TW200550B - - Google Patents

Description

200550 A 6 _ η 6 5. Description of the invention (1) 芟 馬 隤 The present invention is based on non-ionic oligomer oligomers, its function is as an improved dirt release agent (Sra's) and it is used for washing sisters. In detail, the fabric softener is finished. In the invention, if the susceptible substance (specifically, the susceptible substance with synthetic dimensional ingredients) is immersed in the water-based washing or wetting agent in the household or public establishment, the effect of "dirt release" will be produced. The soil release agent (Sra's) containing different polymers or oligomer esters is typically a low K concentration, such as 5 to a few parts per million. Polymers or oligomers are deposited on the fabric surface M to provide soil release finish. The dirt release system is different from the cleaning effect of ordinary washing and cleaning surfactants and detergents in that it has multiple cleaning effects. For example, fabrics that have been washed individually tend to undergo 2, 3, or 4 times of washing and cutting cycles It is easier to add W for cleaning gradually, and some dirt redeposition benefits are often obtained. Dirt release is particularly noticeable for polyester fabrics, but good results are also obtained for polyester / cotton blends. The benefits of dirt release are also seen (please read the meaning of ^ first and then fill out this page). Install &Order; Green · Printed by the Central Bureau of Economic Affairs of the Ministry of Economic Affairs Α 工 consumer cooperatives, category 3i, without cleaning Shi Qing fabrics are fine with S's qualities a '. Use the sister H lnsr as a deodorant to disperse the sun, Sr, etc. Some of the clothes are dried and dried in the pulp. There is a style that is not in style-medium in the square. The wonderful article is a good way to explain the scriptures, which is more dirty, more complicated, and more effective in keeping the shape or shape. In the middle, the classics are excellent. , Weaving under the weaving Yu Jiazhong's system on the same pole pieces of acid-purifying agent agent Dilute washing system Η He organic Chrysanthemum surface is added as a living and water side in the face-washing theory at present. In the table of the same item to the paper sheet size in the use of the same standard in the home standard (CNS) f4 specifications (210x29 / g *) 81. Sichuan, 8000 Zhang (丨 丨) 200550 A 6 Π 6 V. Invention Description (2)

In the presence of BX Industrial Consumers, Central Bureau of Standards, Ministry of Economic Affairs ^ Cooperative Du Yin M softener, Sra typically deposits only on the suspects to a limited extent. Conversely, industrial finishing is usually done in highly controllable process equipment (such as dip dyeing machines). Typical suspects are clean, and the concentration of detergent or softener (if any) tends to be low. At least at this stage, the soil release treatment is intended to be used on fabric substrates. Due to the difference in washing and industrial finishing technology *, there are also significant differences between sister types (such as washing detergent, washing softener, washing bleach, etc.). This kind of washing and cleaning products and different types of M, such as granular, liquid, gel, paste-form, and products with desiccant are also prepared. The formulators in the washing technique have realized that different forms of washing sisters have inherent formula restrictions. For example, the solid ingredients required by the adult formula can generally be dispersed or dissolved in an aqueous cleaning bath. At the same time, the liquid ingredients together need the ingredients to be freely mixed without thorny chemical or physical interactions such as phase change or precipitation. In particular, the modern washing sisters are more and more popular in the form of "concentration". For example, the concentration of the intestinal ion softener component contained in the commercially available liquid fabric softener is 3 times higher than that of the fabric softener obtained so far. It is difficult to realize that the formulation of such a composition should have its own stable form and a reasonable particle size range. Of course, if you want to incorporate ingredients with additional functions (such as sra ’s) into this kind of finished product, it is more difficult to prepare and volatile performance. Therefore, continuous research on the effective, compatible, and easy-to-make sra ’s that are available for washing sisters ’products is continued. ___ _ " ----- -4- (please read the back-to-back ¾ 意 节 ¾ # 墦 筠 this page first) Binding and ordering paper 51c standard Chinese National Standard (CNS) T4 specification (210x297 ) 81. 4. lO.OUOfSL (| () 200550 A 6 Π 6 V. Description of the invention (3.) The present invention provides yuraf basket line sra's and is suitable for washing compositions ^. The present invention also avoids non- Chicks are sra · s and are especially used for the combination of cationic textile softener Ning. In addition, even if K softener "concentrate" is prepared, many of the sra · s are also excessively increased liquid S1 fabric softening _ The viscosity of the sister product. U.S. Patent No. 4,711,7 No. 30 issued to Gosselink and Diehl on December 8th, 2005, is related to the capped 1,2-propylene terephthalate-polyoxyethylene pair Phthalates are used in washing detergents and fabric softener products (including concentrates) and as a soil release agent. In this category, as described in Gossellnk and Diehl The reference documents include the following: L Ethylene p-Cage Dimethyl Ester / PRn Pyong Rong Second Examination Sg Cool Smudge Smoke Piece Polyester ( Read the back-to-back simple matters 4 and fill out this page) Printed by the Ministry of Economic Affairs, Pyongyang Bureau, Beigong Consumer Cooperative, September 4, 1978, No. 4, 116, δ 85 2 5% (Κ 0. 5% Diformate The amount of dirt is 5,000 to some specific agents into the detergent and the detergent and the detergent and detergent disclosed in the United States awarded to Derstadt on the 26th are best to 10%). A release polyester, such as MILEASET, is 200,000 (M 10, 000 to 50,000 in a step containing 5% to 95% (M 10% compatible alcohol sulfate and ethoxyalkyl sulfate 10% other incompatible The patent for Yin-Zhezizi contains 0.15% to ester / PEG-p-benzene with an average molecular weight). These are clear to 25%, the best) Detergent surface active surfactant, this paper scale is used in the national B standard (CNS) T4 regulation (210 father, 297 mm) 81.4.1 (), 〇〇〇 张 (ίί) Cooperated with the Central Standard of the Ministry of Economic Affairs ^ β 工 工 伢 Cooperated by Du Printed 200550 Λ fi ____ Π6_V. Invention Description (4) Such as linear alkane benzene sulfonate. US Patent No. 4,132,680 issued to Nicol on January 2, 1979 also discloses that the detergent and cleaning agent has dirt release properties , This contains 2% to 95% (M to 60% better) detergent surfactant and 0.15% to 25% (1% to 10% best) ethylene terephthalate / PEG p-benzene Dicarboxylic acid esters (with grate ratios of 65:35 to 80:20) have soil release polyesters with molecular weights of 10,000 to 50,000, such as "11 ^ / ^ £ 1 '. These sister products further include 〇5% 5% to 15% (preferably 0.1% to 5%) components and will produce 1 to 3 (: 8 to (: 24 alkyl quaternary ammonium) in aqueous solution陔 雔 子. These cations taught by Nicol are used to improve the deposition of dirt-releasing polyester on washed suspects. See its 11th line, lines 14 to 21 ° L. Polyester Μ 偻 潟 道 訟 多余 袢 was issued on May 15, 1981 to the Becker Canadian Patent No. 1, 100,262 disclosed in the fabric softener sister composition contains 1% to 80% (Μ 5% to 50% is better) fabric softener such as ammonium ditallow ammonium dicarboxylate with certain cholera fatty acid compounds ranging from 0.5% to 25% (Ml% to 10% is better). These softeners The product M contains 0.5% to 10%. (Preferably 1% to 5%) ethylene terephthalate / PEG terephthalate soil release polyester such as PERMAL0SE or ZELCON. July 1975 U.S. Patent No. 3,893,929, issued to Basadur on the 8th, discloses an acid-wet solution that increases wetting and contains a soil release agent made from the following substances: dimeric carboxylic acid (preferably terephthalic acid), one Polyalkylene -6 ** (Please read the precautions first to write this page) This paper is used for 8 to 8 years. The standard is called 〒4 specifications (210 > < 297 male dragon) 81. 4. ω, ϋϋΟ Zhang (Η) 200550 A 6 Π 6 V. Description of the invention (5) The Ministry of Economic Affairs, Central Bureau of Economy, Labor and Social Sciences, Co., Ltd. Printed 51. Two enzymes (M has a molecular weight of 1,300 PEG up to 1,800 is preferred) and alkylene glycol (glyoxygenation, malonylation or succinylation). The preferred soil release agent has a molecular weight of 3,000 to 5,000. These sister products may contain cationic textile softeners such as chlorinated ditallow dimethyl ammonium, but it is said to be unsatisfactory "because they tend to retard the deposition of dirt release agents in the polymer during acid extraction Ester follows the dimension. " See lines 54 to 59 on page 7. U.S. Patent No. 3,712,873 issued to Zenk on January 23, 1973 discloses a fabric treatment composition applied by spraying or dipping (pad dyeing), which includes 1% to 5% of the type of dirt release polymer shown in the Basadur patent ester. These sister products may additionally contain up to 4% of quaternary ammonium compounds with 1 Cie to C2 2 alkyl group. The combination of this quaternary ammonium compound and polyester has been shown to improve the soil release properties of the treated fabric. Zenk also shows that other quaternary ammonium compounds (such as ditallow dimethyl ammonium chloride) do not achieve the same superior efficacy. See pages 57 to 61 on page 3. L Polyester # Quietly added to the dry animals, the slack X, W, Fu, Shou, Yu, Yu, Xie, Xi, U.S. Patent No. 4,238,531 issued to Rudy on December 9, 1980, it was revealed that the added dry product contains "dispensing agent" Such as polyethylene glycol and adjuvant applied to fabrics can be used as soil release agent. The released dirt release agents include polyacrylic acid resin, polyvinyl alcohol and PERMALOSE TG polyester (see Example 8). L Use polyester in sickle products or deer skein roll liquid, curing and curing to transport dirt and rubbish and Cheng Hangjing Lei Huanxiyi-(please read first, please go back and back to the wayi 亊 item #fill this page ) 装 装-定-This paper standard is used in the 8 S home standard (CN5) T4 specification (2 丨 0x297 public Λ) 81. 