TW200406448A - Flame retarded resin composition - Google Patents

Abstract

This invention relates to a flame retarded resin composition, suitable for the application in electric machinery, electronics and electric appliances, which mainly comprises one or blended thermoplastic or thermosetting resin, polar monomer, non-halogen flame retardant, micro-porous inorganic material and flame retardant synergist. Various flame retarded resin compositions for different purposes can be produced by further adjusting various flame retardant materials.

Description

V. Description of the Invention (/) The present invention relates to flame-retardant resin compositions used in electrical, electronic, and electrical products, especially resistive resin compositions that do not contain i !, low smoke yield, and high flame resistance. w High-molecular polymers have become indispensable materials in today's life. Because of their high strength, high plasticity, low price and easy access, etc., they have been applied to various aspects of life. Boundaries and supplies become a convenient and necessary material. However, despite the above-mentioned advantages of polymer materials, compared with other metals and ceramic magnetic materials, they are easier to burn. At this stage, in order to improve the combustion characteristics of polymer admixtures, the most common and effective method is to use letters; and: = Hua Erlu is blended with high-molecular polymers to form a flame retardant resin group two. Although this flame retardant resin composition is low in cost, it has a good flame retardant effect. However, when it burns, it will produce a large amount of black smoke and halogenated chlorine gas, which often obstructs sight during a fire and even hinders the escape speed. At the same time, it can hurt the escapeee's respiratory system and cause human casualties. Therefore, even if the δ-type flame retardant resin composition has the flame retardant effect, it cannot be widely used in complex building structures or other occasions. μ: Therefore, the main object of the present invention is to provide a flame retardant resin composition with more safety, which can achieve the flame retardant properties and at the same time have the safety and environmental protection characteristics such as no dense smoke and tooth hydrogen gas.组合 物。 Composition. In order to achieve the above object, the flame-retardant resin composition of the present invention comprises: a gram of resin 'wherein the resin may be selected from a thermoplastic or a thermosetting tree 3 200406448

1 1-I A7-~~ --—————— 2Z____ V. Description of the invention (2) Separate or two or more types of grease; (Please read the precautions on the back before filling out this page) ^ Polarity sheet of bg Body or its modified thermoplastic or thermosetting resins should be used alone or in combination of two or more types, and a + b = A = 100 pHR, where PHR (Per-Hundred Resin) is 100 parts by weight Resin is used as the basis of the formulation. For example, take 100 parts by weight of resin and add 30 weight of plasticizer. 'The plasticizer added at this time is called 30pHR; c grams of microporous inorganic substances, d grams of non- Halogen flame retardant, ea gram of inorganic filled flame retardant c + d + e = B =: 0.1 to 350 PHR relative to a (resin content), where c, d, and e can be used alone or in combination. In order to further understand the purpose and characteristics of the invention, your reviewers are described in detail as follows:-Line · The flame retardant resin composition of Ben Sheming includes the following: one or more thermoplastic or thermosetting resins used in combination, Remote selection based on fire resistance requirements. The types of resins used are, for example, polyethylene, polypropylene, ethylene and vinyl acetate copolymer (EVA resin), ethylene and ethyl acrylate copolymer (EEA resin), ethylene and acrylic copolymer (ee A resin), ethylene and octene Acid copolymer (POE resin), poly 4 _fluorenyl_fluorene-pentene, _ sub-bond polymer, poly 1-butene, 1,2 butadiene, polystyrene (PS resin), propylene Monostyrene resin (as resin), propylene-butadiene-styrene resin (ABS resin), poly-p-methylstyrene, butadiene-styrene block polymer (K glue, sbs resin), styrene vinyl Isoprene block polymer (SIS resin), benzene dilute-fluorenyl acrylate block polymer (MS resin), styrene-maleic anhydride copolymer (S M A resin) There are 4 papers of stupid ethylene and maleimide. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 200406448 I 'i 1 A7 __ ___B7_____ 5. Description of the invention (>)

