TW200907139A - Fabric care compositions - Google Patents

Abstract

Polyurethaneurea compositions in the form of powders and dispersions are provided for enhancing properties of washed fabric including easy care, better iron gliding, improved shape retention, perfume substantiation and stain management properties.

Description

200907139 IX. Description of the invention: [Technical field to which the invention pertains] Polyamine-based oximes having fabric care properties are included. The present invention also provides a knee-washing agent and a fabric softening agent, and a mouth softening agent, which comprises a polyamine <treatment group [Prior Art] A uremic urea-forming urea composition. == added to the detergent to impart a reduction in electrostatic adsorption, giving pleasure to... Less sensitive folds and easier to iron... Reduced ^, dried time, reduced - followed by time =. However, the benefit of these characteristics is usually that the == component is based on a long-chain fat called a quaternary compound = "quality is cationic. Therefore, it is soft to prevent the introduction of fabric during the period of substantially washable or dry = Looking at the reaction, usually in the fabric punching force = less time and cost of fabric washing county 'in the industry need to be compatible with the detergent composition. The industry also needs to be able to soften the fabric with the body The duration of the various benefits of ease of care and the use of an extended fabric care composition. [SUMMARY] The present invention provides a combination of a polyurethane-based fabric softener composition in the form of a powder or an aqueous dispersion. In a preferred embodiment, the fabric care composition is in the form of a nonionic film-forming dispersion comprising a polyaminocarbamic acid 123499.doc 200907139 urea polymer and water. The polymer prepolymer and the chain The reaction product of the water of the extender, wherein the prepolymer is a reaction of a mixture of a glycol or a plurality of diols with a polyisocyanate such as 4,4,-methylenebis(phenylisocyanate) Product. Another embodiment is a nonionic non-film-forming dispersion comprising water and a polyurethane urea polymer. The polymer is a reaction product of a prepolymer with a chain extender such as a diamine chain extender 'water and combinations thereof, wherein The prepolymer is a reaction product of a diol (polyol) or a mixture of a diol and a polyisocyanate (for example, 4,4,-methylenebis(n-iso-iso-acid). The polymer can then be converted. And grinding or spray drying to provide a powder. Yet another embodiment provides a method of extending the aroma or aroma of the fabric or garment. The method comprises contacting the fabric or garment with a scented oil and in the form of a powder or an aqueous dispersion. Polyurethane urea composition. The contacting can occur in a variety of ways including, but not limited to, the addition of sesame oil and polyurethane urea to a detergent or fabric softener prior to washing and/or drying the fabric. It is added directly to the wash water, or it is introduced directly or in combination with the fabric softener composition during the rinse cycle. Yet another embodiment provides a method of providing a desired property to a fabric or garment. This includes contacting the fabric with a polyurethane urethane in the form of a powder or an aqueous dispersion. The desired properties imparted to the fabric include, but are not limited to, shape retention, ease of care (i.e., easy ironing), and resistance to stationing. [Embodiment] The term "powder" as used herein means a particulate material composed of loose agglomerates of fine solid particles having a maximum diameter of less than i mm and a flat 123499.doc 200907139 average particle diameter of less than 100 μm. The term "film forming" as used herein means that the material is formed in the absence of other reagents. _ _ == The term used herein under synthetic conditions, • non-film forming, meaning that the material is not disclosed in the presence of other reagents. Conditions cannot be formed - continuous film forming conditions The term "fabric" as used herein means any woven, non-woven, knitted, tufted, fused, woven, or bonded material composed of fibers and/or yarn combinations.

These include, but are not limited to, those used for clothing (clothing), bedding, towels, and curtains. Hungry The term "fabric care composition" as used herein refers to any article that can be applied to fabrics, especially during fabric washing or drying, to impart beneficial properties to the fabric. These features include cleaning, removal, and, t'' monthly cloud degreasing/shell and clever stains, smoothing fabric hands, reducing electrostatic adsorption, imparting pleasant aroma, reducing drying time, and reducing wrinkles And make ironing easier. The polycarbamic acid-coating compositions provided herein provide f-like improved fabric shape retention characteristics as compared to currently commercially available fabric care compositions. In addition, it also provides fabrics with ease of care or ease of care. In other words, the fabric treated with the polyurethaneurea composition has less wrinkles after washing and is easier to iron. The polyurethane urethanes of certain embodiments also have surprisingly good water and oil absorption (especially when applied to fabrics). This is especially important for stain resistance. After the fabric is contacted with the polyurethane urethane composition of some embodiments, the polyurethane urethane will absorb moisture and oil from the source of the stain and thereby limit the absorption of the fabric itself. I23499.doc 200907139 The absorption characteristics of the polyurethaneurea composition' also contribute to the elongation of the aroma of the fabric that has been in contact with the composition. This is the result of absorption and subsequent gradual release of the urethane composition from the urethane composition. There are a range of fragrance materials in the industry that are well deposited or well retained on the polyurethane uret urea. Such materials include, but are not limited to, the following two categories, Class A and Class B, as set forth below. Class A. Hydroxyl material, which is the common logarithm of the octanol/water partition coefficient (p) (l〇gi.P) is 2.5 or more, and the gas chromatographic K〇vats index (eg for polydimethyl sch Oxygen is determined as a non-polar stationary phase) of at least 1 〇 5 〇 of alcohol, benzene or salicylate. The octanol-water partition coefficient (or its usual logarithm "l〇gP") has been well known in the literature as an indicator of hydrophobicity and water solubility (see 11 & 11^11 and 1^0, Chemical Reviews, 71, 526_616, (1971); Hansch, (^ with (10) and

Lawrence, J. Organic Chemistry, 33, 347-350 (1968)). When this value cannot be obtained from the literature, it can be measured directly or roughly estimated using a mathematical algorithm. Software providing such estimates is commercially available, for example, from Advanced Chemistry Design, 'LogP". Materials with a logio P of 2.5 or higher are quite hydrophobic.

The Kovats index is calculated based on the retention time of the alkane based on the retention time in gas chromatography measurements [see K〇vats, Helv. Chim. Acta 41, 1915 (1958)]. In the sesame oil industry, the index based on the use of non-polar stationary phase fragrant oil has been used as a descriptor for the molecular size and boiling point of the component for several years. The description of the Kovats index in the sesame industry by τ Shibamoto, 'Capillary Gas

Chromatography in Essential Oil Analysis", p Sandra and C 123499.doc 200907139

Bicchi (ed.) Huetig (1987), pp. 259-274. Suitable for the general non-polar phase system 100% dimethyl polyoxane, for example, under various trade names (eg RP-1 (Hewlett-Packard), cp Sil 5 CB (Chrompack), 〇Vl (〇hio Valley) ) and Rtx-l (Restek)). Low Kovats index materials are volatile and do not hold well on many fabrics. Class A includes alcohols having the formula R〇H, wherein the thiol group can be a primary, secondary or secondary transradical, and the R group is optionally branched or substituted, cyclic or acyclic. An alkyl or alkenyl group such that ROH has the partition coefficient and Kovats properties as defined above. The alcohol having a Kovats index of from 1050 to 1 600 is usually a monofunctional alkyl or aryl alkyl alcohol having a molecular weight of from 150 to 230. Class A also includes phenols of the formula Ar〇H, wherein the Ar group represents a bond which may be via one or more alkyl or alkenyl groups or via a group _C〇2A (wherein A is a hydrocarbon group) In this case the compound is a salicylate substituted benzene ring. Ar〇Ii has a partition coefficient as defined above and a K〇vats index. Usually, these Kovats coefficients are from 1 to 50 to 16 Å of phenolic monohydric phenol having a molecular weight in the range of 15 Å to 21 Å. An example of a class A sesame oil material is 1-(2,-tri-butylcyclohexyloxy)-butan-2-ol, 3-methyl-5-(2,,2|,3'-trimethylcyclo Pentyl-3-enyl)-pent-2-ol, 4-methyl-3-decene-5-alcohol, amyl salicylate, 2_ethyl_4_(2,,2,,3_3 Methylcyclopentazenyl)butane-2 -homyl alcohol, decyl alcohol, carnation, citronellol, 9-decane, dihydroeugenol, dihydrolinalol, dihydromyrcene Alcohol, dihydroterpineol, eugenol, geraniol, hydroxycitronellal, shuiyang 123499.doc 200907139 isovalerate, salicylic acid, .. " knowing 'isoeugenol, linalool , menthol, nerolitriol, neroli to di-butylcyclohexanol, phenoxyethyl hydrazine, ethenyl alcohol, tetrahydro citron, m ^ ν ” %, tetralinol, four Hydrogen lauryl alcohol, musk, 2_methoxy μf-based phenol, (4-isopropylcyclohexyl)-methanol, benzyl salicylate, salicylic acid, hexyl group, salicylic acid Hexyl ester, patchouli alcohol, and farnesol. ', Class B: S, ether, dark, ^^, ^ 鲷 or aldehyde, its octanol/water partition coefficient (P) hanging logarithm (l〇g1〇p) is 2 s ·+, s ^ ) horse 2.5 or more, and the gas chromatographic K〇vats index (eg for polydimethyl hydrazine/contained as a non-polar stationary phase) For the 1300 〇B type scented oil system has one wanted one, and the middle X can be in the first, second or

