TW200938620A - Cokes processing system and cokes processing method - Google Patents

Cokes processing system and cokes processing method Download PDF

Info

Publication number
TW200938620A
TW200938620A TW098102894A TW98102894A TW200938620A TW 200938620 A TW200938620 A TW 200938620A TW 098102894 A TW098102894 A TW 098102894A TW 98102894 A TW98102894 A TW 98102894A TW 200938620 A TW200938620 A TW 200938620A
Authority
TW
Taiwan
Prior art keywords
coke
powder
organic
cokes
furnace
Prior art date
Application number
TW098102894A
Other languages
Chinese (zh)
Inventor
Atsushi Kotani
Masaru Nishimura
Shingo Asada
Original Assignee
Kansai Coke & Chemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kansai Coke & Chemicals Co Ltd filed Critical Kansai Coke & Chemicals Co Ltd
Publication of TW200938620A publication Critical patent/TW200938620A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B45/00Other details
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B39/00Cooling or quenching coke

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Coke Industry (AREA)

Abstract

The present invention relates to the cokes processing system and cokes processing method, which produce the cokes with a high reactivity with CO2 by a simpler configuration. The present invention makes an organic granular material to adhere to the cokes with heat by sprinkling and melting the organic granular material containing alkaline-earth metals onto the cokes conveyed from a coke oven to a shaft furnace. The above method raises the reactivity of the cokes with CO2 by adhering the organic granular material containing alkaline-earth metals onto the cokes. The present invention provides a simpler configuration to produce the cokes with a high reactivity with CO2 by sprinkling the organic granular material to the cokes instead of making an organic compound dissolve and distribute in the water.

Description

200938620 六、發明說明: 【發明所屬之技術領域】 本^麵關於-種焦炭處理系統及焦炭處理 :用以進行對從焦炭爐搬送往高爐之焦炭之處 【先前技術】 ❹ %今已提出有各種技術(例如,專利文獻一至 三),用以對供應至焦炭爐之煤炭或藉由該煤炭在焦 炭爐乾餾所產生之焦炭進行各種處理,#此提升高 爐中c〇2與焦炭之反應性。 專利文獻一所揭示之技術,係將用以使焦炭之 反應活性化之觸媒溶解及分散於水之後,使該液體 與焦炭接觸,藉此使觸媒附著於焦炭。專利文獻二 ❹ 所揭示之技術,係將用以使焦炭之反應活性化之觸 媒添加於煤炭並在焦炭爐乾餾。專利文獻三所揭示 之技術’係將含有鹼土類金屬及/或過渡金屬質量 1%以上之煤炭’摻合質量2%以上於摻合炭中並 在焦炭爐乾德。 專利文獻一:曰本特開2〇02 — 22686 5號公報。 專利文獻二:曰本特開2〇0 1 — 3 4 8 5 7 3 200938620 6號公報。 專利文獻三:曰本特開2003—30668 1號公報。 上述專利文獻一之方法中,由於必須有使觸媒 洛角午及分散於水之步驟,因此有會使系統複雜化等 問題。又’亦有水分殘留於焦炭之可能,對高爐操 作而言並不佳D 、200938620 VI. Description of the invention: [Technical field to which the invention pertains] This section relates to a coke processing system and coke processing: for carrying out coke from a coke oven to a blast furnace [Prior Art] ❹ % has been proposed Various techniques (for example, Patent Documents 1 to 3) for various treatments of coal supplied to a coke oven or coke produced by coking of the coal in a coke oven, which improves the reactivity of c〇2 and coke in the blast furnace . According to the technique disclosed in Patent Document 1, a catalyst for activating coke reaction is dissolved and dispersed in water, and the liquid is brought into contact with coke, whereby the catalyst is attached to coke. The technique disclosed in Patent Document 2 discloses that a catalyst for activating coke reaction is added to coal and retorted in a coke oven. The technique disclosed in Patent Document 3 is to blend a coal containing an alkaline earth metal and/or a transition metal having a mass of 1% or more by 2% or more in a carbon blend and dry in a coke oven. Patent Document 1: 曰本特开2〇02 — 22686 5 bulletin. Patent Document 2: 曰本特开2〇0 1 — 3 4 8 5 7 3 200938620 No. 6 Bulletin. Patent Document 3: 曰本特开2003-30668 No. 1 Bulletin. In the method of the above Patent Document 1, since it is necessary to have a step of dispersing the catalyst in the water and dispersing it in the water, there is a problem that the system is complicated. Also, there is also the possibility that water remains in coke, which is not good for blast furnace operation.

上述專利文獻二之方法中,則有因將觸媒混合 於煤炭而導致在焦炭爐所產生之焦炭的強度(D 祕之虞。為了抑制此強度(D I )之降低,雖亦考 f可將焦炭加以高強度化之煤炭摻合等方法, 此時卻有焦炭之製造成本變高等問題。 ° Κ η / ^ 叩说言有鹼土類 :及/或過渡金屬質量1%以上之煤炭的摻“In the method of the above Patent Document 2, there is a case where the strength of the coke generated in the coke oven is caused by mixing the catalyst with coal (D is secretive. In order to suppress the decrease in the strength (DI), it is also possible to Coking with high-strength coal blending methods, etc., at this time, there are problems such as high manufacturing cost of coke. ° Κ η / ^ 叩 有 有 有 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱 碱

