be α. The basic blue quinone is a quinolquinoline-based dye, and for example, C.·Ben Blue 9 or the like, as 97136291 LI. Yellow 33, CI Acid Yellow 3, CI. 22 200948907 Knife Dispersion Steam 64, etc., as a true base dye, For example, c· ι. Acidic Acid Orange 3, CI Disperse Yellow 42, etc. θ, αί. These t' are better at the end of the main silk coating film and/or the resistance and robustness. (4) The color material uses a pigment. In addition, in terms of adjustment, etc., it is also possible to use a pigment and a dye as needed. = The coloring of the present invention is verified by t. (4) The ratio of the color material to the total solid content is usually more than 5% by weight. Preferably, it is 20 or more, more preferably 30 or more, and particularly preferably 4% by weight or more, usually 卯% by weight or less, preferably 80% by weight or less, more preferably 6% by weight or less. When the ratio is too small, the coloring power is lowered, and the film thickness becomes too thick with respect to the color density, which adversely affects the control during the liquid crystal cell formation. In contrast, if (a) the color material is excessively contained, For example, there is a risk of dispersion and stabilization of pigments, re-condensation of Qianlin, etc. [1 _3 ] (b) Adhesive resin The color-curable resin composition of the present invention is required to (b) a binder resin (b) The binder resin can be used, for example, Japanese Patent Laid-Open No. 7_2〇7211 Bulletin of No. 8-259876, Special Kaiping 1〇_3〇〇922, Special Kaiping 11-140144, Special Kaiping 1 Bu 174224, Special Opening 2000-56118, Special Opening 2003-233179胄Although the known polymer compound described in the above is mentioned, it is especially preferable as (b) binder resin. (b-Ι) ··· For a copolymer of an epoxy group-containing (fluorenyl) acrylate and another radical polymerizable monomer, at least a part of the epoxy group of the copolymer is added 97136291 23 200948907 A resin obtained by dissolving a monobasic acid or a resin obtained by adding a polybasic acid anhydride to at least a part of a radical formed by the addition reaction is considered as one of the particularly preferable resins. a copolymer of (meth) acrylate and another radical polymerizable monomer, which is obtained by adding an unsaturated monobasic acid to at least a part of an epoxy group of the copolymer, or by the addition reaction A tree moon which is obtained by adding a polybasic acid anhydride to at least a part of the formed radical (hereinafter referred to as "(b-1) resin"). © As the epoxy group-containing (fluorenyl) acrylate, for example, (meth)acrylic acid propyl acrylate, (meth)acrylic acid 3, 4-epoxy butyl acrylate, (mercapto) acrylic acid (3) , 4-epoxycyclohexyl)methyl ester, 4-hydroxybutyl (meth) acrylate, glycidyl ether, and the like. Among them, preferred is (fluorenyl) propylene acrylate. These epoxy group-containing (meth) acrylates may be used alone or in combination of two or more. The "other radical polymerizable monomer" copolymerized with the above epoxy group-containing (fluorenyl) acrylate is preferably a mono-(meth) propylene having a structure represented by the following general formula (1). Acid ester. [Chem. 13]

In the above formula (1), R1 to R6 each independently represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and R and R are each independently a surface hydrogen atom or an alkyl group having a carbon number of 3, and may be mutually 97136291 24 200948907 The bond forms a loop. In the formula (1), in the formula (1), the ring formed by the bonding of R7 and R8 is preferably an aliphatic ring, and or the unsaturated one, and the carbon number is preferably 5 to 6. Wherein, the structure represented by the general formula (1) is preferably the following formula (5), wherein the aliphatic ring represented by the one or (lc) may be saturated (lb) by introducing the resin into the binder resin. In the case of using the colored curable resin composition of the present invention in a color filter or a liquid crystal display element, the heat resistance of the colored curable resin composition can be improved, or the composition of the colored curable resin can be increased. The intensity of the pixels formed by the object. Further, the mono(meth)acrylate having a structure represented by the general formula (1) may be used singly or in combination of two or more. [Chem. 14]

As the mono(meth)acrylic acid having the structure shown in the above general formula (1), 97136291 25 200948907 is shown in the general formula (2) before having this configuration. [Chemical 15] Various known substances can be used', but the following are excellent (2) C. 〇 - Latch 1〇

R1° represents the above formula (1) of the general formula (1), and R represents a hydrogen atom or a methyl group.

In the copolymer of the epoxy group-containing (meth)acrylic acid g and the other radical polymerizable monomer, the repeating unit derived from the mono(methyl) propyl group having the structure represented by the above formula (1) The stress from the "other free silky monomer" is preferably from 5 to 90 mol%, more preferably from 1 to 7 mol%, and particularly preferably from 15 to 50 mol%. Further, the mono-(meth) propylene vinegar having the structure represented by the above general formula (1) is not particularly limited as long as it is a radical polymerizable monomer other than Q. Specific examples thereof include styrene, or a vinyl aromatic group of a styrene-based 2-, o-, m- or p-alkyl group, a nitro group, a cyano group, a decylamine group, or an ester derivative. ; dienes such as butadiene, 2, didecyl butadiene, isoprene, pentadiene; (mercapto) decyl acrylate, ethyl (meth) acrylate, (meth) acrylate N-propyl ester, isopropyl (meth) acrylate, n-butyl (meth) acrylate, second butyl (meth) acrylate, tert-butyl (meth) acrylate, amyl (meth) acrylate , neopentyl (meth)acrylate, isoamyl (meth)acrylate, hexyl (meth)acrylate, (mercapto) 97136291 26 200948907 2-ethylhexyl acrylate, lauryl (meth)acrylate, (decyl) dodecyl acrylate, cyclopentyl (meth) acrylate, cyclohexyl (meth) acrylate, 2-methylcyclohexyl (meth) acrylate, dicyclohexyl (meth) acrylate , (meth)acrylic acid isodecyl ester, adamantyl (meth)acrylate, propargyl (meth)acrylate, (a) Acetyl acrylate, naphthyl (meth) acrylate, decyl (meth) acrylate, o-aminophenyl (meth) acrylate, (mercapto) acrylate to decyl ester, (meth) acrylate hydration Ester, furyl (meth) acrylate, decyl (meth) acrylate, tetrahydrofuran (meth) acrylate, piperidyl (meth) acrylate, benzyl (meth) acrylate, benzene (meth) acrylate Ethyl ester, cresyl (meth)acrylate, 1,1,1-trifluoroethyl (meth)acrylate, perfluoroethyl (meth)acrylate, perfluoro-n-propyl (meth)acrylate, (fluorenyl) perfluoroisopropyl acrylate, triphenylmethyl (mercapto) acrylate, cumyl (meth) acrylate, 3-(N, N-didecylamino) (meth) acrylate (meth) acrylates such as propyl ester, 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate; (decyl) decyl acrylate, (meth) hydrazine , N-dimethyl decylamine, bismuth (meth) acrylate, hydrazine-diethyl decylamine, bismuth (meth) acrylate, hydrazine-dipropyl (mercapto)acrylic acid decylamine, (meth)acrylic acid aniline, (mercapto), ruthenium (meth) acrylate, ruthenium-diisopropyl decylamine, (mercapto) decyl decylamine Vinyl compounds such as acrylonitrile, acrolein, vinyl chloride, vinylidene chloride, fluorinated ethylene, vinylidene fluoride, fluorene-acetonitrile, butyl ketone, vinyl butyl, vinyl acetate, etc. Unsaturated dicarboxylic acid diesters such as diethyl thioglycolate, diethyl maleate, diethyl fumarate, diethyl itaconate; Ν-phenyl-n-butylene Dimethyleneimine, fluorene-cyclohexylmethyleneimine, hydrazine - 97136291 27 200948907 ^ soil-based cis-butanthine diamine, N_(4_#ylphenyl) cis is diimine, etc. Maleimide, N-(methyl) propylene decyl imide, and the like.

❹ These "other radical polymerizable monomers" + are effective in imparting excellent age resistance and strength to the colored curable resin composition, and are effective in styrene, benzyl (meth) acrylate and mono At least one selected from the group consisting of butene diimine. In particular, in a repeating unit derived from "other radical polymerizable monomers", at least one selected from the group consisting of stupid ethylene, benzyl (meth) acrylate, and mono-n-butylene diimide. The content of the repeating unit is preferably from mol%, more preferably from 3 to 50 mol%. Further, the copolymerization reaction of the above-mentioned epoxy group-containing (meth) acetoacetate with the above-mentioned "other radical sclerosing monomer" is a known solution polymerization method. The solvent to be used is not particularly limited as long as it is inert to radical polymerization, and an organic solvent generally used can be used. Specific examples of the solvent include, for example, ethyl acetate, isopropyl acetate, propyl acetonide, and ethylene glycol monofilament (tetra) acid of butyl acetonide; diethyl alcohol; Transferring secrets from the purpose, butyl card to riding vinegar and other diethylene glycol quaternary acid _ acid _; propylene glycol single-burning fine acetic acid vinegar; dipropanol mono-burning _ acetic acid _ and other acetic acid vinegar; ethylene glycol Two wire _, · A, card, alcohol, ethyl carbitol, butyl card, etc. diethylene glycol dialkyl base, triethylene glycol dialkyl base; propylene glycol dialkyl dipropylene glycol Burning base; 1,4-dizhi, tetrahydroanthracene, etc.; picking, methyl ethyl hydrazine, methyl isobutyl fine, cyclohexyl ketone, etc.; benzene, toluene, xylene, xinzhu, 97136291 28 200948907 Hydrocarbons such as decane; petroleum solvents such as petroleum ether, petroleum brain, hydrogenated petroleum brain, solvent oil; lactic acid vinegar such as methyl lactate, ethyl lactate, butyl lactate; dimethyl decylamine; N-decylpyrrolidone and the like. These solvents may be used singly or in combination of two or more. The solvent is used in an amount of usually 3 Torr to 1 Torr, preferably 50 to 800 parts by weight based on 1 part by weight of the copolymer obtained. When the amount of the solvent used is outside this range, it is difficult to control the molecular weight of the copolymer. Further, the free-stranding initiator used in the copolymerization reaction is not particularly limited as long as it can initiate polymerization of the radical, and an organic peroxide catalyst or an azo compound catalyst which is generally used can be used. As the organic peroxide, it is used for over-emulsification, hydroperoxide, hydrogen peroxide, diallyl peroxide, oxidized diester, peroxyester or peroxydicarbonate. Specific examples thereof include a oxidized methyl alcohol base, dicumyl peroxide, diisopropyl peroxide, a third butyl succinate, a third butyl vinegar, and a third benzoic acid peroxide. Oxygen: 2-ethylperoxide 2-ethylhexanoic acid, third hexanoic acid, u-oxygen earth, 3 isopropyl hydroperoxide, hydrogen peroxide, first- & peroxydiiso-transfer, hydrogen over-transfer 7 Second butyl, bis(tetra)cyclobutylcyclohexyl)dicarbon _=^^ butyl ester, peroxidation. Cinnamyl, U, tert-butyl peroxide 3, 仏4 yl ring oxidized month 97136291 29 200948907 Double (t-butyl peroxide) 3, 3, 5-tri-f-cyclohexene appearance. The "external" may be, for example, a bis-isobutyl carbamide or the like. Even among these, in combination with the polymerization temperature, one type or two or more types of shots are used. The initial polymerization of the radical polymerization is as follows: the total amount of the monomers used in the polymerization reaction (10) parts by weight, which is 〇5 to 2 〇 by weight ^ preferably 1 to 10 parts by weight ^ 77 copolymerization can be copolymerized The monomer starting agent used is dissolved in a solvent, and is stirred up by the soil I port, and the monomer added with the radical L initiator is added to the solvent which is heated and stirred. And proceed. Alternatively, the free-spinning starter may be added to the spray, and the reaction conditions may be freely changed depending on the molecular weight of the target. Early body. In the present invention, the above-mentioned "methyl) propyl vinegar and the above-mentioned "filament free-bonding monomer" are preferably contained in a silk-containing fluorene-containing oxime (tetra) propyl axis. The repeating unit is 5, the molar %, the repeating unit from other free radical polymerizing early bodies is 1G to 95% by mole, and the better is the former 2G ~ the other is 80~20 mole%, the best is the former (four) (four), The latter 70, Moer%. When the (meth) (tetra) acid vinegar containing the epoxy group is too small, it will be aggregated as described later. The possibility that the addition amount of the eight and polyacids is insufficient, on the other hand, the two knives ((4) excessive acrylic acid vinegar, other radical polymerizations, two or the possibility of insufficient strength. (10) 峨 _ other self-polymerizable single 97136291 30 200948907 The epoxy group of the copolymer, the unsaturated monobasic acid (polymerizable component) and the optional polybasic acid anhydride are reacted. As the epoxy group-unsaturated monobasic acid, a known one can be used, for example, an unsaturated tasting acid having ethylenic acid and a double bond. Specific examples thereof include (meth)acrylic acid, butyric acid, o-, m- or a monocarboxylic acid such as (meth)acrylic acid in which the α-position is substituted with a dentyl group, an alkoxy group, a halogen atom, a nitro group or a cyano group, etc., of which vinylidene benzoate is preferred. ❹ Acrylic acid. These may be used singly or in combination of two or more kinds. By adding such a component, the binder resin used in the present invention can be imparted with polymerizability. These unsaturated monobasic acids are usually added. 10 to the epoxy group of the above copolymer 100% by mole, preferably 30% by mole, more preferably 5〇~1〇〇% by mole. If the addition ratio of unsaturated-7-nicotinic acid is too small, there is a colored curable resin composition. _ The possibility of a decrease in stability. Further, as a method of adding an unsaturated monobasic acid to the epoxy group of the copolymer, a known method can be employed. Further, as an epoxy group in the filament, an unsaturated group is added. _ The generated polybasic acid anhydride can be used by a known one. For example, it can be used as a dianhydride, a shrub, a yoke, a sulphuric acid, a tetrahydroanhydride, a hexahydrophthalic anhydride, or a chlorine. a dibasic acid anhydride such as a bridge anhydride; an anhydride on the ruthenium such as trimellitic anhydride, per-tetracarboxylic anhydride, diphenylphosphonium tetracarboxylate or biphenyltetracarboxylic acid. Among them, tetrahydrophthalic anhydride is preferred.琥11酸酸轩. These 70 acid livers can be used alone or in combination of two or more. 97136291 200948907 By adding this age, we can expect the wet expansion in the pixel bank of the composition of this gamma. Sexual enhancement. These 70 anhydrides are usually unsaturated in the epoxy group added to the above copolymer. Addition of 1 〇 to 1 〇〇 mol % of the hydroxyl group formed in the monobasic acid is preferably 20 to 90 mol %, more preferably 30 to 80 mol %. The adjustment of the addition ratio in this range is It is considered that the wettability of the composition can be effectively controlled. However, if the addition ratio is over, the above effect cannot be expected as such. Further, as a method of adding a multi-reagent to the radical, a known method can be employed. When the color-curable resin composition of the present invention is used as a photocurable composition as described later, in order to increase the degree of the domain, the polybasic acid liver may be added to form a part of the generated carboxyl group ( Glycidyl methacrylate or an epoxy propyl compound having a t σ unsaturated group. Further, in order to improve developability, a polymerizable unsaturated group may be added to a part of the generated carboxyl group. A epoxidized propyl ether compound. Also, both of them can be added. ^ As a specific example of the epoxy propyl ether compound having no polymerizable unsaturated group, for example, a glycidyl ether compound having a phenyl group or an alkyl group can be exemplified. As a commercial item, for example, the product name rDENAC〇L Εχ~1η", "DENACOL EX-121", "DENACOL EX-141", "DENACOL EX~145", "DENACOL EX-146" manufactured by Nagase Chemical Industry Co., Ltd. "DENACOL EX-171", "DENACOL EH 92, etc.", and the structure of the resin is described in, for example, Japanese Laid-Open Patent Publication No. Hei 8-297366 or JP-A No. Hei. known. 97136291 32 200948907 The polystyrene-equivalent weight average molecular weight (IV) of the above (b-i) resin measured by GPC is preferably 3_, _, and particularly good round to 5 〇〇〇〇. When the weight average molecular weight is not full, the possibility of deterioration of the heat resistance or the film strength exceeds 100,000, the viscosity of the resin increases, and the discharge property of the composition using the composition tends to decrease. Further, as an index of the molecular weight distribution, the weight average molecular weight (Mw) / number average molecular weight (Mn) is preferably 2 〇 5 5. 〇. (b-2) : "A linear resin containing a carboxyl group" ❹ As a linear resin containing a Wei group (hereinafter referred to as "(b-2) resin"), it is not particularly limited as long as it has a money base, and usually It is obtained by polymerizing a polymerizable monomer containing several groups. Examples of the polymerizable monomer containing a plurality of groups include (meth)acrylic acid, maleic acid, crotonic acid, isaconic acid, thiobutanic acid, and 2-(methyl)propyl acrylate. Oxyethylethyl succinic acid, 2-(indenyl) propylene methoxyethyl adipate, 2-(methyl) propylene oxiranyl ethyl maleate, 2-(methyl) propylene oxime Ethyl hexahydrofurfuric acid, 2-(indenyl) propylene methoxy propyl succinic acid, 2-(methyl) propylene methoxypropyl adipic acid, 2-(methyl) propylene decyloxy Propyl maleic acid, 2-(methyl) propylene oxypropyl hydroquinone, 2-(indenyl) propylene oxypropyl carboxylic acid, 2-(methyl) propylene oxy butyl Phytate, 2-(methyl) propylene methoxybutyl adipate, 2-(indenyl) propylene methoxy butyl maleate, 2-(methyl) propylene oxy butyl hydrogen Ethyl monomer such as acid, 2-(methyl) propylene oxy butyl uric acid; ε-caprolactone, propiolactone, r-butyrolactone, octal lactone a monomer of a lactone; a hydroxyalkane (meth) acrylate added to the number 97136291 33 2009489 07 Peric acid, maleic acid, ugly acid or such monomers. These can also be used in multiples. Preferably, the oxime is (mercapto)acrylic acid, and the 2-(indenyl) propylene ethoxyethyl chlorophyll acid is more preferably (mercapto)acrylic acid. Further, the (b-2) resin may be obtained by copolymerizing the above-mentioned polymerizable monomer containing a repellent group with another polymerizable monomer having no carboxyl group. The other copolymerizable monomer is not particularly limited, and examples thereof include (mercapto)acrylic acid f vinegar, (meth)acrylic acid ethyl vinegar, (mercapto)acrylic acid propyl s, (mercapto) acrylic acid Propylene vinegar, (mercapto) butyl acetonate, (mercapto) acrylic acid isobutyl vinegar, (meth) acrylic acid vinegar, (meth)acrylic acid benzene vinegar, (mercapto) propylene glycol ring Hex vinegar, phenoxyacetic acid (meth)acrylate, phenoxymethyl acetonate (meth) acrylate, 2-ethylhexyl acrylate (meth) acrylate, vinegar (meth) acrylate, (曱(meth)acrylate, 2-hydroxyethyl acrylate, mono(indenyl)propionic acid glycerin vinegar, (meth) acrylate (tetra) hydrazine, etc.; vinyl styrene of styrene and its derivatives a quinone; a vinyl compound such as N-vinylpyrrolidine; a cyclohexyl succinimide, an N-phenyl cis- decene imipenem, a (tetra) cis s-diimine, etc. N-substituted maleimide diamines; polymethyl (meth) acrylate macromonomers, polystyrene macromonomers, poly-2-hydroxyethyl (decyl) acrylate giants Thereof, polyethylene glycol macromonomer, macromonomer polypropylene glycol, polycaprolactone macromonomer etc. macromonomer like. These can also be used in combination. Particularly preferred is Methyl, methyl (meth) acrylate, cyclohexyl (meth) acrylate, benzyl (meth) acrylate, 4-hydroxybutyl (meth) acrylate, (meth) propylene 97136291 34 200948907 Acid 2-Ethyl vinegar, (mercapto) acrylic acid via propyl vinegar, (mercapto) butyl acetonate, (mercapto) propionate TS, N-cyclohexyl cis-butane Imine, hetero-n-butylene imine, N-benzyl maleimide. (b-2) Resin can also be carried out in a step-by-step manner. Examples of the stilbene monomer include (meth)acrylic acid 2-ethylidene vinegar, (meth)acrylic acid methacrylic acid, (meth)acrylic acid 4-pyridyl vinegar, etc. (meth)acrylic acid Base-based vinegar, mono (meth) acrylate (tetra) and the like. By combining these with each of the above monomers, it is possible to obtain a resin having a ruthenium group and a warp group. Specific examples of the (b-2) resin include, for example, (mercapto)acrylic acid, (meth)acrylic acid methyl vinegar, (mercapto)acrylic acid vinegar, (meth)acrylic acid butyl vinegar, and (meth)acrylic acid butyl ketone. δ, (fluorenyl) cyclohexyl acrylate, cyclohexyl cis-butanimide, and other light-free polymerizable monomers and (meth) acrylic acid 2 _ ethyl vinegar, ( (meth)acrylic acid, propylene glycol, (meth)acrylic acid 4-mercapto vinegar, etc., a copolymer of a trans-group-containing monomer, Κmethyl)acrylic acid, and (meth)acrylic acid vinegar, (A) Copolymer of (meth)acrylic acid vinegar, butyl ketone (meth)acrylate, isobutyl acetonate (meth)acrylate, (meth)acrylic acid 2-methyl acrylate a copolymer of (meth)acrylic acid and styrene; a copolymer of (meth)acrylic acid with styrene and α-methylstyrene; a copolymer of α and cyclohexylmethyleneimine . From the viewpoint of superior pigment dispersibility, a copolymer resin containing a (meth)acrylic acid ester is particularly preferred. The acid value of the (b-2) resin in the present invention is usually from 3 〇 to 5 〇〇 K 〇 H mg / g, preferably from 40 to 350 KOH mg / g, more preferably from 5 to 3 〇〇 K 〇 H mg / g. Further, the weight average molecular weight in terms of polystyrene measured by GPC is usually from 2,000 to 80,000, preferably from 3 to 50,000, more preferably from 4 to 30,000. When the weight average molecular weight is too small, the stability of the colored curable resin composition tends to deteriorate. When the weight is too large, the resin viscosity increases, and the composition using the composition tends to have a lower discharge property from the nozzle. (b-3) "In the (b-2) carboxyl group of the resin, a resin containing an epoxy group-containing unsaturated compound" ❹ Xiao Jia is also in the above (b~2). A resin (b_3) resin containing an epoxy group-containing unsaturated compound is added. The epoxy group-containing unsaturated compound is not particularly limited as long as it has an ethylenically unsaturated group and an epoxy group in the molecule. For example, (meth)acrylic acid propylene glycol acrylate, propyl propylene propyl acrylate, propylene acrylate m crotonyl propyl acrylate (10), (8) butyric acid propylene acrylate, N- (3, 5-Dimercapto-4-epoxypropyl)-benzyl amide, (meth) decenoic acid 4-pyridyl epoxide The unsaturated ring-containing material is preferably an alicyclic epoxy group-containing unsaturated compound from the viewpoint of the heat and the dispersibility of the pigment described later. Here, 4 is an unsaturated compound containing a naphthocyclic epoxy group, and examples of the alicyclic epoxy group include a 2,3-epoxycyclopentyl group, a 3,4-epoxycyclohexyl group, and 7, 8-epoxy group [a ring [5. 2. 1. 〇] 癸 1-yl] and the like. Further, as the ethylidene group, it is preferably a group derived from a (fluorenyl) acrylonitrile group, and examples of the unsaturated compound containing a waxy ring type epoxy group include, for example, the following formula (10) to (10). 3m) the compound shown. 97136291 36 200948907 [Chem. 16] R"0