Polymer (SM resin), styrene-N-phenylmaleimide copolymer (SM resin), methyl methacrylate-butadiene monostyrene tree _ month purpose (MBS resin) Acrylate-acrylic cyanide-styrene resin (AA resin), acryl cyanide-chlorinated polyethylene-styrene resin (acS resin), acryl cyanide-styrene one (ethylene-propylene-diene ternary copolymer rubber) Multi-component copolymer resin (AES resin), vinyl chloride, vinyl chloride, vinylidene chloride, gasified polyethylene, polyamide resin, polycarbonate resin (PC), polyoxymethylene, polyphenylene ether, polyparaphenylene terephthalate Polyethylene formate (PET), polybutylene terephthalate (pbt), polyphenylene sulfide, copper polyether, polyimide, silicone resin, polymethylmethacrylate, cellulose Resin, polyvinyl acid resin, polyurethane resin, polyurethane resin, phenol resin, amine resin (urea resin, melamine resin), epoxy resin, unsaturated polyester resin, Furan resin, natural rubber (NR), isoprene rubber (IR), butadiene styrene Rubber (SBR), butadiene-propylene hydrogen rubber (NBR), butadiene rubber (BR), ethylene-propylene-diene terpolymer copolymer rubber (ep R, EPDM), butyl rubber (IIR), polysulfide Rubber, acrylic rubber, polyacetal (POM), polyoxyalkylene (pp0), polysulfide styrene (PPS), polysulfone, polytetrafluoroethylene (PTFE) , Polyarylphthalate (DPA, polyarylphthalate), Si resin, polyanl ideimide (PAD), bismaleimide-triazine (BT resin), polyimide ί & Amine bismalei Si imide polyamide bismaleleimide (PAB 5 This paper size applies to Chinese National Standard (CNS) A4 specification (210 χ 297 mm) (Please read the precautions on the back before filling out this page) ·- Line · 200406448 A7 B7 V. Description of the invention (1) M), dilute hydrocarbon-vinyl alcohol copolymer 0iefin—viny 1— aichhol compolymer (GL resin), polyoxybenzyleneC FOB), polymethyl Polymethylpentene (TPX), polypentene Maple polyethersulfone (P E S), polyether imide polyetherimide (P E I), polyaryl ester p〇iyaryiate (P A R), polyether ether ketone (P E E K). The above-mentioned resin is optionally mixed with one or more kinds of flame retardants. The fuel burner, especially a nitrogen-filled fuel burner, includes dihydrogen ammonium phosphate, diammonium hydrogen phosphate, urea phosphate, and guanosine phosphate. , Ammonium polyphosphate, melamine phosphate, melamine, red phosphorus encapsulated white phosphorus, red phosphorus, ammonium polyphosphate, phosphate, phosphite and other flame retardants. The principle of the flame-resistant process of dish-based flame retardants is that during combustion, on the one hand, it promotes the dehydration of polymer materials on the one hand, so that the hydrogen of hydrocarbons and oxygen in the air form water, thereby reducing the temperature of the surrounding environment to achieve flame resistance. ; On the one hand, it will decompose phosphoric acid under high temperature heating, promote the carbonization of polymer compounds, and form a non-combustible coke layer. In addition, phosphoric acid will be further dehydrated and esterified at high temperature to form polyphosphoric acid, which is a glassy melt. The molten body is covered on the surface of the combustion material to form a protective layer, which prevents oxygen from entering the unburned inner layer of the polymer, and inhibits the release of volatile pyrolysates, thereby preventing the spread of the flame and achieving the effect of flame resistance. Agent can get better results. In order to make the resin and the flame retardant have a better binding effect, further add polar monomers or modified thermoplastic or thermosetting resins, do this (please read the precautions on the back before filling this page)-- Line · 200406448 A7 V. Explanation of the invention (f) The method can make the flame retardant resin get higher tensile strength, but it will also cause higher cost. This practice can be omitted when the S material itself has sufficient physical properties after the addition of a flame resistant material. Examples of the so-called polar monomers are (a) i carbon to 50 carbon saturated and unsaturated acid compounds and their salts (b) 2 carbon to 50 carbon saturated and unsaturated acid anhydride compounds and their salts (c) 2 carbonitrile to 50 carbon saturated and unsaturated nitrile compounds and their salts ⑷ 2 carbon to 5G carbon saturated and unsaturated phenol compounds (e) 2 carbon to 50 carbon saturated and unsaturated alcohol compounds (丨) gold test family , Alkaline earths, transition element metals and their salts and their coupling agents. The modified thermoplastic or thermosetting resins described herein are the same as the resins exemplified. In addition, in order to increase the flame resistance, various forms of flame retardants are added to the resin and the mixture. The microporous junction in the present invention; 1 The new microsphere, the diameter of the defined micropore is smaller than-hereinafter referred to as millipore (micr_res ), The pores are straight; = between 2 and 50 coffee is called interstitial pores (㈣〇p〇r⑼, the present, microporous structure material (a oporous an "es〇p〇r〇us stickers :: incoming molecular resin , Contributes to the flame retardancy of polymer resins, =: The quality is beneficial to the flame retardancy of polymer materials, mainly because having a chin can increase the formation of a char layer (char layer). The formation of Laoshan private layer is effective Prevent external oxygen from being transmitted to the inside, and the other aspect is that the thermal energy generated by the combustion of the dipolymer is transferred to the outside. / Xishang Ting In the combustion mechanism, the free radical chain reaction will cut off the high & These inorganic salts are suitable for Chinese National Standards (CNS) A4 (210 x 297 mm) at high temperature.

