TR201712330A2 - Hidrojen sülfür gazının hidrojen gazı ve elementel kükürte ayrıştırılması için bir sistem ve yöntem. - Google Patents

Hidrojen sülfür gazının hidrojen gazı ve elementel kükürte ayrıştırılması için bir sistem ve yöntem. Download PDF

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Publication number
TR201712330A2
TR201712330A2 TR2017/12330A TR201712330A TR201712330A2 TR 201712330 A2 TR201712330 A2 TR 201712330A2 TR 2017/12330 A TR2017/12330 A TR 2017/12330A TR 201712330 A TR201712330 A TR 201712330A TR 201712330 A2 TR201712330 A2 TR 201712330A2
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TR
Turkey
Prior art keywords
elemental sulfur
compartment
gas
transmitted
reactor
Prior art date
Application number
TR2017/12330A
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English (en)
Inventor
Karakaya Cüneyt
Original Assignee
Tuepras Tuerkiye Petrol Rafinerileri A S
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tuepras Tuerkiye Petrol Rafinerileri A S filed Critical Tuepras Tuerkiye Petrol Rafinerileri A S
Priority to TR2017/12330A priority Critical patent/TR201712330A2/tr
Priority to PCT/TR2017/050724 priority patent/WO2019035789A1/en
Priority to CN201780095002.5A priority patent/CN111094175B/zh
Priority to US16/638,679 priority patent/US11186916B2/en
Priority to EP17913115.6A priority patent/EP3668816B1/en
Priority to JP2020531418A priority patent/JP7083023B2/ja
Publication of TR201712330A2 publication Critical patent/TR201712330A2/tr

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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/50—Processes
    • C25B1/55—Photoelectrolysis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0495—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by dissociation of hydrogen sulfide into the elements
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/60—Constructional parts of cells
    • C25B9/67—Heating or cooling means
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Treating Waste Gases (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Gas Separation By Absorption (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)

Abstract

Mevcut buluşla hidrojen sülfür (H2S) gazını ayrıştırma sistemi geliştirilmekte olup bu sistem; H2S gazının kabarcıklar halinde verilmesini sağlayan pompayı (1); yoğunluk farkından dolayı birbirine karışmayan, böylece birbirlerine temas ettikleri bölgede ara yüzey (2c) oluşturan, redoks çifti içeren asidik sulu fazı (2a) ve yoğunluğu suyun yoğunluğundan fazla olan, elemental kükürtü çözebilen organik fazı (2b) içeren, pompa (1) vasıtasıyla bahsedilen organik faz (2b) içerisine iletilen H2S kabarcıklarının ara yüzeyde (2c) gerçekleşen oksidasyon reaksiyonu ile elementel kükürte dönüşümünün sağlandığı kolon reaktörünü (2); reaktörde (2) oluşan elementel kükürtün iletildiği, elementel kükürtün kristalize olmasını sağlayıp sistemden alınmasını sağlayan soğutma ünitesini (3; anot elektrodu içeren birinci bölmeyi (5A), katot elektrodu içeren ikinci bölmeyi (5B), birinci bölmeyle (5A) ikinci bölmeyi (5B) ayıran membranı (5C) içeren, reaktördeki (2) asidik sulu fazın (2a) gönderildiği, redoks çifti oksidasyonu ve H+?nın H2'ye indirgenme reaksiyonunun gerçekleştiği, indirgenme reaksiyonunun ardından asidik sulu fazın (2a) tekrar kolon reaktörüne (2) gönderildiği foto/elektrokimyasal hücreyi (5); redoks çifti oksidasyonu ve H+?nın H2'ye indirgenme reaksiyonu için gereken gerilim farkını oluşturarak elektrotlardan birine iletildiği enerji kaynağını (6) içermektedir.
TR2017/12330A 2017-08-18 2017-08-18 Hidrojen sülfür gazının hidrojen gazı ve elementel kükürte ayrıştırılması için bir sistem ve yöntem. TR201712330A2 (tr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
TR2017/12330A TR201712330A2 (tr) 2017-08-18 2017-08-18 Hidrojen sülfür gazının hidrojen gazı ve elementel kükürte ayrıştırılması için bir sistem ve yöntem.
PCT/TR2017/050724 WO2019035789A1 (en) 2017-08-18 2017-12-29 SYSTEM AND METHOD FOR THE DECOMPOSITION OF GASEOUS HYDROGEN SULFIDE IN HYDROGEN GAS AND ELEMENTAL SULFUR
CN201780095002.5A CN111094175B (zh) 2017-08-18 2017-12-29 将气态硫化氢分解成氢气和单质硫的系统和方法
US16/638,679 US11186916B2 (en) 2017-08-18 2017-12-29 System and method for decomposing gaseous hydrogen sulfide into hydrogen gas and elementary sulfur
EP17913115.6A EP3668816B1 (en) 2017-08-18 2017-12-29 A system and method for decomposing gaseous hydrogen sulfide into hydrogen gas and elementary sulfur
JP2020531418A JP7083023B2 (ja) 2017-08-18 2017-12-29 ガス状硫化水素を水素ガスおよび元素硫黄に分解するためのシステムおよび方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
TR2017/12330A TR201712330A2 (tr) 2017-08-18 2017-08-18 Hidrojen sülfür gazının hidrojen gazı ve elementel kükürte ayrıştırılması için bir sistem ve yöntem.

