TW201130430A - Organic deoxidizer - Google Patents

Organic deoxidizer Download PDF

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Publication number
TW201130430A
TW201130430A TW100101594A TW100101594A TW201130430A TW 201130430 A TW201130430 A TW 201130430A TW 100101594 A TW100101594 A TW 100101594A TW 100101594 A TW100101594 A TW 100101594A TW 201130430 A TW201130430 A TW 201130430A
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TW
Taiwan
Prior art keywords
deoxidizer
organic
weight
parts
agent
Prior art date
Application number
TW100101594A
Other languages
Chinese (zh)
Other versions
TWI535389B (en
Inventor
Toshitaka Wada
Osamu Sekiguchi
Original Assignee
Powdertech Co Ltd
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Publication date
Application filed by Powdertech Co Ltd filed Critical Powdertech Co Ltd
Publication of TW201130430A publication Critical patent/TW201130430A/en
Application granted granted Critical
Publication of TWI535389B publication Critical patent/TWI535389B/en

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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/043—Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/262—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon to carbon unsaturated bonds, e.g. obtained by polycondensation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
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    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28011—Other properties, e.g. density, crush strength
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    • B01J20/2805—Sorbents inside a permeable or porous casing, e.g. inside a container, bag or membrane
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3014—Kneading
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
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  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
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  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
  • Packages (AREA)

Abstract

Deoxidizers have been demanded which cannot be detected by metal detectors. Thus, disclosed is an organic deoxidizer in which a metal such as a reducing iron powder is not used, and which does not undergo the scattering of powders of raw materials upon the mixing of the raw materials, can be produced with improved production efficiency, and has improved deoxidization performance. Specifically disclosed is an organic deoxidizer which comprises the main component comprising an easily oxidizable organic substance, an alkali agent and water, and which is characterized in that calcium hydroxide and calcium carbonate are used as the alkali agent and the alkali agent is contained in an amount of 20 to 200 parts by weight relative to 100 parts by weight of the main component.

Description

201130430 四、 指定代表圖： (一）本案指定代表圖為：無。 (一）本代表圖之元件符號簡單說明：鉦。 五、 本案若有化學式時，請揭示最能顯示發明特徵的化學式： 無。 六、發明說明： 【發明所屬之技術領域】 本發明係關於有機系脫氧劑，詳言之，係關於不會被201130430 IV. Designation of the representative representative: (1) The representative representative of the case is: None. (1) A brief description of the symbol of the representative figure: 钲. 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: None. 6. Description of the invention: [Technical field to which the invention pertains] The present invention relates to an organic deoxidizer, in particular,

金屬探測器所偵測，安全性古 N 文主注阿’且具備優良的脫氧性能之 有機系脫氧劑。 【先前技術】 將食品、藥品、雷子機哭 亀于機盗、電氣器具等的商品封入包 材=存時’含於保存氣氛之氧，會有使該等保存品氧 化’或誘發發霉而招致σ皙 m κ 化之虞。因此，先前，為防 止氧化、防止發霉等，在以盔 _ 狀匕、保皆較佳的食品或藥 劑專，於該等之包步。肉 /j, 〆：.、 匕裝00内一併封入脫氧劑。 脫氧劑’係由無機系材料戋 刺田条τ叶次有機糸材料所組成，藉由 利用氧化反應將存在於氣氛中的氧吸 ：由 氧。然而，以鐵粉等的無機李材料…'該钱中的 氧性能優良而廣泛地被使用。 脫氧劏，脫 但是’在於食品等的經口品 叩！屬探測器作為 2 201130430 4貞測異物, . 產品的手段檢查包裝之保存品之安全性之情 形’在此情带 所知# β於保存品一併封入由鐵粉等的無機系材料 ’、成之脫氧劑，則有金屬 从左 > 々金屬彳木測态對脫氧劑反應而有妨礙 檢查之課題。 劑，而 破期望能有不會被金屬探測器所偵測之脫氧 而有不使用還原鐵粉等的金屬之有 茶 0 例如，直 ν , 利文獻1(日本國專利申請特開2000-50849 號公報），規- 揭不-種有機系脫氧劑，其係包含選自由兒茶 财、間笨二酚、斛埜_ ^ 人榀你 +本—酚、甲酚、鄰苯三酚之低分子酚化 二物與活性碳所組成者。此外，專利文獻2(日本國專利申 〇〇3 38143號公報）揭示·種脫氧劑’其係以多元 -醇化a物、盼化合物、不飽 t Λ 跑矛油月曰、不飽和脂肪酸、不飽 、和t合物等所組成 . 有機糸易氧化性組成物為主劑，擔持 在以化學合成之平均 ° ,n 祖佐O.ivm以下的二氧化矽造粒成 l.(hm以上之造粒二氧化矽。 揭示於專利文_ τ + /rf、 之低为子酚化合物為主劑之脫氧 有在内部通氣性句岱 匕衣表面看到如液體滲出之深色，有 發生所謂「滲出」之 ^ 滑形，而有損外觀，並且對消費者帶 來=性的不安感而在實用上將成課題。此外，專利文獻 所揭不之脫氧劑，為得到良好的流動性及填充包裝適性 之脫氧劑，須經擔體的造 粒步驟’而製造上的管理點多， 反而造成製造成本的損失。 因此’本案發明人，接安 . 知案了例如專利文獻3(日本國專 利申請特開2〇〇7_7 4⑽2就公報）、專利文獻4(曰本國專 3 201130430 利申請特開2〇〇7-268326號公報）之有機系脫氧劑，作為 不會被金屬探測器價測之脫氧劑。但是，以該專利文獻3、 4之有機系脫氧劑’在混合脫氧劑原料時原料粉容易飛散， 由於主劑之流動性不佳而無法提高生產效率，成為 有機糸脫氧劑之製造成本上升的原因，而期望改良。 本案發明之目的係在於研究有機系脫氧劑之祕，以 &供脫氧能力及生產效率更加提升之有機系脫氧劑。 【發明内容】 :此’本案發明者們，進一步研究有機系脫氧 4用以下的有機系脫氧劑達成上述課題。 關於本案發明之有機系脫氧劑，其特徵在於：其係含 脫由易氧化性有機物質所組成之主劑、驗劑及水之有機系 重量：時转及碳_作為驗劑，使主劑為1。〇 σ 匕3 20重量部〜2〇〇重量部該鹼劑。 質 關Γ本案發明之有機系脫氧劑，上述易氧化性有機物 以單寧或單㈣S佳。 微物 關於本案發明之右诚备 # 時 有機系脫氧劑，使主劑為100重量部 匕3 10重量部〜2〇〇重量部的水更佳。 關於本案發日月之右祕金 時 u之有機系脫氧劑，使主劑為1〇〇重量部 L 3 5重量部以下的反應觸媒者更佳 關於本案發明之有機系妝、薪令丨 9〜ι2更佳。 有機系脫氣劑，原料混和後的ρΗ以 關於本案發明之右趟备& 有機糸脱礼劑包裝體，其特徵在於·· 201130430 將上述有機系脫氧劑以氧穿透性包裝材包裝。 [發明效果] 入關於本發明之有機系脫氧劑，藉由對主劑1〇。重量部 含有2〇重量部〜200重量部由氫氧化舞及碳酸的所組成之 驗劑，可抑制脫氧劑的發塵性，並且可提升脫氧能力。因 此’可抑制混合脫氧劑原料時之起粉，並且將脫氧劑封入 =時可抑制脫氧劑咬入密封部。結果，可較先前的有 機糸脫氧劑抑制產生粉塵或…，可減低製造成本。再 者，亦改善在於脫氧劑原料混合時之主劑之流動性差的 點’可大大地提升生產效率。 -【實施方式】 ' ^關於本發明之有機系脫氧劑之較佳的實施 〜關於本案發明之有機系脫氧劑，係含有由易氧化性 有機物質所組成之主劑、驗劑及水之有㈣脫氧劑。 在二，使用易氧化性有機物質。該易氧化性有機物質， =早：、單寧酸、兒茶盼、撕黃素、黃_、黃烧嗣、黃 =外：、花青素、對苯二"食子酸等為主成分 該等之中!：血：、甘油、葡萄糖等的多元醇化合物。 " 、以早寧或單寧酸為佳。