TW200831398A - Method of preparing chlorine dioxide with fast activation properties - Google Patents

Method of preparing chlorine dioxide with fast activation properties Download PDF

Info

Publication number
TW200831398A
TW200831398A TW96102798A TW96102798A TW200831398A TW 200831398 A TW200831398 A TW 200831398A TW 96102798 A TW96102798 A TW 96102798A TW 96102798 A TW96102798 A TW 96102798A TW 200831398 A TW200831398 A TW 200831398A
Authority
TW
Taiwan
Prior art keywords
acid
sodium
catalyst
activator
cellulose
Prior art date
Application number
TW96102798A
Other languages
Chinese (zh)
Inventor
Jian-Yi Huang
han-rong Liu
Jun-Wen Huang
Original Assignee
Ji Yi Bi Biochemical Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ji Yi Bi Biochemical Technology Co Ltd filed Critical Ji Yi Bi Biochemical Technology Co Ltd
Priority to TW96102798A priority Critical patent/TW200831398A/en
Publication of TW200831398A publication Critical patent/TW200831398A/en

Links

Landscapes

  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention provides a method of preparing chlorine dioxide with fast activation properties which is an innovative preparation method for especially targeting at chlorine dioxide synthesis whose materials or solutions are adopted with adequate preparation forms and packing for its convenient transportation and storage and is capable of quickly manufacturing and synthesizing. The preparation method is that NaClO2 or NaClO3 is used as main agent and one or more materials selected from C4H6O6, (COOH)2, HCl, HOC3H4(COOH)3, H2SO4, and acid salts is mixed to form the activator. One or more materials selected from bromochlorodimethylhydantoin, chloramine T, dichlorodimethyl, sodium dichloroisocyanurate, and sodium dichlorinated isocyanuric acid are mixed to form the catalyst. The package of materials used in chlorine dioxide synthesis can be simplified to obtain excellent preservation for convenient transportation and storage. While being in use, the materials can be fast manufactured and synthesized to achieve excellent industrial application and usability.

Description

200831398 ’加水調合,即可調製成快速活化二氧化氯殺菌消毒劑,據 此特能將二氧化氯合成所需之劑料的包裝予以簡化,並獲 得良好的保存狀態使其得以便於運輸及貯存,而使用時又 可快速調製合成,達極佳之產業利用價值與實用性者。 六、英文發明摘要: / 七、 指定代表圖: (一)本案指定代表圖為:第(1)圖。 八、 發明說明: 【發明所屬之技術領域】 本發明係關於一種快速活化二氧化氯製備方法,主要 是將二氧化氯合成所需之主劑、活化劑及催化劑等配合輔 助劑料製成三合一粒狀型態之單一包裝、各別包裝、組合 調配包裝或將主劑、活化劑、催化劑調製成溶液狀以瓶罐 包襞之,或將主劑、活化劑、催化劑配合辅助劑料調製成 溶液狀以瓶罐包裝之,待欲使用時再予加水調合,即可快 200831398 速調製成快速活化二氧化氣 劑料、溶液之包裝,並使其以便2於據此特能簡化其 時又可快速調製合成,成一種、運輪及貯存,而使用 【先前技術】 貝、彳新製備方法者。 按,二氧化氯是一種綠色消 生組織列為A 1級,1係一1 ,、女王性被世界衛 的氣體,沸點為i U :、常、;::氣相似的刺激性氣味 忌八,其有效氯為氯氣的26 9 氧化劑,而不是氯 ^•匕部疋-種尚效 。 月〗匕的虱化旎力是氣氣的2 · 5倍 二氧化氯對微生物的殺菌捣 且 _叙困機此為·二氧化氯對細胞壁 ;=的:附和穿透能力’可有效地氧化細胞内含疏基 田^ 抑制微生物蛋白質的合成來破壞微生物 主在一氧化氣除對一般細菌有殺菌作用外,對芽孢、 、藻類、鐵細菌、硫酸鹽還原菌和真菌等均有很好的 Γ、作用,溫度越高,二氧化氯的殺菌效力越大,越適合 作為工業迴流水以及溫度偏高領域的殺菌劑。 it,國内、外大量的研究發表,可知二氧化氣是作為 取代氯氣消毋的最佳方案,二氧化氯的消毒殺菌特性十分 優越,與氯氣比較,二氧化氯的殺菌特點是: (1 )殺菌效果好,用量少,作用快,二氧化氯溶於 水後,基本不與水發生化學反應,也不與二聚或多聚狀態 存在’它在水中的擴散速度與滲透能力都比氯快,特別在 低 >辰度時更突出,又二氧化氯孢子的殺滅作用比氯強,二 氧化氣對水處理系統中的藻類、異氧菌、鐵細菌及硫酸鹽 200831398 還原菌等均有較好的防止繁殖和去除、滅殺效果。 (2 )二氧化氯在很H範圍内有很㈣殺菌能力 ,二氧化氣㈣效果可以說基本不受介fpH值的影塑, 而在驗性條件下,所加的氯大部分以殺菌效果較差的^氯 ^(OC i -)形式存在’據報導,次氣酸根殺菌效果 人乳酸的1/i 〇〜i /2 〇,是以在冷卻水的鹼性 广案配用二氧化氯來控制菌蕩滋長要比加氣效果好得 多。 ’ (3 )二氧化氯殺菌效果持續時間長,經試驗證明, 伴牲ί : Μ的二氧化氯在1 2小時内對異氧菌的滅殺率 ‘下:作用時間長達成24小時時殺菌率才 .,鄉 3% ’且:氧化氣不與氨及氨基化合物反應 殺囷效果不受氨的影響。 無機二應不產生氣紛,與有機物、 有機物這使二氧化氯與腐值質及 作用的…坑有致癌 看,— )u此,從健康與環境的角度 ^命―虱取代氯氣有極其重要的意義,另外,由於氣 虱鸹要的投加量比二氧古 _ 、、 環境,需要預先餘氯排放將污染 。 齓可排放,這就造成處理成本的增加 的⑽=盖二t化氯不僅能殺死微生物,而且能分解殘留 地和殺病毒的作用,從…有* 味,與护於翻卢' 、、,心用一氧化氯處理水池的藻類臭 "<-夂、s处理法相比,發現在可比擬的處理成本下, 200831398 硫酸銅更有效’並且由於少200831398 'With water mixing, it can be prepared into a fast-acting chlorine dioxide disinfectant. According to this, the packaging of the required materials for chlorine dioxide synthesis can be simplified and obtained a good storage state for transportation and storage. And when used, it can quickly modulate and synthesize, and achieve excellent industrial use value and practicality. 6. English Abstracts: / VII. Designation of Representative Representatives: (1) The representative representative of the case is: (1). VIII. Description of the Invention: [Technical Field] The present invention relates to a method for rapidly activating chlorine dioxide, mainly for preparing a main agent, an activator and a catalyst for synthesizing chlorine dioxide into an auxiliary material. Single-package, individual packaging, combined packaging, or the main agent, activator, and catalyst are prepared into a solution in a bottle, or the main agent, activator, and catalyst are compounded with the auxiliary agent. It is prepared into a solution and packed in a bottle. When it is used, it can be mixed with water. It can be quickly prepared into a quick-activated dioxide gas agent and a solution package, so that it can be simplified according to this. At the same time, the synthesis can be quickly modulated into one type, transport wheel and storage, and the [previous technique] beneficiary method can be used. According to the chlorine dioxide, a green hygienic tissue is classified as A 1 grade, 1 strain 1 , and the queen is a world-regulated gas. The boiling point is i U :, often, ::: gas is similar to the pungent smell. The effective chlorine is the 26 9 oxidant of chlorine, not the chlorine ^ 匕 疋 种 - kind of effect. The 虱 匕 旎 是 是 是 是 是 是 是 是 是 是 是 是 是 是 是 是 是 是 是 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 Intracellular sulphate field inhibits the synthesis of microbial proteins to destroy microbial organisms. In addition to bactericidal effects on general bacteria, it has good effects on spores, algae, iron bacteria, sulfate-reducing bacteria and fungi. The higher the temperature, the higher the sterilization efficiency of chlorine dioxide, and the more suitable it is as a fungicide for industrial reflux water and high temperature. It, a large number of domestic and foreign research publications, it is known that dioxide is the best alternative to chlorine gas elimination. The disinfection and sterilization characteristics of chlorine dioxide are very superior. Compared with chlorine, the sterilization characteristics of chlorine dioxide are: The bactericidal effect is good, the dosage is small, and the effect is fast. After the chlorine dioxide is dissolved in water, it does not chemically react with water, nor does it exist in the dimeric or polymeric state. 'It has higher diffusion speed and permeability than that in water. Chlorine is fast, especially at low > Chen, and the killing effect of chlorine dioxide spores is stronger than that of chlorine. The algae, aerobic bacteria, iron bacteria and sulfate 200831398 reducing bacteria in the water treatment system. And so on have better prevention of reproduction and removal, killing effect. (2) Chlorine dioxide has very (four) bactericidal ability in the range of H, and the effect of dioxide (4) can be said to be basically free from the shadow of fpH. Under the test conditions, most of the added chlorine has a bactericidal effect. Poor ^ chloro^(OC i -) form exists] It is reported that the sulphuric acid bactericidal effect of human lactic acid is 1/i 〇~i /2 〇, which is based on the alkaline solution of cooling water. Controlling the growth of bacteria is much better than adding gas. ' (3) Chlorine dioxide bactericidal effect lasts for a long time, and it has been proved by experiments that the chlorine dioxide of Μ: Μ 二 对 在 在 1 1 1 1 1 1 1 1 1 1 1 : : : : : 异 异 异 异 异 异Rate only., Township 3% 'and: Oxidation gas does not react with ammonia and amino compounds. The killing effect is not affected by ammonia. Inorganic two should not produce gas, and organic matter, organic matter, which makes chlorine dioxide and sulphur value and role of ... pit carcinogenic, -) u, from the perspective of health and the environment - life - 虱 to replace chlorine is extremely important The meaning, in addition, due to the amount of gas to be added than the dioxin _, the environment, the need for pre-remaining chlorine emissions will be contaminated.齓 can be discharged, which causes an increase in the cost of treatment (10) = cover two chlorine can not only kill the microorganisms, but also can decompose the residual and the role of killing viruses, from ... have a taste, and protect the turn of the ', Compared with the treatment of algae in the pool with chlorine dioxide, the heart was found to be more effective at 200831398 copper sulfate at a comparable treatment cost.

