200831399 吊^下在水中的溶解度為2 的氣體，沸點為1 g/L，其有效氣為氯氣的2 6 3 %，但它卻是一種高效 氧化劑，而不是氣化劑’它的氡化能力是氣氣的2.5倍 〇 二氧化氯對微生物的殺菌機理為：二氧化氯對細胞壁 具有很強的吸附和穿透能力’可有效地氧化細胞内含酼基 的，還可以快速地抑制微生物蛋白質的合成來破壞微生物 ，因此，二氧化氯除對一般細菌有殺死作用外，對芽孢、 病毒、藻類、、鐵細菌、硫酸鹽還原菌和真菌等均有很好的 滅殺作用’溫度越高，二氧化氣的殺菌效力越大，這非常 適合作為工業迴流水以及溫度偏高領域的殺菌劑。 透過則、外大量的研究發表，可知二氧化氯是作為 ::乳：消毒的最佳方案，…氯的消毒殺菌特性十分 優越，/、虱虱比較，二氧化氯的殺菌特點是： (1 )殺菌效果好’用量少，作用快，二氧化氯溶於 水後，基本不與水發生化學反廣 “ 、 =度的刪度ί渗透能力都比氯快，特別在 氧化2對1C : X -氧化乳孢子的殺滅作用比氯強，二 系統中的藻類、異氧菌、鐵細菌及硫酸鹽 遇原=均有較好的防止繁殖和切、滅殺效果。 二氧化氣化氯在很寬ΡΗ範圍内有报強的殺菌能力 一乳化乳杈囷效果可以說基本不 在驗性條件下，所加的氯大部分以殺菌效響：； 根（〇 c 1 —)拟斗士丄 、.固双果較差的次虱酸 ^ ，據報導，次氯酸根殺菌效果是 5 200831399 次氯酸的1/1〇〜]θ 丄/ Ζ 〇，疋以，在冷卻水的鹼性處 理方案配用二氧化氣來扣r — 木控制囷澡滋長要比加氯效果好得多 0 · 5 保持在 下降為 ，其殺 ( 無機物 有機物 作用的 看，二 氣需要 環境， 氧化氯救菌政果持續時間長，經試驗證明， P P:的-乳化氯在1 2小時内對異氧菌的滅殺率 9 9 % X上’作用時間長達成2 4小時時殺菌率才 86.3%，且-麵 a， ^ 一虱化氣不與氨及氨基化合物反應 菌效果不受氨的影響。 ^ 4)二氧化氯與紛類反應不產生⑽，與有機物、 的反應具有強的選擇性’這使二氧化氯與腐殖質及 反應幾乎不產生發散性有機i化物，不生成有致癌 :齒甲烷（THM)，因此’從健康與環境的角度 乳化乳，代氯氣有極其重要的意義，另外，由於氯 的投加量比二氧化氯高得多，高的餘氯排放將污毕 需要預先脫氯才可排放，這就造成處理成本的增加 (5 ) —氧化氯不僅能殺死料 的细^㈣目〇 ―死微生物m分解殘留 控制細菌、藻類及粘泥，用-氧 咗k 用—乳化虱處理水池的藻類臭 ，舁硫酸銅處理法相比，發現在 、、 -, 兄仕了比擬的處理成本下， —虱化氣比硫酸銅更有效，並且由於 減缥蚪Μ冰ΛΛ f V用了石爪酸銅，也可 較差，财物對氯的耐藥性也 長』使用而不產生顯著的抗藥性。 (6 )溫度升高，二氧化氯 又囷犯力增強，經大量 6 200831399 實驗證明，例如對大 ，在2 S V栌 粹菌，加二氧化氣0 · 2 5 mg/1 乙D L捋，欲達到q Q η 鐘，而在Jy9 · 9%的殺死效果需190分 仗J υ c時則僅愛 是很有利的。 里而1 〇秒，這對迴流水的殺生來講 (7 ) —氧化氯的* 體中的微量有 Λ虱化作用很強，它能有效地破壞水 四氣化炉*Λ巧木物，如苯並芘...等，且對氯仿、 同時還有助凝和脫d4氣化有機物時不發生氣化反應， 的新鮮度，可以用六、、_用，可以降低水的濁度，提高水質 化氣洁主尨At 於'亏水和惡臭氣體的處理，水在經二氧 = :;Γ=餘消毒作用，但無殘留毒性，對人體 »，其在急性用濃度時對皮膚枯膜無刺激作 — 和m傳毋理學上都是絕對安全的。 )二氧化氯消毒液用於食品 裝食品和飲料的容器、管道及果；；二广用具、盛 洗，可直接生彦勺壯4入 毋後，不需再行清 屋匕衣和食用，安令姓古仅《X炊 化氯消毒液成Α θ 丨有保证，因此使二氧 持劑，且 毋用的理想藥劑和管網中的餘氯保 大大-二乳化氯殺菌消毒液可反復使用多次，因而可以 大大即約消毒費用。 J 乂 用之2可知，二氧化氯乃得作為-種綠色消毒劑，其應 代氣:^’不管就環境角度還是從衛生角纟，二氧化氣取 代虱衣劑都是必然的趨勢。 然，因二氧化氯並非自然存在的物質， 化學作用才能產生，是以目前市面可見的…:疋：要經過 劑箄-气儿— j φ曲τ見的洛液、粉劑或片 乳化鼠殺菌消毒產品，在使用時均需加入活化劑進 7 200831399 行活化，才能釋放出具有強烈殺菌能力之二氧化氯，惟此 類產品因其劑型的差異，在運輸及貯存及使用上，卻普遍 存在有安全性方面的問題，以溶液型產品而言，其最丄的 問題便是運輸極為不便，且當其液體含量超過一定程度， 即必須按危險物品標準方式運輸，而粉劑或片劑產=因 t原料本身具有強氧化性，與可燃性物質接觸或與酸性物 貝此口即會發生爆炸、燃燒，而活化劑就是酸性物質，因 此除了必須依危險物品標準運輸外，在其使用時更需一定 、的程序加4量的水中’或先將劑料與水混合後，再換入 活化劑，否則即有爆炸、燃燒之問題，相當不安全，择 ，待設法加以解決改善者。 貝 【發明内容】 ==現有二氧化氯殺@消毒劑製備上所存在的 失，發明人特著手進行研發，基於其從事相關行 :備=、讀與技術，$而研創出本發明之二氧化氯造粒 : = ;，即其主要目的乃在於提供-種得以將二氧化氯 、、曰人複二主劑及活化劑配合輔助劑料採獨立造粒包覆或 二二：：粒包覆之方式’據以製成包覆粒狀型態，使其 蜀立包裝1簡化其劑料的包裝，俾能方便運 ^明而使用時又可快速調製合成之創新製備方者。 作為主劑在：利用輔助劑料形成的包覆層 覆式粒狀型離，戋獨：P::、、、巴{吏其即使製成混合複層包 生化學作Γ、梭:覆而混合包襄時，亦不致相互產 ’俾-確保其運輸及貯藏的安全性，同時得以 200831399 延長其保存期限者。 本电明之又一目的係在於經由其造粒包覆的組成型態 ，使其在加水調合時，將使其活化劑及主劑同時與水混合 ，而非兩者先行混合，俾可維持其使用安全性，有效避免 刼作不慎發生爆炸、燃燒之安全疑慮，俾能大幅提昇其使 用便利性與安全性者。 為達前揭目的，本發明主要是將合成二氧化氯所需主 劑及活化劑配合輔助劑料採獨立造粒包覆或混合複層造粒 包覆方式製成粒狀型態，使其得作混合或獨立包裝，待欲 使用時再予加水調合，即可調製成二氧化氯殺菌消毒劑， 據此特能簡化其劑料之包裝，並使其得以 ，而使用時又可快速調製合成，從而可獲致極佳 用價值與實用性者。 