單寧或單寧酸，可為藉 化學合成所製造者，或由植物 望私1 某子或花、樹皮 =取者均可。由植物所萃取的單寧或單寧酸 荆樹(金合歡)、栗材、_、兒茶、鐵杉' 橡㈣卒取者。藉㈣用如此之易氧化性有機物質 201130430 廉價而安全性高的脫氧劑。 易氧化I·生有機物質，更詳言之，以縮合型單寧或單寧 酸為主成分者特另"圭。縮合型單寧，由於主骨架構造不容 易因W或％境的變化而變化’ @時可保持涉及脫氧反應 之官能基，故在用於長期保存保存品之脫氧劑之用途，可 安定地維持脫氧能力。 、产關於本發明之有機系、脫氧劑，其關於本發明之有機系 、氧劑之特徵之—係使用氫氧化妈及碳酸㉝作為驗劑，使 主劑為m重量部時，包含20重量部〜2〇〇重量部該脸劑。 驗劑，係與水作用顯示驗性之物質，進行脫氧反應所 需的物質。於本發明，併用氫氧化約及碳酸弼作為驗劑。 氫比用於Μ之有㈣脫氧劑之其他 L較少引起主劑之易氧化性有機物f之水解等反應， :、寺涉及易氧化性有機物質之脫氧反應之官能基。此 卜’可έ忍為藉由與水的交互作 ηΗ 父Α作用可穩疋化產生脫氧反應之 pH，可仟穩定的脫氧反應。 氫氧化鈣的平均粒徑I以η ς Λ 更佳，以2 ^〜2〇〇“為佳，以 # m〜6〇//111最佳。藉由使用具有如 之柘體特性之氫氧化軒， i 亲冷^ J霄現優良的脫氧能力、脫氧 、又，並且在於製造脫氧劑時， 成物調合。即m鉦 煉與其他的組 气氛 風氧化鈣的平均粒徑汛。未滿0.5“者， 風氧化鈣的粉塵容易飛揚，封 不完全，古护从& 匕教材訏也體°父入而密封 有扣外觀，或漏粉等而產生。 脱氧劑原料的混煉，團聚而流動性:：外’在於 助『生差，使混煉狀態產生不 6 201130430 均，或發生黏著在混合容器等不適。另一方面，氣氧㈣ 的平均粒徑I超過200 //m，則氫氧化鈣的比表面積變小， 脫氧劑的反應速率降低而不佳。 然後，作為驗劑的氫氧化弼，使用微粉則可認為比表 "積s變大而可提尚脫氧反應，但如上所述，使用微粒的 氩氧㈣，則會有發塵性的問題，或在與其他的組成物之 混煉性或流動性發生問題。因此，關於本案發明之有機系 脫氧劑’發現藉由作為驗劑，進一步併用微粒的碳酸約， 即使使用微粒的氫氧㈣可消解上述課題，可提高生產效 率’並且可提高脫氧能力。 關於本案發明之有機系脫氧劑，藉由添加碳_，可 ..防止主劑溶液與氫氧㈣之混合時之起粉，並且，可兼且 •作為驗劑促進脫氧反應之魏，及擔持主劑㈣之功能Γ 即’石反酸㈣難溶於水的弱驗劑，比重較大，故與氮氧化 鈣一起使用作為碳酸妈，則可得抑制氯氧化飼之起粉之效 果。此外，碳酸鈣，擔持主劑的 ^ 门時亦可發揮作為提供反 應％之擔體之功能。關於本案發 ㈣w 茶發明之有機系脫氧劑，作為 驗劑，藉由在氫氧化鈣之外併 ㈣t ^ 卜㈣碳㈣’即使使用適於促 進脫氧反應之微粒的氫氧化鈣， ^ ± ^ π ± 卩制其起粉，且碳酸鈣 ^用主劑㈣時亦發揮作杨劑的作用。結果，相較於先 二=”等作為擔體之情形，變得無須擔體，可增 :在於有機系脫氧劑全體之驗劑之量，故可 力。此外，有機系脫氧劑，可按 ^ b 脫童及靡4由 A H …而要添加反應觸媒提高 速度’惟關於本案發明之有機系脫氧劑，藉由增 201130430 量驗劑的量，促進反應’可減低觸媒的添加量，進而關係 到降低成本。 然後，作為驗劑的碳酸弼，對氫氧化辦1 〇 〇重量部， 以5重量部〜50重量部為佳。碳酸鈣的含量未滿5重量部， 則混合時會發生起粉的同時會降低流動性，並不適合填充 封入包裝體使用的脫氧劑。另一方面，碳酸鈣為弱鹼劑， 僅使用碳酸鈣作為脫氧劑之鹼劑，則脫氧能力會變得不充 刀故對於氫氧化鈣100重量部添加超過50重量部的量的 碳酸鈣，則在於鹼劑之碳酸鈣的含量變多，脫氧劑單位重 量之脫氧量會減少而不佳。 具:人，關於本案發明之有機系脫氧劑必須有水。水係 將構成脫氧劑之組成物暈染，提供反應場者，使主劑為刚 =量部時’包含H)重量部,重量部的水為佳。關於本 ’、氧劑，由於含有碳酸鈣作為鹼劑，故即The metal detector is used to detect the safety of the ancient N-type main injection and has excellent deoxidation performance of the organic deoxidizer. [Prior Art] The food, medicine, and thunder machine are cried in the pirates, electrical appliances, etc., and the goods are sealed in the package. If the oxygen contained in the atmosphere is stored, it will oxidize the preserves or induce mold. Incurs 皙 皙 m κ 化 虞. Therefore, in the past, in order to prevent oxidation, prevent mold, and the like, it is necessary to use a food or a medicine which is better in the form of a helmet. Meat /j, 〆:., 匕 00 is enclosed in a deoxidizer. The deoxidizer ' is composed of an inorganic material 戋 田 τ τ 次 次 , , , , , , , , , , , , , , , τ τ τ τ τ τ τ τ τ τ τ 氧 氧 氧 氧However, it is widely used as an inorganic plum material such as iron powder, which has excellent oxygen performance. Deoxidation, but it is a product of food, etc. 叩! Detector as 2 201130430 4 贞 异 异 , . . 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 In the case of a deoxidizer, there is a problem that the metal reacts from the left side of the ruthenium metal eucalyptus to the deoxidizer and hinders the inspection. In addition, it is expected that there is a deoxidation which is not detected by a metal detector, and there is a tea which does not use a reduced iron powder or the like. For example, Zhi Wei, Li Wen 1 (Japanese Patent Application No. 2000-50849) No.), Regulation - Uncovering - an organic deoxidizer, which contains a low amount selected from the group consisting of catechins, stupid phenols, 斛野_^人榀你+本-phenol, cresol, pyrogallol A molecule consisting of a phenolic bisphenol and an activated carbon. In addition, Patent Document 2 (Japanese Patent Application No. 3 38143) discloses a type of deoxidizer which is characterized by a poly-alcoholized a substance, a desired compound, an unsaturated t 跑 跑 跑 曰 曰, an unsaturated fatty acid, It is composed of satiety and t-complex. The organic oxime oxidizing component is the main agent, and it is granulated into cerium oxide with an average of chemical synthesis, n zuzu O.ivm or less. The granulated cerium oxide. Revealed in the patent text _ τ + /rf, the low phenolic compound as the main agent for deoxidation has a dark color on the surface of the internal ventilating sentence, such as liquid oozing, there is a so-called The "smoothing" is slippery, which impairs the appearance and brings a sense of uneasiness to the consumer, which is a problem in practical use. Moreover, the deoxidizing agent disclosed in the patent literature provides good fluidity and The deoxidizing agent that fills the package is required to be manufactured by the granulation step of the support, and the manufacturing cost is reduced. Therefore, the inventor of the present case, Jie An. Knows the case, for example, Patent Document 3 (Japan) Patent application special opening 2〇〇7_7 4(10)2 on the bulletin) An organic deoxidizer as a deoxidizer which is not measured by a metal detector is used as a deoxidizer which is not measured by a metal detector. However, the patent documents 3 and 4 are disclosed in Japanese Patent Application No. Hei. No. Hei. No. Hei. In the organic deoxidizer, when the deoxidizer raw material is mixed, the raw material powder is easily scattered, and the fluidity of the main agent is not good, so that the production efficiency cannot be improved, and the production cost of the organic antimony deoxidizer is increased, and improvement is desired. It is based on the study of the secrets of organic deoxidizers, and the organic deoxidizers that provide improved deoxidation capacity and production efficiency. [Invention]: Inventors of this case further studied the following organic systems for organic deoxygenation. The deoxidizing agent achieves the above-mentioned problem. The organic deoxidizing agent according to the present invention is characterized in that it contains an organic agent which is composed of a main component, an analyte, and water which are composed of an easily oxidizable organic substance: time-shift and carbon_as The test agent is such that the main agent is 1. 