TW200534527A - Manufacturing method of packed integrated fuel cell and the fuel cell thereof - Google Patents

Manufacturing method of packed integrated fuel cell and the fuel cell thereof Download PDF

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Publication number
TW200534527A
TW200534527A TW093109318A TW93109318A TW200534527A TW 200534527 A TW200534527 A TW 200534527A TW 093109318 A TW093109318 A TW 093109318A TW 93109318 A TW93109318 A TW 93109318A TW 200534527 A TW200534527 A TW 200534527A
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TW
Taiwan
Prior art keywords
electricity
printed circuit
circuit board
fuel cell
line
Prior art date
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TW093109318A
Other languages
Chinese (zh)
Inventor
Shi-Ming Shu
Tsang-Ming Chang
Feng-Yi Deng
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Antig Tech Co Ltd
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Publication date
Application filed by Antig Tech Co Ltd filed Critical Antig Tech Co Ltd
Priority to TW093109318A priority Critical patent/TW200534527A/en
Priority to GB0504788A priority patent/GB2412785A/en
Priority to JP2005081875A priority patent/JP2005294256A/en
Priority to DE102005015020A priority patent/DE102005015020A1/en
Publication of TW200534527A publication Critical patent/TW200534527A/en

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Classifications

    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00—Printed circuits
    • H05K1/16—Printed circuits incorporating printed electric components, e.g. printed resistor, capacitor, inductor
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/023—Porous and characterised by the material
    • H01M8/0241—Composites
    • H01M8/0245—Composites in the form of layered or coated products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0247—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0269—Separators, collectors or interconnectors including a printed circuit board
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1007—Fuel cells with solid electrolytes with both reactants being gaseous or vaporised
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M2008/1095—Fuel cells with polymeric electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1009—Fuel cells with solid electrolytes with one of the reactants being liquid, solid or liquid-charged
    • H01M8/1011—Direct alcohol fuel cells [DAFC], e.g. direct methanol fuel cells [DMFC]
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00—Printed circuits
    • H05K1/18—Printed circuits structurally associated with non-printed electric components
    • H05K1/182—Printed circuits structurally associated with non-printed electric components associated with components mounted in the printed circuit board, e.g. insert mounted components [IMC]
    • H05K1/185—Components encapsulated in the insulating substrate of the printed circuit or incorporated in internal layers of a multilayer circuit
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Abstract

The invention provides a packed integrated fuel cell comprising the following constitution: electrolyte layer, including at least one fuel cell unit; the first printed circuit board, forming the anode collector circuit on the first printed circuit board contacting the anode of single surface of each fuel cell unit; the second printed circuit board, forming the cathode collector circuit on the second printed circuit board contacting the cathode of single surface of each fuel cell unit. The electrolyte layer is placed between the first printed circuit board and the second printed circuit board. After piling up together the packed integrated fuel cell forms a sandwich structure with compact connection.

Description

200534527 域 領 術 技 1)之 /IV 屬 明 說所 明月 發日 五 發 發 本 於 關 係 積 二&1一 種 方 造 製 的 池 電 料 燃 式 合 整 法 其 係 別 ， 於 池 ^& ^ur 料 燃 式 合 整 層 積 於 用 種 妾一、 電 刷線 印電 自集 各極 在陰 ，與 程路 製線 板電 路集 電極 刷陽 印出 用作 利製 乃別 分 法面 方單 造的 製板 的基。 層路路 的 池 料 燃 於 關 係 皆 乃 藝 技 造 製 的 池 電 料 燃 術知 技習 前 先 容容 内内 藝藝 技技 的等 軸構 主結 為的 質電 解集 電者 以或 於式 關方 是造 者製 或的 ， 層 構電 結集 體於 整對 或集先 墨揮其 石發有 用夠， 採能段 然亦手 雖且的 ，並層 段，電 手層集 等電造 等集製 網出於 屬造行 金製採 、以知 墨可習 石係惟 用段， 牙手能 於等功 及網的 僅屬層 皆金電 製 的 池 料 燃 的 小 。 、行 短採 、法 薄無 、全 輕完 在則 這藝 ，技 制知 限習 礙， 障下 的求 性要 天造 改的 思性 亟特 乃小 失短 缺、 的薄 藝、 技輕 知備 習具。 於於層 鑑合電 有適集 人常為 明^^做 發種用 的一使 明出來 發明池 本發電 而料 良燃 在 程 製 板 路 ^^ 刷 印 用 利 種 一 供 提 係 的 目 的 明 容發 内本 明 發 陰 與 路。 線池 筹米 極燃 陽式 出合 作整 層 別積 分於 面用 單使 的其 板將 基並 路， 電路 刷線 C2— 一£一〇0 •^二 -^3 自集 各極200534527 Field Leading Techniques 1) of / IV is clearly stated that the five monthly releases are published in the relationship product two & 1 a square-shaped battery-electric fuel-combustion integration method, which is related to Yuchi ^ & ^ The ur material combustion type is integrated and laminated in a variety of ways. First, the brush wire is printed on the self-collection of the poles in the yin, and the Cheng Lu wire board circuit collector brush is printed on the positive side for profit. Manufactured board base. The layers of pool materials are all related to the quality of the electrolyzed collectors that are mainly based on the isometric structure of the art and technology of the pool. The formula is based on the creator system, and the layered structure is collectively used in the whole pair or the first set of waves, and the energy generation section is also handy, and the layered section, the electric hand, and other electrical manufacturing Iso-grid nets are the only sections of the gold system that are used to make gold mining and understand the Moxian stone system. Tooth-handlers can only burn the pool materials made of gold and electricity that are equal to the power and net. , The short-term mining, the method is weak, the whole light is complete, the art is limited, the know-how of technology is limited, and the ideological nature of seeking sexual change under obstacles is urgently a small loss, a thin skill, a light technique Prepare tools. Yu Yujian Jianhe has the right set of people who often make seeds for the Ming ^ ^ to make a seed to invent the Ichimoto power generation, and it is expected to burn well in the process board road ^ ^ The purpose of printing is to use the seeds and provide for the system. Inside Rongfa, the hair and the road are clear. Line pools, rice, poles, poles, anodes, co-operation, whole layers, don't accumulate on the surface, and use a single board to connect the bases to the circuit. Circuits are wired. C2— One £ 100 • Two two-^ 3 Self-collection poles