【實施方式】 有關本發明製備方法、技術手段及功效達成方面，謹 再加以說明於后： 口 本發明在合成二氧化氯殺菌消毒劑所需的劑料，主要 (A ) (B )200831399 Hanging gas with a solubility of 2 in water, boiling point 1 g / L, its effective gas is 263% of chlorine, but it is a highly efficient oxidant, not a gasifying agent' its deuteration ability It is 2.5 times the gas. The bactericidal mechanism of bismuth dioxide on microorganisms is: chlorine dioxide has strong adsorption and penetration ability to the cell wall. It can effectively oxidize thiol groups in cells, and can also rapidly inhibit microbial proteins. Synthetic to destroy microorganisms, therefore, chlorine dioxide has a good killing effect on spores, viruses, algae, iron bacteria, sulfate-reducing bacteria and fungi, in addition to killing common bacteria. High, the greater the bactericidal effect of the dioxide gas, which is very suitable as a biocide for industrial reflux water and high temperature. Through a large number of research publications, it is known that: chlorine dioxide is used as:: milk: the best solution for disinfection, ... chlorine disinfection and sterilization characteristics are very superior, /, 虱虱 comparison, chlorine dioxide sterilization characteristics are: (1 ) Good bactericidal effect 'Low dosage, fast effect, chlorine dioxide dissolved in water, basically does not chemically react with water." The killing effect of X-oxidized milk spores is stronger than that of chlorine. The algae, aerobic bacteria, iron bacteria and sulfate in the second system have better anti-propagation, cutting and killing effects. In a very wide range, there is a strong bactericidal ability. The effect of emulsified chyle can be said to be basically not under the conditions of the test. The chlorine added is mostly bactericidal:; The poor quality of the secondary bismuth acid ^, it is reported that the hypochlorite bactericidal effect is 5 200831399 hypochlorous acid 1 / 1 〇 ~] θ 丄 / Ζ 〇, 疋, in the cooling water alkaline treatment plan Using sulphur dioxide to deduct r - wood control bathing is much better than chlorination 0 · 5 Keeping it down, its killing (the role of inorganic organic matter, the second gas requires the environment, the oxidation of chlorine to save the fruit of the fruit for a long time, the test proved that PP: - emulsified chlorine in 12 hours against the aerobic bacteria The killing rate is 9 9 % X. When the action time is long, the sterilization rate is 86.3%, and the surface a, ^ a gas does not react with ammonia and amino compounds. The effect of the bacteria is not affected by ammonia. ^ 4) Chlorine dioxide does not produce a complex reaction with (10), and has strong selectivity with organic matter. This makes chlorine dioxide and humus and reaction hardly produce divergent organic compounds, and does not produce carcinogenic: tooth methane (THM). Therefore, it is extremely important to emulsify milk from the perspective of health and environment. In addition, since the dosage of chlorine is much higher than that of chlorine dioxide, high residual chlorine emissions will require pre-dechlorination. Emissions, which causes an increase in processing costs (5) - Oxidation of chlorine can not only kill the fineness of the material (4), the target - the dead microorganisms, the decomposition of bacteria, algae and slime, and the treatment with - oxo Algae smell in the pool, sulphuric acid Compared with