TW200810691A - Synergistic active compound combinations - Google Patents

Abstract

Novel active compound combinations comprising a phthalamide of the formula (I), where Hal represents chlorine, bromine or iodine, * denotes a carbon atom in the R or the S configuration, preferably in the S configuration, and the active compound groups (1) to (24) listed in the description have very good insecticidal and fungicidal properties.

Description

200810691 IX. INSTRUCTIONS OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to a novel active compound composition which first comprises at least one known guanamine, and secondarily comprises another known active compound of bactericidal bacterium, The novel active compound composition is highly suitable for controlling unwanted animal pests such as insects and undesirable phytopathogenic fungi. [Prior Art] It is known that the indoleamine of the formula (I) has insecticidal activity. This point is applicable to the racemic type of the compound (EP-A 1 006 107), and is more applicable to the (S)-configurable enantiomers (Japanese Patent Application JP 2006-089469). In addition, a variety of different triterpene derivatives, aniline derivatives, bismuthimides and other heterocyclic compounds are known for controlling fungi (see EP-A 0 040 345, DE-A 22 01 063, DE-A 2324010). Pesticide Manual, 9th edition (1991), ρ·249 and 827, EP-A 0382 15 375, EP-A 0515901, DE-B2 2732257). However, the effects of these compounds are also always insufficient at low application rates. Further, 1·(3,5-dimethyl-isoxazole-4-sulfonyl)-2-chloroindole difluoro-[1,3]-disaki-[4,5f> benzo is known. Imidazole has fungicidal properties (see WO 97/06171). Finally, it is also known that substituted halo is known to have fungicidal properties (see DE-A1-196 46 407, ΕΡ-Β-712 396). SUMMARY OF THE INVENTION We have now discovered a novel active compound composition having excellent insecticidal and fungicidal properties comprising a guanamine of the formula (I) (Class 1) 200810691

among them

Hal represents chlorine, bromine or moth, * represents a carbon atom in the R or S configuration, preferably in the S configuration, and at least one active compound selected from the following classes (2) to (24): 10 (2) ··Strobilurins of the following formula

15 where A1 represents one of the following groups,

A2 represents NH or 0, A3 represents N or CH, and L represents one of the following groups,

20 200810691 η wherein the bond represented by an asterisk (*) is attached to a phenyl ring, and R represents a phenyl group, a phenoxy group or a group. The thiol group, which may be the same or a different substituent in the following group, may be mono- or disubstituted, chlorine, cyano, methyl and trifluoromethyl, or represent Μ4·chlorophenylh-azole- 3-yl or on behalf of hydrazine, 2-propanedione _ bis (〇-methyl fluorenyl,

Rl2 represents hydrogen or fluorine; dH is a general formula of ΠΊΙ) 3 10 R14

Wherein Q represents hydrogen or SH, m represents 0 or 1, and R represents hydrogen, fluorine, chlorine, phenyl or 4-oxophenoxy,

Rl4 represents hydrogen or chlorine, A4 represents a direct bond, _CH2-, -(CH2)2, -0- represents *-CH2-CHR17- or *_CH=CR17-, wherein the bond represented by * is attached Phenyl ring, in which R15 and Ri7 together represent -CHyCHyCHCCI^CE^b]- or -αί2-(:ΙΙ2-0〇3ΙΙ3:)2·, Α5 represents C or Si (cut), and A also represents -N ( R17)-, and A5 may also be represented by R15 and R16 together with a group of 200810691 group C=N-R18, in which case R17 and R18 together represent a group 5, wherein the bond represented by * is attached to R17, and R15 represents an anthracene and a hydroxyl group. Or cyano, R16 represents 1-cyclopropylethyl, 1-chlorocyclopropyl, CrC4-alkyl, CrQ-hydroxyalkyl, Q-CV alkylcarbonyl, CrC2-i alkoxy-CkCV ίο alkyl , trimethyldecylalkyl, monofluorophenyl or phenyl, R15 and R16 may also collectively represent ·0_0Η2-αΐ(ί118)_0-, -0-CH2-CH(R18)-CH2-, or -0 -CH_(2-chlorophenyl)-, R18 represents hydrazine, CVCr alkyl or bromine; 15 (4): sulphenamide of the general formula (IV) FC 丨 2C,

H3C-N,

S k (ιν) CH3 wherein R19 represents hydrogen or methyl; (5): amidoxime selected from the group consisting of: (5-1) iprovalicarb 200810691

(5-2) (5-3) 5 £6}|| where X 10 15 20 γ Z n1_[2-(4-{[3-(4-chlorophenyl)-2-propanyl]oxygen Carboguanamines of hydrazine phenyl)ethyl]-N2-(benthiavalicarb UL type αν)

Represents 2-chloro-3-acridinyl, which represents Κmethylcarbazolyl (the 3_ position is substituted by fluorenyl or difluoromethyl and 5' position is replaced by hydrogen or gas)' stands for 4-ethyl-2- Ethylaminol_1,3-thiazole-5-yl, representing 1-methylcyclohexyl' represents 2,2·digas+ethyl_3_methylcyclopropyldi represents 2-fluoro-2-propanyl , 3,4-dichloroisothiazole _5-yl, 5,6-dihydro-2-indenyl hydrazine, 4-oxothiahexyl _3_yl, 4-methyl phantom 嗟 ϋ Base, 4,5-dimethyl-2_trimethyl sulphate spur _3·yl, 1-indenyl-3-yl (the 4-position is substituted by methyl or trifluoromethyl and 5- a position substituted by hydrogen or chlorine, or a phenyl group which is monosubstituted or disubstituted with the same or different substituents selected from the group consisting of: chlorine, methyl and trifluoromethyl, = Γ Γ direct bond, CKV burnt two base (stretched wire) (which may be replaced by chlorine, cyano or oxo, 丨 ', thin base) or shot: base, Μ represents (four), two base (extension represents hydrogen , CVC6-alkyl or a group of the following formula-10- 200810691

A6 represents CH or N, and r2° represents hydrazine, chloro, cyano, cvcv alkyl, phenyl (which may optionally be the same or different substituents selected from the following groups: mono- or disubstituted: chlorine And di(CVCV alkyl)aminocarbonyl, r21 represents hydrazine, chlorine or isopropoxy, r22 represents hydrogen, chloro, hydroxy, decyl, trifluoromethyl or bis(c"c3-alkyl)aminocarbonyl , 10 15 20 R2G and R21 may also collectively represent *_ch(ch3)-ch2_c(ch3)2- or *-ch(ch3)-oc(ch3)2_, wherein the bond indicated by * is attached to R20; From the following dithiocarbamate (7·1) zinc mannaze (mancozeb) (7-2) mannapura (maneb) (7-3) to avoid ruin (metiram) (7-4) methyl Propineb (7-5) thiram (7-6) Zinc (zineb) (7-7) ziram (8) class: general formula (VTk arginine) -11- (VI) 200810691

5 where * represents a carbon atom in the form of R or S, preferably configured as S, R23 represents phenylhydrazine, furyl or decyloxymethyl; (9) class: formula (VII) melamine pyrimidine Class 10

CH wherein 15 R24 represents anthracenyl, cyclopropyl or 1-propynyl; Π0) class: formula (VIII) stupid imidazole

Wherein R25 and R26 represent argon or together represent -〇_CF2-0-, R27 represents hydrogen, CrC4-alkylaminocarbonyl or represents 3,5-dimercaptoisoxazole-4-ylsulfonyl, - 12- 200810691 R28 represents chloro, nonyloxycarbonylamino, chlorophenyl, furyl or thiazolyl; Π1): alkyl phthalate of formula (IX)

Wherein R29 represents a positive " or iso-propyl 'R30 represents a bis(CrCr alkyl)amino-c2_c4-alkyl or diethoxybenzene 10 group, including the salts of such compounds; Π2): selected from The following bis-imines (12-1) tetrahydropalm (captafol) 15 20 (12-2) captan (12-3) folfet (12-4) Yi Putong (iprodione) (12-5) procymidone (12-6) vinclozolin Π3): from the following steroids (13-1) dodin (13_2) gram (guazatine) (13_3) gram heat triacetate (iminoctadine triacetate) -13- 200810691 (13-4) gram heat (burning benzoate) (iminoctadine tris (albesilate) Μ) class: choose _ from The following imidazoles (14-1) cyazofamid (14-2) poker pull (prochloraz) (14-3) taste 17 sulphur (triazoxide) (14-4) rice sulphate (pefurazoate) class = General formula OP

RV

/""Vr33 (x) wherein R31 and R32 each independently represent hydrogen or methyl, R33 represents CrCu-alkyl (preferably Ci2-Ci4_alkyl), C5_Cl2•cycloalkyl (preferably C1 ( rC12-cycloalkyl), phenyl-Ci-CU-alkyl (whose phenyl moiety may be substituted by halogen or radical) or acryloyl substituted by chlorophenyl and dimethoxyphenyl; R3\ r36

Ην^\ )rA m -14- 200810691 where R34 represents chlorine or cyano, R35 represents chlorine or nitro, r36 represents chlorine, and R35 and R36 together represent -〇-CF2-0-; (17) From the following (thio)phosphonates (17-1) Fossetyl-Al, (17-2) phosphonic acid, ίο (17-3) Tolclophos-methyl; Π8) : General formula (XII) phenylacetamide

Wherein R37 represents phenyl, 2-methyl, 1,2,3,4-tetrazincyl or indane substituted unsubstituted or substituted by fluorine-, chloro-, bromo-, decyl- or ethyl; Π9 Class: Fungicides selected from the group consisting of: (19-1) Acibenzolar-S-methyl (19-2) tetrachloroisophthalonitrile (19-3) (cymoxanil) -15- 200810691 (19-4) granules (edifenphos) (19-5) morphine (famoxadone) (19-6) chlorazinam (19-7) test chlorine Copper oxychloride 5 (19-8) Copper Hydroxide (19-9) oxadixyl (19-10) spiroxamine (19-11) nitrile sulphide (dithianon) (19-12) meprafenone ίο (19-13) fenamidone (19-14) 2,3_dibutyl-6-chlorothieno[2,3-( 1] Pyrimidine-4(311)-ketone (19-15) probenazole (19-16) isofothiolane (19-17) kasugamycin 15 (19-18) heat Phthalate (19-19) fermizone (19-20) tricyclazole (19-21) cyprosulfamide (19-22) diacetylergicillin (mandipropamid) 2〇(19-23) 快oxyf (quinoxyf En) (known from EP-A 326 330), as follows

• 16- 200810691 (19-24) proquinazid (known in WO 94/26722), as follows

CH3 (20) class: (thiol) urea derivative (20-1) from the following (pencycuron) (20-2) thiophanate-methyl ίο (20-3) ethyl multi-protection Thiophanate-ethyl (21): general formula (XIII) guanamine

15 wherein A7 represents a direct bond or -Ο-, A8 represents -C(2O)ΝΗ- or -NHC(=0)-, 20 R38 represents hydrogen or CrC4-alkyl, and R39 represents CrC6-alkyl; 22) Class: Formula (XIV) Triazolopyrimidines-17- (XIV) 200810691

5 wherein R40 represents a Ci-Cf alkyl group or a C2-C6-fried base 'R41 represents a CrC6-alkyl group, and r4〇 and R41 together represent a C4-C5-alkanediyl group (alkylene group) which is burned by CVCV 10 The mono- or di-substituted 'R42 represents bromine or gas, R43 and R47 independently represent hydrogen, fluorine, chlorine or methyl, R44 and R46 respectively represent hydrazine or fluorine, R45 represents hydrazine, fluorine or fluorenyl, 15 (23 ) class: general formula (XV) iodinone oxime

Wherein R48 represents CVCV alkyl, R49 represents Ci_C6_alkyl, C2-C6- fine or C2-C6-block, -18- 200810691 (24): general formula (XVI) biphenyl carbamide

Wherein R50 represents hydrazine or fluorine, and R51 represents chloro, chloro, thiol, trifluoromethyl, trifluoromethoxy, ίο -CH=N-OMe or -C(Me)=N_OMe, and R52 represents hydrogen and fluorine. , chlorine, bromine, sulfhydryl or trifluoromethyl,

Het represents one of the following Hetl to Het7 groups:

Hetl Het2 Het3 Het4 Het5 Het6 Het7 R53 represents iodine, methyl, difluoromethyl or trifluoromethyl, R54 represents hydrazine, fluorine, chlorine or fluorenyl, and R55 represents methyl, difluoroindenyl or trifluoromethyl. 20 R56 represents chloro, bromo, iodo, decyl, difluorodecyl or trifluoromethyl, and R57 represents methyl or trifluoromethyl. The fungicidal action of the active compound compositions according to the invention is surprisingly significantly better than the sum of the activities of the individual active compounds. It exhibits unpredictable -19- 200810691 synergy, and not only additive activity. The insecticidal action of the active compound compositions according to the invention is surprisingly significantly better than the total activity of the individual active compounds. It exhibits unpredictable synergistic effects and is not only additive activity. Formula (1) includes the following mixed objects;

10

(la) · · (S)-3-iodo-NLp-mercapto ice [1,2,2,2_tetrafluoro-1-(trifluoromethyl)ethyl]phenylindolyl-2-methyl sulphate Ethyl) anthraquinone (lb) · (S)-3-chloro-methyl ice [i,2,2,2-tetrafluoro-H-trifluoromethyl)ethyl]phenyl}_n2_(1_methyl -2-methyl schistosyl ethyl decylamine 15

(Ic) ··(S)-3-bromomethyl|[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl}_N2_(1-methyl-2- The sulfhydryl xanthylethyl) ugly amine 20 particularly emphasizes the active compound composition according to the invention, in addition to & guanamine (la): (S)-3-iodomethyl-4-[l,2,2, 2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl}-indole 2-(1-methyl-2-methylsulfonylethyl) decylamine 'except one or more, A kind of (2) to (2 sentence type active compound • 20-200810691 substance 0 is particularly emphasized according to the present hair amide (10): compound composition, one of which is in addition to thiol) B A1 cage I, 2 mercapto-4 -[l,2,2,2-tetrafluoro-1-(difluoro- 5 10 , ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, An active compound composition according to the present invention, wherein in addition to Tian Qi \ l · (S) _3 Ν 1] 2-methyl _4_ [1, 2, 2,2-tetrafluorotrismethylmethyl)ethyl] phenyl hydrazine 2 servoyl methyl 1 methyl stellate ethyl ethyl) urethane external packaging 3 one or more, preferably one (2) to (24) Active compound 0 Formula (II) includes the following The (2) Mixed Object class: (2-1) Yatuo Min (azoxystr〇bin) (from ερ · α〇 known 382,375), such as the formula

Genus CN

YV (2-2) floxastr (binoxa) (known from DE-A 196 02 095), 20

-21- 200810691 (2-3) (2E)-2-(2-{[6-(3-Chloro-2-indolylphenoxy)-5-fluoro-4-pyrimidinyl]oxy}phenyl) -2-(decyloxy-imino)-N-methylacetamide (known in DE-Person 196 46 407, EP-B 0 712 396), as follows

(2-4) Trifloxystrobin (known in ΕΡ-Α 0 460 575), as follows

(2-5) (2E)_2-(methoxyimino)-N-methyl 15 -2-(2_{[({(1Ε)-1-[3-(trifluoromethyl)phenyl) Ethylene oxime) oxo] phenyl) acetamidine (known from EP-A 0 569 384), as follows

(2-6) (2E)-2-(decyloxyimino)_N_methyl-2-{2_[(Ε)-({ 1-[3-(trifluoromethyl)phenyl)ethoxy (imino)-indenyl]phenyl}acetamidamine (known in ΕΡ-Α 0 596 254), as shown in the following formula -22- 200810691

5 (2-7) willsostazone (known in DE-A 195 39 324), as follows 〇

(2-8) 5-methoxy-2-methyl_4_(2-{[({(1Ε)-Η3-(trifluoromethyl)phenyl]ethyl}amino)oxy)-- Phenyl)-2,4-diaza-3H-1,2,4-oxadiazol-3-one (known from WO 98/23155), as follows, ch3

(2-9) Kresoxim·曱基 (known in EP-A 0 253 213), 20

-23- 200810691 (2-10) dimoxystrobin (known in EP-A 0398 692), as follows

(2-11) picoxystrobin (known in EP-A 0 278 595), as follows:

(2-12) pyracostrobin, as known from DE-A 44 23 612, as follows

(2-13) phenoxy vinegar (metominostrobin) (as known from EP-A 0 398 692), as follows

-24- 200810691 Formula (III) includes the following preferred (3) mixed objects: (3-1) azaconazole (known in DE-A25 51 560), as follows

5 (3-2) etaconazole (known in DE-A25 51 560), as follows

10 15 (3-3) propiconazole (known in DE-A 25 51 560), as follows

20 (3-4) difnoconazole (known from EP-A 0112 284), as follows -25- 200810691 η η

(3-5) Bromuconazole (known in ΕΡ-Α 0 258 161), as follows

(3-6) Cyproconazole (known in DE-A 34 06 993), as follows

(3-7) hexaconazole (known in DE-A 30 42 303), as shown in the following formula 20

CI

-(CH2)3CH3 -26- 200810691 (3-8) penconazole (known in DE-A27 35 872), as follows

CI

(3-9) Myclobutanil (known in ΕΡ-Α0 145 294), as in the following formula CH0 ci-〇

CN -(CH2)3CH3 15 (3,10) tetraconazole (known in ΕΡ-Α 0 234 242), as follows: ci ci—x>—CH-CHr〇-CF0CF0H CH0

2〇 (3-11) flutriafol (known in EP-A 0 015 756), as follows

-27- 200810691 (3-12) Sitting in the ring (60 〇 father 1 (: 〇 11 & 2 〇 16) (known from ugly? - 〇 〇 〇 〇 〇 8 8 8), as follows: '~Qr CH.

