TW200428138A

TW200428138A - Colored photosensitive resin composition

Info

Publication number: TW200428138A
Application number: TW093107245A
Authority: TW
Inventors: Koji Ichikawa
Original assignee: Sumitomo Chemical Co
Priority date: 2003-03-28
Filing date: 2004-03-18
Publication date: 2004-12-16
Also published as: KR101096829B1; TWI313397B; KR20040084839A; CN1550891A; CN1550891B

Abstract

A colored photosensitive resin composition comprises a coloring agent (A), a binder polymer (B), a photo-polymerization compound c, a photo-polymerization initiator (D), a solvent (E), and a surfactant (F), wherein a viscosity of the composition is from 3.0 mPa.S to 6.5 mPa.S at a temperature of 23 DEG C, and a contact angle at 0.2 sec. And 1 sec. After dropping 10 μL of the composition to a glass plate is from 10 DEG to 20 DEG. The colored photosensitive resin composition according to the present invention can provide a film with good flatness when applied to a paint-saving coater such as a slit coater.

Description

200428138 玖、發明說明【發明所屬之技術領域】本發明係有關著色感光性樹脂組成物。【先前技術】著色感光性樹脂組成物為含有著色劑之感光性樹脂組成物，可作爲形成濾色器之著色圖型之材料。關於將著色感光性樹脂組成物用於晶片等被塗布基板上而形成膜之方法，先前已知使用旋轉塗布器之方法。不過使用旋轉塗布器之方法中，因於lm四面等廣面積之玻璃基板4基板上難於形成均一之膜，故相繼開發出不需旋轉基板之刮刀塗布器等省液塗布器。最適合供先前旋轉塗布器用之組成物，先前已知例如包括著色劑、黏結劑聚合物、光聚合性化合物、光聚合起始劑、丙二醇-甲驗乙酸醋以及界面活性劑，黏度為 6.8mPa*s’且將1〇以！滴到玻璃基板上〇 2秒後之接觸角為 21·5之組成物（參照特開平8-171200 )，但當該組成物應用於刮刀塗布器（省液塗布器之一種）時，經由加熱等除去冷齊丨里顯著多於旋轉塗布器者，因從層内部除去溶劑，故出現形成之膜之平坦性不充分之問題。【發明内容】 ^本發明之目的係提供一種著色感光性樹脂組成物，該著色感光性樹脂組成物可形成平坦性良好之膜。本發明者，經過深入研究結果，發現黏度以及接觸角、矿圍之著色感光性樹脂組成物應用於刮刀塗布器等省 315613 5 200428138 液塗布器時，可形成平坦性良好之膜。亦即’本發明係提供以下之[1 ]至[7]。 Π] —種著色感光性樹脂組成物，係包括著色劑（A )、黏結劑聚合物（B )、光聚合性化合物（c)、光聚合起始劑（D)、洛劑（E)以及界面活性劑（F)，該組成物在231：之黏度為 3.0mPa.s以上65mPa，s以下，且將該組成物1〇以i滴到玻璃基板上0.2秒後與1秒後之接觸角皆為ι〇β以上2〇。以200428138 发明. Description of the invention [Technical field to which the invention belongs] The present invention relates to a colored photosensitive resin composition. [Prior art] A colored photosensitive resin composition is a photosensitive resin composition containing a colorant, and can be used as a material for forming a coloring pattern of a color filter. As a method for forming a film by using a colored photosensitive resin composition on a coated substrate such as a wafer, a method using a spin coater has been conventionally known. However, in the method using a spin coater, since it is difficult to form a uniform film on a glass substrate 4 substrate having a wide area such as lm four sides, a liquid-saving coater such as a blade coater that does not need to rotate the substrate has been successively developed. Compositions most suitable for previous spin coaters, previously known to include, for example, colorants, binder polymers, photopolymerizable compounds, photopolymerization initiators, propylene glycol-methyl acetate and surfactants, with a viscosity of 6.8 mPa * s' and will start with 10! A composition with a contact angle of 21.5 after dripping onto a glass substrate (refer to JP-A-8-171200), but when the composition is applied to a doctor blade applicator (a liquid-saving applicator), it is heated Those who removed significantly more cold spinners than the spin coater removed the solvent from the inside of the layer, so that the flatness of the formed film was insufficient. SUMMARY OF THE INVENTION The object of the present invention is to provide a colored photosensitive resin composition, which can form a film with good flatness. As a result of in-depth research, the present inventor found that when the photosensitive resin composition with viscosity, contact angle, and color of the mine is applied to a squeegee coater and other provincial 315613 5 200428138 liquid coaters, a film with good flatness can be formed. That is, the present invention provides the following [1] to [7]. Π] — a coloring photosensitive resin composition, including a colorant (A), a binder polymer (B), a photopolymerizable compound (c), a photopolymerization initiator (D), a lotion (E), and Surfactant (F), the viscosity of this composition at 231: 3.0 mPa.s or more and 65 mPa, s or less, and the contact angle of the composition 10 drops i to the glass substrate after 0.2 seconds and 1 second Both are ι〇β and above 20. To

下。 []如[1 ]揭示之著色感光性樹脂組成物，其中溶劑（Ε)含有丙二醇-甲醚乙酸醋與3·乙氧基丙酸乙醋，著色感光性樹脂組成物中之溶劑（Ε)之含量為7〇質量％以上％質量％以下，界面活性劑（F)係選自由矽酮系界面活氟活性_及具有，原一系界面活性劑所組= 之至少1種，著色感光性樹脂組成物中之界面活性劑（F) 之含量為0.001質量％以上0·2質量％以下。 [3]黏結劑聚合物⑻之酸價為5〇以上15〇以下，黏結劑聚合物⑻之聚苯乙烯換算重量平均分子量為5, _ :5〇, 〇〇〇,著色感光性樹脂組成物之固體成分中之黏結 Μ聚合物（Β)之含量為15質量％至26質量。乂。至[3]揭示之任意之著色感光性樹脂組成物刀塗佈器用。項之著色感光性樹脂 [5] —種圖型，係使用[丨]至[4]之任— 組成物而形成者。 [6] 一種濾色器，係含有[5]之圖型者 315613 6 200428138 [7] —種液晶顯示裝置，係具備[6]之濾色器者。【實施方式】本發明之著色感光性樹脂組成物為包括著色劑（A )、黏結劑聚合物（B )、光聚合性化合物（C)、光聚合起始劑 (D)、溶劑（E)以及界面活性劑（F)，該組成物在23 °C之黏度為3.0mPa.s以上6.5mPaw以下，且將該組成物1滴到玻璃基板上0 · 2秒後與1秒後之接觸角皆為1 〇。以上2 〇。以下。著色感光性樹脂組成物之黏度係使用黏度計（如， VISCOMETER RE120L SYSTEM(東機產業（公司）製造等 )，在一定之液溫（通常23X：)下，將裝置之轉子之旋轉速度保持一定（通常為5 Orpm )而測定。本發明之著色感光性樹脂組成物之黏度，當使用前述裝置在液溫23艽、旋轉速度50rpm下測定時，為3_〇mPa.s以上6.5mPa.s以下，較佳為3.1mPa.s以上5.5mPa.s以下，更佳為3.2mPa.s以上5 .OmPa.s以下。若黏度為3 .〇mPa*s以上6.5mPa,s以下，在基板上塗布著色感光性樹脂組成物時之擴展性良好，故較佳。前述之接觸角，係藉由在玻璃基板（較佳為清淨之玻璃基板）上滴著色感光性樹脂組成物丨〇 # 1，於滴下〇.2 秒後與1秒後使用接觸角測定裝置（Dgd Fast/60 Contact Angle Meter(GBX公司製造）測定接觸角而得。滴下〇.2秒後與1秒後之接觸角需皆為丨〇。以上2〇。以下，較佳為】3 以上19以下。若接觸角為1 〇。以上20。以下，由於平 7 315613 200428138 坦性良好，可形成無斑點之著色感光性樹脂組成物層，故 “較佳。尤其，適合用於到刀塗布器等省液塗布器。使用於接觸角之測定之基板例如為用於形成滤色器之 * 玻璃基板，較佳為使用清淨之玻璃基板。玻璃基板，可使用例如Dow_c〇rning公司製造之#丄737 等。若想清淨玻璃基板，可採用例如將玻璃基板在丙酮等 Φ 溶劑中藉由超音波洗滌除去雜質等之方法等。在本發明中使用之著色劑（A)可為有機顏料及無機顔料中之任一種。其中，從耐熱性及顯色性優異之角度觀之’以有機顏料為較佳。前述之有機顏料以及無機顏料例如為在顏色索引 Color Index ( The s〇ciety 〇fDyers and c〇1〇uHsts 出版）中被~類為顏料（Pigment )之化合物等。具體而言，C.I.顏料黃-1、C.I.顏料黃-3、C.I.顏料黃_ 鲁 12、C.I.顏料黃_13、c !顏料黃_14、c τ顏料黃_15、匸工顏料黃-16、C.L顏料黃47、^•顏料顏料黃_24、 C.I.顏料黃-31、C.I.顏料黃-53、C.I.顔料黃_83、CI顏料黃-86、C.I·顏料黃_93、‘顏料黃_94、c :顏料黃]〇9、 c.i·顏料黃-110 ' C I•顏料黃_117、c〗顏料黃·i25、c工顏料黃_128、C.I.顏料黃-137、C.I.顏料黃-138、C.I.顏料黃_ 139、C.I·顏料黃_147、C I顏料黃·148、c〗顏料黃_15〇、 C.I.顏料黃-153、C I顏料黃_154、C I顏料黃_166、c丄顏料黃-173、（：.1.顏料黃_194、匚.1.顏料黃-214等之黃色顏料； 315613 8 ^υυ428138 C.I.顏料撥under. [] The colored photosensitive resin composition as disclosed in [1], in which the solvent (E) contains propylene glycol-methyl ether acetate and 3.ethoxypropionate, and the solvent (E) in the colored photosensitive resin composition The content is 70% by mass or more and %% by mass or less. The surfactant (F) is at least one selected from the group consisting of silicone-based interfacial active fluorine activity, and has, the original series of surfactants = color sensitivity. The content of the surfactant (F) in the resin composition is 0.001% by mass or more and 0.2% by mass or less. [3] The acid value of the binder polymer ⑻ is 50 or more and 150 or less, and the polystyrene equivalent weight average molecular weight of the binder polymer is 5, :: 50,000, the colored photosensitive resin composition. The content of the sticky M polymer (B) in the solid content is 15% by mass to 26% by mass. Alas. Any of the colored photosensitive resin compositions disclosed in [3] to a knife coater. The colored photosensitive resin of item [5] — a kind of pattern, which is formed by using any of [丨] to [4]-a composition. [6] A color filter, which contains the pattern of [5] 315613 6 200428138 [7] A liquid crystal display device, which has the color filter of [6]. [Embodiment] The colored photosensitive resin composition of the present invention includes a colorant (A), a binder polymer (B), a photopolymerizable compound (C), a photopolymerization initiator (D), and a solvent (E). And surfactant (F), the viscosity of the composition at 23 ° C is 3.0 mPa.s or more and 6.5 mPaw or less, and the composition is dropped onto the glass substrate at a contact angle of 0.2 seconds and 1 second Both are 1 〇. Above 2 〇. the following. The viscosity of the colored photosensitive resin composition is determined by using a viscometer (eg, VISCOMETER RE120L SYSTEM (manufactured by Toki Sangyo Co., Ltd.), etc.) at a certain liquid temperature (usually 23X :) to keep the rotation speed of the rotor of the device constant (Usually 5 Orpm). The viscosity of the coloring photosensitive resin composition of the present invention is 3-5 mPa.s or more and 6.5 mPa.s or more when measured at a liquid temperature of 23 ° C and a rotation speed of 50 rpm using the aforementioned device. Below, preferably 3.1 mPa.s or more and 5.5 mPa.s or less, more preferably 3.2 mPa.s or more and 5.0 mPa.s or less. If the viscosity is 3.0 mPa * s or more and 6.5 mPa, s or less, the substrate is on the substrate When the colored photosensitive resin composition is applied, the spreadability is good, so it is preferable. The aforementioned contact angle is obtained by dripping the colored photosensitive resin composition on a glass substrate (preferably a clean glass substrate). Obtained by measuring the contact angle using a contact angle measuring device (Dgd Fast / 60 Contact Angle Meter (manufactured by GBX) after 0.2 seconds and 1 second after dropping. The contact angles after 0.2 seconds and after 1 second are required. It is 丨〇. The above is 20. The following, preferably, is 3 or more and 19 or less. If the contact angle is 1 0. Above 20. Below, since flat 7 315613 200428138 has good frankness and can form a spotless colored photosensitive resin composition layer, it is "preferable. Especially, it is suitable for use in knife applicators, etc. Liquid-saving coating device. The substrate used for measuring the contact angle is, for example, a * glass substrate for forming a color filter, preferably a clean glass substrate. For the glass substrate, # 丄 737 manufactured by Dow_corning Company can be used, for example. If you want to clean the glass substrate, you can use, for example, a method of removing the impurities by ultrasonic washing in a Φ solvent such as acetone, etc. The coloring agent (A) used in the present invention may be an organic pigment or an inorganic pigment. Among them, organic pigments are preferred from the standpoint of excellent heat resistance and color rendering properties. The aforementioned organic pigments and inorganic pigments are, for example, in the Color Index (The Society 〇fDyers and c). 〇1〇Hsts (published) in the category of pigments (Pigment), etc. Specifically, CI Pigment Yellow-1, CI Pigment Yellow-3, CI Pigment Yellow_ Lu 12, CI Pigment Yellow_ 13, c! Pigment Yellow _14, c τ Pigment Yellow _15, Masonry Pigment Yellow-16, CL Pigment Yellow 47, ^ • Pigment Pigment Yellow_24, CI Pigment Yellow-31, CI Pigment Yellow-53, CI Pigment Yellow_83, CI Pigment Yellow-86, CI · Pigment Yellow_93, 'Pigment Yellow_94, c: Pigment Yellow] 09, Ci · Pigment Yellow-110' CI · Pigment Yellow_117, c〗 Pigment Yellow · i25, c pigment yellow_128, CI pigment yellow-137, CI pigment yellow-138, CI pigment yellow_139, CI · pigment yellow_147, CI pigment yellow · 148, c〗 Pigment yellow_15〇, CI pigment Yellow-153, CI Pigment Yellow_154, CI Pigment Yellow_166, C 丄 Pigment Yellow-173, (: .1.Pigment Yellow_194, 匚 .1.Pigment Yellow-214 and other yellow pigments; 315613 8 ^ υυ428138 CI pigment dial

38、C.I.顏料橙：=31、CJ.顏料撥36、C.L顏料撥顏料橙51、C !結丄顏枓橙42、C.1·顏料橙43、C.L C丄顏料橙64、.^+撥Μ」·顏料撥WC.1.顏料橙6卜 73等之撥色_.;顏料撥65、CJ.顏料橙71心.顔料撥 C.I.顏料紅 9、Γ T 122、 C·1.顏料紅97、匚丄顏料紅l〇5、C丄顏料紅 C L顏料紅123、C.I.顏料紅144、 C-I.顏料紅149、r τ紅丨丨 c丄顏料紅176、c..f 66、CJ.顏料紅168、料紅192、CI_T顏料紅177、^.顏料紅180、c丄顏 (^顏料么-” ⑽^丄顏料紅以^匚丄顏料紅以卜 .〜枓、、I 224、CJ.顏料紅242 料紅264、C ][轺把，顋枓紅254、C.I.顏 L·1·顏枓紅265等之紅色顏料； C.I·顏料藍-15、ρ τ 丨 # .1.顏料藍 _15:3、C.I.顏料藍 _15:4、Γτ 7；-15：6-^«6〇^μ,Ιμ,4；] ^1· 顏料紫19、。丄顏料紫23、CI顏料紫 .通料兔32、CJ.顏料紫36、C.I.顏料紫38等颅料紫色顏料； J丁寸系Μ等之顏 C‘I.顏料綠7、c ί鈕女L k .·顏枓綠36等之綠色顏料； C.I.顏料棕23、C丄顏料棕25等之棕色顏料；] C.1.顏料黑1、C.1.顏料黑7等之黑色顏料；等。 °亥等中，較好使用由C·1.顏料黃-138、C.I.顏料黃 139、C.1·顏料黃]50、C.1·顏料紅-177、C.I.顏料紅，9、 C.I.顏料紅_254、c丄顏料紫·& c丄顏料藍七·· 6以及 315613 9 200428138 C.1.顏料綠36中選擇之至少一種顏料。 :等之有機顏料以及無機顏料亦可分可混合2種以上使用。 71 例如’若要形成紅色像素，較 IV « ^ 权野3有C.I.顏料紅_209 乂及C丄顏料黃]39,若要形成綠色像素，較好顏料綠36以及C.I.顏料黃-150以及c J g · i 久ι·ι·顏枓黃138選擇之38. CI Pigment Orange: = 31, CJ. Pigment Dial 36, CL Pigment Dial Pigment Orange 51, C! Cyan Yaki Orange 42, C.1 · Pigment Orange 43, CL C Pigment Orange 64,. ^ + Dial Μ ″ · Pigment dial WC.1. Pigment orange 6 and 73, etc .; Pigment dial 65, CJ. Pigment orange 71 heart. Pigment dial CI Pigment Red 9, Γ T 122, C · 1. Pigment Red 97匚丄 Pigment Red 105, C 丄 Pigment Red CL Pigment Red 123, CI Pigment Red 144, CI. Pigment Red 149, r τ Red 丨丨 C 丄 Pigment Red 176, c .. f 66, CJ. Pigment Red 168, Material Red 192, CI_T Pigment Red 177, ^. Pigment Red 180, c 丄 yan (^ Pigment-"⑽ ^ 丄 Pigment Red to ^ 匚丄 Pigment Red to Bu. ~ 枓 ,, I 224, CJ. Pigment Red 242, Red 264, C] [Red handle, Red 254, CI Yan L · 1, Yan Yan 265 and other red pigments; CI · Pigment Blue-15, ρ τ 丨 # .1. Pigment Blue _15: 3 , CI Pigment Blue_15: 4, Γτ 7; -15: 6-^ «6〇 ^ μ, Ιμ, 4;] ^ 1 · Pigment Violet 19, 丄 Pigment Pigment Violet 23, CI Pigment Violet. Feeding Rabbit 32 , CJ. Pigment Violet 36, CI Pigment Violet 38, and other skull purple pigments; J Ding C, M, and other colors C'I. Pigment Green 7, c c button female L k. · Yan Li Green 36 and other green colors Brown pigments such as CI Pigment Brown 23, C 丄 Pigment Brown 25, etc.]] Black pigments such as C.1. Pigment Black 1, C.1. Pigment Black 7, etc .; etc. Among C · 1.Pigment Yellow-138, CI Pigment Yellow 139, C.1 · Pigment Yellow] 50, C.1 · Pigment Red-177, CI Pigment Red, 9, CI Pigment Red_254, C 丄 Pigment Purple · & c 丄 Pigment Blue VII ·· 6 and 315613 9 200428138 C.1. Pigment Green 36 is at least one pigment. Organic pigments and inorganic pigments can also be used in combination of two or more types. 71 For example, 'If you want to form Red pixels, compared to IV «^ Quanye 3 has CI Pigment Red _209 乂 and C 丄 Pigment Yellow] 39, to form green pixels, better pigment green 36 and CI Pigment Yellow-150 and c J g · i · Ι · Yan Yanhuang 138 choose

