TW200811331A - In-bath quality enhancing agent for fiber processing and method of processing - Google Patents

In-bath quality enhancing agent for fiber processing and method of processing Download PDF

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Publication number
TW200811331A
TW200811331A TW096120634A TW96120634A TW200811331A TW 200811331 A TW200811331 A TW 200811331A TW 096120634 A TW096120634 A TW 096120634A TW 96120634 A TW96120634 A TW 96120634A TW 200811331 A TW200811331 A TW 200811331A
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Taiwan
Prior art keywords
bath
acid
group
processing
dyeing
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TW096120634A
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Chinese (zh)
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Tadahiko Kato
Masatoshi Hayashi
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Nicca Chemical Co
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/20—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen
    • D06L4/21—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which contain halogen combined with specific additives
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/419—Amides having nitrogen atoms of amide groups substituted by hydroxyalkyl or by etherified or esterified hydroxyalkyl groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)
  • Detergent Compositions (AREA)

Abstract

An in-bath quality enhancing agent comprising at least one member selected from the group consisting of amide compounds of given structure, at least one member selected from the group consisting of trihydric or higher polyhydric carboxylic acid mono- or dialkyl ester compounds and mono- or dialkenyl ester compounds, and at least one member selected from the group consisting of anionic surfactants of sulfosuccinic acid of given structure. This in-bath quality enhancing agent ensures favorable miscibility with various concomitant chemicals and dyes for use in the scouring bleaching processing and dying processing of fiber materials and excels in the effect of inhibiting rumpling.

Description

200811331 九、發明說明： 【發明所屬之技術領域】 本發明係關於一種用於各種纖維材料之浴中品質提曰添 及使用其之加工方法。本發明尤苴係 貝汁劑 儿關於一種浴中品 昇劑以及精煉漂白加工方法或染色' 乃忒，该洛中品皙 提昇劑可防止於各種纖雄材料之精煉漂白加工或染色加卫 等浴中處理之際或脫水處理之際，由布帛與布帛：或： :加工機械間產生之物理力而引起擦傷.、掩色等纖維損 知、及賴之產生，防止精煉斑或染色斑，提供 、 之加工品。 貝乂良 【先前技術】 -般而言’於各種纖維布帛材料之精煉漂白加工及染色 加工中’與以開幅狀進行加 夂乂捲木色機、經軸染色機. 二目比，使用以繩狀進行加工之繩狀染色機、液流染色機， 在加工品之手感、加工效率方面優良，故利用較多。並 且，自加工用水之節約資调卟 貝源化及即月匕化、高生產性等觀點 真二正進行高速化、低浴比化。然而，另一方面現狀 二伴隨，速化及低浴比化，以下情況增多：由升溢速度 ^之移動速度加快而引起繩褶敵或擦傷 由布之填充密度較大而引起稍飯1 & 士 给 引起柏皺產生。尤其是以棉、嫘 ，麻為代表之纖維素系纖維，因濕潤時之收縮率變大、 、且為之自由度變小’故易於由成為繩狀之狀態下（折疊為 =狀之狀恶）的收縮而產生稱為繩摺敏之糟敵。並且，先 狀為對方；精煉漂白及染色之各步驟中所產生之褶 I21587.doc 200811331 皺，以藉由最終精加工 之方法來處理。 η中拉幅之際的熱或張力而修復 精煉漂白時所產吐、 驟中，阻礙、、谷中μ賴或纖維之損傷於後續之染色步 即使纖維擴散，從而導致不均染。又， W便稭由取終精加工 消撕漂白步驟及;=幅機之熱或張力處理，來 為暫時性，缝製後，认 產生之摺敵，其效果亦 來狀能，引：r:。肖費者進行洗滌等之際因恢復到原 末狀引起變形等而弓丨發消費者投訴。 自提高最終纖維,σ 、卩口的σ口位之觀點考慮肖 工步驟中所產生之_1 “ 4 ^ H述各加 相敬或纖維損傷問題係重要因素。 進而，於精煉漂白浴中…、 解之雔气、須使用雙氧水、抑制雙氧水分 又氧水穩疋劑、氫氧化 全 等藥劑；於染色浴中必項…束d i屬離子螯合劑 -姑^ 須使用氷料、最大為150 g/L之大量. 亡石[均染劑、金屬離子螯合劑、以及作為用 = 料與纖維反應之鹼劑" ’’、 反應染 ^ 、反次鈉或氫氧化鈉等藥劑，因此由 於该專無機化合物、 由 性不足，而亦產生阻礙品質提昇劑之相容 有-種浴中品質提曰木且、染色斑等問題。因此’期望 、汁剑，其與精煉漂白浴 '染色浴中m 用之無機化合物、右施&八i 中所使 褶皺產生之防皺效果方面優良。 在了朴制 本申明人於日尽專利特公平6巧7916號公報中，提 用包含芳香㈣酸κ其硫酸化物及苯甲醇之浴中品^ 作為如下方法··抑制精煉漂白加工、染色加工步； 之袼皺的產生，並且僅於加工步驟最初的精煉漂白步駟 121587.doc 200811331 中即可不僅於下—步驟之染色步驟中、且 均維持效果，铁 至攻、冬乾燥時 …、而現狀為無法達到穿 之效果的水準。 滿足抑制褶皺產生 【發明内容】 本發明之目的在於提供一種浴 精煉漂白加工或毕声Λ 士 貝‘汁劑，其對於因 口口之品質的材料，尤苴θ 、、隹持加工 及麻為代表之纖唯布帛枯料中以棉、螺營 巧代表之纖維素糸纖維材料 該等材料與精煉漂白加工、染色加工牛：：、准材科，可使 併用藥嶋編… 驟中所使用之各種 良。“4的相谷性優良’且抑制糟皺產生之效果優 本發明者們為解決上硫啤 解夬上述㈣而反覆專心研究，結果發 =由將特定之醯胺系化合物、酿化合物及陰離子界面 t性劑加以組合而用作浴中品質提昇劑，可獲得下述令人 驚歎之效果··抑制各種纖維布率材料之精煉漂白加工、半 色加工步驟中稽敏產生的效果優良，與各種併用藥劑或染 枓之相容性良好’並且僅於一系列之精煉漂白加工、染色 加工步驟之最初步驟的精煉漂白加工步驟中使用，即可不 僅於下乂驟之杂色加工步驟中，且至最終之乾燥步驟均 維持效果’進而缝製品亦可獲得柔軟手感；從而依據該知 識見解而完成本發明。 即，本發明提供一種纖維加工用之浴中品質提昇劑，其 特徵在於含有下述(A)、（B)及（C)。 (A):選自下述通式（1)、（2)及（3)所表示之醯胺系化合物 121587.doc 200811331 之群中的至少一種， / C 2 Η 4 〇 R ’ R C 〇 C 2 Η4 〇Η RCONHC2 H4 NHC2 nhr5 RC〇NHC2 H4 NHC2 H4 〇R， (上式中，R表不碳數為9、23之直鏈或支鏈烷基或烯基，200811331 IX. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to a method for processing quality in a bath of various fiber materials and a method of using the same. The invention relates to a bathing agent for a bath, a refining bleaching method or a dyeing method, which can prevent the refining bleaching treatment or dyeing and other baths of various fibrin materials. At the time of processing or dehydration treatment, the physical force generated by the cloth and cloth: or : processing machinery causes scratches, color loss and other fiber damage, and the production of the film to prevent refining or staining. , processed products. Puiliang [Prior Art] - Generally speaking, 'in the refining bleaching process and dyeing process of various fiber fabric materials' and twisting the wood color machine and the warp beam dyeing machine in the open width. The rope dyeing machine and the liquid flow dyeing machine which are processed in a rope shape are excellent in the hand feeling and processing efficiency of the processed product, and therefore are used in many cases. In addition, the self-processing water is saved, and the advantages of high-quality and low-bath ratio are achieved. However, on the other hand, the status quo is accompanied by speeding up and low bath ratio, and the following situation is increased: the speed of the lifting speed is increased, and the pleats or scratches caused by the cloth are caused by the high packing density of the cloth. The sergeant caused the crease. In particular, cellulose fibers, which are represented by cotton, sputum, and hemp, have a large shrinkage rate when wet, and the degree of freedom is small, so that it is easy to be in a rope-like state (folded to a shape of = The contraction of evil) produces a bad enemy called rope folding. And, the first shape is the other side; the pleats generated in the steps of refining bleaching and dyeing are treated by the final finishing method. The heat or tension during the η stretching is used to repair the sputum, the sputum, the hindrance, the damage in the valley, or the damage of the fibers in the subsequent dyeing step. Even if the fibers diffuse, the unevenness is caused. Moreover, the W straw is processed by the final finishing finishing and tearing bleaching step; and the heat or tension treatment of the width of the machine is temporary, and after the sewing, the enemy is recognized, and the effect is also in the form of energy. :. When the Xiao Fei is washing, etc., the consumer complains due to the deformation caused by the return to the original shape. From the point of view of increasing the final fiber, σ and σ mouth position of 卩, consider the _1 “4 ^ H described in the Xiaogong step, which is an important factor in the addition of respect or fiber damage. Furthermore, in the refining bleach bath... To solve the suffocation, to use hydrogen peroxide, to suppress hydrogen peroxide and oxygen water stabilizer, hydrogen peroxide and other agents; in the dye bath, must be... bundle di ionic chelating agent - gu ~ must use ice, up to 150 g /L of a large amount. Dead stone [leveling agent, metal ion chelating agent, and as an alkali agent used in the reaction of the material with the fiber " '', reaction dyed, reverse sodium or sodium hydroxide, etc., therefore Inorganic compounds, insufficient in nature, but also hinder the compatibility of the quality improver - the quality of the bath, the quality of the eucalyptus, dye spots, etc. Therefore, 'expect, juice sword, and the refined bleach bath' dye bath m is excellent in the anti-wrinkle effect of wrinkles caused by the inorganic compound, the right application & the eighth. In the Japanese version of the patent, the patent contains the aromatic (tetra) acid. κ its sulphate and benzyl alcohol bath products ^ As a method of the following: · inhibiting the refining bleaching process, the dyeing process step; the generation of wrinkles, and only in the initial refining bleaching step 121587.doc 200811331 of the processing step, not only in the dyeing step of the next step, but also Maintaining the effect, the iron is attacked, the winter is dry, and the current situation is the level at which the effect of wearing is not achieved. Satisfying the suppression of wrinkles. SUMMARY OF THE INVENTION The object of the present invention is to provide a bath refining bleaching process or a Bismuth's juice. Agent, for the material of the quality of the mouth, especially 苴 θ, 隹 加工 及 及 麻 麻 麻 麻 麻 麻 麻 麻 麻 麻 代表 代表 代表 代表 代表 代表 代表 棉 棉 棉 棉 棉 棉 棉 棉 棉 棉 棉 棉 棉 棉 棉 棉 棉 棉 棉 棉 棉 棉 棉Processing, dyeing and processing of cattle::, quasi-materials, can be used in combination with drugs. The various uses used in the process. "4 good phase grainability" and the effect of suppressing wrinkles is excellent. The inventors have solved Sulphur Brewery solves the above (4) and repeatedly concentrates on the research. The result is as a quality enhancer in the bath by combining a specific amide compound, a brewing compound and an anionic interfacial t-agent. The following amazing effects can be obtained. · The refining bleaching process for suppressing various fiber cloth materials, the effect of sensitization during the half-color processing step is excellent, and the compatibility with various co-agents or dyes is good' and only A series of refining bleaching processes, used in the refining bleaching step of the first step of the dyeing process, can maintain the effect not only in the variegated processing steps of the next step, but also in the final drying step. A soft hand is obtained; thus, the present invention has been completed on the basis of this knowledge. That is, the present invention provides a bath quality improving agent for fiber processing, which comprises the following (A), (B) and (C). (A): at least one selected from the group consisting of the amide-based compounds 121587.doc 200811331 represented by the following general formulae (1), (2), and (3), /C 2 Η 4 〇R ' RC 〇C 2 Η4 〇Η RCONHC2 H4 NHC2 nhr5 RC〇NHC2 H4 NHC2 H4 〇R, (In the above formula, R represents a straight or branched alkyl or alkenyl group having a carbon number of 9,23,