減綾對投備的腐蝕,另外,微 — 乜J 較差,可以+期# & π # 士 一乳化氯的耐藥性也 長d使用而不產生顯著的抗藥性。 實驗丄Γ 升高,二氧化氯的殺菌能力增強,經大量 =二=對大腸桿菌’加二氧化氯〇· 而 9〇分鐘,而在3〇t時則僅需=殺囷效果需耗時1 菌來講是很有利的。1僅而1〇秒,這對迴流水的殺 ’體中二化氯的氧化作用很強,它能有效地破壞水 > =里有機3染物,如苯並祐···等,且對氯仿、 ⑱和I化物等氧化有機物時不發生氯化反應, 和脫臭作用’可以降低水的濁度,提高水質 二:广可以用於污水和惡臭氣體的處理,水在經二氧 消毒後能保持剩餘消毒作用,但無殘留毒性,對人體 =吾’二氧化氯消毒液在使用濃度時對皮膚粘膜無刺激作 用,其在急性毒性和遺傳毒理學上都是絕對安全的。 人(8 ) 一氧化氯消毒液用於食品加工設備、用具、盛 裝艮。口和飲料的容器、管道及果蔬等消毒後,不需再行清 先—可直接生產包裝和食用,安全性有保證,因此使二氧 匕^消毋液成為最終消毒用的理想藥劑和管網中的餘氣保 持劑,且二氧化氯殺菌消毒液可反復使用多次,因而可以 大大節約消毒費用。 由疋可知’二氧化氣乃得作為一種綠色消毒劑,其應 用^廣泛’不管就環境角度還是從衛生角度,二氧化氯取 代氯製劑都是必然的趨勢。 200831398 然,因二氧化氣並非自然存在的物質,而是需要經過 3 0分鐘以上的化學作用才能產生效果,是以目前市面可 見的溶液、粉劑或片劑等二氧化氯殺菌消毒產品,在使用 時均需,入活化劑進行活化,才能釋放出具有強烈殺菌能 力之二氧化氣,惟此類產品因其劑型的差異,在運輸及貯 存及使用上,卻普遍存在有安全性方面的問題,以溶㈣ 產2而言,其最大的問題便是運輸極為不便,且當其液體 含量超過-定程度,即必須按危險物品標準方式運輸,而 ί粉劑或片劑產品,因其原料本身具有強氧化性,與可燃性 物質接觸或與酸性物質混合即會 劑就是酸性物質,因此除了燃燒,而活化 -^ ^ U此除了必須依危險物品標準運輸外, 更需一定的程序加入定量的水中,或先麵 ,相當;L入再ί入活化劑’否則即有爆炸、燃燒之問題 田女王,只有待設法加以解決改善者。 【發明内容】 .問題見!二氧化氯殺菌消毒劍製被上所存在的諸多 /、、表明人特著手進行研發,基於1從事;^ 業之多年經驗與技術’進而研創出本發明之;:事關: 而其主要目的乃=::i〇分鐘左右即可產生效果, j长於徒供一種得以 主劑、催化劑、活化 子—乳化乳5成所需之 之單-包裝、各別辅助劑料製成三合-粒狀型態 劑、催化劑調=狀::, 化劑、催化劑配人輔/ 瓶罐包裝之,或將主劍、活 ’達到劑料、溶液包裝溶液狀各以瓶罐包裝之 之目的,俾能方便運輸及貯存 8 200831398 ,而使用時又可快速調製合成之創新製備方法者。 離目的係在於經由其三合-粒劑的組成型 吏八在加水調合時’將使其活化劑、催化劑、主劑配 合輔助劑料或主劑、催化劑、活化劑配合輔助劑料依序鱼 水混合’而非兩者同時混合’俾可維持其使用安全性,^ ,避免操作不慎發生爆炸、燃燒之安全疑慮,俾能大幅提 幵其使用便利性與安全性者。 為達前揭目的,本發明主要是以亞氯酸鈉齡他或氣 酸納NaClOs為主劑,以酒石酸議6、草酸(c〇〇h)2、鹽酸 HC1 、檸檬酸H0C3H4(C00H)3、硫酸H2S〇4、酸性鹽類等上述一 種或數種混合組成為活化劑,另以溴氯海因、氯氨丁、二 氣二甲基海因、二氯異氰尿酸鈉、三氯異氰尿酸鈉等上述 一種或數種混合組成為催化劑,而進行造粒包覆所需的辅 助劑料由下列一種或數種混合組成包括有:糊精C6Hiq〇5、 重碳酸鈉NaHC〇3、碳酸鈉Na2C〇3、硫酸鈉%$〇4、硫酸鎂Decrease the corrosion of the preparation, in addition, the micro- 乜J is poor, can be + phase # & π # 士 一 emulsified chlorine resistance is also long d use without significant resistance. The experiment 丄Γ is raised, the bactericidal ability of chlorine dioxide is enhanced, and a large amount = two = E. coli 'with chlorine dioxide chlorination · and 9 〇 minutes, while at 3 〇 t only need = killing effect takes time 1 bacteria is very beneficial. 1 only 1 〇 second, which is very strong in the oxidation of chlorine in the body of the reflux water, it can effectively destroy the water > = organic 3 dyes, such as benzo and so on, and Chloroform, 18 and I compounds do not chlorinate when oxidizing organic matter, and deodorization can reduce the turbidity of water and improve water quality. 2. Widely used for the treatment of sewage and malodorous gases. It can maintain the residual disinfection effect, but no residual toxicity. It has no stimulating effect on the skin and mucous membrane when the concentration of human body chlorine dioxide disinfectant is used. It is absolutely safe in acute toxicity and genetic toxicology. Human (8) Chlorine Dioxide Disinfectant is used in food processing equipment, utensils, and containers. After disinfecting the mouth, beverage containers, pipes, fruits and vegetables, there is no need to clear the first--can directly produce packaging and food, and the safety is guaranteed. Therefore, the dioxin solution is the ideal agent and tube for final disinfection. The residual gas retaining agent in the net, and the chlorine dioxide disinfectant can be used repeatedly for many times, thereby greatly saving the disinfection cost. It can be seen from the above that 'dioxide gas is used as a green disinfectant, and its application is extensive. Regardless of the environmental angle or the hygienic point of view, chlorine dioxide is an inevitable trend. 200831398 However, because dioxide is not a naturally occurring substance, it takes more than 30 minutes of chemistry to produce an effect. It is a chlorine dioxide disinfectant product such as a solution, powder or tablet currently available on the market. It is necessary to activate the activator to release the oxidizing gas with strong bactericidal ability. However, due to the difference in the dosage form, such products generally have safety problems in transportation, storage and use. In terms of solution (4) production 2, the biggest problem is that transportation is extremely inconvenient, and when the liquid content exceeds a certain level, it must be transported according to the standard of dangerous goods, while the powder or tablet product has its own raw material. Strong oxidizing property, when it is in contact with flammable substances or mixed with acidic substances, the agent is an acidic substance, so in addition to burning, the activation - ^ ^ U must be transported according to the dangerous goods standard, and a certain procedure is required to be added to the quantitative water. , or first, quite; L into the activator 'otherwise there is a problem of explosion, burning, Queen of the field, only to be managed to solve Improver. [Summary of the Invention] See the problem! The chlorine dioxide sterilization and disinfection of the sword system is based on the existence of many /, indicating that people specialize in research and development, based on 1; ^ industry's many years of experience and technology 'and then research and develop the invention;: matters: and its main purpose乃 =::i 〇 minutes or so can produce the effect, j is longer than a single agent for the main agent, catalyst, activator - emulsified milk, 50% Granular type agent, catalyst adjustment =::, chemical agent, catalyst with human auxiliary / bottle packaging, or the main sword, live 'to reach the agent material, solution packaging solution, the purpose of packaging each bottle,俾 Easy to transport and store 8 200831398, and can be used to quickly prepare synthetic innovative preparation methods. The purpose is to mix the activator, the catalyst, the main agent with the auxiliary agent or the main agent, the catalyst, the activator, and the auxiliary agent according to the composition of the triad-granules. Mixing 'not both at the same time' can maintain its safety of use, ^, to avoid accidental explosion and burning safety concerns, and to greatly improve the ease of use and safety. In order to achieve the goal, the present invention mainly uses sodium chlorite or sodium sulphate as the main agent, and tartaric acid 6, oxalic acid (c〇〇h) 2, hydrochloric acid HC1, citric acid H0C3H4 (C00H) 3 One or more of the above-mentioned mixed components such as sulfuric acid H2S〇4 and acidic salts are activators, and bromochlorohydantoin, chloramidine, di-dimethyldimethylhydantoin, sodium dichloroisocyanurate, trichloroethylene One or more of the above-mentioned mixed compositions such as sodium cyanurate are used as catalysts, and the auxiliary materials required for granulation coating are composed of one or more of the following: dextrin C6Hiq〇5, sodium bicarbonate NaHC〇3, Sodium carbonate, Na2C〇3, sodium sulfate%$〇4, magnesium sulfate

