TH35074B - Method for measuring isotropic gases via spectrometric And the equipment of them - Google Patents

Abstract

DC60 (03/04/47) The correct curve (Fig. 19) was prepared by entering the 12CO2 concentration point and the 13CO2/12CO2 concentration ratio, which were obtained on the calibration curve standard, and the 13CO2 and 12CO2 suction were added. of the sample as a gas with the same concentration ratio of 13CO2/12CO2, but the ratio of 12CO2 is different. The gaseous test sample with 13CO2 and 12CO2 as its constituent gases was introduced into the cell, and measured spectrometrically. The 12CO2 concentration of the gaseous test sample was determined by The approach of spectrometric measurement values allows the correct concentration ratio to be obtained on the standard of the correct curve. and the 12CO2 concentration of the test sample as a gas was obtained. The measured 13CO2/12CO2 concentration ratio was divided by the concentration ratio valid value obtained for making the 13CO2/12CO2 concentration ratio accurate thereby measuring the measurement accuracy of the concentration ratio of 13CO2/12CO2. The gas composition can be adjusted. The correct curve (Fig. 19) is prepared by inserting the concentration point (formula) and concentration ratio (formula) which are found on the standard of the calibration curve and the suction (formula) and (formula) of the substance. gas example with the same concentration ratio (formula) but different ratio (formula) The test sample is a gas that has (formula) and (formula) are gaseous elements being introduced into the cell. and measured spectrometrically, the concentration (formula) of the gaseous test sample was determined by the spectrometric method of measurement. must be obtained on the standard of the correct curve and the concentration (formula) of the gaseous test sample was found. The measured concentration ratio (formula) is divided by the concentration ratio correct value obtained for the concentration ratio (formula) to be correct. The gas composition can be adjusted.

Claims (4)