Cl

(3-13) flusilazole (known in EP-A0 068 813), as follows

CH, (3-14) simeconazole (known in EP, A 0537 957), as follows: 15 3/3 -CHj-Si(CH3) 20 (3,15) propyl sulphur (prothioconazole) (known from WO 96/16048), as follows

-28- 200810691 (3-16) fenbuconazole (known in DE-A 37 21 786), as follows

(3·17) tebuconazole (known in EP-A0 040 345), as follows

10

OH CHrCHrC-C(CH3)3 ch2

(3-18) ipconazole (known from EP-A 0 329 397), as follows

15 (3-19) metconazole (known in EP-A 0 329 397), such as 20

CI -29- 200810691 (3·20) Triticonazole (known in EP-A0 378 953), as follows

(3-21) bitertanol (known in DE-A23 24 010), as follows

(3-22) triadimenol (known in DE-A 23 24 010), such as 15

20 (3-23) triadimefon (known in DE-A 22 01 063), as follows

CI

-30- 200810691 (3-24) Fluquinconazole (known in EP-A 0 183 458), as follows

(3-25) quinconazole (known in EP-A0183 458), as follows

10 Formula (IV) includes the following preferred (4) mixed objects: 15 (4-1) dichlofluanid (known in DE-A 11 93 498), as follows

(4-2) Tolylfluanid (known in DE-A 11 93 498), as follows -31 - 200810691

Preferred (5) mixed objects are: (5-1) iprovalicarb (known from DE-A40 26 966), such as the following formula H3〇v^〇 CH. % 〇叫八肌

CH. (5-3) benthiavalicarb (known from W0 96/04252)

15 Formula (V) includes the following preferred (6) mixed objects: (6-1) 2-Chloro-N-(l,1,3-didecylindan-4-yl)-branched amine (from EP -A 0256503 is known), as follows

-32- 200810691 (6-2) boscalid (known in DE_A 195 31 813), as follows

(6-3) Furabi (furametpyr) (known in ΕΡ·Α 0 315 502),

ο IX Η

(6-4) N-(3-p-Tolylthiophen-2-yl)-1-methyl-3-trifluoromethyl-exoprozole-4-carboxamide (from EP-A 0737 682) Known), as follows

(6-5) ethabazole xam (known from EP-A 0 639 574) 20

HNEt -33- 200810691 (6-6) fenhexamid (known in EP-A 0 339 418), as follows

(6-7) carpropamid (known in EP-A 0 341 475), as in the following formula 〇

Cl CI 10 (6-8) 2-chloro-4-(2-fluoro-2-methylpropenylamino)-N,N-dimercaptobenzamide (from ΕΡ-Α 0 600 629 Known), as follows

15 (6-9) fluopicolid (known in WO 99/42447), as follows

-34- 200810691 (6-10) zoxamide (known from EP-AO 604 019), as follows

(6-12) Carboxin (known in US 3,249,499), as follows

(6-13) tiadinil (known from US 6,616,054), as follows

(6-14) penthiopyrad (known in ΕΡ·Α 0 737 682), as follows

(6-15) silthiofam (known in WO 96/18631), as shown in the following formula -35- 200810691

5 For example, (6) Mo 1,3- dimethyl butyl) phenyl] small methyl · 4 · (trifluoro) - 1 Η - mouth ratio 嘻 _ 3 carboxy carbamide (from w 〇 02 / 38542 Known),

10 (6-17) Fortune (£11^〇1&1^1) (known from -£-八27 31 522 >1 ‘’ is as follows 20

(6_18) Ν-[2_(1,3-Dimercaptobutyl)phenyl]-5-fluoro-1,3-oxazol-4-carboxyguanamine (known in ΕΡ-Α 1 414 803) , methyl, ΙΗι are as follows

-36- 200810691 吖trifluoromethyl)benzamide (6-20) Ν-[2-(1,3-dimethylbutyl)phenyl]_2 (from EP_A 1 519 913), as follows

5 10 (6·21) Ν-[2-(1,3-dimethylbutyl)phenyl group in phthalic acid (known from 4 1519913), as follows

15 (6-22)Ν-(4'_Chloro-3'-fluorobiphenyl-2-yl)-4-(difluoromethyl)_2•methyl< 3 Thiazole Carboxamide (from EP_A 1 4〇4 4〇7 is known), as follows

20-37-200810691 (6-23) N-[5-(4-Phenylphenyl)pyrimidine _4.yl]-2-iodo-N-(2-iodo-acne-intoxicated benzamide, as follows: Shame

(6-24) N-(3',4'-Dichlorobiphenyl-2-yl)_2-methyl_4_(trifluoromethyl M 3 agazole-5-carboxamide (from EP-A 1 Known in 474 406), as follows:

(6-25) Ν-{2-[3ϋ(Trifluoromethyl)-2-°pyridinyl]ethyl}_2_(trimethoxymethyl)phenylguanamine (known from WO 04/16088) , as follows

F

Preferred (7) types of mixed objects are: (7-1) zinc-manganese (mancozeb) (known from DE-A 12 34 704), the IUPAC name is exoethyl bis(dithioaminic acid) Manganese and zinc salts -38 - 200810691 (polymerization) complex (7-2) Manna (known in US 2,504,404), as follows (7-3) to avoid ruin (metiram) (from DE -A 10 76 434 is known), its IUPAC name is exoethyl bis(dithioaminic acid) ammonium zincate-poly(ethylamine decyl disulfide) ίο (7_4) fluorenyl zinc Propineb (known in GB 935 981), as follows

(7-5) thiram (known in US 1,972,961), as follows

(7_6) Zinb (known from DE-A 1081 446), as follows

-39- 200810691 (7-7) ziram (known in US 2,588,428), as follows

CH3 /N 丨CHSA 'S /zn S SAHs NICc, 3 H Formula (VI) includes the following preferred (8) mixed objects: (8-1) Benalaxyl (as of DE-A29 03 612) Know), as follows

(8·2) furalaxyl (known in DE-A 25 13 732), as follows

15 (8-3) metalaxyl (known in DE-A25 15 091), as follows

(8-4) metalaxyl-M (known from WO 96/01559), as shown in the following formula 20 200810691

(8-5) Benalaxyl-M, as follows

Ίο Formula (VII) includes the following preferred (9) hybrid objects: (9-1) cyprodinil (known in EP-A0310 550), as follows

(9-2) mepanipyrim (known in EP-A0 270 111), as follows

(9-3) pyrimethanil (known from DD 151 404), as shown in the following formula -41 - 200810691

5 Formula (VIII) includes the following preferred (10) mixed objects: (10-1) 6-chloro-5-[(3,5-dimethylisoxazol-4-yl)sulfonyl]-2 , 2-diindole-5H-[1,3]dioxime [4,5_f> benzimidazole (known from WO 97/06171), as follows

(10_2) benomyl (known in US 3,631,176), as follows

(10-3) carbendazim (known in US 3,010,968), as follows

(10-4) Keflon (known in chlorfenazole), as follows -42- 200810691 H Ck

(10-5) fuberidazole (known in DE-A 12 09 799), as follows

(10-6) thiabendazole (known in US 3,206,468), as follows

Formula (IX) includes the following preferred (11) type of mixed objects: 15 20 (11-1) diehofencarb (known in EP-A 0 078 663), as follows: 〇CH. Β〇V If 〇 ( (11-2) propamocarb (known in US 3,513,241), as shown in the following formula C 3 Η ΟΛ 〇

NH

NICH-43-200810691 (11-3) propamocarb-hydrochloride (known in US 3,513,241),

Η I HCI CH,

(11-4) propamocarb - fosetyl, as follows: I h3c^\ , H+/CH3 V H3cr chq

〇 , II -o-p-o H The preferred (12) type of mixed object is: (12_1) tetrachlor (captafol) (known in US 3,178,447), as follows

15 (12-2) captan (known in US 2,553,770), as follows

20 (12-3) Folpet (known in US 2,553,770), as follows

200810691 (12-4) Iprodione (known in DE-A21 49 923), as follows

Η CH, (12-5) procymidone (known in DE-A 20 12 656)

(12_6) vinclozolin (known in DE-A 22 07 576), as shown in the following formula 15

20 Preferred (13) mixed objects are: (13-1) dodine (known from GB 11 03 989), the following formula h2n ml ch3 0丫CH, -45- 200810691 (13_2) g heat Guazatine (known from GB 11 14 155), (13-3) iminoctadine triacetate (known from EP, A 0 155 509), as follows

The preferred (14) type of mixed object is: (14-1) cyazofamid (known in ΕΡ-Α 0 298 196), as shown in the following formula 10 SO^NMe,

CH3 15 (14-2) prochloraz (known in DE-A 24 29 523), as follows

20 (14-3) triazoxide (known in DE-A28 02 488), as follows

-46- 200810691 (14-4) pefurazoate (known in EP-A 0 248 086), as in the following formula

Formula (X) includes the following preferred (15) hybrid objects: (15-1) aldimorph (known from DD 140 041), as follows

Ch3 (15-2) tridemorph (known from GB 988 630), as follows

Ch3 (15_3) dodemorph (known in DE-A 25 432 79), as follows

(15-4) Fenfen fenpropimorph) (known in DE-A 26 56 747), -47- 200810691

5 (15·5) dimethomorph (known in ΕΡ·Α 0219 756), as follows

Formula (XI) includes the following preferred (16) hybrid objects: 15 (16-1) fenpiclonil (known from EP_A0236 272), as follows

NC

20 (16-2) fludioxonil (known in EP-A 0 206 999), as follows

•48- 200810691 (16_3)σ pyrrolnitrin (known from JP 65-25876), as follows

CI

5 The preferred (17) type of mixed object is (17-1) Fossetyl-Al (known in DE-A 24 56 627), as shown in the following formula: 10 II AIH3 h3c^s^o>&quot ;h^oh (17-2)phosphonic acid (known chemical), as follows:

II

HO^H^OH 15 (17-3) tolclofos-methyl (as known from DE-A 25 01 040), as follows

Formula (XII) includes the following preferred (18) hybrid objects, which are known from WO 96/23793 and which may each be an E or Z isomer. Thus, the compound of formula (XII) may be in the form of a mixture of different isomers or in a single isomer form. Preferably, -49- 200810691 is an isomer of the compound of formula (XII) in the form of E: (18-1) the compound 2-(2,3-dihydro-1H-indan-5-yl)-N-[2 -(3,4-dimethoxyphenyl)ethyl]-2-(decyloxy-imino)acetamide, as follows

(18-2) Compound N-[2-(3,4-Dimethoxyphenyl)ethyl]-2-(methoxyimino)-2·(5,6,7,8-tetra奈奈_2_基)Ethylamine' is as follows: 10

(18-3) Compound 2-(4-chlorophenyl)-indole-|>(3,4-dimethoxyphenyl)ethyl15-yl]-2-(methoxyimino)-B Guanamine, as follows:

2〇(18-4) compound 2-(4-bromophenyl)-N-[2-(3,4-dimethoxyphenyl)ethyl]-2-(decyloxyimino)- Acetamine, as follows:

-50- 200810691 (18-5) Compound 2-(4-Mercaptophenyl)-N-[2-(3,4-dimethoxyphenyl)ethyl]-2-(methoxyimine) Base)-Ethylamine' is as follows:

(18-6) Compound 2-(4-ethylphenyl)-N-[2-(3,4-dimethoxyphenyl)ethyl]-2·(methoxyimino)-B Guanamine, as follows:

The preferred (19) type of mixed objects are: (19-1) arsenic acid benzene-8-fluorenyl (eight (^6112〇1&1^8-11161;]^1) (from £?-人0313512 Known), as shown in the following formula 10 15

(19-2) Tetrachloroisobenil (known as known from US 3,290,353), as follows

CN

20 200810691 (19-3) cymoxanil (known in DE_A 23 12 956), as follows

Ch3 5 (19-4) edifenphos (known in DE-A 14 93 736), as follows

10 (19,5) Where is the famoxadone (known in EP-A 0 393 911), as follows

15 (19-6) fluazinam (known in ΕΡ-Α0 031 257), as follows

(19-7) Copper oxychloride (19-9) oxadixyl (known in DE-A 30 30 026), as follows -52- 200810691

5 (19-10) spiroxamine (known in DE-A 37 35 555), as follows

10 (19-11) dithianon (known from JP-A 44-29464), as follows 〇

(19-12) metrafenone (known in EP-A 0897 904), as follows

(19-13) Fenamidone (known from EP-A 0 629 616), the following formula -53- 200810691

(19-14) 2,3-dibutyl-6-chlorothieno[2,3-d]pyrimidin-4(3H)-one (known from WO 99/14202), as follows

Ίο (19-15) probenazole (known in US 3,629,428), as follows

15 (19-16) Isoprothiolane (known in US 3,856,814), as follows

Ch3 kasugamycin (known from GB 1 094 567), as follows -54- 200810691

(19-18) phthalide (known from JP-A 57-55844), as follows

(19-19) Fermizone (known from EP-A0019 450), as follows

(19-20) Tricyclazole (known in DE-A 22 50 077), as follows

(19-21) Cyprosulfamide, as follows: ο: ο:

CH

NH

TH OMSMO

-55- 200810691 (19-22) Mandipropamid (known from WO 01/87822)

Preferred (20) hybrid objects are: (20-1) pencycuron (known in DE-A27 32 257), such as

(20-2) thiophanate-methyl (known in DE-A 18 06 123 15), as follows

20 (20_3) thiophanate-ethyl (known in DE-A 18 06 123), as follows

-56- 200810691 The preferred (21) type of mixed object is: (21-1) fenoxanil (known from EP-A 0262 393), as follows

(21_2) Diclocymet (known from JP_A 7-206608), as shown in the following formula 10

CI

The preferred (22) type of mixed object is: (22-1) 5-chloro-N-[(lS)-2,2,2_diqi-1-methylethyl]-6·(2,4, 6-digas 15 phenyl)[1,2,4]triazolo[l,5-a]pyrimidin-7-amine (known from US 5,986,135), as follows

(22-2) 5-Chloro-N-[(1R)-1,2·dimercaptopropyl]_6-(2,4,6-trifluorophenyl)[1,2,4]triazole [l,5-a]-pyrimidine-7-amine (known from WO 02/38565), as shown in the following formula -57- 200810691

(22-3)5-Chloro_6_(2_Chloro-fluorophenyl hydrazine·(4·曱-ylpiperidin-1 -yl)[1,2,4] Diindolo[l,5-a]- Pyrimidine (known in us 5,593,996) as follows

(22 o-chloro-6_(2,4,6-trifluorophenyl is called 4 methyl brigade biting small base II sniffing [l,5-a] pyridine (known from de_a 1〇1 24 208) , such as 15

20 Preferred (23) mixed objects are: (23_1)2_butoxy_6-iodo-3-propylbenzopyranone (known from w〇03/0Ml03)' is as follows-58 200810691

(23-2) 2-ethoxy-6-indol-3-propylbenzopyran-4-one (known from WO 03/014103), as follows

〇zCH3(23_3)6-iodo-2-propoxy_3-propylbenzopyran-4-one (known from WO 03/014103), as follows

〇 〇 15 (23-4) 2-but-2-ynyloxy-6-bromo-3-propylbenzopyran-4-one (known from WO 03/014103), as follows

2〇(23-5)6-iodo-2-(1-decylbutoxy)_3-propylbenzoin-4-one (known from WO 03/014103), as follows

-59- 200810691 (23-6) 2-but-3-dyloxy-6------------------------------------------------------------------------------------

(23_7)3_butyl-6_hard-2-1 tS##propoxybenzopyran-4-enone (known from WO 〇3/014103), as shown in the following formula 10, preferred (24) The object is: (24-l) N_(3,4 'mi,! ', Benzene-2-yl)·3_(difluoromethyl)小methyl-1Η-pyrazole_4_carboxamide (from w 〇〇3/〇7〇7〇5 is known), 15

As follows

(24-2) 3-(Difluoroindolyl)-N-{3'-fluoromethoxyimino)methyl]-1, fluorene-biphenyl-2-yl}_1-methyl·m_ Pyrazole ice carboguanamine (known from WO 02/08197), as follows: 200810691

(24-3) 3-(difluoromethyl)^^3,_fluoro-4-4, ivr:, yl]-1,1,-biphenyl-2-yl}small ()-(methoxy Imino) is known in WO 02/08197), such as soil_1H"pyrazole Icarboxamide (from

(24-4) N-(3',4'-Dichloro-II'-biphenyl-2-yl)-5-fluoro-l,3-dimercapto 15 ° than saliva-4-carboxamide ( Known from WO 00/14701),

(24-5) N-(4,_Chloro-3,-fluoro-1,1,-biphenyl-2yl)-2_indolyl-4_(trifluoromethyl)-1,3-thiazole-5 Carboxylamamine (known from W〇03/066609), as shown below. 61-200810691

(24_6) N-(4', chloro], 1, 4-biphenyl-2-yl)-4-(difluoroindolyl)_2_ fluorenyl^ thiour·5_carboxamide (from WO 03/066610) Known), such as ^3

(24-7) N-(4'-bromo-1,1'-biphenyl-2-yl)-4-(difluoromethyl)-2_methyl 11 saponin-5-: decylamine (from Known in WO 03/066610, as follows

15 2〇(24-8)4-(Difluoromethyl)-2-methyl-N_[4'-(trifluoromethyl)-1, fluorene-linked phenyl]-1,3-thiazole-5 Carboxylamamine (known from WO 03/066610), the following formula -62- 200810691

5 Compound (6-7), carpropamid has three asymmetrically substituted carbon atoms. Therefore, the compound (6-7) may be present in a mixture of different isomers or in a single component form. A particularly preferred compound is (lS,3R)-2,2-dichloro-N-[(1R)-1_(4-chlorophenyl)ethyl]-1·ethyl-3-indole-10-ylcyclopropanecarboxylate Amine, as follows