至>、-種’若要形成藍色像素，較好含有.顏料藍七： .6。前述之顏料根據所需可實施以下處理，如樹脂處理，使用弓I入酸性基或驗性基之顏料衍生物等之表面處理經由高分子化合物等顏料表面之接枝聚合處理，經由硫酸微粒化法等之微粒化處理，或經由除去雜質之有機溶劑、水等之洗淨處理，經由離子交換法等之離子性雜質之除去處理等。前述之顏料之使用量為以著色感光性樹脂組成物之固體成分為100質量份計，通常為25質量份以上60質量份 L較佳為27質量份以上55質量份以下’更佳為30 貝量伤以上50質量份以下。顏料之含量若為25質量份以上貝量伤以下，作爲濾色器時之色濃度充分，且因組成物中可含有必要量之黏結劑聚合物，故可形成強度充分之圖型，故較佳。作爲著色劑（A )使用之顏料較佳為其粒徑均一者。使顏料之粒徑均一之方法如，將後述之（F )成分以外之界面活性劑作爲顏料分散劑而進行分散處理之方法等，由 10 315613 200428138 此方法可得顏料在溶液中均—地分散之顏料分散液。前述顏料分散劑例舉如，陽離子系、陰離子系、非離子系等界面活性㈣，彼等可分別單獨使用，亦可將2種以上混合使用。顏料分散劑之使用量，相對於每丨質量份著色劑，通常為丄質量份以下，較佳為〇·〇5質量份以上〇 5質量份以下4述顏料分散劑之使用量，若相對於每丨質量份著色劑，為1質量份以下，將可得均一粒徑之顏料，故較佳。在本發明使用之黏結劑聚合物（B)例舉如，丙烯酸系共聚物。丙烯酸系纟聚物例如為可與含幾基單體共聚之其他單體與含鲮基單體之共聚合物等。含竣基單體例如，不飽和單賴、不飽和二叛酸、不飽和多元緩酸等分子中含有至少基之不飽和缓酸。在此，不飽和單缓酸例舉如，丙稀酸、甲基丙稀酸、巴丑酸、α-氣丙烯酸、肉桂酸等。不飽和二緩酸例舉如馬來酸、富馬酸、衣康酸、酸、中康酸等。不飽和多元叛酸亦可為其酸酐，具體而言，例舉 = 、檸康酸料。又，不飽和多域酸亦〜、早（2-甲基丙烯醯氧烷酯），例如，琥珀酸單（孓 :烯酿氧基乙醋）、號轴酸單（2_甲基丙婦酿氧基“”、本一甲酸單（2_丙烯醯氧基乙醋）、笨二甲烯醯氧基乙酯）等。 Τ "而 315613 11 200428138 ' 且，不飽和多元羧酸亦可為其兩末端二羧基聚合物之 “ 單（甲基）丙烯酸酯，例如，ω -羧基聚己内酯單丙烯酸酯、 ω-羧基聚己内酯單甲基丙烯酸酯等。該等之含羧基單體可，單獨使用’亦可將2種以上混合使用。前述之可與含羧基單體共聚之其他單體例如為笨乙烯、a-甲基苯乙烯、鄰-乙烯曱苯、間_乙烯曱苯、對-乙烯甲苯、對-氯苯乙烯、鄰-曱氧基苯乙烯、間_曱氧基笨乙烯、 • 對-甲氧基苯乙烯、鄰-乙烯苄基甲醚、間-乙烯苄基曱醚、對-乙烯苄基甲醚、鄰-乙烯苄基縮水甘油醚、間_乙烯苄基縮水甘油醚、對-乙烯苄基縮水甘油醚、茚等芳香族乙烯系化合物；丙烯酸甲酯、曱基丙烯酸曱酯、丙烯酸乙酯、甲基丙烯酸乙酯、丙烯酸正丙酯、曱基丙烯酸正丙酿、丙歸酸異丙酯、甲基丙烯酸異丙酯、丙烯酸正丁酯、甲基丙稀酸正丁自曰、丙浠酸異丁醋、曱基丙稀酸異丁酿、丙烯酸第一丁酯、曱基丙烯酸第二丁酯、丙稀酸第三丁酯、甲基丙 • 烯酸第三丁酯、丙烯酸2-羥基乙酯、曱基丙烯酸2_經基乙酯、丙烯酸2-羥基丙酯、甲基丙烯酸2-羥基丙酯、丙稀酸 3_沒基丙S旨、甲基丙細酸3 -經基丙g旨、丙稀酸2 -經基丁 g旨、甲基丙烯酸2 -羥基丁酯、丙烯酸3 -羥基丁酯、曱基丙稀酸 3 -經基丁酯、丙烯酸4 -經基丁酯、曱基丙婦酸4 -經基丁 g旨、丙烯酸烯丙酯、甲基丙烯酸烯丙酯、丙烯酸节基、甲基丙烯酸苄酯、丙烯酸環己酯、甲基丙烯酸環己酯、丙稀酸苯酯、甲基丙烯酸苯酯、丙烯酸2-甲氧基乙酯、曱基丙稀酸 2 -甲氧基乙酯、丙稀酸2 -苯氧基乙酯、甲基丙烯酸2_苯氧 12 315613 200428138 基乙酯、甲氧基二乙二醇丙烯酸酯、曱氧基二乙二酵甲基丙烯酸酯、曱氧基三乙二醇丙烯酸酯、甲氧基三乙二醇曱基丙烯酸酯、甲氧基丙二醇丙烯酸酯、甲氧基丙二醇甲基丙烯酸酯、曱氧基二丙二醇丙烯酸酯、曱氧基二丙二醇甲基丙烯酸酯、丙烯酸異冰片酯、甲基丙烯酸異冰片酯、丙烯酸聯環戊二烯酯（dicyclopentadienyl methcrylate)、甲基丙烯酸聯環戊二烯酯、丙烯酸2-羥基-3-苯氧基丙酯、甲基丙烯酸2-羥基-3-苯氧基丙酯、甘油單丙烯酸酯、甘油單甲基丙烯酸酯等不飽和羧酸酯類；丙烯酸2-胺基乙酯、曱基丙稀酸2 -胺基乙酯、丙稀酸2 -二曱胺基乙酯、曱基丙晞酸 2-二甲胺基乙酯、丙烯酸2-胺基丙酯、曱基丙烯酸2-胺基丙酯、丙烯酸2-二曱胺基丙酯、曱基丙烯酸2-二甲胺基丙酯、丙烯酸3 -胺基丙酯、曱基丙稀酸3 -胺基丙酯、丙烯酸 3 -二甲胺基丙酯、甲基丙稀酸3 -二曱胺基丙酯等不飽和叛酸胺基烷酯類；丙烯酸縮水甘油酯、甲基丙烯酸縮水甘油酯等不飽和羧酸縮水甘油酯類；乙酸乙烯酯、丙酸乙烯酯、酪酸乙烯酯、苯曱酸乙烯酯等羧酸乙烯酯類；乙烯基甲醚、乙烯基乙醚、烯丙基縮水甘油醚等不飽和醚類；丙烯腈、甲基丙烯腈、《 -氣丙烯腈、氰基化亞乙烯等氰基化亞乙婦化合物等，丙烯醯胺、曱基丙稀酿胺、α -氯丙晞醯胺、 Ν-2-羥基乙基丙烯醯胺、ν-2-羥基乙基曱基丙烯醯胺等不飽和醯胺類；馬來酸醯亞胺、Ν-苯基馬來醯亞胺、Ν-環己基馬來醯亞胺等不飽和醯亞胺類；1，3-丁二烯、異戊二稀、氯丁一烯荨脂肪族共輛二稀類；聚苯乙烯、聚丙稀酸甲基 13 315613 200428138 酉旨、聚甲基丙烯酸甲醋、聚丙稀酸正丁酉旨、聚甲基丙稀酸正丁，、聚發氧烧等聚合物分子鏈之末端上具有單丙稀酿基或單甲基丙烯醯基之巨單體類等。 =等單體可單獨使用，亦可2種以上混合使用。前述之共聚合物中含羧基單體單位之含量以莫耳百分率計’通常為1G至5G莫耳％、較佳為15至4{)莫耳％、To >, -species' To form blue pixels, it is preferable to contain .Pigment Blue Seven: .6. The aforementioned pigments can be subjected to the following treatments as required, such as resin treatment, surface treatment using pigment derivatives such as acid groups or test groups, etc., via graft polymerization treatment on the surface of pigments such as polymer compounds, and micronization by sulfuric acid Methods such as micronization, or organic solvents, water, etc. to remove impurities, and ionic impurities, such as ion exchange methods. The pigment is used in an amount of 100 parts by mass based on the solid content of the colored photosensitive resin composition, usually 25 parts by mass or more and 60 parts by mass, preferably 27 parts by mass or more and 55 parts by mass or less, more preferably 30 shells. Measure the injury above 50 parts by mass. If the content of the pigment is 25 parts by mass or more, the color concentration when used as a color filter is sufficient, and the composition may contain a necessary amount of a binder polymer, so that a pattern with sufficient strength can be formed. good. The pigment used as the colorant (A) is preferably one having a uniform particle size. A method for making the particle diameter of the pigment uniform is, for example, a method in which a surfactant other than the component (F) described later is used as a pigment dispersant to perform a dispersing treatment. From this method, 10 315613 200428138 can be obtained to uniformly disperse the pigment in the solution. Pigment dispersion. The pigment dispersant is exemplified by interface-active fluorenes such as cationic, anionic, and nonionic systems, and these can be used alone or in combination of two or more kinds. The amount of the pigment dispersant used is usually 丄 parts by mass or less, preferably from 0.05 parts by mass to 0.5 parts by mass per pigment part of the colorant. Each color part of the colorant is preferably 1 part by mass or less, and a pigment having a uniform particle size can be obtained, so it is preferable. The binder polymer (B) used in the present invention is exemplified by an acrylic copolymer. The acrylic fluorene polymer is, for example, a copolymer of other monomers copolymerizable with several monomers and a fluorene group-containing monomer. For example, unsaturated monomers containing unsaturated radicals, unsaturated dibasic acids, unsaturated polybasic acids, and the like containing unsaturated radicals have at least radicals in their molecules. Here, examples of the unsaturated monobasic acid include acrylic acid, methacrylic acid, acetic acid, α-gas acrylic acid, and cinnamic acid. Examples of unsaturated dibasic acids include maleic acid, fumaric acid, itaconic acid, acids, mesaconic acids, and the like. Unsaturated polybasic acid can also be its anhydride. Specifically, for example, =, citraconic acid. In addition, unsaturated polydomain acids are also available. Early (2-methacrylic acid oxyalkyl esters), for example, succinic acid mono (fluorene: ethyl alcohol ethoxylate), horne acid mono (2-methylpropyl acetic acid) Fermented oxygen "", Benzoic acid mono- (2-propenyloxyethyl acetate), Dibenzyloxyethyl) and the like. T " and 315613 11 200428138 ', and unsaturated polycarboxylic acids can also be "mono (meth) acrylates of dicarboxyl polymers at both ends, for example, ω-carboxy polycaprolactone monoacrylate, ω- Carboxyl polycaprolactone monomethacrylate, etc. These carboxyl-containing monomers may be used alone or in combination of two or more. The other monomers that can be copolymerized with the carboxyl-containing monomers are, for example, stupid ethylene. , A-methylstyrene, o-vinylbenzene, m-vinylbenzene, p-vinyltoluene, p-chlorostyrene, o-vinyloxystyrene, m-benzyloxystyrene, • p- Methoxystyrene, o-vinyl benzyl methyl ether, m-vinyl benzyl fluorenyl ether, p-vinyl benzyl methyl ether, o-vinyl benzyl glycidyl ether, m-vinyl benzyl glycidyl ether, p- Aromatic vinyl compounds such as vinyl benzyl glycidyl ether, indene, etc .; methyl acrylate, ethyl fluorenyl acrylate, ethyl acrylate, ethyl methacrylate, n-propyl acrylate, n-propyl acrylate, and propionic acid Isopropyl ester, isopropyl methacrylate, n-butyl acrylate, methyl propylene N-butyl acid, isobutyl propyl acetate, isobutyl isopropyl acrylate, first butyl acrylate, second butyl acrylate, third butyl acrylate, methacrylic acid Tert-butyl ester, 2-hydroxyethyl acrylate, 2-ethyl methacrylate, 2-hydroxypropyl acrylate, 2-hydroxypropyl methacrylate, 3-hydroxypropyl acrylate, methyl ester Acrylic acid 3-Acrylic acid, Acrylic acid 2- Acrylic acid, 2-Acrylic acid, 2-Hydroxybutyl methacrylate, Acrylic acid 3-Hydroxybutyl, Acetyl Acrylic acid 3-Acrylic acid 4-acrylic acid, 4-butyl methacrylic acid, 4-methylpropyl acetic acid, allyl acrylate, allyl acrylate, allyl methacrylate, benzyl acrylate, benzyl methacrylate, cyclohexyl acrylate, formazan Cyclohexyl acrylate, phenyl acrylate, phenyl methacrylate, 2-methoxyethyl acrylate, 2-methoxyethyl acrylate, 2-methoxyethyl acrylate, 2-phenoxyethyl acrylate , 2-phenoxy 12 methacrylate 12 315613 200428138 ethyl ester, methoxy diethylene glycol acrylate, methoxy diethylene glycol methacrylate, methoxy triethylene glycol acrylate, methyl Triethylene glycol fluorenyl acrylate, methoxy propylene glycol acrylate, methoxy propylene glycol methacrylate, methoxy dipropylene glycol acrylate, methoxy dipropylene glycol methacrylate, isobornyl acrylate, methyl Isobornyl acrylate, dicyclopentadienyl methcrylate, bicyclopentadienyl methacrylate, 2-hydroxy-3-phenoxypropyl acrylate, 2-hydroxy-3-methacrylate Unsaturated carboxylic acid esters such as phenoxypropyl, glycerol monoacrylate, glycerol monomethacrylate; 2-aminoethyl acrylate, fluorenyl acrylic acid 2-aminoethyl ester, acrylic acid 2- Dimethylaminoethyl, 2-dimethylaminoethyl propylpropionate, 2-aminopropyl acrylate, 2-aminopropyl acrylate, 2-diaminopropyl acrylate, fluorene 2-dimethylaminopropyl acrylate, 3-aminopropyl acrylate, 3-aminopropyl acrylic acid, 3-dimethylaminopropyl acrylate, 3-dimethyacrylic acid Unsaturated amino acid alkyl esters such as aminopropyl esters; glycidyl acrylate, glycidyl methacrylate, etc. Saturated carboxylic acid glycidyl esters; vinyl carboxylates such as vinyl acetate, vinyl propionate, vinyl caseinate, and vinyl phenylacetate; vinyl methyl ether, vinyl ether, allyl glycidyl ether, etc. Saturated ethers; acrylonitrile, methacrylonitrile, cyanoacrylic acid compounds such as acrylonitrile, cyanidene vinylene, etc., acrylamide, acrylamine, alpha-chloropropanidine Unsaturated amines such as amines, NH-2-hydroxyethylpropenamide, and ν-2-hydroxyethylpropenamide, etc .; imines, N-phenylmaleimide, N -Unsaturated hydrazones such as cyclohexylmaleimide; 1,3-butadiene, isoprene, chloroprene, etc .; aliphatic amines; polystyrene, polypropylene acrylic acid 13 315613 200428138 酉酉, polymethyl methacrylate, poly-n-butyl 酉, 正 -methyl methacrylate, poly-oxygen, and other polymer molecular chains at the end of the molecular chain with a mono-acrylic group or Macromonomers of monomethacryl fluorenyl and the like. = And other monomers can be used alone or in combination of two or more. The content of the carboxyl-containing monomer unit in the aforementioned copolymer is, in terms of mole percentage, generally 1G to 5G mole%, preferably 15 to 4 {) mole%,