R，表示姻-COR”（其中，R，，表示㈣為9〜23之直键或支 鏈烷基或烯基））。 (B):選自由3元以上之多元羧酸的單或二烷基酯化合 物、以及早或二焊基醋化合物所組成4群中的至少一種 (其中’该專烧基或婦暮可或古4、丄 可為直鏈或支鏈，其碳數為 8 〜2 4 ) 〇 (c):選自下述通式（4)所 * k )斤表不之石頁基琥珀酸型陰離子界 面活性劑之群的至少一種， K 〇 C Ο - c Η 2 R - °CO-CH-S〇3 X (4) 式/，^❼別表示魏抓以直鏈或支鏈 土或㈣’X表示_Na'_K、_NH4或貌醇胺基）。 又，本發明提供一種精燒挪 以含右卜猜煉/示白加工方法，其特徵在於 以B有上述冷中品質提昇 材料。 W之處理洽來精煉漂白加工纖」 進而，本發明提供一種染色加工 含有卜、f、/、+ 法，其特徵在於：i 5有上述冷中品質提昇 ^ /合來染色加工纖維材料。 32I587.doc 200811331 本發明之浴中品質提昇劑具有習知浴中品質提昇劑所無 法獲得之、抑制精煉漂白加工及染色加工步驟中褶皺產I 之優良效果。利用本發明之浴中品質提昇劑，不僅可防止 精煉漂白加工、染色加工步驟之纖維損傷，並且可防止處 理沦中由褶皺所引起之不均染、縫製品之變形，從而可獲 得高品位之染色加工品。又，因精煉漂白加工、染色加工 浴中之防皺效果優良，故不需要在降低浴中之加工纖維 量降低布速、降低冷卻速度之加工條件方面的防止褶敵 對朿，因此可實現生產性、生產效率的提高。可用於各種 纖維材料，尤其是以棉、螺縈及麻為代表之纖維素系纖維 材料及其混紡纖維材料，該等材料因精煉漂白加工'毕色 加工時所產生之糟皱而難以進行加工品的品質維持管 【實施方式】 以下就本發明之較好實施形態加以說明，但本發 僅限於該等形態，可於本發明之 各種變更。 7及/、具鞑乾圍内進行 本發明之浴中品質提昇劑含有： 之me八—入 匕名特疋酉监胺系化合物 -、匕3特定酿化合物之(B)成分以 王白酸型陰離子界面活性劑之（c)成分。 ”基琥 ==用的包含特定醯胺系化合物之⑷成分， 中… ⑴、(2)及(3)所表示之酿胺系化合物之群 中的至少1種。 w〈砰 胺ίϊ=(1)所表示之§_、化合物，係例如將二乙醇 ”厌為10〜24之羧酸調整為莫耳比i m於 J2J587.doc •】0- 200811331 n〇〜2〇〇°c下使其進行脫水反應而獲得。作為碳數為10〜24 之羧酸，例如可列舉：癸酸、十一酸、十二酸、十三酸、 十四@义十五酸、十六酸、十七酸、十八酸、異十八酸、 十九酸、二十酸、二十二酸、二十四酸、十八烯酸等。 又’亦可藉由上述羧酸之低級烷基酯例如甲酯與二乙醇胺 之脫每化反應，或者上述羧酸之酸酐的醯胺化反應，而释 得通式（1)所表示之醯胺系化合物。R, represents a marriage -COR" (wherein R, represents (4) is a direct bond or a branched alkyl or alkenyl group of 9 to 23). (B): single or two selected from a polycarboxylic acid of 3 or more An alkyl ester compound, and at least one of the group consisting of an early or a second base vinegar compound (wherein the specialty group or the genus or the genus can be linear or branched, and the carbon number is 8 ～2 4 ) 〇(c): at least one selected from the group consisting of the following general formula (4) * k ), which is not a group of succinic acid type anionic surfactants, K 〇C Ο - c Η 2 R - °CO-CH-S〇3 X (4) where /, ^ indicates that Wei grabs a straight or branched chain or (d) 'X indicates _Na'_K, _NH4 or a prolamine base.) The invention provides a method for processing a fine burning and containing a quiz/whitening process, characterized in that the above-mentioned cold medium quality improving material is obtained by B. The processing of W is to refine the bleaching processing fiber. Further, the present invention provides a dyeing process. Containing the Bu, f, /, + method, characterized in that i 5 has the above-mentioned cold-medium quality improvement / combined dyeing processed fiber material. 32I587.doc 200811331 The in-bath quality enhancer of the present invention has an excellent effect of suppressing the wrinkle production I in the refining bleaching process and the dyeing process step which is not obtained by the conventional bath quality improving agent. By using the quality enhancer in the bath of the invention, not only the fiber damage of the refining bleaching process and the dyeing process step can be prevented, but also the uneven dyeing caused by the wrinkles in the treated crucible and the deformation of the sewn product can be prevented, thereby obtaining a high grade. Dyed processed products. Moreover, since the anti-wrinkle effect in the refining bleaching processing and the dyeing processing bath is excellent, it is not necessary to prevent entanglement in the processing conditions for lowering the amount of processed fibers in the bath, reducing the cloth speed and lowering the cooling rate, so that productivity can be achieved. Increased production efficiency. It can be used in various fiber materials, especially cellulose fiber materials represented by cotton, snails and hemp, and their blended fiber materials, which are difficult to process due to the wrinkles generated during the refining bleaching process. BEST MODE FOR CARRYING OUT THE INVENTION [Embodiment] Hereinafter, preferred embodiments of the present invention will be described. However, the present invention is limited to these embodiments and can be variously modified in the present invention. 7 and /, the bath quality improving agent of the present invention is contained in the 鞑 围 含有 之 含有 含有 含有 含有 含有 含有 含有 含有 me me me me me me me me me me me me me 品质 品质 品质 品质 品质 品质 品质 品质 品质 品质 品质 品质 品质 品质Component (c) of an anionic surfactant. "Base Hu == at least one of the group of the amine-based compounds represented by the component (4) of the specific amide-based compound, (1), (2) and (3). w<砰amine ϊ ϊ = ( 1) The indicated §_, compound, for example, the dicarboxylic acid anodicated to 10~24 carboxylic acid is adjusted to Moer than im in J2J587.doc • 0-200811331 n〇~2〇〇°c Obtained by performing a dehydration reaction. Examples of the carboxylic acid having a carbon number of 10 to 24 include citric acid, undecanoic acid, dodecanoic acid, tridecanoic acid, tetradecanoic acid, hexadecanoic acid, heptadecanoic acid, and octadecanoic acid. Isooctadecanoic acid, nineteen acid, twenty acid, behenic acid, tetracosic acid, octadecenoic acid, and the like. Further, the oxime represented by the general formula (1) can also be obtained by a dealkylation reaction of a lower alkyl ester of the above carboxylic acid, such as a methyl ester and diethanolamine, or a guanidation reaction of an acid anhydride of the above carboxylic acid. Amine compound.