4. ΙΟ, υυϋίί. (H) 200550 Λ (5η 6 Ministry of Economic Affairs Biyang Bureau Printed by the β Industry Consumer Cooperative 51 51. Description of the invention (6) The low-molecular-weight dioxin / polyoxanediase terephthalate polyesters disclosed in US Patent No. 3,512,920 issued to Dunlop on May 9, 1970 It is used in resin treatment baths containing starch or cellulose derivatives, and after heat curing, it is used to transfer the dirt release properties to cotton / polyester fabrics. It can be used to make these alkylene glycols Contains glyphosate, 1,2-propanediol, 1,3-propanediol, butanediol and their mixtures. The polyalkylene glycols that can be used include PEG, polybutanediol and their mixtures. The average molecular weight is 200 to 20,000 (M 1,000 to 5,000 is preferred). The polyester antistatic in US Patent No. 3,416,952 issued to Me Intyre on December 7, 968 The reagent contains 1 water-soluble polymer such as polyoxyalkylene and has an average molecular weight of 300 to 6,000. The preferred polyoxyalkylene is PEG'S and has an average molecular weight of 1,000 to 4,000. It is treated to Apply an aqueous powder of polyester in the presence of an antioxidant, and then heat to a temperature exceeding 90 = to obtain a durable polybrown coating on the treated object. Example 6 reveals the formation of this type of polyester. Dimethyl phthalate, ethylene fermentation and 0-methyl poly (ethylene oxide) fermentation with an average molecular weight of 350 are used for the catalytic reaction. Use this polyester in a 20% solution of benzyl fermentation M to transmit antistatic The properties are similar to polyester sickles. Example 7 discloses the use of a polyester-like 20% aqueous solution to apply antistatic properties to polyester fabrics. U.S. Patent No. 4,427,557 issued to Stockburger on January 24, 1984 was formed Low-molecular-weight copolyester (2,000 to 10,000) and ethylene glycol, a PEG (having an average molecular weight of 200 to 1,000), and an aromatic dicarboxylic acid (such as p-dibenzic acid dimethyl-8-this A B home for paper size Ning (CNS) specifications (2 丨 0X297 male dragon) ~~ 81. 4. 10,000¾ (11) (please pay attention to the considerations Λ fill in this page) Install · 200550 Λ 6 Π 6 V. Description of invention ( 7) Ester) and sulfonated aromatic dicarboxylic acid (such as dimethyl 5-sulfoisophthalate). It can be partially substituted with PEG and K PEG monoalkyl ether such as methyl, ethyl and Butyl ether. The dispersant or solution of the copolyester is applied to the fabric, and then it is heated at an elevated temperature (90 scoops to 150 C) to cure the soil release properties of the M transfer soil. See also the patents of Me Intyre, where Example 2 discloses the use of random arrangement of copolyester K to transmit antistatic properties to form them to convert para-dicarboxylic acid, dimethyl isophthalate sulfonate, and ethylenedioxide Yeast and PEG with an average molecular suspension of 1,5 40. In addition, there are several disclosures in polyester technology, more specifically, their low molecular weight oligomers, which can be used as sra's in washing products. It was disclosed earlier that it is a polyimide-type substance modified by Nai, and it does not need to be a recruiter and the contained part does not have a specific terminal cover. They are polyether fragments derived from glyphosate. See, for example, U.S. Patent No. 3,962,152 issued to Nicol on June 8, 1976, U.S. Patent No. 4,116,885 issued to Derstadt on September 7, 1978, and Becker issued on May 5, 1981 You Canadian Patent No. 1,100,262, U.S. Patent No. 4,238,531 issued to Rudy on December 9, 1980, and U.S. Patent Application No. 2,1 72,608 published by Crossin on September 24, 1986. The CX Industrial and Consumer Cooperative of the Ministry of Economic Affairs of the Ministry of Economic Affairs recently printed the sra's category for the development of detergent and detergent applications. It contains certain terminal-coated oligomers, such as the following awarded to Gosse link in the United States. Patent disclosure: See, for example, U.S. Patent No. 4,702,857 (issued October 27, 1987). U.S. Patent No. 4,721,580 (January 26, 1988) and U.S. Patent 4,877,896 -9-81.4.1 (), 000 to Malc ^ onads, Trink and Gonsslink on October 31, 1989 (please read the back Please note the code and write this page) The specifications of the HB family sample guide (CNS) in the paper standard R1 (210x2 Machiko) 200550 Λ 6 Π 6 V. Description of the invention (8) No. 0 The present invention covers dirt release agents and includes an oligomer esterification product of a reaction mixture, which includes: U) arbitrarily (but preferably) one (^ to "alkane Oxygen-terminated (M methoxy terminator is preferred) polyethoxy units [^-(OCi ^ CHdx-O-source or optionally with a small number of propoxy units with terminated polyethoxy units Mixture; (b) — source of terephthaloyl units, optionally, a mixture of terephthaloyl units and a small amount of m-xylylene units; (c) a poly (ethylene oxide) oxy group The source of the unit [ie _ (0CH2CH2) y-0-]; (d)-the source of the oxyisopropenyloxy unit contains CH3 and -0CHCH20-; (e)-the type of ethylene oxide Oxygen is the source of -〇CH2CH2〇-; the dirt release agent has a further feature of having a molar ratio of oxidized ethoxylated units to oxidized isopropenyloxy units of at least about 0.5: 1. Therefore, here The dirt release agent includes, for example, an ester reaction product of a reaction mixture including: (a) CH3 (0CH2CH2) 1Θ0Η; -10-This paper scale is used in China Η Jia 楳 quasi (CNS) A 4 specifications (210X297 male dragon) 81. 4. l (), 〇U〇 Zhang (H) (please read the back-up notes first and fill in this page) 200550 5. Description of the invention (9) (b) dimethyl terephthalate; (c) Polyethylene glycol 1 500 (E34); (d) 1,2-propanediol; and (e) ethylene glycol; wherein the molar ratio of oxyethyleneoxy units · oxypropyleneoxy units is at least about 0. 5: 1, M is preferably at least about 1.2 5: 1. Such soil release agent differs from sra's (disclosed in Gosselink and Diehl U.S. Patent No. 4,711,730 above) in that they contain oxide ethyleneoxy units. The sra's of the present invention unexpectedly have the better performance of the '730 patent. Although it is not intended to add the K limit, it is tested by theory or structure. .Xianxin's preferred s "a's special form of the invention is the formula:-_0, 0 11 / \ | 1 Ri〇- (CH2CH20) x cY ^ / V-CO-CH-CH ^-R2 _ m ο ο / 1 / = Λ »C-^ > -C-0 (CHzCH ^ Jx-R1 —0 0 C- < ^ > -C0 (CH2CHz0) y η Ministry of Economic Affairs Standards and Employee Consumers ’Cooperative Printing 51 (please read the back-to-back issues " 塥 write this page) where R1 is low-level (for example (^ to (: 4) Alkyl, in particular, methyl; and R2 is a mixture of H and CH3 (ie, both ethylene and isopropylene are present in the molecular structure), M provides oxyethyleneoxy: oxyisopropylene The molar ratio of oxy groups is at least about 0.5: 1 and M is preferably at least about 1.2 5: 1. In the formulae drawn, X, y, m and η are integers and are in the following ranges -11 -The size of the paper is used in the Ha Ha home sample standard (CNS) T4 specification (210x297 male dragon) 8 丨 .4. 丨 0,000 sheets (H) 200550 Λ 6 Β6 V. Description of the invention (10) The wide range is the best Best range X 6 to 100 6 to 43 12 to 30 y 6 to 100 12 to 77 12 to 50 m 0.75 to 30 1.5 to 25 2.25 to 20 η 0.25 to 20 0.5 to 15 0.75 to 12 m + n + l々n + l 1 to 5 1.2 to 4.5 1-5 to 4 (please read the information first, please note it. Note this page again) The Bureau of Standards, Ministry of Economic Affairs, only the consumer cooperation Du Yinyu These projects are pointed out to be inserted in the MPEG unit Average neighbor Connect the number of terephthalate units. It can be seen that the ratio of oxyethyleneoxy: oxypropyleneoxy units can be changed to meet the needs of the modulator. H and Li plaque_drink .. 'North..agent_the. —Uses, squares .. noodles—, this ratio is preferably at least about 0.7 5: 1, and ¥ at least about 1.2 5; 1 is more f. For the ϋ Li Jie. Li Jin m, if At such a ratio, some products may become childlike, so the blender may choose a slightly lower ratio, for example, _0.5: 1 ... The invention also covers washing compositions such as detergents, Softeners, wetting ribs, etc., include at least about 0.1% by weight (preferably from about 0.2% to about 10% by weight) of the aforementioned s "a's. Preferred fabric softeners here typically include about 0.3 Weight% up to «-12- This paper is used in the 5k-scale side-to-side model (CNS) A4 specifications (2〗 0x297 g;« :) 81. 4. Ιϋ, ΟϋΟ ^ (11) 200550 Λ 6 ___ V. DESCRIPTION OF THE INVENTION (11) About 3% by weight of 2sra and about 3% by weight to about 25% by weight of fabric softener ingredients. A dilute liquid fabric softener sister product concentrate includes: (a) about 10% by weight to about 32% % By weight cationic fabric softener; (b) about 4% by weight to about 20% by weight imidazole cake fabric softener; and (c) about 1% by weight to about 5% by weight 2sra. Typical detergent and detergent products here include conventional detergent surfactants, any builder, any carrier, and 5 "3 from about 0.1% to about 10% by weight. Preferred detergents are Including about 0.3% by weight to about 3% by weight of the soil release agent and at least about 3% by weight (M is about 3% by weight to about 20% by weight) fatty acid polyhydroxyamide surfactant, in detail , C12 to C1S fatty acid N-methyl glucosamine. Printed by the Ministry of Central Standards Bureau KX Industry and Consumers ’Cooperation Co., Ltd." The present invention also covers a method to provide a dirt release finishing for suspected products. With an aqueous medium [containing at least about 2 ppm (2 parts per million) of the aforementioned sr * a 's]. In a preferred horizontal mode, such a method includes Μ followers and a water bath [including at least 3 ppm (W about 4ρριπ To about 25 ppm, preferably) the aforementioned sra's and at least about 10 ppm (preferably from about 30 ppm to about 10 ppm) of the cationic softener] come into contact and separate the fabric from the water bath for a period of at least about 1 Minutes (preferably from about 1 minute to about 10 minutes). (Satisfied Even with a low S "a's Medo can also effectively perform multiple cycle processing). Satisfied with the conventional automatic cleaning machine during the wetting cycle * This method can be easily performed. Here all percentages, The ratios and ratios are based on the weight of the M 'unless otherwise specified. -13- 81. 