TW200823056A - A holographic film with partial holographic pattern and the process applied for - Google Patents

A holographic film with partial holographic pattern and the process applied for Download PDF

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TW200823056A
TW200823056A TW95142935A TW95142935A TW200823056A TW 200823056 A TW200823056 A TW 200823056A TW 95142935 A TW95142935 A TW 95142935A TW 95142935 A TW95142935 A TW 95142935A TW 200823056 A TW200823056 A TW 200823056A
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Taiwan
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laser
pattern
film
full
image
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TW95142935A
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Chinese (zh)
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Wen Wang
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Wen Wang
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Abstract

A holographic thin film with partial holographic pattern and the process for were invented. The holographic film was composed by plastic substrate, pressure sensitive coatings with/without micro-notch and metallic/ metal oxide deposition layer. Before the non-etching process was applied for metallic thin film deposition in partial patterning application, the protective ink was covered partially on the film and following holography process was conducted earlier than vacuum metallization. The holographic pattern was formed via sheltering-printing technology and vacuum deposition. The process was free from using etching chemicals and merely using water solution at room temperature for striping.

Description

200823056 九、發明說明: 【發明所屬之技術領域】 /本發明係關於一種局部雷射全像圖案之雷射膜及其 其係指一種可以免用化學蝕刻並能進行雙面或單面^傻 之雷射獻其製法。 ㈣王俅政果 【先前技術】 按’雷射全像圖案係近年來被廣泛應用防偽、表面F 板及其他外觀機構件,其伽包括色彩,賴富變化, 柄 ^品被仿冒之風險並增加產品之價值感,更可提高防偽 應用於容易被仿冒之有價證件或民生消f用品上,而 全像標簽都係以黏貼方式黏置於產品上,如此,往往會產生^县 等缺失;亦有業者將該商標圖案設置之:置作為消 射全像印刷則不易被仿製,因為雷射印刷在餘上= ^父商’且可將文字與商標圖案同時—體形成於—文件上。 二般圖案皆以全鏡面之金屬f賴基 ^ 之雷Γ像加工’亦有部分文字與商標圖案係土 ,以避免文字或圖案無法順利辨讀之_。因此, :僅ii須化費較多之製作程序來完成,因此,如何改盖此-技 術,便成為業者思及之方向。 讽„此技 射全像獏 其上施以雷射壓膜作紐,完成透明全面雷 印刷雷將雷射全鑛,以褒金之方式熱烫於 於烫金Hi;基材以形成所欲之局部圖樣。此製法由 w十分昂貴’且局«金的定位不易率確,又容易產生 200823056 雷射全像效果之熱壓破壞,導致圖樣效果不佳。 全面雷射全像鍍膜··其係將PET膜以表面電暈技 理,將溶劑型架橋劑樹脂塗佈於電暈_後之ΡΕτ表1 = 像Ϊ膜作業’於該作業面上蒸錢金屬膜後,於^ 以貼人進仃'讀型雜麵脂塗佈再將其與^—薄膜基材加 作業。此觀在印刷成品之外觀上, 將會使仵雷射全像紋路或圖樣之效果不佳。 口此 局部雷射全像鑛膜:其係將ΡΕΤ膜以表面電晕技 i施ΐίϊίΐ,樹脂塗佈於電晕處理後之ΡΕΤ表面,並於ΐ 於膜作業,再於該作業面上蒸鑛金屬膜後, :==合’再進行印刷加工作業此製法由於雷射紋路與# 的問題。不易’因此會導致雷射紋路與印刷圖樣套料準及錯位 透明1局部金屬_侧之方式進行雷射全像膜的局部 、容必須以化學_方式去除金屬鑛膜或以有機溶劑 低,不易製造,目前僅有極少數特殊需求之用 =。士防偽或商標文字等黏貼膜,其技術仍屬不成熟而終將被淘 透明ΐίί述雷射全細製程不論是全面或局部圖案之 源浪眷^ ’ 2在有塑膠膜於使用時之成本增加及使用後之資 存在右ϋ再者就局部雷射全像線路或圖樣之雷射膜而言,亦 雷射明效果及印刷圖樣定位不易而導致 藥液透明退雷射全像膜之製程方式,大多以酸鹼化學 刻溶解二;不易控制綱速率,且因藥液中_ Π馬导向丨生蝕刻,亦即,在三度空間中的金屬鍍膜受酸 200823056 加=致,降 刻,而造成铲^甚至導致邊緣鋸齒狀或鍍臈侧向過度蝕 =Ξί Ιϋΐ。而傳統使用酸鹼化學藥液進行反應 庄蚀到得策私疋成後會產生大量污毕性廢太,盆由'人綠、产这 進行金屬㈣之雜有機减,因此,以侧方式 進仃金屬鍍膜之局部_處理,也將遭遇廢水處理的棘手問題。 【發明内容】 透明的局部飾全像圖案之 4, _ 象膜及,、製知’使雷射全像膜同時且備金屬 圖案具雷射全像效果之載體薄膜: ^ ί,射全像膜及其製程,使雷射全像_日夺具備透 摸。 =;:月,膜, 在k供—__局部分雷射全像圖案 體 :像圖案效果之金屬光澤鑛膜或局部雷射全像效果i透^載 ,發明之另一目地在於提供—種獨特的局部雷射全 雙面之局部不透射全像效果。 王早㈣ ,發明之另一目地在於提供—種獨特的局200823056 IX. Description of the invention: [Technical field to which the invention pertains] / The present invention relates to a laser film of a partial laser holographic pattern and a system thereof which can be chemically etched and can be double-sided or single-sided The laser offers its method of production. (4) Wang Weizheng [Prior Art] According to the 'Laser All-Picture Pattern, the anti-counterfeiting, surface F-plate and other exterior components have been widely used in recent years. The gamma includes color, the change of the