又’上述通式（2)所表示之醯胺系化合物，係例如藉由 將二伸乙三胺與碳數為1〇〜24之緩酸調整為莫耳比1 : 1〜1 : 2、於120〜i8(TC下使其進行脫水反應而獲得。作為 碳數為10〜24之羧酸，例如可列舉：癸酸、十一酸、十二 酉义十二酸、十四酸、十五酸、十六酸、十七酸、十八 酸、異十八酸、十九酸、二十酸、二十二酸、二十四酸、 十八烯酸等。又，亦可藉由上述羧酸之低級烷基酯例如甲 3曰與一伸乙二胺之脫醇化反應，或者上述叛酸之酸野的酿 胺化反應，而獲得通式（2)所表示之醯胺系化合物。 進而，上述通式（3)所表示之醯胺系化合物，係例如藉 由將胺.乙基乙醇胺與碳數為1 〇〜24之緩酸調整為莫耳比i : 1〜1 : 2，於120〜180°C下使其進行脫水反應而獲得。作為 碳數為1 〇〜24之羧酸，例如可列舉：癸酸、--酸、十二 酸、十三酸、十四酸、十五酸、十六酸、十七酸、十八 酸、異十八酸、十九酸、二十酸、二十二酸‘、二十四酸、 十八晞酸等。又，亦可藉由上述羧酸之低級烧基酯例如曱 錯與胺乙基乙醇胺的脫醇化反應，或者上述羧酸之酸酐的 i21587.doc 200811331 醯胺化反應，而獲得通式（3)所表示之醯胺系化合物。 於本發明之浴中品質提昇劑中，可將上述通式⑴、⑺ 及⑺所表示痛系化合物單獨使用i種或組合使用2種以 上，作為（A)成分之醯胺系化合物，較好的是使浴中品質 提昇劑中含有卜20質量％之(A)成分，更好的是含有$〜〇質 量％。 、 包含特定酿化合物之⑻成分，係選自由分子中具有3個 ^域基之多元賴的單或二燒基_化合物以及單或二烤 基知化合物之所組成之群中的至 ^ ^ ^ 種。/、中，該等酯化 口物的烷基或烯基可具有側鏈，其碳數為8〜Μ。 (B)成分之酯化合物，係例 8 24^ ^ 猎由將3兀以上之多元羧酸 人数為S〜Μ之醇調整為莫耳比i 。Further, the guanamine compound represented by the above formula (2) is adjusted to a molar ratio of 1: 1 to 1 by, for example, diamethylenetriamine and a slow acid having a carbon number of from 1 to 24. It is obtained by subjecting it to a dehydration reaction at 120 to i8 (TC). Examples of the carboxylic acid having a carbon number of 10 to 24 include citric acid, undecanoic acid, dodecanoic acid, tetradecanoic acid, and ten. Pentaic acid, palmitic acid, heptadecanoic acid, octadecanoic acid, isooctadecanoic acid, nonadedic acid, icosonic acid, behenic acid, tetracosic acid, octadecenoic acid, etc. The lower alkyl ester of the above carboxylic acid, for example, the dealcoholization reaction of methyl hydrazine with ethylene glycol diamine, or the amidation reaction of the above-mentioned acid-removing acid field, gives the amide compound represented by the general formula (2). Further, the guanamine compound represented by the above formula (3) is adjusted, for example, by an amine.ethylethanolamine and a slow acid having a carbon number of 1 〇 to 24 to a molar ratio i: 1 to 1: 2, It is obtained by dehydration reaction at 120 to 180 ° C. Examples of the carboxylic acid having a carbon number of 1 to 24 include citric acid, acid, dodecanoic acid, tridecanoic acid, and tetradecanoic acid. Fifteen acid, ten Hexaic acid, heptadecanoic acid, octadecanoic acid, isooctadecanoic acid, nonadedic acid, icosonic acid, behenic acid', tetracosic acid, octadecanoic acid, etc. Also, by the above carboxylic acid The lower alkyl ester such as decoupling reaction with amine ethylethanolamine or the amidation reaction of the above-mentioned carboxylic acid anhydride i21587.doc 200811331 to obtain a guanamine compound represented by the general formula (3). In the in-bath quality improving agent of the present invention, the pain-based compound represented by the above formulas (1), (7) and (7) may be used singly or in combination of two or more kinds thereof as the amide-based compound of the component (A). It is such that the quality improving agent in the bath contains 20% by mass of the component (A), more preferably, it contains $% by mass. The component (8) containing the specific brewing compound is selected from the group consisting of three domains. The alkyl or alkenyl group of the esterified mouth may have a plurality of mono- or di-alkyl-based compounds and a mono- or di-baked compound. The side chain has a carbon number of 8 to Μ. (B) The ester compound of the component, the example 8 24 ^ ^ The hunting is more than 3 之Element number of carboxylic acid is adjusted to an alcohol S~Μ the molar ratio of i.

.下使其進行脫水反 ，於120〜2〇〇 C 多元㈣/ 或脫S子反應而獲得。作為3元以上之 ^竣馱，例如可列舉： 酸、偏笨三甲酸w +Λ 均本四甲酸、檸檬 τ酉夂野、均苯四甲酸酐等。 三曱酸單子酯、偏鼓_田&amp; 亦可使用偏苯 偏苯三甲酸二”二甲西夂二甲，、偏笨三甲酸單乙醋、 酸單乙SI、卿I ϋ酸早甲_、檸檬酸二甲醋、檸檬 缓酸。又，^夂二乙酉旨等低級炫基能，來代替該等多元 乙基已醇、壬^數為8〜24之醇’例如可列舉：辛醇、2- 醇 醇 等 -予癸醇、異癸醇、十—醇、一 十四醇、十五醇、/ 十一醇、十三 十九醇、二 /、j、七醇、十八醇、異十八 酉子、二十二醇、二十四醇、十八烯醇 月之洽中品質提昇劑中，可 田上述多兀羧酸與 121587.doc -32- 200811331 醇所獲得之_化合物單獨使用i種單獨或組合使用2種以 上，作為⑻成分之酿化合物，較好的是使浴巾品質提昇 浏中合有1〜30質量％之（B)成分，更好的是含有、^質量 包含磺基琥拍酸型陰離子界面活性劑之（c)成分，係選 自上述通式⑷絲㈣陰料界面活性劑的 群中之至少1種。It is obtained by dehydrating it in the form of 120~2〇〇C multivariate (four)/ or de-S sub-reaction. Examples of the trivalent or higher hydrazine include, for example, an acid, a stupitricarboxylic acid, w + fluorene, a tetracarboxylic acid, a lemon, a benzoic acid, and a pyromellitic anhydride. Triterpenic acid monoester, partial drum _ field &amp; can also use benzene trimellitic acid di "dimethyl dimethyl hydrazine," stupid tricarboxylic acid monoacetic acid, acid single ethyl SI, Qing I citrate early _ , citric acid citrate, lemon acid-lowering, and lower-grade phosgene energy such as 夂 夂 酉 , , , , 代替 代替 代替 代替 代替 代替 代替 多元 多元 多元 辛 ' 辛 辛 辛 ' ' ' ' ' ' ' ' ' ' ' ' ' ' , 2-alcohol, etc. - sterol, isodecyl alcohol, decaol, tetradecanol, pentadecyl alcohol, / undecyl alcohol, tridecyl alcohol, di /, j, heptaol, stearyl alcohol In the quality improving agent of the same, the octadecyl alcohol, the octadecyl alcohol, the hexadecanol, the octadecyl alcohol, the octadecyl alcohol, the octadecyl alcohol, the above-mentioned polyhydric carboxylic acid and 121587.doc -32-200811331 The compound is used singly or in combination of two or more kinds, and as the brewing compound of the component (8), it is preferred to increase the quality of the bath towel by adding 1 to 30% by mass of the component (B), and more preferably, containing The component (c) containing a sulfo-succinic acid type anionic surfactant is at least one selected from the group consisting of the above-mentioned general formula (4) silk (iv) negative surfactant.

(C)成分之磺基琥珀酸型陰離子界面活性劑，係例如藉 由將順丁稀二gf與碳數為8〜24之醇調整為莫耳比工·· 2， 於14 0〜1 8 〇 c下使其進行脫水反應以獲得丁二酸二酿後， 使用無水亞硫酸氫鈉等磺化劑，於7〇〜13〇它下使其進行磺 化反應而獲得。作為碳數為8〜24之醇，例如可列舉：辛 酉予、2-乙基己醇、壬醇、癸醇、異癸醇、十一醇、十二 醇、十三醇、十四醇、十五醇、十六醇、十七醇、十： 醇、異十八醇、十九醇、二十醇、二十二醇、二十四醇、 十八烯醇等。 於本發明之浴中品質提昇劑中，可將上述通式⑷所表 示之續基琥轴酸型陰離子界面活性劑單獨使用“重或組合 種乂上，作為（c)成分之石黃基琥珀酸型陰離子界面活 性劑，較好的是使…口質提昇劑中含有M0質量％之(0) 成分’更好的是含有5〜15質量％。 可藉由以上述方式控制本發明之浴中品質提昇劑中的 ⑷成为、（B)成分及（C)成分的含量，而平衡性良好地控制 防皺性、柔軟性、及與各種併用藥劑或染料的相容性之各 121587.doc 200811331 性能，因此較好。 進而，於本發明之浴中品質提昇劑中，較好的是構成為 下述製劑，該製劑包含：上述（A)成分、（B)成分及（c)成分 之3種必要成分，作為其他成分的殘部為水或曱醇、乙 酉子異丙.、乙二醇、丙三醇、山梨醇、丁基乙二醇等親 水性溶劑，以及水。The sulfosuccinic acid type anionic surfactant of the component (C) is adjusted, for example, by adjusting the cis-butyl dig gf and the alcohol having a carbon number of 8 to 24 to a molar ratio of 2, at 14 0 to 18 After dehydration reaction is carried out under 〇c to obtain succinic acid, it is obtained by sulfonation reaction using a sulfonating agent such as anhydrous sodium hydrogen sulfite under the conditions of 7 Torr to 13 Torr. Examples of the alcohol having a carbon number of 8 to 24 include, for example, octyl phthalate, 2-ethylhexyl alcohol, decyl alcohol, decyl alcohol, isodecyl alcohol, undecyl alcohol, dodecanol, tridecyl alcohol, tetradecanol, and ten. Pentaol, cetyl alcohol, heptadecyl alcohol, ten: alcohol, isostearyl alcohol, nonadecanol, eicosyl alcohol, behenyl alcohol, tetracosyl alcohol, stearyl alcohol, and the like. In the bath quality improving agent of the present invention, the succinic acid type anionic surfactant represented by the above formula (4) can be used alone as "heavy or combined species" as the component (c) of the rhubarb amber. The acid type anionic surfactant preferably contains (0) component of M0% by mass in the oral substance-improving agent, and more preferably contains 5 to 15% by mass. The bath of the present invention can be controlled by the above manner. (4) in the medium quality improving agent, the content of the component (B) and the component (C), and the balance of the crease resistance, the flexibility, and the compatibility with various chemicals or dyes are well controlled. Further, in the bath quality improving agent of the present invention, it is preferred to be a preparation comprising the above-mentioned (A) component, (B) component, and (c) component. The three essential components, and the remaining components of the other components are water or sterol, ethyl isopropyl isophthalate, a hydrophilic solvent such as ethylene glycol, glycerin, sorbitol, or butyl glycol, and water.

