TW200427467A - Cleansing composition, cleansing sheet and makeup removing method - Google Patents

Cleansing composition, cleansing sheet and makeup removing method Download PDF

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Publication number
TW200427467A
TW200427467A TW93111227A TW93111227A TW200427467A TW 200427467 A TW200427467 A TW 200427467A TW 93111227 A TW93111227 A TW 93111227A TW 93111227 A TW93111227 A TW 93111227A TW 200427467 A TW200427467 A TW 200427467A
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Taiwan
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water
mass
makeup
oil
mascara
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TW93111227A
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Chinese (zh)
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TWI355943B (en
Inventor
Atsuhiro Ueda
Hiroko Tsuda
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Kao Corp
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Priority claimed from JP2004047504A external-priority patent/JP3789455B2/en
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Publication of TWI355943B publication Critical patent/TWI355943B/en

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Abstract

A cleansing composition according to the present invention comprises (A) an aqueous phase containing 1 to 25% by weight of a water-soluble compound (a) which has a polyoxypropylene structure having 3 moles or more of propylene oxide but not an alkyl group having 4 ormore carbon atoms and/or a polyoxyethylene structure and (B) an oil phase which is liquid at 30 DEG C, wherein the weight ratio (A):(B) of the aqueous phase (A) and the oil phase (B) is 97:3 to 40:60, and water is contained more than 10% by weight in the total composition. Moreover, a cleansing sheet according to the present invention comprises a nonwoven fabric which is made of a fiber having a cellulose content of at least 70% by weight and has a density of 0.15 to 0.3 g/cm3 impregnated with an oil-in-water emulsion composition containing (A) an aqueous phase containing 1 to 25% by weight of a water-soluble compound (a) which has a polyoxypropylene structure having 3 moles or more of propylene oxide but not an alkyl group having 4 or more carbon atoms and/or a polyoxyethylene structure, (B) an oil phase containing 50% by weight or more of an oily component (b) having a boiling point of 160 to 300 DEG C at 1, 013.25 hPa and c 0.01 to 1% by weight of an aqueous thickening agent having a hydrophobic part, wherein the weight ratio (A):(B) of the aqueous phase (A) and the oil phase (B) is 97:3 to 40:60.