the treatment method, it is found that the gasification of bismuth gas is more effective than that of copper sulphate at the processing cost of brethren, and it can be worse because the scorpion scorpion f V is made of copper cinnabar. The property is also resistant to chlorine. It is used without significant resistance. (6) The temperature rises, the chlorine dioxide and the cockroaches increase the violent force. After a large number of 6 200831399 experiments prove that, for example, the large, at 2 SV栌The bacterium, adding 2 · 2 5 mg / 1 B 捋 捋, want to reach q Q η 钟 , and in Jy9 · 9% killing effect requires 190 points 仗 J υ c only love is very beneficial In 1 〇 second, this is the killing of reflux water (7) - the amount of oxidized chlorine in the body is very strong, it can effectively destroy the water four gasifier * Λ 木 wood For example, benzopyrene, etc., and the chloroform, and also the co-agglomeration and de-d4 gasification of organic matter do not gasification reaction, the freshness, can be used with six, _, can reduce the turbidity of water To improve the quality of water, gas, clean and main 尨At in the treatment of 'deficiency and malodorous gas, water in the dioxin = :; Γ = residual disinfection, but no residual toxicity, The human body », which has no irritation to the skin's dead skin at acute concentrations - and m-transfer is absolutely safe. Chlorine dioxide disinfectant is used for food containers and pipes and pipes for food and beverages; Erguang utensils and washing, can be directly produced after the simmering of the squid, no need to clean the house and eat, An Ling surnamed only "X 炊 氯 氯 消毒 氯 θ θ θ 丨 丨 丨 丨 , , , , , , , θ θ θ θ 理想 理想 理想 理想 理想 理想 理想 理想 理想 理想 理想 理想 理想 理想 理想 理想 理想 理想 理想 理想 理想 理想 理想 理想 理想It is used many times, so it can be greatly reduced. J 乂 2 It can be seen that chlorine dioxide is used as a kind of green disinfectant, which should be replaced by gas: ^' Regardless of the environmental angle or the sanitary angle, the replacement of dioxide by the dioxide is an inevitable trend. However, because chlorine dioxide is not a naturally occurring substance, chemical action can be produced. It is currently visible in the market...: 疋: It must be sterilized by lotion, powder or emulsified rat with 箄-气儿- j φ曲τ Disinfecting products, when used, need to be added with activator to activate chlorine dioxide with strong bactericidal ability, but such products are ubiquitous in transportation, storage and use due to differences in dosage forms. There are safety problems. In the case of solution-type products, the most problematic problem is that transportation is extremely inconvenient, and when the liquid content exceeds a certain level, it must be transported according to the standard method of dangerous goods, and powder or tablet production = Because the raw material itself has strong oxidizing property, it may explode and burn with the flammable substance or the acidic substance, and the activator is an acidic substance, so in addition