4. 10,000 sheets (H) (please read the back-up notes ^ Item " this page) This paper is 5 gram size and is used in a Ming Family Standard (CNS) «P4 specification (210x297 mm) 200550 Λ 6_η 6 V. Description of the invention (12) Printed by the Employee Consumer Cooperative of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs ^ mm m The sra's and M ester of the present invention were prepared The substituted hydroxy- and carboxylate reactants disclosed above. The following examples further illustrate the preparation of sra's in accordance with the present invention, but do not limit the scope thereof. II. Poly (ethylene dioxonate) S7 5 0), p-cage dimethyl dimethyl ester, poly f 7, di quinone) (sub-hanshan 15 00), 7, synthesis of bis bis propyl propylene dimer polymer respectively add the following substances to the magnetic Stirring rod, modified C 1 aise η joint, condenser (for distillation unit), thermometer, and temperature (THERM-0-WATCH > I2R) in a 250 ml 3-neck round bottom flask: poly (ethylene glycol) methyl ether with a molecular weight of 750 (Aldrich, 50.0 g, 0.067 mol), paraben dicarboxylic acid Methyl ester (35.6 g, 0.183 mol), poly (ethylene glycol) with a molecular weight of 1500 (Aldrich, 50.0 g, 0.033 mol), ethylene glycol (Baker, 7.2 g, 0.116 mg), 1,2-propanediol (Fisher, 8,9 grams, 0.117 mole), monobutyltin hydrated gas (produced by M & T Chemicals, 0.30 grams, 0.2% knot! Reaction weight), and butylated hydroxytoluene (Calbiochem, 0.15 g, 0.1% reaction weight). This mixture was heated to 180 ° C and maintained at this temperature under argon overnight while distilling methanol and water from the reaction vessel. 13C-NMR (DMS〇-de) shows that there is residual resonance of reed for methyl ester at about 52 ppm. Raise the temperature to 200t: for 5 hours, then add additional glyphosate (7.2 g, 0.116 mole) and propylene glycol (8.9 g, 0.117 mg ear) -1 4-(Please read the notes beforehand (Fill in this page) This paper uses the Chinese National Standard (CNS) (210X297 male dragon) for free use of the paper. 81. 4 · 丨 0,0⑻ Zhang (H) 200550 Λ 6 η 6 V. Description of the invention (13). Reduce the temperature to 190C, and maintain it overnight under this condition. 13C-NMR (DMS〇-de) shows that the reaction at this stage has been completed without methyl ester resonance. This material was transferred to a 1 liter single-neck round bottom flask and heated gradually to 2 30 t in a Kugelrohr apparatus (Aldrich) under about 1.5 mm Hg for more than 20 minutes and maintained under this condition for 1 + Hour. Then, the flask was allowed to cool down to near room temperature (approximately 30 minutes) under a vacuum. Nitrogen yielded 124.1 grams of soft brown solid stern. (UMLHDMSO-de) shows extremely dense resonance at about 3.5 ppm for poly (ethylene oxide) fragments, about 8.0 ppm for parabens, and about 2.00 for methyl esters of double esterified malonase There is resonance at 1.4 ppm and there is resonance at about 4.7 ppm for double esterified ethylene glycol. The resonance of tb at 1.4 and 4.7 ppm indicates that the molar ratio of units derived from glyphosate to units derived from propylene glycol is about 2.2: 1. This is called the E / P ratio. Its 13C-NMR (DMS〇-de) is also consistent with the desired polymer structure and shows that these resonances are at 70.2 ppm (polyethylene oxide part). . 5 ppm (C Η 3 of double esterified propylene glycol), 6 3 .6 p P m (double esterified glyphosate), and 58_4ppra ((HO CH2CH2〇-). Because for the ethylene glycol (-C (0 ) OCHaCH ^ OH) any single compound at about 60 ppm or for the propylene glycol (_C (0) 0CH (CH3) CH2OH) isomer is one of the methyl ester and there is no resonance at about 20 ppm It is pointed out that this has a high degree of polymerization. It is possible to obtain oligomers with a low E / P ratio and to use the same synthesis conditions in addition to reducing the initial ratio of glyphosate to malonylase. It is about 0.25: 1 and the final E / P ratio is about 〇.5. -15- 51 papers are widely used in a B home dazzle kite (CHS) A 4 specifications (2 father 0 father 297 male dragon) 81. 4. 10,000¾ (||) 200550 Λ 6 ΙΪ6 V. Description of the invention (14) m τ τ 7ι Two brews, p-dimethyme dimethicone 8¾, poly (ethylene glycol) Tianyu (ϋ g 750), poly (Ethyl yeast) ( The amount is 15 00) and 1.2-propanediazide F / P = 1.M polymer (Xihuicheng) Place the substances listed in the table below with a magnetic stirrer, heating hood, built-in thermometer, steamed joint, A 5-liter large, cooler device for distillation, for the inert gas tank, and THERM-0-WATCH (I2R) for temperature control, etc., j, 3 neck round bottom flask: (Please read in advance (Besides pay attention to the Bian item on this page.) The Central Bureau of Economics of the Ministry of Economic Affairs only works with the consumer to cooperate with Du Yinweig. The number of moles is derived from oxalase 130.2 2.1. — — MCB dimethyl terephthalate 640.2 3.3 Aldrich poly (Glyoxal) methyl ether (molecular weight 750) 300 0.4 United Carbonization Corporation poly (ethylene glycol) (molecular weight 1500) 1500 1.0 United Carbonization Corporation 1,2-propanediol 322 4.2 Fisher's hydrated monobutyltin oxide (FASCAT 4100) 5.5 M & T Chem company's water-based hydroxymethyl stupid (BHT) 3.2 Calbiochem company stirred this system and its temperature gradually increased to 185t: and maintained under this condition for 28 hours while there is formazan steamed from the reactant. Then Insert the transparent glass inlet tube close to the bottom of the bottle The inert gas is introduced at a high speed and the -16- 81. 4. ΙΟ, ΟΟΟΙ (Η) This paper size is used in the BB home sample standard (CNS) Ή specification (210x297 public *) 200550 V. Invention description (15) Printed by the β-Consumer Evaluation Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs to raise the temperature to 24010. It took about 13 hours to push this situation. The resulting polymer was allowed to cool to obtain about 2400 grams of soft solids. If K was tested at 10% solids and M was stirred overnight, most of it was soluble in water at room temperature. 1H-NMR (de-DMS0) showed a very dense resonance at about 3.45 ΡΡίπ for the polyethylene oxide moiety, a complex or resonance at about 8.05 ppm for parabens, and for double esterification The methyl group of propylene glycol has resonance at about 1.4 ppm | and has resonance at about 4.7 ρρπ for double esterification of glyphosate. Comparing the resonances at 1.4 and 4.7 ppm indicates that the molar ratio of units derived from glyphosate to units derived from propylene glycol is about 1.5: 1. This refers to the E / P ratio. The 13C-NMR (d--nMsm data is also consistent with the desired polymer structure, and the resonances shown are: 70.2 ppm (polyoxyethylene part), 16 ppm (CH3 after double esterification of propylene glycol ), 63.6 ppm (by double esterification of ethylene glycol), and a very small peak at 58 ppm (CH ^ OCH ^ O-). From about 60% for any oxalase monoester (-ίΜίυοεΗζςϋ ^ ΟΗ) There is no real resonance at about 20 ppm at the ppm or for one of the isomers of malonate (-C (0) 0CH (CH3) CH2〇H). This indicates a high degree of polymerization Extent of action. Examples TTT Ethylene glycol, dimethyl terephthalate, poly (glyoxal paste (p aa 7.5 00), poly (glyoxal) (p. 15 00) and 1.?- Methylenedioxiride complex (will be 1) Place the substances listed in the table below in a magnetic stirrer, heating hood, built-in thermometer, distillation joint, condenser device for distillation, for inert gas inlet-17- (Be sure to read the precautions first and then fill out this page) Install _ * 3r_ This paper is in 5 gram size and is used in the middle. 8 Η home sample standard (CNS) TM specifications (210x297 public *) 81. 4. ιο, υυο Zhang ( η) 20055 0 V. Description of the invention (16) Port, and THERM-0-WATCH (I2R) 5L size, 3-neck round bottom flask for temperature controllers etc .: Gram Molar number Source Glycogen 408 6.58 Fisher Dimethyl phthalate 1024 5.28 Aldrich poly (ethylene glycol) methyl ether (molecular weight 750) 480 0.64 Aldrich poly (ethylene glycol) (molecular weight 1500) 2400 1.60 Aldrich 1,2-propanediol 510 6.71 Ma 11 inkrodt hydrated oxidation mono Butyl tin (FASCAT 4100) 3 M8, T Chein Water-based hydroxymethyl stupid (BHT) 3 Calbiochem Central Bureau of Standards of the Ministry of Economic Affairs only "Consumer Printed by Cooperative Society" Stirs the system and gradually raises the temperature from 175T: to 195Ό After a period of more than 36 hours, 290 grams of distillate (mostly methanol) was collected. Then the temperature was raised to 2101C for 18 hours and more distillate was collected at this time. Then a transparent glass inlet tube was inserted Close to the bottom of the flask and passing the inert gas K at a high speed to maintain the temperature at 200 C. A small amount of additional steam was collected for about 4 days in this condition. Allowing the resulting polymer to cool to about 3800 grams of soft solids, If 1 % Solids was tested and stirred overnight, about 65% of them were soluble in water at room temperature. (In the lower solids solution, a relatively high dissolved part is clearly visible). It is shown by 1- ^ 1? ((^ -0> ^ 0) for the polyethylene oxide part with extremely dense resonance at about 3.45 ppm, and about 8.〇5 -18 for parabens -81. 