200908427 九、發明說明： 【發明所屬之技術領域】 …本發明係關於燃料電池技術，特別是有關於—種改良之燃料電 池模組結構，可確實防止燃料外洩的疑慮。 【先前技術】 如熟習該領域者所知，燃料電池(FuelCell，簡稱為fc)係一種 利用燃料(如：甲醇、氫氣），透過電化學程序將化學能_成電力 之發電裝置。與傳統的發電方式她，燃料電池具有低污染、低 噪音、高能量密度以及較高的能量轉換效轉優點，乃具有前瞻 性之乾淨能源，可躺之傾包括家用發電祕、不斷電系統、 電子產品、運輸工具、軍用設備、太空工業等。 /然料電池之運作原理乃輯:料在陽極觸進行氧化反應，產 生氫離子(H+)、f子⑹，其中氫離子經岭解f傳遞至陰極，電 貝!A由外。卩電路觸至陰極，此時供給陰極端的氧氣會與氣離 子及電子在陰極觸媒層進行反應，並產生水。燃料電池一般 料數個基本單摘組成。由於每個基本單元所能提供之電壓很 電壓=在應用時必_聯多個基本單元，以達到所需要的操作 200908427 在燃料電池元件之模組結構中，通常包括有集電片以及流道 板’分別扮演著不同重要的角色，其中集電片負責收集電化學反 應所產生的電子，碰道板則是負責燃料流動的分佈與控制:流 道^的部分主要著重在流道的設計’使燃料能夠順利通過流道^ 而流入膜電極組(membrane electrode assembly，MEA)。 目前的燃料電池已發展至成熟實用階段，且較過去燃料電池呈 广妓高的操作效能以及較佳的可靠度。然而，燃料電池模組仍存 ' 有一些缺點需要進一步克服及改良。 【發明内容】 本發明之主要目的在提供一種改良之燃料電池模組，可確實提 昇電池模組之安全性。 〇 根據本發明之難實施例，本發明提供-麵料電池模組，包 含有-整合式陽極流道板，包含一流道板，其側邊上設有一凹槽， 用來容置一陽極集電片的導片；—陰極板，其包含至少-陰鋪 電區域’其巾該料係可崎並與該陰極板電路連接；—陣列膜 電極、、且’I㈣整合式陽極流道板與該陰極板之間，該陣列膜電 ::包t有一個或多個膜電極組、質子交換臈;以及-預固定黏 ，”於該整合式陽極流道板與該陣列膜電極組之間，以及介 於該陰極板與該陣列膜電極組之間，該預固定黏著材具有一對應 200908427 =開口’㈣容置膜電極組’其愧删定黏著材包含一中間固 疋框’其上、下面均被—黏著層蓋住。 根據本發日狀她實施例，本發_料電池触包含有一 陽極板，其由-軟硬複合板所構成，射該陽極板包含一陽極集 電區域以及-可麟的導電耳部，且在該陽極集電區域内設有複 數個穿孔，-流道板，其上設有複數個流道；—陰極板，包含至 少-陰極集電區域；—陣酬電極組，介於娜極板與該陰極板 之間，該陣顺電極組包含至少—個臈電極_f子交換膜；以 及-黏著材’介於該陽極板與該陣舰電極組之間，以及介於該 陰極板與鱗舰·組之間，該黏著材具有—對應的開口，用 以容置該膜電極組。 為讓本發明之上述目的、特徵、和優點能更明顯易懂，下文特 舉較佳實施方式，並配合所關式，作詳細制如下。然而如下 之較佳實施方式熊式僅供參考與說_，並_ 以限制去。 【實施方式】 目前的燃料電池已發展域熟實用階段，且較過去燃料電池呈 有更而的操作效糾及齡的可靠度。_，燃料電池㈣仍存、 有一些缺點需要進-步克服錢良。舉触說，轉著方式努作 200908427 燃料電池時’常因為黏著材與膜電極組之間的接合力不佳，容易 導致脫層(delamination)現象，並造成惱人的燃料電池浅漏現象。 另外，在實際應用上發j見，燃料外茂亦可能發生在靠近陽極集 ，片端’其經由集電片與其周圍黏著材之間的界面漏出，這主要 是由於集電片耳籠折所造成的應力，導致黏著效果不良，加上 熱衝擊實驗的過程巾’金屬的熱漲冷縮造隸著材錢電片間的 界面損毀所致。 上述的熱衝擊實驗75是根據國際電器委員會卿)針對燃料電 池模組的安全和性能所發佈之安規認·準所進行者。 請參閱第1圖及第2圖，其中第i圖是依據本發明較佳實施例 所緣不的燃料電池模組丨的爆炸圖，第2 _示的是第〗圖中燃 料電池模組1的組立圖(以2W之燃料電池為例）。 如第1圖及第2圖所示’本發明較佳實施例燃料電池模植】主 要包含有整合式陽顿触1G、陰極板12、絲著材Μ，以 及陣列膜雜組16，堆疊組裝而成。 其中，根據本發明較佳實施例，整 :板與流繼合•軸構彳_===^陽 可以是《_電额、石墨缺销鱗方讀作而成。 200908427 預固定黏著材14以及陣舰電極組16係層疊壓合纽在整合式 =極流_()與陰極板12之間，且預_卿14具有對應的 歼口用來谷置陣列膜電極組16，並使陣列膜電極組_兩面分 別與陽極流道板10上的陽極集電片Π0及陰極板12上的陰極集 電區域120相接觸。 ’、 所產其 編UG嘛⑽議物_料氧化 斤產^電子，且藉由集電片與陰極板12上的電路相連接，而將 電子傳導出去。此外，1上且右令夕 、 應物與生成麵管道/ ° ’用途是提供電池反 入陽極集電片則可以由金、白金、銀、.絡、欽、録等各種 巫、金屬乳化物、金屬合金，如各類型不鏽鋼、或者碳、石墨、 FR4、FR5等非金屬材料所構成之複合 二 鍍、益雷雪*雜〇 刊丁寸Ί作方式可採電 於騎層上 或其它化學、物理沈積方法，將導電層附著 板的板材(通常為破璃纖維或塑膠基板)有良 力，較人摘·仙… 土攸作民好％、疋的黏著能 熔膠;==_~材，高溫時會熱 u者使燃科電池各個元件得以緊密黏固。 200908427 圖所示，根據本發明之較佳實施例，預固定黏著材Μ 匕3中間固疋框141以及黏著層142，使中間固定框141的上、下 面刀別被-片黏著層142夾住。其巾，中間固定框141可以為較 緻密的材料所構成，例如，FR5或其它類似的材料。 預固定黏著材14除了可以提供黏著的效果之外，也可藉由調 ^中間固定框141的厚度賴料電池模組整體所使㈣預固定黏 著材14的張數，使得製程上得已控制膜電極組的壓縮量。其中， 2者層142為-種可無道板、極板及質子交顧均有良好的黏 著月b力的熱壓黏著材，例如，卿呵黏著材、環氧樹脂、pu系黏 著劑或silicone系黏著劑等。 根據本發明之較佳實施例’陣列膜電極組16是由多個膜電極 組116製作在同一質子交換膜16a上，且可以呈陣列方式排列， 以方便模組的對位、疊合及壓合。質子交換膜16a係為一氟系質 ^父換膜，例如杜邦公司的Nafion膜電極，但不限於此，其亦可 以為％1氫系質子交換膜。這樣的作法可以使質子交換膜l6a上的 黏著面積增加’進一步改善燃料電池模組的可靠度。 根據本發明之較佳實施例’在整合式陽極流道板10、陰極板 、預固定黏著材14，以及陣列膜電極組16的相對應的位置上， 例如’四個角落’均設有定位孔202，方便燃料電池模組的疊合對 200908427 ^外’如第9圖所示，本發明的陣舰電極组16其大小雜 與其匕各層大致上相同，因此具有較多_合面積，且質子交換 膜16a上沿著膜電極、组116的周圍可以另外設置有複數個貫穿通 孔126，可以在壓合時讓膠流入貫穿通孔既中，$增加陣列膜電 極組16與預固定黏著材14之間的黏合力。 本毛明燃料電池模組丨的另—重要特徵在於整合式陽極流道板 |〇的6又梢以往不同。請參閱第4圖以及第5圖，其中第4圖為 第1圖中整合式陽極流道板⑴的爆賴，第$騎示的是第*圖 中整合式陽極流道板10的組立圖。 如第4圖及第5圖所示，整合式陽極流道板1〇包含有流道板 1〇2、黏著材馳、黏著材獅、一體成型的陽極集電片削以 及口疋框108。上述組件層疊在—起並經過熱壓合後，即構成本發 明之整合式陽極流道板10。 陽極集電片11〇另包括可拗折的導片110a，可與陰極板12電 連接如此’在組裝後，藉由導片11Ga的彻折，使得燃料電池模 組1中的各個電池單元胞構成串聯或並聯組態。黏著材购及、 HMb可以是卿reg黏著材或者環氧樹脂。此外，黏著材购及 104b、固定框108均有相對應的開孔，使得壓合後，陽極集電片 110可以被曝露出來。 200908427 明參閱第6圖及第7圖，其中第6圖繪示的是本發明流道板搬 之側視圖，第7圖繪示的是流道板1〇2加上陽極集電片110之後 的側視圖。如第6圖及第7圖所示，本發明另在於流道板 102上相對應於陽極集電片11〇的導片的位置形成有凹槽 102a，這使得陽極集電片u㈣導片隐可以緊密的嵌合、固定 在流道板102上。 如第8圖所示’本發明這種在相對應於導片U〇a位置的凹槽 設計’使得導片ll0a、黏著材购、獅以及流道板1〇2之間可 以有更好的接著，因此可以有效解決燃料電池之燃料外触問題。 明參閱第10® ’其為依據本發雜佳實補所繪示的陰極板 的側視圖。如第U)圖所示，陰極板12包含陰極集電區域12〇以 及電池枝所需的電子線路，射陰轉電區域12G表面特別經 匕抗電化予腐理。