更佳為25至40莫耳％。含羧基單體單位之含量若為1〇至 50莫耳％ ’在顯難巾之轉性良好，且顯料正確地形成圖型，故較佳。刖述之丙烯腈系共聚合物例舉如，（甲基）丙烯酸/(甲基1丙烯酸甲酯共聚合物、（甲基）丙烯酸/(甲基）丙烯酸卞酯共聚合物、（曱基）丙烯酸/(曱基）丙烯酸2_羥基乙S曰/(甲基）丙歸酸苄酯共聚合物、（甲基）丙烯酸/ (曱基）丙婦酸甲酯/聚苯乙烯巨單體共聚合物、（甲基）丙烯酸/ (甲基）丙烯酸甲酯/聚（甲基）丙烯酸甲酯巨單體共聚合物、（甲基）丙烯酸/ (甲基）丙烯酸苄酯/聚苯乙烯巨單體共聚合物、（甲基）丙烯酸/(曱基）丙烯酸苄酯/聚（甲基）丙稀甲酯巨單體共聚合物、（甲基）丙烯酸/(甲基）丙締酸2-經基乙酯/(甲基）丙烯酸苄酯/聚苯乙烯巨單體共聚合物、C甲基）丙烯酸/(曱基）丙烯酸2-羥基乙酯/(甲基）丙稀酸苄酯/聚（甲基）丙烯酸甲酯巨單體共聚合物、（甲基）内烯酸/苯乙烯/(甲基）丙烯酸苄酯/N-苯基馬來醯亞胺共聚合物、（甲基）丙烯酸/琥珀酸單.（2-丙烯醯氧基乙醋）/笨乙烯/(甲基）丙烯酸苄酯/N-苯基馬來醯亞胺共聚 14 315613 200428138 合物、（甲基）丙烯酸/琥珀酸單（2-丙烯醯氧基乙酯）/苯乙烯/(甲基）丙烯酸烯丙酯/N-苯基馬來醯亞胺共聚合物’ (甲基）丙烯酸/(曱基）丙烯酸苄酯/N_苯基馬來醯亞胺/ 苯乙稀/甘油單（甲基）丙烯酸酯共聚物等。且’（甲基）丙烯酸酯意味著丙稀酸酯或曱基丙烯酸醋。該等中較佳使用（甲基）丙烯酸/(甲基）丙烯酸苄酯共聚物、（甲基）丙烯酸/(甲基）丙烯苄酸酯/苯乙烯共聚物、（甲基）丙烯酸/(甲基）丙烤酸甲酯共聚物、（甲基）丙烯酸/(甲基）丙烯酸曱酯/苯乙烯共聚合物等。前述之黏結劑聚合物，其之聚苯乙烯換算重量平均分子篁（即換算成聚乙烯之重量平均分子量）通常為5，〇⑽至 50,000,較佳為 8,000 至 4G，则，更佳為 1G，_i 35 〇〇〇。黏結劑聚合物之分子量若為5，_至5〇，_，塗膜硬度提面’殘膜率亦冑’在未曝光部之顯影液中之溶解性良好，解像度提高，因此較佳。黏結劑聚合物之酸價通常為More preferably, it is 25 to 40 mol%. If the content of the carboxyl group-containing monomer unit is 10 to 50 mol%, it is preferable that the reversibility of the cloth is good, and the material is correctly formed into a pattern, so it is preferable. Examples of the acrylonitrile-based copolymers described herein include (meth) acrylic acid / (methyl 1 acrylate copolymer), (meth) acrylic acid / (meth) acrylic acid ester copolymer, and (fluorenyl) group. ) Acrylic acid / (fluorenyl) acrylic acid 2-hydroxyethyl sulphuric acid / (meth) benzyl propionate copolymer, (meth) acrylic acid / (fluorenyl) propionic acid methyl ester / polystyrene macromonomer Copolymer, (meth) acrylic acid / methyl (meth) acrylate / poly (meth) acrylate macromonomer copolymer, (meth) acrylic acid / benzyl (meth) acrylate / polystyrene Macromonomer copolymer, (meth) acrylic acid / (fluorenyl) benzyl acrylate / poly (meth) acrylic acid methyl ester macromonomer copolymer, (meth) acrylic acid / (meth) acrylic acid 2-Ethyl ethyl ester / benzyl (meth) acrylate / polystyrene macromonomer copolymer, C meth) acrylic acid / (fluorenyl) 2-hydroxyethyl acrylate / (meth) benzyl acrylic acid Ester / poly (meth) acrylate macromonomer copolymer, (meth) endenoic acid / styrene / benzyl (meth) acrylate / N-phenylmaleimide copolymer, ( (Meth) acrylic acid / succinic acid mono. (2-propenyloxyethyl acetate) / Styrene / (meth) acrylic acid benzyl ester / N-phenylmaleimide copolymerization 14 315613 200428138 Compound, (methyl ) Acrylic acid / succinic acid mono (2-propenyloxyethyl) / styrene / (meth) acrylic acid allyl / N-phenylmaleimide imine copolymers ((meth) acrylic acid / (曱Based) benzyl acrylate / N-phenylmaleimide / phenylene / glycerol mono (meth) acrylate copolymer, etc. And '(meth) acrylate means acrylic acid or methacrylic acid. Among these, (meth) acrylic acid / (meth) acrylic acid benzyl copolymer, (meth) acrylic acid / (meth) acrylic acid benzyl ester / styrene copolymer, and (meth) acrylic acid / (formaldehyde) are preferably used. (Meth) acrylic acid methyl ester copolymer, (meth) acrylic acid / (meth) acrylic acid methyl ester / styrene copolymer, etc. The aforementioned binder polymer has a polystyrene-equivalent weight-average molecular weight 篁 (ie, weight-average molecular weight converted to polyethylene) of usually 5,000 to 50,000, preferably 8,000 to 4G, and more preferably 1G. , _I 35 〇〇〇. If the molecular weight of the binder polymer is 5, _ to 50, _, the hardness of the coating film is improved, and the residual film rate is also high, and the solubility in the developing solution of the unexposed portion is good, and the resolution is improved, so it is preferable. The acid value of the binder polymer is usually