I 又：某些情況下，亦可於本發明之浴中品質提昇劑中調 _反數為1 〇 1 8之回級醇、高級烷基胺、高級脂肪酸等 之環氧烷(碳數為2〜3)加成物，多元醇脂肪酸(碳數為 10 18)¾之％氧烷（碳數為2〜3)加成物，脂肪酸（碳數為 10 18&gt;月女之&amp;氧烧（碳數為2〜3)加成物，聚氧乙稀山梨醇 脂肪酸酿等各種非離；、、丰u ^ 、寺合徑非離子，舌性劑；柔軟劑成分，平滑劑成 分，滲透劑成分，均染劑成分等界面活性劑；抗靜電劑； 金屬離子螯合劑；抗氧化劑；消泡劑等。 精由將本發明之浴中口所e 甲口口貝棱幵劑用於精煉漂白加工、染 色加工等系列步驟中’尤其是最初步驟之精煉漂白加工 步驟中，不僅抑制褶敏產生，其後不會出現由稽皺所引起 之不均染或纖维損傷，並且可有效獲得縫製後亦難以產生 變形之染色加工品。當然’除精煉漂白加工浴以外，於染 色加工浴中亦可追加使用本發明之浴中品質提昇劑。 使用本發明之浴中品質提昇劑進行精煉漂白加工、染色 加工之際：通常可使用普遍所使用之染色機械，即繩狀染. 色機、液流染色機、交捲染色# 、奴七 邑祛專。又，於精煉漂白浴或 染色浴中可使用通常所使用之無.機或有機化學藥品或染 121587.doc 200811331 料。 本ι明之冷中品質提昇劑可用於 工、染色加…棉、麻、羊毛、/哉、准之各煉漂白加 勞、贈酸西旨、鋼錢纖維（Bemb :'網等天然纖維，嫘 聚醯胺系、聚丙、協生纖維，聚酯系、 腈线料合I 4 以下製品之浴中品質提昇劑：包含棉、二八可有效用作 系纖維之纖維製品，或者被看作於㈣。=等、=维素 工中易於產生褶皺、易於殘留之 ：°工、染色加 且使用強撚紗之棉織物。 ^冑物的高密度 本發明之浴中品質提昇劑可藉 用，並且相對於纖而使 本發明之浴中〇所担曰十丨 νΏ 、中口口貝鲛汁劑之效果，藉由（Α)成分、（Β^ 为及（C)成分的3成分址在而古方* 攻刀/、存而1*次產生。即，（A)成分之醯 女系化口物與⑻成分之酯化合物的組合時，與用於精煉 漂白浴或染色浴中之藥劑的相容性並不充分，在精煉性方 面無法獲传充分效果’·（B)成分之酯化合物與（C)成分之硌 基琥珀I型陰離子界面活性劑的組合時，在防皺、賦予柔 孝人丨生方面無法獲得充分效果，·（A)成分之醯胺系化合物與 (C)成分之續基琥珀酸型陰離子界面活性劑的組合時，洛 中口口貝k汁劑之製品穩定性或處理浴的穩定性並不充分。 僅於使成分、（B)成分、（C)成分之3成分共存而使用 4 ’於處理洛中穩定，且在浴中柔軟性、防敏性方面發揮 優良效果。一般認為其原因在於，因（A)成分之醯胺系化 121587.doc 200811331 合物表現陽離子性行為，故對 / Δ、氺八 芦心親和性拎咼，因此對 (A) 成分、(B)成分及（c) 、，區m““維材料的吸附量易於自低 E或大。先珂’醯胺 ^ t σ物之（A)成分的柔軟效果 優良，但與精煉漂白加工 乂木色加工浴中之各種併用筚 劑或染料之相容性不良，因此i不、_入你&amp; 伢用梁 此並不適合作為精煉漂白加 工、染色加工中所使用之浴中品質提昇劑的組合物。缺 而，於本發明中，將作為特定結構之化合物的（a)成分、I: In some cases, it is also possible to adjust the alkylene oxide, the higher alkylamine, the higher fatty acid, etc., in the quality improving agent of the bath of the present invention. 2 to 3) adduct, polyol fatty acid (carbon number 10 18) 3⁄4% oxane (carbon number 2 to 3) adduct, fatty acid (carbon number 10 18 &gt; month female &amp; oxygen burning (carbon number is 2~3) adduct, polyoxyethylene sorbitan fatty acid and other non-separating;, Feng u ^, temple diameter non-ionic, tongue agent; softener component, smoothing agent component, penetration Surfactant, leveling agent and other surfactants; antistatic agent; metal ion chelating agent; antioxidant; antifoaming agent, etc. Finely used in the bath of the present invention, the mouth of the mouth is used for refining In the series of steps such as bleaching processing and dyeing processing, especially in the refining bleaching step of the initial step, not only the occurrence of pleats is suppressed, but also the uneven dyeing or fiber damage caused by the wrinkles does not occur, and can be effectively obtained. It is also difficult to produce a deformed dyed product after sewing. Of course, in addition to the refining bleaching bath, dyeing The bath quality improving agent of the present invention may be additionally used in the processing bath. When the bathing quality improving agent of the present invention is used for refining bleaching processing and dyeing processing, generally, a dyeing machine generally used, that is, rope dyeing may be used. Color machine, liquid dyeing machine, cross-dyeing #, slave seven-in-one. Also, in the refining bleach bath or dye bath, the commonly used machine or organic chemicals or dyed 121587.doc 200811331 can be used. This kind of cold medium quality enhancer can be used for work, dyeing and adding... cotton, hemp, wool, / 哉, quasi-each bleaching plus labor, donating acid, and steel fiber (Bemb: 'net and other natural fibers, 嫘Polyurethane-based, polypropylene-based, synergistic fiber, polyester-based, nitrile-based material I 4 or less products in the bath quality improver: including cotton, 28 can be effectively used as a fiber product, or as (4) ==, = 维 工 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于 易于And the bath of the present invention is relative to the fiber The effect of the 丨 Ώ 、 中 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 When it is combined with the ester compound of the component (8) and the ester compound of the component (8), the compatibility with the agent used for refining the bleaching bath or the dyeing bath is not sufficient, and the refining property cannot be obtained. When a combination of an ester compound having a sufficient effect '·(B) component and a mercapto amber type I anionic surfactant of the component (C) is obtained, sufficient effect cannot be obtained in terms of wrinkle prevention and imparting hygiene to a soft person. When the combination of the amidoxime compound of the component A) and the succinic acid type anionic surfactant of the component (C) is insufficient, the stability of the product of the Luozhongkoubei k-solution or the stability of the treatment bath is not sufficient. The use of the components, the component (B), and the component (C) is coexisting, and the use of 4' is stable in the treatment, and exhibits excellent effects in flexibility and anti-allergy in the bath. It is generally considered that the reason is that the amidoxime-based compound of the (A) component 121587.doc 200811331 exhibits a cationic behavior, so the affinity for / Δ, 氺八芦, 对, therefore, the (A) component, (B) The composition and (c), the area m "" the amount of adsorbed material of the dimension is easy to be low E or large. The softening effect of the component (A) of 醯 醯 ' 醯 ^ t σ σ 优良 优良 优良 优良 优良 优良 优良 优良 优良 精 精 精 精 精 精 精 精 精 精 精 精 精 精 精 精 精 精 精 精 精 精 精 精 精 精 精 精 精 精&amp; 梁 梁 This is not suitable as a composition for the quality improvement agent in the bath used in refining bleaching and dyeing. In the present invention, the component (a) which is a compound of a specific structure,

