TW200920690A - Novel method for releasing chlorine dioxide gas - Google Patents

Novel method for releasing chlorine dioxide gas Download PDF

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TW200920690A
TW200920690A TW96141193A TW96141193A TW200920690A TW 200920690 A TW200920690 A TW 200920690A TW 96141193 A TW96141193 A TW 96141193A TW 96141193 A TW96141193 A TW 96141193A TW 200920690 A TW200920690 A TW 200920690A
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Taiwan
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carrier
layer
agent
fine particle
type
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TW96141193A
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Chinese (zh)
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Jian-Yi Huang
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Ji Yi Bi Biochemical Technology Co Ltd
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Priority to TW96141193A priority Critical patent/TW200920690A/en
Publication of TW200920690A publication Critical patent/TW200920690A/en

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Abstract

This invention provides a novel method for releasing chlorine dioxide gas. Chlorine dioxide is synthesized from a master agent, which is obtained by mixing at least one or several components such as sodium chlorite, ammonium chlorite, lithium chlorite, and potassium chlorite; a sub-agent, which is obtained by mixing at least one or several components such as ammonium persulfate, lithium persulfate, potassium persulfate, and sodium persulfate; and carriers, including a first carrier selected from kaolin, zeolite powder, water containing clay, calcination clay, acidified clay, acidified calcined clay, salts, solid acid, organic acid anhydride and composition thereof, or a second carrier applying the water absorbing materials such as foams, sponges, clothes, nonwoven fabric, papers, and fibers, or a third carrier composed of double faced tapes or a Velcro tape (the upper layer is non-adhesive, and the lower layer is adhesive) to form fine grains (or particles). The grains then are packed into a packaging bag, which is composed of waterproof and ventilation materials, based upon a predetermined ratio. While in use, the packaging bag is opened so that the grains can absorb moisture within air under the room temperature or can generate a chemical reaction by adding proper water to release chlorine dioxide gas with slow action speed. Durable disinfection and sterilization functions can be therefore achieved to increase more safety in use.

Description

200920690 九、發明說明: ’【發明所屬之技術領域】 本發明係關於一種新式二氧化氯氣體之釋放方法,宜 主要將合成二氧化氯必備之主劑及副劑選擇搭配第一載體 $第二載體或第三載體混合製成細粒(或微粒),再依預 定比例包裝於防水透氣之包裝袋中^ m 士 門,蚀π 使用時將此包裝袋打 開 使其传以在一般的官ti® ϊΙΛ* 朴 町至/皿吸收空虱中之濕氣或加入適量 7氣Γ 化學Ϊ應’以和緩的作用迷度釋出二氧化氯 耽體,達到長效之消毒殺菌功能’使其在使用上更為安全 者。 【先前技術】 生組氯是一種綠色消毒劑’其安全性被世界衛 俨,:級’其係-種具有氯氣相似的刺激性氣味 、:,點為llc’常溫下在水中的溶解度為2.9 忌/ L ’其有效氯為氣翁的. 4仆劍A 3 3 % ’但它卻是一種高效 氧化劑’而不是氯化劑’它的氧化能力是氯氣的2.5倍 〇 且右氣對微生物的殺菌理由為:二氧化氯對細胞壁 ^吸附和穿透能力’可有效地氧化細胞内含疏基 :可:快速二抑制微生物蛋白質的合成來破壞微生物 4 一氧化氯除對一般細菌有殺死作用外,對芽孢、 ,轉你ί類、鐵細菌、硫酸鹽還原菌和真菌等均有很好的 溫度越高’二氧化氯的殺菌效力越大,這非常 “為工業迴流水以及溫度偏高領域的殺菌劑。 200920690 再者’因為二氧化氯不會形成不良副產品(如:氯胺 或氯化有機化合物),是以人類接觸低濃度的二氧化氯氣 體,通常被視為安全的,但當其濃度大於丄〇 〇 ◦ p P 時’則二氧化氣對人類而言,係具有毒性的,可能造成人 體健康的危害,且二氧化氯的濃度在約〇 .工大氣壓以上 ’可能會產生料的危險H般之二氧化氣係未在壓 力下製造及裝運’無形中限制了其使用之便利性與運輸成 本’尤其是其製造上不僅需要昂貴的生產設備,且需仰賴 操作員的經驗與技巧來游& $ Λ A Μ /、议,木避免產生危險的高濃度,故此種方 式僅適用於大量之商業料,並不適用於-般之殺菌消毒 用途。 為解決一般性之使用需求,目前市面可見的溶液、粉 H片劑等二氧化氯殺㈣毒產品,在使用時均需加入活 匕劑進饤/¾•化,才能釋放出具有強烈殺菌能力之二氣化氯200920690 IX. Description of the invention: '[Technical field to which the invention belongs] The present invention relates to a new method for releasing chlorine dioxide gas, which is mainly suitable for selecting the main carrier and the auxiliary agent for synthesizing chlorine dioxide, and matching the first carrier with the second carrier. The carrier or the third carrier is mixed to form fine particles (or fine particles), and then packaged in a waterproof and breathable packaging bag according to a predetermined ratio. The etched π is used to open the package to make it pass in the general official ti ® ϊΙΛ* 朴町至/ dish absorbs the moisture in the open space or adds an appropriate amount of 7 gas Γ Ϊ ' ' 以 以 以 以 以 和 和 和 和 和 和 和 和 和 和 和 和 和 释 释 释 释 释 释 释 释 释 释 释 释 释 释 释 释 释 释More secure to use. [Prior Art] Biochemical chlorine is a green disinfectant's safety is defended by the world, the grade 'the strain' has a pungent odor similar to chlorine, and the point is 'llc'. The solubility in water is 2.9 at room temperature. Avoid / L 'its effective chlorine is gas. 4 servant A 3 3 % 'but it is a highly efficient oxidant 'instead of chlorinating agent' its oxidizing power is 2.5 times that of chlorine and right gas to microorganisms The reason for sterilization is: the ability of chlorine dioxide to adsorb and penetrate cell walls can effectively oxidize cell-containing sulphate: can: quickly inhibit the synthesis of microbial proteins to destroy microorganisms 4, chlorine dioxide, in addition to killing common bacteria In addition, the spores, the transfer of your genus, iron bacteria, sulfate-reducing bacteria and fungi have a very good temperature. The more bactericidal effect of chlorine dioxide, the more "for industrial return water and high temperature In the field of