TW200422436A - Process and device for pickling metal strip - Google Patents

Process and device for pickling metal strip Download PDF

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Publication number
TW200422436A
TW200422436A TW092120865A TW92120865A TW200422436A TW 200422436 A TW200422436 A TW 200422436A TW 092120865 A TW092120865 A TW 092120865A TW 92120865 A TW92120865 A TW 92120865A TW 200422436 A TW200422436 A TW 200422436A
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TW
Taiwan
Prior art keywords
medium
cleaning
area
pickling
acid
Prior art date
Application number
TW092120865A
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Chinese (zh)
Inventor
Walter Koza
Stefan Fehringer
Original Assignee
Andritz Ag Maschf
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Application filed by Andritz Ag Maschf filed Critical Andritz Ag Maschf
Publication of TW200422436A publication Critical patent/TW200422436A/en

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G3/00Apparatus for cleaning or pickling metallic material
    • C23G3/02Apparatus for cleaning or pickling metallic material for cleaning wires, strips, filaments continuously
    • C23G3/021Apparatus for cleaning or pickling metallic material for cleaning wires, strips, filaments continuously by dipping
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G3/00Apparatus for cleaning or pickling metallic material
    • C23G3/02Apparatus for cleaning or pickling metallic material for cleaning wires, strips, filaments continuously
    • C23G3/027Associated apparatus, e.g. for pretreating or after-treating
    • C23G3/029Associated apparatus, e.g. for pretreating or after-treating for removing the pickling fluid from the objects

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Cleaning In General (AREA)
  • Cleaning By Liquid Or Steam (AREA)

Abstract

A process and a device are described for pickling metal strip, where the material in normal operation passes continuously through at least one pickling section and then enters at least one rinsing section, in which the surface of the material is sprayed with a rinsing medium, which is removed again by at least one pair of squeeze rolls. In order to avoid spots forming on the material being treated if it comes to a standstill in the plant, with the least possible equipment and control instrumentation, as well as using media that are already available in the plant, pickling medium is applied to the surface of the material, at least in sections, if the strip comes to a standstill.