MgS〇4、聚乙二醇 Η(〇〇ΜΙ2)ηΟΗ、聚乙烯醇 h(CH2CH(0H)) nH、羧 Λ 甲基纖維素、羥曱基纖維素、羥甲基纖維素鈉、羥乙基纖 維素、羥丙基纖維素、羥丙基曱基纖維素、普威隆類、明 膠、海藻酸鈉、瓊脂、聚丙烯酸樹脂、樹脂、酸醇樹脂等 各種水溶性和醇溶性高分子材料及具有隔離作用的礦物油 脂(例如··二曱基硅油、石蠟··等),再利用流動層喷 物造粒包覆機或遠心流動床造粒包覆機,將前述主劑及活 化劑及催化劑配合輔助劑料採獨立造粒包覆或混合複層造 粒包覆方式,藉由上述之方式可將主劑、活化劑、催化劑 製成三合一粒狀型態之單一包裝、各別包裝、組合調配包 200831398 裝’或將主劑、活化劑、催化劑、 裝,或將主劑、活化劑、催化劑配合輔::::以瓶罐包 狀各以瓶罐包1,待欲制時衫 ^調製成溶液 快速活化二氧化氯殺㈣毒劑,據此特^ ^可調製成 化氯合成所需之劑料的包裝予以簡化師=化二氧 狀態使其得以便於運輸及貯存,而使用時;;二= 成’達極佳之產業利用價值與實用性者。H 【實施方式】 有關本發明製備方法、技術手段及功 再加以說明於后: ά 本發明快速活化二氧化氯殺菌消毒劑所需的劑料,主 要包括: (A )主劑·亞氯酸鈉NaCl〇2或氯酸納NaCl〇3 ,· (B )活化劑由下列一種或數種混合組成包括有·· 酒石酸Μ6〇6 、草酸(COOH)2、鹽酸HC1 、擰檬酸 ΪΚΧ:3ΐΙ4(ω〇Η)3、硫酸 H2S〇4、酸性鹽類; (C )催化劑由下列一種或數種混合組成包括有··可為漠 氯海因、氯氨丁、二氯二甲基海因、二氯異氰尿酸 鈉、三氯異氰尿酸鈉; ※進行造粒包覆所需的輔助劑料由下列一種或數種混合組 成包括有:糊精C6Hig〇5、重碳酸鈉NaHC〇3、碳酸納 Na2C〇3、硫酸鈉Na2S〇4、硫酸鎂MgS〇4、聚乙二醇 H(OCH2CH2)nOH、聚乙烯醇Η(ΟΜ:Η(ΟΗ)) nH、羧曱基纖維素、經 甲基纖維素、羥曱基纖維素鈉、羥乙基纖維素、羥丙基纖 維素、羥丙基曱基纖素、普威隆類、明膠、海藻酸納瓊脂 200831398 酸醇樹脂等各種^容性和醇溶性 用的礦物油脂(例如:二甲基凌 、聚丙烯酸樹脂、樹脂、 南分子材料及具有隔離作 油、石蠟· ··等), 在上揭的主劑(A)、活化劑(B)和催化 三種劑料中,主要是利用主舞 1(A)和活化劑( ^作用來產生快速活化:氧化氯,而催 =,而因其主劑(A)與活㈣"”直接混i :; =^燒之安全疑慮’而為了取得快速活化二氧化^ 囷消,劑的㈣便利性,本發明乃將主劑(a)、活都 (B)和催化劑(C)三種劑料製成三合一之粒 : 知以知單一包裝型態製備,而在此種三合一粒劑的製備上 ’大概有以下幾種方案: 第一方案··係以粒狀的主劑(A )為載體,而將催化 劑(C )與活化劑(B )製成粉狀,再利用輔助劑料,將 催化劑(C )與活化劑(b )依序包覆於主劑(A )的外 部L其作法上係將主劑(A)置於流動層喷霧造粒包覆機 I或遠心流動床造粒包覆機中,再將粉末狀的催化劑(c) 與辅助劑料同步喷入流動層喷霧造粒包覆機或遠心流動床 造粒包覆機中,令催化劑(c )包覆於主劑(A )外層, 而後再將粉末狀之活化劑(B )及辅助劑料同步噴入流動 層喷霧造粒包覆機或遠心流動床造粒包覆機中,使活化劑 (B )得以包覆於催化劑(C )外層,依此製成如第丄圖 所示之三合一包覆顆粒型態,使主劑(A )、活化劑(B )不致接觸產生化學作用,如此一來將可使其得採單一包 裝’且毋庸擔心其會產生化學作用,因此在運輸及貯存上 只要將此粒狀劑料加入水中, 劑(C )和主劑(A )依序溶 的快速活化二氧化氣殺菌消秦 且安全; 活化劑(B )為載體,而將催 成粉狀,再利用辅助劑料,將 依序包覆於活化劑(B )的外 劑(B )置於流動層喷霧造粒 覆機中’再將粉末狀的催化劑 流動層噴霧造粒包覆機或遠心 化劑(C )包覆於活化劑(b 主劑(A )及輔助劑料同步噴 遠心流動床造粒包覆機中,使 劑(C )外層,依此製成如第 型態,使活化劑(B )、主劑 用,措以使其得採單一包裝, 女全性’而在欲調製使用時, ,即可使主劑(A)、催化劑 溶解於水中,進而調製成所需 毒劑,提供便利且安全之實用 ,將主劑(A )、活化劑(b 劑料製成粒狀、粉狀或片狀的 袋,待欲使用時再予依序加入 化作用而調製成快速活化二氧 200831398 均相當安全,而在使用時’ 即可使活化劑(B )、催化 解於水中,進而調製成所需 劑,在整個使用上相當便利 第二方案:係以粒狀的 化劑(C )與主劑(A )製 催化劑(C )與主劑(A ) 部,其作法上係將粒狀活化 f 包覆機或遠心流動床造粒包 (C )及輔助劑料同步喷入 流動床造粒包覆機中,令催 )外層,而後再將粉末狀之 入流動層喷霧造粒包覆機或 主劑(A )得以包覆於催化 2圖所示之三合一包覆顆粒 (A)不致接觸產生化學作 、 並得確保其運輸及貯存上的 只要將此粒狀劑料加入水中 (C )和活化劑(B)依序 的快速活化二氧化氯殺菌消 價值; 第二方案··係在調製上 )、催化劑(C )配合輔助 劑料後,再予分別包裝成三 水中調和,即可經其化學變 200831398 化氯殺菌消毒劑者。 ^四方案:係在調製上,將主劑")、活化劑(b =化劑(c)配合辅助劑料製成粒狀、粉狀或片狀的 劑料後,將活化劑(B)、催化劑(c)包裝成一袋,再 =主劑(A)包裝成-袋,待欲使用時再予依序加入水令 經其化學變化作用而調製成快速活化二氧化氣 杀又囷消毒劑者。 第五方案:係在調製上’將主劑")、活化劑(b ㈣:化劑(C)配合辅助劑料製成粒狀、粉狀或片狀的 二:將主劑(A)、催化劑(C )包裝成-袋,再將 活化刮(B )包裝成一势,彡主/、A At ro Μ 风衣待欲使用時再予依序加入水中 调和,即可經其化學變化作 殺菌消毒劑者。 用而㈣成快速活化二氧化氣 弟六方案:係在調製上,將主劑(Α)、活化劑(Β 催化制(c )製成溶液狀後’再將主劑(幻、活化 、催化劑(c)各別包裝成一瓶(罐),待欲使 =再予依序加人水t調和,即可經其化學變化作用而調 1成快速活化二氧化氯殺菌消毒劑者。 第七方案·係在调製上,將主劑(A )、活化劑(B 催化蜊(◦)配合辅助劑料製成溶液狀後,再將主劑 鐯^/舌化劑(B )、催化劑(c )各別包裝成-瓶( 辦),待欲使用時再予依序加入水中調和,即可經其化學 交化作用而調製成快速活化二氧化氣殺菌消毒劑者。 即,經由以上說明,可知本發明快速活化二氧化氯殺 “勢4的製備上,為了確保其運輸、貯存及使用上的安 200831398 全性,同時兼顧其使用上 劑及催化劑配合輔助劑料 一包裝、各別包裝、組合 催化劑調製成溶液狀各以 催化劑配合辅助劑料調製 輸及貯存上更為便利、安 的水加以調合,即可輕易 殺菌消毒劑,其使用上可 ^統製備方式所潛在的安全 值與實用性者,誠不失為 法提出專利申請。 【圖式簡單說明】 苐1圖:係本創作較佳實 第2圖:係本創作另第一 第3圖:係本創作另第二 第4圖:係本創作另第三 、1第5圖:係本創作另第四 第6圖:係本創作另第五 第7圖:係本創作另第六 第8圖:係本創作另第七 的便利性,創新地將主劑、活化 ,將其製成三合一粒狀型態之單 调配包裝’或將主劑、活化劑、 瓶罐包裝,或將主劑、活化劑、 成溶液狀各以瓶罐包裝,令其運 全’而在使用時亦僅需加入適量 地製成所需之快速活化二氧化氣 明十分間早、安全,有效解決傳 隱憂,誠具有極佳之產業利用價 一優異、突出之創新設計,爰依 例之結構型態示意圖。 較佳實例之結構型態示意圖。 較佳實例之結構型態示意圖。 較佳實例之結構型態示意圖。 較佳實例之結構型態示意圖。 較佳實例之結構型態示意圖。 較佳實例之結構型態示意圖。 較佳實例之結構型態示意圖。 九 1 化 申請專利範圍: 種快速活 二氧卜友扭— 虱化軋I備方法,其調製合成快速 A) hI剎所需的劑料,主要包括: "亞氯馱鈉NaCl〇2或氯酸鈉NaCi〇3 ;MgS〇4, polyethylene glycol Η(〇〇ΜΙ2)ηΟΗ, polyvinyl alcohol h(CH2CH(0H)) nH, carboxymethyl cellulose, hydroxymethyl cellulose, sodium carboxymethyl cellulose, hydroxyethyl Various water-soluble and alcohol-soluble polymer materials such as cellulose, hydroxypropyl cellulose, hydroxypropyl fluorenyl cellulose, puweiron, gelatin, sodium alginate, agar, polyacrylic resin, resin, acid alcohol resin And mineral oils and fats having an insulating effect (for example, diterpene-based silicone oil, paraffin wax, etc.), and then using a fluidized bed spray granulation coating machine or a telecentric fluidized bed granulation coating machine, the above-mentioned main agent and activator And the catalyst compounding agent material adopts independent granulation coating or mixed layer granulation coating method, and the main agent, the activator and the catalyst can be made into a single package of three-in-one granular form by the above method, and each Do not pack, mix and match package 200831398 Pack 'or the main agent, activator, catalyst, equipment, or the main agent, activator, catalyst with the auxiliary:::: in the shape of a bottle and a bottle, each bottle, 1 When the system is made into a solution, the solution quickly activates the chlorine dioxide to kill the (four) poison, according to which The package of the agent required for the synthesis of chlorine can be simplified to simplify the division = the state of dioxin to make it easy to transport and store, and when used;; 2 = into an excellent industrial use value and practical Sex. H [Embodiment] The preparation method, technical means and work of the present invention are described later: 剂 The agent material required for rapidly activating chlorine dioxide disinfectant of the present invention mainly comprises: (A) a main agent · chlorous acid Sodium NaCl〇2 or sodium chlorate NaCl〇3, · (B) Activator consists of one or more of the following: 有6酒6, oxalic acid (COOH) 2, hydrochloric acid HC1, citric acid citrate: 3ΐΙ4 (ω〇Η)3, sulfuric acid H2S〇4, acid salts; (C) catalyst consists of one or more of the following mixtures: ··································································· , sodium dichloroisocyanurate, sodium trichloroisocyanurate; ※ The auxiliary material required for granulation coating consists of one or more of the following: dextrin C6Hig〇5, sodium bicarbonate NaHC〇3 Na2C〇3, sodium sulfate Na2S〇4, magnesium sulfate MgS〇4, polyethylene glycol H(OCH2CH2)nOH, polyvinyl alcohol (ΟΜ:Η(ΟΗ)) nH, carboxymethyl cellulose, Methylcellulose, sodium hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl fluorenyl fibrin, Pweron, Gelatin, alginate alginate 200831398 acid alcohol resin and other mineral oils for compatibility with alcohol and alcohol (for example: dimethyl ling, polyacrylic resin, resin, southern molecular materials, and segregating oil, paraffin, etc. In the above-mentioned main agent (A), activator (B) and catalytic three kinds of materials, mainly using the main dance 1 (A) and activator (^ to produce rapid activation: oxidized chlorine, and urging = And because the main agent (A) and the living (four) "" directly mixed i:; = ^ burning safety concerns' and in order to obtain rapid activation of the dioxide, the (four) convenience of the agent, the present invention is the main agent ( a), living (B) and catalyst (C) three kinds of three-in-one granules: known to know the preparation of a single package, and in the preparation of such three-in-one granules, 'there are the following The first scheme is to use the granular main agent (A) as a carrier, and the catalyst (C) and the activator (B) are powdered, and then the auxiliary agent is used to carry out the catalyst (C) and The activator (b) is sequentially coated on the outer portion of the main agent (A). The method is as follows: the main agent (A) is placed in a fluid layer spray granulation coating In