to being transported according to the dangerous goods standard, it is more used when it is used. Need a certain procedure, add 4 amounts of water' or mix the agent with water first, then change into the activator, otherwise there will be problems of explosion and burning, which is quite unsafe. , choose, try to solve the improvement. [Inventive content] == Existing chlorine dioxide kill @ disinfectant preparation loss, the inventor specializes in research and development, based on its related lines: preparation =, reading and technology, $ and research to create the second invention Oxidation of chlorinated chlorine: = ;, that is, its main purpose is to provide chlorine dioxide, bismuth complex, and activator with auxiliary agent materials for independent granulation coating or two:: The method of covering is made into a coated granular form, so that it can be packaged in a package 1 to simplify the packaging of the agent, and it can be easily used in the manufacture of innovative preparations. As the main agent: the coating layer formed by the auxiliary material is covered by the granular type, and the only one is: P::,,,,,,,,,,,,,,,,,,,,,,, When mixing the bags, they will not produce each other's - ensuring the safety of their transportation and storage, and will be able to extend their shelf life by 200831399. Another purpose of the present invention is to form a granulation-coated composition such that when the water is blended, the activator and the main agent are simultaneously mixed with water, instead of being mixed first, and the 俾 can be maintained. The safety of use can effectively avoid the safety concerns of inadvertent explosion and burning, and can greatly improve the convenience and safety of its use. In order to achieve the above objective, the present invention mainly comprises the following steps: preparing a main agent and an activator for synthesizing chlorine dioxide, and preparing a granular material by using an independent granulation coating or a mixed layer granulation coating method; It can be mixed or packaged separately. When it is used, it can be mixed with water to prepare chlorine dioxide disinfectant. According to this, it can simplify the packaging of the agent and make it available. Synthetic, so that it can be used for excellent value and practicality. [Embodiment] Regarding the preparation method, technical means and efficacy of the present invention, it is to be further explained: The present invention is a reagent for synthesizing chlorine dioxide disinfectant, mainly (A) (B)
主劑·氯酸納NaCl〇3或亞氯酸納此· 合組成包括有： 、鹽酸HC1 、擰 、及無機鹽類； 料由下列一種或數 活化劑由下列一種或數種混 酒石酸C4H6〇6 、草酸（C00H)2 檬酸 HOC3H4(COOH)3、硫酸 H2SO4 進行造粒包覆所需的辅助劑 種混合組成包括有： 9 200831399 糊精C_5、重碳酸鈉NaHC〇3、碳酸鈉Na2C〇3 、硫酸鈉Na2S〇4 、硫酸鎂MgS(k、聚乙二醇 Η(ΟΟΜ2)η〇Η、聚乙烯醇職迎⑽)）nH、羧甲基 纖維素、规甲基纖維素、羥甲基纖維素鈉、羥 乙基纖維素、羥丙基纖維素、羥丙基甲基纖^ 素、普威隆類、明膠、海藻酸鈉、瓊脂、聚丙 稀酸樹脂、樹脂、酸醇樹脂等各種水溶性和醇 溶性高分子材料及具有隔離作用的礦物油脂（ 例如：二甲基硅油、石蠟· ··等）。 