Publications (1)

Publication Number Publication Date
TR201712330A2 true TR201712330A2 (tr) 2019-03-21

Family

ID=64650459

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TR2017/12330A TR201712330A2 (tr) 2017-08-18 2017-08-18 Hidrojen sülfür gazının hidrojen gazı ve elementel kükürte ayrıştırılması için bir sistem ve yöntem.

Country Status (6)

Country Link
US (1) US11186916B2 (tr)
EP (1) EP3668816B1 (tr)
JP (1) JP7083023B2 (tr)
CN (1) CN111094175B (tr)
TR (1) TR201712330A2 (tr)
WO (1) WO2019035789A1 (tr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7336126B2 (ja) * 2019-03-11 2023-08-31 国立研究開発法人産業技術総合研究所 高価数マンガンの製造方法、及び製造装置
CN112569754B (zh) * 2019-09-29 2022-07-01 中国科学技术大学苏州高等研究院 一种生物电化学反应装置及气体纯化方法
CN110791768A (zh) * 2019-10-22 2020-02-14 国电新能源技术研究院有限公司 一种改进的有机物电解制氢系统与方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4436712A (en) * 1982-09-30 1984-03-13 Shell Oil Company Method of removing hydrogen sulfide from gases utilizing a polyvalent metal chelate of nitrilotriacetic acid and electrolytically regenerating the solution
US4544461A (en) * 1983-03-28 1985-10-01 Energy Conversion Devices, Inc. Hydrogen sulfide decomposition cell and catalytic materials therefor
US4526774A (en) * 1984-04-27 1985-07-02 Standard Oil Company (Indiana) Separation of hydrogen sulfide from gaseous and non-aqueous liquid streams
US5648054A (en) * 1995-01-31 1997-07-15 Gas Research Institute Double loop liquid-liquid H2 S removal process
US5908545A (en) * 1997-08-19 1999-06-01 Natural Resources Canada Electrochemical process for decomposing hydrogen sulfide to produce hydrogen and sulfur
AU2003245510A1 (en) * 2003-02-19 2004-09-09 Sheeta Global Technology Corporation A single step removal of hydrogen sulfide from gases
JP5194284B2 (ja) * 2005-03-31 2013-05-08 日鉄鉱業株式会社 硫化水素の処理方法、水素の製造方法および光触媒反応装置
US7378068B2 (en) * 2005-06-01 2008-05-27 Conocophillips Company Electrochemical process for decomposition of hydrogen sulfide and production of sulfur
CN100450917C (zh) * 2006-02-28 2009-01-14 中国石油大学(北京) 从硫化氢气中同时回收硫磺和制取氢气的方法
US20090188164A1 (en) * 2008-01-25 2009-07-30 University Of Central Florida Research Foundation, Inc. Method and system for hydrogen sulfide removal
CN104511236A (zh) * 2013-10-08 2015-04-15 中国石油化工股份有限公司 一种酸性铁离子溶液脱除硫化氢的方法

Also Published As

Publication number Publication date
US20210189573A1 (en) 2021-06-24
JP7083023B2 (ja) 2022-06-09
US11186916B2 (en) 2021-11-30
JP2020532426A (ja) 2020-11-12
EP3668816A1 (en) 2020-06-24
CN111094175A (zh) 2020-05-01
CN111094175B (zh) 2023-02-03
EP3668816B1 (en) 2023-07-12
WO2019035789A1 (en) 2019-02-21

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