第5頁 200534527 五、發明說明（2) 本發明另一目的係提供一種非常適合於具備輕、薄、 短、小特性的燃料電池來使用做為集電層。 為達成本發明上述目的，本發明提供一種積層整合 式燃料電池的製造方法包括下列步驟：（A ).提供電解質 層，其中電解質層至少包含一個以上的燃料電池單元； (B). 利用印刷電路板製程，在接觸各個燃料電池單元陽 極的第一印刷電路基板的單面上形成陽極集電線路； (C ).利用印刷電路板製程，在接觸各個燃料電池單元陰 極的第二印刷電路基板的單面上形成陰極集電線路； (D).將電解質層置於完成步驟（B)的第一印刷電路基板與 完成步驟（C )的第二印刷電路基板之間後疊合一起呈緊密 接合的三明治結構。 再者，為達成本發明上述目的，本發明提供一種積 層整合式燃料電池包括：電解質層係至少包含一個以上 的燃料電池單元；具有陽極集電線路的第一印刷電路基 板，其中陽極集電線路係形成在第一印刷電路基板接觸 各個燃料電池單元陽極的單面上；具有陰極集電線路的 第二印刷電路基板，其中陰極集電線路係形成在第二印 刷電路基板接觸各個燃料電池單元陰極的單面上；其中 電解質層，係置於第一印刷電路基板與第二印刷電路基 板之間後疊合一起，使積層整合式燃料電池呈緊密接合 的三明治結構。 為使熟悉該項技藝人士瞭解本發明之目的、特徵及Page 5 200534527 V. Description of the invention (2) Another object of the present invention is to provide a fuel cell with light, thin, short, and small characteristics for use as a current collecting layer. In order to achieve the above object of the present invention, the present invention provides a method for manufacturing a laminated integrated fuel cell including the following steps: (A). Providing an electrolyte layer, wherein the electrolyte layer includes at least one or more fuel cell units; (B). Using a printed circuit An anode current collecting line is formed on one side of a first printed circuit substrate contacting the anode of each fuel cell unit by a board manufacturing process; (C). Using a printed circuit board process, A cathode current collecting line is formed on one side; (D). The electrolyte layer is placed on the first printed circuit board that completes step (B) and the second printed circuit board that completes step (C), and then is superimposed to form a tight joint. Sandwich structure. Furthermore, in order to achieve the above object of the present invention, the present invention provides a laminated integrated fuel cell including: an electrolyte layer system including at least one fuel cell unit; and a first printed circuit substrate having an anode current collecting circuit, wherein the anode current collecting circuit It is formed on the single side of the first printed circuit board that contacts the anode of each fuel cell unit; the second printed circuit board has a cathode current collecting line, wherein the cathode current collecting line is formed on the second printed circuit board that contacts the cathode of each fuel cell unit The electrolyte layer is placed between the first printed circuit substrate and the second printed circuit substrate and then stacked together, so that the laminated integrated fuel cell has a tightly bonded sandwich structure. In order for those skilled in the art to understand the purpose, characteristics and

