TW200932687A - Method for making drinking water containing hydrogen - Google Patents

Method for making drinking water containing hydrogen Download PDF

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Publication number
TW200932687A
TW200932687A TW097145051A TW97145051A TW200932687A TW 200932687 A TW200932687 A TW 200932687A TW 097145051 A TW097145051 A TW 097145051A TW 97145051 A TW97145051 A TW 97145051A TW 200932687 A TW200932687 A TW 200932687A
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Taiwan
Prior art keywords
water
hydrogen
raw material
supplied
gas
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TW097145051A
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Chinese (zh)
Inventor
Akira Kato
Michio Yoshizawa
Kosuke Kinno
Tomonori Yuzaki
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Bio Res Inc
Organo Corp
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Publication of TW200932687A publication Critical patent/TW200932687A/en

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    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52—Adding ingredients
    • A23L2/54—Mixing with gases
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K33/00—Medicinal preparations containing inorganic active ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P1/00—Drugs for disorders of the alimentary tract or the digestive system
    • A61P1/04—Drugs for disorders of the alimentary tract or the digestive system for ulcers, gastritis or reflux esophagitis, e.g. antacids, inhibitors of acid secretion, mucosal protectants
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P11/00—Drugs for disorders of the respiratory system
    • A61P11/06—Antiasthmatics
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P37/00—Drugs for immunological or allergic disorders
    • A61P37/08—Antiallergic agents
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P9/00—Drugs for disorders of the cardiovascular system
    • A61P9/12—Antihypertensives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/025—Reverse osmosis; Hyperfiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/027—Nanofiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/04—Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/145—Ultrafiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/16—Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/06—Tubular membrane modules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20—Mixing gases with liquids
    • B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/231—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids by bubbling
    • B01F23/23105—Arrangement or manipulation of the gas bubbling devices
    • B01F23/2312—Diffusers
    • B01F23/23124—Diffusers consisting of flexible porous or perforated material, e.g. fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20—Mixing gases with liquids
    • B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/231—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids by bubbling
    • B01F23/23105—Arrangement or manipulation of the gas bubbling devices
    • B01F23/2312—Diffusers
    • B01F23/23124—Diffusers consisting of flexible porous or perforated material, e.g. fabric
    • B01F23/231244—Dissolving, hollow fiber membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20—Mixing gases with liquids
    • B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/237—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media
    • B01F23/2376—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media characterised by the gas being introduced
    • B01F23/23764—Hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • C01B3/503—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion characterised by the membrane
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4676—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electroreduction
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/04—Specific process operations in the feed stream; Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/13—Use of sweep gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/16—Flow or flux control
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0495—Composition of the impurity the impurity being water
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/20—Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/30—Treatment of water, waste water, or sewage by irradiation
    • C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Water Supply & Treatment (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Nanotechnology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Pulmonology (AREA)
  • Inorganic Chemistry (AREA)
  • Immunology (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Electrochemistry (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Cardiology (AREA)
  • Epidemiology (AREA)
  • Combustion & Propulsion (AREA)
  • Nutrition Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Physical Water Treatments (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
  • Degasification And Air Bubble Elimination (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Non-Alcoholic Beverages (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

This invention provides a method for making drinking water containing hydrogen having a high concentration of hydrogen and less variation in the amount of dissolved hydrogen, the method being suitable for mass production. A hydrogen gas dissolving module which is separated by a gas pervious membrane made of a hydrophilic material into a raw water passing portion and a hydrogen passing portion is prepared, and the raw water is supplied to the raw water passing portion while a pressurized hydrogen gas is supplied to the hydrogen gas passing portion to dissolve the hydrogen in the raw water. Thereafter, the raw water having the hydrogen gas dissolved therein discharged from the raw water passing portion of the hydrogen gas dissolving module is charged in a vessel which is then sealed, and the raw water containing dissolved hydrogen gas is subject to sterilization treatment.

Description

200932687 六、發明說明： 【發明所屬之技術領域】 【先關適合於飲料用之含氣水之製造方法。 冑文獻報告揭示，氧化還位 去除-般認為老化或疾病的原因物質==水，能 腸胃等消化㈣ίί iopie)、氣喘等過敏性疾病， © 由与η'、疾病’以及鬲血壓症等健康障害。 可提高還t還原力強，若使井水或㈣水中含有氫，則 ^ 斗用含氫水’例如將氫氣分散於原料水 化然而’由於氫氣在大氣壓下幾乎不躲水，以 造。態加壓使壓力容器内的原料水含有氫之方式集 ❹ 夕厭I!如’ Μ專利讀1 ’將氫氣充填於經去除空棄200932687 VI. Description of the invention: [Technical field to which the invention pertains] [Firstly, a manufacturing method suitable for a gas-containing water for beverages.胄 胄 胄 胄 , 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化Barriers. It can be improved to reduce the reductive power. If the well water or (4) water contains hydrogen, then the hydrogen-containing water is used to disperse the hydrogen gas in the raw material, for example, because hydrogen gas hardly occludes water under atmospheric pressure. The state of pressurization causes the raw material water in the pressure vessel to contain hydrogen in a manner such as 'Μ Μ Patent Read 1 ' to fill the hydrogen with the removed air