4. Ιϋ, ουο Zhang (if) (please read ^ Backwards "# items to write this page) This paper size is not included in China National Standards (CNS) Ή specification (210X297mm) 200550 V. Description of the invention (17) (please read the notes on the back and write this page first) There is a double resonance at PPm, and about 1.4 ppm for the methyl ester of the double esterified malonase For the dual oxalase, there is resonance at about 4.7 ppb. Comparing the resonances at 1.4 and 4.7 ppm indicates that the molar ratio of units derived from oxalase to units derived from malonylase is approximately 2.6: 1. This is referred to as the E / P ratio. The 13C-NMR (d «-nMsm age sow the desired polymer structure is consistent and shows the following resonance: 70.2 ppm (polyargonated ethylene part), 16 ppm (after double Esterified malonase CH,), ^ «PPm (extracted double esterification of oxalase), and a very small peak at 58 ppm (QiU〇CH2CH2〇-). Since for any oxalase (-C ( 0) OCH2 CJL2.O Η) monoester at about 60 ppm or for a propylene glycol isomer 糸 monoester (_C (0) 0CH (CLlaJ CH20H) and at about 2 0 dd ™ there is no real resonance indicating that it has high polymerization Following the imaginary description of the Ministry of Economic Affairs and the Central Bureau of Industry and Commerce β-consumer cooperation Du Yinju can use the sra's according to the present invention in a variety of different environments where it is necessary to transfer the dirt release finishing to In the fabric, in detail, in the washing operation. For example, the sra's can be added directly to the washing or wetting bath of the automatic cleaning machine. Or during the ironing operation, the sra's can be sprinkled on the fabric In other modes, sra's will be deposited on the fabric during the washing and drying operation in the automatic eye dryer. In the preferred mode, the sra's will never contain fabric softener (as It is a well-known cationic fabric agent) deposited in the water bath in the water. In fact, a variety of different sra's can be selected from those shown here and is quite compatible with the cationic Shitou even if "triple shrinking agent" Liquid weave · -19- 81. 4. 10, (W0 Zhang (H) The 5fc scale of each paper is used in the national B standard (CNS) T4 specifications (210X29? Public *) 00550 Λ 6η 6 V. Description of the invention (18) (please read the back and forth precautions #pot write this page) product softening The product that has recently flowed into the market will not deleteriously increase the viscosity. Generally speaking, sra's with lower molecular weight will produce lower viscosity increase. Therefore, all of the better sister systems here can provide the ingredients of brazilian agent and bra ’s * and this K is designed to provide softening (and antistatic) benefits with dirt release conditioning. The following is intended to assist the modulator to manufacture the combined fabric softener / soil release agent, but does not intend to limit its scope by M. Liquid fabrics are used as agents V. The liquid secondary softener agent of the present invention, the objects include the foregoing The defined effective amount of s "a's. The so-called" effective amount "depends on the following factors: the specific sra's used, the specific form of the suspected softener formula and the required benefit. Generally, if the sra's content is accounted for by the sister From about 0.01% to about 10% by weight of the finished product, they are effective. In terms of soil release benefits, the preferred fabric softener sister products include about 0.1 to about 5% by weight of sra's, but Typically, these compounds include about 0.3 to about 3% by weight of these compounds. The Ministry of Economic Affairs, Central Standards, Employee Consumer Cooperatives of the invention printed the suspected softener of the present invention, further comprising about 2 to about 50% by weight (from about 3 to about 25% by weight is preferred) fabric softener component. Used in conventional strength (1 times) fabric softener composition, fabric softener composition typically includes about 3 to about 10% by weight of the fabric composition. Shanghai shrink For example, 3 times) fabric softener composition, the fabric softener composition typically includes about 15 to about 25% by weight of the fabric composition. The fabric softener composition typically includes mono- or bis (higher alkyl) quaternary ammonium Salt or a mixture of such salts. See December 20, 1975, issued to Temple -20-81. 4. 10,000 sheets (H) of this paper on 51 scales for easy use 8 »Home Samples (CKS) A 4 specifications ( 210x297 public *) 200550 A 6 Π 6 V. Description of the invention (19)-U.S. Patent No. 3,928,213 at position γ, in detail, its second line from line 57 to its fourth line from line 34, and August 1983 U.S. Patent No. 4,399,045 issued to Burns on May 16th, in detail, its fourth line from the 23rd line to the second line from the 7th line (herein and in this article for reference), which shows the appropriate quaternary ammonium salt "Higher alkyl" used in the context of quaternary ammonium salts means alkyl having 8 to 30 carbon atoms, preferably 12 to 22 carbon atoms. Such conventional quaternary ammonium salts Examples include: 1. Quaternary ammonium salts of the single nitrogen atom with the following formula: (please read the back-to-hand a meaning matter #pot to write this page) equipment-consumption by employees of the Bureau of Economics and Trade of the Ministry of Economic Affairs Cooperative Innu R.-N +-R3 A ', 1 t R: where 1 ^ is an aliphatic C12 to C22 hydrocarbon group; R2 is (^ to "saturated or a hydroxyalkyl group. R2 is selected from Ri (preferred) Or R2 group and A is an anion tetrachloro, bromine or methyl sulfate. Examples of suitable single nitrogen atom quaternary ammonium salts are atmospheric monotallow trimethyl ammonium (MTTMAC), ditallow tallow methyl chloride Ammonium (DTDMAC), ditallow methyl dimethyl sulfate, dimethyl ammonium bis (hydrogenated tallow) dimethyl ammonium, bis (ammonium based) dimethyl ammonium, di (16) Alkyl) dimethyl ammonium, bis (octadecyl) dimethyl ammonium chloride, bis (eicosyl) dimethyl ammonium chloride, bis (docosyl) dimethyl ammonium chloride , Di (hydrogenated tallow) dimethyl ammonium, di (hexadecyl) diethylammonium chloride, ditallow bromide _ This paper standard is used in Chinese ® Sleepy Family Shade Standard (CNS ) T4 specifications (210x297 male dragons) 8 !. 4. 10, UUt) Zhang (H) 200550 Λ 6 Π 6 Ministry of Economic Affairs, Ministry of Economic Affairs, Ministry of Economic Affairs, Beigong Consumer Co., Ltd. Printed by the cooperative ^ V. Description of the invention (20) Base 2 Propyl ammonium; bis (coconut alkyl) chloride Methyl chloride; and mixtures thereof class. 2. Quaternary ammonium salts of diamides with the following formula: 0 R6 〇R4-C-NH-R3-N +-Rg-NH-C-R4 A-Rr where R4 is an aliphatic C12 to C22 hydrocarbon group; R3 and R5 is a divalent alkylene group each having 1 to 3 carbon atoms; 1 to 3 series (: 1 to (^ saturated alkane or hydroxyalkyl; R7 is Re or (CaH2e〇) bH part, where a is 2 or 3 and b is from 1 to about 5; and A is an anion. An example of a suitable quaternary ammonium salt of diamide is methyl bis (tallowamide ethyl) (2-hydroxyethyl) ammonium methyl sulfate, Methyl bis (hydrogenated tallowamide ethyl) ammonium (2-hydroxyethyl) ammonium and bis (2-hydrogenated tallowamide ethyl) ammonium ethoxide; these substances were taken from Sherex Chemical Company The commodities are VARIS0FT 222, VARIS0FT 220 and VARIS0FT 110 respectively; 3. Tetraimidazole cake salt such as methyl 1-methyl-1 -tallowamide ethyl ethyl 2-tallowimidazole cake (trade name of MVARIS0FT 475 Sale), 1-methyl-1- (hydrogenated tallowamide ethyl ethyl) methylsulfate-2 -tallow fatty oxazolidine (sold under the trade name of MVARIS0FT 445), 1-ethylidene-bis (methylsulfate 2 -Tallow-1 -methyl-imidazole ) (With the trade name of VAR IS0FT 61 12-22- winter paper 5 good standard universal SB home sample (〇 ^) dry 4 specifications (210x297 mm) 81. 4. 1 (), 000¾ (! |) ( Please read the precautions and write this page first) 200550 Λ 6 Π 6 V. Description of the invention (21) Sale); and methionine tallow amine ethyl VARIS0FT 3012 is used to soften the softening products including: (A) About 2 to 0 to about 14% by weight of the second most amount of the fourth-grade zona azole salt about 15 to about 22.5% by weight National Patent 4,399,045 1 Fabric softener sister amines, typically as amines It has the following formula: acid 1-methyl-2 tallow amine group), the trade name of the sales agent composition of B, about 15% by weight of monoacetamide quaternary ammonium salts; and A, B,. See 1 In August 983, its content-and also included some special and four-saddle saddle salt (class)-animal fat base-3-"base] squint cake (Μ) ° The preferred fabric softener composition Nitrogen quaternary ammonium compounds; (B); (C) about 2 to about 13 weights and the number of hair types of C is awarded to Burins on the 16th of this article and reference. Ding two (higher alkyl) ring mixture. These Ring system Z-Rf ? Read first and then-Note: Items Μ C I R «Central Bureau of Standards of the Ministry of Economic Affairs cx 工 消 1-Ϊ-Cooperative Duin ¾ Where c is 2 or 3K2 is better; it is a separate SCa $ C3. Alkyl, or alkenyl hydroxy, preferably Cn to C22 alkyl, K (: even Cle timid, or a mixture of such alkyls, such as those obtained from coconut oil, "soft" (non-hardening) Animal fat, and hardened animal fat; CI is CH or n, and MN is better; Z is 23-the standard of this paper is used in a country "quasi (CNS) T4 specification (210X297 mm) 81. 4. 10,000 sheets ⑻ V. Description of invention ()