(B) 成分及（C)成分用作必要成分，且較好的是調整彼等之 觸比，藉此，可兼具浴中柔軟性、防敵性以及與各種併 用藥劑或染料之相容性的相反性能。 以下，使用實施例及比較例來進一步說明本發明，但本 發明並不受該等例任何限制。再者，實施例、比較例中之 份及％分別表示質量份及質量〇/〇。 合成例1 將564份（2莫耳）之十八烯酸投入至反應容器中，於氮氣 流下加熱升溫至約100°C。於該溫度下添加1〇5份（1莫耳）之 二乙醇胺後，進而加熱升溫，於150〜16 0°C下使其、進行約4 小時之脫水反應，其後冷卻，以酸值9.0、總胺值ιι·〇獲得 黃褐色透明黏液狀酸胺系化合物（Α)成分。 合成例2 將400份（2莫耳）之十二酸投入至反應容器，於氮氣流下 加熱升溫至約1⑻°C。於該溫度下添加1〇5份（1莫耳）之二乙 醇胺後，進而加熱升溫’於15 〇〜16 〇 °c下使其進行約4小時 之脫水反應，其後冷卻，以酸值'14 ·0、總胺值15.0獲得黃 121587.doc -16- 200811331 白色固體之醯胺系化合物（A)成分。 合成例3 將564份（2莫耳）之十八烯酸投入至反應容器中，於氮氣 流下加熱升溫至約l〇〇°C。於該溫度下添加103份（1莫耳）之 一伸乙三胺後，進而加熱升溫，於150〜160°C下使其進行 約4小時之脫水反應，其後冷卻，以酸值9〇、總胺值 91.0、 三級胺值10 5獲得黃褐色固體之醯胺系化合物成 分。 合成例4 將282份（1莫耳）之十八烯酸投入至反應容器中，於氮氣 流下加熱升溫至約1〇&lt;rc。於該溫度下添加1〇4份（丨莫耳）之 月女乙基乙醇胺後，進而加熱升溫，於15〇〜16〇。〇下使其進 行約4小時之脫水反應，其後冷卻，以酸值7〇、總胺值 148.0、 三級胺值15 〇獲得黃褐色透明黏液狀醯胺系化合物 (A)成分。 合成例5 將192份（1莫耳）之偏苯三曱酸酐及536份莫耳）之十八 稀释投入至反應容器中，於氮氣流下加熱升溫，於 1 7 0〜1 8 0 C下使其進行約4小時之脫水反應，其後冷卻，以 酸值74.8獲得淡黃白色漿狀酯化物成分。 合成例6 將192份（1莫耳）之偏苯三曱酸酐及4〇〇份莫耳）之以碳 數為13之醇為主成分的合成醇投入至反應容器中，於氮氣 流下加熱升溫，於170〜18〇。〇下使其進行約4小時之脫水反 121587.doc 200811331 應，其後冷卻，以酸值92」獲得白色黏液狀之酿化物作）成 分。 合成例7 將192份（1莫耳）之無水檸檬酸及536份（2莫耳）之十八烯 醇投入至反應容器中，於氮氣流下加熱升溫，於 160〜170C下使其進行約4小時之脫水反應，其後冷卻，以 酸值58.3獲得淡黃白色漿狀酯化物成分。 合成例8 將98份（1莫耳）之順丁烯二酸酐、536份（2莫耳）之十八烯 醇及1.2份作為觸媒之對曱苯磺酸投入至反應容器中，於 氮氣流下加熱升溫，於155〜165〇c下使其進行約4小時之脫 水反應’其後冷卻，以酸值8.0獲得二酯化物。 將6 16伤4所付一酯化物及1 〇 5份之水、1 〇 5份之異丙醇 及105份之無水亞硫酸氫鈉投入至高壓反應容器中，於密 封系統中加熱升溫，於11〇〜115它下使其進行約5小時之磺 化反應反應結束後進行冷卻，脫氣後，於約8 〇 °C下添加 104份之水及64份之異丙醇，混合1〇〜2〇分鐘，其後冷卻， 以結合硫酸成分6·8、非揮發性成分約66%獲得淡黃白色漿 狀磺基琥珀酸型陰離子界面活性劑（c)成分。 合成例9 將98份（1莫耳）之順丁烯二酸酐、400份（2莫耳）的以碳數 為13之醇為主成分之合成醇以及1份作為觸媒之對曱苯磺 &amp;L 4又入至反應各器中，於氮氣流下加熱升溫，於 155〜165C下使其進行約4小時之脫水反應，其後冷卻，以 121587.doc 200811331 酸值12 · 9獲得二I旨化物。 將480份所獲得之二酯化物及82份之水、82份之異丙醇 及105份之無水亞硫酸氫鈉投入至高壓反應容器中，於密 封系統中加熱升溫，於110〜115°C下使進行約5小時之磺化 反應。反應結束後進行冷卻，脫氣後，於約8〇°C下添加88 份之水及55份之異丙醇，混合1〇〜20分鐘，其後冷卻，以 結合硫酸成分7.8、非揮發性成分約66%獲得白色軟聚狀磺 基琥珀酸型陰離子界面活性劑（C)成分。 實施例1 將12份之合成例1的（A)成分、8份之合成例5的⑻成 分、16份之合成例8的（C)成分及4份以碳數為13之醇為主 成分之合成醇的環氧乙烧9莫耳加成物投入至乳化容器 中，一面混合一面加熱升溫至8〇〇c。繼而，緩緩加入 伤約80 c之熱水後，於該溫度進行均質.處理，使其乳化。 其後冷卻至4(TC以下，以48%苛性鈉將？11值調整為約7〇, 以非揮發性成分約2,0%獲得白色黏液狀浴中品質提昇劑。 貫施例2〜12、比較例1〜5 除將（A)成分、（B)成分及（C)成分之種類及調配量變更為 2表1所示以外，以與實施例i相同之方式進行操作，獲得 實施例2〜！2、比較例1〜5之浴中品質提昇劑。 121587.doc * 19- 200811331 表1 (A)成分 (B)成分 (C)成分 調配量（質量份） 外觀 實施例1 合成例1 合成例5 合成例8 12:8:16 白色黏液狀 實施例2 合成例9 白色液狀 實施例3 合成例6 合成例8 白色黏液狀 實施例4 备成例9 白色液狀 實施例5 合成例7 合成例8 白色黏液狀 實施例6 合成例9 白色液狀 實施例7 合成例2 合成例6 合成例9 白色黏液狀 實施例8 合成例3 白色黏液狀 實施例9 合成例4 白色液狀 實施例10 合成例1 合成例6 合成例9 24 ： 6 ： 6 白色液狀 實施例11 6 ： 24 ： 6 白色液狀 實施例12 6 ： 6 ： 24 白色液狀 比較例1 合成例1 36 白色液狀 比較例2 合成例1 合成例6 18 ： 18 白色液狀 比較例3 合成例6 36 白色液狀 比較例4 合成例9 36 白色液狀 比較例5 合成例6 合成例9 18 ： 18 白色液狀(B) The component and the component (C) are used as essential components, and it is preferred to adjust their contact ratio, thereby providing flexibility in the bath, compatibility against the host, and compatibility with various concomitant agents or dyes. The opposite performance. Hereinafter, the present invention will be further described by way of Examples and Comparative Examples, but the present invention is not limited by the examples. Further, the parts and % in the examples and comparative examples represent the mass parts and the mass 〇/〇, respectively. Synthesis Example 1 564 parts (2 moles) of octadecenoic acid was placed in a reaction vessel, and the temperature was raised to about 100 ° C by heating under a nitrogen stream. After adding 1 part of 5 parts (1 mole) of diethanolamine at this temperature, the mixture was heated and heated, and subjected to a dehydration reaction at 150 to 160 ° C for about 4 hours, followed by cooling to an acid value of 9.0. The total amine value ιι·〇 obtained a yellow-brown transparent viscous acid amine compound (Α) component. Synthesis Example 2 400 parts (2 moles) of dodecanoic acid was placed in a reaction vessel, and the temperature was raised to about 1 (8) ° C under a nitrogen stream. After adding 1 〇 5 parts (1 mol) of diethanolamine at this temperature, the mixture was further heated to a temperature of '15 Torr to 16 ° C for about 4 hours of dehydration reaction, followed by cooling to an acid value' 14·0, total amine value 15.0 obtained yellow 121587.doc -16- 200811331 White solid amide compound (A) component. Synthesis Example 3 564 parts (2 moles) of octadecenoic acid was placed in a reaction vessel, and the temperature was raised to about 10 °C by heating under a nitrogen stream. After adding 103 parts (1 mole) of ethylenediamine to the temperature, the mixture was heated and heated, and subjected to a dehydration reaction at 150 to 160 ° C for about 4 hours, followed by cooling to an acid value of 9 Torr. A total amine value of 91.0 and a tertiary amine value of 10 5 gave a guanamine compound component as a tan solid. Synthesis Example 4 282 parts (1 mole) of octadecenoic acid was placed in a reaction vessel, and the temperature was raised to about 1 Torr &lt; rc under a nitrogen stream. After adding 1 part of 4 parts of the female ethyl ethanolamine at this temperature, the temperature was further raised to 15 Torr to 16 Torr. The mixture was subjected to a dehydration reaction for about 4 hours, and then cooled to obtain a yellowish brown transparent mucic amide compound (A) with an acid value of 7 Torr, a total amine value of 148.0, and a tertiary amine value of 15 Å. Synthesis Example 5 A mixture of 192 parts (1 mole) of trimellitic anhydride and 536 parts of moles was added to a reaction vessel, and the mixture was heated under a nitrogen stream to be heated at 170 to 180 ° C. This was subjected to a dehydration reaction for about 4 hours, followed by cooling to obtain a pale yellowish white esterified ester component with an acid value of 74.8. Synthesis Example 6 A synthetic alcohol containing 192 parts (1 mole) of trimellitic anhydride and 4 parts by mole of an alcohol having a carbon number of 13 as a main component was placed in a reaction vessel, and heated under a nitrogen stream. At 170~18〇. The underarm is allowed to undergo dehydration for about 4 hours. After that, it is cooled, and then it is cooled to obtain a white viscous brewing compound as an acid value of 92". Synthesis Example 7 192 parts (1 mole) of anhydrous citric acid and 536 parts (2 moles) of stearyl alcohol were placed in a reaction vessel, heated under a nitrogen stream, and subjected to about 4 at 160 to 170 C. The dehydration reaction was carried out for an hour, followed by cooling to obtain a pale yellowish white esterified ester component with an acid value of 58.3. Synthesis Example 8 98 parts (1 mole) of maleic anhydride, 536 parts (2 moles) of stearyl alcohol, and 1.2 parts of p-toluenesulfonic acid as a catalyst were placed in a reaction vessel under nitrogen. The mixture was heated under heating, and subjected to a dehydration reaction at 155 to 165 Torr c for about 4 hours. Thereafter, it was cooled, and a diesterified product was obtained at an acid value of 8.0. 6 16 wounds of 4 monoesters and 1 part of 5 parts of water, 1 part of 5 parts of isopropanol and 105 parts of anhydrous sodium hydrogen sulfite are put into a high pressure reaction vessel, and heated in a sealing system. 11〇~115, it is subjected to sulfonation reaction for about 5 hours, and then cooled. After degassing, 104 parts of water and 64 parts of isopropanol are added at about 8 ° C, and 1 〇 is mixed. After 2 minutes, it was cooled, and a pale yellowish white sulfosuccinic acid type anionic surfactant (c) component was obtained in combination with a sulfuric acid component of 6.8% and a nonvolatile component of about 66%. Synthesis Example 9 98 parts (1 mol) of maleic anhydride, 400 parts (2 mol) of a synthetic alcohol having a carbon number of 13 as a main component, and 1 part of p-toluenesulfonate as a catalyst &amp;L 4 was further introduced into the reaction apparatus, heated and heated under a nitrogen stream, and subjected to a dehydration reaction at 155 to 165 C for about 4 hours, followed by cooling to obtain a second I value at 121587.doc 200811331 acid value 12 · 9 Dedication. 480 parts of the obtained diesterified product and 82 parts of water, 82 parts of isopropyl alcohol and 105 parts of anhydrous sodium hydrogen sulfite are put into a high pressure reaction vessel, and heated in a sealing system at 110 to 115 ° C. The sulfonation reaction was carried out for about 5 hours. After the reaction is completed, the mixture is cooled. After degassing, 88 parts of water and 55 parts of isopropanol are added at about 8 ° C, mixed for 1 to 20 minutes, and then cooled to bind sulfuric acid component 7.8, non-volatile. A white soft polysulfosuccinic acid type anionic surfactant (C) component was obtained in about 66% of the composition. Example 1 12 parts of the component (A) of Synthesis Example 1, 8 parts of the component (8) of Synthesis Example 5, 16 parts of the component (C) of Synthesis Example 8 and 4 parts of the alcohol having 13 carbon atoms as a main component The 9-mole ethylene oxide addition product of the synthetic alcohol was placed in an emulsion container, and heated while heating to 8 〇〇c. Then, slowly add about 80 c of hot water, and then homogenize and treat at this temperature to emulsify. Thereafter, it was cooled to 4 (TC or less, adjusted to a value of about 7 以 with 48% caustic soda, and a white viscous bath quality improving agent with a non-volatile content of about 2, 0%. Example 2 to 12 Comparative Examples 1 to 5 Operations were carried out in the same manner as in Example i except that the types and the amounts of the components (A), (B) and (C) were changed to 2, and the examples were obtained. 2 to 2, the quality improving agent in the bath of Comparative Examples 1 to 5. 121587.doc * 19- 200811331 Table 1 (A) Component (B) Component (C) Component Formulation Amount (Part by mass) Appearance Example 1 Synthesis Example 1 Synthesis Example 5 Synthesis Example 8 12:8:16 White Mucilage Example 2 Synthesis Example 9 White Liquid Example 3 Synthesis Example 6 Synthesis Example 8 White Mucilage Example 4 Preparation Example 9 White Liquid Example 5 Synthesis Example 7 Synthesis Example 8 White Mucus Example 6 Synthesis Example 9 White Liquid Example 7 Synthesis Example 2 Synthesis Example 6 Synthesis Example 9 White Mucilage Example 8 Synthesis Example 3 White Mucilage Example 9 Synthesis Example 4 White Liquid Example 10 Synthesis Example 1 Synthesis Example 6 Synthesis Example 9 24 : 6 : 6 White liquid Example 11 6 : 24 : 6 Color liquid Example 12 6 : 6 : 24 White liquid Comparative Example 1 Synthesis Example 1 36 White liquid Comparative Example 2 Synthesis Example 1 Synthesis Example 6 18 : 18 White liquid Comparative Example 3 Synthesis Example 6 36 White liquid comparison Example 4 Synthesis Example 9 36 White liquid Comparative Example 5 Synthesis Example 6 Synthesis Example 9 18 : 18 White liquid