R"0 I II , CHr «C-C-O-R1 〇

R"〇 0 CH2=C-C^0-R,s-C^0-R,a-r^v〇 R"0 CHi «C-C-O-R^-O R"0I II CHi =C-C-0-

*-CHI OH R"〇CH, =CC-〇-R'* OH R"0 0 CH* =CC - OR^J^jCO-CH* ❹ R"01 II , CH, -CCOR' HO' RM0I II CH: **0—C—0

0IICHr -O-C

Oot> HO Rn〇I II CH* «-0

HO R"0 R1 I i I CH» «C-C-N-R*

R"0 R'*I II I CH, «CCNR^-O- x> In the formula (3a) to (3m), R11 represents a hydrogen atom or a fluorenyl group, R1 represents a divalent hydrocarbon group, and n is 1 to 10 Integer. (3 a) (3b) (3c) (3d) (3 e> (3 f) (3g) (3h) (3 i ) (3 j) (3 k> (3 I) (3 m) 2 means stretch Alkyl group, R13 97136291 37 200948907 In the general formula (3aM3m), the alkylene group of R12 is preferably a carbon number, and specific examples thereof include a methylene group, an ethyl group, a propyl group, a butyl group, and the like. Preferably, it is an anthracene group, an ethyl group, and a propyl group. Further, as the hydrocarbon group of R13, a carbon number is preferably one, and examples thereof include an alkyl group, a phenyl group, and the like. The epoxy group-containing unsaturated compound may be used singly or in combination of two or more kinds thereof. Among them, a compound represented by the general formula (3c) is preferred, and a (fluorenyl) acrylic acid 3, 4 is particularly preferred. - Epoxycyclohexyl decyl ester. When the above epoxy group-containing unsaturated compound is added to the carboxyl group of the above (b-2) resin, a known method can be used. For example, a carboxyl group-containing linear resin can be used. An epoxy group-containing unsaturated compound, a tertiary amine such as triethylamine or benzylmethylamine, an eleven alkyldithiocarbamate, a tetradecyl chloride, and a tetraethyl chlorinated , tetrabutylammonium chloride, benzyltriethylammonium chloride, etc. 4-stage ammonium salt; in the presence of a catalyst such as pyridine or triphenylphosphine, in an organic solvent, the reaction temperature is 50 to 150 Torr for several hours to several tens of hours, thereby introducing an epoxy group into the slow-acting group of the resin. The acid value of the resin (b-3) is usually from 1 200 to 200 KOH mg/g, preferably from 20 to 150 KOH mg/g, more preferably from 30 to 15 KOH mg/g. Further, polyphenylene measured by GPC The weight average molecular weight in terms of ethylene is usually 200 (M〇0〇〇〇, preferably 4〇〇〇 to 50000, more preferably 5000 to 30000. (b-4): "(indenyl) acrylic resin" as (b -4) (fluorenyl) acrylic resin (hereinafter referred to as "(b_4) resin"), 97136291 38 200948907 refers to the polymerization of these as a single carrier with a mixture of propylene and/or propylene. The polymer W is preferably a (b) resin, and may, for example, be a polymer obtained by polymerizing a monomer component containing (meth)acrylic acid and (meth)acrylic acid (tetra)acrylic acid and B-4-2): a polymer obtained by polymerizing a compound represented by the following general formula (4) and/or (5) as an essential monomer component. [Chemistry]

In the formula (4), 'R11R' independently represents a hydroxyl group having 1 to 25 carbon atoms which may have a hydrogen atom or a substituent. [Chem. 18]

In the formula (5), Rib represents an alkyl group which may have a hydrogen atom or a substituent, L3 represents a divalent bond group or a direct bond, and X represents a group represented by the following formula (6) or an adamantyl group which may be substituted . [Chem. 19] 97136291 39 200948907

" In the formula (6), 'R2b, R3b, and R4b each independently represent a hydrogen atom, a fluorenyl group, a self atom, an amine group or an organic group, and l and l2 each independently represent a divalent bond group. Further, the formula (5) allows L3 to be bonded to π or ... to form a loop. Further, two or more of L1, ^ and L3 of the above formula may be bonded to each other to form a ring. ® (b_4—丨). “Polymerized polymer containing (meth)acrylic acid and benzyl (meth) acrylate.” It will contain (meth)acrylic acid and benzyl (meth)acrylate. The polymer obtained by polymerizing the monomer component of the ester (the term "α_4_υ") is suitable for use from the viewpoint of high affinity with the pigment. The ratio of the above (meth)acrylic acid and benzyl (meth)acrylate in the monomer component is not particularly limited, and (曱-)acrylic acid is usually 1 〇 in the total monomer component of the (b_4-i) resin). 90% by weight, preferably 15 to 80% by weight, more preferably 20 to 70% by weight, and further, the benzyl (meth) acrylate is usually 5 to 9 % by weight, preferably 15%, based on the total monomer component. 80% by weight, more preferably 20 to 70% by weight. If the amount of (fluorenyl)acrylic acid is too large or too small, dispersion tends to be difficult. (b-4-2): "Polymer obtained by polymerizing a compound represented by the general formula (4) and/or (5) as an essential monomer component" Hereinafter, the general formula (4) and/or The polymer represented by the compound (5) which is polymerized as an essential monomer component is called r(b-4-2) resin. 97136291 40 200948907 First, the compound of the above general formula (4) will be described. In the ether dimer of the general formula (4), 'the secret of carbon number 1 to 25 which may have a dry substituent of Ria and ^, there is no special system, and for example, methyl unethyl, positive a linear or branched alkyl group such as propyl, isopropyl, n-butyl, isobutyl, tert-butyl, second amine, stearyl, lauryl or 2-ethylhexyl; An aryl group such as a cyclo group; a cyclohexyl group, a tert-butylcyclohexyl group, a dicyclopentadienyl group, a tridecyl group, an isodecyl group, an adamantyl group, a 2_fluorenyl group, a ruthenium group, or the like An alkoxy-substituted aryl group, a 1-methoxyethyl group, an ethoxyethyl group, or the like; a aryl group-substituted alkyl group; Among these, from the viewpoint of heat resistance, s ' is particularly preferably a substituent of a primary or secondary carbon which is hard to be removed by acid or heat, such as a mercapto group, an ethyl group, a cyclohexyl group or a benzyl group. Further, 1?18 and R2a may be the same substituent or may be different substituents. Specific examples of the ether dimer include, for example, dimethyl-2,2'-[oxobis(indenyl)]bis-2-acrylate, diethyl-2,2,_ [oxy bis (methylene diacrylate, di(n-propyl)-2,2,-[oxybis(methylene)] bis-2~' acrylate, di(isopropyl)-2 , 2'-[oxybis(indenyl)]bis-2-propionic acid from hydrazine, di(n-butyl)-2, 2'-[oxybis(methylene)]bis-2- Acyl-(isobutyl) __2,2'-[oxybis(methylene)]bis-2-acrylate, di-diyl)-2,2'-[oxybis(methylene) Di- 2-acrylate, bis(pent-pentyl)-2,2'-[oxybis(methylene)]bis_2_acrylate, bis(stearyl)-2'2,- [oxybis(methylene)]bis_2 monoacrylate, bis(lauryl) 2,2-[oxybis(methylene)]bis-2-acrylate, di(2-ethylhexyl) 97136291 200948907 yl)-2,2'-[oxybis(indenyl)]di- 2-acrylate, bis(1-methoxyethyl)-2, 2'-[oxybis(- Base)]bis-2-acrylate, bis(1-ethoxyethyl)-2, 2'-[oxybis(indenyl)]bis-2-acrylate, dibenzyl•-2,2'-[oxybis(methylene)]bis_2-acrylate, diphenyl -2,2,-[oxo-bis(methylene)]bis-2-acrylate, dicyclohexyl-2,2,-[oxybis(methylene)]bis-2-acrylate, Bis(t-butylcyclohexyl)-2,2'-[oxybis(indenyl)]bis-2-acrylate, bis(dicyclopentadienyl)_2, 2'-[oxy double 〇(methylene)]bis-2-acrylate, bis(tricycloindenyl)-2,2,-[oxybis(methylene)]bis-2-acrylate, di(isodecyl) -2,2'-[oxybis(methylene)]bis-2-acrylate, diamantyl-2, 2,-[oxybis(methylene)]bis-2-acrylate vinegar, Bis(2-mercapto-2-adamantyl)-2, 2,-[oxybis(methylene)]bis_2_acrylate, and the like. Among these, it is particularly preferred to be dimercapto-2,2,-[oxybis(methylene)]bis-2-acrylate, diethyl-2,2,-[oxybis(sub. Base]] bis-2-acrylic acid, dicyclohexyl 2,2, _[oxybis(methylene)]bis_2_propenoic acid vinegar, bis- 2,2'-[oxygen Bis(methylene)] bis-2-acrylate. These oxime dimers may be used alone or in combination of two or more. The ratio of the above ether dimer in the monomer component in the case of obtaining the above (b-4-2) resin is not particularly limited, and is usually 2 to 2 in the total monomer component of the (b-4-2) resin. 60% by weight, preferably 5 to 55% by weight, more preferably 5 to 50% by weight. If the amount of the dimer is too large, it is difficult to obtain a low molecular weight at the time of polymerization, or there is a possibility that gelation is easy. On the other hand, if the amount is too small, there is a possibility that the coating property such as transparency or heat resistance is insufficient. Sex. 97136291 42 200948907 Next, the description will be made on the compound of the above general formula (5). The general formula (5) is a ruthenium group, and more preferably a ruthenium atom or a ruthenium group. Further, in the above general formula (6), the organic group of R2b or "KR" may be independently listed as an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkylene group, an alkylthio group, a decyl group, a carboxyl group or The oxime or the like is preferably an alkyl group having a carbon number of β ^ bis 18 , a cycloalkyl group having 3 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms, and a decene A 0 alkenyl group having a carbon number of 3 to 18. Carbon alkoxylate 15 alkoxy group, carbon number 1 to 15 alkylthio group 'carbon number 彳, D sulfhydryl group, carbon number 1 carboxyl group or carbon number 1 to 15 decyloxy group, more preferably carbon number q · Azide 1 to an alkyl group or a cycloalkyl group having a carbon number of 3 to 15. As a preferred substituent H0 in R2b, R3b, and R4b, the genus, the secret, the carbon number, and the general formula (6), If it is not independently defined as 2 or 2 valence bond groups or direct bond, it is not particularly limited. Preferably, at least ^ or L is a bond with a carbon number of more than 'L, L, L respectively. It is better to be a direct bond, a carbon number of 15 stone Yin Xuan 1. soil, -ο-, -S-, -CO0)-, carbon number of 15 alkenyl, phenyl or its etc. As a preferred combination of L1, L2 and L3, pass 3 a for direct bonding, carbon number 1 to 5 The alkyl group, or the extension of the ring or the R4» bond type 5. The formula (6) is exemplified by the servant i having the carbon number of the touch, for example, the compound represented by the following formula (7) 97136291 43 200948907 [Chem. 20]

Do not independently represent a hydrogen atom, a hydroxyl group, an _ atom, an amine group or an organic group. In the general formula (7), examples of the organic group of R5b and R6b include an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, an alkoxy group, an alkylthio group, a decyl group, a carboxyl group or a decyloxy group. And the like, preferably an alkyl group having 1 to 18 carbon atoms, a cycloalkyl group having 3 to 18 carbon atoms, a dilute group having 2 to 18 carbon atoms, a cyclodecyl group having a slave number of 3 to 18, and a carbon number of 1 to 15 An oxy group, an alkylthio group having 1 to 15 carbon atoms, a fluorenyl group having 1 to 15 carbon atoms, a carboxyl group having a carbon number of 丨 or a decyloxy group having a carbon number of M5, more preferably an alkyl group having 1 to 10 carbon atoms or a carbon number 3 to 15 cycloalkyl groups. The particularly preferred substituents for R5b and R6b are a hydrogen atom, a hydroxyl group, and an alkylene group having a carbon number of 11 Å. Further, the respective organic groups L1, L2, [2 valent linking group and X adamantyl group of the alkyl group, R2b, and R gas IT may each independently have a substituent. Specifically, for example, the following substituents may be mentioned. Ruthenium atom; thiol; cyano; methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, pentyl, tert-pentyl, n-hexyl, a straight or branched alkyl group having a carbon number of 丨~18 such as n-heptyl, n-octyl or trioctyl; a carbon number of a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, an adamantyl group or the like 3 to 18 of 97136291 44 200948907 cycloalkyl; a vinyl or propylene group, a hexenyl group or the like having a linear or branched alkenyl group having 2 to 18 carbon atoms; a cyclopentenyl group, a cyclohexenyl group or the like having a carbon number of 3 ~18 cycloalkenyl; methoxy, ethoxy, n-propoxy, isopropoxy, n-butoxy, second butoxy, tert-butoxy, pentyloxy, third pentoxide Base, n-hexyloxy, n-heptyloxy, n-octyloxy, octyloxy, etc., the number of slaves 1 to 18 or alkoxy groups; methylthio, ethylthio, n-propylthio , isopropylthio, n-butylthio, second butylthio, tert-butylthio, pentylthio, third pentylthio, n-hexylthio, n-heptylthio, n-yl octylthio, third a linear or branched alkylthio group having a carbon number of octylthio group; An aryl group having 6 to 18 carbon atoms; a aryl group; a phenyl group; a linear or branched alkenyloxy group having a carbon number of 2 to 18; a linear or branched alkylthio group having a carbon number of 2 to 18 such as an ethylenethio group, a propylenethio group or a hexenethio group; The base of the tasting; the oxy group represented by _〇c〇R18; the amine group represented by -nr19r20; the amide group represented by -NHC0R21; the amine hydrazine represented by -NHC00R22 An acid group; an amine carbenyl group represented by -C0NR23R24, a carboxylic acid group represented by -C00R25; an amine fluorenyl group represented by -S〇3NR26R27, a reductant group represented by -s〇3R28 ; 2-mersole, 2-indenyl, indolyl, sinoyl, benzoxyl and the like, thiazolyl, benzothiazolyl, porphyrinyl, pyrrolidinyl, tetrahydrothiophene a saturated or unsaturated heterocyclic group of 4; a trimethyl sulphate or the like; Further, 'Rn to R28' each represents a hydrogen atom, an alkyl group which may have a substituent, an alkenyl group which may have a substituent, an aryl group which may have a substituent or an aromatic group which may have a substituent. 97136291 45 200948907 A pyridyl group. Further, the positional relationship of the above substituents is not particularly limited, and in the case of having a plurality of substituents, the same or different species may be used. Specific examples of the compound represented by the general formula (5) include the following (M-1) to (M-22). [Chem. 21]

97136291 46 200948907 M-l Μ— 7

97136291 47 200948907 [Chem. 22]