10氣^器内’在保持前述壓力容器内之氫氣壓力為2J 宏n肉Γ，使含有礦物質(minerals)之原水喷撒於該壓乂 水中後，、氳氣接觸，使前賴力容11内的氫氣溶解於該眉 將該含有氳之水填充於高氣密性容11中並加以密 該狀態下施加加熱殺菌處理以製造含氫水之方法。 [專利文獻曰本專利第3606466號公報 【發明内容】 [發明所欲解決之課題] 准上迷專利文獻1所揭示之製造方法，係-種分批 320797 200932687 (batch)式方法，故生產效率差如 則有製造裝置大型化% 里生產3虱水時， .原料水中，以致有二，能使氫氣有效溶解於 度容易變動之問題。I $增多，且每批次之氫濃 氫濃=變3明Si於提供-種適合於大量生產、 [祕解絲狀飲仙錢水之製造方法。 ©方法為=目：，本發明係-種飲料用含氣水之製造 透#… 供給於藉由疏水性材料所成之 仏膜（g s pem_ _brane)區隔為原 風氣1部之氫氣溶解模組—）的前_料=通 ，前述氫氣溶解模組的前述氫氣流通部供給經加 壓之氫風，使風氣溶解於前述原料水中，並將從前述狀 答解模組的前述原料水流通部排出之溶解有氫氣之原料水 填充於容器内後加以密封，並實施殺菌處理。 ❹ 依照本發明之飲料用含氫水之製造方法，如將原料水 供給於氫氣溶解模組的原料水流通部，同時於氫氣溶解模 組的氫氣流通部供給經加壓之氳氣，則經供給於氫氣流通 部之氫氣將藉由分壓差而通過透氣膜並溶解於流通於原料 水流動部之原料水中。因此，從氫氣溶解模組的原料水流 通部排出之原料水中，溶解有多量氫氣。如此，採用本發 明’由於可依有效方式，短時間内使原料水令含有氫之故， 可依生產性良好之方式製造品質穩定的飲料用含氫水。 本發明之飲料用含氫水之製造方法中，作為供給於前 320797 5 200932687 述風氣溶解模_前述原料水流通部之前述補水，較佳 為採用含有金屬離子者。純錢超純水料含有金屬離子 之水’飲㈣由於渗透壓的_，可能發生下解症狀。 ❹ 作為、0加1料用含氫水之還原力（降低氧化還原電位） 之方法，可考慮提高pH(作成驗性）之方式。並且，為提高 pH起見’有實施電解處理以生成電解驗性水之方法。然而， 不含有金屬離子之水，則不能藉由電解處理而生成電解驗 性水’以雜於$造還原性較高的飲制含氫水。使用含 有金屬離子者作為原料水，則可有效製造適合飲用、還原 力較強的飲料用含氫水。 本發明之飲料用含氫水之製造方法，在將前述原料水 供給於則述氫氣;谷解模組之前，較佳為通水於奈米過滤器 (nano filter)中以調整電導率（electric c〇nductivity) 為5至2,000#s/cm。由於使原料水通水於奈米過滤器即 可藉由奈米過濾器捕捉鈉離子或鉀離子等礦物質以外之成 φ 分，可製造適合於飲用、還原力較高的飲料用含氫水》 本發明之飲料用含氫水之製造方法，在將前述原料水 供給於前述氫氣溶解模組之前，較佳為通水於r〇膜（逆滲 透膜’ reverse osmosis membrane)，接著’添加金屬離子 以調整電導率為5至2, 000 μ s/cm。在藉由R〇膜之過濾處 理中，雖然可有效去除原料中的不純物，惟連金屬離子亦 會被R0膜所去除。因此，在使原料水通水於R0膜後，添 加金屬離子以調整電導率為5至2,000 /zs/cm，即可製造 適合於飲用、還原力較高的飲料用含氫水。 6 320797 200932687 本發明之飲料用含氫水之製造方法，較佳為使用經通 水於奈米過濾器或R0膜者作為前述原料水，並於從前述氫 氣溶解模組的前述原料水流通部排出之溶解有氫氣之原料 水中，添加選自果汁、蔬菜萃取物、可可萃取物、咖啡萃 取物、茶萃取物、生藥萃取物、蜂蜜、甜味料、以及乳酸 菌中之1種以上。如採用此種狀態，則可製造還原力高的 嗜好性飲料。 本發明之傾帛錢水之製造方法，在將前述原料水 供給於前述錢溶解模組之前，較佳為實施職處理。實 施原料水脫減理之結果，可使錢容易溶解於原料水， 而可有效且短時間製造氫濃度高的飲料用含氫水。In the gas cylinder, the hydrogen pressure in the pressure vessel is kept at 2J macron meat, so that the raw water containing minerals is sprayed in the compressed water, and the helium gas contacts, so that the front force is within 11 The hydrogen gas is dissolved in the eyebrow to fill the high-air-tightness 11 with the water containing the hydrazine, and the heat sterilization treatment is applied to make the hydrogen-containing water. [Patent Document 曰 Patent No. 3606466] [Disclosure of the Invention] [Problems to be Solved by the Invention] The manufacturing method disclosed in Patent Document 1 is a batch method of batching 320797 200932687 (batch) method, so production efficiency If there is a difference in the size of the manufacturing equipment, the production of 3 虱 water, the raw material water, so that there is a problem, the hydrogen can be effectively dissolved in the degree of easy change. I $ increased, and each batch of hydrogen concentrated hydrogen = change 3 Ming Si in the provision - a variety suitable for mass production, [mystery silky drink Xianqian water manufacturing method. The method is as follows: the invention is a method for producing a beverage containing a gas-containing water. The hydrogen-soluble dissolution mode is obtained by supplying a ruthenium film (gs pem_ _brane) formed by a hydrophobic material to a portion of the original atmosphere. The pre-product of the group-) is supplied to the hydrogen gas-distributing portion of the hydrogen-dissolving module, and the pressurized hydrogen gas is supplied to dissolve the wind in the raw material water, and the raw material water flowing from the shape answering module is distributed. The raw material water in which the hydrogen gas is dissolved is filled in the container, sealed, and sterilized.制造 According to the method for producing hydrogen-containing water for beverages according to the present invention, if the raw material water is supplied to the raw material water circulation portion of the hydrogen dissolution module and the pressurized helium gas is supplied to the hydrogen gas flow portion of the hydrogen dissolution module, The hydrogen gas supplied to the hydrogen gas flow portion passes through the gas permeable membrane by the partial pressure difference and is dissolved in the raw material water flowing through the raw material water flowing portion. Therefore, a large amount of hydrogen gas is dissolved in the raw material water discharged from the raw material water flow portion of the hydrogen gas dissolution module. As described above, according to the present invention, since the raw material water can be made to contain hydrogen in a short period of time, the hydrogen-containing water of a stable quality can be produced in a manner that is excellent in productivity. In the method for producing hydrogen-containing water for beverages according to the present invention, it is preferable to use the metal-containing ion as the hydrating water supplied to the raw material water-distributing portion of the first embodiment. Pure money ultra-pure water containing metal ions of water 'drink (four) due to osmotic pressure _, may occur under the symptoms. ❹ As a method of reducing the reducing power (reducing the oxidation-reduction potential) of hydrogen-containing water with 0 and 1 materials, the method of increasing the pH (for verification) can be considered. Further, in order to increase the pH, there is a method of performing electrolytic treatment to generate electrolytically-acceptable water. However, in the case of water containing no metal ions, electrolytically-predictable water cannot be produced by electrolytic treatment to be mixed with hydrogen-containing water having high reductive properties. When a metal ion-containing material is used as the raw material water, it is possible to efficiently produce hydrogen-containing water for beverages which are suitable for drinking and having a strong reducing power. In the method for producing hydrogen-containing water for beverages according to the present invention, the raw material water is supplied to the hydrogen gas; before the glutathion module, it is preferably passed through a nano filter to adjust the electrical conductivity (electric c〇). Nductivity) is 5 to 2,000 #s/cm. By allowing the raw material water to pass through the nano filter, it is possible to capture a hydrogen content of a beverage suitable for drinking and having a high reducing power by capturing a φ component other than a mineral such as sodium ion or potassium ion by a nano filter. In the method for producing hydrogen-containing water for beverages of the present invention, before the supply of the raw material water to the hydrogen dissolving module, it is preferred to pass water through a reverse osmosis membrane, followed by 'adding metal ions. To adjust the conductivity to 5 to 2 000 μ s / cm. In the filtration treatment by the R ruthenium film, although the impurities in the raw material can be effectively removed, only the metal ions are removed by the R0 film. Therefore, after the raw material water is passed through the R0 film, metal ions are added to adjust the electric conductivity to 5 to 2,000 /zs/cm, whereby hydrogen-containing water for beverages having high drinking power and high reducing power can be produced. 6 320797 200932687 The method for producing hydrogen-containing water for beverages according to the present invention is preferably a method of using water passing through a nano filter or a R0 film as the raw material water, and in the raw material water circulation portion of the hydrogen dissolving module. One or more selected from the group consisting of fruit juice, vegetable extract, cocoa extract, coffee extract, tea extract, crude drug extract, honey, sweetener, and lactic acid bacteria are added to the raw material water in which the hydrogen gas is dissolved. When such a state is employed, a preference-producing beverage having a high reducing power can be produced. In the method for producing the decanted water of the present invention, it is preferred to carry out the treatment before supplying the raw material water to the money dissolving module. As a result of the dehydration of the raw material water, the money can be easily dissolved in the raw material water, and the hydrogen-containing water for beverages having a high hydrogen concentration can be produced efficiently and in a short time.