Description

200422436 玖、發明說明: 【發明所屬之技術領域] 本發明係關於-種酸浸金屬帶之方法,其中正常操作中 的材料連續通過至少—個酸浸區4,且然後進人至少一個 清洗區域’其中該材料之表㈣—種清洗媒介物嗔洗,且 該清洗媒介物再次由至少—對擠㈣除去,^㈣於 -種酸浸金屬帶之裝置,該裝置具有在正常操作金屬帶連 續通過運行的至少-個酸浸區域和至少—個其中提供用於 清洗媒介物之喷淋器噴嘴或噴淋器之鄰接清洗區域以及至 少一對擠壓輥。 【先前技術】 在至今已建立的酸浸設備中,由於酸浸媒介物在上乾燥 以及在正常操作中大量通過設備連續進料的帶出現停頓時 氧化,在帶表面上形成斑點。因此開發一種系、统,以允許 在帶出現停頓時泛溢金屬帶,然而,$意味需要大量清洗 媒介物,且清洗區域必須適合應付此大量媒介物。 另方面,已有人建議,如果帶出現停頓,可將惰性或 稀有氣體吹泡進人清洗區域或吹到清洗區域中的帶表面上 而這思味必須提供至少一種亦作為酸浸或清洗媒介 物存在於另相的額外媒介物和適當源以及管道和定量給 料裝置。例如,一種此類系統在歐洲專利第7〇7 668…號 製造中公開。 【發明内容】 因此,本發明之目標為改良上述方法及裝置,以此方式 86815 200422436 在其於裝置中出現停_ 0i m π 、可用攻小可能裝置和控制儀器以及 使用已在I置中存在的媒介物避免於正經處理材料上形 斑點。 為取得這一目標,jf古、+ & 此方去特徵為在帶出現停頓時將正施 加於材料表面的媒介物至少在此區域酸浸。這即使在帶出 現分頓後仍保持正經處理材料之品質,同時仍避免於清洗 區域泛溢該材料。當矣而$ 、 再-人酸浸時’已形成的斑點有效 除去。 双 如果已再_人用酸浸媒介物濕潤的材料表面再用清洗媒介 物噴洗一次,此係一優點。 、 、根據該裝置之第一較佳具體實施例,帶以對正常操作中 運仃方向相反之方向逆向運行進人酸浸區域 方向返回到正當婷栳、,⑽ ^ 木,亚將已再次用酸浸媒介物濕潤的區 域再-次帶到清洗區域。因此,在清洗區域不需額外元件。 無論為附加或作為選擇性㈣實施例使帶反向進 區:或:該帶亦可再用酸浸媒介物喷洗-次,如果如此計書又 車又佳在其逆向往目進入酸浸區域之前。 μ車又咎在π處於停頓時用酸浸媒介物噴洗該帶。 據本土明,第一具體實施例中的裝置特徵為,在裝置 =:=中包括一程式’該程式允許在停頓後帶自動以 w作相反之方向逆向進人酸浸區域,然後使運行方 二3Γ:到正常操作,並將已再次施加酸浸媒介物之區域再 構二!到清洗區域。在此具體實施例中沒有對裂置做出結 文,但僅改變或再規劃控制系統。 86815 200422436 然而’用僅輕微結構變化亦 為噴嘴或喷淋器連接到酸浸媒 ’文或清洗媒介物選擇性進料的 一具體實施例中,無需改變控 體。 可擴展邊裝置,如此該噴淋 介物之進料管並具有允許酸 閥配件。在根據本發明的這 制系統以處理不同帶引導變 以相同方式和相同作用,除清洗媒介物的喷嘴或喷淋器 外,本發明能夠較佳在清洗區域預見酸浸媒介物的 噴淋器。 、/ 【實施方式】 在乂下彳田述中’本發明之具體實施例之實例將更詳細用 附加示意圖說明。圖式中所示簡圖包含部分根據本發明裝 置之示意侧視圖。 在欲經處理帶材料_動的正常方向,在酸浸槽i或用酸 浸媒介物填充的類似者下流提供清洗區域2。在清洗區域2 車“土有數個此夠通過其對材料M施加清洗媒介物的噴淋器 4 ’在酸浸槽1的入口和清洗區域出口提供擠壓輥5。 如果帶Μ停頓數分鐘時間,例士口,由於裝置操作的原因 ’在部分帶上形成斑點,這在清洗區域2很普遍。為再次除 去此等斑點並因此保證所處理材料河的高品質,可通過現 有喷淋器4或額外噴淋器或噴嘴(未顯示)將帶Μ用酸浸媒介 物再喷一次’及/或使材料Μ以對正常操作相反之方向反向 經過一定距離,直到斑點在酸浸槽丨於酸浸媒介物中再次消 失。由帶Μ帶出酸浸槽i的任何酉吏浸媒介物(儘管在槽入口提 供擠壓輥5)在酸浸槽丨上流收集於矮盤中。帶可於停頓處再 86815 200422436 次短暫停留,直到斑點已消失,或者,可立刻再次以正常 運行方向傳輸該材料。 【圖式簡單說明】 圖式中所示簡圖包含本發明裝置部分之示意側視圖。 【圖式代表符號說明】 Μ 帶材料 1 酸浸槽 2 清洗區域 3 矮盤 4 喷淋器喷嘴或喷淋器 5 擠壓輥 86815200422436 发明 Description of the invention: [Technical field to which the invention belongs] The present invention relates to a method for pickling a metal strip, in which materials in normal operation continuously pass through at least one pickling zone 4, and then enter at least one cleaning zone 'Where the surface of the material is washed with a cleaning medium, and the cleaning medium is removed again by at least one pair of squeezes, and the device is provided with an acid leaching metal belt, which has continuous operation of the metal belt during normal operation. Pass at least one acid leaching area and at least one sprayer nozzle or adjacent cleaning area in which the sprayer is provided for cleaning the medium and at least one pair of squeeze rollers. [Prior Art] In the acid leaching equipment that has been established so far, spots on the surface of the belt are formed due to the dwelling of the acid leaching medium on drying and oxidation of the belt continuously fed through the equipment during normal operation. Therefore, a system was developed to allow the metal band to overflow in the event of a pause in the band, however, $ means that a large amount of cleaning medium is needed, and the cleaning area must be suitable to cope with this large amount of medium. On the other hand, it has been suggested that if the belt stops, inert or noble gases can be blown into the person's cleaning area or onto the surface of the belt in the cleaning area and this must be provided as at least one which also acts as an acid dipping or cleaning medium Additional media and suitable sources as well as pipes and dosing devices are present in another phase. For example, one such system is disclosed in the manufacture of European Patent No. 7,007,668 ... [Summary of the Invention] Therefore, the object of the present invention is to improve the above-mentioned method and device, in this way 86815 200422436 appears in its device _ 0i m π, available devices and control devices that can be attacked, and use already existing in the device Avoid the formation of spots on the treated material. To achieve this goal, this feature is characterized by the acid leaching of the medium being applied to the surface of the material at least in this area when the belt pauses. This maintains the quality of the treated material even after the deflection is brought