fungicides 200920690 Furthermore, because chlorine dioxide does not form undesirable by-products (such as chloramines or chlorinated organic compounds), it is generally considered safe by human exposure to low concentrations of chlorine dioxide gas. However, when the concentration is greater than 丄〇〇◦ p P, then the dioxide gas is toxic to humans, which may cause harm to human health, and the concentration of chlorine dioxide is above about 工. Hazard of material production H-like oxidizing gas system is not manufactured and shipped under pressure 'invisibly limits the convenience and transportation cost of its use', especially its manufacture requires not only expensive production equipment, but also depends on the operator. Experience and skill to swim & $ Λ A Μ /, discussion, wood to avoid dangerous high concentrations, so this method is only suitable for a large number of commercial materials, not suitable for general sterilization purposes. To solve the general The use of the demand, the current market visible solutions, powder H tablets and other chlorine dioxide to kill (four) toxic products, the use of live cockroaches in the use of 饤 饤 / / / / / / / / / / / / / / / / / / / / / / / /

Hb類產品因其劑型的差異,在運輸及貯存及使用上, :曰遍存在有安全性方面的問題,以溶液型產品而言,其 敢大的問題便是運輸極為不便’且當其液體含量超過一定 。又㉛必/頁按危險物品標準方式運冑,而粉劑或片劑產 品’因其原料本身具有強氧化性’與可燃性物質接觸或與 Γ物質混合即會發生爆炸、燃燒,而活化劑就是酸性物 貝’ f此除了必須依危險物品標準運輸夕卜,在纟使用時更 需疋的程序加入定量的水,或先將劑料與水混合後再推 入活化劑’否則即有爆炸、燃燒之問題,相當不安全,實 有待設法加以解決改善者。 200920690 【發明内容】 有鑑於現有二氧化惠细制 ,仍有未盡完善之缺失;=及劑料儲存、運輸方面 從事相關行業之多年經驗:技:特者手進行研發,基於其 氧化氯氣體釋放方法,即宜主 月之一 二且,, 即其主要目的乃在於提供一種安全 而長效之二氧化氯釋放方法, 文王 二氧化氯使用需求者。 < 、本發月之另目的係在於經由劑料之組製型態與包裝 方式設計’不但得以使其運輸及貯存上更為安全,同時在 使用的安全性方面亦可獲得顯著提昇者。 為達前揭目的,本發明於士Λ 士+ ^ 个赞a於°又汁上,其主要將合成二氧 :氯必備之主d及副劑選擇搭配第一載體或第二載體或第 三载體混合f成細Ή或微粒),再依預定比例包裝於防 κ透氣之包裝衣中’使用時將此包裝袋打開,使其得以在 -般的室溫吸收空氣中之濕氣或加入適量水份使其產生化 學反應’以和緩的作用速度釋出二氧化氯氣體,達到長效 之消毒殺菌功能,使其在使用上更為安全者。 【實施方式】 有關本發明製備方法、技術手段及功效達成方面,謹 再加以說明於后: 本發明在合成二氧化氯殺菌消毒劑所需的劑料,主要 包括: 主劑(A),係由以下一種或數種成份混合而成:至 氣酸鈉、亞氣酸銨、亞氯酸鋰、亞氯酸鉀; 200920690 副劑(B ),係由以下一種或數種成份混合而成:過 硫酸銨、過硫酸鋰、過硫酸鉀、過硫酸鈉; 第一載體(C):係選自南嶺土、沸石粉、含水黏土 、煅燒的黏土、酸化的黏土、酸化的烺燒黏土、鹽類、固 體酸、有機酸酐以及它們的合成物; 第二載體(D ):泡綿、海綿、布料、不織布、紙張 、纖維之吸水材質等合成二氧化氯載體混合製成細粒(或 微粒)。 第三載體(E):雙面貼紙或魔鬼氈(上層為無膠層 ’下層為有膠層)。 本發明乃嘗試將主劑(A )、副劑(b )、第一載體 (C )、第二載體(D )、第三載體(E)等五種劑料採 用數種方式製成細粒(或微粒),藉以簡化其包裝型態’ 大概有以下方案: ~ 第一方案:係將主劑(A )與第—載體(c )粉碎化 後,同步喷入造粒機中,使主劑(A )與第一載體(c) 組成一細粒(或微粒)型態,製成如第一圖所示。 第二方案:係將副齊“ B)與第-載體(C)粉碎化 後,同步喷入造粒機中,使副劑(B)與第一載體(c) 組成一細粒(或微粒)型態,製成如第二圖所示。 第三方案:係將主劑(A)與第一載體(c)粉碎化 後,同步喷入造粒機中,使主劑(A)與第一載體 組成一細粒(或微粒)型態,再將副冑(B)與第一載體 (C)粉碎化後,$步噴人造粒機中,使副劑(b〉血第 200920690 一載體(c)組成另一細粒(或微粒)塑態’製成如第三 圖所示。 第四方案:係將主劑(A )與第二載體(D )粉碎化 後’同步喷入造粒機中,使主劑(A )與第二载體(D ) 組成一細粒(或微粒)塑態,製成如第四圖所示。 第五方案:係將副劑(B )與第二載體(D )粉碎化 後,同步嘴入造粒機中,使副劑(B )與第二载體(D ) 組成一細粒(或微粒)塑態,製成如第五圖所示。 第六方案:係將主劑(A)與第二載體(D)粉碎化 後,同步噴入造粒機中,使主劑(A)與第二載體(D) 組成一細粒(或微粒)变態’再將副劑(B )與第二載體 (D )粉碎化後,同步喷入造粒機中,使副劑(b )與第 二載體(D )組成另一細粒(或微粒)型態,製成如 圖所示。 & 第七方案:係將主劑(A )與第一載體(c )粉碎 後同步噴入造粒機中,使主劑(a)與第一载體 組成一細粒(或微粒)型態,再將副劑(B )與第一 (C )粉碎化後,同步喷入造粒機中,使副劑(b )與= 載體(C )組成另一細粒(或微粒)型態,在一处;; 包裝主劑(A)與第一載體(c)、副劑(B)與;二: 體(C),製成如第七圖所示。 方案.係將主劑(A )粉碎化後喷入造粒機 使主劑(A )組成一細粒(或微粒)⑽態,再將第’ (C)與第二載體(D)粉碎化後,同步喷人造粒機= 9 200920690 使第一載體(C )與第二載體(d )與主劑(A )組成另 一細粒(或微粒)包覆型態,又將副劑(B )粉碎化後噴 入造粒機中,最後使副劑(B )第—載體(c )與第二載 體(D )與主劑(A )組成另一細粒(或微粒)包覆型態 ,製成如第八圖所示。 第九方案:係將副劑(B )粉碎化後喷入造粒機中, 使副劑(B )組成一細粒(或微粒)型態,再將第一載體 (C)與第一載體(d)粉碎化後,同步喷入造粒機中, 使第-載體(C )與第二載體(D )肖副劑(B )組成另 一細粒(或微粒)包覆型態,又將主劑(A )粉碎化後喷 入造粒機中,最後使主劑(A)與第一載體(c)與第二 載體(D )與田ij劑(b )組成另一細粒(或微粒)包覆型 態’製成如第九圖所示。 .第十方案.係將主劑(A )粉碎化後噴入附著於第二 載體(D )上’再將副齊丨(B )粉碎化後噴入附著於第二 載體(D)上’在—空間中包裝主劑(a)與第二載體( D)、副劑(B)肖第二載體⑶),製成如第十圖所示 第十一方案:係將主劑(A)粉碎化置於下層 二化後置於主劑A之上端即中層位置: 取=一:體(c)置於副劑(b)之上端即上層位, 副劑第(:)、主劑(A) ’製成如第十-圖= 方案:係將副劑(B)粉碎化置於下層,再網 10 200920690 主劑(A )粉碎化後置於副劑(B )之上端即中層位置, 最後將第—載體(C )置於主劑(A )之上端即上層位置 ,而成為三層組合型態在一空間中包裝第一載體(c)、 主劑(A )副劑(B ),製成如第十二圖所示。 …第十三方案:係將第三載體(E)(雙面貼紙或魔鬼 氈.上層為無膠層,下層為有膠層)置於底層處,再將主 劑(A)粉碎化後喷入附著於第二載體(D)(布料:有 微小細孔)即為下層,此下層放置在底層上端,另置 二載體(D)(不織布:具隔離作用)即為中層,此中層 置於下層上端’又將副齊,丨(B )粉碎化後噴入附著於第: (布料:有微小細孔)即為上層,此上層^ =端,即完成四層組合型態在一空間中包裝第三载體 s,丨劑((A )與第二载體(D )、第二載體(D ) 。 。 一载體(D)成袋,如第十三圖所示者 範層係二(E)(雙面貼紙_ 劑(B )於磁 9 ^ a )置於底層處,再將副 微小細孔;即為;載體⑼)(布料:有 二離作用)即為",此中層 載體…(布料:右:)粉碎化後喷入附著於第二 中層上端,即完成四::孔)即為上層’此上層置於 ⑴、副劑合型態在一空間中包裝第三載體 ,、第一載體(D)、第二載體(D) 200920690 主劑(A )與第 體(D)成袋,如第十 四圖所示者Due to the difference in dosage form, Hb products are used in transportation, storage and use. There are safety problems in the whole process. In the case of solution type products, the problem is that transportation is extremely inconvenient and when it is liquid The content exceeds a certain level. 31 must/page is transported according to the standard method of dangerous goods, and the powder or tablet product 'because its raw material itself has strong oxidizing property' is in contact with flammable substances or mixed with cerium material, it will explode and burn, and the activator is Acidic shellfish 'f This must be transported according to the standard of dangerous goods. When using it, it is more necessary to add a certain amount of water to the procedure, or to mix the agent with water and then push the activator. Otherwise, there will be an explosion. The problem of burning is quite unsafe and there is a need to try to solve the improvement. 