200534527 五、發明說明（3) 功效，茲藉由下述具體實施例，並配合所附之圖式，對 本發明詳加說明，說明如后： 實施方式 第一圖顯示本發明方法的流程圖，以及第二圖顯示 依據本發明方法製造的積層整合式燃料電池之分解圖。 本發明的積層整合式燃料電池的製造方法1 0包括主要的 步驟有步驟（1 0 1 )、步驟（1 0 3 )、步驟（1 0 5 )，分述如下 文。步驟（1 0 1 )係提供電解質層2 3，而本發明實現步驟 (1 0 1 )的具體手段係電解質層2 3可以利用質子交換膜與高 分子材料上於分別於塗佈（c 〇 a t i n g )上的預定濃度的白金 (P t)及預定濃度的白金（P t) /釕（R u )後，利用膠合手段將 質子交換膜、高分子觸媒層以及碳紙/碳布形成質傳電解 質層2 3。質子交換膜的材料可以選用杜邦N a f i ο η (DoPont Nafion)材料，而塗佈（coating)的手段係可以 採行高分子聚合物印刷（Polyimide Printing)的方式來 進行。例如採用金屬真空蒸鍍方式，以蒸鍍出預定濃度 介於1〜5 m g / c m 2之間的白金（P t)，以及蒸鍍出預定濃度介 於1〜10mg/cm2之間的白金（Pt) /釕（Ru)。再以採用網板 印刷的手段，印刷上碳粉、鐵弗龍（T e f 1 ο η )、溶劑 (S ο 1 v e n t)等混合物質，或者採用壓板印刷手段，印刷上 碳粉、鐵弗龍（T e f 1 ο η )、溶劑（S ο 1 v e n t)等混合物質，此 即便完成質傳電解質層2 3的製作。經上述所製造出來的 質傳電解質層2 3係包括有複數個燃料電池單元2 3 a，請參200534527 V. Description of the invention (3) The effects are described in detail by the following specific examples and the accompanying drawings, as described below: Implementation The first figure shows a flowchart of the method of the present invention. And the second figure shows an exploded view of a laminated integrated fuel cell manufactured according to the method of the present invention. The manufacturing method of the laminated integrated fuel cell 10 of the present invention includes main steps including a step (101), a step (103), and a step (105), which are described below. Step (1 0 1) is to provide the electrolyte layer 23, and the specific means for realizing step (1 0 1) of the present invention is the electrolyte layer 2 3, which can be coated with a proton exchange membrane and a polymer material, respectively. ) And platinum (P t) and platinum (P t) / ruthenium (Ru) on a predetermined concentration, then the proton exchange membrane, the polymer catalyst layer, and the carbon paper / carbon cloth are mass-transmitted by gluing. Electrolyte layer 2 3. The material of the proton exchange membrane can be selected from DuPont Nafion (DoPont Nafion), and the coating method can be performed by polymer printing (Polyimide Printing). For example, a metal vacuum evaporation method is used to evaporate platinum (P t) with a predetermined concentration between 1 and 5 mg / cm 2, and evaporate platinum with a predetermined concentration between 1 and 10 mg / cm 2 ( Pt) / Ruthenium (Ru). Then, screen printing is used to print a mixture of toner, Teflon (T ef 1 ο η), solvent (S ο 1 vent), or press printing is used to print toner, Teflon. (T ef 1 ο η), solvent (S ο 1 vent), etc., even if the production of the mass transfer electrolyte layer 2 3 is completed. The mass transfer electrolyte layer 2 3 manufactured above includes a plurality of fuel cell units 2 3 a. Please refer to

200534527 五、發明說明（4) 見第二圖。200534527 V. Description of Invention (4) See the second figure.