the I or telecentric fluidized bed granulation coating machine, the powdered catalyst (c) and the auxiliary agent are simultaneously sprayed into the fluidized bed spray granulation coating machine or the telecentric fluidized bed granulation coating machine to make the catalyst (c) coating the outer layer of the main agent (A), and then simultaneously spraying the powdered activator (B) and the auxiliary agent into the fluidized bed spray granulation coating machine or the telecentric flow bed granulation coating machine So that the activator (B) can be coated on the outer layer of the catalyst (C), thereby forming a three-in-one coated particle type as shown in the figure, so that the main agent (A) and the activator (B) are not The contact produces a chemical action, which will allow it to be taken in a single package' and there is no fear that it will produce a chemical action. Therefore, it is only necessary to add the granular agent to the water during transportation and storage, the agent (C) and the main agent ( A) The rapid activation of the dioxide gas in the order of sterilization and sterilization is safe; the activator (B) is the carrier, and will be powdered, and then the auxiliary agent is used to coat the activator (B) sequentially. The external agent (B) is placed in a fluidized bed spray granulation machine to spray granulation of the powdered catalyst flow layer. The covering machine or the telecentricizer (C) is coated with an activator (b main agent (A) and an auxiliary agent synchronous sprayed telecentric flow bed granulation coating machine, and the outer layer of the agent (C) is prepared as described above. The type, the activator (B), the main agent is used, so that it can be taken in a single package, and the whole agent can be used to prepare the main agent (A) and the catalyst to be dissolved in water. It is prepared into a desired poison to provide convenience and safety. The main agent (A) and the activator (b agent are made into a granular, powder or flaked bag, and then added sequentially when needed. The modulation into rapid activation of dioxin 200831398 is quite safe, and when used, the activator (B) can be catalyzed in water and then prepared into the desired agent, which is quite convenient for the whole process. a granulating agent (C) and a main agent (A) catalyst (C) and a main agent (A), which are granulated activated f coating machine or telecentric fluidized bed granulation package (C) and The auxiliary agent is sprayed synchronously into the fluidized bed granulation coating machine to make the outer layer, and then spray the powder into the flowing layer. The granulation coating machine or the main agent (A) can be coated on the three-in-one coated particles (A) shown in the catalysis diagram 2 to prevent the chemical from being produced, and to ensure the transportation and storage thereof, as long as the granules are The addition of the agent to the water (C) and the activator (B) sequentially activates the chlorine dioxide to eliminate the value; the second solution is based on the preparation), and the catalyst (C) is compounded with the auxiliary agent, and then separately packaged. It can be reconciled into three waters, and it can be chemically modified by 200831398. ^ Four schemes: after the preparation of the main agent ", activator (b = chemical agent (c) with adjuvant material into a granular, powder or flake-like agent, the activator (B ), the catalyst (c) is packaged into a bag, and then the main agent (A) is packaged into a bag. When it is intended to be used, the water is added in sequence to prepare a rapid activation of the dioxide gas by means of its chemical change. The fifth scheme: in the preparation of the 'main agent', the activator (b (four): the agent (C) with the adjuvant material into a granular, powder or flake 2: the main agent (A), the catalyst (C) is packaged into a bag, and then the activation scraper (B) is packaged into a potential, and the At//A At ro Μ windbreaker is added to the water to be conditioned and then passed through the chemistry. Change as a disinfectant. Use (4) to quickly activate the dioxide gas six program: in the preparation, the main agent (Α), activator (Β catalytic system (c) into a solution after the 're-master The agent (illusion, activation, catalyst (c) is packaged into a bottle (can), and if it is to be re-adjusted, it can be adjusted by its chemical change. 1% of the rapid activation of chlorine dioxide disinfectant. The seventh scheme is to prepare the main agent (A), activator (B catalytic ruthenium (◦) with adjuvant material into a solution, and then The main agent 鐯^/tonylating agent (B) and the catalyst (c) are respectively packaged into a bottle (handle), and then added to the water and then adjusted in order to be used, and then can be rapidly formed by chemical crosslinking. The activated sulfur dioxide sterilization disinfectant. That is, according to the above description, it can be seen that the present invention rapidly activates the chlorine dioxide to kill the "potential 4" preparation, in order to ensure its transport, storage and use of the integrity of 200831398, while taking into account its use The upper agent and the catalyst are combined with the auxiliary material, a package, a separate package, and a combined catalyst to prepare a solution. The catalyst is mixed with the auxiliary agent to prepare and transport, and the water is more convenient and safe to be blended, so that the disinfectant can be easily disinfected. If you use the potential safety value and practicability of the preparation method, you can file a patent application for the law. [Simplified illustration] 苐1图: This book is better than the second picture: One third Figure: This is the second and fourth picture of this creation: the third and the first picture of this creation: the fourth and sixth picture of this creation: the fifth and seventh picture of this creation: the sixth Figure 8: The seventh convenience of this creation, innovatively, the main agent, activated, made into a three-in-one granular type of monotonous packaging 'or packaging the main agent, activator, bottle, Or the main agent, the activator, and the solution are packaged in a bottle and can be transported. In addition, it is only necessary to add an appropriate amount of the rapidly activated dioxide gas to be used in the early, safe and effective manner. Resolving the hidden worry, Cheng has an excellent industrial utilization price, an outstanding and innovative design, and a schematic diagram of the structure of the example. A schematic diagram of the structure of the preferred example. A schematic diagram of a structural form of a preferred embodiment. A schematic diagram of a structural form of a preferred embodiment. A schematic diagram of a structural form of a preferred embodiment. A schematic diagram of a structural form of a preferred embodiment. A schematic diagram of a structural form of a preferred embodiment. IX1 patent application scope: a kind of fast-acting dioxo-twisting------------------------------------------------------------------------------------------------------------------------------ Sodium chlorate NaCi〇3;

