TH61728B - Cyano Insecticide Anthra nilamide - Google Patents

Abstract

DC60 (03/03/47) This invention provides a compound of formula 1, N-oxide and its salts, suitable (chemical formula) I, where R1 is Me, Cl, Br, or F; R2 is F, Cl, Br, C1-C4 haloalkyl or C1-C4 haloalkoxy; R3 is F, Cl, or Br; R4 is H; C1-C4 alkyl, C3-C4 alkenyl, C3-C4 alkynyl, C3-C5 cycloalkyl, or C4-C6 cycloalkylalkyl, each substituent replaced by one substituent selected from halogenated, CN, SMe, S(O)Me, S(O)2Me, and OMe; R5 is H or Me; R6 is H, F, or Cl; and R7 is H, F, or Cl. Also disclosed is a method for the control of pests and invertebrates. By exposing pests and invertebrates or their environments to biologically effective quantities of compounds of the formulation 1,N-oxides of those substances or salts of suitable compounds (for example, a mixture described therein), this invention also concerns mixtures for the control of pests and invertebrates comprising biologically effective quantities of compounds of the formulation 1,N-oxides of those substances or salts of suitable compounds and at least one additional component selected from a group consisting of surfactants, solid diluents and liquid diluents. Revised 8/9/2017. This invention provides compounds of the formulation 1,N-oxides and suitable salts of those substances (chemical formula) 1, where R1 is Me, Cl, Br or F; R2 is F, Cl, Br, C1-C4 haloalkyl or C1-C4 haloalkoxy; R3 is F, Cl, or Br; R4 is H; C1-C4 alkyl, C3-C4 alkenyl, C3-C4 alkynyl, C3-C5 cycloalkyl, or C4-C6 cycloalkylalkyl, each substituent replaced by one substituent selected from halogenated, CN, SMe, S(O)Me, S(O)2Me, and OMe substituents; R5 is H or Me; R6 is H, F, or Cl; and R7 is H, F, or Cl. Also disclosed is a method for controlling insect pests and invertebrates comprising the exposure of the insect pests or their environment to a biologically effective amount of a compound of formula 1, N-oxide of such compounds, or salts of a suitable compound (e.g., an element described therein). This invention also concerns the composition for controlling insect pests and invertebrates comprising the exposure of a biologically effective amount of a compound of formula 1, N-oxide of such compounds, or salts of a suitable compound. and at least one additional component selected from the group consisting of surfactants, solid diluents and liquid diluents. ----------------------------------------------------------------------------------------------- (Original) This invention provides a compound of formula 1, N-oxide and its appropriate salts (chemical formulas) where R1 is Me, Cl, Br or F; R2 is F, Cl, Br, C1-C4 haloalkyl or C1-C4 haloalkoxy; R3 is F, Cl or Br; R4 is H; C1-C4 alkyl, C3-C4 alkenyl, C3-C4 alkynyl, C3-C5 cycloalkyl, or C4-C6 cycloalkylalkyl, each selected group is replaced by one substituent selected from the group consisting of halogens, Cn, SMe, S(O)Me, S(O)2Me and OMe; R5 is H or Me; R6 is H, F or Cl; And R7 is H, F, or Cl. Also disclosed is a method for controlling pests and invertebrates comprising the exposure of the pests and invertebrates or their environment to a biologically effective quantity of a compound of the formulation 1,N-oxide of those compounds or a salt of a suitable compound (for example, a mixture described therein). This invention also concerns a mixture for controlling pests and invertebrates comprising a biologically effective quantity of a compound of the formulation 1,N-oxide of those compounds or a salt of a suitable compound and at least one additional component selected from a group consisting of surfactants, solid diluents and liquid diluents.

Claims (14)