Disclaimer (all) which will not appear on the advertisement page: 1. Method for measuring two isotopic test gas samples via spectrometrics containing element gases. More than one, including 12CO2 and 13CO2, measures the intensity of the light transmitted throughout the sample. Test as a gas at the appropriate wavelength for the respective element gas and data processing. The method consists of the first step of introducing the test sample as a gas into the cell. And measure the adsorption of gas The respective component in the test sample is a gas; The second step of the determination of the concentration and concentration ratio of the component gas in the test sample is the gas on the calibration curve standard and the third step of obtaining the concentration proportional correction for the element gas on the standard of the calibration. The concentrate of the element gas obtained in the second step by using the pre-prepared corrective curve. By measuring the adsorption of the element gases in the test sample as gases containing the respective element gases. In known concentrations to known concentrations Determination of Concentration and Proportion The component gas concentration in the test sample is a gas on the standardization of the calibration curve and by means of the equation the concentration obtained. And the proportion of the element gas concentration in the test sample to gas, and the division of the component gas concentration ratio obtained in the second step by the correction value. Concentration proportions for respective element gases For this reason, correction of the concentration proportion of The element gas in the test sample was a gas 2. The method as defined in claim 1, where the correction curve was prepared in the third step, was An approximate fourth-order curve representing the relationship between concentrations. And concentration proportion The respective element gas in the sample is the gas collected in the third step. 3. The method for the measurement of isotopic gases spectrometric by means of the test sample as a gas. Where more than one element gas, including 12CO2 and 13CO2, enters the intensity cell The substances transmitted throughout the test sample are gas at the appropriate wavelength for the respective component gases, and data is processed to determine the gas concentration of the elements. In the sample, the test was gas. Method consists of The first step of bringing the test sample into gas Into the cell The suction of the component gases were measured respectively in the test sample as the second step of the determination of the component gas concentration in the test sample as the standard primary gas. Of the calibration curve was prepared by using the data obtained by measuring the sample as gas with gas. Sequential elements in known concentrations within pre-defined ranges. And the third step Of preparing the recalibration curve by applying some data within a limited range of gas concentration. The elements in the test sample were gas initially sought in the second step. And the concentration The elements in the test sample were gas by using a prepared adjustment curve. 4. Method for measuring isothotrophic gas via spectrometry by taking the sample. The test is a gas containing CO into the cell by measuring the intensity of the gas transmitted throughout the test sample in gas at length. Wavelengths are suitable for CO and process intensity data to determine the CO concentration in the test sample as gas. Method consists of The first step of taking the test sample Is gas into the cell And measure the CO2 uptake in the test sample as gas. The second stage of Determination of the CO2 concentration in the test sample as gas on the standard of the calibration curve. The third step of the measurement of the oxygen concentration in the test sample is gas. Resulting in a correction fee Concentrate for CCo2 on the standard of rectifying curves. And the measured oxygen concentration Correction curve It was initially prepared by measuring the uptake of CO2 in samples as gases with known CO and oxygen concentrations. The determination of the CO2 concentration in the sample is the standard gas of the calibration curve and by plotting the CO2 concentration determined by the oxygen concentration and dividing the obtained CO concentration in The procedure with the concentration rectifier for CO2 was determined on the standard of the correction curve. For this reason, the CO2 concentration in the test sample is converted into gas. 5. Method for isotopic gaseous spectrometric by using the test sample into a gas that is With CO and CO into the cell By measuring the intensity of the emits transmitted throughout the test sample. It is a gas with wavelength suitable for CO2 and CO2 and intensity data processing. Objects to determine the concentration of or the concentration ratio between CO2 and CO2. In the test sample is a gas solution consisting of The first step is to introduce a gas sample into the cell and measure the absorption of CO2 and CO2 in the test sample as gas. The second step is the determination of the concentration or concentration of CO2 and CO2 in the test sample as gas into the cell and measure the absorption of CO2 and CO2 in the test sample as gas. The second step is the determination of the concentration or concentration of CO2 and CO2 in the test sample as gas on the standard. Of the calibration curve And the third step of the measurement of concentrations for CO2 and CO2 on the standard of the rectifying curve. And the measured oxygen concentration The curves were initially prepared by measuring the uptake of CO2 and CO2 in samples as gases containing CO2 and CO2 and oxygen at known concentrations. Determination of concentrations or concentration proportions. Between CO2 and CO2 in the sample is a gas. On the standard of the calibration curve And by plotting the concentration or concentration ratio between CO2 and CO2 that was determined oxygen concentration. And by dividing the concentration or concentration ratio between CO2 and CO2 obtained in the second step by the concentration correction or the concentration correction value for that were determined on the standardization of the curves. For this reason, the concentration of or the concentration ratio between CO2 and CO2 in the test sample is gas. 6. l Method for measuring isotopic gaseous spectrometry. The test samples are gases containing CO2 and CO2 as constituents into the cells. Measure the absorbency of the waste transmitted throughout the sample. Tested gas at the appropriate wavelength for the respective component gases. And the concentration Of the standard sequence gases of the calibration curve prepared by measuring the gas sample With the respective gas components in known concentrations How to comprise Measurement of two test samples It is gas that is obtained from one body and if the CO2 concentration in one of the two samples is The gas is higher than the concentration of CO2 in the test sample as another gas, one diluted sample. Tested in such gas to the level of the CO2 concentration equivalent to that of the test sample in gas. Another example And then the determination of the CO2 / CO2 concentration in the test sample in gas, respectively. 7. Method as set out in claim 6, which is supplemented by the preliminary measurement. And the main measure Where the CO2 concentration in the test sample is the first gas. And the second was obtained from one body being measured. Respectively in the initial measurement And if the measured concentration of CO2 in the test sample was the first gas, The measured concentration of CO2 in the test sample was the second gas, the test sample was the first gas. Dilute the CO2 concentration with that of the tester to a second gas. Then, the proportion of the CO2 / CO2 concentration in the test sample is the gas that was found in the primary measurement 8. Methods set out in claim 6, which are supplemented by the primary measurement. And the main measure Where the CO2 concentration in the test sample is the first gas. And the second was obtained from one body being measured. Respectively in the initial measurement And if the measured concentration of CO2 in the test sample is lower than the first gas, The measured concentration of CO2 in the test sample is a second gas, proportional to the CO2 / CO2 concentration in the test sample being the first gas was determined. The second gas sample was then diluted to the CO concentration compared to that of the test sample as the first gas. And the proportion of CO2 / CO2 concentration in the test sample as the second gas, which was diluted, was determined in the main measurement. 9. Isotopic gaseous spectrometric equipment by Determination of gas concentration More than one element, CO2 and CO in the test sample are gas. The device consists of cells for obtaining gas samples. Path for transmission throughout The test sample is gas that is received in the cell. A method for measuring the concentration of mediums transmitted throughout the sample. Tested gas at the appropriate wavelength for the respective component gases. And data processing Of the concentration of Skip the gas method for sucking the test sample into gas. And then mechanically ejected the test sample into the cells at a constant rate during the measurement of the intensity 1 0. The device, as set out in claim 9, is supplemented with a therapeutic method. temperature For the treatment of cells receiving test samples as gases were introduced into them at constant temperature 1. 1. A device for measuring isotopic gaseous spectrometric, adjusted for concentration. Many of the elements in the test sample are gas by taking the test sample. Is gas into the cell The gas concentration passed through the test sample was then measured in gas. At the appropriate wavelength for the respective element gas And data processing of intensity The product consists of a pathway for locating the cells that receive the test sample as the gas that is imported. In it, in the path between the two And image receiver Reference cells that are filled with no reference gas. Absorption at wavelengths for measurements placed in the cell-free and non-cell-and-path part 1 2. The device, as set out in claim 11, is supplemented by a thermoregulatory pathway. For the treatment of cells receiving a test sample as gases were introduced into it. And reference cell at constant temperature 1 3. A device for measuring isotopic gas via spectrometric adjusted for concentration. Of more than one type of Gases in the test sample is gas by taking the test sample Into two cells The gas concentration transmitted throughout the test sample was then measured in gas at the The wave length is suitable for the respective element gas. And data processing of medium intensity It consists of a path for aligning two cells to obtain the test sample as gas is introduced into the That are parallel along the path between the source And image receiver Two cells of different lengths Reference cells were filled with non-absorbent reference gas at the measurement wavelength placed between One of the two shorter cells And the image receiver or during the source And shorter cells and gas flow pathways for constant referencing throughout reference cells at constant flow rate 1. 4. The equipment set out in claim 13 is supplemented by means of thermoregulation. For the treatment of cells that take the test sample into gas that is imported into it. And reference cells at constant temperature