In the monomer component of the (b-4-2) resin of the present invention, the ratio of the general formula (5) is not particularly limited, and is usually 0.5 to 60 in the total monomer component of the (b-4-2) resin. The weight%, preferably 1 to 55% by weight, more preferably 5 to 50% by weight. If it is too much, when it is used as a dispersing agent, there is a possibility that the dispersion stability is lowered. The (b-4) acrylic resin of the present invention contains (b~4-l) resin and (b-4-2) 97136291 48 200948907. By having an acidic, - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - The above-mentioned acid group may be, for example, several or more of a hardenable colored hard base, a dilute base, a fine or the like. When the new acid base is only one type or two types of oxime acid groups, it is, for example, a monomer of the fiscal county and a single monomer of the US m (hereinafter also referred to as "use" When the monomer which is an acid group is used as a monomer component, the monomer which gives an acid group is used as a monomer component, and the process of the acid group is used after the polymerization is used. After the combination, the acid: = mercapto group monomer may be, for example, a monomer having a silk such as (meth)acrylic acid or itacon; and a phenyl group, a phenyl cis-butyl quinone, and the like. =: body; Shun Ding,, itaconic acid, etc., having a turbid group, particularly preferably (meth)acrylic acid. The above-mentioned monomer which can be acidified after polymerization, for example, : 2 a monomer having a transradical group such as an ethyl group; an acrylic acid; an epoxy group having a (meth)acrylic acid epoxy group; and a (meth)propionic acid 2 different A monomer having an isocyanate group such as an acetoacetate or the like. These monomers for introducing a human acid group may be used alone or in combination of two or more. (b-4) The monomer component of the resin also contains When the monomer of the acid group is introduced into the acid group, the content ratio thereof is not particularly limited, and is usually 5 to 70% by weight, preferably 10 to 60% by weight, based on the total amount of the body component of the penta-lipe 97136291 49 200948907. (b-4) The resin may also be a radically polymerizable double bond. When a radical polymerizable double bond is introduced into the (b-4) tree wax, for example, The monomer (hereinafter referred to as "a monomer for introducing a radical polymerizable double bond") is subjected to polymerization as a monomer component, and is subjected to a treatment for imparting a radical polymerizable double bond which will be described later. ❹ (A monomer which can impart a radically polymerizable double bond, for example, a dibasic) a monomer having a county such as acrylic acid or itaconic acid; a cis-butanoic acid liver, (4) === base) _ Epoxy _, 峨 基 基 峨 = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = The single bond of the double bond, which contains 5, wt%, preferably _wt%_) of the total monomer component of the base resin (4) in the present invention (in the case of the gamma (four) (M_2) gamma Place , The compound is of a material compound (iv) will feed axis component, based upon the preferred i introducing an epoxy group, for example, having a group of the counties in the monomer introducing an epoxy group ") for polymerization as a monomer component. The term "used as the monomer having an epoxy group as described above" may, for example, be a fluorenyl group, a material, an acid, an acid, a polymer, a phenol, a propyl propyl ether, or the like. The monomer of the epoxy group may be one type or two or more types. The monomer component of the (b-4) resin also contains a ratio of 3 in the presence of the epoxy group π monomer. It is not particularly limited, and is usually 5 to 70% by weight, preferably 1 to 60% by weight, based on the total monomer component of the resin (b-4). The monomer component when the (b-4) resin is obtained, in addition to the above-mentioned necessity In addition to the monomer component, other monomers which can be copolymerized may be contained as needed. © As another monomer which can be copolymerized, for example, (meth)acrylic acid, methyl (meth)acrylate Dilute acid B, n-propyl (meth)acrylate, isopropyl (meth) acrylate, n-butyl (meth) acrylate, isobutyl acetonate (methyl) acrylate, (methyl) ) 3rd butyl vinegar, (mercapto) fluorenyl 2 - ethyl hexanoic acid, (meth) propyl hexanoic acid, (methyl) propylene (tetra) vinegar, (meth) propylene 2_(meth)acrylates such as acetal vinegar; aromatic ethylenic compounds such as styrene, vinyl toluene, and α-mercaptostyrene; fluorene-phenyl-butenylenediamine, hydrazine - N-substituted maleimide, such as cyclohexyl cis-butanthine, butadiene or substituted butadiene compound, such as butadiene or isoprene; ethylene, propylene, chlorine Ethylene or substituted vinyl compound such as ethylene or acrylonitrile; vinyl ester such as vinyl acetate; etc. Among these, it is preferably (meth) from the viewpoint of good transparency and resistance to heat resistance. Methyl acrylate, cyclohexyl (meth) acrylate, benzyl ruthenium (meth) acrylate, and stupid ethylene. These other monomers which can be copolymerized may be used alone or in combination of two or more. 97136291 51 In addition, in the case where a part or all of the (b-4) resin is used as a dispersing agent, it is preferable to use (meth)propionic acid vinegar, and the content thereof is usually (b-4). 1 to 70% by weight, preferably 5 to 60% by weight, based on the total monomer component of the resin, in the case of (b-4) resin When the body component also contains the other monomer which can be copolymerized, the content ratio thereof is not particularly limited, and is preferably 95% by weight or less, more preferably 85% by weight or less based on the total monomer component of the (1^4) resin. ❹ In addition, the content of the resin is 1% by mass or more, preferably 5% by mass or more, based on the total monomer component of the resin (b-4). Next, the method for producing (b-4) resin (polymerization method) is carried out. The polymerization method of the above monomer component is limited to various known methods, and it is particularly preferably carried out by a solution polymerization method. Further, polymerization temperature or polymerization concentration (polymerization concentration = [total weight of monomer components] / (total weight of monomer component + solvent weight m 〇〇) varies depending on the kind or ratio of the monomer component to be used and the molecular weight of the target polymer. Regarding the polymerization temperature, it is preferably (10). c: Better (four) thief. Further, the polymerization concentration is preferably a polymerization concentration of 5, and further, when a solvent is used for the polymerization, a radical polymerization reaction can be used. Specifically, for example, tetrahydroanthracene, two you: B: alcohol monomethyl fine, diethylene glycol dimethyl scaly; ketones such as: dimethyl dimethyl isobutyl ketone, cyclohexanone, etc. ; ethyl acetate, butyl propylene glycol monomethyl (tetra) _, 3 - methoxy butyl vine _, etc.; keto alcohol,: 97136291 52 200948907 alcohol, isopropanol, n-butanol, ethylene glycol Alkyl groups, alcohols; aromatic benzenes such as Yin benzene, M, ethyl benzene, etc., · Chloroform = Substance. These solvents may be used alone or in combination of two or more. When the above monomer components are polymerized, they may be used as needed. It is especially useful to polymerize the initiator and to specifically limit n. For the first time, for example, · cumene hydroperoxide, 2: Γ oxidized di-tert-butyl, peroxylated lauryl, hydrazine: formazan, perbutyl carbonate butyl isopropyl vinegar An organic peroxide such as a second pentyl-2-ethylhexyl peroxide, a third butyl peroxyhexanoate, or an ethyl ester; 2, 2,-even f镂r s-rnt, Tian Hao,. , isobutyronitrile), u, 'azo double (cyclohexanone), 2 azobis (2,4~dimethylvaleronitrile, dimethyl 2'2,-azobis(2- An azo compound such as methacrylic acid vinegar or the like. These polymerization initiators may be used alone or in combination of two or more. The amount of the initiator may be used in combination with the monomer combination or reaction strip used.

The molecular weight of the polymer of the target and the target is appropriately set, and is not particularly limited. From the viewpoint of not forming a nanometer to a polymer having a weight of several thousand to several tens of thousands, it is usually relative to ( B-4) The total monomer component of the resin is 〇·1 to 15% by weight, preferably 〇5 to 1% by weight. Further, in order to adjust the molecular weight, a chain shifting agent may be added. The chain shifting agent may, for example, be a thiol-based chain such as n-dodecyl mercaptan, indole acetic acid or methyl hydrazine acetate, or a d α methyl present ethylene dimer. Among them, n-dodecyl mercaptan and indole acetic acid, which have a better effect of moving the chain, and which can reduce the residual monomer. When the key shifting agent is used, the amount thereof can be appropriately set in accordance with the monomer combination used or the reaction conditions of the polymer of 97136291 53 200948907, the molecular weight of the target polymer, and the like, and is not particularly limited, and gelation does not occur. From the viewpoint of obtaining a polymer having a weight average molecular weight of several thousands to several tens of thousands, the total monomer component of the group is 〇·1 to 15% by weight, preferably 〇·5~1〇. weight%. When the compound of the above general formula (4) is used as an essential monomer component, it is considered that the cyclization reaction of the ether dimer is carried out simultaneously in the above polymerization reaction, and the cyclization ratio of the ether dimer at this time is not Must be 100% by mole. In the case of the monomeric age, when the acid group is introduced by using the monomer to which the acid group is added, it is necessary to carry out the treatment for imparting the acid group after the polymerization. The treatment varies depending on the type of the monomer to be used. For example, when a monomer having a hydroxyl group like 2-hydroxyethyl (meth)acrylate is used, succinic anhydride, tetrahydrophthalic anhydride, or cis is added. Anhydride such as enedic anhydride. When an epoxy group-containing monomer such as (meth)acrylic acid epoxy propyl vinegar is used, an amine group and an acid group such as N-methylaminobenzoic acid or amide benzene may be added. The hydrazine compound 'or the first domain (methyl) propyl acid, is added to the base formed thereon to form an anhydride such as succinic anhydride, tetrahydrophthalic anhydride, maleic anhydride or the like. In the case of using a monomer having an isocyanato group of (meth)acrylic acid 2-isocyanatoethylglycol, for example, a transbasic group and an acid group may be added to a 2-butyric acid or the like. Compound. When the above-mentioned (b-4) resin is obtained, when a monomer capable of imparting a radical polymerizable double bond is used as a monomer component to introduce a radical polymerizable double bond, it is necessary to use it after polymerization. The treatment of imparting a radically polymerizable double bond. 97136291 54 200948907 This treatment varies depending on the type of the compound to be used. For example, in the case of a monomer having a carboxyl group such as acrylic acid or itaconic acid, it is possible to add (meth)acrylic acid propylene oxide. Base ester, 3, 4-epoxycyclohexyl methyl (meth)acrylate, o-(or m- or p-)vinylbenzyl epoxypropyl hydrazine, etc. having epoxy groups and self-twisting A compound that binds to a double bond. In the case of a monomer having a carboxylic acid anhydride group such as stilbene or itaconic anhydride, a compound having a radical and a radical polymerizable double bond such as (meth)acrylic acid hydroxyacetic acid can be added. In the use of (meth)acrylic acid J oxypropyl ester, (meth)acrylic acid 3, 4-epoxycyclohexyl methyl vinegar, o-- («- or p-) ethyl acetate ¥ base epoxy propylene In the case of a monomer having an epoxy group, a compound having an acid group and a radical-bondable double bond such as (meth)acrylic acid can be added. The (b-4) dendritic weight average molecular weight of the present invention is not mosquito-producing, and it is preferred that the weight average molecular weight in terms of styrene in terms of GPC is 2000 to 20 mm, more preferably. In the case where the weight average molecular weight exceeds ❹2G0()()(), the (4) is high, and the group containing the money is reduced from the soil of the mouth. If the other side is not full, the film strength is changed. There is a tendency to be insufficient. In the case where the above (b-4) resin has an acid group, the acid value is preferably from 30 to 500 mgKOH/g, more preferably from 50 to 0.001 mg/g. In the above-mentioned (b-4), the composition of the above-mentioned (b-4) is a polymer having a compound represented by the above formula (4) as an essential monomer component, and is a known compound itself, and for example, JP-A-2004-300203 And the compound disclosed in Japanese Laid-Open Patent Publication No. _3〇〇2〇4, No. 97136291 55 200948907. (b-5) : "Epoxy acrylate resin having a mercapto group" Hereinafter, (b-5) an epoxy acrylate resin having a carboxyl group is referred to as "(b_5) resin". The (b-5) resin of the present invention is based on an epoxy resin addition α, a point-unsaturated monocarboxylic acid or an α, 10,000-unsaturated monocarboxylic acid ester having a carboxyl group in an ester moiety, and reacting the polybasic acid anhydride And by this synthesis. Such a reaction product is chemically structurally free of epoxy groups and is not limited to "acrylates". However, since epoxy resins are used as raw materials and "acrylates" are representative examples, they are conventionally used. So named. As the raw material epoxy resin, for example, a bisphenol quinone type epoxy resin (for example, "EPIK0AT828", "EPIKOAT1001", "EPIKOAT1002", "EPIKOAT1004", etc., manufactured by Japan Epoxy Resin Co., Ltd.), bisphenol A type can be suitably used. An epoxy resin obtained by reacting an alcoholic hydroxyl group of an epoxy resin with epichlorohydrin (for example, 'NER_13〇2' (epoxy equivalent 323, softening point® 76 C) manufactured by Nippon Kayaku Co., Ltd.' Resin (for example, 'EPIKOAT807', 'EP-4001', 'EP-4002', 'EP-4004, etc.' manufactured by japan Epoxy Resin Co., Ltd.), double-seeking alcoholic hydroxyl group of F-type epoxy resin and epichlorohydrin Epoxy resin obtained by the reaction (for example, "NER-7406" (epoxy equivalent 350, softening point 66. 〇) manufactured by Sakamoto Chemical Co., Ltd. 'bisphenol S type epoxy resin, biphenyl epoxide propyl ether (For example, "γχ-4000" manufactured by Japan Epoxy Resin Co., Ltd.), phenol novolac type epoxy resin (for example, "EPPN-201" manufactured by Nippon Kayaku Co., Ltd., "EP-152" manufactured by Japan Epoxy Resin Co., Ltd.," EP-154", manufactured by DOW CHEMICAL, 97136291 56 200948907 "DEN-438" , (o-, m-, or p-) phenolic phenolic epoxy resin (for example, "EOCN-102S", "EOQM020", "EOCN-104S" manufactured by Nippon Kayaku Co., Ltd.), trimeric isocyanic acid Epoxypropyl ester (for example, "TEPIC" manufactured by Seiko Chemical Co., Ltd.), paraben-type epoxy resin (for example, "EPPN-501", "EPN_5〇2", "EppN_5" manufactured by Nippon Kayaku Co., Ltd. 〇3"), 薙 epoxy resin (for example, Card 〇 epoxy resin "ESF_3 〇〇" manufactured by Nippon Steel Chemical Co., Ltd.), ❹ 脂 alicyclic epoxy resin ("CELLOXIDE 2021P" manufactured by DAICEL Chemical Industry Co., Ltd." "CELL E-deletion", a bicyclo red epoxy resin which is epoxy-propylated by a reaction of dicyclopentane and a desired reaction (for example, Cl_ manufactured by Nippon Kayaku Co., Ltd.), Dai-Japan "EXA-7200" manufactured by Ink Co., Ltd., "NC__" l manufactured by Nippon Kayaku Co., Ltd., and ring 4 shown by the following structural formula; Rushu (refer to Japanese Patent Laid-Open No. 4-355450), etc.

Ut 23]

= One type can be used alone or two or more types can be used in combination. Other examples of the tree wax include, for example, a copolymerized epoxy resin _ a copolymerized epoxy resin. Make

Vinegar, (methyl)-propyl-branched methyloxygen I (meth)acrylic acid epoxy propyl _291 " appearance, ethical cyclohexene, etc. U 57 200948907 The first component of the epoxy resin, and the compound containing a monofunctional ethylenically unsaturated group (hereinafter referred to as "the second component of the copolymerized epoxy resin"), for example, from (meth) Methyl acrylate, ethyl (meth)acrylate, butyl (meth)acrylate, 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, (mercapto)acrylic acid, styrene , phenoxyethyl (meth) acrylate, benzyl (meth) acrylate, α-methyl styrene, glycerol mono(meth)acrylate, and selected from the group consisting of the compounds represented by the following general formula (8) Then, one or more kinds of copolymers obtained by the reaction are obtained. [Chem. 24]

CH

C2h4o^:r

6Z (8) In the formula (8), R61 represents hydrogen or an ethyl group, and R62 represents hydrogen or an alkyl group having a carbon number of 丨6, and r is an integer of 2 to 1〇.

Examples of the compound of the general formula (8) include diethylene glycol mono(methyl)acrylic acid, diethyl alcohol mono(indenyl)acrylate, and tetraethylene glycol mono(methyl)acrylic acid vinegar. Ethylene glycol mono(meth)acrylate; methoxydiethylene glycol mono(indenyl) acrylate, decyloxytriethylene glycol mono(decyl) acrylate, decyloxytetraethylene An alkoxypolyethylene glycol (mercapto) acrylate such as an alcohol mono(meth)acrylate. The molecular weight of the above copolymerized epoxy resin is preferably from about 1,000 to 200,000. Further, the amount of the first component of the above-mentioned co-toxy epoxy resin is preferably ig weight, particularly preferably 20% by weight or more based on the above-mentioned 97136291 58 200948907 /, the second component of the polyether type oxygen resin. 'It is preferably 7% by weight or less, and particularly preferably 5% by weight or less. Specific examples of such a "polymeric epoxy resin" include CP-15 manufactured by Oyster Sauce Co., Ltd., "CP-30", "Cp-5〇", "cp_2〇SA", and "邙_5 gallbladder". "CP-50S", "CP-50M", "CP-20MA", etc. (b 5) The molecular weight of the raw material epoxy resin, which is determined by Gpc

G The weight average molecular weight of the ethylene conversion is usually 4 2 GG to 200,000, preferably 30 (M0_). If the weight average molecular weight is less than the upper rank, there is a film formation property, and conversely, if the resin is more than the above, the resin will be gelled when the addition reaction of the + saturated single fine ^ There are also situations in which manufacturing is difficult. · As α, a non-unsaturated single _, for example, itaconic acid, butyric acid, cinnamic acid acrylic acid f-based acrylic acid, etc., preferably acrylic acid and methyl acrylic acid, especially acrylic acid rich reactivity Better. As a part of the § day, there is a county unsaturated single bond, for example: acrylic acid 2 gamma oxyethylene brewing, acrylic acid 2 - cis butyl ethoxy ethoxy vinegar, acrylic acid 2- ethoxy ethoxy vinegar, acrylic acid _2_hexahydro-ethyl acetoacetate, methacrylic acid-2-sodium oxy-ethyl yttrium, methacrylic acid-2-butyleneoxy acetoacetate, methyl propylene acid '2- _ Ethoxyethyl s, methacrylic acid-2-hexahydro oxime acetoacetate, butyl-2- sulphonyloxy (f), etc., preferably acrylic acid _2 cis butyl ethoxylate , acrylic acid - 2 ugly oxyacetic acid vinegar, particularly preferably acrylic acid _2 _ butylene oxide ethoxylates ^ These can be used alone or in combination with two kinds of 97136291 59 200948907. «, /3-unsaturated monocarboxylic acid or a carboxyl group in the ester moiety, an addition reaction of a point-unsaturated monocarboxylic acid ester with an epoxy resin, a known method can be used, for example, in the presence of an esterification catalyst It is carried out by carrying out a reaction at a temperature of 50 to 150 ° C. As the esterification catalyst, a tertiary amine such as triethylamine, tridecylamine, benzyldimethylamine or benzyldiethylamine can be used; tetramethylammonium chloride and tetraethylchlorinated a grade 4 ammonium salt such as ammonium or dodecyltrimethylammonium vaporate. © α, cold-unsaturated monocarboxylic acid or oxime having a carboxyl group in the ester moiety: the amount of the cold-unsaturated monocarboxylic acid ester used is preferably 0.5 to 5 equivalents to the epoxy group of the epoxy resin. The range of 1.2 equivalents is more preferably in the range of 〇·7 to Μ equivalent. If the amount of the sulphuric acid is less than that of the sulphuric acid, the amount of the unsaturated group is insufficient, and the reaction with the polybasic acid is also insufficient. Also, when a large amount of epoxy groups remain, the α-unsaturated mono Wei or the α'泠-unsaturated monocarboxylic acid ester having an oxime carboxyl group in the vinegar portion is in the form of an unreacted substance. Residual. In either case, there is a tendency for the hardening characteristics to deteriorate. As an α, /3-unsaturated carboxylic acid or an ester-containing part of the "stone-unsaturated single-tone S-type epoxy resin", the addition of the soil to the multi-component ^, needle ' can be For example, maleic acid, succinic anhydride, itaconic anhydride, sulphuric acid, tetrahydrophthalic anhydride, hexahydrophthalic anhydride, pyromellitic anhydride, triamteric acid anhydride: base _ tetracarboxylic acid dixanthine, Methyl hexahydroglycolic acid anhydride, endomethylene tetrahydrouric acid liver:: olefinic anhydride, mercaptotetrahydrophthalic anhydride, phenylidene tetracarboxylic acid dianhydride, etc., preferably cis-butyl 97136291 200948907 diacyl anhydride, a Take acid needle, itaconic acid Xuan, defeated acid Xuan, four nitrogen ugly acid Xuan, hexazone dichlorvos, pyromellitic acid needle, triphenyl hexacarboxylate, biphenyl tetracarboxylic acid two needles, especially good compound for four Hydrogen carrier acid and diphenyl phthalate. These can be used alone or in combination of two or more. ' _ Multiple _ addition reaction, the village uses well-known techniques, can be used with α, /3 - the unsaturated carboxylic acid or (4) part of the surface group, the addition reaction of the plant unsaturated monoacid ester is carried out under the same conditions to continue the reaction. The acid value of the genus Weiji __ becomes the range of HMSOmgKOH/g, particularly preferably 2 (M4 〇 ing K 〇 H / g range. Also 'from the viewpoint of the preservation of the composition, the preferred system Other than the other ones, the epoxy resin-containing resin of the prefecture is, for example, the naphthalene-containing resin described in Japanese Patent Laid-Open No. Hei 6-49174, and the special Kaikai No. 16 'Special opening 165830. Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. 2001-354735 In addition, as a commercial product, for example, "ACA-200M" manufactured by DAICEL Co., Ltd. can be used as a commercial product, and it is also possible to use, for example, 曰 as a binder resin. The propylene-based resin described in JP-A-2005-154708, etc. Among the various resins described above, (6) the adhesive _lipid of the present invention is particularly preferable (for the epoxy group-containing (meth) acrylate) Copolymer of vinegar and other radical polymerizable monomers 97136291 61 200948907' in the epoxy group of the copolymer a resin obtained by adding at least a part of an unsaturated monobasic acid or a resin obtained by adding a polybasic acid anhydride to at least a part of a hydroxyl group formed by the addition reaction. Further, the molecular weight is polystyrene measured by Gpc. The weight-average molecular weight of the conversion is particularly preferably about 5,000 to 20,000. The color-curable resin composition of the present invention is photocurable or thermosetting as described later, and may be carried out by both of them. Hardened. 较 More bribe Wei Zuo test its Wei (four) condition, for Yang Jiefa, best (b-1) "For epoxy-containing (meth) acrylate vinegar and other free radical polymerization single a copolymer of a body obtained by adding at least a part of an epoxy group of the copolymer to an unsaturated-acid acid, or a polybasic acid anhydride obtained by adding a polybasic acid via a radical H formed by the addition reaction (Resin) and/or (b-6) an epoxy group-containing resin. In the case where the inkjet method is used to form a pixel for a color filter, it is preferable to use a photopolymerization initiator which does not require a reduction in luminance, and the photocuring process is omitted to improve the production. A thermosetting resin composition having a thermosetting property. (b-6) : "Resin having epoxy group". The epoxy group-containing resin (hereinafter referred to as "(b-6) tree I") in the present month has a structure in which the tree axis has a secret structure and is not limited. Among them, preferred are, for example, an alicyclic polyether compound having an epoxy group in a side chain, a polyepoxypropyl compound, a polyepoxy group 97136291 62 200948907. An amine compound, a polymer obtained by polymerizing two or more kinds of epoxy group-containing (meth) acrylates, or a (meth) acrylate vinegar having an epoxy group and other monomers Copolymer. (b 6) Specific examples of the tree shrew are as follows, but are not limited thereto. (b-6-l) : "The alicyclic polyether compound having an epoxy group in the side chain"

