TW200537056A - Method and apparatus for producing ceramics - Google Patents

Abstract

The present invention relates to a method and an apparatus for producing ceramics by utilizing a pyrolyzer of organic materials. A method of the present invention includes a step for pyrolyzing organic materials having a small quantity of inorganic components and a step for treating gases generated in said pyrolzing step, wherein said pyrolyzing step includes a step for decomposing said organic materials into gas components and carbides including said inorganic components, a step for keeping a reaction chamber in reductive condition by providing a large amount of electrons to said decomposed carbides and for gasifying said carbides to separate said inorganic materials from said carbides, a steps for reacting said separated inorganic components with oxygen components which have been sent along with said electrons to generate oxides.

Description

200537056 Description of the invention: [Technical field to which the invention belongs] Method and device for forming ceramics, in particular regenerating ceramics that produce ceramics in a step The present invention relates to a method and device for producing ceramics by thermal decomposition of organic wastes . [Prior art] Generally speaking, ceramics must be resistant to manufacture *

Monthly distribution as raw materials of inorganic substances and I

Ingredients are made by sintering. Therefore, it is known that the ceramic manufacturing method must require a baking step, which requires a large baking step.

Yae Energy. In addition, at present, ceramics manufacturers must purchase inorganic inorganic inertia to make ceramics using M A Α Kouhara. It also produces high-quality ceramic products with excellent malodor, absorbing and decomposing, decomposing effects, and sterilization. After roasting raw materials in a reducing environment, you must ... the step of firing again in an oxygen environment requires a lot of effort. Moreover, it is necessary to have an oxidation furnace and a reduction furnace device, which also requires a lot of cost in equipment investment.

On the other hand, the so-called industrial waste treatment methods such as rubbish are generally treated by burning in an incinerator. Although the combustion treatment can reduce the volume reduction rate of the waste by about zero, a large amount of external energy is required during combustion, and there is a problem of environmental damage such as dioxin and carbon dioxide during combustion. In order to solve this problem, industrial waste treatment has recently started using carbonization furnaces and thermal decomposition reactions. The municipal waste treatment by dioxin, carbon dioxide gas, etc. can be suppressed by thermally decomposing municipal waste in a reducing environment and completely burning the waste. Device, and furthermore 3 200537056 Many resources are being developed using the heat, water and other resources generated in this thermal decomposition step. [Patent Document] Japanese Patent Application Laid-Open No. 1 1-230522 [Summary of the Invention] As mentioned above, the conventional manufacturing method requires a large amount of energy in the firing step using electricity or firepower. In addition, the burning step is because Dioxin or carbon dioxide gas has caused the problem of gradual warming of the earth. In addition, the purchase of inorganic materials used as raw materials for ceramics also requires costs, and there are also problems in increasing the cost of manufacturing ceramics. It is an object of the present invention to provide a method and an apparatus for producing ceramics, which are used in organic wastes and are contained in wastes such as municipal waste. 2 Wood and ethene (using gas ethene, polyethene, polystyrene, etc.) as raw materials and residues, and the use of thermal decomposition of organic waste to generate ceramics. According to the present invention, since industrial wastes such as those described above can be used as raw materials for the production of ceramics, while the cost of raw materials can be reduced, the industry can make use of the heat of ordinary processing steps because of the AL · · r ^. Decomposition processing, Jin, # almost without the use of external energy can also be produced pottery, combined with the reduction of raw material costs can greatly reduce the manufacturing cost of ceramics. " Equipped with electric heaters or heat exchange tubes, there is no need to purge, just add J5, Shi 70 ·, ', organic waste in the tank to thermally decompose. The burner's method of 200537056 will be regarded as a procedure in which the burner must obtain a permit before it can be installed. 'However, if the method of forcibly increasing the temperature in the device by a method other than combustion is not required, there is no restriction on the location of the installation.

According to the invention, in order to obtain good quality ceramics, one of the necessary reduction and oxidation steps can be performed: less, a simpler device can be used to obtain good quality ceramics. The ceramics produced by the method of the present invention The reason is that the adsorption and decomposition of malodorous substances or the bactericidal effect on bacteria such as coliform, salmonella, and MRSA are very good. In addition, wood acetic acid, a by-product of the pottery production process, can also be effectively used in various fields such as insect repellents and soil improvement materials.