比較例6 將40份合成例6中所獲得之酯化物投入至混合容器中， 添加20份苯甲醇及140份之溫水進行混合授拌，成為均勻 白濁液狀。繼而，以48%苛性鈉將pH值調整為6.5，以藍白 色透明液狀獲得酯化物濃度為20%之浴中品質提昇劑。 評價試驗例1 使用所獲得之實施例1〜12、比較例1〜6之浴中品質提昇 劑，利用微型喷射式染色機，比較評償以假定精煉漂白加 工之處理方法進行處理時之布料的防皺性及柔軟性。 試驗方法1 被測布：增加密度棉織物原胚布（單、位面積重量210 g/m2) 121587.doc -20- 200811331 使用機器：微型喷射式染色機(Texam技研製造，布速70 m/分鐘） 試驗步驟： 精煉漂白：98^x30分鐘（升溫2°C/分鐘）（浴比1 : 20)Comparative Example 6 40 parts of the esterified product obtained in Synthesis Example 6 was placed in a mixing vessel, and 20 parts of benzyl alcohol and 140 parts of warm water were added and mixed and mixed to obtain a uniform white turbid liquid. Then, the pH was adjusted to 6.5 with 48% caustic soda, and a quality enhancer in the bath having an esterification concentration of 20% was obtained in a blue-white transparent liquid. Evaluation Test Example 1 Using the obtained bath quality improvers of Examples 1 to 12 and Comparative Examples 1 to 6, the fabric of the fabric was treated with a micro-jet dyeing machine to compare the treatments with the assumption of the refining bleaching treatment. Wrinkle resistance and softness. Test method 1 Fabric to be tested: increased density cotton fabric raw fabric (single and bit area weight 210 g/m2) 121587.doc -20- 200811331 Machine: Microjet dyeing machine (manufactured by Texam), cloth speed 70 m/ Minutes) Test procedure: Refining bleaching: 98^x30 minutes (2°C/min) (bath ratio 1: 20)

浴組成：雙氧水（35%) 5 g/LBath composition: hydrogen peroxide (35%) 5 g / L

苛性鈉 1 g/L 精煉劑（SUNMORLBH-6，日華化學（股）Caustic Soda 1 g/L Refining Agent (SUNMORLBH-6, Rihua Chemical Co., Ltd.)

製造） 2 g/LManufacturing) 2 g/L

雙氧水穩定劑（NEORATE PLC-2，Hydrogen peroxide stabilizer (NEORATE PLC-2,

曰華化學（股）製造） 1 g/L 金屬離子螯合劑（NEOCRYSTAL 1 70，曰华化学(股)) 1 g/L metal ion chelating agent (NEOCRYSTAL 1 70,

曰華化學（股）製造） 0.5 g/L曰华化学(股)制造) 0.5 g/L

浴中品質提昇劑 3 g/L 水洗：5分鐘χ3次 雙氧水中和：60°〇1〇分鐘（浴比1 : 20) 浴組成：雙氧水中和劑（CROAKS NT，Bath quality improver 3 g / L Washing: 5 minutes χ 3 times Hydrogen peroxide: 60 ° 〇 1 〇 minutes (bath ratio 1: 20) Bath composition: hydrogen peroxide agent (CROAKS NT,

曰華化學(股）製造） 2 g/L曰华化学(股)) 2 g/L

80%醋酸 0.5 g/L 水洗：5分鐘X 3次 脫水 風乾 評價： 以下述基準進行評價:之結果示於表2中。 防皺性：以目視判定處理布之褶皺“狀態。 121587.doc -21 · 200811331 〇：難以產生褶皺，褶皺數較少 △:稍微產生褶皺，褶皺數一般 χ:易於產生褶i，褶皺數較多 再者，將〇與△的中間等級記作〇△，將△與χ的中間等多 記作△&gt;&lt;。 柔軟性··以柔軟（5級）〜粗硬（1級）之5階段、及其中間等 級進行評價。 表2 防皺性 柔軟性 實施例1 〇 5 實施例2 〇 5 — 實施例3 〇 5 — _實施例4 〇 5 實施例5 〇△ 4-5 〜 實施例6 〇△ 4-5 〜 實施例7 〇△ 4 ^ 實施例8 〇 5 — _ 實施例9 實施例10 〇 5 — 〇 5 — _ 實施例1〗 〇Δ 4-5 _ 實施例12 〇Δ 4 — 比較例1 〇 5 一 _ 比較例2 〇Δ 4-5 ^ _ 比較例3 Δ ^ 3-4 _ 比較例4 △χ 3 ^ 比較例5 Δ 3-4 比較例6 Δ -----—---^ 4 _比較例7氺 X 180% acetic acid 0.5 g/L Water washing: 5 minutes X 3 times Dehydration Air drying Evaluation: Evaluation was performed on the following basis: The results are shown in Table 2. Wrinkle resistance: The state of the wrinkles of the treated cloth is visually judged. 121587.doc -21 · 200811331 〇: It is difficult to produce wrinkles, and the number of wrinkles is small △: wrinkles are slightly generated, and the number of wrinkles is generally χ: pleats are easily generated, and the number of wrinkles is relatively high. In addition, the intermediate level of 〇 and △ is denoted by 〇 Δ, and the middle of △ and χ is denoted as Δ &gt;&lt; Softness · · Soft (5 grades) ~ Rough (1 grade) 5 stages, and their intermediate grades were evaluated. Table 2 Wrinkle Resistance Softness Example 1 〇 5 Example 2 〇 5 - Example 3 〇 5 - _ Example 4 〇 5 Example 5 〇 △ 4-5 〜 Implementation Example 6 〇 Δ 4-5 〜 Example 7 〇 Δ 4 ^ Example 8 〇 5 - _ Example 9 Example 10 〇 5 - 〇 5 - _ Example 1 〇 Δ 4-5 _ Example 12 〇 Δ 4 - Comparative Example 1 〇 5 - Comparative Example 2 〇 Δ 4-5 ^ _ Comparative Example 3 Δ ^ 3-4 _ Comparative Example 4 Δχ 3 ^ Comparative Example 5 Δ 3-4 Comparative Example 6 Δ ---- -—---^ 4 _Comparative example 7氺X 1

*比較例7 :無浴中品質提昇劑 根據表2之試驗結果瞭解到，浴中品質提昇劑之防皺效 果與柔軟性有密切關係，自低溫區域的吸附活動優良、i 可賦予良好柔軟性的本發明之浴中品質提昇劑，在抑制精 121587.doc -22- 200811331 煉漂白加工1色加工步驟中最易產生褶皺之精煉漂白步 驟中的褶皺產生方面具有優良效果。因此，可藉由調整作 為必要成分而含有的3種化合物之調配比率或取代基，而 控制防皺性及柔軟性。 評價試驗例2 使用貫施例1〜12、比較例}〜6之浴中品質提昇劑，藉由 Colorpet染色機，進行比較評價以假設精煉漂白加工之處 理方法處理之際的質地的精煉性。 試驗方法2 試驗布：棉織物原胚布（單位面積重i18〇g/m2) 使用機器：Col〇rpet染色機（（股）Nissen製造） 試驗步驟：*Comparative Example 7: No bath quality improver According to the test results in Table 2, the anti-wrinkle effect of the quality enhancer in the bath is closely related to the softness, and the adsorption activity from the low temperature region is excellent, and i can impart good flexibility. The bath quality improving agent of the present invention has an excellent effect in suppressing wrinkle generation in the refining bleaching step which is most prone to wrinkles in the one-color processing step of the refining bleaching process of 121587.doc -22-200811331. Therefore, the wrinkle resistance and the flexibility can be controlled by adjusting the compounding ratio or the substituent of the three compounds contained as an essential component. Evaluation Test Example 2 Using the quality enhancer in the baths of Examples 1 to 12 and Comparative Examples ～6, the color paste dyeing machine was used for comparative evaluation to judge the refining property of the texture at the time of the processing of the refining bleaching process. Test method 2 Test cloth: cotton fabric raw fabric (unit weight i18〇g/m2) Machine: Col〇rpet dyeing machine (manufactured by Nissen) Test procedure:

精煉漂白：98°Cx30分鐘（升溫2°C/分鐘）(浴比1 : 15) 浴組成：雙氧水（35%) 5 g/LRefining bleaching: 98 ° C x 30 minutes (2 ° C / min) (bath ratio 1: 15) Bath composition: hydrogen peroxide (35%) 5 g / L

苛性鈉 1 g/L 精煉劑（SUNMORLBH-6，日華化學（股）Caustic Soda 1 g/L Refining Agent (SUNMORLBH-6, Rihua Chemical Co., Ltd.)

製造） 2 g/L 雙氧水穩定劑（NEORATE PLC-2，Manufacture) 2 g/L hydrogen peroxide stabilizer (NEORATE PLC-2,

曰華化學（股）製造） 1 g/L 金屬離子螯合劑（NEOCRYSTAL 1 70，曰华化学(股)) 1 g/L metal ion chelating agent (NEOCRYSTAL 1 70,

曰華化學（股）製造） 0.5 g/L曰华化学(股)制造) 0.5 g/L

浴中品質提昇劑 3 g/L 水洗·· 5分鐘χ 2次 雙氧水中和：60\&gt;10分鐘（浴比1 : 15) 121587.doc -23- 200811331Bath quality improver 3 g / L Wash · · 5 minutes χ 2 times Hydrogen peroxide: 60 \ &gt; 10 minutes (bath ratio 1: 15) 121587.doc -23- 200811331

浴組成：雙氧水中和劑(CROAKS NT，日華化學(股增造）2 g/L 80%醋酸 〇 5 g/L 水洗：5分鐘χ2次 脫水Bath composition: Hydrogen peroxide agent (CROAKS NT, Nikko Chemical Co., Ltd. 2 g/L 80% acetic acid 〇 5 g/L Washing: 5 minutes χ 2 times Dehydration

