200848504 九、發明說明： 【發明所屬之技術領域】 本發明係有關一種在常溫下為半固體狀之潤滑劑組成 物，特別是有關一種抗磨損性（Anti__wear 耐極壓性（Extreme Pressure Properties )優異，且具有 高動摩擦係數之潤滑劑組成物。本發明另有關一種將該潤 滑劑組成物使用在傳動要件機構上之潤滑系統。 【先前技術】200848504 IX. INSTRUCTIONS OF THE INVENTION: TECHNICAL FIELD The present invention relates to a lubricant composition which is semi-solid at normal temperature, and particularly relates to an anti-wear property (Anti__wear excellent in extreme pressure properties) And a lubricant composition having a high dynamic friction coefficient. The invention further relates to a lubrication system for using the lubricant composition on a transmission element mechanism.
立近年來，各種產業技術中之多功能化、高性能化、環 境對應、節約能源 '持久化成為重要的關鍵技術。在環境 課題方面可列舉如··-氧仆 々 —乳化奴排放量之減少、節省電力、 卽、力能源、資源的有效運 擔Ο ^ ^ 叉建用4多種例子。因此在小型精宓 機械、產業機械、輪穿糸 Ul 产㈣心錢4各種機械系統中，除了使環 支兄優良化之外，更賊芊杜 ικ ^ 等之特性。 4久化、提昇信賴性以及高性能化 你付又化万面，々丨丨L莊七Η 效地維持至製品的使 ^械之滑動部的潤滑性可有 件日漸嚴苛，潤滑油劑方面必須4=:、統之潤滑條 濁滑油劑有液態，滑油 2更同性叙潤滑性。 用途而分別使用。 /、 體狀之潤滑脂，係依適當 雷資訊機器之普及日漸廣泛。 電腦之各種設計進行商。化 =5仃動電話以及筆記型 之顯示面與操作部呈現^化。在該等製品當中，有些產品 (Hinge)之鉸鏈構件二才"，此開閉係經由所謂轉轴 進仃，在開閉之開始操作時，為了順 319938 5 200848504 -利滑動而抑制滞動（stick_slip)之觀點而言，必須盡量使 靜摩擦係數與動摩擦係數之差為最小，並且在機界之使用 中，為了需要長期維持所要求之開閉角度而必須盡量提高 靜摩擦係數。如此之轉軸由於多在消費者直接接觸之環境 下使用句頁徹底地避開因漏油所引起的污 潤滑油並不適用。另一古而、叫1 /促狀 另方面”潤滑脂在常溫下雖可抑制漏 ==而如經由滑動部的昇溫使得油分與增黏劑分離，則 f' 有引起漏油以及無法維持初期的潤滑性能之問題。除了轉 ’在要求油劑之高傳動能力的傳動要件機構方面， 等齒:此:::^ 二H 機構被廣泛地使用在家庭電器用 二機械、工程機械等各種產業機械;汽車、 面二鐵路等輸送系統。特別是機械式無段變 coefficient)高的動摩擦係數、牽引係數⑴如· 外，二動要件機構方面，除了具有充分之潤滑性以 卜门以有馬的動摩擦係數、牽 動摩擦係數而適用以註夕ρ為了只現同的 系基油。該等基^ 油（加⑽如）使用=防磨劑等而作為牽引 溶入油中而氧化、劣化，或因心：油為液狀，氧氣會 密封部外料或者經由 面’與使用潤滑油時相 守的問題。另-方 密閉構造Μ曰在古、w π 潤？月脂雖可不將系統作成 在回溫下油分與增黏劑分離，-旦分離之油 319938 6 200848504 分與增黏劑即無法恢復原狀，因 而無法發揮初期性能、或分離 ;;：：：二劑不足 尤1十l w刀，可m周邊之危險。 型化、持久：：地要求機械系統之高機能化、小 求即使以極少量之、法旦介叮 尺更间性此化，特別是要 里之/由里亦可順利地潤滑。 對於該等問題，本荦 狀之且右、、A卞毛月者雖美案一種熱可逆性凝膠 使用該等之轴承（bea叫）用潤滑劑、以及 或行動㈣)，然而對於筆記型電腦 =動電料之轉軸以及機械式無段變速機等 機構，仍根深蒂固地強列期 卞 耗性之潤滑劑。…μ王現㈣動摩擦係數與财磨 [專利文獻2]國際專利公開W02006-051671號 [非專利文獻1](社）日本摩擦學會（Japanese⑽ Tribologist)編’摩擦手冊，養賢堂出版（2謝）ρ 【發明内容】 [專利文獻1]日本專利第3775986號 [發明所欲解決之課題] 本發明之課題係為了解決上述問題而提供一種潤滑劑 、、且成物，本發明之潤滑劑組成物係將極少量之油劑塗佈在 潤滑滑動部位，即使在薄膜狀態亦具有高潤滑性，且呈現 利於動力傳動之高的動摩擦係數，並在常溫下為半固體狀 者。本發明另提供一種將該潤滑劑組成物使用在傳動要件 機構之潤滑系統。 本案發明者等為了解決上述問題，對於潤滑油基油、 319938 7 200848504 保持潤滑性之化學物質、添加劑等，以及對於該等之組合， 經過專心致志研究之結果而聯想到本發明。 亦即，本發明係如下所述之潤滑劑組成物以及潤滑系 統： (1) 一種潤滑劑組成物，其特徵為：常溫下為半固體狀， 且含有10至98· 9質量％之選自％Cp為7〇以下之烴碳 基油、鱗酸g旨、以及石夕酮（s i 1 i c〇ne )之至少一種液狀 , 基油’ 1至20質量％之鹼土金屬鹽、以及〇· 1至89質 里％之Si&胺化合物者。 (2) 如（1)之潤滑劑組成物，其中，鹼土金屬鹽係選自總鹼 值（TBN : Total Base Number)為 5 至 400 mgKOH/g 之 石黃酸鹽、酚鹽、水揚酸鹽之至少一種以上者。 (3) 如（1)或（2)之潤滑劑組成物，其中，醯胺化合物係至 種下述式（1)至（3)所示之化合物： —CO-NH-R2 (1) —CO-NH-A1-丽-C0 - R4 (2) - NH - C0-A2 - C0 - NH - R6 (3) (式（1)至式（3)中，R1、R2、R3、R4、R5以及R6各自獨 立係故數5至2 5之飽和或不飽和鏈狀烴基；r2亦可 為氣原子；A1以及A2係選自碳數1至1〇之伸烷基、伸 苯基或碳數7至1 〇之烷基伸苯基的碳數1至1 〇之二 價烴基）。 (4)如（3)之潤滑劑組成物，其中，式（1)至式（3)所示之醯 胺化合物係：R1、R2、R3、R4、R5以及R6各自獨立，^ 8 319938 200848504 具有碳數12$ 9/1 醒胺化合物及烴基’ m氫原子之 少 或R與R2、R3與R4、R5與各組之至 化合物:、有厌數12至20之不飽和鏈狀烴基的醯胺 (5) —種潤滑系統，1 ^ 八特欲為·將（1)至（4)中任—種潤滑 ^組成物使用在傳動要件機構者。 (6) ^機械式無段變速機，係作為傳動要件機構，尤其 疋猎由可維持既定角度的轉軸（Hinge)、高牵引係數之 油劑以進行動力傳達者。 竿^係數之 [發明之效果] Ψ =本發明之潤滑劑組成物，經由少量地塗佈在濁滑 與言的細麻Ϊ 動知形成安定之薄膜，達到呈現高極壓性 物:且^㈣數之特職果。由於本發明之潤滑劑組成 n熱可逆性、在常溫下呈現半固體狀、並在酿胺化 :、、典之熔點以上之溫度中呈現均勻之液體狀態者，因此， :動邛因進行加熱-冷卻而反覆為液體—半固體，離開滑 並在不升/JnL至熔點以上之溫度下可維持半固體狀。因 b並無氧化劣化、蒸發消失、漏油等情事，而可有效地 2用作為齒輪、傳送帶、鏈條、鋼索、轉軸、機械式無段 、欠逮機等傳動要件機構的潤滑劑。 【實施方式】 w本發明之潤滑劑組成物，其特徵係：在常溫下為半固 版狀’且含有10至98· 9質量％之液狀基油、1至20質量％ 之金屬鹽、以及〇· 1至89質量％之醯胺化合物，如預先塗 319938 9 200848504 佈在需要潤滑之傳動要件 Λ浚妝而π括一 a谭日可’在需潤滑之狀態下即成 马展狀而發揮而的動摩抹In recent years, multi-functionalization, high-performance, environmental response, and energy conservation in various industrial technologies have become an important key technology. In terms of environmental issues, for example, the reduction of emissions of emulsified slaves, the reduction of electricity, electricity, energy, and resources can be cited. ^ ^ There are four examples of fork construction. Therefore, in the small-scale fine-tuning machinery, industrial machinery, and the various mechanical systems that are used in the production of the four types of machinery, in addition to making the ring brothers superior, the characteristics of the thief ι ικ ^ and so on. 4 long-term, improve the reliability and high-performance, you pay and turn the surface, 々丨丨L Zhuang Qi Η Effectively maintain the product's lubricity of the sliding part of the machine can be increasingly harsh, lubricant The aspect must be 4=:, the lubrication strip of the lubricating oil has a liquid state, and the lubricating oil 2 has a more homogenous lubricity. Used separately for use. /, the body of the grease, according to the appropriate information technology has become more widespread. Various designs of computers are conducted. The display surface and the operation unit of the smashing telephone and the notebook type are displayed. Among these products, some products (Hinge) hinge members are two, this opening and closing system is controlled by the so-called rotating shaft, and when the opening and closing operation is performed, the stagnation is suppressed in order to slide 319939 5 200848504 - stick_slip From the point of view, it is necessary to minimize the difference between the static friction coefficient and the dynamic friction coefficient, and in the use of the machine, in order to maintain the required opening and closing angle for a long period of time, it is necessary to increase the static