200920690 [Summary of the Invention] In view of the existing dioxide dioxide fine system, there are still some imperfections; = and years of experience in the relevant industries in the storage and transportation of pharmaceutical materials: technology: special research and development, based on its chlorine oxide gas The release method, which is one of the main months, is to provide a safe and long-lasting chlorine dioxide release method. < The other purpose of this month is to design the packaging type and packaging method by the agent' not only to make it safer to transport and store, but also to achieve significant improvement in the safety of use. In order to achieve the goal, the present invention is applied to the first carrier or the second carrier or the third agent, which is mainly used for synthesizing dioxine: chlorine. The carrier is mixed with fine particles or fine particles, and then packaged in a packaging package for preventing κ breathability in a predetermined ratio. When the container is used, the package is opened to absorb the moisture in the air at a general room temperature or to be added. The right amount of water makes it chemically reacted to release chlorine dioxide gas at a slow rate of action, achieving a long-lasting disinfection and sterilization function, making it safer to use. [Embodiment] Related to the preparation method, technical means and efficacy of the present invention, it will be further described later: The agent material for synthesizing chlorine dioxide disinfectant of the present invention mainly includes: main agent (A), It is prepared by mixing one or more of the following components: sodium sulphate, ammonium sulfite, lithium chlorite, potassium chlorite; 200920690 a secondary agent (B), which is a mixture of one or more of the following components: persulfuric acid Ammonium, lithium persulfate, potassium persulfate, sodium persulfate; first carrier (C): selected from the group consisting of kaolin, zeolite powder, aqueous clay, calcined clay, acidified clay, acidified smoldering clay, salt The solid carrier, the organic acid anhydride, and the composite thereof; the second carrier (D): a synthetic chlorine dioxide carrier such as foam, sponge, cloth, non-woven fabric, paper, and water absorbing material of the fiber is mixed to form fine particles (or fine particles). The third carrier (E): a double-sided sticker or a devil's felt (the upper layer is a non-adhesive layer) and the lower layer is a rubber layer. The invention attempts to prepare five kinds of materials, such as main agent (A), auxiliary agent (b), first carrier (C), second carrier (D) and third carrier (E), into fine particles by several methods. (or microparticles), in order to simplify its packaging type' There are probably the following schemes: ~ The first scheme: after the main agent (A) and the carrier (c) are pulverized, they are simultaneously sprayed into the granulator to make the main The agent (A) and the first carrier (c) constitute a fine particle (or fine particle) type, and are formed as shown in the first figure. The second scheme: pulverizing the secondary "B" and the first carrier (C), and simultaneously spraying into the granulator to make the auxiliary agent (B) and the first carrier (c) form a fine particle (or fine particle) The type is made as shown in the second figure. The third scheme: after the main agent (A) and the first carrier (c) are pulverized, they are simultaneously sprayed into the granulator to make the main agent (A) and The first carrier is composed of a fine particle (or fine particle) type, and then the secondary enthalpy (B) and the first carrier (C) are pulverized, and then the granule is sprayed into the artificial granule machine to make a secondary agent (b> blood No. 200920690 One carrier (c) constitutes another fine particle (or microparticle) plastic state' as shown in the third figure. The fourth scheme: the main agent (A) and the second carrier (D) are pulverized and then 'synchronized spray Into the granulator, the main agent (A) and the second carrier (D) are combined into a fine particle (or fine particle) plastic state, as shown in the fourth figure. The fifth scheme: a secondary agent (B) After being pulverized with the second carrier (D), the nozzle is synchronously introduced into the granulator, and the auxiliary agent (B) and the second carrier (D) are combined into a fine particle (or fine particle) plastic state to form a fifth. Figure 6. Sixth scheme: the main agent (A) and the second load After the body (D) is pulverized, it is sprayed into the granulator simultaneously, so that the main agent (A) and the second carrier (D) form a fine particle (or fine particle) metamorphosis' and then the auxiliary agent (B) and the second After the carrier (D) is pulverized, it is simultaneously sprayed into the granulator to form the auxiliary agent (b) and the second carrier (D) into another fine particle (or fine particle) type, as shown in the figure. The seventh scheme: the main agent (A) and the first carrier (c) are pulverized and sprayed into the granulator simultaneously, so that the main agent (a) and the first carrier form a fine particle (or fine particle) type. After the auxiliary agent (B) and the first (C) are pulverized, they are simultaneously sprayed into the granulator to form the auxiliary agent (b) and the = carrier (C) into another fine particle (or fine particle) type. a package; a main agent (A) and a first carrier (c), a secondary agent (B) and a second body (C), as shown in the seventh figure. Scheme. The main agent (A) After pulverization, it is sprayed into a granulator to form a fine particle (or fine particle) (10) state of the main agent (A), and then pulverized the first (C) and the second carrier (D), and simultaneously sprays the artificial particle machine = 9 200920690 The first carrier (C) and the second carrier (d) are combined with the main agent (A) After the fine particle (or fine particle) coating type, the auxiliary agent (B) is pulverized and sprayed into the granulator, and finally the auxiliary agent (B)-carrier (c) and the second carrier (D) are main The agent (A) is composed of another fine particle (or fine particle) coating type, and is formed as shown in the eighth figure. The ninth embodiment: the auxiliary agent (B) is pulverized and sprayed into the granulator to make the auxiliary The agent (B) is composed of a fine particle (or fine particle) type, and then the first carrier (C) and the first carrier (d) are pulverized, and then simultaneously sprayed into a granulator to make the first carrier (C) and The second carrier (D) xiao auxiliary agent (B) constitutes another fine particle (or fine particle) coating type, and the main agent (A) is pulverized, sprayed into the granulator, and finally the main agent (A) Forming another fine particle (or microparticle) coated form with the first carrier (c) and the second carrier (D) and the field ij agent (b) is as shown in the ninth figure. The tenth aspect is that the main agent (A) is pulverized and then sprayed onto the second carrier (D), and then the bismuth (B) is pulverized and then sprayed onto the second carrier (D). The main agent (a) and the second carrier (D), the auxiliary agent (B) and the second carrier (3) are packaged in a space to form an eleventh scheme as shown in the tenth figure: the main agent (A) The pulverization is placed in the lower layer after the second layer is placed at the upper end of the main agent A, that is, the middle layer position: Take = one: the body (c) is placed on the upper end of the auxiliary agent (b), that is, the upper layer, the auxiliary agent (:), the main agent ( A) 'Formed as the tenth-figure = scheme: the pulverization of the auxiliary agent (B) is placed in the lower layer, and the re-net 10 200920690 is pulverized and placed on the upper end of the auxiliary agent (B), that is, the middle layer position. Finally, the first carrier (C) is placed at the upper end of the main agent (A), that is, the upper layer position, and becomes a three-layer combined type, and the first carrier (c) and the main agent (A) are added in a space (B). ), made as shown in the twelfth figure. ...the thirteenth scheme: the third carrier (E) (double-sided sticker or devil's felt. the upper layer is a glue-free layer, the lower layer is a rubber layer) is placed on the bottom layer, and then the main agent (A) is pulverized and sprayed. Attached to the second carrier (D) (cloth: with tiny pores) is the lower layer, the lower layer is placed at the upper end of the bottom layer, and the other carrier (D) (non-woven fabric: with isolation) is the middle layer, and the middle layer is placed. The upper end of the lower layer is smashed and smashed (B) and then sprayed into the first: (cloth: there are tiny pores), that is, the upper layer, the upper layer ^ = end, that is, the four-layer combination type is completed in a space. Packaging a third carrier s, an elixir ((A) and a second carrier (D), a second carrier (D). A carrier (D) is bagged, as shown in Fig. 13 Two (E) (double-sided sticker _ agent (B) on the magnetic 9 ^ a) placed at the bottom layer, and then the sub-fine pores; that is, the carrier (9)) (cloth: two-way effect) is "," The middle layer carrier... (cloth: right:) is pulverized and sprayed into the upper end of the second intermediate layer, that is, the completion of the four:: hole) is the upper layer 'this upper layer is placed in (1), the auxiliary agent is in a space A first carrier means ,, third vector (D), a second carrier (D) 200 920 690 Main agent (A) and the first member (D) into a bag, such as those shown in FIG fourteenth

第十五方案:係將第三載體(E 氈:上層為無膠層,下層為有膠層、(又面貼紙或魔鬼 劑(B)粉…… 層)置於底層處,再將副 別)杨碎化後噴入附著於第二 士 微小細孔)即A 丁 ® , 體(D )(布料:有 1胃/ 下層放置在 -載體⑼)(不織布:具隔 :: 置於下層上端,又將主劍…丄、為中層,此中層 載體(D)… 碎化後噴入附著於第二 )(布料.有微小細孔)即為上厗 置一第二載體Ρ為上層,在上層處又 頂層置於上吸水作用)即為頂層,此The fifteenth scheme: the third carrier (E felt: the upper layer is a non-adhesive layer, the lower layer is a rubber layer, (also a sticker or a devil agent (B) powder ... layer) is placed at the bottom layer, and then the sub-division ) After being shredded, it is sprayed into the tiny pores of the second person, ie, A Ding®, body (D) (cloth: 1 stomach/lower layer placed on the carrier (9)) (non-woven: with septum:: placed on the upper end of the lower layer) And the main sword... 丄, for the middle layer, the middle layer carrier (D)... is shredded and sprayed into the second) (cloth. There are tiny pores), that is, the upper layer is placed on the second carrier, and the upper layer is The upper layer is placed on the top layer and the top layer is placed on the top layer.