Description

200427467 玖、發明說明： 【發明所屬之技術領域】 本發明為關於卸妝用之卸妝組成物及卸妝材料。 【先前技術】 除去彩妝之技術已知為使用界面活性劑水溶液，且將油 劑以凝膠、乳霜和油等之劑型供使用。於彩妝化妝料中較 難除去的睫毛膏有為了保持捲曲效果等而含有水溶性聚合 物的水性睫毛膏、和對於汗及水難引起掉妝的油性睫毛 膏。但是，先前的界面活性劑水溶液，雖可迅速除去於水 中可輕易溶解或分散的水性睫毛膏，但並無法除去油性睫 毛膏，油劑系卸妝劑雖可除去油性睫毛膏，但具有無法除 去水性睫毛膏的問題。 隨著近年睫毛膏的流行，利用膠乳聚合物之被膜形成能 力的被膜形成型睫毛膏，特別為配合被膜形成能力優良之 丙稀酸烧酯共聚合體的睫毛膏，不論是油性、水性均增加。 膠乳聚合物為令水中不溶之聚合物於水中以乳狀液型式存 在，隨著水分之蒸散而於聚合物粒子間產生強固之鍵結且 被膜化，故於水和界面活性劑水溶液中無法輕易分散，且 於油中亦無法迅速溶解。因此，一旦形成的被膜以使用界 面活性劑水溶液和油劑之先前的彩妝除去技術，具有無法 有效除去之問題。 以除去油性及形成被膜之眼部彩妝化妝料之目的下，於 日本專利特開平5 - 1 6 3 1 1 6號公報中，揭示令異鏈烷烴以聚 氧乙烯烷醚系界面活性劑予以水中乳化的眼部彩妝除去材 312/發明說明書(補件)/93-07/93111227 200427467 料。但是，其對於形成強力被膜且含有大量丙 聚合體的睫毛膏而言，洗淨力並不充分。 此外未使用一般界面活性劑而除去彩妝的技 專利特表平1 1 - 5 0 3 4 6 1號公報中揭示令含有丙 酸烧酯共聚物型乳化劑、油劑、含水乳化物中 化性界面活性劑的技術。於日本專利特開平9 報中揭示於做為保濕劑之大量多元醇中共存油 組成物。又，於日本專利特開昭6 2 - 1 3 5 4 0 6號 令低沸點異鏈烷烴和低沸點矽酣油，於聚丙烯 中以水相分散的彩妝除去材料。於日本專利特 9 - 1 1 0 6 3 8號公報中揭示以水溶性多糖類、低沸 做為必須成分的彩妝除去材料。但是，其雖可 水性睫毛膏，但並無法有效除去被膜形成型睫 又，於曰本專利特開平2 - 1 0 4 5 1 1號公報中， 伸烧基乙二醇和乙醇和水溶性多元醇和界面活 構成的卸妝棉用組成物。於日本專利特開平9 -報中揭示含有聚氧乙烯曱基葡萄糖苷及聚氧丙 糖苷中選出一種或二種以上、和H L B為1 0以上 界面活性劑所構成的彩妝化妝料除去用組成物 雖可除去水性睫毛膏但並無法除去油性睫毛膏 有效除去被膜形成型睫毛膏。 另一方面，關於片狀之卸妝材料有下列之先 本專利特開2 0 0 1 - 3 0 2 4 5 0號公報為揭示令黏度 2 0 0〜4 0 0 0 m P a · s之乳狀化妝料含浸於薄片所構 312/發明說明書(補件)/93-07/93111227 稀酸烧酯共 術，於日本 烯酸一丙烯 ，共存非乳 -4 8 7 0 6號公 和水的卸妝 公號中揭示 酸系增黏劑 開平 點油劑及水 除去油性或 毛膏。 揭示配合聚 性劑和水所 1 4 3 0 2 8號公 烯曱基葡萄 之非離子性 。但是，其 ，且亦無法 前技術。曰 成的卸妝材 7 200427467 料。更且，於日本專利特開2 0 0 3 - 3 3 5 6 2 7號公 具有觸變性之二相型（0 / W型）化妝料含浸的薄， 片雖可除去油性睫毛膏和水性睫毛膏，但並無 被膜形成型睫毛膏。 【發明内容】 本發明為提供含有（A )水相中含有1〜2 5質量 丙烷加成莫耳數3以上之聚氧丙烯構造，且不 個以上之烷基和/或聚氧乙烯構造的水溶性化名 相、和（B )於3 0 °C下液狀油相的組成物，（A )成 分之質量比（A ) : ( B )為9 7 : 3〜4 0 : 6 0，水於全 多於1 0質量％的卸妝組成物。 更且，本發明為提供令含有（A )水相中含有] 具有環氧丙烷加成莫耳數3以上之聚氧丙烯構 有碳數4個以上之烷基和/或聚氧乙烯構造的4 物（a )的水相、和（B )含有5 0質量％以上於1 0 1 3 · 沸點為1 6 0〜3 0 0 °C之油劑（b )的油相、和（C )具； 水系增黏劑0· 0 1〜1質量％，且水相（A)與油相（ (A ) : ( B )為9 7 : 3〜4 0 : 6 0的水中油型乳化組成 素含量為7 0質量％以上之纖維所構成、密度為 cm 3之非織布中含浸而成的片狀卸妝材料。 【實施方式】 首先，說明關於本發明之卸妝組成物、及本 卸妝材料中所用的水中油型乳化組成物（將上ϋ 「組成物」）。 312/發明說明書(補件)/93-07/931 ] 1227 報中揭示令 片。此些薄 法有效除去 %具有環氧 具有碳數4 >物（a )的水 分與（B )成 組成中含有 .〜2 5質量％ 造，且不具 〔溶性化合 2 5 h P a中之 穿斥水部之 B )之質量比 物，於纖維 0. 15〜0· 3g/ 發明之片狀 L合併稱為 8 200427467 本發明所用之（A )成分為於水相中含有1〜2 5質量％具有 環氧丙烷加成莫耳數3以上之聚氧丙烯構造，且不具有碳 數4個以上之烷基和/或聚氧乙烯構造的水溶性化合物 (a )(以下，稱為化合物（a ))的水相。此類水相（A )雖然對於 一般的油性彩妝化妝料的洗淨力少，但對於聚合物被膜具 有某程度的洗淨力。經由令此水相（A )、與對於油性彩妝化 妝料具有優良洗淨力，且即使對於聚合物被膜亦具有若干 洗淨力的油相（B)以特定之比例組合，則可對於油性睫毛膏 和其他一般的彩妝化妝料具有高洗淨力。更且，顯著提高 被膜形成型睫毛膏、特別為含有大量形成強力被膜之丙烯 酸烧酯共聚合體之睫毛膏的除去效果。 水相（A)中所含之化合物（a)由對於聚合物被膜之洗淨力 觀點而言，具有環氧丙烷加成莫耳數3以上的聚氧丙烯構 造。化合物（a )為不具有碳數4個以上之烷基，故不顯示界 面活性劑般的舉動，且於水中難形成微胞，故易進入聚合 物被膜的微細部分。更且，推定聚氧丙烯構造為作用於聚 合物分子間的強力鍵結並且促進聚合物被膜對於水的再分 散，故認為被膜形成型睫毛膏之除去效果優良，但若具有 聚氧乙稀構造，則對於水相的分配提高，並且減弱洗淨效 果。 又，彳匕合物（a)為具有適度之水溶性。此處所謂之水溶 性，為於2 5 °C下對於水具有1質量％以上的溶解度者。 本發明之水相（A )中所含的化合物（a )，以環氧丙烧加成 莫耳數3以上之聚氧丙烯構造結合羥基、甘油基、多甘油 9 312/發明說明書(補件)/93-07/9311〗227 200427467 基、或糖殘基等之親水性基的化合物為佳。 化合物（a)具體而言可列舉聚氧丙烯二甘油醚、聚氧丙 甘油醚、聚氧丙烯甲基葡萄糖苷、聚丙二醇等。 聚氧丙烯二甘油醚為對二甘油加成聚合環氧丙烷者。 中，環氧丙烷.之加成莫耳數由對於聚合物被膜之洗淨力 點而言以4〜2 4莫耳為佳，更且以6〜1 8莫耳為佳。聚氧 烯甘油醚為對甘油加成聚合環氧丙烷者。其中，環氧丙 之加成莫耳數由對於聚合物被膜之洗淨力觀點而言以 8〜24莫耳為佳，更且以8〜16莫耳為佳。聚氧丙烯甲基 萄糖苷為對甲基葡萄糖苷加成聚合環氧丙烷者。其中， 氧丙烷之加成莫耳數係由對於聚合物被膜之洗淨力觀點 言，以5〜25莫耳為佳，而以10〜20莫耳更佳。聚丙二醇 對於聚合物被膜之洗淨力觀點而言，環氧丙烧之加成莫 數為5〜20莫耳為佳，更且以7〜16莫耳為佳。 其中，聚氧丙烯二甘油醚和聚氧丙烯甘油醚除了具有 成物滲入肌膚之效果，加上使用後不會發黏，且提供濕 觸感，故為佳，且以聚氧丙烯二甘油醚為特佳。 水相（A )中所含之化合物（a)可使用一種或組合二種以 上。水相（A )中之化合物（a )份量，由對於被膜形成型睫 膏亦可取得充分洗淨力之觀點而言，相對於水相（A )全量 1質量％以上、又、使用後對肌膚不會產生殘留感之2 5 量％以下。由洗淨力與使用感之平衡而言，更佳相對於水 (A )全量使用3〜2 0質量％、特佳為5〜1 5質量％。 水相（A )中所含之水量，由充分之洗淨力與良好使用感 312/發明說明書(補件)/93-07/93111227 烯 其 觀 丙 炫 葡 環 而 由 耳 組 潤 毛 以 質 相 之 10 200427467 方面而言，相對於組成物全量含有多於1 〇質量％為佳，更 佳為3 0質量％以上，特佳為5 0質量％以上。 水相（A )為以上述化合物（a )、及水做為主成分，亦可含 有除此以外的水溶性成分。例如，經由含有乙醇、多元醇 等之醇類則可提高使用感。特別，乙醇之配合為在提高清 爽感之效果高，又，1，3 _ 丁二醇和甘油之配合為在提高濕 潤感之效果1¾ 。 其次，本發明所用之（B )成分於3 0 °C下為液狀之油相， 對於油性睫毛膏和一般之油性彩妝化妝料具有優良的洗淨 力。又，即使對於聚合物被膜具有（A )成分所未有的溶解 力，且具有若干的洗淨力。黏度低之油相為對於細微部分 的滲透性高，且污染物的溶解性亦高，故洗淨力高。更且， 不會伴隨強烈的油性感且使用感亦良好。 因此，油相（B )以3 0 °C下具有1 0 m P a · s以下之黏度為佳。 油相（B )可與一種或二種以上之油性成分組合使用。於組合 使用二種以上之油性成分做為油相（B )之情形中，即使使用 3 0 °C下非液狀之油性成分、和3 0 °C下具有大於1 0 m P a · s 之黏度的油性成分，若混合二種以上之全體黏度為 1 0 m P a . s以下，則適於使用。此處，黏度為以B Μ型黏度計 (例如，度奇美克（Τ 〇 k i m a k e )公司製）予以測定（測定條件： Rotor No,l、 60rpm)0 於3 0 °C下具有1 0 m P a . s以下黏度之油性成分的具體例可 列舉流動異鏈烷烴、烷基1，3 -二曱基丁醚（日本專利特開 平9 - 8 7 2 2 3號公報）、2 -乙基己酸鯨蠟酯、肉豆蔻酸異丙 11 312/發明說明書(補件)/93-07/93111227 200427467 酯、棕櫚酸異丙酯、異壬酸異壬酯、異壬酸異十三烷酯、 己二酸二異丁酯、己二酸二異丙酯、八曱基三矽氧烷、十 曱基環五矽氧烷、十二甲基五矽氧烷、八曱基環四矽氧烷 等。 其中以分子量3 0 0以下之油性成分為洗淨力南’且具有 使用後油性感少之優良使用感，故為更佳。具體而言，可 列舉輕質流動異鏈烷烴、肉豆蔻酸異丙酯、棕櫚酸異丙酯、 異壬酸異壬酯、己二酸二異丁酯、己二酸二異丙酯、八曱 基三矽氧烷、八曱基環四矽氧烷等。 又，於1 0 1 3 . 2 5 h P a中之沸點為1 6 0〜3 0 0 °C的油劑（b )為 黏度低且對於微細部分的滲透性高，且彩妝污染物的溶解 性或分解性高。又，低沸點之油劑為不伴隨強烈的油性感 且使用後之殘留感亦少，故令其含浸於片材且使用於擦拭 上為特別合適。此時，上述油劑（b )為對於油性彩妝化妝料 的卸妝性能和油性感少之使用感觀點而言，相對於油相（B) 全量含有5 0質量％以上、特別為7 0質量％以上為佳。 其中，於1 0 1 3 . 2 5 h P a中之沸點為1 6 0〜2 5 0 °C的油劑於使 用後對於肌膚之殘留感弱的觀點而言為佳，更且，於 1 0 1 3 · 2 5 h P a中之沸點為1 6 0〜2 3 0 °C 、特別為1 6 0〜2 1 0 °C之 油劑為卸妝性能和不會於肌膚上殘留油性感方面而言為 佳。 上述油劑（b )可列舉輕質流動異鏈烷烴、揮發性矽酮油 等，由卸妝性能而言以使用輕質流動異鏈烷烴為特佳。此 些油劑（b)可使用一種或組合二種以上。 12 312/發明說明書(補件)/93-07/93111227 200427467 輕質流動異鏈烷烴一般為碳數8〜1 8個之分支碳氫化合 物的混合物，若含有低分子量的碳氫化合物則具有獨特氣 味。此類氣味有時令使用者不悅，故儘可能不含有碳數為 8〜9個的低分子量成分為佳。另一方面，若含有許多破數 為1 6〜1 8個的碳氫化合物，則洗淨力差，且使用後之油性 感有變強之傾向。由此類觀點而言，以含有許多碳數為 1 0〜1 5個之異鏈烧烴系碳氫化合物為佳。其中，由氣味、 使用感和卸妝性能的平衡而言，以含有許多碳數為1 2個的 異十二烷為佳。特別，含有9 0質量％以上，更佳為9 5質量 %以上之異十二烷的油劑為適合使用於本發明。 輕質流動異鏈烷烴可列舉商品名麻卡索R ( M A R C A S 0 L R)(丸善石油化學）、IP 溶劑 1 6 2 0 ( IP SOLVENT 1 6 2 0 )、IP 溶劑2 0 2 8 ( I P S 0 L V E N T 2 0 2 8 )(以上，出光石油化學）、艾 索浦L(ISOPERL)、艾索浦H(ISOPERH)(以上，艾克生（EXON) 化學）、艾索卓300、400USOSOL 300、400)(以上，新日 本石油化學）等，但由含有高純度異十二烷的觀點而言，以 麻卡索R(MARCASOL R)(丸善石油化學）為特別適於使用。 又，揮發性矽酮油可列舉例如八甲基三矽氧烷（沸點 1 5 3 °C )、十二曱基五矽氧烷（沸點2 2 9 °C )等之低聚合度鏈 狀二曱基聚矽氧烷、八曱基環四矽氧烷（沸點1 7 2 °C )和十 曱基環五矽氧烷（沸點2 0 5 °C )等之環狀矽酮油。 油相（B )由取得充分洗淨力、和油性感不會變強之良好使 用感的觀點而言，與水相（A )之質量比（A ) : ( B )為9 7 : 3〜4 0 : 6 0、較佳為9 0 : 1 0〜7 0 : 3 0、特佳為含有8 8 : 1 2〜7 5 : 13 312/發明說明 *：(補件)/93-07/93111227 25 ° 200427467 水相（A )及油相（b )之混合物若於置則分離成二相，經由 振盪混合則可暫時均句化，且令化妝用之綿片等中含有此 混合物並擦栻彩妝，或就其原樣以手取用，且溶化污染物。 更且’令混合物含浸於非織布等之片狀基材，作成片狀卸 妝材料亦可。 僅水相（A )與油相（B )於短時間下易分離成二相時，於更 加輕易使用之目的下，於本發明之卸妝組成物中可含有水 系增黏劑做為（C)成分。經由含有水系增黏劑，則在將混合 物振盪混合時可持續均勻狀態，更且，因為易令黏度上升， 故對於肌膚的溶合和按摩性亦提高。 水系增黏劑之具體列可列舉以下的水溶性高分子。天然 之水 >谷性兩分子可列舉例如阿拉伯膠（（j u m A r a b i c )、黃蓍 樹膠（G u m T r a g a c a n t h )、半乳聚糖（G a 1 a c t a n )、瓜阿樹膠 (Gum Guaiac)、角豆樹勝（Carob Gum)、刺梧桐樹膠（Karaya Gum)、角又菜膠（Carrageenan)、果膠（Pectin)、洋菜 (Agar)、槟榼子樹滕（Quince seed gum)、褐藻萃取物、殿 粉（Starch)(米、玉蜀黍、馬鈐薯、小麥）、甘草酸（Glycyrrhi zinicacid)等之植物系高分子，黃原樹膠（xanthanGum)、 糊精（Dextrin)、琥珀葡聚糖（Succinoglucan)、支鏈殿粉 (Pul lu lan)等之微生物系高分子、膠原蛋白（c〇l lag en)、 酿蛋白（Casein)、白蛋白（Albumin)、明膠（Gelatin)等之 動物系高分子。半合成之水溶性高分子可列舉例如羧曱基 殿粉、甲基羥丙基澱粉等之澱粉系高分子、曱基纖維素、 14 312/發明說明書(補件)/93-07/93111227 200427467 硝基纖維素、乙基纖維素、曱基羥丙基纖維素、羥 維素、纖維素硫酸鈉、羥丙基纖維素、羧曱基纖維素i 等之纖維素系高分子、藻酸鈉、藻酸丙二醇酯等之 高分子。合成之水溶性高分子可列舉例如聚乙烯醇 烯基曱醚系高分子、聚乙烯咄咯烷酮、羧乙烯基聚 (CARB0P0L 940， 941 ；諾譽（Noveon，Inc.)公司）等 系高分子、聚乙二醇2 0 0 0 0、聚乙二醇6 0 0 0、聚乙二 等之聚氧乙稀系高分子、聚氧乙烤聚氧丙婦共聚合 共聚合體系高分子、聚丙烯酸鈉、聚丙烯酸乙酯、 醯胺等之丙烯酸系高分子、聚伸乙基亞胺、陽離子 寺。. 更且，若使用水系增黏劑中具有斥水部者，則可 相（A )被增黏、且油相（B )為於水中油型中分散之表 勻的製劑。此處所謂之具有斥水部的水系增黏劑， 鏈具有碳數1 0個以上斥水基的水溶性高分子。 特別關於本發明之片狀卸妝材料中所使用的組成 片材中難引起組成變化，且為了取得卸妝材料的保 性、及良好的洗淨力上，乃使用具有斥水部之水系 做為（C )成分作成水中油型乳化組成物，並令其含浸 中 〇 若使用水系增黏劑中具有斥水部者，則經由斥水 油劑相互作用，使得油劑於水中可較安定保持，因 用通常之界面活性劑所乳化般令油劑微細乳化，故 時易釋出油劑，且亦不會損害洗淨力。即，若使用 312/發明說明書(補件)/93-07/93111227 乙基纖 内（CMC) 藻酸系 、聚乙 合物 之乙烯 醇 4 0 0 0 體等之 聚丙烯 聚合物 作成水 觀上均 為指側 物，於 存安定 增黏劑 於片材 部為與 為未使 於使用 此類水 15 200427467 系增黏劑，則組成物中之油劑為在不損害洗淨力之程度上 分散，且液體的均句性和安定性提高，可發揮做為片狀卸 妝材料的安定性能。其被認為組成物於片材中含浸後，水 系增黏劑聚合物為與油劑共同於纖維間交纏，使得油可在 片材中安定保持。 具有此類斥水部的水系增黏劑可列舉丙烯酸·曱基丙烯 酸烷酯（C10〜C30)共聚合體（Noveon，Inc.公司製、商品名： 胚目聯 TR-1(PEMULEN TR-1)、胚目聯 TR-2(PEMULEN TR - 2)、CARB0P0L ETD等）、羥乙基纖維素羥丙基硬脂醚羥 丙基磺酸鈉（日本專利特開平9 - 2 3 5 3 0 1號公報）等。 上述水系增黏劑（C )可使用一種或組合二種以上。被使用 於本發明之卸妝組成物時，水系增黏劑（C )之含量由使用容 易度、皮膚上之展開、滑溜感方面而言，相對於組成物全 量以0 . 0 1〜5質量％為佳，更佳為0 · 0 1〜2質量％，特別以 ◦ . (H〜1質量％為佳。特別，於本發明之片狀卸妝材料中含 浸且被使用於水中油型乳化組成物時，該具有斥水部之水 系增黏劑的含量由乳化組成物之乳化安定化方面而言，相 對於組成物全量為以0 . 0 1質量％以上，由乳化組成物作成 易含浸於片材之黏度且加工性良好方面而言，相對於組成 物全量為以1質量％以下。其中由乳化安定性能與加工性之 平衡而言，相對於組成物全量為以0 . 1〜0. 5質量％之範圍為 佳。 還有，視需要，亦可使用將上述水系增黏劑中和並且增 黏的中和劑。中和劑可列舉例如氫氧化納、氫氧化鉀等之 16 312/發明說明書(補件)/93-07/93111227 200427467 無機鹼劑、L -精胺酸等之鹼性胺基酸、三乙醇胺等之胺類、 氣等。中和劑之添加量若根據水系增黏劑之種類、使用量 等決定即可，相對於組成物全量以0 . 0 0 5〜0 . 5質量％左右為 佳。中和劑為預先溶解於水中，或者直接與水系增黏劑混 合添加即可。 使用界面活性劑的乳化系中，油劑未於系統中安定分散 且無法充分發揮彩妝除去性能，故乳化或分散安定化之機 能為要求前述之水系增黏劑為佳。因此，於本發明中，界 面活性劑為在不損害本發明效果之範圍下，於提高組成物 對於肌膚的溶合之目的或提高組成物對於片材之濕潤性和 滲透性之目的下，可少量使用。 界面活性劑在不妨礙水相（A )及油相（B )之卸妝性能的範 圍使用上，界面活性劑的含量相對於組成物全量以2質量％ 以下為佳，更佳為0 . 5質量％以下，特別以未滿0 . 0 5質量％ 為佳。 界面活性劑可使用一種或二種以上。具體例由對於肌膚 溫和之觀點而言，可列舉聚氧乙烯烷醚類和蔗糖脂肪酸酯 類、脂肪酸單甘油酯類、山梨糖醇酐脂肪酸酯及其聚氧伸 烷基加成型、聚氧乙烯硬化蓖麻油及其脂肪酸酯、聚氧伸 烷基脂肪酸酯系等。 又，於本發明之組成物中除了上述成分以外，例如將保 濕劑、油膠化劑、紫外線吸收劑、香料、顏料、染料、鹽 類、安定化劑、防腐劑、抗氧化劑、維生素類、蛋白質、 調理劑等之各種添加劑，可在不損害本發明目的及效果的 17 312/發明說明書(補件)/93-07/93111227 200427467 質及量之範圍内添加。 本發明之卸妝組成物可使用上述各材料依常法製造，且 可作成液狀型態、膠狀型態、乳霜狀型態和二相分離型態 等之製劑形態。 使用本發明之卸妝組成物除去彩妝的方法可列舉將組成 物就其原樣、或振動混合物均勻化後，含浸入擦拭媒體且 擦拭皮膚上之彩妝的方法、和以手取用且塗佈至皮膚令彩 妝溶合，並以擦拭媒體予以擦拭或沖洗的方法。此處，擦 拭媒體可列舉例如棉片和紙巾等。 如上所述般，本發明之卸妝組成物為將水相中含有1〜2 5 質量％具有環氧丙烷加成莫耳數3以上之聚氧丙烯構造，且 不具有碳數4個以上之烷基和/或聚氧乙烯構造之水溶性 化合物（a)的水相、及3 0 °C下液狀之油相予以組合，並且 令全組成中含有多於1 0質量°/◦之水，則不僅對於通常的彩 妝，且對於其中難除去之睫毛膏亦可有效除去，特別，對 於油性睫毛膏、和含有大量被膜形成劑之膠乳聚合物中特 別可形成強力被膜之丙烯酸烷酯共聚合體的被膜形成型睫 毛膏，亦可顯示良好的卸妝性能。本發明之卸妝組成物可 有效除去全部的彩妝，且為使用感優良的卸妝組成物。 其次，說明本發明之片狀卸妝材料。 上述之卸妝組成物中，以含有（A)水相中含有1〜25質量％ 具有環氧丙烷加成莫耳數3以上之聚氧丙烯構造，且不具 有碳數4個以上之烷基和/或聚氧乙烯構造之水溶性化合 物（a )的水相、和（B )含有5 0質量％以上於1 0 1 3 · 2 5 h P a中之 18 312/發明說明書(補件)/93-07/93 111 227 200427467 沸點為1 6 0〜3 0 0 °C之油劑（b )的油相、和（C )具有斥水部之 水系增黏劑0 · 0 1〜1質量％，且水相（A )與油相（B )之質量比 (A ) : ( B )為9 7 : 3〜4 0 : 6 0的組成物，由卸妝性能和使用感 優良方面而言，以含浸於片狀基材之水中油型乳化組成物 為特別合適。 於本發明之片狀卸妝材料中，令上述水中油型乳化組成 物含浸於特定的非織布。本發明之卸妝材料因係為片狀， 故可立即使用，且因僅擦拭即可除去彩妝，故可簡便且迅 速除去彩妝。 片狀卸妝材料所使用的水中油型乳化組成物黏度，由加 工時之含浸效率而言以2 0 0 0 m P a · s以下為佳，更且由使用 時自片材滲出液體的容易度而言，特別以3 0 0〜8 0 0 m P a · s 為佳。此處所謂黏度，為指使用B Μ型黏度計（度奇美克公 司製），以R 〇 t 〇 r Ν 〇 · 2、6 r p m、3 0 °C之條件下測定之值。 又，片狀卸妝材料所用的水中油型乳化組成物，若放置 則隨著時間經過而分離，且分成透明的水相和水中油型乳 化相亦可。具體而言，均勻調製後，於3 0 °C靜置時，於1 曰以上1個月以内，分離（提取）成水相和其他乳化相之稍 微不安定的乳化組成物，由卸妝性能和使用感方面而言為 佳。此時，對於非織布的含浸為於分離前進行。於乳化組 成物為稍微不安定的乳化組成物時，水相亦比高分子化合 物所增黏的安定乳化組成物，於使用時由片材中滲出液體 良好，且，卸妝性能優良。 本發明之片狀卸妝材料中做為基材的非織布，於使用時 19 312/發明說明書(補件)/93-07/93111227 200427467 的肌觸感良好，且，即使以積層形態長期保存亦可安定維 持品質之方面而言，使用纖維素含量為7 0質量％以上之纖 維所構成，密度為0 . 1 5〜0 . 3 g / c m3者。如此為親水性且於 較高密度之非織布中含浸，則即使使用保存引起分離之稍 微不安定的乳化組成物，亦可經由令非織布安定保持乳化 組成物外相的水相，更且，包含油劑之水系增黏劑聚合物 為於纖維間交纏且於非織布中安定保持油劑，使得非織布 中之乳化組成物的移動受到抑制，且可維持非織布中之乳 化組成物的份量和組成。 為了抑制含浸之水中油型乳化組成物於薄片基材中的移 動，非織布以可令外相之水相安定保存的親水性為佳。即， 非織布為使用纖維素含量為7 0質量％以上之纖維所構成 者。由安定保持外相之水相的觀點而言，較佳令纖維素含 量為80質量％以上。 纖維素纖維具體而言可列舉棉片、人造纖維等。特別， 棉片為使用時不會不滑，且有濕潤擦拭去掉污染物的感觸 而言為佳。又，由取得滑溜肌膚觸感的方面而言，以水流 交纏法取得非織布為佳。 若滿足上述範圍，則亦可進行斥水性纖維的混合，將薄 片予以改質。斥水性纖維可列舉聚酯系纖維及聚烯烴系纖 維。例如，聚對酞酸乙二醇酯（P E T )、聚對酞酸丁二醇酯 (PBT)、聚丙烯（PP)、聚乙烯（PE)等。 又，為了安定保持含浸之水中油型乳化組成物的組成， 且抑制液體於所積層片材中的上下移動，令非織布為較高 20 312/發明說明書(補件)/93-07/93111227 200427467 密度為佳。由液體為不會經由重力而移動至下方片 點而言，非織布之密度為0.15g/cm3以上，另一方 浸液為易滲入片材中，且片材之使用觸感柔軟之觀 言，以0 . 3 g / c m3以下。由抑制液體移動及使用感之 言，非織布之密度為0.17〜0.25g/cm3為特佳。 又，非織布之平均坪量（每單位面積的重量），由 不會扭轉，且使用情況良好，污染物不會内移之觀點 以4 0 g / m2以上為佳，且由積層時不會膨鬆、並取得 感之觀點而言，以1 0 0 g / m2以下為佳。特別，以5 0 m2因使用時易操作，且積層時可呈適度膨鬆度，故 非織布可為將二種以上之非織布予以重疊或貼合 材料。又，非織布之形狀以人手易取用之形狀、大 度為佳，例如，一邊或直徑為5〜2 0公分左右的正方 方形、圓形、橢圓形、且厚度以0 . 2〜0. 5 mm左右為 相對於非織布1克所含浸之水中油型乳化組成物 量，由良好使用感之觀點而言以2〜5克為佳，特別 2 . 5〜4 . 5克為佳。 本發明之片狀卸妝材料可經由非織布，將乳化組 喷嘴滴下或流下塗佈，或者喷霧含浸，其後放置且 材料中充分溶合則可製造。 本發明之片狀卸妝材料，為各一牧、或重疊數牧 中密封供使用。使用時，將袋開封，並由其中取出 狀卸妝材料，並且觸壓至欲除去彩妝化妝料的部位 拭彩妝化妝料般使用。藉此，對於各種類型的彩妝 312/發明說明書(補件)/93-07/93111227 材之觀 面由含 點而 平衡而 擦拭時 而言， 柔軟觸 〜8 0 g / 為佳。 的薄片 小及厚 形、長 佳。 的份 以 成物由 於薄片 且於袋 一枚片 ，以擦 污染物 21 200427467 可發揮優良的卸妝效果，並可簡便且迅速地除去彩妝。 因此，本發明之片狀卸妝材料不僅可簡便且迅速除去粉 底、口紅等通常之彩妝，且可除去水性睫毛膏及油性睫毛 膏，更且，亦可除去含有大量丙烯酸烷酯共聚合體的被膜 形成型睫毛膏。使用時及使用後之肌觸感優良，且於薄片 所積層之商品形態中亦為品質安定性優良的卸妝材料。 (實施例） 根據以下之實施例，更加說明本發明，且明示本發明的 實施態樣。 實施例A系列：卸妝組成物 (洗淨力之評估方法） 於洗淨力之評估上，使用油性睫毛膏、和大量配合丙婦 酸烷酯共聚合體之被膜形成型水性睫毛膏。 將指定量之睫毛膏於載玻片上以直徑1 . 2公分之圓狀均 勻塗佈，且放置1 2小時令其乾燥，被膜形成型水性睫毛膏 為將佳麗寶（Kane bo)公司製 TEST IMO MASCARA EFFECT C U R L L 0 N G B K 1 8以0 . 0 0 7 0克塗佈，油性睫毛膏為將高絲 (Kose)公司製 SPORTS BEAUTY FASIO POWER STAY MASCARA CURLLONG BK00 1以0. 0 0 4 5克塗佈。根據各睫毛膏的液性 不同，使得睫毛膏以一定面積均勻塗佈時之各個塗佈量為 不同。 由（A )及（B )成分所構成之卸妝組成物即使混合亦可迅速 分離，故進行洗淨力評估時，令棉片1克含有卸妝組成物 3 . 8克且輕揉棉片，令組成物橫遍棉片全體均勻化後，以 22 312/發明說明書(補件)/93-07/93111227 200427467 棉片壓押睫毛膏，且於輕押5秒鐘後以一定壓力（1 0 0 g / cm 2)進行擦拭，測定除去睫毛膏所必要的擦拭回數，並且對 於各睫毛膏依據下列基準評估（實施例A卜比較例A卜A 5 )。 . 〈對於被膜形成型水性睫毛膏之洗淨力的評估基準〉 ◎ 1 4回以下 〇 1 5〜1 9回 〇△ 20〜24回 △ 2 5〜2 9回 X 30回以上 · 〈對於油性睫毛膏之洗淨力的評估基準〉 ◎ 5回以下 〇 6〜1 0回 〇△ 1 1〜1 5回 △ 1 6〜2 0回 X 21回以上 更且，對於使用（C)成分均勻化之液狀型態的卸妝組成200427467 发明 Description of the invention: [Technical field to which the invention belongs] The present invention relates to a makeup removing composition and a makeup removing material for removing makeup. [Prior art] A technique for removing makeup is known as the use of an aqueous surfactant solution, and the oil is used in the form of a gel, cream, oil, or the like. Among the mascaras that are difficult to remove from make-up cosmetics are water-based mascara containing a water-soluble polymer in order to maintain a curling effect and the like, and oily mascara that is hard to cause makeup loss with sweat and water. However, the conventional aqueous surfactant solution can quickly remove the water-based mascara that can be easily dissolved or dispersed in water, but it cannot remove the oily mascara. Although the oil-based makeup remover can remove the oil-based mascara, it cannot remove water Problems with mascara. With the popularity of mascara in recent years, the film-forming mascara using the film-forming ability of the latex polymer, especially the mascara of succinic ester copolymer with excellent film-forming ability, has increased in oiliness and water. Latex polymer is an emulsion that makes insoluble polymers in water in water. With the evaporation of water, strong bonds between polymer particles are formed and filmed, so it cannot be easily dissolved in water and aqueous surfactant solutions. Disperses and does not dissolve quickly in oil. Therefore, the conventional makeup removal technique using a surfactant aqueous solution and an oil agent once the formed film has a problem that it cannot be effectively removed. For the purpose of removing oiliness and forming an eye makeup cosmetic, in Japanese Patent Laid-Open No. 5-1 6 3 1 1 6 it is disclosed that isoparaffin is added to water with a polyoxyethylene alkyl ether surfactant. Emulsified eye makeup remover 312 / Invention specification (Supplement) / 93-07 / 93111227 200427467. However, it is not sufficient for a mascara which forms a strong film and contains a large amount of an acrylic polymer. In addition, Japanese Patent Laid-Open No. 1 1-5 0 3 4 6 disclosed in Japanese Patent Application Publication No. 1 1-5 0 3 4 6 without using a common surfactant, imparts neutralization properties to a propionate-containing copolymer emulsifier, an oil agent, and an aqueous emulsion. Surfactant technology. Japanese Patent Application Laid-Open No. 9 discloses the coexistence of an oil composition in a large number of polyols used as a humectant. Further, in Japanese Patent Laid-Open No. 6 2-1 3 5 4 0 6, a make-up removal material is made by dispersing a low-boiling isoparaffin and a low-boiling silicone oil in a water phase in polypropylene. Japanese Patent Application Laid-Open No. 9-1 10 6 38 discloses a makeup removing material containing water-soluble polysaccharides and low boiling as essential components. However, although it is a water-based mascara, it cannot effectively remove the film-forming eyelashes. In Japanese Patent Application Laid-Open No. 2-1 0 4 5 1 1, elongated glycol and ethanol, water-soluble polyols, and Composition for cleansing cotton composed of interface activity. In Japanese Patent Laid-Open No. 9-Report, it is disclosed that a composition for removing cosmetics comprising one or two or more polyoxyethylene glucosinolates and polyoxypropylene glycosides and an HLB of 10 or more surfactants is disclosed. Although water-based mascara can be removed, oil-based mascara cannot be effectively removed. On the other hand, as for the sheet-like makeup removing material, the following patent publication No. 2 0 0 1-3 0 2 4 50 is to disclose the milk having a viscosity of 2 0 to 4 0 0 m P a · s The cosmetic material is impregnated with a thin sheet 312 / Invention Manual (Supplement) / 93-07 / 93111227 Dilute acid burning ester co-operation, co-existing with non-emulsion-4 8 7 0 6 male and water The makeup remover reveals that the acidic thickener Kaiping Dot oil and water remove oiliness or hair cream. Reveals the non-ionicity of No. 1 3 0 2 8 olefinic grape based on a polymer and water. However, it is also not pre-technical. Makeup Remover 7 200427467. In addition, in Japanese Patent Laid-Open No. 2 0 3-3 3 5 6 2 7 has a thixotropic two-phase (0 / W type) cosmetic impregnated thin, although the sheet can remove oily mascara and water-based eyelashes Cream, but no film-forming mascara. [Summary of the Invention] The present invention provides a polyoxypropylene structure containing (A) a water phase containing 1 to 25 mass propane addition moles of 3 or more, and having more than one alkyl and / or polyoxyethylene structure. The composition of the water-soluble pseudophase and (B) the liquid oil phase at 30 ° C, the mass ratio of the (A) component (A): (B) is 9 7: 3 to 4 0: 60, water More than 10% by mass of the makeup removing composition. Furthermore, the present invention is to provide a structure containing poly (A) in a water phase] having a propylene oxide addition mole number of 3 or more and having an alkyl group and / or a polyoxyethylene structure having 4 or more carbon atoms. (A) The water phase of the substance (a), and (B) The oil phase containing the oil agent (b), which has a boiling point of 160 to 300 ° C, and 50% by mass or more than 10 1 3, and (C) ； Water-based thickener 0 · 0 1 ~ 1% by mass, and the water phase (A) and oil phase ((A): (B) are 9 7: 3 to 4 0: 60 A sheet-like makeup removing material impregnated into a non-woven fabric having a density of cm 3 composed of fibers with a content of 70% by mass or more. [Embodiment] First, the makeup removing composition of the present invention and the makeup removing material will be described. The oil-in-water type emulsified composition used (the "composition" will be listed above). 312 / Invention Specification (Supplement) / 93-07 / 931] 1227 The disc is disclosed in the newspaper. These thin methods effectively remove% epoxy Moisture with carbon number 4 > The substance (a) is contained in the composition of (B). ~ 25% by mass, and does not have a mass ratio of [the water-repellent part B in the soluble compound 25 h P a] Thing Dimensions 0.15 ~ 0.3g / Inventive sheet-like L is called 8 200427467 The component (A) used in the present invention contains 1 to 25% by mass in the aqueous phase and has a propylene oxide addition mole number of 3 or more. The water phase of a water-soluble compound (a) (hereinafter, referred to as a compound (a)) having a polyoxypropylene structure and having no alkyl groups having 4 or more carbon atoms and / or a polyoxyethylene structure. Although this type of water phase (A) has a small detergency for general oily makeup cosmetics, it has a certain degree of detergency for polymer coatings. By combining this aqueous phase (A) with an excellent detergency for oily makeup cosmetics and an oily phase (B) that has some detergency even for polymer coatings, it can be used for oily eyelashes Creams and other general color cosmetics have high detergency. Furthermore, the removal effect of a film-forming mascara, particularly a mascara copolymer containing a large amount of acryl acrylate copolymer which forms a strong film, is significantly improved. The compound (a) contained in the water phase (A) is composed of polyoxypropylene having a propylene oxide addition mole number of 3 or more from the viewpoint of the detergency of the polymer film. The compound (a) does not have an alkyl group having 4 or more carbon atoms, so it does not show a surfactant-like behavior, and it is difficult to form microcells in water, so it easily enters a fine portion of a polymer film. Furthermore, it is presumed that the polyoxypropylene structure acts on the strong bonding between the polymer molecules and promotes the redispersion of the polymer film with respect to water. Therefore, it is considered that the film-forming mascara has an excellent removal effect. , The distribution of the water phase is increased, and the cleaning effect is reduced. Moreover, the stilbene compound (a) has moderate water solubility. The so-called water solubility herein refers to one having a solubility of 1% by mass or more with respect to water at 25 ° C. The compound (a) contained in the aqueous phase (A) of the present invention is a polyoxypropylene structure with a propylene oxide addition mole number of 3 or more, and a hydroxyl group, glyceryl group, and polyglycerol 9 312 / Invention specification (Supplement) ) / 93-07 / 9311〗 227 200427467 group, or a hydrophilic group compound such as a sugar residue is preferred. Specific examples of the compound (a) include polyoxypropylene diglyceryl ether, polyoxypropylene glyceryl ether, polyoxypropylene methylglucoside, and polypropylene glycol. Polyoxypropylene diglyceryl ether is an addition polymerization polymer of propylene oxide to diglycerin. In addition, the added mole number of propylene oxide is preferably from 4 to 24 moles, and more preferably from 6 to 18 moles for the cleaning power point of the polymer film. Polyoxyglyceryl ethers are those obtained by addition polymerization of glycerol to glycerol. Among them, the addition mole number of propylene oxide is from 8 to 24 moles, and more preferably from 8 to 16 moles from the viewpoint of the cleaning power of the polymer film. Polyoxypropylene methylglucoside is a polymer of propylene oxide by addition of p-methylglucoside. Among them, the addition mole number of oxypropane is from the viewpoint of the detergency of the polymer film, preferably 5 to 25 moles, and more preferably 10 to 20 moles. Polypropylene glycol From the viewpoint of the detergency of the polymer film, the addition mole of propylene oxide is preferably 5 to 20 moles, and more preferably 7 to 16 moles. Among them, polyoxypropylene diglyceryl ether and polyoxypropylene diglyceryl ether have the effect of penetrating into the skin, and they are not sticky after use, and provide a wet touch. Therefore, polyoxypropylene diglyceryl ether is preferred. Especially good. The compound (a) contained in the water phase (A) may be used singly or in combination of two or more kinds. The amount of the compound (a) in the aqueous phase (A) is 1 mass% or more relative to the total amount of the aqueous phase (A) from the viewpoint that a sufficient detergency can also be obtained for the film-forming mascara. Less than 25% by weight of skin does not leave a feeling of residue. From the balance of detergency and feeling of use, it is more preferable to use 3 to 20% by mass, and particularly preferably 5 to 15% by mass with respect to the total amount of water (A). The amount of water contained in the water phase (A) is based on sufficient detergency and a good feeling of use. 312 / Invention Manual (Supplements) / 93-07 / 93111227 The diazepam is shown to be moisturized by the ear. In terms of Phase 10 200427467, it is more preferable that the total content of the composition is more than 10% by mass, more preferably 30% by mass or more, and particularly preferably 50% by mass or more. The water phase (A) contains the above-mentioned compound (a) and water as main components, and may contain other water-soluble components. For example, the use of alcohols such as ethanol and polyhydric alcohols can improve the usability. In particular, the blending of ethanol has a high effect in improving the refreshing feeling, and the blending of 1,3-butanediol and glycerin has an effect of improving the moisturizing feeling. Secondly, the component (B) used in the present invention is a liquid oil phase at 30 ° C, and has excellent detergency for oily mascara and general oily makeup cosmetics. In addition, the polymer film has a dissolving power which is not available in the (A) component, and has a small cleaning power. The low viscosity oil phase has high permeability to fine parts and high solubility of pollutants, so it has high detergency. Furthermore, it is not accompanied by strong oily sensuality and also has a good use feeling. Therefore, the oil phase (B) preferably has a viscosity of 10 m P a · s or less at 30 ° C. The oil phase (B) can be used in combination with one or two or more oily components. In the case where two or more kinds of oily components are used as the oil phase (B) in combination, even if a non-liquid oily component is used at 30 ° C, and a component having a value greater than 10 m P a · s at 30 ° C is used. An oily component having a viscosity of 2 or more is suitable for use if the total viscosity is 10 m P a. S or less. Here, the viscosity is measured with a BM-type viscosity meter (for example, manufactured by Tokimake) (measurement conditions: Rotor No. 1, 60 rpm) 0 having 10 m P at 30 ° C a. Specific examples of the oily component having a viscosity of s or less include mobile isoparaffin, alkyl 1,3-difluorenyl butyl ether (Japanese Patent Laid-Open No. 9-8 7 2 2 3), and 2-ethylhexyl Cetyl myristate, isopropyl myristate 11 312 / Invention Specification (Supplement) / 93-07 / 93111227 200427467 ester, isopropyl palmitate, isononyl isononanoate, isododecyl isononanoate, Diisobutyl adipate, diisopropyl adipate, octadecyltrisiloxane, decadecylcyclopentasiloxane, dodecylpentasiloxane, octamethylcyclotetrasiloxane Wait. Among them, an oily component having a molecular weight of 300 or less is detergency, and it has an excellent use feeling with less oily feeling after use, so it is more preferable. Specific examples include light flowing isoparaffin, isopropyl myristate, isopropyl palmitate, isononyl isononanoate, diisobutyl adipate, diisopropyl adipate, and Fluorenyltrisiloxane, octamethylcyclotetrasiloxane, etc. In addition, the oil agent (b) having a boiling point of 160 to 300 ° C at 10 1 3. 