The alicyclic polyether compound having an epoxy group in the side chain may, for example, be a U-epoxy group (2-epoxyethyl) ring of 2,2-bis(transmethyl)-butanol. A polycyclohexyl scale having an epoxy group in a side chain, such as a calcined adduct. As a commercial item of such a compound, for example, Sheng E315(10) manufactured by CEL Chemical Industries Co., Ltd., and the like can be mentioned. (b-6-2) : "Polyepoxypropyl ether compound"

Examples of the polyepoxypropyl scaly compound include a diepoxypropyl hydrazine type of polyethylene glycol, a bis(epoxyphenyl) bis-epoxypropyl ether type epoxy group, and a biguanide. Di-epoxypropyl ether type epoxy group, bisphenol ρ diglycidyl epoxy group, (iv) dianede propyl epoxide, tetramethyl (tetra) A ring Oxypropane fine epoxy group, epoxy Ethylene addition, double expectation A =-nuclear oxygen (tetra)-epoxy group, di-hetero-epoxy group, di-extension-based oxy group type epoxy group, double-anticipation Type epoxy group, lin (tetra) epoxy group, thiol oxy group, and oxypropyl group exposure can be exemplified by a double ring, a sulphur epoxy resin, a sulphur epoxy resin, and an epoxy resin. (10) A phenol resin type epoxy resin such as a polymerized epoxy resin of a diene, a polymerized epoxy resin of a phenol and a naphthalene. These (poly)epoxy ether compounds may also be those which have been introduced into the carboxyl group by reacting the remaining acid or the acid compound or the like 2 97136291 36291 63 200948907. (b-6-3): "Polyoxypropyl propyl ester compound" As the polyepoxy propyl hybrid, for example, a di-epoxypropyl hydrazine hexaoxy acid type epoxy group or a citric acid type II may be mentioned. Epoxypropyl vinegar type epoxy group and the like. (b-6-4) : "Polyepoxypropylamine compound" As the polyepoxypropylamine compound, for example, bis (4 _ phenylene) 甲 dimethyl digoxypropyl amide type epoxy A tri-epoxy-amine-type cyclic lactide group of a base or a trimeric isocyanic acid. (H) "A polymer obtained by polymerizing an epoxy group-containing (fluorenyl) acrylic acid s or a polymer of the above-mentioned (b_6) resin", for example, A polymer obtained by polymerizing one or two or more kinds of (meth)acrylic groups of the above-mentioned compound, such as "(b-6-5) tree-shaped"). b+5) a material of a resin having an epoxy group (meth)acrylic acid hydrazine J such as (meth)acrylic acid epoxy propyl vinegar, α-ethyl propylene diacetate propylene propane = n-propyl Propylene epoxidized propyl ester, n-butyl butyl acid epoxide cyclohexamethyl methacrylate acrylate 3'4, oxybutyl vinegar, (meth) acrylate-4, 5- acrylate - 6,7-ring Gas-based, "acrylic acid aι6" is particularly preferred (a fine epoxy propyl vinegar.) ~ (Ethyloxyethyl acetoacetate having an epoxy group) Another example of the (b_6) resin of the invention may also be referred to as "epoxy-based (fluorenyl) propylene vinegar" and other monomers as taught in the item of 97136291 64 200948907 (b 6 5) Copolymer. Hereinafter, the copolymer It is "(6) (four) resin"." The amount of his monomer is based on the total monomer composition of the resin (Bu 6_6), usually • 10~mol%, preferably 15~60 mol%. , ❹ • as other The monomer may, for example, be (meth)acrylic acid, (meth)acrylic acid, ortho(meth)acrylic acid, (meth)acrylic acid, butyric acid, (meth)acrylic acid Acid I ethyl hexanoic acid, phenyl ketone (meth) acrylate, cyclohexyl acrylate (meth) acrylate, dicyclopentanyl (meth) acrylate, dicyclopentadienyl (meth) acrylate Acetate, vinegar, etc.; and styrene-based aromatic compounds such as phenelzine, i-methylstyrene, p-methylstyrene, ethenylnaphthalene Further, as the (meth)acrylic acid group having a % oxy group, for example, (methacrylic acid epoxy propyl acrylate) is preferable. As another monomer, for example, (meth) acrylic acid is particularly preferable. Dicyclopentadienyl ester, and methyl styrene. The epoxy group used in the resin of the present invention is usually an epoxy group, but the stability or flexibility is improved over time. For the imparting, etc., a 1,3-epoxy group (oxycyclobutane) or a 4,3-epoxycyclohexyl group may be used. Further, in the (b-6) resin, an aromatic ring is not contained. In addition, it is preferable that the base material can be inhibited from heat treatment. As such an epoxy compound, an epoxy resin having a first skeleton which may have a substituent, a copolymer of a base vinegar, and the like may be mentioned. The content of (meth)acrylic acid propylene (IV)) resin is usually (1) mole 97136291 65 200948907% or more, preferably 1% 〇 mol% or more 'usually Μ mol% or less based on the entire resin. If it is less than 5%, if there is too little resin (b-6), there is a tendency that the chemical resistance is insufficient, and if it is too large, there is a possibility that the storage stability is insufficient. The weight average molecular weight (Mw) of the (b-6) resin is usually at least the above, preferably 5 Å or more, usually just _ or less, preferably 5 Å or less. If the molecular weight is too small, the heat resistance and the film strength tend to be deteriorated. If the molecular weight is too large, the solubility may be insufficient, or the liquid property of the coating liquid may become non-Newtonian. © Again, the molecular weight distribution (weight average molecular weight (Mw) / number average molecular weight (10) is 2.0 or more and 5. 〇 below. (b-6) Resin_ _ hiding the total solid content of the color hardening rider of the present invention The ratio of the resin is preferably 0.5% by weight or more, more preferably i% by weight or more, usually 50% by weight or less, preferably 40% by weight or less, more preferably 35% by weight or less. If the proportion ratio of the resin is too small, Therefore, the effect of improving the chemical resistance cannot be expected too much, and if too much, there is a tendency for insufficient storage stability.各种 The above-mentioned various binder resins may be used singly or in combination of two or more. In the colored curable resin composition of the present invention, (b) the content ratio of the binder resin is in the total solid content, and is usually 丨% by weight or more, preferably 1% by weight, and usually 80% by weight. Hereinafter, it is preferably 60% by weight or less. If the content of the (b) binder resin is less than this range, the film becomes brittle and the adhesion to the substrate is lowered. On the contrary, if it is larger than this range, the film hardness is insufficient and there is a case where the color strength is insufficient. 97136291 66 200948907 [l-4] (c) Organic solvent The colored curing resin composition of the present invention contains (c) an organic solvent as an essential component. (5) The organic solvent has a function of dissolving the above components to adjust the viscosity. ❹ ❹ 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 Your agent (c-1) accounts for 80% of (c) organic solvent as (C) organic falling agent, fine B, ethylene (4), such as: ethylene glycol monoterpene fine, ethylene glycol monoether, propylene glycol mono 7 alcohol mono-n-butyl Ethyl ether, propylene glycol monomethyl dry 0 base oxime, propylene distillate ether, diethylene glycol monomethyl fine, called n-butyl butyl, propylene glycol mono-tert-butyl ether, methoxy fluorenyl 2 = B Alcohol monoethyl ether, diethylene glycol mono-n-butyl ether, 3-methyloxybutanyl fine, dipropylene glycol monodecylethyl hydrazine, triterpene _ ~ ethylene glycol monomethyl ether, triethyl - J~ alcohol methyl ether 箄 ethylene glycol dimethyl I f < ~ alcohol monoalkyl ether; base, diethanol diethylene glycol diethyl _ fine, diethylene glycol dimethyl ether, ethylene glycol Dibutyl ether, propylene glycol dimethyl _, etc.: = ~ ethylene glycol monoterpene - alkyl face; Millennium screams acetate, n-butyl __, propylene diethyl ether acetate , ethylene glycol monoacetate, propylene glycol single shout _ J vinegar , propylene glycol monoethyl acetate butyl acetate, 3 q propylene glycol monobutyl ether acetate, fungus _91 'A &quot; butyl butyl ketone ~, methoxy fluorenyl acid series,: 67 200948907 ethylene glycol single Mercaptoether acetate mono-n-butyl ether acetate, di-ether ether acetate alcohol monoethyl ether vinegar 醇 醇 alcohol monodecyl ether acetate, ethyl alcohol triethylene glycol monohexyl ether acetate, 3- Diethylene glycol monomethyl vinegar _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Two different members, Ethyl, Ethyl isobutyl, Dihexyl, etc., butyl ❹ 、 I, w ~ 尖 贝 · Propionate, mercapto ethyl ketone, decylpentyl hydrazine, fluorenyl Isopropyl _, 'methyl fine, diisopropyl _, pentylene _, f group, fine ring, ethyl pentyl _, fluorenyl T fine, f base fine, y base fine a ketone such as methoxymethylpentanol; ethanol propanol, butanol, hexanol, cyclohexanol, benzyl alcohol, ethylene glycol, propylene glycol, butanol, triethylene glycol, methoxymethyl Pentanol, diethylene glycol, dipropylene glycol, glycerin, etc. 1 yuan or polyhydric alcohols; aliphatic hydrocarbons such as n-pentyl, n-octyl, diisobutyl, n-hexyl, heptane, iso-bi-, dipentene, dodecane; An alicyclic hydrocarbon such as a ketone, a methyl ring (tetra) or a cyclohexyl group; an aromatic hydrocarbon such as benzene, xylene or cumene; an amyl phthalate, ethyl citrate or ethyl acetate Ester, butyl acetate, propyl acetate, pentane acetate, decyl isobutyrate, ethylene glycol acetate, ethyl propionate, propyl propionate, butyl butyrate, isobutyl butyrate, isobutylate Methyl ester, ethyl hexanoate, butyl stearate, ethyl benzoate, methyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, 3-methoxy 97136291 68 200948907 a chain or cyclic ester of methyl vinegar, 3-methoxypropionic acid methyl vinegar, 3-methoxypropionic acid butyl vinegar, butyl butyrolactone, etc.; 3-foxypropionic acid, 3-ethoxyl group A carboxylic acid such as propionic acid; a chlorinated butyl chloride, a pentyl chloride or the like; a methoxymethylpentanone or the like; a acetonitrile, a benzonitrile or the like; and the like. ❹ As the above-mentioned commercially available solvent, for example, mineral spirit spiHt), Vars〇i #2, Apc〇#18 solvent, Apc® diluent (thinnern), Socai solvent N〇丨, and N〇2, 黯Es_5〇, TS28 solvent, alcohol, ethyl carbitol, butyl carbitol, methyl serotonol, ethyl celecoxib, ethyl serotonin acetate, methyl serotonin vinegar, Diglyme (diethylene glycol dimethyl ether) (all trade names) and the like. These solvents may be used singly or in combination of two or more.

G In the production of color county film by inkjet method, since the inner ink is very fine, only ten pL, it is attached to the periphery of the nozzle mouth = '疋, that is, solvent evaporation and ink concentration · The tendency to dry. In order to avoid this situation, the color of the present invention ^-c^(,,101,25[hPa^ accounted for 80% of the (C) organic solvent "above. In the solvent solvent (C-1)% by weight, there will be no Give full play to the proportion of self-oil is not full. The η η * The evaporation effect of the ink droplets is preferably 2 〇〇 in the solvent (6). Wo's up. Preferably, the boiling point is 22 (TC is 97136291 69 200948907. Further, the solvent (C-1) is preferably ((:) preferably 90% by weight or more. 80% by weight or more of the organic solvent, more. As dissolved·-D, For example, in the above organic solvent, it is diethylene glycol monobutyl hydrazine vinegar, monoethylene glycol monoethyl acetate vinegar, dipropylene glycol methyl ketone, diol diacetate vinegar, L 6-hexanol diacetate series, glycerol triacetate, etc. Among them, particularly preferred is diethylene glycol mono-n-butyl ether acetate vinegar.

❹ For the viscosity adjustment of the ink or the solubility adjustment of the solid part, it is also effective to partially contain a paste having a lower than 18GC. The material is preferably low-viscosity, solubility, and low-profile. It is difficult to have such as _, surface or ketone, etc. Among them, decyl ketone, dipropylene glycol dimethyl bond, cyclohexanol acetate vinegar Wait. On the other hand, if (c) the organic solvent contains an alcohol, there is an If shape in which the discharge by the ink jet method is lowered. Therefore, it is preferable to set the alcohol to be less than or equal to 8% by weight in the total solvent, more preferably 10% by weight or less, and particularly preferably 5% by weight or less. (c) The vapor pressure of the organic solvent is usually 10 _Hg or less, more preferably 5 mmHg or less, still more preferably 1 djmnHg or less, from the viewpoint of the uniformity of the coating form obtained. The ratio (c) of the organic solvent to be occupied by the entire color-curable resin composition of the present invention is not particularly limited, but is usually 5% by weight or more, preferably more than or equal to, and usually not more than 99% by weight. Preferably, it is 95% by weight or less. If (c) the organic solvent is too large, the relative solid content is too low to form a coating film, or the viscosity of the ink is too high, which may cause an obstacle to the stability of the coloring resin composition. Further, when the colored curable resin composition is applied to the ink jet method of 97136291 200948907, there is a possibility that the discharge stability is lowered. [l-5] (e) Dispersant The color-curable resin composition of the present invention preferably further contains (e) a dispersant. (e) The type of the dispersing agent is not particularly limited as long as it does not impair the effects of the present invention. Preferably, one or more kinds of dispersing agents selected from the group consisting of: (e-Ι). An atomic branch copolymer; (e_2) an acrylic block copolymer containing a nitrogen atom; and (e-3) an amino phthalic acid ethyl ester resin dispersant. 〇In the above (e-1) to (e_3), 'the nitrogen atoms contained in the above-mentioned atoms have an affinity for the surface of the pigment', and the affinity of the portion other than the nitrogen atom for the medium can be improved, and it is suggested that this will contribute to the improvement. The overall dispersion stability. The performance of the dispersant is greatly affected by its adsorption behavior on solid surfaces. Regarding the relationship between the texture of the molecule and the adsorption behavior, it is known that the case of using the same unit 'the adsorption behavior is the random copolymer &lt;graft copolymer&lt;block co-t order (for example, Jones and Richrads) , "Polymers at © Surfaces and Interfaces", 1999 edition, p281). The detailed mechanism is still unclear, and it is speculated as follows. That is, in the case of a general random copolymer, when the monomer constituting the copolymer is formed into a polymer, the probability of being stereoscopically and/or electrically stably disposed in the copolymer becomes high. The portion (molecule) in which the monomer is stably disposed is sterically and/or electrically stable, so that it can be adsorbed to the pigment, and it may become a hindrance. On the other hand, the graft copolymer or the resin whose molecular arrangement is controlled by the segment copolymer can dispose the portion which hinders the adsorption of the dispersant at a position away from the adsorption portion of the pigment and the dispersant, 97136291 71 200948907, and also the pigment and The adsorption portion of the dispersing agent is disposed in a portion suitable for adsorption, and a portion suitable for the solvent is disposed in a portion where solvent affinity is required. In particular, the dispersion of the color material of the pigment having a smaller "βθθ sub-size" has the effect of good dispersibility in the molecular arrangement. (e-υ: "Graft copolymer containing a nitrogen atom" / a graft copolymer having a mouse atom (hereinafter sometimes referred to as "(5)) copolymer)" is based on the viewpoint of efficiently dispersing a pigment. The words are better. The reason is not yet ❹ 但 但 但 但 但 但 但 但 但 但 但 但 但 但 但 但 但 但 但 但 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料 颜料As the graft copolymer containing a mouse atom, it is preferred that the primary bond has a repeating unit containing a nitrogen atom. Wherein 'preferably has the repeating single-like formula or formula represented by formula (1) (the repeating unit shown in (1). [Chemical Formula 25] 〇(1) In the formula (I), r represents a carbon number of the alkyl group, and Α represents a hydrogen atom or any one of the following formulas (111) to (V): In the formula (I), R51 represents a linear or branched 'branched carbon number of an anthracene group, an exoethyl group, a propyl group or the like. The alkyl group of ～5 is preferably a carbon number of 2 to 3, more preferably an ethyl group. 'A represents a hydrogen atom or any of the following formula (IIIMV), preferably a formula (11〇). ] 97136291 72 200948907 In the formula (II), the r51 and A systems are synonymous with Rsi and A in the formula (i).

Αι&&gt; In the formula (ΠΙ), 'WlA shows a linear or branched alkyl group having a carbon number of 2 to 10, and preferably a carbon number of 4 to 7 such as a stretching group, a pentyl group, and a hexyl group. Extend the base. P represents an integer of 1 to 20, preferably an integer of 5 to 1 。. [化 28]

In the formula (IV), Yi represents a divalent bond group, and among them, an alkyl group having 1 to 4 carbon atoms such as an ethyl group or a propyl group, or a carbon such as an ethoxy group or a propoxy group is preferably used. An alkoxy group. % represents a straight chain of a stretched ethyl group, a propyl group, a butyl group, or the like, and a carbon number of 2, which is preferably a stretched base, a stretched propyl group, etc. ~3 of the base. Y2 represents an argon atom or -c〇-r52 (r52 represents a carbon number of ethyl bromide, propyl group, butyl group, pentyl group, hexyl group or the like; and an alkyl group of Ul), wherein preferably, it is a group of propyl 97136291 73 200948907, a propyl group, A butyl group, a pentyl group or the like having a carbon number of 2 to 5. q represents an integer of the division, preferably an integer of 5 to 1 。. [化29]

式 In the formula (V), w3 represents an alkyl group having a carbon number of U0 or a group of carbon having a carbon number of 51 50, wherein the carbon number of the hard group such as a stearyl group is 1Q to 2Q, A stearyl group or the like having a carbon number of 1Q to 2 (). The content of the repeating unit represented by the formula (I) and ((1) of the graft copolymer towel of the (e) dispersing agent of the present invention is preferably the higher, usually 50 mol% or more, preferably 70 Mole % or more. There may be a combination of the repeating unit represented by the formula (1) and the repeating unit represented by the formula (Π). The content ratio thereof is not particularly limited, but preferably contains a repeat of the formula (1). The total number of repeating units represented by the formulas (I) and (II) is usually 1 to 100, preferably 10 to 70, more preferably 20 in one molecule. Further, the formula (1) and the formula may be contained. The repeating unit other than (1)), as another repeating unit, may, for example, be an alkyl group or an alkoxy group. The graft copolymer of the (e) dispersant of the present invention is preferably one in which -NH2 and -R51-NIKR51 are synonymous with R5丨 described above. Further, if the above conditions are satisfied, the main chain may be linear or branched. The amine value of the (e-Ι) copolymer is usually 5 to 1 〇〇 mg K 〇 H / g, preferably 97136291 74 200948907 1 〇 ~ 7 〇 fflg, more preferably 15, _. If the amine price is too high or too low, the dispersion stability is lowered and the # degree becomes unstable. Moreover, if it is too high, the electrical characteristics after forming a liquid crystal panel may fall. η 且 且 'The amine valence of the dispersant is the weight of the cc of the solid content of the dispersant sample other than the solvent per lg and the equivalent of the coffee, and by the second method

