CN103897254A - Formula of low smoke zero halogen cable sheathing compound - Google Patents
Formula of low smoke zero halogen cable sheathing compound Download PDFInfo
- Publication number
- CN103897254A CN103897254A CN201410086154.7A CN201410086154A CN103897254A CN 103897254 A CN103897254 A CN 103897254A CN 201410086154 A CN201410086154 A CN 201410086154A CN 103897254 A CN103897254 A CN 103897254A
- Authority
- CN
- China
- Prior art keywords
- cable sheathing
- formula
- sheathing compound
- low smoke
- zero halogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000779 smoke Substances 0.000 title claims abstract description 14
- 150000001875 compounds Chemical class 0.000 title abstract 6
- 229910052736 halogen Inorganic materials 0.000 title abstract 4
- 150000002367 halogens Chemical class 0.000 title abstract 4
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 16
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 8
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 8
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 8
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 8
- 239000007822 coupling agent Substances 0.000 claims abstract description 7
- 239000000314 lubricant Substances 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims description 14
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 7
- 239000003112 inhibitor Substances 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 239000004698 Polyethylene Substances 0.000 abstract description 9
- 239000005038 ethylene vinyl acetate Substances 0.000 abstract description 9
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 abstract description 9
- 239000003063 flame retardant Substances 0.000 abstract description 8
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 5
- -1 polyethylene Polymers 0.000 abstract description 4
- 230000032683 aging Effects 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 3
- 229920000573 polyethylene Polymers 0.000 abstract description 3
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 abstract 2
- 238000005299 abrasion Methods 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 239000004595 color masterbatch Substances 0.000 abstract 1
- 239000003344 environmental pollutant Substances 0.000 abstract 1
- 231100000719 pollutant Toxicity 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 description 8
- 239000004033 plastic Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004610 Internal Lubricant Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0853—Ethene vinyl acetate copolymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/18—Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
- H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
Landscapes
- Chemical & Material Sciences (AREA)
- Insulated Conductors (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
Abstract
The invention relates to a formula of a low smoke zero halogen cable sheathing compound. The formula comprises the following components in percentage by mass: 30-45% of EVA (ethylene-vinyl acetate), 3%-4.5% of PE (polyethylene), 35%-47% of aluminum hydroxide, 5%-11% of magnesium hydroxide, 0.4%-1.2% of antioxidant, 0.5%-1.8% of coupling agent, 1.2%-2.8% of silicone master batch, 0.7%-1.8% of lubricant, 1.8%-3.4% of compatilizer and 0.9%-2.3% of black color master batch. The low smoke zero halogen cable sheathing compound has the advantages of good flame retardant property, simple preparation and high forming rate and does not generate pollutants after being burned; the quality of the cable sheathing compound is improved; the flame retardant property, abrasion resistance and ageing resistance of the cable sheathing compound are improved; environments and the physical health of people are protected; the low smoke zero halogen cable sheathing compound is relatively suitable for modern life.
Description
Technical field
The present invention relates to cable sheath technical field, is a kind of formula of low-smoke halogen-free cable line sheath material specifically.
Background technology
The application of cable in life is more and more extensive, in increasing Highrise buildings, using increasing cable, and common cable does not have fire resistance, once Highrise buildings or public place presence of fire, the cable of burning will produce a large amount of hazardous and noxious substances, become people's killer, the flame resistant cable that adopts mica tape to be wound around needs multiple wraps in process of production, due to the restriction of processing condition, often easily cause seam lap place to occur defect, mica tape embrittlement after burning, easily come off, cause fire-resistant weak effect, being difficult to provides safety control for people.
Summary of the invention
Technical problem to be solved by this invention is to provide that a kind of flame retardant properties is good, with low cost, ratio of briquetting is high, uses the formula of safe material, i.e. a kind of formula of low-smoke halogen-free cable line sheath material.