Tertiary, and one of the following groups: _c〇2A, Confucian, KN or -CHO. Group! ^ and A are cyclic or acyclic and optionally substituted tobacco residues. Typically, the K〇vats index does not exceed 16 单 between 16〇 and 230 monofunctional compounds. An example of a B-type scented oil material is J-based 1-methyl-4-(4-methylpentenyl)_3_cyclohexene small formic acid, hydrazine, dimethylcyclohexenyl) pentane-dione 2_heptylcyclopentanone, 2_methyl_3-(4,_t-butylphenyl)propyl, 2-methylundecanoic acid, 2_11 稀, 2,2~2 Methyl o-, -ethylphenyl-acid, 3-(4'-isopropylphenyl)-2-methylpropionic acid, acetic acid"-based 4-phenylpentan-2-yl vinegar, cyclohexylpropionic acid Dilyl propyl vinegar, cyclohexyloxyacetic acid allyl vinegar, bismuth benzoate s, methyl ethyl hydrazine trimer, diphenyl ig, 3 (4,. tri-butyl phenyl)-propionic acid , lavender, cis-jasmone, spirulina diethyl acetal, citronellal diethyl acetal, citronellyl acetate, phenylethylbutyl I23499.doc 200907139 ether, α-large Ketone, β-Damarone, δ-Damascone, γ_Damasolone, Dihydroisojasmonate, Dihydro Jasmine S, Dihydrofurfuryl acetate, Dimethyl ortho-benzoate , diphenyl ether, monophenylmethane, dodecanal, dodecene _2 aldehyde, dodecanenitrile, 1-ethoxy-1-phenoxyethane, 3 _(Γ_ethoxy ethoxylate Base)-3,7-dimercapto-1 6-diene, 4·(4,_methylpenta-3,-alkenyl)-cyclohex-3-enal, tricyclo[5.2.1.〇-2,6-]decane_2_decanoic acid Ethyl ester, 1-(7-isopropyl-5-nonylbicyclo[2.2.2]oct-5-en-2-yl)-e-ketone, allyl tricyclodecene ether, tricyclic guanidinium propionate Alkenyl ester, γ, undecanoic acid lactone, n-decyl-n-phenyl-2-mercaptobutylamine, tricyclodecenyl isobutyrate, geranyl acetate, hexyl benzoate, ionone α, violet S with β, isobutyl cinnamate, isobutylquinoline, iso-syringyl acetate, 2,2,7,7-tetramethyltricyclo eleven-5-one, tricyclodecene acetate Base ester, 2-hexylcyclopentanone, 4-ethenyloxy_3_pentyltetrahydropyran, ethyl 2-hexylacetate, 8-isopropyl-6-indenylbicyclo[2 2.2] Oct-5-ene-2-carbaldehyde, 4-isopropyl-1-methylbicyclo[2.2.2]oct-5-ene-2-carboxylic acid decyl ester, methyl cinnamate, alpha isomethylionone , decylnaphthyl ketone, neroli, azlactone γ, decyl acetate, acetic acid to tert-butylcyclohexyl ester, 4-isopropyl-1-indenyl-2-[1·-propenyl ]-Benzene, phenoxyethyl isobutyrate, phenylethyl isoamyl ether, phenylethyl isobutyrate, pivalic acid Terpene ester, phenylethyl pivalate, phenylacetaldehyde glycol acetal, 2,4-dimethyl-4-ylphenyltetradecyl, rose acetone, acetic acid, 4 - different Propyl_1_methyl_2_[1'-propenyl], benzene, 2-naphthylmethyl ether, (4-isopropylcyclohexadienyl) formate, pentyl cinnamate, amyl cinnamaldehyde , amyl cinnamaldehyde dimethyl acetal, cinnamic cinnamate, 1,2,3,5,6,7,8,8&_octahydro-1,2,8,8-tetramethyl_2_ Ethyl ketone, ring-1,13-extended ethyldioxytrisulphate_1,13-dione, ring fifteen inside 123499.doc -32- 200907139 6 hexyl cinnamic acid, 1,3,4, 6,7,8-hexahydro_4,6,6,7,8,8-hexamethylcyclononanthene [g] 2 benzene #比南, phenylacetate geranyl ester, &ethinyl isopropyl -2,3,3,5-tetramethyl diterpene, and u, 2,4,4,7_hexainyl 6-ethoxyl-1,2,3,4-tetrahydronaphthalene. Although this is in general agreement with spandex compositions - particularly good sesame oils and fragrances, it should be recognized that a variety of other sesame oils may also be used in this practice. The scented oil may include a substance or mixture of substances, including natural (ie, by flower, grass, leaf, cockroach... cockroach, bark, wood, flower or plant extract (mixture of different natural oils or oil components) and synthesis (ie, synthetically produced) Odor substance. A non-limiting list of emulsifiable aldehydes; m Μ 1 Table I includes hexyl cinnamaldehyde; amyl cinnamate salicylate; water stick 舻. _2 己 Sa Sa; terpineol; 7-dimercapto-cis' 2,6-octadiene _;!_ alcohol; 2,6-di-T base"2 · 辛Sj· ? 2,6 · first trial of its i jL·ene-2·alcohol 3,7-Dimethyl_3^,6-methyl-7-octene i π octanol; 3,7-dimethyl-trans-2,6-octadien-1-ol; , 7_ dimethyl ' ψ A , r 酉 酉 , 3,7-dimethyl-1-octanol; 2_ T-based-3-(p-tri-butyl ^ X. soil)-acrylic; 4_(4_hydroxy-4_methylpentylhexene-1-carbaldehyde._ a s pentyl W lane cut. Acid bicyclic terpene vinegar; acetic acid Cyclodecene ' 回 aldehyde; 2-methyl 2 _ (p-_ _. 3-f ^ -3- ...: "base brew; 4 _ (p- phenyl) phenyl) (A6, 6-three Methyl·2_顼^ Γ , -土)-2-butene·1-顚I丨--methoxybenzamine B,·p-methoxy-p-methoxy acid methyl ester.+ mt 3·oxo·cyclopentane carboxy oxime, eleven lactone γ, orange oil; clove oil. Ten...t 豕 oil, grapefruit oil; bergamot methyl γ; 2_(2-penta ··3·oxo-cyclopentyl)acetic acid r丞酉曰, β-naphtholmethylmethyl-β-naphthyl ketone; coumarin; furfural; benzene 123499.doc -13- 200907139 曱路, acetic acid 4-tert-butylcyclohexyl ester; α,α-dimethylphenethyl hydrazide acetate decyl phenyl orthoester; cyclic ethylene glycol diester of thirteen succinic acid; 3,7 _ dimethyl-2,6-octadiene-i-nitrile; ionone γ methyl; ionone α; sorghum, sulphur oil; methyl cedarone; 7-ethenyl_1 , 2,3,4,5,6,7,8-eight