rich, the risk of counterfeiting and the increase of products. The sense of value can improve the anti-counterfeiting application of valuable documents or people's livelihoods that are easily counterfeited, while the hologram labels are adhered to the products by means of pasting, so that there are often missing such as ^ County; The manufacturer sets the trademark pattern: it is not easy to be copied as the photographic full-image printing, because the laser printing is on the rest = ^ parent quotient and the text and the trademark pattern can be simultaneously formed on the file. The two patterns are all mirrored metal f ^ ^ ^ Γ Γ Γ Γ 加工 亦 亦 亦 亦 亦 亦 亦 亦 亦 亦 亦 亦 亦 亦 亦 亦 亦 亦 亦 亦 亦 亦 亦 。 。 。 。 。 Therefore, only ii is required to complete the production process, so how to change this technology becomes the direction that the industry thinks. Irony „This technical shot is full of 雷 雷 施 施 施 施 施 施 施 施 施 施 施 施 施 施 施 施 施 施 雷 雷 雷 雷 雷 雷 雷 雷 雷 雷 雷 雷 雷 雷 雷 雷 雷 雷 雷 雷 雷 雷 雷 雷 雷 雷Partial pattern. This method is very expensive by w and the location of the gold is not easy to determine, and it is easy to produce the thermal compression damage of the 200823056 laser holographic effect, resulting in poor pattern effect. Comprehensive laser holographic coating ·· Applying the PET film to the surface corona technique, the solvent-type bridging agent resin is applied to the corona _ after the ΡΕ τ table 1 = like the enamel operation 'after the steaming of the metal film on the work surface,仃 'Reading type grease coating and then adding it to the film substrate. This view will make the ruthenium laser full image lines or patterns have a poor effect on the appearance of the printed product. The whole image of the ore film: the film is coated with a surface corona technique, and the resin is applied to the surface of the crucible after corona treatment, and after the operation of the film, and then the metal film is evaporated on the working surface. , :==合' and then carry out the printing processing operation. This method is difficult due to the problem of laser grain and #. This causes the laser pattern and the printed pattern to be aligned and the transparent part 1 metal_side to be part of the laser holographic film. The content must be chemically removed to remove the metal ore film or low in organic solvent, which is difficult to manufacture. At present, there are only a handful of special needs =. Anti-counterfeiting or trademark texts and other adhesive films, the technology is still immature and will eventually be transparent. ί 雷 雷 全 全 全 全 全 全 全 全 全 全 全 全 全 全 全 全 全 全 全 全 全 全 全 全 全 全 全 全 全' 2 In the case of plastic film in use, the cost increases and the use of the right after the right, and then the local laser holographic line or pattern of the laser film, also the lightning effect and the printing pattern positioning is not easy The process of transparent liquid-removing photographic film of liquid medicine is mostly dissolved by acid-base chemistry; it is difficult to control the rate, and the metal in the liquid solution is etched by the Π 丨 丨, ie, the metal in the third space The coating is affected by acid 200823056, which causes the shovel to even cause the edge to be jagged or ruthenium laterally over-etched = Ξί Ιϋΐ. The traditional use of acid-base chemical liquid to react to the ruthless Produce big The pollution is too wasteful, and the basin is made of 'human green, producing metal (4). Therefore, the partial treatment of the metal coating in the side way will also encounter the thorny problem of wastewater treatment. [Invention] Transparent The partial