㊁體(;)、副劑(Β)與第二載體(D)、第二載 CD)、主劑(a)盥第載體 )成袋,如第十五圖所;;。(D)、第二載體(DThe two bodies (;), the auxiliary agent (Β) and the second carrier (D), the second carrier CD), and the main agent (a) the carrier are formed into a bag, as shown in Fig. 15; (D), second carrier (D)

二載案*係將主劑(A)粉碎化後噴入附著於第 )(布料:有微小細孔)即為下層,另置一第 置於下不織布:具隔離作用)即為”,此中層 載俨又將副齊“B)粉碎化後喷入附著於第二 申屛D)(布料:有微小細孔)即為上層,此上層置於 層上端,即完成三層組合型態在一空間中包裝主劑(A 一與第二載體(D)、第二載體(D)、副劑(B)與第 戴體(D)成袋,如第十六圖所示者。 袋♦因該包裝袋係採防水透氣材質製成,使用時將此包裝 衣丁開,使其得以在一般的室溫吸收空氣中所含的濕氣, 12 200920690 使其内部承裝的細粒(戎妈私、、务± ./± ^ (次微粒)逐漸党潮或加入適量水份 • 產生相互的化學反應,使二氧化氯氣體被逐漸 /在此使用型態下,因空氣中的濕氣係逐漸 =’是以其產生化學反應的速度並不會太快,而是以 和緩的速度逐漸反應釋放出-童仆务 出一化加上其細粒(或微 氣化效延長其使用時間’同時其釋放的二 致於過高,係為一種長效之微量低濃度以和 :緩的==出二氧化氯氣體,達到長效之消毒殺菌功 月匕,使其在使用上更為安全者。 即,經由以上說明,π知士政。口丄A 將人m灰 T知本發明在製備上,乃創新地 夺口成一氧化亂之主劑及副劑選擇搭配第 體或第三載體混合製成細粒(或微 戰體或弟-载 裝於防太读潜夕…“ 再依預定比例包 !:水透乳之包裝袋中,使用時將此包裝袋打開,使Α 侍以在一般的室溫吸收空氣中所含 一 使其釋放二氧化氯氣體,成為一種=、乳或加入適量水份 化氯合成方式,令其使用二效微量低濃度二氧 量低濃产的#用-节丁义 侍長,特別適用於微 重低/農度的使用*求,不但使用 在運輸過程及貯存上亦相當便利且安全杜:喝,同時 而安全之製備方法,確深具極佳之二減不失為-創新 者。 、極佳之產業利用價值與實用性 綜上所述,本發明之二氧化氯氣體 ― 劑料的細粒(或微粒)製造及包 、,經由其 ,經由吸收空氣中所含之濕氣或加入適量用上 學反應’以和緩的作用速度釋出二氧化氯氣二達到土= 200920690 之消毒殺菌功%’使其在使用上更為 實具有極佳產業利用價值與實用性: 安全,整體而言 爰依法提出專利 ,確 申請 【圖式簡單說明】 弟1圖·係本創作第1較佳 第2圖:係本創作第2較佳 第3圖:係本創作第3較佳 第4圖:係本創作第4較佳 第5圖:係本創作第5較佳 第6圖:係本創作第6較佳 第7圖:係本創作第7較佳 第8圖:係本創作第8較佳 第9圖:係本創作第g較佳 第1 0圖:係本創作第1 〇 第1 1圖:係本創作第1 1 第1 2圖:係本創作第1 2 第1 3圖:係本創作第1 3 第1 4圖:係本創作第丄4 第1 5圖:係本創作第1 5 第1 6圖:係本創作第1 6 【主要元件符號說明】 (A )主劑 (C )第一載體 (E )第三载體 實例之結構型態示意圖。 實例之結構型態示意圖。 實例之結構型態示意圖。 實例之結構型態示意圖。 實例之結構型態示意圖。 實例之結構型態示意圖。 實例之結構型態示意圖。 實例之結構型態示意圖。 實例之結構型態示意圖。 較佳實例之結構型態示意圖。 較佳實例之結構型態示意圖。 較佳實例之結構型態示意圖。 較佳實例之結構型態示意圖。 較佳實例之結構型態示意圖。 較佳實例之結構型態示意圖。 較佳實例之結構型態示意圖。 (B )副劑 (D )第二載體 14The second case* is that the main agent (A) is pulverized and then sprayed into the first layer (cloth: there are tiny pores), that is, the lower layer, and the other one is placed under the lower non-woven fabric: with isolation function), The middle layer is pulverized and then pulverized and attached to the second application D) (cloth: small pores) is the upper layer, and the upper layer is placed on the upper end of the layer, that is, the three-layer combination type is completed. The packaging main agent (A-and second carrier (D), second carrier (D), auxiliary agent (B) and the wearing body (D) are bagged in a space, as shown in Fig. 16. Since the bag is made of waterproof and breathable material, the package is opened during use to absorb the moisture contained in the air at a normal room temperature, 12 200920690 Mom's private affairs, work ± ./± ^ (secondary particles) gradually party tide or add appropriate amount of water • Produce mutual chemical reaction, so that chlorine dioxide gas is gradually / in this type of use, due to moisture in the air Gradually = 'the speed at which the chemical reaction is produced is not too fast, but is gradually released at a moderate rate - the child servant is out Its fine particles (or micro-gasification effect prolongs its use time) and its release is too high, which is a long-acting trace low concentration and: slow == chlorine dioxide gas, achieving long-lasting effect The disinfection and sterilization function makes it safer to use. That is, through the above description, π knows the ethics. The mouth 将A will be the human m ash T know that the invention is prepared, and it is innovatively smashed into an oxidation. The main agent and the auxiliary agent of the chaos are selected to be mixed with the first or third carrier to make fine particles (or micro warfare or younger-loaded in the anti-reading slogan..." and then according to the predetermined proportion of the package!: Water-transparent milk packaging In the bag, when the bag is used, the bag is opened, so that the user can absorb the chlorine dioxide gas in the air at a normal room temperature to become a kind of =, milk or add appropriate amount of water to synthesize chlorine, so that It uses the second-effect micro-low concentration and low-concentration dioxane low-concentration #用-节丁义长, which is especially suitable for the use of micro-heavy/agricultural use. It is also convenient and safe to use not only in transportation and storage. Du: Drinking, at the same time, the safe preparation method, it is indeed an excellent two to lose - Newer. Excellent industrial use value and practicality. In summary, the fine particles (or fine particles) of the chlorine dioxide gas-agent of the present invention are manufactured and packaged, through which the air is contained. Moisture or adding appropriate amount of schooling reaction to release chlorine dioxide gas at a slow rate of action to achieve soil disinfection workability of 200920690 makes it more practical and has excellent industrial use value and practicability: safety, As a whole, 提出 patents are applied in accordance with the law, and the application is made [simple description of the drawings] 弟1图·This is the first best picture of the creation: the second best picture of this creation: the third best 4: This is the fourth best picture of this creation: the fifth best picture of this creation: the sixth best picture of this creation: the seventh best picture of this creation: the original creation 8th, 9th, and 9th: This is the first glance of the creation of the book. The first picture of the book is the first one. The first picture is the 1st picture. 