In a 1 mL mL beaker, a fine scale dispersant was tested for mi. 5 g, and dissolved in 50 mL of acetic acid. Using an automatic titration device equipped with a pH electrode, the solution is neutralized and titrated with lysole of 1 mol/L perchloric acid (HCL0 醋酸 acetic acid solution. The inverse of the titration pH curve is used as the titration end point, and the amine is obtained by the following formula Amine price [mgKOH/g]=(561xV)/(WxS) (2) 'W-side dispersion depends on the amount [g], the amount of droplets on the v-side is [mL], S represents the dispersant sample The weight average molecular weight of the above-mentioned (el) copolymer measured by GPC is preferably 〜5〇_, especially preferably _〜2 coffee. The weight average molecular weight is not Full _, it is impossible to prevent (4) agglomeration of the color material, there will be high viscosity: or gelation. If it exceeds _ 〇, it becomes high viscosity itself, or has solubility for (C) organic solvent. In addition, the steric hindrance of the splitting molecule itself will hinder the possibility of dispersibility for (4)(10). The above-mentioned dispersed synthetic green can be purely branched, and can be used. (4) Japanese Patent Publication No. 63-30057 The method described in the following. 97136291 75 200948907 In the present invention, it is also possible to suitably use a curtain having the same structure as the above. Branch copolymer. (e-2) : "Propylene-containing block copolymer containing a nitrogen atom" A propylene-based copolymer having a nitrogen atom (hereinafter sometimes referred to as "(e_2) copolymer)") It is preferable from the viewpoint that (a) the color material is dispersed extremely efficiently. The reason for this is not clear, and since the molecular system is subjected to enthalpy, the structure which becomes hindered when adsorbed to (a) the color material is less. The (e-2) copolymer is preferably composed of an A block having a 4th-order salt group and/or an amine group in a side chain, and a B block having no 4-stage salt group and/or an amine group. The AB block copolymer and/or the block copolymer formed by the segment. The segment of the propylene-based block copolymer containing a nitrogen atom constituting the block copolymer has a 4-stage ammonium salt group and/or an amine group. The ammonium salt group is preferably a product Z- (wherein R31 and r33 are each independently, and represent a 3 atom or a substituted cyclic or chain hydrocarbon group. Alternatively, it may be in r3i, R and R. Two or more bonds are bonded to each other to form a cyclic structure. z_ represents a 4-stage ammonium salt group shown by a pair of ions. The 4-stage ammonium salt group may be directly bonded to the main two, or may be bonded via a divalent bond. Keyed to the primary key In the ring structure formed by R33·"' as ^ =, for example, a condensed ring obtained by condensation of a nitrogen-containing heterocyclic monocyclic ring of (10) ring may be mentioned. The aromaticity is more preferably a saturated ring. Specific examples thereof include the following: [Chem. 30] 97136291 76 200948907

In the above formula, R represents any one of R31, R32 and R33. These cyclic structures may further have a substituent. Further, as the N-R+R31R32R33 · Z, R31, R32, and R33, each of them is independently an alkyl group having 1 to 3 carbon atoms which may have a substituent, a phenyl group which may have a substituent, or may have a substituent. Benzyl. The A-segment segment having a 4-stage salt base preferably contains a part constructor of the following formula (vi). &lt; ❹ 97136291 77 200948907 [Chem. 31]

© In the above general formula (5), R31, R32 and R33 are discretely represented by a hydrogen atom or a cyclic or chain hydrocarbon group which may be substituted. Alternatively, two or more of r31, r and 俨 may be bonded to each other to form a ring structure. R34 represents a hydrogen atom or a fluorenyl group. Χ1 indicates a divalent bond group, and Ζ- indicates a pair of anions. In the general formula m), as the nicotine group of R33, it is preferred to independently represent an alkyl group having 1 to 10 carbon atoms or a substituent having an aromatic group having 6 to 20 carbon atoms. Specific examples thereof include a mercapto group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a fluorenyl group, a phenyl group and the like. Among them, a methyl group, an ethyl group, a propyl group or a benzyl group is preferred. The divalent bond group X1 in the general formula (VI) may, for example, be an alkyl group having a carbon number M〇, an extended aryl group, _c〇NH_R35-, or -C00_R36- (wherein R35 and π respectively represent a direct A bond group, an alkyl group of a carbon number of 10, or an ether group of a carbon number (-R37-〇-Rt: R37 and r38 are each independently an alkyl group).), etc., -COOf -. In addition, as the anion Z, for example, Cl—, Br_, Γ, “丨n: BF′, _) 〇 'PF6, etc. C1〇&quot; 97136291 78 200948907 As the A block, it is particularly preferable to have The amine group is preferably an aryl group 142 (wherein R and R42 each independently represent a cyclic or chain alkyl group which may have a substituent, an allyl group which may have a substituent, or may have a substituent The aryl group () is more preferably an amine group represented by the following formula.

❹ r41, N, r42 wherein R41 and R42 are synonymous with the above and r42, r43 represents an alkylene group having a carbon number i, and R44 represents a hydrogen atom or a methyl group. Wherein R41 and R42 are preferably a fluorenyl group, and R43 is preferably a methylene group or an ethyl group, r44

It is preferably a hydrogen atom. As such an ageing compound, a substituent which is represented by the following formula can be used. [化33]

The partial structure containing a specific four-stage ammonium salt group and/or an amine group as described above may be contained in two or more types in the block. In this case, a partial structure containing two or more kinds of four grades 97136291 79 200948907 ammonium salt group and/or an amine group may be contained in the A block in any of random copolymerization or fragmentation copolymerization. Further, the partial structure containing no amine group of the 4-grade base material may be contained in the A block. As an example of the structure of this part, for example, a partial structure derived from &quot;(mercapto)acrylic acid-based monomer, etc., which will be described later, may be mentioned. The content of the portion which does not contain the ammonium salt group and the amine group is not contained in the A block, and is preferably 〇 5 5% by weight, more preferably 0 〜 20% by weight, most preferably in the A block. The partial structure containing no 4 〇 ammonium salt group and/or amine group is not contained therein. On the other hand, as the b block constituting the (e-2) copolymer, for example, a copolymer structure in which copolymerization is carried out, such as a styrene monomer such as styrene or α-mercaptostyrene; (fluorenyl) decyl acrylate, ethyl (meth) acrylate, propyl (meth) acrylate, isopropyl (meth) acrylate, butyl acrylate (meth) acrylate, octyl (meth) acrylate, ( Mercapto) 2-ethylhexyl acrylate, glycidyl (meth) acrylate, benzyl (meth) acrylate, hydroxyethyl (meth) acrylate, ethyl acrylate propyl acrylate, etc. (meth) acrylate monomer; (mercapto) acrylate monomer such as vaporized (meth) acrylate; vinyl acetate monomer; allyl epoxidized ether, butenoic acid epoxy A comonomer such as a propyl propyl ether monomer such as propyl ether. The oxime block is particularly preferred from the partial structure of the (meth) acrylate monomer represented by the following general formula (VII). 97136291 80 200948907 [m 34] m) In the general formula (νιι), the 'R39 table money atom or? Base &lt; indicates that it can have a substitution

A cyclic or chain alkyl group, an allyl group which may have a substituent, or an aralkyl group which may have a substituent. The partial structure derived from the (meth)acrylic acid-based monomer may be contained in two or more kinds of β-embedded &amp; That is, the B block can also be advanced to have a structure other than these. In the case where the partial structure derived from the monomer is present in the B segment, the material structure may be contained in any of the forms of the block or the block copolymerization. In the B block containing the above from (methyl)

In the case of a partial structure other than the partial structure of the bupropion acid m body, the content of the 3 block of the structure other than the (meth) = acid s Japanese monomer is preferably 0 to 99% by weight, more preferably 0 to 85% by weight. = (e_2) copolymer, which is formed by such a block and β-formed -= segmental Α-Β block copolymer, which is conditioned, for example, by the active t law. The polymerization activity of the anion living polymerization method, the cationic living polymerization method, and the anionic living polymerization method described in the second example is an anion, 97136291 81 200948907 [Anionic living polymerization method] Monomer 1: h2c==9H Monomer 2: In the case of Η 2 〇 = ί: ΟΗ Organometallic (Μ) compound ΛΛΛ / 〇Η 2 - 单体 Monomer 1 &gt; Monomer -»► CHi-CH:

-CH2—wP I* ——fci n+1

-CH

H

〇nr-〇H n*1 ATJm+1 聚合 The radically active species of the radical living polymerization method is a radical, as shown in the following scheme. 97136291 82 200948907 [Chemical Process: Free Radical Living Polymerization Method: Nitroxide Method)

Situation

97136291 83 200948907 [Chem. 37]

(Free radical living polymerization method: atrp method)

Monomer 2:

The situation Φ:

+organic metal (Me) compound Me : transition metal

Λλγ «CHg—C ·|· one * «- COOR*Jn

Me

For the synthesis of such an acrylic acid-incorporated copolymer, Japanese Patent Laid-Open Publication No. SHO 60-89452, JP-A-9-62002, p. Lutz, p. Mass〇n et al, Polym. Bull, 12 , 79 (1984), BC Anderson, GD Andrews etal, Macromolecules, 14, 1601 (1981), K. Hatada, K. Ute, etal, Polym. J. 17, 977 (1985), K. Hatada, K. Ute , et al, Polym. J.18, 1037 (1986), Right Hand Hao Yi, Putian Gengyi, Polymer Processing, 36, 366 (1987), Dong Cun Min Yan, Sakamoto K., Polymer Proceedings, 46, 189 (1989), M. Kuroki, T. Aida, J. Am. Chem. Sic, 109, 97136291 84 200948907 4737 (1987), Xiangtian Zhuo San, Inoue Xiangping, Organic Synthetic Chemistry, 43, 300 (1985), DY Sogoh, WR Hertler et al A well-known method described in Macromolecules, 20, 1473 (1987), K. Matyaszewski et al, Chem, Rev. 2001, 101, 2921-2990. • The amine value (in terms of effective solid content) in lg of the (e-2) copolymer of the present invention is preferably 10 mgKOH/g or more, more preferably 20 mgKOH/g or more, still more preferably 5〇mgKOH/g or more, It is preferably 80 mgKOH/g or more, and is usually 3 〇〇mgKOH/g or less. Further, the acid value of the (e-2) copolymer depends on the presence or absence of the acidic group which is the basis of the acid value, and is generally preferably the lower one, and is usually not more than 1 mgK〇H/g. (e-2) The molecular weight of the copolymer is a polystyrene-equivalent weight measured by GPC, which is an average amount (Mw), and is usually in the range of 1 Torr or more and 〇〇Q or less. When the weight average molecular weight of the block copolymer is too small, the dispersion stability is lowered, and if it is too large, the dispersant molecules themselves are sterically hindered, and the adsorption to the (4) color material and the dispersibility tend to be lowered. The present invention may also have a commercially available acrylic block copolymer having the above-described complementary structure. (e-3) Amine Θ Θ 乙酯 乙酯 乙酯 树脂 」 」 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为 作为A cyanate compound, a compound having one or two hydroxyl groups in the same molecule, and a compound having an active hydrogen and a tertiary amino group in the same molecule. As an example of the above polyisocyanate compounding g-substrate, for example, p-phenylene diisocyanate 97136291 85 200948907 vinegar, 2,4-toluene diisocyanate, 2,6-toluene diisocyanate, 4, 4,-diphenyl group Aromatic diisocyanate of decane diisocyanate, naphthalene-1,5-diisocyanate, biphenyl diisocyanate, etc.; hexamethylene diisocyanate, aryl acid F ester 2'4'4 monomethyl phthalate Aliphatic diisocyanate of diisocyanate, dimer acid diisocyanate, etc.; isophorone diisocyanate, 4, 4, yttrium bis(cyclohexyl isocyanate), ω, ω, _ diisocyanate An aliphatic diisocyanate having an aromatic ring such as an alicyclic diisocyanate such as mercaptocyclohexane, xylene diisocyanate, α,α,α,α,-tetramethyl-tolyl diisocyanate or the like; Vinegar diisocyanate, 1,6,11-deca- dasan cyanide, 1,8-diisocyanate 4-isocyanate decyl octane, 1,3,6-hexyl triisocyanate, hydrazine Alkane triisocyanate, ginseng (isocyanate phenylmethane), ginseng (isocyanate phenyl) thiophosphorus One diisocyanate and the like; and a trimer of these, as well as hydrides such adducts of polyols and the like. Preferred as a terpolymer f of a polyisocyanate-based organic diisocyanate: a terpolymer of a good toluene diisocyanate g and a dimer of isophorone diisocyanate, which can be used alone or A plurality of kinds can be used in combination. Examples of the method for producing the isocyanate-based terpolymer include the above-mentioned polyiso are, for example, a tertiary amine, a phosphine, or an alkoxide.

Examples of the compound having one or two groups in the same molecule include cyanic acid and vinegar, which are evolved by using an appropriate trimerization catalyst, a metal oxide, a carboxylate or the like. *Miscellaneous Gangui / Main 97136291 86 200948907 Polyether diol, polyester single compound single-end m alcohol, hydrocarbon diol, etc., or such lysine 25 lysine, or 4 Two or more kinds of mixtures. As the dimethyl diol, a mixture of two or more kinds of these may be used, such as a polyether diol, a polyether ester diol, or the like. ❹

The poly(tetra)-alcohol can be homopolymerized or copolymerized by epoxy burning, for example, polyethylene glycol, polypropylene glycol, polyethylene-propylene glycol, polyoxybutanol, polyoxyethylene diol, poly Oxyoctanediol or a mixture of two or more of these. The diol of 1|5|1 is a reaction of a peak-containing diol or a mixture with another diol with an acid of citric acid or the like, or a reaction of a polyester diol with an alkylene oxide. 'For example, poly(polyoxytetradecyl) adipic acid or the like can be mentioned. The most preferred polyether diol is a compound in which polyethylene glycol, polypropylene glycol, polyoxybutylene glycol, or a single terminal hydroxyl group of these compounds is alkoxylated with an alkyl group having 1 to 25 carbon atoms. The polyester diol is, for example, a dicarboxylic acid such as succinic acid, glutaric acid, adipic acid, sebacic acid, fumaric acid, maleic acid or citric acid or an anhydride thereof. For example, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 2, 3 -butanediol, 3-mercapto-1,5-pentanediol, neopentyl glycol, 2-mercapto-1,3-propanediol, 2-mercapto-2~propyl~1,3-propanediol, 2-butyl-2-ethyl-1,3-propanediol, 1,5-pentanediol, 1,6-hexanediol, 2-methyl-2, 4-pentanediol, 2, 2, 4 -trimethyl-l,3-pentanol, 2-ethyl-1,3-hexanediol, 2,5-dimercapto-2, 5-hexanediol, 1,8-97136291 87 200948907 Xin An aliphatic diol such as a diol, 2-mercapto-1,8-octanediol, j, anthracene alcohol or the like; an aromatic diol such as an alicyclic H-benzene or the like having a double-based F-based ring-like appearance a glycol which is obtained by polycondensation of a diol such as N-methyldiethylammonyl alcohol or a bis-acetoxy group, and can be N-aminodithioanilide ethyl ester or polyadipate butyl vinegar , polyadipate hexahydrate =: use polyadipate extension / extension A vinegar or the like, or a poly(tetra) diol or a polyhydric alcohol obtained from the above diol or carbon number = hexanoic acid

(4) Stealing... For example, poly-hexane diol, t-methyl valerate, or two or more of the present alcohol diols, which are poly-caprol diol or carbon number 2 Vinegar vinegar, more specific and ancient, M t is the starting compound of the compound. The (4) bribe is added to the monool. As the polycarbonate diol, for example, poly(16-extended hexyl)carbon _, poly(3)methyl-1,5-exopentyl) carbonate or the like can be mentioned. Further, examples of the hydrocarbon diol include polybutylene dilute diol, hydrogenated polybutadiene diol, and hydrogenated polyisoprene diol. Among these, a compound having one or two mercapto groups in the same molecule is particularly preferably a polyether diol and a polyglycol diol. Further, the number average molecular weight of the compound having i or two radicals in the same molecule is usually from 3 Å to 1 Torr, preferably from 500 to 6,000, more preferably from 1,000 to 4, 000. In the compound having an active hydrogen and a tertiary amino group in the same molecule, the active hydrazine, that is, a hydrogen atom directly bonded to an oxygen atom, a nitrogen atom or a sulfur atom, may, for example, be a hydroxyl group, an amine group or a thiol group. The hydrogen atom in the functional group of the group or the like is preferably a hydrogen atom of the amine group which is preferably an amine group in 97136291 88 200948907. Further, examples of the tertiary amine group include a dialkylamino group having a carbon number of a methyl group, an ethyl group, an isopropyl group, a n-butyl group or the like, or a dialkylamino group bonded to form a hetero group. The base of the ring structure can be more specifically exemplified by (4) or three pins, wherein the f-base wire is preferred because it has superior dispersion stability. ❹ If such a compound having an active hydrogen and a tertiary amino group in the same molecule is exemplified, for example, dimethyl-1,3-propanediamine, N,N-diethyl+3-propylenediamine, N ,N-di-diyl-1 3-propanediamine, N,N-dibutyl gas 3-propylenediamine, N,N-dimethylethylenediamine, N,N-diethylethylenediamine Dipropylethylenediamine, N'N-dibutylethylenediamine, N,N-dimercaptodecylbutylamine, bismuth-diethyl-1'4-butanediamine, N'N-II Propyl 4-butanediamine, N, n-dibutyl-indole-butylene diamine, and the like. 'Alternative' is a nitrogen-containing heterocyclic ring, and examples thereof include a (tetra) ring, a taste ring, a triplet, a three-salt ring, a (tetra) ring, a ten-ring ring, an anthracene ring, a benzo ring, and a benzotriene. a 5-membered ring containing a nitrogen atom such as a ring, a benzo ring, a benzene (tetra) or a divalent ring; a pyridine ring, an anthracene ring, a pyrimidine ring, a three-till ring, a quinoline ring, a bite ring, a foreign material A compound having a ring of such an imidazole ring and a group 1 amine group, such as 丨-(3-aminopropyl)imidazole, histidine, 2-amino group, etc. Imidazole, di(2-aminoethyl)carbazole, and the like. ^, if a compound having a triazole ring and a phosphonium amino group is specifically exemplified, for example, t-amino-1,2,4-triazole, 5-(2-amino-5-phenylphenyl)_3_phenyl - 丨肜丨, 2 4 1-3 spit, 4-amino rulu u'4-tris- 3,5-diol, 3~amine benzene: 97136291 89 200948907 -111-1,3,4-three Oxazole, 5-amino-1,4-diphenyl-1,2,3-triazole, 3-amino-1-benzyl-1H-2, 4-triazole, and the like. Among these, n,N-dimethyl-i,3-propanamine, Ν'N-diethyl-1,3-propylenediamine, 1-(3-aminopropyl) are preferred. Imidazole, 3-amino-1,2,4-triπ sitting and the like. (e-3) A preferred use ratio of the raw material of the dispersant is usually 10 to 200 parts by weight, preferably 2 Å, based on 100 parts by weight of the polyisocyanate compound in the same molecule. 2〜25重量份,优选〇3〜24重量份。 190 parts by weight, more preferably 30~180 parts by weight, the same molecule having active hydrogen and a tertiary amine group is usually 0. 2~25 parts by weight, preferably 〇. 3~24 parts by weight. Further, the production of the (e-3) dispersant is carried out in accordance with a known method for producing a urethane resin. As a solvent at the time of manufacture, a ketone of acetone, mercaptoethyl ketone, methyl isobutyl ketone, cyclopentanone, cyclohexanone, isophorone, etc., ethyl acetate, butyl acetate, acetic acid raceway is generally used. An ester of sulphate, a hydrocarbon such as benzene, toluene, xylene or hexane; a sterol such as diacetone alcohol, isopropanol, second butanol or third butanol; dichlorodecane chloroform; Halogenated hydrocarbons, ethers such as tetrahydrofuran and diethyl ether; aprotic polar solvents such as dimercaptocaramine, N-methylpyrrolidone and dimethyl sulfoxide. Further, as a catalyst for production, a general amine ruthenate reaction catalyst can be used. For example, dibutyltin dilaurate, dioctyltin dilaurate, dibutyltin dioctanoate, stannous octoate, etc.; iron; iron; ferric chloride; a tertiary amine system such as an amine or triethylenediamine. The amount of introduction of the compound having active hydrogen and the third-order filament in the molecule is preferably controlled so that the amine price of the (e-3) dispersant after the reaction becomes in the range of 97, 136, 291, 2009, 907 mg KOH / g, It is preferably in the range of 5 to 8 〇 mg K 〇 H / g, more preferably in the range of 1 〇 to 6 〇 mgKOH / g. If the amine value is outside the above range, the dispersing ability tends to decrease. Also, in the above reaction, in the (e_3) dispersant molecule, in the case of the base, the money-step reacts the alcohol or the silk compound with the isocyanate group, because of the (e-3) dispersant. It is preferred when the stability becomes high. Further, the polystyrene-equivalent weight average molecular weight of the 4-amino decanoic acid ethyl ester resin dispersant measured by Gpc is usually 1 〇〇〇 2 〇〇〇〇〇, preferably ' 2 ' 000 〜 100 , 000, better 3, 000 to 50, the range of 〇〇〇. When the weight average molecular weight is 1,000 or less, dispersibility and dispersion stability tend to be deteriorated, and when it is 200,000 or more, solubility is lowered and dispersibility is deteriorated, and it is difficult to control the reaction. (e-4): "Other dispersing agent" The (e) dispersing agent used in the colored curable resin composition of the present invention may be a dispersing agent other than the above (e-Ι) to (e-3). Contains other dispersing agents. ❹ Examples of the other dispersing agent (e-4) include a polyallylamine-based dispersing agent, a dispersing agent having a monomer having a private monomer and a macromonomer, and a polyoxyethylene alkyl ether-based dispersing agent. The polyoxyethylene diester dispersing agent, the polyether tartaric acid dispersing agent, the polyester acid filling type are a powder, a sorbitan aliphatic vinegar dispersing agent, and an aliphatic modified polyester dispersing agent. As a specific example of such a dispersing agent, for example, efka (efka)