embossed pattern 4, _ _ film and, the carrier film that makes the laser holographic film and the metal pattern with the laser holographic effect: ^ ί, the photographic film and its process, Make the laser full image _ 日夺 has a touch. =;: month, film, in k for -__ partial laser holographic pattern body: like the effect of the metallic luster film or partial laser holographic effect i Through the transmission, another object of the invention is to provide a unique partial laser full-sided partial non-transmission holographic effect. Wang Zao (4), another object of the invention is to provide a unique bureau

乃改善傳_刻方S 』至職膜’軸局部雷射全像之製程;本發明 改,鍍膜圖案之製造技術,以水溶性油 ^ r _局部金屬圖案製造之製_序,以加成方‘ 7 200823056 德突破以往雷射全像金屬光澤鑛膜需以選擇性化學 之1方式,除去不欲鍍膜存在的鏤空部位,僅以室溫條件 阿完全將水溶性油墨材料與其上覆蓋之金屬光澤鑛膜 亦可“=3;丨itr峨刻製程所導致的低生產良率, 效率。免侧廢水的處理_,並提高水資狀回收使用 膠薄部雷射全像糊賴造技術,包t提供一塑 Γ 传先進i f斛入&astlc fllm substrate supporting) ’該載體之一表面 ΐΐίϊί 壓層之全面塗佈,再接著以印刷附著方 接其餘周圍則印滿遮蔽油墨保護材料; r彳凌社制八鍍VaCUUm deP〇Siti〇n)或濺鍍(sPuttering)方式等 二=程形:ί:屬氧 一薄膜之鰱成ί; m 像效果;或是,以乾式黏著之方式,;雷射全 ,蔓層剝離,'繼續,對已形成之線路=== 购換,將可形成透明薄膜在局部 當然,本發明在某些另件上,或另件 :=!=製二本發_書中,詳 8 200823056 【實施方式】 參閱本發明騎之圖示,以下將列舉實施例說明: 像膜補,-種局部魏全像_之雷射全 射a牵之命汾入你,如苐1圖之製造流程所示,有關局部全像雷 面膜局部圖案及水溶性覆蓋油墨保護層材料之截 雷射G膜第3圖所示;在局部全像雷射圖案之 Γ (; 衝選自非導電性塑膠材料製成之透明或不透明緩 it或、ΐίϊ材f之—種’且於製程開始時先進行基材表面之潔 為雷射i像響後續製程之油污或顆粒,並以其一表面作 高分3工面;又參閱第3a圖,以感壓式或熱感壓式 像顯影感壓層2之塗佈材料,披覆於雷射 像膜基材層1之上,作為一雷射全像膜之原膜;又再參閱第犯 以印刷(printing)或塗佈(coating)或轉印(transfer)等方式進 材料的附著,在披覆雷射全像顯影感壓 nmt材層1的—端表面形成鏤空之覆蓋油墨保護 1、十再參閱第3C圖’以雷射雕刻處理之滾壓輪輥進行對 及2 it材料表面的雷射全像圖案轉移,亦即在表面以賴 朗Hi式’形成雷射全像顯影區4之局部或全面圖案;另又參 圖,以真空蒸鍍(vacuum deposition)、直空濺梦(vacuu =ring則子束_EB 一㈣等方式在先前 ,鍍膜層5附著,該鑛膜層之材質係選具高反;^金屬, 相關聯合金材料之其中之―;最後請參閱第犯圖 容解附著了鑛膜層之覆蓋油墨i 成覆墨其屬鑛膜堆疊結構破麵離,進而形成 ^線路或_顯影於雷射全像膜基材層】表面 疊金屬鐘膜之覆蓋油墨保護層3部位加以從i射‘ 像膜基材層1表面_,即成為—具有局部f射全像圖案效果之 9 200823056 雷射全像膜,其中,号蕾# 則具備雙面雷射全像效1射以,塑膠薄膜作為基材, 偽辨識功能或雷射全像金屬二_、^績製程中,不論是作為防 之雷射全像膜產品。、^屬澤外觀裝飾之用,皆能有別於以往 依本發明之另一且雜音 全像膜與其製程方法「如第2 g之射全=案之雷射 射全像膜美糾1 Λ像^紐層之塗佈材料’披覆於雷 mm 、’ 0 上,作為一雷射全像膜之原膜;又再表閱第 1B目圖,以印刷㈣nting)或塗佈(_ing)或轉替麵㈣等^式^ 壓材料的附著,在披覆雷射全像顯影^ 護層3的的了端气面形成鏤空之覆蓋油墨保 亩二、、…案再多閱第4C圖,以真空蒸鍍(vacuum deposition)、 工工錢鍍(vacuum sputtering)或電子束蒸鍍(EB _〇郝如 ,先前已附著覆蓋油墨保護層3之·全像膜基材層丨表面,^ 仃全表面之金屬光澤鍍膜層5附著,該鍍膜層之材質係選具古 ^率之金屬/金屬氧化物及相關聯合金材料之其中之一;另 第4D圖,以雷射雕刻處理之滾壓輪輥進行對上述第4八圖之二 表面的雷射全像圖案轉移,亦即在表面以滾壓反轉之方式,形成 雷射全像顯影區4之局部或全面圖案;最後請參閱第4E圖,^濕 式選擇性溶解剝離之方式,藉由水溶解附著了鍍膜層之覆蓋油= 保護層3,造成覆蓋油墨其上金屬鍍膜堆疊結構破壞剝離,進而$ 成局部線路或圖案顯影於雷射全像膜基材層1表面,或以乾式= 200823056 材轉倾層3雜加峨雷射 之雷射全像膜,复中,兮蕾成為一具有局部雷射全像圖案效果 則具備單面雷射全像效王像膜若以透明塑膠薄膜作為基材, 偽辨識功能或雷身于全像会屬也為後續製程中,不論是作為防 之雷射全像臈產品。〃屬先澤外觀裝飾之用,皆能有別於以往 局部雷X射全^膜產品^ 分屬單面或雙面雷射全像效果之 Γ、 化,如第5圖之成品示意圖有J中之^雷射全像圖案之表現變 金屬光澤輯膜,时局 ^ ®之雷射全像效果為全 第5B圖之雷射全像=、f王像文字效果『W』之圖案表示; 效果『W』之_表‘ ;有局部全像文字 ,全像面薄膜,内有局^透明鏤=1 全f效果為全金屬光澤之 第5D圖之雷射全像效果為全金屬二澤_^果『W』之圖案表示; 部非雷射全像,金屬光^文字全效屬果先fw之雷射全像面薄膜,内有局 施成品示意圖乃為依本發 表不。上述之實 射膜圖賴化者,㈣縣發日^2|^製輯產生之局部雷 ^本發明之保護範圍當視後附之申 何熟知此項技藝者,再视離本„定者為準,任 變化與修改,均屬於本發明之保護範圍Γ神和範圍内所作之任何 200823056 f 【圖式簡單說明】 第1圖 . 第2圖 第3圖 第3A圖 第3B圖 第3C圖 第3D目 第3E圖 第4圖 第4A圖 :種可產生雙面局部雷射全像圖案效果之雷 射全像膜製造流程示意圖; •:種可產生單面局部雷射全像圖案效果之雷 射全像膜製造流程示意圖; • ΐΐΛ㈣射全像_之雷射全像膜局部圖 二,程加工順序及水溶性覆蓋油墨保護層 •材料之截面示意圖; ^局部雷射全侧案之雷射全像膜局部圖 程中已塗佈雷射全像顯影感壓層的雷 •射全像膜基材之截面示意圖; • ^局部魏全側案之簡全像膜局部圖 =程中印刷水難覆蓋油墨保護層材料 <戠面示意圖; 魏全侧案之雷射全像膜局部圖 ^反二f行I面或局部雷射全像圖案滚 •縻反轉效果之截面示意圖; • ^局部雷射全像贿之雷射全像 =製程,進行全表面鍵膜處理 全賴案之雷射全_@#® :ίίί!?行水洗顯影後之截面示意圖; .1¾圖及水溶性覆蓋=護層 .;=雷已射二圖/之雷射全像膜局部圖 -像膜基ί之=圏顯爾層的胃 200823056 第4B圖 :單面局部雷射全像圖案之雷射全像膜局部圖 第4C圖 案製程中印刷水溶性覆蓋油墨保護層材料 之截面示意圖; :單面局部雷射全像圖案之雷射全像膜局部圖 案製程中進行全表面鍍膜處理之戴面示意 圖; 第4D圖 :單面局部雷射全像圖案之雷射全像膜局部圖 案製程中進行全面或局部雷射全像圖案滾 壓反轉效果之截面示意圖; 第4E圖 η :單面局部雷射全像圖案之雷射全像膜局部圖 案製程中進行水洗顯影後之截面示意圖; 第5圖 :局部雷射全像圖案之雷射全像膜成品示意 圖, 第5Α圖 :局部雷射全像圖案之雷射全像膜,其中,全 金屬光澤鍍膜面之局部文字雷射全像圖案 效果成品未意圖; 第5Β圖 :局部雷射全像圖案之雷射全像膜,其中,部 分文字圖案金屬光澤鍍膜與透明背景面之 局部雷射全像圖案效果成品示意圖; C 第5C圖 :局部雷射全像圖案之雷射全像膜,其中,局 部鏤空透明文字圖案與背景金屬光澤鍍膜 面之局部雷射全像圖案效果成品示意圖; 第5D圖 :局部雷射全像圖案之雷射全像膜,其中,全 金屬光澤鍍膜面之局部文字非雷射全像圖 案效果成品示意圖; 13 200823056It is a process for improving the transmission of the image of the 'localized laser' of the film. The invention is modified, and the manufacturing technique of the coating pattern is made by the water-soluble oil ^ r _ partial metal pattern.