CI 15 and (1 R,3S)-2,2_Dichloro_N-[( 1 R)_ 1 -(4-chlorophenyl)ethyl]-1 -ethyl-3-methylcyclopropanecarboxylate Guanamine, as follows

CI 20 Particularly preferred active compounds of categories (2) to (24) are the following active compounds: (2-1) azoxystrobin (2-2) fluoxastrobin -63- 200810691 (2-3) (2Ε)-2-(2·{[6-(3-chloro-2-indolylphenoxy)-5•fluoro-4-pyrimidinyl]oxy}phenyl)-2-(indenyl imine) -N-mercaptoacetamide (2-4) trifloxystrobin (2-5) (2Ε)·2-(nonoxyimino)-fluorene-fluorenyl 5 -2-( 2-{[({(1Ε)·1·[3-(Trifluoromethyl)-phenyl]ethylidene)amino)oxy]indolyl}phenyl)acetamidamine (2-6) (2Ε )-2-(indenyloxyimido)-indole_indenyl-2-{2-[(Ε)-({1-[3-(difluoroindolyl)phenyl]-ethoxy}imine Methyl]phenyl}acetamide (2-8) 5-methoxy-2-methyl-4-(2-{[({(1Ε)-1-[3-(difluoromethyl)) Phenyl] 1 〇ethylidene}-amino)oxy]indolyl}phenyl)_2,4_dihydro_3Η_1,2,4_triazin-3-one (2-9) 克收欣 (kresoxim ) thiol (2-10) fenfluramine ((^111〇乂}^1; 1: 〇1^11) (2-11) oxytocin 酉 (卩1(;〇乂3^1;1 :〇1^11) 15 (2-12) 百克敏(pyraclostrobin) (2-13) phenoxybacteria (11161; 〇11^11〇51; 1: 〇1^11) (3-3) Sitting on the mouth (propiconazole) (3- 4) difnoconazole (3-6) cyproconazole 2 〇 (3-7) hexaconazole (3·8) pingke (penconazole) (3-9) McAfee ( Myclobutanil) (3_10) tetraconazole (3 -12) epoxiconazole 200810691 (3·13) flusilazole (3·15) prothioconazole (3-16) Fenbuconazole (3-17) tebuconazole 5 10 15 20 (3 -18) ipconazole (3-19) metconazole (3_20) triticonazole (triticonazole) 3-21) bitertanol (3-22) triadimenol (3-23) triadimefon (3-24) fluquinconazole (4_1) diphlofluanid (4-2) tolylfluanid (5-1) iprovalicarb (5-3) benthiavalicarb (6-2) boscalid (6-5) Ethamycin (ethaboxam) (6-6) cyclohexamid (6_7) gpropamine (6-8) 2-chloro-4-[(2-fluoro-2-methylpropane) Amidino)-amino]-N,N-dimercaptobenzamine (6-9) fluopicolid (6-10) benzoxamide (2 〇 311^(16) (6_11) 3 , 4_Dichloro-N-(2-cyanophenyl)isothiazol-5-carboxyguanamine-65- 200810691 (6-14) penthiopyrad (6-16)Ν-[2 -(1,3-Dimercaptobutyl)phenyl]-1-mercapto-4-(trifluoromethyl)-1Η-pyrrole-3-carboxamide (6-17) fluolanil 5 10 15 20 (6-18)Ν-〇(1,3_Dimethylbutyl)phenyl]_5_fluoro-1,3_didecyl-1H-port toxazole-4-carboxyguanamine (6_25 N-{2-[3-chloro-5-(trifluoromethyl)-2. Bipyridyl]ethyl}_2_trifluoromethylbenzamide (7-1) zinc-manganese (mancozeb) (7-2) manganese napo (maneb) (7-4) sulfhydryl zinc (propineb) (7-5) thiram (7-6) Zinna (zineb) (8-1) Benalaxyl (8-2) Furalaxyl (8-3) Metalaxyl (8-4) metalaxyl-M (8-5) benalaxyl-M (9-1) cyprodinil (9-2) (mepanipyrim) (9-3) Pyrimamine (pyrimethanil) (10-1) 6-chloro-5-[(3,5-diamidazosin-4-yl)sulfonyl]-2 , 2 · difluoro-5 Η-[1,3] bismutho[4,5_f]_benzimid. Sit (10-3) carbendazim -66- 200810691 (11-1) diethofencarb (11 -2) propamocarb (11 -3) propamocarb _ Hydrochloride (11 -4) propamocarb - fosetyl 5 (12-2) captan (12-3) folfet (12-4) Iprodione (12-5) procymidone (13-1) dodine ίο (13-2) guazatine (13_3) gram heat (acetate) (iminoctadine triacetate) (14_1) cyazofamid (14_2) prochloraz (14-3) triazoxide 15 (15-4) fenpropimorph (15_5) dimethomorph (16-2) fludioxonil (17·1) Fossyl-Al (17-2) phosphonic acid 2〇 (17-3) tolclofos-methyl (19-1) ) Acibenzolar-S-methyl (19-2) chlorothalonil (19-3) cymoxanil (19-5) suffix (famoxadone) -67- 200810691 (19-6) fluazinam (19-7) Copper oxychloride (19-9) oxadixyl (19-10) Fusarium (19-10) 3卩11:〇\&11111^) 5 (19_21) cyprosulfamide (19_22) mandipropamid (20_1) pencycuron (20-2) thiophanate-methyl (22-1) 5-Gas·Ν-[(18)-2,2,2·Trifluoroindolylethyl]_6-(2,4,6-trifluoro)phenyl][1,2,4]-triazole And [l,5-a]pyrimidin-7-amine (22-2) 5-chloro-N-[(1R)_1,2·dimercaptopropyl]-6-(2,4,6-trifluoro Phenyl)[1,2,4]triazolo[l,5-a]-pyrimidin-7-amine (22-4) 5-chloro-6-(2,4,6-trifluorophenyl)- 7-(4-methylpiperidin-1-yl)[1,2,4]-triazolo[l,5-a]pyrimidine 15 (23-1) 2-butoxy-6-moth-3- Propyl 弁ϋ 弁ϋ 喃 酉 酉 酉 23 (23·2) 2-ethoxy-6-iodo-3 propyl benzofuran _4 ketone (23-3) 6 · 峨-2- propyl Lacto-3-propyl benzopyrene than -4-pyrene (24-1) Ν-(3,4匕 dichloro-5-fluoro-1,1 biphenyl-2-yl)-3_(two Fluoromethyl)-1-mercapto-1H-pyrazole-4-carboxamide 20 (24-3) 3-(trifluoromethyl)·Ν-{3 fluoro-4'_[(E)_( Nonyloxyimido)indenyl]- 1,1 f-biphenyl-2-yl}-1-indenyl-1 ϋ-4--4-anthracene (24-7) N-(4f-> Odor-1,1'-biphenyl-2-yl)-4-(dimethylmethyl)_2.indolyl-1,3_嗟峻-5- oxoamine. Very particularly preferred active compounds of categories (2) to (24) are the following active compounds: -68 - 200810691 (2-2) fluoxastrobin (2-3) (2E)-2-(2-{[6 -(3-Chloro-2-mercaptophenylyl lactyl)_5_fluorodecyl]oxy}phenyl)-2-(methoxyimino)-fluorenyl-mercaptoamine (2-4) trifluoro-sensitive (trifloxystrobin) 5 (3_15) prothioconazole (3 -17) tebuconazole (3-18) ipconazole (3-20) triticonazole (3-21) Biertanol ίο (3-22) triadimenol (3 -24) fluquinconazole (4-1) diphlofluanid (4-2) methyl effluent (tolylfluanid) (5·1) iprovalicarb 15 (6·6) cyclohexamid (6-7) carpropamid (6-9) fluopicolid (6-14) ) penthiopyrad (6-17) flutolanil 2〇(6-18)Ν-[2-(1,3·didecylbutyl)phenyl]-5-fluoro _1,3_Dimethyl-1H-portyrazole-4-propanolamine (6-25)Ν-{2-[3-chloro-5-(trifluoromethyl)-2-piperidinyl] Ethyl 2-trifluoromethanebenzamide (7-4) decyl zinc is a propineb -69- 200810691 (7-5) Thiram (8-3) metalaxyl (8-4) metalaxyl-M (8-5) benalaxyl-M 5 (9-3) Amine (pyrimethanil) (10_3) fenfendicarb (11 _4) propamocarb _ fosetyl (12-4) iprodione (14-2) poker pull (prochloraz ) ίο (14-3) 口口口aziazine (triazoxide) (16-2) 护理宁 (fludioxonil) (17-3) 脱克松(tolclofos_methyl) (19-10) Fusarium (3 port 11 :〇叉&1111116) (19-21) cyprosulfamide 15 (19-22) mandipropamid (20-1) penmone (pencycuron) (22-4)5 -Chloro-6·(2,4,6-trifluorophenyl)-7_(4-mercaptopiperidin-1yl)[1,2,4] triterpene [l,5-a] mouth bite (24_ 1 )N-(3',4f-dichloro_5-gas-I,!/-biphenyl-2-yl)_3-(dimurazolyl)-1_ 2〇methyl-111-吼-4- Rebel amine. Particularly preferred mixed objects are the following active compounds: (2-2) fluoxastrobin (2-4) trifloxystrobin (3-15) thiosulfate saliva (mouth 1*〇1]^〇 ( ;〇11&2〇16) -70- 200810691 (3-17) tebuconazole (3-18) ipconazole (3-20) triticonazole (3-22) three tailong (triadimenol) (6-7) carpropamid (6·18) N-[2-(l,3-dimercaptobutyl)phenyl]-5-fluoro-1,3-dimethyl _1H_ carbazole-4-carboxamide 10 15 (6-25) N-{2-[3-chloro-5-(trifluoromethyl)-2-acridinyl]ethyl b 2-trifluoromethyl Benzoylamine (7-5) thiram (8-3) metalaxyl (8-4) metalaxyl _M (19-21) cyprosulfamide (20_ 1) Pencycuron (24-1) Ν·(3',4'-Dichloro-5-fluoro-1, Γ-biphenyl-2-yl)-3-(difluoromethyl) Small indolyl-1H-pyrazole-4-carboxamide. The active compound compositions highlighted are shown in the following table: Class 1 Active Compounds 2 to 24 Active Compounds (la) (2-2) Fluorostrobin (la) (2-4) trifloxystrobin (la) (3-15) prothioconazole (la) (3-1 7) tebuconazole (la) (3-18) species of mites (^) (: 〇 1 ^ (^) (la) (3-20 ^ _ ^ (triticonazole) (la) (3 -22) three Triadimenol (la) (6-7) gpropamine (carpropamid) -71 - 200810691 Class 1 active compound 2 to 24 active compounds (la) (6-18) N-[2-(l,3- Dimercaptobutyl)phenyl]-5_fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide (la) (6-25)Ν·{2-[3-chloro-5 -(Trifluoromethyl)-2-.pyridyl]ethyl b 2-trifluoromethylbenzamide (la) (7-5) thiram (la) (8-3) Metalaxyl (la) (8-4) metalaxyl-M (la) (19-21) cyprosulfamide (la) (20-1) pcencuron (pencycuron) La) (24-l) N-(3',4f-Dichloro-5-fluoro_1, Γ_biphenyl-2-yl)-3·(difluoro-methyl)-1-methyl-1Η- Oralazol-4-carboxamide (lb) (2_2) fluoxastrobin (lb) (2-4) trifloxystrobin (lb) (3-15) prothioconazole (lb) (3-17) tebuconazole (lb) (3-18) ipconazole (lb) (3-20) ring fungus (1:111^〇11^2〇16) ( Lb) (3-22) Three Tailong (1:^^(1丨111€11〇1) (lb) (6-7) gupamine (car Propamid) (lb) (6-18) Ν-[2-(1,3-dimethylbutyl)phenyl]-5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxylate Indoleamine (lb) (6-25) N-{2-[3-chloro-5-(trifluoromethyl)-2-cyclopyridyl]ethyl}-2-trifluorodecylbenzamide (lb) (7-5) thiram (lb) (8 -3) metalaxyl (lb) (8 _4) metalaxyl-M (lb) (19-21) Cyprosulfamide (lb) (20-1) pencycuron -72- 200810691 Class 1 active compound 2 to 24 active compounds (lb) (24-l) N-(3', 4' ·Dichloro-5-fluoro-l,lf·biphenyl)-3-(difluoromethyl)_1·methyl-1Η_σ-biazole-4-carboxyguanamine (Ic) (2-2) Fluoramine (fluoxastrobin) (Ic) (2-4) trifloxystrobin (Ic) (3-15) prothioconazole (Ic) (3-17) tebuconazole (Ic) (3 -18) Inoculum such as (: 〇11〇2〇16) (Ic) (3-20) Triticonazole (Ic) (3-22) Triadimenol (Ic) (6-7 ) carpropamid (Ic) (6-18) Ν·[2_(1,3·didecylbutyl)phenyl]-5_fluoro-1,3-dimethyl-1H-pyrazole- 4-Carboxyguanamine (Ic) (6-25)Ν_{2-[3·Chloro·5-(trifluoromethyl)-2_acridine ]ethyl}-2-trifluoromethylbenzamide (Ic) (7,5) thiram (Ic) (8-3) metalaxyl (Ic) (8-4) Metalaxyl-M (Ic) (19·21) cyprosulfamide (Ic) (20-1) pencycuron (Ic) (24-1) Ν·(3' , 4'-Dichloro-5-fluorobiphenyl-2-yl)-3-(difluoromethyl)-1-methyl-1Η-σ-pyrazole-4-carboxyguanamine The invention emphasizes the specificity for treating seeds Examples include (la) and fluoxastrobin (2-2) and / or trifloxystrobin (2_4) and / or prothi〇 conaz〇le (3_15) and / Or tebuconazole (3-17) and / or inoculum -73- 5 200810691 (ipconazole) (3_18) and / or triticonazole (3-20) and / or three tailong (triadimenol) (3_22) and / or carpropamid (6-7) and / or N-[2-(l,3-dimethylbutyl)phenyl]_5_fluoro", ^ dimercapto 1H _Pyrazole-4-carboxyguanamine (6-18) and/or team {2-[3_Chloro-5-(trifluoromethyl)_2·-pyridinyl] 5 ethyl}-2-(trifluoro Methyl)benzamine (6_25) and/or thiram (7-5) and / or metalaxyl (8_3) and / or halal (metalaxyl)-M(8_4) and/or N_({4-[(cyclopropylamino)carbonyl]phenyl}sulfonyl)-2-methoxybenzimidamide (19-21) and / Or pencycuron (20_l) and / or n-(3,,4'-dichloro-5-fluoro-1,1,-biphenyl-2-yl)-3-(difluoromethyl) A mixture of 1-mercapto-1H-pyrazole-4-carboxyguanamine (24-1). The present invention emphasizes that the specific embodiment for treating seeds also includes (Ib) and fluoxastrobin (2-2) and/or trifloxystrobin (2-4) and/or prothiotoxin. (pr〇thi〇conazole)(3-15) 15 and/or tebuconazole (3_17) and/or ipconazole (3_l 8) and/or tritic〇nazole (3- 20) and / or triadimenol (3-22) and / or carpropamid (6_7) and / or N-[2-(l,3-dimethylbutyl)phenyl] winter Fluoro-;^dimethyl-1Η_σ-pyrazole-4-carboxamide (6-18) and/or Ν-{2-[3-chloro-5-(trifluoromethyl)-2-indolyl] 20 ethyl}_2_(trifluoromethyl)benzoguanamine (6-25) and/or thiram (7-5) and/or metaaXyi (g_3) and/or annihilation Metalaxyl-M(8-4) and/or N_({4_[(cyclopropylamino)methyl]phenyl}sulfonyl)-2-nonyloxybenzamide (19_21) / or clone (pencycuron) (2 (M) and / or team (3,,4,-dichloro_5_ fluorine_ 1,1,_biphenyl_2-200810691 base)-3-(difluorodecyl) a mixture of 1-methyl-1H-pyrazole-4-carboxyguanamine (24-1). The present invention emphasizes the use of seeds for treatment. The embodiment also includes (Ic) and fluoxastrobin (2-2) and/or trifloxystrobin (2_4) and/or prothioconazole (3-15) 10 15 20 and / or tebuconazole (3-17) and / or ipconazole (3-l 8) and / or triticonazole (3-20) and / or three tailong (triadimenol (3-22) and / or carpropamid (6-7) and / or N_[2-(l,3_monomethylbutyl)phenyl]-5-fluoro_1,3_ Dimercapto·1Η_ϋ than saliva•4_carboxamide (6-18) and/or Ν-{2_[3ϋ(trifluorodecyridinyl)ethyl}-2-(trifluoromethyl)benzoquinone Amine (6_25) and/or thiram (7-5) and / or metaaXyi (g_3) and / or metalaxyl _M (8-4) and / or N_ ({ 4_[(cyclopropylamino)methyl]phenyl}sulfonyl)-2-methoxybenzamine (19_21) and/or clone (penCyCUr〇n) (20_l) and / or N_( 3,, 4, _ two gas _5_ fluoro·u, biphenyl 4 yl)-3-(diindole) sulfhydryl group Η η η than salicylamine (24_ υ mixture 0 except from 1 In addition to the active compound of the formula (1), the active compound composition according to the invention still contains at least Selected from (2) to the active compound class of ⑽. In addition, it may also contain other fungicidal active additives. When the active compound compositions according to the invention comprise certain weight ratios of the active compounds, their synergistic potency is particularly pronounced. The active compound composition: the active compound weight ratio can vary over a considerable range. By hanging, the active compound composition according to the present invention comprises a compound of the formula (1) activated from 75 to 200810691 and a mixed object selected from the group consisting of 2 to 24, and the mixing ratio examples thereof are shown in the following table. The mixing ratio is based on the weight ratio. It is understood that this ratio refers to the active compound of formula (I): a mixed object. Mixed objects are preferred for mixing ratios. Mixing ratios (2): strobilurins 100 : 1 to 1: 2000 50 : 1 to 1: 1000 (3): triazoles 100 : 1 to 1 : 2000 50 : 1 to 1: 1000 (4): sulfenamide 500 : 1 to 1: 10 250 : 1 to 1: 1 (5): amidoxime 100 : 1 to 1: 2000 50 : 1 to 1: 1000 (6): Carboxylamamine, except (6-6) 100 : 1 to 1: 2000 50 : 1 to 1: 1000 (6-6) 500 : 1 to 1 ·· 10 250 : 1 To 1: 1 (7): Dithiol phthalate 500 : 1 to 1: 10 250 : 1 to 1: 1 (8): mercaptoalanine 100 : 1 to 1: 2000 50 : 1 To 1: 1000 (9): Anilinopyrimidines 500 : 1 to 1: 10 250 : 1 to 1: 1 (10): Benzimidazoles 125 : 1 to 1: 2000 50 : 1 to 1: 1000 (11) Class: Aminic acid vinegar 500 : 1 to 1: 10 250 : 1 to 1: 1 (12): Dicarbimine 500 : 1 to 1: 10 250 : 1 to 1: 1 (13) Class: Terpenoid 125 : 1 to 1: 2000 50 : 1 to 1: 1000 (14) Class: Imidazole 125 : 1 to 1: 2000 50 : 1 to 1: 1000 (15): Morpholine 125 : 1 to 1 ·· 2000 50 : 1 to 1: 1000 (16) Category: Pyrrole 125 : 1 to 1 ·· 2000 50 : 1 to 1: 1000 (17) Category: (Sulfur) Phosphonate 500 : 1 to 1: 10 250 : 1 to 1: 1 (18): Phenylacetamide 125 : 1 to 1: 2000 50 : 1 to 1: 1000 -76- 200810691 Mixed mixing ratio Mixing ratio (19-1): Acibenzolar-S-methyl 125: 1 to 1: 2000 50 : 1 to 1: 1000 (19-2): tetrachloroisophthalonitrile ( Chlorothhalonil) 500 : 1 to 1: 10 250 : 1 to 1: 1 (19-3): cymoxanil 125 : 1 to 1: 2000 50 : 1 to 1: 1000 (19-4): granules (edifenphos) 125 : 1 to 1: 2000 50 : 1 to 1: 1000 (19-5): Where to kill (famoxadone) 125 : 1 to 1: 2000 50 : 1 to 1: 1000 (19-6): Fluazinam 125 : 1 to 1: 2000 50 : 1 to 1: 1000 (19-7): Copper oxychloride 500 : 1 to 1: 10 250 ·· 1 to 1 : 1 ( 19-8): Copper hydroxide 500 : 1 to 1: 10 250 : 1 to 1: 1 (19-9): oxadixyl 125 : 1 to 1: 2000 50 : 1 to 1: 1000 (19 -10): Fusarium Spiroxamine 125 : 1 to 1: 2000 50 : 1 to 1: 1000 (19-11) dithianon 500 : 1 to 1: 10 250 : 1 to 1: 1 (19-12) Ketox (]\^ plus £611〇1^) 125 : 1 to 1: 2000 50 ·· 1 to 1: 1000 (19-13) ftamidone _ (fenamidone) 125 : 1 to 1: 2000 50 : 1 to 1: 1000 (19_14): 2,3-dibutyl_6_ gas thieno-[2,3-d]pyrimidin-4(3H)-one 125 : 1 to 1: 2000 50 : 1 to 1: 1000 (19-15): Probenazole 125 : 1 to 1: 2000 50 : 1 to 1: 1000 (19-16): Isoprothiolane 125 : 1 to 1: 2000 50 : 1 to 1 : 1000 (19-17): kasugamycin 125 : 1 to 1: 2000 50 : 1 to 1: 1000 (19-18): phthalide 125 : 1 to 1: 2000 50 : 1 to 1: 1000 -77- 200810691 Mixed objects are better than others. (19-19): Fermizone 125 : 1 to 1: 2000 50 ·· 1 to 1: 1〇〇 0 (19-20): Tricyclazole 125 : 1 to 1: 2000 50 : 1 to 1: 1〇0〇 (19-21): cyproteril 125 : 1 to 1: 2000 50 : 1 To 1: 1〇〇〇 (cyprosulfamid e) (19-22) 2-(4-chlorophenyl)-N-{2-[3-methyl 125 ·· 1 to 1: 2000 50 : 1 to 1: 1 methoxy-4-( Propion-2-ytyl-1-yloxy)phenyl]ethyl}-2-prop-2-yn-1-yloxy)acetamide (20): (thio)urea derivative 125 : 1 to 1 : 2000 50 : 1 to 1: 1 〇〇〇 (21): guanamine 125 : 1 to 1: 2000 50 : 1 to 1: 1 〇〇〇 (22) · triazolopyrimidine 125 : 1 to 1: 2000 50 : 1 to 1: 1 〇〇〇 (23) · chromone 125 : 1 to 1: 2000 50 : 1 to 1: 1 〇〇〇 (24): biphenyl carboxylate Indoleamine 125 ·· 1 to 1: 2000 50 : 1 to 1: 1 In each case, the mixing ratio selected should be a synergistic mixture. The mixing ratio between the compound of the formula (i) and the compound of the formula (2) to (24) may vary between the respective compounds. 5 The active compound composition according to the invention has excellent fungicidal properties and is suitable for controlling phytopathogenic fungi, such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromycetes, and so on. -78- 200810691 The active compound compositions according to the invention are particularly suitable for controlling Phytophthora infestans, plasm〇para viticola and B〇trytis cinerea. As described above, some of the fungal and bacterial diseases are caused by the common name. The pathogens indicated by the common name are for illustrative purposes only and are not limited: According to the present invention, the active compound composition has a strong microbicidal action and can be used for protecting crops and protecting raw materials. Do not use microorganisms such as fungi and bacteria. Fungicides can be used in the crop protection law to control the roots of the bacteria ίο (Plasmodiophoromycetes), Inobacterium (Oomycetes), Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and know-how Deuteromycetes can be used in the crop protection method to control Pseudomonadaceae, Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae and Streptomycetaceae. Some cause fungal and bacterial diseases. The pathogens indicated by the common name are for illustrative purposes only and are not limited: 2) pathogens causing powdery mildew, such as, for example, Blumeria species, such as, for example, wheat powdery mildew. (Blumeria graminis); Podosphaera species, such as, for example, Podosphaera leucotricha; -79- 200810691 For Sphaerotheca species, eg, for example, melon to powdery mildew (Sphaerotheca) Fuliginea); Uncinula species, such as, for example, · Uncinula necator; 5 causes pathogenic bacteria such as: gyros genus (Gymnosporangium species), such as, for example, Gymnosporangium sabinae, Hemileia species, such as For example: Hemileia vastatrix; ίο Phakopsora species, such as, for example, Phakopsora pachyrhizi and Phakopsora meibomiae; Puccinia species, For example, wheat leaf rust (Puccinia recondita); 15 Uromyces species, such as, for example, Uromyces appendiculatus; diseases caused by Oomycetes pathogens, such as, for example: Bremia species, such as, for example, Bremia lactucae; 2 Peronospora species, such as, for example, Peronosporapisi or P. brassicae Phytophthora species, such as, for example, Phytophthora infestans; Plasmopara species, eg, · Raw grapes as single-axis 200,810,691 mildew (? 1&5111(^&^¥ also (:〇1&); Pseudomonas genus (?5611 (1〇卩61*01105卩0^3卩6(^63), eg, for example: hop fake cream Pseudoperonospora humuli or Cucumber for Pseudoperonospora cubensis; 5 Pythium species, such as, for example, Pythium ultimum; pathogens causing leaf spot and leaf blight, such as: Alternaria (Otto) "^1^3卩6 (^8), such as, for example, Alternaria solani; ίο Cercospora species, such as, for example, B. cinerea (Cercospora beticola); Cladiosporium species, such as, for example, Cladiosporium cucumerinum; Cochliobolus species, such as, for example, Cochhobolus sativus (Conidia type: Drechslera, synonym: Helminthosporium); Colletotrichum species, such as, for example, Colletotrichum lindemuthanium; Peacock genus (0}^1〇(;01^111113 Mouth 6 (^3), such as, for example, oily 20 孑L sphaeroides (Cy Cloconium oleaginum); Diaporthe species, such as, for example, Diaporthe citri; Elsinoe species, such as, for example, Elsinoe fawcettii • 81 - 200810691 Gloeosporium species, such as, for example, Gloeosporium laeticolor; Glomerella species such as, for example, Glomerella cingulata; Guignardia species, such as, for example, Guignardia bidwelli; Leptosphaeria species such as, for example, Leptosphaeria maculans; Magnaporthe species For example, such as: Magnaporthe grisea; Mycosphaerella species, such as, for example, Mycosphaerelle graminicola; Phaeospharia species, such as, for example, · Phaeosphaeria nodorum; 15 Pyrenophora species, such as, for example, barley mesh spot (Pyreno) Phoraaria species; such as, for example, Ramularia collo-cygni; Rhynchosporium species, such as, for example, Rhynchosporium secalis; Actinobacillus (Septoria species), for example, Septoria apii; Typhula species, such as, for example, Typhula incarnata; -82 - 200810691 Ventura species, such as, for example, Venturia inaequalis; pathogens causing root and stem diseases, such as: Phytophthora ([011^丨111118口6(^8) For example,: Corticium graminearum, Fusarium species, such as, for example, Fusarium oxysporum; Gaeumannomyces species For example,: Gaeumannomyces graminis; ίο Rhizoctonia species, such as, for example, Rhizoctonia solani;