(Please read the precautions on the back before filling this page) -n n n. -N n cl Order ---- • Line · 200406448 A7 V. Become the absorber of Lewis acid under the description of the invention (&). The free radicals in the chain reaction are absorbed, and the free radical chain reaction is blocked, so that the combustion reaction no longer proceeds. (3) Due to the structure of the microporous structure, there are complex and complicated paths and a large surface area. As a result, the oxygen transmission path is blocked everywhere. The combustible polymer is separated into intermittent conditions, which makes it difficult to burn. The chemical composition of the stable microporous structure material includes: niobium pentoxide (Nb205), aluminum oxide (Al203), titanium dioxide (Ti〇2), hafnium dioxide (ZKK, tungsten oxide (woo, three Silicon aluminum oxide (A1Si〇3), stone pentoxide (AlSiG5), titanium tetraoxide stone howl, silicon dioxide (SiO2), silicon tetraoxide (sioj, aluminum phosphate (A1P〇4), Phosphate phosphate, metal compound (MeAip〇), etc. In addition, an inorganic filler can be further added as the main inorganic flame retardant filler or auxiliary inorganic flame retardant to reduce costs and strengthen physical properties. Fuel, oxygen, ignition energy or temperature 4. The chemical chain reaction is the four major conditions of combustion. When the inorganic materials can provide the four major conditions to block the combustion, it can be called the main ring flame resistant filler. The main inorganic flame resistant filler of the present invention contains hydroxide to oxide system. Flame retardants, types are: aluminum hydroxide, hydroxide, magnesium, calcium hydroxide, alkaline magnesium carbonate, .hyerodrtaliteite type metal hydroxides, oxidized lutetium, thorium oxide, oxidized feed; Shi Peng The acid salt has boron, Boric acid, borax, zinc metaborate, barium metaborate, etc .; stannate and flame retardants use stannous acid, hydroxystannous acid, etc .; Records are dichemical records, pentaoxide records and sodium acid records; and other oxidation translation :, : 1: Iron :: powder, sodium aluminum carbonate, calcium carbonate, magnesium sulfate, expanded graphite powder, etc.

S ¥ Zhang scale applies to Chinese g 豕 standard (Cns) a4 specification (210 X 297) quotation " --------- ’

---------------- (Please read the precautions on the back before filling this page) Order · _-Line · 200406448 V. Description of the invention (combined release; Hydroxide Hydroxide releases water when heated again, and water molecules will be taken away by gasification-partial burning capacity; graphite graphite powder has the ability to block oxygen from contact with combustible materials, and is therefore the main inorganic flame retardant. .The above inorganic flame retardants can be used alone, and the combination of the above two flame retardants will have better flame retardant effect. One "", the machine has non-combustibility, and the use of filling flame retardants is an auxiliary non-combustible material. For example, mica, barium sulfate, sulfur, gypsum, oxidized stone Xishan Γ / dead soil, oxidized salt, carbonic acid carbonate, carbonated ballroom dance, stone Xi acid acid, talc, kaolin clay, clay, zeolite, carbon black, glass fiber Taking into account the compatibility of the above-mentioned flame-resistant inorganic substances with resin, the moldability appearance of the flame-resistant resin composition, etc. It is recommended to use an inorganic particle with an average particle size of 0.25 metre, especially about 0.2 um For the same reason, the surface of inorganic compounds is Acid Si amines, fatty acid salts, fatty acid salts, aliphatic alcohols, petrolatum coupling agents, titanium coupling agents, osmium coupling agents, silane oils, phosphate esters and other surface treatments can obtain a flat molding appearance. 0 In addition, in the fire Smoke often occurs in the field because some small particles are generated during combustion. These small particles are caused by the temperature difference of the fire field and the disturbance of the hot air flow, causing small particle fragments to fly around, obstructing people's horizons, and affecting people's ability to escape the fire field. In order to avoid or reduce the amount of smoke, we will appropriately add a smoke suppressant to the flame retardant resin composition. The smoke suppressant used in the flame retardant resin composition includes borate, borate, amine borate, and barium metaborate. ; Molybdenum oxide, molybdate, amine molybdate; zinc phosphate, copper phosphate, nickel phosphate, and zinc sulfate, chromium oxalate, copper oxalate, etc. It helps 9 200406448 A7 V. Description of the invention (&) The completeness of combustion, avoiding the products after combustion to avoid becoming small solid particles, in order to facilitate the opportunity for people to escape at a dangerous time. Furthermore, doped with high molecular weight siloxane Polymers help reduce the amount of heat generated during combustion (to reduce the rate at which macromolecules are thermally cracked into flammable small molecules during combustion) and the amount of smoke (reduce barriers to escape from the fire, and increase the chance of survival for personnel). What is better than other inorganic additives is that there will be no more adding and processing will be more difficult. This is a good method to help prevent combustion. In other aspects, the flame-retardant resin composition of the present invention can be mixed with other Polymers or additives for other purposes. Examples of such additives are antistatic agents, antioxidants, light stabilizers, heat stabilizers, anti-caking agents, flame retardants, slip agents, ultraviolet absorbers, foaming agents, hair Foam additives, pigments, dyes, hardeners, cross-linking agents, cross-linking assistants, etc. The flame-retardant resin composition of the present invention is weighed to an appropriate weight ratio and placed in a polymer resin kneading, blending or mixing machine Only when the above components are uniformly distributed, can a material with consistency and good mechanical properties and flame retardancy be obtained. Use equipment such as a Booth mixer, ten-horsepower mixer, snap mixer, pressurized mixer, uniaxial extruder, biaxial extruder, roller, reaction tank, etc. to mix. If necessary, the granulation step can be used for extrusion molding, injection molding, compression molding, hot compression molding, hollow molding, foam molding and other methods. The molding process selected according to the target object is to reduce the flame resistance of the shell. Resin molding. It was also able to be crosslinked using electron beam irradiation. Because the flame-resistant resin composition of the present invention has a good flame retardant effect, it is suitable for the production of electric wires and cables, enameled wires, and construction. This product is a CNS A4 specification (21G X 297 male f --------

