200810797 九、發明說明： 【發明所屬之技術領域】 本發明係有關於一種除臭裝置，更 —種應用；u 之係有關於 、谷置物中之光觸媒除臭裝置。 【先前技術】 產生里Γ於長期使用下’因為低溫儲放各種食物而容易且 之新鮮ΐ。’若不加以清除’容易影響儲藏於冰箱中之食物 傳Hx清洗冰箱内部的方式來去除臭味， ==食物取出、插頭拔除，且於清洗後心 、、主後才可正常使用’而使得—般使用者較不願意去 箱，況^ ’冰箱即使經過清理後内部之異味仍然益 ^全>肖除’因此，各式應用於冰箱之除臭產品應運而生， 炭、以及芳香劑等，其中由於芳香劑容易污染冰 相内。卩存放的食品而不利於一般家庭應用。 以使用活性炭為例，由於活性炭本身具有吸臭之功效 而達除臭作用，惟—但吸臭飽和即無法使用而必須丢棄二 且更新’對於使用者而言不僅耗費成本，亦有違環保概念， :然目前化工業已開發飽和活性炭的再生特殊處理，但是 二全無法提供家庭使用，對於一般使用者而言反倒是增加 頜外的成本與不便。例如加熱再生法可以將活性炭的吸附 能力，復9G%左右，但是需將使料的活性炭長途運輸到 f生厌生產廠豕，再生成本較咼，加上磨損和高溫再生時 的燒失，活性炭會損失近1 〇 % ’其應用受到相當的局限性。 19740 5 200810797 * \ 再利如化學藥品再生法和電化學再生法均{根據活性炭吸 附物貝的不同，利用反應產物在一定條件下易脫附的特點 選擇不同的化學藥品和不同的工藝使吸附質與之反應，使 活性厌彳寸以再生，其再生效率較低，只能達到〜兀％， 但使用比較方便，應用較多，但是這種再生法會帶來第二 次污染，同樣使其應用受到限制。 近年來使用光觸媒來進行殺菌、除臭、與表面清潔已 愈趨普遍，光觸媒是-種利用光能進行催化反應的觸媒， .一般係在物品原财混合光觸媒材料後-體成&，再透過 光能㈣動，使光觸媒材料與附著在物體表面的有害物質 產生氧化或還原作用，以達到除污、殺菌、抑菌或使物體 表面清潔的目的。適合作為光觸媒的材料如氧化鋅 …(^、二氧化鈦^叫卜二氧化錫^叫卜硫化飙⑽） 之中又以一氧化鈦的氧化還原力較強，並具有化學性 穩定，、對環境無害、材料取得容易等優勢，因此，目前使 用的光觸媒材料大多以二氧化鈦為主。 目前各式光觸媒均必須要由32電子伏特（ev)以上 的3激發方能啟動氧化還原之功能，32電子伏特相當 於波長380奈米（nm )以下的紫外線，f ^ ^ λα - ^ , , 身、即踝，而某些使用於室内 純的谷置物並無法接受如此等同陽光含量的紫外線照 =、’特別例如冰箱、櫥#等經常性昏暗的環境中，更不可 月匕透過光此進行催化反應，因此 + U此奴將先觸媒應用於例如冰 相或橋樞中來進行除臭，首先 ㈣私自__困難即是無法藉由光 線激么先觸媒’亦即光觸媒應用於例如冰箱或橋樞中時無 19740 6 200810797 法產生任何有關除污、殺菌、抑 效’除非❹者更換 ^以面清潔的功 I、、耗費的成本遠高於㈣A量活 i仁疋 效益。 人的知值而不符經濟 外，二氧化鈦雖然於分解有害物 能，但是二氧化鈦對 且-有卓越的功 而佔处 丞材亦具有破壞的作用， 于二氧化鈦之功效仍在’卻 壞而無法繼續使用。 勹岍咐者基材的損 因此，如何改善以上種種缺點，進而提供 用於各種容置物中；隹广队白 種传以適 除臭梦罟，火入 每保鮮之光觸媒 μ為㊣5亟待思考之課題。 【發明内容】 雲於以上所述習知技術之缺點，本發明之-目的在於 提供一種可於容置物中進杆 # ; 進仃除六、亚了重稷使用之光觸媒除 昊裝置。 本發明之另一目的為提供一種光觸媒除臭裝置，可應 用於昏暗之容置物中主動吸附有害物質。 本心明之又一目的為提供一種光觸媒除臭裝置，俾具 有南度财用性。 為達上揭目的，本發明提供一種光觸媒除臭裝置，供 應用於一容置物中進行除臭，係包括：載件，具有用以吊 掛於該容置物之吊掛部；以及除臭本體，結合至該載件， 且表面覆蓋含有披覆磷灰石之光觸媒材料，俾可藉該磷灰 石吸附該容置物中之有害物質，並可透過光能照射該光觸 7 19740 200810797 * Υ 媒材料而予以分解淨化。 之你14 I亥載件係可為局部或完全包覆該除臭本體外部 於一ν土t】如選自紙板、塑膠板、壓克力板之其中—者。 二=貫施例中，該載件係可為完全包覆該除臭本體外 1兩侧具有開口以及對應覆蓋該開口之 二Γ選擇性地大部外露該除臭本體之二表面，心吊 2:::史於該遮擔片上。該吊掛部係可為設於該遮擋片上200810797 IX. Description of the Invention: [Technical Field] The present invention relates to a deodorizing device, and more particularly to a photocatalyst deodorizing device in a grain storage. [Prior Art] It is easy and fresh because of the low temperature storage of various foods. 'If you don't remove it', it is easy to affect the way the food stored in the refrigerator passes Hx to clean the inside of the refrigerator to remove the odor. == Food removal, plug removal, and after cleaning, the heart can be used normally after the main one. Ordinary users are less willing to go to the box, the situation ^ 'The refrigerator even after cleaning the internal odor is still good ^ full> Xiao Di' Therefore, all kinds of deodorant products applied to the refrigerator came into being, charcoal, and fragrance Etc., because the fragrance is easy to contaminate the ice phase.卩 Stored food is not conducive to general household applications. Taking activated carbon as an example, since activated carbon itself has the effect of odor absorption and deodorization, but the absorption of odor is unusable and must be discarded and updated, it is not only costly for the user, but also contrary to the concept of environmental protection. However, the current chemical industry has developed a special treatment for the regeneration of saturated activated carbon, but the second can not provide home use, but for the average user is to increase the cost and inconvenience of the jaw. For example, the heating regeneration method can increase the adsorption capacity of activated carbon by about 9G%, but it is necessary to transport the activated carbon for long-distance transportation to the production plant, and the regeneration cost is relatively high, plus the loss of burning during burning and high-temperature regeneration, activated carbon. There will be a loss of nearly 1%. 