〇σ 匕3 20 parts by weight to 2 parts by weight of the alkali agent. The organic deoxidizer of the invention of the present invention, the above oxidizable organic substance Ning or single (four) S Jia. Micro-objects on the right side of the invention of the invention # When the organic deoxidizer, the main agent is 100 weight parts 匕 3 10 weight parts ~ 2 〇〇 weight part of the water is better. The right part of the month is the organic deoxidizer of the secret gold, so that the main agent is 1 〇〇 part of the weight of the L 3 5 parts of the reaction catalyst is better. The organic makeup of the invention of the present invention, salary 丨 9 ~ ι2 Preferably, the organic deaerator is a mixture of raw materials and a mixture of raw materials and organic deodorizers according to the present invention, characterized in that: · 201130430, the organic deoxidizer is an oxygen penetrating packaging material. [Effect of the Invention] The organic deoxidizer of the present invention is prepared by using the main agent. The weight portion contains 2 parts by weight to 200 parts by weight of an agent composed of hydrogen hydroxide and carbonic acid, which suppresses the dusting property of the deoxidizer and improves the deoxidizing ability. Therefore, the powder at the time of mixing the deoxidizer raw material can be suppressed, and when the deoxidizer is sealed, the deoxidizer can be prevented from biting into the sealing portion. As a result, it is possible to suppress the generation of dust or the like by the conventional organic deoxidizer, which can reduce the manufacturing cost. Further, it is also improved that the point where the fluidity of the main agent is poor when the deoxidizer raw materials are mixed can greatly improve the production efficiency. - [Embodiment] ' ^About the preferred embodiment of the organic deoxidizer of the present invention~ The organic deoxidizer of the present invention contains a main component consisting of an easily oxidizable organic substance, a test agent, and water. (4) Deoxidizer. In the second, the use of oxidizable organic substances. The oxidizable organic substance, = early:, tannic acid, catechu, toxanthin, yellow _, yellow sputum, yellow = outside:, anthocyanin, benzoic acid " food acid Among these ingredients: blood: a polyol compound such as glycerin or glucose. ", with morning or tannic acid is better. Tannin or tannic acid, which can be made by chemical synthesis, or by plants, 1 or flower, bark = can be taken. Tannins or tannins extracted from plants. Acacia (Acacia), chestnut, _, catechu, and hemlock's rubber (4). Borrow (four) use such oxidizable organic substances 201130430 Cheap and safe deoxidizer. It is easy to oxidize I. Raw organic substances, in more detail, those with condensed tannins or tannic acid as the main component. Condensed tannins, because the main skeleton structure is not easily changed by the change of W or % environment, the functional group involved in the deoxidation reaction can be maintained, so the use of the deoxidizer for long-term preservation of the preserved product can be stably maintained. Deoxidation ability. The organic system and the deoxidizing agent according to the present invention are characterized in that the organic system and the oxygen agent of the present invention are characterized in that a hydroxide and a carbonic acid 33 are used as an examination agent, and when the main component is an m weight portion, 20 weights are contained. Department ~ 2 〇〇 weight part of the face. An examination, which is a substance required to perform a deoxygenation reaction with water. In the present invention, about hydrazine hydroxide and cesium carbonate are used as an assay. The hydrogen ratio is less than that of the other components of the deoxidizer (4), and the reaction of the oxidizing organic substance f of the main component is less. This can be used as a pH for the deoxygenation reaction by the interaction of water with ηΗ father, which can stabilize the deoxygenation reaction. The average particle diameter I of calcium hydroxide is preferably η ς ,, preferably 2 ^ 2 〇〇 ,, preferably # m 〜 6 〇 / / 111. By using a hydroxide having a steroidal property as described above. Xuan, i 亲冷^ J霄 is now excellent in deoxidizing ability, deoxidizing, and in the production of deoxidizer, the product is blended. That is, the average particle size of m smelting and other group atmospheres of oxidized calcium 汛. Less than 0.5 "People, the dust of the wind-calcium oxide is easy to fly, and the seal is not complete. The ancient guards are produced from the & 匕 textbooks, which are also sealed by the father and sealed with a buckle appearance or powder leakage. Mixing of deoxidizer raw materials, agglomeration and fluidity:: The