friction coefficient as much as possible. Such a shaft is not suitable for use because it is used in a direct contact with the consumer to completely avoid the contamination caused by oil leakage. Another ancient one, called 1 / spurt, the other side of the grease can suppress leakage at normal temperature == and if the oil is separated from the thickener by the temperature rise of the sliding portion, f' causes oil leakage and cannot maintain the initial stage. The problem of lubrication performance. In addition to the transmission mechanism in the high transmission capacity of the oil agent, etc.: This:::^ The two H mechanism is widely used in various industries such as household electrical appliances, two machinery, engineering machinery, etc. Machinery; transportation systems such as automobiles and No. 2 railways. Especially mechanical non-segment variable coefficient) high dynamic friction coefficient, traction coefficient (1), etc., in addition to the full-motion mechanism, in addition to having sufficient lubricity The coefficient of dynamic friction and the coefficient of friction are applied to the same base oil. The base oil (additional (10), for example, is oxidized, deteriorated, or absorbed as a traction into the oil using an anti-wear agent or the like. Because of the heart: the oil is in the form of liquid, and the oxygen will seal the external material or the problem of the surface through the use of the lubricating oil. The other-closed structure is in the ancient, w π moist? Although the fat can not be made in the system Return to warm oil Separation from the tackifier, the oil separated from the product 319938 6 200848504 can not be restored to the original state with the tackifier, so it can not play the initial performance, or separation;;:: two doses less than 1 l lw knife, can be around m Dangerous. Modeling and long-lasting: The ground requires the high-performance of the mechanical system, and even if it is in a very small amount, the method can be smoothed even if it is in the middle. For these problems, the shape of the right and the right, A 卞 月 虽 虽 虽 虽 虽 虽 虽 虽 虽 虽 虽 虽 虽 虽 虽 虽 一种 一种 一种 一种 一种 一种 一种 一种 一种 一种 一种 一种 一种 一种 一种 一种 一种 一种 一种 一种 一种 一种 一种 一种 一种 一种 一种 一种 一种The rotating shaft of the moving material and the mechanical type of stepless speed changer are still deeply entrenched in the consumption of the lubricant....μ王现(4) Dynamic friction coefficient and wealth grinding [Patent Document 2] International Patent Publication No. WO2006-051671 [Non-Patent Document 1] (Society) Japanese Society of Friction (Japanese (10) Tribologist), ed., "Rubbing Manual, Yangxiantang Publishing (2 Thanks) ρ [Invention] [Patent Document 1] Japanese Patent No. 3775986 [Invented Problem] The lesson of the present invention In order to solve the above problems, a lubricant and a composition are provided. The lubricant composition of the present invention coats a very small amount of an oil agent on a lubricating sliding portion, and has high lubricity even in a film state, and exhibits It is advantageous for the high dynamic friction coefficient of the power transmission and is semi-solid at normal temperature. The present invention further provides a lubrication system using the lubricant composition in a transmission element mechanism. The inventors of the present invention have solved the above problems for lubrication. Oil-based oils, 319938 7 200848504 Chemical substances, additives, etc., which maintain lubricity, and the combination of these, have been contemplating the present invention as a result of intensive research. That is, the present invention is a lubricant composition and a lubricating system as described below: (1) A lubricant composition characterized by being semi-solid at normal temperature and containing 10 to 98.9% by mass selected from the group consisting of %Cp is at least one liquid of a hydrocarbon-based base oil of 7 Torr or less, a sulphuric acid, and a si ic〇ne, an alkaline earth metal salt of 1 to 20% by mass of the base oil, and 〇· 1 to 89% of Si& amine compounds. (2) The lubricant composition according to (1), wherein the alkaline earth metal salt is selected from the group consisting of rhein, phenolate, and salicylic acid having a total base number of TBN of 5 to 400 mgKOH/g. At least one or more of the salts. (3) The lubricant composition according to (1) or (2), wherein the guanamine compound is a compound represented by the following formulas (1) to (3): -CO-NH-R2 (1) - CO-NH-A1-丽-C0 - R4 (2) - NH - C0-A2 - C0 - NH - R6 (3) (in formula (1) to formula (3), R1, R2, R3, R4, R5 And R6 are each independently a saturated or unsaturated chain hydrocarbon group of 5 to 25; r2 may also be a gas atom; A1 and A2 are selected from a C 1 to 1 fluorene alkyl group, a phenyl group or a carbon number. The alkyl group of 7 to 1 伸 has a carbon number of 1 to 1 二 of a divalent hydrocarbon group). (4) The lubricant composition according to (3), wherein the indoleamine compound represented by the formulae (1) to (3): R1, R2, R3, R4, R5 and R6 are each independently, ^ 8 319938 200848504 Has a carbon number of 12$ 9/1 amine compound and a hydrocarbon group 'm hydrogen atom or R and R2, R3 and R4, R5 and each group of compounds: an unsaturated chain hydrocarbon group having an anisotropy of 12 to 20 Indoleamine (5) - a kind of lubrication system, 1 ^ 八特欲为·(1) to (4) Any of the lubrication compounds used in the transmission requirements mechanism. (6) ^Mechanical stepless speed changer is used as the transmission element mechanism, especially for the power transmission by the oil agent that can maintain the hinge of a certain angle (Hinge) and high traction coefficient.