Technical problem to be solved by this invention realizes by the following technical solutions:
A formula for low-smoke halogen-free cable line sheath material, this formula comprises EVA, PE, aluminium hydroxide, magnesium hydroxide, oxidation inhibitor, coupling agent, silicone masterbatch, lubricant, compatilizer, black masterbatch, the shared mass percent of described each component is as follows:
The shared best in quality per-cent of described each component is as follows:
The performance of described each component and effect are as follows:
EVA: i.e. ethylene-vinyl acetate copolymer, owing to having introduced Vinyl Acetate Monomer in ethylene-vinyl acetate copolymer molecular chain, thereby reduce high-crystallinity, improve snappiness, shock resistance, filler intermiscibility and heat seal performance.
PE: i.e. polyethylene, because of polyethylene nonpolarity, so there is the electrical property excellence that dielectric loss is low, dielectric strength is large.
Aluminium hydroxide: aluminium hydroxide can not only be fire-retardant as fire retardant, and can prevent from being fuming, do not produce dropping, do not produce toxic gas.
Magnesium hydroxide: magnesium hydroxide is a kind of novel filled-type fire retardant, during by decomposes, discharge in conjunction with water, absorb a large amount of latent heat, reduce synthetic materials that it the fills surface temperature in flame, there is the polymer unwinds of inhibition and produced inflammable gas is carried out to cooling effect.Decomposing the magnesium oxide generating is again good refractory materials, also can help to improve the fire resistance of synthetic materials, and the water vapour that it is emitted simultaneously also can be used as a kind of smoke suppressant.
Oxidation inhibitor: in the time that it only exists on a small quantity in polymeric system, just can delay or suppress the carrying out of polymkeric substance oxidising process, thereby stop the aging of polymkeric substance and extend its work-ing life, " anti-aging agent " is otherwise known as.
Coupling agent: in plastics compounding, improve a kind of plastics additive of the interface performance of synthetic resins and inorganic filler or strongthener.Claim again surface-modifying agent.It can reduce the viscosity of molten synthetic resin in plastic working process, improves the dispersity of weighting agent to improve processing characteristics, and then makes goods obtain good surface quality and machinery, heat and electrical property.
Silicone masterbatch: in silicone masterbatch, content of siloxane is higher, the viscosity of material is just larger, is more not easy to disperse during for plastics.The content of siloxanes and molecular weight do anti-wear agent compared with Gao Shike and use.
Lubricant: internal lubricant and polymkeric substance have good consistency, it plays a part to reduce force of cohesion between polymer molecule in polymkeric substance inside, thereby improves the internal friction heat-dissipating of plastic melt and the mobility of melt.
Compatilizer: compatilizer increases the consistency of two kinds of polymkeric substance, makes it bonding force between two kinds of polymkeric substance and increases, and forms stable structure, makes disperse phase and external phase even, i.e. compatibilized.Why compatilizer can make the polymer-compatible of two kinds of different in kinds, is because have the cause that can carry out with two kinds of polymkeric substance respectively physics or chemically combined group in its molecule.
Black masterbatch: black masterbatch is the most frequently used a kind of Masterbatch in plastic cement processing, by a high proportion of pigment or additive and thermoplastic resin, the plastic colorant forming through good distribution, its selected resin has good wet and dissemination to tinting material, and be colored material and there is good consistency.
The invention has the beneficial effects as follows: the present invention have flame retardant properties good, manufacture simple, ratio of briquetting is high, do not produce the advantages such as pollutent after calcination; improve the quality of cable sheath material; flame retardant of plastic performance, wear resisting property and ageing resistance are improved; protect the healthy of environment and people, the use of the modern life preferably.
Embodiment
For technique means and creation characteristic that the present invention realizes are easy to understand, below in conjunction with embodiment, the present invention is further set forth.
Embodiment mono-:
A formula for low-smoke halogen-free cable line sheath material, this formula comprises EVA, PE, aluminium hydroxide, magnesium hydroxide, oxidation inhibitor, coupling agent, silicone masterbatch, lubricant, compatilizer, black masterbatch, the shared mass percent of described each component is as follows:
Embodiment bis-:
A formula for low-smoke halogen-free cable line sheath material, this formula comprises EVA, PE, aluminium hydroxide, magnesium hydroxide, oxidation inhibitor, coupling agent, silicone masterbatch, lubricant, compatilizer, black masterbatch, the shared mass percent of described each component is as follows:
Embodiment tri-:
A formula for low-smoke halogen-free cable line sheath material, this formula comprises EVA, PE, aluminium hydroxide, magnesium hydroxide, oxidation inhibitor, coupling agent, silicone masterbatch, lubricant, compatilizer, black masterbatch, the shared mass percent of described each component is as follows:
More than show and described ultimate principle of the present invention, principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; what in above-described embodiment and specification sheets, describe is principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.The claimed scope of the present invention is defined by appending claims and equivalent thereof.