方' 7 200823056 The breakthrough of the previous laser full-image metallic luster film requires selective chemical method 1 to remove the hollow parts that are not required to be coated, and completely separate the water-soluble ink material and the metal covered thereon at room temperature. The lustrous ore film can also be used as a “=3; 丨itr engraving process for low production yield, efficiency. Treatment of side-free wastewater _, and improved water-based recycling of thin-film lasers. Package t provides a plastic Γ advanced advanced 斛 斛 ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast ast彳 社 社 八 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 镀 或 或 或 或 或 或 或 = = = : : : : : : : : : : 属 属 属 属 属 属 属 属 属 属 属 属 属 属 属 属 属 属 属 属 属 属 属 属 氧 氧 氧Full laser, stripping of the vine, 'continue, right Forming the line === Buying, the transparent film will be formed locally. Of course, the invention is on some other parts, or the other parts: =!= system two hairs _ book, detail 8 200823056 [embodiment] The illustration of the ride of the present invention will be described below by way of example: a film fill, a partial type of Wei full image, a laser full shot, and a life-like shot, as shown in the manufacturing process of Figure 1, the relevant part The lithographic partial pattern of the holographic film and the cut-off laser film of the water-soluble overprinting protective layer material are shown in Fig. 3; in the partial holographic laser pattern (; rushed from a non-conductive plastic material made of transparent or The opaque easing or ΐ ϊ ϊ f 种 且 且 且 且 且 ϊ ϊ ϊ ϊ ϊ ϊ ϊ ϊ ϊ ϊ ϊ ϊ ϊ ϊ ϊ 于 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材 基材Figure 3a, the coating material of the pressure sensitive layer or the photosensitive layer 2 is coated on the laser image film substrate layer 1 as a film of a laser photographic film; Referring again to the first committing of the material by printing or coating or transfer, The full-image developing pressure-sensitive nmt material layer 1 is formed on the end surface to form a hollow cover ink protection. 1. Referring again to FIG. 3C, the laser roller for laser engraving treatment is performed on the surface of the 2 it material. Like pattern transfer, that is, forming a partial or comprehensive pattern of the laser holographic development area 4 on the surface by Rylang Hi-type; another reference, vacuum deposition, direct splattering dream (vacuu =ring Then the beam bundle _EB one (four) and the like in the past, the coating layer 5 is attached, the material of the mineral film layer is selected to be high-reverse; ^ metal, related to the joint gold material -; finally, please refer to the first map The cover film of the mineral film layer i is covered with ink, and the mineral film stack structure is broken away, and then formed into a line or _ developed on the laser holographic film substrate layer] the surface of the metal film covering the ink protective layer 3 is applied From the surface of the film substrate layer 1, it becomes a 9200823056 laser holographic film with a partial f-image effect, in which the bud # has a double-sided laser full-image effect. , plastic film as a substrate, pseudo-identification function or laser lithography