--n n n ϋ · (Please read the precautions on the back before filling this page) Order ·---- Line 200406448 A7 _______________B7 V. Description of the invention (7) Materials, motors, electronics, electrical parts, components. The following is a detailed description of the flame-retardant resin composition provided by the present invention in various embodiments as follows: 1. Embodiment 1: A flame-retardant resin composition characterized by including: aa gram of thermoplastic or thermosetting resin, Among them, the resin type can be used alone or in combination of two or more kinds as required. b grams of polar monomer or modified thermoplastic or thermosetting resin (can be used alone or in combination of two or more). a + br = A = 1〇p service, where the weight of a and dagger can be any ratio, but usually considering the cost factor, a can be designed more than b, where PHR (Per-Hundred Resin) is An ingredient method based on taking 100 parts by weight of resin as an ingredient basis, for example, taking 100 parts by weight of resin and adding 30 parts by weight of a plasticizer, at this time, the added plasticizer is called 30PHR. c grams of microporous structure inorganics, d grams of non-halogen flame retardants, e grams of inorganic filled flame retardants, c + d + e = rB = (M ~ 350 PHR relative to A (resin content), where c, d , E can be used alone or in combination. Fg smoke suppressant, gg high molecular weight siloxane polymer, f + g = E = relative A (resin content). 丨 ~ 35 PHR. (F, g can be used alone or in combination). 0 · relative to a (resin amount); 1 ~ 350 PHR. Example 2: Another flame retardant resin composition, the composition of which includes: This paper Applicable to China National Standard (CNS) A4 (210 x 297 mm)

200406448

5. Description of the invention (/ d) a gram of thermoplastic or thermosetting resin, of which the resin type can be used alone or in combination of two or more. b grams of polar monomer or modified thermoplastic or thermosetting resin (can be used alone or in combination of two or more). a + b = A = i〇〇 PHR, where the weight of a and b can be any ratio, but usually considering the cost factor, a can be designed more than b. c gram microporous structure inorganic substance, d gram non-halogen flame retardant, e gram inorganic filled flame retardant, c + d + e = B = 0.1 to 350 PHR relative to A (resin content). (C, d, ⑽ used alone or mixed). f smoke suppressant per unit weight, f = G = 0.3 PHR relative to A (resin amount). (F, g can be used alone or in combination), B + G = H two phases relative to A (resin amount); 0; [~ 350 PHR. Embodiment 3: Another flame-retardant resin composition, comprising: a gram of thermoplastic or thermosetting resin, wherein the resin type can be used alone or in combination of two or more kinds as required. b grams of polar monomer or modified thermoplastic or thermosetting resin (can be used alone or in combination of two or more), a + b = A = 10.00pHR, where the weight of 3 and dagger can be any ratio , But usually considering the cost factor, & can be designed more than b. c gram of microporous structure inorganic substance, d gram of non-halogen frying agent, e gram of inorganic filled flame retardant, c + d + e = B = ρ 350 PHR relative to A (resin content). (C, d, e can be used alone or in combination). (Please read the precautions on the back before filling this page)-Line · 2004200448 A7 V. Description of the invention (// The above examples are directed to tensile strength, elongation, oxygen index (〇xygen index), UL The fire resistance level is tested, and the results of various tests and experiments are described as follows: (a) Tensile strength: made into a dumbbell test piece, using a tensile machine to extend the force, and measure the force per unit area when it breaks. Strength (kg / mm2) = Pull force (kg) / Dumbbell test piece force cross-sectional area (mm2) \ b) Elongation · Manufactured into a dumbbell test piece, using a tensile machine to extend outward to apply force. The percentage of length deformation per unit length. L〇 = Label length of original dumbbell test piece Ll = Mark length of dummy test piece when broken Elongation (%) KL1-L0) / (L0) (c) Test method for oxygen index (astm