2 5 h is low in viscosity, has high permeability to fine parts, and dissolves makeup pollutants. Highly decomposable or decomposable. In addition, a low boiling point oil agent is not accompanied by strong oiliness and has a small residual feeling after use. Therefore, it is particularly suitable to impregnate a sheet and use it for wiping. At this time, the above-mentioned oil agent (b) is from the viewpoint of the cleansing performance and the feeling of oiliness of the oily makeup cosmetics, and contains 50% by mass or more, particularly 70% by mass, with respect to the entire amount of the oil phase (B). The above is better. Among them, an oil agent having a boiling point in 10 1 3. 2 5 h P a of 16 0 to 2 50 ° C is preferred from the viewpoint of weak skin residual feeling after use, and moreover, at 1 0 1 3 · 2 5 h The boiling point in P a is 16 0 ~ 2 3 0 ° C, especially 16 0 ~ 2 1 0 ° C. The oil remover has a makeup removing performance and does not leave oil on the skin. It's better. Examples of the oil agent (b) include a light-flowing isoparaffin, a volatile silicone oil, and the like, and it is particularly preferable to use a light-flowing isoparaffin from the viewpoint of cleansing performance. These oil agents (b) may be used singly or in combination of two or more kinds. 12 312 / Instruction of the Invention (Supplement) / 93-07 / 93111227 200427467 Light-flowing isoparaffin is generally a mixture of branched hydrocarbons with 8 to 18 carbons, and it is unique if it contains low molecular weight hydrocarbons odor. Such odors are sometimes unpleasant to the user, so it is better not to contain low-molecular-weight components with 8 to 9 carbons as much as possible. On the other hand, if a large number of hydrocarbons containing 16 to 18 are contained, the cleaning power is poor, and the oily feeling after use tends to be strong. From such viewpoints, it is preferable to contain a large number of heterochain hydrocarbon-based hydrocarbons having 10 to 15 carbon atoms. Among these, from the balance of odor, feeling of use, and makeup removing performance, it is preferable to contain a large amount of isododecane having 12 carbon atoms. In particular, an oil agent containing 90% by mass or more of isododecane is more suitable for use in the present invention. Examples of light flowing isoparaffins include the trade names Makassol R (MARCAS 0 LR) (Maruzen Petrochemical), IP Solvent 1 6 2 0 (IP SOLVENT 1 6 2 0), IP Solvent 2 0 2 8 (IPS 0 LVENT 2 0 2 8) (above, Idemitsu Petrochemical), Aesop L (ISOPERL), Aisop H (ISOPERH) (above, EXON chemistry), Aesop 300, 400 USOSOL 300, 400) (Above, Nippon Petrochemical) and the like, but from the viewpoint of containing high-purity isododecane, MARCASOL R (Maruzen Petrochemical) is particularly suitable for use. Examples of the volatile silicone oil include low-polymerization chain chains of octamethyltrisiloxane (boiling point: 15 3 ° C), dodecylpentasiloxane (boiling point: 2 2 9 ° C), and the like. Cyclosiloxane oils such as fluorenyl polysiloxane, octadecylcyclotetrasiloxane (boiling point 17 2 ° C) and decadecylcyclopentasiloxane (boiling point 2 05 ° C). The oil phase (B) has a mass ratio (A): (B) to the water phase (A) of 9 7: 3 ~ from the viewpoint of obtaining sufficient detergency and a good feeling of use without oily feeling. 4 0: 6 0, preferably 9 0: 1 0 to 7 0: 3 0, particularly preferably contains 8 8: 1 2 to 7 5: 13 312 / Explanation of the invention *: (Supplement) / 93-07 / 93111227 25 ° 200427467 The mixture of the water phase (A) and the oil phase (b) is separated into two phases if placed, and can be temporarily homogenized by shaking and mixing, and this mixture is included in the cotton pad for makeup and wiped.栻 Make-up, or use it by hand, and dissolve contaminants. In addition, the mixture may be impregnated with a sheet-like base material such as a non-woven fabric, or a sheet-like makeup remover. When only the water phase (A) and the oil phase (B) are easily separated into two phases in a short time, for the purpose of easier use, the makeup remover composition of the present invention may contain an aqueous tackifier as (C) ingredient. With the inclusion of an aqueous thickener, the mixture can be kept in a uniform state when the mixture is oscillated and mixed, and because the viscosity is easily increased, the solubility and massage properties to the skin are also improved. Specific examples of the water-based thickener include the following water-soluble polymers. Examples of natural water molecules include: gum arabic (jum A rabic), gum tragacanth, galactan (G a 1 actan), Gum Guaiac, Carob Gum, Karaya Gum, Carrageenan, Pectin, Agar, Quince seed gum, Brown algae extract Plants, starch, rice (maize, maize, potato, wheat), glycyrrhizic acid (Glycyrrhi zinicacid) and other plant-based polymers, xanthan Gum, dextrin, succinoglucan ( Succinoglucan, Pul lu lan, etc. are high in microorganisms, collagen (coll lag en), protein (Casein), albumin (Albumin), gelatin (Gelatin) and other animal systems. Molecules. Semi-synthetic water-soluble polymers include, for example, starch-based polymers such as carbohydrazone powder, methylhydroxypropyl starch, fluorenyl cellulose, 14 312 / Invention Specification (Supplement) / 93-07 / 93111227 200427467 nitrocellulose, ethyl cellulose, fluorenyl hydroxypropyl cellulose Cellulose, macromolecules, hydroxyvitamin, sodium sulfate cellulose, hydroxypropyl cellulose, carboxymethyl cellulose, etc., cellulose polymers, sodium alginate, propylene glycol alginate, etc. Synthetic water-soluble polymers Examples include polyvinyl alcohol alkenyl ether-based polymers, polyvinylpyrrolidone, and carboxyvinyl poly (CARB0P0L 940, 941; Noveon, Inc.) and other polymers and polyethylene glycol. 2 0 0 0 0, polyethylene glycol 6 0 0, polyethylene oxide and other polyoxyethylene-based polymers, polyoxyethylene-baked polyoxypropylene copolymers, copolymerization system polymers, sodium polyacrylate, polyacrylic acid Acrylic polymers such as ethyl esters, amidines, polyethylenimines, cations, etc. Moreover, if a water-based thickener is used which has a water repellent part, the phase (A) can be thickened, and The oil phase (B) is a uniformly dispersed preparation in an oil-in-water type. The so-called water-based tackifier having a water-repellent portion has a chain of water-soluble polymers having 10 or more carbon atoms in the water-repellent group. Special Regarding the composition sheet used in the sheet-like makeup remover of the present invention, it is difficult to cause a composition change, and in order to obtain For the retention and good detergency of makeup materials, the water system with a water repellent part is used as the (C) component to form an oil-in-water emulsified composition, and it is impregnated. If a water-based thickener is used, Those in the water-repellent department interact with the water-repellent oil agent to make the oil agent more stable in water. Because the oil agent is emulsified finely with the usual surfactant, it is easy to release the oil agent. Does not impair the detergency. That is, if using 312 / Invention Specification (Supplement) / 93-07 / 93111227 Ethylcellulose (CMC) alginic acid type, polyethylene polymer such as vinyl alcohol 4 00 0 body, etc. to make water view All of the above refers to side objects, and the presence of tackifiers in the sheet material is not suitable for the use of such water. 15 200427467 series of tackifiers, the oil agent in the composition is to the extent that the cleaning power is not impaired. It can disperse on the top and improve the uniformity and stability of the liquid, and can exert the stability performance as a sheet-like makeup remover. It is thought that after the composition is impregnated in the sheet, the water-based tackifier polymer is intertwined with the oil agent in the fiber, so that the oil can be stably maintained in the sheet. Examples of the water-based tackifier having such a water-repellent part include an acrylic acid / alkyl acrylate (C10 to C30) copolymer (manufactured by Noveon, Inc., trade name: PEMULEN TR-1) , Embryo-membrane TR-2 (PEMULEN TR-2), CARB0P0L ETD, etc.), hydroxyethyl cellulose hydroxypropyl stearate ether hydroxypropyl sulfonate (Japanese Patent Laid-Open No. 9-2 3 5 3 0 1 Bulletin) and so on. These water-based thickeners (C) may be used alone or in combination of two or more. When used in the makeup remover composition of the present invention, the content of the water-based tackifier (C) is from 0.01 to 5% by mass relative to the total amount of the composition in terms of ease of use, spread on the skin, and slippery feel. More preferably, it is more preferably 0. 0 to 1 to 2% by mass, particularly ◦. (H to 1% by mass is preferable. In particular, the sheet-like makeup remover of the present invention is impregnated and used in an oil-in-water emulsion composition. At the time, the content of the water-based thickener having a water-repellent part is 0.01% by mass or more with respect to the total amount of the composition from the aspect of emulsification stabilization of the emulsified composition. 1〜0. 5 With respect to the viscosity of the material and good processability, it is less than 1% by mass relative to the total amount of the composition. Among them, from the balance of emulsification stability and processability, the total amount of the composition is 0.1 to 0.5. A mass% range is preferred. If necessary, a neutralizing agent that neutralizes and thickens the above-mentioned water-based thickener may be used. Examples of the neutralizing agent include 16 312 / of sodium hydroxide and potassium hydroxide. Invention Specification (Supplement) / 93-07 / 93111227 200427467 None Alkali agents, basic amino acids such as L-arginine, amines such as triethanolamine, gas, etc. The addition amount of the neutralizing agent may be determined according to the type and amount of the water-based thickener. The total amount of the composition is preferably about 0.05 to 0.5% by mass. The neutralizing agent may be dissolved in water in advance, or it may be directly mixed with the water-based thickener and added. In the emulsified system using a surfactant, oil The agent is not stably dispersed in the system and cannot fully exert the makeup removal performance, so the function of emulsification or dispersion stabilization is preferably the aforementioned water-based tackifier. Therefore, in the present invention, the surfactant does not damage the present invention Within the scope of the effect, it can be used in small amounts for the purpose of improving the skin's solubility or the composition's wettability and permeability to the sheet. The surfactant does not hinder the water phase (A) and oil Phase (B) is used in a range of makeup removing performance. The content of the surfactant is preferably 2% by mass or less, more preferably 0.5% by mass or less, and particularly less than 0.5% by mass relative to the total amount of the composition. Better.Interfacial activity One or two or more agents can be used. Specific examples include polyoxyethylene alkyl ethers and sucrose fatty acid esters, fatty acid monoglycerides, sorbitan fatty acid esters, and polysaccharides thereof from the viewpoint of mild skin. Oxyalkylene addition molding, polyoxyethylene hardened castor oil and its fatty acid esters, polyoxyalkylene fatty acid esters, etc. In addition to the above components in the composition of the present invention, for example, moisturizers and oils Various additives such as gelling agents, ultraviolet absorbers, perfumes, pigments, dyes, salts, stabilizers, preservatives, antioxidants, vitamins, proteins, and conditioning agents can be used without impairing the purpose and effect of the present invention. 312 / Invention Specification (Supplement) / 93-07 / 93111227 200427467 Add within the range of quality and quantity. The makeup removing composition of the present invention can be produced by the conventional methods using the above-mentioned materials, and can be prepared into a liquid form, a gel form, a cream form, and a two-phase separation form. Methods for removing makeup using the makeup remover composition of the present invention include a method of homogenizing the composition as it is or a vibrational mixture, immersing it in a wiping medium and wiping the makeup on the skin, and applying by hand and applying to the skin. Make-up is dissolved and wiped or rinsed with a wiping medium. Here, examples of the wiping medium include cotton pads and paper towels. As described above, the makeup remover composition of the present invention contains 1 to 25 mass% of a polyoxypropylene structure having a propylene oxide addition mole number of 3 or more in an aqueous phase, and does not have an alkane having 4 or more carbon atoms. The water phase of the water-soluble compound (a) with a base and / or polyoxyethylene structure and the liquid oil phase at 30 ° C are combined, and the total composition contains more than 10 mass ° / ◦ water, It can be effectively removed not only for ordinary make-up, but also for mascara which is difficult to remove, especially for oily mascara and latex polymer containing a large amount of film-forming agent, which can form a strong film of an alkyl acrylate copolymer. Film-forming mascara can also show good makeup removal performance. The makeup remover composition of the present invention can effectively remove all makeup, and is a makeup remover composition with excellent usability. Next, the sheet-like makeup remover of the present invention will be described. The above-mentioned makeup removing composition contains (A) a water phase containing 1 to 25% by mass of a polyoxypropylene structure having a propylene oxide addition mole number of 3 or more, and having no alkyl groups having 4 or more carbon atoms and / Or the water phase of the water-soluble compound (a) with a polyoxyethylene structure and (B) contains 50% by mass or more of 10 1 3 · 2 5 h 18 of P a 312 / Invention Specification (Supplement) / 93-07 / 93 111 227 200427467 Oil phase of oil agent (b) with boiling point of 16 0 ~ 3 0 0 ° C, and (C) water-based thickener with water repellent part 0 · 0 1 ~ 1 mass% And the mass ratio (A): (B) of the water phase (A) to the oil phase (B) is 9 7: 3 to 4 0: 60, from the viewpoint of excellent makeup removing performance and use feeling, An oil-in-water emulsified composition impregnated with a sheet-like substrate is particularly suitable. In the sheet-like makeup remover of the present invention, the above-mentioned oil-in-water emulsion composition is impregnated with a specific nonwoven fabric. Since the makeup removing material of the present invention is sheet-like, it can be used immediately, and makeup can be removed simply by wiping, so makeup can be removed easily and quickly. The viscosity of the oil-in-water emulsified composition used for the sheet-like makeup remover is preferably less than 2000 m P a · s from the impregnation efficiency during processing, and the ease of exuding liquid from the sheet during use In particular, 300 m to 800 m P a · s is preferred. Here, the viscosity refers to a value measured under the conditions of R 0 t 〇 r Ν 〇 2, 6 r p m, and 30 ° C using a BM viscometer (manufactured by Ducmec). In addition, the oil-in-water emulsion composition used for the sheet-like makeup remover may be separated over time when left to stand, and may be separated into a transparent water phase and an oil-in-water emulsion phase. Specifically, after being uniformly prepared, when it is left at 30 ° C, it is separated (extracted) into a slightly unstable emulsified composition of the aqueous phase and other emulsified phases within 1 month or more and 1 month. It is better in terms of usability. In this case, impregnation of the nonwoven fabric is performed before separation. When the emulsified composition is a slightly unstable emulsified composition, the aqueous phase is also a stable emulsified composition thickened by the polymer compound, and the liquid exuded from the sheet is good during use, and the makeup removal performance is excellent. The non-woven fabric used as the base material in the sheet-like makeup removing material of the present invention has a good muscle feel during use 19 312 / Invention Specification (Supplement) / 93-07 / 93111227 200427467, and even stored in a laminated form for a long time In terms of stability and quality maintenance, a fiber having a cellulose content of 70% by mass or more and a density of 0.15 to 0.3 g / c m3 can be used. As it is hydrophilic and impregnated in a non-woven fabric having a higher density, even if a slightly unstable emulsified composition which causes separation due to storage is used, the non-woven fabric can be stabilized to maintain the aqueous phase of the emulsified composition external phase, and The water-based tackifier polymer containing the oil agent is entangled between fibers and stably maintains the oil agent in the non-woven fabric, so that the movement of the emulsified composition in the non-woven fabric is suppressed, and the The amount and composition of the emulsified composition. In order to suppress the movement of the oil-based emulsified composition in the sheet substrate in the impregnated water, the non-woven fabric preferably has a hydrophilic property capable of stably preserving the aqueous phase of the outer phase. That is, the non-woven fabric is constituted by using a fiber having a cellulose content of 70% by mass or more. From the viewpoint of stably maintaining the aqueous phase of the external phase, it is preferred that the cellulose content be 80% by mass or more. Specific examples of the cellulose fiber include cotton flakes and rayon. In particular, cotton pads are not slippery during use, and have a moist feeling to remove the contaminants. Further, in terms of obtaining a smooth skin feel, it is preferable to obtain a non-woven fabric by a water flow entanglement method. If the above range is satisfied, the water-repellent fibers can be mixed to modify the sheet. Examples of the water-repellent fiber include polyester-based fibers and polyolefin-based fibers. For example, polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polypropylene (PP), polyethylene (PE), and the like. In addition, in order to stably maintain the composition of the oil-based emulsified composition in impregnated water, and to suppress the liquid from moving up and down in the laminated sheet, the non-woven fabric is made higher. 20 312 / Invention Specification (Supplement) / 93-07 / 93111227 200427467 The density is better. From the point that the liquid does not move to the lower point through gravity, the density of the non-woven fabric is 0.15g / cm3 or more, and the other side of the immersion liquid is easy to penetrate into the sheet, and the use of the sheet is soft to the touch. To 0.3 g / c m3 or less. From the viewpoint of suppressing the movement of the liquid and the feeling of use, the density of the non-woven fabric is particularly preferably 0.17 to 0.25 g / cm3. In addition, the average weight of the non-woven fabric (weight per unit area) is not twisted, and the use is good, and the viewpoint that the pollutants do not move inward is preferably 40 g / m2 or more. From the viewpoint of bulkiness and feeling, it is preferably 100 g / m2 or less. In particular, 50 m2 is easy to handle during use, and it can show a moderate bulkiness when laminated. Therefore, the non-woven fabric can be a material in which two or more types of non-woven fabrics are overlapped or bonded. In addition, the shape of the non-woven fabric is preferably a shape that can be easily accessed by a human hand, for example, a square or a square with a diameter of about 5 to 20 cm, a circle, an oval, and a thickness of 0.2 to 0. About 5 mm is the amount of oil-in-water emulsified composition impregnated with 1 g of non-woven fabric. From the viewpoint of good use feeling, 2 to 5 g is preferred, and 2.5 to 4.5 g is particularly preferred. The sheet-like makeup remover of the present invention can be manufactured by drip-coating or drip-feeding the nozzle of an emulsification group through a non-woven fabric, or by spray impregnation, and then leaving it to stand and the material is sufficiently mixed. The sheet-like makeup removing material of the present invention is sealed for use in each animal or in a plurality of animals. When using, open the bag, remove the makeup remover from the bag, and touch it to the part where you want to remove the makeup makeup. Use the makeup makeup. Therefore, for various types of make-up 312 / Invention Manual (Supplements) / 93-07 / 93111227, the surface of the material is balanced with dots and wiped with a soft touch of ~ 80 g /. The flakes are small, thick and long. The content of the finished product is a thin sheet and a piece in the bag to wipe the contaminants 21 200427467 can exert excellent makeup remover effect, and can easily and quickly remove makeup. Therefore, the sheet-like makeup remover of the present invention can not only easily and quickly remove ordinary makeup such as foundations, lipsticks, etc., but also remove water-based mascara and oil-based mascara. Furthermore, it can also remove the formation of a film containing a large amount of an alkyl acrylate copolymer. Type mascara. The muscle feel is excellent during and after use, and it is also a makeup remover with excellent quality and stability in the form of the product laminated on the sheet. (Embodiments) The present invention will be described in more detail with reference to the following examples, and embodiments of the present invention will be clearly shown. Example A series: makeup removing composition (method for evaluating detergency) To evaluate the detergency, an oily mascara and a film-forming water-based mascara mixed with an alkyl methacrylate copolymer were used. The specified amount of mascara was evenly coated on a glass slide in a circular shape with a diameter of 1.2 cm, and left to dry for 12 hours. The film-forming water-based mascara was made by Kane bo company TEST IMO MASCARA EFFECT CURLL 0 NGBK 1 8 was applied at 0.07 g, and the oily mascara was coated with Sports BEAUTY FASIO POWER STAY MASCARA CURLLONG BK00 1 manufactured by Kose Corporation at 0. 0 0 4 5 g. Depending on the liquid properties of each mascara, the amount of application when the mascara is uniformly applied over a certain area is different. The makeup remover composition composed of the components (A) and (B) can be quickly separated even if mixed. Therefore, when evaluating the cleaning power, make 1 g of a cotton sheet containing 3.8 g of the makeup remover and gently rub the cotton sheet. After the composition is uniformized across the entire cotton sheet, press the mascara with cotton sheet 22 312 / Invention Manual (Supplement) / 93-07 / 93111227 200427467, and press it for 5 seconds with a certain pressure (1 0 0 g / cm 2) Wipe, measure the number of wipes necessary to remove the mascara, and evaluate each mascara according to the following criteria (Example A and Comparative Example A and A 5). 〈Evaluation criteria for the detergency of the film-forming water-based mascara〉 ◎ 14 times or less 〇 1 5 to 19 times 〇 20 to 24 times △ 2 5 to 2 9 times X 30 times or more 〈For oily Evaluation Criteria for Washing Power of Mascara> ◎ 5 times or less 〇6 ~ 1 0 times △ 1 1 ~ 1 5 times △ 1 6 ~ 2 0 times X 21 times or more Liquid makeup remover