Ri〇-TC-A 6-B6 where T is 0 or NR ^, Ru is Η or Cl to C4 alkyl, ΜΗ is preferred; and R1〇 is a divalent "to" alkyl or (C2H4〇) 4 group , Where d is the number from 1 to 8, or redundant! ? 10. Specific examples of such amines are as follows: 1-tallowamide ethyl-2-tallowoxazoline; 1- (2-C14-18-alkyl-acetaminoethyl) -2-Ci3-C17- alkyl. 4,5-dihydroimidazole; 1-stearylaminopropyl-2-stearic oxazoline; and 1_aniline fatty butylamine-2-butyl tallow hexahydropyridine. These amines and their preparation methods are fully described in British Patent Application No. 8,508,130 filed by Koenig and <^ 81 ^ 23〇8 "1111 on March 28, 1985, and are hereby incorporated by reference. (See also U.S. Patent No. 4,711,730, No. 28). 1. Acids and chrysanthemums that can be removed-if the ring system amines are present in the fabric cooking agent component *, the suspected agent is a chemical It is important to properly disperse amines. In addition, some acids are better for the hydrolytic stability of the soil release compound of the present invention. Therefore, acids and / or alcohols can be added to sister compounds Adjust the amount. The amount of acid or test is false after mixing. • The pH range of the dispersant is about 2.5 to about 6.5 t. Examples of suitable acids include inorganic mineral acids and carboxylic acids, in particular, low scores. Amount ((^ to (: 3) Carboxylic acid * and alkane sulfonic acid. {Please first read the precautions on the back and then write this page). ¾. • Hitting • • Edge. A 4 (210X 297 public)- 21- 200550 Λ 6η 6 approved by the central government of the Ministry of Industry and Commerce 13: Industry and Consumer Cooperation Du Yin 3i V. Description of the invention (23) Low molecular weight ((^ to (: 3) carboxylic acid, and alkane sulfonate Suitable inorganic acids include HCl, H2S〇4, HN〇3 and η3ρ〇4. Suitable organic acids include formic acid, acetic acid, methanesulfonic acid and ethanesulfonic acid. Preferred acids are hydrochloric acid, phosphoric acid, formic acid and methanesulfonic acid Acid. Convenient bases include NaOH and Ha2C〇3. 2. Organic solvent-The fabric softener composition of the present invention can be prepared without using any organic solvent. However, organic solvents exist (for example, with a low molecular weight and water-soluble phase) Mixed aliphatic alcohols) are not detrimental to the storage stability, viscosity, or softening performance of the adult products. Examples of such solvents include ethyl yeast and isopropyl alcohol. Typically, quaternary ammonium salts (or cyclic amines) are obtained. K is supplied in a solid form or as a solution in an organic solvent (such as isopropanol) from a supplier of B u 1 k Chemical Company. It is not necessary to remove the solvent in order to prepare the finished product. In fact, if really needed , Additional solvent can be added. 3. Any non-ionic system-fabric softener product can optionally contain non-ionic materials as disclosed for use in softener products. Such non-ionic system The substance and the use concentration were on June 12, 1984 U.S. Patent No. 4,454,049 issued to MacGilp has been disclosed herein and is hereby incorporated by reference. Non-ionics suitable for use in fabric softener compositions in particular include glycerides (eg glyceryl monostearate) Esters), lipases (e.g. stearase), and alkoxylated fatty alcohols. If non-ionics are used, the typical dosage range is about 0.5 to about 10% by weight ° ~ 2 5-(please start with ΙΙ1 ,? 背 而 之-注解 亊 项 #Fill in this page) 装 · 线-This paper 5Jt scale is easy to use in the Chinese National Standard (〇 阳) Yuan 4 specifications (210x297 male dragon) 81. 4. Zhang (Η) 200550 Λ 6 Π 6 V. Description of the invention (24)

The Ministry of Economic Affairs, Ministry of Economic Affairs, Bureau of Engineering, A, Consumer, Cooperation, Du Yin, M. Although it is generally recognized that non-ionic materials have the softening properties of Burmese products, in order to calculate the amount of suspected softener components in the sister product, it is not considered this It is part of the suspected softener ingredients. 4r Any silicon component-the suspected softener is free of water-based emulsifiers containing mainly linear polydialkyl or alkylaryl siloxanes, where the alkyl group can have 1 to 5 carbon atoms and all Or partially fluorinated. It is suitable that the silicon-based polydimethylsiloxanes have a particle size in the range of about 100 to about 100,000 centipoise, and preferably in the range of about 1,000 to about 12,000 centipoise. The ion valence of the silicon feed as used in the combination is important for the determination of the following sexual foods: the degree of silicon deposition and the uniformity of distribution and the nature of the fabrics treated from then on. Silicones with ultra-fine cation strips show a tendency to enhance deposition. It is found that the value of silicon is to provide the benefit of softness of the suspected product. This has mainly linear characteristics and polydialkylsiloxanes are preferred, among which alkyl M groups are the most common. In the commercial aspect, such silicon polymerization is often produced, and M uses a strong acid or a strong base catalyst to emulsify and polymerize in the presence of a non-ionic or mixed non-carved and anionic milling agent system. Any silicon component also includes silicon with cationic characteristics and is defined as one of the following: (a) Mainly linear poly (^ to (^ alkyl- or d-alkyl, aryl, polysiloxane, They are prepared from emulsification polymerization using cationized surfactants as emulsifiers; (b) α-W-two or four quaternary CiMCs or (^ to "alkyl, arylsiloxane-26 -(Please read the back-to-back &gt;: t notice Λ fill in this page) Binding-Order _ Line. This paper is used in the "Mingjia" standard (CNS) &lt; P4 specification (2 丨 0X297 公 *) ) 81. 4. 10,000¾ (I!) 200550 Central Ministry of Economic Affairs Bei Gong Xiao # Cooperative seal 4 Λ 6 __Π_6 _____ V. Description of the invention (25) Polymer; or (c) Amino functional group di (^ To "alkyl" or alkylaryl siloxane polymers, in which the amine group can be substituted with M and tetramethylated and the degree of substitution (ds) ranges from 0.001 to 0.2, and M 0.01 to 0.073 is preferred ; But the viscosity of silicon at 251C is about 100 to about 100,000 centipoises. The fabric softening composition here may contain up to about 10% (about 0.1 to about 5% is preferred) of silicon components. 5. Other Ren Ingredients-In order to further improve the characterization of the spikes of the suspected softener sister products and further adjust their viscosity, these sister products may contain relatively small amounts of electrolytes (eg, 0.1% to 3%), such as NaCl, KC 1. LiCl, MgCU or CaCl2 ° Fabric softener can also contain any other ingredients known to be suitable for use as an analyte softener. Such adjuvants include fragrances, preservatives, biocides, colors, dyes , Antimicrobial agents, stabilizers, brighteners and opaque agents. If these adjuvants are used, they are usually added at a conventional concentration (approximately 0.1% to 5%). However, in the composition ' For the purpose of (increasing) the fabric treatment effect (for example, the use of fragrances) *, these substances are added to a higher degree than the conventional degree (equivalent to the majestic degree of the product). The remaining substances of the liquid softener of the present invention It is water. The following describes the liquid composition of the aforementioned type. -27- This paper uses standard BB standard (CNS) f 4 specifications (210X297 g *) 81. 4. 1 (), 000 sheets (II) 200550 Λ 6 Π 6 V. Description of the invention (26) Examples of TV made woven The softener is the base compound and M is composed of the following components: Serving t% Adiated Ditallowyl Dimethyl Ammonium 4.33 Methyl Sulfate Methyl Sulfate 1-Tallowyl Acetyl Ethyl Ethyl 2-Tallowyl Fatty Imidazole m (VARIS0FT 475) 1.0 Ethanol 0.7 Isopropyl alcohol 0.1 Fragrance 0.42 Dyes 0.1 Small amount »&lt;» Up to 0.1 Water balance * Refers to preservatives, HaCl, NaOH, H2S〇4 Antioxidant solution. In Examples I and II, respectively,% by weight of Ssra's was added to this and the base compound to provide fabric softening / sra compound IVA and IVB. (Please read the precautions / f fill in this page first) Binding and threading.

Printed by the Employee Consumers Cooperative of the Ministry of Economic Affairs of the Central Committee of the Ministry of Economic Affairs. Printed on this paper. S »Home Sample Standard (CHS) 4 specifications (210x297 male dragon) 8i. 4. 10,000¾ (||) Λ 6 Π 6 200550 V. Description of the invention (27) Example V-V Τ Τ Τ prepared with a conventional strength and concentrated suspect softener-based sister compound and M from the following ingredients: (please read the back and pay attention to this item &quot; 碣 写 本Page) The Ministry of Economic Affairs, Ministry of Economic Affairs β 工 消 # Cooperative Society Seal 31 * Refers to CaCU, dyes, and fungicides adding 0.5% by weight 3 "3'5 of Example I and Example III to the conventional strength base sister product V" And VII. The 1.5% by weight sra of Example I and Example II were added to the concentrated sister products VI and VIII. -29- ^ _ia_ Che *% V VI VII VIII dichloride Tallow dimethyl ammonium 3.65 7.7 2.33 7.0 1-tallow fatty amine ethyl-2- tallow imidazoline 3.65 14.3 4 .33 3. 0 tallow trimethyl ammonium chloride 0.5 0.5 — — polydimethyl Siloxane (viscosity is 00 centipoise) 0.2 0.6 1.33 4.0 Perfume 0.25 0.45 0.25 0.45 Small amount * 0.13 0.13 0.13 0.13 HC 1 --- Add to fH 4--Water --- η Amount-The 5fc scale of the paper is used in the national standard of China (CNS &gt; A 4 specifications (210 &gt; &lt; 297 public; »:) 200550 Λ 6 Π 6 V. Description of the invention (28) Example 1. Mae shrinkage softener is based on the elder sister's finished product and is based on the following ingredients: m_fiL ray day% Ammonia dihydrogenated tallow dimethyl ammonium 13 Methyl sulfate 1-methyl-1-tallow fatty amide ethyl ethyl- 2- Tallow fat imidazole cake 3 Polar bright blue dye 80 ppm CaC 1 2 0.265 Perfume 0.75 Ethanase 0.92 Isozyme 1.36 Water balance Add 1.5% by weight isra's in Examples I, II and III to this type Ji Jicheng Cheng M provides IXA, IXB, and IXC with concentrated softener and sra's. (Please read the precautions before filling out this page) Central Ministry of Economic Affairs and A Gongxiao Cooperative Society Printed in 31 copies of the Λ5 Gen scale using the Chinese B home sample standard (CNS) T4 specification (210x297 g; 4) 81. 4. Ιυ, ουϋ Zhang (π) 200550 A 6 η 6 V. Description of the invention (29) Example y species The preferred softener products are as follows: 6R Fang Ruan %% of the Ministry of Economic Affairs, Ministry of Economic Affairs, Central Bureau of Accreditation, KX Engineering Consumer Cooperative Cooperative, Cooperative Printed DDTMAC _ 4.00 MTTMAC 0.67 VARIS0FT 475 ^ 2.00 Water Seat (Water Seat ·) Pure water balance Si1icone DC-1520 (anti-foaming agent) 0.02 H C1 * * 0.35 Lytrο η 621 (dye) 0.75 SRA ϋ ϊ: * 2.25 KATHON (after addition) Preservative) 0.04 Poly (dimethylsiloxane) *** :: = 0.20 Perfume 0.30 =: = anazoyl fabric softener ** enough to make the pH of the final product between 3 and 3.5. Prepared as in Example I; E / D ratio 1.5. 