1 J U 卞人 Ί 土，〇 U 140,更佳為80至135。酸價若為5〇至15〇,在峨之溶解性提高’使未曝光部之溶解變易，又高靈敏度十使顯影時之曝光部之圊型殘留而提高殘膜率。在此，s 係測定中和黏結劑聚合物lg所需之氫氧化钟之而得之值，通常藉由使践氧化鈉水溶㈣定而求出。黏結劑聚合物於著色威光性妨尤11樹脂組成物之固體成；所占之質量百分率，通常為5皙县0/ 千逋*马5責量％以上26質量％以] 315613 15 200428138 較佳為1 〇質量％以上26質量％以下，更佳為丨5質量％以 — 上26質量％以下。含量若為5質量。/〇以上26質量％以下，因可形成圖型，或提高解像度以及殘膜率，因此較佳。 « 在本發明使用之光聚合性化合物（C )係可藉由光聚合起始劑以光照射後產生之活性自由基及酸等而聚合之化合物，例如，具有聚合性之碳碳不飽和鍵之化合物等。光聚合性化合物（C )較佳為3官能以上之多官能光 ^ 聚合性化合物。3官能以上之多官能之光聚合性化合物例如’季戊四醇四丙烯酸酯、季戊四醇四甲基丙烯酸酯、二季戊四醇五（丙烯酸酯）、二季戊四醇五（甲基丙烯酸酯）、二季戊四醇六（丙烯酸酯）、二季戊四醇六（甲基丙烯酸酯）等。光聚合性化合物（C )可分別單獨使用，亦可將2種以上此σ使用’其在著色感光性樹脂組成物中之含量，以質量百分率計，通常為5質量％以上90質量％以下，較佳為i 〇質量％以上80質量％以下，更佳為2〇質量％以上7〇質量乂下。其含量若為5質量％以上9 0質量％以下，硬化充分，殘膜率提高，對圖型揚底切（undeycut)且密著性良好，因此較佳。在本發明使用之光聚合起始劑（D)較佳為含有至少 —種乙醯苯系化合物者。乙酿苯系化合物例如為二乙氧基乙醯苯系化合物、2 甲基-2-嗎啉-‘基—卜（4_甲基噻吩基）丙酮、2_羥基甲基-1-本基丙_1_酮、二甲醇縮节酮、2_經基甲基[4 (2-羥基乙氧基）苯基]丙_卜酮、丨_羥基環己基笨酮、 315613 16 200428138 羥基-2-甲基-l-[4- ( 1-甲基乙烯）苯基]丙-1-酮之低聚物等。在該等中較佳使用2-羥基-2-甲基-1- ( 4-甲基噻吩基] 丙-1 -酮。又，關於光聚合起始劑（D )，亦可使用複數種乙醯苯系、乙醯苯系以外之光聚合起始劑之組合。乙醯苯系以外之光聚合起始劑例如，經由光照射產生活性自由基之自由基引發劑、增感劑、酸引發劑等。活性自由基引發劑例如為苯偶姻（benz〇in)系化合物、一本基_系化合物、硫代口山酮（thioxanthone)系化合物、三哄系化合物、2，4 ’ 6-三甲基苯甲醯基二苯基膦氧化物、2, 2’-雙（鄰-氯苯基）_4’4，，5，5，-四苯基-1，2，-雙味唑、10·丁基-2-氯吖啶酮、2_乙基蒽醌、苄基、9，1〇_菲醌 (9，10-phenanthrene qUinone)、樟腦醌（camph〇rquin〇ne)、笨基乙搭酸甲酯、雙（環戊二烯）鈦（titan〇cene)化合物等。苯偶姻系化合物例如為苯偶姻、苯偶姻甲醚、苯偶姻乙醚、本偶姻丙趟、苯偶姻丁趟等。一苯基酮系化合物例如為二苯基酮、鄰·苯甲醯基苯甲酸甲酯、4-苯基二苯基酮、4_苯甲醯基、，-甲基二苯基硫醚、3,3’’4’4，_四（第三丁基過氧幾基）二笨基酮、2, 4，6-三甲基二苯基酮等。硫代口山酮(thioxanthone、会人此η ,止 n〇ne)系化合物例如為2_異丙基硫代口山酮、4-異丙基硫代口山 m 2 , 4_—乙基硫代口山酮、2， 4-二氣硫代口山酮、1 _氣_4 与机4_丙氧基硫代口山酮等。三畊系化合物例如為 4_雙（三氣甲基）-6- (4·甲 315613 17 200428138 氧基苯基）-1 ’ 3，5_三畊、2 ’ 4-雙（三氯甲基）-6_ ( 4-甲氧基萘基）-1 ’ 3，5-三畊、2，4-雙（三氣甲基）-6-(4-甲氧基苯乙烯基）-1，3，5-三哄、2，4_雙（三氣甲基）-6-[2-〔5 -曱基吱喃-2-基〕乙烯基]-1，3，5-三哄、2，4-雙（三氯曱基）-6-[2-(呋喃-2-基）乙稀基]，3，5_三口井、 2 ’ 4-雙（三氯甲基）-6-[2- ( 4-二乙基胺基_2-甲基苯基）乙烯基]-1，3，5-三哄、2，4-雙（三氯甲基）-6_[2- (3， 4_ 一曱氧基苯基）乙稀基]-1，3，5 -三□井等。酸引發劑例如為4-羥基苯基二甲基鏑對-曱苯磺酸鹽、4-羥基笨基二曱基毓六氟銻酸鹽、4_乙醯氧基苯基二甲基疏對-甲苯石黃酸鹽、4-乙醯氧基笨基•甲基•苄基六氟銻酸鹽、三苯基锍對·甲苯磺酸鹽、三苯基毓六氟銻酸鹽、 —笨基碘鏽對曱苯磺酸鹽、二笨基碘鑌六氟銻酸鹽等鑌鹽類，硝基苄基甲苯磺酸鹽類，苯偶姻曱苯磺酸鹽類等。又’係活性自由基引發劑之上述之化合物中，有同時產生活性自由基及酸之化合物。如，三哄系光聚合起始劑亦可作爲酸引發劑使用。、光聚合起始劑（D )之含量，相對於黏結劑聚合物（B ) 以及光聚合性化合物（c )之合計量丨〇〇質量份，通常為〇· 1質量份以上20質量份以下，較佳為i質量份以上u 質量份以下。 θ、本發明起始劑（D)之含量若為0」重量份以上2〇重 1伤以下，將高敏感度化，使曝光時間縮短從而提高生産 !·生，且無解像度不良之現象，因此較佳。 315613 18 200428138 本發明之著色感光性樹脂紐成物亦可添加光聚合起始幻（G )。光聚合起始劑（G )通常與光聚合起始劑（D ) 組合使用，其可更加促進由光聚合起始劑（D )引發聚合開始之光聚合性化合物（c )之聚合。光聚合起始劑（G ) 例如為胺系化合物、烷氧基蒽系化合物、硫代口山酮系化合物等。、甲基二乙醇胺、三異丙、4-二曱基胺基苯甲酸乙胺系化合物例如為三乙醇胺醇胺、4-二曱基胺基苯甲酸甲顆 4· 一甲基胺基苯甲酸異戊酯、苯曱酸2二曱胺基乙酯 —甲胺基笨曱酸2-乙基己酯、N，N_二曱基對曱苯胺、4 酯 4-4 -雙（_甲基月安基）三苯基_ (通稱米氏_ michler，s ketone)、4, 4’-雙（二乙基胺基）二苯基酮、4, 4,_雙（乙基甲基胺基）二苯基酮等，其申較佳使用4,斗，_雙（二乙基胺基）二苯基酮。烷氧基蒽系化合物例如為9，丨〇_二甲氧基貧、2乙美 -9’ 1〇·二甲氧基蒽、9, 1〇_二乙氧基葱、2乙H / 二乙氧基蒽等。硫代口山酮系化合物例如為2_異丙基硫代口山酮、心異基硫代口山酿Ι、2，4· 一 ,其 _ ^ 一乙基硫代口山酮、2,4-二氯硫代口山醐、氣-4-丙氧基硫代口山_等。用或複數個組合使用。市售者，作爲市售之光 EAB-F」（保土榖化學工光聚合起始劑（D )可單獨使又，光聚合起始助劑（G)可使用聚合起始劑（G)例如，商品名「業（公司）製）等。 315613 19 200428138 在本發明之著色感光性樹脂組成物中，光聚合起始劑 “ （D)以及光聚合起始助劑（G)之組合有如，二乙氧基乙醯苯/4, 4，-雙（二乙基胺基）二苯基酮、2_甲基_2_嗎啉_ 4基-1-(4 -甲基嗟吩基）丙_ι·酮/4，雙（二甲基胺基）二苯基酮、2-羥基-2-曱基-1-苯基丙4 •酮/4，4, ·雙（二乙基胺基）二苯基酮、二甲醇縮苄酮/4，4，_雙（二乙基胺基）一笨基酮、2-羥基-2-甲基-l-[4- ( 2-羥基乙氧基）苯基]丙 • ·1_酮/4, 4’-雙（二乙基胺基）二苯基酮、1-羥基環己基苯酮/4，4 _雙（二乙基胺基）二苯基酮、2-羥基-2-甲基_ 1-[4-(1-曱基乙稀）苯基]丙^•酮之低聚物/4，4，_雙（二乙基胺基）二苯基酮、2-苄基·2_二甲基胺基_丨_ ( 4-嗎啉_ 4-基苯基）丁 _1_酮/4,4, _雙（二乙基胺基）二苯基酮之組合等’較佳為2-甲基-2-嗎琳_4_基-1- ( 4-甲基噻吩基）丙1酮/4，4 -雙（一乙基胺基）二苯基酮之組合。使用光聚合起始助劑（G)時，其使用量，相對於每1 鳙冑耳光聚合起始劑（D)，通常為1〇莫耳以下，較佳為〇〇1 莫耳以上5莫耳以下。在本發明中使用之溶劑（E )例如為醚類、芳香族烴類、酮類、醇類、酯類、醯胺類等。醚類例如為四氫呋喃、四氫吡喃、1，扣二噁烷、乙二醇一甲醚、乙二醇一乙醚、乙二醇一丙醚、乙二醇—丁鹎、二乙二醇一甲醚、二乙二醇一乙醚、二匕二酵一丁糙、二乙一醇二甲醚、二乙二醇二乙醚、二乙二醇二丙醚、二乙一醇一丁醚、丙二醇一曱醚乙酸酯、丙二醇〆乙醚乙酸酯、 20 315613 200428138 丙二醇一丙醚乙酸酯、 ^ 酸醋、乙酸乙爲… ^甲喊乙心、乙二酵乙醚乙土、酉曰、乙酸丁基卡必酯、丙二醇甲醚乙酸s曰、乙酸甲羞其虱基丁8曰、乙酸甲氧基戊醋、菌香醚、苯乙醚、甲基茴香醚等。芳香族煙類例如為苯、甲笨、二甲苯、基苯等。一 τ1 J U 卞人 Ί 土, 0 U 140, more preferably 80 to 135. If the acid value is 50 to 150, increasing the solubility in E will increase the dissolution of the unexposed portion, and it will have high sensitivity, leaving the exposed portion of the exposed portion at the time of development to increase the residual film rate. Here, s is a value obtained by measuring a hydroxide hydroxide required to neutralize the binder polymer lg, and is usually determined by dissolving sodium hydroxide in water. The binder polymer is a solid component of the resin composition with tinted gloss and gloss. The percentage of the mass is usually 0/1000 县 * horse 5% by weight or more by 26% by mass] 315613 15 200428138 Better It is 10% by mass or more and 26% by mass or less, more preferably 5% by mass or more and 26% by mass or less. If the content is 5 masses. Above / 0 and at most 26% by mass, it is preferable because a pattern can be formed, and the resolution and the residual film ratio can be improved. «The photopolymerizable compound (C) used in the present invention is a compound that can be polymerized by a living radical and an acid generated by the photopolymerization initiator with light irradiation, for example, a polymerizable carbon-carbon unsaturated bond Of compounds, etc. The photopolymerizable compound (C) is preferably a trifunctional or more polyfunctional photopolymerizable compound. Multifunctional photopolymerizable compounds having three or more functions such as' pentaerythritol tetraacrylate, pentaerythritol tetramethacrylate, dipentaerythritol penta (acrylate), dipentaerythritol penta (methacrylate), dipentaerythritol hexa (acrylate) , Dipentaerythritol hexa (methacrylate), etc. The photopolymerizable compound (C) may be used alone, or two or more kinds of this σ may be used, and its content in the colored photosensitive resin composition is usually 5% by mass or more and 90% by mass or less. It is preferably at least 80% by mass and more preferably at most 70% by mass. If its content is 5 mass% or more and 90 mass% or less, it is sufficiently hardened, the residual film rate is increased, the pattern is undercut and the adhesion is good, so it is preferable. The photopolymerization initiator (D) used in the present invention is preferably one containing at least one acetophenone-based compound. Ethylbenzene compounds are, for example, diethoxyacetamidine compounds, 2-methyl-2-morpholine-'yl-bu (4-methylthienyl) acetone, and 2-hydroxymethyl-1-benzyl Propan-1_one, dimethanolketal, 2-merylmethyl [4 (2-hydroxyethoxy) phenyl] propanone, 丨 _hydroxycyclohexylbenone, 315613 16 200428138 hydroxy-2 -Methyl-l- [4- (1-methylethylene) phenyl] propan-1-one oligomer and the like. Among these, 2-hydroxy-2-methyl-1- (4-methylthienyl) propan-1-one is preferably used. In addition, as for the photopolymerization initiator (D), plural kinds of ethyl may be used. A combination of photopolymerization initiators other than acetophenone-based and acetophenone-based. Photopolymerization initiators other than acetophenone-based, for example, radical initiators, sensitizers, and acid initiators that generate active radicals by light irradiation Agents, etc. The active radical initiators are, for example, benzin-based compounds, mono-based compounds, thioxanthone-based compounds, trioxan-based compounds, 2, 4 '6- Trimethyl benzamidinediphenylphosphine oxide, 2, 2'-bis (o-chlorophenyl) -4'4,5,5,5, -tetraphenyl-1,2, -bisamizole, 10 · Butyl-2-chloroacridone, 2-ethylanthraquinone, benzyl, 9,10-phenanthrene qUinone, camphorquinone, benzyl Methyl glycolate, titanium (titanocene) compounds, etc. Benzoin-based compounds are, for example, benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin ethyl ether, Benzoin butane, etc. Compounds are, for example, diphenyl ketone, methyl o-benzylidene benzoate, 4-phenyl diphenyl ketone, 4-benzyl methenyl, -methyldiphenyl sulfide, 3,3 ' '4'4, _tetrakis (tertiary butylperoxoyl) dibenzyl ketone, 2,4,6-trimethyldiphenyl ketone, etc. thioxanthone (thioxanthone, Huiren this η, (Nonene) -based compounds are, for example, 2-isopropylthioxanthone, 4-isopropylthioxanthone m 2, 4-ethyl ethylxanthone, and 2,4-digasthioxanthone. Xanthomone, 1_qi_4 and organic 4_propoxythioxanthinone, etc. The compound of the Three Cultivation System is, for example, 4_bis (trifluoromethyl) -6- (4 · 315315613 17 200428138oxy Phenyl) -1'3,5_trigenol, 2'4-bis (trichloromethyl) -6_ (4-methoxynaphthyl) -1'3,5-trigenol, 2,4-bis (Trifluoromethyl) -6- (4-methoxystyryl) -1,3,5-trioxane, 2,4-bis (trifluoromethyl) -6- [2- [5-曱Succin-2-yl] vinyl] -1,3,5-triazine, 2,4-bis (trichlorofluorenyl) -6- [2- (furan-2-yl) ethenyl], 3,5_three wells, 2 '4-bis (trichloromethyl) -6- [2- (4-diethylamino_2-methyl Group) vinyl] -1,3,5-trisyl, 2,4-bis (trichloromethyl) -6_ [2- (3, 4_monomethoxyphenyl) ethenyl] -1,3 , 5-trifluorocarbon, etc. The acid initiator is, for example, 4-hydroxyphenyldimethylfluorene p-fluorenebenzenesulfonate, 4-hydroxybenzyldifluorenylhexafluoroantimonate, 4-acetamidine Phenylphenyl dimethyl p-toluene xanthanate, 4-ethenyloxybenzyl, methyl, benzyl hexafluoroantimonate, triphenylsulfonium p-toluenesulfonate, triphenylene Hexafluoroantimonate, Benzyl iodorust p-xylbenzenesulfonate, dibenzyl iodopyrene hexafluoroantimonate and other phosphonium salts, nitrobenzyltoluene sulfonates, benzoin benzenesulfonic acid Salt, etc. Among the above-mentioned compounds which are active radical initiators, there are compounds which simultaneously generate active radicals and acids. For example, a triad photopolymerization initiator can also be used as an acid initiator. The content of the photopolymerization initiator (D) is usually 0.1 to 20 parts by mass relative to the total amount of the binder polymer (B) and the photopolymerizable compound (c). It is preferably at least i parts by mass and at most u parts by mass. θ. If the content of the initiator (D) of the present invention is 0 "by weight or more and 20 or less, the sensitivity will be increased, the exposure time will be shortened, and the production will be improved, and there will be no poor resolution. So better. 315613 18 200428138 The colored photosensitive resin button product of the present invention can also be added with photopolymerization initiation (G). The photopolymerization initiator (G) is usually used in combination with the photopolymerization initiator (D), which can further promote the polymerization of the photopolymerizable compound (c) initiated by the photopolymerization initiator (D). The photopolymerization initiator (G) is, for example, an amine-based compound, an alkoxyanthracene-based compound, a thioxanthone-based compound, and the like. , Methyldiethanolamine, triisopropyl, 4-diamidinoaminobenzoic acid ethylamine-based compounds are, for example, triethanolamine alcoholamine, 4-diamidinoaminobenzoic acid methyl ester 4. · methylaminobenzoic acid Isoamyl ester, 2-diethylaminoethyl phenylarsonate-2-ethylhexyl methylbenzylate, N, N-dimethylpyrrolanilide, 4-ester 4-4 -bis (_methyl Moonyl) triphenyl_ (commonly known as michler, sketone), 4, 4'-bis (diethylamino) diphenyl ketone, 4, 4, _bis (ethylmethylamino) ) Diphenyl ketone, etc., and its application preferably uses 4,4-bis (diethylamino) diphenyl ketone. Examples of the alkoxyanthracene-based compound are 9, 丨 -dimethoxy-lean, 2 ethoxy-9 '10-dimethoxyanthracene, 9, 10-diethoxy onion, and 2 ethyl H / di Ethoxyanthracene and the like. The thioxanthinone-based compounds are, for example, 2-isopropylthioxanthone, cardiisothiothioxanthine 1, 2, 4, and 1, which are ^ -ethylthioxanthone, 2, 4-dichlorothio thiokoushan, gas-4-propoxythio koukou_ and so on. Use with or in combination. Commercially available, as the commercially available light EAB-F "(Hodo Chemical Co., Ltd. photopolymerization initiator (D) can be used alone, and the photopolymerization initiator (G) can use the polymerization initiator (G) For example, the product name is "manufactured by the company", etc. 315613 19 200428138 In the colored photosensitive resin composition of the present invention, the combination of the photopolymerization initiator "(D) and the photopolymerization initiator (G) is as follows , Diethoxyacetamidine / 4, 4, -bis (diethylamino) diphenyl ketone, 2-methyl-2-morpholine 4-yl-1- (4-methylfluorenyl ) Propionone / 4, bis (dimethylamino) diphenyl ketone, 2-hydroxy-2-fluorenyl-1-phenylpropanone 4 • ketone / 4, 4, bis (diethyl Amine) diphenyl ketone, dimethanol ketal / 4,4, _bis (diethylamino) monobenzyl ketone, 2-hydroxy-2-methyl-l- [4- (2-hydroxy Ethoxy) phenyl] propane ·· 1-ketone / 4, 4'-bis (diethylamino) diphenylketone, 1-hydroxycyclohexylbenzophenone / 4,4_bis (diethylamine) Oligomers of diphenyl ketone, 2-hydroxy-2-methyl_1- [4- (1-fluorenylethenyl) phenyl] propanone / 4,4, _bis (diethyl Amino) diphenyl ketone, 2- -2_dimethylamino group_ 丨 _ (4-morpholine_4-ylphenyl) butan-1_one / 4,4, _bis (diethylamino) diphenylketone combination, etc. 'Preferable combination of 2-methyl-2-morpholin-4_yl-1- (4-methylthienyl) propanone / 4,4-bis (monoethylamino) diphenyl ketone . When the photopolymerization initiation aid (G) is used, the amount of the photopolymerization initiation aid (G) is usually 10 mol or less, preferably 0.001 mol or more and 5 mol per 1 mol of the photopolymerization initiator (D). Below the ear. The solvent (E) used in the present invention is, for example, ethers, aromatic hydrocarbons, ketones, alcohols, esters, amidines, and the like. The ethers are, for example, tetrahydrofuran, tetrahydropyran, 1, dioxane, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol-butane, and diethylene glycol monohydrate. Methyl ether, diethylene glycol monoethyl ether, dioxin monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol dipropyl ether, diethylene glycol monobutyl ether, propylene glycol monohydrate Ether acetate, propylene glycol / ether ether acetate, 20 315613 200428138 propylene glycol monopropyl ether acetate, ^ acid vinegar, ethyl acetate are ... Carbitate, propylene glycol methyl ether acetate, methyl ethyl acetate, methyl pentyl acetate, methoxypentyl acetate, fungal ether, phenyl ether, methyl anisole and the like. Aromatic tobaccos are, for example, benzene, methylbenzene, xylene, and benzene. A τ

_類例如為丙酮、2_丁酮、？ ^ A J z ]酮、2_庚酮、3-庚酮、4-庚酮、 4-甲基-2-戊_、環戊酮、環己酮等。醇類例如為甲醇、乙醇、丙醇、丁酵、己醇、環己醇、乙二醇、甘油等。酯類例舉如，乙酸乙酯、乙酸正丁酯、乙酸異丁酯、甲l戊Sg、乙酸異戊酯、乙酸異丁酯、丙酸丁酯、赂酸異丙酯、酪酸乙酯、酪酸丁酯、烷酯類、乳酸甲酯、乳酸乙酯、羥乙酸甲酯、羥乙酸乙酯、羥乙酸丁酯、曱氧基乙酸甲醋、甲氧基乙酸乙酯、甲氧基乙酸丁酯、乙氧基乙酸甲酯、乙氧基乙酸乙酯、3-羥基丙酸曱酯、3-羥基丙酸乙酯、 3 -甲氣基丙酸甲醋、3 -曱氧基丙酸乙酿、3 -乙氧基丙酸甲酯、3 -乙氧基丙酸乙醋、2 -氧基丙酸曱醋、2 -氧基丙酸乙酯、2_氧基丙酸丙醋、2_甲氧基丙酸甲酯、2_曱氧基丙酸乙酯、2-甲氧基丙酸丙酯、2·乙氧基丙酸甲酯、2-乙氧基丙酸乙酯、2-酮基-2·甲基丙酸甲酯、2-酮基-2-甲基丙酸乙酯、2-甲氧基-2-甲基丙酸曱酯、2-乙氧基-2-甲基丙酸乙酯、丙酮酸甲酯、丙酮酸乙酯、丙酮酸丙酯、乙醯乙酸甲酯、乙醯乙酸乙酯、2_酮基丁酸甲酯、2-酮基丁酸乙酯、 21 315613 3_ ▼氧基丁基乙酸醋丁内酯等。酿胺類有如N，N 等。， 3-甲基-3-甲氧基丁基乙酸酯、y 二甲基甲醯胺、N，N-二甲基乙醯胺其他丨谷劑有如，N-甲基η比吸,p an ^ r巷比咯烷酮、二甲亞砜等。月|J述之溶劑令較好使用令醢 „ 有3·乙虱基丙酸乙酯與丙二醇-甲醚乙酸職之溶劑。該溶劑中之匕含" 乙西曰之買更佳為5至40質量％。又，該/谷劑中之丙二醇— =0/ 甲醚乙酸知之含量較佳為50至97質量/〇 ’更佳為60至95質量％。前述之溶劑亦可單獨使用或2種以上混合使用。胃本發明之著色感光性樹脂組成物中之溶劑（E)之含 :質里百刀率3十’通常為70質量％以上95質量。/〇以下β車又佳為75質量％以上9〇質量％以下。溶劑（ε )之含有量若為7〇質量％以上95質量％以下，塗布時之平坦性良好’且形成濾色器時之色濃度充分，顯示特性良好。在本發明中使用之界面活性劑（F)例如為矽酮系界面活性劑、氟系界面活性劑、含有氟原子之矽酮系界面活性劑及該等之混合物等。石夕嗣系界面活性劑例如為有矽氧烷鍵之界面活性劑等具體而έ，有東麗矽酮DC3PA、東麗矽酮SH7PA、東麗石夕綱DC11PA、東麗矽酮SH21PA、東麗矽酮SH28PA、東麗矽酮SH29PA、東麗矽酮δΗ30ΡΑ、聚醚變性矽酮油 SH8400(東麗矽（公司）製造）、κΡ321、KP322、KP323、 22 315613 200428138 KP324、KP326、KP340、KP341 (信越矽製造）、TSF400、 TSF401、TSF410、 TSF4300、TSF4440、TSF4445、TSF4446、TSF445 2、TSF4460 (GE東芝矽（公司）製造）等。氟系界面活性劑例如為具有氟碳鏈之界面活性劑等。具體而言，Florinate (商品名）FC430、FlorinateFC431 (住友（公司製造）、Megafac(商品名）F142D、MegafacF171、 MegafacF172、MegafacF173、Classes are, for example, acetone, 2-butanone,? ^ A J z] ketone, 2-heptanone, 3-heptanone, 4-heptanone, 4-methyl-2-pentanone, cyclopentanone, cyclohexanone, and the like. The alcohols are, for example, methanol, ethanol, propanol, butanol, hexanol, cyclohexanol, ethylene glycol, glycerol, and the like. The esters are exemplified by ethyl acetate, n-butyl acetate, isobutyl acetate, methylpentyl Sg, isoamyl acetate, isobutyl acetate, butyl propionate, isopropyl pivalate, ethyl caseinate, Butyl Butyrate, Alkyl Esters, Methyl Lactate, Ethyl Lactate, Methyl Glycolate, Ethyl Glycolate, Butyl Glycolate, Methyl Ethyl Acetate, Ethyl Methoxylate, Butyl Methoxylate Esters, methyl ethoxyacetate, ethyl ethoxyacetate, ethyl 3-hydroxypropionate, ethyl 3-hydroxypropionate, methyl 3-methylpropionate, ethyl 3-propoxypropionate Alcohol, methyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, ethyl 2-oxypropionate, ethyl 2-oxypropionate, 2-propoxypropionate, 2 _ Methyl methoxypropionate, 2-Methyl ethoxypropionate, propyl 2-methoxypropionate, methyl ethoxypropionate, ethyl 2-ethoxypropionate, 2 -Methyl keto-2 · methylpropionate, ethyl 2-keto-2-methylpropionate, ethyl 2-methoxy-2-methylpropionate, 2-ethoxy-2- Ethyl methyl propionate, methyl pyruvate, ethyl pyruvate, propyl pyruvate, methyl ethyl acetate, ethyl ethyl acetate, 2_ , Methyl, 2-methylbutyrate, vinegar 21315613 3_ ▼ methoxybutyl acetate butyrolactone. Stuffed amines such as N, N and so on. , 3-methyl-3-methoxybutyl acetate, y dimethylformamide, N, N-dimethylacetamide, and other cereals such as N-methyl η specific absorption, p An ^ r lane than pyrrolidone, dimethyl sulfoxide and so on. Yue | The solvent described in J is better to use. 醢 „Solvents with ethyl ethylacetate and propylene glycol-methyl ether acetate. The solvent in this solvent contains " Ethiopian Buy better 5 To 40% by mass. The content of propylene glycol in this / cereal— = 0 / methyl ether acetic acid is preferably 50 to 97% by mass /, and more preferably 60 to 95% by mass. The aforementioned solvents may also be used alone or Two or more types are used in combination. The content of the solvent (E) in the coloring photosensitive resin composition of the present invention is as follows: the quality is 100%, and the ratio is usually 70% by mass to 95%. 75% by mass or more and 90% by mass or less. If the content of the solvent (ε) is 70% by mass or more and 95% by mass or less, the flatness at the time of coating is good, and the color density at the time of forming a color filter is sufficient, and the display characteristics are good. The surfactant (F) used in the present invention is, for example, a silicone-based surfactant, a fluorine-based surfactant, a fluorine-containing silicone-based surfactant, or a mixture of these. The active agent is, for example, a surfactant having a siloxane bond, etc. Rex Silicone DC3PA, Toray Silicone SH7PA, Toray Silicone Yugang DC11PA, Toray Silicone SH21PA, Toray Silicone SH28PA, Toray Silicone SH29PA, Toray Silicone δΗ30PAC, Polyether Modified Silicone Oil SH8400 ( (Manufactured by Toray Silicon), κΡ321, KP322, KP323, 22 315613 200428138 KP324, KP326, KP340, KP341 (made by Shin-Etsu Silicon), TSF400, TSF401, TSF410, TSF4300, TSF4440, TSF4445, TSF4446, TSF445 2, TSF4460 ( GE Toshiba Silicon (manufactured by Toshiba Corporation)), etc. The fluorine-based surfactant is, for example, a surfactant with a fluorocarbon chain. Specifically, Florinate (trade name) FC430, Florinate FC431 (Sumitomo (manufactured by)), Megafac (trade name) ) F142D, MegafacF171, MegafacF172, MegafacF173,