步驟（1 0 3 )是利用印刷電路板製程，在接觸各個燃料 電池單元23a陽極的第一印刷電路基板21的單面上形成陽 極集電線路2 1 1 。請配合參見第二圖，本發明第一印刷電 路基板2 1的單面，乃就是指與各個燃料電池單元2 3 a陽極 接觸的那一面，至於第一印刷電路基板2 1單面的相對另 一面，其不屬於本發明方法1 0的重點所在。在步驟（1 0 3 ) 中，本發明可以利用印刷電路板製程，在第一印刷電路 基板21的單面上形成陽極集電線路211 ，其實施的具體手 段係乃先在陽極集電線路2 1 1所屬的區域鑽孔，這若干的 孔洞2 1 7可以讓陽極燃料通過而流入至燃料電池單元 2 3 a ，接著，例如利用塗佈、印刷、貼合、電鍍增層等等 製程手段，將導電膠、導電膠帶、金屬薄層等導電材料 形成於第一印刷電路基板2 1上或利用蝕刻基板2 1上金屬 等製程手段而製造出陽極集電線路2 1 1 ，因此如果採以金 屬做為陽極集電線路2 1 1的實施方式，金屬材質例如可以 是銅金屬、或是其它金屬。本發明在一印刷電路基板21 的單面上形成陽極集電線路2 1 1所採用的手段，其並不以 上述所揭露的内文為揭限，凡熟悉該項技藝人士可以利 用相關製程手段，凡此等效差異係皆屬於本發明的範疇 以内。 步驟（1 0 5 )是利用印刷電路板製程，在接觸各個燃料 電池單元2 3 a陰極的第二印刷電路基板2 5的單面上形成陰 極集電線路2 5 1 。請配合參見第二圖，本發明第二印刷電Step (103) is to use a printed circuit board process to form an anode current collecting line 2 1 1 on one side of the first printed circuit substrate 21 contacting the anode of each fuel cell unit 23a. Please refer to the second figure for reference. The single side of the first printed circuit board 21 of the present invention refers to the side that is in contact with the anode of each fuel cell unit 2 3 a. On the one hand, it is not the focus of the method 10 of the present invention. In step (103), the present invention can use a printed circuit board process to form an anode current collecting line 211 on one side of the first printed circuit substrate 21, and the specific method for implementing it is to firstly form the anode current collecting line 2 1 1 Drill holes in the area. These holes 2 1 7 allow anode fuel to pass through and flow into the fuel cell 2 3 a. Then, for example, using coating, printing, laminating, plating and other process methods, A conductive adhesive, a conductive tape, a thin metal layer and the like are formed on the first printed circuit board 21 or a process such as etching a metal on the substrate 21 is used to produce an anode current collecting line 2 1 1. Therefore, if a metal is used, As an embodiment of the anode current collecting line 2 1 1, the metal material may be, for example, copper metal or other metal. The method for forming the anode current collecting line 2 1 1 on one side of the printed circuit board 21 in the present invention is not limited to the above-disclosed content. Those skilled in the art can use relevant process means All such equivalent differences are within the scope of the present invention. Step (105) is to use a printed circuit board process to form a negative electrode current collecting line 2 5 1 on one side of the second printed circuit substrate 25 contacting the cathode of each fuel cell unit 2 3 a. Please refer to the second figure for cooperation.

第8頁 200534527 極 陰 a 3 2 元 單 池 電 料 燃 個 各 與 指 是 就 乃 面 單 5)的 /(\ 5 明 2 說板 |基 五路 另05 對(1 相驟 的步 面在 單〇 5在 2 ^ 板所 基¾ 路重 電的 刷10 印法 二方 第明 於發 至本 ，於 面 一不 那其 的， 觸面 接一 同 如 用 採 以 〇 可1 明25 發路 本線 ，電 中集 孔 ίι 同 極 陰 成 形 來 段 手 的Page 8 200534527 Very Yin a 3 2 yuan single cell electric material burns each means refers to the face 5) / (\ 5 Ming 2 say board | Ji Wu Road another 05 pairs (1 phase step in the Single 〇5 on the 2 ^ board base ¾ road heavy electric brush 10 printing method two parties first to send to the present, on the face of the other is not the case, the contact is used together if you can use 0 to 1 25 to send the main line, electricity CIMC Holes