As described above, in order to suppress the occurrence of dioxin, carbon dioxide, and the like, thermal decomposition treatment of industrial waste has been widely used recently, but conventional thermal decomposition treatment is only performed until the carbonization of the waste is performed because the thermal decomposition is completed in the furnace. A large amount of organic matter remains, and the volume reduction rate of the waste is only reduced to about 1/10 to 1/20. Further, the conventional thermal decomposition device has a problem that dioxin and carbon dioxide are generated in the exhaust gas treatment because the gas generated by thermal decomposition is burned in the combustion chamber. In the present invention, since there is no combustion step at all from the start of the thermal decomposition treatment to the exhaust treatment, it can provide extraordinary safety. In order to solve the aforementioned problems, the ceramic production method of the present invention is characterized by including a step of thermally decomposing a raw material organic substance containing a trace amount of an inorganic component, and a gas treatment step for treating a gas generated in the thermal decomposition step, and the thermal decomposition step It is provided with a decomposition step of decomposing the raw material organic matter into 5 200537056 containing the inorganic component and the gas component in the reaction tank; and sending a large amount of electrons into the reaction tank to maintain a reducing environment in the reaction tank. At the same time, the step of gasifying the carbide and separating the inorganic component from the carbide; and the step of reacting the separated inorganic component with an oxygen component to form an oxide. The ceramic production method of the present invention sends a large amount of electrons to the carbides generated in the thermal decomposition step of the organic matter, and the carbides are further decomposed and gasified to separate the inorganic components from the carbides, and the oxygen contained in the organic resources Combined with the inorganic components separated from carbides to form inorganic oxides, that is, ceramics are formed. Because the organic matter is thermally decomposed, the production of ceramics does not require a conventional firing step, which can significantly reduce manufacturing costs. In addition, the ceramics produced in the present invention are produced through a reduction step and an oxidation step, and have the equivalent effect of adsorbing, decomposing, and sterilizing very high malodorous components. In the method of the present invention, if a trace amount of an inorganic component is contained, all organic substances can be used as raw materials, and in particular, paper, wood, and ethylene (gas ethylene, polyethylene, polypropylene, polystyrene, etc.) contained in industrial waste can be used. , Or food residues, etc. as suitable raw materials. At present, industrial waste from thermal decomposition treatment is widely used. Therefore, it is not necessary to purchase ceramic raw materials (inorganic materials) to produce ceramics, which can reduce manufacturing costs. The method of the present invention is characterized in that the thermal decomposition step includes a heating step for raising the temperature in the reaction tank. 200537056 The thermal decomposition step of the raw material organic matter can be burned using the usual waste treatment methods, but it is not necessary to use a method other than combustion such as an electric heater or a heat exchange tube that circulates warm air to force the temperature inside the device to be increased. Thermal decomposition of raw material organic matter can be achieved by combustion. Thereby, the method of the present invention does not need a combustion step at all from the start of the thermal decomposition treatment to the exhaust treatment, and it does not need to obtain a combustion furnace installation permit, and can provide very high safety. When the raw material organic matter is burned in the reaction tank, the raw material organic matter preferably contains 3,000 calories / g or more. Since the raw material contains such a degree of calories, thermal decomposition can be actively performed, and ceramics can be efficiently produced. The ceramic production method of the present invention is characterized in that the gas treatment step includes a step of cooling the liquefied gas generated in the thermal decomposition step and collecting the liquid. In this way, the gas generated in the thermal decomposition step contains a carbon component because it is a gaseous carbide, and liquefied, it becomes lignoacetic acid. The wood acetic acid collected by the device of the present invention can be effectively used as an insect repellent, a soil improver, etc., through secondary processing through a neutralization treatment or the like. Furthermore, the "ceramic production method of the present invention" is characterized in that the gas processing step includes a reduction step of feeding electrons to the gas discharged from the reaction tank. Although the gas exhausted in the thermal decomposition step contains almost no dioxin and carbon dioxide gas, since these are trace amounts of substances, the electrons (negative ions) are supplied to make them harmless because they are expected to be complete. In addition, it is also possible to have a gas to return most of the electrons here. 200537056 Return to the aforementioned reaction tank. As mentioned above, the discharged components are reintroduced. Moreover, the present treatment step has a step of treating water. As mentioned above, it is related to the present invention to dissolve the remaining harmful hydrogen into safe water. It is equipped with a thermal decomposition reaction tank. The foregoing is the case with thermal decomposition. As the present compound is sent in a large amount, the carbide is entered into the material organic matter. Thermal decomposition anti-porcelain containing mineral (mineral) reaction waste is not a step of large-scale oxidation and primordial two-step adsorption and decomposition of materials by removing heat from the product. The method for producing ceramics of the Ming Dynasty is characterized in that the aforementioned gas or the liquid gas is thrown into a large part of the oxidative decomposition step containing active oxygen which reacts with the active oxygen in the treated water to be liquefied or decomposed by electrons, and finally Carbon oxide is contacted with active oxygen, and this is converted to carbon dioxide without harm. The ceramic generating device is characterized in that it has a heat input and material input port and a ceramic outlet, a means for feeding electrons to the aforementioned carbides, and an exhaust gas for collecting exhaust gas generated in the tank. Means of collection. The device of the Ming Dynasty decomposes and gasifies the carbon and electrons generated by the thermal decomposition reaction while maintaining the reducing environment. In the lower part of the reaction tank, ceramics are formed by an oxygen component and a small amount of inorganic components separated from carbides. In the device of the present invention, while using the waste reaction tank, the same reaction tank can also produce ceramic equipment and ceramics. In addition, since the ceramics produced by this step can provide high-quality ceramics having excellent malodorous effects, sterilizing effects, and the like. Moreover, the ceramics can be taken out in sequence under the pretext that raw materials can be continuously cast.