物，同上述，於載玻片上塗佈、且乾燥之睫毛膏，塗佈卸 妝組成物0 . 1克，且對於被膜形成型水性睫毛膏6 0回、對 於油性睫毛膏3 0回，以指按摩令污染物浮起並以紙巾擦 拭，依據下列之評估基準予以評估（實施例A 2〜A 9，比較例 A6〜A1 1 ) ° 〈對於各睫毛膏之洗淨力的評估基準〉 ◎ 睫毛膏充分掉落。 〇睫毛膏幾乎完全掉落。 23 312/發明說明書(補件)/93-07/93111227 200427467 〇△睫毛膏為一部分殘留掉落。 △ 睫毛膏頗多未掉落。 X 睫毛膏未掉落。 (使用感之評估方法） 於專門評審員1 〇名之臉上均勻且適量塗佈卸妝組成 物，對於使用感（發黏、滑溜）以「良好」、「稍微良好」、「任 一者均未指出」、「頗不良好」、「不良」之五階段予以官能 評估，並以下列基準判定。 [評估基準] ◎: 10 名 中 9名 以 上 為 回 答 『 良 好 j 或 稍 微 良好 〇： 10 名 中 7〜8 名 為 回 答 『 良 好 j 或 『 稍 微 良 好』。 Δ : 10 名 中 4〜6 名 為 回 答 r 良 好 或 1Γ 稍 微 良 好』。 X ：10 名 中 3名 以 下 為 回 答 『 良 好 或 Γ 稍 微 良好 (實施例A 1、比較例A 1〜A 5 ) 以表A - 1所示之組成製造卸妝組成物，且評估使用各卸 妝組成物時之對於被膜形成型水性睫毛膏的洗淨力、對於 油性睫毛膏的洗淨力、及使用感。各卸妝組成物之評估結 果示於表A-1。 24 312/發明說明書(補件)/93-07/93111227 200427467The same thing as above, the mascara applied and dried on the glass slide was coated with 0.1 g of the makeup removing composition, and 60 times for the film-forming water-based mascara and 30 times for the oily mascara. The massage lifts the contaminants and wipes them with a paper towel, and is evaluated according to the following evaluation criteria (Example A 2 to A 9, Comparative Examples A6 to A1 1) ° <Evaluation Criteria for the Detergency of Each Mascara> ◎ Eyelashes The cream is fully dropped. 〇 The mascara dropped almost completely. 23 312 / Invention Manual (Supplement) / 93-07 / 93111227 200427467 〇 △ Mascara is left as a part. △ Quite a lot of mascara did not fall off. X Mascara does not fall. (Evaluation method of the feeling of use) Apply the makeup remover composition evenly and appropriately on the faces of 10 specialized reviewers. For the feeling of use (sticky, slippery), "good", "slightly good", "any The five stages of "not pointed out", "very poor", and "bad" will be evaluated based on the following criteria. [Evaluation criteria] ◎: 9 or more of the 10 people answered "Good or slightly better": 7 of 8 out of 10 answered "Good or J" or "Slightly good". Δ: 4 to 6 out of 10 people answered that r is good or 1Γ is slightly good. " X: 3 out of 10 people answered "Good or Γ is slightly good (Example A 1, Comparative Examples A 1 to A 5). Makeup remover compositions were prepared with the composition shown in Table A-1, and each makeup remover composition was evaluated for use. The detergency for the film-forming water-based mascara, the detergency for the oily mascara, and the feeling during use. The evaluation results of each makeup removing composition are shown in Table A-1. 24 312 / Invention Specification (Supplement) / 93-07 / 93111227 200427467