metal _, performance Process, whether as Defense in laser holographic film products. , ^ is the appearance of the appearance of the decoration, can be different from the previous invention according to another invention and the holographic holographic film and its manufacturing method "such as the 2 g of the full shot = the case of the laser photographic film mei 1 1 Λ The coating material like the ^ layer is coated on the Ray mm, '0 as the original film of a laser holographic film; and then the 1B image is printed to print (4) nting or coating (_ing) or The transfer surface (four) and other ^ type ^ pressure material adhesion, in the coating of the laser full image development ^ protective layer 3 of the end of the gas surface to form a hollow cover ink to protect the mu two, ... ... and then read the 4C picture, Vacuum deposition, vacuum sputtering or electron beam evaporation (EB _ 〇 Hao Ru, previously attached to cover the ink protective layer 3 · holographic film substrate layer , surface, ^ 仃The metal luster coating layer 5 of the surface is attached, and the material of the coating layer is one of metal/metal oxide and related joint gold material selected from the group; and the 4D image is a roller for laser engraving processing. The roller performs the transfer of the laser holographic pattern on the surface of the second image of the fourth figure, that is, the laser is formed on the surface by the roll reversal. Partial or full pattern of the developing zone 4; finally, refer to FIG. 4E, the method of wet selective dissolution and stripping, by coating the coating layer with the coating layer by water to dissolve the protective layer 3, resulting in the coating of the metal coating on the covering ink. The structure is broken and peeled, and then the local line or pattern is developed on the surface of the laser holographic film substrate layer 1, or in the dry type = 200823056, the material is turned into a tilted layer, and the laser is fully imaged by the laser, zhongzhong, 兮The bud becomes a one-sided laser full-image effect film with a single-sided laser full-image effect. If the transparent plastic film is used as the substrate, the pseudo-identification function or the thunder in the hologram will also be in the subsequent process, regardless of It is used as a laser-proof full-image 〃 product. It belongs to the appearance of the first zee. It can be different from the previous local X-ray full-film products ^ is a single-sided or double-sided laser holographic effect, As shown in Fig. 5, the schematic diagram of the finished product has the appearance of a laser full-image pattern in J, and the laser full-image effect of the current ^^ laser is the full laser image of the 5th image =, f The pattern of the king's character effect "W"; the effect of the "W" _ table'; there is a bureau Full-image text, full-image film, with a transparent ^ 镂 = full f effect for the full metallic luster of the 5D map of the laser full-image effect for the whole metal Erze _ ^ fruit "W" pattern representation; Non-laser full image, metal light ^ text full effect is the first fruit fw laser full-image film, there is a schematic diagram of the finished product is not published according to this. The above-mentioned real film film Lai, (4) County The local ^2|^ is generated by the local mine. The scope of protection of the present invention is considered to be the subject of the present invention, and the change is subject to the present invention. Protection range 和神 and any of the scopes made in 200823056 f [Simple diagram of the diagram] Fig. 1 