一在上揭的主劑（A )、活化劑（B )、輔助劑料（C )三種劑料中’主要是利用主劑（A)和活化劑（ 化學作用來產生二氧化氯’❿因其主劑（A)與活化劑（ B )直接混合將會有爆炸、燃燒之安全疑慮，是以 ㈣之混合包裝，為解決此-問題，本發明乃嘗試;:用； 助別料（C )將主劑（A )、活化劑（B )兩種劑料 獨或複合式包覆製成粒狀劑料，並藉以簡化其^ 而：：包覆製粒所使用的設備’大致可採用流動層噴二 粒包復機或遠心流動床造粒包覆機兩種、： 備上大概有以下方案： 思战其製 第-方案：係分別以粒狀的主劑（A)及活 )為載體，並將之分別置入流動層喷物 ；、土 木造粒包覆機中，使其外層包覆-層由輔助 衣成的包覆層’如此—來，將可使主齊彳（ (B )被獨立隔離，而$致相互接觸產生^ 印用，猎以 200831399 得將兩種粒劑依比例採單一混合 立包裝（第2圖所示），使 、（弟1圖所示）或獨 擔心其會產生化學作用，因此運=獲得簡化’且毋庸 ，而在使用時，m 運輸及貯存上均相當安全 η 粒狀劑料加入水令，即可使主,丨 ⑷及活化齊"Β)溶解於水：吏^ 調細需的二氧化氣殺菌消毒劑；“㈣進而 弟一方木·係以粒狀的主劑（Δ & 流動層喷物造粒包覆機…J (A)為載體’將之置入 其外層包覆-層由辅助_ ^ ^機中’再於 活化劑（B)喷入包覆二j i製成的包㈣，而後將 外#德曰β £ 辅助劊料（c )製成的包覆層 外層後，瑕後再於該活化劑（ ：層 劑料…及製成的包覆層，即可由辅助 合稷層包覆顆粒型態，蕻兮笙 此 展蔣<古猎5亥專輔助劑料（C )製成的包覆 :有效區隔内層主劑（A)與外層活化劑（B)，八 包f，且毋唐換、甘： 來將可使其得採單- 毋庸擔心其會產生化學作用，因此在運輪及貯存 上均相當安全，而在使用砗，口⑮ 牡連輸及貯存 p . ，、要將此粒狀劑料加入水中 而二杰/舌化劑（B )及主劑（A )依序溶解於水中，進 便利且安全； b亂权困“劑，在整個使用上相當 入方案：係以粒狀的活化劑（b)》载體，將之置 入/’IL動層T物造粒包覆機式旁、 於立外屛包P屏“ 動床造粒包覆機中，再 將^ ^ 齊製成的包覆層，而後 w 纟入包覆於該輔助劑料（C )製成的包覆層 200831399 = 再於該主劑(A)外層又包覆—層由辅助劑 -(c)衣成的包覆層’即可製成如第4圖所示之 型態混合複層包覆顆粒型態，藉該等輔助劑料（c) 4 ，包覆層將可有效區隔内層活化劑（ ： :令彼此不致接觸產生化學作用，如此—來將可= 知：-包裝’且毋庸擔心其會產生化學作用，因運： 及貯存上均相當安全，而在使剧 入4 。 丁 八要將此拉狀劑料加 f )中Γ 主劑（A)及活化劑（b)依序溶解於水 ’進而調製成所需的二氧化氯殺菌消毒劑； 、 劑的：備ΓΓ說明’可知本發明在二氧化氯殺菌消毒 d的衣備上，為了確保其運輸、貯毋 同時兼顧其使用上的用上的女-性’ 輔助劑料，利用+創新地將主劑及活化劑配合 斗利用流動層喷物造粒包覆 ==其分別獨立造粒包覆或混合複 -成包覆粒狀型態，利用1 t 。復據以 >，使其不致產生化與作用\ 寸传區隔主劑與活化劑 其包袭上得以二 之採混合或獨立包裝，令 、安全，：在！传間化且可確保其運輸及貯存上更為便利 輕易地制点辦兩 —_ 適®的水加以調合，即可 分簡單、安入而：一乳化氯殺菌消毒劑，其使用上可謂十 ，誠Ur解決傳統製備方式所潛在的安全隱憂 : 么之產業利用價值與實用性者。 ， 、’、示上所述，本發日月二 斤 其包覆製粒的製備型態，粒製備發法，確能經 佳便利性與安全性， 八包裝、運輸及貯存上的極 ’在使用調製上亦極為簡單、便利而 200831399 安全，整體而言 誠不失為一優異 確具有極佳 犬出之創新 之產業利用價值與實用性， 设計，爰依法提出專利申請 【圖式簡單說明】The main agent · sodium chlorate NaCl 〇 3 or chlorite sodium · The composition includes: , hydrochloric acid HC1, screw, and inorganic salts; the following one or several activators from one or more of the following mixed tartaric acid C4H6 〇 6. Oxalic acid (C00H)2 citric acid HOC3H4(COOH)3, sulfuric acid H2SO4 The mixed components required for granulation coating include: 9 200831399 Dextrin C_5, sodium bicarbonate NaHC〇3, sodium carbonate Na2C〇 3, sodium sulfate Na2S〇4, magnesium sulfate MgS (k, polyethylene glycol Η (ΟΟΜ2) η 〇Η, polyvinyl alcohol (10))) nH, carboxymethyl cellulose, methyl cellulose, methylol Cellulose sodium, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, puweiron, gelatin, sodium alginate, agar, polyacrylic acid resin, resin, acid alcohol resin, etc. Various water-soluble and alcohol-soluble polymer materials and mineral oils with isolation (for example, dimethyl silicone oil, paraffin, etc.). In the three main agents (A), activator (B) and auxiliary agent (C), the main agent (A) and activator (chemical action to produce chlorine dioxide) The direct mixing of the main agent (A) and the activator (B) will have the safety concerns of explosion and burning, and is a mixed package of (4). In order to solve this problem, the present invention attempts to:; use; The main agent (A) and the activator (B) are separately or compositely coated into a granular agent, thereby simplifying the process: the equipment used for the coating and granulation is generally applicable. There are