outer side is to help the "difference", so that the kneading state does not occur, and the adhesion occurs in the mixing container. On the other hand, when the average particle diameter I of the gas oxygen (tetra) exceeds 200 //m, the specific surface area of the calcium hydroxide becomes small, and the reaction rate of the deoxidizer is lowered. Then, as the cerium hydroxide used as the test, the use of the fine powder is considered to be larger than the table quotation s, and the deoxygenation reaction can be promoted. However, as described above, the argon oxygen (four) using the fine particles has a problem of dusting. Or problems with mixing or fluidity with other components. Therefore, the organic deoxidizer of the present invention has been found to further use the carbonic acid of the fine particles as an assay, and even if the above-mentioned problem can be solved by using the hydrogen and oxygen (4) of the fine particles, the production efficiency can be improved and the deoxidizing ability can be improved. The organic deoxidizer of the invention of the present invention can prevent the powder from being mixed when the main solution is mixed with the hydrogen and oxygen (4) by adding carbon_, and can also be used as an assay to promote the deoxygenation reaction. The function of holding the main agent (4) is the weak test agent which is hardly soluble in water, and the specific gravity is large. Therefore, it can be used together with calcium oxynitride as a carbonic acid mother to suppress the effect of chlorine oxide feeding. In addition, calcium carbonate can also function as a support for providing % reaction when it is used as a main ingredient. About the case (4) w The organic deoxidizer of the invention of tea, as an examination, by using calcium hydroxide and (iv) t ^ Bu (4) carbon (4) ' even if calcium hydroxide suitable for promoting the deoxidation reaction is used, ^ ± ^ π ± 卩 其 起 , , , , , , , , , , , , , 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸As a result, compared with the case where the first two =" or the like is used as the support, it is possible to increase the amount of the organic deoxidizer as a whole. Therefore, the organic deoxidizer can be pressed. ^ b 脱 童 and 靡 4 by AH ... and adding reaction catalyst to increase the speed 'On the organic deoxidizer of the invention of the present invention, by increasing the amount of the test agent of 201130430, promoting the reaction 'can reduce the amount of catalyst added, Further, it is related to the cost reduction. Then, the strontium carbonate as the test solution is preferably a weight of 5 parts by weight to 50 parts by weight, and the content of calcium carbonate is less than 5 parts by weight. When the powder is generated, the fluidity is lowered, and it is not suitable for filling the deoxidizer used for packaging the package. On the other hand, calcium carbonate is a weak base agent, and only calcium carbonate is used as an alkali agent for the deoxidizer, and the deoxidizing ability is not improved. When the calcium carbonate is added in an amount of more than 50 parts by weight to 100 parts by weight of the calcium hydroxide, the content of calcium carbonate in the alkali agent is increased, and the amount of deoxidation per unit weight of the deoxidizer is decreased. About the invention of the case The deoxidizer of the machine must have water. The water system will smudge the composition constituting the deoxidizer, and provide the reaction field. The main agent is the weight part of the 'containing H' when the amount is just the amount, and the water of the weight is better. 'Oxygen agent, because it contains calcium carbonate as an alkali agent, it is

:提高水分對主劑之含量’可保持實用上容許之流動性。 使主劑為100重I A 。卩時，水的含量未滿10重量部，則有機 糸脫氧劑的組成物不容易、3 關於本案發明之有機系降低脫氧性能。再者， F材m蚀冑系脫氧劑’係以封入具有透氣性之包 裝材之狀態使用， ^ 能吸收含於保存二糸脫氧劑的水分不足時，亦可 點，水的含量^ 而發揮職能力。即使考慮此 >幻3里的下限值， 另-方面，使主劑“。重.重量部為1〇重量部。 多的水，則流動性會降低時，包含較200重量部為 裝。 氏而不適於對包裝材之自動填充包 8 201130430 此外，關於本案發明之有機系脫氧劑，亦可 反應速度之反應觸媒。觸媒，可使 门 载、錄、鋼、經等的 過度金屬之鹽酸鹽、硝酸鹽、硫酸瞄、 ’ 氣化納等的驗金Μ 鹽或鹼土金屬鹽等的無機系觸媒·— ^ , 啁烯’及奈二酚、間笨三酚、 第二丁基鄰笨二酚、第三丁基對 了本—酚、5_曱基間苯二酚 等的有機系觸媒。特別是，以不會 攸宠屬抓測盗偵測之有 機系觸媒為佳。添加該反應觸媒時’使主劑為ι〇〇重量部 時含量以15重量部以下為佳。關於本案發明之有機系脫氧 劑’如上所述，由於鹼劑的含量报 里很阿，故反應觸媒的添加 量即使是以15重量部以下的少晉 — ]^里亦可貫現充分的脫氧能 力。 - 此外，亦可添加活性碳。活神石由 _ ^ _ 古性妷’可捕捉脫氧反應後 所產生的低分子晉勒7哲，"όΓ亡η - 卞里物質可有效防止該低分子量物質之飛 散。活性碳的含量，對主劑1〇。重量部以5。重量部以下為 佳。活性碳的含量超過5G重量部，則有降低脫氧反應速度 之情形而不佳。 ’’、、後±述原料混合後的有機系脫氧劑的Μ以㈠2 為關於本案發明之有機系脫氧劑，係使用易氧化性有 機物質’ pH在此範圍’則易氧化性有機物質可安定地存在， 可使脫氧性能安定。 、其-人，說明關於本發明之有機系脫氧劑之製造方法》 首先對既疋置的主劑，加入水及按照需要之觸媒混合之。 子此依序添加作為驗劑之氫氧化舞、碳酸#5，混煉後粉體 化之後，按照需要添加活性碳，混合後，填充包裝於透 201130430 氣性包材，得到有她么u ^ 機糸脫氧劑包裝體之產。 脫氧劑包裝體·關& ▲也 & σ°。 士 關於本案發明之脫氧劑 上述脫氧劑藉由氧穿、# 裝體’係將 乳穿透性的包裝材所包 肝 劑係由如上所述的構成材料所組成有機系脫氧 態，故實用上，藉由氧φ ;'、叙體狀的形 两田氣穿透性的包裝材包 以下，說明用於有媳 " 系脫氧劑。 、有機糸脫軋劑包裝體之包 材，只要是在其厚户古μ * 匕裝材。包裝 即可使用，惟以兼且、商痒μ* 氧穿透之素材 佳。此外’以具備耐水性、耐油性 層積體為 以有孔（聚酯/聚乙稀）膜 °吏用例如’ 己烯）膜、紙、有孔聚乙烯膜之順序 層積體、紙或不織布鱼古 ι之 飞邛與有孔聚乙烯膜層壓之層積體 外，聚乙烯不織布雖然 此 从早體使用，但要求可防 劑流出的同時’密封性優良的包裝材。 脫氧 包裝材，可考慮例如’將紙與聚乙烯薄片黏貼者，微 多，膜或合成樹脂製不織布、層積外層材與内層材之複合 膜等。特別是，作為脫氧密丨 、 軋劏用包裝材，以可調整氧穿透性 等之複。膜為佳。&外，複合膜，特別是以層壓加工層積 外層材與内層材者為佳。以下，#明關於複合膜之各層之 構成材料。 内層材，知藉由在厚度方向形成貫通之細微貫通孔而 具備氧穿透性之膜。加上，可藉由層壓加工與外層材接著 者為佳。具有如此之性質之膜之材質，以聚乙烯(pE)為佳， 可良好地使用低氆度聚乙烯(LDpE)、直鏈低密度聚乙烯 (LLDPE) 〇 10 201130430 外層材，以可葬由爲厭^ θ ^ ^ ^ 藉由層壓加工與内層材接著，且接著接 具備氧穿透性者為#。 後 ，、，〇可牛例如，紙、織布、不織布 ' 料 多孔膜等。