陰極板12係採與印刷電路板(PCB)製程相 合之方法崎成’包括將峨基板裁製糊成所要尺寸大小後， 於銅’I基板上之陰極集電區域12G進行鑽孔製程，形成複數個穿 孔120a。較佳者’所有穿孔之總面積約佔該陰極集電區域概左 —„接著於銅4基板上及穿孔12〇a内壁沈積一化學銅層。然後在 銅石基板上以《阻(乾膜)暴露出陰極集電區域12〇。接著進行電鍍 製程’、以光阻為電鍍阻劑，在未被光阻覆蓋之區域，包括陰極集 電區域120内’電鑛一層銅層以及在銅層上鍍上-層錫錯層。接 13 200908427 著將光阻剝除。進行-銅餘刻製程，將未被錫錯層覆蓋之區域内 的僻銅層以及銅·板上的銅祕除。紐，再進行另一蝴 ,私韻除錫此層。為避免後續焊錫過程中對基板損傷或造成短 路’可塗佈—防焊阻劑。再進行-電鑛製程，於電極上進-步鑛 上-層保制’例城/金、_域化學銀等材料。 陰極板12上可設置一金屬圖案23〇,主要目的係作為燃料電池 (的政熱五屬圖案230可以為虛設的(dummy)大面積金屬圖案，可 以是多層電路板其中任何一層銅層。前述的金屬圖案，還可作為 内嵌式(embedded)的主動電路，例如可與控制燃料電池之電源管理 糸統(Energy Management System，EMs)電路整合，其佈局可視控 制電池之功能需求設計。 此外’陰極板12表面或⑽可以嵌人電子科24()，此電子元 件240依實際需要，可包含主動或被動電子元件，如電容、電阻、 ί電感以及積體電路“等。依據本發明較佳實施例，電子元件24〇 可量測電池溫度或具有短路保護功能。 請參閱第U圖，其為依據本發明另一較佳實施例所緣示_ 料電池模組13的爆炸圖。如第u圖所示，燃料電池模—主要 由流道板102、陽極板、降搞^ U極板12、黏著材104以及陣列膜電 極組16堆疊組裝而成。與燃料電池模組1不同處在於，燃料電池 模組la的流道板102及陽極板1〇a並未整合在一起。這使得陽極 200908427 板10a上的集電區域中的開孔率可以單獨設計，無須考量到流道 板的因素。 本發明利用電路板或金屬集電片製作成電極板，可使得流道板 的設計更娜性，可触動或被動電池需求設計流道板，無須考 慮膜電極_支撐及電流導料_。例如，流道㈣可以是拇 欄式或者蛇管式均可應用。此外，本發明的流道板1〇2可為雙面 設計或者單面設計。本㈣的流道板脱的板體紐可運用射出 成型技術形成，利用-種可射出成型之高分子複合材料，例如， 來鱗鱗嗣(polyetheretherketone，簡稱為PEEK)、聚醚酮酮 (P〇lyetherketoneketone，簡稱為 pEKK)、聚％(p〇lysuif〇ne，簡稱為 psu)、液晶高分子(liquidcrystalp〇lymer，簡稱為吻、高分子塑 化基板或複合式材料等之工程塑膠中之其中一種。此外，上述之 可射出成型之南分子複合侧可以採用與填充劑—併射出的加工 方式力述之填充劑例如改質劑、流動劑、脫膜劑等。 材14取代。 在第11圖中，黏著材1〇4為—種可與流道板1〇2、陽極板1〇、 陰極板12及陣列臈電極組16的質子交換膜均有良好黏著能力的 熱壓型片狀黏著材，例如，卿reg黏著材、環氧樹脂、柯系黏著 劑或sm_系點著鮮。黏著材1〇4具有相對應的舰區 開孔。當然，黏著材顺也可以被如第3圖中所示的預固定黏著 15 200908427 請參閱第12圖，其繪示的是第11圖中燃料電池模組la的陽 贿施側視圖。如第12圖所示，陽極板池包含陽極集電區域 〇以及電池串麵f㈣子鱗，_顯_電職製程相容 之方法所製成’包括將銅羯基板裁製切割成所要尺寸大小後，於 銅縣板上之陽轉賴域31Q進行鑽孔製程，形成複數個穿孔 3爲。杈佳者’所有穿孔之總面積約佔該陰極集電區域娜左右。 ^者於銅絲板上及穿孔島内壁沈積一化學銅層。然後在銅箱 土反上以光阻(乾膜)暴露㈣極集電區域3ι〇。接著進行電鑛譽 程’以光阻為魏阻劑，在未被光阻覆蓋之區域，包括陽極集電 區域3K)内，電鑛一層銅層以及在銅層上錄上一層锡錯層。接著 將先阻剝除。進行—織刻製程，將未被錫錯層覆蓋之區域内的 化學銅相及輔基板上_祕除。錢，再進行p 程’蝕除錫鉛層。 乂 根據本發明’陽極板衞可以是利用軟板、硬板或者軟硬複八 :=flexb◦㈣製作而成者，其中陽極板她另包含有一可捣 ϋ電耳部職，較佳者，導電耳部31〇a係以軟板構成，使得 模組電路的電池串並更為料。雜，触電路的電池串並除了 :以利用上述可拗折的導電耳部職來完成，亦可以利用金屬 =_祕焊财_，其_的方式是以電線 ==刪片的方式，可先將金屬片凹折，再點焊固定 但歧是採外加金屬財式，可在雜短的時 候直接使用銲錫(因為錫也是一種金屬，所以才會已外加金屬稱 16 200908427 之）；距離長時可以加以電線等的導線物件再焊上導電金屬，如錫 等(銲錫的方式為將電路拉至板邊在使用銲錫達到串並效果)。本發 明利用電路板技術所製成的電極板’使得平面式燃料電池的各電 池單元之間的串並問題迎刀而解。 請參閱第13圖，其緣示的是本發明燃料電池系、统彻的組立 圖如第13圖所不，燃料電池系統4〇〇是由複數個燃料電池模組 la所組合而成。複數個燃料電池模組&之間藉由鎖固件搬，例 如’鉚釘或螺絲等物理嵌合方式固定。鎖固件屻穿過各個燃料 電池模組la四個角落的相對應通孔，並且使簡電池模組^之 間，准持疋的間隙。鎖固件4〇2也可以作為複數個燃料電池模組 的導電用途。^然’燃料電池模組ia可以是由第2圖中的200908427 IX. INSTRUCTIONS: [Technical field to which the invention pertains] The present invention relates to fuel cell technology, and more particularly to an improved fuel cell module structure, which can surely prevent fuel leakage. [Prior Art] As is well known to those skilled in the art, a fuel cell (Fuel Cell, abbreviated as fc) is a power generating device that uses a fuel (e.g., methanol, hydrogen) to conduct chemical energy through an electrochemical process. With the traditional power generation method, the fuel cell has the advantages of low pollution, low noise, high energy density and high energy conversion efficiency. It is a forward-looking clean energy, and the reclining includes the household power generation secret and the uninterruptible power system. , electronics, transportation, military equipment, space industry, etc. / The operation principle of the battery is the series: the oxidation reaction is carried out at the anode, and hydrogen ions (H+) and f (6) are generated, wherein the hydrogen ions are transmitted to the cathode through the ridge solution f, and the electrons are outside. The 卩 circuit touches the cathode, and the oxygen supplied to the cathode end reacts with the gas and electrons in the cathode catalyst layer to generate water. Fuel cells are generally composed of several basic single extracts. Since the voltage that each basic unit can provide is very voltage=multiple basic units must be connected in order to achieve the required operation. 