MegafacF177、MegafacF183、MegafacR30(大日本油墨化學工業公司製造）、Eftop(商品名）EF3(H、EftopEF303、Eftop EF351、EftopEF352 (新秋田化成公司製造）、Surflon (商品名）S381、SurflonS382、SurflonSClOl 、SurflonSC105 (旭硝子公司製造）、E5844(Daikin Fine Chemical研究所製造）、BM-1000、BM-1100 (皆為商品名：BM Chemie 公司製造）等。具有氟原子之矽酮系界面活性劑有如，具矽氧烷鍵以及氣碳鍵結構之界面活性劑等。具體而言，有Megafac (商品名）R08、MegafacBL20、MegafacF475、MegafacF177, MegafacF183, MegafacR30 (manufactured by Dainippon Ink Chemical Industry Co., Ltd.), Eftop (trade name) EF3 (H, EftopEF303, Eftop EF351, EftopEF352 (manufactured by Shin Akita Kasei Co., Ltd.), Surflon (trade name) S381, SurfonS382, SurfflonSClOl, (Manufactured by Asahi Glass Co., Ltd.), E5844 (manufactured by Daikin Fine Chemical Research Institute), BM-1000, BM-1100 (both are trade names: BM Chemie company), etc. Silicone surfactants having a fluorine atom are, for example, silicon Surfactant of oxo-alkane bond and gas-carbon bond structure, etc. Specifically, there are Megafac (trade name) R08, MegafacBL20, MegafacF475,

MegafacF477、MegafacF443(大日本油墨化學工業公司製造）等。該等之界面活性劑亦可單獨使用或將2種以上組合而使用。著色感光性樹脂組成物中之界面活性劑（F )之含量較佳為0.001質量份以上0.2質量份以下，更佳為0 002 23 315613 200428138 質量份以上0.1質量份以下，再佳為〇〇〇3質量份以上〇質量份以下，若界面活性劑之含量為〇〇〇1質量份以上〇 2 質量份以下，所得之塗膜之平坦性良好。MegafacF477, MegafacF443 (manufactured by Dainippon Ink Chemical Industry Co., Ltd.), etc. These surfactants may be used alone or in combination of two or more. The content of the surfactant (F) in the colored photosensitive resin composition is preferably 0.001 parts by mass or more and 0.2 parts by mass or less, more preferably 0 002 23 315613 200428138 parts by mass or more and 0.1 parts by mass, and still more preferably 0.000. 3 parts by mass or more and 0 parts by mass or less, and if the content of the surfactant is not less than 0.001 part by mass and not more than 2 parts by mass, the flatness of the obtained coating film is good.

調製本發明之著色感光性樹脂組成物之方法有如，混合除界面活性劑以外之成份後，以「在23。(：之黏度為丨 3.〇mPa.s以上6.5mPa，s以下，且該組成物ι〇μ滴^到玻璃基板上0.2秒後與丨秒後之接觸角在1〇。以上2〇。以下」之方式添加界面活性劑之方法’預先，預備性地求出界面活性劑之添加量與23°C之黏度及該組成物心丨滴到玻璃基板上〇.2秒後及1秒後之接觸角之關係，依據該結果一起添加各成分並混合之方法等。本發明之著色感光性樹脂黏結劑聚合物以外之高分子化劑、紫外線吸收劑、防凝集劑硬化劑等添加劑。組成物中亦可含有填充劑、合物、黏著促進劑、抗氧化、有機酸、有機胺化合物及 ϋ 充填劑可例舉如玻璃、鋁等微粒子。黏結劑聚合物（B )以外之离八阿刀子化合物可例舉如，斌乙烯酵、聚丙稀酸、聚等。％—烷醚、聚丙烯酸氟烷酯黏著促進劑可例舉如，乙缔= 惫其功^ T虱基矽烷、乙烯三乙乙其、, 土乙氧基）矽烷、N- ( 2-胺基乙基）-3-胺基丙基甲基二甲4 -3脖其π # 乳基夕烷、Ν- ( 2-胺基乙基） 3_胺基丙基甲基三甲氧基矽烷、烷、Ip θ ^ 3_胺基丙基三乙氧基矽衣氧丙氧基丙基三甲氧甚功& 基石夕燒、3-環氧丙氧基甲基 315613 24 200428138 二甲氧基矽烷、3_氯丙基曱基二甲氧基矽烷甲氧基石夕燒、3-甲基丙稀醯氧基丙基三甲氧美石氧内基三基丙基三甲氧基矽烷等。夕烷、丁基-3 -甲酚）抗氧化劑例舉如，4,4’-硫代雙（6-第 2，6-二-第三丁基_4_甲酚等。紫外線吸收劑例舉如有2_( 2_羥基第= 苯基）-5.氯苯幷三嗤等苯幷三㈣化合物、^ 5·甲基基二苯基酮等二笨基酮系、2，4_二_第三—4辛氧二-第三丁基-4-羥基苯甲酸酯等苯甲酸 ~ 6m。㈣曰糸化合物、2-“， 6-一本基 q，3，5_三哄 _2_基）_5_ 物等。己虱基酚等三畊系化合防止凝集劑有如，聚丙烯酸鈉等。、有機酸例舉如，甲酸、乙酸、丙酸、路酸、戊酸、新戊酸、己酸、二乙基乙酸、庚酸、辛酸等月旨肪族單致酸類. 草酸、丙二酸、號轴酸、戊二酸、己二酸、庚二酸、辛二酸、壬二酸、癸二酸'巴西二酸'甲基丙二酸、乙基丙二酸、·"甲基丙二酸、甲基琥雖酸、四甲基琥拍酸、環己基二叛酸、衣康酸、擰康酸、馬來酸、富馬酸、甲基反丁烯二酸（mesaconicacid)等脂肪族二幾酸類；土丙三缓酸（tricarbaUyHc aeid)、烏頭酸（ae〇nitic 以⑷、樟腦三酸（camphoronic acid)等脂肪族三緩酸類；苯甲酸、苯乙酸、枯酸、2,3-二甲基苯基酸 (hemeUiticacid)、3, 5-二甲基苯甲酸等芳香族單羧酸類；苯二甲酸、鄰苯二甲酸、對苯二甲酸等芳香族二缓酸 315613 25 200428138 類；偏笨三酸、均苯三酸、偏笨四酸、均苯四酸等芳香族多元幾酸類等。有機胺化合物例舉如’正丙胺、異丙胺'正丁胺、異丁胺、第二丁胺、第三丁胺、正戊胺、正己胺、正庚胺、正辛胺、正壬胺、正癸胺、正_1 —胺、正十二胺等之單院胺類；The method for preparing the coloring photosensitive resin composition of the present invention is, for example, after mixing ingredients other than the surfactant, the viscosity is "at 23." (: the viscosity is 3.0 mPa.s or more and 6.5 mPa, s or less, and the The composition was dripped onto the glass substrate for 0.2 seconds and the contact angle between the second and second seconds was between 10 and 20. The method of adding a surfactant is to obtain the surfactant in advance. The relationship between the amount of addition and the viscosity at 23 ° C and the contact angle of the composition core dripping onto the glass substrate after 0.2 seconds and 1 second, and the method of adding the components together and mixing according to the results. Additives such as polymerizers, UV absorbers, and anti-aggregation hardeners other than colored photosensitive resin binder polymers. The composition may also contain fillers, compounds, adhesion promoters, antioxidants, organic acids, and organics. Examples of amine compounds and rhenium fillers include fine particles such as glass and aluminum. Compounds other than the binder polymer (B) can be exemplified by bin ethylene fermentation, polyacrylic acid, poly, and the like.%-Alkyl ether ,Polyacrylic acid The fluoroalkyl ester adhesion promoters can be exemplified by, for example, ethylene = exhaustion ^ Tylsilane, ethylenetriethylethene, ethoxy) silane, N- (2-aminoethyl) -3- Aminopropylmethyl dimethyl 4 -3 neck its π # lactyl oxane, N- (2-aminoethyl) 3-aminopropylmethyltrimethoxysilane, alkane, Ip θ ^ 3_ Aminopropyltriethoxysilane-coated oxypropoxypropyltrimethoxysilane & Keystone yakiya, 3-glycidoxymethyl 315613 24 200428138 dimethoxysilane, 3-chloropropylamidine Dimethoxysilyl methoxylithium, 3-methylpropanyloxypropyltrimethoxymetyloxytriylpropyltrimethoxysilane, and the like. Oxane, butyl-3 -cresol) antioxidants are exemplified by 4,4'-thiobis (6-second, 6-di-third-butyl-4-cresol, etc.) Examples of ultraviolet absorbers For example, there are 2_ (2_hydroxyth = phenyl) -5. Benzene hydrazone compounds such as chlorobenzene hydrazone, hydrazene compounds such as ^ 5. methyl diphenyl ketone, etc. _Thirty-four octyl di-third butyl-4-hydroxybenzoate and other benzoic acid ~ 6m. ㈣ said hydrazone compound, 2- ", 6-monobenzyl q, 3, 5_ three coax_ 2_base) _5_, etc. The three-tillage combination anti-agglomerating agents such as caprylol are sodium polyacrylate. Examples of organic acids include formic acid, acetic acid, propionic acid, road acid, valeric acid, and pivalic acid. , Hexanoic acid, diethylacetic acid, heptanoic acid, caprylic acid and other fatty monoacids. Oxalic acid, malonic acid, hornic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid Acid, sebacic acid, 'malonic acid', methylmalonic acid, ethylmalonic acid, " methylmalonic acid, methylsuccinic acid, tetramethylsuccinic acid, cyclohexyl dicarbamic acid, Itaconic acid, fumaric acid, maleic acid, fumaric acid, mesaconicacid and other lipids Groups of bisacids; TritarbaUyHc aeid, aconitic acid, hydrazone, camphoronic acid, etc .; aliphatic benzoic acids; benzoic acid, phenylacetic acid, cumic acid, 2,3 -Aromatic monocarboxylic acids such as dimethylphenyl acid (hemeUiticacid), 3,5-dimethylbenzoic acid; aromatic dicarboxylic acids such as phthalic acid, phthalic acid, terephthalic acid 315613 25 200428138 Aromatic polybasic acids such as trimellitic acid, trimesic acid, trimellitic acid, pyromellitic acid, etc. Organic amine compounds are exemplified by 'n-propylamine, isopropylamine', n-butylamine, isobutylamine, Single-academic amines such as dibutylamine, tertiary butylamine, n-pentylamine, n-hexylamine, n-heptylamine, n-octylamine, n-nonylamine, n-decylamine, n- 1-amine, n-dodecylamine;

υ 環己胺、2-甲基環己胺、3_曱基環己胺、4_甲基環己胺等單環烷胺類；甲基乙胺、二乙胺、甲基正丙胺、乙基正丙胺、二正丙胺、二異丙胺、二正丁胺、二異丁胺、二第二丁胺、二第三丁胺、二正戊胺、二正己胺等之二烷胺類；甲基環己胺、乙基環己胺等單烷基單環烷胺類；二環己胺等二環烷胺類；二曱基乙胺、甲基二乙胺、三乙胺、二甲基正丙胺、二乙基正丙胺、甲基二正丙胺、乙基二正丙胺、三正丙胺、三異丙胺、三正丁胺、三異丁胺、三第二丁胺、三第三丁胺、三正戊胺、三正已胺等三烷胺類；二甲基環己胺、二乙基環己胺等之二燒基單環烧胺類；甲基二環己胺環烷胺類；乙基二環己胺、三環己胺等單烷基二胺基乙醇、3 -胺基- l- 内醇基-1-丁醇、5_胺基-1-戊醇、1-胺基-2-丙醇、4 -胺、6-胺基-1-己醇等單烷醇胺 315613 26 200428138υ Cyclohexylamine, 2-methylcyclohexylamine, 3-methylcyclohexylamine, 4-methylcyclohexylamine and other monocyclic alkylamines; methylethylamine, diethylamine, methyl-n-propylamine, ethyl Dialkylamines such as di-n-propylamine, di-n-propylamine, diisopropylamine, di-n-butylamine, diisobutylamine, second-second butylamine, second-third butylamine, di-n-pentylamine, and di-n-hexylamine; Monoalkyl monocycloalkylamines such as cyclohexylamine, ethylcyclohexylamine; Dicycloalkylamines such as dicyclohexylamine; Dimethylethylamine, methyldiethylamine, triethylamine, dimethyl N-propylamine, diethyl-n-propylamine, methyl-di-n-propylamine, ethyl-di-n-propylamine, tri-n-propylamine, tri-isopropylamine, tri-n-butylamine, tri-isobutylamine, tri-second butylamine, tri-third butylamine , Tri-n-pentylamine, tri-n-hexylamine, and other trialkylamines; dimethylcyclohexylamine, diethylcyclohexylamine, and other dialkyl monocyclic alkylamines; methyldicyclohexylamine cycloalkylamines ; Monoalkyldiaminoethanol such as ethyldicyclohexylamine, tricyclohexylamine, 3-amino-l-lactone-1-butanol, 5-amino-1-pentanol, 1-amine Monoalkanolamines such as 2-propanol, 4-amine, 6-amino-1-hexanol 315613 26 200428138