3: This is the first of the creation of the 1st 1st 4th figure: the second part of this creation, the fourth picture, the first picture: 1st, the first picture, the first 1 6 [Explanation of main component symbols] (A) Main agent (C) First carrier (E) Schematic diagram of the structure of the third carrier. A schematic diagram of the structure of an example. A schematic diagram of the structure of an example. A schematic diagram of the structure of an example. A schematic diagram of the structure of an example. A schematic diagram of the structure of an example. A schematic diagram of the structure of an example. A schematic diagram of the structure of an example. A schematic diagram of the structure of an example. A schematic diagram of a structural form of a preferred embodiment. A schematic diagram of a structural form of a preferred embodiment. A schematic diagram of a structural form of a preferred embodiment. A schematic diagram of a structural form of a preferred embodiment. A schematic diagram of a structural form of a preferred embodiment. A schematic diagram of a structural form of a preferred embodiment. A schematic diagram of a structural form of a preferred embodiment. (B) secondary agent (D) second carrier 14

Claims (1)

200920690 十、申凊專利範圍: 1 種新式二氧化氯氣體之釋放方法,其合成二氧 化氣殺f消毒劑所需的劑料,主要包括:纟劑係由亞氯酸 氯酸叙、亞氯酸鐘、亞氯酸鉀(由以上一種或數種 成伤此σ而成),副劑係由過硫酸銨、過硫酸鋰、過硫酸 奸過硫酸納(由以上一種或數種成份混合而成),第一 載體係選自高嶺土、_石粉、含水黏丨、锻燒的黏土、酸 化的黏土、酸化的煅燒黏土、鹽類 、固體酸、 體:泡綿、 或配合第三 層為有膠層 ),係將主 使主劑與第 2、如 氣體之釋放 入造粒機中 態者。 有機酸酐以及它們的合成物,或可運用第二載 海、·、$、布料、不織布、紙張、纖維之吸水材質 载體:雙面貼紙或魔鬼氈(上層為無膠層,下 )4合成一氧化氯載體混合製成細粒(或微粒 劑與第一載體粉碎化後,同步噴入造粒機中, —载體組成一細粒(或微粒)型態者。 申請專利範圍第1項所述之一種新式二氧化氯 方法,係將副劑與第一載體粉碎化後,同步喷 使副劑與第一載體組成一細粒(或微粒)型 氣體之釋Γ請專利範圍第1項所述之—種新式二氧化氯 入造粒機中方法,係將主劑與第一載體粉碎化後,同步喷 離,再’使主劑與第-載體組成-細粒(或微粒)型 u劑:一載體粉碎化後,同步喷入造粒機中, 齊匕、第一載體組成另一細粒(或微粒)型態者。 4、如申請專利範圍第i項所述之一種新:二氧化氯 <s 15 200920690 氣體之釋放方法,構脾士卞 、# "與第二載體粉碎化後,同步噴 態去 使主劑與第二載體挺成-細粒(或微粒)型 態肴° 5、如申請專利範圍第丄項 ϋ H Μ -ίτ >+ ν ^ ^ 種新式一軋化氯 方法’係將副劑與第二載體粉碎化後,同步噴 熊者。 、弟一载體組成一細粒(或微粒)型 6經如申咕專利範圍第1項所述之-種新式二氧化氯 虱-之&方法,係將主劑與第體粉 入造粒機中,使主劑盥m —哉酙α 佼「〗步喷 ,,劑”弟一載體組成一細粒(或微粒)型 態,再將副劑與第二载體粉碎化後,同步噴入造粒機中 使副劑與第二載體袓έ 4交J,噴入、粒機中’ 執菔、、且成另一細粒(或微粒)型態者。 氣體1=1請專1項所述之—種新“氧化氣 亂體之釋放方法’係將主劑與第一載體粉碎化後, 入造粒機中,使主劑與第一截 、 態,再將副劑與第一載=(或微粒)型 _ 戰體叔碎化後,同步喷入造粒機中, 使峭劑與第-载體組成另一細粒(或微粒)型# 一* 間中包裝主劑與第—載體、副劑與第-載體者Γ 工 8、如申請專利範圍第i項所述之一種新式二 氣體之釋放方法,係將主劑粉碎化後噴入造粒機中,使主 劑組成-細粒(或微粒)型態,再將第一載體與第 叙碎化後’同步噴入造粒機中’使第一载體與第二载體 主劑組成另一細粒(或微粒)包覆型態,又將副劑粉化 後嘴入造粒機中,最後使副劑第一載體與第二載體與主劑 (S 16 200920690 組成另一細粒(或微粒)包覆型態者。 9、如中請㈣範㈣i項;;述之一種新式 氡體之釋放方法,係將副劑粉碎化㈣人造粒機中= 劑組成一細粒(或微粒)型態,再將第一載體與第二= 化後/步喷入造粒機中’使第一載 ::組成另'細粒(或微粒)包覆型態,又將主劑= 入造粒機中,最後使主劑與第-載體與第二載體: 劑细成另-細粒(或微粒)包覆型 —“ 卜10、如申請專利範圍第1項i述之一種新式一 氣氣體之釋放方法,係將主逾丨 T 一氧化 , ”.劑柘碎化後噴入附著於第二载 丄後喷入附著於第二載體上,在-ΐ 匕裝劑與第二載體、副劑與第二載體者。 二 & 11、如中請專利範圍第i項所述之一 ^體之釋放方法’係將主劑粉碎二-乳化 粉碎化後置於主劑之上端g卩中s 、下層,再將副劑 劑之上端即上層位置,而成為三層 :體置 令包裝第-載體、副劑、主劑者。 、、在-空間 1 2、如申請專利㈣第以所述之 虱氣體之釋放方法,係將副 ,新式二乳化 :碎化後置於副劑之上端即中層第, 2劑之上端即上層位置,而成載截置 中包敦第-栽號、主劑、副劑者。…U在-空間 氛心釋m園第1項所述之-種新式… 方法,係將第三裁趙(雙面貼紙或魔鬼耗·· r ·χ«· 17 200920690 上層為無膠層,下 卜層為有膠層)置於底層處,再將主劑 :化後噴入附著於第二载體(布料:有微小細孔)即為; ^此下層放置在底層上端,另置—第二載體(不織布下 具隔離作用)卩卩為中層,此中 粉碎化後喷入附著於第一載體(士於下層上知將田,]劑 上層,此上層置於中料:有微小細孔)即為 „ ^ 七 9上^ ’即完成四層組合型態在一办 間中包裝第三載體、主劑盥筐二 第二载體成袋者。H载體、第二載體、副劑與 氣二I請專利範圍第1項所述之-種新式二氧化 氣虱體之釋放方法,係將第三 虱化 上層為無膠層,下層為有膠声 ^貝占紙或魔鬼鼓: 碎化後喷入附著於第二载體丄;於底層處’再將副劑粉 戶,此下厚放署" 枓:有微小細孔)即為下 具隔離作用為中層,此中 第一载體(不織布: 粉碎化後喷入附著於第二載體::下=了:主劑 上層,此上層置於中層上端,即.有微小細孔)即為 間中包裝第三载體、副劑與第二:=四層組合型態在-空 第二載體成袋者。 、第二載體、主劑與 1 5、如申請專利範圍第丄 氯氣體之釋放方法,係將第三载雔之—種新式二氧化 上層為無膠層,下層為有膠層)雙面貼紙或魔鬼氈: 碎化後喷入附著於第二載體(布_於底層處,再將副劑粉 層’此下層放置在底層上端,另$丄有微小細孔)即為下 具隔離作用)即為中層,此中居 第二载體(不織布·· θ置於下層上端,又將主劑 200920690 粉碎化後喷入附著於第二载冑(布料:有微小細孔) 上層,在上層處又置一第二载體(泡缔:具吸水作用 為頂層’此頂層置於上層上端1完成五層組合型態在一 空間中包裝第三載體、副劑與第二載體、第二载體 與第二載體、第二載體成袋者。 1 6、如申請專利範圍第1項所述之一種新式二 ^氣體之釋放方法,係將主劑粉碎化後噴人附著於第 一布料:有微小細孔)即為下層,另置一第_ # 織布:具隔離作用)即為中層,…置於;:二體(不 將副劑粉碎化後喷入附著於第二載體 ,又 二即為上層,此上層置於中層上端,,p完成 ι間中包裝主劑與第二載體、第二 ^ 載體成袋者。 