Tapesia genus, for example, Tapesia acuformis; Thielaviopsis species, such as, for example, Thielaviopsis basicola; 15 Pathogens causing ear and cone disease (including cornstalk), such as: Alternaria species, such as, for example, Alternaria spp.; Aspergillus species, such as, for example, Aspergillus flavus; 2 Cladosporium ( Cladosporium species, such as, for example, Cladosporium spp.; Claviceps species, such as, for example, ciaviceps purpurea; Fusarium species, such as, for example. : Fusarium oxysporum - 83 - 200810691 (Fusarium culmorum); Gibberella species, such as, for example, Gibberella zeae; Monographella species, such as, for example, red snow 5 Monographella nivalis; a pathogen causing smut, such as, for example, Sphacelotheca species, such as, for example, Sphace Lotheca reiliana); Tilletia species, such as, for example, wheat net 腥ίο illetia caries; Urocystis species, such as, for example, rye bar black spikes Urocystis occulta; Ustilago species, such as, for example, Ustilago nuda; 15 pathogens causing fruit rot, such as: Aspergillus species, such as, for example: Aspergillus flavus; Botrytis species, such as, for example, Botrytis cinerea; 2 Penicillium species, such as, for example, Penicillium expansum; Sclerotinia species, such as, for example, Sclerotinia sclerotiorum; Verticilium species, such as, for example, cotton withering-84-200810691 pathogen (Verticilium alboatrum); causing seeds And soil-borne rot, and pathogens of seedling diseases, such as: Fusarium species, such as, for example, Fusarium culm 5 Orum); Phytophthora species, such as, for example, Phytophthora cactorum; Pythium species such as, for example, Pythium ultimum; Rhizoctonia genus Rhizoctonia species), for example, Rhizoctonia solani; Rhodobacter genus (8 (; 161:0 7111113卩6 (^68), eg, for example: 8 (:161: €^11111) Rolfsii ; a pathogen causing cancer, insects and brooms' broom, 15 eg: Nectria species, such as, for example, Nectria galligena; causing pathogens of wilting For example: Monilinia species, such as, for example, Monilinia laxa; pathogens that cause deformation of leaves, flowers and fruits, such as: Taphrina species, such as: peach Taphrina deformans; pathogens causing degradation of woody plants, for example: -85- 200810691

Esca genus, such as, for example, Phaemoniella clamydospora; pathogens causing flower and seed diseases, such as: Botrytis species, such as, for example, Botrytis cinerea; 5 pathogens causing plant bulb disease, for example : Rhizoctonia (111^0(;1; 01^8 6 (^5), eg, Rhizoctonia solani; a disease of a bacterial pathogen such as, for example, leaf blight Xanthomonas species, such as, for example, Xanthomonas campestris pv. oryzae; Pseudomonas species, such as, for example, Pseudomonas syringae ρν. lachrymans Erwinia species, such as, for example, Erwinia amylovora, preferably control the following soybean diseases: fungal diseases of leaves, stems, pods and seeds, for example: Alternaria (Alternaria) Spec· atrans tenuissima), anthrax (Colletotrichum gloeosporoides dematium var. 2〇truncatum), brown spot (Septoria glycines), purple Spot disease (Cercospora kikuchii), Choanephora infundibulifera trispora (Syn·), red leaf spot (Dactuliophora glycines), downy mildew (Peronospora manshurica) , leaf bar disease (Drechslera glycini), -86- 200810691 spot disease (Cercospora sojina), clover leaf spot (Leptosphaerulina trifolii), gray star disease ( Phyllostica sojaecola, powdery mildew (Microsphaera diffusa), leaf blight (Pyrenochaea 5 glycines), shoots, leaf blight and seedlings Disease (Rhizoctonia solani), pound disease (phakopsora pachyrhizi), round disease (Sphaceloma glycines), black mold (chili black mold) (Stemphylium botryosum)), spot disease (Corynespora assiicola) 〇10 causes fungal diseases of roots and stems, such as: black rot (Calonectria crotalariae), charcoal Rot (Macrophomina phaseolina), wilting or withering caused by sputum bacteria, root rot and fruit and neck rot (Fusarium oxysporum), 15 彖σ彖(Fusarium orthoceras), Fusarium semitectum, Fusarium equiseti, Streptomyces root rot (Mycoleptodiscus terrestris), pod black spot (Neocosmospora vasinfecta), pod and stem wilt (Diaporthe phaseolorum), stem canker (Diaporthe phaseolorum var. caulivora), sweet pepper blight (Phytophthora) Megasperma)), Phialophora gregata, wheat mites (pythium aphanidermatum, Pythium irregulare, Pythium debaryanum, ginger soft rot) Pythium -87- 200810691 myriotylum), pythium uitumum, root rot, stem disease and larvae (Rhiz〇ctonia solani), sclerotia Disease (/Sclerotinia sclerotiorum), white smut (Sderotinia rolfsii), pseudo-black root rot (Thielavi〇psis 5 basicola). The plants are well tolerated at the concentrations required for controlling the plant diseases of the active compound composition, so that the whole plants (plant tops and roots), reproductive branches and seeds, and soil can be treated. The active compound compositions according to the invention can be used for application of leaves or as seed coatings. 10 Plants are well tolerated at the concentrations required for the active compound to control plant diseases, thus allowing the seed to be treated. Therefore, the active compound composition according to the present invention can be used as a seed coating. Most crop injuries are caused by seeds during storage, after sowing seeds into the soil, during plant germination, or immediately after germination. This is particularly important because the roots and shoots of growing plants are particularly sensitive, and even minor injuries can cause pruning plants to die. Therefore, the use of suitable compositions to protect seeds and planting plants in germination is particularly worthy of attention. The main method of controlling injury to plants after germination is to use soil protection agents to treat soil and plant shoots. Since crop protection agents can impact the environment and human and animal health, efforts are needed to reduce the amount of active compound. It has long been known to control plant pathogenic fungi by treating plant seeds and still in the process of improvement. However, when dealing with seeds, there are often problems that cannot be solved in a satisfactory manner. Therefore, there is a need to develop a bacterium to avoid the additional application of a crop protection agent after sowing or plant germination or a method of reducing the protection of other seeds and the germinated plants by other agents. In addition, it is also desirable to use the active compound in an amount sufficient to maximize the degree of protection of the seed and the germinating plant against phytopathogenic fungi and from the active compound which is harmful to the plant itself. In particular, the method of seed treatment should also consider the inherent fungicidal properties of the transgenic plants so that the dragons and germinations are properly protected at the lowest crops (4). The invention is therefore particularly directed to methods of using the compositions according to the invention to protect seeds and germinating plants from phytopathogenic fungi. The invention is also related to the use of a composition according to the invention for treating seed to protect pathogenic and germinating plants from pathogenicity. Further, the present invention relates to seeds which are treated according to the composition of the present invention to protect against phytopathogenic fungi. The nature of the whole plant according to the date of the present day, the whole plant 2, which means that the seed composition is treated with good quality and can protect the seed and can be protected (4) after growing, the plant is grown, free of plant 2: in this way, it does not need to During the sowing of the crop or after sowing; in the case of the conversion = the amount of Xiefa Nisaki (4) can also be used = the composition of the invention is suitable for protecting any seed of the plant variety used in agriculture, greenhouse, Mori, 1%. Specifically, it refers to cockroaches (eg, rye barley, rye, millet and oats), corn, cotton, soybeans, -89 - 200810691 rice, potatoes, sunflowers, beans, coffee 4, thank you (for example, with sweet ^Feed beet), peanuts, vegetables (such as: "courgette", virgin and lettuce), turf and ornamental plants, etc. Treated with cereals (eg wheat: barley, rye and oats), corn seeds The method is particularly important. In the context of the present invention, the composition according to the invention is applied to the seed, either alone or in a suitable formulation, preferably in the stable state of the seed: to avoid damage during handling. Seeds can be treated at any point between harvest and _. The seeds used are usually separated from the plants and have no rods, shells, stems, coatings, ears or flesh. Therefore, for example, can be used, cleaned, cleaned And drying to a seed having a moisture content of 15% by weight or less. For example, a seed which has been dried after being treated with water may be used. When the seed is treated, it is usually necessary to carefully handle the composition according to the present invention. Use the amount of seed and/or the amount of other additives selected to avoid adversely affecting the seed's teeth' or avoiding damage to the grown plant. This must be done in the heart, especially when the active compound is at certain application rates. May have a phytotoxic effect. The composition according to the invention may be applied directly, i.e. without other ingredients and without the use of any diluent. In general, it is preferred to administer the composition in a suitable formulation. Suitable formulations and methods for treating the seed It is known to those skilled in the art, and is described, for example, in the following documents: US 4,272,417 A, US 4,245,432 A, US 4,808,430 A, US 5,876,739 A, US 2003/0176428 A1, WO 2002/080675 A1, WO 2002/028186 The active compound composition of the invention is also suitable for improving the crop yield - 90. 200810691 1. In addition, its toxicity is reduced and the plant tolerance is good. The active compound composition according to the invention also has a potent strengthening effect in the plant (4). (4) The defense against microbial infestation. In this paper, the understanding of the compound (inducing resistance) of the plant is known as ^Shen the plant defense system, f, # after receiving the unwanted microorganisms, 'the treated plants can show their degree to the microbes. + At this time, do not know the microbial salt, it means the plant disease Sexual fungi, bacteria and viruses. Therefore, according to the present invention, the plant can be secreted against the above-mentioned pathogens for a period of time after the treatment. The time for producing the protective effect is usually after treatment with the active compound for a period of up to 1 day. Preferably, it is from 1 to 7. The plant is well tolerated at the concentration required to control the plant disease of the active compound composition, thereby allowing the plant to propagate the material and seeds, and the soil on the ground. In this case, the effect of the active compound composition according to the invention for controlling cereal diseases is particularly good, for example, against puccinia species, diseases of viticulture and diseases of fruit and vegetable cultivation, such as For example, against Botrytis, Vemuria or Alternaria, the active compound composition according to the invention is also suitable for increasing harvest. In addition, it also exhibits low toxicity and good financial acceptability of plants. If appropriate, the active compound compositions according to the invention may also be employed as herbicides at concentrations and application rates of 200810691 for affecting plant growth and controlling animal pests. If appropriate, it can also be used as an intermediate and precursor for the synthesis of other active compounds. All plants and plant parts can also be treated in accordance with the invention. At this time, 5 salty plants refer to all plants and plant groups, such as wild plants or crops (including natural crops) that are needed and not needed. Crops may be obtained from traditional plant breeding methods and optimization methods or using biotechnology and genetic engineering methods or combinations of such methods, including genetically modified plants, including protected by plant breeders and unprotected. Plant cultivars. It is also salty. The plant part means all the above-ground and underground parts and organs of the plant, $: buds, leaves, flowers and roots. Examples can be described as: broadleaf, needles, shafts, stems, flowers, Fruits, fruits, seeds, roots, bulbs and rhizomes. Plant damage also includes harvested materials, and nutritive and reproductive materials such as 扦15 plugs, bulbs, rhizomes, lychees and seeds. Qiu, according to the present invention, the method for treating plants and plants by using the active compound composition is treated according to the general treatment method, or the compound is applied in the environment, habitat or inventory space, for example, soaking and spraying When sprinkling, producing I spray, spreading, painting, and processing propagation materials, the specific ancient 2 . Cover one or more layers of coating. At this time, the activity: combined with the application of η is prepared by first mixing the respective active compounds. Or after the treatment of the (4) amines, the plant actives may be treated with the active compounds of (2) to (24), or the plant actives may be treated with the active compounds of (2) to (24). Treated with guanamine (1). It is hoped that the compound composition according to the present invention can be used to protect the raw materials of the industry from the unwanted microbial infection and destruction. In this paper, the salty understanding of industrial raw materials refers to inanimate materials for industrial use. For example, industrial raw materials that need to be protected from microbial changes or destruction according to the active compounds of the present invention can be used as adhesives, glues, paper and paperboard, spun fabrics, leather, wood, paints and plastics, cooling lubricants and Other materials that may be infected and destroyed by microorganisms. Parts of the production plant, for example, cooling water circulation lines that may be damaged by microbial growth are also within the scope of the protectable raw materials. Preferred industrial materials which can be mentioned for the purposes of the present invention are adhesives, glues, paper and board, leather, wood, paints, cooling lubricants, and heat transfer liquids, preferably wood. Microorganisms which can decompose or change industrial raw materials can be described, for example, bacteria, fungi, yeasts, algae, and cohesive organisms. The active compound according to the invention is preferably active against fungi, in particular against fungi which inhibits mold, discolors wood and destroys wood (Basidiomycetes), and against mucoids and algae. For example, microorganisms of the following genera may be mentioned: Alternaria such as Alternaria tenuis, Aspergillus such as Aspergillus niger, and shell (0^6沁) 111丨11111) such as: ball shell (〇^6^)111丨1111^1〇130311111), 20 Coniophora such as Coniophora puetana, Lentinus such as: tiger skin Lentinus tigrinus, Penicillium (?611丨(:丨11丨11111) such as: Penicillium grisea (?61^(^11丨1111131&11.11111), Polyporus such as: Polychromic polyporus (p 〇iyp〇rus versicolor), Aureobasidium such as: Aureobasidium -93- 200810691 pullulans,