竿^ coefficient [effect of the invention] Ψ = the lubricant composition of the present invention, which is coated with a small amount of turbidity and fine numbness to form a stable film to achieve a high extreme pressure property: and ^ (4) The number of special effects. Since the lubricant composition of the present invention is n-thermally reversible, exhibits a semi-solid state at normal temperature, and exhibits a uniform liquid state at a temperature above the melting point of the acrylating:, and the melting point of the code, therefore, the heating is caused by heating- Cooling and repeating as a liquid-semi-solid, leaving slippery and maintaining a semi-solid state at temperatures not above liter/JnL to above the melting point. Since b has no oxidative degradation, evaporation disappearance, oil leakage, etc., it can effectively be used as a lubricant for gears, conveyor belts, chains, steel cables, rotating shafts, mechanical type without sections, and under-loading mechanisms. [Embodiment] The lubricant composition of the present invention is characterized in that it is a semi-solid form at normal temperature and contains 10 to 98.9% by mass of a liquid base oil and 1 to 20% by mass of a metal salt. And 〇·1 to 89% by mass of the guanamine compound, such as pre-coated 319938 9 200848504 cloth in the need to lubricate the transmission requirements π π 一 a a a a a a a a a 谭 谭 谭 谭 谭 谭 谭 谭 谭 谭 谭 谭 需 需 需 需 需 需 需Play and move
CseizurH田振々把土 不係數。尤其可適用在有融執 I seizure)困擾之低速、高荷 粁。^ τ + ^ ^ 7重的運行等要求極壓潤滑之運 "ί 丁除了在溥膜下呈現高潤、、典认 e ^ ^ n l 门，間W性，並因油保持性亦佳而不 易發生缺油，因此不玄总21 + — .. 起融執。另外，本發明之潤滑 背J組成物係當傳動要件機槿 動部之、、”卜“： 滑動部開始運轉時，因該滑 、、典說划, 千U體狀受成液體狀態並進入狹窄之 r ^ ^ ^ ^ 丨而未傳導摩擦熱之部分則保持半 固體狀而無漏油之顧慮，可經f保持周邊清潔。 _ 卜纟此之“皿」係指室内的-般溫度，具體而 、二…0至抓，更為—般者係在，至3rc左右之 >皿度環境。 該潤滑劑組成物可得到高的動摩擦係數，例如以呈現 0.1至0.3為佳，尤其是〇.14至〇 2〇較佳，以〇15至〇18 為更佳。 ([液狀基油] 本發明所使用之液狀基油係選自％ c p為7 0以下之烴基 油、碟酸酯、以及石夕酮之至少一種。烴基油、碟酸_以及 矽酮可單獨使用或使用2種以上之混合油。 /〇Cp為70以下之烴基油可使用烷基環烷烴、烷基苯， 亦可使用礦物基油。烴基油係由碳氫化合物所組成，大多 含有環烷烴、環芳烴，亦即，％(：11與％(^之和必須超過3〇。 烴基油之黏度指數在8〇以下，尤以2〇以下為佳，通常為 — 400以上。 319938 10 200848504 液狀基油之物性並無特別限定，較佳者係在4〇它中之 動力黏度（dynamic viscosity)為 5 至 5〇〇〇mm2/s，以 至3000mmVs為較佳，又以5〇〇至2〇〇〇_Vs為更佳。另CseizurH Tian Zhenyu does not have a coefficient of soil. Especially suitable for low speed and high load that are plagued by I Seizure. ^ τ + ^ ^ 7 heavy operation, etc. requires extreme pressure lubrication. In addition to the high turbidity under the aponeurosis, the identifiable e ^ ^ nl door, between the W, and because of oil retention It is not easy to suffer from lack of oil, so it is not a total of 21 + —. In addition, the lubricating back J composition of the present invention is a moving part of the transmission component, and "b": when the sliding portion starts to operate, due to the sliding, the pattern, the thousand U-shaped body is subjected to a liquid state and enters The portion of the narrow r ^ ^ ^ ^ 丨 that does not conduct the frictional heat remains semi-solid without the risk of oil leakage, and the periphery can be cleaned by f. _ 纟 纟 纟 纟 皿 系 系 系 系 系 系 系 系 系 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内 室内The lubricant composition can attain a high coefficient of dynamic friction, for example, preferably from 0.1 to 0.3, particularly preferably from 1414 to 〇2, more preferably from 〇15 to 〇18. ([Liquid base oil] The liquid base oil used in the present invention is at least one selected from the group consisting of a hydrocarbon base oil having a % cp of 70 or less, a dish ester, and a linaloic acid. Hydrocarbon-based oil, dish acid _, and fluorenone Two or more types of mixed oil may be used singly or in combination. The hydrocarbon base oil having a Cp of 70 or less may be an alkylcycloalkane or an alkylbenzene, or a mineral base oil may be used. The hydrocarbon based oil is composed of a hydrocarbon, and most of them are used. Containing cycloalkane, cycloarene, that is, % (: 11 and % (the sum of ^ must exceed 3 〇. The viscosity index of the hydrocarbon-based oil is below 8 ,, especially preferably below 2 ,, usually - 400 or more. 319938 10 200848504 The physical properties of the liquid base oil are not particularly limited. Preferably, the dynamic viscosity of the liquid base oil is 5 to 5 〇〇〇 mm 2 / s, preferably 3000 mmVs, and 5 〇. 〇 to 2〇〇〇_Vs is better.