Hydrogen-1,1,6,7·tetradecyl-naphthalene; ionone oxime; methyl-1,6,1〇-trimethyl-2,5,9-cyclododecatriene-1 -ketone; 7-ethenyl-I,1,3,4,4,6-hexamethylenetetrahydronaphthalene; 4·ethinyl-6-tri-butyl-1,1-dimethyl Dihydroanthracene; benzophenone; 6-ethyl fluorenyl group; mountain 弘 曱 曱 曱 二 dihydro hydrazine: ^ ethoxylated isopropyl-1,1,2,6-tetradecyldihydroanthracene; Dodecanal; 7-hydroxy-3,7-didecyloctanoyl; 1〇-undecene-1-aldehyde; iso-hexenylcyclohexylcarbaldehyde; formazan-based gangrene; Ester; 16_hydroxy_9_hexadecenolactone; 1,3,4,6,7,8-hexahydro_4,6,6,7,8,8-hexamethylcyclopentyl_7_2_ Benzopyran 4; ammonium; dodecaine_3a,6,6,9a_tetradecylnaphthalene-[2,lb]furan; Xuequan.,5-(2,2,3-two Methylcyclopenta-3-ene >3_methylpentane-2-ol; 2_ethyl 4 (2,2,3-methyl_3_cyclopentanyl)_2_butenol , syringenol, acetaminophen acetate; B-branched #— hexyl-p-butyl-butylcyclohexyl ester; Guanghuoxiang; frankincense rosin; labdanum; lane #,, fragrant oil; Cuba Balsam; eucalyptus; hydroxy citronella and ° quot ;|其七„ _ 土乙路 and 吲哚; geraniol; acetic acid fragrant leaves @旨, Chennaol; acetic acid which cool. m kg * ^ from the day, tetraterpene alcohol; citronellol; acetic acid Citronellol, dihydromyrcenol; ^ ® 夂 虱 虱 烯 ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; Phenylethanol; 2-phenylethyl acetate; benzyl alcohol. 7 deficiency - ^ 'Oxyl acetate; benzyl salicylate; benzyl benzoate; sulphate acetate; di A, ^ benzyl methanol; Phenyl tertiary methyl ethyl hydrazine dichloromethyl phenyl orthoester. , Ethyl sulphate; Acetyl acetate; Fragrance J23499.doc • 14- 200907139 Root alcohol ' 2 _ _ 3_ (for - Tert-butylphenyl)-propionic acid; 2-methyl-3-(p-isopropyl)phenylpropanal; 3-(p-tris-butylphenyl)-propanal; 4*A 3-pentenyl)_3_cyclohexenecarbaldehyde (I)-acetoxypentyltetrahydropyran^dihydrojasmine oxime acid; 2_n-heptylcycloindole _ ; 3-methyl_2 _Pentyl% pentanone, n-decanoic acid; Zheng 12; 9_chewing alcohol hexaisobutyric acid phenoxyethyl vine; phenylacetaldehyde dimethyl acetal; phenylacetaldehyde Ethyl acetal, geranyl nitrile: citronellin; cedar acetal; 3_isodecylcyclohexanol cedaryl methyl ^ long leaf simmered 回 回 carbonitrile; fennel; pepper acid; ; vanillic acid H Zhaojixiang Maojun ionone; f-based ionone; isomethyl violet if; ketone; 値彳 cis-3-hexenol and its ester; dihydro eucalyptus oil; tetrahydrogen Naphthoquinone scented oil; iso-dihydrobenzo-d-pyrene sesame oil; macrocyclic ketone; macrocyclic vinegar eucalyptus oil; brazil acid vinegar, and combinations thereof. The polyaminoglycines _ Ββ g , t , , j T acid urea of some embodiments may be in the form of an aqueous dispersion or powder. When a powder form is desired, 1" is separated from the aqueous bifurcated knife by filtration, drying and grinding or by a re-drying dispersion. For a film-forming or non-film-forming liquid, 'dispersion The solid content may vary. For example, the solid content may be from about 5% to about 50%, from about 2 ounces to about 40% by weight of the balsam pebbles, and the right, right, and right The liquid is from 32% by weight to about 37% by weight. The viscosity of the dispersion may also vary depending on the way. The viscosity example is suitable from about 4 叩 to about 36 cps, including self-approximately. 8. To about IN. Miscellaneous: When the dispersion is added to, for example, a detergent or a soft fabric, it is expected to have a similar texture to the fabric care composition:; the dispersion PH may also be used depending on its use - Where the fabric care composition is acidic, the pH of the field liquid to be added to the knife solution is 123499.doc -15-200907139 to acidic and it is expected to have a pH similar to the fabric care composition, Including pH 7 or lower, such as pH 2-4. To prepare an anionic film-forming aqueous dispersion of some embodiments, preparation is required. Prepolymers of blocked diols. Examples of suitable prepolymers are the following reaction products: at least one hydroxyl terminated polymer, such as a polyether (including copolyether), polycarbonate or a number average molecular weight of from about 600 to about a polyester polyol component of 3,5 Å, for example, a poly(tetramethylene ether) diol having a number average molecular weight of from about 400 to about 24 Å; a polyisocyanate of 4, 4 a mixture of -, and 2,4,-arylene-bis(phenylisocyanate S?) (MDI) isomers, wherein the ratio of isomers is from about 65:35 to about 35:65; and at least one a diol compound having the following groups: (1) a hydroxyl group reactive with a mixture of MDI isomers of a polyisocyanate and (ii) at least one carboxylic acid group capable of forming a salt upon neutralization, wherein the at least one carboxylic acid group cannot Reacting with a mixture of MDI isomers of polyisocyanate. The precursor is then neutralized by, for example, triethylamine to form a salt and finally chain extended using a diamine chain extender and water to form Aqueous dispersions, which may include, for example, surfactants, antifoaming agents/antifoaming agents, antioxidants, Additives such as thickeners and combinations thereof. The MDI isomer mixture used in the anionic dispersion can achieve a reduction in the viscosity of the prepolymer without adding a solvent. The MDI isomer mixture is also used to reduce the reaction rate. Prepared by a batch process or a continuous process. When the diol is included in some embodiments, an alcohol including a hydroxyl group and a carboxylic acid group 123499.doc 16 200907139 can be described as an acid diol. Examples of available acid diols include 2 , 2 - di-m-acetic acid, 2,2-dimethylolpropionic acid (]:) 1 ^ 1 > VIII), 2,2-dihydroxymethylbutyric acid, 2,2-monomethylvalerate And their combinations. The nonionic film-forming dispersion of some embodiments comprises a prepolymer which is an isocyanate-terminated polyurethane prepolymer. Examples of suitable prepolymers are hydroxy-J-based polymers (for example polyols such as poly(tetramethylene-co-extension ethyl ether)-alcohol or poly(tetramethylene ether) diol and ethoxylate The reaction product of a mixture of polypropylene glycol and a diisocyanate such as 4,4,-methylenebis(phenylisocyanate). The prepolymer chain is then extended with water and dispersed in water or dispersed in water to extend the chain with water. The nonionic non-film forming dispersion of some embodiments comprises a prepolymer of a monoisocyanate-terminated polyurethane urethane prepolymer. The prepolymer is also a reaction of a polyol such as polybutadiene diol or poly(tetramethylene ether) diol with a diisocyanate such as 4, methylene bis(phenylisocyanate). product. The prepolymer can be chain extended using water in combination with a diamine bond extender such as ethylenediamine or an amine-functional crosslinker such as polyethylene. A hydrophilic or hydrophobic diol can be selected to produce a polymer powder having different water/oil absorption capabilities. Further, the powder particle control can be carried out by adjusting the prepolymer viscosity η Ί 7'4 ^ ν ??? π 哔 哔 预 预 预 预 预 预 预 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 To prepare such dispersions, the water-cooled portion can be more completely dispersed before the chain extension reaction begins. For example... can: to about "" low, including about 7 ° C or lower. "Some examples of a variety of sources are used in the case of liquids, such as steaming water, deionized l23499.d〇c • 17- 200907139 water or ultrapure water. For non-film forming or film forming dispersions, dispersions The average particle size of the medium particles is variable. As described above, one of the factors affecting the particle size is the viscosity of the prepolymer. The other factor is the dispersion speed, which can be, for example, about 5, 〇〇〇 rpm. Up to about 〇, 〇〇〇 rpm 'includes 7, 〇 0 rpm. The particle size range of the dispersions and powders of some embodiments includes about 400 micrometers (μm) or less, such as from about 0.01 μm to about 0.5 μm, 0.1 μηι to about 1.0 μηι, about 01 μηι to about 5 μηηη, about 〇15 μιη to about 0.65 μιη, and larger particles (for example, from about 1 〇μιη to about 1500 μm). In some embodiments a polyamino phthalate urea powder by dispersing the isocyanate-terminated prepolymer with high shear force in an aqueous medium containing a dispersing agent, a chain extender or a crosslinking agent, with or without a solvent. Preparation. High shear force is defined as a force sufficient to cause particles to be no greater than 5 microns. The prepolymer may be composed of a polyol or a polyol copolymer or a polyol mixture (for example, a polyether diol, a polyester diol, a polycarbonate diol, a polybutadiene diol or a hydrogenated derivative thereof, and a hydrazine). The base end group polydimethyl fluorene is reacted with an isocyanate (such as methylene bis(4-phenylisocyanate) (MDI)) to form an nc〇_end group prepolymer or ''capped Glycol " to prepare. In the polymer composition, the molar ratio of NCO / 〇H is between 1.2 and 5. An example of a chain extending agent is an aliphatic diamine such as ethylenediamine (EDA). When cross-linking of the powder is desired, the chain cross-linking agent can be an organic compound or polymer having at least three "- or amine-functional amine groups" capable of reacting with the foot groups. Dissolved or not: the right 撼C of the glutinous rice in the water, y, the organic / mixture of y (such as 1_methyl 2- oxapyridone 123499.doc -18- 200907139 (NMP) or xylene) can be used in Dilute the prepolymer before dispersion. The formed polyurethane urethane polymer fine particles dispersed in water can be used as such or separated into a solid powder by drying and drying. Alternatively, a spray process that also provides higher particle size control can be used. Some implementations may have a particle size that varies depending on their expectations. For example, the average particle size may be less than 1 mm (峨), and # includes an average particle diameter of less than (10) microns (μιη). In some embodiments, the polyurethane used in the preparation of the elastomeric powder comprises: a) a polyol or polyol copolymer or a polyol ketone having a number average molecular weight of from 500 to 5 Å, It includes, but is not limited to, polyttanol, polyglycol diol, poly lysine diol, polybutadiene diol or its chlorinated derivative, and base-based polydimethyl oxalate; b) Anisotropic acid vinegar, pots of t aliphatic diisocyanate, aromatic diisocyanate, cycloaliphatic diisocyanate, and c) aliphatic diamine (gp, _ (an amine chain) An extender) or a mixture or at least one amine-terminated polymer selected from the group consisting of aliphatic diamines and cycloaliphatic diamines G, each having from 2 to 13 carbon atoms. Or an organic compound or polymer having an organic hydrazine b to a primary or secondary amine group; and optionally, as a chain terminator. Examples of polyols that can be used in a certain class of A, 丨-&... include those having two or more of them, which are known from epoxy epoxide, tetrasulphate岵咗π oxime, oxyfuban, and 3_yinyl tetrahydroanthracene are obtained by ring-opening polymerization and/or copolymerization, or from multiple (four) (10), for example, every 12 carbon precursors have an iq /butanol or diol mixture, such as ethylene glycol, propylene, butylene glycol, hydrazine, 5-decanediol, hexanediol, neodecanediol, 123499.doc -19· 200907139 3-methyl-1, Polycondensation of 5-pentanediol, 1,7-heptanediol '1,8-octanediol, 1; 9-nonanediol, 1,10-nonanol and 1,12-edecyl alcohol obtain. By way of example, it may include a straight chain, difunctional polyether polyol, especially a poly(tetradecyl sulfonium 1) diol having a molecular weight of from about 1700 to 2100, such as a functionality of 2