Claims (1)

200831398 全性,同時兼顧其使用上 劑及催化劑配合輔助劑料 一包裝、各別包裝、組合 催化劑調製成溶液狀各以 催化劑配合辅助劑料調製 輸及貯存上更為便利、安 的水加以調合,即可輕易 殺菌消毒劑,其使用上可 ^統製備方式所潛在的安全 值與實用性者,誠不失為 法提出專利申請。 【圖式簡單說明】 苐1圖:係本創作較佳實 第2圖:係本創作另第一 第3圖:係本創作另第二 第4圖:係本創作另第三 、1第5圖:係本創作另第四 第6圖:係本創作另第五 第7圖:係本創作另第六 第8圖:係本創作另第七 的便利性,創新地將主劑、活化 ,將其製成三合一粒狀型態之單 调配包裝’或將主劑、活化劑、 瓶罐包裝,或將主劑、活化劑、 成溶液狀各以瓶罐包裝,令其運 全’而在使用時亦僅需加入適量 地製成所需之快速活化二氧化氣 明十分間早、安全,有效解決傳 隱憂,誠具有極佳之產業利用價 一優異、突出之創新設計,爰依 例之結構型態示意圖。 較佳實例之結構型態示意圖。 較佳實例之結構型態示意圖。 較佳實例之結構型態示意圖。 較佳實例之結構型態示意圖。 較佳實例之結構型態示意圖。 較佳實例之結構型態示意圖。 較佳實例之結構型態示意圖。 九 1 化 申請專利範圍: 種快速活 二氧卜友扭— 虱化軋I備方法,其調製合成快速 A) hI剎所需的劑料,主要包括: "亞氯馱鈉NaCl〇2或氯酸鈉NaCi〇3 ; 200831398 (B )活化劑由下列一種或數種混合組成包括有: 酒石酸Μ6〇6 、草酸(c〇〇H)2、鹽酸HC1 、檸檬酸 HOC3H4(COOH)3、硫酸 H2S〇4、酸性鹽類; (C)催化劑由下列一種或數種混合組成包括有:可為溴 氣海因、氯氨T、二氯二甲基海因、二氯異氛尿酸 鈉、三氯異氰尿酸納; ※進行造粒包覆所需的輔助劑料由下列一種或數種混合組 成包括有:糊精CeHioO5、重碳酸鈉NaHC〇3、碳酸納 ( %2〇)3、硫酸鈉Na2S〇4、硫酸鎂MgS〇4、聚乙二醇 油、石蠟 H(OCH2CH2)nOH、聚乙烯醇 H(CH2CH(0H)) nH、羧曱基纖維素、_ 甲基纖維素、羥甲基纖維素鈉、羥乙基纖維素、羥丙基纖 維素、經丙基甲基纖素、普威隆類、明膠、海藻酸納^脂 •、聚丙烯酸樹脂、樹脂、酸醇樹脂等各種水溶性和醇溶^ 高分子材料及具有隔離作用的礦物油脂(例如:二甲基破 等) 而在其製備上,係以粒狀的主劑(A )為載體,而將 活化劑(B )與催化劑(C )製成粉狀,再利用輔助劑料 ’將催化劑(C )與活化劑(B )依序包覆於主劑(A ) 的外部’其作法上係將主劑(A )置於流動層噴物造粒包 覆機或遠心流動床造粒包覆機中,再將粉末狀的催化劑( c )及輔助劑料同步喷入流動層喷物造粒包覆機或遠心谅 動床造粒包覆機中,令催化劑(C )包覆於主劑(A)外 層,而後再將粉末狀之活化劑(B )及輔助劑料同步喷入 流動層喷物造粒包覆機或遠心流動床造粒包覆機中,使、、舌 化劑(B )得以包覆於催化劑(c )外層,依此製成如第 5 200831398 1圖所示之三合一包覆顆粒型態,使三者不致接觸產生化 學作用,俾使其得採單一包裝,且運輸及貯存上均相當安 全,而在使用時,只要將此粒狀劑料加入水中,即可使舌 化劑(B )、催化劑(C )和主劑(A )依序溶解於水令 ’進而調製成所需的快速活化二氧化氯殺菌消毒劑者。 2、一種快速活化^一氧化氣製備方法,其調製合成快 速活化二氧化氯殺菌消毒劑所需的劑料,主要包括: (A )主劑:亞氣酸鈉或氯酸鈉; r ( B )活化劑由下列一種或數種混合組成包括有:酒石酸 、草酸、鹽酸、檸檬酸、硫酸、酸性鹽類; (c )催化劑由下列一種或數種混合組成包括有··可為溴 氯海因、氯氨T、二氣二甲基海因、二氯異氰尿酸 ’ 鈉、三氯異氰尿酸鈉; ※進行造粒包覆所需的輔助劑料由下列一種或數種混合組 成包括有:糊精、重碳酸鈉、碳酸鈉、硫酸鈉、硫酸鎂、 、聚乙二醇、聚乙烯醇、羧曱基纖維素、羥甲基纖維素、羥 (、甲基纖維素鈉、羥乙基纖維素、羥丙基纖維素、羥丙基曱 基纖素、普威隆類、明膠、海藻酸納壊脂、聚丙稀酸樹脂 、樹脂、酸醇樹脂等各種水溶性和醇溶性高分子材料及具 有隔離作用的礦物油脂(例如:二曱基硅油、石蠟·· · 等); 麻其製備上,係以粒狀的活化劑(B )為载體,而將主 劑(A )與催化劑(c )製成粉狀,再利用輔助劑料,將 ,化:(C )與主劑(A )依序包覆於活化劑(B )的外 部,其作法上係將粒狀活化劑(B)置於流動層噴物造粒 200831398 包覆機或遠心流動床造粒包覆機中,再將粉末狀的催化劑 (c)及輔助劑料同步喷入流動層喷物造粒包覆機或遠心 流動床造粒包覆機中,令催化劑(c )包覆於活化劑(B )外層,而後再將粉末狀之主劑(A )及輔助劑料同步嘴 入机動層喷物造粒包覆機或遠心流動床造粒包覆機中,使 主劑(A)得以包覆於催化劑(c)外層,依此製成如第 =圖所示之三合一包覆顆粒型態,使三者不致接觸產生化 予作用,藉以使其得採單一包裝,並得確保其運輪及貯存 ^上的安全性,而在欲調製使用時,只要將此粒狀劑料加入 水中,即可使主劑(A )、催化劑(C )和活化劑(B )依序溶解於水中,進而調製成所需的快速活化二4 殺菌消毒劑者。 、、3、一種快速活化二氧化氯製備方法,其調製合成快 速活化二氧化氣殺菌消毒劑所需的劑料,主要包括: (A )主劑:亞氯酸鈉或氯酸鈉; (B )活化劑由下列一種或數種混合組成包括有:酒石酸 、 、草酸、鹽酸、擰檬酸、硫酸、酸性鹽類; · (C )催化劑由下列一種或數種混合組成包括有:可為溴 氯海因、氯氨T、二氯二甲基海因、二氯異氛尿酸 鈉、三氯異氰尿酸鈉; 其調製上,係將主劑、活化劑、催化劑製成粒狀、粉 狀或片狀的劑料後,再予分別包裝成三袋,待欲使用時^ 予依序加入水中調和,即可經其化學變化作用而調製成快 速活化一乳化乳殺囷消毒劑者。 4、-種快速活化二氧1 化7氯製備方&,其_製合成快 200831398 速活化二氧化氯殺菌消毒劑所需 (A)主劑:亞氯酸鈉或氯酸納;彳主要包括·· ⑴活:劑由下列一種或數種混合組成包括有: 、卓酸、鹽酸、檸檬酸、硫酸、酸性鹽類; c劑由下列—種或數種混合組成包、’ 虱海因、氯氨T、二氯二 : 納、三氯異氰尿酸鈉; -軋異乱尿酸 ※進行造粒包覆所需的辅助劑料由下列 成包括有:糊精、重碳酸鈉、碳鈉::合虹 聚乙二醇、聚乙婦醇、叛甲基纖維素、=纖=鎂、 甲基纖維素m基纖維素、λ 2纖維素、經 基纖素、普威隆類、明膠、海藻酸甲 、樹脂、酸醇#聚丙烯酸樹脂 _树月曰專各種水溶性和醇溶性高分子 有隔離作用的礦物油脂(例如:二甲其垆 ’八 等); 土土 /田、石壤· · · 其調製上,係將主劑、活化挪丨 =成粒狀、粉狀或片狀的劑料後’再予分二料 :欲使用時再予依序加入水中調和,即可經其化:變: 用而凋製成快速活化二氧化氯殺菌消毒劑者。 、、5、一種快速活化二氡化氯製備方法,其調製 速活化二氧化氯殺菌消毒劑所需的劑料,主要包括·、 (A )主劑:亞氯酸納或氣酸納; ⑴活化劑由下列一種或數種混合組成包括有: 、草酸、鹽酸、檸檬酸、硫酸、酸性鹽類; (C )催化劑由下列—種或^種混合組成包括有:可為漠 200831398 =海因t氨τ、二氯二甲基海因、二氯異氛尿酸 鋼、二乳異氰尿酸納; ※進行造粒包覆所需的辅助劑料由下列-種或數種混合組 f包括有··糊精、重碳酸納、碳酸納、硫㈣、硫酸鎮、 聚乙二醇、聚乙埽醇、羧甲基纖維素、經甲基纖維素、經 甲基纖維素納、經乙基纖維素、㈣基纖維素、㈣基f 基纖^、普威隆類、明膠、耗酸納凌脂、聚丙烯酸樹脂 樹月曰、酸醇樹脂等各種水溶性和醇溶性高分子材料及見 有隔離作料鑛物油脂(例如:二^基❹、 .八 等); 其調製上’係將主劑、活化劑、催化劑配合辅助劑料 衣成粒狀、粉狀或片狀的劑料後,將三者包裳成一袋 欲使用時再予依序加入水中調和’即可經其化學變^作用 而調製成快速活化二氧化氯殺菌消毒劑者。 6、-種快速活化二氧化氯製備方法,其調製合成快 迷活化二氧化氯殺菌消毒劑所需的劑料,主要包括·、 (A )主劑:亞氣酸鈉或氯酸鈉; (B )活化劑由下列一種或數種混合組 # △ , Λ 0枯有·酒石酸 、卓I、鹽酸、擰檬酸、硫酸、酸性鹽類· (C )催化劑由下列一種或數種混合組成包括有·、 氯海因、氣氨Τ、二氯二曱基海因、W可為廣 一β田t —氣異氰尿酸 鈉、二乳異氣尿酸鈉; ※進行造粒包覆所需的輔助劑料由下列一稽 4我歎種混合组 成匕括有·糊精、重碳酸鈉、碳酸鈉、硫酸納、☆知 ^5» All·酸鎮、 來乙二醇、聚乙烯醇、羧曱基纖維素、羥曱 19 土纖维素、經 200831398 f基纖維素m基纖維素、經丙基纖維素、經丙基甲 基纖素θ威隆類、明膠、海藻酸納瓊脂、聚丙烯_脂 树月a馱醇树脂等各種水溶性和醇溶性高分子材料及具 有隔離作用的礦物油脂(例如··=甲基娃油、石蠛· ·:、 等); 其凋製上’係將主劑、活化劑、催化劑配合輔助劑料 製成粒狀、粉狀或片狀的劑料後,再將活化劑(b)、催 化劑(C)包裝成一袋’再將主劑(A)包裝成一袋,待 欲使用時再予依序加人水中調和,即可經其化學變化作用 而調製成快速活化二氧化氯殺菌消毒劑者。 、、7、:種快速活化二氧化氯製備方&,其調製合成快 速活化二氧化氯殺菌消毒劑所需的劑料,主要包括: (A )主劑:亞氣酸鈉或氯酸鈉; (B)活化劑由下列一種或數種混合組成包括有:酒石酸 、草酸、鹽酸、擰檬酸、硫酸、酸性鹽類; (C )催化劑由下列—種或數種混合組成包括有:可為漠 氯海因、氣氨T、二氯二甲基海因、二氯異氰尿酸 鈉、三氯異氰尿酸鈉; ㈣助_由下列—種或數種混合电 成包括有:糊精、重碳酸鈉、碳酸納、硫_、硫_、 聚乙二醇、聚乙稀醇、Μ甲基纖維素、經甲基纖維辛、_ I基纖維素納、經乙基纖維素、_基纖維素、㈣^ 基,素、普威隆類、明膠、㈣酸納瓊脂、聚丙稀酸 右樹脂、酸賴脂等各種水純和醇溶性高分子材料及旦 有隔離作用的礦物油脂(例^〔甲基料、石蠛·.: 200831398 等); 、其凋製上’係將主劑、活化劑、催化劑配合辅助劑料 製成粒狀、粉狀或片狀的劑料後,再將主劑(A )、催化 劑(C )包裝成_袋’再將活化劑(β )包裝成一袋,待 欲使用%再予依序加入水中調和,即可經其化學變化 而調製成快速快速活化二氧化氯殺菌消毒劑者。 /r 、、8 ::種快速活化二氧化氯製備方法,其調製合成快 速活化二氧化氯殺菌消毒劑所需的劑料,主要包括:、 (A )主劑:亞氯酸鈉或氯酸鈉; (B)活化劑由下列—種或數種混合組成包括有:酒石酸 、草酸、鹽酸、擰檬酸、硫酸、酸性鹽類; (C )催化劑由下列—種或數種混合组成包括有:可為臭 氯海因、氯氨T、二氣二甲基海因、二氯異氰尿酸 納、三氯異氰尿酸鈉; ※進行造粒包覆所需的輔助劑料由下列一種或數種混合組 2包括I:糊精、重碳酸鈉、碳酸鈉、硫酸鈉、硫酸鎂、 =乙二醇、聚乙烯醇、羧甲基纖維素、羥甲基纖維素:_ =基纖維素納、M乙基纖維素、經丙基纖維素、㈣基甲 :,素、普威隆類、明膠、海藻酸料脂、聚丙烯酸樹脂 十月曰、酸醇樹脂等各種水溶性和醇溶性高分子材料及具 ,隔離作用的礦物油脂(例如··二曱基硅油、石蠟·· · 等); 其調製上,係將主劑、活化劑、催化劑製成溶液狀後 將主劑(A )、活化劑(B )、催化劑(c )各別包 、成-瓶(罐),待欲使用時再予依序加人水中調和 2 200831398 可經其化學變化作用而調製成快 劑者。 ^心化—减氣殺菌消毒 9、-種快速活化二氧化氣製備方法 速活化二氧化氯殺菌消毒劑所需的劑料,主要包成快 (A )主劑··亞氯酸鈉或氯酸鈉; (B)活化劑由下列一種或數種混合组成包括 、草酸、鹽酸、擰檬酸、硫酸、酸性鹽頬;- (C )催化劑由下列一種或數種混合組成包括有 氯海因、氯氨丁、二氣-甲其也阴 納、三氣異氣尿酸納基海因、二氯異氛尿酸 ※進行造粒包覆所需的辅㈣料下列—種或數種混合缸 成包括有:糊精、重碳酸鈉、碳酸納、硫酸納、硫酸鎮、、 聚乙二醇、聚乙烯醇、叛甲基纖維素、羥甲基纖心、、 甲基纖維素鈉、羥乙基纖維素、_基纖維素、經丙基^ 基纖素、普威隆類、明膠、海藻酸納瑗脂、聚丙埽酸ς脂 、樹脂、酸醇樹脂等各種水溶性和醇溶性高分子材料及呈 有隔離作用的礦物油脂(例如:二甲基娃、、由、 , /、 等); 土 / 、石壤.·. 、其調製上,係m活化劑、催化劑配合辅助劑料 製成溶液狀後,再將主劑(a)、活化劑(B)、催化劑 (c)各別包裝成—瓶(罐),待欲使用時再予依序加入 水中調和,即可經其化學變化作用而調製成快速活化 化氣殺菌消毒劑者。 1 n快速活化二氧化氯製備方法,其調製合成 快速活化一氧化氯殺菌消毒劑所需的劑料,主勺· 2 2 匕枯· 200831398 (A )主劑··亞氯酸納或氯酸鈉; (B)活化劑由下列-種或數種混合組成包括有:酒 、草酸、鹽酸、檸檬酸、硫酸、酸性鹽類· (C )催化劑由下列一種或數種混合組成 : 氯海因、氯氨丁、二氯二甲基海因、二^ 為溴 鈉、三氯異氰尿酸納; Ί異氰尿 ※進行造粒包覆所需的辅助劑料由下列一種 成包括有:糊精、重碳酸鈉、碳酸納:數種混合組 , 守r 一絲 ^ ^ ^ ^ θ夂納、硫酸鎂、 .丨♦乙一知、聚乙烯醇、羧甲基纖維素、羥甲 甲基纖維素鈉、經乙基纖維素、經丙基ς纖維素、經 基纖素、普威隆類、明膠、海藻酸納壤脂、取、無丙基甲 、樹脂、酸醇樹脂等各種水溶性和醇溶性^㈣酸樹脂 有隔離作用的礦物油脂(例如:…刀子材料及具 等); ”如•甲基硅油、石蠟.· · 其調製上,係將主劑、活化劑、 ,再將主劑(Α)、活化劑(Β) :製成溶液狀後 d -瓶(罐)’待欲使用時再予依序 二C)包裝成 其化學變化作用而調製成快速活 中=,即可經 。 化氣殺函消毒劑者200831398 holistic, at the same time, taking into account the use of the agent and catalyst with auxiliary materials, a package, individual packaging, combined catalyst preparation into a solution, each of which is more convenient and safe to be mixed with the catalyst and auxiliary materials. It can be easily disinfected and disinfectant. The potential safety value and practicability of the preparation method can be used as a patent application. [Simple description of the diagram] 苐1图: This is the best example of the creation of the second picture: the first picture of this creation is the third picture: the second part of the creation of this book: the third and the fifth Figure: This is the fourth and sixth picture of this creation: the fifth and seventh pictures of this creation: the sixth and eighth pictures of this creation: the seventh convenience of this creation, innovatively the main agent, activation, Make it into a three-in-one granular type of monotonous package' or package the main agent, activator, bottle, or package the main agent, activator, and solution in a bottle and bottle. In use, it is only necessary to add the right amount of quick-activated oxidizing gas to make it very early and safe, and effectively solve the hidden worry. It has an excellent industrial utilization price, an outstanding and innovative design, and conversion. A schematic diagram of the structural form of the example. A schematic diagram of a structural form of a preferred embodiment. A schematic diagram of a structural form of a preferred embodiment. A schematic diagram of a structural form of a preferred embodiment. A schematic diagram of a structural form of a preferred embodiment. A schematic diagram of a structural form of a preferred embodiment. A schematic diagram of a structural form of a preferred embodiment. A schematic diagram of a structural form of a preferred embodiment. IX1 patent application scope: a kind of fast-acting dioxo-twisting------------------------------------------------------------------------------------------------------------------------------ Sodium chlorate NaCi〇3 ; 200831398 (B) Activator consists of one or more of the following: Μ6酒6, oxalic acid (c〇〇H)2, hydrochloric acid HC1, citric acid HOC3H4(COOH)3, sulfuric acid H2S〇4, acid salt; (C) Catalyst consists of one or more of the following: bromine gas, chloramine T, dichlorodimethylhydantoin, dichloroisosodium