Fig. 2, Fig. 3, Fig. 3A, Fig. 3B, Fig. 3C, Fig. 3D, Fig. 3E, Fig. 4, Fig. 4A: Schematic diagram of a laser photographic film manufacturing process that can produce a double-sided partial laser holographic pattern effect; • A schematic diagram of a laser photographic film manufacturing process that can produce a single-sided partial laser holographic pattern effect; • ΐΐΛ (4) Like _ the laser photographic film partial map 2, process order and water-soluble cover ink protective layer • material Schematic diagram of the surface of the laser-coated full-image film substrate with a laser-coated full-image-developed pressure-sensitive layer in the partial laser image of the local laser full-surface film; The case of the film is a partial image of the film = the printing water in the process is difficult to cover the ink protective layer material < 戠 示意图 schematic; the full face film of the Wei Quan side case film ^ anti-two f line I face or partial laser hologram pattern Cross-sectional schematic diagram of the roll-and-reverse effect; • ^Local laser-like full-bore laser full-image = process, full-surface bond film processing all over the laser _@#® : ίίί!? Rear section schematic; .13⁄4 diagram and water-soluble cover = sheath.; = Ray has shot two map / laser full-image film partial map - like membrane base ί = 圏 尔 尔 layer of stomach 200823056 Figure 4B: A schematic diagram of a cross-sectional view of a water-soluble cover ink protective layer material in a 4C pattern process of a single-sided partial laser holographic pattern; a laser photographic image of a single-sided partial laser holographic pattern Schematic diagram of the full surface coating treatment in the process; 4D: single-sided partial laser hologram A schematic cross-sectional view of a full or partial laser holographic pattern rolling reversal effect in a laser partial image process; 4E η: a single-sided partial laser holographic pattern of a laser lithography partial pattern process Schematic diagram of cross-section after washing and developing; Figure 5: Schematic diagram of laser holographic film of partial laser holographic pattern, Figure 5: Laser holographic film of partial laser holographic pattern, in which full metallic luster The partial text laser image of the coated surface is not intended for the finished product; Figure 5: The laser full-image film of the partial laser holographic pattern, in which part of the text pattern metallic gloss coating and the partial laser lithography of the transparent background surface Schematic diagram of the finished product of the pattern effect; C Figure 5C: Laser holographic film of the partial laser holographic pattern, wherein the partial hollow transparent text pattern and the partial laser lithography surface of the background metallic lithography surface effect finished product schematic; 5D : Laser holographic film of partial laser holographic pattern, wherein the partial text non-laser holographic pattern effect of the full metal gloss coating surface is schematic; 13 200823056

【主要元件符號說明】 1. 雷射全像膜基材層 2. 水雷射全像顯影感壓層 3. 覆蓋油墨保護層 4. 雷射全像顯影區 5. 金屬光澤鑛膜層 14[Description of main component symbols] 1. Laser holographic film substrate layer 2. Water-jet holographic development sensitization layer 3. Cover ink protection layer 4. Laser hologram development area 5. Metallic luster film layer 14

Claims (1)