實施例 比較例 A1 A1 A2 A3 A4 A5 (A) (a)聚氧丙烯（9)二甘油醚 10 0 30 10 5 10 精製水 75 85 55 90 25 5 1，3-丁二醇 0 0 0 0 0 70 (B) 異十二烷 15 15 15 0 70 15 合計 100 100 100 100 100 100 成分（A)中之（a)濃度（質量％) 12 0 35 10 17 12 質量比（A) : (B) 85 ： 15 85 : 15 85 : 15 100 ： 0 30 ： 70 85 ： 15 評 價 對於被膜形成型水性睫毛 膏之洗淨力 ◎ Δ Δ 〇△ ◎ Δ 對於油性睫毛膏之洗淨力 ◎ ◎ ◎ X ◎ ◎ 使用感 ◎ Δ 〇 ◎ X Δ 由表A - 1所示之結果，實施例A 1為令（A )、（ B )二成分 以本發明所特定之比例配合，可有效除去配含大量丙烯酸 烷酯共聚合體之被膜形成型睫毛膏及油性睫毛膏兩者，且 使用感亦為優良。另一方面，（A)成分中未含有化合物 (A )(比較例A 1 )或化合物（a )為以水相濃度含有2 5質量％以 上（比較例A 2 )之組成物，即使令油性睫毛膏掉落，對於被 膜形成型睫毛膏的洗淨力亦差於實施例。又，不含有（B ) 成分之組成物（比較例A 3 )雖對於被膜形成型睫毛膏具有 洗淨力，但對於油性睫毛膏的洗淨力不夠充分，顯然經由 組合（A )成分和（B )成分，則不僅對於油性睫毛膏之洗淨 力，且對於大量配合丙烯酸烷酯共聚合體的被膜形成型睫 毛膏的洗淨力亦顯著提高。含有（A )成分與（B )成分兩者， 但質量比（A ) : ( B )為9 7 : 3〜4 0 : 6 0範圍外的組成物（比較 例A 4 )，雖可有效除去油性睫毛膏及被膜形成型睫毛膏兩 者，但因油性感強，故使用感不及實施例。又，組成物中 25 312/發明說明書(補件)/93-07/93111227 200427467 之水濃度為1 0質量％以 量丙稀酸烧酯共聚合體 感不及實施例。 (實施例A 2〜A 9、比較例 以表A-2所示組成製 有（C )成分的組成物，並 被膜形成型水性睫毛膏 力、及使用感。各卸妝 下（比較例A 5 )，並無 的睫毛膏，且因滑溜 A6〜A7) 造卸妝組成物，做為 且評估使用各卸妝組 的洗淨力、對於油性 組成物的評估結果示 法除去配合大 和發黏故使用 本發明之再含 成物時之對於 睫毛膏的洗淨 於表A - 2。Examples Comparative Examples A1 A1 A2 A3 A4 A5 (A) (a) Polyoxypropylene (9) Diglyceryl ether 10 0 30 10 5 10 Purified water 75 85 55 90 25 5 1,3-butanediol 0 0 0 0 0 70 (B) Isododecane 15 15 15 0 70 15 Total 100 100 100 100 100 100 (a) Concentration (mass%) of component (A) 12 0 35 10 17 12 Mass ratio (A): (B ) 85: 15 85: 15 85: 15 100: 0 30: 70 85: 15 Evaluate the detergency of the film-forming water-based mascara ◎ Δ Δ 〇 △ ◎ Δ The detergency of the oily mascara ◎ ◎ X ◎ ◎ Feeling of use ◎ △ ○ ◎ X Δ From the results shown in Table A-1, Example A 1 is to make the two components (A) and (B) in the proportion specified by the present invention, which can effectively remove a large amount of ingredients Both the film-forming mascara and the oily mascara of the alkyl acrylate copolymer have excellent use feeling. On the other hand, the component (A) does not contain the compound (A) (Comparative Example A 1) or the compound (a) is a composition containing 25% by mass or more (Comparative Example A 2) in a water phase concentration, even if it is oily The mascara dropped, and the cleaning power of the film-forming mascara was also inferior to that of the examples. Also, the composition (Comparative Example A 3) containing no component (B) has a detergency for the film-forming mascara, but the detergency for the oily mascara is not sufficient. Obviously, the combination of the (A) component and ( The component B) not only improves the detergency of the oily mascara, but also significantly improves the detergency of the film-forming mascara mixed with the alkyl acrylate copolymer. Contains both (A) component and (B) component, but a composition (Comparative Example A 4) outside the range of mass ratio (A) :( B) of 97: 3 to 40:60, although it can be effectively removed Both the oily mascara and the film-forming mascara have a poor oily feel, and therefore they are inferior to the examples. In addition, the water concentration of 25 312 / Invention Specification (Supplement) / 93-07 / 93111227 200427467 in the composition was 10% by mass or less, and the acrylic copolymer was not as good as the examples. (Example A 2 to A 9, Comparative Example A composition having the component (C) in the composition shown in Table A-2, a film-forming water-based mascara, and a feeling of use. Under each makeup remover (Comparative Example A 5 ), No mascara, and slippery A6 ~ A7) Make makeup remover composition, and evaluate and use the cleansing power of each makeup remover, the evaluation results for oily composition are shown in addition to the use of Yamato sticky The washing of the mascara when the invention contains the product is shown in Table A-2.

312/發明說明書(補件)/93-07/93111227 26 200427467 表 A-2(l) 實施例 A2 A3 A4 A5 A6 (A) (a) 聚氧丙烯（9)二甘油醚 0 0 0 0 5 聚氧丙稀（10)甘油醚 0 0 0 10 0 聚氧丙烯（10)曱基葡萄糖苷 0 0 10 0 0 聚丙二醇（10) 10 10 0 0 0 甘油 0 0 0 0 0 乙醇 0 0 0 0 0 1,3-丁二醇 5 5 5 5 5 氫氧化鉀液(48%) 0.017 0.017 0.017 0.017 0.017 精製水 64. 363 64. 363 64. 363 64. 363 74.318 苯氧基乙醇 0.3 0.3 0.3 0.3 0.3 對羥基苯曱酸曱酯 0.2 0.2 0.2 0.2 0.2 (a，） 聚氧乙烯(3. 5)聚氧丙烯(7)丁醚 0 0 0 0 0 聚丙二醇(34) 0 0 0 0 0 (B) 異十二烷 0 15 20 20 15 異壬酸異壬酯 15 0 0 0 0 棕櫊酸異丙酯 5 5 0 0 0 (C) PEMULEN TR-2 *1 0.04 0.04 0.04 0.04 0.04 SPS *2 0.08 0.08 0.08 0.08 0.08 界面活 性劑 單月桂酸聚乙二醇酯（12E.0.) 0 0 0 0 0.045 單油酸聚氧乙烯山梨糖醇酐 (20E. 0·) 0 0 0 0 0 合計 100 100 100 100 100 成分A中之(a)濃度（質量％) 13 13 13 13 6 質量比(A) : (B) 79 ： 20 79 ： 20 79 ： 20 79 ： 20 84 ： 15 評價 對於被膜形成型水性睫毛膏之洗淨 力 〇 ◎ ◎ ◎ ◎ 對於油性睫毛膏之洗淨力 〇△ 〇 ◎ ◎ ◎ 使用感 〇 〇 〇 ◎ ◎ 27 312/發明說明書(補件)/93-07/93111227 200427467 表 A-2(2) 實施例 比較例 A7 A8 A9 A6 A7 (A) (a) 聚氧丙稀（9)二甘油醚 5 5 5 0 0 聚氧丙烯（10)甘油醚 0 0 0 0 0 聚氧丙烯（10)曱基葡萄糖苷 0 0 0 0 0 聚丙二醇（10) 0 0 0 0 0 甘油 5 0 0 0 0 乙醇 0 10 0 0 0 1，3_丁二醇 5 5 5 5 5 氫氧化鉀液(48%) 0.017 0.017 0.017 0.017 0.017 精製水 69.318 64.318 72. 363 69.318 69.318 苯氧基乙醇 0.3 0.3 0.3 0.3 0.3 對羥基苯曱酸曱酯 0.2 0.2 0.2 0.2 0.2 (a，） 聚氧乙烯（3. 5)聚氧丙烯（7) 丁醚 0 0 0 10 0 聚丙二醇（34) 0 0 0 0 10 (B) 異十二烷 15 15 15 15 15 異壬酸異壬酯 0 0 0 0 0 棕櫚酸異丙酯 0 0 0 0 0 (C) PEMULEN TR-2 氺1 0.04 0.04 0.04 0.04 0.04 SPS *2 0.08 0.08 0.08 0.08 0.08 界面活 性劑 單月桂酸聚乙二醇酯 (12E. 0.) 0.045 0 2 0.045 0.045 單油酸聚氧乙烯山梨糖醇酐 (20E· 0.) 0 0.045 0 0 0 合計 100 100 100 100 100 成分(A)中之(a)濃度（質量％) 6 6 6 0 0 質量比(A) ·· (B) 84 ： 15 84 ： 15 84 ： 15 — — 評價 對於被膜形成型水性睫毛膏之洗 淨力 ◎ ◎ 〇△ Δ Δ 對於油性睫毛膏之洗淨力 ◎ ◎ 〇△ Δ 〇 使用感 ◎ ◎ ◎ 〇 〇 28 312/發明說明書(補件)/93-07/93111227 200427467 還有，使用材料之由來示於下。 *1 丙烯酸·曱基丙烯酸烷酯共聚合體：商品名PEMULEN TR-2、 Noveon,Inc. *2 羥乙基纖維素羥丙基硬脂醚羥丙基磺酸鈉（日本專利 特開平9 - 2 3 5 3 0 1號公報） 加入具有斥水部之水系增黏劑做為（C )成分之液狀卸妝 組成物的實施例A 2〜A 9，因為（A )成分與（B )成分為呈均勻 乳液狀，故不使用棉片而直接塗佈以評估洗淨力。由表A - 2 所示之結果可知，於實施例A 2〜A 9中，經由令（A )、（ B )二 成分以本發明特定之比例配合，則可有效除去配合大量丙 烯酸烧酯共聚合體的被膜形成型睫毛膏及油性睫毛膏兩 者，並且使用感優良。 (A)成分所含之化合物（a)，於配合聚氧丙稀（10)甘油 之實施例A 5、及、配合聚氧丙稀（9 )二甘油醚之實施例 A 6〜A 9，為比配合其他化合物（a )的實施例A 2〜A 4取得更良 好的使用感。又，此些實施例A 6〜A 9特別為使用感優良， 且取得感覺良好的濕潤感。 另一方面，含有聚氧丙烯構造，並且再具有碳數4個之 烷基和聚氧乙烯構造之化合物的比較例A 6，對於被膜形成 型睫毛膏及油性睫毛膏兩者的洗淨力為差於實施例。又， 因為環氧丙烷之加成莫耳數大，故非為水溶性，而配合非 本發明化合物（a )之聚丙二醇（3 4 )的比較例A 7即使令油性 睫毛膏掉落，對於被膜形成型睫毛膏的洗淨力亦差於實施 例〇 29 312/發明說明書(補件)/93-07/93111227 200427467 又，配合甘油的實施例A 7為比實施例A 6取得更濕潤之 優良使用感，且配合乙醇的實施例A 8為比實施例A 6取得 更濕潤之優良使用感。 又，於油相（B)中配合5 0質量％以上異十二烷的實施例 A 3，為比完全未配合異十二烷的實施例A 2，於被膜形成型 睫毛膏及油性睫毛膏兩者的洗淨力上更為優良。更且，於 油相（B )中配合8 0質量％以上異十二烷的實施例A 4，為比 實施例A 3之油性睫毛膏的洗淨力更為增加。 又，界面活性劑配合0 · 0 4 5質量％的實施例A 6〜A 8、及配 合2質量％的實施例A 9，察見對於被膜形成型睫毛膏及油 性睫毛膏兩者的洗淨力，加上對於肌膚的溶合良好。特別， 配合0 · 0 4 5質量％界面活性劑的實施例A 6〜A 8，為此配合2 質量％的實施例A 9，於被膜形成型睫毛膏及油性睫毛膏兩 者，取得良好的洗淨力。 (比較例A 8 ) 以表A - 3所示之組成製造卸妝組成物，且評估對於睫毛 膏的洗淨力。評估結果示於表A - 3。 表A - 3312 / Instruction of the Invention (Supplement) / 93-07 / 93111227 26 200427467 Table A-2 (l) Example A2 A3 A4 A5 A6 (A) (a) Polyoxypropylene (9) diglyceryl ether 0 0 0 0 5 Polyoxypropylene (10) glyceryl ether 0 0 0 10 0 Polyoxypropylene (10) Glucosinolate 0 0 10 0 0 Polypropylene glycol (10) 10 10 0 0 0 Glycerol 0 0 0 0 0 Ethanol 0 0 0 0 0 0 1,3-butanediol 5 5 5 5 5 Potassium hydroxide solution (48%) 0.017 0.017 0.017 0.017 0.017 purified water 64. 363 64. 363 64. 363 64. 363 74.318 phenoxyethanol 0.3 0.3 0.3 0.3 0.3 Ethyl p-hydroxybenzoate 0.2 0.2 0.2 0.2 0.2 (a,) polyoxyethylene (3.5) polyoxypropylene (7) butyl ether 0 0 0 0 0 polypropylene glycol (34) 0 0 0 0 0 (B) Isododecane 0 15 20 20 15 Isononyl isononanoate 15 0 0 0 0 Isopropyl palmitate 5 5 0 0 0 (C) PEMULEN TR-2 * 1 0.04 0.04 0.04 0.04 0.04 SPS * 2 0.08 0.08 0.08 0.08 0.08 Surfactant polyethylene glycol monolaurate (12E.0.) 0 0 0 0 0.045 Polyoxyethylene sorbitan monooleate (20E. 0 ·) 0 0 0 0 0 Total 100 100 100 100 100 (a) Concentration (% by mass) in Component A 13 13 13 13 6 Mass ratio (A): (B) 79 ： 20 79 ： 20 79 ： 20 79 ： 20 84 ： 15 Evaluation of the detergency of the film-forming water-based mascara ◎ ◎ ◎ ◎ The detergency of the oily mascara △ △ ◎ ◎ ◎ ◎ feeling of use 〇〇〇〇 ◎ ◎ 27 312 / Invention Specification (Supplement) / 93-07 / 93111227 200427467 Table A-2 (2) Examples Comparative Examples A7 A8 A9 A6 A7 (A) (a) Polyoxypropylene (9) Diglyceryl ether 5 5 5 0 0 Polyoxypropylene (10) glyceryl ether 0 0 0 0 0 Polyoxypropylene (10) Glucosinolate 0 0 0 0 0 Polypropylene glycol (10) 0 0 0 0 0 Glycerol 5 0 0 0 0 Ethanol 0 10 0 0 0 1,3-butanediol 5 5 5 5 5 Potassium hydroxide solution (48%) 0.017 0.017 0.017 0.017 0.017 Refined water 69.318 64.318 72. 363 69.318 69.318 Phenoxyethanol 0.3 0.3 0.3 0.3 0.3 Paraben Ethyl Phenylacetate 0.2 0.2 0.2 0.2 0.2 (a,) Polyoxyethylene (3.5) Polyoxypropylene (7) Butyl ether 0 0 0 10 0 Polypropylene glycol (34) 0 0 0 0 10 (B) Isodecyl Dioxane 15 15 15 15 15 Isononyl isononanoate 0 0 0 0 0 Isopropyl palmitate 0 0 0 0 0 (C) PEMULEN TR-2 氺 1 0.04 0.04 0.04 0.04 0.04 SPS * 2 0.08 0.08 0.08 0.08 0.0 8 Surfactant polyethylene glycol monolaurate (12E. 0.) 0.045 0 2 0.045 0.045 Polyoxyethylene sorbitan monooleate (20E ·. 0) 0 0.045 0 0 0 Total 100 100 100 100 100 (A) concentration (% by mass) of the component (A) 6 6 6 0 0 Mass ratio (A) · · (B) 84: 15 84: 15 84: 15 — — Evaluation of the washing of the film-forming water-based mascara Net force ◎ ◎ △ △ Δ Detergent for oily mascara ◎ ◎ △ △ 〇 Feeling of use ◎ ◎ ◎ 〇〇28 312 / Invention Manual (Supplement) / 93-07 / 93111227 200427467 The origin is shown below. * 1 Acrylic acid / alkyl acrylate copolymer: trade name PEMULEN TR-2, Noveon, Inc. * 2 Hydroxyethylcellulose sodium hydroxypropyl stearate ether hydroxypropyl sulfonate (Japanese Patent Laid-Open No. 9-2 3 5 3 0 1) Examples A 2 to A 9 of a liquid makeup remover composition in which a water-based thickener having a water repellent portion is added as the component (C), because the component (A) and the component (B) are It is a uniform emulsion, so it is applied directly without using a cotton sheet to evaluate the detergency. From the results shown in Table A-2, it can be seen that in Examples A 2 to A 9, by mixing the two components (A) and (B) in the specific ratio of the present invention, it is possible to effectively remove and mix a large amount of acrylic acid ester copolymerization. The combined film-forming mascara and oily mascara are excellent in use feeling. (A) The compound (a) contained in the component is blended with Example A 5 of polyoxypropylene (10) glycerin, and Examples A 6 to A 9 of polyoxypropylene (9) diglyceryl ether, In order to obtain better usability than Examples A 2 to A 4 in which other compounds (a) were blended. In addition, these examples A 6 to A 9 are particularly excellent in use feeling and have a good moist feeling. On the other hand, Comparative Example A 6, which contains a polyoxypropylene structure, and further has a compound having an alkyl group of 4 carbons and a polyoxyethylene structure, has a cleaning power of both a film-forming mascara and an oily mascara. Inferior to the examples. In addition, because the propylene oxide has a large addition mole number, it is not water-soluble, and Comparative Example A 7 in which polypropylene glycol (3 4) which is not the compound (a) of the present invention is blended, even if the oily mascara is dropped, The detergency of the film-forming mascara is also worse than that of Example 0229/312 (Instruction of the Invention (Supplement) / 93-07 / 93111227 200427467) In addition, Example A7 with glycerin is more moist than Example A6 Example A 8 with excellent usability, and blended with ethanol obtained an excellent usability more moist than Example A 6. In addition, Example A 3 in which 50% by mass of isododecane was blended in the oil phase (B) was Example A 2 in which no isododecane was blended at all, and was used in a film-forming mascara and an oily mascara. Both have better detergency. Furthermore, Example A 4 in which 80% by mass or more of isododecane was blended in the oil phase (B) was more effective than the oily mascara of Example A 3 in detergency. In addition, Example A 6 to A 8 containing 0. 0 4 55% by mass of the surfactant and Example A 9 containing 2% by mass of the surfactant were observed to clean both the film-forming mascara and the oily mascara. Power, and good fusion to the skin. In particular, Examples A 6 to A 8 with 0. 0 4 5 mass% of a surfactant were blended, and Example A 9 with 2 mass% was blended for both of the film-forming mascara and the oily mascara to obtain good results. Detergency. (Comparative Example A 8) A makeup remover composition was produced with the composition shown in Table A-3, and the detergency of the mascara was evaluated. The evaluation results are shown in Table A-3. Table A-3