體 Μ劑與第二200920690 X. Application scope of Shenhua: A new method for releasing chlorine dioxide gas, which is used to synthesize the sulphur dioxide disinfectant, mainly including: bismuth chlorite, chlorite Acid clock, potassium chlorite (made by one or several of the above-mentioned injuries), the secondary agent is made up of ammonium persulfate, lithium persulfate, sodium persulfate and sodium persulfate (mixed from one or more of the above ingredients) The first carrier is selected from the group consisting of kaolin, _ stone powder, aqueous binder, calcined clay, acidified clay, acidified calcined clay, salt, solid acid, body: foam, or a third layer with a rubber layer ), the main agent and the second, such as the release of gas into the granulator state. Organic acid anhydride and their composites, or can use the second sea, ·, $, cloth, non-woven fabric, paper, fiber absorbent material carrier: double-sided stickers or devil felt (upper layer is no glue layer, bottom) 4 synthesis The chlorine monoxide carrier is mixed to form fine particles (or the microparticles are pulverized with the first carrier, and simultaneously sprayed into the granulator, and the carrier is composed of a fine particle (or microparticle) type. Patent Application No. 1 The novel chlorine dioxide method comprises the steps of: pulverizing the auxiliary agent and the first carrier, and simultaneously spraying the auxiliary agent and the first carrier to form a fine particle (or particulate) type gas. The method for introducing a new type of chlorine dioxide into a granulator is to pulverize the main agent and the first carrier, simultaneously spray off, and then make the main agent and the first carrier-fine particle (or fine particle) type. U agent: after the carrier is pulverized, it is sprayed into the granulator simultaneously, and the first carrier forms another fine particle (or particle) type. 4. A new type as described in the scope of claim patent item i : chlorine dioxide <s 15 200920690 gas release method, spleen卞,# " After pulverization with the second carrier, the simultaneous spray state is used to make the main agent and the second carrier into a fine-grain (or fine particle) type. 5, as claimed in the scope of the patent item ϋ H Μ - Ίτ >+ ν ^ ^ A new method of rolling chlorine is to pulverize the auxiliary agent and the second carrier, and simultaneously spray the bear. The younger carrier forms a fine particle (or microparticle) type 6新 The new type of chlorinated chlorinated bismuth as described in the first paragraph of the patent scope, the main agent and the first body powder are put into the granulator to make the main agent 盥m-哉酙α 佼" , the agent "the carrier" constitutes a fine particle (or microparticle) type, and then the secondary agent and the second carrier are pulverized, and then sprayed into the granulator simultaneously to make the auxiliary agent and the second carrier 袓έ 4 intersect. Injecting into the pellet machine, 'cracking, and forming into another fine particle (or particle) type. Gas 1=1, please specify one of the new ones - a new "release method of oxidizing gas disorder" After pulverizing the main agent and the first carrier, the granule is put into the granulator to make the main agent and the first cut state, and then the auxiliary agent and the first load = (or fine particle) type _ war body unbroken, the same Sprayed into the granulator, the stagnation agent and the first carrier are combined into another fine granule (or microparticle) type #一* intermediate package main agent and the first carrier, the auxiliary agent and the first carrier Γ8, such as The method for releasing a new type of two gas according to item i of the patent application scope is that the main agent is pulverized and sprayed into a granulator to form a main agent-fine particle (or fine particle) type, and then the first carrier After the "synchronous injection into the granulator" after the fragmentation, the first carrier and the second carrier agent are combined to form another fine particle (or fine particle) coating type, and the auxiliary agent is powdered and then injected into the mouth. In the granulator, the first carrier and the second carrier and the main agent (S 16 200920690 are finally combined to form another fine particle (or fine particle) coating type. 9. For example, please refer to (4) Fan (4) item i; describe a new type of carcass release method, which is to pulverize the auxiliary agent (4) in the artificial particle machine to form a fine particle (or particle) type, and then the first The carrier and the second = post-injection/step spray into the granulator 'make the first load:: make up another 'fine particle (or fine particle) coating type, and then the main agent = into the granulator, and finally make the main And the first carrier and the second carrier: the agent is finely formed into a fine-grain (or fine particle) coating type - "", a new one-gas gas release method as described in claim 1 of the patent scope, When the T is oxidized, the agent is mashed and sprayed into the second carrier and then sprayed onto the second carrier, and the second carrier, the secondary agent and the second carrier are sprayed. II & 11, as disclosed in the patent scope of item i, the method of releasing the body is to pulverize the main agent and pulverize it, and then place it on the upper end of the main agent, s, the lower layer, and then the vice The upper end of the agent is the upper layer position, and becomes the three layers: the body is placed to package the carrier-carrier, the auxiliary agent, and the main agent. 