CN100519715C - High molecular pollutant cleaning agent and preparation method thereof - Google Patents
High molecular pollutant cleaning agent and preparation method thereof Download PDFInfo
- Publication number
- CN100519715C CN100519715C CNB2006100100289A CN200610010028A CN100519715C CN 100519715 C CN100519715 C CN 100519715C CN B2006100100289 A CNB2006100100289 A CN B2006100100289A CN 200610010028 A CN200610010028 A CN 200610010028A CN 100519715 C CN100519715 C CN 100519715C
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- Prior art keywords
- parts
- cleaning agent
- high molecular
- pollutant
- distilled water
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- 239000012459 cleaning agent Substances 0.000 title claims abstract description 16
- 239000003344 environmental pollutant Substances 0.000 title claims abstract description 14
- 231100000719 pollutant Toxicity 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title abstract description 10
- 239000000654 additive Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000012153 distilled water Substances 0.000 claims abstract description 10
- 235000003891 ferrous sulphate Nutrition 0.000 claims abstract description 10
- 239000011790 ferrous sulphate Substances 0.000 claims abstract description 10
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims abstract description 10
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 10
- 230000000996 additive effect Effects 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims abstract description 3
- 239000003921 oil Substances 0.000 claims description 16
- YLMGFJXSLBMXHK-UHFFFAOYSA-M potassium perchlorate Chemical class [K+].[O-]Cl(=O)(=O)=O YLMGFJXSLBMXHK-UHFFFAOYSA-M 0.000 claims description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 150000008431 aliphatic amides Chemical class 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 239000004519 grease Substances 0.000 claims description 2
- 229920001515 polyalkylene glycol Polymers 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 6
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 3
- 238000004519 manufacturing process Methods 0.000 abstract description 10
- 229920000642 polymer Polymers 0.000 abstract description 9
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 abstract description 8
- 230000006378 damage Effects 0.000 abstract description 5
- 238000009825 accumulation Methods 0.000 abstract description 2
- 230000007774 longterm Effects 0.000 abstract description 2
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 abstract 1
- 230000001050 lubricating effect Effects 0.000 abstract 1
- 229910001487 potassium perchlorate Inorganic materials 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 6
- 230000009471 action Effects 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 230000004913 activation Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000005553 drilling Methods 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 210000004400 mucous membrane Anatomy 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003519 biomedical and dental material Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- Detergent Compositions (AREA)
Abstract
The invention relates to a polymer pollutant cleaning agent and a preparation method thereof, belonging to the field of cleaning agents and preparation methods thereof, and the polymer pollutant cleaning agent is prepared by mixing and stirring 5-20 parts of potassium perchlorate, 1-5 parts of concentrated sulfuric acid, 4-15 parts of a lubricating additive, 0-255-15 parts of peregal, 6-20 parts of ferrous sulfate and 40-70 parts of distilled water at normal temperature. The cleaning agent has simple compatibility and low cost, does not harm operators and equipment in the production and use processes, does not cause pollution and harm to the operators and the surrounding environment due to long-term accumulation of residues, and is an environment-friendly product.
Description
Technical field
The invention belongs to clean-out system and preparation method, particularly a kind of high molecular cleaning agent for pollutant and preparation method.
Background technology
High molecular polymer is widely used in aspects such as thickening, flocculation, stable colloid, drag reduction, bonding, film forming, scale inhibition, gel and biomedical material.Particularly in industrial sectors such as water treatment, papermaking, mining, coal washing, metallurgy and oil production, its consumption increases day by day.In the oil production process, be used as the precipitation agent of drilling mud, the scavenging agent of oily water treatment and the oil-displacing agent of tertiary oil recovery etc.Facts have proved injection of polymer in suitable oil field of adopting polymer flooding, can produce at least and be equivalent to the crude oil of polymkeric substance injection rate more than 150 times.Along with the widespread use of polymkeric substance in the drilling of oil field, its industrial scale is in continuous expansion, it is in production and transport, storage and use, its chance water that is scattered can form the slick film of thickness, its film can cause operator to slide and get injured by a fall safety residual, that transportation stores vehicle damage and storehouse staff, particularly in the oil recovery production process, because the injection of high molecular polymer, also can make the serious fouling of oil production equipment, cause device fabrication to lose efficacy in advance, in the work-ing life of shortening equipment, cause very big financial loss to enterprise.