Index) is as follows: g First, a test piece is prepared, and the size of the test piece is 150 mm in length and 6 mm in width. The second child ^ adjusts the intake air volume of oxygen and nitrogen on the device. Wait until the intake air μ ~ 疋, and use the sample handle to put the sample upright into the middle of the glass cover. : The electronic ignition grabs the upper edge of the sample and ignites the time. Lifting the page reduces the supply of oxygen;… when it cannot be ignited, it is necessary to know the supply of milk. The judging criterion is: the fire is more like a insect candle 13 ------------- f (Please read the precautions on the back before filling this page) ----- Order ---- ----- Line Λ!.! Applicable to this paper size ϋο X 297 mm) 200406448 A7 V. Description of the invention (/ >) Burning, burning situation in 3 minutes or 5 cm mark extinction percentage The oxygen index is calculated by the formula: Oxygen Index-(ι〇〇x 〇2) / (N2 + 〇2)%

(d) The test summary of UL94 V-0 ′ H and V-2 is summarized as follows. Prepare a test piece with a size of 127mi long and 127 ugly width (thickness is limited to 12.7 delete according to two). The test piece is hung on the fixture of the testing machine, and a cotton layer of 5lmmx51_X6imn is placed on the test piece = square 305mm. Adjusting Bunsen: 1 Fire 〇: The length is the chest, ignite the test piece with Bunsen burner. Ignition time: Judgment criteria: (1) Remove the source of ignition after ignition, the flame afterflame time, the total number of times is less than 5 "less than" and the flame is not dripped during the test, and those who cause cotton fires "are called V- 0 flame resistant material. (2) Remove the ignition source after ignition, and the flame will last for less than 250 seconds, and the cotton will not be ignited by the flame during the test, which is called V-1 flame retardant material. (3) Remove the source of ignition after ignition, the flame afterflame time is more than a total of seconds, or the dripping of the flame during the test causes the cotton to be called V-2 anti-combustion material. Code description: (a) Resin A001 LLDPE 14 This paper size is applicable to China National Standard (C.NS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) -0 · --- line · 200406448, A7 _B7_ V. Description of the invention (丨 3) (Please read the precautions on the back before filling this page)

A002 EVA A003 EPDM A004 Metallocene PE

(b) Thermoplastic or thermosetting resin modified by polar monomer B001 Maleic acid modified PE (c) Microporous structure inorganic substance C001 Microporous silica (d) Nitrogen-filled fuel agent D001 Phosphate D002 Red phosphorus D003 Phosphate (e) Inorganic filling flame retardant E001 Magnesium hydroxide E002 Aluminum hydroxide (f) Smoke suppressant F001 Zinc borate (g) Siloxane polymer G001 4-7081 (Product of Dow Corning) Example description: Example 1, 1-1 A004 95 B001 5 C001 20 D001 10 D002 0 15 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 200406448 A7 _B7 V. Description of the invention (//) E001 130 F001 10 G001 5 Irganox 1010 2 Tensile strength (kg / mm2) 583 Elongation (%) 1.05 Oxygen index (01) 29.3 UL flame resistance rating V-0 Antioxidant Irganox 1010 (Ciba Fine Chemicals Company) (Please read the precautions on the back first Fill in this page again) The oxygen content in a seepage air is about 20.8 (that is, the oxygen index is 20.8). The oxygen index of polyethylene (PE) is 18, that is, the ignition in the air will not extinguish itself, and there will be continued combustion. . Available at 1-1 and 1-2 values. After UL flame resistance test, repeated ignition ten times, the total afterflame time will not exceed 50 seconds. From the oxygen index test, 10% more oxygen is required to continue burning at room temperature. It is proved that the flame-retardant resin composition of the present invention has a fairly good flame-retardant effect. Example 2 2-1 2-2 A002 83 83 B001 17 17 C001 17 17 D003 8.3 8.3 E002 150 125 F001 4.2 4.2 Irganox 1010 1.2 1.2 Tensile strength (kg / mm2) 1.06 1.14 Elongation (%) 196 206 Oxygen index (01) 37.6 34.6 UL flame resistance rating V-0 V-0 Antioxidant Irganox 1010 (product of Ciba Refining Co., Ltd.) 16 • Wire Φ This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 200406448 A7 V. Description of the invention (It can be known from the values of 1 and 2-2 that from the oxygen index test, the polymer will be better at room temperature but the oxygen index will be better. 丄 Example. 3-1 η A001 '7Π' A003 30 ~-C001 ΙΓ ~~ D001 ~ 10 ^ E002 Ϊ30 ~ Irganox 1010 2 Tensile strength (kg / mm2) 0.12 ~~ " Elongation (%) 142 '' Oxygen index (01) 3U ~~ UL flame resistance grade V- 0 ~~ '~ Antioxidant Irgan〇x delete (ciba refined chemical products) ------ I --------- (Please read the precautions on the back before filling this page) Ding Bu The value of η can be known that 'less polar and greater 5¾ B. As mentioned above, the present invention can indeed achieve excellent flame resistance, does not contain hormones during combustion, and has low smoke production. Practicality: It is used in the current manufacturing method of fire-resistant materials in the industry. It has the same damage as I, progress, and meets the requirements of invention patents. It is submitted in accordance with the law. 17 This paper size is applicable to China (CNS) A4 specifications (21 〇X 297 mm)