Φ 本發明之飲科用含氫水之製造方法，在將前述原料水 述氫氣溶解模組之前，較佳為實施電解處理以生 及電解驗性水、並將所得電解驗性水供給於 組的前述原料水流通部。PH與氧化還原電 用此種狀態，則即使不使用藥劑等，μ 氮水的ρΗ上升，可有效製造還祕較高的飲料用含 發月之飲料用含氫水之製造 理’較佳為在㈣肺水之 1述電解 狀態’則可有致製造還原性高的飲料==如採用此 本發明之飲料用含氫水之製造方法 水的一部分之電解(eie伽丨 ：為實施原 將所仵氫氣加壓供 320797 200932687 4 於前述氫氣溶解模組的前述氫氣流通部，以使氫氣溶解於 經供給於氫氣溶解模組的前述原料水流通部之前述原料水 中，或者，實施水之電解’將所得氫氣加壓供給於前述氮 氣溶解模組的前述氮氣流通部，以使氫氣溶解於經供給於 氫氣溶解模組的前述原料水流通部之前述原料水中。如採 用此種狀態，則可省略高壓氫氣容器等的準借、交拖v 及氫氣的殘留量管理等工夫。 ^ 本發明之飲料用含氫水之製造方法中，前述飲料用含 Ό 氫水較佳為嗜好性飲料。 [發明之效果] 如採用本發明，則可以良好生產性製造品質穩定的飲 料用含氮水。 [發明之最佳實施形態] 就可採用於本發明之飲料用含氫水之製造方法之飲料 用含氫水製造裝置的一實施形態，使用第1圖加以說明。 U 此種製造裝置20，主要由活性碳槽1、膜過濾裝置 (membrane filter)2、脫氣裝置（deaerator)3、氫氣溶解 模組（hydrogen gas dissolving module)4、UV(紫外線） 殺菌裝置5，以及填充裝置6所構成。 於活性碳槽1内，進行經供給於槽内之原料水之脫氯 處理（dechlorination)。於活性碳槽1上游’連結有從外 部的原料水源所延伸之配管L1。又，從活性碳槽1下游， 則延伸配管L2而連結於膜過漉裝置2 ° 膜過濾裝置2中，則進行經於活性碳槽1中脫氯處理 320797 8 200932687 之原料水（以下，簡稱「脫氯水」）之過濾處理。兩於膜過 濾裝置2之過濾膜而言，奈米濾器（nan〇 fUte〇很適用。 亦可採用R0膜。從膜過濾裝置2下游，延伸有配管L3而 連結於脫氣裝置3。又，細管L3，則在中 而延伸 有連結於電解裝置7之配管14。 脫氣裝置3中，則去除經於臈過遽裝置 滤處理 ❹ 之原料水簡稱「過遽處理水」)中所離氧氣、 氮氣、碳酸…脫氣裝置3而言’可例舉二脫 置或採用透氣膜之膜脫氣裝置等。你、 又 攸脱氣裝置游， ^配管L5而連接於後述之氫氣溶解模㈣的原料水流通 電解裝置7中，進行過濾處理水 氧氣。電解裝置7具有：陰極室7a ·^生成氫氣與 膜7c，而電解用水（經過濾處理之原 至7b、離子交換 供給於陰極室7a及陽極室7b。並且，,即從配管L4 極室7a(氬氣產生侧），延伸有配管 電解裝置7的陰 氣溶解模組4的氫氣流通部4b。又，％連、°於後述之氫 室7b(氧氣產生劑），延伸有 =電解裝i 7的陽極 等。 S L?而連結於氧氣儲備座 風氣溶解模、組4,係藉由疏水性材粗 4c，而被隔開為原料水流通部&，，料斤成之透氣膜 •通部4a的下游 於原料水流通部4a，連結有前述之配通部4b。並且， 牝’則連結有前述之配管L6。從原料’於氫氣流通部 延伸有配管L8而連結於UV殺菌梦署& 囷展置5。又’從氫氣流動 320797 9 200932687 部4b之下游，延伸有配置管L9而作成將氫氣流通部4b内 的氫氣排出於系外之構成。 用於氫氣溶解模組4之透氣膜4c的材質，只要是具有 疏水性者即可，並無特別限制，可例舉：聚矽氧系樹脂、 聚乙烯或聚丙烯或聚4-曱基戊烯-1等的鏈烯烴系樹脂、聚 氟化乙烯等的含氟系樹脂等。 用於氫氣溶解模組4之透氣膜4c的形態，可舉：空心 絲膜為一例。 ® 第2圖中，表示採用空心絲膜作為透氣膜4c之氳氣溶 解模組的一例。 此種氫氣溶解模組中，於容器41内部配置有由透氣膜 所成之空心絲膜42。於該空心絲膜42中形成有：為導入 原料水於空心絲膜内部之原料水入口 43、以及為往外部排 出空心絲膜内部的水之氣體溶解水出口 44。並且，於原料 水入口 43，連結有配管L5。又，從氣體溶解水出口 44， ❹ 延伸有配管L8。 又，於容器41中形成有：為導入氫氣於容器41内部 的氫氣入口 45、以及為往系統外排出氫氣的氫氣出口 46。 並且，於氫氣入口 45，連結有配管L6。又，從氫氣出口 46，延伸有配管L9。又於配管L9，為了使容器41内部的 壓力能成為既定的壓力而設置有閥47。該閥47可為開閉 闕或減壓閥、以及阻抗（如節流閥）等，只要能維持氣體為 加壓狀態者均可使用。藉由閥47的開閉之控制，可控制容 器41内的壓力為既定值。 10 320797 200932687 亦即，第2圖中，空心絲膜内部係本發明之「原料水 流動部」’而容器41的内部與空心絲膜外侧的空間48，係 本發明之「氫氣流通部」。 在此，第2圖係作成為使原料水流通於空心絲膜内側 之構成准亦可作成為使原料水流通於空心絲膜的外侧、 使氫氣流通於空心絲膜的内側之構成。 ^扒殺菌裝置5中，對已經於氫氣溶解模組4中溶解有 ❹虱氣之原料水（以下，簡稱「氣體溶解水」）照射uv(紫外 線），以使雜菌或微生物等死滅。從Uv殺菌裝置5的下游， 延伸有配管L10而連結於填充裝置6。 於填充裝置6中’將已經於UV殺菌裝置5中殺菌處理 之氣體溶解水，填充於密封容器中加以密封，並實施殺菌 處理。 其次’就本發明之飲料用含氫水之製造方法，以採用 上述製造裝置時為例加以說明。 〇 可於本發明之飲料用含氫水之製造方法使用之原料 水’只要是得自適合於飲料用之水源者即可，並無特別限 定’可例舉：自來水、地下水等。 首先’從配官 L1供給原料水於活性碳槽1. _ ’使原料水 接觸設置於槽内之活性碳，而使原料水中的氯等吸附於活 性碳以進行脫氯處理。 其次，將已經於活性碳槽1中進行脫氯處理之原料水 (脫氯水），從配管L2供給於膜過濾裝置2進行過遽處理， 以去除懸浮物等。 320797 200932687 能調整為5:為過濾膜時，較佳為脫氯水的電導率 1〇〇〇〜αη。如電^S/Cm後再進行過滤，更佳為⑽至 後的水幾乎不含在—町，則由於過滤處理 料用。又，如按2 ηπ屬離子等礦物f成分，不適合作為飲 堝省声棰姓各 ’ 〇"s/cm以上之方式處理時’可能有 之^題。絲去除不充分等情形，以致發生衛生方面 0 . 、吏用R〇膜作為過濾、膜時’由於藉由R0膜之過 :_人飲:連脫氯水中的金屬離子都被rg膜去除，如欲作成 、、'用者較佳為實施過遽處理後添加鈉離子、舒離 子等適合於飲料之金屬離子，藉此，更佳為調整過滤處理 水的電導率為5至2,000# s/cm，特佳為調整為1〇〇至1〇〇〇 #s/cm。或者，亦可不添加金屬離子，而於從後述之氫氣 溶解模組4的原料水流通部4a排出之氣體溶解水中，添加 選自果汁、蔬菜萃取物、可可萃取物、咖啡萃取物、茶萃 ❹ 取物、生藥萃取物、蜂蜜、甜味料、以及乳酸菌中之1種 以上，藉此，即可製造適合於飲料’更具有高嗜好性的含 氫水。 其次，將經由膜過濾裝置2過濾、處理之脫氯水（過滤處 理水）’從配管L3供給於脫氣裝置3 ’同時從配管L4供給 於電解裝置γ。 經配管L3供給於脱氣裝置3之過遽處理水（脫氣水）’ 在此進行脫氣處理，表除過濾處理水中所溶解之氧氣、氮 氣、碳酸氣等。然後，從配管L5供給於氫氣溶解模組4的 12 320797 200932687 原料水流通部、„上 溶解存在於_ #過濾、處理水的脫氣處理，較佳為進行至 屬處理水中之氣體濃度成為 止。由於脫氣處理紐 ^ _為PPm以下為 虱既多篁且翅時間即溶令易 用含氫水。 有政裟每虱虱濃度高的飲料 又從配皆[4供給於電解裝置7之過请 電解為氫氣與氧翁 /慮處理水，在此 ❹ 發生之氯氣供= 然後，將電解裝置7的陰極室h側所 溶解於流經IV:=賴賴4的氫驗通部4b，使其 中。又，於電解驗4的原料水流通部4a之原料水 配管L7抽以的陽極室化侧所發生之氧氣，則從 友友供给於氧氣儲備座等。 於虱氣溶解棋組4足管 流通部4a，同時抑高& S L5供、、、°脫軋水於原料水 壓氫氣流通部4b内己/ L6供給氫氣於氫氣流通部4b以加 内部之結果’氣氣P :於使用虱氣加壓氫氣流通部4b 膜^並溶解心二的二藉由分壓差穿透透氣 則在本發明中，^通部4a之脫氣水中。如此 會溶解之故，可p /水在通過原料水流通部4a時氫氣 氫氣流通部短時間内多量溶解於脫氣水中。 & 2、 争乂佳為1至5kgf(千克力）/cm2。 g cm.以下、，則有時無法使氫氣充分溶解於脫氣 水中。又’如在5kgf/W以上時，則由於需要增高氣氣溶 解模組的各種設備的耐壓性或氣密性之故，經濟上不利。 其次，將經由氫氣溶解模組4使氫氣溶解之原料水（氣 320797 13 200932687 =水:Γυν殺菌装置5照射υνκ使雜菌或微生物 等死滅，然後，使用超渡膜（ultrafilter)等加以過虑 φ 理。並且視需要添加選自果汁、蔬菜萃取物、可可萃取L 咖啡萃取物、茶萃取物、生藥萃取物、蜂蜜、甜味料、、 及乳酸菌中之至少1種以上後，在填充裝置6中填充於以 如使用鋁層合膜等作成之袋狀容器、金屬罐，特佳為具例 嘴子之附喷嘴（SP〇ut)之鋁袋、鋁罐等各種容器中，經二2 後加以殺菌處理，即可製成飲料用含氫水。 雀、 殺菌處理條件，較佳為在65至95〇c實施1〇至加八 鐘。只要在此條件下，即可減少因殺菌處理所引起之^ 的放散，而製得氫濃度更高的飲料用含氫水。 1氣 如採用本發明之飲料用含氲水之製造方法，則可在短 時間内使氫氣溶解於原料水中。又，由於可連續製造故2 產性優異。又’如添加選自果汁、蔬菜萃取物、可可萃取 物、茶萃取物、生藥萃取物、蜂蜜、甜味料、以及乳酸菌 中之至少1種以上，則可作成果汁飲料、咖啡飲料 '可可 飲料、茶飲料、乳酸飲料等嗜好性飲料。 w 斤_再者，在此實施形態中，對氫氣溶解模組4所供给之 虱氣，係採用將原料水加以電解後所產生之氫氣，惟^可 作成不用電解裝置7而配置氫氣高壓瓶等，從氫氡高壓瓶. 對氳氣溶解模組4供給氫氣之方式。 就飲料用含氫水之製造裝置之其他實施形態，參 3圖加以說明。 本製造裝置，係與上述實施形態的製造裝置在基本構 320797 14 200932687 成上為相同者’惟在脫氣裝置3與氫氣溶解模組4之間， 配置有進行脫氣水之電解處理以生成電解酸性水與電解驗 性水之電解裝置8之處不相同。電解裝置8而言，可例舉： 陰極與陽極之間具有離子穿透性的隔膜之隔膜型電解裝置 等。本實施形態，係使用隔膜型電解裝置者。並且，電解 裝置8的陰極室8a(電解驗性水生成側），係連接於氫氣溶 解模組4的原料水流通部4a。又，對電解裝置8的陽極室 8b(電極酸性水生成側），則連接有排水配管（draft pipe) • L11。 其次’就採用此種製造裝置之本發明之飲料用含氫水 之製造方法的其他實施形態加以說明。在此，與上述實施 形態相同之處所，則省略其說明。 本實施形態中，將經由脫氣裝置3脫氣處理之原料水 (脫氣水），分別供給電解裝置8的陰極室8a與陽極室8b， 並在此進行電解處理後，從陽極室8b侧生成電解酸性水、 ©從陰極室8a側生成電解鹼性水。此時，如將供給陰極室 8a之水量’作成較供給陽極室此之量為多時，則可提高 電解驗性水的生成量，使之較電解酸性水的生成量為高。 又’如改變電解裝置8的電解條件，則可適當調整所得電 ^鹼眭水的pH。但’作為飲料水的pH，需要大約在6. 5至 .的範圍之故，如所得之電解鹼性水的Pn過高時，則較 8 原料水或電解酸性水等混合，以調整pH為6. 5至 5…又，如供給電解裝置8之原料水的電導率過低時，則 由於電解處理時的施加電壓或施加電流會增大之故，較佳 15 320797 200932687 為添加鈉離子或鉀離子等以調整電導率為5至2,〇〇〇 s/cm、更佳為調整成為100至l,000 /zS/cm。 u 然後，在電解裝置8所生成之電解鹼性水，供給於氫 氣溶解模組4的原料水流通部4a，從配管L6供給氫氣於 氫氣流通部4b以加壓氫氣流通部4b内部而使氫氣溶解: 再者，在電解裝置8所生成之電解酸性水，可直接排除， 亦可作為洗滌水使用，亦可供給於電氣分解裝置7而作為 . 氣發生源利用。 響 然後，將經由氫氣溶解模組4使氫氣溶解之原料水（氣 體溶解水）’使用UV殺菌裝置5照射UV以使雜菌或微生= 等死滅，然後，使用超濾膜等加以過濾處理。並且，視需 要添加選自果汁、蔬菜萃取物、可可萃取物、咖啡萃取物、 茶萃取物、生藥萃取物、蜂蜜、甜味料、以及乳酸菌中之 至少1種以上後，使用填充裝置6，填充於附噴嘴之鋁袋 或鋁罐等各種容器中，經密封後加以殺菌處理即可製成飲 . 料用含氫水。 如採用本實施形態’由於在電解裝置8進行原料水之 電解處理、並使在此生成之電解鹼性水中含有氫氣之故， 即使不使用藥劑，仍能更降低含氫水的氧化還原電位，而 能製造還原性更高的飲料用含氫水。 【實施方式】 [實施例] 採用第1圖所示之製造裝置、採用第2圖所示之氫氣 溶解模組以製造飲料用含氫水。 320797 16 200932687 按流量10公升/分鐘供給自來水於活性破槽1並實施 脫氯處理。其次，按流量10公升/分鐘供給鎳脫氯處理之 自來水於具備NF濾器之過濾裝置2以實施過濾、處理。此 時，從過濾裝置2所排出之自來水的電導率爲110以s/cm。 其次，使用脫氣裝置3進行經過濾處理之自來水之脫氣處 理’將所溶解存在之氣體濃度作成lppm以下後’從第2圖 所示之氫氣溶解模組的原料水入口 43供給於空心絲内 ❾部，同時從氫氣入口 45供給氫氣於容器41内’使用氫氣 將容器内的壓力加壓為1. 