200537056 入 ’can improve the utilization efficiency of the device. Further, for example, if heating means for forcibly increasing the temperature in the apparatus such as an electric heater or a heater is provided, the materials in the reaction tank can be thermally decomposed without burning, and a combustion step can be completely eliminated. Further, the ceramic generating device of the present invention may be provided with an oxygen supply means for feeding carbides generated in the pyrolysis reaction tank and feeding a large amount of electrons as well as a small amount of oxygen components. #When used in the structure that burns organic matter in the reaction tank, the oxygen component can be used to promote combustion and facilitate ceramization. Further, in the ceramic generating apparatus of the present invention, the exhaust gas collection means is effective in that the exhaust gas is cooled and liquefied. Furthermore, a second electron supply means for feeding electrons to the exhaust gas collected by the exhaust gas collection means may be provided. At this time, it is effective to use the structure of the aforementioned electron supply means to allow most of the gas with electrons to be sent to the aforementioned reaction tank again. Furthermore, the ceramic generating device of the present invention is effective in that the exhaust gas collecting means includes a means for sending the collected exhaust gas into a processing tank (containing active oxygen-containing water). In this way, most of the exhaust gas is liquefied or decomposed by electrons, and finally harmful hydrogen and carbon monoxide are brought into contact with active oxygen, which is converted into safe water and carbon dioxide without harm. Using the conventional thermal decomposition system for all gas combustion treatments, the above steps can be used to achieve exhaust treatment without the need for a combustion step. In the case where the exhaust gas is reacted with active oxygen, the ceramic generating device I is provided with active oxygen production means and means for feeding active oxygen produced by the means into the water in the aforementioned treatment tank. Here, it is preferable that the above-mentioned activity 9 200537056 means for producing oxygen is provided with a means for reducing water in the treatment tank and an ozone generating device. The means for bringing the water in the processing tank into a reduced state is preferably provided with an electron (e ·) generating device and / or a means for putting a reducing agent into the processing tank. As described above, the present invention can oxidize and decompose exhaust gas by containing active oxygen (Q-) in the water in the treatment tank. When the active oxygen is contained in water, the water in the treatment tank is brought into a reduced state ', thereby making it possible to easily dissolve an odor which is not easily dissolved in water. Ozone is split into 02 and 0- in water, and the active oxygen 0- reacts (oxidatively decomposes) with residual harmful argon (HO and carbon monoxide (CO)) into harmless water (H20) and carbon dioxide (CO2). When the water is brought into a reduced state, electrons can be injected into the water in the processing tank, and a reducing agent can be added to the processed water to more efficiently accelerate the oxidative decomposition. [Embodiment] Hereinafter, the ceramics according to the present invention will be described with reference to the drawings. Device for generating ί. Figure 1 is a diagram for explaining the overall structure of the ceramic generating device of the present invention. The device of the present invention includes a thermal decomposition reaction tank 1 and electron generation for supplying electrons / oxygen to the reaction tank. Device 2, a reaction gas collection tank 3 that collects the reaction gas generated in the thermal decomposition reaction tank 1, and an exhaust gas treatment device 4 that processes the exhaust gas collected there. The thermal decomposition reaction tank 1 is provided with a raw material input port 11 at the top. The lower part is provided with a ceramic take-out port 1 2 and a reaction gas collection opening 13. It is also configured so that when the raw material input port i 1 and the ceramic take-out port 1 2 are closed, it can be guaranteed. The inside of the reaction tank 1 is airtight. The reaction gas collection opening i 3 is connected to the reaction gas collection tank 3 through a conduit 