I

Claims (1)

200406448 A8 B8 C8 D8 夂, patent application scope 1 · A flame retardant resin composition, whose composition contains: (Please read the precautions on the back before filling out this page} ta grams of resin, where the resin can be selected from thermoplastic or thermosetting Shuyue said alone or in combination of 2 or more types; ^ b grams of polar monomers or modified thermoplastic or thermosetting resins should be used alone or in combination of 2 or more types, and a + b = A = 100 phr; ^ C grams of microporous structure inorganic substances, d grams of non-halogen flame-resistant Wee grams of natural gas filled fuel c + d + e = B = relative A (resin content), 0.1350 PHR, where c, d and e can be used singly or in combination. 2 · The flame retardant resin composition according to item 1 of the patent application scope, wherein the component further comprises: f smoke suppressant per unit weight, so that the relative A (resin amount) is 0 · 1 ~ 350 PHR, B + G = H = PHR relative to A (resin content). 3 · The flame retardant resin composition according to item 2 of the patent application scope, wherein the component further includes: g gram of high molecular weight Siloxane polymer, f + g = E = relative A (tree Fat content) (u ~ 35〇PHR, of which fg can be used alone or mixed, B + E = F = relative to A (resin content) 0.1 ~ 350 PHR. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 4. The flame retardant resin composition as claimed in claims 1 to 3, wherein the thermoplastic or thermosetting resin can be selected from one or the following of the following groups: H ethylene 'polypropylene, ethylene and ethyl acetate copolymer ( e VA resin), copolymer of ethylene and ethyl acrylate (eea resin), copolymer of ethylene and acrylic acid (EEA resin), copolymer of ethylene and octanoic acid (POE resin), poly 4-methyl-ammonium pentylene Ionic bond polymerization 18 This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 200406448 Printed clothing A8 B8 C8 D8 of the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Butadiene, 1,2 — butadiene, polystyrene (PS resin), acryl-styrene resin (AS resin), acryl-butadiene-styrene resin (ABS resin), poly-p-methyl Styrene, butadiene-Styrene Polymer (K glue, SBS resin), styrene isoprene block polymer (SIS resin), styrene-methyl methacrylate block polymer (MS resin), styrene-maleic acid Sour wine anhydride copolymer (SM resin), styrene-maleimide copolymer (SM resin), styrene-N-phenylmaleimide copolymer (SM resin), Methyl methacrylate-butadiene-styrene resin (M BS resin), propionate-acrylic cyanide-styrene resin (AAS resin), acryl cyanide-chlorinated polyethylene-styrene resin (ACS resin) 、 Acrylocyanine-styrene- (ethylene-propylene-diene ternary copolymer rubber) multiple copolymer resin (AES resin), gasified ethylene, dichloroethylene, vinylidene dichloride, chlorinated polyethylene, polyamide resin , Polycarbonate resin (p C), polyformaldehyde, polyphenylene ether, polyethylene terephthalate (PE T), polybutylene terephthalate (p-butylene), polyphenylene sulfide, Polyether copper 'polyimide, silicone resin, polymethyl acrylate, cellulose resin, Vinyl acetal resin, polyurethane resin, polyalkyd resin, disc resin, amine resin (urea resin, melamine resin), epoxy resin, unsaturated polyester resin, furan resin , Natural Rubber (NR), Isoprene Rubber (IR), Butadiene Styrene Rubber (SBR), Butadiene-Propylene Hydrogen Rubber (NBR), Butadiene Rubber (BR), Ethylene-propylene Dilute hydrocarbon ternary copolymer rubber (£ p R, EPD Μ), butyl rubber (IIR), polysulfide rubber, propylene 19 This paper is applicable to China National Standard (CNS) A4 (210 X 297 mm) '" (Please read the notes on the back before filling this page) Erding · 'Line 4 200406448 A8 B8 C8 D8 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 6. Apply for a patent Pak Wai Rubber, Polyacetal (P 〇), polyoxyphenylene (PP〇), polysulfide styrene (PPS), polysulfone resin (polysulfone), polytetrafluoroethylene (PTFE, polytetraf luoroethylene), polyarylphthalate (DPA, polyarylphthalate ), Si resin, polyaniline lyanl ideimide (PAD), bismaleimide-triazine (BT resin), polyamide bismaleleimide (PABM), olefin-ethylene glycol copolymer vinyl- alchohol compolymer (GL resin), polyoxybenzylene (FOB), polymethylpentene (TPX), poly-maple polyethersulfone (PES), polyimide polyetherimide (PEI), polyarylate (PAR), polyetheretherketone (PEE K). 