urate, three Chloro-isocyanuric acid sodium; ※ The auxiliary material required for granulation coating consists of one or several of the following: dextrin CeHioO5, sodium bicarbonate NaHC〇3, sodium carbonate (%2〇)3, sulfuric acid Sodium Na2S〇4, magnesium sulfate MgS〇4, polyethylene glycol oil, paraffin H(OCH2CH2)nOH, polyvinyl alcohol H(CH2CH(0H)) nH, carboxymethyl cellulose, _methyl cellulose, hydroxymethyl Cellulose sodium, hydroxyethyl cellulose, hydroxypropyl cellulose, propyl methyl cellulose, Pweron, gelatin, sodium alginate • Polyacrylic resin, resin, acid alcohol resin, and other water-soluble and alcohol-soluble polymer materials and mineral oils with isolation (for example, dimethyl group), etc. The agent (A) is a carrier, and the activator (B) and the catalyst (C) are powdered, and the catalyst (C) and the activator (B) are sequentially coated on the main agent (A). The external part of the process is to place the main agent (A) in a fluidized bed spray granulation coating machine or a telecentric fluidized bed granulation coating machine, and then synchronize the powdered catalyst (c) and the auxiliary material. Sprayed into a fluidized bed spray granulation coating machine or a telecentric bed granulation coating machine to coat the catalyst (C) on the outer layer of the main agent (A), and then the powdered activator (B) and The auxiliary agent is synchronously sprayed into the flowing layer spray granulation coating machine or the telecentric fluidized bed granulation coating machine, so that the ligating agent (B) can be coated on the outer layer of the catalyst (c), thereby forming The third three-in-one coated particle type shown in Figure 5, 200831398, so that the three do not contact to produce a chemical action, so that it can be harvested One package, and safe in transportation and storage. When used, the granules (B), catalyst (C) and main agent (A) can be dissolved in sequence by adding the granules to water. In the water, 'and then into the required rapid activation of chlorine dioxide disinfectant. 2. A method for rapidly activating activated carbon monoxide, which comprises preparing a reagent for rapidly activating chlorine dioxide disinfectant, mainly comprising: (A) a main agent: sodium sulfite or sodium chlorate; r (B The activator consists of one or more of the following: tartaric acid, oxalic acid, hydrochloric acid, citric acid, sulfuric acid, acid salts; (c) the catalyst consists of one or more of the following mixtures, including Cause, Chloramine T, Dimethyldimethylhydantoin, Dichloroisocyanuric acid 'sodium, sodium trichloroisocyanurate; ※Auxiliary materials required for granulation coating consist of one or more of the following There are: dextrin, sodium bicarbonate, sodium carbonate, sodium sulfate, magnesium sulfate, polyethylene glycol, polyvinyl alcohol, carboxymethyl cellulose, hydroxymethyl cellulose, hydroxyl (, sodium methyl cellulose, hydroxyl Ethyl cellulose, hydroxypropyl cellulose, hydroxypropyl fluorenyl fibrin, puweiron, gelatin, sodium glutamate, polyacrylic acid resin, resin, acid alcohol resin, etc., various water-soluble and alcohol-soluble Molecular materials and mineral oils with barrier properties (eg Di-based silicone oil, paraffin···, etc.;; in the preparation of hemp, the granular active agent (B) is used as a carrier, and the main agent (A) and the catalyst (c) are powdered and reused. The auxiliary agent is prepared by: (C) and the main agent (A) are sequentially coated on the outside of the activator (B), and the granular activator (B) is placed in the flowing layer spray granulation. 200831398 In a coating machine or a telecentric fluidized bed granulation coating machine, the powdered catalyst (c) and the auxiliary agent are simultaneously sprayed into the fluidized bed spray granulation coating machine or the telecentric fluidized bed granulation coating machine. , the catalyst (c) is coated on the outer layer of the activator (B), and then the powdered main agent (A) and the auxiliary agent are synchronously injected into the mobile layer spray granulation coating machine or the telecentric flow bed granulation package. In the coating machine, the main agent (A) is coated on the outer layer of the catalyst (c), thereby forming a three-in-one coated particle type as shown in the figure below, so that the three are not contacted and produced. In order to make it a single package, and to ensure the safety of its wheels and storage, when you want to use it, just add this granular material to the water. The main agent (A), the catalyst (C) and the activator (B) are sequentially dissolved in water to prepare a desired rapid activation of the disinfectant. 3, a rapid activation of oxidation A chlorine preparation method for preparing and synthesizing a reagent for rapidly activating a gas dioxide disinfectant, mainly comprising: (A) a main agent: sodium chlorite or sodium chlorate; (B) an activator consisting of one or more of the following The mixed composition includes: tartaric acid, oxalic acid, hydrochloric acid, citric acid, sulfuric acid, acid salts; (C) the catalyst consists of one or more of the following: including bromochlorohydantoin, chloramine T, and Chlorodimethylhydantoin, sodium dichloroisosodium urate, sodium trichloroisocyanurate; in preparation, the main agent, activator, and catalyst are prepared into a granular, powder or flake-like preparation, and then They are packaged into three bags separately, and when they are to be used, they are added to the water in order, and then they can be prepared into a quick-activated emulsion of emulsified milk by the chemical change. 4, - a kind of rapid activation of dioxygen 1 7 chlorine preparation square &, its synthesis of fast 200831398 speed activated chlorine dioxide disinfectant required (A) main agent: sodium chlorite or sodium chlorate; Including (1) Live: The agent consists of one or more of the following: 、, acid, hydrochloric acid, citric acid, sulfuric acid, acid salt; c agent consists of the following one or several kinds of mixed packages, '虱海因, Chloroammonium T, Dichlorodi: Na, Sodium Trichloroisocyanurate; - Rolling Disordered Uric Acid ※ The auxiliary materials required for granulation coating include: dextrin, sodium bicarbonate, sodium carbonate :: Hehong Polyethylene Glycol, Polyethyl Ethyl Alcohol, Methylcellulose, = Fiber = Magnesium, Methyl Cellulose M-Based Cellulose, λ 2 Cellulose, Fibrin, Puweiron, Gelatin , Alginic acid A, resin, acid alcohol # polyacrylic resin _ eucalyptus special mineral oils and oils with various water-soluble and alcohol-soluble polymers (for example: dimethyl ketone 'eight, etc.); soil / field, stone The soil · · · The preparation of the main agent, the activation of the sputum = granulated, powder or flake-like agent after the 're Divided into two materials: If you want to use it, add it to the water and adjust it in sequence. It can be transformed into: It can be used to make a rapid activation of chlorine dioxide disinfectant. , 5, a rapid activation method for preparing dioxon chloride, which is used for preparing a quick-activated chlorine dioxide disinfectant, mainly comprising: (A) a main agent: sodium chlorite or sodium sulphate; (1) The activator is composed of one or more of the following: oxalic acid, hydrochloric acid, citric acid, sulfuric acid, acid salt; (C) the catalyst consists of the following species or a mixture of substances: may be desert 200831398 = hydan t ammonia tau, dichlorodimethyl hydantoin, dichloroisouric acid steel, diammonium isocyanurate; ※ the auxiliary materials required for granulation coating are included in the following one or several mixed groups f ·Dextrin, sodium bicarbonate, sodium carbonate, sulfur (tetra), sulphuric acid, polyethylene glycol, polyethylene glycol, carboxymethyl cellulose, methyl cellulose, methyl cellulose, ethyl Various water-soluble and alcohol-soluble polymer materials such as cellulose, (tetra)-based cellulose, (tetra)-based f-based fiber, Puweiron, gelatin, acid-consuming nano-lipid, polyacrylic resin resin, and acid-alcohol resin. There are isolated mineral oils (for example: bismuth, .8, etc.); After the main agent, activator, and catalyst are mixed into a granule, powder or flake, the three bags are packaged into a bag, and then added to the water in order to be used in sequence. Modification into a rapid activation of chlorine dioxide disinfectant. 