μ夕如 , w 微 1可牛牛皮紙、撥油紙、撥水紙等。織 布及不織布，可舉使用聚醋、聚醯胺等的材質者。” ’於該外層材，亦可為具備最外層膜，其係具有 多數貝通厚度方向之細微貫通孔之膜所組成者。該最2 膜，可使用例如聚酯、耳” @ 玻外層 声膜所呈傷 ^乙細、聚丙稀等的樹脂膜。最外 二、備之細微貫通孔，以層壓加工前或之後形成者均 可。但疋’切實地得到透氣性 貫通孔者為佳。再丨乂加工别形成細微 再者，細微貫通孔之形狀並不限於圓形， 根據有孔加工法可作成各式各樣的形狀。 :列如’外層材，亦可係於紙，層積聚對 用塗有聚醋膜之最卜等的膜作為最外層。即，使 面，與外二 將該最外層膜之塗有聚酿之 /、 a材之紙接觸熱壓接，則層壓力σ I n & 用具備如此夕县此a a i加工今易而佳。使 多數細微的言吁韁由對最外層膜形成 的貫通孔，可精度佳地調整空氣透氣度。 如此所得之外層材與内層材， 層Μ β u丄 J舉使内層材之膜與外 層材之、、、氏错由熱壓接加工層 時之加工土 s槓作成複合膜之例。層壓各層 法，可採用熱屋接加工、乾式層-加工。 、上例示了外層材、内層；fef夕^浙·松 膜，各層之材質〜：、 質等，惟作為複合 氧穿透性的同時，可採取夢由層…要疋至少具備 層積之構成者即可。 卜層材與内層材 11 201130430 以下’以實施例及比較例具體說明本案發明。惟本 案發明並非受限於以下實施例者。 [實施例1 ] 混合llg縮合型單寧（白堅木萃取單寧）與llg水作為 主劑。接著，對該混合物，依序添加9. lg氫氧化鈣（平均 粒徑1 = 4. 7 /z m)與3. 9g碳酸鈣作為鹼劑，混煉。此時， 主劑的流動性良好而容易混煉。之後，添加2· 〇g活性碳， 得到有機系脫氧劑。為測定所得有機系脫氧劑之pH，對k 有機系脫氧劑添加99g蒸餾水攪拌，作成1%的懸浮液，將 液溫保持在25t：，使用東亞電波工業株式會社製pH測定 儀HK-1K測定。結果，實施例有機系脫氧劑，顯示u i。 又脫氧劑的包裝材，使用將由厚度12/zm之有孔聚醋/ p乙烯層壓膜所組成之外層材，由5〇g/m2之耐水耐油紙所 、’且成之中層材’及由厚度25 "之有孔聚乙烯膜所組成之 内層材，熱層壓加工而得之氧穿透性複合膜，Gur I”式透 乳度為8000秒/10〇1111空氣者。使用該包裝材，準備將三 邊封口之外尺寸65mmx55mm之包裝袋於該包裝袋填充切 有機系脫氧劑，將開口部藉由熱層壓封口而封入，作成有 機系脫氧劑包裝體。將該有機系脫氧劑封入包裝體時，抑 、·塵的發生，幾乎沒有有機系脫氧劑被咬入熱層壓之 封口。卩，在假定大量生產之製造速度及製造量，並沒有發 生不良品。 ^次，將該有機系脫氧劑包裝體，放入聚偏氣乙烯塗 曰聚乙稀層壓膜之氣體阻障性的袋子（22Gx300mm)，-併 12 201130430 放入吸有水分活性顯示0. 95之氯化鈉水溶液之脫脂棉’填 充1 50 0ml的空氣，作成密封之密封袋A。此外’同樣地’ 將有機系脫氧劑包裝體，放入聚偏氯乙烯塗層/聚乙烯層壓 膜之氣體阻障性的袋子（220x1 5Omm)，一併放入吸有水分活 性顯示0. 95之氣化鈉水溶液之脫脂棉，填充50Om 1的空 氣，作成密封之密封袋B。 .測定所得脫氧劑包裝體之氧吸收量。將密封袋A保持 於室溫（25°C )’使用TORAY ENGINEERING株式會社製氧化 結式氧濃度計LC-700F測定袋内7天後的氧濃度（％)，算出 1個脫氧劑之氧吸收量（ml/個），由該值算出每lg主劑之 氧吸收量（m 1 /主劑1 g)評估之。再者，關於密封袋b，保持 於室溫（25°C )測定24小時後的氧濃度評估氧吸收速度。結 果示於表1。 [實施例2] 混合iig縮合型單寧（白堅木萃取單寧）與Ug水作為 主劑。接著’添加〇.14g第三丁基鄰苯二酚作為反應觸媒， 混合之。接著對該混合物，依序添加9. lg氫氧化帜平均 粒徑DH.7與3.9g碳酸料為驗劑，混煉 添加2. Og活性碳，進—步混煉後 氣劑。以盘f方“，】η 定之熟成侍到有機系脫 實^1同樣地測定所得有機系脫氧劑之dH 顯示11.0。 乳剧之pH， ，肌礼削封入盘音 包裝袋。將該有機系脫氧劑封入包裝材時1相同 發生’幾乎沒有有機系脫氧劑被 了粉塵 .、、、增壓之封口部， 13 201130430 假定大量生產之製造速度及製造量，並沒有發生不良品。 此外，以與實施例1相同的方法測定氧吸收量及氧吸收速 度。結果示於表1。 [比較例] 於比較例，僅使用氫氧化鈣作為驗劑，表示使用二氧 化矽作為擔體之例。混合8. Og縮合型單寧（白堅木萃取單 寺）與7. 3g水作為主劑。對此添加〇. 72g第三丁基鄰苯二 酚作為反應觸媒，混合之。接著，對該混合物添加2. 2g二 氧化矽，混合之。接著，添加54g氫氧化鈣（平均粒徑 ^一^“約作為鹼劑^昆煉之❶之後’添加活性碳^蛇， 得到有機系脫氧劑。於該混煉時，比較例之有機系脫氧劑， 流動性比實施例卜2差，混煉需時。與實施例1同樣㈣ 定比較例的有㈣脫氧劑之…顯示pH9.7。 包之有機系脫氣劑封入與實施例1相同的 起氧劑封μ裝體時，有機系脫氧劑 起粉很多，在於假 孔⑷ 以與實施例相同的方法測定氧吸收量及！ 劑被咬人熱層壓製造試驗，因有機系脫氧 而出現不良品·之封…’而無法將包裝袋的封口密封 吸收速度 14 201130430: Increasing the content of moisture to the main agent' maintains practically acceptable fluidity. The main agent was made to weigh 100 A. In the case of hydrazine, if the content of water is less than 10 parts by weight, the composition of the organic hydrazine deoxidizer is not easy, and 3 the organic system of the invention of the present invention reduces the deoxidizing performance. In addition, the F material m etchant deoxidizer is used in a state in which a gas permeable packaging material is sealed, and the water content contained in the deuterium deoxidizing agent can be absorbed, and the water content can be utilized. Job ability. Even if you consider the lower limit of this > magic 3, the other side will make the main agent ". The weight part is 1 〇 weight part. If more water, the fluidity will fall, it will contain more than 200 weight parts. It is not suitable for automatic filling of packaging materials. 8 201130430 In addition, the organic deoxidizing agent of the invention of the present invention can also react to the reaction rate of the reaction medium. The catalyst can make the door load, recording, steel, and the like excessive. Metal hydrochloride, nitrate, sulphuric acid, gold sulphate, etc., inorganic catalysts such as salt or alkaline earth metal salts, ^, terpene's and naphthalenes, m-trisphenol, Dibutyl o-diphenol and tert-butyl are organic catalysts such as phenol and 5-nonyl resorcinol. In particular, the organic system is not to be used for detection and detection. When the reaction catalyst is added, the content of the main component is 135 parts by weight, and the content is preferably 15 parts by weight or less. Regarding the organic deoxidizer of the invention of the present invention, as described above, the content of the alkali agent is reported. It’s very good, so the amount of reaction catalyst added can be filled even if it is less than 15 parts by weight. Deoxidation ability - In addition, activated carbon can be added. The sacred stone from _ ^ _ ancient 妷 can capture the low molecular weight of the genus Jinle 7 genius, and the όΓ η η - 卞 物质 material can effectively prevent The low molecular weight substance is scattered. The content of the activated carbon is preferably 1 part by weight of the main component, and the weight part is preferably 5. parts by weight or less. When the content of the activated carbon exceeds 5 parts by weight, it is not preferable to lower the deoxidation reaction rate. '', 后, ± 述 述 述 述 述 ± ± ± ± ± ± ± ± 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机 有机The presence of the ground can stabilize the deoxidation performance. The method for producing the organic deoxidizer of the present invention is described. First, the main agent to be disposed is added with water and mixed with a catalyst as needed. Adding the hydroxide dance and carbonic acid #5 as the test agent, after mixing and powdering, add activated carbon as needed, mix it, and fill it in the 201130430 gas-containing packaging material to get her. Agent The production of the