比較例A8 組 成 六 甘 油 基 單 肉 豆 謹 酸 酯 4 聚 氧 丙 烯 (1 5) 曱 基 葡 萄 糖 苷 15 聚 丙 稀 酸 鈉 0. 5 精 製 水 80.5 合 計 100 評 價 對 於 被 膜 形 成 型 水 性 睫 毛 膏之洗淨力 〇△ 對 於 油 性 睫 毛 膏 之 洗 淨 力 X 含有聚氧丙烯曱基葡萄糖苷、和HLB為10以上之非離子 性界面活性劑（六甘油基單肉豆蔻酸酯）所構成的組成物為 30 312/發明說明書(補件)/93-07/93111227 200427467 對應於前述曰本專利特開平9 - 1 4 3 0 2 8號公報之實施例，雖 然對於被膜形成型睫毛膏具有某程度洗淨力，但對於油性 睫毛膏的洗淨力顯然為差。 (比較例A 9 ) 以表A-4所示之組成製造卸妝組成物，且評估對於睫毛 膏的洗淨力。評估結果示於表A-4。 表A - 4Comparative Example A8 Composition hexaglyceryl monomyristate 4 Polyoxypropylene (1 5) Glucosinolate 15 Polyacrylic acid sodium 0.5 Purified water 80.5 Total 100 Evaluation of the detergency of the film-forming aqueous mascara 〇 △ The cleansing power of oily mascara X Contains polyoxypropylene glucosinolate and a nonionic surfactant (hexaglyceryl monomyristate) with an HLB of 10 or more. 30 312 / Invention Specification (Supplement) / 93-07 / 93111227 200427467 corresponds to the embodiment of Japanese Patent Application Laid-Open No. 9-1 4 3 0 2 8 mentioned above, although the film-forming mascara has a certain degree of detergency, But the detergency of oily mascara is obviously poor. (Comparative Example A 9) A makeup removing composition was produced with the composition shown in Table A-4, and the detergency of the mascara was evaluated. The evaluation results are shown in Table A-4. Table A-4

比較例A 9 組 成 聚 丙 二 醇 (1 0) 5 乙 醇 15 甘 油 5 聚 氧 乙 稀 山 梨 糖 醇 Sf 單 油 酸酯 (20E. 0.) 3 精 製 水 72 合 計 100 評 價 對 於 被 膜 形 成 型 水 性 睫 毛 膏之 洗淨力 〇△ 對 於 油 性 睫 毛 膏 之 洗 淨 力 X 含有聚伸烷基乙二醇和乙醇和水溶性多元醇和界面活 性劑和水所構成的組成物為對應於前述日本專利特開平 2 - 1 0 4 5 1 1號公報之實施例，雖然對於被膜形成型睫毛膏具 有某程度洗淨力，但對於油性睫毛膏的洗淨力顯然為差。 (比較例A 1 0 ) 以表A-5所示之組成製造卸妝組成物，且評估對於睫毛 膏的洗淨力。評估結果示於表A - 5。 31 312/發明說明書(補件)/93-07/93111227 200427467 表A-5 比較例A 1 0 組 成 異 十 二 烧 15 烧 基 (8 〜1 6) 葡 萄 糖 苷 3 甘 油 5 PEMULEN TR -2 氺1 0. 04 氫 氧 化 鉀 液 (48%) 0.017 苯 氧 基 乙 醇 0. 3 對 羥 基 苯 曱 酸 曱 酯 0. 2 精 製 水 76.443 合 計 100 評 價 對 於 被 膜 形 成 型 水 性 睫 毛膏之洗淨力 Δ 對 於 油 性 睫 毛 膏 之 洗 淨 力 ◎ 於含有丙烯酸·曱基丙烯酸烷酯共聚合體（Noveon，Inc. 公司、商品名：P E M U L E N T R - 2 )、油劑、含水乳化物、非乳 化性界面活性劑（烷基（8〜1 6 )葡萄糖苷）共存所構成的組成 物為對應於前述曰本專利特表平1 1 - 5 0 3 4 6 1號公報之實施 例，因為不含有本發明所用的化合物（a )，故與比較例A 1 同樣，即使令油性睫毛膏掉落，對於配合大量丙稀酸烧酯 共聚合體之被膜形成型睫毛膏的洗淨力亦差於實施例。 (比較例A 1 1 ) 以表A-6所示之組成製造卸妝組成物，且評估對於睫毛 膏的洗淨力。評估結果示於表A-6。 32 312/發明說明書(補件)/93-07/93111227 200427467Comparative Example A 9 Composition Polypropylene Glycol (1 0) 5 Ethanol 15 Glycerin 5 Polyoxyethylene Sorbitol Sf Monooleate (20E. 0.) 3 Refined Water 72 Total 100 Evaluation for washing of film-forming water-based mascara Netting power △ Washing power of oily mascara X Composition containing polyalkylene glycol, ethanol, water-soluble polyol, surfactant and water is a composition corresponding to the aforementioned Japanese Patent Laid-Open No. 2-1 0 4 In the example of Gazette No. 5-1, although the washing power of the film-forming mascara is a certain degree, the washing power of the oily mascara is obviously poor. (Comparative Example A 1 0) A makeup removing composition was produced with the composition shown in Table A-5, and the detergency of the mascara was evaluated. The evaluation results are shown in Table A-5. 31 312 / Instruction of the Invention (Supplement) / 93-07 / 93111227 200427467 Table A-5 Comparative Example A 1 0 Composition Isododecane 15 Benzyl (8 ~ 1 6) Glucoside 3 Glycerin 5 PEMULEN TR -2 氺 1 0.04 Potassium hydroxide solution (48%) 0.017 Phenoxyethanol 0.3 Peptone p-hydroxybenzoate 0.2 Purified water 76.443 Total 100 Evaluation of the cleaning power for film-forming water-based mascara Δ For oily eyelashes Detergency of paste ◎ It contains acrylic acid and alkyl acrylate copolymer (Noveon, Inc., trade name: PEMULENTR-2), oil, aqueous emulsion, non-emulsifying surfactant (alkyl (8 ~ 16) The composition of glucoside) coexistence is an example corresponding to the aforementioned Japanese Patent Publication No. 1 1-5 0 3 4 6 1 because it does not contain the compound (a) used in the present invention, Therefore, similar to Comparative Example A 1, even if the oily mascara is dropped, the film-forming type eyelashes are formulated with a large amount of acrylic copolymer. The detergency were poor in the Examples. (Comparative Example A 1 1) A makeup remover composition was produced with the composition shown in Table A-6, and the detergency of the mascara was evaluated. The evaluation results are shown in Table A-6. 32 312 / Invention Specification (Supplement) / 93-07 / 93111227 200427467

令異鏈烷烴以聚氧乙烯烷醚系活性劑予以水中乳化的組 成物為對應於前述曰本專利特開平5 - 1 6 3 1 1 6號公報之實 施例，但即使令油性睫毛膏掉落，對於配合大量丙烯酸烷 酯共聚合體之被膜形成型水性睫毛膏的洗淨力亦差於實施 例〇 實施例B系列：片狀卸妝材料 (洗淨力之評估方法） 於洗淨力之評估上，使用配合丙烯酸烷酯共聚合體的被 膜形成型水性睫毛膏和被膜形成型油性睫毛膏、及油性睫 毛膏。The composition in which isoparaffin is emulsified in water with a polyoxyethylene alkane-based active agent is an example corresponding to the aforementioned Japanese Patent Laid-Open No. 5-1 6 3 1 1 6, but even if the oily mascara is dropped The cleaning power of the film-forming water-based mascara with a large amount of alkyl acrylate copolymer is also worse than that of Example 0. Example B series: sheet-like makeup remover (evaluation method of cleaning power) on the evaluation of cleaning power A film-forming water-based mascara, a film-forming oily mascara, and an oil-based mascara mixed with an alkyl acrylate copolymer are used.

將指定量之睫毛膏於載玻片上以直徑1 . 2公分之圓狀均 勻塗佈，且放置1 2小時令其乾燥，製作試驗污染物。被膜 形成型水性睫毛膏為將佳麗寶公司製T E S T I Μ 0 M A S C A R A EFFECT CURLLONG BN1 8以0.007克塗佈，被膜形成型油性 睫毛膏為將花王公司製AUBE REAL EFFECT MASCARA BK941 以0 . 0 0 4 5克塗佈，油性睫毛膏為將高絲公司製S P 0 R 丁 S 33 312/發明說明書(補件)/93-07/93111227 200427467 BEAUTY FASIO POWER STAY MASCARA CURLLONG BK001 W 0 . 0 0 4 5克塗佈。根據各睫毛膏的液性不同，使得睫毛膏以 一定面積均勻塗佈時之各個塗佈量為不同。 將片狀卸妝材料放於各試驗污染物上，且輕押5秒鐘後 以一定壓力（1 0 0 g / c m2)進行擦拭，並且測定除去睫毛膏所 必要的擦拭回數。 〈對於被膜形成型水性睫毛膏之洗淨力的評估基準〉 ◎ 1 4回以下 〇15〜19回 〇△ 20〜24回 △ 2 5〜2 9回 X 3 0回以上 〈對於被膜形成型油性睫毛膏及油性睫毛膏之洗淨力的評 估基準〉 ◎ 5回以下 〇6〜1 0回 〇△ 1 1〜1 5回 △ 1 6〜20回 X 2 1回以上 (使用後之肌觸感的評估方法） 專門評審員1 0名以各片狀卸妝材料將臉擦拭後，官能評 估肌膚的感覺。 [評估基準] ◎ : 1 0名中9名以上，評估為無發黏且無油性感。 34 312/發明說明書(補件)/93-07/93111227 200427467 〇：1 0名中7名〜8名，評估為無發黏且無油性感。 △ : 1 0名中5名〜6名，評估為無發黏且無油性感。 X : 1 0名中4名以下，評估為無發黏且無油性感。 (氣味之評估方法） 專門評審員1 0名以各片狀卸妝材料將臉擦拭時或其 後，官能評估氣味。 [評估基準] 〇：1 0名中8名以上，評估為使用中可容許的氣味。 △ : 10名中5名〜7名，評估為使用中可容許的氣味。 X : 1 0名中4名以下，評估為使用中可容許的氣味。 (黏度） 所調製之乳化組成物的黏度，使用ΒΜ型黏度計 (Τ 〇 k i m a k e 公司製），以 R o t o r N ο · 2、6 r p m、3 0 °C 之 t条件測 定。 (乳化組成物之安定性評估） 將所調製之乳化組成物放入附有螺旋蓋之玻璃瓶中，並 於3 0 °C之恆溫室中保管。觀察1日後、3日後、7日後、 1 0日後、1 4日後、1個月後之外觀變化。 (擦拭時之肌觸感的評估方法） 專門評審員1 0名以各片狀卸妝材料擦拭臉時之使用感 予以官能評估。 [評估基準] ◎ : 10名中9名以上，評估為薄片的肌觸感良好，不會上 滑且牢固擦拭。 35 312/發明說明書(補件)/93-07/93111227 200427467 〇：1 0名中7名〜8名，評估為薄片的肌觸感良好，不會上 滑且牢固擦拭。 △ : 1 0名中5名〜6名，評估為薄片的肌觸感良好，不會上 滑且牢固擦拭。 X: 10名中4名以下，評估為薄片的肌觸感良好，不會上 滑且牢固擦拭。 (薄片積層時之品質安定性的評估方法：立即調製後及保存 後的含浸率） 將切成7 5 m m X 2 0 0 m m大小之非織布薄片以Ζ字形折疊4 0 牧，且含浸乳化組成物。測定此處立即調製後的含浸率。 其次將此積層體放入鋁襯且密封，並於5 0 °C保存一個月。 其後，恢復至室溫，並且評估由上方開始第二牧薄片與由 下方開始第二牧薄片的含浸率、及各卸妝性能。含浸率為 經由測定各含浸薄片的重量後，並以洗劑清洗薄片，且以 水洗條乾燥並測定乾燥薄片的重量，根據下式算出。 含浸率％ =(含浸薄片重量一乾燥薄片重量）X 1 0 0 /乾燥薄 片重量 [評估基準] ◎:相對於立即調製後之含浸率，保存後之含浸率變化為 ± 2 5 %以内。 〇：相對於立即調製後之含浸率，保存後之含浸率變化為 大於± 2 5 %且為± 4 0 %以内。 △:相對於立即調製後之含浸率，保存後之含浸率變化為 大於± 4 0 %且為± 6 0 °/〇以内。 36 312/發明說明書(補件)/93-07/93111227 200427467 X :相對於立即調製後之含浸率，保存後之含浸率變化為 大於± 6 0 %。 (實施例B 1〜B 7、比較例B 1〜B 5 ) 以表B - 1所示之組成調製乳化組成物，並將其對棉片 10 0%、密度0 . 1 5 g / c m3、平均坪量6 0 g / m2之非織布，以相 對於非織布1克含浸乳化組成物3. 5克，調製樣品，評估 結果合併示於表B - 1。各成分之份量為以全量為1 0 0質量 份。 (乳化組成物之製法） 於精製水中添加（C)成分的水系增黏劑並以分散器以 1，2 0 0 r p m、3 0分鐘攪拌令其均勻分散。一邊以螺旋槳 2 0 0 r p m授拌，一邊添加中和劑之氫氧化鉀液且保持1 0分 鐘予以中和及增黏。繼續授拌，加入其他（A )成分、（a ’ ) 成分及界面活性劑且溶解。更且於攪拌下，將（B )成分之油 劑慢慢滴下且保持2小時，其後以均質器4 , 5 0 0 r p m攪拌 3 0分鐘，取得乳化組成物。 37A specified amount of mascara was evenly coated on a glass slide in a circular shape having a diameter of 1.2 cm, and left to stand for 12 hours to dry, to prepare a test contaminant. The film-forming water-based mascara was coated with 0.007 g of TESTI MU 0 MASCARA EFFECT CURLLONG BN1 8 manufactured by Kanebo, and the film-forming oil-based mascara was AUBE REAL EFFECT MASCARA BK941 manufactured by Kao Corporation at 0. 0 0 4 5 g The oily mascara is coated with 5 grams of SP 0 R D S S 312 / Invention Specification (Supplement) / 93-07 / 93111227 200427467 BEAUTY FASIO POWER STAY MASCARA CURLLONG BK001 W 0. 0 0 4 manufactured by Kose Corporation. Depending on the liquid properties of each mascara, the amount applied when the mascara is uniformly applied over a certain area is different. The sheet-shaped makeup remover was placed on each of the test contaminants, lightly pressed for 5 seconds, and then wiped with a certain pressure (100 g / cm2), and the number of wipes necessary to remove the mascara was measured. <Evaluation criteria for the detergency of the film-forming water-based mascara> ◎ 14 times or less 〇15 ~ 19 times △ 20 ~ 24 times △ 2 5 ~ 2 9 times X 3 0 times or more <for the film-forming type oiliness Evaluation Criteria for Detergency of Mascara and Oily Mascara> ◎ 5 times or less 〇6 ~ 1 0 times △ 1 1 ~ 1 5 times △ 1 6 ~ 20 times X 2 1 times or more (muscle touch after use) Evaluation method) 10 specialized reviewers wiped the face with each sheet of makeup remover, and evaluated the feeling of the skin. [Evaluation Criteria] ◎: 9 or more out of 10 persons were evaluated as non-sticky and oil-free. 34 312 / Invention Specification (Supplement) / 93-07 / 93111227 200427467 0: 7 to 8 out of 10, evaluated as non-sticky and oil-free. △: Five to six out of ten were evaluated as non-sticky and oil-free. X: No more than 4 out of 10 persons were evaluated as non-sticky and oil-free. (Evaluation method of odor) 10 specialized panelists evaluated the odor when or after wiping the face with each sheet of makeup remover. [Evaluation criteria] ○: 8 or more of the 10 persons were evaluated as acceptable odor during use. △: Five to seven out of ten were evaluated as acceptable odor during use. X: 4 or less out of 10, evaluated as acceptable odor during use. (Viscosity) The viscosity of the prepared emulsified composition was measured using a BM-type viscometer (manufactured by Tokimak Co., Ltd.) under conditions of t o r r N ο · 2, 6 r p m, and 30 ° C. (Evaluation of Stability of Emulsified Composition) The prepared emulsified composition was placed in a glass bottle with a screw cap and stored in a constant temperature room at 30 ° C. Observe the appearance changes after 1 day, 3 days, 7 days, 10 days, 14 days, and 1 month. (Evaluation Method of Muscle Touch during Wiping) 10 expert panelists evaluated the feeling of use when wiping the face with each sheet of makeup remover. [Evaluation Criteria] :: 9 or more out of 10 persons were evaluated as having a thin sheet with good tactile sensation, and no slipping and firm wiping. 35 312 / Invention specification (Supplement) / 93-07 / 93111227 200427467 〇: 7 to 8 out of 10, it is evaluated that the thin sheet has good tactile sensation, does not slip and is firmly wiped. △: 5 to 6 out of 10 persons. It was evaluated that the thin sheet had a good tactile sensation, and did not slip and was wiped firmly. X: Less than 4 out of 10, it was evaluated that the thin sheet had good tactile sensation, and did not slide up and wipe firmly. (Evaluation method of quality stability when the sheets are laminated: impregnation rate immediately after preparation and after storage) A non-woven sheet cut into a size of 75 mm X 2 0 mm is folded in a zigzag pattern, and is impregnated and emulsified.组合 物。 Composition. The impregnation rate immediately after the preparation was measured here. Next, the laminate was placed in an aluminum lining and sealed, and stored at 50 ° C for one month. Thereafter, the temperature was returned to room temperature, and the impregnation rate and the makeup removing performance of the second flakes from the top and the second flakes from the bottom were evaluated. The impregnation rate is determined by measuring the weight of each impregnated sheet, washing the sheet with a lotion, drying it with a water-washed strip, and measuring the weight of the dried sheet, and calculating it according to the following formula. Impregnation% = (weight of impregnated sheet-weight of dry sheet) X 1 0 0 / weight of dry sheet [Evaluation Criteria] ◎: The impregnation rate after storage is changed within ± 25% relative to the impregnation rate immediately after preparation. 〇: Relative to the impregnation rate immediately after preparation, the impregnation rate after storage is greater than ± 25% and within ± 40%. △: Compared to the impregnation rate immediately after preparation, the impregnation rate after storage is greater than ± 40% and within ± 60 ° / 〇. 36 312 / Invention Specification (Supplement) / 93-07 / 93111227 200427467 X: Compared to the impregnation rate immediately after preparation, the impregnation rate after storage is greater than ± 60%. (Examples B1 to B7, Comparative Examples B1 to B5) The emulsified composition was prepared with the composition shown in Table B-1, and it was applied to a cotton sheet at 100% density and 0.15 g / c m3. For non-woven fabrics with an average weight of 60 g / m2, 3.5 g of impregnated emulsified composition relative to 1 g of non-woven fabric was used to prepare samples. The evaluation results are shown in Table B-1. The amount of each component is 100 parts by mass based on the entire amount. (Manufacturing Method of Emulsified Composition) A water-based thickener (C) is added to the purified water, and the mixture is stirred with a disperser at 1,200 r p m for 30 minutes to uniformly disperse it. While mixing with a propeller 2000 r p m, add potassium hydroxide solution of a neutralizer and keep it for 10 minutes for neutralization and thickening. Continue mixing, add other (A) component, (a ') component and surfactant, and dissolve. Furthermore, the (B) component oil was slowly dropped and kept under stirring for 2 hours, and then stirred with a homogenizer 4,500 r pm for 30 minutes to obtain an emulsified composition. 37