6. A method for rapidly activating activated chlorine dioxide, which comprises preparing a reagent for activating a chlorine dioxide disinfectant, mainly comprising: (A) a main agent: sodium sulfite or sodium chlorate; B) The activator consists of one or more of the following mixed groups # △ , Λ 0 有 · · tartaric acid, Zhuo I, hydrochloric acid, citric acid, sulfuric acid, acid salts · (C ) catalyst consists of one or more of the following ························································································· The auxiliary material is composed of the following ones. I have a mixture of sighs, including dextrin, sodium bicarbonate, sodium carbonate, sodium sulphate, ☆ knowing ^5» All· acid town, ethylene glycol, polyvinyl alcohol, carboxy Sulfhydryl cellulose, oxonium 19 soil cellulose, 200831398 f-based cellulose m-based cellulose, propyl cellulose, propylmethylcellulose θ weilong, gelatin, sodium alginate, poly Various water-soluble and alcohol-soluble polymer materials such as propylene-fat tree a-alcohol resin and mineral oil with isolation effect ( Such as ··= methyl ketone oil, sarcophagus · ·:, etc.); its dying is the main agent, activator, catalyst and auxiliary agent material into granular, powder or flake Then, the activator (b) and the catalyst (C) are packaged into a bag, and then the main agent (A) is packaged into a bag. When it is to be used, it is added to the water in order, and then it can be prepared by its chemical change. To quickly activate chlorine dioxide disinfectant. , 7, 7, a rapid activation of chlorine dioxide preparation square &, the preparation of the rapid activation of chlorine dioxide disinfectant required for the agent, mainly including: (A) the main agent: sodium sulfite or sodium chlorate (B) The activator is composed of one or more of the following: tartaric acid, oxalic acid, hydrochloric acid, citric acid, sulfuric acid, acid salts; (C) the catalyst consists of the following one or several kinds of mixtures: It is chlorochlorohydantoin, aerobic T, dichlorodimethylhydantoin, sodium dichloroisocyanurate, sodium trichloroisocyanurate; (4) _ by the following one or several kinds of mixed electroforming: dextrin , sodium bicarbonate, sodium carbonate, sulfur _, sulfur _, polyethylene glycol, polyethylene glycol, hydrazine methyl cellulose, methyl cellulose xin, _ I based cellulose sodium, ethyl cellulose, _ Base water, (tetra), base, puprolon, gelatin, (d) acid agar, polyacrylic acid right resin, acid lysate, and other water-soluble and alcohol-soluble polymer materials and mineral oils with isolation ( Example ^ [methyl material, sarcophagus ·.: 200831398, etc.); After the catalyst is mixed with the auxiliary material to form a granular, powder or flake-like agent, the main agent (A) and the catalyst (C) are packaged into a bag, and the activator (β) is packaged into a bag. The % is added to the water and then blended in sequence, and the chemical change can be used to prepare a rapid and rapid activation of the chlorine dioxide disinfectant. /r , , 8 :: a rapid activation of chlorine dioxide preparation method, which prepares and synthesizes the required materials for rapidly activating chlorine dioxide disinfectant, mainly including: (A) main agent: sodium chlorite or chloric acid (B) The activator is composed of the following one or more kinds of mixtures: tartaric acid, oxalic acid, hydrochloric acid, citric acid, sulfuric acid, acid salts; (C) the catalyst consists of the following one or several kinds of mixtures including : It can be odorous chlorohydantoin, chloramine T, dioxetane dimethylhydantoin, sodium dichloroisocyanurate or sodium trichloroisocyanurate; ※ the auxiliary material required for granulation coating is one or the following Several mixed groups 2 include I: dextrin, sodium bicarbonate, sodium carbonate, sodium sulfate, magnesium sulfate, = ethylene glycol, polyvinyl alcohol, carboxymethyl cellulose, hydroxymethyl cellulose: _ = cellulose Various water-soluble and alcohol-soluble properties such as sodium, Methyl cellulose, propyl cellulose, (4) ketone: mersin, puweiron, gelatin, alginic acid ester, polyacrylic resin, october, acid alcohol resin, etc. Polymer materials and mineral oils with a barrier effect (for example, diterpene silicone oil, paraffin wax·· · etc.); in the preparation, the main agent, activator, and catalyst are made into a solution, and then the main agent (A), the activator (B), and the catalyst (c) are separately packaged into a bottle (can). When you want to use it, you can add it to the water in the same way. 2 200831398 It can be prepared into a fast-acting agent by its chemical change. ^Heartification - gas sterilization and disinfection 9, a rapid activation of the preparation of dioxide gas, the reagents required for the rapid activation of chlorine dioxide disinfectant, mainly packaged into fast (A) main agent · sodium chlorite or chlorine (B) The activator consists of one or more of the following: oxalic acid, hydrochloric acid, citric acid, sulfuric acid, acid salt; - (C) catalyst consists of one or more of the following mixtures including chlorohydantoin , chloramine, two gas - A, it is also yin, three gas, uric acid, niacin, chlorinated uric acid ※ the auxiliary (four) materials required for granulation coating, the following kinds or several kinds of mixing cylinders Including: dextrin, sodium bicarbonate, sodium carbonate, sodium sulphate, sulphuric acid, polyethylene glycol, polyvinyl alcohol, methyl cellulose, hydroxymethyl core, sodium methyl cellulose, hydroxyethyl Various kinds of water-soluble and alcohol-soluble polymers such as cellulose, _-based cellulose, propyl-based fibrin, puweiron, gelatin, sodium glutamate, polyacrylic acid decyl, resin, acid alcohol resin Materials and mineral oils with sequestration (eg dimethyl ke, , , , , , etc.); /, stone soil. ·. In its preparation, after the m activator and the catalyst are mixed with the auxiliary agent to form a solution, the main agent (a), the activator (B) and the catalyst (c) are separately packaged into - Bottles (cans), which are added to the water and then blended in order to be used, can be prepared into a rapid activation gas sterilization disinfectant by its chemical change. 1 n rapid activation of chlorine dioxide preparation method, which prepares and synthesizes the agent needed for rapid activation of chlorine dioxide disinfectant, main spoon · 2 2 匕 · · 200831398 (A ) main agent · chlorite or chloric acid (B) The activator consists of the following species or mixtures: alcohol, oxalic acid, hydrochloric acid, citric acid, sulfuric acid, acid salts. (C) The catalyst consists of one or more of the following: Chlorohydan , chloramine, dichlorodimethylhydantoin, bismuth bromide, sodium trichloroisocyanurate; bismuth cyanuric urinary urinary urinary urinary granules Sperm, sodium bicarbonate, sodium carbonate: several mixed groups, Shou r a wire ^ ^ ^ ^ θ 夂, magnesium sulfate, 丨 乙 乙 知 、, polyvinyl alcohol, carboxymethyl cellulose, hydroxymethyl cellulose Sodium, ethyl cellulose, propyl phthalocyanine, basal fibrin, puweiron, gelatin, alginate, propylidene, resin, acid alcohol resin, etc. Alcohol-soluble ^ (tetra) acid resin has a separation of mineral oils (for example: ... knife materials and tools, etc.); • Methyl silicone oil, paraffin. · · In its preparation, it is the main agent, activator, and then the main agent (Α), activator (Β): after making a solution, d-bottle (can) When used, it can be packaged into its chemical change and then prepared into a fast-lived medium, which can be passed through.
TW96102798A 2007-01-25 2007-01-25 Method of preparing chlorine dioxide with fast activation properties TW200831398A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
TW96102798A TW200831398A (en) 2007-01-25 2007-01-25 Method of preparing chlorine dioxide with fast activation properties