two kinds of flow layer spray two-package machine or telecentric flow bed granulation coating machine: There are probably the following schemes on the preparation: The first plan of the battle: the main agent (A) and the granular agent As the carrier, and placed separately into the flowing layer spray; in the civil granulation coating machine, the outer cladding-layer is covered by the auxiliary coating's coating - so that the main Qi (B) is isolated independently, and $ is in contact with each other to produce the seal. For the 200831399, the two granules should be combined in a single mixed package (Figure 2). , , (different from the picture 1) or alone, it will produce a chemical effect, so the operation = get simplified 'and no doubt, and in use, m transport and storage are quite safe η granular material added to the water, The main, 丨 (4) and activated & quot Β 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解Layer spray granulation coating machine...J (A) is a carrier which is placed in its outer coating layer - layer is prepared by auxiliary _ ^ machine and then activator (B) is sprayed into cladding ji Package (4), and then the outer layer of the coating layer made of #德曰β £ auxiliary material (c), and then the activator (: layer material... and the coated layer can be assisted by The enamel layer is coated with the particle type, and the coating made by Jiang < Guhun 5 Hai special adjuvant material (C) is effective: the inner layer main agent (A) and the outer layer activator (B) are effectively partitioned. , eight packs of f, and the Sui and Tang Dynasties, Gan: will be able to make it available - no fear that it will produce chemical effects, so it is quite safe in the transport and storage, and in the use of 砗, mouth The yum is transported and stored p. , the granules are added to the water and the jiejie/tongue agent (B) and the main agent (A) are dissolved in the water in order to facilitate and safely; The agent is used in the whole process: it is a granular activator (b) carrier, which is placed in the /'IL moving layer T material granulation coating machine, and the outer outer bag P screen "In the moving bed granulation coating machine, the coating layer is prepared separately, and then w is wrapped in the coating layer coated with the auxiliary material (C). 200831399 = then the main agent ( A) the outer layer is further coated - the layer is coated with an auxiliary agent - (c) to form a type of mixed layer coated particle type as shown in Fig. 4, by means of such auxiliary materials (c) 4, the coating layer will effectively separate the inner layer activator ( : : make each other not contact to produce a chemical effect, so - will be able to know: - packaging 'and there is no fear that it will produce a chemical effect, because: And the storage is quite safe, and the play is 4 . Ding Ba should add this pull agent to f) the main agent (A) and the activator (b) are dissolved in water in order to prepare the desired chlorine dioxide