入 流 而 過 通 氣 空 讓 > > 3 了 ο 1為 /(\ 驟是 步57於S ,κιχ 驟 步 成 完 於 置 3 2 層 質 解 ^^ ο a將 3 2是 元} 与ο 池(1 電驟 料步 燃 至 第 的 :合 05整 (1層 驟積 步個 成整 完讓 與， 21起 2 板一 基合 路疊 電後 刷間 印之 一 5 2 第 的 板 基 路 刷 印 呈 ο 2 池 電 料 燃 式 ， 合 段疊 手片 一?7·1 具或 的刷 合印 疊以 \ly ， 7 ο 質 C介。 罾著人口 步纟壓 #為 # 進}進 〇 y中 X 構P0機 結(E壓 治脂熱 明樹用 三用利 的運並合以， 接可式 密乃方 形， 行術 進技 步程 一製 進的 以板 可路 明電 發刷 本印 ，用 時利 同， 的驟 3)步 10的 /(\ 3 驟1 2 步路 行線 進聯 在併 串 成 板： 基21 路路 電線 刷聯 印併 一串 第於 在由 的 11 3連 1 杜 2 ' 路氣 線電 聯此 併彼 串1 1 - < 造 製 來 上 面 單 路 線 電 集 極 陽 與 是 併〜 串3 2 由元 藉單 ，池 起電 一料 接燃 聯 極 陽 的 個對 各所 將合 以結 可且 乃並 計起 設一 路聯 線併 的串 3 以 11 2予 3 2 元 單 池 電 料 燃 個 各 將 夠 ο 能 此壓 藉應 3供 5的 2 路要 線需 聯所 併成 串聯 的併 應串 形， 行術 進技 步程 一製 進的 以板 可路 明電 發刷 本印 ’ 用 時利 同， 的驟 5)步 10的 (' 3 驟25 步路 行線 進聯 在併 串 成 板： 基25 路路 電線 刷聯 印併 二串 第於 在由 hBV 3連 5 陳 2 ' 路氣 線電 聯此 併彼 串1 5 造 製 來 上 面 單 的 路 線 電 集 極 陰 與 是Inflow through the ventilating air let > > 3 ο 1 is / (\ step is step 57 at S, κιχ step is completed at 3 2 layer solution ^^ ο a will be 3 2 is element} and ο pool (1 The electrical material is burned to the first: the combination of 05 and 1 (1 layer of the product is completed and transferred, 21 from 2 plates and a base are combined and one of the brushes is printed after the electricity is stacked.) The brush print is ο 2 cells of electric fuel type, and the combined hand piece is 7.1. The brush print is printed with \ ly, 7 ο quality C. 罾 着 人民 步 纟 压 # 为 # 进} 进〇y in the X structure P0 machine knot (E pressure fat Zhiming tree is combined with the three-purpose profit and use, and then can be combined with a square shape, the technical progress of the process of one step by the plate can Luming electric hair brush This seal, when used in the same way, Step 3) Step 10 / (\ 3 Step 1 2 Steps are connected in parallel to form a board: Base 21 roads are connected with a wire brush and printed in a string. 11 3 even 1 Du 2 'Road and gas lines are connected together and connected in series 1 1-< made from the above single-line electricity collection poles and is paralleled ~ string 3 2 borrowed from the yuan, the pool of electricity is connected to the fire Lian Jiyang For each of the institutes, a string of 3 lines and a line of 3 will be counted together. It will be enough to charge a single pool of electricity for 11 2 to 3 2 yuan. The two main lines that can borrow 3 supplies and 5 will be sufficient. Need to be connected in series and should be connected in series, the technical progress of the process is to use a plate of Luming electric hair brush to print this seal 'Use the same time, step 5) step 10 (' 3 step 25 Lines and lines are connected in parallel to form a board: 25 lines of wire brushes are printed and connected in parallel. The series is made by hBV 3 to 5 Chen 2 'Road and gas lines are connected to each other and made in series 1 5 above. The route of the electricity collector extremely Yin and is

第9頁 200534527 五、發明說明（6) 接一起，藉由串併聯線路2 5 3的線路設計，乃可以將各個 燃料電池單元2 3 a的陰極予以串併聯一起，配合串併聯線 路2 1 3 ，藉此能夠將各個燃料電池單元2 3 a串併聯成所需 要的供應電壓。 當完成上述的陽極集電線路2 1 1 、串併聯線路2 1 3、 陰極集電線路2 5 1 、以及串併聯線路2 5 3的製造後，本發 明在第一印刷電路基板2 1的單面以及第二印刷電路基板 2 5的單面上分別形成隔絕層2 1 5、2 5 5 ，在陽極集電線路 2 1 1 、陰極集電線路2 5 1以外的區域，利用隔絕層2 1 5、Page 9 200534527 V. Description of the invention (6) Connected together, through the design of the series-parallel line 2 5 3, the cathodes of each fuel cell unit 2 3 a can be connected in series and parallel to match the series-parallel line 2 1 3 In this way, each fuel cell unit 2 3 a can be connected in series and parallel to a required supply voltage. After the above-mentioned manufacturing of the anode current collecting line 2 1 1, the series-parallel line 2 1 3, the cathode current collecting line 2 5 1, and the series-parallel line 2 5 3 are completed, the present invention The insulating layers 2 1 5 and 2 5 5 are respectively formed on one surface of the second printed circuit board 25 and the single printed circuit board 25. The insulating layer 2 1 is used in areas other than the anode current collecting line 2 1 1 and the cathode current collecting line 2 5 1. 5.

2 5 5來與電解質層2 3隔離開來，如此達成僅由陽極集電線 路2 Π 、陰極集電線路2 1 5來接觸到各個燃料電池單元 2 3 a。實施隔絕層2 1 5、2 5 5的具體手段，本發明可以採用 塗佈綠漆方式來實現。2 5 5 is isolated from the electrolyte layer 2 3, so that only the anode current collecting line 2 Π and the cathode current collecting line 2 1 5 are in contact with each fuel cell unit 2 3 a. The specific means for implementing the insulation layers 2 1 5 and 2 5 5 can be implemented by applying green paint.