out, while still avoiding overflow of the material in the cleaning area. The formed spots were effectively removed when the acid was re-soaked. Double It is an advantage if the surface of the material wetted by the acid-soaked vehicle is sprayed again with the cleaning medium. According to the first preferred embodiment of the device, the belt is moved back into the acid pickling area in the direction opposite to the direction of transportation in normal operation, and returned to the proper place. The wetted area of the acid leaching vehicle is taken to the cleaning area again. Therefore, no additional components are required in the cleaning area. Whether it is additional or as an optional example, the belt can be reversed into the zone: or: the belt can also be spray-washed with an acid dipping medium, if it is so booked, it is better to enter the acid dipping in its reverse direction Before the area. The μ car also blamed the belt for spray cleaning with leaching medium when π was at a standstill. According to local knowledge, the device in the first specific embodiment is characterized in that a program is included in the device =: =. This program allows the belt to automatically enter the acid leaching area in the opposite direction after the pause, and then makes the operator 2 3Γ: To normal operation, and restructure the area where the acid leaching vehicle has been applied again to the cleaning area. No closure is made in this particular embodiment, but only the control system is changed or re-planned. 86815 200422436 However, in a specific embodiment where 'with only minor structural changes and also nozzles or sprinklers are connected to the acid leaching medium', the selective feeding of the cleaning or cleaning medium, there is no need to change the control body. The side device can be extended so that the spray medium has a feed tube and has an acid valve fitting. In the system according to the present invention, in order to process different belt guides, the same manner and the same effect can be achieved. In addition to the nozzle or sprayer for cleaning the media, the present invention can better predict the sprayer for pickling the media in the cleaning area. . / [Embodiment] In the description of "The Next Step", an example of a specific embodiment of the present invention will be described in more detail with an additional schematic diagram. The diagram shown in the drawings contains a schematic side view of part of a device according to the invention. In the normal direction of the material to be treated, the cleaning zone 2 is provided downstream in the acid pickling tank i or the like filled with the acid pickling medium. In the cleaning area 2, there are several sprayers 4 'through which the cleaning medium can be applied to the material M. The squeeze roller 5 is provided at the entrance of the pickling tank 1 and the exit of the cleaning area. If the belt M is stopped for several minutes, For example, due to the operation of the device, spots formed on part of the belt, which is common in the cleaning area 2. In order to remove these spots again and thus ensure the high quality of the processed material, the existing sprinkler 4 can be passed Or additional sprayers or nozzles (not shown) spray the belt M with the acid leaching medium again 'and / or cause the material M to travel a certain distance in the opposite direction to normal operation until the spots are in the acid leaching tank. The acid leaching medium disappears again. Any official immersion medium brought out of the acid leaching tank i by the belt M (although the squeeze roller 5 is provided at the tank entrance) is collected in the acid leaching tank and collected in the low plate. The stoppage stopped for another 86815 200422436 times until the spots had disappeared, or the material could be immediately transported again in the normal operating direction. [Simplified illustration of the figure] The diagram shown in the figure contains a schematic side view of the device part of the present invention FIG represented by the formula [Legend] 1 Μ material pickling tank with washing area 2 3 4 short shower tray or shower nozzle pressing roller 5 86815