Sclerophoma such as Sclerophoma pityophila? Trichoderma (Ding also 110 (^111^) such as: Trichoderma viride (1 > 丨 (: 110 (1611113 ¥ 114 (16), Bacillus (Escherichia) such as: Escherichia coli) 5, Pseudomonas such as Pseudomonas aeruginosa, and Staphylococcus such as Staphylococcus aureus 〇 In addition, the active compound composition according to the present invention also has Excellent anti-mythratic activity. It has a wide range of anti-fungal effects on dermatophytes and budding fungi, molds and biphasic fungi (eg against Candida, such as white silk) "Candida albicans, Candida glabrata" and "Epidermophyton floccosum", Aspergillus such as Aspergillus 15 niger and Aspergillus fumigatus , Trichophyton (Trichophyton) such as: Trichophyton mentagrophytes, Microsporon (Microsporon) such as: Microsporon canis (Microsporon canis) and M. variabilis (Mier〇sp〇r〇n audouinii)). These fungis do not limit their mold range for illustrative purposes only. 20 The active compound composition may be used in its own form or in the form of its formulation or made from a formulation. In the form of ready-to-use solutions, suspensions, wettable powders, pastes, soluble powders, fine powders and granules, which can be applied in a conventional manner, for example: washing, spraying, spraying, spreading , dusting, foaming, painting, etc. It can also be applied by ultra-low volume method -94- 200810691 with active compound, New Zealand (four) to soil f. It can also be used to treat plant seeds or active compounds themselves: use according to this When the invention is activated, its application rate can be changed within a considerable dry circumference in the case of 0. When treating a part of the plant, the activity: the application form and the door of 10,000 g/ha, _ Du & The utilization rate is usually between 0.1 and 10,000, and the father is 10 to 1 ,. When the seed is used, the application rate of the active compound is usually between. Between the seeds and the seed, preferably 〇〇1 to 50 g/ When the public soil is used, the application rate of the active compound is usually ^^ It is preferably between i and 5 g/ha between the treated soils. 10, gram per hectare According to the invention, the plants listed are particularly suitable for treatment. The plants are treated as a mixture of the above active compounds and mixed; η. The month does not mean the compound or 15 20