200908427 In the module structure of fuel cell components, it usually includes collector tabs and runners. The plates' play different important roles, in which the collectors are responsible for collecting the electrons generated by the electrochemical reaction, and the touch plates are responsible for the distribution and control of the fuel flow: the part of the flow channel is mainly focused on the design of the flow channel. The fuel can flow smoothly through the flow channel and into the membrane electrode assembly (MEA). The current fuel cell has been developed to a mature and practical stage, and has a much higher operating efficiency and better reliability than the past fuel cells. However, fuel cell modules still have 'some shortcomings that need to be further overcome and improved. SUMMARY OF THE INVENTION The main object of the present invention is to provide an improved fuel cell module that can surely improve the safety of the battery module. According to a difficult embodiment of the present invention, the present invention provides a fabric battery module comprising an integrated anode flow channel plate, including a first-class channel plate, and a groove on a side thereof for accommodating an anode current collection a guide sheet of the sheet; a cathode plate comprising at least a cathode dielectric region, wherein the substrate is electrically connected to the cathode plate circuit; an array film electrode, and an 'I (four) integrated anode flow channel plate Between the cathode plates, the array film is electrically:: the package t has one or more membrane electrode sets, proton exchange enthalpy; and - pre-fixed adhesion," between the integrated anode flow channel plate and the array membrane electrode assembly, And between the cathode plate and the array membrane electrode set, the pre-fixed adhesive material has a corresponding 200908427 = opening '(four) accommodating membrane electrode group 'the 愧 黏 黏 黏 包含 包含 包含 包含 包含 包含 包含The following is covered by an adhesive layer. According to the embodiment of the present invention, the battery contact comprises an anode plate, which is composed of a soft-hard composite plate, and the anode plate comprises an anode current collecting region and - the conductive ear of the collar, and in the anode current collection area a plurality of perforations, a flow channel plate having a plurality of flow channels thereon; a cathode plate comprising at least a cathode current collecting region; and a array of electrode electrodes, between the nanoplate and the cathode plate, The array electrode group includes at least one 臈 electrode _f sub-exchange membrane; and - an adhesive material is interposed between the anode plate and the array of ship electrodes, and between the cathode plate and the scale ship group, The adhesive material has a corresponding opening for accommodating the membrane electrode assembly. To make the above objects, features, and advantages of the present invention more apparent, the preferred embodiments are described below, and The detailed system is as follows. However, the following preferred embodiment bear type is for reference only and _, and _ to limit. [Embodiment] The current fuel cell has developed a field of practical use, and more than the past fuel cell The operation efficiency is correct and the reliability of the age. _, the fuel cell (4) still exists, there are some shortcomings that need to further overcome Qian Liang. The touch said that the way to turn the way into the 200908427 fuel cell 'often because of the adhesive and membrane