13a. The tank 3 is further connected to the exhaust treatment device 4 through a conduit 13b. The conduit 13b is provided with a fan or It is a gas absorption device 14 such as a pump, which can easily introduce the reaction gas into the collection tank 3. The device of the present invention further includes an electron generating device 2 which is configured to send electrons into the reaction tank 1. The electron generating device 2 can Using any device, a form that generates electrons from a unipolar output electrode by generating a high voltage, or a form that generates electrons by exciting air in the air with a strong magnetic field, and a device that uses minerals that can continuously emit electrons. It is particularly suitable for use. In addition, the position where electrons are sent in can be sent in the position where the carbonized layer is generated later in the reaction tank 1. The lower part of the exhaust tank 3 is provided with a condensed liquid component (wood acetic acid) on the inner wall of the receiving tank. The receiving section (not shown in the figure) and the liquid component extraction outlet 13c are described below for the ceramic production steps of this device. The initial steps of the operation are explained. Organic waste is used as the raw material from the raw material input port 11. Take the outlet 12 from the ceramic magnet installed below the reaction tank, and use the burner and other ignition means to directly ignite the raw material. Here, the raw material input port is open. As the oxygen enters the reaction tank 1, once the raw material is burned, the raw material input port 11 and the ceramic magnetic take-out outlet 12 are closed. Since the raw material input port 11 and the ceramic magnetic take-out outlet 12 are closed, the raw material combustion is stopped. The temperature in the thermal decomposition reaction tank 1 rises to about 300 to 500 degrees due to the previous combustion. The raw materials in the reaction tank 1 start to be thermally decomposed since 200537056. The raw materials are organic substances that contain at least 3,000 calories. You can use the heat you have for thermal decomposition. As such organic materials, for example, paper, wood vinyls (gas ethylene, polyethylene, polypropylene, polystyrene, etc.) in urban waste, or food residues can be used as suitable raw materials. The gas generated during the initial combustion and thermal decomposition described above is in the form of a smoke, and flows to the side of the exhaust groove 3 through the duct 13. As described above, this device is provided with the electron generating device 2 which is configured to supply electrons from the device 2 to the reaction tank 1 through the electron supply port provided on the side wall of the reaction tank 1. The electronic supply port is provided with an air intake port (not shown) for drawing in external air, and the gas generated in the reaction tank 1 due to thermal decomposition flows out to the exhaust tank 13 and flows out to the exhaust tank j 3 The same amount of air and electrons will flow into the reaction tank 1 together. Of course, the oxygen contained in the air flowing with the electrons in the reaction tank 1 will also be sent in, but because the electrons sent in have greater energy than this, the reducing environment in the reaction tank 丨 can maintain the temperature in the tank even if There will be no fire in the raw materials. That is, the inside of the 'thermal decomposition tank' uses the calories of the organic substance input as a raw material to perform thermal decomposition. When the thermal decomposition proceeds, the organic material of the raw material becomes a carbide, and a carbonized layer 5 is generated in the lower part of the thermal decomposition reaction tank i. The electron supply port of the electron generating device 2 is provided at the position where the carbonized layer is generated. After the carbonized layer 5 is generated, electrons or air (oxygen component) can be supplied to the carbonized layer. As mentioned above, when the organic material is put in, ignited, and the raw material is burned to a certain degree, the air is cut off, and the flame is caused by the heat generated by the combustion. That is, components other than the carbon component contained in the raw material and the micromineral inorganic component are converted into a gas and evaporated. The remaining carbon components remain in the carbonization tank at the lower part of the