外，％Ca、％Cp、以及％(：11 係依據 ASTM D3238 定義之 n__d_M 環分析所求得者。 烷基環烷烴有合成環烷烴、環烷烴系礦物油。烷基苯 有合成類硬質絲苯、軟f絲苯。磷酸§旨有正碟酸醋、 Γ 亞填酸酯等’通常可列舉如··鱗酸三甲苯§旨等。相類油 之例可列舉如：聚二甲基發氧烧、聚甲基苯基石夕氧院等。 其中亦以％(^為10以下之烴基油為適用，具體之例 如：烧基環烧烴具有高的動摩擦特性，且潤滑性優異。該 等基油只要為滿足上述之物性者即可，可單獨使用亦可植 合2種以上使用。 液狀基油之調配係使加工後在常溫下為半固體狀之潤 滑劑組成物中含有10至98· 9質量％為宜，以3〇至97質量 %為佳，Μ 70至93質量％為更佳。液狀基油之調配量在未 滿上述範圍時’因無法得到基油應有之高的動摩擦特性而 不佳。 [驗土金屬鹽] 本發明中，為提高動摩擦係數而使用Ca、如、心等驗 土金屬鹽，其中以驗土金屬之有機酸鹽為佳。有機酸方面 可使㈣酸、石黃酸、齡、麟酸、水揚酸等。其卜驗土金 屬鹽係以選自磺酸鹽、酚鹽、水揚酸鹽中之至少一種以上 者為佳，又以Ca鹼土金屬之磺酸鹽、酚鹽、水楊酸鹽等， 319938 11 200848504 特別是磺酸鹽為適用。該等係作 于牙忭马至屬類清淨分散劑販 =。該寺之鹼土金屬鹽可含由碳酸鹽所成之過鹼成分。具 體上可適用總驗值為5至400mgK〇H/g，尤其是5〇至_ mgKOH/g之鹼土金屬鹽。 鹼土金屬鹽之調配係使加工後在常溫下為半固體狀之 潤滑劑組成物中含有1至2 〇質量％為宜，以2至2 〇 f量％ 為以2至10質量%為更佳。金屬鹽之調配量在未滿上 述範圍時’因無法有效賦予摩擦特性而不佳；另一方面， 調配量超出該範圍時’由於賦予效果已達頂點而使成本增 多，因而不佳。 [醯胺化合物] 本I明中使用之醯胺化合物係具有—個以上酸胺基 (一-丽-⑶-）之脂肪酸_化合物，可適t使用下列式⑴所 示具有1個醯胺基的單醯胺，Μ及式⑵與式⑶所示具有 2個酿&基的雙醯胺。以使用單醯胺與雙酿胺之組合者為 佳。 (1) l-C0-關 - R: 式中，R以及R2各自獨立，係碳數5至25之飽和或 不飽和鏈狀烴基；R2可為氫原子。 (2) (3) R3-C0-NH-A1-NH-C0-K R5 - NH-CO-A^CO-NH—j^ 式（2)以及式（3)中，r3、R4、R5以及以自獨立，係 石炭數5至25之飽和或不飽和鏈狀烴基；a1以及a2係選自 石厌數1至10之伸燒基、伸苯基或碳韋文7至工〇之烧基伸苯 319938 12 200848504 •基的碳數1至10之2價烴基。另外，如為烷基伸苯基時， 可為伸苯基與2個以上之烷基及/或伸烷基結合型態之2 價烴基。 單酸胺化合物係由上式（1)所示者，然構成R1以及r2 之氫的一部分可經羥基取代。如此之單醯胺化合物，可具 體列舉如：月桂醯胺、棕櫚醯胺、硬脂醯胺、山窬醯胺、 經基硬脂醯胺等飽和脂肪醯胺；油醯胺、芥子醯胺等不飽 Γ和脂肪醯胺；以及硬脂基硬脂醯胺、油基油醯胺、油基硬 脂醯胺、硬脂基油醯胺等飽和或不飽和之長鏈脂肪酸與長 鏈胺取代之醯胺類等。 在該等之單醯胺化合物中，以下述之醯胺化合物為 佳·式（1)之R1以及R2各自獨立，係碳數12至2〇之飽和 鏈狀烴基的醯胺化合物及/或R2之至少一者為碳數12 至20之不飽和鏈狀烴基的醯胺化合物，而以兩醯胺化合物 的混合物為更佳。又以不飽和鏈狀烴基為碳數18之具有不 (，飽和鍵之油基的單醯胺化合物為最佳。具體上以油醯胺、 油基油醯胺為佳，在滑動部上形成薄膜並保持，而確保有 效地解除融執困擾之薄膜保持性。 雙胺化合物係以作成二胺之醢胺或二酸之醯胺 之3L L的上述式（2)或（3)分別表示之化合物。另外，在 ⑵以及⑶中，以R3、R4、R5以及r6，尤其是以^以及； 表不之烴基中，部分之氫可經羥基（—〇H)取代。 式（2)所示之醯胺化合物可具體列舉如：乙撐雙硬脂醯 胺、乙擇雙異硬脂醉聪1r $ Μ , 日k 6撐雙㈣胺、亞甲基雙月桂酿 319938 200848504 胺、六亞甲基雙油醯胺、六亞甲基雙羥基硬脂醯胺、間苯 二曱基雙硬脂醯胺等。式（3)所示醯胺化合物具體上可列舉 如：Ν，Ν’-二硬脂基癸二醯胺等。 在該等雙醯胺化合物中，亦與單醯胺化合物之情形相 同，以下述之醯胺化合物為佳：式（2)之R3與R4以及式（3) 之R5與R6各自獨立，係碳數12至2〇之飽和鏈狀烴基的 醯胺化合物及/或R3與R4以及R5與R6之至少任一者為碳 數12至20之不飽和鏈狀烴基的醯胺化合物，而以兩醯胺 化合物的混合物為更佳。在確保薄膜保持性之點上，又以 =飽和鏈狀烴基為碳數18之具有不飽和鍵之油基的雙醯 胺化合物為佳。如此之化合物可列舉如··乙撐雙油醯胺、 六亞甲基雙油驢胺等。 、醯胺化合物如與液狀基油均勻混合，則在常溫下形 成凝膠狀之具有潤滑性之組成物。因此，醯胺化合物除了 作為將液狀基油半固化（凝膠化）之半固化化合物之作用以 外i亚在發揮潤滑劑組成物原有之潤滑特性的狀況中，以 熱熔解而成為液體之潤滑劑組成物發揮作用。如想在 =溫下以半固體、高溫下以液體之狀態使料，所適用之 ㈣W物之_以5〇至20(rc為佳’ 8〇至i8(rc更佳， 再者，分子量以100至1〇〇〇為佳，15〇至8〇〇更佳。 用托卜，由於機械系統在設計上的限制”使在僅能使 量油劑之滑動部中，為了在嚴苛之潤滑環境下亦不 广執等現象’必須使油劑強固地吸附.附著在滑動表 亚保持油膜。因此必須為具有附著性之油劑，因而在 319938 14 200848504 .本發明中發現半固化化合 和鍵狀時，則增加附著性。附著:化°物之以如為不飽 表面塗佈成薄膜狀，即使於，：性一則可對滑動 油膜不足的情形，而可提”;：：’閏滑％境中亦難以產生 方面，以碳數18之|有不在不飽和鏈狀烴基 佳。 ^有不飽和鍵之油基的雙醯胺化合物為 ^月女化合物之調配係使加工後 ::劑組成撕有至”量— 上述I卩HP & / 為更佺。酏胺化合物之調配量未滿 广二7’”溫*因無*形成凝膠狀之組成物而不 ^而不佳 調配量超出該範圍時，因過於堅硬難以操 [潤滑劑組成物之調製] :發明於常溫下為半固體狀之潤滑劑組成物並無特別 =者，可藉由將液狀基油、金屬鹽、以及酸胺化合物以 =之調配比例均勾混合而調製。例如：將液狀基油、金 屬'、以及酿胺化合物分別秤取預定量，加熱至溶點以上 :加以授拌至成為均勻液體狀態之後，經冷卻形成半固體 狀即可獲得。 本發明之組成物中，可再適當地調配習知之極麗劑、 防腐钱劑、抗磨損劑、防鏽劑、抗氧化劑、以及消泡劑等 添加齊卜極壓劑、抗磨損劑可列舉如：二烧基二硫代鱗酸 、辛(ZnDTP)、硫系化合物、碟系化合物等；防腐姓劑可列舉 如：。塞二唾衍生物、苯並三峻以及其衍生物；防錐劑可列 319938 15 200848504 舉如··脂肪酸部分酯、磷系化合物等；抗氧化劑可列舉如： 紛系、胺系化合物等，以及作為消泡劑之石夕酮系化合物' PMA聚合物；流動點下降劑（PPD ·· p〇ur-p〇in1： depressant)、作為黏度指數增進劑（yisc〇sity IndexIn addition, %Ca, %Cp, and %(:11 are obtained according to the n__d_M ring analysis defined by ASTM D3238. The alkylcycloalkanes are synthetic naphthenes and naphthenic mineral oils. The alkylbenzenes have synthetic hard filaments. Benzene, soft f-benzene benzene, phosphoric acid § is intended to have a positive-disc vinegar, Γ sub-alginate, etc. 'Generally, for example, tricresyl trimethoxide §, etc. Examples of phase oils can be exemplified by: polydimethyl Oxygen-fired, polymethylphenyl oxalate, etc. Among them, a hydrocarbon-based oil having a % (?) of 10 or less is suitable, and specifically, for example, a burn-in ring-burning hydrocarbon has high dynamic friction characteristics and is excellent in lubricity. The base oil may be used alone or in combination of two or more kinds. The liquid base oil is formulated to have a semi-solid lubricant composition at room temperature after processing. It is preferably 98.9% by mass, preferably 3 to 97% by mass, and more preferably 70 to 93% by mass. When the liquid base oil is less than the above range, the base oil should not be obtained. The high dynamic friction characteristics are not good. [Soil Testing Metal Salt] In the present invention, in order to increase the dynamic friction coefficient Use Ca, such as, heart and other soil metal salts, of which organic acid salt of soil test metal is preferred. Organic acid can make (four) acid, tartaric acid, age, linic acid, salicylic acid, etc. The metal salt is preferably at least one selected from the group consisting of a sulfonate, a phenate, and a salicylate, and a sulfonate, a phenate, a salicylate, etc. of a Ca alkaline earth metal, 319938 11 200848504 The sulfonate is suitable for use in the genus of the gums. The alkaline earth metal salt of the temple may contain an alkali component formed by a carbonate. The specific value is 5 To 400 mg K 〇 H / g, especially an alkaline earth metal salt of 5 〇 to _ mg KOH / g. The alkaline earth metal salt is formulated so that the lubricant composition which is semi-solid at normal temperature after processing contains 1 to 2% by mass. Preferably, the amount of 2 to 2 〇f is preferably 2 to 10% by mass. When the amount of the metal salt is less than the above range, it is not preferable because the friction property cannot be effectively imparted; on the other hand, the amount of the compound is adjusted. When it is outside this range, 'the cost is increased because the effect is already at its peak, so it is not good. [Hydrazine compound] The guanamine compound used in the above-mentioned formula is a fatty acid compound having one or more acid amine groups (mono---(3)-), and a monodecylamine having one guanamine group represented by the following formula (1) can be suitably used. And (2) and the diterpene amine having two brewing & base groups represented by formula (3). It is preferred to use a combination of monodecylamine and bis-amine. (1) l-C0- Guan-R: where R And R2 is independently a saturated or