electrode Poor bonding between groups, easy The phenomenon of delamination and the annoying phenomenon of shallow leakage of the fuel cell. In addition, in practical applications, the fuel can also occur near the anode set, and the end of the sheet is attached to the surrounding material via the collector tab. The interface between the leakage, which is mainly due to the stress caused by the tabs of the collector tabs, resulting in poor adhesion, plus the process of the thermal shock experiment, the metal's heat expansion and cold shrinkage is the interface between the materials. The above-mentioned thermal shock test 75 is carried out according to the Safety Regulations issued by the International Electrical Committee for the safety and performance of fuel cell modules. Please refer to Figure 1 and Figure 2, where i The figure is an exploded view of a fuel cell module according to a preferred embodiment of the present invention, and the second drawing shows a group diagram of the fuel cell module 1 in the first embodiment (taking a 2W fuel cell as an example). As shown in Figures 1 and 2, the fuel cell module of the preferred embodiment of the present invention mainly comprises an integrated male contact 1G, a cathode plate 12, a wire raft, and an array film stack 16, stacked assembly. Made. According to a preferred embodiment of the present invention, the whole: the plate and the flow succeeding and the shaft structure 彳====^yang can be read as "the amount of electricity, the graphite lack of scales." 200908427 Pre-fixed adhesive 14 and array of electrode sets 16 are laminated between integrated = pole flow _ () and cathode plate 12, and pre-clear 14 has a corresponding opening for valley array film electrode Group 16, and the array membrane electrode assembly _ both sides are in contact with the anode collector tab Π0 on the anode runner plate 10 and the cathode collector region 120 on the cathode plate 12, respectively. </ br> </ br> </ br> <br><br><br><br><br><br><br><br><br><br><br><br><br><br><br><br><br><br><br><br><br><br><br><br><br> In addition, 1 and right-handed, the object and the generated surface pipe / ° 'use is to provide battery reverse anode collector piece can be made of gold, platinum, silver, .., Qin, recorded and other witch, metal emulsion Metal alloys, such as various types of stainless steel, or non-metallic materials such as carbon, graphite, FR4, FR5, etc., composite two-plating, Yileixue* miscellaneous magazines can be used on the riding layer or other chemistry. The physical deposition method, the plate of the conductive layer attached to the board (usually the glass fiber or the plastic substrate) has a good power, and it is better than the people to pick up the celestial celestial scorpion. The material, which is hot at high temperatures, allows the various components of the fuel cell to be tightly bonded. 200908427 shows that, according to a preferred embodiment of the present invention, the intermediate fixing frame 141 and the adhesive layer 142 are pre-fixed, so that the upper and lower blades of the intermediate fixing frame 141 are sandwiched by the adhesive layer 142. . The towel, intermediate fixing frame 141 may be constructed of a relatively dense material such as FR5 or the like. In addition to providing an adhesive effect, the pre-fixed adhesive material 14 can also be used to adjust the thickness of the intermediate fixing frame 141 to the fourth (4) pre-fixed number of sheets of the adhesive material 14, so that the process is controlled. The amount of compression of the membrane electrode set. Among them, the two layers 142 are a kind of hot-pressing adhesive material