評價I 以下述基準進行評價之結果示於表3中。 白度：以測色機Minolta CM-3700d測定亨特白度 (brightness by Hunter) 〇 杂料擴展性：以目視判定將Levafj[X Briii Blue e-BRA之 1 /〇水/合液滴下1滴至試驗布時之滲透時間（秒）、及風乾後 之斑點部的擴展狀態。 〇：良好 △:普通 X :不良 再者，將0與△的中間等級記作〇△，將△與X的中間等級 記作A X。 121587.doc 24- 200811331 表3 白色度 染料擴展性 滲透時間 擴展狀態 實施例1 83.6 3 〇 實施例2 83.7 2 〇 實施例3 83.6 3 〇 實施例4 83.7 2 〇 實施例5 83.6 3 〇 實施例6 83,7 2 〇 實施例7 83.5 4 〇 實施例8 83.2 4 〇 實施例9 83.4 2 〇 實施例10 83.5 6 〇△ 實施例11 83.7 2 〇 實施例12 83.7 2 〇 比較例1 81.7 31 △ X 比較例2 82.1 12 Δ 比較例3 83.8 2 〇 比較例4 83.9 2 〇 比較例5 83.8 2 〇 比較例6 82.7 6 〇Δ 比較例7氺 84.0 2 〇 *比較例7 :無浴中品質提昇劑 根據表3之試驗結果可確認，本發明之浴中品質提昇劑 對用於精煉漂白浴中時之加工布的精煉性影響較少。其結 果表明，本發明之浴中品質提昇劑並不阻礙精煉漂白加工 原本之目的即去除原胚布中所含雜質的作用，且可賦予良 好防皺牲、柔軟性，因此不會產生精煉斑或下一步驟之染 色加工中的染色斑等問題。 評價試驗·例3 使用實施例1〜12、比較例1〜6之浴中品質提昇劑，對在Evaluation I The results of evaluation based on the following criteria are shown in Table 3. Whiteness: Brightness by Hunter is measured by the color measuring machine Minolta CM-3700d. The extensibility of the impurities is determined by visual inspection. 1 drop of Levafj [X Briii Blue e-BRA 1 / 〇 water / combined drop The penetration time (seconds) to the test cloth and the expanded state of the spot portion after air drying. 〇: Good △: Normal X: Bad Again, the intermediate level of 0 and Δ is denoted as 〇Δ, and the intermediate level of △ and X is denoted as A X . 121587.doc 24-200811331 Table 3 Whiteness dye extended penetration time expansion state Example 1 83.6 3 〇 Example 2 83.7 2 〇 Example 3 83.6 3 〇 Example 4 83.7 2 〇 Example 5 83.6 3 〇 Example 6 83, 7 2 〇 Example 7 83.5 4 〇 Example 8 83.2 4 〇 Example 9 83.4 2 〇 Example 10 83.5 6 〇 △ Example 11 83.7 2 〇 Example 12 83.7 2 〇 Comparative Example 1 81.7 31 △ X Comparison Example 2 82.1 12 Δ Comparative Example 3 83.8 2 〇 Comparative Example 4 83.9 2 〇 Comparative Example 5 83.8 2 〇 Comparative Example 6 82.7 6 〇 Δ Comparative Example 7 氺 84.0 2 〇 * Comparative Example 7 : No Bath Quality Enhancer According to Table As a result of the test of 3, it was confirmed that the quality enhancer in the bath of the present invention has less influence on the refining property of the processed cloth used in the refining bleach bath. The results show that the quality enhancer in the bath of the present invention does not hinder the original purpose of the refining bleaching process, that is, the effect of removing impurities contained in the original fabric, and can impart good anti-wrinkle and softness, so that no refining spots are generated. Or problems such as stain spots in the dyeing process of the next step. Evaluation Test Example 3 Using the bath quality improving agents of Examples 1 to 12 and Comparative Examples 1 to 6,

121587.doc -25- 200811331 假定精煉漂白處理方法之鹼性條件下的穩定性進行比較評 價。 試驗方法3 使用機器:Colorpet染色機（（股）Nissen製造） 試驗步驟： 於Colorpet染色機用染槽中製備300 mL之下述2種試驗121587.doc -25- 200811331 It is assumed that the stability under alkaline conditions of the refining bleaching treatment method is comparatively evaluated. Test method 3 Machine: Colorpet dyeing machine (manufactured by Nissen) Test procedure: Prepare 300 mL of the following two tests in a dyeing tank for Colorpet dyeing machine

浴組成1 :雙氧水（35%) 5 g/LBath composition 1: hydrogen peroxide (35%) 5 g/L

苛性鈉 1 g/LCaustic soda 1 g/L

精煉劑（SUNMORL BH-6，曰華化學 (股）製造） 2 g/L 雙氧水穩定劑（NEORATE PLC-2，Refining agent (SUNMORL BH-6, manufactured by Yuhua Chemical Co., Ltd.) 2 g/L hydrogen peroxide stabilizer (NEORATE PLC-2,

曰華化學（股）製造） 1 g/L 金屬離子螯合劑（NEOCRYSTAL 170，曰华化学(股)) 1 g/L metal ion chelating agent (NEOCRYSTAL 170,

曰華化學（股）製造） 0.5 g/L曰华化学(股)制造) 0.5 g/L

浴中品質提昇劑 .3 g/LBath quality improver .3 g/L

浴組成2 :雙氧水（35%) 10 g/LBath Composition 2: Hydrogen peroxide (35%) 10 g/L

苛性鈉 2 g/LCaustic soda 2 g/L

精煉劑（SUNMORL BH-6，曰華化學 (股）製造) 2 g/L 雙氧水穩定劑（NEORATE PLC-2， 曰華化學（股)製造） 1 g/L 金屬離子螯合劑（NEOCRYSTAL 170， 121587.doc -26- 200811331 0.5 g/L 3 g/L ，一邊自40°C 精煉漂白條 之5 A過濾紙 目視判定過渡 曰華化學（股）製造） 浴中品質提昇劑 一面以Colorpet染色機之支架衝擊試驗浴 以2°C/分鐘升溫，於98°C保持30分鐘（假定 件）。冷卻至40°C後，以預先染色為黑色 (ADVANTEC製造）過濾試驗浴，以下述基準Ί 狀態。結果示於表4中。 〇 :無過濾殘渣 A :稍有過濾殘渣 x :過濾殘渣較多 X的中間等級 再者，將〇與△的中間等級記作〇 A，將A與 記作Ax。 表4 過濾狀態 浴組成1 浴組成2 實施例1 〇Δ 〇Δ 實施例2 〇 〇 實施例3 〇△ 〇Δ 實施例4 〇 ο 實施例5 〇Δ 〇Δ 實施例6 〇 〇 實施例7 〇 〇 實施例8 〇Δ 〇Δ 實施例9 〇Δ ο Δ 實施例10 〇Δ 〇△ 實施例11 〇 〇 實施例12 〇 〇 比較例1 X X 比較例2 Δ Αχ 比較例3 〇Δ 〇Δ 比較例4 〇Δ 〇Δ 121587.doc -27- 200811331 評價試驗例4 使用實施例1〜12、比較例1〜6之浴中品質提昇劑，以使 疋反應染料之染色處理方法的條件，對染科分散性進行 較評價。 試驗方法4Refining agent (SUNMORL BH-6, manufactured by Yuhua Chemical Co., Ltd.) 2 g/L hydrogen peroxide stabilizer (NEORATE PLC-2, manufactured by Yuhua Chemical Co., Ltd.) 1 g/L metal ion chelating agent (NEOCRYSTAL 170, 121587 .doc -26- 200811331 0.5 g/L 3 g/L, 5 A filter paper from 40 ° C refining bleaching strip visually judged the transition of Huanhua Chemical Co., Ltd.) The quality enhancer in the bath is colored with Colorpet dyeing machine The stent impact test bath was warmed at 2 ° C/min and held at 98 ° C for 30 minutes (hypothetical piece). After cooling to 40 ° C, the test bath was filtered in a black color (manufactured by ADVANTEC), and the following conditions were used. The results are shown in Table 4. 〇 : No filter residue A : Slightly filtered residue x : Filter residue is large X Intermediate level In addition, the intermediate level of 〇 and △ is denoted as 〇 A, and A and A are denoted as Ax. Table 4 Filtration State Bath Composition 1 Bath Composition 2 Example 1 〇Δ 〇Δ Example 2 〇〇Example 3 〇Δ 〇Δ Example 4 〇ο Example 5 〇Δ 〇Δ Example 6 〇〇Example 7 〇 〇 Example 8 〇Δ 〇 Δ Example 9 〇Δ ο Δ Example 10 〇Δ 〇 △ Example 11 〇〇 Example 12 〇〇 Comparative Example 1 XX Comparative Example 2 Δ Αχ Comparative Example 3 〇Δ 〇 Δ Comparative Example 4 〇Δ 〇Δ 121587.doc -27- 200811331 Evaluation Test Example 4 The bath quality improving agents of Examples 1 to 12 and Comparative Examples 1 to 6 were used to prepare the dyeing treatment method for the ruthenium reaction dye. The dispersion was evaluated. Test method 4

使用機器：Colorpet染色機（(股）Nissen製造） 試驗步驟： 於Colorpet染色機用染槽中製備3〇〇 mL之試驗浴。 浴組成：反應染料Machine: Colorpet dyeing machine (manufactured by Nissen) Test procedure: A 3 〇〇 mL test bath was prepared in a dyeing tank for a Colorpet dyeing machine. Bath composition: reactive dye

1 g/L 5〇 g/L1 g/L 5〇 g/L

20 g/L20 g/L

比較例5 〇Δ 〇Δ 比較例6 〇Δ 〇Δ 比較例7氺Ί ο 〇 氺比較例7 :無浴中品質提昇劑 (Sumifix supra Blue BRF 150% gran) 芒硝 蘇打灰 浴中品質提昇劑Comparative Example 5 〇Δ 〇Δ Comparative Example 6 〇Δ 〇Δ Comparative Example 7氺Ί ο 〇 氺Comparative Example 7: No bath quality improver (Sumifix supra Blue BRF 150% gran) Glauber's salt Soda ash Bath quality improver

3 g/L 一面以c〇1〇rpet染色機之支架衝擊試驗浴，一邊自赋 以2°C/分鐘升 &gt;盈，於机保持⑼分鐘（經過5分鐘時投入蘇 打灰，假定反應染料之染色條件）。冷卻至贼後，以Μ 過濾紙（ADVANTEC製造）過濾試驗 、观冷，u下迷基準目視判 定過濾狀態。結果示於表5。 〇 :無染料斑點 A :稍有染料斑點 X :染料斑點較多 121587.doc •28- 200811331 再者，將◦與A的中間等級記作〇A，將A與x的中間等級 記作Ax。 表53 g/L side with c〇1〇rpet dyeing machine bracket impact test bath, while self-giving 2 ° C / min liters, hold on machine for (9) minutes (after 5 minutes, put soda ash, assuming reactive dye Dyeing conditions). After cooling to the thief, the filter paper (made by ADVANTEC) was used to filter the test, and the cold was observed. The results are shown in Table 5. 〇 : No dye spots A : Slightly dye spots X : Dye spots are more 121587.doc •28- 200811331 Furthermore, the intermediate level of ◦ and A is denoted as 〇A, and the intermediate level of A and x is denoted as Ax. table 5