'The application is subject to considerable limitations. 19740 5 200810797 * \ Re-rule chemical regeneration method and electrochemical regeneration method are different according to the characteristics of activated carbon adsorbent shell, using the characteristics of the reaction product to be easily desorbed under certain conditions to select different chemicals and different processes to make adsorption The quality reacts with it, so that the activity is reversible for regeneration, and its regeneration efficiency is low, which can only reach ~兀%, but it is convenient to use and has many applications, but this regeneration method will bring about the second pollution, also make Its application is limited. In recent years, the use of photocatalysts for sterilization, deodorization, and surface cleaning has become more and more common. Photocatalysts are catalysts that use light energy to carry out catalytic reactions. Generally, they are used in the original mixed-source photocatalyst materials. Through the movement of light energy (four), the photocatalyst material and the harmful substances attached to the surface of the object are oxidized or reduced to achieve the purpose of decontamination, sterilization, bacteriostatic or clean the surface of the object. Suitable materials for photocatalysts such as zinc oxide...(^, TiO2, 二 二 二 ^ ^ ^ ^ 飙 飙 飙 飙 飙 飙 飙 飙 飙 飙 飙 飙 飙 飙 飙 一 一 一 一 一 一 一 一 一 一 一 一 一 一 一 一 一 一 一 一 一 一 一The advantages of materials are easy to obtain. Therefore, most of the photocatalyst materials currently used are mainly titanium dioxide. At present, all kinds of photocatalysts must be activated by 3 excitations above 32 electron volts (ev) to activate redox. 32 electron volts is equivalent to ultraviolet light below 380 nm (nm), f ^ ^ λα - ^ , , The body, that is, the sputum, and some of the purely indoor grain storage used in the room can not accept the ultraviolet light of such equivalent sunlight content, 'specially such as refrigerator, cabinet # and other often dim environment, it is not possible to pass through the light Catalytic reaction, so + U this slave will be used in the first phase of the catalyst for deodorization, for example, in the ice phase or bridge. First, (4) privately, __the difficulty is that it cannot be stimulated by the light, that is, the photocatalyst is applied to, for example, photocatalyst. In the refrigerator or bridge pivot, there is no 19740 6 200810797 law to produce any decontamination, sterilization, and inhibition. 'Unless the person replaces the surface to clean the surface I, the cost is much higher than (4) A quantity of live benefits. Although the value of human beings does not conform to the economy, although titanium dioxide decomposes harmful substances, titanium dioxide has a detrimental effect on the work of the coffin, and the effect of titanium dioxide is still 'bad but cannot continue to use. . Therefore, the damage of the substrate of the latter is improved, and the above various shortcomings are provided, and thus it is provided for use in various contents; the white group of the 隹广队 is transmitted to the deodorant nightmare, and the light photocatalyst for each preservation is positive. Question. SUMMARY OF THE INVENTION Clouds are a disadvantage of the above-mentioned