unsaturated chain hydrocarbon group having 5 to 25 carbon atoms; R2 may be a hydrogen atom. (2) (3) R3-C0-NH-A1-NH-C0-K R5 - NH-CO -A^CO-NH-j^ In formula (2) and formula (3), r3, R4, R5 and a saturated or unsaturated chain hydrocarbon group of 5 to 25 intrinsic charcoal; a1 and a2 From the calculus of 1 to 10, the phenyl group or the carbon kevin 7 to the benzene benzene 319938 12 200848504 • The carbon number of the base is 1 to 10 bis. Further, when the alkyl group is a phenyl group, it may be a 2-valent hydrocarbon group in which a phenyl group is bonded to two or more alkyl groups and/or an alkyl group. The monoacid amine compound is represented by the above formula (1), and a part of hydrogen constituting R1 and r2 may be substituted with a hydroxyl group. Such a monoamine compound may, for example, be specifically exemplified by: salicylamine, palmitoylamine, stearylamine, behenamide, stearylamine such as stearylamine; ceramide, mustard amide, etc. Unsaturated and fatty amines; and saturated or unsaturated long-chain fatty acids such as stearyl stearamine, oleyl oleylamine, oleyl stearylamine, stearyl amide, and long-chain amines Amines and the like. Among the above monoamine compounds, the following indoleamine compound is preferably an indoleamine compound and/or R 2 each independently having R1 and R2 of the formula (1), a saturated chain hydrocarbon group having 12 to 2 carbon atoms. At least one of them is a decylamine compound having a carbon number of 12 to 20 unsaturated chain hydrocarbon groups, and a mixture of two decylamine compounds is more preferable. Further, the unsaturated chain hydrocarbon group is preferably a monoammonium compound having a carbon number of 18 or less, and an oil group based on a saturated bond is preferred. Specifically, it is preferably an oily amine or an oil based oil amine, which is formed on the sliding portion. The film is held to ensure effective release of the film retention property of the entanglement. The bisamine compound is represented by the above formula (2) or (3) which is 3 L L of a guanamine or a diacid of a diamine. In addition, in (2) and (3), a part of hydrogen may be substituted by a hydroxyl group (-〇H) with R3, R4, R5 and r6, especially in the hydrocarbon group represented by the formula (2). The guanamine compound can be specifically exemplified by: ethylenebisstearylamine, bis-isostearyl sulphate 1r $ Μ, day k 6 bis (tetra)amine, methylene double laurel 319938 200848504 amine, hexamethine a bis-indolylamine, hexamethylene bishydroxystearylamine, m-benzodiazepine bis-lipidamine, etc. The guanamine compound represented by the formula (3) can be specifically exemplified by: Ν, Ν '- Stearyl quinone diamine or the like. In the case of the bis-amine compound, it is also the same as in the case of the monoamine compound, and the following guanamine compound is used. R3 and R4 of the formula (2) and R5 and R6 of the formula (3) are each independently, and are a decylamine compound having a saturated chain hydrocarbon group having 12 to 2 carbon atoms and/or at least R3 and R4 and R5 and R6. One is a decylamine compound having an unsaturated chain hydrocarbon group of 12 to 20 carbon atoms, and a mixture of two decylamine compounds is more preferable. In terms of ensuring film retention, a saturated chain hydrocarbon group is used as a carbon number. An oleylamine compound having an oil group having an unsaturated bond of 18 is preferred. Examples of such a compound include, for example, ethylene bis decylamine, hexamethylene bis decylamine, and the like, and a guanamine compound such as a liquid. When the base oil is uniformly mixed, a gel-like lubricious composition is formed at normal temperature. Therefore, the guanamine compound is used as a semi-cured compound which is semi-cured (gelled) to the liquid base oil. In the case where the lubricating properties of the lubricant composition are exhibited, the lubricant composition which becomes a liquid by heat melting functions. If it is intended to be a liquid at a temperature of a semi-solid or a high temperature at a temperature, it is suitable. (4) W of the _ to 5 〇 to 20 (rc is better '8 〇 to i8 (rc is better, then The molecular weight is preferably 100 to 1 Torr, preferably 15 Å to 8 Torr. With Tob, due to the design limitation of the mechanical system, it is only possible to make the sliding portion of the oiling agent, in order to be strict In the harsh lubrication environment, it is not widely practiced. 'The oil must be strongly adsorbed. It adheres to the sliding surface to maintain the oil film. Therefore, it must be an oily agent with adhesion. Therefore, it is found in 319938 14 200848504. When it is combined and bonded, the adhesion is increased. Adhesion: If the surface is not saturated, it is coated into a film, and even if it is: the first one can be insufficient for the sliding oil film, and can be mentioned; It is also difficult to produce aspects in the % of slippery, and it is better to have no carbon chain number. ^The oil-based bis-amine compound with unsaturated bond is the compounding system of the female compound. After processing: the composition of the agent is torn to the amount - the above I卩HP & / is more 佺. The amount is less than the second two 7'" temperature * because there is no * forming a gel-like composition without ^ poorly adjusted amount beyond this range, because it is too hard to handle [modulation of lubricant composition]: invented at room temperature The lubricant composition having a semi-solid state is not particularly limited, and can be prepared by mixing a liquid base oil, a metal salt, and an acid amine compound at a mixing ratio of =. For example, the liquid base oil, the metal', and the brewing amine compound are separately weighed to a predetermined amount and heated to a melting point or higher: after being mixed until they are in a uniform liquid state, they are obtained by cooling to form a semi-solid state. In the composition of the present invention, a conventional extreme agent, an anti-corrosion agent, an anti-wear agent, a rust preventive agent, an antioxidant, an antifoaming agent, etc. may be further appropriately added, and an anti-wear agent may be added. For example: dialkyldithioselic acid, octane (ZnDTP), sulfur compounds, dish compounds, etc.; antiseptic surnames can be listed as: a di-salt derivative, a benzotriazine, and a derivative thereof; an anti-taper agent may be listed as 319938 15 200848504, such as a fatty acid partial ester, a phosphorus-based compound, etc.; and an antioxidant may, for example, be a compound or an amine compound. And as a defoamer, the diarrhea compound 'PMA polymer; a pour point depressant (PPD ·· p〇ur-p〇in1: depressant), as a viscosity index improver (yisc〇sity Index)
Improver)之PMA聚合物等。而且，亦可使用預先混合數種 上述各種添加劑之所謂添加劑組合之型態。 本發明之常溫下為半固體狀之潤滑劑組成物使用在需 要潤β作用之機械機構（滑動部）時，當滑動之際因摩擦熱 而變成液體狀態並浸透於滑動部中，在金屬或樹脂等；構 成之滑動部的固體表面形成薄膜而使滑動部潤滑。如停止 滑動，則溫度下降’呈液體狀態之潤滑劑組成物再回復為 半固體，(凝膠狀）。而且，由於本發明之潤滑劑組成物特 別具有尚融執負#以及高的動摩擦係冑，更在長期間保 優異之摩擦特性，因此適用在低速、高荷重之極廢運行用 途，並且亦Τ使用在難以補給潤滑劑之滑動部或一旦組壯 後即無法解組之構造的裝置之滑動部上。再者，本發明: 潤滑劑組成物即使反覆地承受在使用、不使用之間戶^ 溫、冷卻之壓力，因凝膠(半固狀)構造可再建I籌， ΡΤ避免漏油所引起的污染，且不易蒸發，使用壽命長。 因此，可充分地使用作為以往液狀牵引油之、。 品，例如：齒輪、傳送帶、鏈條、鋼 件機構上，亦可適 要件機構上。尤其適用之用途可列舉如要求所 2 持的開關式筆記型電腦、行動電話、或電子字典等之;:參 319938 16 200848504 藉由高的動摩擦係數之潤滑油 變速機等。 [實施例] 進行動力傳達之機械式無段 惟本發明 以下依據實施例將本發明加以更詳細說明 並不受該等實施例所限定。 [液狀基油] 之潤滑劑組成物而使用 為调製貫施例以及比較例使用 以下之3種液狀基油。 基油A :合成環烷烴（特坎門（音譯）公司製造之 Techtrac M3Conc) 基油B :軟質烷基苯（動黏度（4〇。〇 ) ·· 32_2/s) 基油C: α-烯烴低聚物（Mobil公司製造之邠卜4〇〇) 將該3種液狀基油之物性示於表i。另外，在該等液 狀基油中預先調配預定量之抗氧化劑、抗磨損劑等添加 釗，使其具有潤滑油之基本性能（抗氧化、抗磨損等）。 319938 17 200848504 [表1] 基油A 基油B 基油C 基油種類 合成壞烧經 烧基苯 α -烯烴低聚物 黏度等級 1500 32 400 密度（15°C ) g/cm1 0. 92 0. 88 0. 85 動黏度 (40°C ) 1520 32 400 mm2/s (100°C ) 19. 65 4. 9 40 黏度指數 - 209 69 "1 :—-—__ 150 °/〇Ca 7 19 ~__ 0 ' %Cn 62 12 —^--—-~~_ 0 %Cp 31 69 100 S--—~_ [醯胺化合物] 為了半固狀化而調配在液狀基油者係使用以下之酿月安 化合物。 醯胺A ··乙撐雙油醯胺（日本化成製造之斯力帕克斯〇 (音譯），熔點119°c ) 醯胺B :乙撐雙硬脂醯胺（日本化成製造之斯力帕克斯 E(音譯），熔點i45°C ) [鹼土金屬鹽] 鹼土金屬鹽係使用以下2種化合物。Improver) PMA polymer, etc. Further, a form of a so-called additive combination in which a plurality of the above various additives are mixed in advance may also be used. The lubricant composition which is semi-solid at normal temperature in the present invention is used in a mechanical mechanism (sliding portion) which requires the action of moistening β, and becomes a liquid state due to frictional heat when it slides, and saturates in the sliding portion, in the metal or A resin or the like; a solid surface of the sliding portion formed to form a film to lubricate the sliding portion. If the sliding is stopped, the temperature of the lubricant composition in the liquid state returns to a semi-solid (gel-like). Moreover, since the lubricant composition of the present invention particularly has a high dynamic friction system and a high dynamic friction system, it has excellent friction characteristics for a long period of time, and is therefore suitable for use in low-speed, high-load, extremely waste operation applications, and also It is used on the sliding portion of the device which is difficult to replenish the sliding portion of the lubricant or the structure which cannot be disassembled once the group is strong. Furthermore, the present invention: the lubricant composition can be re-established by the gel (semi-solid structure) even if it repeatedly withstands the pressure between the use and the use, and avoids oil leakage. It is polluted and does not evaporate easily, and has a long service life. Therefore, it is possible to sufficiently use the conventional liquid traction oil. Products, such as gears, conveyor belts, chains, and steel mechanisms, can also be used on suitable parts. In particular, the application can be exemplified by a switch-type notebook computer, a mobile phone, or an electronic dictionary held by the driver; 319938 16 200848504 A lubricating oil transmission machine having a high dynamic friction coefficient. [Embodiment] Mechanically Non-Segmented Power Transmission The present invention will be described in more detail below based on the embodiments and is not limited by the embodiments. Use of the lubricant composition of [liquid base oil] The following three kinds of liquid base oils were used for the preparation of the examples and the comparative examples. Base oil A: Synthetic cycloalkane (Techtrac M3Conc manufactured by Tecanmen) Base oil B: Soft alkylbenzene (kinetic viscosity (4〇.