在料合率較低時觸媒效果會變小,而在;I 較面時卻有灰分會增加等問題。 σ 【發明内容】 本發明係有4監於上述實情而構成 供-種能以更簡單之構成製造與及= 的焦炭處理系統及焦炭處理方法。之反應性 第—本發明之焦炭處理系統,係用以對從焦 200938620 =送往高爐之焦炭科處理 爐搬送往該高爐之諛隹Λ ,、豬由對攸該焦厌 有機化合物所構叙有:::由::土類金屬之 藉由熱而炫融並附著於:使'有機系粉雜 根據此種構成,對户Λ隹& # t 所最佈之有機系粉體往高爐之焦戾 ❹ ❹ 有嶋體附著於焦炭金二之提有機:合:所構成之 應性。尤1丄 p J徒升c〇2與焦炭之反 因此里於將右:於係以粉體直接散佈有機化合物, 以更:,: 合物溶解及分散於水之構成,能 製造與c〇2之反應性高丄 吏用水故亦無焦炭水分會增加之顧慮。 為二 之焦炭處理系統,係該有機系粉體 融並附著於該焦炭。^亥间爐之该焦厌的熱而溶 根據此種構成,由於可藉由焦炭之敎使 粉體溶融而附著㈣焦炭,因此無須另外設置用以、 ::機系粉體炫融之熱源。因此,能以更簡單之構 成製造與c〇2之反應性高的焦炭。更門早之構 從#發明之焦炭處理系統’係具備用以冷卻 U'、、、厌爐所搬送之該焦炭的冷卻裝置;粉體 藉由該冷卻裝置冷卻後之該焦炭散心 及有機系粉體之溶點係較藉由該冷卻裝 5 200938620 置冷卻後之該焦炭的溫度低。 根據此種構成,對冷卻後之焦炭所散佈之有機 系粉體係藉由焦炭之餘熱而熔融並附著於該焦炭。 藉此,由於可使有機系粉體良好地對冷卻後之焦炭 附著,因此可有效提升C 〇2與焦炭之反應性。’、、、人 第四本發明之焦炭處 有機系粉體加熱之加熱裝 該加熱裝置之加熱而熔融 送往該高爐之該焦炭。 理系統’係具備用以將該 置’該有機系粉體係藉由 ,並附著於從該焦炭爐搬 根據此種構成,由於係藉由加熱裝置之加熱使 有機系粉體熔融而附著於焦炭,因此能以穩定之埶 使有機系粉體良好⑽融,並對焦炭良好地附著了 因此’可有效提升C〇2與焦炭之反應性。 第五本發明之焦炭處理方法,係用以對從隹 =搬送往高爐之焦炭進行處理,其 ”,:藉八㈣從該焦炭爐搬送往該高爐之: :系“由It類金屬之有機化合物所構成之 使邊有機系粉體藉由熱而㈣並 该焦厌。 根據此種構成,可提供—種 本發明之焦炭處理系統同樣效果的J處理= 第六本發明之焦炭處理方法,係該有機系粉 200938620 為藉由從該焦炭爐搬送往該高焯 融並附著於該焦炭。 |该焦厌的熱而熔 根據此種構成,可提供— 本發明之隹山忐X®/ 禋了發揮與上述第二 焦厌處理系統同樣效果的焦炭處理方法。 第七本發明之焦炭處理方法, 驟用以冷卻從該焦炭爐所搬送之該::備=卻步 =驟中’係對藉由該冷卻步驟冷卻:之:體: 佈该有機系粉體,該有機系粉體之;放 冷卻步驟冷卻後之該焦炭的溫度低/’藉由該 根據此種構成,可提供一 本發明之隹*忐 八種了么揮與上述第三 ★"、、厌處理系統同樣效果的焦炭處理方法。 第八本發明之焦炭處理方, 驟用以將該有機系於髀4痴 係一備一加熱步 該加熱步驟之加二二 有機系粉體係藉由 送往該高爐之該焦炭。 有、攸》亥焦厌爐搬 根據此種構成,可# _ ν 本發明之^_ &供—種可發揮與上述第四 月之焦厌處理系統同樣效果的焦炭處理方法。 熱使其溶融二=體以粉體直接散佈,並藉由 製造與co2之反:「厌,因此能以更簡單之構成 U2之反應性高的焦炭。 7 200938620 【實施方式] <第一實施形態> 第-圖係表示本發明之第 理系統之一例的古# θ ι她办心之…厌處 焦炭爐1該焦炭處理系統係具傷: 裝置3、 Q (乾式滅火設備)2、粉體散佈 J 及向爐4等,以進行針從隹户摅!板 往高爐4之焦炭的處理。亦=== 餾煤炭所產生之隹户糟由在…厌爐工乾 過程中,藉由過搬送路徑5搬送之 種處理。 Q2絲體散佈裝置3等實施各 從焦炭爐1所搬出 * CDQ2^^-v^出之焦厌係紅熱之焦炭,藉由 竽CD 2 處理^冷卻至既定溫度以下。 炭=Γ系構?用以冷卻從焦炭爐1所搬送二、 以2 0:c1:由C D Q 2冷卻後之焦炭的溫度 2〇OCu下較佳,亦可設定在例如 l9〇°c之溫度範圍内。 C〜 之焦:體f佈裝置3係對從焦炭爐1搬送往高爐4 之放佈由含鹼土類金屬之有機化合物所:成 之有機系粉體6 ’本例中係對藉由c 冓成 後之焦炭來散佈有機彳^ Q 2所冷卻 从對剛藉由C D Q 2冷卻後 f置3係 在緊接粉體散佈裝置3設置 Q2之後’亦可在不造成有機系粉體 200938620 6熱分解下,將Γ 、 、 Q2裝設於粉體散佈裝置3。 上述驗土類合属, 〇2反庫且右網# 可例不對高爐4中焦炭之c 汉應具有觸媒效果的鈣(C a )笪山士 機化合物則可例干寻,此時上述有 等。 W硬脂酸鈣、檸檬酸鈣、及油酸鈣 179t:〜18crc 左右。 〇 C左右。油酸鈣之熔點則 。因此,若採用此等有機化 ,則可將該有機化合物之熔 2冷部後之焦炭的溫度低。 可藉由從焦炭爐1搬送往高 體而言,可藉由以CDQ2 ,使散佈之有機系粉體6熔 ❹ 硬脂酸鈣之熔點係 檸檬酸鈣之熔點係i 2 為83。。〜84 t左右 s物作為有機系粉體6 點設定成較藉由C D Q 根據此種溫度設定,即 爐4之焦炭的埶, v ”'、 尺具 融而附著於焦炭 所冷卻後之焦炭的餘熱 物所Κι機藉由使由含驗土類金屬之有機化合 -與附:於焦炭,即可提升。 有機化合物,因I異:將有:=:粉體直接散佈 …成,能《更簡單之構有成機;=解及分散於 高的焦戾。 再风展4與C 〇2之反應性 而附ΐ於=:藉由焦炭之熱使有機系粉體6炫融 粉體“融I:源因=須另外設置用以使有機系 一原。因此,能以更簡單之構成製造 9 200938620 與c〇2之反應性高的焦炭。尤其,由於藉由隹岸之 餘熱使對冷卻後之焦炭所散佈之有機化合物6炫融 而附著於該焦炭’即可使有機系粉體6對冷卻後之 焦炭良好地附著,因此可有效提升C 〇 2與声炭之反 應性。 此外,根據CDQ2之運轉狀態,有時藉由該 C DQ 2冷卻後之焦炭的溫度亦會產生偏差。在此 種情形下,亦可設置成如上述般準㈣融不同之複 數種有機化合物作為有機系粉體6,並將配合冷卻 後之焦炭溫度的有機系粉體6散佈於該焦炭的構 八 ,…右马含鹼…則有機 二I:'無特別限制。又,有機化合物對焦炭之附 里係以0 . 5 w t %以上較佳。 行之^二圖係表示藉由第—圖之焦炭處理系統所進 餘所I::::的流程圖。在焦炭爐1藉由煤炭乾 後r此 厌’係從焦炭爐1搬出至搬送路徑5 予以1驟”Q1)’藉由CDQ2之乾式滅火處理 卜部(步驟Sl02 :冷卻步驟)。接 對从C D Q 2冷卻& # 曰由 稀有機系粉體6(步驟;、Γ〇 = 該有機系粉體6即藉由隹户之敎而::放怖步驟), 焦炭(步驟S1 0 4—附著於該 200938620 著於t 而炫融之有機系粉體6,雖以附 面之一;八的V正體車父佳,不過即使是僅附著於表 性。附著二下’亦可提升C02與焦炭之反應 杜附者於焦厌之有機系粉體6,係在到達 之搬送過較溫度降低輕定: 炭之表面。以此方式,表面附著(固二=、 ❹ 驟厂即透過搬送路徑5搬入高爐4 (步 由雖針對粉體散佈裝置3係對藉 作了·^兒明 後炭散佈有機系粉體6之構成 ^兄月’不過並不限於此種構成,在從焦 搬出後透過搬送路徑5至 ^ 佈有機系粉體6之構成亦可。Q2之間’對焦炭散 〈第一貫施形態> 從了施形態中,已針對有機系粉體6係藉由 '、、、厌爐1搬送往高爐4之焦炭之 ::焦炭的構成作了說明。相對於 並附著焦炭這一點上相異。…裝置之加熱而溶融 第三圖係表示本發明之第二實施形態 呈::之-例的方塊圖。由於本焦炭處理 ; /、備有加熱裝置7之點以外, ’、了 態同樣之構成,因此針對同樣之構::二-實施形 κ構成係於圖式賦予 11 200938620 相同符號並省略其說明。 加熱裝置7係用以將有機 你伞、_冉欲壯® η 风系知體6予以加埶, 從心體放佈裝置3所散佈之有機 : 該加熱裝置7之加埶而熔融廿二刀⑽’系藉由 送往高爐4之焦炭融並附者於從焦炭爐1搬 例如,在粉體散佈裝置3係設置 2之位置的情況下,剛由CDQ2 = 溫度即使是較從粉體散佈p 交<,'、、厌的 ❹ 體6的熔點^ Γ 3所散佈之有機系粉 脰b的広點回’但在該有機系粉體 焦炭之溫度會降低$ μ、+ 夺,有時 又θ丨牛低至上述熔點以^ i 融。又’在有機系粉體6之炫點較剛丄良= ::之焦炭之溫度高的情形下,即: 6散佈於剛由cdqw卻後之焦炭,亦無 =: 有機系粉體6良好祕融而附著於焦炭。此外,在' 〇 C D Q冷卻後之焦炭溫度較低的c WQ 厌濕式滅火法)肖,或外部購入或預先製作之 姥留焦炭等’使用冷卻後經過長時間之焦炭時等情 :/下,即使亦直接將有機系粉體6散佈於焦炭,有 日守部無法使該有機系粉體6良好地附著於焦炭。 :P使在此種情況下’如本實施形態般,若為以 〇”、、衷置7將有機系粉體6予以加熱之構成,則可 使有機系粉體6良好地熔融並附著於焦炭。尤其, ;° 、來自加熱裝置γ之穩定之熱使有機系粉體 12 200938620 地炫融樣'炭良好地附著,因此可有效提 L、焦厌之反應性。又,根擄c D Q 2之運轉 差::使Γ該CDQ2冷卻後之焦炭的溫度產 有機化合物作為有機系:二偷點不同之複數種 此外’加熱裝置7若為將從粉體散佈裴置 散佈之有機系粉體6加熱至熔點以上之構 限於如第二圖# # # # 、 CD。:: 佈裝置3及加熱裝置7係與 二:各別設置之構成,在不造成有機系粉㈣ '二=,將粉體散佈裝置3及加熱裝置7裝設於 CDQ 2之構成亦可。 ❹ 行係表示藉由第三圖之焦炭處理系統所進 二=:!的流程圖。在焦炭爐1藉由煤炭乾 後(切之,'、、厌、錢1搬出至搬送路徑5 ,藉由CDQ2之乾式滅火處】 =:(步驟S2〇2·•冷卻步驟)。接著,對夢 有機系冷卻後之焦炭,從粉體散佈裝置3 “ 將节有^版1 (步驟S 2 0 3 :粉體散佈步驟),且 系粉體6籍由加熱裝置7予以加熱()步; 13 1 炭2:表加二:之有1“體 2 正餒季父佳,不過即使是 200938620 僅附著於表面之一部分的情況下,亦可提升◦ 〇 與焦炭之反應性。附著於焦炭之有機系粉體6,』 藉由在到達高爐4之搬送過程使溫度降低至熔點: :而固定於焦炭之表面。以此方式,表面附著固. 定)了有機系粉體6之焦炭,係透過搬送路徑5搬, 入高爐4 (步驟S206)。 <實施例> 第五圖係表示用以測量附著了有機系粉體6之 焦炭與C Q 2之反應性所使狀熱反應性測試裝置© 1 0 0之一例的概略圖。該熱反應性測試裝置工〇 0係藉由以反應管蓋1 0 2封閉作為試料裝填部之 反應管1 〇 1而構成,可從氣體導入口 1 〇 3將氣 體導入至反應管101内,並可將反應管1〇1内 之氣體從氣體排出口 1 〇 4排出。 使用該熱反應性測試裝置2 〇 〇進行測試前之 刖處理步驟,係採取藉由c D Q 2冷卻後之焦炭,〇 並將粒徑調整至1 9 m m〜2 i m m藉此製作底 焦。以乾燥機將該底焦加熱至2 〇 〇 ,在受熱之 狀態下直接投入已置入有作為有機系粉體6之硬脂 酉文舞的燒杯之中’藉此使硬脂酸鈣熔融並附著於底 焦。 之後’將以上述方式所製作之試料裝填於熱反 應性測試裝置1 〇 〇之反應管i 〇丄内,並從氣體 14 200938620 導入口 1 0 3以5L/m i η導入氮氣(n2) 1 5 分鐘。以此方式,以氮氣取代反應管1 〇 1内之空 氣後’將反應管1 0 1插入已設定在1 1 〇 〇。〇之 黾爐。接著,在4 5分鐘後,將從氣體導入口 1 〇 3所導入氣體從氮氣切換成二氧化碳氣體(c〇 2 ),使該二氧化碳氣體與焦炭試料反應兩個小時。 可根據藉由以上實驗所製得之反應後之焦炭試When the feed rate is low, the catalyst effect will become smaller, and when I is facing, there will be problems such as increased ash. σ [Summary of the Invention] The present invention is directed to a coke processing system and a coke processing method which can be constructed and manufactured in a simpler manner. Responsiveness - The coke processing system of the present invention is used to transport the coke from the coke 200938620 = coke oven to the blast furnace, and the pig is constructed by confronting the coke organic compound Yes::: By:: Earth-based metal is melted by heat and attached to it: Make 'organic powder based on this composition, the most organic powder of the household Λ隹 &# t to the blast furnace The anxious 戾❹ ❹ has a carcass attached to the coke gold two to mention the organic: combined: the composition of the nature.尤1丄p J is the opposite of coke and coke. Therefore, it is right-handed: the organic compound is directly dispersed in the powder, and the composition of the compound is dissolved and dispersed in water. 2 The reactivity is high, so there is no concern that the coke moisture will increase. In the coke processing system of the second embodiment, the organic powder is fused and adhered to the coke. According to this configuration, since the coke is melted by the coke and the coke is adhered to (4) coke, there is no need to separately provide a heat source for the powder of the machine. . Therefore, coke having high reactivity with c〇2 can be produced in a simpler constitution. The coke processing system of the invention is provided with a cooling device for cooling the coke conveyed by the U', and the furnace, and the coke centering and organic system of the powder cooled by the cooling device The melting point of the powder is lower than the temperature of the coke after being cooled by the cooling device 5 200938620. According to this configuration, the organic powder system dispersed in the cooled coke is melted by the residual heat of the coke and adheres to the coke. Thereby, since the organic powder can be favorably adhered to the cooled coke, the reactivity of C 〇 2 and coke can be effectively improved. The coke of the fourth invention is heated by the heating of the organic powder. The heating device heats and melts the coke fed to the blast furnace. The system is provided with the organic powder system for adhering to the coke oven, and is attached to the coke oven. The organic powder is adhered to the coke by heating by the heating device. Therefore, the organic powder can be well (10) melted and the coke adheres well, so that the reactivity of C〇2 and coke can be effectively improved. The fifth coke processing method of the present invention is for treating coke from 隹=transferred to a blast furnace, and::: transferring from the coke oven to the blast furnace by means of eight (four): : "organic" by the class metal The compound is composed of the organic powder by heat (4) and is anxious. According to such a configuration, it is possible to provide a J treatment of the same effect of the coke processing system of the present invention. The coke processing method of the sixth invention is that the organic powder 200938620 is transferred from the coke oven to the sorghum and adhered thereto. The coke. According to such a configuration, it is possible to provide a coke processing method in which the same effect as the above-described second anaerobic treatment system is achieved. The seventh coke processing method of the present invention, wherein the cooling is carried out from the coke oven: the preparation: the step = the middle step is cooled by the cooling step: the body: the organic powder is coated, The organic powder; the temperature of the coke after cooling in the cooling step is low/', according to the configuration, one of the inventions can be provided, and the third and the above are provided. The coke treatment method that has the same effect as the treatment system. The coke treating side of the eighth invention is for use in the step of heating the organic system in the heating step. The addition of the organic powder system in the heating step is carried out by the coke fed to the blast furnace. According to this configuration, it is possible to use the _ _ ν method of the invention to produce a coke treatment method which has the same effect as the above-mentioned fourth month of the anomalous treatment system. The heat is melted and the body is directly dispersed by the powder, and by the reverse of the production of co2: "there is a disgusting, so that the coke having a high reactivity of U2 can be formed in a simpler manner. 7 200938620 [Embodiment] <First [Embodiment] Fig. 1 shows an example of the first embodiment of the present invention. #θ ι She is attentive to the heart of the coke oven 1 The coke treatment system is wounded: Device 3, Q (dry fire extinguishing equipment) 2 , powder dispersion J and furnace 4, etc., in order to carry out the treatment of the coke from the Seto 摅! plate to the blast furnace 4. Also === The housewife produced by the distilling coal is in the process of dry cooking The Q2 silk dispersing device 3 and the like carry out each of the cokes that are discharged from the coke oven 1 *CDQ2^^-v^, which is burned by 竽CD 2 It is below the predetermined temperature. Charcoal = Γ 构 ? 