Terathane® 1800 (available from Invista Si r.l· 〇f Wichita, KS and

Wilmington, DE). Other examples of commercially available polyether polyols available on the market are Acclaim® 4220N from Bayer, Pittsburgh, PA and PLURACOL® 1062P from BASF, Wyandotte, MI. Other useful polyols include, inter alia, copolymers of tetrahydrofuran and ethylene oxide, and copolymers of acetylene and private emulsions. More than one type of polyol can be combined to provide the polyurethane urethane compositions of certain embodiments. For example, when two different polyols are used, they should be combined in a ratio of from about 25:75 to about 75:25 (including about 40:60 to 50:50). Examples of polyether polyols which may be used include those ether diols having two or more hydroxyl groups which may be formed by aliphatic polycarboxylic acids and low molecular weight having not more than 12 carbon atoms per molecule. It is prepared by polycondensation of a polyol, or a mixture thereof. Examples of suitable polycarboxylic acids are malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid 'undecane monocarboxylic acid and dodecanedicarboxylic acid. Polyols suitable for the preparation of polyether polyols are exemplified by ethylene glycol, 1,3-propanediol, butanediol, [,5-pentanediol, 1,6-hexanediol, neopentyl glycol, 3_methylpentanediol, L7-heptanediol, 1,8-octanediol, itodiol, iota, 1 庚 heptanediol, and i, l2 dodecane disaccharide. For example, a linear, difunctional polyether polyol having a melting temperature of from about 5 〇c to about 5 (rc) can be included. Examples of polycarbonate polyols that can be used include 123499.doc -20- 200907139 a carbonate diol having two or more trans-bases which is lower by phosgene, gas phthalate, dialkyl carbonate or dipropylene carbonate with no more than 12 carbon atoms per molecule A polycondensation of a molecular weight aliphatic polyol, or a mixture thereof, is prepared. Examples of polyols suitable for use in the preparation of polycarbonate polyols are diethylene glycol, 1,3-propanediol, M-butanediol, i,5-pentane Alcohol, 150_hexanediol, neopentyl glycol, 3-mercapto-1,5-pentanediol, I?·heptanediol, •octanediol, i,9_

Decylene glycol, U0-heptanediol and U2·dodecanediol. For example, a melting temperature of about 5 t; to about 5 (TC's linear 'bifunctional polycarbonate S' polyol may be included. An example of a suitable diisocyanate component is 1,6-hexamethylene diisocyanate, hydrazine, 12_Dodecane diisocyanate, isophorone diisocyanate, trimethyl-hexamethylene diisocyanate, 2-methylpentane, diisocyanate, cyclohexane diisocyanate, methylene double (4 _cyclohexyl isocyanate), tetramethyl-xylene diisocyanate, bis(isocyanatoinyl)cyclohexane, toluene diisocyanate, methylene bis(4-phenylisocyanate), phenylene a mixture of diisocyanate, xylene diisocyanate, and such diisocyanates. For example, the diisocyanate may be an aromatic diisocyanate, such as phenyl diisocyanate, Toluene diisocyanate γΤητ, cyanide day (TDI), xylylene diisocyanate, biphenyl diisocyanate, stilbene diisocyanate, diphenylmethane diisocyanate S (MDI) (including 4, 4,_methylenebis(phenylisocyanate), 2,4'-methylenebis(phenyliso)醆 wine), and combinations thereof), and - a combination of two or more different cyanate esters suitable diamine component (diamine chain extender) of 1,2-propylene diamine-based examples

• 2K 123499.doc 200907139 1,4-butanediamine, amine, 1,3-propanediamine, 2,2-didecyl-153-propylenediamine, 1,5-pentanediamine, hexamethylene Diamine, 1,7-heptanediamine, -octanediamine, 1,9-nonanediamine, u〇j diamine, dodecanediamine, mercapto], 5·pentanediamine, cyclohexane Amine, cyclohexane bis(methylamine), isophoronediamine, xylylene diamine, and methylene bis(cyclohexanediamine). It is also possible to use two or more: a mixture of amines. As mentioned above, water can also be included as a bond extender.