Chemicals BV (made by EFKA), Disperbyk (manufactured by BYK Chemi Co., Ltd.), DISPARLON (manufactured by Nanmoto Chemical Co., Ltd.), s〇LSPERSE (manufactured by Lubrizo Co., Ltd.), 97136291 91 200948907 ΚΡ (manufactured by Shin-Etsu Chemical Co., Ltd.), p〇iypr〇 (available from Kyoeisha Chemical Co., Ltd.) and AJISPER (manufactured by Ajinomoto FINETECH Co., Ltd.). In the colored curable resin composition of the present invention, the content ratio of the (e) dispersant is usually 95% by weight or less, preferably 65% by weight or less, more preferably 50% by weight or less, based on the (a) color material. The amount is usually 5% by weight or more, preferably 7% by weight or more, and particularly preferably 1% by weight or more. When the content ratio of the (e) dispersant is too small, the adsorption of (a) the color material is insufficient, and aggregation cannot be prevented, and there is a case where the viscosity is high or even gelled. As a result, there is a possibility that the dispersion stability is deteriorated, and problems such as re-aggregation or thickening occur. On the other hand, if it is too large, the coloring power is lowered because the ratio of (a) the color material is relatively decreased. Therefore, the film thickness becomes excessive with respect to the color density, and when used in a color filter, there is a case where the cell gap control at the liquid crystal cell formation step is poor. In the colored curable resin composition of the present invention, in the case where the dispersant contains, in particular, (e-2): an acrylic block copolymer, the effect is remarkably remarkable. Specifically, for example, an ab block copolymer and/or a B_A_B block copolymer formed of an A block having an amine group in a side chain and a B block having no amine group in a side chain, and the block may be mentioned. The copolymer has an amine valence of 1 〇 mg K 〇 H / g (calculated as effective solids) or more. Moreover, the amine value (calculated as the effective solid content) of the dispersing agent is preferably 10 mgKOH/g or more, more preferably 2〇mgKOH/g or more, still more preferably 5〇mgKOH/g or more, and particularly preferably 80 mgKOH/g or more. Usually it is 300 mgK〇H/g or less. Further, the color-curable resin composition of the present invention is in the step of dispersion treatment 97136291 92 200948907 described later, and can be used as the dispersant in the above (e), and in the above (b):::. As such, sometimes the resin of the same % is referred to as "dispersion resin". [1 - 6] (f) monomer The color-curable tree composition of the present invention preferably contains a monomer which is a low-molecular compound which can be polymerized - Quantitative Tricor (L) has a miscellaneous A compound capable of undergoing addition polymerization of a double bond (hereinafter sometimes referred to as "ethylenic compound"). When the color-curable resin composition of the present invention is irradiated with active light, the thermal polymerization initiation mechanism described later by the heat of the Wei-light polymerization initiation system is carried out, and the addition and hardening of the ethylene is carried out. Sex double _ compound. Further, the monomer of the present system means a concept relating to a polymer substance, and includes a dimer, a trimer, and an oligomer in addition to a narrowly defined monomer.

Examples of the ethylenic compound include unsaturated acid such as (meth)acrylic acid, monoester and unsaturated ester, ester of polyhydroxyl compound and unsaturated carboxylic acid, and aromatic polyhydroxy compound. An ester of a saturated carboxylic acid, which is obtained by an esterification reaction of a polyvalent carboxyl compound such as Weishen (4) and the above-mentioned fat-based compound, an aromatic polyhydroxy compound, etc. An ethylenic compound having an urethane skeleton and the like which are reacted with a compound of (meth) acrylonitrile. Examples of the ester of the polyhydroxy compound and the unsaturated carboxylic acid of the aliphatic group include, for example, Ethylene No. 97136291 93 200948907 Alcohol di(meth)acrylate, Tris(hydroxymethylolpropane) tris(methylpyryl)-(meth)acrylic acid Ester, ethoxylated acid vinegar, three-way acetazone _ acid _, tri-n-propyl propyl tris(methyl) propylene propylene, c methyl propyl propylene, quaternary monomethyl) 丙 C riding, two seasons :: alcohol,) propylene, pentaerythritol is called propionate, dipentamethyl) acrylic acid 1, dipentaerythritol penta(methyl) vinegar, triglycerin diethylene hexa(meth) acrylate, glycerol (Methyl)propionic acid acrylic acid, such as phthalic acid ester, isopropyloxy diglycerin di(yl) (methyl) propyl group, for example, such a propyl (tetra) acid moiety 2, the clothing of the Kang Kang, replaced by Ding, in addition, is said to be &quot; acid cis enedic acid vinegar, etc. ^ &amp; money base compound for the purpose of saturated ships, such as hydroquinone (methyl ) acrylate, resorcinol di(meth) acrylate, triploid tris(monomethyl) acrylate, etc. Also, as a measure of the polyunacid and the oxime compound by the unsaturated test Anti-reverse The obtained ester, which is not a single substance, may be a mixture. As a representative example thereof, a condensate of glycerol, citric acid and ethylene glycol may be used; (mercapto)acrylic acid, cis a condensate of butenedioic acid and diethylene glycol; a condensate of (mercapto)acrylic acid, p-citric acid and pentaerythritol; a condensate of (meth)acrylic acid, adipic acid, butanediol and glycerin, etc. The ethylenic compound having an amino ruthenium ruthenate skeleton which is reacted with a perylene group-containing compound of a (meth) fluorenyl group, and the like, may be an aliphatic group such as hexamethylene diisocyanate or trimethylhexamethylene diisocyanate. Alicyclic diisocyanate such as diisocyanate, cyclohexyl diisocyanate, isophorone diisocyanate, etc. 97136291 94 200948907 Aromatic diisocyanate, such as ester, toluene diisocyanate, diphenylnonane diisocyanate, etc. a reaction product of a (meth) acrylonitrile-containing hydroxy compound such as 2-hydroxyethyl styrene or 3-hydroxy[m-tris(methyl) propylene fluorenyl fluorenyl]propane. Invention used Examples of the ethylenic compound include, for example, (mercapto) acrylamide such as ethylene bis(indenyl) acrylamide; allyl esters such as diallyl phthalate; and divinyl phthalate. Further, the vinyl compound may be a monomer having an acid value. As the monomer having an acid value, for example, an ester of an aliphatic polyhydroxy compound and an unsaturated carboxylic acid, it is preferred to The polyfunctional monomer having an acid group in which the anti-contact group of the aliphatic hetero compound is reacted with the non-aromatic acid liver is particularly preferably in the vinegar, and the aliphatic compounding compound is pentaerythritol and/or dipentaerythritol. The monomer may be used alone or in combination, and it may be difficult to obtain a mono-compound. Therefore, two or more kinds may be used in combination. Further, if necessary, a polyfunctional monomer having no acid group and a polyfunctional group having an acid group may be used in combination. The monomer acts as a monomer. The preferred acid value of the polyfunctional monomer having an acid group is (U 4 4 mgKGH/g, particularly preferably 5 to deposited/g. Further, a polyfunctional monomer having two or more different acid groups in combination is used. When the polyfunctional monomer having no acid group is used in combination, it is preferred to adjust the acid group of the entire polyfunctional monomer to the above range. The polyfunctional monomer having an acid group is preferably used in East Asia. 々 々 ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ ΊΌ 95 200948907, $$ can be used in combination with other polyfunctional monomers. The color hardening composition of the present invention is used in an inkjet color/lighting sheet '(1) monomer Preferably, it is a linear one or a relatively small molecular weight, and is preferably, for example, an ethoxylated trisyl propyl succinate ((iv) acryl vinegar, triglycerin bis (methyl, isopropyloxy diglyceride) Methyl) acrylate, etc. This compound is based on "brain" and "face FA" (all products) . Co-Prosperity

It is commercially available from the company of "Chemical Chemicals Co., Ltd." and "Α_ΤΜρτ一勘" (trade name. New Lingcun Chemical Industry Co., Ltd.). In the color-curable resin composition of the present month, the content ratio of the (1) monomer is in the total solid content, and is usually 〇% by weight or more, preferably 5% by weight or more, more preferably one, and usually two

G is more preferably 50% by weight or less, and particularly preferably 4% by weight or less. Further, the ratio '(4) of the color material is usually 〇% by weight or more, preferably 5% by weight or more, more preferably 10% by weight or more, particularly preferably 20% by weight or more, usually 2% by weight or less, preferably 100%. It is below weight%, more preferably 80% by weight or less. [l-7] (h) Photopolymerization Initiating System and/or Thermal Polymerization Initiator The curable resin composition of the present invention is intended to harden a coating film, and preferably contains (h) a photopolymerization initiating system. And/or a thermal polymerization initiator (hereinafter sometimes referred to as "(h) component"), but the curing method may be carried out other than the above-mentioned initiator. In particular, when the curable resin composition of the present invention contains a resin having an ethylenic double bond as the (b) binder resin or an ethylenic compound as a (丨) monomer component, it is a curable resin composition. The middle is blended with the following: directly absorbs 97136291 96 200948907 light, or undergoes photo-sensitization to undergo decomposition reaction or dehydrogenation reaction, and has a photopolymerization enthalpy system which generates a function of polymerizing active radicals and/or is generated by heat. A thermal polymerization initiator for polymerizing living radicals. In addition, the component (h) which is a photopolymerization initiation system in the present invention means an accelerator (hereinafter sometimes referred to as (h2)) in combination with a photopolymerization initiator (hereinafter sometimes referred to as a (hi) component). A mixture of an additive such as a component) or a sensitizing dye (hereinafter sometimes referred to as a component (10)).卜 [Bu 7~1] Photopolymerization Initiator The color-curable resin composition of the present invention contains a photopolymerization initiation system as the component (h). The photopolymerization initiation system of the component (h) is usually used as a mixture of a (hi) photopolymerization initiator and, if necessary, an additive of (h2) a polymerization accelerator or a (h3) sensitizing dye. A component which directly absorbs light or undergoes photo-sensitization to cause a decomposition reaction or a dehydrogenation reaction, and has a function of generating a living radical. For example, the (hi) photopolymerization initiator which is a photopolymerization initiation system, for example, is disclosed in Japanese Patent Laid-Open Publication No. Sho 59-152396, No. 6M51197, and the like. The genus of the genus of the genus of the genus of the genus of the syllabus of the Japanese Patent Laid-Open No. Hei 10-- No. Hei. Tetramethylated $ triterpenoid derivatives, dentate methyl-allotene derivatives, N-phenylglycine and other square-α-amino acids, N_aryl_α-amino groups a radical active agent such as an acid salt or an N-aryl amino acid ester, or an α-amino phenylalkyl ketone derivative; and an oxime ester derivative described in JP-A-97136291 97 200948907 2000-80068 Things and so on. Specifically, for example, as the titanocene derivative, for example, dicyclopentadienyl dititanium dichloride, dicyclopentadienyl diphenyl titanium, dicyclopentadienyl bis (2' 3, 4, 5, 6-pentafluorophenyl]-based light, dicyclopentanol double (2, &&amp;&lt;&lt;&gt; _Trifluorophenyl)titanium, dicyclopentadienyl bis(2,6-difluorobenzene+yl)titanium, dicyclopentadienylbis(2,4-difluorophenyl-1-yl)titanium, Bis(methylcyclopentadienyl)bis(2,3,4,5,6-pentafluorophenylindenyl)titanium, mono(methylcyclopentadienyl)bis(2,6-di-benzene)卜基)钦, Dicyclopentadienyl [2,6-di-fluoro-3-(pyrrole-fluorenyl)-based benzoyl-titanium, etc. As a conjugate-reading organism, for example, 2_(2 , _ chlorophenyl) _ 4,5-diphenyl odor wad dimer, 2-(2,-chlorophenyl)], 5-bis(3,f oxyphenyl)imidin II, 2 -(2'-fluorophenyl)-4,5-diphenyl-saliva dimer, 2_(2, _methoxy-based)-4, 5-diphenyl dimer, (4, _ Methoxyphenyl) 5-diphenylimidazole dimer, etc. ❹ as a di-salt derivative such as methylated For example, 2_trichloromethyl+(2'-benzo-dopyranyl)go 3,4u-seat, 2_trichloromethyl_5_[π-benzoxyl)-ethylene group H,3, 4H,2-trichloromethyl-(2-(6''-benzophenanyl)B)&amp; 4_崎二哇,2_trichloromethyl-5-furanyl-1,3, 4-n-dioxadiazole, etc. As a dentate methyl--tris-morphine derivative, 2_(4-methoxyphenyl-) 4,6-bis(trichloromethyl)-single beer can be mentioned. 2 (4-methoxynaphthyl η, bis (disyl) - sylvestre, 2_(4-ethoxynaphthyl)_4,6-bis(trichloromethyl)-97136291 98 200948907 6~ Bis(trismethyl)-tris-triphthyl, tris-, 2-(4-ethoxydylnaphthyl)__4, etc. 〇❹ As the aminobenzoalkyl ketone derivative, for example, 2_ Methyl-methylmethylthio)phenyl]-2-indenylpropane-1, thiodiphenylphosphonium phenyl)-based ketone] ♦ 琳 phenyl phenyl butyl ketone , 4-dimethylaminoethyl benzoic acid, 4 dimethylaminoisoamyl phenyl hydrazine, 4-diethylaminophenyl benzene, 4 dimethylamino phenyl propyl , 2_ethylhexyl-1,4-dimethylaminobenzoic acid vinegar, 2,5-bis(4-diethylaminobenzene) Methylene)cyclohexanone, 7-diethylamino 1 (4-diethylaminobenzimidyl) coumarin, 4-(diethylamino)chalcone, and the like. Examples of the glycerin derivative include octanediol, benzo[4-(phenylthio)phenyl], 2-[o-benzil-based brick], ethyl ketone, and [9_ethyl_6_ (2-methylbenzhydryl)-9H-flavor-3-yl], 1-(o-ethylidene), and the like. In addition, it can also be exemplified by benzoin fine, benzoin isobutyl ether, benzoin and other benzoin silk _ 贞; 2_f kewei, 2-ethyl germination, 2 _ third butyl brewing, brewing Derivatives; diphenyl ketone, rice ketone, 2-methyl diphenyl ketone, 3 fluorenyl diphenyl ketone, 4-methyl diphenyl ketone, 2-chlorodiphenyl ketone, 4 Diphenyl ketone derivatives such as brominated diphenyl ketone and 2 fluorenyl diphenyl ketone; 2,2-dimethoxy-2-phenylacetophenone, 2 2 -diethoxydiethyl Ketone, 1, cyclohexylphenyl-, α-hydroxy-2-methylphenylpropanoid: hydroxy-1-methylethyl-(p-isopropylphenyl)one, 1-hydroxy-1 -(p-dodecylphenyl) ketone, 2-mercapto-(4,-methylthiophenyl)_2_ morpholinyl-propanone, ^97136291 99 200948907 #曱土(对butyl Base)_ and other acetophenone derivatives; oxysulfosin, soil 9 oxopurine beta star, 2-isopropyl _9_oxythiocarbanin, 2_chlorine oxysulfide star 2'4 one 9-oxo-sulfur dJjd star derivatives such as methyl-9-oxysulfur 0 Yamaguchi, 2,4-diethyl-9-oxosulfide+star, 2,4_-isopropyl-9-oxathione; P-dimethylaminophenyl hydrazine Benzoic acid vinegar derivatives such as ethyl acetoacetate and p-diethylaminophenyl phthalate; 9 bite-based bites, 9-(p-methoxyphenyl) bites, etc. A morphine derivative such as benzomorphine; a quinone derivative such as benzopyrone and the like. Examples of the (h2) polymerization accelerator used as needed include hydrazine, hydrazine-dimethylamino benzoate, and the like, hydrazine-dialkylaminobenzoic acid alkyl esters; a mercapto compound having a heterocyclic ring such as benzothiazole, 2-mercaptobenzoxazole or 2-mercaptobenzimidazole; or a mercapto compound such as an aliphatic polyfunctional mercapto compound. These (hi) photopolymerization initiators and (h2) polymerization accelerators may be used alone or in combination of two or more. In the colored curable resin composition of the present invention, the total content of the (hi) photopolymerization initiator and the (h2) polymerization accelerator is usually 〇·1% by weight or more, preferably in the total solid content. 0.5% by weight or more, and usually 40% by weight or less, preferably 30% by weight or less. If the content ratio is significantly lower, there is a case where the sensitivity to exposure light is lowered. If it is significantly higher, the unexposed portion is less soluble in the developing solution, and the image is poorly induced. situation. In addition, (h3) sensitizing 97136291 100 200948907 pigment can be used as needed to improve the sensitivity of the sensing. (10) The sensitizing dye may be used in an appropriate manner in accordance with the wavelength of the pattern exposure light source, and y, for example, ♦ 星 色素 色素 958 958 958 958 958 958 958 958 958 958 958 ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; a coumarin-based dye having a heterocyclic ring described in each of the publications of the Japanese Patent Publication No. Hei 5-289335, and a soy-based compound described in the publications of the Japanese Patent Publication No. Hei No. Hei No. Hei. Etc. Narrative to methylene-based pigments; special opening Zhan 47-2528, special opening 54-155292, special: Zhaoyi 45_37377, special opening 48-84183, special opening 52-112681, ^ open昭58-15503号, 特开昭6〇_88〇〇5号特开昭59_56备号: Special Kaikai 2-69, Special Kaikai 57_16 No., Special Kaiping 5]〇7761, Special Kaiping 5-210240 A dye having a dialkylamino benzene skeleton described in each of the publications of Japanese Laid-Open Patent Publication No. Hei. The sensitizing dye is preferably a sensitizing dye containing an amine group, and more preferably a compound having an amine group and a phenyl group in the same molecule. Particularly preferred are, for example, 4, 4,-didecylaminodiphenyl ketone, 4,4,-diethylaminodiphenyl ketone, 2-aminodibenzolone, 4-amino group a diphenyl ketone compound such as diphenyl ketone, 4, 4,-diaminodiphenyl ketone, 3,3,diaminodiphenyl ketone or 3,4-diaminodiphenyl ketone; 2 gas monomethylaminophenyl)benzoxazole, 2-(p-diethylaminophenyl)benzoxazole, 2-(p-monomethylaminophenyl)benzo[4, 5] benzopyridinium, 2-(p-dimethylamine iphenyl)benzo[6,7]benzoxazole, 2,5-bis(p-diethylaminophenyl)purine, 3 , ' : carbazole, 2-(p-dimethylaminophenyl)benzothiazole, 2-(p-diethylaminophenyl)benzothiazole, 2-(p-dimethylaminophenyl) Benzimidazole, 2_(p-diethyl I 97136291 101 200948907 aminophenyl) benzimidazole, 2, 5-bis(p-diethylaminophenyl), 3, 4-thiadiazole, (pair two F-aminoaminophenyl)acridine, (p-diethylaminophenyl) pyridine, (p-monodecylamine basic) 啥 、, (p-diethylaminophenyl) 噎 琳, (p-dimethylaminophenyl) a compound containing a p-dialkylaminophenyl group such as pyridine or (p-diethylaminophenyl)pyrimidine, etc. Among them, 4, 4'-didecylaminodiphenyl ketone, 4'4' is most preferred. - 4,4,-dialkylaminodiphenyl ketone, such as diethylaminodiphenyl ketone. The sensitizing dye may be used alone or in combination of two or more. Ο 著 The color-curable resin of the present invention In the composition, the content ratio of the (h3) sensitizing dye is in the total solid content, and is usually 〇% by weight or more, preferably Q·2% by weight or more, more preferably 5% by weight or more, and X is usually 2 The range of the weight % or less, preferably 15% by weight or less, more preferably 10% by weight or less. [m] The thermal polymerization initiator is a specific example of the starting lion of the present invention (8), and may be, for example, even A nitrogen-based compound, an organic peroxide, hydrogen peroxide, etc. Among these, an azo-based compound is suitably used. Examples of the azo-based compound include: ?氦氦 potential〇^... 2,2,-azobis(2-methylbutyronitrile), u, azobis(bis(cyclohexene-M-phthalonitrile),