body. Deoxidizer package · Guan & ▲ also & σ °. About the deoxidizer of the invention of the present invention, the above-mentioned deoxidizer is packaged by the oxygen penetrating, #装体' The liver agent is composed of the above-mentioned constituent materials and is organically deoxidized. Therefore, it is practically used in the package of oxygen gas φ; " is a deoxidizer. The packaging material of the organic de-rolling agent package, as long as it is in its thick household μ * 匕 loading material. The package can be used, but the combination of itch, itch μ* oxygen penetration material Further, in the case of a water-resistant and oil-resistant laminate, a layered body in the order of a porous (polyester/polyethylene) film, a film such as a hexene, a paper, or a porous polyethylene film, Paper or non-woven fish, the ancient scorpion, and the porous polyethylene film are laminated on the outside of the body. Although the polyethylene non-woven fabric is used from the early body, it requires a preventable agent to flow out at the same time as a 'sealing excellent packaging material. As the deoxidizing packaging material, for example, a paper which is adhered to a polyethylene sheet, a nonwoven fabric, a synthetic resin non-woven fabric, a composite film of a laminated outer layer material and an inner layer material, or the like can be considered. In particular, as a packaging material for deoxidizing and rolling, the oxygen permeability can be adjusted. The film is better. In addition, the composite film is particularly preferably laminated and laminated with an outer layer and an inner layer. Hereinafter, the constituent materials of the respective layers of the composite film will be described. The inner layer material is a film having oxygen permeability by forming a fine through hole penetrating in the thickness direction. In addition, it is preferable to laminate and process the outer layer. The material of the film having such properties is preferably polyethylene (pE), and can be used well in low-twist polyethylene (LDpE), linear low-density polyethylene (LLDPE) 〇10 201130430 outer layer. For the acne θ ^ ^ ^ by lamination processing followed by the inner layer, and then with oxygen permeability is #. After that, , for example, paper, woven fabric, non-woven fabric, porous film, etc. μ夕如 , w 微 1 can be cow kraft paper, grease paper, water-repellent paper, etc. For weaving and non-woven fabrics, we can use materials such as polyester or polyamide. "In the outer layer material, it may be a film having an outermost layer film which has a fine through-hole of a majority of the thickness of the Beton. The second film can be used, for example, polyester, ear" @ A resin film such as B fine or polypropylene is formed on the film. The outermost two, prepared fine through holes, can be formed before or after lamination. However, it is better to have a breathable through hole. Further, the shape of the fine through hole is not limited to a circular shape, and various shapes can be formed according to the hole processing method. : Listed as 'outer material, it can be attached to paper, and the layer accumulates the most outer film coated with the polyester film as the outermost layer. That is, the surface and the outer layer of the outermost layer of the film coated with the a//a paper are thermocompression bonded, and the layer pressure σ I n & . The fineness of the air permeability can be adjusted with high precision by the fine hole formed by the outermost layer film. In the outer layer material and the inner layer material thus obtained, the layer Μ β u丄 J is an example in which the film of the inner layer material and the outer layer material are formed into a composite film by the processed soil s bar when the hot-pressure bonded layer is formed. For lamination of various layers, hot-storage processing and dry layer-processing can be used. The outer layer and the inner layer are exemplified; the fef eve, the zhe sap, the material of each layer is ~:, the quality, etc., but as the composite oxygen permeability, the dream layer can be taken... Yes. Bu Lam and Inner Laminate 11 201130430 Hereinafter, the present invention will be specifically described by way of examples and comparative examples. However, the invention is not limited to the following embodiments. [Example 1] llg of condensed tannin (white hardwood extract tannin) and llg of water were mixed as a main agent. Then, 9. g of calcium hydroxide (average particle diameter 1 = 4. 7 /z m) and 3.9 g of calcium carbonate were added as an alkaline agent, and the mixture was kneaded. At this time, the fluidity of the main agent is good and it is easy to knead. Thereafter, 2·〇g of activated carbon was added to obtain an organic deoxidizer. In order to measure the pH of the obtained organic deoxidizer, 99 g of distilled water was added to the k organic deoxidizer, and the mixture was stirred to prepare a 1% suspension, and the liquid temperature was maintained at 25 t: and measured by a pH meter HK-1K manufactured by Toa Dentsu Kogyo Co., Ltd. . As a result, the example organic deoxidizer showed u i . The deoxidizer packaging material is made of a layered polystyrene/p-ethylene laminated film having a thickness of 12/zm, and is made of a water-resistant and oil-resistant paper of 5〇g/m2, and is formed into an intermediate layer and An inner layer composed of a porous polyethylene film having a thickness of 25 ", an oxygen-permeable composite film obtained by heat lamination, and a Gur I" type of milk permeability of 8000 sec/10 〇1111 air. In the packaging material, a packaging bag having a size of 65 mm x 55 mm other than the three-side sealing is prepared, and the organic deoxidizing agent is filled in the packaging bag, and the opening is sealed by hot lamination sealing to form an organic deoxidizing agent package. When the deoxidizer is sealed in the package, the generation of dust and dust is almost eliminated, and almost no organic deoxidizer is bitten into the seal of the heat laminate. 