200823056 十、申請專利範圍: L 7局部雷射全像圖案之雷射全像膜,可進行單面或雙面局部 1射全像之圖案效果,其產品與製程方法,包含: 提供一透明或不透明之塑膠基材載體,該載體之一表面係 局部雷f全像圖案結構之附著載體; 、 Γ200823056 X. Patent application scope: L 7 partial laser holographic pattern of laser holographic film, can be used for single-sided or double-sided partial 1 full-image effect, its product and process methods, including: Provide a transparent or An opaque plastic substrate carrier, one of the surfaces of which is a local carrier of a ray-like holographic pattern structure; 八覆蓋一層感壓式高分子樹脂於該塑膠基材之一端表面,作為雷 射全像滾壓顯影之感壓層,以利後續之雷射全像滚壓輥之加工;田 一形成一水溶性覆蓋油墨保護層於該覆蓋感壓層之塑膠基材载 體之上方端表面,其保護層為局部鏤空之圖案或線路,唯部分線 路或圖案之位置不加以油墨覆蓋附著; 、、、 將已形成覆蓋油墨保護層處理之塑膠基材載體,先以雷射雕 处理之滾壓輪輥進行對材料表面的雷射全像圖案轉移,亦即在^ ,以滾壓反轉之方式,形成於透明塑膠基材上雙面雷射全像顯景^ ,之局部或全面圖案,再利用電漿清洗或電暈處理或臭氧氧1匕$ V驟進行表面活化(surface activati〇n),藉以提高後續製 附著與加工性; 7热 、、形成高反射金屬光澤鍍膜層於先前已附著油墨保護層並 材載體表面,所形成之金屬光澤鍍膜層乃為^ 獨特且於透難膠基材上單面雷射全像顯部c 上述雷射全像滾壓與保護油墨覆蓋之程序可以互換次序, 面圖案 以濕式選擇性溶解讎之方式,把堆疊了金屬綺_ 盍油墨保護層溶解剝除,造成其表面之鑛膜堆疊、 ,透明或不透明塑膠基材載體表面,或以乾丄象 離’即成為-具桃路或_之局部雷射全伽產品。伴r % 15 200823056 2. Γ 4· 6· 7· 如申請專利範圍第-項所述之局部雷射全像_之雷射全像膜 製造方法,其中該塑膠基材載體之材料可包含聚乙烯(ρΕ)、聚 氣乙烯(PVC)、聚苯乙烯(pS)、聚丙婦(ρρ)、聚對苯二甲酸乙 二酯(PET)、聚碳酸脂(pC)、聚甲基丙婦酸甲醋(ρΜΜΑ)、聚酰 亞胺(ΡΙ)等有機材料,其形式可為板狀、薄膜捲材料、片材狀 等。 如申請專利範圍第-項所述之局部雷射全側案之雷射全像膜 製造方法’其^該娜基材細所披覆之雷射全像顯影層材料 可包含熱塑性南分子材料,如壓克力成分(Acrylic)之高分 齡或其他賤祕或絲舰之《分子材料 如申請專利範圍第-項所述之局部雷射全像_之雷射 $方法’其巾雷射雜輪輥所具備轉移贿可包含全面滿版 二二二2、負片圖案、局部圖案、紐/對位點圖案及 空白鏤空圖案等。 μ木a 項所述之局部f射全像賴之雷射全像膜 凹版印刷、凸版印刷、平版印刷、柔版印刷、移 雷 射印刷、喷墨印刷等技術與方式。 轉f7雷 ^申清專利細第-項所述之局部雷射全像圖案 其中,蓋油墨保護層形成所使用之油墨保護G 、顏上;化J ======== =學S二束);;法化學氣_^^ 如申請專利麵第-項所述之局部雷射全像圖案之雷射全像膜 8· 200823056 製造方法,其中該金屬光澤鍍膜厣彡 9 鐵、鎳、鋅、錮、錫、錯、鉛mf可包含金、銀、銅、 鉑、鈦、鎢等金屬或其合金之材料等、、、鋁、鋇、鉈、鉍、 =======敝像膜 鐵 '鎳、鋅、銦、錫、銘姑n成材^可包含金、銀、銅、 始、鈦、鶴等金屬之氧化物或其他且備=、f、鋇、銘♦ 化物或氮化物等。、他,、備阿反射率之上述金屬硫 Γ 10. 如申請專利範圍第一項所述之局部 Γ〇=方法’其㈣金屬光澤鑛模 11. 如申請專利範圍第一項所述 膜製造方法,其中該金屬光澤鑛 5000nm之間。 兄檟与度可從O.lnm至 11·如申請專利範圍第一項所 膜製造方法,其中該濕式選擇性像 同溫度下之水溶液、純水、或含有H使狀減包含不 12. 如申請專利範圍第一項所 水之混和物等。 ;以方法’其中該乾式膠輪黏著;所採S g =合黏著再分離之方式或多個膠輪直 13·如申請專利範圍第一項所述之局 ;飾性油墨之前置裝飾附著堆疊目或圖進 之射全像圖案之雷射 膠基材上完成多種圖案鑛臈之堆疊,藉由;申==塑7 17 200823056 項之鍍膜產生方式,配合應用如申請專利範園 f應用之鍍膜材料,產生不同特性,如電阻,^及第9項 休巧堆疊組合’作為在雷射全像膜於圖案設計及 卜規變化上之應用目的。 Ο8. Covering a layer of pressure-sensitive polymer resin on one end surface of the plastic substrate, as a pressure-sensitive layer of the laser full-image rolling development, in order to facilitate the processing of the subsequent laser full-image rolling roller; Tian Yi forms a water-soluble solution The cover layer of the ink covering layer is disposed on the upper end surface of the plastic substrate carrier covering the pressure sensitive layer, and the protective layer is partially hollowed out or patterned, and only the position of the line or pattern is not covered with ink; The plastic substrate carrier covering the ink protective layer treatment has been formed, and the laser full-image pattern transfer on the surface of the material is first performed by the roller roller roller processed by the laser engraving, that is, in the form of rolling reversal. On a transparent plastic substrate, a double-sided laser full-image display, partial or full-scale pattern, and then surface cleaning or corona treatment or ozone oxygen 1 匕 $ V for surface activation (surface activati〇n) Improve the adhesion and processability of the subsequent system; 7 heat, form a highly reflective metallic gloss coating layer on the surface of the carrier layer on which the ink protective layer has been attached previously, and the formed metallic gloss coating layer is a unique and transparent substrate Single-sided laser full-image display unit c The above-mentioned laser full-image rolling and protective ink-covering procedures can be interchanged, and the surface pattern is melt-selectively dissolved in a manner that dissolves the metal 绮 盍 ink protective layer. In addition, it causes the surface of the mineral film stack, the surface of the transparent or opaque plastic