第三圖顯示本發明具有陽極集電線路與串併聯線路 的第一印刷電路基板，以及第四圖顯示本發明具有陰極 集電線路與串併聯線路的二印刷電路基板。本發明的第 一印刷電路基板2 1與第二印刷電路基板2 5的材質，例如 可以使用銅结印刷電路基板（CCL-Copper Clad L a m i n a t e )、軟性印刷電路板、或者是其它適合印刷電路 板製程的基板等，本發明可以各別製造如第三圖與第四 圖的印刷電路基板2 1 、2 5 ，最後再與電解質層2 3緊密接 合呈三明治結構的積層整合式燃料電池。 第五圖顯示本發明流道層與積層整合式燃料電池接 合一起的結構圖。經由本發明方法所製造完成的積層整The third figure shows a first printed circuit board having an anode current collecting line and a series-parallel line according to the present invention, and the fourth figure shows two printed circuit boards having a cathode current collecting line and a series-parallel line according to the present invention. The materials of the first printed circuit board 21 and the second printed circuit board 25 in the present invention can be, for example, copper-clad printed circuit boards (CCL-Copper Clad Laminate), flexible printed circuit boards, or other suitable printed circuit boards. In the manufacturing process of the substrate, etc., the present invention can separately manufacture the printed circuit substrates 2 1 and 2 5 as shown in the third and fourth figures, and finally, the laminated integrated fuel cell having a sandwich structure which is tightly bonded to the electrolyte layer 23. The fifth figure shows the structure of the flow channel layer and the laminated integrated fuel cell of the present invention. Laminated layers manufactured by the method of the present invention

第10頁 200534527 五、發明說明（7) 合式燃料電池2 0 ，其在與流道層3 0接合一起，流道層3 0 的内部區域3 0 a是用來容納陽極燃料，例如甲醇溶液等， 而内部區域3 0 a與陽極集電線路2 1 1的孔洞2 1 7是相通的， 因此陽極燃料能夠流入至各個的燃料電池單元2 3 a。 本發明上述的積層整合式燃料電池2 0 ，其具體範例可以 是積層整合式直接甲醇燃料電池。 雖然本發明已以較佳實施例揭露如上，然其並非用 以限定本發明，任何熟悉此項技藝者，在不脫離本發明 之精神和範圍内，當可做些許更動與潤飾，所作更動與 潤飾仍屬於本發明後附之申請專利範圍之内。 參Page 10 200534527 V. Description of the invention (7) The combined fuel cell 20 is joined with the flow channel layer 30, and the internal area 30 a of the flow channel layer 30 is used to contain the anode fuel, such as a methanol solution, etc. The internal area 30 a is in communication with the holes 2 1 7 of the anode current collecting line 2 1 1, so the anode fuel can flow into each fuel cell unit 2 3 a. A specific example of the above-mentioned laminated integrated fuel cell 20 of the present invention may be a laminated integrated direct methanol fuel cell. Although the present invention has been disclosed as above with preferred embodiments, it is not intended to limit the present invention. Anyone skilled in the art can make some modifications and retouches without departing from the spirit and scope of the present invention. Retouching is still within the scope of the patent application attached to the present invention. Participate

第11頁 200534527 圖式簡單說明 第一圖顯示本發明方法的流程圖。 第二圖顯示依據本發明方法製造的積層整合式燃料電池 之分解圖。 第三圖顯示本發明具有陽極集電線路與串併聯線路的第 一印刷電路基板。 第四圖顯示本發明具有陰極集電線路與串併聯線路的二 印刷電路基板。 第五圖顯示本發明流道層與積層整合式燃料電池接合一 起的結構圖。Page 11 200534527 Brief description of the drawings The first figure shows a flowchart of the method of the invention. The second figure shows an exploded view of a laminated integrated fuel cell manufactured according to the method of the present invention. The third figure shows a first printed circuit board having an anode current collecting line and a series-parallel line according to the present invention. The fourth figure shows two printed circuit boards having a cathode current collecting line and a series-parallel line according to the present invention. The fifth figure shows the structure of the flow channel layer and the laminated integrated fuel cell of the present invention joined together.

圖號編號說明 10 製造方法 2 0 積層整合式燃料電池 3 0 流道層 30a 内部區域 2 1 第一印刷電路基板 23 電解質層 23a 燃料電池單元 2 5 第二印刷電路基板 1 0 1 、1 0 3、1 0 5、1 0 7 步驟Description of drawing number 10 Manufacturing method 2 0 Laminated integrated fuel cell 3 0 Flow path layer 30a Inner area 2 1 First printed circuit board 23 Electrolyte layer 23a Fuel cell unit 2 5 Second printed circuit board 1 0 1, 1 0 3 , 1 0 5, 1 7 steps

211 陽極集電線路 2 13 串併聯線路 2 15 隔絕層 2 17 孔洞211 Anode collector line 2 13 Series-parallel line 2 15 Insulation layer 2 17 Hole

第12頁 200534527 圖式簡單說明 2 5 1 陰極集電線路 2 5 3 串併聯線路 2 5 5 隔絕層 2 5 7 孔洞Page 12 200534527 Brief description of the drawing 2 5 1 Cathode collector line 2 5 3 Series-parallel line 2 5 5 Insulation layer 2 5 7 Hole