Examples of suitable amine-terminated polymers are poly(3-aminopropyl) end group polydimethyl methoxy alkane, amine end group poly(acrylonitrile-co-butadiene broad bis(mono)-amine group Poly (ethylene glycol) end group poly(ethylene glycol), bis(2-aminopropyl) end group poly(propylene glycol), and bis(3-aminopropyl) end group polytetrahydroethylene. Examples of suitable organic compounds or polymers having at least three primary or secondary amine groups are anthracene-2-aminoethylamine, poly(decylamine) dendrimer, polyethyleneimine, Poly(vinylamine), and poly(propyleneamine). Examples of suitable monoamine components include primary alkylamines (such as ethylamine 'butylamine, hexylamine, cyclohexylamine, ethanolamine, and 2-amino-2-methyl-oxime-propanol), and secondary two Alkylamines (such as N,N-diethylamine, N-ethyl·anthraceneamine, quinone diisopropylamine, hydrazine-tertiary-butyl-hydrazine-methylamine, hydrazine_third-butyl-hydrazine) _ 节 、, Ν, Ν-dicyclohexylamine, Ν-ethyl Ν 异丙 isopropylamine, hydrazine tert-butyl isopropylamine, hydrazine-isopropyl-hydrazine-cyclohexylamine, hydrazine ethyl Ν _cyclohexylamine, hydrazine, hydrazine-diethanolamine, and 2,2,6,6-tetramethylhexahydropyridine). In the manufacture of the polyurethane urethane powder of certain embodiments, the diol is first reacted with a diisocyanate in the presence of a catalyst as appropriate to form an NCO-terminated prepolymer or "blocking diol" This reaction is usually carried out by heating in a homogeneous blending mixture of molten form I23499.doc -22-200907139 at a temperature of 45 to 98 t for 1 hour to 6 hours. The amount of each reaction component is the weight of the diol ( The weight of Wgl) and diisocyanate (Wdi) is adjusted by the capping ratio (CR), which is defined as the molar ratio of monoisocyanate to diol as follows: CR=(Wdi/MWdi) /(Wgl/MWgl) wherein Wdi is the molecular weight of the diisocyanate and the amount of the "diol" is the average S. According to the invention, the end capping ratio is between 12 and 5 Torr, especially between 1.5 and 3.0. The capping reaction is completed when all of the hydroxyl groups (_〇H) from the diol molecule are consumed by the isocyanate (-NCO) group from the diisocyanate to form a urethane bond, thereby forming a terminal NC thiol group. A viscous polyamino phthalate prepolymer. This prepolymer is then added and dispersed into an aqueous solution containing a surface active agent such as a dispersing agent and an antifoaming agent/antifoaming agent, and optionally a chain extender such as a diamine. Alternatively, it may be diluted with an organic solvent such as water-soluble N-methylpyrrolidone (NMP) or water-insoluble xylene before the prepolymer is dispersed in an aqueous medium. The solid polymer particles are formed under high shear under a period of dispersion and elongation of the chain with water and/or diamine. These polyaminophthalate urea particles can then be filtered and dried. The polyaminophthalate urea compositions prepared by the above process surprisingly have good water and oil absorbency, especially when applied to fabrics. This is especially important for stain resistance. After the fabric is contacted with the polyurethane urethane composition of certain embodiments, the polyurethane urethane causes the source to absorb moisture and oil from the dye point and thereby limit the absorption of the fabric itself. Due to the absorption characteristics of the polyamino phthalate urea composition, it also contributes to the extension of the aroma of the fabric in contact with the composition. 123499.doc -23- 200907139 = aroma of the fabric in contact with the composition. The absorption of the eucalyptus composition and the subsequent gradual release of the knot: the fabric care composition of the embodiment may comprise a polyamine compound which may be added to the sputum-a brain, and The acid (iv) composition may also be in the form of a dispersion or a powder, etc. 'This polyaminocarbazide is intended to serve the person* 〆 ^ ^ 接 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加 添加(for hand washing), or to automatic drying. Alternatively, the powder or dispersion can be used as a substitute for a fabric softener to impart stain resistance to the garment by household washing. Fabric softeners are often used to impart a taste or aroma and secondly to impart softness to the fabric. The softening of the fabric is not necessary when using the drum to dry. This is because the drum-dried fabric is very soft. The detergent compositions of certain embodiments typically comprise anionic, nonionic, S-alkaline or amphoteric surfactants or mixtures thereof and often additionally comprise an organic or inorganic builder. Fabric softeners typically include an active ingredient such as a quaternary ammonium salt. Examples of the acyclic quaternary ammonium salt include tallow trimethylammonium chloride; ditallow dimethyl ammonium sulfate; ditallow dimethyl ammonium methyl sulfate; hexadecyldimethyl chloride Ammonium, di(hydrogenated tallow) dimethyl vaporized ammonium; octadecyldiindenyl ammonium hydride, diicosyldimethylammonium chloride; didocosyldimethyl Base gasification ammonium; di(hydrogenated tallow) diinocyl ammonium methyl sulfate; tens/, alkyl diethyl chlorinated, · cetyl dimethyl ammonium acetate; ditallow dipropylene Ammonium phosphate; ditallow dimethyl ammonium nitrate and bis (coco® alkyl group) di-T-chloride. 123499.doc _24· 200907139 Other optional group wounds of fabric care compositions of certain embodiments that are conventional in nature are generally from about 〇1% to about 10% by weight of the composition or dispersion. .5 to about 5%, and including from about 2% to about 4%). Such optional components include, but are not limited to, colorants, perfumes, bacterial inhibitors, photoinhibitors, opacifiers, viscosity modifiers, fabric treatments in solid form such as clay, fabric absorption enhancers, emulsifiers, Stabilizers, shrinkage control agents, spot removers, fungicides, fungicides, anti-corrosion agents, and the like. Examples of other additives include preservatives (such as lactic acid), antioxidants, pigments, colorants, sesame oils, antimicrobial agents (such as silver), active ingredients (wetting agents, UV-masks), surfactants, antifoaming agents. / antifoaming agent, solvent and the like 'this f can be in the pre-dispersed, fresh, or post-human polyurethane urethane composition. Any active substance may be used alone or in combination with other similar or dissimilar types of additives. For example, t, suitable surfactants include those constructed by Stepan Inc.' Northfield, IL under the trademarks SOFT® and Stepante, and those purchased from KA〇 Co., Ltd. as Ding. Combinations of such surfactants can be used in any suitable amount, such as a 50/5 blend. The fabric care compositions of the present invention can be prepared by conventional methods. No need to homogenize. A convenient and satisfactory method is to prepare a pre-mix of the softener in water at about i 5 Torr and then add it to the hot water solution of the other components. The temperature sensitive component can be added after the fabric treatment composition has cooled to about . The fabric care compositions of certain embodiments can be used by a rinse cycle that is added to a conventional household laundry operation. Alternatively, the fabric care compositions can be added directly to the fabric, part or directly or hand-washed until the wash is added to the detergent prior to the wash cycle, as a detergent or fabric softening composition in water, 123499.doc -25-200907139 . Therefore, the fabric care composition J is to be applied in a form known per se, such as a powder, a liquid, a solid tablet, an encapsulated liquid (for example, a composition of polyvinyl alcohol encapsulated), or an automatic dryer is used. In the case of application without a fabric sheet. The fabric care compositions of certain embodiments can be added in any amount needed to achieve the desired properties of the fabric. For example, the fabric care compositions can be from about 5% to about 5% by weight of the aqueous rinse bath or wash water! 5% (for example, about 0.2% to about 1%) is added in an amount. The polyurethane urethane composition of certain embodiments may be present in an amount of from about 1% to about 鸠 (for example, from about 5 to about 5% by weight of the fabric care composition) when present in an aqueous dispersion. In fabric care compositions. When present in the form of a powder, the polyurethane urethane composition can be from about 0.1% to about 2% by weight of the fabric care composition (for example, from about 5% to about 1%, or about From 1% to about 5%) is present in the fabric care composition. Alternatively, the polyurethane urea powder or dispersion can be added as a substitute for the fabric care composition rather than as a component of the fabric care composition, wherein the polyuretic acid S urea composition can be added at 0% . In this case, the polyurethaneurea composition may be from about 0.05% to about 1.5 Å/0 (specifically, from about %2% to about 1%) by weight of the rinse water or wash water. The amount is added directly to the wash water or rinse water. The features and advantages of the present invention are more fully shown by the following examples, which are not intended to be construed as the description. The blocked diol prepolymer, which is formed in any way to limit the surface of the invention (provided by Invista, Γ丄) and 1 tidy 125 and has a capping ratio of 1 is obtained from a pilot LYCRA® spandex line. Lycr^

EXAMPLES Example 1 A registered trademark of Spandex by Terathane mvista. 3 g of this prepolymer was mixed with 15 g of NMp solvent in a -plastic bottle for 1 G minutes to reduce the viscosity. The diluted mixture is poured into a steel tube to be poured into a stainless steel container for dispersion. The vessel contained 2000 grams of deionized water, 3 gram of DET Nm surfactant (Harcors available from Kansas City, Kansas) and 4.5 grams of ethylenediamine chain extender, which were premixed and cooled to 5. Hey. The diluted prepolymer was injected at about 40 psi with a tube of 1/8 inch internal diameter under air pressure into a laboratory disperser operated at 5 rpm (model hsm1〇〇lc, purchased from

Hauppauge, Charles Ross & Son Company, New York). The addition of the diluted prepolymer was completed within 15 minutes, and the resulting milky white dispersion was further dispersed for 5 minutes. The reverse weighing of the vessel gave a total of 328 grams of the diluted capped glycol added to the dispersion, corresponding to the addition of 2 1 8.7 grams of blocked diol prepolymer to the dispersion. Add 3 grams of Additive 65 bubble control agent (from Dow Corning, Midland, Michigan) to the dispersion and mix the dispersion at 5000 rpm for 30 minutes, then pour into a plastic bottle and analyze with Microtrac X100 particle size. The instrument (Leeds, Northrup) was determined to have a mean particle size of 52.83 microns and 202.6 microns. Example 2 The same ingredients and dispersion procedure as in the real m were used except that the diluted prepolymer was dispersed in the water mixture and 4.55 g of ethylenediamine chain extender was added. The reverse weighing of the vessel gave a total of (2) grams of the diluted capped glycol added to the dispersion, corresponding to the addition of 219 grams of capped glycol prepolymer to the dispersion. The average particle size of the dispersion was determined to be 33, 45 μm, and the particles were smaller than 64.91 彳. No solid film is formed when the solid polymer particles are separated. Example 3 'The capped glycol prepolymer was passed through 500 g of Kras〇l® HLB 2000 diol (provided by Extern, PAiSartomer Ltd. 1 25 MDR at 90 C in 2000 ml equipped with a heating jacket and mechanical stirrer) The reaction was carried out by reacting in the dad for 120 minutes. The reaction was carried out in a nitrogen-filled dry box. After the reaction, the prepolymer had a hydroxyl group of 298% by weight, as determined by titration. Pour into a steel tube to be poured into a stainless steel container for dispersion. Deionized water (2 gram) and 30 grams of T DET N14 surfactant at room temperature (Harscos from Kansas City, Kansas) And 3 grams of Additive 65 foam control agent (available from Dow Corning, Midland, Michigan) was mixed in a container. The prepolymer was injected at about 80 psi with a tube having an inner diameter of 1/8 inch under air pressure. High-speed laboratory disperser (model HSM-100LC, available from Charles Ross & Son Company, Hauppauge, New York) running at 5000 rpm. Adding the diluted prepolymer in 15 minutes, the resulting milky white 123499.doc -28- 200907139 Dispersion Disperse for 5 minutes. The reverse weighing of the container gives 422 grams of the total amount of diluted capped glycol added to the dispersion. 4. 5 grams of ethylenediamine chain extender is added to the dispersion and the mixture is The mixture was further mixed for 30 minutes at 5 rpm. The average particle diameter of the resulting dispersion was determined to be 49.8 1 μm, of which 95% of the particles were less than 3 〇 9.7 μm. Example 4 The procedure was the same as in Example 3 except that 250 g was used. A mixture of Terathane® 1800 diol and 250 grams of Krasol® HLB 2000 diol to form a prepolymer. A total of 465 grams of prepolymer was dispersed. The average particle size of the resulting dispersion was determined to be 13.67 microns, 95 of which % of the particles are less than 38.26 microns. Example 5 Prepolymer preparation was carried out in a glove box with a nitrogen atmosphere. Pyrex® equipped with an air pressure driven stirrer, heating jacket, and thermocouple temperature gauge to 2000 ml The glass reactor was filled with approximately 382.5 grams of Terathane® 1800 diol (available from lnvista, r丄, Wichita, Ks) and approximately 12.5 grams of 2,2-dimethylolpropionic acid (〇河卩八). This mixture is heated to about 5 (TC, then added 105 g Lupranate® MI diisocyanate (commercially available from BASF, Wyandotte, Michigan). Then while continuing stirring away reaction mixture was heated to about 90. (: and at about 90. (: for about 120 minutes, after which the reaction is completed, at which time the % of the mixture is reduced to a stable value, which is consistent with the calculated value of the prepolymer having isocyanate end groups (% NCO) The target value is 1.914. The viscosity of the prepolymer is about 40 for the general method of astm D1343-69. (: DV-8 type ball viscous meter (sold by Duratech, Waynesboro, VA_) Blocking two 123499.doc • 29- 200907139 The total isocyanate content of the alcohol prepolymer (in weight percent of NCO groups) is determined by S. Siggia, "Quantitative Organic Analysis via