prior art, and it is an object of the present invention to provide a photocatalyst removing device that can be used in a container for loading and unloading. Another object of the present invention is to provide a photocatalyst deodorizing device which can be applied to actively absorb harmful substances in a dark container. Another object of the present invention is to provide a photocatalyst deodorizing device which has a southerly property. In order to achieve the above object, the present invention provides a photocatalyst deodorizing device for supplying deodorization in a container, comprising: a carrier having a hanging portion for hanging on the container; and a deodorizing body Bonding to the carrier, and covering the surface with a photocatalyst material containing apatite, the apatite can be used to adsorb harmful substances in the container, and the light can be irradiated by light energy. 7 19740 200810797 * Υ The material is decomposed and purified. The 14 I hai carrier may be partially or completely coated on the exterior of the deodorizing body, such as selected from cardboard, plastic sheets, and acrylic sheets. In the second embodiment, the carrier may be a cover that completely covers the deodorant body, and has two openings on both sides of the body and correspondingly covering the opening, selectively exposing the two surfaces of the deodorizing body. 2::: History is on the cover sheet. The hanging portion can be disposed on the shielding piece
該吊掛部係可_側連設於該遮擋片，且S .:之吊二！ 吊掛部之複數開口。較佳地，該遮播片 係可藉由可撕式虛線與該開口邊緣相連，另 縫^遮擋片於該可撕式虛線之相對兩端復可具有延伸裂 載件in擔片之相對兩侧係可藉由可撕式虛線與該 != 口邊緣相連’因此於該遮擔片未撕離該載件之 :，：：：係可形成完全包覆該除臭本體之型式，故可充 = 褒’而無須另外設置外包裝。此外，該載 面设可印製有關於該除臭裝置光觸 不，例㈣自使用說明、商標之至少一者。 置之心 冰箱Π物可為冰箱或衣櫃等，而該吊掛部則可吊掛於 / 蛋#、飲料架、或是吊掛在衣櫃中的衣架捍等。 e亥除臭本體係為選自紙、布、不織布、壓克力、托 樹脂之其中一種基材。該含有披覆鱗灰石 =觸媒材料係可由水溶液乾燥化而成薄膜者，其中，該 7命液係可具有丙烯酸樹脂㈣咖㈣n)、以及外表披覆 19740 8 200810797 Λ > 磷灰石（Cal0(PO4)6(OH)2)之光觸媒化合物，較佳地， 该光觸媒化合物係可選自二氧化鈦（Ti〇2 )、氧化辞 (ZnO)、二氧化錫（Sn〇2)、以及硫化鎘（Cds)之其 中一者，且該磷灰石係可為氟化磷灰石。 相較於習知技術中之光觸媒必須以紫外線激發而無 法應用於例如冰箱或櫥櫃等昏暗的容置體中進行除臭，本 發明之光觸媒除臭裝置所具之除臭本體表面覆蓋含有披覆 磷灰石之光觸媒材料，而可藉該磷灰石持續地於容置物中 將有害物質吸附，而當磷灰石吸附飽和後，可將該光觸媒 除臭裝置曝曬於陽光下或適當的紫外線照射環境中，以激 卷内含之光觸媒化合物進行催化反應而將有害物質分解， 故可重複使用而大幅降低使用者所需負擔的更換成本。 再者，即使習知技術於冰箱中供應紫外線激發光觸 媒，然而冰箱中不斷流動的氣流卻使得光觸媒化合物不易 接觸於冰箱中有害物質，而本發明之光觸媒除臭裝置所具 έ有披復辑灰石之光觸媒材料因具有可主動吸附有害物質 之麟灰石成分，因此可不斷地將有害物質吸附，而使得本 發明之光觸媒除臭裝置具有高效能之除臭、殺菌效率。 本發明光觸媒除臭裝置之光觸媒材料係受麟灰石之 包覆，因此即使該光觸媒化合物為二氧化欽，由於並未直 接接觸於該除臭本體，因此不致於對除臭本體 藉此避免如習知技術中-氧化姑斜认& # 、每 仪彳ΤΤΤ 一虱化鈦對於所附著基材的損壞， 以&升该光觸媒除臭裝置之耐用度。 另外，本發明之光觸媒除臭裝置可藉該吊掛部吊挂卜於 9 19740 200810797 * ϊ 諸如冰箱、衣櫃等之容詈物由 M 而使得該除臭本體接觸於 二風之面積不叉遮擋’俾可增進除臭、殺菌之效率。 之缺：上因可:且Γ發Γ光觸媒除臭裝置可改善習知技術 之缺2因此具有尚度產業利用價值。 【實施方式】 ' 以下係藉由特定的具體實施例說明本發明之實施方 =以下請配合圖式說明本發明之具體實施例，以使所屬 達有通承知識者可輕易地瞭解本發明之技術特徵與 1一實施例 第=係顯示本發明光觸媒除臭裝置之第一較佳具體 =例不思圖，如圖所示，本發明之光觸媒除臭裳置卜 以及結合至該載件11之除臭本㈣，該載 心〇係2=:::容置且:之吊掛部110’而該除臭本 来弼二且表面覆蓋含有披覆-灰石之 料’俾可藉該磷灰石吸附有害物質，並可透過光 月匕W射该光觸媒材料而予以分解淨化。 於本實施例中，該載件n係為局部包覆該除臭本體 外=例如為塑膠板之板片，具有足夠強度與輕薄之特 當然所屬技術領域中具有通常知識者應均知可採用塑 二二=外之材質取代，例如紙板、壓克力板等。而用以吊 :—容置物之吊掛部110係可連接於該載件u之頂部， 例如外加黏著固定一掛鉤即可構成該吊掛部110。、 該除臭本體10係一種例如為不織布之基材，其表面 19740 10 200810797 ，盍含有披㈣灰石之光觸媒材料係、由水溶液乾燥化而成 溥膜者其中，δ亥水溶液係具有丙烯酸樹脂resin)、 =及外表披㈣灰；5 (CalG(pC)4)6(QH)2)之光觸媒化合 勿而該光觸媒化合物係例如為二氧化欽（)、氧化 於本貫施例中所述之載件1Hf局部包覆該除臭本體 卜部’因此於實際販售時應需要再增加-個外包裝予以 包覆，“基本發明之技術思想，該載件η並非僅以本實 :歹•所不者為限，4 了考慮安裳與吊掛結構方面之整合功 效’亦可改變該裁件1】 科鉑耸㈣W 相省略外加之外包裝或 卦鉤4、、、σ構成本，茲容後實施例詳述。 辛（Zn〇)-氧化錫（Sn02)、或硫化鎘（CdS)。當 f所屬㈣領域巾具有通常知識者應均知，㈣灰石亦可 、、擇由氟化_灰石來取代’以提昇其抗酸性質，非以本實 _所述之磷灰石為限，相同地，該除臭本體a以非以本 貫施例所述之傾布基材為限，亦可選擇由紙、布、壓克 力、PE樹脂、以及pp樹脂之其中一種基材取代。 