第13頁Page 13

Claims (1)

200534527 六、申請專利範圍 1 . 一種積層整合式燃料電池的製造方法，包括下列步 驟： (A ). 提供一電解質層，其中該電解質層至少包含一 個以上的燃料電池單元； (B ). 利用印刷電路板製程，在接觸該各個燃料電池 單元陽極的第一印刷電路基板的單面上形成一陽極集電 線路； (C ). 利用印刷電路板製程，在接觸該各個燃料電池 單元陰極的第二印刷電路基板的單面上形成一陰極集電 線路； (D). 將該電解質層置於完成步驟（B)的第一印刷電路 基板與完成步驟（C )的第二印刷電路基板之間後疊合一起 呈緊密接合的三明治結構。 2 .如申請專利範圍第1項所述之製造方法，其中在該步驟 (B )進一步包括下列步驟： .在具有該陽極集電線路的單面上，形成一與該陽極 集電線路電氣性連接的串併聯線路。 3 .如申請專利範圍第1項所述之製造方法，其中在該步驟 (C )進一步包括下列步驟： .在具有該陰極集電線路的單面上，形成一與該陰極 集電線路電氣性連接的串併聯線路。 4 ·如申請專利範圍第1項所述之製造方法，其中在該第一 印刷電路基板，係可以選自一銅箔印刷電路基板、一軟 性印刷電路板、一適用於印刷電路板製程的電路基板。200534527 6. Scope of patent application 1. A method for manufacturing a laminated integrated fuel cell, including the following steps: (A). Provide an electrolyte layer, wherein the electrolyte layer contains at least one fuel cell unit; (B). Use printing A circuit board process, forming an anode current collecting circuit on one side of a first printed circuit substrate that contacts the anode of each fuel cell unit; (C). Using a printed circuit board process, a second circuit that contacts the cathode of each fuel cell unit A cathode current collecting circuit is formed on one side of the printed circuit substrate; (D). The electrolyte layer is placed between the first printed circuit substrate that completes step (B) and the second printed circuit substrate that completes step (C). Folded together to form a tight-fitting sandwich structure. 2. The manufacturing method according to item 1 of the scope of patent application, wherein the step (B) further includes the following steps: On one side of the anode current collecting line, forming an electrical property with the anode current collecting line Connected series and parallel lines. 3. The manufacturing method according to item 1 of the scope of patent application, wherein the step (C) further includes the following steps: On one side of the cathode current collecting line, forming an electrical property with the cathode current collecting line Connected series and parallel lines. 4 · The manufacturing method according to item 1 of the scope of patent application, wherein the first printed circuit board is selected from a copper foil printed circuit board, a flexible printed circuit board, and a circuit suitable for a printed circuit board process. Substrate. 第14頁 200534527 第 該 在 中 其 法 方 造 製 之 述 所 項 第 圍 範 利 圍專 範請 利 專申 膏 =口 ο 申士 、 · 六5 軟。 一板 、基 板路 基電 路的 電程 刷製 印板 猪路 銅電 一刷 自印 選於 以用 可適 係一 > e 板板 基路 路電 電刷 刷印 印性 法 方 造 製 之 述 所 項 整 層 積 該 中 其 池 電 料 燃 醇 甲 接 直 式 合 整 層 積 第一 圍係 範， 利池 專電 請料 申燃 D UVN •合 6 y 單 池 料 燃 的 上 :以 括個 包一 ，含 池包 電少 料至 燃係 式， 合層 整質 層解 積電 種一 一 元 的第上 路該面 線在單 電成的 集形極 極係陽 陽路元 有線單 具電池 一集電 極料 陽燃 第 印 該個 中各 其該 ，觸 板接 基板 路基 電路 刷電 印刷 該個 中各 其該 ，觸 板接 基板 路基 電路 刷電 印刷 二印 第二 的第 路該 線在 電成 集形 極係 陰路 有線 具電 一集 極 陰 二電 第料 該燃 與式 板合 基整 路層 電積 刷該 印使 一 J ;第起 上該一 面於合 單置疊 的係後 極，間 陰層之 元質板 單解基 池電路 電該電 料中刷 燃其印 其 池 t&ioD 料 燃 式 合 整 層 積 之 述 構所 结 、項 厶口 、> 7 明第 三圍 的範 合利 接專 密請 緊申 呈如 也 · 、、/ 8 電集 集極 極陽 陽該 該有 與具 一在 :成 括形 包係 步， 一路 進線 板聯 基併 路串 電的 刷接 印連 一性 第氣 該電 在路 中線 其 池 電 料 燃 式 合 整 層 積 之 述 所 項 7 第 。圍 面利 單專 的請 路申 線如 電· 9 電集 集極 極陰 陰該 該有 與具 一在 :成 括形 包係 步， 一路 進線 板聯 基併 路串 刷接 印連 二性 第氣 該電 在路 中線Page 14 200534527 Articles made in the legal system of the Chinese government should be covered in the following paragraphs: Fan Li, Zhuan Li, Zhuan Shuang, Gao Sheng = 口 Shen Shi, · 6 5 Soft. One-board, substrate-based roadbed circuit for electric circuit board printing board pig road copper electric one-brush self-printing is selected by the method made by the applicable system> e board board road road electric brush brush printing printing method The entire layer is laminated, the first battery of the battery is directly connected to the whole layer, and the Li Chi special electricity is requested to apply for D UVN. • 6 y Single battery is burned: enclosed in a package First, the battery pack contains electricity to the fuel system type, and the integrated layer deconsolidates the electricity type. The first line is the first line. The surface line is in the form of a single pole. The Yangyang Road line is a single battery. The electrode material is