Polymkeric substance is hard glassy solids at normal temperatures, during 23 ℃ of density is 1.302g/cm3, and second-order transition temperature is 153 ℃, and softening temperature is 210 ℃, soluble in water under its normal temperature, water-soluble back forms homogeneous transparent liquid, and when strength of solution was higher than 10%, polymkeric substance was because of intermolecular hydrogen atom bonding action, the structure that similar gels can occur, thickness and smooth causes serious harm, and environment is had very big pollution for production operation personnel, carrier vehicle, storage management personal security; Its extremely strong sticking power of polymkeric substance in addition then forms the hard mucous membrane of polymer on surfaces such as latent oily equipment, subsurface tools, has directly caused the overhaul of the equipments number of times to increase, shorten work-ing life, serious waste manpower and materials.
Summary of the invention
The present invention is intended to overcome the deficiencies in the prior art, has developed a kind of high molecular cleaning agent for pollutant.
High molecular cleaning agent for pollutant of the present invention is made up of for 40～70 parts: 5～20 parts of potassium perchlorates, 1～5 part of 98% vitriol oil, 4～15 parts of slip additives, peregal 0-255～15 part, 6～20 parts in ferrous sulfate and distilled water by weight;
Its preparation method is: drop into 1～5 part of 40～70 parts of distilled water, 5～20 parts of potassium perchlorates and the vitriol oil under the normal temperature by weight in stirring tank, after stirring, adding 4～15 parts of slip additives, peregal 0-255～15 part and ferrous sulfate again stirs for 6～20 parts, be in harmonious proportion evenly, promptly make finished product.
Preferable component of the present invention is to select for use 8～15 parts of potassium perchlorates, 2～4 parts of the vitriol oils, 6～12 parts of slip additives, 8～12 parts of peregal 0-25,10～15 parts in ferrous sulfate, distilled water to be prepared from as stated above for 50～60 parts.
Described peregal 0-25 sends out the chemical plant forever by the Zhang Dian of Zibo City and produces, and outward appearance is a white, and pH value is 5～7, and content is more than 99%; Slip additive mainly be with polyalkylene glycol be the main and auxiliary mixture of forming with aliphatic amide or ring grease amine, phosphoric acid fat (be prior art, number of patent application: 86100480).
Crux of the present invention is to use the surface activation of slip additive, and the polymerization of high molecular polymer mainly relies on the bonding action of hydrogen, and slip additive has very strong activation, and it can make hydrogen bond rupture at short notice, reduces viscosity simultaneously.
High molecular cleaning agent for pollutant of the present invention has degradation polymer preferably, destroys its hydrogen atom bonding action, make its formed mucous membrane by thickness, smoothly become dissolving and be beneficial to cleaning, and the speed of degraded wants fast, cleaning back noresidue.Its compatibility is simple, with low cost, and effect is remarkable, and production technique is simple and easy to operate.
The present invention does not have injury to operator and equipment in the production use, its residue long-term accumulation can not pollute and endangers operator and surrounding enviroment, is the environmental type product.
Embodiment
Embodiment 1
High molecular cleaning agent for pollutant of the present invention, form by following component by weight:
40～70 parts of distilled water, 5～20 parts of potassium perchlorates, 1～5 part of the vitriol oil, 4～15 parts of slip additives, 5～15 parts of peregal 0-25,6～20 parts in ferrous sulfate;
Its preparation method is: drop into 1～5 part of 40～70 parts of distilled water, 5～20 parts of potassium perchlorates and the vitriol oil under the normal temperature by weight in stirring tank, after stirring, adding 4～15 parts of slip additives, 5～15 parts of peregal 0-25 and ferrous sulfate again stirs for 6～20 parts, be in harmonious proportion evenly, promptly make finished product.