用以 用以 用以 用以 用以 用以 用以 用以 用以 用以 用以 用以 用以 用以 用以 用以 用以 用以 、 、 、 、 焦 焦 、 焦 焦 炭 炭 炭 炭 炭 炭 炭 炭 炭 炭 炭 炭 炭 炭 炭 炭 炭 炭 炭 炭 炭In the temperature range of 〇°c. C~ The focus of the body: the body f cloth device 3 is the one that transports the coke oven 1 to the blast furnace 4 from the alkaline earth gold Organic compound of the genus: organic organic powder 6 'In this example, the organic coke is dispersed by coke after c 冓 ^ Q 2 is cooled from the pair just after cooling by CDQ 2 Immediately after the powder dispersing device 3 is provided with Q2, 'Γ, 、, Q2 can be installed in the powder dispersing device 3 without causing thermal decomposition of the organic powder 200938620 6 . The above-mentioned soil testing is a genus, 〇 2 anti- The library and the right net can be used as examples. The calcium (C a ) 笪山士机 compound which has a catalytic effect on the coke in the blast furnace 4 can be found as usual. At this time, the above is equal. W calcium stearate, lemon Calcium acid and calcium oleate 179t: ~18crc. About 〇C. The melting point of calcium oleate. Therefore, if these organic compounds are used, the temperature of the coke after melting the organic compound can be low. By transferring from the coke oven 1 to the high body, the organic powder 6 to be dispersed can be melted by CDQ2, and the melting point i 2 of the calcium sulphate of the calcium sulphate is 83. ~84 t or so s as the organic powder 6 points set to be more than CDQ according to this temperature setting, that is, coke 4 Shame, v " ', having a foot attached to thaw after cooling of the coke was heat the coke Κι machine by making test earth metal-containing organic compound of - and is attached: to coke, can be improved. Organic compounds, because of I: there will be: =: the powder is directly dispersed ... into, can be "simpler structure of the machine; = solution and dispersion in high eschar. Re-winding 4 and C 〇 2 reactivity and attached to =: by the heat of coke to make the organic powder 6 fused powder "melt I: source factor = must be additionally set to make the organic system. Therefore, the coke having high reactivity of 9 200938620 and c〇2 can be manufactured with a simpler constitution. In particular, since the organic compound 6 dispersed by the cooled coke is condensed by the residual heat of the bank, the coke is attached thereto. 'Eso can make the organic powder 6 adhere well to the cooled coke, so that the reactivity of C 〇 2 and the sonic carbon can be effectively improved. Further, depending on the operating state of CDQ2, it may be cooled by the C DQ 2 The temperature of the coke may also vary. In this case, it may be set as the above-mentioned (four) different organic compounds as the organic powder 6, and the organic powder of the coke temperature after cooling may be blended. The body 6 is interspersed with the structure of the coke, ... the right horse contains alkali ... then the organic II I: ' is not particularly limited. In addition, the organic compound is attached to the charcoal with a concentration of 0.5 wt% or more. The figure shows the flow of I:::: by the coke processing system of the first figure Figure 1 after the coke oven dry coal by this repulsive r 'lines to carry-out conveyance path 15 from the coke oven 1 to be rapidly "Q1)' CDQ2 by the dry quenching process (step Sl02 unit BU: cooling step). Connected from CDQ 2 to cool &# 曰 from rare organic powder 6 (step; Γ〇 = the organic powder 6 by the Seto:: let go step), coke (step S1 0 4—attached to the 200938620, which is based on t, and the organic powder 6 of the sleek, although one of the attached faces; the eight V-body car is good, but even if it is only attached to the phenotype. The reaction between C02 and coke is attached to the organic powder 6 of Jiaoyu, which is conveyed when it arrives. The temperature is lowered: the surface of the carbon. In this way, the surface is attached (solid 2 = ❹ The transport path 5 is carried into the blast furnace 4 (the step is to make the body of the powder dispersing device 3, and the charcoal is distributed to the organic powder 6). After the removal, the configuration may be carried out through the transport path 5 to the organic powder 6. The "cobalt dispersion" between the Q2 and the first embodiment is the same as the organic powder 6 ',,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, The third embodiment of the present invention is a block diagram of the second embodiment of the present invention. The coke treatment; /, the heating device 7 is provided, and the state is the same. Therefore, for the same configuration: the second-implementation-shaped κ configuration is assigned the same reference numeral 11 200938620 and the description thereof is omitted. The heating device 7 is used to apply the organic umbrella, the _ 冉 壮 ® η η Twisting, organically dispersed from the core discharge device 3: the twisting of the heating device 7 and melting of the second knife (10)' is carried out by coke fed to the blast furnace 4 and attached to the coke oven 1 for example, In the case where the powder dispersing device 3 is provided at the position 2, the organic system which is just distributed by the melting point ^ Γ 3 of the 6 body of the 、 、 、 、 CD CD CD CD CD CD CD CD CD 、 、 、 、 、 、 The defect of the buckwheat b is 'but the temperature of the coke in the organic powder is reduced by $μ, +, and sometimes the 丨 丨 低 is as low as the above melting point to melt. ^ In the organic powder 6 Hyun point is better than just 丄 = = :: coke temperature is high, that is: 6 scattered just after cdqw but after Coke, no =: Organic powder 6 adheres well to coke. In addition, c WQ anaerobic fire extinguishing method with low coke temperature after 〇CDQ cooling, or external purchase or pre-production In the case of coke, etc., when the coke is used for a long period of time after cooling, the organic powder 6 is directly dispersed in the coke, and the organic powder 6 cannot be adhered to the coke. In the case where the organic powder 6 is heated in the case where the organic powder 6 is heated as in the present embodiment, the organic powder 6 can be satisfactorily melted. Attached to coke. In particular, the stable heat from the heating device γ causes the organic powder 12 200938620 to be smothered and the carbon is adhered well, so that the reactivity of the L and the anorexia can be effectively improved. In addition, the operation difference of the root 掳 c DQ 2 is: the temperature of the coke after cooling the CDQ2 is produced as an organic system: a plurality of different types of the second sneak point, and the heating device 7 is disposed from the powder. The structure in which the dispersed organic powder 6 is heated above the melting point is limited to the second figure ####, CD. :: The cloth device 3 and the heating device 7 are configured separately from each other. The organic powder (4) '2' is not used, and the powder distributing device 3 and the heating device 7 may be installed in the CDQ 2 . The ❹ line indicates the flow chart of the second =:! by the coke processing system of the third figure. After the coke oven 1 is dried by coal (cut, ', 厌, money 1 is carried out to the transport path 5, dry fire extinguishing place by CDQ2】 =: (step S2〇2·• cooling step). Next, Dream organic cooling of the coke, from the powder dispersing device 3 "will have a version 1 (step S 2 0 3: powder dispersion step), and the powder 6 is heated by the heating device 7 () step; 13 1 Charcoal 2: Table plus two: There is 1 "body 2 is the best of the season, but even if 200938620 is only attached to one part of the surface, it can improve the reactivity of ◦ and coke. Attached to coke The organic powder 6," is fixed to the surface of the coke by lowering the temperature to the melting point during the transfer process to the blast furnace 4: in this way, the surface is adhered to the coke of the organic powder 6, The blast furnace 4 is carried through the transport path 5 (step S206). <Examples> The fifth diagram is a schematic view showing an example of a thermal reactivity test apparatus © 1000 for measuring the reactivity of coke and C Q 2 to which the organic powder 6 is adhered. The thermal reactivity test apparatus is configured by closing the reaction tube 1 〇1 as a sample loading unit with a reaction tube cover 102, and introducing a gas into the reaction tube 101 from the gas introduction port 1 〇3. The gas in the reaction tube 1〇1 can be discharged from the gas discharge port 1 〇4. Using the thermal reactivity test apparatus 2 〇 〇 to carry out the pre-test enthalpy treatment step, the coke was cooled by c D Q 2 , and the particle size was adjusted to 1 9 m 2 to 2 m m to prepare a bottom coke. The bottom coke is heated to 2 Torr in a dryer, and directly put into a beaker in which the hard fat glutinous rice which has been placed as the organic powder 6 is placed in a heated state, thereby melting the calcium stearate and Attached to the bottom focus. Then, the sample prepared in the above manner was loaded into the reaction tube i 热 of the thermal reactivity test device 1 , and nitrogen gas (n2) was introduced from the gas 14 200938620 inlet 1 0 3 at 5 L/mi η 1 5 minute. In this way, after the air in the reaction tube 1 〇 1 is replaced with nitrogen, the reaction tube 1 0 1 is inserted and set at 1 1 〇 〇. 〇之黾 furnace. Next, after 45 minutes, the gas introduced from the gas introduction port 1 〇 3 was switched from nitrogen gas to carbon dioxide gas (c〇 2 ), and the carbon dioxide gas was reacted with the coke sample for two hours. According to the coke test after the reaction prepared by the above experiment