4-胺基-1-環己醇等單環烷醇胺類；一醇胺、—正丙醇胺、二異丙醇胺、二正丁醇胺、 J'酉予月念、* _» 、、 _ —戊醇胺、二正己醇胺等二烷醇胺類；一（4_環己醇）胺等二環烷醇胺類；醇胺二正丙醇胺、二異丙醇胺、三正丁醇胺、八丁％胺二正戊醇胺、三正己醇胺等三烷醇胺類；二（心環己醇）胺等三環烷醇胺類；胺基1 2 -丙一醇、2 -胺基·1，3 -丙二醇、4 -胺基-1， 2_丁二醇、4·胺基-1，3-丁二醇、3-二曱基胺基“，2_丙二醇、3-二乙基胺基“，2_丙二醇、2_二曱基胺基-丄，3-丙二醇—乙基胺基-1，3 -丙二醇等胺基炫二醇類； 4-胺基-1，2_環己二醇、4_胺基，3_環己二醇等胺基環己二醇類； 1-胺基環戊酮甲醇、4-胺基環戊酮甲醇等含有胺基之環烷酮曱醇類； 1-胺基環己酮曱醇、4-胺基環己酮甲醇、4-二甲基胺基ί衷戊烧曱醇、4 -二乙基胺基環戍烧曱醇、4-二曱基胺基環己烷甲醇、4-二乙基胺基環己烷甲醇等含胺基之環烷甲醇類； yS -丙胺酸、2-胺基酪酸、3-胺基酪酸、4-胺基酪酸、 2-胺基異乙酸、3-胺基異乙酸、2-胺基戊酸、5-胺基戊酸、 6-胺基己酸、1-胺基環丙烷羧酸、卜胺基環己烷羧酸、4-胺基環己烷羧酸等胺基羧酸類； 27 315613 200428138 苯胺、鄰-甲基苯胺、間-甲基苯胺、對-甲基苯胺、對 -乙基苯胺、對-正丙基苯胺、對-異丙基本細、對-正丁基苯胺、對-第三丁基苯胺、1-萘胺、2-萘胺、N，N-二甲基苯胺、 N，N-二乙基苯胺、對-甲基-N，N-二甲基苯胺等芳香族胺類；鄰-胺基苄醇、間-胺基苄醇、對-胺基苄醇、對-二曱基胺基苄醇、對-二乙基胺基苄醇等胺基苄醇類；鄰-胺基酚、間-胺基對-二乙基胺基苯酚等胺基酚類；間-胺基苯甲酸、對-胺基苯甲酸、對-二甲基胺基苯甲酸、對·二乙基胺基苯甲酸等胺基苯甲酸類等。作爲硬化劑如，經由加熱與黏結劑聚合物中之羧基反應可交聯黏結劑聚合物之化合物、硬化劑單獨聚合可硬化者色圖，之化合物等。可交聯黏結劑聚合物之化合物例舉如’環氧化合物、氧雜環丁烧（oxetane)化合物等。環氧：有如，A系環氧樹脂、氫化雙“系衰處、雙盼F系環氧樹脂、氫化雙 _一，)環氧樹脂、其他芳】=、脂環族系環氧樹脂、雜環式環氧樹脂、縮水甘樹月曰、縮水甘油胺系環氧樹腊、環氧樹脂化、、由等!“環氧該等環氧樹脂之演化衍生物 4環乳樹脂、以外之脂肪族、脂環族或芳香族之；其溴化衍生物 (共）聚合物之環氧化物物、丁二婦之氧：物、縮水甘油& (甲基）㈣酸醋之；i聚t物之環一縮水甘油基異氰酸酯等。（，、）聚合物、 315613 28 200428138 氧雜環丁烷化合物例舉如，碳酸鹽雙氧雜環苯基雙氧雜環丁烧、己三酸雙氧雜環丁醋、雙乳雜環丁 s旨、環己烧二m酸雙氧雜環丁酿等。伸酸本發明之著色感光性樹脂環氧化合物、氧雜環丁烷等時化合物之環氧基、氧雜環丁烷化合物。前述之化合物例舉如類、酸引發劑等。丁烷、對苯二組成物，含有作爲硬化劑之，亦可含有可開環聚合環氣化合物之氧雜環丁烷骨架之，^元幾酸類、多元叛酸軒多元羧酸類有如，苯二甲酸 _ H—甲基苯二甲酿、鄰笨二甲酸、對苴_田减 & ^ τ敬、本一甲酸、均笨四酸、偏笨三酸、丨，4 , 5 8-萘四羧酸、3，3’，4 ,4， —廿， 4 _二本基酮四羧酸等元羧酸類；万甘務夕视阳吸、戊來酸、富馬酸、衣康酸等脂肪族多元羧酸類；六經基苯二甲酸、3味二甲基四減苯酸、六經基異苯：甲酸、六經基對笨-甲酷，、~ 本—甲酸、1，2，4-環戊烷三羧酸、i，2， 4 -環己烧三叛酸、援& ρ 夂衣戊烷四羧酸、1’2’4,5_環己烷四筹酸專脂環族多元缓酸類等。多元羧酸酐類例舉如，1 _ 千邪本一甲酸酐、均苯四甲酸酐、偏苯三酸酐、3，3，，4，4， 4 -二本基酮四羧酸二酐等芳夭族多元羧酸酐類；曰知康酸Sf、十一烧基珑轴酸肝、 2，3, 4-丁烷四羧酸二酐等脂肪衣康酸酐、琥珀酸軒、丙三酸酐、馬來酸酐、j，族多元羧酸酐類； 315613 29 200428138 τ丞四氫苯二甲酸酐穴羥丞笨二甲酸軒環戊炫四幾酸二酐、卜2,4，％環己烧四致酸二軒、降苗稀一甲酸肝（himie —―咖仏、飢酸酐等元羧酸酐類；、夕甘油偏苯三酸酐等含有酯基之羧乙一醇雙偏苯三酸酸肝類等。Monocycloalkanolamines such as 4-amino-1-cyclohexanol; monoalcoholamines, -n-propanolamines, diisopropanolamines, di-n-butanolamines, J '酉 Yuenian, * _ » ,, _ —dialkanolamines such as pentanolamine, di-n-hexanolamine; dicycloalkanolamines such as mono (4-cyclohexanol) amine; alcoholamines di-n-propanolamine, diisopropanolamine, Trialkanolamines such as tri-n-butanolamine, octabutylamine, di-n-pentanolamine, and tri-n-hexanolamine; Tricycloalkanolamines such as di (cardiocyclohexanol) amine; Amine 1 2 -propanol , 2-amino-1,3-propanediol, 4-amino-1,2-butanediol, 4-amino-1,3-butanediol, 3-difluorenylamino ", 2-propanediol , 3-diethylamino ", 2-propanediol, 2-difluorenylamino-fluorene, 3-propanediol-ethylamino-1,3-propanediol, and other aminodiols; 4-amino groups Aminocyclohexanediols such as 1,2-cyclohexanediol, 4-amino, and 3-cyclohexanediol; 1-aminocyclopentanone methanol, 4-aminocyclopentanone methanol, etc. contain amines Cycloalkanone alcohols; 1-aminocyclohexanone alcohols, 4-aminocyclohexanone alcohols, 4-dimethylamino alcohols, 4-diethylamino alcohols Burnt alcohol, 4-Difluorenylaminocyclohexanemethanol, 4-diethylaminocyclohexanemethanol, and other amine-containing cycloalkanols; yS -alanine, 2-aminobutyric acid, 3-aminobutyric acid, 4-aminobutyric acid, 2-aminoisoacetic acid, 3-aminoisoacetic acid, 2-aminovaleric acid, 5-aminovaleric acid, 6-aminohexanoic acid, 1-aminocyclopropanecarboxylic acid, Aminocarboxylic acids such as diaminocyclohexanecarboxylic acid, 4-aminocyclohexanecarboxylic acid; 27 315613 200428138 aniline, o-methylaniline, m-methylaniline, p-methylaniline, p-ethyl Aniline, p-n-propylaniline, p-isopropyl basic fine, p-n-butylaniline, p-tertiary butylaniline, 1-naphthylamine, 2-naphthylamine, N, N-dimethylaniline , N, N-diethylaniline, p-methyl-N, N-dimethylaniline and other aromatic amines; o-aminobenzyl alcohol, m-aminobenzyl alcohol, p-aminobenzyl alcohol, Amino-benzyl alcohols such as p-difluorenylaminobenzyl alcohol and p-diethylaminobenzyl alcohol; Aminophenols such as o-aminophenol, m-aminop-diethylaminophenol; Amines such as m-aminobenzoic acid, p-aminobenzoic acid, p-dimethylaminobenzoic acid, and p-diethylaminobenzoic acid Benzoic acid and the like. As the hardener, for example, a compound that crosslinks the binder polymer by reacting with a carboxyl group in the binder polymer by heating, a color chart of a hardener that can be hardened by polymerizing the hardener alone, a compound, and the like. Examples of the compound of the crosslinkable binder polymer include 'epoxy compounds, oxetane compounds, and the like. Epoxy: For example, A-series epoxy resin, hydrogenated double "series", Shuangpan F-series epoxy resin, hydrogenated bis_a,) epoxy resin, other aromatic] =, alicyclic epoxy resin, miscellaneous Cyclic epoxy resin, glycyrrhizin, glycidylamine-based epoxy wax, epoxy resin, and so on! "Evolutionary derivatives of epoxy resins such as 4-ring emulsion, other than aliphatic, Cycloaliphatic or aromatic; epoxides of brominated derivatives (co) polymers, oxygen of succinic acid, glycidol & (meth) acetic acid; i Ring-glycidyl isocyanate and the like. (,,) polymer, 315613 28 200428138 oxetane compounds are exemplified by carbonate dioxophenyldioxetane, adipate dioxetane, dilactone s purpose, cyclohexyl dimethylene dioxetane and so on. Acetic acid The coloring photosensitive resin of the present invention is an epoxy group or an oxetane compound when it is an epoxy compound or an oxetane compound. The aforementioned compounds are exemplified by acetone, acid initiator and the like. Butane, terephthalic acid composition, containing as a hardener, can also contain an oxetane skeleton that can ring-open and polymerize ring gas compounds, such as quinone acids, polybasic acids, polycarboxylic acids, and the like Formic acid_H-methylxylene, o-benzyl dicarboxylic acid, p-benzyl phthalate & ^ Tau Jing, Benzoic acid, mesitylene tetracarboxylic acid, meta-benzyltricarboxylic acid, 4, 5, 8-naphthalene tetra Carboxylic acids, 3,3 ', 4,4, — 廿, 4 _ dibenone ketone tetracarboxylic acids and other carboxylic acids; fats such as Wanganxixiyangyang, glutaric acid, fumaric acid, itaconic acid Polybasic carboxylic acids of the family; Hexacyl phthalic acid, 3-dimethyl dimethyltetrabenzoic acid, hexaacyl isobenzene: formic acid, hexaacyl p-benzyl-methacryl,, ~ Ben-formic acid, 1,2,4 -Cyclopentanetricarboxylic acid, i, 2,4 -Cyclohexanoic acid, A &P; p-pentanetetracarboxylic acid, 1'2'4,5_cyclohexane tetracarboxylic acid alicyclic ring Multivariate slow acids and so on. Examples of polybasic carboxylic acid anhydrides include aromatic stilbene polycarboxylic acids such as 1 _ succinic acid monocarboxylic acid anhydride, pyromellitic anhydride, trimellitic anhydride, 3,3,4,4,4 -dibenone ketone tetracarboxylic dianhydride and the like. Anhydrides; fatty itaconic anhydrides such as sphincate Sf, undecyl-based long axis acid liver, 2,3,4-butanetetracarboxylic dianhydride, succinic acid, malonic anhydride, maleic anhydride, j Polycarboxylic anhydrides; 315613 29 200428138 τ 酐 tetrahydrophthalic anhydride, hydroxyammonium dibenzoate, cyclopentaphthalic acid, tetracarboxylic acid dianhydride, 2,4,% cyclohexyl tetracarboxylic acid, two compounds, Miaoxian mono-formic acid liver (himie --- Kaji, hunan anhydride, and other carboxylic acid anhydrides; Ethyl glycerol trimellitic anhydride and other ester-containing carboxyglycerol di trimellitic acid livers and so on.

者厂關於幾酸肝類、亦可使用市售做為環氧樹脂硬化。前述之環氧樹脂硬化劑有如，商品名AdecahardenerEH_7o〇」（旭電化工業公司製造）、商 RikacidRegarding a few acidic livers, you can also use commercially available epoxy resin hardening. The aforementioned epoxy resin hardener is, for example, a trade name of Adecahardener EH_7o〇 (manufactured by Asahi Denka Kogyo Co., Ltd.), and Rikacid.

品名 HH」（新日本理化公司製造）、商品名「顧_7〇〇」（新理化公司製造）等。酸引發劑可例舉如，與前述相同者。前述硬化劑可分別單獨使用，亦可2種以上組合使 \J 用。使用本發明之以《光性樹脂組成物形成圖型之方法將本毛月之著色感光性樹脂組成物塗布於於基板或事先形成在基板上之固體著色感光性樹脂組成物層（以下，將此稱爲基板等。）上，藉由加熱從塗布之著色感光性樹脂組成物層中去除溶劑等揮發成分而形成層，將·該層放掩模中介下曝光以顯像之方法等。作爲基板有如’玻璃基板、石夕基板、聚碳酸醋基板、忒知基板、芳香族聚醯胺基板、聚醯胺醯亞胺基板、聚醯 30 315613 200428138 亞胺基板、A1基板、Ga As基板等表面平坦之基板。亦可對該等基板實施以下處理，如經由矽烷偶合劑等藥品處理、電漿處理、離子電鍍處理、濺射處理、氣相反應處理、真空蒸著處理等前處理。使用矽基板等作爲基板時，在前述矽基板等之表面上亦可形成電荷偶合元件（CCD )、薄膜電晶體（TFT)等。前述之基板上塗布著色感光性樹脂組成物之方法有如，使用先前之旋轉塗布器之方法、使用刮刀塗布器等省液塗布器之方法等，其中較佳為使用刮刀塗布器之方法。使用本發明之著色感光性樹脂組成物形成圖型之較佳之方法如，使用刮刀塗布器將本發明之著色感光性樹脂組成物塗布於基板等上，其次藉由加熱使溶劑等揮發性成分揮發之方法。藉此’在基板等上可形成包含著色感光性樹脂組成物之固體成分且平坦性佳之層。在本文中’「平坦性」為以Na燈照射經加熱乾燥之基板，煞後觀察塗膜狀態，並藉目視以下述基準測定塗膜上是否形成斑。在塗膜表面無法看到斑平坦性佳組成=明提供可形成平坦性良好之膜之著色感光性樹脂可作爲形成使用該組成物形成之圖型因平坦性良好濾色器之著色圖型之材料。【實施方式】以下以實施例詳細説明本發明但並非以實施例限 315613 31 制本發明。在本實施例使用之成份以下述簡稱表示。 (A-1)著色劑：CI.顏料紅254 (A-2)著色劑：c』.顏料黃139 ‘ (A-3 )著色劑：C I•顏料綠％ (A-4)著色劑：C.I.顏料黃15〇 (A-5)著色劑：CI•顏料藍15 : 6 (A-6)著色劑：C I顏料紫23 (Β-υ黏結劑聚合物：甲基㈣酸與甲基丙稀酸节醋之共聚物[曱基丙烯酸單位與甲基丙稀酸^單位之比，以物質量比（莫耳比）計’為27: 73’酸價為83,聚苯乙烯換算重量平均分子量為18,〇〇〇。 (Β-2)黏結劑聚合物：曱基丙烯酸與甲基丙烯酸苄酯之共 =物[甲基丙烯酸單位與甲基丙烯酸苄酯單位之比，以物質量比（莫耳比）計’為27 : 73，酸價為1〇2，聚苯乙烯換算重量平均分子量為28〇〇(^ ' (Β-3 )黏結劑聚合物：甲基丙烯酸與甲基丙烯酸苄酯之共聚物[曱基丙烯酸單位與甲基丙烯酸苄酯單位之比，以物質置比（莫耳比）計，為30 : 70 ’酸價為113，聚苯乙稀換算重量平均分子量為2〇,〇〇〇。 (Β-4)黏結劑聚合物：曱基丙烯酸與曱基丙烯酸苄酯之共聚物[甲基丙烯酸單位與曱基丙烯酸苄酯單位之比，以物質置比（莫耳比）計，為30 : 70，酸價為113，聚笨乙稀換算重量平均分子量為25，000 315613 32 200428138 上述之黏結劑聚合物之5^本乙婦換算重量平均八子量，係藉用GPC法，於以下條件測定。裝置；HLC-8120GPC(東麗公司製造）管柱；TSK-GELG2000HXL 管柱濃度；40°C 溶劑；THF 流速；1.0m 1/m in"HH" (manufactured by Shin Nihon Chemical Co., Ltd.), trade name "Gu_700" (manufactured by Shin Ricoh Chemical Corporation), etc. Examples of the acid initiator include the same ones as described above. The aforementioned hardeners can be used individually or in combination of two or more types. Using the method for forming a pattern of a photosensitive resin composition of the present invention, a colored photosensitive resin composition of the present month is applied to a substrate or a solid colored photosensitive resin composition layer (hereinafter, This is referred to as a substrate or the like.) A method of removing a volatile component such as a solvent from the applied colored photosensitive resin composition layer by heating to form a layer, and exposing the layer through a mask to develop the image. Examples of the substrate include a glass substrate, a stone substrate, a polycarbonate substrate, an unknown substrate, an aromatic polyimide substrate, a polyimide substrate, a polyimide substrate 30 315613 200428138 imine substrate, an A1 substrate, and a Ga As substrate. Wait for a flat substrate. These substrates can also be subjected to the following treatments, such as pretreatments such as chemical treatments such as silane coupling agents, plasma treatments, ion plating treatments, sputtering treatments, gas phase reaction treatments, and vacuum evaporation treatments. When a silicon substrate or the like is used as the substrate, a charge coupling element (CCD), a thin film transistor (TFT), or the like may be formed on the surface of the aforementioned silicon substrate or the like. The aforementioned method for applying the colored photosensitive resin composition to the substrate includes, for example, a method using a conventional spin coater, a method using a liquid-saving coater such as a knife coater, and the like, and a method using a knife coater is preferable. A preferred method for forming a pattern using the colored photosensitive resin composition of the present invention is, for example, coating the colored photosensitive resin composition of the present invention on a substrate or the like using a doctor blade applicator, and then volatilizing a volatile component such as a solvent by heating. Method. Thereby, a layer having a solid content of a colored photosensitive resin composition and a good flatness can be formed on a substrate or the like. In this article, "" flatness "refers to the heating and drying of a substrate by irradiating it with a Na lamp, observing the state of the coating film after the shaving, and visually measuring whether a spot is formed on the coating film with the following criteria. No spots can be seen on the surface of the coating film. Composition with good flatness = providing a coloring photosensitive resin that can form a film with good flatness can be used as a coloring pattern for forming a color filter with good flatness by forming a pattern formed using the composition material. [Embodiment] The following describes the present invention in detail by way of examples, but the present invention is not limited to the examples. The components used in this embodiment are represented by the following abbreviations. (A-1) Colorant: CI. Pigment Red 254 (A-2) Colorant: c ′. Pigment Yellow 139 '(A-3) Colorant: CI • Pigment Green% (A-4) Colorant: CI Pigment Yellow 15 (A-5) Colorant: CI • Pigment Blue 15: 6 (A-6) Colorant: CI Pigment Violet 23 (B-υ Binder Polymer: Methyl acetic acid and methyl acrylic acid Vinegar copolymer [ratio of fluorene-based acrylic acid units to methacrylic acid ^ units, based on mass ratio (molar ratio) 'is 27: 73' acid value is 83, polystyrene equivalent weight average molecular weight is 18,00. (B-2) Adhesive polymer: co-polymer of methacrylic acid and benzyl methacrylate [ratio of methacrylic acid unit to benzyl methacrylate unit, based on mass ratio (Mo Ear ratio) 27: 73, acid value is 102, polystyrene equivalent weight average molecular weight is 2800 (^ ((B-3)) binder polymer: methacrylic acid and benzyl methacrylate The copolymer [ratio of fluorene-based acrylic acid units to benzyl methacrylate units is 30:70 in terms of material ratio (molar ratio), the acid value is 113, and the weight average molecular weight in terms of polystyrene is 2. 〇〇〇. (Β- 4) Binder polymer: copolymer of fluorenyl acrylic acid and fluorenyl benzyl acrylate [ratio of methacrylic acid units to fluorenyl benzyl acrylate unit, in terms of material ratio (molar ratio), 30: 70, The acid value is 113, and the average molecular weight of polystyrene-equivalent weight is 25,000 315613 32 200428138. The average weight of 5 ^ the equivalent weight of the above-mentioned binder polymer is measured by GPC method under the following conditions. HLC-8120GPC (manufactured by Toray Corporation); TSK-GELG2000HXL column concentration; 40 ° C solvent; THF flow rate; 1.0m 1 / m in