Functional Group" ' Third Edition, Wiley & Sons, New York, pp. 559-561 (1963), the entire disclosure of which is incorporated herein by reference. Example 6 A solventless prepolymer prepared according to the procedure and composition described in Example 5 was used to produce an aqueous polyurethaneurea dispersion of the present invention. A 2,000 ml stainless steel beaker was filled with about 700 grams of deionized water, about 15 grams of sodium dodecyl benzoate (SDBS), and about 1 gram of triethylamine (TEA). The mixture was then cooled to about 5 with ice/water. The mixture was mixed with a still shearing laboratory mixer (Ross, Model 100LC) having a rotor/stator mixing head at about 5, rpm for about 3 seconds. The viscous prepolymer prepared by the method of Example i and contained in the metal tubular circle was simultaneously applied to the bottom of the mixing head in the aqueous solution by means of a flexible tube while applying air pressure. The prepolymer temperature is maintained between about 5 ° C and about 70 ° C. The extruded prepolymer stream was dispersed and the chain was extended with water with continuous mixing at about 5 rpm. A prepolymer having a total amount of about 540 g was introduced and dispersed into water in about 5 minutes. Immediately after the prepolymer was added and dispersed, about 2 g of AddiUve 65 was filled into the dispersion mixture (purchased from

Dow Corning®, Midland Michigan). The reaction mixture was then mixed for a further 30 minutes, followed by the addition of about 6 grams of diethylamine (DEA) and additional mixing. The resulting solvent-free aqueous dispersion is milky white and stable. Example 7 125MDR (available from Dow Corporation from Terathane® 1800 diol and Is〇nate® 123499.doc -30-200907139, Midland, Michigan) and a 1 688 capping ratio of the succinyl alcohol prepolymer system From the commercial LYCRA® spandex production line. LYCRA® is a registered trademark of Inv1Sta's spandex. Mix 3 g of this prepolymer with 15 g of NMP in a plastic bottle for a few minutes to reduce the viscosity. The diluted mixture is poured into a steel tube to be poured into a stainless steel container for dispersion. The volume contains 2000 grams of deionized water, 3 grams of τ DET N14 surfactant (purchased from Kansas City, Kansas, Harcr〇s) and 3 grams of ethylenediamine chain extender, which are premixed and cooled to 5 ° c. The diluted prepolymer was injected into a high speed laboratory disperser operating at 5 000 rpm with a diameter of 1/8 inch at about 40 psi under air pressure (model hSm-1〇〇LC, available from Hauppange , Charles R0SS & Son, New York.) The addition of the diluted prepolymer was completed in 15 minutes, and the resulting milky white dispersion was further dispersed for 5 minutes. The reverse weighing of the vessel gave a total of 347 grams of the diluted capped glycol added to the dispersion, corresponding to the addition of 23 1 grams of the capped glycol prepolymer to the dispersion. 3 grams of Additive 65 foam control agent (available from Dow Corning, Midland, Michigan) was added to the dispersion and the dispersion was mixed for another 3 minutes at 5000 rpm and poured into a plastic bottle. The average particle size of the dispersion was determined to be 32.59 μm by using a ^100 particle size analyzer (1^6(18,]^〇1^1>1;11)), wherein 95% of the particles were low. At 65.98 microns, the solid prepolymer particles were rinsed three times with a Buchner funnel and Whatman® crepe paper under low pressure and dried at 60-651 for 4 hours. The particles were filtered or dried. No film is formed during the period. With the laboratory Waring® mixer (by Dynamics, New

Hartford, Connecticut, manufactured by Blender 700 33BL79) easily 123499.doc -31 · 200907139 The dried filter cake can be ground into fine powder using conventional dry welding ~, in practice, 忒 special solid particles such as by fog drying) directly Separation from the dispersion. The sub-quantity and 85,200 丄"^ dry ends have a weight average molecular weight of 352,550 and an average molecular weight of 85,200. Knife Example 8 The same components and dispersion procedures as in Example 7 were used, except that the solvent of the long "diol prepolymer was changed to trimethylbenzene and the amount of the ethyl extender was increased by $4 ς ^ month female chain... 曰Up to 4.5 gram. The reverse weighing of the container results in the diluted end-capped second-knife alcohol prepolymer added to the dispersion, 339 grams, which is equivalent to 226 grams of the end of the two The material is added to the dispersion. The average particle size of the nitrogen-measuring dispersion is 22 88 μm, and the outer particle is 6.97 μm. The solid polymer particles are not formed into a film when separated. Example 9 Use and Example of 9 The same components and dispersing procedures in 7 except that the female model chain extender of the month is replaced by an equivalent amount of the branched polyethylenimine (determined by Μη, which is obtained from Yangdi). Reverse weighing gives the total amount of diluted capped glycol added to the dispersion 34 g, which corresponds to the addition of 227 g of capped glycol prepolymer to the dispersion. '...then the dispersion The average particle size is 58.12 microns, of which 95% of the particles are small; 8.5 microns. The solid polymer particles do not form a film when separated. 10 Prepare the prepolymer using a glove box with a dry nitrogen atmosphere. Fill the two separate: 2000 ml Pyrex® glass with an air pressure driven stirrer, heating jacket, and thermocouple temperature detector. 22 gram 123499.doc •32- 200907139

Terathane 1 800 - 舻广诚 & τ, - alcohol (available from Invista) and 220.0 grams of Pluracol® HP 4000D diol (from ba ςρ, 目BASF) ° while mixing the diol mixture to 50 C, Add 75 〇 3 g 125MDR after Ik (purchased from

Chemical). The reaction mixture was then heated to 卯 C while continuing to stir and maintained at 9 G C for 12 G minutes. The samples were taken from the reactor and determined to have 2.170 and 2.169% NCO, respectively, as by S. Siggia, Quantitative Organic Analysis via Functional Group", Second Edition, Wiley & Sons, New York, pages 559-561. Measured by the method of (1963). Fill a 3 000 ml stainless steel beaker with 16 g of deionized water, 15 g of τ DET N14 surfactant (purchased from Kansas Chy, Kansas Harcr〇s) and 5 g of Additive 65 (purchased from Dow Corning). The mixture was then cooled to 10 with ice/water. (: and mixed with a high shear laboratory mixer (Ross, Model 100LC) with a rotor/stator mixing head at 5000 rpm for 30 seconds. The viscous prepolymer prepared in the two reactors as above was poured into a metal tubular cylinder and added to the bottom of the mixing head in the aqueous solution by means of a flexible tube while applying air pressure. The temperature of the prepolymer was kept at a temperature. 50-70. (Between: The extruded prepolymer stream was dispersed and chain extended with water at 5000 rpm with continuous mixing. In a total of 6 16 g of prepolymer introduced and dispersed in 5 minutes To the water. Prepolymer addition After dispersion, the dispersion mixture was further mixed for 4 minutes. The resulting solvent-free aqueous dispersion was milky white to pale blue with a solid content of 28.84% by weight and a viscosity of 44 centipoise. The dispersion was washed in 1 estro It was dried on-chip and in a ventilated kitchen under ambient conditions to form an elastic continuous film. The weight of the enamel was 127 9 123 by the GPC measurement. 123499.doc • 33- 200907139 The average molecular weight and 41,000 Number average molecular weight. Example 11 Procedures and conditions were essentially the same as in Example 10 above, except that the surfactant was changed to Bio-soft® Nl-9 (purchased from Stepan of Northfield, Illinois). There will be 2.1 56 from both reactors. And 2.136% NCO total 640 grams of prepolymer dispersed into water. The resulting solvent-free dispersion has a solids content of 26.12% and a viscosity of 51 centipoise. The cast and dried elastic film has a weight average molecular weight of 133,900 and Number average molecular weight of 44,400. Example 12 A prepolymer was prepared using a glove box with a dry nitrogen atmosphere. Two separate air-driven agitators, heating jackets, Each filled the 2,000 ml glass reactor pyrex® thermocouple temperature measuring device measures the 440.0 g

Terathane® 1800 diol (available from invista) and 440.0 grams of Plurac〇i® 1〇62 diol (available from BASF). This diol mixture was heated to 5 〇 C ' while stirring, followed by the addition of 150.0 g of Isonate® 125 MDR (available from Dow Chemical). The reaction mixture was then heated to 卯 ° C while continuing to stir and maintained at 90 ° C for 120 minutes. The sample was taken out of the reactor and determined to have about 2% NCO, respectively, as by s· Siggia,” Quantitative