which can adhere to the monthly b-force, such as the adhesive sheet, the epoxy resin, the pu-based adhesive or the silicone. Adhesives, etc. According to a preferred embodiment of the present invention, the array film electrode assembly 16 is formed on the same proton exchange membrane 16a by a plurality of membrane electrode assemblies 116, and may be arranged in an array to facilitate alignment, lamination and pressing of the module. Hehe. The proton exchange membrane 16a is a fluorine-based parent membrane, for example, a Nafion membrane electrode of DuPont, but is not limited thereto, and may be a %1 hydrogen-based proton exchange membrane. Such an approach can increase the adhesion area on the proton exchange membrane 16a to further improve the reliability of the fuel cell module. According to a preferred embodiment of the present invention, at the corresponding positions of the integrated anode flow channel plate 10, the cathode plate, the pre-fixed adhesive material 14, and the array film electrode assembly 16, for example, 'four corners' are provided with positioning The hole 202 facilitates the stacking of the fuel cell module. As shown in FIG. 9, the array electrode group 16 of the present invention has substantially the same size as the layers of the crucible, and thus has a larger area. A plurality of through-holes 126 may be additionally disposed on the proton exchange membrane 16a along the periphery of the membrane electrode and the group 116, so that the glue can flow into the through-holes during the pressing, and the array membrane electrode group 16 is pre-fixed and adhered. The adhesion between the materials 14. Another important feature of the Benming fuel cell module is the integrated anode flow channel plate. Please refer to FIG. 4 and FIG. 5, wherein FIG. 4 is a breakdown of the integrated anode flow channel plate (1) in FIG. 1, and the first ride shows the assembled view of the integrated anode flow channel plate 10 in FIG. . As shown in Figs. 4 and 5, the integrated anode flow path plate 1 includes a flow path plate 1 2, an adhesive material, an adhesive lion, an integrally formed anode current collecting piece, and a port frame 108. The above components are laminated and thermocompression bonded to form the integrated anode runner plate 10 of the present invention. The anode current collecting tab 11a further includes a foldable guide piece 110a, which can be electrically connected to the cathode plate 12, so that after assembly, each battery cell in the fuel cell module 1 is made by the folding of the guide piece 11Ga. Form a series or parallel configuration. Adhesive materials can be purchased, HMb can be qing reg adhesive or epoxy resin. In addition, the adhesive material purchase 104b and the fixing frame 108 have corresponding openings, so that the anode current collecting sheet 110 can be exposed after pressing. 200908427 Referring to FIG. 6 and FIG. 7, FIG. 6 is a side view of the flow path plate of the present invention, and FIG. 7 is a view of the flow path plate 1〇2 plus the anode current collecting piece 110. Side view. As shown in FIG. 6 and FIG. 7, the present invention is further characterized in that a groove 102a is formed at a position on the flow path plate 102 corresponding to the guide piece of the anode current collecting piece 11A, which causes the anode current collecting piece u (four) guide piece to be hidden. It can be tightly fitted and fixed on the flow channel plate 102. As shown in Fig. 8, the groove design of the present invention corresponding to the position of the guide U 〇 a can make the guide piece 110a, the adhesive material purchase, the lion and the