〇kgf/cm2。此時，從氫氣溶解模 組所排出之自來水的氫濃度為2至2. 5ppm。然後’實施UV 殺面，填充於附喷嘴之鋁袋中，經密封後於85°C下加熱殺 菌30分鐘以製造飲料用含氳水。 剛製造後之經填充於附噴嘴之銘袋内之飲料用含氫水 的風濃度’大約為1. 0至1. 5ppm，而每批製品之風濃度並, 無變動’可依生產性良好之方式製造含高濃度氫氣之飲料 〇 用含氫水。 【圖式簡單說明】 第1圖係表示可採用為本發明之飲料用含氫水之製造 方法之飲枓用含氫水之製造裝置之一種實施形態。 第2圖係表示使用空心絲膜作為透氣膜時的氫氣溶解 模組的一例之概略圖。 第3圖係表不可採用為本發明之飲料用含氫水之製造 方法之飲料用含氫水之製造裝置之其他實施形態。 【主要元件符號說明】 320797 17 200932687 1 活性碳槽 2 過濾裝置 3 脫氣裝置 4 氫氣溶解模組 4a 原料水流通部 4b 氫氣流通部 4c 透氣膜 5 殺菌裝置 6 填充裝置 7 電解裝置 7a 陰極室 7b 陽極室 7c 離子交換膜 8 電解裝置 8a 陰極室 8b 陽極室 20 製造裝置 41 容器 42 空心絲膜 43 原料水入口 44 氣體溶解水出口 45 氩氣入口 46 氫氣出口 47 閥 L1至L11配管 18 320797Φ The method for producing hydrogen-containing water for beverages according to the present invention is preferably subjected to electrolytic treatment to produce and electrolyze water before the hydrogen is dissolved in the module, and the obtained electrolyzed water is supplied to the group. The raw material water circulation portion. In the state in which the pH and the redox power are used, the pH of the nitrogen water is increased without using a chemical or the like, and the production of the hydrogen-containing water for the drink containing the moon is high. In the case of (4) the electrolysis state of the lung water, it is possible to produce a beverage having high reductivity == the electrolysis of a part of water using the hydrogen-containing water for the beverage of the present invention (eie gamma: for the implementation of the original仵 Hydrogen pressure is supplied to 320797 200932687 4 in the hydrogen gas circulation portion of the hydrogen dissolving module to dissolve hydrogen gas in the raw material water supplied to the raw material water circulation portion of the hydrogen dissolving module, or to perform electrolysis of water The obtained hydrogen gas is supplied to the nitrogen gas circulation portion of the nitrogen gas dissolution module in a pressurized manner to dissolve the hydrogen gas in the raw material water supplied to the raw material water circulation portion of the hydrogen gas dissolution module. If such a state is employed, the hydrogen gas may be omitted. In the method for producing a hydrogen-containing water for beverages of the present invention, it is preferred to use a hydrogen-containing water for the beverage in the high-pressure hydrogen container or the like. [Effect of the Invention] According to the present invention, nitrogen-containing water for beverages having stable quality can be produced with good productivity. [Best Embodiment of the Invention] It can be used for the hydrogen-containing water for beverages of the present invention. An embodiment of a hydrogen-containing water producing apparatus for beverages according to the manufacturing method will be described with reference to Fig. 1. U This manufacturing apparatus 20 mainly consists of an activated carbon tank 1, a membrane filter 2, and a deaerator (deaerator). 3, a hydrogen gas dissolving module 4, a UV (ultraviolet) sterilizing device 5, and a filling device 6. The dechlorination treatment of the raw material water supplied to the tank is performed in the activated carbon tank 1. (dechlorination). A pipe L1 extending from an external raw material water source is connected to the upstream of the activated carbon tank 1. Further, from the downstream of the activated carbon tank 1, the pipe L2 is extended and connected to the membrane passing device 2° membrane filtering device 2 In the middle, the filtration treatment of the raw material water (hereinafter referred to as "dechlorinated water") in the decarburization treatment 320797 8 200932687 in the activated carbon tank 1 is carried out. In the filtration membrane of the membrane filtration device 2, the nanofiltration is carried out. It is also suitable for use. The R0 film can also be used. From the downstream of the membrane filtration device 2, a pipe L3 is extended and connected to the deaerator 3. Further, the thin tube L3 extends in the middle and is connected to the electrolysis device 7. In the degassing device 3, the degassing device 3 is removed from the oxygen, nitrogen, and carbonic acid degassing devices 3 in the raw material water that has been subjected to the filtration treatment of the crucible filtering device. A two-deposited or membrane degassing device using a gas permeable membrane, etc., and a degassing device, and a pipe L5 connected to a raw material water circulation electrolysis device 7 of a hydrogen dissolving mold (4) to be described later, is subjected to filtration treatment of water and oxygen. . The electrolysis device 7 has a cathode chamber 7a that generates hydrogen gas and a membrane 7c, and electrolyzed water (filtered to 7b, ion exchange supplied to the cathode chamber 7a and the anode chamber 7b. And, that is, from the pipe L4 pole chamber 7a (argon generating side), the hydrogen gas flowing portion 4b of the cathode gas dissolution module 4 of the pipe electrolysis device 7 is extended. Further, the hydrogen chamber 7b (oxygen generating agent), which will be described later, is extended to have an electrolysis device i. 7 anode, etc. SL? and connected to the oxygen reserve seat gas dissolution mold, group 4, is separated by the hydrophobic material thick 4c, and is separated into the raw material water circulation part & The above-described distribution portion 4b is connected to the raw material water distribution portion 4a downstream of the portion 4a. The above-described pipe L6 is connected to the 牝'. The pipe L8 is extended from the raw material 'flow to the hydrogen gas flow portion, and is connected to the UV sterilization system. & 囷 置 。 。 