❹ 料的重量(反應後重量)與反應前之焦炭試料的^ 量(反應前重量),藉由下述數式(丄)或(2 )求 出CRI (與C〇2反應量相關之指標)。此外,藉 由加熱或c〇2反應,則不僅是焦炭,硬脂_(s曰 t C a )亦會減量’不過下述數式⑴ 該減量之計算式,而下述數式f 量之計算式。 Λ(2)則為不含該減 數式(1 ) cm 反應前重量一反應後重量 反應前重量 ^100 …⑴ 數式(2 ) 15 200938620 cm上應前重f 一齡附的 反應前®蛩~WCo"附著$ ^ —The weight of the feed (weight after the reaction) and the amount of the coke sample before the reaction (weight before the reaction), the CRI (the index related to the amount of C〇2 reaction) is obtained by the following formula (丄) or (2) ). In addition, by heating or c〇2 reaction, not only coke, but also the hard fat _(s曰t C a ) will be reduced, but the following formula (1) is the calculation formula of the reduction, and the following formula f Calculation formula. Λ(2) is not containing the subtraction formula (1) cm before the reaction weight-reaction weight before reaction weight ^100 ... (1) formula (2) 15 200938620 cm on the front weight f one age attached pre-reaction®蛩~WCo" Attach $^ —