過濾狀態 實施例1 〇Δ 實施例2 〇 實施例3 〇Δ 實施例4 0 實施例5 〇Δ 實施例6 〇 實施例7 0 實施例8 ο Δ 實施例9 〇Δ 實施例10 • Δ 實施例11 〇 實施例12 〇 比較例1 X 比較例2 Δχ 比較例3 〇Δ 比較例4 〇Δ 比較例5 〇Δ 比較例6 〇△ 比較例7* 〇 氺比較例7 :無浴中品質提昇劑 根據表4及表5之試驗結果瞭解到，本發明之浴t品質提 昇劑於鹼性條件下之精煉漂白加工浴中，於芒硝、鹼存在 下之染料的相容性（染色浴）優良。因此，可籍由調整作為 必要成分而含有之3種化合物的調配比率及取代基，而控 制與精煉漂白加工浴、染色加工浴中所假定使用之各種併 用藥劑或染料的相容性。 121587.doc -29- 200811331 根據土述評價試驗例1〜4之結果可確認，本發明之浴中 品質提昇劑賦予精煉漂白加工、染色加工時之防鈹性、柔 軟性之效果較好，且與精煉漂白加工、染色加工中所使用 之各種併用藥劑及染料的相容性優良。又，可藉由調整作 為本發明之浴中品質提昇劑的必要成分而含有之3種化合 物的調配比率及取代基，而兼具先前較困難之防皺性、柔 軟性’及與各種併用藥劑及染料的相容性之相反性能。Filtration State Example 1 〇 Δ Example 2 〇 Example 3 〇 Δ Example 4 0 Example 5 〇 Δ Example 6 〇 Example 7 0 Example 8 ο Δ Example 9 〇 Δ Example 10 • Δ Example 11 〇 Example 12 〇 Comparative Example 1 X Comparative Example 2 Δχ Comparative Example 3 〇Δ Comparative Example 4 〇Δ Comparative Example 5 〇Δ Comparative Example 6 〇Δ Comparative Example 7* 〇氺Comparative Example 7: No bath quality improving agent According to the test results of Tables 4 and 5, it is understood that the bath t quality enhancer of the present invention is excellent in compatibility (dye bath) in the presence of Glauber's salt and alkali in the refining bleaching bath under alkaline conditions. Therefore, it is possible to control the compatibility with various chemicals or dyes assumed to be used in the refining bleaching processing bath and the dyeing processing bath by adjusting the compounding ratio and the substituent of the three kinds of compounds contained as essential components. 121587.doc -29-200811331 According to the results of the soil evaluation test examples 1 to 4, it was confirmed that the quality enhancer in the bath of the present invention imparts an effect of preventing smudging and softening during refining bleaching and dyeing processing, and It has excellent compatibility with various co-agents and dyes used in refining bleaching and dyeing. Moreover, by adjusting the compounding ratio and the substituent of the three kinds of compounds which are essential components of the quality improving agent in the bath of the present invention, it is possible to have both the previously difficult wrinkle resistance and flexibility, and various concomitant agents. And the opposite performance of the compatibility of the dye.

[產業上之可利用性] 本‘明之浴中品質提昇劑，抑制習知浴中品質提昇劑所 …、法獲得的精煉漂白加工、染色加工步驟中之褶皺產生的 效果優良。利用本發明之浴中品質提昇劑，不僅可防止染 巧步驟中之纖維損傷，並且可防止由處理浴中所產生 之槽皺而引起的不均染、缝製品變形，可獲得高品位之染 色加工品。又，因於精煉漂白加工浴、染色加工浴中之防 、、文果k良，故不需要降低浴中之加工纖維量、降低布 、—+低冷卻速度等加工條件方面的習知防皺對策，因此 可貫現生產性、生產效率之提高。 致:用於各種纖維材料之精煉漂白加工、染色加工中，尤 纖棉、嫘縈及麻為代表之纖維素系纖維材料及其混紡 、截維材料，該等材料因 、九 U檟煉你白加工、杂色加工時所產生 袼皺而難以進行加工品位管理[Industrial Applicability] The effect of the wrinkle in the refining bleaching process and the dyeing process obtained by the method of suppressing the quality enhancer in the bath is excellent. By using the quality enhancer in the bath of the invention, not only the fiber damage in the dyeing step can be prevented, but also the uneven dyeing caused by the wrinkles generated in the treatment bath and the deformation of the sewing product can be prevented, and the high-grade dyeing can be obtained. Processed products. Moreover, since it is good in the refining bleaching processing bath, the dyeing processing bath, and the good result, it is not necessary to reduce the amount of processed fibers in the bath, and to reduce the conventional wrinkle resistance in terms of processing conditions such as cloth, low cooling rate, and the like. Countermeasures, so that productivity and productivity can be improved. To: used in the refining bleaching processing and dyeing processing of various fiber materials, especially the cellulosic fiber materials represented by cotton, enamel and hemp, and their blended and cut-off materials. These materials are used to smelt you. White processing, variegated processing, wrinkles and difficult processing quality management

121587.dOC •30-121587.dOC •30-

Claims (1)

200811331 十、申請專利範圍： 1 · 一種纖維加工用之浴中品質提昇劑，其特徵在於··含有 下述(A)、（B)及（C)， (A) ··選自下述通式（1)、（2)及（3)所表示之醯胺系化合 » 物之群中的至少一種， • 〆 C 2 Η 4 〇 R ’ RCON ⑴ ' C 2 Η 4 〇 Η RC〇NHC2H4NHC2H4NHR， ( 2 ) _ Rc〇NHC2H4NHC2H4〇R， ( 3 ) (上式中，R表示碳數為9〜23之直鏈或支鏈烷基或烯 基，R’表示或-COR”（其中，R”表示碳數為9〜23之直鏈 或支鏈烷基或烯基））； (B) ·選自由包含3元以上之多元羧酸的單或二烧基酯 石物以及單或一烯基S旨化合物所組成之群中的至少 一種（其中，該等之烷基或烯基可為直鏈或支鏈，其碳數 為 8〜24); (C) :選自下述通式（4)所表示之磺基琥珀酸型陰離子 界面活性劑的群中的至少一種， 'ψ R1〇co—^ R2〇CO-CH-S〇.3X (4) (上式中’ R1及R2分別表示碳數為卜24之直鏈或支鍵燒 基或烯基，X表示_Na、、倘或炫醇胺基）。 @长項1之冷中品質提昇劑，其含有卜2〇質量％之上述 ()1 30貝里％之上逑（Β)、及υο質量％之上述（c) 〇 121587.doc 200811331 3. -種精煉漂白加工方法，其特徵在於：以含有 1或2之浴中品質提昇劑的處理浴來精煉漂白加工=項 料。 ^纖維材 4. -種染色加工方法’其特徵在於：以含有如請 之浴中品質提昇劑的處理浴來染色加工纖維材料或2200811331 X. Patent application scope: 1 · A bath quality improving agent for fiber processing, characterized in that it contains the following (A), (B) and (C), (A) ·· At least one of the group of the indoleamine compounds represented by the formulas (1), (2), and (3), • 〆C 2 Η 4 〇R ' RCON (1) ' C 2 Η 4 〇Η RC〇NHC2H4NHC2H4NHR, ( 2 ) _ Rc 〇 NHC2H4NHC2H4 〇 R, ( 3 ) (In the above formula, R represents a linear or branched alkyl or alkenyl group having a carbon number of 9 to 23, and R' represents or -COR" (wherein R) a linear or branched alkyl or alkenyl group having a carbon number of 9 to 23); (B) selected from a mono or dialkyl esterite containing a polyvalent carboxylic acid of 3 or more and a mono- or monoalkenyl group At least one of the group consisting of the compounds (wherein the alkyl or alkenyl group may be a straight or branched chain having a carbon number of 8 to 24); (C): selected from the following formula ( 4) at least one of the group of sulfosuccinic acid type anionic surfactants represented, 'ψ R1〇co—^ R2〇CO-CH-S〇.3X (4) (in the above formula, 'R1 and R2 respectively Indicates that the carbon number is a straight chain or branch of A bond or an alkenyl group, and X represents a _Na, if or a oleylamine group. @长项1's cold medium quality enhancer, which contains the above-mentioned ()1 30% of the above 逑(Β), and υο质量% of the above (c) 〇121587.doc 200811331 3. A refining bleaching processing method characterized in that a bleaching process = a material is refined in a treatment bath containing a quality enhancer in a bath of 1 or 2. ^Fiber material 4. - A method for dyeing processing' is characterized in that the fiber material is dyed by a treatment bath containing a quality enhancer in the bath such as 2 121587.doc -2- 200811331 七、指定代表圖： (一) 本案指定代表圖為：（無） (二) 本代表圖之元件符號簡單說明： ⑩ 八、本案若有化學式時，請揭示最能顯示發明特徵的化學式： (無）121587.doc -2- 200811331 VII. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbol of the symbol of the representative figure is simple: 10 VIII. If there is a chemical formula in this case, please reveal the best Chemical formula showing the characteristics of the invention: (none) 121587.doc121587.doc
TW096120634A 2006-08-22 2007-06-08 In-bath quality enhancing agent for fiber processing and method of processing TW200811331A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102191683A (en) * 2010-03-15 2011-09-21 日华化学株式会社 Bath quality promoter for processing fibers and processing method
TWI688606B (en) * 2015-04-23 2020-03-21 日商聖諾普科股份有限公司 Dissolving pulp composition and method for manufacturing mucus

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DE3601856A1 (en) * 1986-01-23 1987-07-30 Henkel Kgaa TEXTILE TREATMENT AGENTS
JPH02251676A (en) * 1989-03-21 1990-10-09 Yushiro Chem Ind Co Ltd Softening and smoothing agent composition for fiber
JP2506276B2 (en) * 1991-04-03 1996-06-12 三洋化成工業株式会社 Softening agent for fibers
JPH06192975A (en) * 1992-12-24 1994-07-12 Senka Kk Agent capable of imparting improvement in quality in bath and softness in dyeing and finishing cellulosic fiber and its blended yarn interwoven product
JP3712384B2 (en) * 2002-07-22 2005-11-02 三洋化成工業株式会社 Softener composition
EP2796163A4 (en) * 2011-12-21 2015-05-20 Terumo Clinical Supply Co Ltd Subcutaneously implanted device for injecting drug solution

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102191683A (en) * 2010-03-15 2011-09-21 日华化学株式会社 Bath quality promoter for processing fibers and processing method
TWI688606B (en) * 2015-04-23 2020-03-21 日商聖諾普科股份有限公司 Dissolving pulp composition and method for manufacturing mucus

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