JP2009300719A5 - - Google Patents

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Publication number
JP2009300719A5
JP2009300719A5 JP2008154947A JP2008154947A JP2009300719A5 JP 2009300719 A5 JP2009300719 A5 JP 2009300719A5 JP 2008154947 A JP2008154947 A JP 2008154947A JP 2008154947 A JP2008154947 A JP 2008154947A JP 2009300719 A5 JP2009300719 A5 JP 2009300719A5
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JP
Japan
Prior art keywords
toner
producing
sulfonic acid
soluble initiator
oil
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JP2008154947A
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Japanese (ja)
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JP5137702B2 (en
JP2009300719A (en
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Priority claimed from JP2008154947A external-priority patent/JP5137702B2/en
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Publication of JP2009300719A5 publication Critical patent/JP2009300719A5/ja
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Claims (7)

少なくとも重合性単量体と着色剤とスルホン酸系官能基を有する重合体を含有する重合性単量体組成物を水系媒体中で造粒し、重合する工程を有するトナーの製造方法において、
該スルホン酸系官能基を有する重合体は、スルホン酸基、スルホン酸塩基又はスルホン酸エステル基を有する重合体又は共重合体であり、
該工程は、該水系媒体中に油溶性開始剤を添加して該重合性単量体を重合し、該重合性単量体の転化率が97.500乃至99.990%となったときに、該水系媒体のpHを7.00以下とし、かつ、該水系媒体中に水溶性開始剤を添加して更に重合する工程を含むことを特徴とするトナーの製造方法。
At least a polymerizable monomer containing a polymer having a colorant and a sulfonic acid functional group polymerizable monomer composition was granulated in an aqueous medium, in the method for producing a toner having a step of polymerizing,
The polymer having a sulfonic acid functional group is a polymer or copolymer having a sulfonic acid group, a sulfonic acid group, or a sulfonic acid ester group,
The process in aqueous medium with the addition of oil-soluble initiator to polymerize the polymerizable monomer, when polymerizable monomer conversion reached a 97.500 to 99.990% And a method for producing a toner, comprising a step of setting the pH of the aqueous medium to 7.00 or less, and further adding a water-soluble initiator to the aqueous medium and further polymerizing.
前記水溶性開始剤が過硫酸塩系開始剤であることを特徴とする請求項1に記載のトナーの製造方法。   The toner manufacturing method according to claim 1, wherein the water-soluble initiator is a persulfate-based initiator. 前記油溶性開始剤が有機過酸化物開始剤であることを特徴とする請求項1又は2に記載のトナーの製造方法。   3. The method for producing a toner according to claim 1, wherein the oil-soluble initiator is an organic peroxide initiator. 前記トナーの100℃粘度が5000Pa・s乃至100000Pa・sであることを特徴とする請求項1乃至3のいずれか一項に記載のトナーの製造方法。   4. The toner production method according to claim 1, wherein the toner has a 100 ° C. viscosity of 5000 Pa · s to 100,000 Pa · s. 5. 前記トナーのTHF不溶分が16.0質量%未満であることを特徴とする請求項1乃至4のいずれか一項に記載のトナーの製造方法。   The method for producing a toner according to claim 1, wherein the toner has a THF-insoluble content of less than 16.0% by mass. 前記油溶性開始剤の10時間半減期温度が50℃を超える有機過酸化物を使用することを特徴とする請求項1乃至5のいずれか一項に記載のトナーの製造方法。   6. The method for producing a toner according to claim 1, wherein an organic peroxide having a 10-hour half-life temperature exceeding 50 ° C. of the oil-soluble initiator is used. 前記油溶性開始剤がt−ブチルパーオキシピバレ−ト、t−ブチルパーオキシ−2−エチルヘキサノエート、t−ブチルパーオキシイソブチレートから選ばれることを特徴とする請求項1乃至6のいずれか一項に記載のトナーの製造方法。   7. The oil-soluble initiator is selected from t-butyl peroxypivalate, t-butyl peroxy-2-ethylhexanoate, and t-butyl peroxyisobutyrate. The method for producing a toner according to any one of the above.
JP2008154947A 2008-06-13 2008-06-13 Toner production method Active JP5137702B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2008154947A JP5137702B2 (en) 2008-06-13 2008-06-13 Toner production method

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Application Number Priority Date Filing Date Title
JP2008154947A JP5137702B2 (en) 2008-06-13 2008-06-13 Toner production method

Publications (3)

Publication Number Publication Date
JP2009300719A JP2009300719A (en) 2009-12-24
JP2009300719A5 true JP2009300719A5 (en) 2011-07-28
JP5137702B2 JP5137702B2 (en) 2013-02-06

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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20110097668A (en) * 2010-02-23 2011-08-31 주식회사 엘지화학 Polymerized toner and preparation method of the same
EP2378364B1 (en) * 2010-04-14 2015-09-23 Canon Kabushiki Kaisha Toner
JP6592332B2 (en) * 2015-11-02 2019-10-16 キヤノン株式会社 Method for producing toner particles
JP6800765B2 (en) * 2017-01-24 2020-12-16 キヤノン株式会社 Method of manufacturing resin particles
JP7130484B2 (en) * 2018-07-24 2022-09-05 キヤノン株式会社 Method for producing toner particles
JP7271347B2 (en) * 2019-07-09 2023-05-11 キヤノン株式会社 Method for producing toner particles

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1934505A (en) * 2004-03-26 2007-03-21 日本瑞翁株式会社 Toner for developing electrostatic charge image
JP4609294B2 (en) * 2005-11-30 2011-01-12 日本ゼオン株式会社 Method for producing toner for developing electrostatic image
KR101102202B1 (en) * 2006-03-13 2012-01-05 캐논 가부시끼가이샤 Toner and process for producing said toner
JP2007293183A (en) * 2006-04-27 2007-11-08 Canon Inc Toner, image forming method and image forming apparatus

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