flow channel plate 1 〇 2 better. Then, the problem of fuel external contact of the fuel cell can be effectively solved. See section 10®' for a side view of the cathode plate as illustrated by this hybrid. As shown in Fig. U), the cathode plate 12 includes a cathode collector region 12 and an electronic circuit required for the battery branch, and the surface of the cathode-transferred region 12G is particularly resistant to electrolysis. The cathode plate 12 adopts a method of conforming with a printed circuit board (PCB) process. The method comprises the steps of: dicing the substrate into a desired size, and then performing a drilling process on the cathode collector region 12G on the copper 'I substrate to form a drilling process. A plurality of perforations 120a. Preferably, the total area of all the perforations is about the left side of the cathode current collecting area—and then a chemical copper layer is deposited on the copper 4 substrate and the inner wall of the perforated 12〇a. Then, the resist is used on the copper substrate. Exposing the cathode current collecting region 12〇. Then performing an electroplating process, using a photoresist as a plating resist, in a region not covered by the photoresist, including a copper layer in the cathode current collecting region 120, and a copper layer in the copper layer The upper layer is plated with a tin-stacked layer. The photoresist is stripped off at the end of 2009. The copper-engraving process is performed to remove the copper layer in the area not covered by the tin-stagger layer and the copper on the copper plate. New, then another butterfly, private rhyme to remove this layer of tin. In order to avoid damage or short circuit on the substrate during the subsequent soldering process, it can be coated - anti-solder resist. Then - electro-elastic process, step on the electrode The mineral-layer protection system is a material such as city/gold, _ domain chemical silver, etc. A metal pattern 23〇 can be placed on the cathode plate 12, and the main purpose is as a fuel cell (the political heat five-genus pattern 230 can be dummy ( Dummy) A large-area metal pattern that can be any layer of copper in a multilayer circuit board. The metal pattern can also be used as an embedded active circuit, for example, integrated with an Energy Management System (EMs) circuit that controls the fuel cell, and its layout can be designed to control the functional requirements of the battery. The surface of the board 12 or (10) can be embedded in the electronic department 24 (), the electronic component 240 can include active or passive electronic components, such as capacitors, resistors, inductors, and integrated circuits, etc. according to actual needs. For example, the electronic component 24 can measure the battery temperature or have a short-circuit protection function. Please refer to the figure U, which is an exploded view of the battery module 13 according to another preferred embodiment of the present invention. As shown in the figure, the fuel cell module is mainly composed of a flow channel plate 102, an anode plate, a lower electrode plate 12, an adhesive material 104, and an array film electrode group 16. The difference from the fuel cell module 1 is that The flow channel plate 102 and the anode plate 1A of the fuel cell module la are not integrated. This allows the opening ratio of the collector region on the anode 200908427 plate 10a to be separately designed without considering the flow channel plate. The invention utilizes a circuit board or a metal collector sheet to form an electrode plate, which can make the design of the flow channel plate more versatile, and