Methyl dimethyl valeronitrile, H azo] amylamine (2-(Aminomethyl azo) methyl ethyl) methyl, ship methyl "side 2 ~ etched "λτ working ethyl" Propylamine], 2,2,-even, 〇# makeup, 2,2-azobis[Ν-(2-propyl)-2-ethylpropanamide], 2 2, Occasionally bis[Ν-butyl-2-methylpropene 97136291 102 200948907 amine], 2,2,-diox bis[N-cyclohexyl-2-indenyl-propyl], 2,2, _azo Bis(dimethyl-1methylpropionamide), 2'2,, bis(dimethyl-2-methylpropanoate@曰, 2'2'-azobis(2,4'4-three Methylpentene), etc., among these, 2,2, 'azobisisobutyronitrile, 2,2, 'azobis(2,4-dimethylvaleronitrile), etc. are as organic. Examples of the peroxide include, for example, benzammonium peroxide, dibutyl peroxide, cumene hydroperoxide, etc., and specific examples thereof include diisobutyl peroxide, and cumene peroxynonanoate. Base vinegar, di-n-propyl sulphate diacetate, diisopropyl thiodicarbonate, peroxydicarbonate, second butyl vinegar, peroxidation, hexaic acid 1,1,3,3- Tetramethyl butyl g, peroxydicarbonate Tert-butylcyclo) vinegar, peroxy neodecanoic acid cyclohexyl group + methyl ethyl vinegar, peroxidized monolithic acid 1-(2-ethoxyethyl) vinegar, diethylhexyl peroxydicarbonate ) - 曰peroxidic neodecanoic acid second hexyl g, peroxydicarbonate two oxybutyl hydrazine, peroxy neodecanoic acid tert-butyl vinegar, peroxypivalic acid third hexyl styrene, ^ oxidized neopentyl Acid tert-butyl vinegar, bis(3,5,5-trimethyl hexyl peroxide), di-n-octane octyl alcohol, dilauroyl peroxide, distearyl peroxide, Oxidized 2-ethylhexanoic acid L!,3,3_tetramethylbutyl vinegar, peroxidized No. 2, 5-, 5-dimethyl-2'5-di(peroxide 2-ethylhexyl peroxide Hexane, peroxyl ethylhexanoic acid, third hexyl vinegar, bis(4-methylbenzaldehyde), peroxyethylhexanoic acid, tert-butyl vinegar, dibenzoyl peroxide , Isobutylbutyric acid, butyrate, 1,1-di(t-butylperoxide), 2-methylcyclohexan,! , Bu 2 (tert-butyl peroxy)-3,3,5-tri-T-cyclohexane, U-di (peroxidized third hexyl) cyclohexyl, 1,1-di (peroxidized third) Base) cyclohexene, 2,2_2 (4,4—97136291 103 200948907 tributyl) cyclohexyl) propyl, Weihua: isopropyl monocarbonate peroxidation: acid third Purpose, peroxidation - such as tris-butyl ester, butyl laurate tributyl, 2,5-di-nic acid 3_f_f fluorenyl (four), wedip propyl single carbonization 1 &amp; Weihua 2~ Ethylhexyl monocarbonate, third τ-ester, peroxy^^-hexyl ester, 2,5-di-methyl '5-di(peroxybenzoyl) ❹ 、, broadly oxidized acetic acid Butyl vinegar, 2,2_di-(t-butylperoxy peroxide) butane peroxybenzoic acid tert-butyl ester, 4,4-di-(t-butylperoxy)pentanoic acid n-butyl , 2 (peroxide 2_t-butyliso-yl)benzene, diisopropyl peroxide, di-hexyl peroxide, 2,5-dimethyl- 2, and b (third oxidation) Base) hexane, dibutyl butyl peroxide, hydroperoxide ruthenium, 2,5-dimethyl^5-di(t-butylperoxy)hexyne-3 , diisopropylbenzene hydroperoxide, hydrogen peremulsification 1,1'3, 3-dimercaptobutyl, cumene hydroperoxide, tert-butyl hydroperoxide, tert-butyl trimethyl peroxide Base alkyl, 2 3 - dimethyl mono-diphenyl butyl hydride, bis(3- mercapto benzene fluorenyl) and peroxy benzoic acid (3 - decyl phenyl hydrazine) and peroxidation A benzophenone group, etc., and a mixture of these, and the like. Further, the above-mentioned (hi) photopolymerization initiator may, for example, function as a thermal polymerization initiator as in the case of an amine phenyl ketone compound. Therefore, a compound selected from the examples enumerated as (hi) photopolymerization initiator can also be used as the thermal polymerization initiator. These thermal polymerization initiators may be used singly or in combination of two or more. When the proportion of the thermal polymerization initiator is too small, the film is insufficiently hardened, and the durability of the film as a color 遽 97136291 104 200948907 is insufficient. If the amount is too large, the degree of heat shrinkage becomes large, and cracks and cracks occur after heat curing. Moreover, the storage stability is also lowered. Therefore, the coloring of the present invention is more suitable for the thermal polymerization of the tanning tree A composition towel, and is preferably in the form of i«solid injury, 〇30% by weight, and particularly preferably 〇2% by weight. Choose within the scope. [1-8] Other surfactants As described above, the colored hardening tree of the present invention does not impair the invention.

Within the scope of the effect, other surfactants may be included in addition to the compound described in the item (g) surfactant. As other interfaces, _ sub-, yang, non-ionic, and amphoteric interface can be used, which can cause adverse effects on electrical prevalence or (6) organic dissolved miscellaneous women. From a lower point of view, it is preferred to use a nonionic surfactant. As the cationic surfactant, for example, an alkyl sulfate-based surfactant such as "Measure 10" manufactured by Kao Corporation, and an alkylnaphthalenesulfonate such as "PELEX nb-l" manufactured by Kao Corporation. It is a surfactant-based surfactant, a special polymer surfactant such as "H0M0GEN0L L-18" and "H0M0GEN0L L-100" manufactured by Kao Corporation. Among these, it is preferable that the specific polymer interface activity is a special polycarboxylic acid type polymer surfactant. Examples of the cation surfactant include a silk fibroin (IV) surfactant such as "ACETAM brain" manufactured by Kao Corporation, and a quaternary salt-based surfactant such as "QUA_IN24P" and "qUARTAM brain w" manufactured by Kao Corporation. . Among these, a 4-grade ammonium salt-based surfactant is more preferably a hard grease 97136291 105 200948907-based dimethyl-methyl salt-based surfactant. The non-ionic surfactants include, for example, "SH_" in the TORAY SILIC0NE, "Gold" in SILICONE, and surfactants; "Fc injury" manufactured by Sumitomo 3M Co., Ltd. , "F470" manufactured by Otsuka Ink Chemical Co., Ltd., a fluorine-based system such as _S company's factory-18", rEMULGENl〇4Pj 'rEMULGEN A60j # polyoxyethylene women's surfactant. Among these, it is preferable that the poly-stone-oxygen interface is a so-called poly-mystery structure having a structure in which a side chain of a (tetra) group or an aromatic group is added to a polydimethyl oxo group. A carboxylic or aryl-based modified polyoxo-based surfactant. The interface/tongue agent may be used in combination of two or more kinds, and examples thereof include a polyoxygen-based surfactant/gas-based surfactant, a polyoxo-based surfactant/special polymer-based surfactant, and a fluorine-based interfacial activity. Among them, a combination of a surfactant/special polymer surfactant and the like is preferably a combination of a polyoxynitride surfactant/fluorine surfactant. The combination of the polyoxymethylene-based surfactant/fluorine-based surfactant may, for example, be a combination of a polyether-modified polyoxon-based surfactant/oligomer-type fluorine-based surfactant. Specifically, for example, "TSF4460" manufactured by GE Toshiba SILICONE Co., Ltd., "DFX-18" manufactured by NEOS Co., Ltd., "S-393" manufactured by CHEMIE Co., Ltd., "S-393" manufactured by SEIMI CHEMICAL Co., Ltd., and "KP340" manufactured by Shin-Etsu SILICONE Co., Ltd. "F-478" manufactured by Dainippon Ink Chemical Industry Co., Ltd., "SH7PA" manufactured by T0RAY SILICONE Co., Ltd. / "DS-401" manufactured by DAIKIN Co., Ltd., 97136291 106 200948907 L 77 by UNICAR, Japan / "FC443 by Sumitomo 3M Co., Ltd." 〇" and so on. [1-9] Other components The color-curable resin composition of the present invention may contain a dispersing aid, an organic nucleus and/or an organic Wei liver, a plasticizer, a dye, a thermal polymerization inhibitor, and a preservation in addition to the above components. Stabilizer, surface protectant, dense adhesion improver, etc. * The dispersing aid is used to improve the dispersibility of the pigment in the above (4) color material, and to improve the dispersion stability of the crucible. Examples of the dispersing aid include an azo system, an ugly crystal system, a 喧*丫疋_ system, a benzopyro-based system, a sister-in-the-sole system, an n-series, a brewing system, an indanthrene system, and a system. Derivatives of pigments such as Per_ne纟, II, bicinch, bismuth, and diploid. Examples of such a simple touch-and-removal include, for example, a two-group, a sulfhydryl group, a quaternary salt thereof, a quinone imine cyclyl group, a di-silyl aryl group, a thiol group, a slow group, a fluorene, and the like. These substituents may be directly bonded to the skeleton, or may be bonded via a fluorenyl group, an aryl group, a heterocyclic group or the like. The above substituent is preferably a bis-amino group and a quaternary salt thereof, a sulfonic acid group, and more preferably a sulfonic acid group. These substituents may be subjected to a plurality of substitutions on a heterocyclic group, or a mixture of compounds having different substitution numbers. Specific examples of the pigment derivative include, for example, a continuous acid derivative of an azo pigment, a two-touch of an ugly pigment, a derivative of ruthenium (four), a derivative of a dye of a brewing pigment, and ten. The acid derivative of the tantalum-based pigment, the sulfonic acid derivative of the bismuth-based fluorene-based pigment, and the phthalocyanine pigment of the phthalocyanine pigment, 97136291 107 200948907, etc. Among them, a sulfonic acid derivative of Pigment Yellow 138, a sulfonic acid derivative of Pigment Yellow 139, a sulfonic acid derivative of Pigment Red 254, a sulfonic acid derivative of Pigment Red 255, a dye derivative of Pigment Red 264, and a red pigment are preferred. 272 acid derivative, sulfonic acid derivative of pigment red 209, sulfonic acid derivative of pigment orange 71, phthalic acid derivative of pigment purple 23, more preferably sulfonic acid derivative of pigment yellow 138, pigment red 254 Acid derivative. In the colored curable resin composition of the present invention, the content of the dispersing aid is usually 〇·1% by weight or less, and usually 300% by 1% or less, relative to the above-mentioned (a) color material. It is preferably 2% by weight or less, more preferably 1% by weight or less, and particularly preferably 5% by weight or less. If the amount of addition is small, the effect cannot be exhibited. On the contrary, if the amount of addition to the right is too large, the dispersibility and the dispersion stability tend to deteriorate. When the colored curable resin composition of the present invention is used as a color filter as described later, 'in order to maintain high pattern adhesion, and to further reduce the residual of the coloring curable resin composition, it may contain molecular weight 1 〇〇〇The following organic © New Zealand / / Syrian New Zealand. These (four) (four) color hard-recording resin compositions contain (e-3) an amino phthalic acid ethyl ester resin dispersing agent as (e) a dispersing agent. Specific examples of the organic acid retardant include aliphatic carboxylic acids and aromatic carboxylic acids. Examples of the aliphatic carboxylic acid include monocarboxylic acids such as formic acid, acetic acid, propionic acid, butyric acid, valeric acid, dimethylacetic acid, caproic acid, glycolic acid, and methacrylic acid; oxalic acid, propionic acid, and succinic acid; Station acid, glutaric acid, adipic acid, pimelic acid, cyclohexanedicarboxylic acid, cycloheptacarboxylic acid, itaconic acid, citraconic acid, maleic acid, fumaric acid, etc. 97136291 108 200948907 Carboxylic acid; tri-f-acid, guanine acid, etc. Further, for example, benzene (tetra), a thief or the like may be directly bonded to a phenyl group; = child nucleus, and a phenyl group is bonded to the phenyl group via a carbon bond. ▲ of citric acid, among these, preferably having a molecular weight of 600 or less, particularly preferred. Specifically, it is preferably a cis-diacid, a di-acid, or a saponin as an organic fine _, and for example, an aliphatic pro-xuan, an aromatic surface, for example, a gambling _, a tri-acid, a wild, a s , cis-butanol dianhydride, transfer Kang _, itaconic acid field, 2-cycloheptanic acid anhydride, hexadesine _ _, 5, win ^ =:: _. Examples of the aromatic group include phthalic anhydride, a phthalic anhydride, a pyromellitic anhydride, and naphthalic anhydride. Among these, it is preferable that the molecular weight is less than or equal to the above, and particularly preferably a molecular weight of 5 〇 to _. Specifically, it is preferably cis-tautic acid itaconic anhydride. In the color-hardening resin composition of gamma-, citraconic acid liver and sputum, the ratio of such acid and/or organic fineness is in the total solid content, usually in the weight% by weight or more, and more The weight of the good heart - again, the wealth is 10 gh, preferably 5 趟 or less, more preferably 3% by weight or less. The color-curable resin composition of the present invention may further contain a plasticizer, and examples of the plasticizer include, for example, bismuth vinegar, bismuth citrate, and bismuth phthalate. Trimethyl sulphate, dioctyl succinate, dibutyl sulphate, triethylene glycerol, etc. The proportion of these plasticizers is in the total solid content of the curable resin composition of 97136291 109 200948907. In addition, the colored curable resin composition of the present invention may contain a thermal polymerization preventing agent, and examples of the thermal polymerization preventing agent include hydroquinone, p-methoxyphenol, and gallic phenol. ' o-diphenol, 2,6-tert-butyl-p-nonylphenol, p-naphthol, etc. The content ratio of these thermal polymerization inhibitors is preferably 3 in the total solid content of the colored curable resin composition. 5% [%] The method of preparing the colored curable resin composition Next, the method of preparing the colored curable resin composition of the present invention will be described. Further, the colored curable resin composition of the present invention can be used by Pre-modulation of pigment dispersion In the case where the other components are mixed and prepared, or all the components may be mixed together, the case of the former method of riding the former method is described as an example, but the invention is not limited thereto. First, the quantitative (4) color materials are separately weighed. (6) The organic solvent and the (4) color material are (4) minutes containing any age of the lyophilized form, and the pigment in the color material is dispersed in the dispersion treatment step to form a pigment dispersion liquid. In the dispersion treatment step, a pigment may be used. The conditioner, the sand mill, the ball mill n grinder, the stone grinder, the jet mill, and the homogenization solution 1 perform the dispersion treatment to pulverize the pigment, thereby improving the coating characteristics of the colored curable resin composition and improving The light transmittance of the pixel of the color filter produced by the film is used. (4) When the pigment is subjected to the dispersion treatment, it is preferred to use (b) a part of the binder resin and a dispersing aid as appropriate, and further, using a sand mill. When dispersing, it is better to use glass beads or oxidized beads of ο. 1 to several coffee paths. The temperature during dispersion treatment is usually set to (^ above, preferably above room temperature, and usually, (10) = the range below, preferably _ below. x, the dispersion time is different depending on the composition of the pigment dispersion and the size of the sander, etc., and must be adjusted appropriately. In the dispersion liquid, the (g) surfactant and (8) binder resin, (6) organic solvent, and the deficiencies are included in the dispersion of the necessary components; (1) frequency, (8) integration of the components * and/or Or a polymerization initiator, and a component other than these, as a homogeneous dispersion solution, thereby obtaining a colored curable resin composition. Further, in the dispersion treatment step and the mixing, each v. It is preferable to filter the pigment dispersion liquid by a filter or the like. [3] Application of colored curable resin composition The color-curable resin composition of the present invention is usually dissolved by all constituent components. © or a state of dispersion in a solvent. This is supplied onto a substrate to form a color filter or a constituent member of the liquid crystal display device. In the following, a method of producing a color filter using the color-curable resin composition of the present invention and a liquid crystal display device (panel) using the same will be described. &quot; [1] Color filter manufacturing method A method of producing a color filter by an inkjet method using the colored curable resin composition of the present invention will be described. In the inkjet method, a partition pattern (black matrix) is first provided on a substrate, and an ink for forming a pixel is directly applied to the pattern to form a color filter. Since the fine droplets of the ink can be drawn at the desired position, the high production efficiency and cost of the color filter can be achieved. The black matrix of the color filter obtained by the inkjet method not only has a conventional shading function, but also functions as a partition wall for coloring the RGB ink filled in the pixel, so that it is compared with the conventional one. The color filter slab obtained by the photolithography method has a thick film thickness (usually, the film thickness is 1.5/zm or more, preferably 1. 8~2. 5#m or so, more preferably 2· 〇~2· The thickness of the left and right). Further, in order to prevent color mixing of RGB inks, liquid dispensing is often performed on the black matrix. Therefore, compared with a conventionally used black matrix formed of a chromium compound such as metal chromium, chromium oxide or chromium nitride, or a light-shielding metal material such as nickel or a tungsten alloy, a photosensitive material containing a black color material is used. The formed resin black matrix (BM) is preferred. In the color filter of the present invention, the resin black matrix (BM) can be formed by a general photolithography method. With respect to the obtained resin BM, the hydrophilization of the surface of the transparent substrate and the liquid repellency of the black matrix (BM) pattern are carried out by various chemical treatments or physical treatments. Next, in the slightly rectangular recessed region surrounded by the resin black matrix (BM) pattern, the colored curable resin composition of the present invention is drawn by an inkjet device to dry and photoharden and/or thermally harden the composition. The object is completely hardened to form a pixel, thereby obtaining a color filter. The coloring curable resin composition for forming a pixel is often three colors of R (red), G (green), and B (blue), but is not limited to 97136291 112 200948907. The material of the transparent substrate used in the color filter of the present invention is not particularly limited, and examples thereof include polyesters such as polyethylene terephthalate, polyolefins such as polypropylene and polyethylene, and polycarbonate. Thermoplastic plastic sheets such as polymethyl methacrylate and polysulfone; thermosetting plastic sheets such as epoxy resin, polyester resin and poly(meth)acrylic resin; various glass plates. In particular, from the viewpoint of heat resistance, it is preferable to use a glass plate or a heat-resistant plastic plate.涂 The coating film of the coloring curable resin composition is dried, and heating can be used for heating plates, 丨吖 infrared ray ovens, ovens, etc., preferably dry parts are scratched (10) C 'drying time is 1 〜 sec~6 The range of minutes. Further, it is also possible to use a subtractive drying condition, preferably a drying condition of WTQrr, and a drying time of 1 sec. Furthermore, the two may be used in combination, or may be performed sequentially or simultaneously. ^ "Pour the color of the hardening resin composition to harden (four), as a light source for exposure, for example, the gas lamp, the self-primary lamp, the tungsten lamp, the same pressure mercury lamp, the super-pressure water button, the metal , filaments such as towel compaction lamps, low-pressure mercury lamps, etc., laser light sources such as Qianxuan riding, Wei, excimer laser, and laser; use optical filters when only the wavelength of the illumination light is specified. J [3- 2] Manufacture of liquid crystal display device - The liquid crystal age device (panel) of the present invention will be described. The wire crystal device of the present invention is manufactured by the above-described invention sheet, for example, as follows. Μ 97136291 113 200948907 First, An alignment film is formed on the color filter, and a spacer is disposed on the alignment film, and then bonded to the opposite substrate to form a liquid crystal cell. Secondly, liquid crystal is injected into the formed liquid crystal cell, and the wiring is aligned. The electrode is completed. - The alignment film is preferably a resin film such as polyimide. When forming the alignment film, usually - by gravure printing or flexible printing, the thickness of the alignment film is usually 10 to 100 nm. Orientation After the hardening treatment, the surface treatment is performed by irradiation of ultraviolet rays (uv) or rubbing cloth, and processed into a surface state in which the liquid crystal tilt ratio can be adjusted. The spacers are used to match the distance (gap) between the opposite substrates. The size is usually preferably 2 to 8 μm. The light spacer (PS) of the transparent resin film can also be formed by photolithography on a color filter, and it can be used as a substitute for the spacer. The matrix substrate is particularly preferably a TFT (Thin Film Transistor) substrate. The pitch of the bonding between the opposing substrates varies depending on the use of the liquid crystal display device, and is usually selected within the range of 2 to 8 Am. After that, the portion other than the liquid crystal injection port is sealed with a sealing material such as an epoxy resin. The sealing material is cured by irradiation and/or heating to seal the liquid crystal cell periphery. The peripheral sealed liquid crystal cell is sealed. After being cut into the panel unit, the pressure is reduced in the vacuum chamber, and the liquid crystal injection port is immersed in the liquid crystal, and then the vacuum chamber is vented and pressurized to inject the liquid crystal into the liquid crystal cell. The pressure is usually &lt;1, 10 9 lxl0_7Pa, preferably 1χ1 (Γ3~lxl〇-6Pa. Also, preferably under reduced pressure: the liquid crystal cell is heated, the heating temperature is usually 30~10 (TC, preferably ~9) 〇°c. The heating at the time of depressurization is usually set to a range of 1 〇 to 60 minutes, after which the liquid crystal injection 97136291 114 200948907 inlet is immersed in the liquid crystal. The liquid crystal cell of the liquid crystal is made of uv hardening resin. Hardening, sealing the liquid crystal injection port, thereby completing the liquid crystal display device (panel). There is no restriction on the surface of the liquid crystal, and (4) a liquid crystal, an aliphatic system, a polycyclic compound, or the like, or a liquid crystal. Any one of a liquid crystal, a thermotropic liquid crystal, etc. A nematic liquid crystal, a smectic liquid crystal, a cholesteric liquid crystal, etc. are known to a thermal liquid crystal, and it can be either. [3-3] Manufacture of Organic EL Display ❹ When an organic EL display using the color filter of the present invention is mounted, as shown in FIG. 3, the color filter of the present invention described below is first produced: transparent A pixel 2 is formed on the support substrate 1 (wherein at least a portion of the pixel 20 is formed using the color hardening tree composition of the present invention), and is disposed between adjacent pixels 20. Resin black matrix (not shown). Next, on the color filter, an organic protective layer 30 and an inorganic oxide film 4 are laminated to form an organic EL 500, whereby an organic EL device can be obtained. As a method of laminating the organic light-emitting body 500, for example, a method of sequentially forming a transparent anode 5 on a color light-receiving sheet, a hole injection layer 5, a hole transport layer, and a 3 | child's master layer 54 and a cathode 55 can be mentioned. Or a method of bonding the organic light-emitting body 500 formed on the other substrate to the inorganic oxide film 40 or the like. By using the organic EL element 100 thus produced, for example, the method described in "The Ministry" (OHM, issued on August 2, 2004, and at the time of the Jingshi 'Anda Boya Murata Yukiyuki) can be used. Made of organic rainbow display. Further, the color filter of the present invention can be applied to a passive drive type organic 97136291 115 200948907 EL display' can also be applied to an active drive type organic EL display. (Examples) Hereinafter, the present invention will be specifically described by way of examples and comparative examples, but the present invention is not limited to the following examples. • (Synthesis Example 1: Acrylic block copolymer corresponding to (e-2) nitrogen atom) Except that the amine group (mercaptoamine group) in the copolymer is not subjected to level 4, In Example 1 of JP-A-1-229014, an acrylic-based AB block copolymer having a 3 fluorene-based amine group was synthesized. The obtained copolymer had a weight average molecular weight Mw of 9000, an amine value of l21 mgKOH/g, and an acid value of 〇mgK〇H/g. Further, the amine valence is expressed by the following method, based on the weight of the solid content per lg of the solid content other than the solvent and the weight of the equivalent weight of Η0. In a 100 mL beaker, the fine scale was dissolved in 50 mL of acetic acid by using 5% to 5 g of the dispersant obtained by the above synthesis. The solution was neutralized and titrated with a 〇.lmol/L HCL〇4 acetic acid solution using an automatic titrator equipped with a pH electrode. The titration point of the pH curve is titrated as the end point of the titration, and the amine price is obtained by the following formula. Amine value [mgKOH/gH561xV)/(WxS) (Whether, W represents the amount of dispersant sample [g], v represents the titer [mL] at the end of the titration, and S represents the solid concentration of the dispersant sample [wt% (Synthesis Example 2: (b) Synthesis of binder resin) V A separation flask equipped with a cooling tube was prepared as a reaction vessel, and a propylene glycol monomethyl group was charged: (iv) an acid ester shed weight fraction, after nitrogen substitution, Heated in an oil bath to raise the temperature of the reaction vessel to 90 °C. ... 97136291 116 200948907 On the other hand, in the monomer injection human dimethyl-2,2, _[oxybis(methylene)] bis-2-propene fine 1G parts by weight, mercapto-acid 15 weight The content is 20 parts by weight of methyl methacrylate, 55 parts by weight of fluorenyl propylene, 2.6 parts by weight of t-butyl phthalate, and propylene glycol monomethyl acetate. &quot; In the chain moving agent tank, packed with 12 tons of mercaptan 5.2 parts by weight and propylene glycol monodecyl lysine (4) parts by weight, the temperature of the reaction tank is stabilized at (10) ^ from the monomer tank and the chain shifting agent The tank starts to be loaded with each other _ drop to start the polymerization. The temperature of the reaction vessel was maintained at 9 (rc and dropped for 135 minutes, and after 60 minutes from the end of the dropwise addition, the temperature was raised to bring the reaction vessel to 11 Torr. 丨. Maintain 丨, 3