Claims (2)
1. the formula of a low-smoke halogen-free cable line sheath material, it is characterized in that: this formula comprises EVA, PE, aluminium hydroxide, magnesium hydroxide, oxidation inhibitor, coupling agent, silicone masterbatch, lubricant, compatilizer, black masterbatch, the shared mass percent of described each component is as follows:
2. a kind of formula of low-smoke halogen-free cable line sheath material according to claim 1, is characterized in that: the shared best in quality per-cent of described each component is as follows:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410086154.7A CN103897254A (en) | 2014-03-07 | 2014-03-07 | Formula of low smoke zero halogen cable sheathing compound |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410086154.7A CN103897254A (en) | 2014-03-07 | 2014-03-07 | Formula of low smoke zero halogen cable sheathing compound |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103897254A true CN103897254A (en) | 2014-07-02 |
Family
ID=50988853
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410086154.7A Pending CN103897254A (en) | 2014-03-07 | 2014-03-07 | Formula of low smoke zero halogen cable sheathing compound |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103897254A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861293A (en) * | 2015-05-06 | 2015-08-26 | 沈太英 | Flame-retardant polyolefin cable material for electric power industry |
| CN111662495A (en) * | 2020-07-04 | 2020-09-15 | 上海方之德新材料有限公司 | Scratch-resistant low-smoke halogen-free flame-retardant polyolefin cable material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101608032A (en) * | 2008-06-20 | 2009-12-23 | 苏州亨利通信材料有限公司 | Environmental-friendly halogen-free low-smoke flame retardant material for coaxial cable and preparation method thereof |
| CN102977451A (en) * | 2012-12-04 | 2013-03-20 | 苏州亨利通信材料有限公司 | Low smoke zero halogen flame retardant sheath layer for optical cable |
| CN103275385A (en) * | 2013-05-23 | 2013-09-04 | 宝胜科技创新股份有限公司 | Nuclear power halogen-free, low-smoke and flame-retardant cable sheath material with high elongation and long service life and preparation method thereof |
| CN103524869A (en) * | 2013-10-11 | 2014-01-22 | 常熟市中联光电新材料有限责任公司 | Heat-resisting thermoplastic halogen-free low-smoke flame retardant polyolefin plastic for wire and cable |
-
2014
- 2014-03-07 CN CN201410086154.7A patent/CN103897254A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101608032A (en) * | 2008-06-20 | 2009-12-23 | 苏州亨利通信材料有限公司 | Environmental-friendly halogen-free low-smoke flame retardant material for coaxial cable and preparation method thereof |
| CN102977451A (en) * | 2012-12-04 | 2013-03-20 | 苏州亨利通信材料有限公司 | Low smoke zero halogen flame retardant sheath layer for optical cable |
| CN103275385A (en) * | 2013-05-23 | 2013-09-04 | 宝胜科技创新股份有限公司 | Nuclear power halogen-free, low-smoke and flame-retardant cable sheath material with high elongation and long service life and preparation method thereof |
| CN103524869A (en) * | 2013-10-11 | 2014-01-22 | 常熟市中联光电新材料有限责任公司 | Heat-resisting thermoplastic halogen-free low-smoke flame retardant polyolefin plastic for wire and cable |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861293A (en) * | 2015-05-06 | 2015-08-26 | 沈太英 | Flame-retardant polyolefin cable material for electric power industry |
| CN111662495A (en) * | 2020-07-04 | 2020-09-15 | 上海方之德新材料有限公司 | Scratch-resistant low-smoke halogen-free flame-retardant polyolefin cable material |
| CN111662495B (en) * | 2020-07-04 | 2022-10-11 | 上海方之德新材料有限公司 | Scratch-resistant low-smoke halogen-free flame-retardant polyolefin cable material |
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Application publication date: 20140702 |