〇) ··················· Oligomer (manufactured by Mobil Co., Ltd.) The physical properties of the three liquid base oils are shown in Table i. Further, a predetermined amount of an antioxidant such as an antioxidant or an anti-wear agent is preliminarily formulated in the liquid base oil to have a basic property (antioxidation, abrasion resistance, etc.) of the lubricating oil. 319938 17 200848504 [Table 1] Base oil A base oil B base oil C base oil type synthesis bad burny burnt benzene α-olefin oligomer viscosity grade 1500 32 400 density (15 ° C) g / cm1 0. 92 0 88 0. 85 Dynamic viscosity (40 ° C) 1520 32 400 mm2 / s (100 ° C) 19. 65 4. 9 40 Viscosity index - 209 69 "1 :---__ 150 ° / 〇 Ca 7 19 ~__ 0 ' %Cn 62 12 —^----~~_ 0 %Cp 31 69 100 S---~_ [Valeramine compound] For the semi-solidification, the liquid base oil is used in the following systems: Brewed Yue'an compound. Indole A · · Ethylene bis-indoleamine (Slippax 制造 manufactured by Nippon Kasei Co., Ltd., melting point 119 ° C) guanamine B: ethylene bis-lipidamine (Slipaks manufactured by Nippon Kasei Co., Ltd.) E (transliteration), melting point i45 ° C) [Alkaline earth metal salt] The following two compounds were used for the alkaline earth metal salt.
Ca石黃酸鹽：總驗值300mgKOH/g Ca水揚酸鹽··總鹼值70mgKOH/g [潤滑脂] 為了與本發明之潤滑劑組成物做比較 (Li)潤滑脂（日本能源公司製造之里作尼 18 1 19938 200848504 =No· 2’稠度號碼2(混合稠度範圍265至挪））作為 例4。 [潤滑劑組成物之調製] ^使用作為上述液狀基油之基油A(合成環烷烴）、 土油B(尨基苯）、以及基油C(a—烯烴低聚物）；作為醯胺 =口·物之㈣A(乙樓雙油酿胺）以及酿胺B(乙樓雙硬脂酿 胺）力上作為鹼土金屬鹽之Ca磺酸鹽以及a水揚酸鹽， 依下列順序調製實施例！至6以及比較例3之供試油（潤滑 劑組成物）。 在不鏽鋼製燒杯中，對應表2上部所示加工之供試油 的比例（貝里/°)，分別秤取預定量之液狀基油、鹼土金屬 鹽、酿胺化合物，得到各約為lGGml之供試油，使用桌上 里電磁加熱攪拌器’一邊加溫一邊攪拌至醯胺化合物之熔 點以上（熔點+20¾ )的溫度。由外觀觀察並判斷已均勻溶解 之後’將約100ml之均句溶解液移至耐熱玻璃容器（内徑 60mm X问度90mm)，放冷後，分別調製為實施例1至6以 及比較例3之常溫下為半固體狀之潤滑劑組成物。 比杈例1不含醯胺化合物與鹼土金屬鹽，係僅由基油 1之合成環烷烴所組成之供試油；而比較例2不含醯胺化 口物，係基油A之合成環烷烴與金屬鹽之Ca磺酸鹽所組成 之供試油，兩者均為常溫下具有液體之潤滑性的組成物。 此外，比較例4係上述市售之l丨潤滑脂。 [評估方法] 依下述方法進行實施例1至6以及比較例1至4之各 19 319938 200848504 。將其結果 潤滑劑組成物料估試驗（摩擦係數之測定等 示於表2之下部。 (1 )SRV試驗 使用依ASTM D57G6標準規^之球盤㈣卜。n_disk) 型sm摩擦試驗機。球係使用材質為suj_2之直徑丽球 軸承（ball bearing)用鋼球，盤係使用材質為su卜2之直 徑24_、厚度7.85mm之圓盤狀試驗片。盤之表面實施糖 度（如為_0. 45至0.65//m之研磨加工。摩擦試驗係在荷重 5⑽、振幅數50Hz、振幅寬度ι_、温度4(rc之條件下進 行’測定剛開始摩擦時之靜摩擦係數以及進行15分鐘時之 動摩擦係數，停止摩擦後，測定試驗球之磨痕。 (2)蒸發試驗 在直徑70mm之玻璃製培養皿上秤取各供試樣品2g， 使液體狀之樣品維持原狀，而半固體狀之樣品均勻地塗 薄，靜置於120 C之高溫槽中。由經過2〇〇小時之質量變 ( 化而求取蒸發減量（質量％)。 又 319938 20 200848504 [表2] 比較例 4 1 1 1 1 1 1 1 100 油分離 80 〇> I>- LO r-H CD 寸 O Q ◦ 比較例 3 1 1 LO 〇〇 (Ν1 〇〇 LO 1 1 〇 卜 CO r-H C3 CO CD Ο ◦ 比較例 2 LO CJD 1 1 1 1 LO 1 1 S CO CD 卜 r—l r-H CO CD CD CD 比較例 1 100 1 1 1 1 1 1 1 LO UTD C〇 CO OO t—H T-H CO CD CD 實施例 6 LO 〇〇 1 1 1 ◦ LO 1 1 〇〇 LTD LO CO t—H t—H CO ◦ ◦ o 實施例 5 LO 〇〇 1 1 ◦ 1 LO 1 1 卜 LO LO CO r-H r-H CO 〇>〇>〇> 實施例 4 寸 CO 却 1 CX1 CSO LO 1 1 〇〇 _ 寸 LO t—H r-H CO O CD CD 實施例 3 1 LO 〇〇 1 CN1 oo LO 1 1 ◦ CO 寸 CO r—i T—H CO • * 參 C3> CD CD 實施例 2 LO 〇〇 1 1 CN1 oo 1 LO 1 CO L〇 LO t—( i—H r-H CO CD 〇> o 實施例 1 LO 〇〇 1 1 oo LO 1 1 卜 卜 CO CO T—H t—H CO ◦ CD ◦ 基油A : 合成環烷烴 基油B : 烷基苯 基油C : α -烯烴低聚物 醯胺A 醯胺B Ca續酸鹽 Ca水揚酸鹽 * 1 市售鋰潤滑脂 Μ Μ %愈 B B u u 孝孝 oo 21 319938 200848504 • 實施例1至6在SRV摩檫試驗之轉麻w / 至0· 17，而動靜摩擦係數為〇. 14至'士祭係數為〇· 13 ， 王υ 16，各提口夕播麼 擦係數與動摩擦係數完全等值或幾乎 〇· 31至〇· 36mm，係耐磨損性優異者。 磨扣痕径小至 另-方面，使用基油A之比較例卜2在 樣品，靜摩擦係數與動摩擦係數$ μ / 一 η „ n Q7 ^ 0·^ °磨損痕徑為 ^至u7_’雖比貫_者稍大，卻屬耐磨損性優旦 者。然而，使用基油c之比較例3鱼況 C ^ ^ /凡用潤滑脂之比較例 4之靜摩擦係數均為〇·Η)、動摩擦係數均為〇 3? 一浐而J f ’呈示低於實施例之摩擦係數。試驗球之磨損隸在^匕 的磨損性。 ^U5mm ’呈示大 可知半固體狀之實施例}至6之蒸發減量遠少於比較 2二3者;=實施例4之潤滑脂為半固體狀，蒸發減 g劑分離。 下好置⑽小卜會使油與增黏 旦由上述之結果得知’在本發明之實施例中，即使極少 里之潤滑劑亦呈示高的動摩擦係數，耐磨損性優異，而且 即使塗佈成薄膜狀，在高溫下亦不易蒸發，可以長期 滑動部上形成摩擦覆膜。 ’ [產業上之可利用性] 、、門可明瞭，依本發明在常溫下為半固體狀之 且成物’以極少之使用量形成薄膜狀態，不但呈現 咼的動摩擦係數盘優I + 默〃饭異之耐知耗性，並且難以蒸發損失而 319938 22 200848504 可長期間使滑動部濁滑* 例如：齒輪、傳送帶 的動摩擦係數可適用在 速樯簟且古禮# ，、鋼索、轉軸、機械式無段變 、械等具有傳動要件機禮 文什Μ構之機械糸統，並且耐摩耗性 /、’又少有漏油與蒸發損失現象，因此可期待對於機 統之長期使用有所貢獻。 ’、 【圖式簡單說明】 無。 ◎ 【主要元件符號說明】 無。 319938 23Ca lithinate: total value 300 mg KOH / g Ca salicylate · total base number 70 mg KOH / g [grease] For comparison with the lubricant composition of the present invention (Li) grease (manufactured by Nippon Energy Co., Ltd.) In the case of Nie 18 1 19938 200848504 = No · 2 'Consistency number 2 (mixed consistency range 265 to move)) as Example 4. [Preparation of Lubricant Composition] ^Use of base oil A (synthetic cycloalkane), earth oil B (mercaptobenzene), and base oil C (a-olefin oligomer) as the above liquid base oil; Amine = mouth (4) A (B floor double oil-branched amine) and brewing amine B (B floor double stearic amine) force as an alkaline earth metal salt of Ca sulfonate and a salicylate, in the following order Example! Test oil (lubricant composition) to 6 and Comparative Example 3. In a stainless steel beaker, a predetermined amount of the liquid base oil, the alkaline earth metal salt, and the brewing amine compound were weighed in proportion to the ratio of the test oil (Berry/°) processed in the upper part of Table 2, and each obtained was about 1 GGml. The test oil was stirred while using the electromagnetic heating stirrer on the table while stirring to a temperature above the melting point of the guanamine compound (melting point + 203⁄4). After observing the appearance and judging that it has been uniformly dissolved, 'about 100 ml of the homogenous solution was transferred to a heat-resistant glass container (inner diameter: 60 mm X degree 90 mm), and after cooling, it was prepared into Examples 1 to 6 and Comparative Example 3, respectively. A semi-solid lubricant composition at room temperature. Comparative Example 1 does not contain a guanamine compound and an alkaline earth metal salt, which is a test oil composed only of a synthetic cycloalkane of base oil 1; and Comparative Example 2 does not contain a guanamined mouth, which is a synthetic ring of base oil A. A test oil composed of an alkane and a metal salt of a Ca sulfonate, both of which have a liquid lubricity at normal temperature. Further, Comparative Example 4 is a commercially available l grease. [Evaluation Method] Each of Examples 1 to 6 and Comparative Examples 1 to 4 was carried out in the following manner. 