又 又 氢气 氢气 氢气 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 797 The material of the gas permeable membrane 4c may be any one as long as it is hydrophobic, and In particular, a polyfluorene-based resin, an olefin-based resin such as polyethylene or polypropylene or poly 4-decylpentene-1, or a fluorine-containing resin such as polyfluorinated fluoride can be used. The form of the gas permeable membrane 4c of the dissolution module 4 is exemplified by a hollow fiber membrane. ® Fig. 2 shows an example of a helium gas dissolution module using a hollow fiber membrane as the gas permeable membrane 4c. In the inside of the container 41, a hollow fiber membrane 42 made of a gas permeable membrane is disposed. The hollow fiber membrane 42 is formed with a raw material water inlet 43 for introducing raw material water into the hollow fiber membrane, and for discharging the hollow to the outside. The water gas inside the silk film dissolves the water outlet 44. Further, a pipe L5 is connected to the raw material water inlet 43. Further, a pipe L8 is extended from the gas dissolved water outlet 44, and the container 41 is formed: A hydrogen inlet 45 for introducing hydrogen into the interior of the vessel 41 and a hydrogen outlet 46 for discharging hydrogen to the outside of the system are provided. Further, a pipe L6 is connected to the hydrogen inlet 45. Further, a pipe L9 is extended from the hydrogen outlet 46. L9, in order to make it The internal pressure of 41 can be a predetermined pressure and is provided with a valve 47. The valve 47 can be an opening/closing port or a pressure reducing valve, and an impedance (such as a throttle valve), and can be used as long as the gas can be maintained in a pressurized state. The pressure in the container 41 can be controlled to a predetermined value by the control of opening and closing of the valve 47. 10 320797 200932687 That is, in the second figure, the inside of the hollow fiber membrane is the "raw material water flow portion" of the present invention and the container 41 is The space 48 outside the hollow fiber membrane is the "hydrogen flow portion" of the present invention. Here, the second diagram is used to make the raw material water circulate inside the hollow fiber membrane. The outer side of the hollow fiber membrane has a structure in which hydrogen gas flows through the inner side of the hollow fiber membrane. In the sterilizing device 5, raw material water (hereinafter, simply referred to as "gas dissolved water") in which helium gas has been dissolved in the hydrogen gas dissolution module 4 is irradiated with uv (ultraviolet rays) to kill bacteria or microorganisms. A pipe L10 is extended from the downstream of the Uv sterilization device 5 and connected to the filling device 6. In the filling device 6, the gas which has been sterilized in the UV sterilizing device 5 is dissolved in water, filled in a sealed container, sealed, and sterilized. Next, the manufacturing method of the hydrogen-containing water for beverages of the present invention will be described by taking the above-mentioned manufacturing apparatus as an example.原料 The raw material water to be used in the method for producing hydrogen-containing water for beverages of the present invention is not particularly limited as long as it is obtained from a water source suitable for beverages, and may be exemplified by tap water or ground water. First, the raw material water is supplied to the activated carbon tank 1. _ ’, and the raw material water is brought into contact with the activated carbon provided in the tank, and chlorine or the like in the raw material water is adsorbed to the activated carbon to perform dechlorination treatment. Then, the raw material water (dechlorinated water) which has been subjected to dechlorination treatment in the activated carbon tank 1 is supplied to the membrane filtration device 2 from the pipe L2 to be subjected to a ruthenium treatment to remove suspended matter or the like. 320797 200932687 It can be adjusted to 5: for the filter membrane, the conductivity of dechlorinated water is preferably 1〇〇〇~αη. If it is filtered after electricity ^S/Cm, it is more preferable that the water after (10) is almost not contained in the town, and it is used for filtration treatment. In addition, if the mineral f component such as 2 ηπ genus ions is not suitable as a treatment for the 棰 quot quot quot quot quot quot s s s s s s s s s s s s s ’ ’ ’ ’ ’ ’ ’ ’ ’ ’. Insufficient removal of silk, etc., resulting in hygiene. 0. When using R〇 film as filtration, when film is used, because of the R0 film: _ people drink: even the metal ions in the dechlorinated water are removed by the rg film. If it is desired to use, it is preferable to add sodium ions and sulphur ions to the metal ions of the beverage after the treatment, and it is more preferable to adjust the conductivity of the filtered water to 5 to 2,000 # s/ Cm, especially good for adjustment from 1〇〇 to 1〇〇〇#s/cm. Alternatively, it is also possible to add, in the gas-dissolved water discharged from the raw material water-passing portion 4a of the hydrogen-dissolving module 4 to be described later, to the gas-dissolved water discharged from the raw material water-distributing portion 4a of the hydrogen-dissolving module 4 to be described later, and to be selected from the group consisting of fruit juice, vegetable extract, cocoa extract, coffee extract, One or more of the extract, the crude drug extract, the honey, the sweetener, and the lactic acid bacteria can be used to produce a hydrogen-containing water suitable for the beverage to have a higher taste. Then, the dechlorinated water (filtered water) filtered and treated by the membrane filtration device 2 is supplied from the pipe L3 to the deaerator 3' while being supplied to the electrolysis device γ from the pipe L4. The treated water (degassed water) supplied to the deaerator 3 via the pipe L3 is subjected to a degassing treatment to remove oxygen, nitrogen, carbonic acid gas or the like dissolved in the filtered treated water. Then, it is supplied from the pipe L5 to the 12 320797 200932687 raw material water circulation portion of the hydrogen gas dissolution module 4, and the degassing treatment in which the upper solution is dissolved in the _#filtration and treated water, preferably the gas concentration in the treated water is changed. Since the degassing treatment ^ is _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ After electrolysis, it is hydrogen and oxygen/treated water, and chlorine gas is generated in this case. Then, the cathode chamber h side of the electrolysis device 7 is dissolved in the hydrogen detecting portion 4b flowing through IV:=Lailai 4, In addition, the oxygen generated on the anode compartment side of the raw material water pipe L7 of the raw material water circulation part 4a of the electrolysis test 4 is supplied from the friend to the oxygen reserve seat, etc. The foot tube circulation portion 4a simultaneously suppresses the high & S L5 supply, and the ° de-rolling water in the raw material water pressure hydrogen gas flow portion 4b to supply hydrogen gas to the hydrogen gas flow portion 4b to add internal results. Pressurizing the hydrogen gas circulation portion 4b with helium gas and dissolving the core 2 by means of partial pressure difference In the present invention, the degassed water of the passage portion 4a is so dissolved that the hydrogen/hydrogen flow portion of the hydrogen/hydrogen flow portion can be dissolved in the deaerated water in a short time when passing through the raw material water circulation portion 4a. 2, the competition is preferably 1 to 5kgf (kilogram force) / cm2. g cm. below, sometimes it is impossible to fully dissolve hydrogen in degassed water. Also, if it is above 5kgf/W, it needs to be increased The pressure resistance or airtightness of various equipments of the gas-dissolving module is economically disadvantageous. Secondly, the raw material water which dissolves hydrogen through the hydrogen dissolution module 4 (gas 320797 13 200932687 = water: Γυ 杀菌 sterilizing device 5 Irradiation of υνκ to kill bacteria or microorganisms, and then using ultrafilter or the like to treat it, and optionally adding juice, vegetable extract, cocoa extract L coffee extract, tea extract, crude drug After at least one of the extract, the honey, the sweetener, and the lactic acid bacteria, the filling device 6 is filled in a bag-shaped container or a metal can made of, for example, an aluminum laminate film, and is preferably a mouthpiece. Attached nozzle (SP〇ut) In various containers such as bags and aluminum cans, after sterilizing treatment, the hydrogen-containing water for beverages can be prepared. The conditions for sterilization and sterilization are preferably from 1 to 8 in the range of 65 to 95 °c. Under these conditions, it is possible to reduce the dispersion caused by the sterilization treatment, and to obtain a hydrogen-containing water for beverages having a higher hydrogen concentration. 1 Gas If the method for producing a beverage containing water according to the present invention is used, Hydrogen can be dissolved in raw water in a short period of time. Moreover, it can be continuously produced because of its high productivity. It can also be selected from juices, vegetable extracts, cocoa extracts, tea extracts, crude extracts, honey, and At least one of the sweetener and the lactic acid bacteria can be used as a hobby beverage such as a juice drink or a coffee drink, a cocoa drink, a tea drink, or a lactic acid drink. w kg_ Further, in this embodiment, the helium gas supplied to the hydrogen dissolution module 4 is hydrogen gas generated by electrolyzing the raw material water, but can be configured to dispose the hydrogen high pressure bottle without using the electrolysis device 7. Etc., from the hydroquinone high pressure bottle. The method of supplying hydrogen to the helium gas dissolution module 4. Another embodiment of a manufacturing apparatus for hydrogenated water for beverages will be described with reference to the drawings. The manufacturing apparatus is the same as the manufacturing apparatus of the above-described embodiment in the basic configuration 320797 14 200932687. However, between the deaerator 3 and the hydrogen dissolution module 4, electrolytic treatment for degassing water is disposed to generate The electrolytic acid water is different from the electrolysis device 8 for electrolyzing water. The electrolysis device 8 may, for example, be a diaphragm type electrolysis device having a separator having an ion permeability between a cathode and an anode. In the present embodiment, a separator type electrolysis device is used. Further, the cathode chamber 8a (electrolytic water generation side) of the electrolysis device 8 is connected to the raw material water circulation portion 4a of the hydrogen gas dissolution module 4. Further, a drain pipe (L11) is connected to the anode chamber 8b (electrode acidic water generating side) of the electrolysis device 8. Next, another embodiment of the method for producing hydrogenated water for beverages of the present invention using such a manufacturing apparatus will be described. Here, the description of the same points as those of the above embodiment