The active compound composition of the invention is also suitable for worms, especially for animal pests in agriculture, animal health, forests, and forests, preferably arthropods and elegans and insects. It is active against general susceptibility and resistance, and against all or some stages of development. The above pests include: Isopoda, such as 〇niscus asellus, Armadillidium vulgare, Porcellio scaber; Diplopoda, for example: Blaniulus guttulatus; Lip From the order of the genus Chilopoda, for example, Geophilus carpophagus and the genus Scutigera spp.; -95- 200810691, which binds to the genus (Symphyla), for example: Scutigerella immaculata. Thysanura, for example: Lepisma saccharina Collembola, for example: Onychiurus 5 armatus Orthoptera, for example: Acheta domesticus , Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria 〇i 〇 B B B (Blattaria), for example: Oriental 棑蠊 ( Blatta orientalis), Periplaneta americana, Leucophaea maderae, Blattella germanica, Dermaptera, for example: Forficula auricularia 〇15, etc. Isoptera, for example: Reticulitermes spp. Phthiraptera, for example, Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalina. Thysanoptera, for example: Hercinothrips 20 femoralis, Thrips tabaci, Thrips palmi, Frankliniella occidentals. Heteroptera, for example: Eurygaster spp., Dysdercus intermedius, Piesema quadrata, Cimex lectularius, Rhodnius prolixus, -96- 200810691 cone Triatoma genus. Homoptera, for example: Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne 5 brassicae, tea Cryptomyzus ribis, Aphis fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis, and Meizhou spears Phylloxera vastatrix), Pemphigus spp., Macrosiphum avenae, Myzus spp., Phorodon humuli, Rhopalosiphum padi, small yellow floats (Empoasca spp.), Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatellus, Brown Fitz (Nilaparvata lugens), Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp., Psylla spp. Lepidoptera, for example: Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Bucculatrix thurberiella, Phyllocnistis citrella ), Agrotis spp., genus Helicoverpa-97- 200810691 genus (Euxoa spp.), genus Feltia spp., Earias insulana, Heliothis spp. ), Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, and Pieris spp. ), Chilo spp·, Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisse Lliella), Tinea pellionella, Hofmannophila pseudospretella, Cacoecia 10 podana, Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Homona magnanima, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae o 15 Coleoptera, for example: Anobium punctatum , Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Potato beetle (Leptinotarsa decemlineata), Loquat leaves Phaedon 2〇cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachnavarivestis, Atomaria, Oryzaephilus surinamensis, cotton boll Weevil (Anthonomus spp.), genus Sitophilus spp., deep groove weevil (Otiorrhynch Us sulcatus), banana bulbous weevil -98- 200810691 (Cosmopolites sordidus), cannabis weevil (Ceuthorrhynchxis assimilis), yp 苜蓿 H (Hypera postica), 鲣 D (Dermestes spp·), 鲣 虫(Trogoderma spp.), Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp. Niptus hololeucus, Gibbium psylloides, Tribolium spp·, Tenebrio molitor, Agriotes spp·, Conoderus spp· ), Melonontha melolontha, June chafer ίο (Amphimallon solstitialis), Costelytra zealandica, Lisorhoptrus oryzophilus o Hymenoptera, for example: Diprion SPP·, leaf bee Genus (Hoplocampa spp.), genus (Lasius spp.), ant (Monomorium pharaonis), Vespa (Vespa spp.). 15 Diptera (Diptera), for example, Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca domestica Musca spp.), Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cutrebra spp., stomach 2 genus (Gastrophilus spp.), Hyppobosca genus, Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia Genus, Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, -99- 200810691 Dacus oleae), Tipula paludosa, Hylemyia spp., Liriomyza spp. Siphonaptera, for example: Xenopsylla cheopis, I. Ceratophyllus spp. 5 Arachnida, for example: Scorpio maurus, Latrodectus mactans, Acarus siro, Argas spp., Ornithodoros Spp.), Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., flower bud Genus (Amblyomma spp.), Hyalomma spp., Ixodes spp., Psoroptes spp., Choriooptes spp., Sarcoptes Spp.), Tarsonemus spp., Bryobia praetiosa, Panonychus spp., 14 species of Tetranychus spp., Hemitarsonemus , Red genus (Brevipalpus spp.) 〇 plant parasitic nematodes include, for example, the genus Pratylenchus SPP, Radopholus similes, Ditylenchus dipsaci, citrus mites ( Tyienchulus 2〇semipenetrans), Hete Rodera genus, Globodera genus, Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp. , Bursaphelenchus genus. Depending on the specific physical and/or chemical nature of the active compound, it can be converted into a general formulation, such as: solution, emulsion, wettable powder, suspension, powder, blister, fine powder, paste. Agents, soluble powders, granules, aerosols, suspension emulsion concentrates, natural and synthetic materials impregnated with active compounds, microencapsulated agents contained in polymeric materials, and coated materials for seeds 5 , and ULV low temperature and heating atomization formulations. The formulations are prepared according to known methods, for example, by mixing active compounds with supplements, ie liquid solvents and/or solid carriers, if desired, surfactants, ie emulsifiers and/or dispersing agents and/or hairs. Foaming agent. When water is used as a supplement, for example, an organic solvent may be used as an auxiliary solvent. Substantially applicable liquid solvents are: aromatics such as: diphenylbenzene, toluene or alkylnaphthalenes, chlorinated aromatics and gasified aliphatic hydrocarbons such as chlorobenzene, chlorinated ethylene or dichlorodecane, aliphatic Hydrocarbons such as cyclohexane or paraffin such as petroleum fractions, mineral oils and vegetable oils, alcohols such as butanol or ethylene glycol and their ethers and esters, ketones such as acetone and mercaptoethyl Ketone, methyl 15 isobutyl ketone or cyclohexanone, a strong polar solvent such as dimethyl decylamine and dioxane, or water. Suitable solid carriers are: For example: ammonium salts and natural mineral mills, such as: kaolin, clay, talc, white ridge, quartz, clay, montmorillonite or shixia, and synthetic mineral mill 20 powder such as: high Dispersed vermiculite, bauxite and silicates. The solid carrier suitable for granules is, for example, a natural ore crushed and divided, such as; calcite, marble, pumice, sepiolite and dolomite or synthetic particles of inorganic and organic milling; and particles of organic matter Such as: sawdust, coconut shell, corn cob and tobacco rod. Suitable emulsifiers and/or foaming agents are, for example, nonionic and -101 - 200810691 anionic emulsifiers such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example: alkaryl polyethylene Alcohol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates or protein hydrolysates. Suitable dispersing agents are, for example, lignin sulfite waste liquid and mercapto cellulose. 5 Adhesives such as carboxymethyl cellulose and natural and synthetic polymer powders, granules or latexes such as gum arabic, polyvinyl alcohol and polyvinyl acetate or natural phospholipids such as cephalin and Lecithin, and synthetic phospholipids. Other additives available are: mineral oil and vegetable oil. It is possible to use dyes such as inorganic pigments such as iron oxide, oxidized 10 titanium and Prussian blue, and organic dyes such as alizarin dyes, azo dyes and metal phthalocyanine dyes and micronutrients such as iron, manganese and boron. , copper, cobalt, molybdenum and zinc salts. The formulation usually comprises from 0.1 to 95% by weight of active compound, preferably from 0.5 to 90% by weight. 15 The active compound composition according to the invention may be in the form of a general commercial formulation and a formulation in which the formulation is mixed with other active compounds, such as: insecticides, baits, infertility agents, bactericides, sputum killers, Nematicides, fungicides, growth regulating substances or herbicides. In particular, insecticides include, for example, phosphates, carbamates, carboxylates, chlorinated hydrocarbons, 20 phenylureas, and substances produced by microorganisms. It may also be admixed with other known active compounds, such as herbicides, or with fertilizers and growth regulators. When used as an insecticide, the active compound composition according to the invention may further form a mixture with the synergist, in the form of its commercial formulation and in the form of administration of the formulation from -102 to 200810691. Synergist means a compound which increases the activity of the active compound but which is not necessarily active per se. The active compound content of the application form made from the formulation commercials can vary widely. The active compound concentration in the application form may range from 5 〇·〇〇〇〇〇〇1 to 95% by weight of the active compound, preferably from 0.0001 to 1% by weight. These compounds can be administered in a conventional manner suitable for the form of administration. The active compound composition has excellent residual efficacy on wood and clay in the case of pests against sanitary pests and stock products, and is well tolerated to alkali on the stone 10 ash matrix. The active compound composition according to the invention is not only active against plant pests, sanitary environment pests and stock product pests, but also can be used in veterinary medicine to combat animal parasites (external parasites) such as soft monuments, hard monuments, / worms, Autumn harvest, ticks and flies, parasitic larvae, crickets, head lice, guanines and 15 fleas. Such parasites include: Anoplurada, for example: Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp. Solenopotes spp. Mallophagida and Amblycerina and Ischnocerina, for example: Trimenopon spp., Menopon spp., Trioton Spp·), Bovicola spp., Werneckiella, Lepikentron, Damalina, Trichodectes spp., Felicola spp. 〇-103- 200810691 Diptera and Nematocerina and Brachycerina, for example: Aedes spp., Anopheles spp., Culex spp ·), Simulium SPP., Eusimulium spp., Phlebotomus 5 spp., Lutzomyia, Culicoides spp., genus (Chrysops spp.), Hyopomia spp., Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia, Braula Genus, Musca spp., Hydrotaea, Stomoxys spp., Haematobia 1 0 spp·), Morellia genus, Fannia spp., Glossina spp., Calliphora spp., Lucilia spp., gold rope Genus (Chrysomyia spp.), Woolfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp. ), 15 genera (Hippobosca spp.), genus Lipoptena, Melophagus spp., Siphonapterida, for example: Pulex spp., brown-headed genus Ctenocephalides spp·), Xenopsylla spp., Ceratophyllus spp. 20 Heteropterida, for example: Cimex spp·, Triatomaspp·, Rhodnisspp·, Panstrongylus spp·, Aphid (Blattaria), for example, Blatt orientalis, Periplaneta Americana, Blattella-104-200810691 germanica, Supella spp. Acaria (Acarida) and Metastigmata and Mesostigmata, for example: 'Argas spp., Orthodox genus (Ornithodorus spp) ·), Otobius spp., Ixodes spp., Amblyomma SPP·, Boophilus spp., Dermacentor spp·, Haemophysalis spp., Hyalomma spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp., lung thorn Pneumonyssus 10 spp·, Sternostoma spp., Varroa sp p·) o Actinedida (Prostigmata) and Acaridida (Astigmata), for example: Acarapis spp., Aphis gossypii Cheyletiella spp.), Ornithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombula spp. ), Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp., Hypodectes, and Pterolichus SPP. ), genus Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., bird worm Genus (Knemidocoptes spp.), genus Cytodites spp., larvae (Lamimosioptes spp.). The active compound composition according to the invention is also suitable for controlling arthropods infesting agricultural livestock animals such as, for example, cattle, sheep, mountain-105-200810691 sheep, horse, pig, donkey, Luo Cong, buffalo, rabbit, chicken , turkeys, ducks, cranes and bees, other livestock animals such as dogs, cats, birds in bird cages and fish in aquariums, and so-called experimental animals such as, for example, hamsters, guinea pigs, rats and Little mouse. By controlling these arthropods, it should be possible to reduce its mortality and improve its productivity (referred to as meat, dairy, wool, hide, egg, honey, etc.), so that it can be achieved with the active compound composition according to the invention. Economic and simple animal management. The active compound compositions according to the invention are used in the veterinary field in a known manner, in the form of enteral administration, for example: tablets, capsules, drink 10, medicated, granules, pastes, boluses, silver Food, suppository, parenteral administration, such as, for example, injection (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.), implantable, intranasal administration, transdermal administration, eg, for example : dipping or soaking, spraying, pouring, dispensing, cleaning and dusting, and by means of molded articles containing active compounds such as: collar, ear hook, tail hanging, foot strap, 15 Xinjiang rope, marking device, etc. Wait. When used in cattle, poultry, livestock animals, and the like, the active compound composition can be applied in the form of a formulation (for example, a powder, an emulsion, a flowable agent) containing from 1 to 80% by weight of the active compound, which can be used as it is. It can be used after diluted 100 to 10,000 times, or it can be used as chemical dipping water. Further, it has been found that the active compound composition according to the present invention has a strong insecticidal action against insects which destroy industrial raw materials. The following insects can be mentioned, which are exemplified and preferred examples, but are not limited: Aphids such as Hylotrupes bajulus, Polychaeta-106-200810691 (Chlorophorus pilosis), furniture stolen (Anobium) Punctatum), Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, 桴粉橐(Lyctus linearis), Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec, Tryptodendron genus, Apate monachus, Bostrychus capucins, European bamboo Heterobostrychus brunneus, Sinoxylon spec, and Dinoderus minutus. Hymenopterans such as: Sirex juvencus, Urocerus gigas, Urocerus gigas taignus ^ Urocerus augur ° Termites such as Kalotermes flavicollis, short termites 15 (Cryptotermes brevis), Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Nevada Zootermopsis nevadensis, Coptotermes 20 formosanus o, such as: Lepismasaccharina. It is understood that the industrial raw materials referred to herein are inanimate materials such as polymers, adhesives, glues, paper and board, leather, wood and processed wood products and coatings. -107- 200810691 It is especially good to use wood and processed wood products to protect the raw materials from insects. It is understood that wood and processed wood products which are protected according to the composition of the invention or mixtures thereof can be used, for example: construction timber, wooden beams, rails 5 sleepers, bridge parts, breakwaters, wooden vehicles, boxes, conveyor tables, containers , electric poles, barrel boards, wooden windows and wooden doors, plywood, cardboard, joinery, or wooden products commonly used in building or construction woodworking. The active compound composition may also be used in the form of a concentrate, or in a conventionally used formulation such as a powder, a granule, a solution, a suspension, a milk solution or a paste. The above preparations can be prepared in a manner known per se, for example, by mixing at least one solvent or diluent, emulsifier, dispersing agent and/or binder or fixative, water flooding agent, and desiccant if necessary. UV stabilizers, and if necessary, dyes and pigments and other processing aids. 15 Insecticidal compositions or concentrates for the protection of wood and board products comprise active compounds according to the invention in a concentration of from 0.0001 to 95% by weight, in particular from 0.001 to 60% by weight. The concentration of the composition or concentrate used will depend on the type of insect and the amount and medium present. The most appropriate amount is easily determined by a series of tests. However, it is usually sufficient to use from 0.0001 to 20% by weight (preferably from 0.001 to 10% by weight) of the active compound of the raw material to be protected. Suitable solvents and/or diluents are organic chemical solvents or solvent mixtures, and/or low volatile oily or oily organic chemical solvents or solvent mixtures and/or polar organic chemical solvents or solvent mixtures and/or water, and -108- 10 15 20 200810691 Emulsifiers and/or humidifiers were used at the time. A more suitable organic chemistry & an oily or oily solvent that is above (with a number of evaporations above 35 and a flash point that is soluble in water and low in volatility). This kind of non-fragrance yam or yoghurt, ^ and ^ 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛In 17 oils around 170 to 2203⁄4, ☆ 2〇C mineral oil, boiling point low viscosity lubricants, Buddha% around 250 to 35 series, turpentine, etc. _ illusion (9) to (10). C oil and ^ are more specific than the specific examples, liquid aliphatic hydrocarbons, or Foshan Fan 1 〆 点 points around (10) to 21 (TC hydrocarbons and / or low viscosity lubricants and / to 220 C Aromatic hydrocarbons and lipids with high boiling point mixture. 2 Early 虱 ( (more suitable for centrochlorin) and organic (4) or flammable at 3 (TC or above) Sexual organic chemical solution _ generation, = partial conversion to the height or the evaporation of the compound should also be in the 35" " limiting conditions are better than solvent mixing, and the mixture can be: upper; =: above _, In a preferred embodiment of 45 ° C, some of the m compounds are dissolved or emulsified. Lipid polar organic chemical solvent I solvent mixture is replaced by residues and / or ester and / or ether groups. The use of glycol ethers, esters, etc. 曰 /, money chemical solvents, such as, for example, the organic chemical bonding w used for the purpose of the present invention is known per se ' 109- 200810691 synthetic resin and / or combined drying oil ( It can be diluted with water and/or dissolved or dispersed or emulsified in the organic chemical solvent used), in particular Binder containing or consisting of acrylic resin, vinyl resin (eg polyvinyl acetate), polyester resin, polycondensation or polyaddition resin, 5 polyurethane resin, alkyd resin Or modified alkyd resin, benzene resin, hydrocarbon resin (such as: 茚 / coumarone resin), linalone resin, dry vegetable oil and / or dry oil and / or based on natural and / or synthetic resin Physical dry adhesive. Synthetic resin used as binder can be used in the form of emulsion, leveling liquid or solution. It can also be used as asphalt as asphalt or as a binder, and its dosage is up to 10% by weight. Known dyes, pigments, flooding agents, odor masking agents, and inhibitors or anti-corrosion agents can be used, etc. According to the invention, the composition or concentrate preferably comprises at least one alkyd resin or modified An alkyd resin and/or a dry vegetable oil is used as an organic 15th binder. The alkyd resin which is more suitable according to the present invention is preferably 50 to 68% by weight, more preferably 50 to 68% by weight. Part All may be replaced by a fixative (mixture) or a plasticizer (mixture). These additives are used to prevent the active compound from volatilizing, and to crystallize or precipitate. These adjuvants preferably replace 0.01 to 30% of the adhesive 2 chelating agent ( The binder used is based on 100%.) Plasticizers are derived from phthalate chemistry, such as dibutyl phthalate, dioctyl glycerate, or butyl phthalate, phosphoric acid. Esters such as: tributyl phosphate, adipates such as: di(2-ethylhexyl) adipate, stearates such as butyl stearate or amyl stearate, oleate Such as: butyl oleate, glyceryl ether • 110- 200810691 or high molecular weight glycol ethers, glycerides and p-toluenesulfonate. Fixatives are based on the chemical properties of polyvinyl alkyl ethers, such as, for example, poly Ethylene methyl ether, or _ such as benzophenone and vinyl benzophenone. Other suitable solvents or diluents are, in particular, water, if appropriate, a mixture with one or more of the above-mentioned organic chemical solvents or diluents, emulsifiers and granules. A particularly effective wood protection method is the industrial scale impregnation method. For example: vacuum method, double vacuum method or pressurization method. The active compound compositions according to the invention can likewise be used for the protection of articles which are in contact with 雎10 water or salty water, preventing contamination of the shell algae, such as: f bodies, partitions, nets, buildings, mooring equipment and signals system. Oligochaeta due to sessile growth, such as: Serpulidae, and Ledamorpha (Ledamorpha), such as Lepas and 铠茗(Scalpellum), or due to the 15 barnamorpha (barnacles) such as: Barnaus (Balanus) or Pollicipes genus, will improve the friction of the hull, resulting in increased energy consumption The operating cost is greatly increased, and it often stagnate on the dry dock. In addition to algae such as Ectocapus and Ceramium, Entomostraka (commonly known as the vine and Cirripedia (Crustacean)) is also of particular importance. It has now surprisingly been found that the compound compositions according to the invention have superior anti-staining action. When the active compound composition according to the invention is used, heavy metals such as, for example, bis(trialkyltin)sulfonium, tri-n-butyltin laurate, -111 - 200810691 tri-n-butyltin chloride, cuprous oxide can be dispensed with ( i), triethyltin chloride, tri-n-butyl (2-p-styl-4-chlorophenoxy) ruthenium, tributyltin oxide, molybdenum disulfide, ruthenium oxide, polymerized butyl titanate, phenyl Bipyridine)_铋 gasification, tri-n-butyltin fluoride, manganese ethyldithiocarbamate, dimethyldithiocarbamic acid, zinc ethyl thiocarbamate, pyridine sulfur Zinc and copper salts of alcohol oxides, bis-dimethyl monothiocarbamyl zinc, zinc oxide, and ethyl bisdithiocarbamate I), copper thiocyanate, copper succinate, and tributyltin halide, or substantially reducing the concentration of such compounds. If appropriate, the ready-to-use stain-resistant coatings may additionally comprise other active compounds, preferably algaecides, fungicides, herbicides, molluscicides or other anti-fouling active compounds. Preferred components suitable for combination with the anti-smudge agent according to the present invention are: algaecides, such as: 2-tert-butylamino-4-cyclopropylamino-6-methylthio-1,3,5_three tillage , dichlorophen, diuron, endothal, fentin acetate, isoproturon, mebisbenzthiazuron, complex Oxyfluorfen, quinoclamine and terbutry; fungicides such as benzo[b]thiophenecarboxycyclohexylamine S,S-trioxide, dichlofluanid, Fluorofolpet, 3-iodo-2-propynyl butyl carbamate, tolylfluanid and serotypes, such as azaconazoles, cyproconazole, Epoxyconazole, hexaconazole, metconazole, propioconazole, and tebuconazole; -112- 200810691 molluscicides, such as triphenyltin acetate ( Fentin acetate), metaldehyde, metiocarb, niclosamid, thiodicarb and trimeth Acarb); or a conventional anti-staining active compound, such as: 4,5-dichloro-2-octyl-4-5 isoindole, diiodomethylparatryl sulfone, 2- (N,N-Dimethylthioaminemethanylthio)-5•Nitrothin, 2-pyridine thiol-1-oxide potassium salt, copper salt, sodium salt and zinc salt, pyridine triphenyl Borane, tetrabutyldistannane, 2,3,5,6-tetrachloro-4-(methylsulfonyl)-pyridine, 2,4,5,6-tetrachloroisoindolonitrile, tetraterpenoid Kethiram disulfide and 2,4,6-tris10-chlorophenylmaleic acid imide. The concentration of the active compound composition according to the invention in the anti-soil plug composition used is from 0.001 to 50% by weight (specifically 0.01 to 2% by weight). Furthermore, the anti-contamination compositions according to the invention comprise conventional ingredients such as: 15 For example: they are described in Ungerer, Chem. Ind. 1985, 37, 730-732 and Williams "Antifouling Marine"

Coatings)", Noyes, Park Ridge, 1973. In addition to the algae-removing, fungicidal, molluscicidal and insecticidal active compounds according to the invention, the stain-resistant coatings also contain a specific bond. 2〇 Known binders Examples are solvent systems containing polyvinyl chloride, solvent systems containing gasified rubber, solvent systems containing acrylic resins, specific aqueous systems, ethylene chloride/vinyl acetate S copolymer systems, which are aqueous scoops Form or in the form of an organic solvent system, butadiene / styrene / propylene rubber, dry oil such as: linseed oil, resin ester or modified hardened resin -113- 200810691 with tar or asphalt combination, tar and Epoxy compounds, limited amounts of chlorine rubber, gasified polypropylene and vinyl. If appropriate, the coating also contains inorganic pigments, organic pigments or colorants which are preferably insoluble in sea water. The coating may additionally contain controlled release of the active compound. The material of 5 is rosin. In addition, the coating may also contain a plasticizer, a modifier which affects rheological properties, and other generally used components. Alternatively, the above mixture may be added to a self-polishing anti-contamination system. The active compound composition is also suitable for controlling animal pests, especially in closed spaces such as: apartments, factories, offices, cars, etc. 10 Pests, such as insects, spiders, and mites, which can be used to control this pest in households. This is active against sensitive and resistant varieties and against all stages of development. These include: Scorpionidea ' For example: Buthus occitanus Acarina' For example: Argas persicus, 15 Arga reflexus, Moss ( Bryobia ssp.), Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, 恙螨 (Trombicula 2〇 European thorns (Dermatophagoides pteronissimus), Dermatophagoides forinae. Araneae, for example: the bird mites (Avicularii) Dae), Araneidae, Opiliones, for example: Pseudoscorpiones -114- 200810691 chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium, etc. (Isopoda) ), for example: Oniscus asellus, Porcellio scaber o 5 Diplopoda, for example: Blaniulus guttulatus, Polydesmus spp· o Chilopoda, for example : Geophilus spp. Zygentoma, for example: Ctenolepisma spp., Lepisma saccharina, Lepismodes ίο inquilinus, and the genus Blattaria, for example: Blatta orientalis ), Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp. , Periplaneta 15 australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa. From the order of the genus (Saltatoria), for example: Acheta domesticus D2 D map ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( Spp·), Reticulitermes spp. Psocoptera, for example: Lepinatus genus, genus-115- 200810691 (Liposcelis spp.) Coleoptera ' For example: Anthrenus spp., Attagenus spp· ), Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Guxiang Sitophilus granaries), Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum, Diptera, eg Aedes aegypti, Aedes albopictus ), Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus 15 spp·, Sarcophaga c Arnaria), Simulium spp., Stomoxys calcitrans, Tipula paludosa o Lepidoptera, such as Achroia grisella, Galleria mellonella , Plodia 2〇interputictella, Tinea cloacella, Siphonaptera, for example: Ctenocephalides canis, Ctenocephalides felis ), Pulex irritans, Tunga penetrans, Xenopsylla -116- 10 15 20 200810691 cheopis, Hymenoptera, for example: carpentry ant (Camponotus herculeanus), black Grassius (Lasius fuliginosus), ordinary black sacrifice (Lasius niger), Lasius umbratus, Monomorium pharaonis,

Paravespula genus, terracotta ant (Tetramorium caespitum). Anoplura, for example, Pediculus humanus capitis, Pediculus humanus corporis, Phthirus pubis, Heteroptera, for example: tropical bug (cimex hemipterus), temperate bed bug (cimex iectuiarius), Rh〇dnius Prolixus, Triatoma infestans. + ιϊ can be aerosolized, non-pressure spray products, such as pumping and atomizing sprayers, automatic spray systems, atomizers, foams, gels, evaporator products, liquid evaporation When spreading a shaft or fine powder, 俜:: Both plants and plant parts are acceptable for treatment. This field of need: if refers to all plants and plant groups, such as .m traditional plant breeding === crops). For the '^ method or these methods; ^ f or use the biotechnology street and genetics to include the plant breeder's right two gene transfer plants, Bao Xian understand 'plant partial sound two and protect 5 蒦 plants Cut the variety. (4) All above-ground and underground parts of plants -117- 200810691 2. T, ί, leaves, flowers and roots, examples of which can be described: broadleaf, needles, leaves, fruits, fruits, seeds, roots , bulbs and rhizomes. Planting also includes harvested plants, and nutritive and reproductive materials, such as: seedlings,: bulbs, rhizomes, lychees and seeds. 1 Soil As described above, all plants and some of their plants can be treated according to the invention. ^仏, in the case of the treatment of wild plant varieties and plant cultivars, they were obtained from traditional biological breeding methods (such as mating method or protoplast fusion method) 2 and some of their plants. In another preferred embodiment, the transgenic plants and plant cultivars (genetically modified organisms) obtained by the rumor project (and, if appropriate, conventional methods), and some of the plants are treated. The term "partial" or "plant part" or "partial plant" has been described above. Particularly preferred 'In accordance with the present invention, a plant cultivar obtained or used in a commercial product is treated. Depending on the plant variety or plant cultivar, its location and growth conditions (soil, climate, vegetative growth period, fertilizer), the treatment according to the invention may also produce more than additive ("potentiating") effects. Thus, it is possible to exceed the expected effect, for example, to reduce the application rate and/or to broaden the range of activity and/or to increase the activity of the substances and compositions used according to the invention, to improve plant growth, to increase tolerance to high or low temperatures, and to increase Tolerance to drought or to water content or soil salt content, to increase flowering rate, to simplify harvest, to accelerate ripening, to increase yield, to improve the quality of harvested products and/or to improve nutritional value, better storage stability and/or Improve the processability of the harvested products. Preferred transgenic plants or plant cultivars (i.e., those obtained by genetic engineering) treated in accordance with the present invention include all of the particularly advantageous properties ("characteristics,") accepted in the genetic modification process -118-200810691. Plants of genetic material. These examples are good for plant growth, to improve tolerance to high or low temperatures, tolerant to drought or to water content or soil salt content, to change flowering rate, to simplify harvest, Accelerate maturity, increase yield, improve the quality of harvested products and/or improve nutritional value, better storage stability and/or improve the processability of harvested products. Other and special emphasis on these characteristics is plant confrontation Better defensiveness of animal pests and microbial pests, such as against insects, mites, phytopathogenic fungi, bacteria and/or viruses, and the tolerance of plants to certain herbicidal active compounds. Examples of genetic plants are important crops such as: cereals (wheat, rice), corn, soybeans, potatoes, cotton, canola and fruit plants (apples, pears, citrus and grapes) Particular emphasis on corn, soybeans, potatoes, cotton and oilseed rape are especially emphasized that the use of plant characteristics by the formation of toxins, certain words from a Bacillus thuringiensis (Bacillus thuringiensis) of the genetic material (e.g.: Gene