disinfectant; Illustrated 'The invention can be used in the preparation of chlorine dioxide disinfection d, in order to ensure its transportation, storage and at the same time taking into account the use of female-sex' auxiliary materials, using + innovatively to the main agent and activation The agent is matched with the hopper by the flow layer spray granulation coating == it is separately granulated or mixed and mixed into the granulated form, and 1 t is used. The data is >, so that it will not be produced and acted upon. The main agent and activator of the pass-through zone can be mixed or packaged separately, so that it is safe! Inter-transfer and ensure that its transportation and storage are more convenient and easy to make two-_ _ _ water to blend, you can divide it into simple, easy to enter: an emulsified chlorine disinfectant, its use can be described as ten , Cheng Ur solves the potential safety concerns of traditional preparation methods: the value and practicality of the industry. ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, In terms of the use of modulation, it is also extremely simple and convenient. 200831399 is safe. As a whole, it is an excellent industry. It has the value and practicality of the industry with excellent dog innovation. Design, 提出Propose patent application according to law [Simple description]
第1圖··係、本創作較佳 第2圖··係本創作較佳 第3圖：係本創作另一 第4圖：係本創作再一 九、申請專利範圍： 實施例的包裝示意圖。 實施例的另一包裝示意圖 車父佳實施例的包裝示意圖 較佳實施例的包裝示意圖 氣殺菌t:種二氧化氯造粒製備方法，其調製合成二氧 風权囷靖毒劑所需的_，主要⑽： 乳 | A )主劑.氯g曼納NaC1〇3或亞氯酸納ν_2 ; /酉石I夂C4H6〇6、草酸（c〇〇h)2、鹽酸JJC1 、檸 檬酸H0C_00H)3、硫酸趣、及無機鹽類^ c )進行造粒包覆所需的輔助劑料由 種混合组成包括有: 成數 )舌化d由下列一種或數種混合組成包括有：Figure 1 ············································································ . Another packaging diagram of the embodiment is a packaging schematic diagram of the preferred embodiment of the package. The schematic diagram of the packaging of the preferred embodiment of the gas sterilization t: a chlorine dioxide granulation preparation method, which is prepared to synthesize the dioxin of the dioxin Main (10): Milk | A) Main agent. Chlorine g Manna NaC1〇3 or sodium chlorate ν_2 ; / vermiculite I夂C4H6〇6, oxalic acid (c〇〇h) 2, hydrochloric acid JJC1, citric acid H0C_00H)3 , sulfuric acid, and inorganic salts ^ c) The auxiliary materials required for the granulation coating consist of a mixture of species: a number of tongues d consisting of one or more of the following combinations:
糊精Μιο〇5、重碳酸鈉NaH⑶3、碳酸鈉Na2c〇3 、硫酸鈉Na2S〇4、硫酸鎮MgS〇4、聚乙二醇 H(OCH2CH2)nOH、聚乙烯醇H(CH2CH(0H)) ΠΗ、羧甲基 纖維素、羥甲基纖維素、羥甲基纖維素鈉、羥 乙基纖維素、羥丙基纖維素、羥丙基曱基纖維 素、普威隆類、明膠、海藻酸鈉、瓊脂、聚丙 烯酸樹脂、樹脂、酸醇樹脂等各種水溶性和醇Dextrin Μιο〇5, sodium bicarbonate NaH(3)3, sodium carbonate Na2c〇3, sodium sulfate Na2S〇4, sulphuric acid MgS〇4, polyethylene glycol H(OCH2CH2)nOH, polyvinyl alcohol H(CH2CH(0H)) ΠΗ , carboxymethyl cellulose, hydroxymethyl cellulose, sodium carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl fluorenyl cellulose, puweiron, gelatin, sodium alginate , agar, polyacrylic resin, resin, acid alcohol resin, etc.