55% polydimethyl J silicone (350 cps) emulsifier (in water). The premix is blended with the water seat and then combined with the added mixture. -31-B4 Hengjia Standard (CNS) T4 specification (210x297 g; ¢) (please read the first one and fill in this page) 200550 Λ 6 Π 6 V. Invention Description (30) Example X Τ Using the ingredients described in Example X, a 3-fold concentrated fabric softener such as Bian was prepared. m_ί2_ Pre-compound DTDMAC VARIS0FT 475 Water Seat Pure Water Silicone DC-1520 WC \ ly Lytron 621 (dye) SRA (E / P 1.5 / each case II) KATHON poly (dimethyl) after addition Siloxane) Perfume weaving SF Fangxi weight% 14.67 6.00 Balance 0.023.35 0.75 1.50 0.04 0.541.05 (please read the back-to-back information and write this page again) Install · Order _ Line _ Ministry of Economic Affairs The central government quasi-bureau CX 工 消 # Cooperation Du Yin 51 * Fully make the final product in the range of 3 to 3.5 -32- the size of the paper is used in the H B home coal (CNS) specifications (210x297 male dragon) 8i. 4. 10,000¾ (If) Λ 6 Β6 200550 V. Description of the invention (31) (please read the back-to-back item-then item &quot; this page) mmm ma The sra's of the present invention can also be used for certain washing and cleaning The M in the sister product provides dirt release properties. These sister products can be used as a cleaning detergent, a detergent additive, and a washing pretreatment agent. The detergent cleaner product of the present invention includes a dirt release component and contains the above-defined effective The number of sra's. The so-called "effective number" is determined by the following factors. The specific sr. A's, special The type of cleansing agent formula (liquid, granules, etc.) and the required benefits. Generally, if the content of s "a's in the sister product is from about 10% to about 10% of snow, then they are effective. In the benefit project, the preferred detergent detergent composition may include about 0.1 to about 5 wt% 2sra's, but typically includes about 0.3 to about 3 wt% of these compounds. Economy Printed by the Ministry of Central Standards CX Industrial Consumer Cooperative for _ γ detergent formulations · sra ingredients typically include sra compounds plus any protective coating substances. In the formulation of granular detergents, sra can be exposed to High sickle substances such as NaOH and Κ0Η. S "a's (specifically, those with shorter backbones) can be degraded to an alkaline environment, in particular, those exceeding about 8.5. Therefore, it is preferable The way is to coat sra's in a substance to protect them from the alkaline environment of the granular detergent formulation and still allow the s "a's to be dispersed in the washing operation. Convenient coating substances include non-ionic Shito surfactant, Polyethylene glycol (PEG), fatty acid, two enzyme Fatty acid esters of polyhydric alcohols, anionic Shito surfactants, film-forming polymers, and mixtures of these substances. Examples of suitable nonionic Shito surfactant coating materials include some of those described below and are also used as sisters Useful detergent surfactants in adult products. Heyi-33- Chinese standard (CNS) specifications (210x297 male dragons) for various scales of Xiaoxiao 81. 4. ιυ, υυο Zhang (II) 200550 Λ 6 Π 6 By # 部 屮 央 擂 准 局 CO: Printed by the Industrial and Commercial Cooperatives 31 V. Description of the invention (32) Examples of PEG coating materials are those with an average molecular weight of about 2,000 to 15,000, preferably about 3,000 to about 10,000 and M About 4,000 to about 8,000 is best. An example of a suitable fatty acid wrapper is a high-gold fatty acid having 12 to 1δ carbon atoms. Examples of suitable fatty acid ester coating materials include sorbitan fatty acid esters (e.g. sorbitan monolaurate). Other examples of suitable packaging materials include anionic surfactants and film forming polymers, which are disclosed in U.S. Patent No. 4,486,327 issued to Murphy on December 4, 1984, and are incorporated herein by reference. Sra's can be coated according to the methods disclosed in Murphy patents. For use in liquid detergent formulations, the sra ingredients may contain sra ’s or may further contain water-soluble organic solvents or hydrotropes to assist in dissolving sra ’s. Suitable organic solvents are ordinary aromatics and may include ethyl benzoate, phenoxyethanol, methyl o-methylbenzoate, 2-methoxybenzyl yeast and tetrahydropyrrole. Suitable water-soluble ribs include methyl-capped PEG'S and shorter backbone polyesters. These short backbone polyesters are more soluble in water and therefore their function as hydrotropes for sra's with longer backbones and less water insolubility. The amount of organic solvent or water-soluble rib-lengthening agent used to prepare the liquid detergent formulation containing sra's of the present invention (or the amount needed) is determined by the following factors: the sra's used, part of it in detail It is soluble in water, the components present in the cleaning detergent system, and whether it is required to be an isotropic homogeneous liquid. It is used in the formulation of isotropic liquid cleaners. In order to dissolve sra ’s as much as possible, sometimes it is required to use organic solvents or water-soluble rib-lengthening agents. And Xianxin dissolves sra's in the liquid detergent formula to make them more effective. -34- (please read the back-to-back 泾 意 事 #fill this page) CNS) T4 specification (210X297; ":) 81. 4. 10,000». (II) Λ 6 Π 6 2〇〇55〇 V. Description of the invention (33) (Please read the notes and notes * # 砀Write this page) As a dirt release agent, M is beneficial to dissolve in the washing solution and thus adsorbed on the target suspect. The detergent product of the present invention preferably contains from about 5 to about 75% by weight of non-drying non-ionic cleaning surfactant. It is more preferable that the non-Hina Shito cleansing surfactant K accounts for about 10 to about 40% by weight of the adult product, and about 15 to about 30% by weight of K. Generally speaking, suitable nonionic surfactants for use in the detergent composition of the present invention were issued to LaughterU in the United States on December 30, 1975-'A ·· Patent No. 3,929,678, No.13, No.14 It is revealed in the 6th row to 16th row (here and for reference). The nonionic Shito surfactants include the following categories: 1. Polyethylene oxide condensates of alkylphenols. Examples of compounds of this type include the condensation of nonylphenol with about 9.5 moles of ethylene oxide per mole of nonylphenol; the condensation of dodecylphenol with about 12 moles of ethylene oxide per mole of phenol. Such materials as IGEPAL C0-630 (listed by GAF) and Triton X-45, X-114, X-100 and X-102 (all listed by Rohm &amp; Haas). Printed by Shubei Biyang Bizhunbeigong Consumer Cooperatives 2. Condensation products of aliphatic enzymes and about 1 to about 25 moles of ethylene oxide. The alkyl chain of the aliphatic yeast may be linear or have side chains, one or two, and generally contains about 8 to about 22 carbon atoms. Examples of such ethoxygenases include the condensation product of tetradecane fermentation and (about 10 moles per mole) ethylene oxide condensation, and about 9 moles of ethylene oxide and coconut yeast (a mixture of lipases, The alkyl bond system is variable and the degree of fear is from 10 to 14 carbon atoms). Commercially available non-ionic surfactants of this type are used in the paper as standard (CNS) T4 specifications (210x297 mm) 81 moot) Zhang (II) 200550 Λ 6η 6 Ministry of Economic Affairs Beigong Consumer Cooperation Du Yin 31 5. Examples of inventions (34) include TERGITOL 15-S-9 (listed by United Carbonization Corporation) 'NE0D0L 45-9, NE0D0L 23-6.5, NE0D0L 45-7' and NE0D0L 45- 4 (listed by Shell Chemical Company) and KYR0 Ε0Β (listed by Pr Octer &amp; Ga η b 丨 e). 3. The condensation product formed by ethylene oxide and hydrophobic alkali to condense propylene oxide and malonylase. Examples of compounds of this type include certain specific commercially available PLURONIC surfactants (listed by Wyandotte Chemical Company). 4. The condensation product of ring gas ethane and (product from the reaction of oxipropane and ethylenediamine). Examples of such non-ionic Shito surfactant types include certain specific commercially available TETRONIC compounds (listed by Wyandotte Chemical Company). 5. The semi-polar non-difficult Shito detergent surfactant contains water-soluble amine oxides and contains 1 alkyl portion with about 10 to 18 carbon atoms and 2 portions selected from 1 to about 3 carbons Atom alkyl and hydroxyalkyl groups are sisters; water-soluble phosphorous oxide contains 1 alkyl part (with about 10 to 18 carbon atoms) such as 2 parts and is selected to contain about 1 to 3 Carbon atoms are composed of alkyl and hydroxyalkyl groups; and the water-soluble sulfoxides contain 1 alkyl part (having about 10 to 18 carbon atoms) and 1 part selected from having about 1 The sisters of alkyl and hydroxyalkyl groups up to 3 carbon atoms are group sisters. Preferred amine oxide detergent surfactants are C10 to C18 alkyl dimethylamine oxides and C8 to C12 alkoxyethyl dihydroxyethylamine oxides. 6. Alkyl polybranches (January 19, 1983 by Ramon A. Llenado _ 3 6-(please read back to the law of the intention # Λδ to write this page) Binding · Threading · ft scale of this paper China BB Standard (CNS) T4 specification (210X297 male 81. 4. 10,000¾ (I!) A 6 Π6 20055055, invention description (35) European Patent Application No. 70, 074 disclosed in (35) The system has a hydrophobic group and contains about 6 to about 30 carbon atoms (K is about 10 to about 16 carbon atoms is preferred) and a poly-, such as polyglucoside, is a philosophyl group and contains about 1.5 to about 10 (M is preferably about 1.5 to about 3, preferably about 1.6 to about 2.6) sugar units. 7. Fatty acid amidoamine detergent surfactant (see U.S. Patent No. 4,711,730, 17th line 35, It is used to illustrate such surfactants.) 8. Fatty acid polyhydroxyamide surfactant; see US Patent No. 2,965,576 issued on December 20, 1960; that is, Great Britain Association Patent No. 809,060. For this document Invented the preferred non-ionic Shitou detergent surfactants used in the cleaning of adult products are ethoxylated enzymes and alkylphenols. In detail, C12 to (: 1Λ yeast and Condensation products of about 3 to about 7 moles of ethylene oxide per mole of yeast, for example, condensation of C12 to C13 yeast with (about 6.5 moles of moles of ethylene oxide). N-alkylglucosamine-glycosamine type Surfactants [as described in U.S. Patent 2,965,576 and U.K. Patent 809,060 (ER Wilson)] constitute other types of preferred non-ionic surfactants used herein. The cleaning products of the present invention may also include 0 Up to about 12% by weight (M0 to about 10% by weight is preferred) synthetic anionic Shitou detergent surfactants. These synthetic anionic Shitou detergent surfactants include water-soluble salts of organic sulfuric acid reaction products (typically «(metal, Ammonium and hydroxyalkyl ammonium salts) and the alkyl groups in their molecular structures contain sulfonic acids containing about 10 to about 20 carbon atoms and sulfate groups. (The name "alkyl" contained in this group refers to amides) The alkyl part of the base h -37-