Revised 02/11/2018 Claims: None ---------------------------------------------------------------------------------------------------- Newly Revised 8/9/2017 1. Compounds of the formula 1,N-oxide (N-oxide) or salts of those substances 1 (chemical formula) where R1 is Me, Cl, Br or F; R2 is F, Cl, Br or C1-C4 haloalkoxy; R3 is F, Cl or Br; R4 is H; C1-C4 alkyl, C3-C4 alkenyl, C3-C4 alkinyl, C3-C5 cycloalkyl or C4-C6 cycloalkylalkyl, each group may be selectively replaced by one substituent group chosen from groups consisting of halogens, CN, SMe, S(O)Me, S(O)2Me and OMe; R5 is H or Me; R6 is H, F or Cl; and R7 is H, F or Cl. ------------------------------------------------------------------------- (Original) 1. Compounds of the formula I,N-oxides or salts of those substances (chemical formulas) in which: R1 is Me, Cl, Br, or F; R2 is F, Cl, Br, C1-C4 haloalkyls or C1-C4 haloalkoxys; R3 is F, Cl, or Br; R4 is H; C1-C4 alkyls, C3-C4 alkenyls, C3-C4 alkynyls, C3-C5 cycloalkyls, or C4-C6 cycloalkylalkyls, each of which is substituted by one chosen substituent from the halogenated groups, Cn, SMe, S(O)Me, S(O)2Me, and OMe; R5 is H or Me; R6 is H, F, or Cl; and R7 is H, F, or Cl. 2. Compounds of claim 1 where R1 is Me, or Cl; R2 is Cl, Br, CF3, OCF2H, OCF3, or OCH2CF2; and R4 is H, Me, El, i-Pr, t-Bu, CH2CN, CH(Me)CH2SMe, or C(Me)2CH2SMe. 3. Compounds of claim 2 in which: R2 is Cl, Br, CF2 or OCH2CF3; R4 is H, Me, Et or i-Pr; and R5 is H. 4. A mixture for the control of pests and invertebrates, which contains the biologically effective amount of the compounds of claim 1 and at least one additional component selected from a group of surfactants, solid diluents and liquid diluents, in which such mixture also contains the biologically effective amount of at least one additional selected compound or biologically active agent. 5. A mixture of claims under paragraph 4, selecting at least one additional biologically active compound or agent from the insecticides of the pyrethroid, carbamate, neonicotenoid, neuronal sodium channel blocker, macrocyclic lactogenic, gamma-aminobutyric acid (GABA) antagonist, urea insecticide, larval hormone mimics, members of Bacillus thuringiensis, Bacillus thuringiensis delta endotoxin, and naturally occurring or genetically modified viral insecticides. 6. A combination of claims under Article 4, selecting at least one additional biologically active compound or agent from the following: The group includes abamethin, acephate, acetamiprid, acetoprol, amidoflumate (S1955), avermectin, azadirachtin, aziphos-methyl, bifenthrin, bifenachate, bistrifluron, buprofezin, carbofuran, chlorfenapyr, chlorfluazuron, chlorpyrifos, chlorpyrifos-methyl, chromafenozide, clothianidin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, cypermethrin, cyromazine, deltamethrin, diafenthiuron, diazinon, diflubenzuron, dimethoate, dinotefuran, diofenolan. Emamectin, anddosulfan, esfenvalerate, ethiprol, phenothicarb, phenoxycarb, benpropathrin, fenvalerate, fipronil, phlonicamic, flucythrinate, tau-fluvalinate, flufenerim (UR-50701), flufenoxuron, gamma-kalotrin, halofenoside, hexaflumuron, imidacloprid, indoxacarb, isofenphos, lufenuron, malathion, metaldehyde, methamidophos, methidathion, methomyl, methoprene, methoxychlor, methoxyfenozide, methofluthrin, monotrotopos, methoxyfenozide, navaluron. Noviflumuron (XDE-007), oxamyl, parathion, parathion-methyl, permethrin, foreth, phosalone, phosmate, phosphamecon, perimicarb, profenofos, profluthrin, protrifenbut, pymethrocin, pyridalil, pyriproxifen, rotenone, S1812 (Valent) spinozad, speromesifen (BSN 2060), sulprophos, tebufenozide, teflubenzuron, tefluthrin, terbuphos, tetrachlorvinphos, hyacloprid, thiamethoxam, thiodocarb, hyosultap-sodium, tolfenpyrad, tralomethrin, trichlorfon. and triflumuron, aldicarb, fenamiphos, amitraz, kinamehyomat, chlorobenzylate, cyhexatin, dicofol, dienochlor, etoxazole, fenasaquin, fenbutatin oxide, fenpyroximate, hexylthiazox, propargite, pyridaben, tebufenpyrad, Bacullus thuringiensis aizawai, Bacillus thuringiensis kurstaki, Bacillus thuringiensis delta endotoxin, baculovirus, enthomopathogenic bacteria, enthomopathogenic viruses and enthomopathogenic fungi. 7. A mixture of claims under Article 4, which selects at least one additional biologically active compound or agent from the group that already exists. Acetvamiprid, cypermethrin, cyalothrin, cyfluthrin and beta-cyfluthrin, esfenvalerate, fenvalerate, tralomethrin, phenothicarb, methomyl, oxamyl, thiodicarb, clothianidin, imidacloprid, thiacloprid, indoxacarb, spinosad, abamectin, avermectin, emamectin, endosulfan, ethiprol, fipronil, flufenoxuron, triflumuron, diofenolan, pyriproxifen, pymethrocene, amitraz, Bacillus thuringiensis aizawai, Bacillus thuringiensis kurstaki, Bacillus thuringiensis delda endotoxin and entomaphogas. Fungi 8. A method for controlling pests and invertebrates that involves exposing the pests and invertebrates or their environment to a biologically effective quantity of the compounds of claim I. 9. A method for controlling pests and invertebrates, which involves exposing the pests and invertebrates or their environment to a biologically effective quantity of the mixture of claim 4. 10. The method of claiming Article 8 or Article 9 in which pests and invertebrates such as cockroaches, ants or termites are exposed to the compound by ingesting a bait mixture containing the compound. 11. The method of claiming Article 8 or Article 9 in which pests and invertebrates such as mosquitoes, black flies, stable flies, deer flies, horseflies, wasps, yellow jackets, hornets, ticks, spiders, ants, or gnats are exposed to a spray mixture containing the compound dispensed from a spray container. 12. Spray mixtures consisting of: (a) the compounds of claim 1; and (b) the propellant. 13. Lubricating mixtures consisting of: (a) compounds of claim 1; and (b) one or more food materials; (c) selective attractants; and (d) selective humectants. 14. A device for the control of pests and invertebrates comprising (a) the bait mixture of claim 13; and (b) a scaffold adapted to hold the bait mixture, in which the scaffold has at least one opening sized to allow pests and invertebrates to pass through, thus enabling pests and invertebrates to access the bait mixture from a position outside the scaffold, and which also adapts the scaffold to or near a location of potential or known activity for pests and invertebrates.