Claims (1)

200422436 拾、申請專利範圍: 1 ’ 種酸浸金屬帶之方法,其中fp A γ t 過至小义^ 、中正吊輛作中的材料連續通 、後進入至少一個清洗區域,其 τ δ亥材料之表面用一種清洗姐八此+ 物再β, 先媒介物噴洗,且該清洗媒介 刃再-人由至少一對擠壓輥除去,直 現俾±5 , ,、特徵為,如果該帶出 見t頓,則將酸浸媒介物施加 域。 j唸柯枓表面至少一些區 2. 根據申請專利範圍第丨項之方 酴、兮丄*人 具特敛為,已再次用 -文/文媒介物濕潤的該材料之 __A 面用、/月洗媒介物再噴洗 3. 根據申請專利範圍第項 斜丁也 ^友具将徵為,該帶以 對正吊操作中運行方向相反之, ^ ^ 祁汉之方向延向運行進入酸浸 -域’然、後使運行方向返回到正f操作,並將已再次用 酸浸媒介物濕潤的區域再一次帶到清洗區域。 4. =申請專利範圍第⑴項中任一項之方法,其特徵為 该帶亦再用酸浸媒介物噴洗-次,如果如此計畫,較佳 在其逆向往回進入酸浸區域之前。 5·根據中請專利範圍第4項之方法,其特徵為該帶在其處 於停頓時用酸浸媒介物喷洗。 6· -種酸浸金屬帶之裝置’該裝置具有至少一個在正常摔 作中帶連續通過運行之酸浸區域⑴和至少一個其中提 供清洗媒介物之喷淋器喷嘴或噴淋器⑷之鄰接清洗區 域⑺以及至少一對擠壓輥(5),其特徵為,在裝置的控制 系統中包括-程式,該程式允許在停頓後帶(m)自動以 86815 7.200422436 對正常操作相反之方向逆向進入酸浸區域,然後使運行 方向返回到正常操作,並將已再次施加酸浸媒介物之區 域再一次帶到清洗區域(2)。 一種酸浸金屬帶之裝置,該裝置具有至少一個在正常操 作中▼連績通過運行之酸浸區域(丨)和至少一個其中提 8. ^㈣ > 物之噴淋器喷嘴或喷淋器(4)之鄰接清洗區 域(+2)以及至少一對擠壓輥(5),其特徵為,該噴淋器喷嘴 或噴淋态(4)係連接到一酸浸媒介物之進料管並具有允 4酉夂/又或^洗媒介物選擇性進料的閥配件。 一種酸浸金屬帶 > 爿士 $ 斗# 作中帶遠二 裝置具有至少一個在正常操 1k過運行之酸浸區域 供清洗媒介物之喑η “ f ^ 域⑺以及至少=:喷淋器⑷之鄰接清洗區 媒介物的噴嘴或其特被為’除用於清洗 供酸浸媒介物之噴嘴器較佳在清咖 86815200422436 Scope of patent application: 1 'A method of pickling metal strips, in which fp A γ t is too small ^, the materials in the Zhongzheng crane operation are continuously passed, and then enter at least one cleaning area, the τ δ Hai material The surface is cleaned with a cleaning agent and then β, the medium is spray-washed first, and the blade of the cleaning medium is removed by at least one pair of squeeze rollers, and then 5 ± 5, is characterized, if the belt After seeing t, the acid leaching vehicle was applied to the domain. At least some areas on the surface of the reading section 2. According to Fang Ji and Xi Xi of the scope of application for patents, the person has a special behavior, and has been used again with the __A surface of the material wetted with -text / cultural media, / Moonwashing medium is resprayed. 3. According to the scope of the application for patents, the oblique Dingye ^ Friends will be charged, the belt is opposite to the running direction in the upright crane operation, ^ ^ extended to the direction of Qihan into the acid immersion -Domain ', and then return the running direction to the positive f operation, and bring the area that has been wetted again with the acid immersion medium to the cleaning area again. 4. = The method according to any one of the scope of the patent application, characterized in that the belt is also spray-washed with an acid leaching medium once. If so planned, it is preferred that it be reversed before entering the acid leaching area. . 5. The method according to item 4 of the patent application, characterized in that the belt is spray-washed with an acid-dipping medium when it is at a standstill. 6. · A device for pickling a metal strip 'The device has at least one pickling zone 连续 with continuous passing operation in normal fall and at least one sprinkler nozzle or spray ⑷ in which cleaning medium is provided The cleaning area ⑺ and at least one pair of squeezing rollers (5) are characterized in that the device's control system includes a program that allows the belt (m) to automatically enter in the reverse direction of normal operation after the pause (m) at 68615 7.200422436 Pickle the area, then return the running direction to normal operation, and bring the area where the pickling vehicle has been applied again to the cleaning area (2). A device for pickling a metal strip, the device has at least one acid pickling zone (丨) that runs continuously during normal operation and at least one of the spray nozzles or showers which are capable of lifting 8. ^ ㈣ > (4) The adjacent cleaning area (+2) and at least one pair of squeeze rollers (5), characterized in that the shower nozzle or spray state (4) is connected to a feed pipe of an acid leaching medium And has valve fittings that allow selective feed of 4 酉 夂 / or ^ wash media. An acid leaching metal belt > 爿 士 $ 斗 # The working remote device has at least one acid leaching area for cleaning the medium in the normal operating 1k operation area, and the at least "f ^ field" and at least = sprinkler The nozzle adjacent to the medium in the cleaning zone or its special designation is' except for the nozzle device for cleaning the acid-leaching medium, preferably in Qingca 86815
TW092120865A 2002-08-07 2003-07-30 Process and device for pickling metal strip TW200422436A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
AT0119402A ATA11942002A (en) 2002-08-07 2002-08-07 METHOD AND DEVICE FOR STICKING METAL TAPES

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Publication Number Publication Date
TW200422436A true TW200422436A (en) 2004-11-01

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US (1) US20040079398A1 (en)
CN (1) CN1485463A (en)
AT (1) ATA11942002A (en)
BE (1) BE1015624A3 (en)
DE (1) DE10332858A1 (en)
TW (1) TW200422436A (en)

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CN105021768A (en) * 2014-04-15 2015-11-04 上海梅山钢铁股份有限公司 Steel plate high-temperature acid washing test apparatus and use method thereof
CN108330499B (en) * 2018-04-20 2023-09-29 国家能源集团谏壁发电厂 Generator rotor coil water loop pickling device

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CN1485463A (en) 2004-03-31
BE1015624A3 (en) 2005-06-07
DE10332858A1 (en) 2004-02-26
ATA11942002A (en) 2003-10-15
US20040079398A1 (en) 2004-04-29

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