reaction tank 1. By feeding a large amount of electrons from the electron generator into the carbonized layer, the thermal decomposition in the carbonized layer continues, and the carbon component is also converted into a gas and evaporated. Finally, only the inorganic minerals contained in the raw material remain. This inorganic mineral is combined with a trace amount of oxygen contained in the air coming in from the electron generating unit 2 to form an inorganic oxide, that is, pottery tin 6 and remains at the bottom of the reaction tank 1. The ceramic 6 is taken out from a ceramic take-out port i 2 provided at the bottom or bottom of the reaction tank 1 and used. The ceramics produced according to the method of the present invention remain in a trace amount because the trace inorganic substances contained in the raw materials are converted into oxides, and their weight is about one hundredth of the amount of the organic material raw materials initially charged. Although the yield of the product relative to the raw material is low ', industrial waste can be effectively used. The industrial waste has recently been extensively treated by thermal decomposition. Only a slight improvement of the thermal decomposition device of the waste can be used as a part of waste treatment to produce ceramics. Furthermore, since the ceramics produced by this method are produced through a reduction step, they have excellent deodorizing properties, and have antibacterial properties, and can be effectively used in many ways. If there is less organic matter to be injected, the calories in the reaction tank 1 are reduced and the thermal knife solution is reduced. The temperature in the reaction tank 1 is reduced. In order to prevent the thermal decomposition cycle from being stopped due to the temperature decrease, it is best to continue to feed the raw materials. That is, once the operation starts, the device can be operated continuously as long as materials are continuously put into operation. 200537056 The device can be operated continuously. The device can operate efficiently. In another embodiment of the reaction tank 1, a heating device for heating the inside of the reaction tank 1 may be provided. That is, an electric heater forcibly heating the reaction tank of the ceramic production device, or for example, a heat exchange tube surrounding the reaction tank to circulate 1,000 degrees of warm air, etc., the internal temperature can be raised to 300 ~ without using combustion. 5,000 degrees of thermal decomposition of raw material organic matter in the reaction tank. With this structure, the temperature can be increased regardless of the amount of heat of the raw organic matter, which makes it suitable for use in ceramics with fewer calories. In addition, because the organic matter can be kept at a desired temperature even when a small amount of organic matter is charged into the reaction tank 1, the thermal decomposition can be carried out to the end 'because the thermal decomposition cycle can be prevented from being stopped, and it is not necessary to frequently charge the raw materials. In addition, when this structure is adopted, all steps from thermal decomposition to exhaust gas treatment to be described later can be achieved without combustion. While improving the safety, the device of the present invention does not need to be regarded as a combustion furnace, so it is not necessary to apply for a license. cfj "The structure of the above-mentioned embodiment, although a large amount of electrons are fed together with oxygen, but this oxygen supply means is not an essential configuration. That is, even if oxygen is not fed to the reaction tank during thermal decomposition, it is possible to ceramize only the oxygen contained in the raw material organic matter. In order to reduce costs, an additional oxygen supply means may be omitted. The gas generated in the above thermal decomposition process is a flammable gas because the raw material contains a large amount of oil and fat components, hydrogen, carbon and the like. Usually, the thermal decomposition device of industrial wastes has a separate combustion chamber to burn the gas. However, when the 14 200537056 gas is burned, there are problems such as the occurrence of dioxin pollution and global warming caused by the generation of carbon dioxide gas. However, the device of the present invention can perform independent gas treatment without relying on combustion. The gas treatment will be described below.