2. In the space-space 1 2. The method for releasing the gas as described in the patent application (4) is to emulsify the second and the new type: after disintegration, it is placed on the upper end of the auxiliary agent, that is, the middle layer, and the upper end of the second agent is the upper layer. Position, the interception of the package in the Dundy - planting, main agent, auxiliary agent. ...U in the - space ambience release m garden mentioned in the first item - a new style ... method, the third crop Zhao (double-sided stickers or devil consumption · r · χ «· 17 200920690 upper layer is a glue-free layer, The lower layer is a glue layer) placed on the bottom layer, and then the main agent is sprayed and attached to the second carrier (cloth: there are tiny pores); ^ the lower layer is placed on the upper end of the bottom layer, and the other is placed - The second carrier (the non-woven fabric has an insulating effect) is a middle layer, and after being pulverized, it is sprayed and attached to the first carrier (the upper layer is said to be the field, the upper layer of the agent), and the upper layer is placed in the middle material: there is a fine The hole) is „^ 七9上^', that is, the four-layer combination type is completed, and the third carrier, the main agent basket, the second carrier and the second carrier are packaged in one office. The H carrier, the second carrier, and the vice The method for releasing the new type of gas dioxide body described in the first paragraph of the patent scope is the third layer of the upper layer is a non-adhesive layer, and the lower layer is a glued sound, a shell paper or a devil drum. : After being shredded, spray it into the second carrier; at the bottom of the layer, 'there will be a side powder, and then the lowering department" ) is the middle layer with isolation, the first carrier (non-woven: pulverized and sprayed into the second carrier:: lower =: the upper layer of the main agent, the upper layer is placed at the upper end of the middle layer, that is, there is a small The pores are the third carrier, the secondary agent and the second in the intermediate package: = the four-layer combination type in the second empty carrier into the bag. The second carrier, the main agent and the 15. The method for releasing the chlorine gas of the third gas is to use a double-layered upper layer of the second type of bismuth as a non-adhesive layer and a lower layer of a layer of double-layered sticker or devil's felt: after being shredded, it is sprayed and attached to the second carrier ( Cloth_ at the bottom layer, then the auxiliary agent powder layer 'this lower layer is placed on the upper end of the bottom layer, and the other is a small pore), that is, the lower layer is isolated, which is the middle layer, which is the second carrier (non-woven fabric · θ It is placed on the upper end of the lower layer, and the main agent 200920690 is pulverized and sprayed into the upper layer attached to the second carrier (cloth: tiny pores), and a second carrier is placed on the upper layer (bubble: water absorption is the top layer) 'This top layer is placed on the upper end of the upper layer 1 to complete the five-layer combination type in a space Packaging the third carrier, the auxiliary agent and the second carrier, the second carrier and the second carrier, and the second carrier into a bag. 16. A method for releasing a new type of gas as described in claim 1 of the scope of the patent application, After pulverizing the main agent, the spray is attached to the first cloth: there are tiny pores), that is, the lower layer, and another _# woven fabric: with isolation function, that is, the middle layer, ... placed; The auxiliary agent is pulverized and sprayed into the second carrier, and the second layer is the upper layer, and the upper layer is placed on the upper end of the middle layer, and the packaged main agent and the second carrier and the second carrier are formed into bags. Tincture and second
TW96141193A 2007-11-01 2007-11-01 Novel method for releasing chlorine dioxide gas TW200920690A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111943143A (en) * 2019-05-17 2020-11-17 浙江金海环境技术股份有限公司 Chlorine dioxide generating agent composition, preparation method and application
CN114684790A (en) * 2022-03-30 2022-07-01 中源(大连)生物环保科技有限公司 Controllable dry method and device for preparing pure chlorine dioxide gas

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111943143A (en) * 2019-05-17 2020-11-17 浙江金海环境技术股份有限公司 Chlorine dioxide generating agent composition, preparation method and application
CN114684790A (en) * 2022-03-30 2022-07-01 中源(大连)生物环保科技有限公司 Controllable dry method and device for preparing pure chlorine dioxide gas
CN114684790B (en) * 2022-03-30 2023-08-29 中源(大连)生物环保科技有限公司 Method and device for preparing pure chlorine dioxide gas in controllable dry mode

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