被檢驗固體成分濃度；0.001至〇.〇 i質量0/〇注入量；5 0 " 1 檢測器；RI 校正用標準物質；TSK STANDARD POLYSTYRENE F-40、 F-4、F-l、A-2 500、A-5 00 (東麗公司製造）、 (C)光聚合性化合物：二季戊四醇六丙烯酸酯 (D-i)光聚合起始劑：2 -甲基-2-嗎琳-4-基-1- (4-甲硫基苯基）丙-1_酮光聚合起始劑：2 ’ 4-雙（三氣曱基）-6_胡椒基， 3，5-三啡 (G-1)光聚合起始劑：2’ 4-二乙基硫代σ山酮 (Ε-1)溶劑：丙二醇一曱醚乙酸醋 (Ε_2)溶劑：3-乙氧基丙酸乙酯 ()界面活性劑：F475(大曰本油墨化學工業公司製造） (F-2)界面活性劑：SH8400(東麗矽酮公司製造） (F-3 )界面活性劑：E5844 ((公司）Daikin Fine Chemical 研究所製造） 33 315613 200428138Tested solid content concentration; 0.001 to 0.000 mass 0 / 〇 injection volume; 50 " 1 detector; RI calibration standard material; TSK STANDARD POLYSTYRENE F-40, F-4, Fl, A-2 500 , A-5 00 (manufactured by Toray Corporation), (C) photopolymerizable compound: dipentaerythritol hexaacrylate (Di) photopolymerization initiator: 2-methyl-2-morpholin-4-yl-1- (4-Methylthiophenyl) propan-1-one photopolymerization initiator: 2 '4-bis (trifluorofluorenyl) -6-piperyl, 3,5-triorphine (G-1) photopolymerization Starter: 2 '4-diethylthiosigmazanone (E-1) Solvent: propylene glycol monomethyl ether acetate (E_2) Solvent: ethyl 3-ethoxypropionate () Surfactant: F475 (Manufactured by Daiyoku Ink Chemical Industry Co., Ltd.) (F-2) surfactant: SH8400 (manufactured by Toray Silicone) (F-3) surfactant: E5844 (manufactured by Daikin Fine Chemical Research Institute) 33 315613 200428138

Ο (Η )環氧樹脂化合物[鄰曱酌紛酿樹脂ortho- ere sol novolac resin、「Sumi 環氧樹脂 ESCN-195XL-80」（住友化學工業公司製造）] 實施例1 [著色感光性樹脂組成物1之調製] (A-ι ) 4.112質量份 (A-2) 0.964質量份聚酯系分散劑 1.523質量份 (B-1 ) 4.342質量份 (C) 5.307質量份 (D-1 ) 0.579質量份 (D-2) 0.579質量份 (G-1 ) 0.579質量份 (E-1 ) 73.665質量份 (E-2) 8.200質量份 (F-1 ) 0.010質量份混合上述成份 [接觸角評價] ’得到著色感光性樹脂組成物1 使用接觸角測定裴置（DGD Fast/60 Contact Angle Meter(GBX公司製造）），在以丙輞洗滌後之玻璃（#1737 (Corrnng公司製造））上滴丨〇 # [之著色感光性樹脂組成物1’滴入後0.2秒之接觸角為18.6。。飽和丨秒後之接觸角為13.0。。 [黏度評價] 34 315613 200428138 使用黏度測定裝置（VISCOMETER RE120L SYSTEM(東機產業公司製造），在23°C下測定著色感光性樹脂組成物之黏度，在5Orpm下之黏度為4.0mPa*s。 [塗膜之形成] 將上述製得之著色感光性樹脂組成物用微型注射器 MICRO-SYRINGE滴1滴（10 # L )到玻璃基板上時，以直徑7mm之圓形擴展，無干涉弧，且平坦性良好。 [刮刀塗布器之評價] 製得之著色感光性樹脂組成物用刮刀塗布器形成塗膜時平坦性良好，且所得之塗膜無斑點。實施例2 [著色感光性樹脂組成物2之調製] (A-3 ) 3.605 質量份 (A-4 ) 3.395 質量份聚酯系分散劑 1 ·843質量份 (B-3) (C) (D-2) (E-1) (E-2) (F-2) (H) 3.933質量份 3·540質量份〇·787質量份 57_711質量份 24.750質量份 0-004質量份 0·393質量份混合上述成份’得到著色感光性樹脂組成物2。 [接觸角評價] 315613 35 200428138 與實施例1同樣地測定著色感光性樹脂組成物2之接觸角’ 0 · 2秒後之接觸角為17. 〇。。飽和1秒後之接觸角為 16.3° 。 [黏度評價] 與實施例1同樣地測定著色感光性樹脂組成物2之黏度’結果黏度為4.8mPa*s。 [塗膜之形成]〇 (Η) Epoxy compound [ortho-ere sol novolac resin, "Sumi epoxy resin ESCN-195XL-80" (manufactured by Sumitomo Chemical Industries, Ltd.)] Example 1 [Colored photosensitive resin composition Preparation of product 1] (A-ι) 4.112 parts by mass (A-2) 0.964 parts by mass Polyester-based dispersant 1.523 parts by mass (B-1) 4.342 parts by mass (C) 5.307 parts by mass (D-1) 0.579 parts by mass Parts (D-2) 0.579 parts by mass (G-1) 0.579 parts by mass (E-1) 73.665 parts by mass (E-2) 8.200 parts by mass (F-1) 0.010 parts by mass Mixing the above components [contact angle evaluation] ' The colored photosensitive resin composition 1 was obtained. The contact angle was measured using a contact angle meter (DGD Fast / 60 Contact Angle Meter (manufactured by GBX)), and the glass was washed with acrylic (# 1737 (manufactured by Corrnng)). # [The contact angle of the colored photosensitive resin composition 1 '0.2 seconds after dropping was 18.6. . After saturation, the contact angle after 1 second is 13.0. . [Viscosity evaluation] 34 315613 200428138 Using a viscosity measuring device (VISCOMETER RE120L SYSTEM (manufactured by Toki Sangyo Co., Ltd.), the viscosity of the colored photosensitive resin composition was measured at 23 ° C, and the viscosity was 4.0 mPa * s at 50 rpm. [ Coating film formation] When the colored photosensitive resin composition prepared above was dropped (10 # L) on a glass substrate using a micro-injector MICRO-SYRINGE, it expanded in a circular shape with a diameter of 7 mm, without interference arcs, and was flat. [Evaluation of a doctor blade applicator] The colored photosensitive resin composition thus obtained was flat when formed by a doctor blade applicator, and the resulting coating film was spotless. Example 2 [Coloring photosensitive resin composition 2 Preparation] (A-3) 3.605 parts by mass (A-4) 3.395 parts by mass of polyester-based dispersant 1.843 parts by mass (B-3) (C) (D-2) (E-1) (E- 2) (F-2) (H) 3.933 parts by mass 3.540 parts by mass 0.787 parts by mass 57_711 parts by mass 24.750 parts by mass 0-004 parts by mass 0 · 393 parts by mass The above ingredients are mixed to obtain a colored photosensitive resin composition 2. [Contact angle evaluation] 315613 35 200428138 The coloring sensitivity was measured in the same manner as in Example 1. The contact angle of the fat composition 2 was 0. The contact angle after 2 seconds was 17. 0. The contact angle after 1 second of saturation was 16.3 °. [Viscosity Evaluation] The coloring photosensitive resin composition was measured in the same manner as in Example 1. The viscosity of 2 'results in a viscosity of 4.8 mPa * s. [Formation of coating film]

將上述製得之著色感光性樹脂組成物用微型注射器 MICRO-SYRINGE滴1滴（i〇/CZ L)到玻璃基板上時，該組成物以直徑7mm之圓形擴展，無干涉弧，平坦性良好。 [刮刀塗布器之評價] 製得之著色感光性樹脂組成物用刮刀塗布器形成塗膜時平坦性良好，且所得之塗膜無斑點。實施例3 [著色感光性樹脂組成物3之調製] (A-5) (A-6) 聚酯系分散劑 (B-3) (C) (D-1 ) (G-1) (E-1 ) (E-2) 4.433質量份 0.068質量份 1.349質量份 4.732質量份 5.556質量份 1.235質量份 0.617質量份 49.103質量份 32.800質量份 36 315613 200428138 (F-2) (F-3) 0.007質量份 0.004質量份混合上述成份，得到著色感光性樹脂組成物3。 [接觸角評價] 與實施例1同樣地測定著色感光性樹脂組成物3之接觸角，0 · 2秒後之接觸角為1 7 · 0 °。飽和1秒後之接觸角為 15.8° 。 [黏度評價] 與實施例1同樣地測定著色感光性樹脂組成物3之黏度，結果黏度為4.0mPa，s。 [塗膜之形成] 將上述製得之著色感光性樹脂組成物用微型注射器 MICRO-SYRINGE滴1滴（l〇// L)到玻璃基板上時，該組成物以直徑7mm之圓形擴展，無干涉弧，平坦性良好。 [刮刀塗布器之評價] 製得之著色感光性樹脂組成物用刮刀塗布器形成塗膜牯平坦性良好，且所得之塗膜無斑點。比較例1 [著色感光性樹脂組成物4之調製] (A-1 ) (A-2) 聚S旨系分散劑 (Β-2) (C) 5·293質量份 1·4〇7質量份 2.540質量份 5.446質量份 3·644質量份 315613 37 200428138 (D-1 ) 0.547質量份 (D-2) 0.547質量份 (G-1 ) 0.547質量份 (E-1) 79.910質量份 (F-2) 0.010質量份混合上述成份，得到著色感光性樹脂組成物4。 [接觸角評價] 與實施例1同樣地測定著色感光性樹脂組成物4之接觸角’ 0.2秒後之接觸角為21.5。。飽和1秒後之接觸角為 19.2° 。 [黏度評價] 與實施例1同樣地測定著色感光性樹脂組成物4之點度’結果黏度為6.8mPa*s。 [塗膜之形成] 將上述製得之著色感光性樹脂組成物用微型注射器 micr〇-SYRINGE滴i滴（10"L)到玻璃基板上時，該直徑以直徑8mm之圓形擴展，可看見干涉弧，平坦性不良。 [刮刀塗布器之評價] 製得之著色感光性樹脂組成物用刮刀塗布器形成塗祺時平坦性不良，且所得之塗膜有斑點。、實施例4 之調製] 4.112質量份 0.964質量份 [著色感光性樹脂組成物 (A-1 ) (A-2) 315613 38 200428138 聚酯系分散劑 (B-1 ) (C) (D-1 ) (D-2) (G-1) (Ε-1 ) (Ε-2) (F-1 ) 1·523質量份 4_342質量份 5 · 3 0 7質量份〇_579質量份 0-579質量份 0-579質量份 73·665質量份 8-200質量份〇·〇1〇質量份混合上述成分，得到著色感光性樹脂組成物5 [接觸角評價] 使用接觸角測定裝置（DGD Fast/60 Contact Angle Meter(GBX公司製造））’在以丙酮洗蘇後之玻璃（#1737 (Corning公司製造））上滴1〇 a l之著色感光性樹脂組成物5 ’滴加後〇. 2秒之接觸角為19 _ 2。。飽和1秒後之接觸角為14.6° 。 [黏度評價] 使用黏度測定裝置（VISCOMETER RE120L SYSTEM(東機產業公司製造在23 〇c下測定著色感光性樹脂組成物之黏度，在50rpm下之黏度為4.0mPa”。 [塗膜之形成] 將上述製得之著色感光性樹脂組成物用微型注射器 MICRO-SYRINGE滴1滴（i〇/i l)到玻璃基板上時，該組成物以直徑7mm之圓形擴展，無干涉弧，平坦性良好。 315613 39 200428138 [刮刀塗布器之評價] 製付之者色感光性樹脂組成物用刮刀塗布器形成塗膜時平坦性良好，且所得之塗膜無斑點。實施例5 [著色感光性樹脂組成物6之調製]When one drop (i0 / CZ L) of the colored photosensitive resin composition prepared above was dropped on a glass substrate using a micro-injector MICRO-SYRINGE, the composition expanded in a circular shape with a diameter of 7 mm, without interference arcs, and flatness good. [Evaluation of doctor blade applicator] When the prepared colored photosensitive resin composition was formed into a coating film by a doctor blade applicator, the flatness was good, and the obtained coating film was spotless. Example 3 [Preparation of colored photosensitive resin composition 3] (A-5) (A-6) Polyester-based dispersant (B-3) (C) (D-1) (G-1) (E- 1) (E-2) 4.433 parts by mass 0.068 parts by mass 1.349 parts by mass 4.732 parts by mass 5.556 parts by mass 1.235 parts by mass 0.617 parts by mass 49.103 parts by mass 32.800 parts by mass 36 315613 200428138 (F-2) (F-3) 0.007 parts by mass 0.004 parts by mass of the above components were mixed to obtain a colored photosensitive resin composition 3. [Contact angle evaluation] The contact angle of the colored photosensitive resin composition 3 was measured in the same manner as in Example 1. The contact angle after 0 · 2 seconds was 17 · 0 °. The contact angle after 1 second of saturation was 15.8 °. [Viscosity evaluation] The viscosity of the colored photosensitive resin composition 3 was measured in the same manner as in Example 1. As a result, the viscosity was 4.0 mPa, s. [Formation of coating film] When the colored photosensitive resin composition prepared above was dropped (10 // L) on a glass substrate with a micro-injector MICRO-SYRINGE, the composition expanded in a circular shape with a diameter of 7 mm. No interference arc, good flatness. [Evaluation of a doctor blade applicator] The resulting colored photosensitive resin composition was formed into a coating film by a doctor blade applicator. 牯 The flatness was good, and the obtained coating film was spotless. Comparative Example 1 [Preparation of colored photosensitive resin composition 4] (A-1) (A-2) PolyS-based dispersant (B-2) (C) 5.293 parts by mass 1.407 parts by mass 2.540 parts by mass 5.446 parts by mass 3.644 parts by mass 315613 37 200428138 (D-1) 0.547 parts by mass (D-2) 0.547 parts by mass (G-1) 0.547 parts by mass (E-1) 79.910 parts by mass (F-2 ) 0.010 parts by mass of the above components were mixed to obtain a colored photosensitive resin composition 4. [Contact angle evaluation] The contact angle of the colored photosensitive resin composition 4 was measured in the same manner as in Example 1 and the contact angle after 0.2 seconds was 21.5. . The contact angle after saturation for 1 second was 19.2 °. [Viscosity evaluation] The point of the colored photosensitive resin composition 4 was measured in the same manner as in Example 1. As a result, the viscosity was 6.8 mPa * s. [Formation of the coating film] When the colored photosensitive resin composition prepared as described above was dropped on a glass substrate using a micro syringe micr0-SYRINGE (10 " L), the diameter was expanded in a circular shape with a diameter of 8mm, and it can be seen Interference arc, poor flatness. [Evaluation of doctor blade applicator] When the prepared colored photosensitive resin composition was coated with a doctor blade applicator, the flatness was poor, and the obtained coating film was spotted. Preparation of Example 4] 4.112 parts by mass 0.964 parts by mass [colored photosensitive resin composition (A-1) (A-2) 315613 38 200428138 polyester dispersant (B-1) (C) (D-1 ) (D-2) (G-1) (E-1) (E-2) (F-1) 1.523 parts by mass 4_342 parts by mass 5. 3 0 7 parts by mass 0_579 parts by mass 0-579 parts by mass 0-579 parts by mass, 73.665 parts by mass, 8-200 parts by mass, 0.0001 parts by mass, the above components are mixed to obtain a colored photosensitive resin composition 5 [Contact angle evaluation] A contact angle measuring device (DGD Fast / 60 Contact Angle Meter (manufactured by GBX Corporation)) '10 μl of colored photosensitive resin composition was dropped on glass (# 1737 (manufactured by Corning)) washed with acetone 5 '0.2 seconds after dropping The angle is 19 _ 2. . The contact angle after 1 second of saturation was 14.6 °. [Viscosity evaluation] A viscosity measuring device (VISCOMETER RE120L SYSTEM (manufactured by Toki Sangyo Co., Ltd. was used to measure the viscosity of the colored photosensitive resin composition at 23 ° C, and the viscosity at 50 rpm was 4.0 mPa.) [Formation of coating film] When one drop (i0 / il) of the colored photosensitive resin composition prepared as described above was dropped on a glass substrate using a micro-injector MICRO-SYRINGE, the composition expanded in a circular shape with a diameter of 7 mm, had no interference arc, and had good flatness. 315613 39 200428138 [Evaluation of doctor blade applicator] The color of the photosensitive resin composition produced by the doctor blade is good when forming a coating film with a doctor blade applicator, and the resulting coating film is spotless. Example 5 [Coloring photosensitive resin composition Modulation of 6]