The first is that the gas enters the exhaust tank 3 because it is naturally cooled because it is connected to the outside air, so the incoming gas is cooled and condenses on the inside of the tank, and can be recovered as a liquid. The main component of the recovered liquid is carbon, which is in the state of acetic acid (CHsCOOH). It can be used as an insect repellent or soil improvement material through secondary treatment such as neutralization. In addition, depending on the input materials, it may contain a fat component, gas, etc., and these components can be removed appropriately.

The gas that cannot be recovered by the condensation phenomenon of the exhaust gas tank is an extremely acidic gas, and the exhaust gas treatment device 4 is neutralized with alkaline water such as sodium hydroxide. A second electron generator (not shown) for sending electrons to the exhaust gas is provided in the exhaust gas treatment device. The exhaust gas treatment device 4 has a pipe 7 connected to return the gas to the reaction tank 1 again. This structure is to return a large part of the gas in the processing tank 4 to the reaction tank 1 again. The part that could not be returned here to the reaction tank 1 was sent to the second processing device 9 as shown in Fig. 2. The last remaining gas contains trace amounts of harmful hydrogen and carbon monoxide. Because the present invention is intended to be complete, the gas remaining in the treated water is introduced into the water containing active oxygen to cause oxidative decomposition of hydrogen and carbon monoxide. That is, for example, ozone (03) is dissolved in water, and it is split into 0 2 and cr, and the residual gas is oxidized and decomposed by the 0- (active oxygen). However, because ozone is not easily soluble in water, the following method is used to efficiently dissolve ozone in water. As shown in Fig. 2, the second processing device 9 includes a processing tank 1, an ozone generating device 92, a magnetic field generating device 93, and the like. Water is added to the treatment tank ^, and a magnetic field is generated using the magnetic field generator Pei 93, so that the water in the treatment field becomes magnetic water. The ozone generated by the ozone generator 92 is sent there. Because electrons (e ·) are generated in magnetic water, ozone can be easily dissolved in water and split into O2 and CT. This active oxygen (0-) is combined with hydrogen (H) and carbon monoxide (c0) 'to produce harmless water (H2O) and carbon dioxide (C02). It is also possible to use an "electron generator" instead of the magnetic field generating device 93 to drive the generated electrons (e ·) into the processing tank 91 so that the whole treated water becomes reduced water. That is, after the water in the treatment tank 1 is brought into an anoxic state, ozone may be sent from the ozone generating device 92 there to produce active oxygen for oxidatively decomposing the exhaust gas. In addition, when a stirring device for stirring water in a reduced state and ozone is provided, ozone can be dissolved in water more easily. Further, if the ozone generating device 92 is provided with an oxygen permeation filter 94, the air coming in from the outside is transmitted through the filter 94 to the ozone generating device, so that ozone at two concentrations can be generated more efficiently. In addition, since the oxygen permeation filter 94 can remove other components contained in the air, the occurrence of NOx, SOx, and the like can be suppressed. Alternatively, instead of using the ozone generating device 92, a method of adding an oxidant such as hydrogen peroxide to the treated water may be used to obtain treated water containing active oxygen. In addition, instead of the ozone generating device 92, an electrolysis device (200537056) (not shown in the figure) may be provided to electrolyze water to produce active oxygen and inject it into the water. The present inventors conducted the following deodorization test and antibacterial test in order to confirm the characteristics of ceramics produced by thermal decomposition using the above-mentioned apparatus. (1) Deodorization test 5 g of Buddha stone (Sample 1) and 5 g of ceramic powder produced by the apparatus of the present invention were prepared as samples, and the deodorization test was performed using the test apparatus shown in FIG. 3. A test device 20 and an acrylic container 21 with a size of 300 x 300 x 300 mm and a capacity of about 27 liters were prepared. Because the container 21 is provided with an injection device 22, the test gas can be injected into the container 21. In the container 21, a sample container 23 having a plurality of holes on the upper side was placed, and a reaction fan 24 (1.2 m3 / min) capable of agitating the air in the container was placed thereon. The container 21 is further provided with a gas measurement port 25 ', which is a structure in which the internal gas can be sucked in using the pump and the concentration can be measured by the detector 27. Reference numeral 28 denotes a sample insertion port. The test gas was prepared with an initial concentration of 150 ppm of ammonia (test gas 0 and an initial concentration of 32 ppm of formaldehyde (test gas 2). The test gas was introduced into a test device 20, and each sample was measured after 1 hour, 2 hours, 4 hours, After 6 hours and 24 hours, the residual gas concentration was calculated. The initial concentration is the value measured 2 minutes after the gas was injected into the test container. The change in the residual concentration of the test gas 1 and the residual ratio are shown in Figure 4. 'The change in the residual concentration of the test gas 2 and the residual rate are shown in Figure 5. From the results of these tests, it is clear that the residual concentration of the gas in this product is significantly higher than that of zeolite, which is generally used as a deodorant. 200537056 is low, so it can be known to have a high deodorizing effect. (2) Antibacterial test prepared by diluting ceramic powder produced by the device of the present invention with sterilized physiological saline, 0.05%, 0.1% , 0.5%, 1.0%, 10.0% samples, and control samples.