substrate carrier, or the dry-like image to become a part of the laser or _ partial laser full gamma product. With the r % 15 200823056 2. Γ 4· 6· 7· The method for manufacturing a laser holographic film as described in the above-mentioned patent scope, wherein the material of the plastic substrate carrier may comprise a poly Ethylene (ρΕ), polyethylene (PVC), polystyrene (pS), polypropylene (ρρ), polyethylene terephthalate (PET), polycarbonate (pC), polymethyl propylene glycol An organic material such as methyl vinegar (ρΜΜΑ) or polyimide (ΡΙ) may be in the form of a plate, a film roll material, a sheet material or the like. The method for manufacturing a laser holographic film according to the partial laser full-side case described in the above-mentioned patent application scope--the laser full-image developing layer material coated with the fine substrate may comprise a thermoplastic southern molecular material, Such as the high age of Acrylic or other secret or silk ship "Molecular materials such as the application of the scope of the patent range - item of the laser full image _ the laser $ method' its towel laser miscellaneous The transfer of the bribe can include a full version of the 2222, a negative pattern, a partial pattern, a neo/pitch pattern, and a blank cutout pattern. The partial f-shot holographic image of the gamma ray is a technique for gravure printing, letterpress printing, lithography, flexographic printing, laser printing, inkjet printing, etc. Transfer the f7 mine ^ Shen Qing patent fine--the partial laser holographic pattern, wherein the ink protection layer is used to form the ink protection G, the color; J ======== = S (2));;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; , zinc, antimony, tin, wrong, lead mf may include gold, silver, copper, platinum, titanium, tungsten and other metals or alloys thereof, etc., aluminum, bismuth, antimony, bismuth, ======= The film-like iron 'nickel, zinc, indium, tin, and Minggu n can be made of metal, such as gold, silver, copper, tin, titanium, crane, etc., or other materials and/or f, 钡, ♦ Nitride and the like. , he, and the above-mentioned metal sulphide of the reflectivity of the preparation. 10. The partial enthalpy of the first aspect of the patent application is as follows: [the method of the invention] (4) metallic luster ore 11. The film manufacturing as described in the first paragraph of the patent application The method wherein the metallic luster is between 5000 nm. The brothers and sisters can be from O.lnm to 11. The method for manufacturing the film according to the first application of the patent scope, wherein the wet selectivity is like an aqueous solution at the same temperature, pure water, or containing H. For example, the mixture of water in the first item of the patent application scope. By the method 'where the dry rubber wheel is adhered; the S g = the adhesive is re-separated or the plurality of rubber wheels are straight 13 · as described in the first item of the patent application; the decorative ink is pre-decorated and attached Stacking the mesh or the image into the laser image of the full-image pattern to complete the stacking of various patterns of mineral ore, by applying the coating method of the application of the application, such as the patent application Fan Park f application The coating material produces different characteristics, such as resistance, and the ninth item of the stacking combination as the application purpose of the laser holographic film in pattern design and variation. Ο
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