Organic Analysis Via Functi〇nal Gr〇up", Third Edition, Wiley &

Sons’ New York, pp. 559_561 (1963) measures. Fill a 3000*l stainless steel beaker with 15 grams of water to about ultrapure water, 25.9 grams of Bi0-S0ft® Ν25·9 and 25 9 grams of stepantex<& ντ_9〇 (both from Stepan) and 1 Add克 Additive 65 (given from D〇w and then used - high shear laboratory with rotor with sub-mixing head 123499.doc 34, 200907139 mixer (Ross 'l〇〇LC type) mix this mixture at 7000 rpm 30 The viscous prepolymer prepared in the two reactors as above was poured into a metal tubular cylinder and added to the bottom of the mixing head in the aqueous solution by means of a flexible tube while applying air pressure. The temperature of the prepolymer was kept at Between 5〇_7〇. The extruded prepolymer stream was dispersed and subjected to chain extension for 2 minutes with continuous mixing at 7 rpm, after which 2.33 g of PURAC® lactic acid preservative was added. The solvent-containing aqueous dispersion was milky white to light blue with a solids content of 35% by weight.Example 13 A prepolymer was prepared using a glove box with a dry nitrogen atmosphere. Two separate air pressure driven agitators were provided. , heating jacket, and thermoelectric The temperature measuring device's 2000 ml Pyrex® glass reactor was filled with 440.0 g of Terathane® 1800 diol (purchased from invista) and 44 〇 (^plurac〇1® 1〇62 diol (purchased from BASF). The diol mixture was heated to 5 ° C. Then 150.0 grams of lsonate® 125MDR (available from Dow Chemical) was added. The reaction mixture was then heated to 9 ° C while maintaining stirring at 90 ° C for 120 minutes. The sample was taken out of the reactor and determined to contain 2% NCO, respectively, by S. Siggia,

Quantitative Organic Analysis via Functional Group", Second Edition, Wiley & Sons, New York, pp. 559-561 (1963). Fill 15 ml of stainless steel beaker into a 3000 ml to cool to about 1 (Γ (: ultra pure water, 25.9 g is 0-8 〇 anti-> 125_9 (purchased from 邛 scratch company) and 25 9 g

Tetranyl® L1/90L (available from Kao Corporation) and 10 grams of Additive 123499.doc -35- 200907139 65 (available from Dow C〇rning). This mixture was then mixed at 7 rpm for 30 seconds using a high shear laboratory mixer (R〇ss, just LC type) with a rotor/stator mixing head. The viscous prepolymer prepared in the above two reactors was poured into a metal tubular round crucible and added to the bottom of the mixing head in the aqueous solution by means of a flexible tube while applying air pressure. The prepolymer temperature is maintained between 50 and 70 °C. The extruded prepolymer stream was dispersed and subjected to chain extension for 2 minutes with continued mixing at 7 Torr. Thereafter, 2 33 g of PURAC lactic acid preservative was added. The resulting solvent-free aqueous dispersion was milky white to light blue, which had a solids content of 35 wt%. Example 14 A prepolymer was prepared using a glove box in a dry nitrogen atmosphere. Filled in two separate 2000 ml Pyrex® glass reactors equipped with air pressure driven agitators, heating jackets and thermocouple temperature gauges, each filled with 44 〇 gram

Terathane 1800 - Alcohol (from Invista) and 440.0 g Acclaim® 4220N (available from Bayer). While stirring, the diol mixture was heated to 5 ° C. Then 150.0 g of Isonate® 125 MDR (purchased from Dow) was added.

Chemical). The reaction mixture was then heated to 9 ° C while continuing to stir and maintained at 90 ° C for 120 minutes. The sample was taken out of the reactor and determined to contain 2, respectively. /. NCO ’ by s. Siggia, "Quantitative

Organic Analysis via Functional Group", Third Edition, Wiley &

Measured by the method of Sons, New York', pp. 559-561 (1963). Fill 3,000 cc of stainless steel beaker with 1500 g of ultrapure water cooled to approximately 1 〇〇c, 25.9 g of Bio-soft® N25-9 and 25.9 g of Stepantex® VT-90 (both from Stepan) Ten grams of Additive 65 (available from Dow 123499.doc -36. 200907139 followed by a high shear laboratory with a rotor/stator mixing head, Model 100LC) was mixed at 7 rpm for 3 sec. The viscous prepolymer prepared as described above in the two reactors was poured into a metal tubular cylinder and simultaneously applied to the bottom of the mixing head in the aqueous solution by means of a flexible tube simultaneously applying a port air pressure %. The prepolymer temperature was maintained between 5 Å and 7 Torr, and the extruded prepolymer stream was dispersed and continuously mixed at 700 rpm for 2 minutes with water. After that, add 2.33 grams of puRAC® lactate protection

Poisoning agent. The resulting solvent-free aqueous dispersion was milky white to light blue with a solids content of 35% by weight. Example 15 - Fabric Testing The compositions of the present invention were tested in combination with cotton/LYCRA® fabric (97% cotton/3% lycra® spandex). The control of this example was a fabric washed with Uniii's non-concentrated C〇nfortTM fabric softener. The compositions shown in Table i were used with cotton/LYCRA® fabrics in a Wascator® programmable automatic washer according to Procedure 4 at 4 °C.

Corning). Mixer (Ross

Washing was carried out on a Corp0ratlon, St〇ckh〇lm, Sweden) using a standard load fabric up to 2.5 kg load. After the drum was dried, any deposition on the surface of the fabric was evaluated. None of the three fabrics showed any powder or film deposition. The compositions in Table 1 are as follows: (a) fabric softener (control) (b) fabric softener, 1% by weight of Example 6 film-forming anionic polyurethane urea water as a dispersion and 2% by weight Unimer (Synthetic wax to improve the dispersion) (C) Fabric softener, 1% by weight of the polyurethane urethane powder of Example 5, 2 % by weight of Unimer (synthetic wax to improve the dispersion). 123499.doc •37- 200907139 The fine-grained fabrics including fabric softeners / / & W < compositions (b) and (C) obtained a uniform dispersion (no sedimentation and agglomeration).

The ease of care of each fabric was evaluated. The durability (four) rate (DP rate) was determined before and after ironing using the standard test method AATCC TM 124/IS 〇 15487. The DP rate is a measure of the three-dimensional smoothness of the fabric. The slidability of the iron or the scalding is measured to an angle of about 2 inches. After the hot plate, the bucket is slid over the time used for weaving & U. The results of the easy care are shown in Table 1.

According to the results in Table 1 , it was shown that the two fabrics treated with the powder or dispersion showed a better rate of improvement (gain after ironing) compared to the control (gain after 5,000 points of ironing).

The fabrics 卬) and (c) treated with the compositions of the present invention also show a faster sliding of the iron on the surface of the fabric. The aroma/aroma materialization of compositions (a), (b), and (4) was also evaluated. Let the two people smell each fabric separately. Each of these is aware that the treated fabric treated with the composition of the present invention has a stronger aroma. The absorption characteristics (moisture treatment) of the fabrics treated by the compositions of the present invention were also tested. These characteristics were measured to show the difference between the treated fabric of the powder or dispersion of the present invention compared to the untreated fabric. For each of the above fabrics (4), (b), and (4), t linseed oil and 123499.doc -38- 200907139 water each drop (about 30 microliters) per-droplet time and complete it The absorbent fabric is completely absorbed after __ ° ^. The measurement is also recorded in Table 2. Drop surface area in square centimeters (cm2)

The powder (8) and the powder (4) of the present invention are improved in terms of absorption compared to (a). A significant improvement was shown using the powder form (4). Example 16-1% Cotton Fabric Test 1G (four) cotton fabric treated with the red inventive composition was also tested. This example = Control Concentrated Fabric Softener (Colgate Palmoliva Softlan Ultra). Each of the compositions shown in Table 3 was mixed with ι〇〇〇/. Cotton fabrics are used by the Wascator® programmable automatic washing machine at 40 ° C according to Procedure 4 (available from Electr〇lux c〇rp〇rati〇n, St〇ckh〇im,

Washing on a standard load fabric up to 2.5 kg load on Sweden). After the transfer drying, any deposition on the surface of the fabric was evaluated. None of the fabrics showed any powder or film deposition. The compositions in Table 3 are as follows: (e) Fabric softener (control) (f) Fabric righting agent and 10% by weight Example 1 Dispersion of liquid, nonionic polyamine group 123499.doc -39- 200907139 Formic acid The dispersion of the ester urea dispersion (the result of no sedimentation shows that the composition 5 comprising the fabric softener (7) obtains a uniform sentence drop and agglomeration). Measure the weave of each fabric (4) and (7) in Table 3 + Table 3 - Fabric elongation