Ca£t )—Moo …⑵ 第六圖係表示藉由數式(1 )及(2 )所算出-之C R I (%)與硬脂酸舞之附著量(%)之關係, 的圖表。「含硬脂酸C a」係藉由數式(丄)所管出 之值’而「無硬脂酸C a」貝"系藉由數式(2^所 算出之值。從該圖表可知,硬脂酸鈣對焦炭之 量愈增加,則CR !之值會愈高而提升c〇2與焦炭❹ 之反應性。尤其,在硬脂酸鈣之附著量為3 %以上 時,與底焦相較則已大幅提升與c〇2之反應性。 從以上實驗結果可知,藉由增加硬脂酸鈣對隹 炭之附著量,即可謀求CQ2與焦炭之高反應性化。 又,藉由控制硬脂酸鈣對焦炭之附著量,亦可控制 C〇2與焦炭之反應性。 其次,以藉由上述實驗所製得之反應後之焦炭❹ 為試料,進行熱反應後強度(C S R )之測試。具 體而言,係將試料裝填於丨型滾筒測試機,並以每 分鐘轉動二十次之速率旋轉3 〇分鐘共計六百次。 之後,將取出之試料澆置於僅使9 · 5 m m以下之粒 子通過之篩,並測量殘留在篩上之粒子的重量(篩 上重里)。可根據藉由此種實驗所製得之篩上重量與 裝填於I型滾筒測試機前之試料的重量(試料重 16 200938620 里)’藉由下述數式(3 )求出反應後強度。 數式(3 )Ca£t ) - Moo (2) The sixth graph shows a graph of the relationship between C R I (%) calculated by the equations (1) and (2) and the amount of adhesion (%) of stearic acid dance. "Containing stearic acid C a" is the value calculated by the formula (丄) and "no stearic acid C a" is the value calculated by the formula (2^). The higher the amount of calcium stearate coke, the higher the value of CR! will increase the reactivity of c〇2 and coke 。. Especially when the amount of calcium stearate is more than 3%, the bottom The coke phase has greatly improved the reactivity with c〇2. From the above experimental results, it can be seen that by increasing the amount of calcium stearate attached to the charcoal, high reactivity of CQ2 and coke can be achieved. By controlling the amount of calcium stearate to adhere to the carbon, it is also possible to control the reactivity of C〇2 with coke. Secondly, the strength after thermal reaction (CSR) is determined by the coke oxime after the reaction prepared by the above experiment. Specifically, the sample was loaded into a stern-type drum tester and rotated at a rate of 20 revolutions per minute for 3 〇 minutes for a total of six hundred times. After that, the sample taken out was poured into only 9 · Particles below 5 mm pass through the sieve and measure the weight of the particles remaining on the sieve (on the sieve) The post-reaction strength can be determined by the following formula (3) based on the weight of the sieve prepared by such an experiment and the weight of the sample before the I-roller tester (sample weight 16 200938620). Number (3)