卩, the manufacturing speed and the amount of production are assumed to be mass-produced, and no defective product occurs. The organic deoxidizer package is placed in a gas barrier bag (22Gx300mm) of a polymetaethylene-coated polyethylene laminate film, and 12 201130430 is placed in a water-absorbing activity display 0.95 Cotton slip of aqueous sodium chloride solution filled with 15050 ml of air The seal bag A is sealed. In addition, the organic deoxidizer package is placed in a gas barrier bag (220x1 5Omm) with a polyvinylidene chloride coating/polyethylene laminate film. The absorbent cotton having a water activity of 0.95 in an aqueous solution of sodium carbonate was filled with 50 mm of air to form a sealed sealed bag B. The oxygen absorption amount of the obtained deoxidizer package was measured. The sealed bag A was kept at room temperature. (25°C) The oxygen concentration (%) after 7 days in the bag was measured using an oxygenated oxygen concentration meter LC-700F manufactured by TORAY ENGINEERING Co., Ltd., and the oxygen absorption amount (ml/unit) of one deoxidizer was calculated. This value was calculated for the amount of oxygen absorbed per lg of the main agent (m 1 / 1 g of the main agent). Further, regarding the sealed bag b, the oxygen concentration after 24 hours was measured at room temperature (25 ° C) to evaluate the oxygen absorption. The results are shown in Table 1. [Example 2] Mixed iig condensed tannin (white hardwood extract tannin) and Ug water as a main component. Then, '14 g of t-butyl catechol was added as a reaction. Catalyst, mixed. Then, the mixture was sequentially added 9. lg TiO2 average particle size DH.7 3.9 g of carbonic acid was used as an assay, and 2. Og of activated carbon was added to the mixture, and the gas was added after the mixture was further mixed. The obtained organic system was measured in the same manner as the organic compound. The dH of the deoxidizer showed 11.0. The pH of the milk drama, the muscles are cut into the sound of the packaging bag. When the organic deoxidizing agent is sealed in the packaging material, the same occurs. 'There is almost no organic deoxidizing agent that has been dusted, and the pressurized sealing portion. 13 201130430 It is assumed that the manufacturing speed and the manufacturing amount of mass production are large, and no defective product occurs. . Further, the oxygen absorption amount and the oxygen absorption rate were measured in the same manner as in Example 1. The results are shown in Table 1. [Comparative Example] In the comparative example, only calcium hydroxide was used as an assay, and an example in which ruthenium dioxide was used as a support was used. 8克水进行进行。 Mixing 8. Og condensed tannin (Baijianmu extraction single temple) and 7. 3g water as a main agent. To this, 72 g of tert-butyl catechol was added as a reaction catalyst and mixed. Next, 2. 2 g of cerium oxide was added to the mixture and mixed. Next, 54 g of calcium hydroxide (average particle diameter ^1) was added as an alkali agent, and then activated carbon was added to obtain an organic deoxidizer. At the time of the kneading, the organic deoxidation of the comparative example was carried out. The fluidity was inferior to that in Example 2, and the kneading took time. The same as in Example 1. (IV) The comparative example had a (four) deoxidizer which showed pH 9.7. The organic deaerator was encapsulated in the same manner as in Example 1. When the oxygen scavenger seals the package, the organic deoxidizer has a lot of powder, and the dummy pores (4) are measured in the same manner as in the examples, and the agent is subjected to a heat lamination manufacturing test, which is deoxidized by the organic system. There is a defective product seal...' and it is impossible to seal the sealing of the bag to absorb the speed 14 201130430

