TW200702342A - Process for preparation of bead polymers whose average particle size is in the range from 1 μm to 40 μm, and moulding compositions and mouldings comprising bead polymer - Google Patents

Process for preparation of bead polymers whose average particle size is in the range from 1 μm to 40 μm, and moulding compositions and mouldings comprising bead polymer

Info

Publication number
TW200702342A
TW200702342A TW095110558A TW95110558A TW200702342A TW 200702342 A TW200702342 A TW 200702342A TW 095110558 A TW095110558 A TW 095110558A TW 95110558 A TW95110558 A TW 95110558A TW 200702342 A TW200702342 A TW 200702342A
Authority
TW
Taiwan
Prior art keywords
bead
weight
mouldings
preparation
particle size
Prior art date
Application number
TW095110558A
Other languages
Chinese (zh)
Other versions
TWI447128B (en
Inventor
Sabine Schwarz-Barac
Klaus Schultes
Michael Schnabel
Stefan Nau
Ursula Golchert
Original Assignee
Roehm Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roehm Gmbh filed Critical Roehm Gmbh
Publication of TW200702342A publication Critical patent/TW200702342A/en
Application granted granted Critical
Publication of TWI447128B publication Critical patent/TWI447128B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/18—Suspension polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Fats And Perfumes (AREA)

Abstract

Process for preparation of bead polymers whose average particle size is in the range from 1 μm to 40 μm, by dispersing and polymerizing a polymerizable composition in an aqueous phase, where the dispersion stabilized by an aluminium compound is prepared at a shear rate ≥ 10<SP>3</SP> s<SP>-1</SP> A polymerizable composition is used here which, in each case based on its total weight, comprises (a) more than 50.0% by weight of at least one compound of the formula (I), where the radicals 1R to 6R have definitions according to the Description, (b) from 0.1 % by weight to 10.0% by weight of at least one crosslinking agent and (c) less than 49.9% by weight of at least one compound of the formula (II), where the radicals R and 7R to 9R have definitions according to the Description. The bead polymers prepared according to the inventive process are particularly suitable for production of mouldings with light-scattering properties.
TW095110558A 2005-05-04 2006-03-27 Process for preparation of bead polymers whose average particle size is in the range from i μm to 40 μm, and moulding compositions and mouldings comprising bead polymer TWI447128B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102005021335A DE102005021335A1 (en) 2005-05-04 2005-05-04 Process for the preparation of bead polymers having a mean particle size in the range of 1 .mu.m to 40 .mu.m, and molding compositions and moldings comprising bead polymer

Publications (2)

Publication Number Publication Date
TW200702342A true TW200702342A (en) 2007-01-16
TWI447128B TWI447128B (en) 2014-08-01

Family

ID=36636510

Family Applications (1)

Application Number Title Priority Date Filing Date
TW095110558A TWI447128B (en) 2005-05-04 2006-03-27 Process for preparation of bead polymers whose average particle size is in the range from i μm to 40 μm, and moulding compositions and mouldings comprising bead polymer

Country Status (16)

Country Link
US (1) US20090043044A2 (en)
EP (1) EP1877456B1 (en)
JP (1) JP5054676B2 (en)
KR (1) KR101369071B1 (en)
CN (1) CN101142241B (en)
AT (1) ATE459666T1 (en)
BR (1) BRPI0610369A2 (en)
CA (1) CA2604464C (en)
DE (2) DE102005021335A1 (en)
HK (1) HK1116808A1 (en)
MX (1) MX2007013643A (en)
PL (1) PL1877456T3 (en)
RU (1) RU2386643C2 (en)
SI (1) SI1877456T1 (en)
TW (1) TWI447128B (en)
WO (1) WO2006117041A1 (en)

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Also Published As

Publication number Publication date
EP1877456B1 (en) 2010-03-03
JP5054676B2 (en) 2012-10-24
US20090043044A2 (en) 2009-02-12
RU2386643C2 (en) 2010-04-20
JP2008540703A (en) 2008-11-20
BRPI0610369A2 (en) 2010-06-15
CN101142241A (en) 2008-03-12
DE102005021335A1 (en) 2006-11-09
ATE459666T1 (en) 2010-03-15
KR101369071B1 (en) 2014-02-28
US20080188616A1 (en) 2008-08-07
KR20080012866A (en) 2008-02-12
SI1877456T1 (en) 2010-07-30
HK1116808A1 (en) 2009-01-02
MX2007013643A (en) 2008-03-10
PL1877456T3 (en) 2010-08-31
RU2007144517A (en) 2009-06-10
CN101142241B (en) 2011-07-06
CA2604464C (en) 2014-09-02
CA2604464A1 (en) 2006-11-09
DE502006006337D1 (en) 2010-04-15
TWI447128B (en) 2014-08-01
WO2006117041A1 (en) 2006-11-09
EP1877456A1 (en) 2008-01-16

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