can design the flow channel plate with the demand of the touch or passive battery, without considering the membrane electrode _ support and current conduction. For example, the flow passage (4) may be of a thumb-and-shoulder type or a coil type. Further, the flow passage plate 1〇2 of the present invention may be a double-sided design or a single-sided design. The flow passage plate of the present (4) is removed. The body can be formed by injection molding technology, using a kind of polymer composite material which can be injection molded, for example, polyetheretherketone (PEEK), polyetherketoneketone (PEKK), poly % (p〇lysuif〇ne, abbreviated as psu), liquid crystal polymer (liquidcrystalp〇lymer, referred to as kiss, polymer plasticized substrate or composite material, etc.). Further, the above-mentioned injection-molded south molecular composite side may be a filler such as a modifier, a flow agent, a release agent or the like which is described in terms of a processing method in which a filler is injected. Substrate 14 is substituted. In Fig. 11, the adhesive material 1〇4 is a hot-press type which has good adhesion to the proton exchange membrane of the flow channel plate 1, the anode plate 1 , the cathode plate 12 and the array electrode group 16 . Sheet-like adhesives, for example, reg-adhesives, epoxy resins, co-adhesives or sm_ lines are fresh. Adhesive material 1〇4 has a corresponding ship opening. Of course, the adhesive material can also be pre-fixed as shown in Fig. 3. 200908427 Please refer to Fig. 12, which is a side view of the fuel cell module la of Fig. 11. As shown in Fig. 12, the anode plate pool comprises an anode current collecting area 〇 and a battery string surface f (four) sub-scale, which is formed by a method compatible with the electric process, including cutting and cutting the copper enamel substrate into a desired size. After that, the drilling process was carried out on the copper plate of the copper plate on the 31Q, and a plurality of perforations 3 were formed.杈佳者' The total area of all perforations accounts for approximately half of the cathode current collection area. A chemical copper layer is deposited on the copper wire plate and the inner wall of the perforated island. Then, the (4) pole current collecting area 3 〇 is exposed by a photoresist (dry film) on the copper box soil. Then, the electro-mineral reputation is used as a photoresist, and in a region not covered by the photoresist, including the anode collector region 3K, a layer of copper in the electro-mineral layer and a layer of tin on the copper layer are recorded. Then it will be stripped first. The etching process is carried out to remove the chemical copper phase and the auxiliary substrate in the area not covered by the tin-staggered layer. Money, and then p-process etched off the tin-lead layer.乂According to the invention, the anode plate can be made of soft board, hard board or soft and hard complex: =flexb◦ (4), wherein the anode board also includes a squeaking ear part, preferably, The conductive ear 31〇a is formed by a soft board, so that the battery strings of the module circuit are more uniform. Miscellaneous, touch circuit battery string and in addition to: to use the above-mentioned foldable conductive ear position to complete, you can also use the metal = _ secret welding _, the way _ is by wire == delete the film, First, the metal piece is concavely folded and then fixed by spot welding. However, it is a metal type that can be used directly. It can be used directly in the short time (because tin is also a kind of metal, it will be added with metal called 16 200908427); When it is possible to wire a wire