CSR 9.5mm篩上重量 試料重量CSR 9.5mm on-screen weight sample weight

X 100 ⑶ ❹ 第七圖係表示將藉由數式(3)所算出之c:s R (%)與CR { 之關係與操作值比較的圖 表。。操作值意指針對不附著硬脂酸鈣而供應於實際 上操作之高爐4的焦炭(操作上之焦幻,使用上^ 數式(1)及(3)所算出之CSR&CRI之各 值。從此圖表可知,比較附著有硬脂酸鈣之焦炭與 刼作上之焦炭時,附著有硬脂酸鈣之焦炭其C s R ❹值對同等之CRI值較南,且焦炭之強度較高。 從第七圖所示之操作值,雖可知C R I之值愈 =則C S R之值會愈小’亦即c〇2與焦炭之反應性 愈向則焦炭之強度會愈降低,不過從上述實驗結果 可知,藉由使硬脂酸鈣附著於焦炭,即使是同等反 應性亦可使焦炭之強度不易降低。 其次,進行附著有硬脂酸鈣之焦炭之C〇2反應 ^時所產生之氣體的測量。硬脂_等有機物鹽 係错由加熱而熱分解並產生具有熱量之氣體。因 17 200938620 此’係調查在CR I測量時c〇2反應下的硬脂酸鈣 之熱分解狀況。具體而言,係在僅焦炭之情況下、 與將硬脂酸鈣混合(例如i 〇%)於焦炭之情況下, 分別採取加熱反應時之氣體,並測量氣體之組成/ · 產生里。此外,藉由從所採取之氣體的全量減去二 氧化碳氣體之導入量來修正產生氣體量。X 100 (3) 第七 The seventh figure shows a graph comparing the relationship between c:s R (%) and CR { calculated by the equation (3) and the manipulated value. . The manipulated value means a coke which is supplied to the actually operated blast furnace 4 without attaching calcium stearate (operational illusion, using the values of CSR & CRI calculated by the above equations (1) and (3) From this chart, it can be seen that when the coke with calcium stearate and the coke adhered to it are compared, the C s R ❹ value of the coke with calcium stearate attached is equivalent to the CRI value of the same, and the strength of the coke is higher. From the operation values shown in the seventh figure, it can be seen that the higher the value of CRI is, the smaller the value of CSR will be, that is, the more the reactivity of c〇2 and coke will be, the lower the strength of coke will be, but from the above experiment As a result, it has been found that by attaching calcium stearate to coke, the strength of the coke is not easily lowered even by the same reactivity. Next, the gas generated by the C〇2 reaction of the coke to which calcium stearate is adhered is carried out. The measurement of hard acid _ and other organic salts is thermally decomposed by heating and produces a gas with heat. 17 200938620 This is a thermal decomposition of calcium stearate under the c 〇 2 reaction at the CR I measurement. Specifically, in the case of coke only, with stearic acid Mixing (for example, i 〇%) in the case of coke, respectively, taking the gas during the heating reaction, and measuring the composition of the gas / · production. In addition, by subtracting the introduction amount of carbon dioxide gas from the total amount of the gas taken Correct the amount of gas produced.

根據藉由上述實驗所獲得之各氣體的產生率 (% )’算出各氣體之發熱量(卡)。亦即,將熱分 解所產生之各氣體之每1 的熱量乘以各氣體 ,產生率再除以1 0 〇。例如,所產生之氣體中, 若以氫(Η 2 )為例時,僅以焦炭反應時氫的產生率 係1 . 6 1 %。又,氫之發熱量係2 5 7 〇 k a } /The calorific value (card) of each gas was calculated from the production rate (%) of each gas obtained by the above experiment. That is, each heat of each gas generated by thermal decomposition is multiplied by each gas, and the generation rate is further divided by 10 〇. For example, in the gas produced, when hydrogen (Η 2 ) is taken as an example, the hydrogen generation rate in the reaction of only coke is 1.6%. Moreover, the calorific value of hydrogen is 2 5 7 〇 k a } /

Nm3。因此,產生氣體每lNm3之氫的發熱量係 如次式。同樣地,以實驗所產生之其他氣體亦可從 其組成求出產生氣體每1 N m3所貢獻之發熱量。 數式(4 )Nm3. Therefore, the calorific value of hydrogen generated per 1 Nm 3 of the gas is as follows. Similarly, the other gases generated by the experiment can also be used to determine the amount of heat generated by the generated gas per 1 N m3. Equation (4)

Hj\]ccal /Νίτι. 2570x1,61 " II __100 41377 又’根據將硬脂酸鈣摻合於焦炭並使其反應時 之各氣體的產生率Β、僅使焦炭反應時之各氣體的 18 200938620 產生率C、以及硬脂酸鈣對焦炭之摻合率D,藉由 下述數式(α )即可求出僅使硬脂酸鈣反應時之各 氣體的氣體產生率Α。以此方式,藉由將各氣體每 1 Nm3之熱量乘以所求得之各氣體的產生率再除 以1 0 0,即可求出在僅使硬脂酸鈣反應時熱分解 所產生之氣體每1 Nm 3之各氣體的發熱量。 數式(5 )Hj\]ccal /Νίτι. 2570x1,61 " II __100 41377 And 'According to the rate of generation of each gas when calcium stearate is blended into coke and reacted, only the gas of coke is reacted 18 200938620 The production rate C and the blending ratio D of the calcium stearate coke are determined by the following formula (α) to determine the gas generation rate 各 of each gas when only calcium stearate is reacted. In this way, by multiplying the amount of heat per 1 Nm 3 of each gas by the obtained rate of each gas and dividing it by 100, it is possible to determine the thermal decomposition caused by the reaction of only calcium stearate. The calorific value of each gas of the gas per 1 Nm 3 . Number (5)