flammable, the first printed one is printed, the touch plate is connected to the substrate roadbed circuit, and the printed circuit is printed, the touched plate is connected to the substrate roadbed circuit, and the second printing is printed. The set pole system is a Yin Road cable with electricity. The first pole is cathode and the second electricity is the material. The combustor plate is integrated with the entire layer of the electric layer to brush the seal so that the J is on the first side. Elementary plate of the mesoderm Electricity, electricity, electricity, electricity, electricity, electricity, electricity, electricity, electricity, electricity, etc. In the third area, Fan Heli, please contact us for details. 、, / 8 Electricity collector pole pole Yangyang deserves to be connected with the following: forming a package, stepping all the way into the line board, connecting the base line and connecting the electricity in parallel to connect the electricity, the electricity on the middle of the road It is described in item 7 of its battery-fired integrated lamination. The Lushen line for enclosing a single line of electricity, such as electricity · 9 electricity collectors, the poles of the yin and yin should have one with the following: forming a package, stepping all the way into the board, paralleling the lines, and then printing the two sexes. Qi this electricity in the middle of the road 第15頁 Λ 200534527 六、申請專利範圍 電線路的單面上。 1 〇 .如申請專利範圍第7項所述之積層整合式燃料電池， 其中在該第一印刷電路基板，係可以選自一銅箔印刷電 路基板、一軟性印刷電路板、一適用於印刷電路板製程 的電路基板。 1 1 .如申請專利範圍第7項所述之積層整合式燃料電池， 其中在該第二印刷電路基板，係可以選自一銅箔印刷電 路基板、一軟性印刷電路板、一適用於印刷電路板製程 的電路基板。Page 15 Λ 200534527 VI. Scope of patent application Single side of electric circuit. 10. The laminated integrated fuel cell according to item 7 of the scope of the patent application, wherein the first printed circuit board can be selected from a copper foil printed circuit board, a flexible printed circuit board, and a printed circuit board. Circuit board for board process. 1 1. The laminated integrated fuel cell according to item 7 in the scope of the patent application, wherein the second printed circuit board can be selected from a copper foil printed circuit board, a flexible printed circuit board, and a printed circuit board. Circuit board for board process. 1 2 .如申請專利範圍第7項所述之積層整合式燃料電池， 其中該積層整合式燃料電池，係一積層整合式直接甲醇 燃料電池。12. The laminated integrated fuel cell according to item 7 in the scope of the patent application, wherein the laminated integrated fuel cell is a laminated integrated direct methanol fuel cell. 第16頁Page 16
TW093109318A 2004-04-02 2004-04-02 Manufacturing method of packed integrated fuel cell and the fuel cell thereof TW200534527A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
TW093109318A TW200534527A (en) 2004-04-02 2004-04-02 Manufacturing method of packed integrated fuel cell and the fuel cell thereof
GB0504788A GB2412785A (en) 2004-04-02 2005-03-09 Method for manufacturing a layer lamination integrated fuel cell and the fuel cell itself
JP2005081875A JP2005294256A (en) 2004-04-02 2005-03-22 Stack matching type fuel cell and its manufacturing method
DE102005015020A DE102005015020A1 (en) 2004-04-02 2005-04-01 A method of manufacturing a layer-lamination integrated fuel cell and the fuel cell itself

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI385839B (en) * 2009-09-11 2013-02-11 Nec Energy Devices Ltd Stacked battery and method of manufacturing the same

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GB2506925A (en) * 2012-10-15 2014-04-16 Intelligent Energy Ltd A current collector for a fuel cell

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GB9814123D0 (en) * 1998-07-01 1998-08-26 British Gas Plc Electrochemical fuel cell
KR20050010779A (en) * 2002-05-09 2005-01-28 더 보드 오브 트러스티스 오브 더 리랜드 스탠포드 주니어 유니버시티 Improved fuel cell

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI385839B (en) * 2009-09-11 2013-02-11 Nec Energy Devices Ltd Stacked battery and method of manufacturing the same

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