睛麥閱第2圖，本發明之光觸媒除臭裝置2，係 載件21以及結合至該载件21之除臭本體，該載件幻 :::以吊掛於一容置物之吊掛部22〇，而該除臭 =合至該载件21，且表面覆蓋含有披㈣灰石之光觸媒 ]，俾可错該較石吸时#物#，並可 射 該光觸媒材料而予以分解淨化。 此，、、、射 該除臭本體2〇可為選自選自紙張、布、不織布、璧 19740 11 200810797 克力、PE樹脂、以及pp樹脂之其中一種基材。 該含有披覆磷灰石之光觸媒材料可由水溶液乾燥化 後所形成者，而該水溶液中可含有丙烯酸樹脂（acryHc resm)之乳化液以及外部披覆磷灰石之光觸媒化合物。丙烯 酸樹脂具有高透明度，不易因紫外線或其他外在環境因素 影響其透明色澤，丙烯酸樹脂並具有高耐水性（即疏水性） 以及結合力強之特點以附著於該除臭本體2〇之表面，而由 於麟灰石為親水性，因此當進行完水溶液之乾燥化後，碟 ，石會自動地露出於光觸媒材料之表面，俾直接接觸於空 氣中之有害物質。該磷灰石所包覆之域媒化合物可為 自二氧化鈦（Ti〇2)、氧化鋅（Zn〇)、二氧化鈦（叫）、、 以及硫化錦(Cds)等可分解有害物質 先觸媒化5物等，㈣灰石吸附㈣物質後，可藉 光激發光觸媒化合物之氧化還原反應而將有害物質分解。 用於披覆光觸媒化合物的磷灰石，且化學式為 =ρ〇4)6_)2，對於胺基（姻2)、氮氧化物 (-COOH)祕基(個）等官能基具有較強吸 土 有這些官能基的細g、有機物或蛋白質會被 ^此” 吸附的物質會和二氧化鈦接^ ^ 吸附， 走，當光線存在時==會因為空氣流動而飄 羊欽即會發揮分解能力蔣接總# 質分解。因崎石披覆二氧化鈦可以持續吸p:有 害物質，並且強化有害物質和 肖、，及附有 照射時二氧化鈦將有害物質分解，而=:，直到光線 分繼灰石會恢復活性，而可繼續吸氧化鈦 19740 12 200810797 該載件2!可為包覆該除臭本體2〇之紙板 之兩側並具有可外露出該除臭本體加之兩表面的開口 210’且該載件21並具有對應覆蓋該開口训之遮 ^連該遮擒片22之相對兩側並以可撕式虛線與該载"件21 該吊掛部22可為設於該遮擋片22並以 遮擋片22之複數摺耳，該迻 連》又於忒 2 2之開口 2 2卜且二耳之真緣^ 2並具有對應該吊掛部 ⑶之口緣相連。耳之^亦以可撕式虛線與該開口 為了使吊掛部2 2撕離於該開口 2 2!後可定位於一 側’該遮播片22可於該可撕式虛線之相對兩端伸 扣，俾使該勾掛部細於彎折後受該延伸裂縫222之^ 而定位於該遮擋片之一侧。 丁以 f外’該载件21之表面並可印製有商標、使用說明 之文子及圖示等以供使用者閱讀。 請配合參閱第3圖，經由撕開該遮播片22及該载件 ㈣之可撕式虛線，接著反折該遮則22並使兩遮播片 22上之吊掛部220重叠後，可進一步按壓該吊掛部220使 重疊之兩吊掛部220 一同彎折於該遮播片22之一側， 由前述之延伸裂縫222之干涉而使該吊掛部220可保持此曰 一彎折之狀態。 狩此 復請配合參閱第4圖，本發明之光觸媒除臭裝置 應用^一容置物3中’該容置物3可為一冰箱，該光觸媒 除臭裝置2可藉由所具之吊掛部22。掛設於諸如蛋架/、 19740 13 200810797 ， * 以及飲料架32上，而藉由使 媒材料之除臭本體2G接觸^表:具有披㈣灰石之光觸 菌、防霉、保鮮之作用目中之氣流而發揮除臭、殺 而料冰射時有冷凝ϋ 光觸媒材财㈣灰石造成奸 生而可對 所含之磷灰石中可由氣化；^因此两述之光觸媒材料 特性避免磷灰石受到酸性液體之腐I代’俾藉由氣之抗酸 衣櫃中異味、以及殺 （句未圖示）而達成消除 及杈囷、防霉之功效。 相較於習知技術中之光觸 法應用於冰箱中進行除臭1=須以紫外線激發而無 具之披覆磷灰石之光觸據㈣之光觸媒除臭裝置2所 璘灰石，==料係包含有可吸附有害物質之 灰石吸附飽和後，可將w觸：有告物質吸附，而當石舞 發内含之弁網m x觸媒除臭裝置曝曬於陽光下激 知内3之忐觸媒進而將有害物質分解。 媒，：t二了1知技術於冰箱中供應紫外線激發光觸 接觸：、=τ斷流動的氣流卻使得光觸媒化合物不易 接觸於冰相中有害物質， 披覆磷灰石之光觸媒材料闲且: 觸媒除臭裝置所具 灰石点八具有可主動吸附有害物質之磷 之光角此可不斷地將有害物質吸附，而使得本發明 ，媒光觸媒除臭裝置2具有高效能之除臭效率。 石之勺=月之光觸媒除臭裝置2之光觸媒化合物係受鱗灰 W ’因此即使該光觸媒化合物為二氧化欽，由於並 19740 14 200810797 ^ ♦ 未直接接觸於該除臭本體2〇，因此不致於 造成損傷，藉此擗于、六本體20 材計楝 1知技術_二氧化輯於所附著基 、貝私，以提升該光觸媒除臭裝置之耐用度。 林明之光觸媒除臭裝置可藉該吊掛部吊掛於 诸如冰相、衣櫃箄六 、 扣&拉、/ 谷置物中，而使得該除臭本體接觸於 二’大增俾可增進除臭之效率，且該吊掛部並可銥 jt之設計與光觸媒除臭裝置2之包裝整合而可直接擺 於^木亡販售且不需另外的包裝，以避免造成環保負擔月匕。 上可知，本發明之光觸媒除臭裝置可改善習知缺 點，因此具有高度產業利用價值。 、 准以上所述之具體實施例，僅係用以例釋本發明之特 文，而非用以限定本發明之可實施範轉，在未脫離 二揭之精神與技術範訂，任何運用本發明所揭示 内合而70成之等效改變及修飾，均仍應$下述之 範圍所涵蓋。 t ~ 【圖式簡單說明】 第1圖係顯示本發明光觸媒除臭装置之第一較佳 實施例示意圖； 第2圖係顯示本發明光觸媒除臭裳置之第二較佳具體 貫施例不意圖； 第3圖係顯示本發明光觸媒除臭裝置之第二較佳具體 實施例之側視剖面圖；以及 第4圖係顯示本發明光觸媒除臭裝置第二較佳具體實 施例之應用例示意圖。 19740 15 200810797 【主要元件符號說明】 ★ « 1 光觸媒除臭裝置 10 除臭本體 11 載件 110 吊掛部 2 光觸媒除臭裝置 20 除臭本體 21 載件 210 開口 22 遮擋片 220 吊掛部 221 開口 222 延伸裂縫 3 容置物 31 蛋架 32 飲料架The hanging portion can be _ side connected to the shielding piece, and S.: hang two! A plurality of openings in the hanging portion. Preferably, the masking piece can be connected to the edge of the opening by a tearable dashed line, and the other side of the tearable dotted line can have opposite sides of the extended splitting member in the supporting piece. The side system can be connected to the edge of the != mouth by a tearable dashed line. Therefore, the cover sheet is not peeled off from the carrier: ,::: can form a pattern completely covering the deodorizing body, so Charge = 褒 ' without the need to set the outer packaging. Further, the carrier device may be printed with at least one of the light-touching of the deodorizing device, and (4) self-use instructions and trademarks. The heart of the refrigerator can be a refrigerator or a closet, and the hanging part can be hung on the / egg #, beverage rack, or hangers hanging in the closet. The ehai deodorizing system is one of a substrate selected from the group consisting of paper, cloth, non-woven