'ία) b-c4-d) A :僅硬脂酸齊的氣體產生率(kg/kg) B :硬脂酸鈣與焦炭混合時的氣體產生率(kg/kg) C :僅焦炭的氣體產生率(kg/kg) D :硬脂酸約的混合率(kg/kg) 下述表一係將藉由以上運算所算出之各氣體的 發熱量區分表示成僅使焦炭(底焦)反應時之情況、 將硬脂酸鈣摻合於焦炭並使其反應時之情況、以及 僅使以數式α所算出之硬脂酸鈣反應時之情況,並 顯示各情況之各氣體之發熱量的合計值。 19 200938620 【表一】 組成 焦炭(底焦) kcal/Nm3 焦炭(底焦) +StCalO% kcal/Nm3 —--- 上述(X式所計算的僅 StCa kcal/Nm3 H2 41.4 138.0 •一 1007.7 CO 984.2 1181.4 '~~~ 2956.3 C02 0.0 0.0 0.0 n2 0.0 0.0 • 一 · 0.0 ch4 2.6 479.1 4767.5 c3h6 0.0 770.5 7704.7 C3H8 0.0 84.9 ~~~------ 848.9 c2h6 0.0 260.6 2606.1 c2h4 0.0 1167.8 11678.4 合計 -· 1028.2 4082.3 31569.6 ^ +3054.1'ία) b-c4-d) A : gas production rate of only stearic acid (kg/kg) B: gas generation rate when mixed with calcium coke (kg/kg) C : coke-only gas Production rate (kg/kg) D: mixing ratio of stearic acid (kg/kg) The following Table 1 shows that the calorific value of each gas calculated by the above calculation is differentiated to reflect only coke (bottom coke). In the case of the case, when calcium stearate is blended into coke and reacted, and when only calcium stearate calculated by the formula α is reacted, the calorific value of each gas in each case is shown. Total value. 19 200938620 [Table 1] Composition of coke (bottom coke) kcal/Nm3 coke (bottom coke) + StCalO% kcal/Nm3 —--- The above (only StCa kcal/Nm3 H2 41.4 138.0 calculated by X formula • 1007.7 CO 984.2 1181.4 '~~~ 2956.3 C02 0.0 0.0 0.0 n2 0.0 0.0 • One 0.0 ch4 2.6 479.1 4767.5 c3h6 0.0 770.5 7704.7 C3H8 0.0 84.9 ~~~------ 848.9 c2h6 0.0 260.6 2606.1 c2h4 0.0 1167.8 11678.4 Total -· 1028.2 4082.3 31569.6 ^ +3054.1

據°玄表可知,藉由將硬脂酸i弓摻合1 〇 % ^、、、厌’與僅使焦炭(底焦)反應之情況,重烴之 里即增加,發熱量的合計值係增加3 〇 〇 〇 & ◦ a YNm左右。依據此結果,即可藉由使硬脂酸鈣 寸者於焦炭來增加在高爐4所產生之氣體的能量, 而再利用作為煉鋼廠内之能量等。 20 200938620 以上貫施形離、中,、 土類金屬之一例作 Μ鈣(C a )為例作為驗 亦可使用由八說明’但並不限於此種構成, 吏用由3鈣以外之驗According to the ° Xuan table, by blending stearic acid i bow with 1 〇% ^, , 厌 ' with only coke (bottom coke), the weight of heavy hydrocarbons increases, the total value of calorific value Increase 3 〇〇〇 & ◦ a YNm or so. According to this result, the energy of the gas generated in the blast furnace 4 can be increased by using calcium stearate in the coke, and the energy in the steelmaking plant can be reused. 20 200938620 The above examples of the separation of the form, the middle, and the earth metal are used as an example. Calcium (C a ) is used as an example. It can also be used by the eight instructions, but it is not limited to this type of composition.

°、鎂(Μβ)υς 、屬例如鈹(B 女地 u(Sr)、以及鋇) 匕合物所構成的有機系粉體。 此侷限本:述僅為本發明之較佳可行實施例,非因 說明蚩及阎4 ^ & 固故舉凡運用本發明 二:及圖式内容所為之等效技術變 本發明之權利保護範圍内,合予陳明。於 【圖式簡單說明】 理二'係表示本發明之第-實施形態之焦炭處 系 '、'先之一例的方塊圖。 ❹ 行之户理Γ係表不猎由第一圖之焦炭處理系統所進 仃之處理之一例的流程圖。 =圖係表示本發明之第二實施形態之焦炭處 理糸統之一例的方塊圖。 —ί四圖係表示藉由第三圖之焦炭處理系統所進 灯之處理之一例的流程圖。 ^㈣表示用以測量附著有機系粉體之焦炭 人c〇2之反應性所使用之熱反應性測試裝置之一 例的概略圖。 第六圖係表示藉由數式(1 )及(2 )所算出 之CRI⑻與硬脂酸鈣之附著量(幻之:係 200938620 的圖表。 第七圖係表示將藉由數式(3 )所算出之C S R ( %)與C R I ( %)之關係與操作值比較的圖 表。 · 【主要元件符號說明】 ’ 1 焦炭爐 ' 2 CDQ ' 3 粉體散佈裝置 4高爐 ® 5 搬送路徑 6 有機糸粉體 7 加熱裝置 100 熱反應性測試裝置 101 反應管 102 反應管蓋 103 氣體導入口 q 104 氣體排出口 22°, magnesium (Μβ)υς, an organic powder composed of, for example, bismuth (B female y (Sr), and yttrium) chelates. The present invention is only a preferred embodiment of the present invention, and the scope of the present invention is not limited by the description of the invention and the equivalent technology of the present invention. Within, combined with Chen Ming. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 2 is a block diagram showing an example of a coke system of the first embodiment of the present invention. The bank's household management system does not trace the flow chart of one of the processes handled by the coke processing system of the first figure. Fig. 4 is a block diagram showing an example of a coke processing system according to a second embodiment of the present invention. - Figure 4 is a flow chart showing an example of the processing of the lamps entering the coke processing system of the third figure. (4) is a schematic view showing an example of a thermal reactivity test apparatus used for measuring the reactivity of coke human c〇2 to which organic powder is adhered. The sixth figure shows the amount of CRI (8) and calcium stearate deposited by the formulas (1) and (2) (magic: it is a chart of 200938620. The seventh figure shows that it will be represented by the formula (3) Chart of the relationship between the calculated CSR (%) and CRI (%) and the operation value. · [Main component symbol description] ' 1 Coke oven' 2 CDQ ' 3 Powder dispersing device 4 Blast furnace® 5 Transfer path 6 Organic 糸Powder 7 Heating device 100 Thermal reactivity testing device 101 Reaction tube 102 Reaction tube cover 103 Gas introduction port q 104 Gas discharge port 22

Claims (1)