0.010質量份混合上述成分，得到著色感光性樹脂組成物6 [接觸角評價] (A-1 ) (A-2) 聚S旨系分散劑 (B-1) (C) (D-1 ) (D-2) (G-1) (E-1 ) (E-2) (F-1 ) 4-U2質量份〇·964質量份 1·523質量份 4·342質量份 5.307質量份 0.579質量份〇·579質量份〇·579質量份 73·665質量份 8-200質量份使用接觸角測定裝置（DGD Fast/60 Contact Angle Meter(GBX公司製造）），在以丙酮洗滌後之玻璃（#i737 (corning公司製造））上滴1 〇 # L之著色感光性樹脂組成物6,滴加後〇.2秒之接觸角為19.6°。飽和1秒後之接觸角為15.4° 。 [黏度評價] 40 315613 200428138 使用黏度測定裝置（VISCOMETER RE 120L SYSTEM(東機產業公司製造）’在23t下測定著色感光性樹月曰組成物之黏度，在5〇rpm下之黏度為4. imPa«s。 [塗膜之形成] 將上述製得之著色感光性樹脂組成物用微型注射器 MICRO-SYRINGE滴1滴（10μ L)到玻璃基板上時，該組成物以直徑6mm之圓形擴展，無干涉弧’平坦性良好。 [刮刀塗布器之評價] 製得之著色感光性樹脂組成物用刮刀塗布器形成塗膜時平坦性良好，且所得之塗膜無斑點。比較例2 [著色感光性樹脂組成物7之調製] 0.220質量份混合上述成份，得到著色感光性樹脂組成物7 (A-1 )(A-2) 聚酯系分散劑 (B-1 )(C) (D-1 )(D-2) (G-1 ) (E-1)(E-2) (F-1) 4.112質量份 0.964質量份 1.523質量份 4.342質量份 5.307質量份 0.579質量份 0.579質量份 0.579質量份 73.665質量份 8.200質量份 41 315613 200428138 '[接觸角評價] 使用接觸角測定裝置（DGD Fast/60 Contact Angle Meter(GBX公司製造）），在以丙酮洗滌後之玻璃（#i737 (corning公司製造））上滴1〇 "[之著色感光性樹脂組成物7 ’滴加後0.2秒之接觸角為2〇 3 »。飽和1秒後之接觸角為15.9° 。 [黏度評價]0.010 parts by mass of the above components were mixed to obtain a colored photosensitive resin composition 6 [Evaluation of contact angle] (A-1) (A-2) PolyS-based dispersant (B-1) (C) (D-1) ( D-2) (G-1) (E-1) (E-2) (F-1) 4-U2 parts by mass 964 parts by mass 1.523 parts by mass 4.342 parts by mass 5.307 parts by mass 0.579 parts by mass 0.579 parts by mass 0.579 parts by mass 73.665 parts by mass 8-200 parts by mass Using a contact angle measuring device (DGD Fast / 60 Contact Angle Meter (manufactured by GBX)), the glass was washed with acetone (# i737 (manufactured by Corning Corporation)) 10 μL of colored photosensitive resin composition 6 was dripped on, and the contact angle of 0.2 seconds after the dropwise addition was 19.6 °. The contact angle after 1 second of saturation was 15.4 °. [Viscosity evaluation] 40 315613 200428138 Using a viscosity measuring device (VISCOMETER RE 120L SYSTEM (manufactured by Toki Sangyo)) to measure the viscosity of the colored photosensitive tree month composition at 23t, the viscosity at 50rpm is 4. imPa «S. [Formation of the coating film] When one drop (10 μL) of the colored photosensitive resin composition prepared above was dropped onto a glass substrate using a micro-injector MICRO-SYRINGE, the composition expanded in a circular shape with a diameter of 6 mm. "No interference arc" has good flatness. [Evaluation of doctor blade applicator] The colored photosensitive resin composition obtained has a good flatness when a coating film is formed with a doctor blade applicator, and the resulting coating film is free of specks. Comparative Example 2 Of the Resin Composition 7] 0.220 parts by mass of the above components were mixed to obtain a colored photosensitive resin composition 7 (A-1) (A-2) polyester-based dispersant (B-1) (C) (D-1 ) (D-2) (G-1) (E-1) (E-2) (F-1) 4.112 parts by mass 0.964 parts by mass 1.523 parts by mass 4.342 parts by mass 5.307 parts by mass 0.579 parts by mass 0.579 parts by mass 0.579 parts by mass 73.665 parts by mass 8.200 parts by mass 41 315613 200428138 '[contact angle evaluation] measured using contact angle (DGD Fast / 60 Contact Angle Meter (manufactured by GBX Co., Ltd.)), and a glass (# i737 (manufactured by Corning Co., Ltd.)) washed with acetone was dripped 10 " [colored photosensitive resin composition 7 'dropwise The contact angle after 0.2 seconds was 203 ». The contact angle after 1 second of saturation was 15.9 °. [Viscosity Evaluation]

_ 使用黏度測定裝置（VISCOMETER RE120L SYSTEM(東機產業（公司）製造），在23«>c下測定著色感光性樹脂組成物之黏度，在5〇rpm下之黏度為4 lmpa,s。 [塗膜之形成] 將上述製得之著色感光性樹脂組成物用微型注射器 micro-syringe滴1滴（10yL)到玻璃基板上時，該組成物以直徑5mm之圓形擴展，可看到干涉弧，平坦性不良。鲁 [到刀塗布器之評價] 製得之著色感光性樹脂組成物用刮刀塗布器形成塗膜時平坦性不良，且所得之塗膜有斑點。比較例3 [著色感光性樹脂組成物8之調製] (A-1 ) (A-2) 聚S旨系分散劑 (Β-1 ) 4·112質量份 0-964質量份 1.523質量份 4·342質量份 42 315613 200428138 (C) 5.307質量份 (D-1 ) 0.579質量份 (D-2) 〇·579質量份 (G-1) 〇_579質量份 (E-1 ) 73.665質量份 (E-2) 8.200質量份 (F-1 ) 0.0005質量份混合上述成份，得則著色感光性樹脂組成物8 [接觸角評價] 使用接觸角測定裳置（DGD Fast/60 Contact Angle Meter(GBX公司製造）），在以丙酮洗滌後之玻璃（#1737 (corning公司製造））上滴10 /z L之著色感光性樹脂組成物8，滴入後〇·2秒之接觸角為15.3 °。飽和1秒後之接觸角為9.2° 。 [黏度評價] 使用黏度測定裝置（VISCOMETER RE120L SYSTEM(東機產業（公司）製造），在23〇c下測定著色感光性樹脂組成物之黏度，在5〇rprn下之黏度為4.〇mpa,s。 [塗膜之形成] 將上述製得之著色感光性樹脂組成物用微型注射器 MICRO-SYRINGE滴！滴（1〇 # L)到玻璃基板上時，該組成物以直徑9mm之圓形擴展，可看到干涉弧，且平坦性不良。 [刮刀塗布器之評價] 43 315613 200428138 製得之著色感光性樹脂組成物用刮刀塗布器形成塗膜時平坦性不良，且所得之塗膜有斑點。實施例6 [著色感光性樹脂組成物9之調製]_ Using a viscosity measuring device (VISCOMETER RE120L SYSTEM (manufactured by Toki Sangyo Co., Ltd.), the viscosity of the colored photosensitive resin composition was measured at 23 «&c; c, and the viscosity at 50 rpm was 4 lmpa, s. [ [Formation of coating film] When the colored photosensitive resin composition prepared above was dropped on a glass substrate with a micro-syringe of a micro-syringe, the composition expanded in a circular shape with a diameter of 5 mm, and an interference arc was seen. Lu [Evaluation to a knife applicator] The colored photosensitive resin composition prepared was poor in flatness when a coating film was formed with a doctor blade applicator, and the resulting coating film was spotted. Comparative Example 3 [Coloring Photosensitivity Preparation of Resin Composition 8] (A-1) (A-2) PolyS-based dispersant (B-1) 4.112 parts by mass 0-964 parts by mass 1.523 parts by mass 4.342 parts by mass 42 315613 200428138 ( C) 5.307 parts by mass (D-1) 0.579 parts by mass (D-2) 0.579 parts by mass (G-1) 0-579 parts by mass (E-1) 73.665 parts by mass (E-2) 8.200 parts by mass ( F-1) 0.0005 parts by mass of the above components are mixed to obtain a colored photosensitive resin composition 8 [contact angle evaluation] using contact angle measurement Ding Changzhi (DGD Fast / 60 Contact Angle Meter (manufactured by GBX)), drips 10 / z L of colored photosensitive resin composition 8 on glass (# 1737 (manufactured by corning)) washed with acetone, drops The contact angle of 0.2 seconds after entry was 15.3 °. The contact angle of 1 second after saturation was 9.2 °. [Viscosity Evaluation] A viscosity measuring device (VISCOMETER RE120L SYSTEM (manufactured by Toki Sangyo (Company)) was used at 23 ° C. The viscosity of the colored photosensitive resin composition was measured below, and the viscosity was 5.0 mpa, s at 50 rprn. [Formation of coating film] The colored photosensitive resin composition prepared above was dropped with a micro syringe MICRO-SYRINGE. When dropping (10 # L) on a glass substrate, the composition expands in a circular shape with a diameter of 9mm, interference arcs can be seen, and the flatness is poor. [Evaluation of doctor blade applicator] 43 315613 200428138 Example 6 [Preparation of colored photosensitive resin composition 9] The photosensitive resin composition was poor in flatness when a coating film was formed with a blade coater, and the obtained coating film was spotted.

(A-1 ) (A-2) 聚酯系分散劑 (B-1) (C) (D-1 ) (D-2) (G-1 ) (E-1 ) (E-2) (F-1 ) 4·112質量份〇·964質量份 1-523質量份 4·342質量份 5-307質量份 0.579質量份 0-579質量份 0.579質量份 73·665質量份 8·200質量份 0.001質量份混合上述成份’得到著色感光性樹脂組成物9 [接觸角評價] 使用接觸角測疋裝置（DGD Fast/60 Contact Angle Meter(GBX公司製造）），在以丙酮洗滌後之玻璃（#i737 (corning公司製造））上滴1〇" L之著色感光性樹脂組成物9 ’滴加0.2秒後之接觸角為1 6.6。。飽和1秒後之接觸角為12.2° 。 [黏度評價](A-1) (A-2) Polyester-based dispersant (B-1) (C) (D-1) (D-2) (G-1) (E-1) (E-2) (F -1) 4 · 112 parts by mass 0 · 964 parts by mass 1-523 parts by mass 4 · 342 parts by mass 5-307 parts by mass 0.579 parts by mass 0-579 parts by mass 0.579 parts by mass 73 · 665 parts by mass 8.200 parts by mass 0.001 The above-mentioned ingredients were mixed in mass parts to obtain a colored photosensitive resin composition 9 [Contact angle evaluation] The glass (# i737) was washed with acetone using a contact angle measuring device (DGD Fast / 60 Contact Angle Meter (manufactured by GBX)). (manufactured by Corning Co.)) The coloring photosensitive resin composition 9 'of 10 L was contacted with a contact angle of 16.6 after 0.2' dropwise addition. . The contact angle after 1 second of saturation was 12.2 °. [Viscosity evaluation]

使用黏度測定裝置（VISCOMETER RE120L 44 315613 200428138 SYSTEM(東機產業（公司）製造），在23°C下測定著色感光性樹脂組成物之黏度，在50rpm下之黏度為4.0mPa，s。 [塗膜之形成] 將上述製得之著色感光性樹脂組成物用微型注射器 MICRO-SYRINGE滴1滴（10μ L)到玻璃基板上時，該組成物以直徑8mm之圓形擴展，無干涉弧，平坦性良好。 [刮刀塗布器之評價] 時平坦性良好，且所得之塗膜無斑點 315613 45Using a viscosity measuring device (VISCOMETER RE120L 44 315613 200428138 SYSTEM (manufactured by Toki Sangyo Co., Ltd.), the viscosity of the colored photosensitive resin composition was measured at 23 ° C. The viscosity at 50 rpm was 4.0 mPa, s. [Coating film Formation] When one drop (10 μL) of the colored photosensitive resin composition prepared above was dropped onto a glass substrate using a micro-injector MICRO-SYRINGE, the composition expanded in a circular shape with a diameter of 8 mm, without interference arcs, and flatness. Good [Evaluation of doctor blade applicator] The flatness was good and the resulting coating film was spotless 315613 45

Claims

200428138 Μ Pickup, patent application scope: 1. A colored photosensitive resin composition, which includes a colorant (A), a binder polymer (B), a photopolymerizable compound ((:), a photopolymerization initiator (D ), Solvent (E) and surfactant (F), the viscosity of the composition at 23 is 3.0 mPa's or more and 6.5 mPa.s or less, and 10 〆i of the composition is dropped onto the glass substrate after 0.2 seconds and The contact angles after 1 second are all 0%. Above 20 °.

2_ The colored photosensitive resin composition as described in item 丨 of the patent scope, wherein the solvent (E) contains propylene glycol monomethyl ether acetate and 3_ethoxypropionic acid ethyl acetate B, and the colored photosensitive resin composition The content of the solvent (E) is greater than or equal to 95% by mass, and the surfactant (F) is selected from the group consisting of a Shixun type surfactant, a Dun type surfactant, and a silicone type surfactant having a gas atom. In the group, at least W, the content of the surfactant ⑺ in the colored photosensitive resin composition is not less than 0.00% by mass and not more than 0.2% by mass. 3. If the colored photosensitive resin composition of item 1 or item 2 of the scope of the patent application, wherein the acid value of the binder polymer (B) is 50 or more, the polystyrene conversion of the binder polymer The weight average molecular weight is 5,000 to 50,000, and the content of the polymer ⑻ in the solid content of the colored photosensitive resin composition is 15% by mass to 26% by mass. 4. If the patent application ranges from items 丨 to 3, the resin composition is supplied to a knife applicator. —Color photosensitivity of item 5. A pattern is a photoresist composition formed by any one of item P to item 4 of the patent system. 315613 46 200428138 6. —A color filter 7. —A liquid crystal display. , Which contains the pattern of item 5 of the scope of patent application. The display device is equipped with the color filter of item 6 in the scope of patent application. 47 315613 200428138 柒, designated representative map: no representative map in this case (I) The designated representative map in this case is: (). (2) Brief description of the representative symbols of the components in this representative diagram: 捌 If there is a chemical formula in this case, please disclose the chemical formula that can best show the characteristics of the invention: (No representative chemical formula in this case) 4 315613