fabric, acrylic, and retort resin. The coated lepidite=catalyst material can be dried by an aqueous solution to form a film, wherein the 7 life liquid system can have an acrylic resin (4) coffee (4) n), and the outer surface coating 19740 8 200810797 Λ > apatite (Cal0(PO4)6(OH)2) photocatalyst compound, preferably, the photocatalyst compound may be selected from the group consisting of titanium dioxide (Ti〇2), oxidized (ZnO), tin dioxide (Sn〇2), and sulfurized One of cadmium (Cds), and the apatite system may be fluorinated apatite. Compared with the photocatalyst in the prior art, the photocatalyst must be excited by ultraviolet rays and cannot be used for deodorization in a dark container such as a refrigerator or a cabinet. The photocatalyst deodorizing device of the present invention has a surface of the deodorizing body covered with a coating. The photocatalyst material of the apatite can be adsorbed by the apatite continuously in the container, and when the apatite is saturated, the photocatalyst deodorizing device can be exposed to sunlight or appropriate ultraviolet irradiation. In the environment, the photocatalyst compound contained in the stimuli is catalyzed to decompose the harmful substances, so that it can be reused and the replacement cost of the user is greatly reduced. Furthermore, even though the conventional technology supplies ultraviolet light-exciting photocatalyst in a refrigerator, the continuous flow of air in the refrigerator makes the photocatalyst compound less likely to be in contact with harmful substances in the refrigerator, and the photocatalyst deodorizing device of the present invention has a viscous ash. Since the stone photocatalyst material has a lining stone component capable of actively adsorbing harmful substances, the harmful substance can be continuously adsorbed, and the photocatalyst deodorizing device of the present invention has high-efficiency deodorizing and sterilization efficiency. The photocatalyst material of the photocatalyst deodorizing device of the present invention is coated with lindenite, so even if the photocatalyst compound is oxidized, since it is not directly in contact with the deodorizing body, the deodorizing body is not avoided thereby. In the prior art, the oxidation of the substrate is damaged, and the durability of the photocatalyst deodorizing device is increased. In addition, the photocatalyst deodorizing device of the present invention can be hung by the hanging portion at 9 19740 200810797. ϊ The contents of the refrigerator, the wardrobe, and the like are made of M, so that the deodorizing body is in contact with the area of the second wind. '俾 can improve the efficiency of deodorization and sterilization. The lack of: the upper cause: and the development of the photocatalyst deodorizing device can improve the lack of conventional technology 2 and therefore has the value of industrial use. [Embodiment] The following describes the embodiments of the present invention by way of specific embodiments. hereinafter, the specific embodiments of the present invention will be described with reference to the drawings, so that those skilled in the art can easily understand the present invention. The technical features and the first embodiment show that the first preferred embodiment of the photocatalyst deodorizing device of the present invention is not illustrated. As shown in the figure, the photocatalyst of the present invention is deodorized and bonded to the carrier 11 Deodorant (4), the core system 2=::: accommodating and: the hanging portion 110' and the deodorizing is originally two and the surface covered with the covering-grey stone material can be borrowed from the phosphorus The limestone adsorbs harmful substances and can be decomposed and purified by the photocatalyst material. In this embodiment, the carrier n is partially coated with the deodorizing body, for example, a sheet of a plastic plate, and has sufficient strength and lightness. Of course, those having ordinary knowledge in the technical field should be able to adopt Plastic two or two = external material replacement, such as cardboard, acrylic sheet and so on. The hanging portion 110 for attaching the container can be connected to the top of the carrier member u, for example, by attaching and fixing a hook to form the hanging portion 110. The deodorizing body 10 is a substrate such as a non-woven fabric having a surface of 19740 10 200810797, a photocatalyst material containing ruthenium (a) ash, and a deciduous film which is dried by an aqueous solution, wherein the δ hai aqueous solution has an acrylic resin. Photocatalyst combination of resin, = and external (4) ash; 5 (CalG(pC)4)6(QH)2). The photocatalyst compound is, for example, dioxins (oxidized in the present embodiment) The carrier 1Hf partially covers the deodorizing body part. Therefore, it is necessary to add another outer packaging to cover it when it is actually sold. "The technical idea of the basic invention is that the carrier η is not only true: The limit is not limited to 4, considering the integration effect of Anshang and hanging structure' can also change the piece 1] Cobalt towering (4) W phase omitting plus outer packaging or hooking 4,, σ constitute this, Details of the subsequent examples. Xin (Zn〇)-tin oxide (Sn02), or cadmium sulfide (CdS). When f belongs to (4) the field towel has general knowledge should be known, (4) gray stone can also, choose fluorine _ ash stone to replace 'to enhance its acid-resistant properties, not to the actual a _ apatite Similarly, the deodorizing body a is not limited to the tilting substrate described in the present embodiment, and may also be selected from one of paper, cloth, acryl, PE resin, and pp resin. In the second embodiment, the photocatalyst deodorizing device 2 of the present invention is a carrier member 21 and a deodorizing body coupled to the carrier member 21, the carrier is phantom:: hanging from a container The hanging portion 22 is closed, and the deodorizing material is combined with the carrier member 21, and the surface is covered with a photocatalyst containing piloth (four) gray stone, which can be wrongly compared with the stone material, and can be decomposed by the photocatalyst material. The deodorizing body 2 can be selected from one of a substrate selected from the group consisting of paper, cloth, non-woven fabric, 璧19740 11 200810797 gram, PE resin, and pp resin. The stone photocatalyst material can be formed by drying the aqueous solution, and the aqueous solution may contain an emulsion of acrylic resin (acryHc resm) and a photocatalyst compound coated with apatite externally. The acrylic resin has high transparency and is not easily ultraviolet or other External environmental factors affect its transparent color Acrylic resin has high water resistance (ie hydrophobicity) and strong binding force to adhere to the surface of the deodorizing body 2〇, and since the ash stone is hydrophilic, when the aqueous solution is dried, the