A lower growth value indicates that the fabric has a better ability to recover its original shape. The difference in flavor release between fabrics (4) and (7) was also examined after washing and rinsing cycles. One to two grams of each fabric sample was placed in a sealed gas sampling container. The fabric stress is applied by shaking with a rigid ball bearing. The volatile compounds released from the sample were withdrawn from the upper space of the gas sampling vessel by means of a τ_χΤΜ sampling tube using a gas sampling pump operating at 5 g cubic centimeters per minute for 2 g minutes. The TenexTM tube captures volatile organic compounds (VOCs) for analysis. After the lack of heat, the TenexTM tube was used to release volatile organic compounds directly to the GC/MSw for analysis. The VOC measurement of Table 3a shows that the fabric softened by the fabric containing the dispersion of Example 1 (i.e., the nonionic polyamino phthalate urea dispersion) can release more fragrance. - Table 3a-V〇C test fabric volatiles concentration Nike / liter / gram (e) 7 (f) l 48 123499.doc -40- 200907139 Example 17 - ammonia theory / cotton joint fabric test also on some The spandex/cotton blended woven fabric treated with the composition of the examples was tested. The control for this example was a concentrated fabric softener (Colgate Palmolive's SoftlanTM Ultra). Each of the compositions shown in Table 4 was used with an ammonia/cotton blend fabric by using an ArielTM liquid detergent at 40 ° C according to Procedure 4 at 4 (using the Schutless® Programmable Automatic Washer). The standard load fabric was washed up to 2.5 kg load and rinsed with 18 grams of fabric softener composition. After drum drying (at moderate temperatures), any deposition on the fabric surface was evaluated. The fabric did not show any powder or film deposition. The composition is as follows: (g) fabric treated only with fabric softener (control) (h) fabric softener and 1% by weight of the dispersion of Example 1 (ie, nonionic polyurethane) Ester urea dispersion) treated fabric This composition comprises a fabric softener composition (11) to obtain a uniform dispersion (without sinking G $ and agglomeration). The fabric growth of each fabric (4) and (9) was measured. 4:

The fabric grows in a shape with a ridge-like retention. The growth value represents the unrecovered rate of the county y-y, private period of your teeth. A lower growth value indicates that the fabric has the ability to recover its original shape, preferably I23499.doc 200907139. Two theories/cotton blend fabrics treated with the compositions of certain examples were also tested. The control of this example is a concentrated fabric softening #J (Colgate Palmolive^ Soupline^ Ultra) 〇m^4a^4bm each composition is used with cotton and LYCRA® spandex blend fabric, by using Henkel C — on the Dixan® gel cleaner under 4〇υ, , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , After drying (at moderate temperatures), the surface of the fabric was evaluated: 2 deposition. None of the fabrics showed any powder or film deposition. For the following fabrics 'CK' is a circular knit fabric containing 95% cotton _5% LYCRA® spandex and wov is a gray latitudinal stretch fabric containing 97% cotton _3% LYCRA8 spandex. The compositions in Tables 4a and 4b are as follows: (1) Fabric treated only with fabric softener (Control_ck) ω Fabric softener and 丨〇% by weight (3% active ingredient) Example 1 分散 dispersion (ie , Nonionic Polyurethane Urea Dispersion) Fabric Treated (Processed-CK) (k) Fabric treated only with fabric softener (Control_w〇v) (1) Fabric softener and 10% by weight ( 3% active ingredient) Example of a dispersion (ie, nonionic polyaminophthalate urea dispersion) treated fabric (treated - WOV) 123499.doc • 42- 200907139 Table 4a - Fabric Prolongation rate CK fabric growth %) (i) Length direction 7.5 (j) Width direction 7.2 (i) Length direction 6.9 (j) Width direction 6.4 Table 4b - Fabric elongation rate WOV Fabric growth (%) (k) Zonal direction 7.29 (I) The latitudinal direction of 6.97. While the present invention is believed to be a preferred embodiment of the present invention, those skilled in the art will appreciate that changes and modifications can be made without departing from the spirit of the invention, and all Variations and modifications are intended to be included in the actual scope of the invention. 123499.doc -43-

Claims (1)

200907139 X. Patent Application Range: 1 - A fabric care composition comprising: (4) a detergent or fabric softener composition; and (8) # is a polyamine-based gland in the form of a powder or an aqueous dispersion. 2:::wash=composition, which is suitable for a rotten or fabric softener, wherein the detergent or fabric softener is suitable for use in which the detergent or fabric softener is in the form of a solid lozenge, an encapsulating liquid, and a non-woven fabric. Thin 3 · The composition of claim 1 is hand-washed β 4. The composition as claimed is selected from the group consisting of powders, liquids, tablets. 5. The composition of claimant, wherein the polycarbamic acid urea comprises the reaction product of (iv) a terminal polycarbamic acid g prepolymer and a chain extender. 6. The composition of claim 5, wherein the chain extender is selected from the group consisting of bis, water, and combinations thereof. The composition of claim 1, wherein the polyamino phthalate urea It is in powder form and the prepolymer is the following reaction product: 'The base end group polymer is selected from the group consisting of polyethers, polycarbonates, polyesters, and combinations thereof; and monoisocyanate. 8) The composition of claim 1, wherein the polyamino phthalate urea is in the form of a water-based sulphur solution > 4 and the pre-bath polymer is a reaction product of the base end group polymer It is selected from the group consisting of polyether, polycartic acid, poly, and combinations thereof. 123499.doc 200907139 Diisocyanate; and optionally acidic diol. 9. The composition of claim 8 wherein the aqueous dispersion is selected from the group consisting of an anion knife discharge and a nonionic dispersion. 10) The composition of claim 8, wherein the hydroxyl end group polymer is a polyether polyol, and the diisocyanate g is selected from the group consisting of phenylene and phenyldiiso-acid = 'toluene Isocyanate (10)), xylylene diisocyanate, phenyl diisocyanate, naphthyl diisocyanate, diphenylmethane diisocyanate (bribery), & (d) diisocyanic acid vinegar, and the acidic diol is selected from the group consisting of 2,2_di-methylacetic acid, 2,2-di-methylpropionic acid, 2,2-dihydroxydecylbutyric acid, 2,2 a group consisting of dimethylol valeric acid and combinations thereof. 11. The composition of claim 8, wherein the polymer is a poly(tetramethylene ether) glycol, and the diisocyanate is 4,4,-decylene bis(phenyl isocyanate) or 4,4-methylene. A mixture of bis(phenyl isocyanate) and 2,4,-methylenebis(phenyl isocyanate), and the acidic diol is 2,2-dihydroxymethylpropionic acid or the absence thereof. 12. A composition comprising a nonionic film-forming dispersion, wherein the dispersion comprises water and a polymer; the polymer comprises a reaction product of a prepolymer and water as a chain extender; and The material consists essentially of the reaction product of a diol or a mixture of diols with a hydrazine, a hydrazinyl bis(phenylisoacid acid). The composition of claim 12, wherein the diol is selected from the group consisting of a mixture of poly(tetramethylene 123499.doc 200907139 ke-co-ethyl ether) diol polypropylene glycol. Methylene group diols and ethoxylation M. The composition of the composition of claim n, the antifoaming agent, the pigment #, & one step comprises a surfactant selected from the group consisting of surfactants. Addition of a shaking solvent, and a combination thereof. 15. A composition comprising a nonionic non-film forming dispersion, wherein the dispersion comprises water and a polymer; the polymer comprises a prepolymer and a county g* The reaction product of the bond-extension agent and the water chain extender; and the β-hai prepolymer consists essentially of the reaction product of diol /. /, methylene bis(phenylisocyanate) composition. 16. The composition of claim 15 wherein the bovine V is selected from the group consisting of surface active beta, antifoaming agents, pigments, solvents, and, and reds. 17. A polyamine phthalate urea powder obtained from a composition comprising a nonionic non-tanked beverage, wherein the dispersion comprises water and a polymer; the polymer comprises a prepolymer and a diamine version a reaction product of a chain extender and a water chain extender; and the prepolymer consists essentially of the reaction product of a diol and 44,-π field "^ octamethylene bis(phenyl isocyanate). 18. A method of extending aroma aroma on a fabric comprising contacting the fabric with a composition comprising a polyamine & formic acid gland in the form of a powder or an aqueous dispersion of sesame oil A. 123499.doc 200907139 19. The claim 18 wherein the fabric comprises clothing. 2. Kind, add the shape of the clothes to maintain the side + #, the end or the aqueous dispersion shape Γ Make the clothes contact with the powder knife, the night form of polyamine phthalate urea. 2 A method of strong fabric care, which comprises a polyurethane sulphate in the form of a powder or an aqueous dispersion. The method of claim 21, wherein the fabric comprises clothing. 23. A method of imparting stain-repellent properties to a fabric comprising contacting the fabric with a polyamine-based vinegar vinegar in the form of a powder or an aqueous dispersion. 2 4. The method of e-blue item 2 3 wherein the far fabric comprises clothing. 123499.doc 200907139 VII. Designation of Representative Representatives (1) The representative representative of the case is: (none) (2) A brief description of the symbol of the representative figure: 8. If there is a chemical formula in this case, please reveal the characteristics that best show the invention. Chemical formula: (none) \j 123499.doc