312/發明說明書(補件)/93-07/93111227 200427467 表 B-l(l) B1 B2 B3 B4 B5 B6 B7 (A) a 聚氧丙烯(9)二甘油醚 10 10 10 10 聚丙二5|(10) 10 10 10 1· 3-丁 5 乙醇 氫氧_液(48%) 0.023 0.023 0.023 0.023 0.023 0.038 0.023 精製水 平鳅合計100之#*) a 聚乙二ί$(20)聚丙二#(10) (B) b IPSolventl620 *3 15 IPSolvent2028 *4 5 5 5 5 Malcasol *5 15 15 十曱基環五砂氧院(沸點205°C) 5 5 5 5 才宗櫊S曼異丙酯(沸點332°C) 3 3 3 3 (C) PEMULEN TO-2 *1 0.05 0.05 0.05 0.05 0.05 0.05 0.05 Carbopol ETD *6 0.025 SPS*2 0.1 0.1 0.1 0.1 0.1 0.12 0.1 界面活性劑 POEIO月桂酸酿 0.045 P0E15 總 _ P0E6·較· ΡΟΕ20單油酸山梨糖醇酐 單油酸山梨嶽辦 評價 S侧嫌形成型水Ι4Β走毛膏β先淨力 ◎ ◎ 〇 〇 〇 〇 〇 鑛嫡形成型油做毛膏德淨力 ◎ ◎ 〇 〇 〇 〇 〇 案懷油掛走毛膏《先淨力 ◎ ◎ 〇 〇 〇 〇 〇 使用後之肌觸感 〇 ◎ 〇 ◎ 〇 〇 〇 氣味 Δ 〇 〇 〇 〇 〇 〇 黏度(mPa · s) 650 625 600 625 475 2000 600 1個月後之乳^组成物的狀態 鱗 德 娜 未分離 雜 38 312/發明說明書(補件)/93-07/93111227 200427467 表 B_1(2) 比較例 B1 B2 B3 B4 B5 (A) a 聚氧丙稀(9)二甘油fell 聚丙二醇(10) 10 10 1.3-丁二醇 5 乙醇 15 氫氧化鉀液(48%) 0.023 0.023 精製水 平衡(合計100之份量） &gt; a 聚乙二醇(20)聚丙二醇（10) 5 (B) b IPSolventl620 *3 25 IPSolvent2028 *4 5 5 Malcasol *5 十曱基環五矽氧烷(沸點205°C) 5 5 5 棕櫚酸異丙酯（沸點332°C) 3 5 3 流動鏈烧烴 5 (C) PEMULEN TR-2 *1 0.05 0.05 Carbopol ETD *6 SPS *2 0.1 0.1 界面活 性劑 POE10月桂酸酯 P0E15綠堪醚 1.5 P0E6錄躐醚 1 POE20單油酸山梨糖醇酐 3 1.2 單油酸山梨糖醇酐 1.2 評價 對於被膜形成型水性睫毛膏之洗淨力 △ Δ X 〇△ 〇△ 對於被膜形成型油性睫毛膏之洗淨力 〇△ X 〇△ 〇△ Δ 對於油性睫毛膏之洗淨力 ◎ X 〇 〇△ Δ 使用後之肌觸感 Δ Δ 〇 Δ Δ 氣味 Δ 〇 〇 〇 〇 黏度(mPa · s) 300 12 600 800 1200 1個月後之乳化組成物的狀態 分離 氺7 分離 分離 未分離 *7 :因為不含有油故呈均勻溶液 39 312/發明說明書(補件)/93-07/93111227 200427467 還有，使用材料之由來示於下。 *1 丙烯酸·曱基丙烯酸烷酯共聚合體：商品名PEMULEN TR-2、 Noveon,Inc. *2 羥乙基纖維素羥丙基硬脂醚羥丙基磺酸鈉（日本專利 特開平9 - 2 3 5 3 0 1號公報） * 3 輕質流動異鏈烷烴（沸點1 6 6〜2 0 2 °C ):商品名I P Solvent 1620、出光石油化學（股） * 4 輕質流動異鏈烷烴（沸點2 1 3〜2 6 2 °C ):商品名I P Solvent 2028、出光石油化學（股） * 5 輕質流動異鏈烷烴（沸點1 7 5〜1 8 5 °C ):商品名 Malcasol R、丸善石油化學（股） *6 丙烯酸·曱基丙烯酸烷酯共聚合體：商品名Carbopol E T D ' Noveon, Inc. 由表B - 1所示之結果，令本發明所用之水中油型乳化組 成物於非織布中含浸的實施例B 1〜B 7，可簡單且迅速，將 難掉落的被膜形成型水性睫毛膏及被膜形成型油性睫毛 膏、油性睫毛膏有效除去，且使用後的肌膚觸感為良好。 關於氣味，使用含有碳數8個及9個之異鏈烧烴的I P Solvent 1620者被評估為稍差。 實施例B 6為使用黏度較高且於一個月後亦未分離之較 安定的乳化組成物，取得本發明之效果，但若與使用同量 之相同化合物（a )及油劑（b )的實施例B 2相比較，則以使用 1個月後分離之乳化組成物的實施例B 2的效果更為優良。 又，配合1，3 - 丁二醇的實施例B 5，為比使用同量之相同 40312 / Instruction of the Invention (Supplement) / 93-07 / 93111227 200427467 Table Bl (l) B1 B2 B3 B4 B5 B6 B7 (A) a Polyoxypropylene (9) diglyceryl ether 10 10 10 10 Polypropylene 5 | (10 ) 10 10 10 1.3-but 5 ethanol hydroxide (48%) 0.023 0.023 0.023 0.023 0.023 0.038 0.023 Refined level 鳅 Total 100 # *) a Polyethylene (20) Polypropylene # (10) (B) b IPSolventl620 * 3 15 IPSolvent2028 * 4 5 5 5 5 Malcasol * 5 15 15 Decadecyl ring five sand oxygen institute (boiling point 205 ° C) 5 5 5 5 Caizong Sman isopropyl ester (boiling point 332 ° C) 3 3 3 3 (C) PEMULEN TO-2 * 1 0.05 0.05 0.05 0.05 0.05 0.05 0.05 Carbopol ETD * 6 0.025 SPS * 2 0.1 0.1 0.1 0.1 0.1 0.12 0.1 Surfactant POEIO Lauric Acid 0.045 P0E15 Total P0E6 · Compared with · ΟΟ20 sorbitan monooleate monosorbate monosorbate monosorbate monohydrate sorbate evaluation of the S side susceptible forming water I 4B hair removal cream β first net force ◎ ◎ 〇〇〇〇〇 mineral ore formation type oil as a hair cream de net force ◎ ◎ 〇〇〇〇〇〇 case nostalgic hair cream "first net force ◎ ◎ 〇〇〇〇 Muscle touch after use 〇 〇 ◎ 〇〇 odor Δ 〇 〇 〇 〇〇〇 viscosity (mPa · s) 650 625 600 625 475 2000 600 milk ^ composition state after one month scale Dana Unisolated Miscellaneous 38 312 / Invention Specification (Supplement) / 93-07 / 93111227 200427467 Table B_1 (2) Comparative Example B1 B2 B3 B4 B5 (A) a polyoxypropylene (9) diglycerin fellell polypropylene glycol ( 10) 10 10 1.3-Butanediol 5 Ethanol 15 Potassium hydroxide solution (48%) 0.023 0.023 Refined water balance (100 parts in total) &gt; a Polyethylene glycol (20) Polypropylene glycol (10) 5 (B) b IPSolventl620 * 3 25 IPSolvent2028 * 4 5 5 Malcasol * 5 Decadecylcyclopentasiloxane (boiling point: 205 ° C) 5 5 5 Isopropyl palmitate (boiling point: 332 ° C) 3 5 3 Mobile chain hydrocarbons 5 ( C) PEMULEN TR-2 * 1 0.05 0.05 Carbopol ETD * 6 SPS * 2 0.1 0.1 Surfactant POE10 Laurate P0E15 Green Ether 1.5 P0E6 Acetyl ether 1 POE20 Sorbitan monooleate 3 1.2 Sorbitan monooleate Sugar Alcohol Anhydride 1.2 Evaluation Washing power of mascara △ Δ X 〇 △ 〇 △ Washing power of film-forming oily mascara 0 △ X 〇 △ 〇 △ Δ Washing power of oily mascara ◎ X 〇〇 △ Δ Touch Δ Δ 〇 Δ Δ Odour Δ 〇〇〇〇 Viscosity (mPa · s) 300 12 600 800 1200 State of emulsified composition after 1 month separation 氺 7 Separation and separation not separated * 7: Presented because it does not contain oil Homogeneous solution 39 312 / Invention specification (Supplement) / 93-07 / 93111227 200427467 Also, the origin of the materials used is shown below. * 1 Acrylic acid / alkyl acrylate copolymer: trade name PEMULEN TR-2, Noveon, Inc. * 2 Hydroxyethylcellulose sodium hydroxypropyl stearate ether hydroxypropyl sulfonate (Japanese Patent Laid-Open No. 9-2 3 5 3 0 1) * 3 Light flowing isoparaffin (boiling point 1 6 6 ~ 2 0 2 ° C): trade name IP Solvent 1620, Idemitsu Petrochemical (stock) * 4 light flowing isoparaffin ( Boiling point 2 1 3 ~ 2 6 2 ° C): trade name IP Solvent 2028, Idemitsu Petrochemical (stock) * 5 light flowing isoparaffin (boiling point 1 7 5 ~ 1 8 5 ° C): trade name Malcasol R, Maruzen Petrochemical Co., Ltd. * 6 Acrylic acid / alkyl acrylate copolymer: trade name Carbopol ETD 'Noveon, Inc. The results shown in Table B-1 make the oil-in-water emulsion composition used in the present invention non-oil-based. Examples B 1 to B 7 impregnated in the woven fabric can easily and quickly remove the film-forming water-based mascara, film-forming oily mascara, and oil-based mascara, which are difficult to drop, and the skin feel after use For good. Regarding odor, those using IP Solvent 1620 containing hetero-chain burned hydrocarbons having 8 and 9 carbons were evaluated as slightly worse. Example B 6 is a relatively stable emulsified composition that has a high viscosity and is not separated after one month, and achieves the effect of the present invention. However, if the same amount of the same compound (a) and oil agent (b) are used, Compared with Example B 2, the effect of Example B 2 using the emulsified composition separated after one month was more excellent. In addition, in Example B 5 in which 1,3-butanediol was blended, the same amount was used as compared with the same amount 40