CrylA(a), CrylA(b), CrylA(c), CryllA, CrylllA, CryIIIB2

Toxins (hereinafter referred to as "Bt plants") formed in plants by Cry9c, Cry2Ab, Cry3Bb and CrylF and combinations thereof enhance defensiveness against insects. Other special emphasis is on improving the plant's financial acceptability for certain herbicidal active compounds such as misoprostone, carbendazim, glyphosate or phosphinotricin (eg: '' PAT "genes." These genes conferring the desired characteristics can also be combined into a transgenic plant. Examples of nBt plant π can be described as corn, cotton, soybean and potato varieties sold under the following trade names: YIELD GARD8 (eg corn, cotton, soybeans), KnockOut® (eg corn), -119· 200810691

StarLmk® (eg corn), B〇llgar_ (cotton), Nuc〇tn (g) (cotton) and NewLeaf (g) (horse potato). Examples of herbicide-tolerant plants can be described as corn varieties, cotton varieties and soybean varieties sold under the following trade names: Roundup Ready® (tolerant glyphosate, eg corn, cotton, soybean), 5 Liberty Link 8 (tolerance) Phosphine trisyl (phosphiootddn), for example: canola), IMI8 (tolerant imidazoline) and STS8 (tolerant sulfonamides, eg maize). Herbicide-resistant plants (plants that are tolerant to herbicides by conventional breeding methods) include those sold under the trade names Clearfield 8 (e.g., corn). Of course, these instructions also apply to plant cultivars that have developed or/and are listed in the future, which have such genetic traits or are yet to develop such genetic traits. The above plants can be treated in a particularly advantageous manner using the active compound compositions according to the invention. The preferred embodiments of the above active compound compositions are also suitable for treating such plants. Particular emphasis is placed on the treatment of plants using a mixture as specified herein. The good insecticidal killing of the active compound composition according to the invention can be exemplified by the following. Although individual active compounds exhibit a weaker activity, the activity of the combination exceeds the simple sum of their activities. When the insecticidal or fungicidal activity of the active compound composition exceeds the sum of the activities of the 20 active compound when administered alone, the active compound has a synergistic effect. The desired combination of the two groups of the two active compounds, the desired base A and the killing of the tongue, resulted in the synergistic calculation and the anti-effect of the herbicide composition of the following SR· Colby (Calculating Synergistic and Antagonistic -120- 200810691

Responses of Herbicide Coombinations)'', Weeds 1967, 15, 20-22) Calculation: If X is the active compound A, the mortality rate is compared to the untreated control group at an application rate of m ppm or gram per gram. Or potency, expressed in %, Y is the active compound B when administered at ippm or gram/ha, relative to the mortality or potency of the untreated control, expressed as %, E is when active compounds A and B are used , when the application rate rn_ and appm 10 or g/ha, the mortality or efficacy relative to the untreated control, expressed in %,

X-Y E II X+Y-- 15 100 At this time, the mortality or potency % was determined. 0% indicates that the mortality or efficacy is equivalent to the control group, and the mortality rate is 100%, indicating that all animals die and 100% of the efficacy indicates no infection. If the actual fungicidal or insecticidal effect exceeds the discriminant value, then the effect of the group 20 is superadditive, that is, synergistic. The effectiveness observed at this time must exceed the value of the expected effect (E) calculated using the above formula. [Embodiment] The following examples will illustrate the invention. However, the invention is not limited to the 25 examples. -121 - 200810691

Example A Short _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The active compound used is a 5 industrial grade active ingredient, soluble in acetone. Inoculation with a spore suspension of Penicillium brevicaule. Under darkness and shaking (1〇

Hz) ' After culturing for 5 days in each of the filled holes of the Burmese plate, the transmittance was measured by a spectrophotometer. 〇% indicates that its potency is equivalent to the growth of the control group, while 100% efficacy 10 indicates no fungal growth. The table below clearly shows that the activity of the active compound composition according to the invention is higher than the calculated activity, i.e. a synergistic effect occurs.

Table A 15 Short-dense green: (Penicillium brevicaule K in-tube) test / test, test known active compound: active compound application rate (ppm) effectiveness ° / 〇 (lb) 3 2 (6-18) 3 _63 Mixture according to the invention: The actual potency of the active compound in the mixed ratio is calculated by Kirby's formula. 20 Application rate (ppm) Calculated as expected (Ib) + (6-18) 1:1 3+3 73 64 • 122 200810691

Example B Aphis gossvpii test solvent: 7 parts by weight of decylguanamine emulsifier: 2 parts by weight of alkylaryl polyglycol ether 5 10 15 When preparing a suitable preparation of active compound, by weight The active compound is mixed with the above amount of solvent and emulsifier, and the concentrate is diluted to the desired concentration with water containing an emulsifier. It is treated with an active compound preparation at the desired concentration of the cotton leaf (Gossypium herbaceum) which is heavily infected by cotton aphid (Aphis gossypii). , Jin Xia Temple] after the death rate. 1〇〇% means that all cotton aphids have died; 0% means there is no cotton aphid Yishan, L-cho died. The measured mortality rate is substituted into the village ratio formula. In this test, according to the present application <<>>>>

Table B Aphis gossypii test for damage to plants 20 Concentration PPj^ 20 100 Active compound (lb) (6-18) Mortality of celestial % 15 0 -123- 200810691 According to the invention **calc· 15 ( Ib)+(6_18) (1:5) *found 20+100 80 * found=measured activity** calc.=activity calculated using the Kirby formula-124-

Claims (1)