object such as a wire, a conductive metal such as tin or the like is soldered (the soldering method is to pull the circuit to the edge of the board and use solder to achieve the string effect). The electrode plate made by the board technology of the present invention solves the problem of stringing between the battery cells of the planar fuel cell. Referring to Fig. 13, the fuel cell system of the present invention is shown in Fig. 13. The fuel cell system 4 is composed of a plurality of fuel cell modules la. A plurality of fuel cell modules & are fixed by means of a lock, such as a physical fitting such as a rivet or a screw. The fasteners pass through the corresponding through holes in the four corners of each fuel cell module la, and allow the gap between the battery modules to be held. The lock firmware 4〇2 can also be used as a conductive source for a plurality of fuel cell modules. ^然' fuel cell module ia can be from the picture in Figure 2
燃料電池模组1 # |L 、、 ° b卜’本發明簡電池模組可以配合各 種不同的㈣來使用，例如域或者甲醇燃料。 X上所述料本㈣讀佳實侧，凡 所做之均等變化錄& 个知乃甲π專利軌圍 隻儔，皆應屬本發明之涵蓋範圍。 【圖式簡單說明】 樣猶娜的爆炸圖 第一是第::中_池聽的組立圖。 中預固疋黏著材的爆炸圖。 200908427 第4崎示的是第丨圖中整合式陽極流道板的爆炸圖。 第5圖繪示的是第4圖中整合式陽極流道板的組立圖。 第6圖綠示的是本發明流道板之側視圖。 第7 _示的是第6圖的流道板加上集電片之後的側視圖。 第8圖綠補是導片及凹槽之剖面示意圖。 第9圖繪示的是陣賴電極組的上視圖。 第10圖為依據本發明較佳實施例所緣示的陰極板的側視圖。 〇第11圖為依據本發㈣—較佳實_輯料電池模組爆炸 圖。 、 =12圖為第u圖中燃料電池模組的陽極板側視圖。 第13 _示的是本發·料電池系朗組立圖。 【主要元件符號說明】 燃料電池模組 la 燃料電池模組 整合式陽極流道板 10a陽極板 陰極板 14 預固定黏著材 陣列膜電極組 16a 質子交換膜 流道板 102a 凹槽 黏著材 104b 黏著材 固定框 110 陽極集電片 導片 膜電極組 120 陰極集電區域 10 12 16 102 104a 108 110a 18 116 200908427 120a 穿孔 126 貫穿通孔 141 中間固定框 142 202 定位孔 230 240 電子元件 310 310a 導電耳部 320a 400 燃料電池系統 402 黏著層 金屬圖案 陽極集電區域 穿孔 鎖固件 ί 19The fuel cell module 1 # | L , , b b ' The battery module of the present invention can be used in combination with various (4), such as domain or methanol fuel. The material on the X (4) is read on the side of the best, and all the changes made by the directors are only covered by the scope of the present invention. [Simple description of the picture] The explosion diagram of the sample Iana The first is the group diagram of the :: _ pool listening. Explosion diagram of the pre-solidified adhesive material. 200908427 The fourth is the exploded view of the integrated anode runner plate in the second diagram. Figure 5 is a block diagram of the integrated anode runner plate in Figure 4. Figure 6 is a green side view of the flow channel plate of the present invention. Fig. 7 shows a side view of the flow path plate of Fig. 6 after the current collecting tab. Figure 8 is a cross-sectional view of the guide and the groove. Figure 9 is a top view of the electrode assembly. Figure 10 is a side elevational view of a cathode plate in accordance with a preferred embodiment of the present invention. 〇 Figure 11 is an exploded view of the battery module in accordance with the (4)-better. The =12 picture is the side view of the anode plate of the fuel cell module in Fig. u. The 13th _ shows the vertical battery diagram of the hair battery system. [Main component symbol description] Fuel cell module la Fuel cell module integrated anode flow channel plate 10a anode plate cathode plate 14 pre-fixed adhesive material array membrane electrode group 16a Proton exchange membrane flow channel plate 102a Groove adhesive material 104b Adhesive material Fixing frame 110 anode collector tab film electrode group 120 cathode collector region 10 12 16 102 104a 108 110a 18 116 200908427 120a perforation 126 through via 141 intermediate fixing frame 142 202 positioning hole 230 240 electronic component 310 310a conductive ear 320a 400 Fuel Cell System 402 Adhesive Layer Metal Pattern Anode Collector Area Perforated Lock Firmware 19 19