高 於貫施例卜24小時後密封袋B之氧濃度較實施例2 即表不氧吸收速度較慢。此可認為是由於並未添加反 應觸媒。但疋’繼續將實施例1之密封袋B於室溫（25°C ) 保持丄則密封袋B的氧濃度在42小時後成Q lvc)i%以下。 不於實知你]1之有機系脫氧劑，作為用於長期保存品等之 遲放型脫氧劑’具有滿足所期望水準的氧吸收性能。 比較實施例與比較例。看7天後的氧吸收量，則在於 :天後的密封袋内# ^濃度可說實施你J 2卩比較例為同 等可實用。但是，每1g當量的主劑之氧吸收量，實施例 2之有機系脫氧劑包裝體，t匕比較例高很多。由此，可知 主劑的脫氧能力的提升。此外，比較實施W 1與比較例， 則氧吸收量雖声^味日ΡΊ ^，隹 雖為相冋水準，由於實施例1在填充包裝時抑 制起粉等的發4 i d , \生而填充性佳，可抑制不良品的產生，可接 升製造效率。 15 201130430 [產業上的可利性] 關於本案發明之有機系脫 反應之脫氧劑，可實現脫氡性作為不對金屬探測器 料的起粉的同時具備適當 升’且可抑制製造時原 此，Μ # n双 "動生而可提升生產效率。s 關於本案發明之有機 手因 甚丄 犯乳劑，可利用於作A田·^ 產加工品、農產加工品等 、作為用於水 品内之脫氧劑。 ㈣測器進行檢查之保存 圖式簡單說明 盖 〇 【主要元件符號說明】The oxygen concentration of the sealed bag B after 24 hours higher than that of the second embodiment was slower than that of the second embodiment. This can be considered because no reaction catalyst has been added. However, 疋 continued to keep the sealed bag B of Example 1 at room temperature (25 ° C), and the oxygen concentration of the sealed bag B became Q lvc)i% or less after 42 hours. It is not known that the organic deoxidizer of 1 is a late release type deoxidizer for long-term storage or the like, and has an oxygen absorption performance that satisfies a desired level. Comparative examples and comparative examples. Looking at the oxygen uptake after 7 days, it is: in the sealed bag in the day after the concentration of ^ ^ can be said to implement your J 2 卩 comparative example for the same practical. However, the amount of oxygen absorption per 1 g equivalent of the main agent was much higher in the organic deoxidizer package of Example 2 than in the comparative example. From this, it is understood that the deoxidizing ability of the main agent is improved. Further, in the case of performing W 1 and the comparative example, the oxygen absorption amount is sounded, and although it is a relative level, since the first embodiment suppresses the hair styling, etc. in the filling and packaging, the filling is performed. Good quality, can inhibit the production of defective products, and can increase manufacturing efficiency. 15 201130430 [Industrial Applicability] The deoxidizing agent for the organic de-reaction of the invention of the present invention can achieve the dissociation property as a powder which does not impregnate the metal detector material, and has an appropriate rise and can suppress the production. Μ # n双" Move to improve production efficiency. s About the organic hand of the invention of the present invention What is the use of the emulsion, it can be used as a deoxidizer for use in the production of processed products, agricultural products, etc. in the field. (4) Preservation of the inspection of the detector Simple description of the diagram Cover 〇 [Main component symbol description]

Ml 〇 Μ»、 16Ml 〇 Μ», 16

Claims (1)

201130430 七、申請專利範圍·· 1 ·—種有機系脫氧劑，含有由易氧化性有機物質所組 成之主劑、驗劑及水， 其特徵在於： 使用氩氧化鈣及碳酸約作為鹼劑， 使主劑為100重量部時，包含20重量部~200重量部 該鹼劑。 2·如申請專利範圍第1項所述的有機系脫氧劑，其中 上述易氧化性有機物質係單寧或單寧酸。 •如申請專利範圍第丨項所述的有機系脫氧劑，其中 使主劑為1 0 0重量部時， - 4.如申請專利範圍第 -使主劑為1 0 0重量部時， 5 ·如申請專利範圍第 原料混和後的pH為9 ~ 12 包含10重量部〜2〇〇重量部的水。 1項所述的有機系脫氧劑，其中 包含15重量部以下的反應觸媒。 1項所述的有機系脫氧劑，其中 種有機糸脫氧劑包裝 :範圍第1項所述的有機系脫氧心::性=: 201130430 四、 指定代表圖： (一）本案指定代表圖為：無。 (一）本代表圖之元件符號簡單說明：鉦。 五、 本案若有化學式時，請揭示最能顯示發明特徵的化學式： 無。 六、發明說明： 【發明所屬之技術領域】 本發明係關於有機系脫氧劑，詳言之，係關於不會被 金屬探測器所偵測，安全性古 N 文主注阿’且具備優良的脫氧性能之 有機系脫氧劑。 【先前技術】 將食品、藥品、雷子機哭 亀于機盗、電氣器具等的商品封入包 材=存時’含於保存氣氛之氧，會有使該等保存品氧 化’或誘發發霉而招致σ皙 m κ 化之虞。因此，先前，為防 止氧化、防止發霉等，在以盔 _ 狀匕、保皆較佳的食品或藥 劑專，於該等之包步。肉 /j, 〆：.、 匕裝00内一併封入脫氧劑。 脫氧劑’係由無機系材料戋 刺田条τ叶次有機糸材料所組成，藉由 利用氧化反應將存在於氣氛中的氧吸 ：由 氧。然而，以鐵粉等的無機李材料…'該钱中的 氧性能優良而廣泛地被使用。 脫氧劏，脫 但是’在於食品等的經口品 叩！屬探測器作為 2201130430 VII. Scope of application for patents·· 1 · An organic deoxidizer containing a main component, an assay, and water composed of an oxidizable organic substance, characterized in that: calcium argon oxide and carbonic acid are used as an alkali agent, When the main component is 100 parts by weight, the base agent is contained in an amount of from 20 parts by weight to 200 parts by weight. 2. The organic deoxidizer according to claim 1, wherein the oxidizable organic substance is tannin or tannic acid. • If the organic deoxidizer described in the scope of claim 2, wherein the main agent is 100 parts by weight, - 4. If the scope of the application is - the main agent is 100 parts by weight, 5 · The pH of the raw material after the mixing of the raw materials in the patent application range is 9 to 12, and contains 10 parts by weight to 2 parts by weight of water. The organic deoxidizer according to Item 1, which contains 15 parts by weight or less of a reaction catalyst. The organic deoxidizer described in the above item, wherein the organic deoxidizer package: the organic deoxygenated heart described in the first item::==201130430 IV. Designated representative figure: (1) The representative representative figure of the case is: no. (1) A brief description of the symbol of the representative figure: 钲. 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: None. VI. Description of the Invention: [Technical Field] The present invention relates to an organic deoxidizer, and in particular, is not detected by a metal detector, and has a good safety and safety. Organic deoxidizer for deoxidation performance. [Prior Art] The food, medicine, and thunder machine are cried in the pirates, electrical appliances, etc., and the goods are sealed in the package. If the oxygen contained in the atmosphere is stored, it will oxidize the preserves or induce mold. Incurs 皙 皙 m κ 化 虞. Therefore, in the past, in order to prevent oxidation, prevent mold, and the like, it is necessary to use a food or a medicine which is better in the form of a helmet. Meat /j, 〆:., 匕 00 is enclosed in a deoxidizer. The deoxidizer ' is composed of an inorganic material 戋 田 τ τ 次 次 , , , , , , , , , , , , , , , τ τ τ τ τ τ τ τ τ τ τ 氧 氧 氧 氧However, it is widely used as an inorganic plum material such as iron powder, which has excellent oxygen performance. Deoxidation, but it is a product of food, etc. 叩! Detector as 2
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