Embodiment 2
High molecular cleaning agent for pollutant of the present invention, form by following component by weight:
50～60 parts of distilled water, 8～15 parts of potassium perchlorates, 2～4 parts of the vitriol oils, 6～12 parts of slip additives, 8～12 parts of peregal 0-25,10～15 parts of compositions of ferrous sulfate.Preparation method by embodiment 1 makes finished product.
The concrete umber (seeing the following form) of its component of high molecular cleaning agent for pollutant of the present invention makes finished product with following component by the preparation method of embodiment 1 again.
Claims (3)
1, high molecular cleaning agent for pollutant, form by following component by weight:
5～20 parts of potassium perchlorates
1～5 part of the vitriol oil
4～15 parts of slip additives
5～15 parts in aliphatic alcohol polyethenoxy (0-25) ether
6～20 parts in ferrous sulfate
40～70 parts of distilled water
Described slip additive mainly is to be the main and auxiliary mixture of forming with aliphatic amide or ring grease amine, phosphoric acid fat with polyalkylene glycol.
2, high molecular cleaning agent for pollutant as claimed in claim 1 is characterized in that being made up of for 50～60 parts 815 parts of potassium perchlorates, 2～4 parts of the vitriol oils, 6～12 parts of slip additives, 8～12 parts in aliphatic alcohol polyethenoxy (0-25) ether, 10～15 parts in ferrous sulfate and distilled water.
3, the method for preparing the described high molecular cleaning agent for pollutant of claim 1, feature is to drop into 1～5 part of 40～70 parts of distilled water, 5～20 parts of potassium perchlorates and the vitriol oil under the normal temperature by weight in stirring tank, after stirring, adding 4～15 parts of slip additives, 5～15 parts in aliphatic alcohol polyethenoxy (0-25) ether and ferrous sulfate again stirs for 6～20 parts, be in harmonious proportion evenly, promptly make finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100100289A CN100519715C (en) | 2006-05-11 | 2006-05-11 | High molecular pollutant cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100100289A CN100519715C (en) | 2006-05-11 | 2006-05-11 | High molecular pollutant cleaning agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1861772A CN1861772A (en) | 2006-11-15 |
| CN100519715C true CN100519715C (en) | 2009-07-29 |
Family
ID=37389304
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100100289A Expired - Fee Related CN100519715C (en) | 2006-05-11 | 2006-05-11 | High molecular pollutant cleaning agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100519715C (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1012772B (en) * | 1987-03-13 | 1991-06-05 | 东芝有限公司 | X-ray display tube |
| CN1066680A (en) * | 1991-03-28 | 1992-12-02 | 普罗格特-甘布尔公司 | Nonionic soil release agents |
| CN1137287A (en) * | 1993-12-14 | 1996-12-04 | 普罗格特-甘布尔公司 | Liquid laundry detergents containing polyamino acid and polyalkylene glycol |
-
2006
- 2006-05-11 CN CNB2006100100289A patent/CN100519715C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1012772B (en) * | 1987-03-13 | 1991-06-05 | 东芝有限公司 | X-ray display tube |
| CN1066680A (en) * | 1991-03-28 | 1992-12-02 | 普罗格特-甘布尔公司 | Nonionic soil release agents |
| CN1137287A (en) * | 1993-12-14 | 1996-12-04 | 普罗格特-甘布尔公司 | Liquid laundry detergents containing polyamino acid and polyalkylene glycol |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1861772A (en) | 2006-11-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Daqing Jingcheng Chemical Co., Ltd. Assignor: Li Bolin Contract record no.: 2012230000532 Denomination of invention: High molecular cleaning agent for pollutant and preparation process thereof Granted publication date: 20090729 License type: Exclusive License Open date: 20061115 Record date: 20120531 |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090729 Termination date: 20150511 |
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| EXPY | Termination of patent right or utility model |