200938620 七、_請專利範圍·· 1、一種焦炭處理李絲, f高爐之焦炭的處理,其笋H進行對從焦炭爐搬送 爐之該焦炭,散佈由含驗』麵厶< 5亥焦炭爐搬送往該高 之有機系粉體,使該有機㈡屬々有機化合物所構成 該焦炭。 幾系叔粗错由熱而熔融並附著於 2、如申請專利範圍 其中該有機系粉體係藉圍由^; 員所山述之焦炭處理系統, 该焦炭的熱而熔融並附著於該^,、、^爐搬送往該高爐之 其尹具備士 U利㈣第2項所述之焦炭處理系統, 粉體3裝二該;\炭爐所搬送之該焦炭; 冷1置冷㈣之該焦炭點係較藉由該 其中具備加埶id:弟1項所述之焦炭處理系統, 機系粉體係藉由該加熱粉體加熱,該有 5亥焦炭爐搬送往該高爐^該焦炭"了而熔嘁,亚附著於從 往高爐之焦理:2若用τ進行對從焦炭爐搬送 對從該焦炭爐搬送往備一粉體散佈步驟,係藉由 金屬之有機爐;該焦炭,散佈由含鹼土類 體藉由熱而炫融系粉體’使該有機系粉 該”的熱而^並^由=&炭爐搬送往該高爐之 其中具備^Λ5之利範圍第6項所述之焦炭處理方法, 焦炭;該粉體7散卩/牛驟用以冷卻從該焦炭爐所搬送之該 政佈乂驟中,係對藉由該冷卻步驟冷卻後 23 200938620 ^該焦炭散佈該有 藉由該冷卻步驟隹t有機系粉體之熔點 8、如申請專:!後=戾的溫度低。 … 其中具備一加熱步:圍第5項所述之焦炭處理方法, 系粉體係藉由ί加:牛::f f機系粉體加熱;該有機 焦炭爐搬送往哕之加熱而熔融,並附著於從該 "Λ同嗯之該焦炭。 ©200938620 VII, _ please patent scope · 1, a coke treatment Li silk, f blast furnace coke treatment, its bamboo shoots H to the coke from the coke oven transfer furnace, scattered by the test "face" 亥 亥 5 coke The furnace is transported to the high organic powder, and the organic (II) organic compound constitutes the coke. Several uncles are melted by heat and adhered to 2. In the scope of the patent application, the organic powder system is surrounded by a coke processing system, which is hot and melted and adhered to the coke processing system. The furnace that is transported to the blast furnace has the coke treatment system described in item 2 of the Uli (4), the powder 3 is installed; the coke conveyed by the charcoal furnace; the coke cooled by the cold 1 (4) The point system is more than the coke processing system described in the item 1 of the twisting id: the brother system, the machine powder system is heated by the heating powder, and the 5 cc coke oven is transferred to the blast furnace ^ the coke " And the melting, sub-attachment to the kiln of the past blast furnace: 2 if the τ is used to carry the transfer from the coke oven to the coke oven to the preparation of a powder dispersion step, by means of a metal organic furnace; the coke, the dispersion The heat containing the alkaline earth body by the heat and smelting of the powder 'to make the organic powder' is transferred to the blast furnace by the =& charcoal furnace, which has the benefit of the sixth item The method for treating coke, coke; the powder 7 is used to cool the coke oven In the political cloth step, after cooling by the cooling step 23 200938620 ^ the coke dispersion has a melting point of the organic powder by the cooling step 、t, as the application temperature: low = 戾. ... having a heating step: the coke processing method described in item 5, the powder system is heated by the ί:牛::ff machine powder; the organic coke oven is transferred to the crucible for heating and melting, and attached From the coke of the "Λ同嗯. © 24twenty four
TW098102894A 2008-03-05 2009-01-23 Cokes processing system and cokes processing method TW200938620A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2008054893A JP5188842B2 (en) 2008-03-05 2008-03-05 Coke processing system and coke processing method

Publications (1)

Publication Number Publication Date
TW200938620A true TW200938620A (en) 2009-09-16

Family

ID=41093626

Family Applications (1)

Application Number Title Priority Date Filing Date
TW098102894A TW200938620A (en) 2008-03-05 2009-01-23 Cokes processing system and cokes processing method

Country Status (4)

Country Link
JP (1) JP5188842B2 (en)
KR (1) KR20090095468A (en)
CN (1) CN101525556A (en)
TW (1) TW200938620A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5437595B2 (en) * 2008-06-09 2014-03-12 関西熱化学株式会社 Coke production method and system
JP6796354B2 (en) * 2016-09-30 2020-12-09 日本製鉄株式会社 Coke pretreatment method
CN115141639A (en) * 2021-03-28 2022-10-04 上海梅山钢铁股份有限公司 Sample arrangement device and method for coke dry quenching tank

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3110191C2 (en) * 1980-10-04 1986-01-09 Carl Still Gmbh & Co Kg, 4350 Recklinghausen Process for cooling chamber coke
JP3388014B2 (en) * 1994-04-12 2003-03-17 新日本製鐵株式会社 Coke reforming method
JP3936574B2 (en) * 2000-11-30 2007-06-27 新日本製鐵株式会社 Method for producing highly reactive coke for blast furnace
JP4102042B2 (en) * 2001-09-18 2008-06-18 新日本製鐵株式会社 Metallurgical coke reforming process and highly reactive coke
JP2004315664A (en) * 2003-04-16 2004-11-11 Nippon Steel Corp Method for producing highly reactive coke for blast furnace, having different distribution of catalyst concentration
JP4351555B2 (en) * 2004-02-20 2009-10-28 新日本製鐵株式会社 Highly reactive coke for blast furnace and method for producing the same
JP4414902B2 (en) * 2005-01-26 2010-02-17 新日本製鐵株式会社 Method for producing highly reactive coke
CN2793076Y (en) * 2005-06-03 2006-07-05 北京科技大学 Material clock for coke particle distribution on dried quenching furnace

Also Published As

Publication number Publication date
CN101525556A (en) 2009-09-09
JP2009209287A (en) 2009-09-17
JP5188842B2 (en) 2013-04-24
KR20090095468A (en) 2009-09-09

Similar Documents

Publication Publication Date Title
US20210246521A1 (en) Method for Carburization of HDRI produced in H2 based Direct Reduction Process
TW531560B (en) Granular metallic iron
TW201016857A (en) Method and apparatus for operating a melt reduction process
TW201002828A (en) Process and apparatus for producing pin iron or liquid primary steel products
US10316376B2 (en) Methods and systems for increasing the carbon content of sponge iron in a reduction furnace
TW200938620A (en) Cokes processing system and cokes processing method
Liu et al. Carbothermal reduction of iron ore in its concentrate-agricultural waste pellets
CN107881280A (en) It is a kind of to reduce and cool down the system and method for metallized pellet
CN105492633A (en) Raw material for direct reduction applications, method for producing raw material for direct reduction applications, and method for producing reduced iron
BR112019008035B1 (en) CONTINUOUS PROCESS AND APPARATUS FOR DIRECT REDUCTION OF IRON ORE IN A SOLID STATE
Zhang et al. Roasting characteristics of specularite pellets with modified humic acid based (MHA) binder under different oxygen atmospheres
TWI615477B (en) Methods and systems for increasing the carbon content of sponge iron in a reduction furnace
RU2009140757A (en) METHOD AND DEVICE FOR PREPARING A REDUCER FOR APPLICATION IN THE PROCESS OF PRODUCING METAL, THE PROCESS OF PRODUCING METAL AND THE APPARATUS FOR PRODUCING METAL USING THE MENTIONED DEVICE
CN107829018A (en) A kind of method for preparing ferrovanadium nitride
Du et al. The role of MgO powder in preventing defluidization during fluidized bed reduction of fine iron ores with different iron valences
JP4331605B2 (en) Method for reducing particulate material containing metal, especially iron ore
CN110045082B (en) Method for measuring and evaluating high-temperature performance of lump coal in smelting reduction iron making
Jung et al. A kinetic study on carbothermic reduction of hematite with graphite employing thermogravimetry and quadruple mass spectrometry
Kelamanov et al. Study of nickel briquettes by thermographic method
TW200938619A (en) Cokes processing system and cokes processing method
JP6414903B2 (en) Production method of carbon interior ore
CN207877767U (en) A kind of system of reduction and cooling metallized pellet
JP6288139B2 (en) Carbon dioxide regeneration system using slag heat
Santos et al. High‐temperature reduction of iron oxides by solid carbon or carbon dissolved in liquid iron–carbon alloy
TW483936B (en) Process and apparatus for heat treating parts