The following strains were prepared and cultured in SA medium at 37 ° C for 24 hours before testing. 1) Eschericia coli KEC-B-001 2) Staphylococcus auresus KEC-B-002 3) Pseudomonas aeruginosa KIEC-B-003 4) Bacillus sobtillus KEC-B-007 5) Salmonera typhimurium Klebsiella KEC-B-009 Fig. 6 is a diagram showing the test sequence of this antibacterial test. Use sterilized physiological saline to adjust the previously cultured test bacteria to

1007 X CFU / ml. 0.1 ml of this cell liquid was inoculated into each test sample, and shaken using a shaker at 1 85 / rpm at room temperature. After a predetermined time (24 hours, 48 hours), the test sample was taken out, and sterile physiological saline was used. Made into a 10-fold dilution stage series. Next, it was smeared and inoculated on pDA medium for culture. The bacteria were 37t, 2nd, yeast 25, 2nd, and mold 28, 7th. The population formed on the medium was measured. Figures 7 to 12 are tables showing the main points of the above-mentioned antibacterial test agency. As shown in the tables, it can be seen that the ceramics produced by using the present invention have the right antibacterial effect of 18 200537056. The method for generating ceramics of the present invention ^ ^ Because ancient ceramics can be generated without firing steps, and energy can be reduced ^ ^ ^ ^ In addition, there is no pollution problem caused by dioxin due to generation, and diploid pupation caused by generation Ceramics can be produced by issues such as global warming. According to this method, once the initial stage of ^^^ h is started, the temperature in the device can be maintained at 3000 ~ 500 degrees by the organic matter ...

The target system produces the temperature required for thermal decomposition, and the installation operation itself can be performed at low cost and low pollution. Also, because raw materials can use organic waste, waste can be effectively recycled. In addition, the ceramics produced by the method of the present invention can be used in various fields because they have excellent deodorizing properties and antibacterial properties after the reduction step. In addition, lignoacetic acid 'obtained by liquefying the exhausted fluorine can be effectively used by subjecting it to secondary processing. [Simplified description of 囷 style]

Fig. 1 is a structural diagram showing a ceramic manufacturing apparatus of the present invention. FIG. 2 is a configuration diagram showing a second processing device 9. Fig. 3 is a structural diagram showing a test device used in a deodorization test of a raw ceramic produced by the device of the present invention. Fig. 4 is a graph showing the deodorization test results of raw ceramics produced by the device of the present invention. Fig. 5 is a table showing the results of the deodorization test of raw ceramics produced by the device of the present invention. Fig. 6 is a sequence diagram showing an antibacterial test performed on a ceramic produced by the apparatus of the present invention. Fig. 7 is a graph showing the antibacterial test results of the raw ceramics produced by the device of the present invention. Fig. 8 is a graph showing the results of an antibacterial test on the ceramic produced by the device of the present invention. FIG. 9 is a graph showing the antibacterial test results of the ceramic produced by the device of the present invention

Figure 10 is a graph showing the antibacterial test results of the ceramic produced by the device of the present invention. Fig. 11 is a graph showing the antibacterial test results of the green ceramics produced by the device of the present invention. Fig. 12 is a graph showing the results of an antibacterial test on the ceramic produced by the device of the present invention. [Simple description of component representative symbols] 1 Thermal decomposition reaction tank 2 Electron generation device 3 Exhaust tank 4 Exhaust treatment device 9 Second treatment device 11 Raw material input port 12 Product extraction port 20 200537056 13a Duct 13b Duct 13c Liquid component collection port 14 Suction device

twenty one

Claims (1)