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
TW96102798A TW200831398A (en) 2007-01-25 2007-01-25 Method of preparing chlorine dioxide with fast activation properties

Publications (1)

Publication Number Publication Date
TW200831398A true TW200831398A (en) 2008-08-01

Family

ID=44818591

Family Applications (1)

Application Number Title Priority Date Filing Date
TW96102798A TW200831398A (en) 2007-01-25 2007-01-25 Method of preparing chlorine dioxide with fast activation properties

Country Status (1)

Country Link
TW (1) TW200831398A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114680132A (en) * 2020-12-30 2022-07-01 广西国宏智鸿环保科技集团有限公司 Stable chlorine dioxide composite disinfectant powder
CN115299457A (en) * 2022-09-02 2022-11-08 中国农业科学院饲料研究所 Chlorine dioxide solution disinfectant for controlling African swine fever and bringing livestock, and preparation method and application thereof
CN115428804A (en) * 2021-10-09 2022-12-06 四川齐力绿源水处理科技有限公司 Air disinfection and purification composite material and preparation method thereof
CN115500349A (en) * 2022-11-08 2022-12-23 安徽逸天科技有限公司 Preparation process of chlorine dioxide effervescent bomb

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114680132A (en) * 2020-12-30 2022-07-01 广西国宏智鸿环保科技集团有限公司 Stable chlorine dioxide composite disinfectant powder
CN115428804A (en) * 2021-10-09 2022-12-06 四川齐力绿源水处理科技有限公司 Air disinfection and purification composite material and preparation method thereof
CN115299457A (en) * 2022-09-02 2022-11-08 中国农业科学院饲料研究所 Chlorine dioxide solution disinfectant for controlling African swine fever and bringing livestock, and preparation method and application thereof
CN115500349A (en) * 2022-11-08 2022-12-23 安徽逸天科技有限公司 Preparation process of chlorine dioxide effervescent bomb
CN115500349B (en) * 2022-11-08 2024-04-05 安徽逸天科技有限公司 Process for preparing chlorine dioxide effervescent bomb

Similar Documents

Publication Publication Date Title
TWI243014B (en) Compositions for sustained release of a gas
US6663902B1 (en) Method and composition for the generation of chlorine dioxide using Iodo-Compounds, and methods of use
AU2010200387B2 (en) Active bromine containing biocidal compositions and their preparation
CN100407923C (en) Sterilization disinfectant and application thereof
JP2012036072A (en) Product shape and component composition of chlorine dioxide generator at using time
CA2829449A1 (en) A stable composition of hoci, processes for its production and uses thereof
CN101796948B (en) Smoke type disinfectant, preparation method and application thereof
US20060018940A1 (en) Stabilized antimicrobial composition
US7560033B2 (en) Multi-functional oxidizing composition
CN102422841A (en) Reactive chlorine dioxide powder and its preparation method
TW200831398A (en) Method of preparing chlorine dioxide with fast activation properties
CN104255785A (en) Long-acting controllable chlorine dioxide sustained release agent
GB2437489A (en) Disinfectant mixture of a donor of freely available chlorine (e.g. hypochlorite) and a buffering agent or acid, optionally in the form of an aqueous solution
WO2009068834A1 (en) Sanitizing and purifying liquid
AU2004292538B2 (en) Multi-functional oxidizing composition
US20120015948A1 (en) Tablet composition
TW200831399A (en) Method of preparing chlorine dioxide granules
EP1044689A1 (en) Solid iodophor preparations and process for producing the same
TW200831397A (en) Method of preparing new type chlorine dioxide
CN103314956A (en) Sustained-release solid ClO2 disinfectant and preparation method and application thereof
WO2012037047A1 (en) Methods, compositions, and devices for managing chlorine dioxide release
KR20220088066A (en) Portable unit removed bad flavor for sterilizing and deodorizing life space
TW200944475A (en) Chlorine dioxide composition having selectivity antioxidation
US20240156099A1 (en) Composition for generation of chlorine dioxide for use as sanitizer
CN107568208A (en) A kind of sustained-release gel composition containing zinc and chlorine dioxide