After the hour, the mixture was cooled to room temperature to obtain a 30% by weight polymer solution having a weight average molecular weight of 92 Å and an acid value of 107 mgKOH/g. (Example 1) As a (a) color material (pigment) &amp; 6 g of pigment green 36, 8.6 g of pigment yellow 150, (e) a dispersing agent, 5 g of the compound obtained in Synthesis Example 1 was used as (b) The resin obtained in Synthesis Example 2 of the binder resin was 5. 8 g, and the mixture was stirred and homogenized as diethylene glycol mono-n-butyl ether acetate (DEGBEA) 115·2g as an organic solvent, and then added. 300 g of cerium oxide beads having a particle diameter of 0·5 mm were subjected to dispersion treatment by vibration of a pigment conditioner for 5 hours to prepare a pigment dispersion liquid. Further, as (b) a binder resin, 5 g of an epoxy resin EHPE 3150 manufactured by DAlcEL Chemical Co., Ltd. as (g) a thermal polymerization initiator i.4 g of Ciba-Geigy's IRGACURE 907, as a (g) surfactant The compound represented by the following structural formula (iii) ("ρρ-6320" manufactured by 0MN0VA Co., Ltd.) 0.02 g, as (c) one of 97136291 117 200948907 machine/mixture, ethyl alcohol monobutyl ether acetate vinegar 3 interesting A ) i6. So mixed to make a transparent substrate. Further, the surface tension σ and the contact angle 相对 with respect to the glass substrate were measured in accordance with the measurement method described later for the 'compound of the compound of the following formula (iii). The results are shown in Table + again, the surface tension σ of DEGBEA measured in the same manner. It is 3〇mN/m. 2 g of the above transparent base material was dropped and mixed with 72 g of the pigment dispersion liquid, and then filtered through a 5 μm membrane filter to obtain a uniform color-curable resin composition. Further, the color hard resin composition was measured by a fully automatic surface tension meter "CBVP-Z" manufactured by Kyowa Interface Science Co., Ltd., and found to be 28.8 mN/m. With respect to the obtained colored curable resin composition, wet spreadability and pixel flatness were evaluated in the following methods. The evaluation results are shown in Table q. [化38] Hey? CH2CF3 • ch2 · H—O—CH 2 —I—CH 2 OH (iii) L ^ J2 〇 <Measurement of surface tension (7), measured by CBVp_Zj, a fully automatic surface tension meter manufactured by Kyowa Interface Science Co., Ltd. <Measurement of contact angle 〉> 97136291 118 200948907 A glass substrate for liquid crystal panels ("AN1" manufactured by Asahi Glass Co., Ltd.) was washed with a detergent ("SunWashTL-ΙΟΟ" manufactured by Lion Co., Ltd.), and then washed at 1 〇〇〇mJ. The uv ozone treatment is carried out to perform light washing, and the contact angle of the prepared pure water is 〇, that is, the glass substrate which is completely wet and expanded. Next, a commercially available contact angle measuring device by the droplet method is used ( "CA-DT" manufactured by Kyowa Interface Science Co., Ltd., and measured the static contact angle 0 of the sample solution with respect to the glass substrate at 23 C. (Example 2) ❹ ❹

The (g) surfactant added to the transparent substrate was prepared in the same manner as in Example 1 except that the compound represented by the following structural formula (iv) (pF_652® manufactured by OMN〇VA Co., Ltd.) was obtained. A colored curable resin composition. Further, with respect to the compound represented by the following structural formula (iv), 〇2 weight 汕 EGBEA 'excitation liquid' was measured as in Example 1 with the surface tension σ and the contact angle 0 with respect to the glass substrate. The results are shown in Table-1. The surface tension of the colored curable resin composition was 28. 〇mN/m. Further, the results of evaluation of wet spreadability and pixel flatness are shown in Table-1. [化39] ?ch2cf2cf3 ch2 o-ch2· ch3 •ch2-

OH (iv) 20 (Example 3) Except that the (g) surfactant added to the transparent substrate is a compound represented by the following structural formula (11) (PF-656 manufactured by 0MN0VA Co., Ltd.)实97136291 119 200948907 Example 1 was carried out in exactly the same manner to obtain a colored curable resin composition.

Further, the surface tension σ and the contact angle 相对 with respect to the glass substrate were measured as in Example 1 for the 〇〇2 weight ship A solution of the following structural formula (1). The results are shown in Table 1. The surface tension of the colored curable resin composition was 29.8 mN/m. Further, the evaluation results of wet spreadability and pixel flatness are shown in Table _ [40] β 〇ch2cf2cf3 ch2 ' Η —0~CH2 —-- CH2--OH-(1)) CH3J6 (Comparative Example 1) A coloring curable resin composition was obtained in the same manner as in Example 1 except that the surfactant was not added to the transparent substrate. Further, the surface tension of the colored curable resin composition was 30 〇mN/m. Further, the results of evaluation of wet expansion and pixel flatness are shown in Table-1. (Comparative Example 2) Except that (g) the surfactant added to the transparent substrate was set to Seimi

The procedure of the same procedure as in Example 1 was carried out except that Surfl〇n "s-393" (non-ionic "Fahrenheit surfactant" manufactured by Chemical Co., Ltd. was used to obtain a colored curable resin composition. Further, the 0.02 wt% DEGBEA solution of "S-393" was measured for the surface tension cr and the contact angle 0 with respect to the glass substrate as in Example 1. The results are shown in Table-1. 97136291 120 200948907 Further, the surface tension of the colored curable resin composition was 24 〇mN/n^, and the evaluation results of wet spreadability and pixel flatness are shown in Table-i. (Comparative Example 3) • In addition to the (g) surfactant added to the transparent substrate, "F-475" manufactured by Dainippon Ink and Chemical Co., Ltd. (non-ionic system containing polysulfide-type surfactant) Other than the rest of the examples! The same procedure was carried out to obtain a colored curable resin composition. Further, the G. Q2 weight pro-G solution of "F475" was measured as the surface tension σ and the contact angle with respect to the glass substrate as shown in Table 1. Further, the surface tension of the colored curable resin composition was 27. with /m. Further, the results of evaluation of wet spreadability and pixel flatness are shown in Table q. (Method for Evaluating Moisture Spreadability and Pixel Flatness) A photosensitive resin composition containing a colorless color material is applied to a non-test glass substrate "touch 5" 1 〇 方形 square made by Yuxu Glass Co., Ltd. In the surface, a matrix pattern of line width 2 〇 _, opening width 220 (four) 700 _, and thickness 2 〇 _ is formed by photolithography. ~ After the liquid-repellent treatment is performed on the substrate by fluorine gas plasma treatment, the color hardening obtained by coating the respective portions and the comparative examples by the inkjet method is applied to the core portion of each of the pixel banks formed by the black matrix pattern. The composition of the sex tree wax is about 2 cents. After the temperaturelessness of the second generation and the reduced humidity (10) was allowed to stand for 3 minutes, the image ratio of the wet-filled portion of the colored hardening tree composition to the area inside the pixel bank was measured. %). 97136291 121 200948907

Area ratio (%M (area of the coloring-curable resin composition wet/wang expanded part)/pixel bank internal product) X1GG In addition, the color-hardening resin obtained in each of the examples and the comparative examples was similarly composed. The object _PL was applied to the pixel bank and left to stand in a temperatureless pit and a relative humidity leg in a windless environment for 5 minutes. Then, the #coated substrate was dried to form a pixel, which was measured by a 3-dimensional laser microscope. The surface shape of the obtained pixel was evaluated as the ratio (8) of the flat portion with respect to the pixel_. The area ratio (%) of the flat portion = [(area of the flat portion of the pixel V area]] [Table 1] Example 2 Implementation Example 3 Comparative Example 1 Comparative Example Comparative Example (g) Surface active sword surface tension __OnN/m) 29. 28. 29. 30. 24. 27.0 Contact angle 0 (°) 7 5 11 20 15 Color hardening rouge Composition wet expansion〇〇

X Δ___ pixel flatness surface tension 〇 〇

X 〇 〇

X △ The evaluation of the color-curable resin composition of the examples and the comparative examples shown in Table 1 was carried out as follows. In the wet expansion system, when the area ratio of the wet expansion is less than 40%, it is set to X, 40% or more, and less than 60% is set to Δ, and 60% or more is set to 〇. The pixel flatness is set to >&lt;&lt;&gt; when the ratio of the area of the flat portion to the pixel area is less than 60%, and Δ is set to 60% or more and less than 80%, and the number is more than 8% or more. 97136291 122 200948907 Set to 〇. The surface tension is set to X when it is less than 25 mN/m, and is Δ when it is 25 mN/m or more and less than 28 mN/m, and is set to 〇 of 28 mN/m or more and 3 lmN/m or less. From the evaluation results of Table 1 §, it can be seen that the composition of the color-curable resin of the present invention is obtained by adding a compound represented by the general formula (0) without excessive surface tension reduction, and a wet expansion and a pixel can be obtained. A colored curable resin composition having good flatness. ❹ (Industrial Applicability) According to the present invention, in the color filter manufacturing by the ink jet method, it is possible to provide coloring which is superior to the surface smoothness of the pixel and the wet spreadability in the pixel bank. A curable resin composition (ink). Further, by using such an ink cartridge, a high-quality color calender sheet can be produced with good yield, and a large and inexpensive supply of the liquid crystal display device can be realized, which is advantageous to the industry. The entire contents of the specification, the scope of the application, the drawings and the abstract of the Japanese Patent Application No. 1359 filed on May 23, 2008 are hereby incorporated by reference. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a photograph showing the wettability in a pixel bank of a colored curable resin composition prepared in an example and a comparative example of the present invention. 'Object 2 is a photograph of the surface flatness of the pixel formed by the resin composition using the color hardening of the present invention and the comparative example. Fig. 3 is a cross-sectional schematic view showing an organic EL element having a color filter of the present invention - Example 97136291 123 200948907. [Main component symbol description] 10 Transparent support substrate • 20 pixels - 30 Organic protective layer 40 Inorganic oxide film 50 Transparent anode ❹ 51 Hole injection layer 52 Hole transport layer 53 Light-emitting layer 54 Electron injection layer 55 Cathode 100 Organic EL element 500 ❹ Organic light emitter 97136291 124

Claims (1)

200948907 VII. Patent application scope: 1. A color-hardening resin composition containing at least (a) color material, (b) binder resin, (c) organic solvent and (g) surfactant, characterized by , a solvent having a boiling point of 18 (above rc (boiling point at a pressure of l〇13.25 [hPa]) - (c-丨) accounts for 8 〇% by weight or more of (c) an organic solvent; using the solvent (c-1) 0.02 weight of the prepared (g) surfactant; The liquid system satisfies the following conditions and (2): φ (1) The contact angle with respect to the glass substrate is 10 or less; (2) The surface tension σ is relative to the solvent (4)) . The system satisfies (σ. -2)^ σ &lt; σ 〇 ° 2. The color-curable resin composition of the patent application model , 丨 , , , , , , , , , , , , 界面 赖 赖 赖 赖 赖 赖 赖 赖 赖 赖 赖 赖 赖Compound: [Chemical 1] (In the formula, 'R! means a carbon number of 2 to 6, a R2 table, or a hydrogen atom, and 6 means a carbon number, 4, 3, and 3, respectively. ❹ Independently represents an integer of 0 to 2, fluorene and fluorine. The silk, V, ^U knife independently indicates 1 or 2, s table 97136291 125 200948907 shows an integer from 0 to 10; η represents an integer from 2 to 100; and 'when the first side chain of the plural is contained in one molecule, [Chemical 2] They may be the same or different bases respectively). 3. The colored curable resin composition according to the second aspect of the invention, wherein the compound represented by the above formula (10) is a compound represented by the following general formula (〇). HO—CH2—CH2—〇 CH3 (〇) (In the above formula, the substituent G represents a fluorinated alkyl group having a carbon number of 丨 to 4, and η represents an integer). 4. For the application of the color hardwood test of the second or third item of Weiwei, in the above-mentioned general formula (10) or the general formula (8), the substituent G is a perfluoroalkyl group of carbon number 3 And n is an integer of 5 to 30. 5. The colored curing resin group 97136291 126 200948907 of the first aspect of the invention, wherein the above condition (2) is the following condition (3) · (3) surface tension σ It is 28 mN/m or more and less than 3 〇 mN/m. 6. For the full-time (4) 1 to 5 shots of the colored Wei resin group, the product, _, in the above condition (1), the contact angle with respect to the glass substrate is not - 5 . . 7. - The coloring hardening tree remains, which contains at least (4) color material, (8) binder resin' (e) organic solvent ship (g) boundary, sex, characterized by ❹ _ 18G ° C or more (pressure (1) The amount of (g-1) of the organic solvent is 1% or more; (g) the surfactant is contained in the following general formula (1〇); Compound·· [Chemical 4] (wherein R1 represents an alkylene group having 2 to 6 carbon atoms, 匕 represents an alkylene group having 2 to 3 carbon atoms, R3 represents a trans group or a hydrogen atom, and G represents a fluorinated alkyl group having 1 to 4 carbon atoms; , w and u, respectively, represent an integer of 0 to 2, X and t respectively represent 1 or 2, s table; an integer of 0 to 10; η represents an integer of 2 to 100; and, in a molecule, a complex number When the following side chain is used, 97136291 127 200948907 [Chemical 5] They may be the same or different bases respectively). The coloring-curable resin composition of the above-mentioned general formula (1〇) is a compound represented by the following general formula: [Chemistry 6] HO-- 3 CH2—(p-CH2-〇- CH Ή η (〇) (In the above formula, the substituent G represents a fluorinated alkyl group having 1 to 4 carbon atoms, and η represents an integer of 2 to 1 Å). 9. The colored curable resin composition according to claim 7 or 8, wherein in the above-mentioned general formula (1〇) or the general formula (9), the substituent g is a perfluoroalkyl group of carbon number 3; η is an integer of 5 to 30. 10. The color-curable resin according to any one of claims 1 to 9 of the patent application, and the content of the material (the towel) (g) interface (4) is relative to the total solid content of 0·005~ 5 wt%. 97136291 128 200948907 η· 专利 专利 专利 专利 专利 四 四 四 四 四 四 四 四 四 四 四 四 四 四 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项 项The content of the color is i, please, and (the content of the organic solvent is 50 to 99% by weight. 12. The color-hardening resin composition of any one of the above-mentioned items; (a) The color material contains pigments. 13. The coloring hard-recorded tree of the 12th item of the patent application system, in which φ 'further contains (e) a dispersing agent. 14. If the application is for the 13th item a colored curable tree remainder, wherein (e) the dispersant contains an a-B block copolymer formed by an A block having an amine group in a side chain and a B block having no amine group at a side bond, and/or a β-A__B block copolymer, and the amine valence of the block copolymer is 1 〇 mg K 〇 H / g (in terms of effective solid content) or more. 15. Coloring according to any one of claims i to 14 a hardening resin ruthenium composition in which a boiling point of 18 (above TC (boiling point under a pressure of 10i3.25 [hPa]) is dissolved (c-1) is diethylene glycol mono-n-butyl ether acetate, diethylene glycol monoethyl ether acetate, dipropylene glycol monodecyl ether acetate, 1,3-butanediol diacetate And at least one selected from the group consisting of 1,6-hexanol diacetate vinegar and glycerol triacetate vinegar. 16. The colored curable resin composition of claim 15 of the patent application, wherein: the boiling point is 180 〇C or more The solvent (c 1) of the pressure (boiling point under the pressure of 13.25 [hPa]) is diethylene glycol mono-n-butyl carboxyacetate. 97136291 129 200948907 17. Coloring according to any one of claims 1 to 16 The curable resin composition, wherein the content of the alcohol relative to the total amount of the (c) organic solvent is 2% by weight or less. 18. The colored curing resin according to any one of the above claims. In the composition, the contact angle with respect to the glass substrate is less than 5. The color-curable resin composition of any one of claims 1 to 18 is a colored curable resin composition. , is used in inkjet color filter. 20. - Color filter, system 22. The color-curable resin composition according to any one of the above-mentioned claims, wherein the liquid crystal display device is provided with the color filter of the second aspect of the patent application. - An organic EL display device with a color filter with a patent scope of 帛2〇. 〇97136291 130