200537056 The scope of the patent application: 1. A ceramic production method, which uses a special plate to make horses, which contains at least and decomposes raw materials containing trace inorganic components. 4% Decorations ... Steps for processing negative materials, and processing the处理 The treatment step of the gas generated in the decomposition step, the eighth step> "The familiar decomposition step has the decomposition of raw material organic matter into the decomposition step containing the aforementioned inorganic ν ν ^ Μ", the carbide and gas components of the wind y knife, and A large amount of φ electricity is sent to the aforementioned separated carbides, and the aforementioned carbides are maintained while maintaining a reducing environment in the aforementioned reaction tank. The step of gasifying and separating the aforementioned inorganic material from the aforementioned carbide; and the step of reacting the separated inorganic component with the oxygen component by a knife to form an oxide The production method, wherein the aforementioned raw material organic matter is an industrial waste. 3. As described in the patent application scope of item i or item 2 of the method for generating ceramics, the aforementioned thermal decomposition step in # has a heating step of heating the aforementioned reaction tank. 4. The method of researching and producing as described in item i or item 2 of the scope of patent application, wherein the aforementioned raw material organic substance contains at least 3,000 calories. 5. The ceramic production method according to item 1 of the scope of patent application, wherein the aforementioned gas processing step is provided with steps for cooling, liquefying, and collecting the liquefied gas discharged from the reaction tank. 6. According to the patent application method described in item 1 or item 5, the aforementioned gas treatment step is provided with a reduction step of feeding electrons discharged from the reaction tank 22 200537056 into the electron. 7. The gas treatment step described in the scope of the patent application No. 6 is more equipped with '', of which 刖 which is more. · There is a step of returning most of it to the aforementioned reaction tank for heating. "Milk weight 8. As described in the scope of patent application No. 1 red method, in which the ceramic producer described in / item 5 into the ancient leather" "Each of them has the technology of introducing the gas or its liquefaction into 3 active oxygen treated water To carry out the step of oxidative decomposition. 9. A ceramic generating device, which is characterized in that it is provided with a thermal decomposition reaction tank, which is provided with a material input port and ceramics without an outlet; and Carbide delivery in the decomposition reaction tank ^ ^ v 疋 eight electrons; and the exhaust gas collection member that collects the aforementioned exhaust gas generated in the pyrolysis reaction tank. Ο. As described in item 9 of the scope of patent application The ceramic research generating device is provided with a heating member for increasing the temperature in the reaction tank. Π. The ceramic heating generating device described in item 9 of the patent application scope, the heating member is an electric heater or a heat exchange tube that circulates hot air. 12. The ceramic generating device according to item 9 of the scope of the patent application is provided with an oxygen supply member that supplies the aforementioned large amount of electricity to the carbides generated in the thermal decomposition reaction tank and also a trace amount of oxygen components. Patent Scope 9 Constituting gases to item 12 in any one of the ceramic generating means, wherein the exhaust gas collector is provided with a cooling member, said liquefaction. Its its its 14. The ceramic generating device according to item 9 of the patent application scope, further comprising a second electron supply means for feeding electrons to the exhaust gas collected by the exhaust gas collection means. 23 200537056 1 5 · The ceramic generating device described in item 14 of the scope of patent application, which includes a structure in which most of the aforementioned electrons can be sent into the exhaust gas and then returned to the aforementioned thermal decomposition reaction tank. 16. The ceramic generating device according to item 9 of the scope of the patent application, which includes a member for sending the exhaust gas collected by the aforementioned exhaust gas collection means to a processing tank (containing active oxygen-containing water). 17. The ceramic generating device according to item 16 of the scope of application for a patent, which includes a member provided with an active oxygen production member and a member that feeds active oxygen produced using the member into the water in the treatment tank. φ18. The ceramic generating device according to item 17 of the scope of patent application, wherein the aforementioned active oxygen production member is an ozone generating device or an electrolysis device for water. 19. The Tao Yao generating device according to item 16 of the patent scope, which includes a means for making the water in the treatment tank into a reduced state. 2. The ceramic generating device according to item 19 of the scope of the patent application, wherein the component for making the water in the processing tank into a reduced state is provided with an electron (e) generating device or is put into the processing tank for reduction剂 的 组合。 The components of the agent. 21 · -ceramics, which are produced by using the ceramic generation method described in item 丨 · of the aforementioned patent application scope. A kind of wood vinegar S 夂 is characterized in that it is produced by the ceramic production method described in item 5 of the aforementioned patent application. twenty four