19 319938 200848504. The results of the lubricant composition test (the measurement of the friction coefficient are shown in the lower part of Table 2. (1) SRV test The ball disk (four) b. n_disk) type sm friction tester according to ASTM D57G6 standard. For the ball system, a steel ball for a diameter ball bearing material of the size of suj_2 is used, and a disk-shaped test piece having a diameter of 24 mm and a thickness of 7.85 mm of a material of Su 2 is used for the disk. The surface of the disk is subjected to a sugar content (for example, a grinding process of _0.45 to 0.65//m. The friction test is carried out under the conditions of a load of 5 (10), an amplitude of 50 Hz, an amplitude width of ι_, and a temperature of 4 (rc). The coefficient of static friction and the coefficient of dynamic friction at 15 minutes were measured. After the friction was stopped, the wear marks of the test balls were measured. (2) Evaporation test 2 g of each test sample was weighed on a glass petri dish having a diameter of 70 mm to make a liquid sample. The sample was maintained in its original state, and the semi-solid sample was uniformly thinned and placed in a high temperature tank of 120 C. The mass change was obtained after 2 hours (the mass loss was obtained by mass reduction. 319938 20 200848504 [ Table 2] Comparative Example 4 1 1 1 1 1 1 1 100 Oil separation 80 〇>I>- LO rH CD inch OQ ◦ Comparative Example 3 1 1 LO 〇〇(Ν1 〇〇LO 1 1 〇卜 CO rH C3 CO CD Ο ◦ Comparative Example 2 LO CJD 1 1 1 1 LO 1 1 S CO CD 卜 r - l rH CO CD CD CD Comparative Example 1 100 1 1 1 1 1 1 1 LO UTD C〇CO OO t-H TH CO CD CD Example 6 LO 〇〇1 1 1 ◦ LO 1 1 〇〇LTD LO CO t-H t-H CO ◦ ◦ o Example 5 LO 〇〇 1 1 ◦ 1 LO 1 1 卜 LO LO CO rH rH CO 〇>〇>〇> Example 4 inch CO but 1 CX1 CSO LO 1 1 〇〇_ inch LO t-H rH CO O CD CD Example 3 1 LO 〇〇1 CN1 oo LO 1 1 ◦ CO 寸 CO r—i T—H CO • * 参C3> CD CD Example 2 LO 〇〇1 1 CN1 oo 1 LO 1 CO L〇LO t—( i— H rH CO CD 〇> o Example 1 LO 〇〇1 1 oo LO 1 1 Bub CO CO T-H t-H CO ◦ CD ◦ Base oil A : Synthetic naphthenic base oil B : Alkyl phenyl oil C: α-olefin oligomer guanamine A guanamine B Ca sulphate Ca salicylate* 1 Commercially available lithium grease Μ Μ % BB uu 孝孝oo oo 21 319938 200848504 • Examples 1 to 6 in SRV The friction test of the Capricorn test w / to 0. 17, and the dynamic and static friction coefficient is 〇. 14 to 'the coefficient of the sacrifice is 〇 · 13 , Wang Hao 16, each mouth and the date of the coefficient of friction and the coefficient of dynamic friction is completely equivalent or It is almost 〇 · 31 to 〇 · 36mm, and it is excellent in abrasion resistance. The grinding buckle has a small diameter to the other side, and the base oil A is used in the comparison example. In the sample, the static friction coefficient and the dynamic friction coefficient are $ μ / η „ n Q7 ^ 0·^ ° wear scar diameter is ^ to u7_' The _ is slightly larger, but it is the wear-resistant excellent one. However, in the comparative example 3 using the base oil c, the static friction coefficient of the fish case C ^ ^ / the comparative example 4 of the grease is 〇·Η), The dynamic friction coefficient is 〇3? 浐 and J f ' is lower than the friction coefficient of the embodiment. The wear of the test ball is based on the wear of the 。. ^U5mm 'presents the embodiment of the large semi-solid state} to 6 The evaporation reduction is much less than that of the comparison of 2 and 2; = the grease of Example 4 is semi-solid, and the evaporation is reduced by the separation agent. The good setting of (10) small Bu will make the oil and the viscosity increase denier from the above results. In the embodiment of the present invention, even a very small amount of lubricant exhibits a high dynamic friction coefficient, and is excellent in abrasion resistance, and even if it is applied in a film form, it is hard to evaporate at a high temperature, and a friction film can be formed on the long-term sliding portion. '[Industrial availability], and the door is clear, according to the invention, it is semi-solid at normal temperature. And the product 'forms the film state with a very small amount of use, which not only exhibits the dynamic friction coefficient of the crucible, but also has the resistance to consumption, and it is difficult to evaporate the loss. 319938 22 200848504 The sliding portion can be slidable for a long period of time* For example, the dynamic friction coefficient of gears and conveyor belts can be applied to the speed and the ancient ritual #, the steel cable, the rotating shaft, the mechanical type without the section, the mechanical system, etc. /, 'There are few oil leakage and evaporation loss, so you can expect to contribute to the long-term use of the machine. ', [Simple diagram description] No. ◎ [Main component symbol description] None. 319938 23