The size of this paper is in accordance with the specifications of China S Home Standard (CNS) T4 (2 丨 0x297 Gong D (please read it first and back ¾. 意 事 ^ # sulfu to write this page) Printed by the Bureau β Gongxiao Cooperative 81. 4. 10, 〇U (] Zhang (H) A 6 Π 6 V. Description of the invention (36) Examples of such synthetic anionic surfactants are sodium alkyl sulfate and potassium sulfate , In detail, these are derived from high-grade leaven (containing (: 8 to (: 18 carbon atoms) sulfated and sodium alkylbenzenesulfonate and potassium, wherein the alkyl group contains about 9 to about 15 carbon atoms, It has a straight bond or a lateral configuration, such as those described in U.S. Patent Nos. 2,220,099 and 2,477,383. Among these surfactants, straight bond alkane benzene sulfonates are included, in which The average number of carbon atoms in the group is abbreviated to about 11 to 13 'to C13 LAS. Cooperated with the Central Bureau of Cement of the Ministry of Industry, cx, industrial and consumer cooperation Du Yin &quot; (please read the notes beforehand-Er Leng's writing Page) Synthetic anionic Shito surfactant also contains: (: 10 to (: 22 alkyl polyethoxylated sulfate; alkyl glyceryl ether sulfonate; α-sulfonated fatty acid ester water-soluble salt The fatty acid group contains about 6 to 20 carbon atoms and the ester group contains about 1 to 10 carbon atoms; the water-soluble salts of 2-acetoxy-alkane-sulfonic acid are in the acyl group Rings containing about 2 to 9 carbon atoms and about 9 to about 23 carbon atoms in the alkane portion; alkyl ether sulfates containing about 10 to 20 carbon atoms in the alkyl group and about 1 to 30 mole rings Oxides; water-soluble salts of olefin sulfonates containing about 12 to 24 carbon atoms; / 3-alkoxy alkane sulfonates containing about 1 to 3 carbon atoms in the alkyl group and containing in the alkane portion About 8 to 20 carbon atoms. The cleaning product of the present invention also includes amphoteric, zwitterionic and cationic detergent surfactants and Ejin soap. The amphoteric surfactants can be widely described as secondary Or aliphatic derivatives of tertiary amines, or aliphatic derivatives of heterocyclic secondary or tertiary amines, where the aliphatic group may be linear or with a side chain and one of the aliphatic substitutions -38 * This paper The scale is used in the CNB family standard (CNS) Τ4 specification (210X297 male dragon) 81.4.10, 〇ϋΟ Zhang (H) 200550 Λ 6 Π 6 V. Invention (37) The Indian Consumer ’s Cooperative Society of the Bureau of Standards and Economics of the Ministry of Economic Affairs of India contains about 8 to 18 carbon atoms and at least one contains an anionic water-soluble group, such as carboxyl, sulfonate, and sulfate. See 1975 US Patent No. 3,929,678 issued to Laughli η on December 30, lines 18 to 35 (herein and incorporated herein by reference) for examples of amphoteric surfactants. Zwitterionic surfaces can be widely used The description of the active agent is the derivatives of the second amines and tertiary amines, the derivatives of the second and third amines of the heterocyclic system, or the derivatives of the quaternary ammonium, quaternary sulfonate or tertiary sulfonate. See U.S. Patent No. 3,929,678 issued December 30, 1975 to Laughlin, No. 19, line 38 to 22, line 48 (herein and incorporated herein by reference) for examples of zwitterionic surfactants. Convenient cationic surfactants are disclosed in U.S. Patent No. 4,259,217 issued to Mu "phy on March 31, 1981, and are hereby incorporated by reference. Useful alkali soaps include sodium, potassium, Ammonium and hydroxyalkyl ammonium salts and this contains about 8 to about 24 carbon atoms, preferably about 10 to about 20 carbon atoms. The detergent composition of the present invention may optionally include inorganic or organic detergent builder Agents help to control the hardness of minerals. This type of builder typically includes up to about 60% by weight of the finished product; the liquid builder formula generally includes about 1% to about 25% by weight of detergent builder , Μ about 3% by weight to about 20% by weight is the best, while the rib detergent granules generally include about 5% by weight to about 50% by weight detergent builder, preferably from about 10% by weight to about 30% by weight. A wide range of cleaning agents and builders are known in the document, so there is no need to -39- (please read the back and the intention of the first time # fill in this page) This paper is not used in the standard aa family standard (CNS ) Specification (2 丨 0X297 公 #) 81. 4. IO.UUOS. (Η) 200550 Λ 6 η 6 V. Description of invention (38) The Ministry of Economic Affairs, Ministry of Economic Affairs and Economics, Duin 5 5 such substances are listed in full. For example, the deployment staff can refer to Meihuali No. 4,71 1,730 (from column 19) for typical listing of such substances. However, for the convenience of the deployment staff, and do not intend to impose restrictions on M, certain illustrative and suitable detergent rib lotions are listed below. Suitable detergent rib lotions include crystalline aluminosilicate Ion exchange materials typically refer to "zeolite A", "zeolite P" and 'zeolite X ". In detail, zeolite has a particle size of about 0.1 to about 10 microns. The most suitable zeolite for builder applications has a calcium dimensional exchange rate of at least about 4 particles / gallon / minute / gram / gallon. Amorphous aluminosilicates (in particular, these have a magnesium ion exchange rate of at least about 1 grain / gallon / minute shovel / gram / gallon) are also useful. The preparation method of aluminosilicate ion exchangers is described in US Patent No. 3,985,669. Particularly preferred is a hydrated aluminosilicate having the following formula: Nai2 [(Al〇2) i2 (Si〇2) i2]. XH2〇 where X is about 20 to about 30, in detail, 28. Other detergent builders include water-soluble phosphates, polyphosphates, phosphites, carbonates, silicates, acetates, polyhydroxysulfonates and more. Carboxylate. Various types of polycarboxylate builders are disclosed in U.S. Patent Nos. 3,308,067; 3,732,322; 4,144,226; and 4,246,495. Oxydisuccinate (also known as "oxo disuccinates"), tartaric acid is thin, mono- and di-succinates, and citrates are better for this purpose Special case of polycarboxylate rib lotion. The cleaning detergents here also contain clay dirt ig removal and / -40- (please read the first item and note the item ## to write this page) Binding-binding-margin · The scale of this spider is based on 8 Chinese standards (CNS) T4 regulations (210x297 g; ¢) 81. 4. lO.OUOfi. (H) 200550 Λ 6 Β6 V. Description of invention (39 ) Or anti-redeposition agent, and the general range of use of such substances is about 0.1% to about 10% by weight of the adult products. Such substances include various ethoxylated amines, etc., refer to the above-mentioned US Patent No. 4,711,730 Other types of preferred clay soil removal / anti-re-settling agents are cationic compounds and are disclosed in European Patent Application # 1 1 1,965 published on June 27, 1984. Such substances are disclosed in the aforementioned US patents There are also quite detailed disclosures in No. 4,711,730. Other arbitrary ingredients [may be contained in the detergent and cleaning agent composition of the present invention and built by K and their conventional skills Concentration for use (ie about 0% to about 20% by weight)] contains solvents, whitening agents, bleach activators, corrosion inhibitors, dyes, fillers, optical brighteners, fungicides, regulators, enzymes , Mayan stabilizers, perfumes, etc. The intentional ingredients contained in the complete cleansing agent are a separate substance and are used for the purpose of rooting the clerk. Formed to embody the sra's of the present invention The granular cleansing agent is a finished product and K mixes sra's dryly (to be formed by the conventional art) into the adult product. The so-called conventional art is to mix other individual ingredients in water, then atomize and spray dry. The mixture, or M pan or roll choke, granulates the ingredients, or in a fluid bed method.

The Ministry of Economic Affairs, Central Bureau of Economic Cooperation and Industry 3 cooperation of Du Yin M liquid formula can be formed in single-phase (preferred) form or in multi-phase or “dispersant”. Dispersion powders traditionally use viscosity modifiers to produce dispersants with plastic shear characteristics such as K to maintain stability and prevent phase separation or solid deposition. Although the cleaning detergent product of the present invention is operable in a wide range of washing out &gt; if prepared in a liquid, they will provide a near-neutral cleaning cH, that is, a cut-off system in 20¾ water 6.0 to about 8.5 and its concentration -41-8]. 4. 10,0U0 sheets ⑻ (please read it back and forth: please pay attention to this matter and fill in this page) This paper size is based on the Chinese NH family sample (CNS) T4 specification (2) 0 × 297 g *) Λ 6 Π 6 200550 V. Description of the invention (40) Degree is about 0.1% to about 2% by weight. This formulation also needs to be close to neutral cHM to ensure long-term stability for sra's. In such formulations, the product pH is preferably from about 6.5 to about 8.5 and more preferably from about 7.0 to about 8.0. The following illustrates the particularity of the use of s "a | s in the detergent composition of the present invention, but it is not intended to limit its scope.