5. The flame retardant resin composition as described in claims 1 to 3, wherein the polar monomer is a compound selected from: (a) 1 to 50 carbon saturated and unsaturated acid compounds and salts thereof; (b ) 2 Carbonic anhydride to 50 carbon saturated and unsaturated acid anhydride compounds and their salts. Class (c) 2 carbon nitrile to 50 carbon saturated and unsaturated nitrile compounds and their salts (d) 2 carbon ester to 50 carbon saturated and unsaturated Ester compounds (e) 2-carbon alcohols to 50-carbon saturated and unsaturated alcohol compounds; or (f) metallurgical, alkaline earth, transition element metals and their salts and their coupling agents. 20-square scale is applicable to China National Standard (CNS) A4 (210 X 297 mm) ^ (Please read the precautions on the back before filling this page) Order ··-· Thread-4 200406448 A8 B8 C8 D8 6. Application for patent scope 6 · If the flame retardant resin composition of the application scope of items 1 to 3 'in which the modified thermoplastic or thermosetting resin is thermoplastic or thermosetting The resin may be selected from a single or a combination of the following groups: polyethylene, polypropylene, ethylene and vinyl acetate copolymer (EVA resin), ethylene and acrylic acid copolymer (EEA resin), ethylene and acrylic Acid copolymer (E EA resin), copolymerization of ethylene and octanoic acid * (PO resin), poly 4 monomethyl-1 1 pentene, ionomer, poly 1 butene, fluorene, 2 — butane One dilute, 1 styrene (PS resin), propyl styrene-styrene resin (AS resin), propylene-butadiene-styrene resin (AB s resin), poly-p-methylstyrene, butadiene-benzene Ethylene block polymer (κ gum, s BS resin), styrene isoprene block polymer (s 丨 s resin), styrene-ethylene monomethyl acrylate block polymer (1 ^ 3 resin) Styrene-maleic anhydride wine copolymer (s MA resin) Amine copolymer (SM resin), styrene-n-benzyl maleimide copolymer (SM resin), methyl methacrylate-butadiene-styrene resin (MM BS Resin), acrylate-acrylic-cyano-styrene resin (AAS resin), cyano-chlorinated polyethylene-styrene resin (ACS resin), acryl-cyano-styrene- (ethylene-propylene-propylene) Diolefin ternary copolymer rubber) Multiple copolymer resin (A e S tree month), Ethylene chloride, Ethyl chloride, Polyvinyl chloride, Chlorinated polyethylene, Polyammonium resin, Polycarbonate resin ( PC), polyformic acid, polyphenylene ether, polyethylene terephthalate S (PET), polybutylene terephthalate (PBT), polyphenylene sulfide, polybonded copper, polyimide , Silicone Resin, Polymethyl Methacrylate, Cellulose Resin, Polyvinyl Acetal 21 (Please read > i on the back? Matters before filling out this page j 4 · The paper printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs shall be printed on the same paper as the Chinese National Standard (CNS) A4 (21 × 297 mm). 200406448 Patent application resins, polyurethane resins, polyalkyd resins, phenol resins, amine resins (urea formaldehyde resin, melamine formaldehyde resin), epoxy resin, unsaturated polyester resin, furan resin, natural rubber ( NR), isoprene rubber (IR), butadiene styrene rubber (SBR), butadiene-propylene hydrogen rubber (NBR), butadiene rubber (BR), ethylene-propylene-diene terpolymer Rubber (EPR, EPDM), butyl rubber (IIR), polysulfide rubber, acrylic rubber, polyacetal (pOM), polyoxyalkylene (pp〇), polysulfide styrene (pps), polyboron (PSE), polytetrafluoroethylene (PTF E, polytetrafluoroethylene), polyaryl phthalate (d PA, polyarylphthalate), silicon resin (Si resin), polyaniline ideimide (PAD), bismaleic acid Bismaleimide-triazin e (BT resin), polyamide bismaleleimide (PABM), olefin-viny alcohol compolymer (GL resin), polyoxystyrene xybenzylene (F 〇B), polymethylpentene (TPX), polyether boron polyethersulfone (PES), polyetherimide poiyetherimide (PEI), polyaryl ester poiiyaryiate (pa R), polyamine Ether ketone (PEEK); then the resin is modified by a polar monomer, wherein the polar monomer is a compound selected from: (a) 1 to 50 carbon saturated and unsaturated acid compounds and their salts; (b) 2 Jun to 50 carbon saturated and unsaturated acid liver compounds and their salts 22 This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) " '(Please read the precautions on the back before filling in this page) ---Line- 200406448 Printed clothing A8 B8 C8 D8 by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 6. Application for patents (c) 2 Carbonitrile to 50 carbon saturated and unsaturated nitrile compounds and their salts (d) 2 $ Reverse to 50 carbon saturated and unsaturated vinegar compounds (e) 2 carbon to 50 carbon saturated and unsaturated alcohol compounds; or (f) alkali gold, alkaline earth, transition element metals and their salts and their coupling agents. 