will be omitted. In the present embodiment, the raw material water (degassed water) degassed by the deaerator 3 is supplied to the cathode chamber 8a and the anode chamber 8b of the electrolysis device 8, respectively, and subjected to electrolytic treatment, and then from the anode chamber 8b side. Electrolyzed acidic water is generated, and electrolytic alkaline water is generated from the cathode chamber 8a side. At this time, if the amount of water supplied to the cathode chamber 8a is made larger than the amount supplied to the anode chamber, the amount of generated electrolytic water can be increased to be higher than the amount of electrolytic acidic water produced. Further, if the electrolysis conditions of the electrolysis device 8 are changed, the pH of the obtained electrolyzed hydrophobic water can be appropriately adjusted. However, as the pH of the beverage water, it is required to be in the range of about 6.5 to. If the Pn of the obtained electrolytic alkaline water is too high, it is mixed with 8 raw material water or electrolytic acidic water to adjust the pH to 6. 5 to 5... Further, if the conductivity of the raw material water supplied to the electrolysis device 8 is too low, since the applied voltage or the applied current during the electrolysis treatment is increased, it is preferable to add sodium ions or 15 320797 200932687 or The potassium ion or the like is adjusted to have an electric conductivity of 5 to 2, 〇〇〇s/cm, more preferably 100 to 1,000 / zS/cm. Then, the electrolytic alkaline water generated in the electrolysis device 8 is supplied to the raw material water circulation portion 4a of the hydrogen gas dissolution module 4, and hydrogen gas is supplied from the pipe L6 to the hydrogen gas flow portion 4b to pressurize the inside of the hydrogen gas flow portion 4b to hydrogen gas. Dissolving: Further, the electrolytic acidic water generated in the electrolysis device 8 can be directly removed, used as washing water, or supplied to the electric decomposition device 7 to be used as an air generating source. Then, the raw material water (gas dissolved water) which dissolves hydrogen gas through the hydrogen dissolution module 4 is irradiated with UV by the UV sterilizing device 5 to cause the bacteria or the microbes to be quenched, and then filtered by using an ultrafiltration membrane or the like. . Further, if at least one selected from the group consisting of fruit juice, vegetable extract, cocoa extract, coffee extract, tea extract, crude drug extract, honey, sweetener, and lactic acid bacteria is added as needed, the filling device 6 is used. Filled in various containers such as aluminum bags or aluminum cans with nozzles, sealed and sterilized to make a drink. According to the present embodiment, since the electrolysis device 8 performs electrolytic treatment of the raw material water and contains hydrogen gas in the electrolytic alkaline water produced therein, the oxidation-reduction potential of the hydrogen-containing water can be further reduced even without using the chemical. It is also possible to produce hydrogenated water for beverages having higher reducibility. [Embodiment] [Examples] Hydrogen-containing water for beverages was produced by using the manufacturing apparatus shown in Fig. 1 and using the hydrogen dissolving module shown in Fig. 2 . 320797 16 200932687 Supply tap water to the active tank 1 at a flow rate of 10 liters/min and carry out dechlorination treatment. Next, the nickel dechlorination tap water was supplied to the filtration apparatus 2 equipped with the NF filter at a flow rate of 10 liters/min to carry out filtration and treatment. At this time, the conductivity of the tap water discharged from the filtration device 2 was 110 s/cm. Next, the degassing treatment of the filtered water by the deaerator 3 is performed, and after the concentration of the dissolved gas is made 1 ppm or less, the raw material water inlet 43 of the hydrogen dissolving module shown in Fig. 2 is supplied to the hollow fiber. At the same time, the hydrogen is supplied from the hydrogen inlet 45 to the vessel 41. The pressure in the vessel is pressurized to 1. 〇kgf/cm2 using hydrogen gas. 5ppm。 The hydrogen concentration of the tap water from the hydrogen dissolution mode is 2 to 2. 5ppm. Then, the UV killing surface was applied, filled in an aluminum bag with a nozzle, sealed, and sterilized by heating at 85 ° C for 30 minutes to produce a hydrazine-containing water for beverage. Immediately after manufacture, the wind concentration of the hydrogenated water filled in the mouth bag with the nozzle is about 1.0 to 1.5 ppm, and the wind concentration of each batch of the product is unchanged, which is good in productivity. In the manner of producing a beverage containing a high concentration of hydrogen, hydrogen-containing water is used. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a view showing an embodiment of a manufacturing apparatus for hydrogenated water for beverages which can be used as a method for producing hydrogenated water for beverages of the present invention. Fig. 2 is a schematic view showing an example of a hydrogen gas dissolution module when a hollow fiber membrane is used as a gas permeable membrane. Fig. 3 is a view showing another embodiment of the apparatus for producing hydrogenated water for beverages which is a method for producing hydrogenated water for beverages of the present invention. [Main component symbol description] 320797 17 200932687 1 Activated carbon tank 2 Filter device 3 Deaerator 4 Hydrogen dissolution module 4a Raw material water circulation part 4b Hydrogen flow part 4c Gas permeable membrane 5 Sterilization device 6 Filling device 7 Electrolytic device 7a Cathode chamber 7b Anode chamber 7c Ion exchange membrane 8 Electrolyzer 8a Cathode chamber 8b Anode chamber 20 Manufacturing device 41 Container 42 Hollow fiber membrane 43 Raw material water inlet 44 Gas dissolved water outlet 45 Argon inlet 46 Hydrogen outlet 47 Valve L1 to L11 piping 18 320797