312/發明說明書(補件)/93-07/93111227 200427467 化合物（a )及油劑（b )的實施例B 3取得更濕潤的使用感。配 合界面活性劑0 . 0 4 5質量％的實施例B 7，為比使用同量之 相同化合物（a )及油劑（b )的實施例B 3對於肌膚的溶合度 良好。 另一方面，未含有本發明所用之化合物（a )，且使用一般 用以做為乳化劑之界面活性劑代替水系增黏劑所調製的比 較例B 1為對應於前述曰本專利特開平5 - 1 6 3 1 1 6號公報之 組成物，對於配合被膜形成成分之睫毛膏的洗淨力差，使 用後之肌觸感亦差。又，不含有形成油相之（B )成分、且含 有（a ’ ）成分、且使用一般用以做為乳化劑之界面活性劑代 替水系增黏劑所謂製的比較例B 2為對應於前述曰本專利 特開平2 - 1 0 4 5 1 1號公報之組成物，並無法除去油性睫毛 膏，且亦無法有效除去配合被膜形成成分的水性睫毛膏， 使用後之肌觸感亦差。 不含有本發明所用之化合物（a )的比較例B 3，對於配合 被膜形成成分之睫毛膏的洗淨力差。又，沸點為1 6 0〜3 0 0 °C 之油劑（b)於油相中未滿5 0質量％的比較例B 4，對於睫毛 膏之洗淨力及使用感均比實施例差。使用先前的乳化劑代 替（C )成分予以乳化的比較例B 5為乳化安定且難釋出油 劑，且除去性能、特別為油性睫毛膏的除去性能差。 (實施例B 8〜B 1 1，比較例B 6〜B 8 ) 對具有表B-2所示組成、密度、坪量之非織布，於實施 例B 8〜B 1 1、比較例B 6、B 7為將實施例B 2所調製的乳化組 成物、於比較例B 8為將實施例B6所調製的乳化組成物， 41 312/發明說明書(補件)/93-07/93111227 200427467 以表B - 2所示之液量含浸調製樣品。擦拭時之肌觸感、及 薄片積層時之品質安定性的評估結果合併示於表B - 2。還 有，實施例B 2亦併記於表B - 2。 表B-2 實施例 比較例 B2 B8 B9 B10 B11 B6 B7 B8 非織布之組成(％) 棉片 100 100 100 100 50 100 AJ4纖維 100 80 PET 20 50 非織布之密度(g/cm3) 0.15 0.19 0.25 0.19 0.20 0.12 0.15 0.12 非織布之坪量(g/m2) 60 60 100 60 80 30 60 30 含浸液量(g/非織布g) 3.5 3.5 3.5 3.5 3.5 3.2 3.5 3.5 擦拭時之肌觸感 ◎ ◎ 〇 〇 〇 〇 Δ 〇 保存後含浸率（由上方開始第二牧） 〇 ◎ ◎ ◎ 〇 Δ Δ Δ 保存後含浸率（由下方開始第二牧） 〇 ◎ ◎ ◎ 〇 Δ Δ Δ 保存後之洗淨力 (由上方開始第二牧） 被膜形成型水性睫毛膏 ◎ ◎ ◎ ◎ ◎ 〇 〇 Δ 被膜形成型油性睫毛膏 ◎ ◎ ◎ ◎ ◎ Δ Δ Δ 保存後之洗淨力 (由下方開始第二牧） 被膜形成型水性睫毛膏 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 被膜形成型油性睫毛膏 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 42 312/發明說明書(補件)/93-07/93111227 200427467 實施例、比較例之片狀卸妝材料均於立即調製後， 配合被膜形成成分之睫毛膏的卸妝性能優良。由表B 示之結果，關於非織布為由纖維素含量為7 0質量％以 纖維所構成、密度為0 . 1 5〜0 . 3 g / cm 3的實施例B 2、B 8〜 將薄片積層且保存後之卸妝性能亦與立即調製後同樣 良，且薄片積層時之品質安定性優良。又，實施例之 卸妝材料均於擦拭時之肌觸感優良。 另一方面，使用密度較低之非織布的比較例B 6，保 含浸液之組成有差異，且保存後由上方開始第二牧及 方開始第二枚為呈現不同的卸妝性能。又，使用含有 斥水性纖維之P E T (聚對酞酸乙二醇酯）非織布的比較 7，亦於保存後含浸率有差異，且保存後由上方開始第 及由下方開始第二牧為呈現不同的卸妝性能。比較例 為擦拭時之肌觸感亦差。312 / Description of the Invention (Supplement) / 93-07 / 93111227 200427467 Example B 3 of the compound (a) and the oil agent (b) has a more moist feeling. Example B 7 with a surfactant of 0.05% by mass was better than Example B 3 in which the same amount of the same compound (a) and the oil agent (b) were used for the skin. On the other hand, Comparative Example B 1 which does not contain the compound (a) used in the present invention and is prepared by using a surfactant generally used as an emulsifier instead of an aqueous tackifier corresponds to Japanese Patent Application Laid-Open No. Hei 5 -The composition of No. 1 6 3 1 16 has poor cleaning power for mascara blended with a film-forming component, and poor muscle feel after use. In addition, the comparative example B 2 which does not contain the component (B) which forms the oil phase, and contains the component (a '), and which uses a surfactant generally used as an emulsifier instead of the water-based thickener corresponds to the foregoing. The composition of Japanese Patent Laid-Open No. 2-1 0 4 5 1 1 cannot remove oily mascara, nor can it effectively remove the water-based mascara mixed with the film-forming component, and the muscle feel after use is also poor. Comparative Example B 3, which does not contain the compound (a) used in the present invention, has poor cleaning power for a mascara blended with a film-forming component. In addition, Comparative Example B 4 in which the oil agent (b) having a boiling point of 160 to 300 ° C was less than 50% by mass in the oil phase was inferior to the examples in the cleaning power and feeling of use of the mascara. . Comparative Example B5, which was emulsified by using the previous emulsifier in place of the (C) component, was stable and difficult to release the oil, and the removal performance, particularly the oily mascara, was poor. (Examples B 8 to B 1 1 and Comparative Examples B 6 to B 8) For non-woven fabrics having the composition, density, and basis weight shown in Table B-2, Examples B 8 to B 1 1 and Comparative Example B 6. B 7 is the emulsified composition prepared in Example B 2 and Comparative Example B 8 is the emulsified composition prepared in Example B6. 41 312 / Invention Specification (Supplement) / 93-07 / 93111227 200427467 Samples were impregnated with the liquid amounts shown in Table B-2. The evaluation results of the muscle feel during wiping and the quality stability during lamination are shown in Table B-2. Examples B 2 are also shown in Table B-2. Table B-2 Examples Comparative Examples B2 B8 B9 B10 B11 B6 B7 B8 Non-woven fabric composition (%) Cotton sheet 100 100 100 100 50 100 AJ4 fiber 100 80 PET 20 50 Non-woven density (g / cm3) 0.15 0.19 0.25 0.19 0.20 0.12 0.15 0.12 Amount of non-woven fabric (g / m2) 60 60 100 60 80 30 60 30 Impregnation (g / non-woven g) 3.5 3.5 3.5 3.5 3.5 3.2 3.5 3.5 Muscle touch during wiping Feeling ◎ ◎ 〇〇〇〇〇Δ 〇 Impregnation rate after storage (second grazing from above) 〇 ◎ ◎ △ Δ Δ Impregnation rate after storage (second grazing from below) ◎ ◎ ◎ △ Δ Δ Later cleaning power (Second animal husbandry from the top) Film-forming water-based mascara ◎ ◎ ◎ ◎ ◎ 〇〇Δ Film-forming oily mascara ◎ ◎ ◎ ◎ ◎ Δ Δ Δ Started the second animal husbandry) Film-forming water-based mascara ◎ ◎ ◎ ◎ ◎ ◎ 〇 Film-forming oily mascara ◎ ◎ ◎ ◎ ◎ ◎ ○ 42 312 / Invention Specification (Supplement) / 93-07 / 93111227 200427467 Implementation Examples and Comparative Examples Immediately after preparation, the mascara formulated with a film-forming ingredient has excellent makeup removing performance. As a result shown in Table B, the non-woven fabric was composed of fibers with a cellulose content of 70% by mass and a fiber density of 0.15 to 0.3 g / cm 3 in Examples B2 and B 8 to The flakes are laminated and the makeup removal performance after storage is as good as that after the immediate preparation, and the quality stability when the flakes are laminated is excellent. In addition, all of the makeup removers of the examples were excellent in the feel of the muscles during wiping. On the other hand, Comparative Example B 6 using a low-density non-woven fabric has a different composition of the impregnating solution, and the second one from the top after storage and the second one from the top exhibit different makeup removing performance. In addition, the comparison using PET (polyethylene terephthalate) non-woven fabric containing water-repellent fibers also has a different impregnation rate after storage, and after storage, it starts from above and second from below. Presents different makeup remover properties. In the comparative example, the muscle touch was also poor during wiping.

更且，根據使用安定之水中油型乳化組成物和較低 之非織布的比較例B 8，可知即使使用安定的水中油型 組成物，於將薄片積層且保存時，依據含浸薄片之條 得含浸率有差異，且卸妝性能變化並且無法安定維持J 312/發明說明書(補件)/93-07/93111227 對於 -2所 上之 B1 1， 優 片狀 存後 由下 5 0% 例 二牧 B7 密度 乳化 件使 7口質。 43Furthermore, according to Comparative Example B 8 using a stable oil-in-water emulsified composition and a lower non-woven fabric, it can be seen that even when a stable oil-in-water composition is used, the sheets are laminated and stored according to the conditions of the impregnated sheet There is a difference in the impregnation rate, and the makeup removal performance changes and cannot be maintained stably. J 312 / Invention Manual (Supplement) / 93-07 / 93111227 For B1 1 on -2, the excellent flakes are stored from the lower 50%. Example 2 Maki B7 density emulsified pieces make 7 mouthfeel. 43

Claims (1)

200427467 拾、申請專利範圍： 1 . 一種卸妝組成物，其特徵為，含有下列之（A )成分、 及（B )成分的組成物： (A )於水相中含有1〜2 5質量％具有環氧丙烷加成莫耳數3 以上之聚氧丙烯構造，且不具有碳數4個以上之烷基和/ 或聚氧乙烯構造之水溶性化合物（a )的水相；及 (B )於3 0 °C下液狀之油相， 其中，（A)成分與（B)成分之質量比（A):(B)為97:3〜40: 60，水於全組成物中含有多於10質量％。 2 .如申請專利範圍第1項之卸妝組成物，其中，再含有 (C ) 0 · 0 1〜5質量％的水系增黏劑。 3 .如申請專利範圍第2項之卸妝組成物，其中，該（C) 成分為具有斥水部的水系增黏劑。 4 ·如申請專利範圍第1項之卸妝組成物，其中，該（A) 成分中，該水溶性化合物（a)為甘油和/或多甘油的環氧丙 烧加成物。 5 .如申請專利範圍第1項之卸妝組成物，其中，該（B ) 成分為於3 0 °C下具有1 0 m P a · s以下的黏度。 6 ·如申請專利範圍第1項之卸妝組成物，其中，該（B ) 成分為含有5 0質量％以上於1 0 1 3 . 2 5 h P a中之沸點為 1 6 0〜3 0 0 °C的油劑（b )。 7 · —種卸妝組成物，其特徵為，含有下列之（A )、（ B )及 (C )成分： (A )於水相中含有1〜2 5質量％具有環氧丙烷加成莫耳數3 44 312/發明說明書(補件)/93-07/93111227 200427467 以上之聚氧丙烯構造，且不具有碳數4個以上之烷基和/ 或聚氧乙稀構造之水溶性化合物（a )的水相； (B )含有5 0質量％以上於1 0 1 3 · 2 5 h P a中之沸點為 1 6 0〜3 0 0 °C的油劑（b )的油相；及 (C )具有斥水部之水系增黏劑0 · 0 1〜1質量％， 其中，水相（A )與油相（B )之質量比（A ) : ( B )為9 7 : 3〜4 0 : 60 〇 8 . —種片狀卸妝材料，其特徵為，令含有下列之（A )、（ B ) 及（C )成分： (A )於水相中含有1〜2 5質量％具有環氧丙烷加成莫耳數3 以上之聚氧丙烯構造，且不具有碳數4個以上之烷基和/ 或聚氧乙稀構造之水溶性化合物（a)的水相； (B )含有5 0質量％以上於1 0 1 3 . 2 5 h P a中之沸點為 1 6 0〜3 0 0 °C之油劑（b )的油相；及 (C )具有斥水部之水系增黏劑0 · 0 1〜1質量％， 其中，水相（A )與油相（B )之質量比（A ) ·· ( B )為9 7 ·· 3〜4 0 ·· 6 0的水中油型乳化組成物，於纖維素含量為7 0質量％以上 之纖維所構成、密度為0 . 1 5〜0 . 3 g / c m3的非織布中含浸而 成。 9 .如申請專利範圍第8項之片狀卸妝材料，其中，該（B) 成分中之該油劑（b )為異鏈烷烴。 1 0 . —種彩妝除去方法，其特徵為，由皮膚塗佈彩妝化妝 料之區域中除去彩妝之方法，其為使用含有下列之（A )成 分、及（B )成分： 45 312/發明說明書(補件)/93-07/93111227 200427467 (A )於水相中含有1〜2 5質量％具有環氧丙烷加成莫耳數3 以上之聚氧丙烯構造，且不具有碳數4個以上之烷基和/ 或聚氧乙稀構造之水溶性化合物（a )的水相；及 (B )於3 0 °C下液狀之油相， 其中，（A )成分與（B )成分之質量比（A ) : ( B )為9 7 : 3〜4 0 : 6 0，水於全組成物中含有多於1 0質量％的卸妝組成物除去 該彩妝。 46 312/發明說明書(補件)/93-07/93111227 200427467 柒、指定代表圖： (一） 本案指定代表圖為：第（ ）圖。 (二) 本代表圖之元件代表符號簡單說明： 無200427467 Scope of patent application: 1. A makeup remover composition, characterized in that it contains the following components (A) and (B): (A) 1-25% by mass in the water phase A water phase of a water-soluble compound (a) having a polyoxypropylene structure with a propylene oxide addition of 3 or more and an alkyl group having 4 or more carbon atoms and / or a polyoxyethylene structure; and (B) in Liquid phase at 30 ° C, where the mass ratio of (A) component to (B) component (A) :( B) is 97: 3 ~ 40: 60, water contains more than 10% by mass. 2. The makeup removing composition according to item 1 of the patent application scope, further comprising (C) 0. 0 1 to 5% by mass of a water-based tackifier. 3. The makeup removing composition according to item 2 of the patent application scope, wherein the component (C) is a water-based thickener having a water repellent portion. 4. The makeup remover composition according to item 1 of the patent application scope, wherein in the component (A), the water-soluble compound (a) is a glycerol and / or polyglycerin propylene oxide adduct. 5. The makeup removing composition according to item 1 of the patent application scope, wherein the component (B) has a viscosity of 10 m P a · s or less at 30 ° C. 6 · The makeup removing composition according to item 1 of the patent application scope, wherein the (B) component contains 50% by mass or more of 1 0 1 3. 2 5 h The boiling point in P a is 16 0 to 3 0 0 ° C oil (b). 7. A makeup remover composition comprising the following components (A), (B), and (C): (A) 1 to 25% by mass in a water phase with propylene oxide addition mole Number 3 44 312 / Invention Specification (Supplement) / 93-07 / 93111227 200427467 or more Polyoxypropylene structure, and does not have an alkyl group and / or polyoxyethylene structure with 4 or more carbon atoms (a ) Water phase; (B) an oil phase containing an oil agent (b) having a boiling point in the range of 160 to 300 ° C in 50% by mass or more of 10 1 3 · 25 h P a; and ( C) Water-based thickener with water repellent part 0 · 0 1 ~ 1% by mass, wherein the mass ratio (A) of the water phase (A) to the oil phase (B) is 9 7: 3 to 4 0: 60 〇8. — A sheet-like makeup remover characterized in that it contains the following components (A), (B), and (C): (A) 1 to 25% by mass in the water phase with a ring Oxypropane is added to a polyoxypropylene structure with a mole number of 3 or more, and does not have a water phase of a water-soluble compound (a) having an alkyl group with 4 or more carbon atoms and / or a polyoxyethylene structure; (B) contains 5 0 mass% or more Boiling point in 10 a 3. 2 5 h P a 1 6 0 to 3 0 0 ° C oil phase of the oil agent (b); and (C) water-based thickener having a water repellent part 0 · 0 1 to 1 mass%, wherein the water phase (A) and the oil Phase (B) mass ratio (A) .. (B.). An oil-in-water emulsified composition of 9 7... 3 to 4... 60, composed of fibers with a cellulose content of 70 mass% or more. The non-woven fabric with a density of 0.1 5 to 0.3 g / c m3 is impregnated. 9. The sheet-like makeup removing material according to item 8 of the application, wherein the oil agent (b) in the (B) component is an isoparaffin. 1 0. A method for removing makeup, characterized in that the method for removing makeup from the area where the makeup is applied on the skin is to use a component containing the following (A) component and (B) component: 45 312 / Invention Specification (Supplement) / 93-07 / 93111227 200427467 (A) The aqueous phase contains 1 to 25% by mass of a polyoxypropylene structure with a propylene oxide addition mol number of 3 or more, and does not have 4 or more carbon numbers Alkyl group and / or polyoxyethylene-structured water-soluble compound (a) in the aqueous phase; and (B) an oil phase at 30 ° C in a liquid state, wherein (A) component and (B) component are The mass ratio (A): (B) is 97: 3 to 40:60, and water contains more than 10% by mass of the makeup removing composition in the entire composition to remove the makeup. 46 312 / Invention Specification (Supplement) / 93-07 / 93111227 200427467 柒. Designated Representative Map: (1) The designated representative map in this case is: (). (2) Brief description of the component representative symbols of this representative map: None 摘、本案若有化學式時，請揭示最能顯示發明特徵的化學式： 無If there is a chemical formula in this case, please disclose the chemical formula that can best show the characteristics of the invention: None 312/發明說明書(補件)/93-07/93111227312 / Invention Specification (Supplement) / 93-07 / 93111227
TW93111227A 2003-04-22 2004-04-22 Cleansing composition, cleansing sheet and makeup TWI355943B (en)

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JP4629799B2 (en) * 2009-03-27 2011-02-09 株式会社資生堂 Water-in-oil emulsion composition
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KR101379303B1 (en) * 2012-07-13 2014-03-28 김영실 Spray type of form cleanser composition
CN104523507A (en) * 2014-12-16 2015-04-22 广州皇赢生物科技有限公司 Cream cleanser and preparation method thereof
FR3048177B1 (en) * 2016-02-25 2020-10-30 Fabre Pierre Dermo Cosmetique BIPHASE COSMETIC COMPOSITION AND ITS USE BY TOPICAL APPLICATION
CN112292112B (en) * 2018-04-26 2023-09-19 莱雅公司 Two-phase composition for topical application
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EP0714283B1 (en) * 1993-07-03 1999-05-12 The Procter & Gamble Company Personal cleansing compositions
US5840676A (en) * 1994-12-15 1998-11-24 Colgate-Palmolive Company Microemulsion light duty liquid cleaning compositions
US5770554A (en) * 1995-07-20 1998-06-23 Colgate-Palmolive Co. Liquid cleaning compositions
US6063397A (en) * 1996-10-25 2000-05-16 The Procter & Gamble Company Disposable cleansing products for hair and skin

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