dish is The stone is automatically exposed on the surface of the photocatalyst material, and the crucible is directly in contact with the harmful substances in the air. The domain compound coated by the apatite may be from titanium dioxide (Ti〇2), zinc oxide (Zn〇), Titanium dioxide (called), and sulfur sulfide (Cds) and other decomposable harmful substances, first catalytically, etc., (4) after the adsorption of (4) substances by gray stone, the photocatalytic compound can be excited by photocatalytic redox reaction to decompose harmful substances. The apatite coated with the photocatalyst compound has a chemical formula of =ρ〇4)6_)2, and has strong adsorption for functional groups such as an amine group (marine 2) and a nitrogen oxide (-COOH) group. The fine g, organic matter or protein with these functional groups will be adsorbed by the TiO2. The light will be absorbed when the light is present. Total #质分解. Because of the stone coated with titanium dioxide, it can continue to absorb p: harmful substances, and strengthen harmful substances and xiao, and with titanium dioxide to decompose harmful substances, and =: until the light will return to the gray stone to restore activity, and can continue Titanium absorbing titanium 19740 12 200810797 The carrier member 2! may be a side of the cardboard covering the deodorizing body 2〇 and having an opening 210' exposing the deodorizing body plus the two surfaces and the carrier member 21 has Corresponding to the opening of the cover sheet 22, the opposite sides of the concealer 22 are separated by a tear line and the loading member 22, the hanging portion 22 can be disposed on the shielding sheet 22 and the shielding sheet 22 The plurality of folds, the transfer is again connected to the opening 2 2 of the 忒 2 2 and the true edge of the two ears 2 and has the edge corresponding to the hanging portion (3). The ear can also be positioned on one side with a tearable dashed line and the opening in order to tear the hanging portion 2 2 away from the opening 2 2! The obscuring piece 22 can be at opposite ends of the tearable dotted line The buckle is fastened to the side of the shielding piece by the extension crack 222 after being bent. The surface of the carrier 21 may be printed with a trademark, a description of the instructions, and the like for the user to read. Please refer to FIG. 3, by tearing the masking piece 22 and the tearable dotted line of the carrier (4), and then folding the cover 22 and overlapping the hanging portions 220 on the two shielding pieces 22, Further pressing the hanging portion 220 causes the overlapping two hanging portions 220 to be bent together on one side of the shielding piece 22, and the hanging portion 220 can maintain the first bending by the interference of the extending slit 222. State. Referring to FIG. 4, in the photocatalyst deodorizing device of the present invention, the container 3 can be a refrigerator, and the photocatalyst deodorizing device 2 can be provided with the hanging portion 22 . Hanged on, for example, egg rack / 19740 13 200810797 , * and beverage rack 32, and by contacting the deodorizing body 2G of the medium material: the photo-bacteria, anti-mildew, and fresh-keeping effect of the cloth (four) gray stone The airflow exerts deodorization, kills and freezes when there is ice. Photocatalyst material (4) Graystone causes rape and can be vaporized in the apatite contained in it; ^ Therefore, the characteristics of the photocatalyst materials are avoided. The stone is subjected to the rot of the acidic liquid, and the effect of eliminating and licking and preventing mildew is achieved by the odor in the acid-resistant wardrobe of the gas and the killing (not shown). Compared with the light touch method in the prior art, it is applied to the refrigerator for deodorization. 