Example XT T The composition of a liquid detergent cleaner is as follows: Ingredients% SRA * 1.0 C12 Alkylethoxy (1) Sodium Sulfate 9.5 C12 to C13 Fermented Polyethoxylate 10.2 C12 to C14N-Methyl Glucose amine 7.0 Ethanol 5.5 Ethylenediaminetetraacetic acid sodium 0.3 small amount and h2〇 balance (please read the back of the note and the "Item" page)

* SRA is based on the above example I. Printed by the Ministry of Economic Affairs, Central Bureau of Precincts, Consumer Cooperatives ^ -42-81. 4. 10,000¾ (II) This paper scale is used in the China Standard (CHS) Grade 4 (210x297 male dragon) ) 200550 Printed by the Ministry of Economics and Trade, Beta-Consumer Cooperative Society 51 V. Description of the invention (41) Example X Τ Τ Τ A granular detergent is as follows: SRA c12 to c13 yeast polyethoxide MgS04 hydration Zeolite 4A (1 to 10 microns) N a 2 C 0 3 NaHCOs Maxatase MP (a protease) brightener water and a small amount of substances * SRA is coated with polyethylene glycol with an average molecular weight of 8,000 according to Example II above in. The elder sister of Example XI 11 was prepared and M used a standard mixing method to incorporate sra. As seen from the foregoing, the sra's of the present invention can be used for washing and cleaning familiar to the fabricator of the elder sister In the form of the sister into things. In another horizontal mode, the sra's can be added directly to, for example, water-based washing and wetting baths related to sickle. In still other horizontal styles, the sra ’s can be releasably fixed to the laminate substrate, etc., designed for use in automatic clothes dryers. The well-known type in business practice can be added to -43-Pu% 3. 5 20. 0 1.0 26. 0 18.3 15.0 1. 5 1. 2 to 100 (please read back and note the benefit of the item (Gongqiao this page) Pack. Order-many. This JMfc standard is easy to use Chinese H home standard specifications (210x297 g; *) 81. 4.! (), 〇 () 〇 Zhang (||) 2〇〇55〇Λ 6η 6 V. Description of the invention (42) Various types of incandescent softeners and / or antistatic agents printed by the cooperative of the Central Ministry of Economic Affairs of the Ministry of Economic Affairs ^ Cooperative Society are releasably fixed on the substrate of such laminates. During use, the wet suspect and the laminate substrate are rolled, thereby causing sra's and (if present) any fabric softener / antistatic agent to be transported from the laminate substrate to the surface of the suspect. It is also expected here These and other modes of applying sra's to fabrics. Although the previous examples illustrate preferred sra's with capping, the following illustrates any sra's without capping and this is also covered by the present invention, as disclosed above, it is known that it is not capped sra's can be used in washing formulas. Example XTV synthesis is made from dimethyl terephthalate, poly f7, dioxin U; amount 14 5 Q), glyphosate, and propylene Alcohol (with E / P = 2.?) ^ "The following materials are added without the true polymer on a day to night, and the following materials are added to the magnetic stirrer, modified Claiseri joint, condenser (device for distillation), thermometer , And a temperature controller (THERM-0-WATCH &gt; I2R) in a 250 ml size 3-neck squat bottom flask: polyethylene glycol with a molecular weight of 1,450 (by Union Carbide, 93.3 g, 0.064 mol), right Dimethyl phthalate (25.0 g, 0.129 mol), ethanediastase (Baker, 16.0 g, 0.258 mol), 1,2-propanediol (Fisher, 19.6 g, 0.258 mol), And hydrated monobutyltin oxide (produced by M &amp; T Chemicals, 0.27 g, accounting for 0.2% of the weight of the reactants). After heating the mixture to 1801C in argon, it was maintained at this temperature overnight while distilling off the decanter vessel. 13C-NMR (DMS〇-de) showed that this reaction stage had been completed and the resonance of the methyl ester was not seen at ~ 52 ppm. Transfer this material to a 500-ml round-bottom flask at -44- (please pay attention to the items before WJift, and then consolidate this page) The standard of this paper is BB home standard (CNS &gt; T 4 Specification (210x297 public *) .81. 4. 10, (03 sheets (If) Λ 6 η 6 200550 V. Description of the invention (43) (please pay attention to the matters needing attention before writing this page)

In the Kugelrohr apparatus (Aldrich) and gradually heating each other for more than 20 minutes under about 1 millimeter of mercury, it was maintained under this condition for 40 minutes. Then, under vacuum, the flask W was quickly cooled to near room temperature (about 30 minutes). The reaction yielded 94.8 grams of orange soft solid. ^ -NMR (DHSO-de) shows that the resonance system used for -C (0) 0 CH z CHz.OC (0)-is at about 63.2? 01 «at the place (diamide) 'for -〇 (〇) (1) The resonance of 1 ^ (^ 2 [^ is at about-59.4 ρρπ (monoester), and at about 69.8 ppm there is a large peak representing the poly (ethylene oxide) unit. The height of the diester peak versus the height of the monoester peak The ratio is about 5.8 °. The satisfactory concentration of the terminal group formed by ethylene glycol monoacetate shows that the product is a low molecular weight polymer. The spectrum from UMLUDMSO-de) is also consistent with the formed low molecular weight polymer. The peaks in the 1.1 to 1.3 ppm range indicate the presence of malonyl monoester at a concentrable concentration. The peak area measured for the methyl ester of oxalase at approximately 4.7 ppm is used for malonase The ratio of the peak area of the methyl ester of the diester at about 1.4 ppm. From this, the molar ratio of the incorporated ethylene glycol / malonate (E / P ratio) is 2.2: 1. The solubility is tested to The substance is weighed in a vial. Add enough pure water M to make a 5% by weight solution, and vigorously stir the vial of the substance to be soluble under these conditions. The Central Bureau of Economy, Ministry of Economic Affairs β 工 消 合Sheyin 31 As can be seen from the foregoing, a wide range of fabric softener and detergent detergent products have been prepared and used for sr, s. In fact, the modern liquid fabric softeners generally provided as high Liquid (H20) shrinking agent (5 times to 6 times), designed to be diluted by consumers in household M water. Basically, the concentration of ingredients according to the previous Example XI is doubled to provide this high concentration agent Therefore, the sister product includes about 10% to about 32% by weight of the sun _ 4 5 _ 81. 4. lO.OUOijt (I!) This ΙΜgun standard used in China BS home sample Bi (CNS) T4 specifications ( 210x297 mm) 200550 A 6η 6 V. Description of the invention (44) Ionite suspect softener (eg DTDMAC), about 4% to about 20% by weight imidazole and suspect softener and about 1% to about 5 Sra's by weight, and all of them are covered in the present invention. Regarding cleaning detergents and cleaning products * excellent cleaning products include about 0.3% to about 3% by weight of sra's, and about 3 Weight% to about 20% by weight fatty acid polyhydroxyacetamide surfactant as a detergent surfactant ( U.S. Patent No. 2,965,576, which is equivalent to the aforementioned Great Britain Association Patent No. 809,060, hereby incorporated herein by reference), the preferred method is a combination of about 5% to about 25% by weight sulfated or sulfonated anionic surfactant such as C12 To C18 alkyl benzene sulfonate, C12 to Cie alkyl ethoxy sulfonate (average E0 3 to 10; preferably), with a known amount (15% to 50%) of conventional builders , Containing such preferred rib lotions such as zeolite A, oxodisuccinate, and mixtures thereof, the remaining portion of this sister product includes conventional cleansing ingredients with known concentrations. (Please read the back-to-back issues 4 and fill in the ΑΓ page first) Binding · Ordering 'Ministry of Economic Affairs, Ministry of Economic Affairs and Industry 3: Printed by the Industrial and Consumer Cooperatives 31-46 CNS) T4 specification (210X297 male *) 81.1 (), 01) 0¾ (||)

Claims (1)

1. A soil release agent, including the following oligomers into the reaction mixture. The Central Standardization Bureau of the Ministry of Economic Affairs of the Ministry of Economic Affairs is the vinegar product: U) An optional one. The source of the alkoxy-terminated terminal (M methoxy terminal is preferred) polyethoxy units, or optionally a mixture of terminating polyethoxy units and young propoxy units; (b)-a source of p-xylylene units, or a mixture of p-benzyl groups and a small amount of m-benzyl units; (c) a poly (ethylene oxide) oxygen The base unit-(0CH2CH2) y-0-the source of the source; (d)-the source of the following oxyisopropenyloxy units containing CHa I-OCHCHzO-; and (e)-the oxyethyleneoxy unit- 〇CH2CH2〇- the source; the dirt release agent is further characterized as having an oxyethoxylated ethoxy unit: oxidized isopropoxylated unit molar ratio of at least 0.5: 1. 2. The scale release agent according to item 1 of the application scope includes the esterification reaction product of the following reaction mixture: (a) CH3 (0CH2CH2) 1β0Η; (b) dimethyl terephthalate;-(c) Polyesterase 1 500; (d) 1, 2-malonyl fermentation; and f 4 (210X297 ^ 4?) (Please read the precautions on the back before filling in this page) Order · .Green · -1- 200550 A7 B7 C7 D7 VI. Patent application 3. 3. (e) Ethylene glycol; wherein the molar ratio of oxo ethoxy units: oxo isopropoxy units is at least 0.5: 1. The scale release agent according to item 1 of the patent application has the following formula: 0 0 h〇- (CH2CH20): R2) -C-0 (CH ^ HjOjx-R1 〇 ^ 0 u / = \ II 〇0 — / VC0 (CH2CH20) y ................................... is ... ......... 5t (please read the precautions on the back before filling in this page) where R1 is lower (for example (^ to (: 4) alkyl, especially methyl; x is 6 to 43 Integer; y is an integer from 12 to 77; m is an integer from 1.5 to 25; 11 is an integer from 0.5 to 15; 111 + 11 + 1/11 + 1 is an integer from 1.2 to 4.5; and R2 is the value of Η and CH3 Mixture M provides the molar ratio of oxo extended ethoxy: oxo iso extended propoxy to at least 0.5: 1. 4. The scale release agent according to item 1 of the patent application scope, in which oxo extended ethyl Oxygen: oxoisopropenyloxylate ratio is at least 0.75: 1. 5. According to the scope of patent application of the first 1 scale release agent, in which oxo ethoxy: oxyisopropenoxy The base molar ratio is at least 1.2 5: 1. Printed by the Central Bureau of Standards of the Ministry of Economic Affairs ¾ 6. A method to provide dirt release ^ from the finished product on miscellaneous goods At least 2ρριη such as the first one of the scope of the patent application of the dirty armor 4 (210X297 public) 200550 7 7 7 7 AB c D Six, apply for a patent model The Central Standards Bureau of the Ministry of Economic Affairs prints the aqueous medium of the crack release agent. 1 'According to the method of item 6 of the scope of the patent application, including the fabric and the water bath (including at least 2ppm dirt release agent and at least 10ppm cationic system Fabric softener) during contact for at least 1 minute, and then wet the miscellaneous product with water drops. 8, according to the method of item 7 of the patent application scope, wherein the oxo-extended ethoxy group in the soil release agent: oxo-isoextended The molar ratio of the propoxy unit is at least 0,75: 1. 9 * According to the method of item 8 of the scope of the patent application, in the dirt release agent, the oxo ethoxy group: oxo isopropenyl unit The molar ratio is at least 1.25 * 1 〇10.—a cleaning composition in the form of detergents, softeners, wetting ribs, etc. This includes at least 0.1% of dirt release as claimed in item 1 of the patent scope -11. The detergent composition according to item 10 of the patent application scope includes 0.3% to 3% by weight of soil release agent and 3% to 25% by weight of fabric softener ingredients. 12. According to the patent application The eleventh item of the scope of washing, including (a) 10% to 32% by weight of cationic fabric softener; (b) 4% to 20% by weight of imidazole bed hoe softener; and (c) 1% to 5% by weight of the soil release agent 13. A kind of detergent composition, including conventional detergent surfactants, optional builders, optional carriers, and 0.1% to 5% by weight as claimed in the patent application Item 1 dirt release agent. (Please read the precautions on the back before filling in this page) • Install '• Call · • Line. * Ρ4 (210Χ297 Public Broadcasting) __- 3-AB c D 六 、 Apply for Patent Fan® 14.According to the scope of the patent application The elder sisters of item 13 include 0.3% to 3% by weight of soil release agent and 3% to 20% by weight of fatty acid polyhydroxyamide surfactant. (Please read the precautions on the back first, and then spend the night) The Central Bureau of Economic Development of the Ministry of Economic Affairs Printing and Burning A 4 (210X297 Public Broadcasting) 4