Claims (1)

200932687 七、申請專利範圍： 1. 一種飲料用含氫水之製造方法，其特徵為：將原料水供 給於藉由疏水性材料所成之透氣膜區隔為原料水流通 部與氫氣流通部之氫氣溶解模組的前述原料水流通 部，同時於前述氫氣溶解模組的前述氫氣流通部供給經 加壓之氫氣，使氫氣溶解於前述原料水中，並將從前述 氫氣溶解模組的前述原料水流通部所排出之溶解有^ 〇 氣之原料水填充於容器内後加以密封並實施殺菌處理。 2. 如申請專利範圍第1項之飲料用含氯水之製造方法，其 中，作為供給該氫氣溶解模組的該原料水流通部之該原 料水，係使用含有金屬離子者。 3. 如申請專利範圍第1項或第2項之飲料用含氫水之製造 :法，其中，在將該原料水供給於該氫氣溶解模組之 則，通水於奈米過濾器中以調整電導率為5至2, 000 “ s/cm 者。 © 1如申請專利範圍第i項或第2項之飲料用含氫水之製造 :法其中，在將該原料水供給於該氫氣溶解模組之 剧通水於RO膜，接著添加金屬離子以調整電導率為 5 至 2, 000 // s/cm 者。 5.如申請專利範圍第丨項之飲料用含氫水之製造方法，其 中，使用經通水於奈米過濾器或R〇膜者作為該原料 尺於從該氫氧溶解模組的該原料水流通部所排出之溶 解有氫氣之原料水中，添加選自料、蔬菜萃取物、可 可萃取物、咖啡萃取物、茶萃取物、生藥萃取物、蜂蜜、 19 320797 200932687 甜味料、以及乳酸菌中之1種以上者。 6. 如申請專利範圍第1項至第5項中任一項之飲料用含氫 水之製造方法，其中，在將該原料水供給於該氫氣溶解 模組之前，實施脫氣處理者。 7. 如申請專利範圍第1項至第6項中任一項之飲料用含氳 水之製造方法，其中，在將該原料水供給於該氫氣溶解 模組之前，實施電解處理以生成電解酸性水及電解鹼性 水，並將所得電解鹼性水供給於該氫氣溶解模組的該原 料水流通部者。 8. 如申請專利範圍第7項之飲料用含氫水之製造方法，其 中，該電解處理，係在該原料水之脫氣處理後實施者。 9. 如申請專利範圍第1項至第8項中任一項之飲料用含氫 水之製造方法，其中，實施一部分原料水之電解，將所 得氫氣加壓供給於該氫氣溶解模組的該氳氣流通部，使 氳氣溶解於經供給於氫氣溶解模組的該原料水流通部 之該原料水中者。 10. 如申請專利範圍第1項至第8項中任一項之飲料用含氫 水之製造方法，其中，實施水之電解，將所得氫氣加壓 供給於該氫氣溶解模組的該氳氣流通部，使氫氣溶解於 經供給於氫氣溶解模組的該原料水流通部之該原料水 中者。 11. 如申請專利範圍第1項至第10項中任一項之飲料用含 氫水之製造方法，其中，該飲料用含氫水為嗜好性飲料 者。 20 320797200932687 VII. Patent application scope: 1. A method for producing hydrogen-containing water for beverages, characterized in that raw material water is supplied to a gas-permeable membrane partition formed by a hydrophobic material as a raw material water circulation portion and a hydrogen gas circulation portion. a raw material water circulation portion of the hydrogen gas dissolution module, and simultaneously supplying pressurized hydrogen gas to the hydrogen gas flow portion of the hydrogen gas dissolution module to dissolve hydrogen gas in the raw material water, and dissolving the raw material water from the hydrogen gas dissolution module The raw material water discharged from the circulation portion and filled with helium gas is filled in the container, sealed, and sterilized. 2. The method for producing a chlorine-containing water for beverages according to the first aspect of the invention, wherein the raw material water to be supplied to the raw material water circulation portion of the hydrogen-dissolving module is a metal ion-containing material. 3. The method of manufacturing a hydrogenated water for beverages according to claim 1 or 2, wherein the raw material water is supplied to the hydrogen dissolving module, and the water is passed through the nano filter. Adjusting the conductivity to 5 to 2,000 s/cm. © 1 For the manufacture of hydrogenated water for beverages according to item i or item 2 of the patent application: wherein the raw material water is supplied to the hydrogen to dissolve The module is flooded with water on the RO membrane, followed by the addition of metal ions to adjust the conductivity to 5 to 2,000 // s/cm. 5. The method for producing hydrogenated water for beverages according to the scope of the patent application, In the raw material water in which hydrogen gas is discharged from the raw material water circulation portion of the oxyhydrolysis module, the raw material is passed through a water filter or a R 〇 film, and the selected material and vegetables are added. Extract, cocoa extract, coffee extract, tea extract, crude drug extract, honey, 19 320797 200932687 sweetener, and more than one of lactic acid bacteria. 6. If you apply for patent scopes 1 to 5 a method for producing hydrogenated water for beverages according to any one of them, wherein The raw material water is supplied to the hydrogen dissolving module, and the degassing process is performed. 7. The method for producing a water-containing beverage for beverage according to any one of claims 1 to 6, wherein the raw material is Before the water is supplied to the hydrogen dissolution module, electrolytic treatment is performed to generate electrolytic acidic water and electrolytic alkaline water, and the obtained electrolytic alkaline water is supplied to the raw material water circulation portion of the hydrogen dissolution module. The method for producing hydrogenated water for beverages according to the seventh aspect of the invention, wherein the electrolytic treatment is carried out after the degassing treatment of the raw material water. 9. If any one of claims 1 to 8 is applied for. The method for producing a hydrogen-containing water for beverages, wherein a part of the raw material water is electrolyzed, and the obtained hydrogen gas is pressurized and supplied to the gas flow passage portion of the hydrogen dissolution module, so that the helium gas is dissolved in the hydrogen dissolution mold. The method for producing a hydrogen-containing water for beverages according to any one of claims 1 to 8, wherein the electrolysis of water is performed, and the obtained hydrogen is obtained. Pressurize The gas flow passage portion of the hydrogen dissolving module is supplied to dissolve the hydrogen gas in the raw material water supplied to the raw material water circulation portion of the hydrogen dissolving module. 11. Patent Application No. 1 to 10 The method for producing hydrogenated water for beverages according to any of the preceding claims, wherein the beverage containing hydrogen water is a hobby beverage. 20 320797
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