1=The light is excited by ultraviolet rays without the apatite light. (4) The photocatalyst deodorizing device 2 is used to remove the gray stone, == After the adsorption of the limestone containing the adsorbable harmful substances, the w touch: the substance is adsorbed, and when the stone dance is contained in the mx catalyst deodorizing device, the sun is exposed to the sun. The medium then decomposes harmful substances. Media: t two 1 know technology in the refrigerator to supply ultraviolet light to stimulate the light contact:, = τ off the flow of air, but the photocatalyst compound is not easy to contact the harmful substances in the ice phase, the photocatalyst material coated with apatite is idle: The catalyst deodorizing device has a gray light point of phosphorus which can actively adsorb harmful substances, which can continuously adsorb harmful substances, so that the medium photocatalyst deodorizing device 2 has high-efficiency deodorizing efficiency. Stone spoon = light photocatalyst deodorizing device 2 of the photocatalyst compound is subjected to scale gray W 'so even if the photocatalyst compound is dioxin, because 19740 14 200810797 ^ ♦ is not directly in contact with the deodorant body 2〇, therefore not In order to cause damage, the six body 20 materials are known to be attached to the base, and the durability of the photocatalyst deodorizing device is improved. Lin Mingzhi's photocatalyst deodorizing device can be hung from the hanging part such as ice phase, wardrobe 箄6, buckle & pull, / valley, so that the deodorant body can contact the two 'large 俾 俾 to improve deodorization The efficiency, and the hanging part can be integrated with the packaging of the photocatalyst deodorizing device 2, and can be directly sold in the wood and sold without additional packaging to avoid the environmental burden. As can be seen, the photocatalyst deodorizing device of the present invention can improve the conventional disadvantages and thus has a high industrial utilization value. The specific embodiments described above are only used to exemplify the invention, and are not intended to limit the implementation of the present invention. Equivalent changes and modifications of the invention are disclosed in the following claims. t ~ [Simplified description of the drawings] Fig. 1 is a schematic view showing a first preferred embodiment of the photocatalyst deodorizing device of the present invention; and Fig. 2 is a view showing a second preferred embodiment of the photocatalyst deodorizing device of the present invention. 3 is a side cross-sectional view showing a second preferred embodiment of the photocatalyst deodorizing device of the present invention; and FIG. 4 is a view showing an application example of the second preferred embodiment of the photocatalyst deodorizing device of the present invention. . 19740 15 200810797 [Description of main component symbols] ★ « 1 Photocatalyst deodorizing device 10 Deodorizing body 11 Carrier 110 Hanging part 2 Photocatalyst deodorizing device 20 Deodorizing body 21 Carrier 210 Opening 22 Covering piece 220 Hanging part 221 Opening 222 extended crack 3 accommodating 31 egg rack 32 beverage rack