200810691, the scope of patent application: 1. A composition comprising (a) at least one active compound of formula (I) Wherein 10 15 Hal represents chlorine, bromine or moth, * represents a carbon atom in the R or S configuration, and (b) at least one active compound selected from the following classes (2) to (24): (2) Strobilurins Where A1 represents one of the following groups, A2 stands for NH or 0, -125- 200810691 A3 stands for N or CH, L stands for one of the following groups, R12 /〇丫*八O'丫",V〇Y" calving*8 5 N^N CH3 CH3 wherein the bond represented by an asterisk (*) is attached to a phenyl ring, and R11 represents a phenyl group, a phenoxy group or a pyridyl group, which may optionally be the same or different substituents selected from the group consisting of the following: Single- or second-order ίο generation: chlorine, cyano, methyl and trifluoromethyl, or represents 1-(4-chlorophenyl)oxazol-3-yl or represents 1,2-propanedione-double ( 0-methyl肟)_1_ group, R12 represents hydrogen or fluorine; (3) class · triazole of formula (III) 20 wherein Q represents hydrogen or SH, m represents 0 or 1, R13 represents hydrogen, fluorine, chlorine, phenyl or 4-vapor phenoxy 'R14 represents hydrogen or chlorine, -126- 200810691 A4 represents a direct bond, _CH2 -, -(CH2)2, -Ο-, for *_CH2-CHR17· or *_CH=CR17-, wherein the bond represented by * is attached to the phenyl ring, in which case R15 and R17 together represent -CH2.CH2 -CH[CH(CH3)2]-^-CH2-CH2-C(CH3)2-^5 A5 stands for C or Si (Shi Xi), and 八 4 also stands for -N(R17)-, and A5 can also R15 and R16 together represent a group C=N-R18, in which case R17 and R18 together represent a group " 17 wherein the bond represented by * is attached to R17, Rl5 represents hydrogen, hydroxy or cyano, and Rl6 represents 1- Cyclopropylethyl, 1-chlorocyclopropyl, CVCV alkyl, crc6-propenyl, C1-C4-alkyl, C1-C2-haloalkoxy-C1-C2- 15 _ ^ alkane , trimethyldecyl-CrCr.alkyl, monofluorophenyl or phenyl, Rl5 and R16 may also collectively represent -〇-CH2-CH(R18)-〇-, -〇-CH2-CH(R18) -CH2-, or -0-CH-(2-chlorophenyl)-, Ό 18 represents a group i, C1-C4"·alkyl or >odor; 2 quinones of the formula (IV) Sulphenamide) Fci2c, s r19-O~n ("(IV) H3C-N "° 200810691 where R19 represents hydrogen or sulfhydryl; (5): amidoxime selected from the group consisting of: (5-1) Iprovalicarb chlorophenyl)-2-propynyl]oxo-3-methoxyphenyl)ethyl]-N2-(mercaptosulfonyl)-D-nonylamine amide (5-3 ) benthiavalicarb (6): carboxamides of general formula (IV) Wherein X represents 2-chloro-3-acridinyl, which represents 1-mercaptozol-4-yl (the 3-position 15 is substituted with a fluorenyl or trifluoromethyl group and the 5-position is substituted with hydrazine or chlorine) , represents 4-ethyl-2-ethylamino-1,3-11 stopper. Sit-5-based ^ represents 1-mercaptopurine ^ represents 2,2-dichloro-1-ethyl-3-indolyl propyl propyl represents 2 - qi-2-propyl, 3, 4-di Chloroisoindole 11 sit-5-yl, 5,6-di-rho-2-indenyl-1,4-lactothiacyl-3-yl, 4-mercapto-1,2,3-σ嗤-5-yl, 20 4,5-dimercapto-2 -diindenyl ketone-based thiophene-3-yl, 1-indolyl σ-pyrrol-3-yl (the 4-position via fluorenyl group) Or a trifluoromethyl substituted and 5-position substituted by hydrogen or chlorine), or a phenyl group which is monosubstituted to trisubstituted chlorine by the same or a different substituent selected from the group consisting of Mercapto or trifluoromethyl), -128- 200810691 γ represents a direct bond, crcv alkanediyl (alkylene) (which may optionally be substituted by a gas, cyano or oxo group)' represents an enediyl group ( Representing a base or a porphinyl group, z represents hydrogen, crc6-alkyl or a group of the formula Wherein A6 represents CH or N, and r2G represents hydrogen, chlorine, cyano, CrCr alkyl, phenyl (which may be mono- or disubstituted by the same or different substituents selected from the group consisting of: chlorine With a bis(CrC3-alkyl)aminocarbonyl group, r21 represents hydrogen, chlorine or isopropoxy, and R22 represents hydrogen, chloro, thio, methyl, trifluoromethyl or bis(crc3-alkyl)amine. The base, r2() and R21 may also collectively represent *-CH(CH3)-CH2-C(CH3)2- or *-ch(ch3)-oc(ch3)2-, wherein the bond represented by * is attached Connected to R20; selected from the following dithiocarbamate esters (7-1) Zinc sapphire (mancozeb) (7-2) Meng Nai Pu (maneb) to avoid ruin (metiram) (7-4) methyl zinc Naipu (propineb) (7-5) thiram - 129- 200810691 (7-6) Zinna (zineb) (7-7) ziram (8): 通式 通式Alanine Where ίο * represents a carbon atom in the R or S configuration, preferably configured as S, R23 represents a benzyl, furanyl or methoxyindenyl group; (9) class: formula (VII) anthranilic pyrimidine class Ch3 wherein R24 represents fluorenyl, cyclopropyl or 1-propynyl; Π0) class: formula (VIID 茉#imidazole -130- 200810691 wherein R25 and R26 represent hydrogen or together represent -0-CF2-0-, R27 represents hydrogen, CrC4-alkylaminocarbonyl or represents 3,5-diindenyl slogan 17-spin-4-yl Further sulfhydryl, 5 R28 represents chloro, decylamino, chlorophenyl, fluorenyl or fluorenyl; anthracene: general formula (DO urethane hydrazine 10 Λ Η (κ) wherein R29 represents a n- or iso-propyl group, and R3G represents a bis(crc2-alkyl)amino-c2-c4-alkyl or diethoxybenzene 15 group, including salts of such compounds; Class 12): Dicarboxyimine selected from the group consisting of (12-1) captafol 2〇(12_2) captan (12-3) folfet (12_4) Iprodione (12-5) procymidone (12-6) vinclozolin -131- 2〇〇81〇691 from the following steroids (13-1) donin (dodine (13-2) guazatine (13-3) gram heat (acetate) (iminoctadine triacetate) 5 (13-4) gram heat (burning benzoate) (iminoctadine tris (albesilate) )) Door 4: The carbazole selected from the following (14-1) Cyazofamid (14-2) Prochloraz 10 (14-3) Triazoxide (14- 4) Pefurazoate (15): General formula (X) morpholine _ Wherein R31 and R32 each independently represent hydrogen or methyl, 20 r33 represents Cl-Ci4-alkyl (preferably Cu-Ch-alkyl), C5_Ci2_cycloalkyl (preferably c1 (rCl2-cycloalkyl) a phenyl-CrC4_alkyl moiety may be substituted by a dentate or a CrC4 alkyl group) or an acryloyl group substituted with a & = group and a dimethoxyphenyl group; transcript -132- 200810691 Π6) Class: General formula (XI) pyrrole Wherein R34 represents a gas or a cyano group, R35 represents a gas or a nitro group, R36 represents a chlorine, and ίο R35 and R36 together represent -0-CF2-0-; Π7): a (thio)phosphonate selected from the group consisting of (17_1) Fosetyl-Al, (17-2) phosphonic acid, 15 (17-3) Tolclophos-methyl; Π8): general formula (XII) stupid acetamide 20 (ΧΠ) wherein R37 represents unsubstituted or substituted fluoro, chloro-, bromo-, decyl- or ethyl-substituted phenyl, 2-nenyl, 1,2,3,4-tetraazinyl or indane Base, -133- 200810691 ilg] class: from the following bactericidal agents: (19-1) Acibenzolar-S-methyl (19-2) tetraisophthalonitrile (chl〇r〇thalonil) (19_3) grams! g^(cymoxanil) 5 (19-4) granules (edifenphos) (19-5) sedative (fam〇xadone) (19-6) fluazinain (19-7) test gas oxidation Copper (COpper 〇XyChl〇ride) (19-8) Copper Hydroxide 10 (19-9) oxadixyl (19-11) Nitrile Sulfur (dithianon) (19-12) Epiruthenone (19-12) Metrafenone) (19-13)^^g_(fenamidone) 15 (19-14) 2,3-Dibutyl-6-chlorothieno[2,3-d]pyrimidin-4(3H)-one (19- 15) Probenazole (19-16) Isoprothiolane (19-17) Carbachol (1<^11§&111}^11) (19-18) phthalide 20 (19-19) Fermizone (19-20) Tricyclazole (19-21) Cyprosulfamide (19-22) Mandipropamid -134- 200810691 (20) Class: thiophanate-derived (20-1) pencycuron (20-2) thiophanate-methyl (20-3) Thiophanate-ethyl (21) Category: General formula (XIII) guanamine CI 10 wherein A7 represents a direct bond or -0-, A8 represents -C(=0)NH- or -NHC(=0)-, R38 represents a fluorene or CVCV alkyl group, and R39 represents a CrC6-alkyl group; 22) class: general formula (XIV) triazolopyrimidine R41 Wherein r4G represents cKc6-alkyl or c2-c6-alkenyl, R41 represents CVCV alkyl, -135- 200810691 R4G and R41 together represent c4-c5-alkanediyl (alkylene), which is Ci-CV · Alkyl mono- or disubstituted, R42 represents bromine or chlorine, R43 and R47 each independently represent hydrazine, fluorine, chlorine or methyl, R44 and R46 independently represent hydrogen or fluorine, and R45 represents hydrogen, fluorine or methyl, ( 23) Class: General formula (XV) iodinone 10 (XV) wherein R48 represents a q-CV alkyl group, 15 R49 represents a cvcv alkyl group, a C2-C6-alkenyl group or a C2-C6-alkynyl group; (24) a class: a biphenyl carboxamide of the formula (XVI) 20 wherein R5() represents hydrogen or fluoro-136-(XVI) 200810691 R51 represents fluorine, gas, bromine, decyl, trifluoromethyl, trifluoromethoxy, -CH=N-OMe or -C(Me) =N-OMe, R52 represents hydrogen, fluorine, chlorine, bromine, methyl or trifluoromethyl, and Het represents one of the following Hetl to Het7 groups: Het5 Het6 Het7 5 10 R53 represents iodine, methyl, difluoromethyl or trifluoromethyl, R54 represents hydrogen, fluorine, chlorine or methyl, 15 R55 represents methyl, difluoroindenyl or trifluoromethyl, R56 Represents chlorine, bromine, iodine, decyl, difluoromethyl or trifluoromethyl, and R57 represents methyl or trifluoromethyl. 2. A composition according to claim 1 which comprises a compound of formula (lb) And at least one of the following compounds -137- 200810691 - azoxystrobin -fluoxastrobin -(2E)-2-(2-{[6-(3-chloro-2-methylphenoxy) -5-fluoro-4-pyrimidinyl]oxy}phenyl)-2-(decyloxyimido)-N-mercaptoacetamide 5-trifluoro-trifluoro-(2E)-2-(曱oxyimino)-N-indenyl-2-(2·{[({(1Ε)-1-[3-(trifluoromethyl)-phenyl]ethylidene))) Methyl}phenyl)acetamide-(2Ε)·2-(methoxyimino)-fluorenyl-fluorenyl-2-{2-[(Ε)-({1-[3-(trifluoro) Mercapto)phenyl]-ethoxy}imino)indenyl]phenyl}acetamidamine W-denosamine (orysastrobin) _ 5-decyloxy-2-methyl_4-(2· {[({(1Ε)·1_[3-(Trifluoromethyl)phenyl]ethyl}amino)oxy)indolyl}phenyl)-2,4-dihydro-3Η-1,2, 4-triazol-3-one _ kresoxim-methyl 15 _ dimoxystrobin - picoxystrobin - pyraclostrobin - metominostrobin - Azaconazole 2〇-etaconazole - propiconazole - difnoconazole - phuk mouth Conazole) - cyproconazole -138- 200810691 - hexaconazole - penconazole - myclobutanil tetraconazole 5 - flutriafol - gas Epoxiconazole - flusilazole - simeconazole - prothioconazole 10 - fenbuconazole - tebuconazole - ipconazole - metconazole - triticonazole 15 - bitertanol - triadimenol - triadimefon - fluquinconazole - quick mouth ( Quinconazole) 2〇-yichlofluanid - tolylfluanid - iprovalicarb - beimycin (beiUhiavalicarb) 2-a-N-(l,1,3-didecyl) Full-4-yl)----------------------------------------------------------------------------------------------------------------------------------------------- -trifluoromethyl-1H-pyrazole-4-carboxamide 5 - ° eraxin (ethaboxam) - ring-shaped bacteria (fenhexamid) - force alpha purine (carpropamid) -2-chloro-4-(2-fluoro-2_mercaptopropylamino)-N,N-dimercaptobenzamine-fubic ( Fluopicolid) ίο -zoxamide -3,4-dichloro-N-(2-cyanophenyl)isothiazol-5-carboxamide - carboxin - carbamide Tiadinil) - 吼σ塞菌胺 (penthiopyrad) 15 - silthiofam - N-[2-(l,3-dimethylbutyl)phenyl]_1_fluorenyl_4_(trifluoro Methyl)-1Η-吼咯-3-carboxydecylamine-flutolanil-Ν-[2-(1,3·didecylbutyl)phenyl]-5-fluoro-1,3- Dimethyl-1Η-α ratio 20 Jun-Resinamine-Ν-{2_[3-chloro-5-(trifluoromethyl)acridin-2-yl]ethyl}-2-(trifluoromethyl) Benzoamine-manganese (mancozeb), whose IUPAC name is (ethyl) complex of manganese and bis(dithiocarbamic acid) manganese and zinc salts -140- 200810691 - Manganpo (maneb ) - It is free of metiram, its IUPAC name is exoethyl bis(dithioaminic acid) ammonium acid-poly (extended ethylamine deuterated disulfide) - methyl zinc naproxil (propineb) 5 - thiram - zinc nai (zineb) - ziram - benalaxyl - furalaxyl 10 - metalaxyl - metalaxyl, M Benalaxyl - M - Cypro Cyprodinil) - mepanipyrim 15 _ σ 密 methamine (pyrimethanil) -6-gas _5-[(3,5-dimethylisoxazol-4-yl)sulfonyl]-2,2 -difluoro_5H-[1,3]dioxazo[4,5-f]benzimidazole-belool - carbendazim 2〇- chlorfenazole - Fuberidazole - thiabendazole - diethofencarb - propamocarb -141 - 200810691 propamocarb · hydrochloride - propamocarb - blessing Fosetyl - captafol - captan 5 - folpet - iprodione - procymidone - vinclozolin - tannin (dodine) 10 - guazatine (iminoctadine triacetate) - cyazofamid - prochloraz - triazoxide 15 - rice stalk Purpose (pefurazoate) - Ai Aldimorph - tridemorph - dodemorph - fenpropfu morphpropimorph 20 - dimethomorph - fenpiclonil - fludioxonil - σ bilo Pyrrolnitrin - Fosetyl-Al -142- 200810691 - Tolclofos-methyl -2-(2,3-dioxan-1仏茚_5-yl)- N-[2-(3,4-Dimethoxyphenyl)ethyl]-2-(decyloxyimino)-acetamide 5 _ N-[2-(3,4-dioxyloxy) Phenyl)ethyl]-2-(decyloxyimino)-2-(5,6,7,8-tetrazine-n-2-yl)ethenyl -2- 2-chlorobenzene -N-[2-(3,4-Dimethoxyphenyl)ethyl]-2-(decyloxyimino)acetamide-2-(4-diphenyl)-N- [2-(3,4-Dimethoxyphenyl)ethyl]-2-(oximeoxyloxy)imidamine-2-(4-mercaptophenyl)-N-[2- (3,4-dimethoxyphenyl)ethyl]-2-(decyloxyimido)acetamide-2-(4-ethylphenyl)-indole-[2·(3,4 -dimethoxyphenyl)ethyl]-2-(decyloxyimido)acetamide 15 _ Acibenzolar-S-methyl-tetrachloroisophthalonitrile Chlorothallon) - cymoxan Il) - edifenphos famoxadone 2〇-fluazinam - copper oxychloride - oxadixyl - spiroxamine - Nitrile sulfur dithianon -143- 200810691 - metrafenone - 2,3-dibutyl-6-chlorothieno[2,3-d]pyrimidin-4(3H)-one - Probenazole - isoprothiolane 5 - kasugamycin - phthalide - ferimzone - tricyclazole -N-({4-[ (cyclopropylamino)carbonyl]phenyl}sulfonyl)-2-methoxybenzene 10 formamidine-2-(4-phenylphenyl)-N-{2-[3-decyloxy- 4-(propan-2-fast-1 -yloxy)phenyl]ethyl}-2-(propan-2-free-1 -yloxy)acetic acid amine-pcloscription (Pencycuron) - 曱基多保净Thiophanate-methyl) 15 -ethyl phanphanate-ethyl - fenoxanil - diclocymet -5_ chloro-N-((l S)_2,2,2-three Fluor-1 -mercaptoethyl]-6-(2,4,6.difluoro-phenyl)[1,2,4]triazolo[l,5-a]pyrimidin-7-amine 20 - 5_ Chloro-N-[(1R)-1,2-dimercaptopropyl]-6-(2,4,6-trifluorophenyl) [1,2,4]triazolo-[l,5-a]pyrimidine-7-amine-5-gas-6-(2-gas-6-fluorophenyl)-7-(4-mercaptopiperidone Pyridin-1-yl)[1,2,4]tris-[l,5-a]^a--5-chloro-6-(2,4,6-trifluoroiphenyl)-7- (4_曱基旅咬-l-基)[1,2,4]三-144- 200810691 峻和-[l,5-ap-Bite-2-butoxy-3-propylbenzoquinone σ ratio嗣-4-嗣-2 -ethoxy-6-Moth-3-propyl benzoquinone σ-pyran-4-@同--2-propoxy-3-propyl 弁^ 比喃-4-嗣5 - 2_ But-2-Quoxy-6-Batter-3-propylphenylpyrenepyran-4-amine-6_峨2- 2-(1-indolylbutyl)-3-propylbenzene弁ϋ比喃-4 -酉同2 - 丁- 3-细'基氧-6-^^本弁°比喃-4-酉 identical 3-butyl-6-峨-2·isopropoxybenzene弁ϋ比喃-4 -酉同-N_(3f,4f-二鼠-5-气-1,1▼biphenyl-2-yl)_3(dimethylmethyl)-1-曱ίο 基_111-吼嗤-4-carbazone-3-(difluoroindolyl)-N-{3'-fluoro-4'-[(E)-(decyloxyimino)indolyl]·1, Γ- Biphenyl-2-yl}-1_methyl_1H_pyrazole_4_carboxyguanamine-3-(trifluoromethyl)-N_{3'-fluoro-4'-[(E)_(曱Oxyimido)indenyl]-1,1f-biphenyl-2-yl} -1 -methyl_ 1 H_11:7 ratio ° _4_ 竣 amine 15- N-(3 ,4'-Dichloro-1, fluorene-biphenyl-2-yl)-5-fluoro-1,3-dimethyl-1H_pyridinyl--4-oxo-amine-Ν-(4'-chloro- 3'-Fluorobiphenyl-2-yl)-2-methyl-4-(trifluoromethyl)-1,3-thiazol-5-carboxamide-N_(4'-chloro-1, fluorene-linked Benz-2-yl)-4-(difluoromethyl)-2-methyl-1,3-thiaso 20-5-carboxamide-N-(4'-bromo-1, fluorene-biphenyl-2 -yl)-4-(difluoroindolyl)-2-mercapto-1,3-thiasin-5-histidine-4-(difluoroindolyl)-2-indenyl-N-[4' -(Trifluoromethyl)-1, fluorene-biphenyl-2-yl]-1,3-thiazole-5-carboxamide. -145- 200810691 3. The composition according to the scope of the patent application, comprising a compound of the formula (lb) and a compound fenamidone according to the scope of claim 2, according to the scope of the patent application. A composition of 3, which further comprises at least one compound selected from the group consisting of: azoxystrobin, fluoxastrobin, (2E), 2-(2-{[6 -(3-chloro-2-methylphenoxy)_5-fluoro-4-pyrimidinyl]oxy}phenyl)-2-(methoxyimino)-N-indenyl-acetamide, three Fluoramine (trifloxystrobin), (2E)_2-(decyloxyiminomethyl-2-(2-{[({(1Ε)-1-|)(trifluoromethyl)phenyl] 10 ia Ethyl}amino)oxy]indolyl}phenyl)acetamide, (2E)-2-(methoxyimino)_N_methyl-2-{2-[(Ε)-({1_ [3-(Trifluoromethyl)phenyl]ethoxy}imido)indenyl]phenyl}acetamidamine, orsastrobin, 5_decyloxy_2_methyl-4_ (2-{[({(1Ε)-1-[3-(trifluoro-methyl)phenyl]ethylidene)]amino)oxy]methyl}phenyl)-2,4-dihydro_3Η -1,2,4_triazol-3-one, gram 15 , kresoxim-mercapto, ether Dimoxystrobin, picoxystrobin, pyraci〇str〇bin, metominostrobin, azaconaz〇ie, etaconazole, apron Propiconazole), difenoconazole, bromuconazole, cyproconazole, hexaconazole, penconazole, myci〇butanil, tetraconazole ), flutriafol, epoxiconazole, flusiiaz〇ie, simeconazole, prothi〇conazole, 克克撒-146- 200810691 ( Fenbuconazole), tebuconazole, ipconazole, metconazole, triticonazole, bitertanol, triadimenol, triadimefon , fluquinconazole, quinconazole, dichlofluanid, tolylfluanid, iprovalicarb, benthiavalicarb, 2-gas_N_ (1,1,3 -trimethylindan-4_yl)nicotamine, boscalid,furametpyr, N-(3-p-tolylysine-2-yl)-1-methyl- 3_Trifluoromethyl-1^1--4-treacol basketamine, 嗔10 eth 坐 box eth (ethaboxam), cyclohexamid, carpropamid, 2-chloro_ 4-(2-fluoro-2-methylpropionylamine*)_N,N-dimercaptobenzamide, fluopicolid, zoxamide, 3,4-digas -N_(2-cyanophenyl)isothiazole_5_carboxamide, carboxin, tiadinil, penthiopyrad 15 , thiophene (sihhiofam) ), N_[2_(l,3-dimethylbutyl)phenyl]small methyl_4_(trimethylmethyl)_ιΗ-. Biloxi-3-weigan, flutolanil, Ν-[2·(1,3-dimethylbutyl)phenyl]_5-fluoro-1,3-didecyl-1Η-pyridyl Azole_4_carboxyguanamine, Ν_{2_[3_chloro-5-(trifluoromethyl)- or pyridin-2-yl]ethyl 2-(trifluoro-indolyl)phenylamine, zinc manganese Mancozeb (its IUPAC name is exoethyl bis(dithioaminic acid) manganese and zinc salt (polymerized) chelate), Meng Naipu (mane) 3), free of ruin (metiram) (The IUPAC name is exoethyl bis(dithiocarbamic acid) zinc citrate-poly(ethylamine decyl disulfide)), propionb, thiram Zinb, 福美辞-147- 200810691 (ziram), benalaxyl, furalaxyl, metalaxyl, metalaxyl-M, Bunda (benalaxyl)-M, cyprodinil, mepanipyrim, pyrimethanil, 6-chloro-5-[(3,5-dioxin-5-isoxazole-4-yl) Sulfhydryl]-2,2-difluoro-5H-[1,3]dioxazo[4,5-f] benzoxanthene, benomyl, carbendazim, Chlorphenirazole Fenazole), fuberidazole, thiabendazole, diethofencarb, propamocarb, propamocarb hydrochloride, propamocarb-force Fosetyl, captafol, captan, folpet, iprodione, procymidone, vinclozolin, dodine ), guazatine, iminoctadine triacetate, cyazofamid, prochloraz, triazoxide, pefurazoate, Ai Di Aldimorph, tridemorph, dodemorph, fenpropimorph, dimethomorph, fenpiclonil, fludioxonil, pyrrolidin Pyrrolnitrin, Fosetyl-Al, phosphonic acid, tolclofos-methyl, 2-(2,3-dihydro-1H-indol-5-yl)-N-[2 -(3,4-dimethoxyphenyl)ethyl]-2-(methoxyimino)acetamide, N-[2-(3,4-dimethoxyphenyl)ethyl ]-2-(曱2-(5,6,7,8-tetrahydronaphthalen-2-yl)acetamide, 2-(4-phenylphenyl)-N-[2-(3,4-di Nonyloxyphenyl)ethyl]-2-(decyloxyimido)acetamide, 2-(4-bromophenyl)-N-[2-(3,4-di•148- 200810691 曱Oxyphenyl)ethyl]-2-(methoxyimino)acetamide, 2-(4-methyl-phenyl)-1^-[2-(3,4-didecyloxy) Phenyl)ethyl]-2-(decyloxyimido) acetamidine, 2-(4-ethylphenyl)-N-[2-(3,4-dimethoxyphenyl) Alkyl-2-(indenyl imino) anthranil, Acibenzolar-S-methyl, chlorothalonil, cymoxanil, granules Edifenphos), famoxadone, fluazinam, copper oxychloride, oxadixyl, spiroxamine, dithianon, table Metrafenone, 2,3-dibutyl-6-1 〇 σ σ 并 并 [2,3_d] 密密-4 (3H)-g, probenazole, 稻瘟灵(isoprothiolane), kasugamycin, phthalide, ferimzone, Tricyclazole, N-({4-[(cyclopropylamino)carbonyl)phenyl)sulfonyl)-2-nonylbenzamide, 2_(4-chloro-phenyl)_N -{2_[3-decyloxy-4(prop-2-yn-1-yloxy)benzene 15yl]ethyl b-2-((prop-2-yn-1-yloxy)-acetamide, bromo ^ (Pencycuron), thi〇phanate-methyl, thiophanate-ethyl, fenoxanii, dilococymet, 5-gas-N_ [(lS)-2,2,2_trifluoro-1-methylethyl]-6-(2,4,6-dihydrocarbyl)[1,2,4]triterpene-[1,5 -3]. _7_amine, 5·20 chloro-N-[(1R)_1,2-dimercaptopropyl]_6_(2,4,6-trifluoro-phenyl)[1,2,4] Triazolo[l,5-a]pyrimidin-7-amine, 5ϋ(2-chloro-6.fluorophenyl)-7-(4-methylpiperidin-1-yl)[1,2,4] Triazolo[i,5_a]pyrimidine, 5-chloro-6-(2,4,6-trifluorophenyl) knife-(4-mercaptopiperidinyl)[1,2,4]triazole [l,5-a]pyrimidine, 2-butoxy-6-iodo-3-propylbenzopyran-4-one, 2-ethoxy-6-iodo-3-propylbenzo-149 - 200810691 Anthranone, 6_Moth 2-propoxyl propyl benzofuran-4-one, 2 butyl 2_alkynyloxy-6-indol-3-propyl benzo. Compared with the hail, the moth is methylbutoxy)_3_propylbenzopyranone, 2_丁_3•wolkyloxy·6-disc benzo. Chesy-4-ketone, 3-butyl-6-indole-2·isopropoxybenzopyrano-4-one, n_(3,,4,_di-gas-5-fluorobiphenyl_2_ Methyl)h_methyl.pronolol guanamine, μ difluoromethyl)·Ν_{3|_fluorozo[(em曱oxyimino)methyl]-1, Γ-联本-2-yl}+methyl]h_d is more than salicylamine, 3•(trimethylmethyl)-N-P'-fluoro-4,-[(Ε)·(methoxyimino)f-based ]], bisbiphenyl 1 yl}-1·:yl 15 20 5. yl)-5-fluoro-1,3-dimethyl_1H "thans salivary _4_ renegazine, N_d -pi,- Phenyl)-2-methyl_4·(three-gas _methyl hydrazine, 34 ϋ several months, Ν-(4, 'gas-1,1'-biphenyl-2-yl)_4_(difluorocarbamate) ) _2 _2 _2 -5 - - - - - - - - - - - - - - - - - - - - - - 二 二 二 二 二 二 二 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( Indoleamine and 4_(difluoromethyl)_2-methylindenyl H, 1L biphenyl-2-yl]_1,3-thiazole-5-carboxyguanamine. - Fluorine one according to the scope of the patent application No. 4 to 4 Any one of the items in the control of animal pests and / or phytopathogenic fungi, 6 - species in accordance with any one of the scope of the patent application range 丨 to 4 - the composition of the treatment of seeds The purpose of the use. 7. A use of the composition according to any one of claims 1 to 4 for the treatment of a transgenic plant. 弋义之8· A type according to any one of claims 1 to 4 of the scope of the patent application ~, > Use of the composition for treating seeds of a transgenic plant. 疋 之 9· A seed treated with a composition according to the definition of -150-200810691 as defined by any one of claims 1 to 4. Animals that control unwanted animals ▼, ..., candle, or phytopathogenicity are characterized by the application of the active compound composition defined by 壬彳5 to 4 of the scope of the patent application to the unwanted, two:: perched On the ground and / or on the seed. Do not. Moth and / or its 11 · A method of preparing an insecticidal and acaricidal composition according to any one of claims 1 to 4 and a supplement and/or a surfactant. ‘It is characterized by a mixture of mixed definitions. -151 - 200810691 VII. Designation of Representative Representatives (1) The representative representative of the case is: (No). (2) A brief description of the symbol of the symbol of the representative figure: None 8. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: 10