7 · If the flame-retardant resin composition of the items 1 to 3 of the patent application scope, wherein the particle diameter of the microporous structure inorganic substance is 50 micrometers (mm) or less, and the diameter of the pores ranges from 0.25 nm to 50 nm Microporous structured substances, and this kind of microporous structured inorganic substances may be selected from the following inorganic compounds: pentoxide (Nb205), alumina (ai203), titanium dioxide (TiO2), Hafnium dioxide (Zr02), tungsten trioxide (W03), silicon aluminum oxide (AlSi03), silicon aluminum pentoxide (A1Si〇5), silicon tetraoxide (SiTi〇4), silicon dioxide (Si〇2) , Silicon tetraoxide (Si04), aluminum phosphate (Alpo4), aluminum phosphate metal compound (MeAlPO). 8 The flame retardant resin composition according to claims 1 to 3 of the patent scope, wherein the flame retardant is a phosphorus nitrogen flame retardant, which is selected from the following compounds: ammonium dihydrogen phosphate, diammonium hydrogen phosphate, urea phosphate, Guanosine phosphate, ammonium polyphosphate, melamine phosphate, melamine, red phosphorus encapsulated white phosphorus, red phosphorus, ammonium polyphosphate, phosphate, or phosphite flame retardant. 9 · The flame retardant resin composition as described in claims 1 to 3, wherein the inorganic filled flame retardant contains a main inorganic flame retardant and an auxiliary inorganic flame retardant; the main inorganic flame retardant is a single or multiple composition selected from the following compounds. · Hydroxide to oxide-based flame retardants include aluminum hydroxide, magnesium hydroxide, and hydrogen23 The paper size is applicable to China National Standard (CNS) A4 (21〇χ 297 mm) (Please read the precautions on the back first (Fill in this page again) · -line · 200406448 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs g. Patent application scope Calcium oxide, alkaline magnesium carbonate; hyodr〇talcite type double metal hydroxide package = alumina, oxidation Magnesium and calcium oxide; Borate-based flame retardants include zinc limonate, boric acid, borax, zinc metaborate, and barium metaborate; stannate and flame retardants include zinc stannate and zinc hydroxystannate; antimony-based flame retardants Use of trioxide, antimony pentoxide and sodium antimonate; molybdenum oxide; ferrocene; silicon powder; sodium hydroxide with basic stone, calcium carbonate, magnesium sulfate; expanded graphite powder; and auxiliary flame resistance It is a single or multiple composition selected from the following compounds: ^ barium acid, sulfuric acid, gypsum, oxidized stone, diatom earth, alumina, calcium osmate, calcium magnesium carbonate, calcium silicate, talc, kaolin, Clay 'Fosite, slave black, glass fiber and other fillers are used in combination. 1．If the flame retardant resin composition of item 9 in the scope of the application for the patent, /, " ,, and the surface of the machine is filled with fatty acids, fatty acid ammonium, fatty acid salts, fatty acid lipids, aliphatic alcohols, and silane coupling agents , Titanium coupling agent, silane oil wI vinegar and other surface treatment can get a flat molding appearance. 1 1 · If the flame retardant resin composition of item 2 to item 3 of the patent application range, and the medium smoke suppressant is a single or multiple composition selected from the following compounds: zinc borate, amine borate, barium metaborate, t salt; molybdenum Molybdenum oxide, molybdenum, octyl molybdenum amine, phosphonate, copper phosphate, nickel phosphate of linate; and sulfate, chromium oxalate, copper oxalate. 1 2 · Please refer to items 1 to 3 of the flame retardant resin composition in the patent scope, and medium flame retardant resin composition for the production of wires and cables, enameled wires, building materials, electronic parts, and components. 3If the flame retardant resin composition of item 113 of the patent scope is declared, other additives can be added to it, and the additive can be selected from the following components 24 (Please read the precautions on the back before filling this page) Order _ --line_ This paper size is applicable to the country mWm ^) A4 (210 X 297) 200406448 Intellectual Property Bureau, Ministry of Economic Affairs, Employee Consumer Cooperatives, printed agricultural A8 B8 VI. Patent application scope · Antistatic agents, antioxidants, Light stabilizer, heat stabilizer, anti-blocking agent, flame retardant, slip agent, ultraviolet absorber, foaming agent, foaming aid, pigment, dye, hardener, cross-linking agent, or cross-linking aid. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)